Jay Kochi
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American organic chemist
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Chemistry
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Chemistry
Jay Kochi's Degrees
- PhD Chemistry Stanford University
- Masters Chemistry Stanford University
- Bachelors Chemistry Stanford University
Why Is Jay Kochi Influential?
(Suggest an Edit or Addition)According to Wikipedia, Jay Kazuo Kochi was an American physical organometallic chemist who held lectureship at Harvard University, and faculty positions at Case Institute of Technology, 1962-1969, , Indiana University, 1969 to 1984, and the University of Houston, 1984 to 2008.
Jay Kochi's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Metal-catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic Methodology Including Biochemical Processes (1981) (833)
- Epoxidation of olefins with cationic (salen)manganese(III) complexes. The modulation of catalytic activity by substituents. (1986) (649)
- Vinylation of Grignard reagents. Catalysis by iron (1971) (439)
- Coupling of Grignard Reagents with Organic Halides (1971) (325)
- Mechanism of the chromium-catalyzed epoxidation of olefins. Role of oxochromium(V) cations (1985) (302)
- Halide recognition through diagnostic "anion-pi" interactions: molecular complexes of Cl-, Br-, and I- with olefinic and aromatic pi receptors. (2004) (286)
- Mechanism of oxidative addition. Reaction of nickel(0) complexes with aromatic halides (1979) (282)
- An electrically neutral .sigma.-sulfuranyl radical from the homolysis of a perester with neighboring sulfenyl sulfur: 9-S-3 species (1980) (254)
- Silver(I)-catalyzed oxidative decarboxylation of acids by peroxydisulfate. Role of silver(II) (1970) (250)
- Fresh look at electron-transfer mechanisms via the donor/acceptor bindings in the critical encounter complex. (2008) (250)
- Mechanism of biaryl synthesis with nickel complexes (1979) (242)
- Metal-Catalyzed Oxidations of Organic Compounds in the Liquid Phase: A Mechanistic Approach (1976) (241)
- Isolation and oxidation-reduction of methylviologen cation radicals. Novel disproportionation in charge-transfer salts by x-ray crystallography (1990) (228)
- Charge-Transfer Probes for Molecular Recognition Via Steric Hindrance in Donor-Acceptor Pairs (1997) (227)
- Intermolecular pi-to-pi bonding between stacked aromatic dyads. Experimental and theoretical binding energies and near-IR optical transitions for phenalenyl radical/radical versus radical/cation dimerizations. (2004) (224)
- Electron-transfer kinetics from cyclic voltammetry. Quantitative description of electrochemical reversibility (1981) (217)
- Copper(I) catalysis in cyclopropanations with diazo compounds. Role of olefin coordination (1973) (216)
- Electron transfer from aromatic hydrocarbons and their .pi.-complexes with metals. Comparison of the standard oxidation potentials and vertical ionization potentials (1984) (208)
- Electron-transfer mechanisms for organometallic intermediates in catalytic reactions (1974) (206)
- Stable (long-bonded) dimers via the quantitative self-association of different cationic, anionic, and uncharged pi-radicals: structures, energetics, and optical transitions. (2003) (204)
- Reductive elimination and isomerization of organogold complexes. Theoretical studies of trialkylgold species as reactive intermediates (1976) (187)
- Mechanistic studies of iron catalysis in the cross coupling of alkenyl halides and Grignard reagents (1976) (174)
- Electron Transfer and Charge Transfer: Twin Themes in Unifying the Mechanisms of Organic and Organometallic Reactions (1988) (166)
- Synthesis of olefins. Cross-coupling of alkenyl halides and Grignard reagents catalyzed by iron complexes (1975) (162)
- Molecular and electronic structures of the long-bonded pi-dimers of tetrathiafulvalene cation-radical in intermolecular electron transfer and in (solid-state) conductivity. (2007) (144)
- Donor-acceptor (electronic) coupling in the precursor complex to organic electron transfer: intermolecular and intramolecular self-exchange between phenothiazine redox centers. (2004) (134)
- Solvolytic routes via alkylcopper intermediates in the electron-transfer oxidation of alkyl radicals (1972) (131)
- Mechanistic studies of nickel catalysis in the cross coupling of aryl halides with alkylmetals. Role of arylalkylnickel(II) species as intermediates (1975) (131)
- Nickel catalysis of olefin epoxidation (1987) (131)
- Cationic olefin complexes of copper(I). Structure and bonding in group Ib metal-olefin complexes (1973) (119)
- Cobalt-catalyzed epoxidation of olefins. Dual pathways for oxygen-atom transfer (1987) (115)
- Charge-transfer character of halogen bonding: Molecular structures and electronic spectroscopy of carbon tetrabromide and bromoform complexes with organic σ- and π-donors (2006) (115)
- Conformational effects of sulfur, silicon, germanium, and tin on alkyl radicals. Electron spin resonance study of the barriers to internal rotation (1971) (115)
- Unified view of Marcus electron transfer and Mulliken charge transfer theories in organometallic chemistry. Steric effects in alkylmetals as quantitative probes for outer-sphere and inner-sphere mechanisms (1980) (112)
- Alkenes from acids by oxidative decarboxylation (1968) (112)
- Iron catalysis in the reaction of grignard reagents with alkyl halides (1971) (110)
- Synthesis and molecular structure of oxochromium(V) cations. Coordination with donor ligands (1985) (109)
- Homolytic and ionic mechanisms in the ligand-transfer oxidation of alkyl radicals by copper(II) halides and pseudohalides (1972) (106)
- The Mechanism of the Sandmeyer and Meerwein Reactions (1957) (103)
- Charge-transfer bonding in metal–arene coordination (2000) (100)
- Mechanisms of Organic Oxidation and Reduction by Metal Complexes (1967) (99)
- Chemistry of Alkoxy Radicals: Cleavage Reactions (1962) (99)
- Novel Charge-Transfer Materials via Cocrystallization of Planar Aromatic Donors and Spherical Polyoxometalate Acceptors (2000) (97)
- INNER-SPHERE ELECTRON TRANSFER IN ORGANIC CHEMISTRY. RELEVANCE TO ELECTROPHILIC AROMATIC NITRATION (1992) (96)
- Electrophilic aromatic substitution. Charge-transfer excited states and the nature of the activated complex (1981) (96)
- A New Method for Halodecarboxylation of Acids Using Lead(IV) Acetate (1965) (92)
- Isomerization and electron spin resonance of allylic radicals (1968) (92)
- Steric Control of Electron Transfer. Changeover from Outer-Sphere to Inner-Sphere Mechanisms in Arene/Quinone Redox Pairs (1999) (91)
- Silver(II) complexes in oxidative decarboxylation of acids (1970) (91)
- Continuum of outer- and inner-sphere mechanisms for organic electron transfer. Steric modulation of the precursor complex in paramagnetic (ion-radical) self-exchanges. (2007) (90)
- Electron spin resonance of organosilyl radicals in solution (1969) (88)
- Catalysis by gold. Alkyl isomerization, cis-trans rearrangement, and reductive elimination of alkylgold(III) complexes (1974) (88)
- The mechanism of the copper salt catalysed reactions of peroxides (1962) (87)
- Mechanism of the silver-catalyzed reaction of Grignard reagents with alkyl halides (1971) (87)
- Silver(I) complexation of (poly)aromatic ligands. Structural criteria for depth penetration into cis-stilbenoid cavities. (2000) (87)
- Copper-catalyzed coupling of grignard reagents and akyl halides in tetrahydrofuran solutions (1972) (87)
- Electron-transfer catalysis. Radical chain mechanism for the ligand substitution of metal carbonyls (1982) (86)
- Electron transfer and transient radicals in organometallic chemistry (1986) (85)
- Spectroscopic analysis, coordination geometry, and x-ray structures of nickel(II) compounds with sterically demanding tris(pyrazolyl)borate ligands and azide or (thio)cyanate anions. Crystal and molecular structures of bis[(.mu.-thiocyanato-N,S)(hydrotris(3-isopropyl-4-bromopyrazol-1-yl)borato)nicke (1992) (85)
- Homo coupling, disproportionation and cross coupling of alkyl groups. Role of the transition metal catalyst (2002) (84)
- Catalytic mechanism involving oxidative addition in the coupling of alkylgold(I) with alkyl halides (1972) (84)
- Homoallylic rearrangement and electron spin resonance of cyclopropylcarbinyl radicals (1969) (84)
- Electrophilic cleavage of organogold complexes with acids. The mechanism of the reductive elimination of dialkyl(aniono)gold(III) species (1976) (84)
- Heterogeneous rates of electron transfer. Application of cyclic voltammetric techniques to irreversible electrochemical processes (1980) (83)
- Electron spin resonance of aliphatic hydrocarbon radicals in solution (1968) (81)
- Electrochemical oxidation-reduction of organometallic complexes. Effect of the oxidation state on the pathways for reductive elimination of dialkyliron complexes (1982) (80)
- The charge-transfer motif in crystal engineering. Self-assembly of acentric (diamondoid) networks from halide salts and carbon tetrabromide as electron-donor/acceptor synthons. (2003) (80)
- Intervalence (charge-resonance) transitions in organic mixed-valence systems. Through-space versus through-bond electron transfer between bridged aromatic (redox) centers. (2003) (80)
- Preparation and Structures of Crystalline Aromatic Cation-Radical Salts. Triethyloxonium Hexachloroantimonate as a Novel (One-Electron) Oxidant. (1998) (79)
- Mechanism of reduction of alkyl halides by chromium(II) complexes. Alkylchromium species as intermediates (1970) (79)
- Mechanism of electron transfer oxidation of alkyl radicals by copper(II) complexes (1965) (79)
- The Reactions of Grignard Reagents with Transition Metal Halides: Coupling, Disproportionation, and Exchange with Olefins (1971) (78)
- Redox equilibria of the nitrosonium cation and of its nonbonded complexes (1990) (77)
- Reduction of Organic Halides by Chromium(II). Mechanism of the Formation of Benzylchromium Ion (1964) (77)
- Characterizing the dimerizations of phenalenyl radicals by ab initio calculations and spectroscopy: sigma-bond formation versus resonance pi-stabilization. (2005) (76)
- Dual pathways for manganese catalysis of olefin oxidation with alkyl hydroperoxides (1986) (75)
- Alkylcopper(I) in the coupling of Grignard reagents with alkyl halides (1971) (75)
- Charge-transfer interactions of amines with tetrahalomethanes. X-ray crystal structures of the donor-acceptor complexes of quinuclidine and diazabicyclo [2.2.2]octane with carbon tetrabromide (1987) (74)
- Direct observation of superoxide electron transfer with viologens by immobilization in zeolite (1988) (72)
- Charge-transfer structures of aromatic electron donor-acceptor complexes leading to electron transfer with the electrophilic nitrosonium cation (1991) (72)
- Control of back electron transfer from charge-transfer ion pairs by zeolite supercages (1991) (71)
- X-ray structure analysis and the intervalent electron transfer in organic mixed-valence crystals with bridged aromatic cation radicals. (2002) (70)
- Pair production and cage reactions of alkyl radicals in solution (1970) (70)
- Stereoselective Photodimerization of (E)-Stilbenes in Crystalline gamma-Cyclodextrin Inclusion Complexes. (1999) (70)
- Photolyses of Metal Compounds: Cupric Chloride in Organic Media (1962) (70)
- Cation Radicals as Intermediates in Aromatic Halogenation with Iodine Monochloride: Solvent and Salt Effects on the Competition between Chlorination and Iodination (1994) (70)
- Steric modulations in the reversible dimerizations of phenalenyl radicals via unusually weak carbon-centered π- and σ-bonds (2006) (70)
- Manganese(III) complexes in oxidative decarboxylation of acids (1970) (70)
- Kinetics and mechanism of aromatic oxidative substitutions via electron transfer: application of Marcus theory to organic processes in the endergonic region (1984) (69)
- Diels-Alder topochemistry via charge-transfer crystals: novel (thermal) single-crystal-to-single-crystal transformations. (2001) (69)
- Electron transfer from anthracenes. Comparison of photoionization, charge-transfer excitation and electrochemical oxidation (1984) (68)
- Electron transfer with organometals. Steric effects as probes for outer-sphere and inner-sphere oxidations of homoleptic alkylmetals with iron(III) and iridate(IV) complexes (1979) (68)
- Isolation of the latent precursor complex in electron-transfer dynamics. Intermolecular association and self-exchange with acceptor anion radicals. (2003) (68)
- The Decomposition of Peroxides Catalyzed by Copper Compounds and the Oxidation of Alkyl Radicals by Cupric Salts (1963) (68)
- Mechanisms of aromatic substitution. Role of cation-radicals in the oxidative substitution of arenes by cobalt(III) (1973) (67)
- Reductive coupling of organometals induced by oxidation. Detection of metastable paramagnetic intermediates (1978) (67)
- Steric and electronic effects in ligand substitution of metal carbonyls. Rapid kinetics of labile carbonylmanganese complexes by transient electrochemical techniques (1984) (67)
- Formation of Alkyl Halides from Acids by Decarboxylation with Lead(IV) Acetate and Halide Salts (1965) (67)
- Photochemical and thermal reduction of cerium(IV) carboxylates. Formation and oxidation of alkyl radicals (1968) (66)
- Molecular Structures of Cation···π(Arene) Interactions for Alkali Metals with π- and σ-Modalities (2002) (66)
- Hyperconjugative and p-d homoconjugative effects of silicon, germanium, and tin on alkyl radicals from electron spin resonance studies (1972) (66)
- Anion Recognitions via Cocrystallizations with Organic π-Acids in the Efficient Self-Assembly of Nanoscopic One-Dimensional Molecular Chains (Wires) (2008) (66)
- Disproportionation and Structural Changes of Tetraarylethylene Donors upon Successive Oxidation to Cation Radicals and to Dications (1998) (65)
- Direct Nitrosation of Aromatic Hydrocarbons and Ethers with the Electrophilic Nitrosonium Cation (1994) (65)
- Quinones as electron acceptors. X-ray structures, spectral (EPR, UV-vis) characteristics and electron-transfer reactivities of their reduced anion radicals as separated vs contact ion pairs. (2006) (65)
- Through-space (cofacial) pi-delocalization among multiple aromatic centers: toroidal conjugation in hexaphenylbenzene-like radical cations. (2005) (65)
- Alkenes from halides and epoxides by reductive eliminations with CrII complexes (1968) (64)
- Reactive ion pairs from the charge-transfer excitation of electron donor-acceptor complexes (1986) (63)
- Optimized Electron Transfer in Charge-Transfer Ion Pairs. Pronounced Inner-Sphere Behavior of Olefin Donors (1996) (63)
- Isolation and molecular structure of unusual oxochromium(V) cations for the catalytic epoxidation of alkenes (1983) (63)
- The preorganization step in organic reaction mechanisms. Charge-transfer complexes as precursors to electrophilic aromatic substitutions. (2002) (61)
- Charge-transfer structures of aromatic electron donor-acceptor complexes with titanium tetrachloride. Ground-state and excited-state spectroscopy for redox processes (1992) (61)
- Corrections- Kinetics, Thermodynamics, and Mechanism of the Radical Chain Process for Ligand Substitution of Metal Carbonyls (1983) (60)
- Formation and oxidation of alkyl radicals by cobalt(III) complexes (1968) (60)
- Electron spin resonance of group IV organometallic alkyl radicals in solution (1969) (60)
- Thermal (Iodide) and Photoinduced Electron-Transfer Catalysis in Biaryl Synthesis via Aromatic Arylations with Diazonium Salts (1997) (60)
- Very fast electron migrations within p-doped aromatic cofacial arrays leading to three-dimensional (toroidal) pi-delocalization. (2006) (60)
- Electron-Transfer Mechanisms with Photoactivated Quinones. The Encounter Complex versus the Rehm−Weller Paradigm (1999) (60)
- Charge-transfer mechanism for electrophilic aromatic nitration and nitrosation via the convergence of (ab initio) molecular-orbital and Marcus-Hush theories with experiments. (2003) (60)
- Annihilation of aromatic cation radicals by ion-pair and radical pair collapse. Unusual solvent and salt effects in the competition for aromatic substitution (1987) (59)
- Charge-transfer ion pairs. Structure and photoinduced electron transfer of carbonylmetalate salts (1989) (59)
- Aromatic nitration with ion radical pairs [ArH.cntdot.+,NO2.cntdot.] as reactive intermediates. Time-resolved studies of charge-transfer activation of dialkoxybenzenes (1987) (57)
- Thermal and Photochemical Nitration of Aromatic Hydrocarbons with Nitrogen Dioxide (1994) (57)
- Chemical Activation by Electron Transfer in Charge-Transfer Complexes. Formation and Reactions of Transient Ion Radical Pairs. (1990) (56)
- Noncovalent binding of the halogens to aromatic donors. Discrete structures of labile Br2 complexes with benzene and toluene (2001) (56)
- Formation and decomposition of alkyl-gold(I) complexes (1973) (56)
- Studies on the Mechanism of the Reaction of Peroxides and Alkenes with Copper Salts*,1 (1965) (55)
- Charge-transfer forces in the self-assembly of heteromolecular reactive solids: successful design of unique (single-crystal-to-single-crystal) Diels--Alder cycloadditions. (2001) (55)
- RATES AND MECHANISM OF PROTON TRANSFER FROM TRANSIENT CARBON ACIDS. THE ACIDITY OF METHYLBENZENE CATION RADICALS (1984) (55)
- Charge-transfer excitation of electron donor-acceptor complexes. Direct observation of ion pairs by time-resolved (picosecond) spectroscopy (1983) (55)
- Displacement of alkyl groups from organophosphorus compounds studied by electron spin resonance (1969) (54)
- The role of electron transfer and charge transfer in organometallic chemistry (1980) (54)
- Conformation, Distance, and Connectivity Effects on Intramolecular Electron Transfer between Phenylene-Bridged Aromatic Redox Centers † (2002) (53)
- Thallium(III) in one-electron oxidation of arenes by electron spin resonance (1973) (53)
- Direct Observation of Ultrafast Decarboxylation of Acyloxy Radicals via Photoinduced Electron Transfer in Carboxylate Ion Pairs. (1997) (53)
- Electron-transfer catalysis of ligand substitution in triiron clusters. The role of the bridging ligand in anion radical intermediates (1986) (53)
- Electron spin resonance studies of fluoroalkyl radicals in solutions. I. Structures, conformations, and barriers to hindered internal rotation (1974) (53)
- Unusually Short (C−H···π) Hydrogen Bonds for Effective Supramolecular (Aromatic/Aromatic) Organization in Edge-to-Face Motifs (1998) (52)
- Marcus theory in organic chemistry. Mechanisms of electron and proton transfers from aromatics and their cation radicals (1986) (52)
- Oxidation with Lead(IV). I. Mechanism of the Decarboxylation of Pentanoic Acids (1965) (52)
- The Reduction of Cupric Chloride by Carbonyl Compounds (1955) (52)
- Nickel catalysis in halogen exchange with aryl and vinylic halides (1980) (52)
- Copper(I) catalysis in photocycloadditions. I. Norbornene (1974) (51)
- The Oxidation and Reduction of Free Radicals by Metal Salts (1963) (51)
- The stability of organogold compounds. Hydrolytic, thermal, and oxidative cleavages of dimethylaurate(I) and tetramethylaurate(III) (1977) (51)
- Transition-state barrier for electrophilic reactions. Solvation of charge-transfer ion pairs as the unifying factor in alkene addition and aromatic substitution with bromine (1982) (51)
- Electron-transfer mechanism for aromatic nitration via the photoactivation of EDA (electron donor-acceptor) complexes. Direct relationship to electrophilic aromatic substitution (1993) (49)
- Copper(I) catalysis in photocycloadditions. II. Cyclopentene, cyclohexene, and cycloheptene (1974) (49)
- Carbonium ions from alkyl radicals by electron transfer (1968) (49)
- Radical chain mechanisms for alkyl rearrangement in organocobalt complexes (1986) (49)
- Electron spin resonance studies of homolytic substitution reactions. Organoboron, -aluminum, and -gallium compounds (1969) (49)
- Oxidation-reduction and the electrocatalytic ligand substitution of tetracobalt clusters (1986) (48)
- Kinetics and mechanism of oxygen atom transfer from nitro compounds mediated by nickel(0) complexes (1980) (48)
- Autocatalytic decomposition of alkylcopper(I) species. Electron spin resonance spectrum of binuclear copper(O) intermediates (1970) (48)
- Selective Catalysis of Thioether Oxidations with Dioxygen. Critical Role of Nitrosonium EDA Complexes in the Thermal and Photochemical Transfer of Oxygen Atom from Nitrogen Oxides to Sulfur Centers (1995) (48)
- Kinetic Determination of the Monomer-Dimer Equilibrium for Cupric Acetate in Acetic Acid Solutions (1965) (48)
- Epoxidation of olefins with molecular oxygen in the presence of cobalt complexes (1976) (48)
- Role of ion pairs in the photochemistry of electron donor-acceptor complexes. Picosecond spectroscopic studies of arene-tetracyanoethylene systems (1984) (47)
- Charge-transfer structures of aromatic EDA complexes with N-heteroatom-substituted pyridinium cations (1992) (47)
- Isolation of Novel Radical Cations from Hydroquinone Ethers. Conformational Transition of the Methoxy Group upon Electron Transfer (1995) (47)
- Stereochemistry of reductive elimination by chromium(II) complexes (1968) (47)
- Facile Reduction of Alkyl Halides with Chromium(II) Complexes. Alkylchromium Species as Intermediates (1966) (46)
- Elimination and catalytic decomposition of dialkylmanganese species (1971) (46)
- Direct Observation of the Wheland Intermediate in Electrophilic Aromatic Substitution. Reversible Formation of Nitrosoarenium Cations (2000) (46)
- Electron spin resonance spectra and structures of phosphoranyl radicals in solution (1972) (46)
- Electron spin resonance of primary alkyl radicals. Photolysis of acyl peroxides (1969) (45)
- Charge-transfer mechanism for electrophilic reactions. SE2 cleavage of alkylmetals with iodine (1980) (45)
- MOLECULAR STRUCTURE AND CHARGE TRANSFER EXCITATION OF ELECTRON DONOR-ACCEPTOR COMPLEXES. ION PAIRS FROM ARENES AND MERCURY(II) (1982) (45)
- Crystallographic view of fluidic structures for room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate. (2006) (45)
- I. Ligand transfer of halides (chloride, bromide, iodide) and pseudohalides (thiocyanate, azide, cyanide) from copper(II) to alkyl radicals (1971) (45)
- Arene activation with mercury(II) and thallium(III) electrophiles. Mechanistic relevance of charge-transfer transitions in. pi. -complexes as intermediates (1986) (45)
- ACID CATALYSIS VS. ELECTRON-TRANSFER CATALYSIS VIA ORGANIC CATIONS OR CATION-RADICALS AS THE REACTIVE INTERMEDIATE. ARE THESE DISTINCTIVE MECHANISMS ? (1998) (45)
- Direct Observation and Structural Characterization of the Encounter Complex in Bimolecular Electron Transfers with Photoactivated Acceptors (1997) (44)
- Direct observation of the kinetic acidities of transient aromatic cation radicals. The mechanism of electrophilic sidechain nitration of the methylbenzenes (1989) (44)
- Electron-transfer activation in the thermal and photochemical osmylations of aromatic electron donor-acceptor complexes with osmium(VIII) tetroxide (1988) (44)
- Copper Salt-catalyzed Reaction of Butenes with Peresters (1962) (44)
- Electron transfer activation of the Diels-Alder reaction (1982) (44)
- Electron Redistribution of Aromatic Ligands in (Arene)Cr(CO)3 Complexes. Structural (Bond-Length) Changes as Quantitative Measures (2001) (44)
- Reactions of dialkylaurate(I) with electrophiles: synthesis of trialkylgold(III) compounds (1973) (43)
- Charge-transfer excitation of molecular complexes in organic and organometallic chemistry (1991) (43)
- Mechanism of hydrogen transfer from metal hydrides (1979) (43)
- Benzyl Tosylates. I. Preparation and Properties (1953) (42)
- Direct observation of ion-pair dynamics (1985) (41)
- Identification of Photoexcited Singlet Quinones and Their Ultrafast Electron-Transfer vs Intersystem-Crossing Rates (1997) (41)
- Molecular structures of the metastable charge-transfer complexes of benzene (and toluene) with bromine as the pre-reactive intermediates in electrophilic aromatic bromination (2002) (41)
- Contact ion pairs. Picosecond dynamics of solvent separation, internal return, and special salt effect (1992) (40)
- Electron spin resonance studies of the reduction of transition metal complexes with Grignard reagents. 1. Dianion radicals of .beta.-diketonates (1976) (40)
- Mechanism of inner-sphere electron transfer via charge-transfer (precursor) complexes. Redox energetics of aromatic donors with the nitrosonium acceptor. (2001) (40)
- Electron spin resonance study of addition of alkoxy radicals to olefins (1975) (40)
- Donor/acceptor organizations and the electron-transfer paradigm for organic reactivity (2000) (40)
- Photochemical decarboxylation of acids with thallium(III) (1968) (40)
- Polar and Solvent Effects in the Cleavage of t-Alkoxy Radicals (1965) (40)
- Shape-selective access to zeolite supercages. Arene charge-transfer complexes with viologens as visible probes (1989) (40)
- Azoalkanes as electron donors in charge-transfer complexes. Molecular structures with sacrificial (.pi.*,.sigma.*) and increvalent (v) electron acceptors (1987) (40)
- Photoinduced Electron Transfer in Charge-Transfer Crystals by Diffuse-Reflectance (Picosecond) Time-Resolved Spectroscopy (1995) (39)
- SYNTHESIS OF OXOMETALS FROM CARBONYLEMTAL COMPLEXES BY OXIDATIVE DECARBONYLATION WITH DIOXIRANE (1991) (39)
- Oxidation of Allylic Radicals by Electron Transfer: Effect of Complex Copper Salts (1962) (39)
- Cobalt(III) acetate from the ozonation of cobaltous acetate (1971) (39)
- Oxidation of alkyl radicals from decarboxylation of acids by lead(IV) and copper(II) (1968) (39)
- Oxidative aromatic nitration with charge-transfer complexes of arenes and nitrosonium salts (1989) (38)
- Carbon-13 NMR spectra of olefin-copper(I) complexes (1974) (38)
- Ligand bridging and chelation of tetracobalt clusters with difunctional phosphines (1987) (38)
- Oxidation-reduction mechanisms. Inner-sphere and outer-sphere electron transfer in the reduction of iron(III), ruthenium(III), and osmium(III) complexes by alkyl radicals (1982) (38)
- Stepwise assembly of charge-transfer complexes within zeolite supercages as visual probes for shape selectivity (1991) (38)
- METAL ION-FREE RADICAL REACTIONS: COUPLING OF FREE RADICALS (1961) (38)
- Electron spin resonance of free radicals from acetylenes and allenes (1970) (38)
- Solvent effects on the oxidation of alkyl radicals by lead(IV) and copper(II) complexes (1968) (37)
- alpha-Nitration of Ketones via Enol Silyl Ethers. Radical Cations as Reactive Intermediates in Thermal and Photochemical Processes. (1996) (37)
- Electrophilic additions to olefins. A new approach to unifying the mechanisms of bromination and oxymercuration (1981) (37)
- Paterno−Büchi Coupling of (Diaryl)acetylenes and Quinone via Photoinduced Electron Transfer (1998) (36)
- Charge-Transfer Excitation of Electron Donor-Acceptor Complexes in Zeolite Matrixes: Direct Observation of Radical ion Pairs from Picoseconds to Milliseconds by Diffuse-Reflectance Laser Flash Photolysis (1994) (36)
- The Mechanism of Oxidative Decarboxylation with Lead(IV) Acetate (1965) (36)
- Electron spin resonance of alkyl radicals from bicyclobutanes (1969) (36)
- X-ray Structures and Electronic Spectra of the π-Halogen Complexes between Halogen Donors and Acceptors with π-Receptors (2007) (36)
- Carbocations as electron acceptors. Photoexcitation of the charge-transfer complexes of tropylium salts and aromatic hydrocarbons (1989) (36)
- CHARGE TRANSFER SPECTRA AND THE ALKYLATION OF TETRACYANOETHYLENE WITH THE ORGANOMETALLIC DERIVATIVES OF LEAD, TIN, AND MERCURY (1976) (36)
- Photoassisted intermolecular charge-transfer processes for organometals: insertion of tetracyanoethylene and spin adducts with quinones (1978) (35)
- Mechanism of oxidative cleavage of organocobalt(III) macrocycles. Application of electrochemical techniques to irreversible electron-transfer processes (1981) (35)
- Novel catalysis of hydroquinone autoxidation with nitrogen oxides (1994) (35)
- Time-resolved spectroscopy and charge-transfer photochemistry of aromatic EDA complexes with X-pyridinium cations (1992) (35)
- Activation of triiron clusters by electron transfer. Radical anions and dianions of nonacarbonylbis(.mu.3-phenylphosphinidene)triiron and its derivatives (1986) (35)
- Electron spin resonance study of the conformational stabilization of allyl radicals by silicon, germanium, tin, and sulfur substituents. Barriers to hindered internal rotation by line-shape analysis (1972) (34)
- Reactions of Organic Peroxides with Chromium(II). Reduction of Free Radicals by Metal Ions1 (1965) (34)
- Nitrate as an Oxidant in the Reaction of Silver(I) Salts with Grignard Reagents (1972) (34)
- Transition metal hydrides as electron donors. Formation, detection, and dimerization of transient, paramagnetic radical cations from the electrochemical oxidation of tungstenocene hydrides and the crystal structure of the binuclear (Cp2W)2H3+ product (1980) (34)
- Novel Synthesis and Structures of Tris-Annelated Benzene Donors for the Electron-Density Elucidation of the Classical Mills−Nixon Effect (1998) (34)
- Synthesis, structure, and electrochemistry of platinum(II) metallacyclobutanes (1982) (34)
- Reduction of metal carbonyls via electron transfer. Formation and chain decomposition of formylmetal intermediates (1986) (34)
- Cis- and trans-dioxo complexes of chlororuthenium(VI) (1988) (33)
- Ligand exchange of metal carbonyls by chain mechanisms. Electrochemical kinetics of electron transfer catalysis (1983) (33)
- Catalytic reactions of peroxides (1968) (33)
- Benzyl Tosylates. II. The Application of the Hammett Equation to the Rates of their Solvolysis (1953) (33)
- Reactions of Peroxides with Halide Salts. Electrophilic and Homolytic Halogenations (1964) (33)
- Stability of organogold(III) complexes. Isolation and crystal structure of dimethylgold trifluoromethanesulfonate (1977) (32)
- Reversible interchange of charge-transfer versus electron-transfer states in organic electron transfer via cross-exchanges between diamagnetic (donor/acceptor) dyads. (2007) (32)
- Cycloreversion induced by charge-transfer excitation of electron donor-acceptor complexes: wavelength-dependent photochemistry of dianthracene (1985) (32)
- Effects of halogen substitution on alkyl radicals. Conformational studies by electron spin resonance (1972) (32)
- Kinetics and mechanism of aromatic thallation. Identification and proof of competing electrophilic and electron-transfer pathways (1984) (31)
- Synthesis and structures of dioxoruthenium(VI) complexes. Oxo transfer from trans-O2Ru(py)2(O2CR)2 (1990) (31)
- Isolation and X-ray Structure of Chloroarenium Cations as Wheland Intermediates in Electrophilic Aromatic Chlorination (1998) (31)
- Structural and spectral characterization of novel charge-transfer salts of polyoxometalates and the cationic ferrocenyl donor (1995) (31)
- Oxidation of Free Radicals from Unsaturated Compounds by Cupric Salts (1962) (31)
- Structures and photoactivation of the charge-transfer complexes of bis(arene)iron(II) dications with ferrocene and arene donors (1991) (31)
- Electron spin resonance studies of carboxy radicals. Adducts to alkenes (1973) (31)
- "Separated" versus "contact" ion-pair structures in solution from their crystalline states: dynamic effects on dinitrobenzenide as a mixed-valence anion. (2005) (31)
- Nature of electrophiles and electron acceptors. Comparison of their molecular complexes with aromatic donors (1981) (31)
- Paramagnetic hydride and alkyl complexes of niobium(IV) and tantalum(IV) (1974) (30)
- The Mechanism of Toluene and Bibenzyl Formation from Benzylchromium Ion1 (1965) (30)
- Nucleophilic and electron-transfer processes in the ion-pair annihilation of cationic iron complexes (dienyl)Fe(CO)3+ with CpMo(CO)3- (1991) (30)
- Activation of triiron clusters by electron transfer: the pronounced modulation of ETC catalysis by bridging ligands (1987) (30)
- Radical-Cation Catalysis in the Synthesis of Diphenylmethanes via the Dealkylative Coupling of Benzylic Ethers (1995) (30)
- Manganese(0) radicals and the reduction of cationic carbonyl complexes: selectivity in the ligand dissociation from 19-electron species (1986) (30)
- Electron transfer from organolithium and Grignard reagents. Reactions with peroxides (1974) (30)
- Structures and mechanism of multiple ligand substitutions in bicapped tetracobalt clusters (1986) (30)
- DIRECT OBSERVATION OF CARBON-CARBON BOND CLEAVAGE IN ULTRAFAST DECARBOXYLATIONS (1996) (30)
- Importance of work terms in the free energy relationship for electron transfer. (1983) (30)
- Substituent effects in the bridging by oxygen in alkyl radicals by electron spin resonance (1974) (29)
- Alkylation of Pyridinium Acceptors via Thermal and Photoinduced Electron Transfer in Charge-Transfer Salts with Organoborates (1999) (29)
- Catalytic Epoxidation of Hindered Olefins with Dioxygen. Fast Oxygen Atom Transfer to Olefin Cation Radicals from Nitrogen Oxides (1996) (29)
- Selective nitration versus oxidative dealkylation of hydroquinone ethers with nitrogen dioxide (1994) (28)
- pi. Complexes of nickel(0) and ketones. Mechanism of formation and the crystal structure of (benzophenone)bis(triethylphosphine)nickel (1979) (28)
- Rearrangement and decomposition of trialkylgold(III) complexes (1973) (28)
- Free radicals in thermal and photochemical oxidative decarboxylations with lead(IV) (1967) (28)
- Mechanism of reductive elimination of vic-dihalides by chromium(II) (1967) (28)
- Intramolecular (electron) delocalization between aromatic donors and their tethered cation–radicals. Application of electrochemical and structural probes (2001) (27)
- Electron spin resonance spectra of the thiadiazolothiadiazole radical anion and related sulfur-nitrogen heterocycles (1976) (27)
- Time-resolved charge-transfer spectroscopy of aromatic electron donor-acceptor complexes with nitrosonium. Inner-sphere mechanism for electron transfer in the isoergonic region (1992) (27)
- Oxidation-reduction of carbonylcobalt cation-anion pairs in coupling to dimeric cobalt carbonyls (1989) (27)
- Structure and Chemistry of Malonylmethyl‐ and Succinyl‐Radicals. The search for homolytic 1,2‐rearrangements (1983) (27)
- Studies of cationic gold(I) complexes: Preparation of tris(trans-cyclooctene)gold trifluoromethanesulfonate (1977) (27)
- Kinetic Isotope Effects for Electron-Transfer Pathways in the Oxidative C−H Activation of Hydrocarbons (1998) (27)
- Reductive elimination from organometals. Thermal and induced decomposition of arylmethylnickel(II) complexes (1980) (27)
- Stoichiometry and kinetics of p-methoxytoluene oxidation by electron transfer: mechanistic dichotomy between side chain and nuclear substitution (1984) (27)
- Dialkylaurate(I) complexes and the synthesis of trialkylgold(III) compounds (1973) (27)
- Competition between Intramolecular Rearrangement of Free Radicals and Oxidation by Metal Salts (1964) (27)
- Additions and Corrections - Free Energy Relationship for Electron Transfer Far from Equilibrium. Analysis of Reversibility in the Endergonic Region (1982) (27)
- Shape-Selective Assemblies of Charge-Transfer Complexes as Molecular Probes for Water Adsorption in Zeolites (1995) (27)
- Reductive cyclization of .alpha.,.omega.-dihalides with chromium-(II) complexes (1968) (27)
- The spectral elucidation versus the X-ray structure of the critical precursor complex in bimolecular electron transfers: application of experimental/theoretical solvent probes to ion-radical (redox) dyads. (2008) (27)
- Homolytic rearrangements and the conformations of alkyl radicals by electron spin resonance (1972) (26)
- Cobalt(III) trifluoroacetate: An electron transfer oxidant (1973) (26)
- Polarography of Aromatic Diazonium Salts (1955) (26)
- Electron‐transfer photochemistry of benzocyclobutenes stereospecific electrocyclic reactions of their cation radicals (1988) (26)
- Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds (1976) (26)
- Electron spin resonance of free radicals from alkylcyclopropanes (1969) (26)
- CHROMYL COMPLEXES IN THE DIRECT EPOXIDATION OF ALKENES (1983) (26)
- Conformations and rotation barriers in allylcarbinyl radicals by electron spin resonance (1973) (26)
- Halogen-bonded assembly of hybrid inorganic/organic 3D-networks from dibromocuprate salts and tetrabromomethane. (2007) (26)
- Charge-transfer photochemistry from the donor-acceptor complexes of anthracenes with tetranitromethane (1985) (26)
- The Meerwein Reaction. Catalysis by Cuprous Chloride (1955) (25)
- Shape-selective modulation of ion-pair and triple-ion equilibria in zeolites. Charge-transfer salts of methylviologen iodides (1991) (25)
- Catalytic oxidation of chlorpromazine and related phenothiazines. Cation radicals as the reactive intermediates in sulfoxide formation (1995) (25)
- The question of aromaticity in open-shell cations and anions as ion-radical offsprings of polycyclic aromatic and antiaromatic hydrocarbons. (2006) (25)
- Bridging in .beta.-chloroalkyl radicals by electron spin resonance (1973) (25)
- Photolysis of peresters. Reactions of alkoxy-alkyl radical pairs in solution (1970) (25)
- Electron spin resonance studies of fluoroalkyl radicals in solution. III. Photolysis of perfluoroketones and adduct formation (1974) (25)
- Rearrangements and conformations of chloroalkyl radicals by electron spin resonance (1974) (25)
- A correlation of electrochemical oxidation and ionization potentials of group 4B dimetals. (1985) (25)
- Charge-Transfer Photochemistry of Aromatic π-Complexes. Hexamethylbenzene and Mercuric Trifluoroacetate. (1986) (25)
- Direct observation of metastable organometallic cation radicals from group 4B alkyls (1983) (25)
- Unusually stable chromium(V) perfluoropinacolate complexes (1990) (24)
- Shape-selective assemblage of charge-transfer complexes within channel-type zeolites (1993) (24)
- Synthesis and Molecular Structure of Oxochromium(V) Cations. Coordination with Donor Ligands. (1986) (24)
- Observation of ternary electron donor-acceptor complexes of anthracene by picosecond spectroscopy. Molecular structure of the anthracenophane-tetracyanoethylene complex (1985) (24)
- Addition of Peroxides to Conjugated Olefins Catalyzed by Copper Salts (1962) (24)
- THE COPPER SALT CATALYZED PEROXIDE REACTIONS (1961) (24)
- Unusual structural effects of intermolecular π-bonding in the tetracyanopyrazine (ion-radical) dimer (2009) (24)
- Counter-ion modulation of long-distance pi-bonding of the open-shell p-benzoquinone anions. (2009) (24)
- Efficient charge-transfer photochemistry via fragmentable cation radicals with variable lifetimes. Direct comparison with chloranil sensitization (1989) (24)
- Solvolytic and radical processes in the photolysis of benzylammonium salts (1971) (24)
- The Solvolysis of Benzyl Tosylates. V. Some Solvent Effects (1958) (24)
- REVERSIBLE LINKAGE ISOMERISMS OF β-DIKETONATO LIGANDS. OXYGEN-BONDED AND CARBON-BONDED STRUCTURES IN GOLD(III) ACETYLACETONATE COMPLEXES INDUCED BY PHOSPHINES (1977) (24)
- Activation barriers for heterogeneous and homogeneous electron transfer. Experimental tests for Marcus theory in the oxidation of organometallic complexes (1981) (23)
- Electron-transfer mechanisms in organometallic chemistry. Alkyl transfer from organolead compounds with hexachloroiridate(IV) (1975) (23)
- p-p Homoconjugation in the .beta.-chloroethyl radical (1972) (23)
- Benzyl Tosylates. IV. Halogen Substituent Effects1 (1958) (23)
- Cationic benzene and olefin complexes of copper(I) trifluoromethanesulphonate (1972) (23)
- Facile preparation of α-nitroketones from enol silyl ethers (1993) (23)
- Silver(II) complexes of dipyridyl (1971) (22)
- MECHANISMS OF AROMATIC SUBSTITUTION, ROLE OF CATION‐RADICALS IN THE OXIDATIVE SUBSTITUTION OF ARENES BY COBALT(III) (1973) (22)
- X-ray Crystal Structures and the Facile Oxidative (Au−C) Cleavage of the Dimethylaurate(I) and Tetramethylaurate(III) Homologues (1999) (22)
- Convenient preparation of quinones via the catalytic autoxidation of hydroquinones with nitrogen oxides (1994) (22)
- Electron Transfer in the Thermal and Photochemical Activation of Electron Donor-Acceptor Complexes in Organic and Organometallic Reactions (1994) (22)
- 7-Norbornenyl radical. Chemical and electron spin resonance studies (1973) (22)
- Steric hindrance as a mechanistic probe for olefin reactivity: variability of the hydrogenic canopy over the isomeric adamantylideneadamantane/sesquihomoadamantene pair (a combined experimental and theoretical study). (2002) (22)
- Organometallic Mechanisms and Catalysis: The Role of Reactive Intermediates in Organic Processes (1978) (22)
- Decomposition of Azobisisobutyronitrile in the Presence of Cupric Salts. Oxidation of α-Cyanoalkyl Radicals (1965) (22)
- CATALYSIS BY GOLD, ALKYL ISOMERIZATION, CIS‐TRANS REARRANGEMENT, AND REDUCTIVE ELIMINATION OF ALKYLGOLD(III) COMPLEXES (1974) (21)
- Cofacial Phenylene Donors as Novel Organic Sensors for the Reversible Binding of Nitric Oxide (1998) (21)
- Aromatic nitration with electrophilic N-nitropyridinium cations. Transitory charge-transfer complexes as key intermediates (1992) (21)
- Reactions of Benzoyl Peroxide and Olefins Catalyzed by Copper Salts (1962) (21)
- ELECTRON TRANSFER PROCESSES IN ORGANOPLATINUM COMPLEXES. OXIDATION AND CLEAVAGE OF DIALKYLPLATINUM(II) WITH HEXACHLOROIRIDATE(IV) (1977) (21)
- Autoxidation of n-alkylisoindolines (1968) (21)
- Equilibrium of 17-electron and 19-electron organometallic radicals derived from carbonylmanganese anions and cations (1989) (21)
- Interfacial Electron Transfer to the Zeolite-Encapsulated Methylviologen Acceptor from Various Carbonylmanganate Donors. Shape Selectivity of Cations in Mediating Electron Conduction through the Zeolite Framework (1996) (21)
- Interaction of paramagnetic niobium(IV) hydrides with olefins. Electron spin resonance studies of metastable intermediates (1975) (20)
- Electron-transfer kinetics and ternary equilibria of the nitrogen dioxide(1+)/nitrogen dioxide/dinitrogen tetraoxide system by transient electrochemistry (1991) (20)
- Photoinduced electron transfer in pinacol cleavage with quinones via highly labile cation radicals. Direct comparison of charge-transfer excitation and photosensitization (1993) (20)
- Oxetanes from [2+2] Cycloaddition of Stilbenes to Quinone via Photoinduced Electron Transfer† (1999) (20)
- Electronic structures of intermolecular charge-transfer states in fast electron transfers with tetrathiafulvalene donor. Thermal and photoactivation of [2 + 4] cycloaddition to o-chloranil acceptor. (2006) (20)
- Nucleophilic additions to carbonyl ligands on tetracobalt clusters. Formation of polynuclear formyl and carbene complexes (1987) (20)
- Benzyl Tosylates. III. The Relative Conjugative Aptitudes of the Acetylenic and Ethylenic Bonds (1953) (20)
- Rates of photochemical and thermal decarboxylation of acids by lead (IV) tetraacetate (1969) (20)
- Fluorinated biphenyls from aromatic arylations with pentafluorobenzenediazonium and related cations. Competition between arylation and azo coupling (1997) (20)
- Molecular recognition of NO/NO+ via multicenter (charge-transfer) binding to bridged diarene donors. Effect of structure on the optical transitions and complexation thermodynamics. (2003) (20)
- Formation of metal−metal bonds by ion-pair annihilation: dimanganese carbonyls from manganate(−I) anions and manganese(I) cations (1987) (20)
- Direct Observation of Ion-Pair Dynamics. (1986) (19)
- Concurrent one- and two-electron processes in electrophile/nucleophile interactions of organometallic ion pairs (1990) (19)
- Facile rearrangement and electron transfer of 19-electron radicals from the reduction of the bischelated manganese carbonyl cation Mn(CO)2[PPh2(CH2)2PPh2]2+ (1988) (19)
- Molecular distortions in sterically congested organometals. Crystal structure of bis(2,4,6-tri-tert-butylphenyl)mercury (1980) (19)
- Intermolecular electron-transfer mechanisms via quantitative structures and ion-pair equilibria for self-exchange of anionic (dinitrobenzenide) donors. (2005) (19)
- Oxidative alkylation of cobalt complexes with hydrazines (1986) (19)
- Ferric iodide as a nonexistent compound (1990) (19)
- Crystallographic distinction between "contact" and "separated" ion pairs: structural effects on electronic/ESR spectra of alkali-metal nitrobenzenides. (2004) (18)
- Photoinduced hydrometalation and hydrogenation of activated olefins with molybdenum and tungsten dihydrides (Cp2MH2) (1990) (18)
- Ligand effects on the redox potentials of metal carbonyls (1983) (18)
- Electrooxidation of metal cabonyl anions. Formation and reactivity of 17-electron manganese(0) radicals (1987) (18)
- Isolation and Structure Elucidation of Transient (Colored) Complexes of Arenediazonium with Aromatic Hydrocarbons as Intermediates in Arylations and Azo Couplings (1997) (18)
- Electrocatalysis of ligand substitution in metal carbonyls. Thermodynamics of a chain process (1982) (18)
- Isolation, X-ray structures, and electronic spectra of reactive intermediates in Friedel-Crafts acylations. (2005) (18)
- NOVEL CHAIN MECHANISM FOR THE FORMYL-METAL TO HYDRIDO-METAL CONVERSION. FREE RADICAL, PHOTOCHEMICAL AND ELECTROCHEMICAL METHODS OF INITIATION (1983) (18)
- Alkylation as a route to reduction of copper(II) by tetraalkyllead (1973) (18)
- Hydroxycarbene complexes from paramagnetic acylmetals. Electrochemistry of benzoylchromium(0) and -tungsten(0) carbonyls (1981) (18)
- Electrophilic substitution at saturated carbon in mercurials. Alkyl ligands as mechanistic probes in the cleavage of organometals (1976) (17)
- Electroreduction of carbonylmanganese(I) cations. Mechanism of ligand substitution and hydride formation via manganese(0) intermediates. (1987) (17)
- Donor-acceptor complexes of organometals and iodine. Alkyl ligands as probes for steric effects in charge transfer (1980) (17)
- Mulliken–Hush elucidation of the encounter (precursor) complex in intermolecular electron transfer via self-exchange of tetracyanoethylene anion-radical (2006) (17)
- Isolation, Structure, and Reactivity of a Novel Chloro-Arenium Cation for Electrophilic (Transfer) Chlorinations (1994) (17)
- Ligand-induced scission of polyhedral clusters. Synthesis, structures and reactivity of fluorodiphosphine-substituted bis(arylphosphido)-capped tetracobalt carbonyl complexes (1987) (17)
- THE OXIDATION OF FREE RADICALS BY METAL IONS (1961) (17)
- I. The catalytic decomposition of tetraethyllead by copper(I). Acetolysis of alkylcopper(I) intermediates (1972) (17)
- Epoxidation of Olefins with Cationic (salen)Mn(III) Complexes. The Modulation of Catalytic Activity by Substituents. (1986) (17)
- Studies of Ligand Transfer between Metal Halides and Free Radicals from Peroxides1 (1965) (17)
- Charge-Modulated Associates of Anionic Donors with Cationic π-Acceptors: Crystal Structures of Ternary Synthons Leading to Molecular Wires (2009) (16)
- Acetyl substitution of the cyclopentadienyl ligand in molybdenum complexes; nucleophilic additions to coordinated allyl groups (1986) (16)
- STOICHIOMETRY AND KINETICS OF P-METHOXYTOLUENE OXIDATION BY ELECTRON TRANSFER. MECHANISTIC DICHOTOMY BETWEEN SIDE CHAIN AND NUCLEAR SUBSTITUTION (1985) (16)
- Electron-transfer activation in electrophilic mechanisms. Cleavage of alkylmetals by mercury(II) complexes (1980) (16)
- Electron transfer from d10 species: A possible initiation for free radical pathways in oxidative additions (1975) (16)
- II. Kinetics of ligand transfer oxidation of alkyl radicals. Evidence for carbonium ion intermediates (1972) (16)
- Catalytic bromide and iodide exchange of alkyl chlorides with hydrogen bromide and hydrogen iodide (1989) (16)
- Direct osmylation of benzenoid hydrocarbons. Charge-transfer photochemistry of osmium tetraoxide (1988) (16)
- Photoinduced electron transfer in contact ion pairs (1988) (16)
- HOMOLYTIC ADDITION TO OLEFINS: CHAIN TERMINATION BY METAL HALIDES (1956) (16)
- Electron donor-acceptor complexes. 1. Linear free energy correlation of the charge-transfer transition energy with the kinetics of halogenolysis of alkylmetals (1980) (15)
- Alkyl cleavages from organomercurials. 2. Electron transfer process with hexachloroiridate(IV) (1976) (15)
- Stereoselectivity in carbanion addition to coordinated allyl ligands. Catalytic (Exo-Endo) isomerization of cationic molybdenum complexes (1986) (15)
- Charge-Transfer Crystals of Octacarbonyldiferrate. Solid-State Structure and Oxidation-Reduction of an Iron-Iron-Bonded Electron Donor (1995) (15)
- Direct relationship between intermolecular charge-transfer and charge-resonance complexes via structural changes in the arene donor with various π-acceptors (2001) (15)
- The stereochemistry of the cleavage of organometallic complexes with copper(II) (1976) (15)
- Structures and the reversible interconversion of closo rhodium-triiron M4(.mu.4-E) clusters. Oxidation-reduction and ESR spectra of organometallic anion and cation radicals (1986) (14)
- COPPER(I) CATALYSIS IN PHOTOCYCLOADDITIONS PART 2, CYCLOPENTENE, CYCLOHEXENE, AND CYCLOHEPTENE (1974) (14)
- The structure and conformation of stannyl and related radical adducts to cyclopentadiene by ESR (1973) (14)
- Copper(I) triflate: A superior catalyst for olefin photodimerization (1973) (14)
- Rates and mechanisms of reduction of tris(phenanthroline)iron(III) by various radicals: effect of solvent (1985) (14)
- Intermolecular π‐dimer of oxoverdazyl radicals with long‐distance multicenter (2e/8c) bonding via nitrogen atoms (2009) (14)
- SALT EFFECTS ON THE ELECTRON-TRANSFER EQUILIBRAIA OF REDOX-ACTIVE ION PAIRS (1992) (14)
- Reversible linkage isomerisms of .beta.-diketonato ligands. Oxygen-bonded and carbon-bonded structures in gold(III) acetylacetonate complexes induced by phosphines (1977) (14)
- Novel synthesis of ionic clusters (Na43+) in zeolites (1988) (14)
- Hindered internal rotation of the methyl group in .alpha.-substituted ethyl radicals. Effect of fluorine (1974) (14)
- II. Reduction of copper(II) by tetraethyllead. Evidence for ethyl radicals in acetic acid (1972) (14)
- UV Photoelectron Spectra of Peralkylated Catenates of Group 4B Elements (Silicon, Germanium, and Tin) (1985) (14)
- Dehydrosilylation versus α-coupling in the electron-transfer of enol silyl ethers to quinones. Strong solvent effect on photogenerated ion pairs (1993) (14)
- Mechanism of homolytic substitution (SH2) reactions. Radical chain cleavage of alkylmetals by photochemically generated iodine atoms (1980) (14)
- Photoinduced electron transfer from enol silyl ethers to quinone. Part 2. Direct observation of ion-pair dynamics by time-resolved spectroscopy (1996) (14)
- Zeolite catalysis in the selective oligomerization of styrene (1989) (13)
- Strong electronic coupling in intermolecular (charge-transfer) complexes. Mechanistic relevance to thermal and optical electron transfer from aromatic donors (2002) (13)
- Spontaneous oxidation of organic donors to their cation radicals using Brønsted acids. Identification of the elusive oxidant (2000) (13)
- The Kinetics of the Meerwein Reaction (1956) (13)
- Structure and bonding in cationic olefin complexes of copper(I) by NMR (1972) (13)
- Electron spin resonance spectrum of the 7-norbornenyl radical (1970) (13)
- Alkylation of tetracyanoethylene. Reaction with Grignard reagents (1976) (13)
- Structural Characterization of Novel Olefinic Cation Radicals: X‐ray Crystallographic Evidence of σ–π Hyperconjugation (2000) (13)
- Picosecond spectroscopy of charge-transfer processes. Photochemistry of anthracene-tetranitromethane EDA complexes (1984) (13)
- An Efficient Venus Flytrap for the Reversible Binding of Nitric Oxide. (1998) (13)
- Oxidative Decarboxylation of Acids by Lead Tetraacetate (2011) (12)
- Novel electrogeneration of reactive formylmetal complexes from metal carbonyls (1984) (12)
- General synthesis of dioxoruthenium(VI) complexes. Structure and reactivity of trans-dioxobis(acetato)bis(pyridine)ruthenium(VI) (1987) (12)
- Photoinduced electron transfer from enol silyl ethers to quinone. Part 1. Pronounced effects of solvent polarity and added salt on the formation of α-enones (1996) (12)
- UV photoelectron spectra of group IV alkyl hydrides (1980) (12)
- Carbon-13 relaxation and reorientational dynamics in a bicapped tetracobalt cluster (1988) (12)
- Structural effects of carbon monoxide coordination to carbon centers. π and σ bindings in aliphatic acyl versus aromatic aroyl cations (2004) (12)
- Selectivity factors in the electrophilic cleavages of tetraalkyllead compounds (1973) (12)
- Charge-transfer photochemistry of aromatic .pi.-complexes. Hexamethylbenzene and mercuric trifluoroacetate (1986) (12)
- Charge-transfer salts of carbonylmetalates as outer-sphere ion pairs in photochemical and thermal electron transfer (1992) (12)
- Nucleophilic addition versus electron transfer in carbonylmetallate salts. Donor–acceptor interactions in the precursor ion pairs (1997) (12)
- Fresh Look at Electron-Transfer Mechanisms via the Donor/Acceptor Bindings in the Critical Encounter Complex (2008) (11)
- Organometals as electron donors. Effects of alkyl groups on the ionization potentials of tetraalkyltin compounds in the correlation with Taft .sigma.* values (1979) (11)
- Quantitative assessment of electron-donor properties of enol silyl ethers: Charge-transfer complex formation, photoelectron spectra and transient electrochemical oxidation (1994) (11)
- Efficient conversion of alkyl chlorides into bromides (1987) (11)
- Alkyl radicals in lithium clusters by electron spin resonance (1973) (11)
- Activation and transfer of oxygen atom from dioxygen–metal complexes. Epoxidation of olefins induced by electrophiles (1977) (11)
- Pressure-tuning spectroscopy of charge-transfer salts: x-ray crystallography and comparative studies in solution and in the solid state (1990) (11)
- Organogold(III) complexes. Structure of monomethyldibromogold (1977) (11)
- Charge-transfer nitration of naphthalene and the methylnaphthalenes. Part 1. Direct comparison with electrophilic aromatic nitrations (1991) (11)
- Catalytic autoxidation of benzoquinone dioximes with nitrogen oxides: steric effects on the preparation of monomeric dinitrosobenzenes (1994) (11)
- Photoinduced Coupling of Acetylenes and Quinone in the Solid State as Preorganized Donor-Acceptor Pairs. (1998) (11)
- Crystal and molecular structure of allyl(bromo)bis(triethylphosphine)platinum(II). An example of .sigma. bonding of an .eta.1-allyl group (1977) (11)
- Site selectivity in carbonyl reduction of mixed Fe2Co2 clusters. Formyl intermediates in the formation of hydrido derivatives (1987) (10)
- Electron spin resonance studies of hydrogen transfer to alkoxy radicals from the hydroxyl group of alcohols (1974) (10)
- Lewis acid effects on donor–acceptor associations and redox reactions: ternary complexes of heteroaromatic N-oxides with boron trifluoride and organic donors (2009) (10)
- EFFICIENT HYDROGENATION OF STERICALLY HINDERED OLEFINS WITH BORANE-METHYL SULFIDE COMPLEX (1996) (10)
- Dynamics of transient ion pairs and radical pairs. Solvent and salt effects by time-resolved spectroscopy (1985) (10)
- Novel bis-arene (sandwich) complexes with NO+ acceptor. Isolation, X-ray crystallography and electronic structure (2002) (10)
- Kinetics of electrophilic brominations. Mechanistic significance of the third‐order term (1983) (10)
- Electrosynthesis of hydridometal carbonyls. Rapid ligand substitution in transient Mn0 intermediates from the reduction of carbonylmanganese(I) cations (1983) (10)
- The mechanism of charge-transfer nitration of naphthalene (1992) (10)
- Trimethylsilyloxy-radicals from peroxides: electron spin resonance study of homolytic substitution on silicon (1973) (10)
- Electron donor-acceptor complexes. 2. Quantitative evaluation of solvent effects on the reactivity of alkylmetals (1980) (10)
- Transient formyl derivatives of rhenium carbonyls. The facile ligand dissociation of halorhenate species (1986) (10)
- Alkyl transfers from organometallic compounds by one-electron processes (1974) (9)
- Charge‐transfer complex formations of tetracyanoquinone (cyanil) and aromatic electron donors (2016) (9)
- Mechanism of the Chromium-Catalyzed Epoxidation of Olefins. Role of Oxochromium(V) Cations. (1986) (9)
- Electrochemical activation of acyl ligands in organometals. ESR studies of acetyl- and benzoyliron(III) complexes (1980) (9)
- Electron-transfer pathway for photoinduced Diels–Alder cycloadditions (1999) (9)
- Time-resolved cidep and ESR studies: quenching of carbonyl triplets by organometal donors (1980) (9)
- Application of time-resolved chemically induced dynamic electron polarization and electron spin resonance techniques to the quenching of quinone triplets by organometal donors (1981) (9)
- Catalytic de-ligation of bis(arene)iron dications upon electro-reduction (1992) (9)
- Charge‐Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene (1990) (9)
- Newer aspects of electron transfer in electrophilic Aromatic Nitration. Radical pairs as reactive intermediates by time‐resolved spectroscopy (1994) (9)
- AN ELECTRICALLY NEUTRAL Σ-SULFURANYL RADICAL FROM THE HOMOLYSIS OF A PERESTER WITH NEIGHBORING SULFENYL SULFUR: 9-S-3 SPECIES (1981) (9)
- Spontaneous disproportionation of NO2 (N2o4) by aromatic hydrocarbons. Formation of nitrosonium EDA complexes as chemical intermediates (1993) (9)
- Electron spin resonance studies of fluoroalkyl radicals in solution. II. Adducts to fluoroolefins (1974) (8)
- Electron spin resonance of alkylsulfinyl and alkylsulfonyl radicals (1972) (8)
- Preparation of selenoxides from the catalytic autoxidation of organoselenides with nitrogen oxides (1996) (8)
- ESR Spectrum of manganese species in the pohotolysis of Mn2 (CO)10 in solution (1975) (8)
- Nucleophilic addition to coordinated allyl ligands: heteroatom nucleophiles with cationic molybdenum complexes (1985) (8)
- Trimorphism of a model carcinogen 4-nitroquinoline-N-oxide (2009) (8)
- Tris(thianthrene)2+ bis(dodecamethylcarba-closo-dodecaborate) dichloromethane tetrasolvate: a crossed triple-decker pi-trimer dication. (2007) (8)
- Nonplanar allyl radicals. ESR studies of the addition of sulfur, silicon and tin-centered radicals to allenes (1976) (8)
- Notes. The Pyrolysis of o-Halobenzoate Salts (1961) (8)
- Charge-transfer activation of aromatic hydrocarbons with stannic chloride (1992) (8)
- Organomercurials I. Free radical chain mechanisms in the reductive elimination of dialkylmercury in carbon tetrachloride (1977) (8)
- Unusual stabilization of formylmetal complexes (1984) (8)
- Charge-transfer photochemistry in the cleavage of alkylmetals by hexachloroiridate(IV). ESR studies of paramagnetic intermediates (1980) (8)
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- Efficient Conversion of Alkyl Chlorides into Bromides. (1987) (0)
- Reactive Ion Pairs from the Charge-Transfer Excitation of Electron Donor-Acceptor Complexes. (1986) (0)
- Base-Induced Conversion of Macrocyclic Tetradentate to Bidentate Salicylamide Complexes. Structure of the Picoline Adduct to a Co(II)(1,2-bis(o-hydroxybenzoyl)ethylenediamine). (1988) (0)
- Ligand Stereochemistry in the Multiple Substitution of Bicapped Tetracobalt Clusters. (1987) (0)
- Electron-Transfer Catalysis of Ligand Substitution in Triiron Clusters. (1986) (0)
- IRON CATALYSIS OF GRIGNARD REDUCTIONS. MECHANISM OF 1,3-REDUCTIVE ELIMINATIONS FROM Γ-PROPYL HALIDES (1982) (0)
- STUDIES OF CATIONIC GOLD(I) COMPLEXES- PREPARATION OF TRIS(TRANS-CYCLOOCTENE)GOLD TRIFLUOROMETHANESULFONATE (1977) (0)
- ELECTROPHILIC AROMATIC SUBSTITUTION, ELECTRON TRANSFER ROUTES IN SIDE CHAIN SUBSTITUTION (1975) (0)
- Catalytic Autoxidation of Benzoquinone Dioximes with Nitrogen Oxides: Steric Effects on the Preparation of Monomeric Dinitrosobenzenes. (1995) (0)
- Charge-Transfer Cycloaddition of Homobenzvalene with Tetracyanoethylene. (1990) (0)
- Isolation, Structure, and Reactivity of a Novel Chloro‐Arenium Cation for Electrophilic (Transfer) Chlorinations. (1995) (0)
- CCDC 645125: Experimental Crystal Structure Determination (2007) (0)
- Additions and Corrections: The Solvolysis of Benzyl Tosylates. V. Some Solvent Effects. (1958) (0)
- Oxidative Alkylation of Cobalt Complexes with Hydrazines. (1986) (0)
- Convenient Preparation of Quinones via the Catalytic Autoxidation of Hydroquinones with Nitrogen Oxides. (1994) (0)
- Charge Transfer Theory and the Activated Complex (1985) (0)
- Photoinduced Electron Transfer in Pinacol Cleavage with Quinones via Highly Labile Cation Radicals. Direct Comparison of Charge-Transfer Excitation and Photosensitization. (1993) (0)
- Organic reactions, Vol. XIII, A. C. Cope, ed., Wiley, New York, 1963. 382 pp. $12.50 (1964) (0)
- ALKYLATION OF SILVER(I) WITH TETRAAETHYLLEAD (1974) (0)
- Formation of Oxometal Complexes by the Oxidative Decarbonylation of Metal Carbonyls. (1989) (0)
- Oxidation‐Reduction of Carbonylcobalt Cation‐Anion Pairs in Coupling to Dimeric Cobalt Carbonyls. (1989) (0)
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