Jean-Michel Savéant
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French chemist
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Jean-Michel Savéantchemistry Degrees
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Chemistry
Jean-Michel Savéant's Degrees
- PhD Chemistry Université Paris Cité
Why Is Jean-Michel Savéant Influential?
(Suggest an Edit or Addition)According to Wikipedia, Jean-Michel Savéant was a French chemist who specialized in electrochemistry. He was elected member of the French Academy of Sciences in 2000 and foreign associate of the National Academy of Sciences in 2001. He published in excess of 400 peer-reviewed articles in chemistry literature.
Jean-Michel Savéant's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Catalysis of the electrochemical reduction of carbon dioxide. (2013) (1017)
- A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst (2012) (873)
- Covalent Modification of Carbon Surfaces by Aryl Radicals Generated from the Electrochemical Reduction of Diazonium Salts (1997) (812)
- Covalent Modification of Carbon Surfaces by Grafting of Functionalized Aryl Radicals Produced from Electrochemical Reduction of Diazonium Salts (1992) (779)
- Molecular catalysis of electrochemical reactions. Mechanistic aspects. (2008) (682)
- Charge transfer at partially blocked surfaces (1983) (617)
- Turnover numbers, turnover frequencies, and overpotential in molecular catalysis of electrochemical reactions. Cyclic voltammetry and preparative-scale electrolysis. (2012) (517)
- Elements of Molecular and Biomolecular Electrochemistry: An Electrochemical Approach to Electron Transfer Chemistry (2006) (452)
- Heterogeneous (chemically modified electrodes, polymer electrodes) vs. homogeneous catalysis of electrochemical reactions (1978) (376)
- Convolution potential sweep voltammetry (1973) (363)
- Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability (1981) (362)
- Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion. (2016) (346)
- Linear sweep voltammetry: Kinetic control by charge transfer and/or secondary chemical reactions (1973) (337)
- The electrochemistry of vitamin B12 (1983) (314)
- A simple model for the kinetics of dissociative electron transfer in polar solvents. Application to the homogeneous and heterogeneous reduction of alkyl halides (1987) (302)
- Catalysis of electrochemical reactions at redox polymer electrodes: Kinetic model for stationary voltammetric techniques (1982) (285)
- Potential-sweep chronoamperometry: Kinetic currents for first-order chemical reaction parallel to electron-transfer process (catalytic currents)☆ (1965) (284)
- Electron transfer, bond breaking, and bond formation (1993) (273)
- Homogeneous redox catalysis of electrochemical reactions: Part V. Cyclic voltammetry (1980) (272)
- Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts (2014) (261)
- Heterogeneous and homogeneous electron transfers to aromatic halides. An electrochemical redox catalysis study in the halobenzene and halopyridine series (1979) (256)
- Modification of carbon fiber surfaces by electrochemical reduction of aryl diazonium salts: Application to carbon epoxy composites (1997) (256)
- Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids (1996) (255)
- Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations (1991) (242)
- Dynamics of electron hopping in assemblies of redox centers. Percolation and diffusion (1992) (235)
- Homogeneous Catalysis of Electrochemical Hydrogen Evolution by Iron(0) Porphyrins (1996) (233)
- Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2-to-CO Electrochemical Conversion. (2015) (228)
- How Do Pseudocapacitors Store Energy? Theoretical Analysis and Experimental Illustration. (2017) (221)
- Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water (2015) (214)
- Concerted proton-electron transfers: electrochemical and related approaches. (2010) (208)
- Electron Transfer and Bond Breaking. Examples of Passage from a Sequential to a Concerted Mechanism in the Electrochemical Reductive Cleavage of Arylmethyl Halides (1992) (197)
- Electron transfer through redox polymer films (1980) (195)
- Electrodimerization: I. One-electron irreversible dimerization. Diagnostic criteria and rate determination procedures for voltammetric studies (1970) (189)
- Convolution potential sweep voltammetry V. Determination of charge transfer kinetics deviating from the Butler-Volmer behaviour (1975) (185)
- Ultraefficient homogeneous catalyst for the CO2-to-CO electrochemical conversion (2014) (185)
- Pendant acid-base groups in molecular catalysts: H-bond promoters or proton relays? Mechanisms of the conversion of CO2 to CO by electrogenerated iron(0)porphyrins bearing prepositioned phenol functionalities. (2014) (176)
- Disproportionation and ECE mechanisms—I. Theoretical analysis. Relationships for linear sweep voltammetry☆ (1968) (172)
- Potential-sweep chronoamperometry theory of kinetic currents in the case of a first order chemical reaction preceding the electron-transfer process (1963) (169)
- Standard potential and kinetic parameters of the electrochemical reduction of carbon dioxide in dimethylformamide (1977) (169)
- Fast kinetics by means of direct and indirect electrochemical techniques (1990) (167)
- Toward the Rational Benchmarking of Homogeneous H2-Evolving Catalysts. (2014) (165)
- Catalysis of chemical reactions by electrodes (1980) (165)
- Proton-coupled electron transfer cleavage of heavy-atom bonds in electrocatalytic processes. Cleavage of a C-O bond in the catalyzed electrochemical reduction of CO2. (2013) (164)
- Boron-capped tris(glyoximato) cobalt clathrochelate as a precursor for the electrodeposition of nanoparticles catalyzing H2 evolution in water. (2012) (162)
- Dissociative electron transfer. New tests of the theory in the electrochemical and homogeneous reduction of alkyl halides (1992) (154)
- Homogeneous redox catalysis of electrochemical reactions: Part I. Introduction (1978) (151)
- Single Electron Transfer and Nucleophilic Substitution (2010) (150)
- Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations (1996) (149)
- Ece and disproportionation (1977) (148)
- Mechanism of the electrochemical reduction of carbon dioxide at inert electrodes in media of low proton availability (1996) (145)
- Can Single-Electron Transfer Break an Aromatic Carbon−Heteroatom Bond in One Step? A Novel Example of Transition between Stepwise and Concerted Mechanisms in the Reduction of Aromatic Iodides (1999) (144)
- Proton-electron transport and transfer in electrocatalytic films. Application to a cobalt-based O2-evolution catalyst. (2013) (140)
- Potential-sweep voltammetry: General theory of chemical polarization (1967) (140)
- The solvent as hydrogen-atom donor in organic electrochemical reactions. Reduction of aromatic halides (1980) (134)
- Update 1 of: Electrochemical approach to the mechanistic study of proton-coupled electron transfer. (2010) (134)
- A fully active monolayer enzyme electrode derivatized by antigen-antibody attachment (1993) (134)
- Kinetics of electrochemical reactions mediated by redox polymer films: Irreversible cross-exchange reactions: Formulation in terms of characteristic currents for stationary techniques (1982) (132)
- Electrodimerization: VIII. Role of proton transfer reactions in the mechanism of electrohydrodimerization formal kinetics for voltammetric studies (linear sweep, rotating disc, polarography) (1973) (132)
- Mechanism of superoxide ion disproportionation in aprotic solvents (1987) (131)
- Linear sweep voltammetry—compensation of cell resistance and stability (1972) (129)
- Dimerization, disproportionation and e.c.e. mechanisms in the reduction of aromatic carbonyl compounds in alkaline media (1971) (128)
- Outer-sphere dissociative electron transfer to organic molecules: a source of radicals or carbanions? Direct and indirect electrochemistry of perfluoroalkyl bromides and iodides (1990) (125)
- Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst (1994) (123)
- Benchmarking of homogeneous electrocatalysts: overpotential, turnover frequency, limiting turnover number. (2015) (121)
- Kinetics and mechanism of self-protonation reactions in organic electrochemical processes (1985) (121)
- Kinetics of electrochemical reactions mediated by redox polymer films: Reversible cross-exchange reactions (1982) (120)
- Convolution potential sweep voltammetryII. Multistep nernstian waves (1973) (120)
- New model for the interior of polyelectrolyte coatings on electrode surfaces. Mechanisms of charge transport through protonated poly(L-lysine) films containing FeIII(edta)- and FeII(edta)2- as counterions (1982) (118)
- Homogeneous redox catalysis of electrochemical reaction: Part VI. Zone diagram representation of the kinetic regimes (1984) (117)
- Electrodimerization: VII. Electrode and solution electron transfers in the radical-substrate coupling mechanism. discriminative criteria from the other mechanisms in voltammetric studies (Linear sweep, rotating disc, polarography) (1973) (116)
- Fast sweep cyclic voltammetry at ultra-microelectrodes: Evaluation of the method for fast electron-transfer kinetic measurements (1988) (113)
- Electrochemical and homogeneous proton-coupled electron transfers: concerted pathways in the one-electron oxidation of a phenol coupled with an intramolecular amine-driven proton transfer. (2006) (113)
- Fragmentation of aryl halide pi anion radicals. Bending of the cleaving bond and activation vs driving force relationships. (2004) (112)
- Catalysis of the electrochemical reduction of carbon dioxide by iron(“0”) porphyrins (1988) (111)
- Derivatization of Carbon Surfaces by Anodic Oxidation of Arylacetates. Electrochemical Manipulation of the Grafted Films (1997) (111)
- Kinetics of dissociative electron transfer. Direct and mediated electrochemical reductive cleavage of the carbon-halogen bond (1986) (111)
- Molecular Catalysis of Electrochemical Reactions (2017) (110)
- Electrochemical approach to concerted proton and electron transfers. Reduction of the water-superoxide ion complex. (2005) (110)
- Kinetics of film-coated electrodes. Effect of a finite mass transfer rate of substrate across the film-solution interface at steady state (1985) (109)
- Towards an intelligent design of molecular electrocatalysts (2017) (108)
- Thermodynamics of successive electron transfers: Internal and solvation enthalpy and entropy variations in a series of polynitro compounds (1973) (106)
- Electrochemistry of vitamin B12. 2. Redox and acid-base equilibria in the B12a/B12r system. (1977) (105)
- The electrochemical approach to concerted proton—electron transfers in the oxidation of phenols in water (2009) (104)
- Potential-sweep voltammetry: Theoretical analysis of monomerization and dimerization mechanisms (1967) (102)
- Catalysis of electrochemical reactions at redox polymer coated electrodes: mediation of the Fe(III)/Fe(II) oxido-reduction by a polyvinylpyridine polymer containing coordinatively attached bisbipyridine chlororuthenium redox centers (1986) (101)
- Single two-electron transfers vs successive one-electron transfers in polyconjugated systems illustrated by the electrochemical oxidation and reduction of carotenoids. (2001) (101)
- Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins (2016) (100)
- Identification of the first steps of the electrochemical polymerization of pyrroles by means of fast potential step techniques (1991) (99)
- Electrochemistry of vitamin B12. I. Role of the base-on/base-off reaction in the oxidoreduction mechanism of the B12r-B12s system. (1976) (96)
- Efficient electrolyzer for CO2 splitting in neutral water using earth-abundant materials (2016) (94)
- Concerted proton-electron transfer reactions in water. are the driving force and rate constant depending on pH when water acts as proton donor or acceptor? (2007) (93)
- Homogeneous vs. heterogeneous electron transfer in electrochemical reactions (1983) (93)
- Electrochemical and homogeneous electron transfers to the Alzheimer amyloid-β copper complex follow a preorganization mechanism (2010) (92)
- Electroreductive alkylation of iron in porphyrin complexes. Electrochemical and spectral characteristics of .sigma.-alkylironporphyrins (1981) (92)
- Do ECE mechanisms occur in conditions where they could be characterized by electrochemical kinetic techniques (1978) (91)
- Kinetics of electrochemical reactions mediated by redox polymer films: New formulation and strategies for analysis and optimization (1984) (90)
- Outer-sphere electron-transfer reduction of alkyl halides. A source of alkyl radicals or of carbanions? Reduction of alkyl radicals (1989) (90)
- Observation of the cation radicals of pyrrole and of some substituted pyrroles in fast-scan cyclic voltammetry. Standard potentials and lifetimes (1990) (90)
- Convolution potential sweep voltammetry: Part IV. Homogeneous follow-up chemical reactions (1975) (89)
- Dissociative electron transfer. Ab initio study of the carbon-halogen bond reductive cleavage in methyl and perfluoromethyl halides. Role of the solvent (1992) (89)
- Conduction and Reactivity in Heterogeneous-Molecular Catalysis: New Insights in Water Oxidation Catalysis by Phosphate Cobalt Oxide Films. (2016) (88)
- Homogeneous redox catalysis of electrochemical reactions: Part II. Rate determining electron transfer, evaluation of rate and equilibrium parameters (1978) (88)
- Convolution potential sweep voltammetry: III. Effect of sweep rate cyclic voltammetry (1974) (88)
- Kinetics of electron transfer to organic molecules at solid electrodes in organic media (1983) (87)
- Electron transfer and bond breaking: Recent advances (2006) (86)
- Electrochemistry of acids on platinum. Application to the reduction of carbon dioxide in the presence of pyridinium ion in water. (2013) (86)
- DETERMINATION OF THE LIFETIMES OF UNSTABLE ION RADICALS BY HOMOGENEOUS REDOX CATALYSIS OF ELECTROCHEMICAL REACTIONS. APPLICATION TO THE REDUCTION OF AROMATIC HALIDES (1980) (85)
- Hydrogen-bond relays in concerted proton-electron transfers. (2012) (84)
- Linear sweep voltammetry. Effect of uncompensated cell resistance and double layer charging on polarization curves (1970) (83)
- Adiabatic and non-adiabatic concerted proton-electron transfers. Temperature effects in the oxidation of intramolecularly hydrogen-bonded phenols. (2007) (83)
- Electrochemical concerted proton and electron transfers. Potential-dependent rate constant, reorganization factors, proton tunneling and isotope effects (2006) (83)
- Ion association and electric field effects on electron hopping in redox polymers. Application to the tris(2,2'-bipyridine)osmium(3+)/tris(2,2'-bipyridine)osmium(2+) couple in Nafion (1991) (82)
- Step-by-Step Immunological Construction of a Fully Active Multilayer Enzyme Electrode (1994) (82)
- Kinetics of electron-transfer cross-reactions within redox polymers. Coatings of a protonated polylysine copolymer with incorporated electroactive anions (1983) (81)
- Reductive Cleavage of Carbon Tetrachloride in a Polar Solvent. An Example of a Dissociative Electron Transfer with Significant Attractive Interaction between the Caged Product Fragments (2000) (81)
- Dissociative electron transfer to haloacetonitriles. An example of the dependency of in-cage ion-radical interactions upon the leaving group. (2002) (80)
- Self-exchange reactions at redox polymer electrodes. A kinetic model and theory for stationary voltammetric techniques (1983) (79)
- Electrocatalysis at redox polymer electrodes with separation of the catalytic and charge propagation roles. Reduction of dioxygen to hydrogen peroxide as catalyzed by cobalt(II) tetrakis(4-N-methylpyridyl)porphyrin (1985) (79)
- Dynamics of Cleavage and Formation of Anion Radicals into and from Radicals and Nucleophiles. Structure-Reactivity Relationships in SRN1 Reactions (1994) (78)
- Homogeneous redox catalysis of electrochemical reactions: Part IV. Kinetic controls in the homogeneous process as characterized by stationary and quasi-stationary electrochemical techniques (1980) (77)
- Outer-sphere and inner-sphere processes in reductive elimination. Direct and indirect electrochemical reduction of vicinal dibromoalkanes (1990) (76)
- Catalysis of electrochemical reactions at redox polymer electrodes (1980) (75)
- ECE and disproportionation: Part VI. General resolution. Application to potential step chronoamperometry (1979) (75)
- Catalysis and Mass Transport in Spatially Ordered Enzyme Assemblies on Electrodes (1995) (75)
- Molecular catalysis of H2 evolution: diagnosing heterolytic versus homolytic pathways. (2014) (75)
- Mediated electrochemistry of horseradish peroxidase. Catalysis and inhibition. (2002) (75)
- Successive Removal of Chloride Ions from Organic Polychloride Pollutants. Mechanisms of Reductive Electrochemical Elimination in Aliphatic Gem-Polychlorides, α,β-Polychloroalkenes, and α,β-Polychloroalkanes in Mildly Protic Medium (2003) (75)
- Electron hopping between fixed sitesEquivalent diffusion and migration laws (1986) (74)
- Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium Cations (1994) (73)
- Chemical catalysis of the electrochemical reduction of alkyl halides: Comparison between cobalt-tetraphenyl porphin and vitamin B12 derivatives (1979) (71)
- Chemical vs. redox catalysis of electrochemical reactions. Reduction of trans-1,2-dibromocyclohexane by electrogenerated aromatic anion radicals and low oxidation state metalloporphyrins (1987) (71)
- Intrinsic reactivity and driving force dependence in concerted proton–electron transfers to water illustrated by phenol oxidation (2010) (71)
- Variation of the electrochemical transfer coefficient with potential (1982) (70)
- Elements of Molecular and Biomolecular Electrochemistry (2019) (70)
- Electrochemistry of vitamin B12. 3. One-electron intermediates in the reduction of methylcobalamin and methylcobinamide (1978) (69)
- Electrochemistry of NADH/NAD+ analogs. A detailed mechanistic kinetic and thermodynamic analysis of the 10-methylacridan/10-methylacridinium couple in acetonitrile (1990) (69)
- Electrodimerization: V. Mechanism of the electrohydrodimerization of activated olefins in media of low acidity (1973) (68)
- Molecular Catalysis of O2 Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways. (2015) (68)
- Water (in water) as an intrinsically efficient proton acceptor in concerted proton electron transfers. (2011) (68)
- Mechanisms and reactivity in electron transfer induced aromatic nucleophilic substitution. Recent advances (1994) (67)
- Nucleophile and aryl radical reactivity in SRN1 aromatic nucleophilic substitution reactions. Absolute and relative electrochemical determination (1985) (67)
- Concerted and Stepwise Dissociative Electron Transfers. Oxidability of the Leaving Group and Strength of the Breaking Bond as Mechanism and Reactivity Governing Factors Illustrated by the Electrochemical Reduction of α-Substituted Acetophenones (1997) (66)
- Outer-sphere oxidation of ascorbate with os(bpy)33+ incorporated in nafion coatings on graphite electrodes (1984) (66)
- Effects of long-range electron transfer on charge transport in static assemblies of redox centers (1993) (65)
- Electrochemical hydrogenation of aromatic hydrocarbons (1980) (64)
- Diffusional pathways for multiply-charged ions incorporated in polyelectrolyte coatings on graphite electrodes. Cobalt oxalate (Co(C2O4)33-) in coatingsof protonated polylysine (1983) (63)
- Quantitative analysis of catalysis and inhibition at horseradish peroxidase monolayers immobilized on an electrode surface. (2003) (63)
- Potential dependence of the electrochemical transfer coefficient. Reduction of some nitro compounds in aprotic media (1977) (63)
- Concerted proton-electron transfers in the oxidation of phenols. (2010) (62)
- Dynamics of proton transfer from cation radicals. Kinetic and thermodynamic acidities of cation radicals of NADH analogs (1992) (62)
- Homolytic and heterolytic radical cleavage in the Kolbe reaction: Electrochemical oxidation of arylmethyl carboxylate ions (2001) (62)
- Electrochemically induced aromatic nucleophilic substitution (1978) (60)
- Electro-oxidation of 1,2-ene-diamines (1970) (60)
- Single electron transfer and nucleophilic substitution. Reaction of alkyl bromides with aromatic anion radicals and low-oxidation-state iron porphyrins (1988) (59)
- Inserting a hydrogen-bond relay between proton exchanging sites in proton-coupled electron transfers. (2010) (59)
- Trace crossings in cyclic voltammetry and electrochemic electrochemical inducement of chemical reactions (1980) (59)
- Concerted proton-coupled electron transfers in aquo/hydroxo/oxo metal complexes: Electrochemistry of [OsII(bpy)2py(OH2)]2+ in water (2009) (59)
- New insights into the enzymic catalysis of the oxidation of glucose by native and recombinant glucose oxidase mediated by electrochemically generated one-electron redox cosubstrates. (1993) (59)
- Electroneutrality coupling of electron hopping between localized sites with electroinactive counterion displacement. 1. Potential-step plateau currents (1988) (58)
- Homogeneous redox catalysis of electrochemical reactions (1978) (58)
- Electrochemical approach to proton-coupled electron transfers: recent advances (2012) (58)
- ELECTROCHEMICAL GENERATION OF RHODIUM PORPHYRIN HYDRIDES. CATALYSIS OF HYDROGEN EVOLUTION (1997) (57)
- Carboxylates as proton-accepting groups in concerted proton-electron transfers. Electrochemistry of the 2,5-dicarboxylate 1,4-hydrobenzoquinone/2,5-dicarboxy 1,4-benzoquinone couple. (2006) (57)
- Electron Transfer in Organized Assemblies of Biomolecules. Construction and Dynamics of Avidin/Biotin Co-immobilized Glucose Oxidase/Ferrocene Monolayer Carbon Electrodes (1998) (57)
- Electron hopping between fixed sites: “Diffusion” and “migration” in counter-ion conservative redox membranes at steady state (1988) (55)
- Controlling factors of stepwise versus concerted reductive cleavages. Illustrative examples in the electrochemical reductive breaking of nitrogen-halogen bonds in aromatic N-halosultams (1993) (54)
- Kinetics of electrochemical reactions mediated by redox polymer films: Pre-activation (CE) mechanisms (1984) (54)
- Fast chemical steps coupled with outer-sphere electron transfers: application of fast scan voltammetry at ultramicroelectrodes to the cleavage of aromatic halide anion radials in the microsecond lifetime range (1988) (53)
- Convolution potential sweep voltammetry: Part VI. Experimental evaluation in the kilovolt per second sweep rate range (1977) (52)
- Electrochemistry of immobilized redox enzymes: kinetic characteristics of NADH oxidation catalysis at diaphorase monolayers affinity immobilized on electrodes. (2006) (51)
- Permeation through polymer coatings on electrodes: Membrane versus pinhole permeation (1991) (51)
- Effect of Ion Pairing on the Mechanism and Rate of Electron Transfer. Electrochemical Aspects (2001) (50)
- Dynamics of Bond Breaking in Ion Radicals. Mechanisms and Reactivity in the Reductive Cleavage of Carbon−Fluorine Bonds of Fluoromethylarenes (1997) (50)
- Ultramicroelectrodes: cyclic voltammetry above one million v s−1 (1988) (50)
- Homogeneous Molecular Catalysis of Electrochemical Reactions: Catalyst Benchmarking and Optimization Strategies. (2017) (49)
- Electrochemically induced aromatic nucleophilic substitution in liquid ammonia. Competition with electron transfer (1979) (49)
- Catalysis of electrochemical reactions at derivatized electrodes (1981) (49)
- Homogeneous redox catalysis of electrochemical reactions electron transfers followed by a very fast chemical step (1986) (49)
- Dimerization, disproportionation and e.c.e. mechanisms in the reduction of imines in acetonitrile and dimethylformamide (1971) (49)
- Electrodimerization: II. Reduction mechanism of immonium cations (1970) (48)
- Disproportionation and ECE mechanisms—II. Reduction of the uranyl cation in perchloric acid☆ (1968) (48)
- Derivatization of surfaces and self-inhibition in irreversible electrochemical reactions: Cyclic voltammetry and preparative-scale electrolysis (1995) (48)
- Cyclic voltammetry with asymmetrical potential scan: A simple approach to mechanisms involving moderately fast chemical reactions (1967) (48)
- Electron hopping between localized sites: effect of ion pairing on diffusion and migration; general rate laws and steady-state responses (1988) (48)
- Are anion radicals unable to undergo radical-radical dimerization? (1982) (47)
- Enhancement of charge-transport rates by redox cross-reactions between reactants incorporated in Nafion coatings (1984) (47)
- Stepwise and concerted electron-transfer/bond breaking reactions. solvent control of the existence of unstable pi ion radicals and of the activation barriers of their heterolytic cleavage. (2004) (46)
- Concerted proton-electron transfers: fundamentals and recent developments. (2014) (45)
- Energy storage: pseudocapacitance in prospect† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01662g (2019) (45)
- Breaking bonds with electrons and protons. Models and examples. (2014) (44)
- Linear sweep voltammetry—Bandpass limitations andmaximum usable sweep rate in the study of faradaic processes (1974) (43)
- Kinetic analysis of reversible electrodimerization reactions by the combined use of double potential step chronoamperometry and linear sweep voltammetry. Application to the reduction of 9-cyanoanthracene (1985) (43)
- Fast cyclic voltammetry at ultramicroelectrodes: Current measurement and ohmic drop positive feedback compensation by means of current feedback operational amplifiers (1990) (43)
- Electrochemically catalyzed aromatic nucleophilic substitution. Phenoxide ion as nucleophile (1988) (43)
- Evidence for concerted proton-electron transfer in the electrochemical oxidation of phenols with water as proton acceptor. Tri-tert-butylphenol. (2008) (42)
- Electron-transfer coupling of diffusional pathways: Theory for potential step chronoamperometry and chronocoulometry (1984) (42)
- Electron hopping between localized sites. Coupling with electroinactive counterion transport (1988) (42)
- Dissociative electron transfer. Autocatalysis and kinetic characteristics of the electrochemical reductive cleavage of the carbon halogen bond in alkyl halides giving rise to stable radicals and carbanions (1985) (42)
- Ece mechanisms as studied by polarography and linear sweep voltammetry (1967) (41)
- Catalysis of the Electrochemical Reduction of Carbon Dioxide (2013) (41)
- Role of protonation and of axial ligands in the reductive dechlorination of alkyl chlorides by vitamin B12 complexes. Reductive cleavage of chloroacetonitrile by Co(I) cobalamins and cobinamides. (2005) (40)
- Product distribution in preparative scale electrolysis: Part I. Introduction (1981) (40)
- Electrochemistry of vitamin B12: Part VII. Role of the base-off/base-on reaction in the oxido-reduction in the B12r-B12s couple in non-aqueous solvents (1982) (40)
- “Thermal” SRN1 Reactions: How Do They Work? Novel Evidence that the Driving Force Controls the Transition between Stepwise and Concerted Mechanisms in Dissociative Electron Transfers (1999) (39)
- A Convenient Synthesis of Perfluoroalkylated and Fluorinated-Aryl Nitrogen Bases by Electrochemically Induced SRN1 Substitution (1996) (39)
- Electrochemistry of vitamin B12. 6. Diaquocobinamide (1980) (39)
- ElectrodimerizationX. Solvation and protonation in the EHD of activated olefins in low acidity media (1974) (39)
- Hydrogen atom abstraction and solvent involvement in the electrochemistry of haloaromatics (1978) (39)
- Surface modifications with heteropoly and isopoly oxometalates: Part II. Electrocatalytic behaviour of glassy carbon surfaces modified with 17-tungsto, 1-molybdo-diphosphate (1988) (39)
- Instrumentation for fast voltammetry at ultramicroelectrodes: Stability and bandpass limitations (1989) (38)
- Reductive electrochemistry of iron-carbene porphyrins (1983) (38)
- Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement. (2018) (38)
- Concerted heavy-atom bond cleavage and proton and electron transfers illustrated by proton-assisted reductive cleavage of an O–O bond (2011) (38)
- ELECTRON TRANSFER INDUCED REACTIONS. ELECTROCHEMICALLY STIMULATED AROMATIC NUCLEOPHILIC SUBSTITUTION IN ORGANIC SOLVENTS (1982) (38)
- Electrochemically induced nucleophilic substitution of perfluoroalkyl halides. An example of a dissociative electron-transfer-induced chemical reaction (1991) (38)
- Electrodimerization: XI. Coupling mechanism of an activated olefin: p-methylbenzylidene-malononitrile as studied by convolution potential sweep voltammetry (1975) (37)
- Product distribution in preparative scale electrolysis: Part IV. EC reaction schemes followed by competition between first-order chemical reaction and further electron transfer. Electrocatalytic systems (1981) (37)
- Electrochemistry of vitamin B-12. 4. Kinetics and mechanisms in B-12a-B-12r oxido-reduction (1979) (37)
- Linear sweep voltammetry. Ohmic drop and chemical polarization (1971) (36)
- Concepts and tools for mechanism and selectivity analysis in synthetic organic electrochemistry (2019) (36)
- Evidence for inverted region behavior in proton transfer to carbanions. (2003) (36)
- The Role of Homolytic Bond Dissociation Energy in the Deprotonation of Cation Radicals. Examples in the NADH Analogues Series (1998) (36)
- Stepwise and concerted pathways in photoinduced and thermal electron-transfer/bond-breaking reactions. experimental illustration of similarities and contrasts. (2001) (36)
- Fast potential step techniques at ultramicroelectrodes. Application to the kinetic characterization of electrochemically generated short-lived species (1988) (35)
- Methods for investigating the mechanistic and kinetic role of ligand exchange reactions in coordination electrochemistry: Cyclic voltammetry of chloroiron(III)tetraphenylporphyrin in dimethylformamide (1985) (35)
- Electroreductive alkylation of iron porphyrins. Iron(III), iron(II) and iron(I) alkyl complexes from the reaction of doubly reduced iron(II) porphyrins with alkyl halides (1986) (35)
- Outer-sphere and inner-sphere processes in organic chemistry. Reaction of trifluoromethyl bromide with electrochemically generated aromatic anion radicals and sulfur dioxide anion radicals (1990) (35)
- Does catalysis of reductive dechlorination of tetra- and trichloroethylenes by vitamin B12 and corrinoid-based dehalogenases follow an electron transfer mechanism? (2005) (35)
- Proton-coupled electron transfer in azobenzene/hydrazobenzene couples with pendant acid-base functions. Hydrogen-bonding and structural effects. (2014) (35)
- Electron-transfer-induced reactions. A novel approach based on electrochemical redox catalysis. Application to aromatic nucleophilic substitutions (1984) (35)
- Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand? (1989) (35)
- Non-Volmerian charge transfers associated with follow-up chemical reactions. A convolution potential sweep voltammetric study of benzaldehyde reduction in ethanol (1978) (34)
- Electrochemical Concerted Proton and Electron Transfers. Further Insights in the Reduction Mechanism of Superoxide Ion in the Presence of Water and Other Weak Acids (2007) (34)
- Nanodiffusion in electrocatalytic films. (2017) (34)
- Evidence for concerted pathways in ion-pairing coupled electron transfers. (2008) (34)
- Cyclic Voltammetry Analysis of Electrocatalytic Films (2015) (34)
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- Catalysis by immobilized redox enzymes. Diagnosis of inactivation and reactivation effects through odd cyclic voltammetric responses (2004) (33)
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- High amplification rates from the association of two enzymes confined within a nanometric layer immobilized on an electrode: modeling and illustrating example. (2006) (33)
- Preceding chemical reaction mechanisms in homogeneous electron transfer reactions. Mediated electrochemical reduction of highly reactive benzylic halides (1984) (33)
- Pyridine as proton acceptor in the concerted proton electron transfer oxidation of phenol. (2011) (33)
- Kinetics of mediated electrochemical reactions at electrodes coated with redox polymer films (1983) (33)
- Formal hydride transfer from NADH analogs. 1-Benzyl-4-tert-butyl-1,4-dihydronicotinamide as a mechanistic probe (1993) (32)
- Catalysis of CO2 Electrochemical Reduction by Protonated Pyridine and Similar Molecules. Useful Lessons from a Methodological Misadventure (2018) (32)
- Ultramicroelectrodes for fast electrochemical kinetics (1990) (32)
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- Arylation and vinylation of iron porphyrins. Double electrochemical induction of a nucleophilic substitution (1982) (31)
- Proton-coupled electron transfers: pH-dependent driving forces? Fundamentals and artifacts. (2013) (31)
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- SOLVENT REORGANIZATION AS A GOVERNING FACTOR IN THE KINETICS OF INTRAMOLECULAR DISSOCIATIVE ELECTRON TRANSFERS. CLEAVAGE OF ANION RADICALS OF ALPHA -S UBSTITUTED ACETOPHENONES (1996) (29)
- Kinetic control by the substrate and/or the cosubstrate in electrochemically monitored redox enzymatic homogeneous systems. Catalytic responses in cyclic voltammetry (2002) (29)
- First- and second-order chemical-electrochemical mechanisms: Extraction of standard potential, equilibrium and rate constants from linear sweep voltammetric curves (1986) (29)
- Activation and Diffusion in the Kinetics of Adsorption and Molecular Recognition on Surfaces. Enzyme-Amplified Electrochemical Approach to Biorecognition Dynamics Illustrated by the Binding of Antibodies to Immobilized Antigens (1999) (28)
- Electron-transfer-induced reactions. Termination steps and efficiency of the chain process in SRN1 aromatic substitutions (1981) (28)
- Catalytic phenomena in the electrochemical reduction of triphenylphosphine and triphenylphosphine oxide in non-aqueous solvents with tetraalkylammonium supporting electrolytes (1978) (28)
- Electrochemistry of iron(I) porphyrins in the presence of carbon monoxide. Comparison with zinc porphyrins (1994) (28)
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- Step-by-Step Avidin−Biotin Construction of Bienzyme Electrodes. Kinetic Analysis of the Coupling between the Catalytic Activities of Immobilized Monomolecular Layers of Glucose Oxidase and Hexokinase (1999) (27)
- Aryl radicals from electrochemical reduction of aryl halides. Addition on olefins (1991) (27)
- Electrochemical cyclization: III. Mechanism of the intramolecular pinacolization of 1,3-dibenzoylpropane as studied by convolution potential sweep voltammetry (1975) (27)
- Reorganization energies and pre-exponential factors in the one-electron electrochemical and homogeneous oxidation of phenols coupled with an intramolecular amine-driven proton transfer. (2010) (27)
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- Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect. (2019) (27)
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- Product distribution in preparative scale electrolysis: Part VI. Competition between dimerization and first-order deactivation (1981) (26)
- Molecular approach to catalysis of electrochemical reaction in porous films (2019) (25)
- Electrochemically induced chemical reactions (1979) (25)
- Kinetics and mechanisms of electrochemical dimerizations (1984) (25)
- Mechanism analysis of electrochemical reactions involving homogeneous chemical steps (1983) (25)
- Facile Derivatization of Glassy Carbon Surfaces by N-Hydroxysuccinimide Esters in View of Attaching Biomolecules (1998) (25)
- REDOX PROPERTIES AND STABILITY OF HYDROXY COMPLEXES OF PROTECTED IRON(III) AND IRON(II) PORPHYRINS (1985) (25)
- Effect of solvent and ion-pairing on the entropy and enthalpy factors in successive reductions of dinitro compounds (1974) (25)
- Theory and practice of enzyme bioaffinity electrodes. Chemical, enzymatic, and electrochemical amplification of in situ product detection. (2008) (25)
- Hydrogen atom transfer oxidation of primary and secondary alcoholates into aldehydes and ketones by aromatic halides in liquid ammonia. A new electrochemically induceable reaction (1982) (24)
- APPLICATION OF LASER PULSE PHOTOINJECTION OF ELECTRONS FROM METAL ELECTRODES TO THE DETERMINATION OF REDUCTION POTENTIALS OF ORGANICS RADICALS IN APRO TIC SOLVENTS (1995) (24)
- Dimerization of electrochemically generated ion radicals: mechanisms and reactivity factors (2004) (24)
- Oxidation of 10-methylacridan, a synthetic analog of NADH and deprotonation of its cation radical: convergent application of laser flash photolysis, and direct and redox catalyzed electrochemistry to the kinetics of deprotonation of the cation radical (1991) (24)
- Product distribution in preparative-scale electrolysis (1981) (24)
- Competitive pathways in the electrochemical reduction of activated olefins (1983) (24)
- Role of Environmental Factors in the Dynamics of Intramolecular Dissociative Electron Transfer. Effect of Solvation and Ion-Pairing on Cleavage Rates of Anion Radicals (1995) (24)
- The role of water in organic electroreductive dimerizations in aprotic solvents. How general is the anion radical—water complex mechanism? (1982) (24)
- Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects (2008) (24)
- Disproportionation and e.c.e. mechanisms (1973) (24)
- Characterization of electrochemical reactions hidden in the background discharge the redox catalyzed reduction of fluorobenzene (1979) (24)
- Effect of substrate inhibition and cooperativity on the electrochemical responses of glucose dehydrogenase. Kinetic characterization of wild and mutant types. (2011) (24)
- Dissociative Electron Transfer to Dihaloalkanes. Electrochemical Reduction of 1,3-Dihaloadamantanes, 1,4-Dihalobicyclo[2.2.2]octanes, and 1,3-Dihalobicyclo[1.1.1]pentanes (1994) (23)
- Ligand “noninnocence” in coordination complexes vs. kinetic, mechanistic, and selectivity issues in electrochemical catalysis (2018) (23)
- Current dips in polarography and cyclic voltammetry associated with electrochemical inducement of chemical reactions (1980) (23)
- Determination of formal potentials of chemically unstable redox couples by second-harmonic alternating current voltammetry and cyclic voltammetry. Application to the oxidation of thiophenoxide ions (1993) (23)
- Product distribution in preparative scale electrolysis: Part VII. Competition at the level of the first-electron intermediate between self-coupling, coupling with the substrate and first-order deactivation followed by further electron transfer (1981) (23)
- Steric and Kinetic Isotope Effects in the Deprotonation of Cation Radicals of NADH Synthetic Analogs (1995) (23)
- Concerted and stepwise proton-coupled electron transfers in aquo/hydroxo complex couples in water: oxidative electrochemistry of [Os(II)(bpy)(2)(py)(OH(2))](2+). (2009) (23)
- Electrodimerization: Part XII. Coupling mechanism of activated olefins at preparative scale concentrations (1976) (23)
- Effect of the Electrode Continuum of States in Adiabatic and Nonadiabatic Outer-Sphere and Dissociative Electron Transfers. Use of Cyclic Voltammetry for Investigating Nonlinear Activation-Driving Force Laws (2002) (23)
- ECE reaction pathways in the electrochemical reduction of dicyanocobalamin (1980) (23)
- Electrolytic reduction of p-bromobenzophenone in the presence of benzenethiolate: an electrochemically catalysed aromatic nucleophilic substitution (1974) (22)
- Application of dual reference electrode to electrochemical studies in highly resistive media (1978) (22)
- Electrochemically catalyzed aromatic nucleophilic substitution. Reactivity of cyanide ions toward aryl radicals in liquid ammonia (1986) (22)
- Electrochemical cyclization: I. Formal kinetics for voltammetric studies (linear sweep, rotating disc, polarography) (1974) (22)
- Homogeneous redox catalysis of multielectron electrochemical reactions: Part I. Competition between heterogeneous and homogeneous electron transfer (1985) (21)
- Convolution and finite difference approach (1978) (21)
- Analyzing Product Inhibition and pH Gradients in Immobilized Enzyme Films As Illustrated Experimentally by Immunologically Bound Glucose Oxidase Electrode Coatings (1999) (21)
- Thermodynamic Control in Ion Radical Cleavages through Out-of-Cage Diffusion of Products. Dynamics of C−C Fragmentation in Cation Radicals of tert-Butylated NADH Analogues and Other Ion Radicals (1996) (21)
- Molecular Recognition of Artificial Single-Electron Acceptor Cosubstrates by Glucose Oxidase? (1996) (21)
- Electrochemical reduction of halobenzophenones in liquid ammonia (1978) (21)
- Disproportionation and ECE mechanisms—III. Asymmetrical potential-scan method: diagnostic criteria and rate-determination procedures and application to the reduction mechanism of the uranyl cation in perchloric acid (1971) (21)
- Molecular Electrochemistry: Recent Trends and Upcoming Challenges (2016) (21)
- Perfluoroalkylation of imidazoles by electrochemically induced srn1 substitution. (1990) (21)
- Concertedness in proton-coupled electron transfer cleavages of carbon–metal bonds illustrated by the reduction of an alkyl cobalt porphyrin (2013) (20)
- Introduction: molecular and biomolecular electrochemistry. (2008) (20)
- Mechanism and Reactivity Parameters of the Reduction of Arylmethyl Radicals from Time-Resolved Electron-Photoinjection Experiments (1998) (20)
- Electrochemistry of vitamin B12: Part VIII. Thermodynamic and kinetic trans-effects in B12r-B12s oxido-reduction (1982) (20)
- Molecular environment effects in redox and coordination chemistry. Protection against solvation, local solvation, and steric hindrance to ligation in the electrochemistry of basket-handle iron porphyrins (1986) (20)
- Potential dependence of the electrochemical transfer coefficient. An impedance study of the reduction of aromatic compounds (1979) (19)
- Unusual reactions resulting from the addition on olefins of trifluoromethyl radicals obtained from dissociative electron transfer between electrochemically generated aromatic anion radicals and trifluoromethyl bromide (1989) (19)
- REDUCTIVE ELECTROCHEMISTRY OF RHODIUM PORPHYRINS. DISPROPORTIONATION OF INTERMEDIARY OXIDATION STATES (1997) (19)
- One-electron reduction of chromium(III) porphyrins: formation of chromium(II) porphyrins or chromium(III) porphyrin .pi.-radical anions (1992) (19)
- Investigation of Dissociative Electron Transfer Mechanisms and Reactivity Patterns through Kinetic Amplification by a Chain Process (2000) (19)
- Electroenzymatic reactions. Investigation of a reductive dehalogenase by means of electrogenerated redox cosubstrates. (2005) (19)
- Electrochemistry of vitamin B12: Part IX. The Co(III)/Co(II) couple in non-aqueous solvents (1982) (19)
- Reversible two-electron-one-proton systems in the ring-centered oxidation of metalloporphyrins bearing secondary amide-linked superstructures (1991) (19)
- Homogeneous redox catalysis of multielectron electrochemical reactions: Part II. Competition between homogeneous electron transfer and addition on the catalyst (1985) (19)
- Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry of Systems Approaching Reversibility (2018) (18)
- New ligand-bridged polyruthenium(II) complexes with cofacial tetrapyrazolic macrocycles (1986) (18)
- Cyclic Voltammetry of Electrocatalytic Films: Fast Catalysis Regimes (2015) (18)
- Brönsted basicity of vitamin B12s (1975) (18)
- Proton-coupled electron transfers in biomimetic water bound metal complexes. The electrochemical approach. (2011) (18)
- Why are proton transfers at carbon slow? Self-exchange reactions. (2004) (17)
- Cyclic voltammetry of immobilized redox enzymes. Interference of steady-state and non-steady-state Michaelis /Menten kinetics of the enzyme /redox cosubstrate system (2003) (17)
- Resistance conpensation and faradaic instability in diffusion controlled processes (1978) (17)
- Linear sweep voltammetry: kinetic control by charge transfer and/or secondary chemical reactions: II. Reduction of carbonyl compounds (1973) (17)
- Improvement and estimation of precision in the cyclic voltammetric determination of rate constants and activation parameters of coupled homogeneous first order reactions. Halide cleavage in anion radicals of chloroanthracenes (1993) (17)
- Competition between SN2 and Single Electron Transfer Reactions as a Function of Steric Hindrance Illustrated by the Model System AlkylCl + NO- (2000) (17)
- Catalysis of the electrochemical oxidation of glucose by glucose oxidase and a single electron cosubstrate: kinetics in viscous solutions (1996) (17)
- New complexes of ruthenium(II) with a tetrapyrazolic macrocycle (1986) (17)
- Transition between Concerted and Stepwise Dissociative Electron Transfers. An Example of How a Change of Temperature May Trigger a Change in Mechanism in Electrochemical Experiments (1997) (17)
- Catalysis of Electrochemical Reactions by Surface-Active Sites: Analyzing the Occurrence and Significance of Volcano Plots by Cyclic Voltammetry (2017) (16)
- Stepwise and Concerted Pathways in Thermal and Photoinduced Electron-Transfer/Bond-Breaking Reactions (2000) (16)
- Electrochemistry of synthetic analogues of NAD dimers (1992) (16)
- NONCHAIN PROCESSES IN NUCLEOPHILIC SUBSTITUTIONS TRIGGERED BY ELECTRON TRANSFER (SRN1). PHOTOCHEMICAL AND ELECTROCHEMICAL INDUCTION OF THE SUBSTITUTIO N OF 1-IODOADAMANTANE BY ARENETHIOLATE IONS (1995) (16)
- Electrochemical cyclization: II. Intramolecular pinacolization of 1,3-dibenzoylpropane in acetonitrile (1974) (16)
- Molecular environment effects on the reactivity of porphyrins. Influence of basket-handle superstructures on the formation of five-coordinated complexes of iron(II) with neutral nitrogen bases (1986) (16)
- Electrochemically induced aromatic substitution. The 2-nitropropane anion, a powerful nucleophile in SRN1 aromatic substitution (1986) (15)
- The origin of leaving-group effects in radical reactions triggered by solvated electron reduction (1993) (15)
- Electrochemical reduction of tetraphenylphosphonium cation in low acidity media (1975) (15)
- Homogeneous Catalysis of Electrochemical Reactions: The Steady-State and Nonsteady-State Statuses of Intermediates (2018) (15)
- Surface and volume follow-up chemical reactions in electrochemical mechanisms — Double-layer effects (1980) (15)
- Activation barriers in the homolytic cleavage of radicals and ion radicals. (2003) (15)
- Electron transfer catalyzed reactions. Electrochemical induction of the hydrogen atom transfer oxidation of alcohols and other substrates by aromatic halides (1987) (15)
- Electrochemically induced SRN1 aromatic nucleophilic substitution. Monoanions of β-dicarbonyl and β-cyanocarbonyl compounds as nucleophiles (1989) (15)
- Conductive Mesoporous Catalytic Films. Current Distortion and Performance Degradation by Dual-Phase Ohmic Drop Effects. Analysis and Remedies (2016) (15)
- Reorganization energy and pre-exponential factor from temperature-dependent experiments in electron transfer reactions. A typical example: the reduction of tert-nitrobutane. (2012) (14)
- .sigma.-Alkyl iron porphyrins from sterically encumbered alkyl halides and iron(0) porphyrins. Stabilities of the four accessible oxidation states (1989) (14)
- Acceleration of the Homogeneous and Electrochemical Reductions of Dioxygen in Aprotic Media by Ammonium Ions. Is the Driving Force a Function of NH4+ Concentration? What Is the Mechanism of the Reaction? (2007) (14)
- Diffusion-migration for one-dimensional mixed conduction in thin layers at steady state (1987) (14)
- Electron transfer coupling of diffusional pathways Potential step chronoamperometry and cyclic voltammetry of cobalt(II) tetraphenylprophyrin and 4-nitrotoluene in dimethylformamide solutions (1985) (14)
- Effect of base pairing on the electrochemical oxidation of guanine. (2010) (14)
- Reaction of carbon monoxide with alkyliron porphyrins generated from alkyl halides and electrochemically produced iron(I) and iron(0)porphyrins (1990) (13)
- Phenoxide ions as nucleophiles in SRN1 aromatic nucleophilic substitution (1988) (13)
- Theoretical and mechanistic aspects of proton-coupled electron transfer in electrochemistry (2017) (13)
- Electrochemically induced SRN 1 substitution of fluorinated aryl halides. Application to the synthesis of fluorinated-aryl heterocycles (1997) (13)
- Dissociative electron transfer and the principle of microscopic reversibility (2000) (13)
- Kinetics of the protonation of anthracene anion radical by phenol in dimethylformamide (1984) (13)
- Electrochemical Reduction of Diaryl Trithiocarbonates and Related Compounds. (1980) (13)
- Manifestations of Bridgehead-Bridgehead Interactions in the Bicyclo[1.1.1]pentane Ring System. (1999) (13)
- Molecular environment effects in redox chemistry. Reversible multielectron oxidation of amide-linked basket-handle metalloporphyrins (1984) (12)
- Electron Transfer Chemistry of Psoralen and Coumarin Derivatives by Means of Radiolytic and Electrochemical Experiments (1997) (12)
- Cyclic voltammetric responses of horseradish peroxidase multilayers on electrodes. (2006) (12)
- Addition of aryl radicals generated from electrochemical reduction of aryl halides on carbon-carbon double bonds. (1988) (12)
- Catalysis at the nanoscale may change selectivity (2016) (12)
- Electrochemical generation and detection of transient intermediates: Dimerizing species (1991) (12)
- Redox enzymes immobilized on electrodes with solution cosubstrates. General procedure for simulation of time-resolved catalytic responses. (2006) (12)
- Detection of electroactive transient intermediates of electrochemical reactions by steady state and time-dependent techniques: Competition between heterogeneous electron transfer and homogeneous chemical reactions (1989) (11)
- Reductive elimination in vicinal dibromides. Electrochemical reduction of 1,2-dibromo-3-(4-substituted)-phenylpropanes and induction of double-bond migration in the resulting olefins. (1994) (11)
- Hydrogen and proton exchange at carbon. Imbalanced transition state and mechanism crossover† (2019) (11)
- Studies of modified electrodes starting from pyrrole monomers derivatized by anthraquinone, phenothiazine or anthracene moieties on the nitrogen or in the 3-position. Syntheses, cyclic voltammetry and a study of charge-transfer reactions (1990) (11)
- A new convenient synthesis of 5-aryl uracils using SRN1 aromatic nucleophilic substitution (1993) (11)
- Coupling of Electrode Electron Transfers with Homogeneous Chemical Reactions (2006) (11)
- Cyclic voltammetry of fast conducting electrocatalytic films. (2015) (10)
- Investigating the reduction characteristics of transient free radicals by laser-pulse electron photo-injection mechanism diagnostic criteria and determination of reactivity parameters from time-resolved experiments (1999) (10)
- The nature of electronic conduction in "pseudocapacitive" films. Transition from the insulator state to band-conduction. (2019) (10)
- Observation of some reactive pyrrolic radical-cations by use of fast voltammetry at ultramicroelectrodes (1991) (10)
- Electrochemically induced reactions: Kinetics of the competition with homogeneous electron transfer in non-catalytic systems: Application to the substitution of 4-bromobenzophenone by cyanide ions in liquid ammonia (1985) (10)
- Evidence for Orbital Symmetry Restrictions in Intramolecular Dissociative Electron Transfer (1995) (10)
- Electrochemical approach to the dynamics of molecular recognition of redox enzyme sites by artificial cosubstrates in solution and in integrated systems. (2000) (9)
- Electrochemical Capacitive Charging in Porous Materials. Discriminating between Ohmic Potential Drop and Counterion Diffusion (2019) (9)
- Self-inhibition in catalytic processes: Cyclic voltammetry (1996) (9)
- Heterogeneous Molecular Catalysis of Electrochemical Reactions: Volcano Plots and Catalytic Tafel Plots. (2017) (9)
- VACUUM-TRIGGERED FLASH DESOLUBILIZATION METHOD FOR DETERMINING THE SOLUBILITY OF GASES IN PURE AND MIXED SOLVENTS. APPLICATION TO CARBON DIOXIDE (1994) (9)
- Electrochemical reductive cleavage of biaryls. The formation of anthracene and 9,10-dihydroanthracene from 9,9′-bianthryl (1979) (9)
- Slow charge transfer associated with a fast equilibrated follow-up dimerization reaction (1984) (8)
- Electrochemistry of hanging-base basket-handle iron porphyrins. Coordination of iron(II) by the base and dioxygen (1986) (8)
- Proton-coupled intervalence charge transfer: concerted processes. (2012) (8)
- Carbon monoxide insertion in carbon-iron porphyrin bonds generated from alkyl halides and electrochemically reduced iron porphyrins (1988) (8)
- A computer coupled high frequency a.c. technique for investigating fast non-Volmerian electron transfers (1979) (8)
- Improvement and estimation of precision in cyclic voltammetry: Thermodynamic and kinetic determinations in chemically reversible systems (1993) (8)
- Repetitive cyclic voltammetry of irreversible systems (1993) (8)
- Electrochemistry of vitamin B12. Equilibria, kinetics and mechanisms in the B12a - B12r - B12s oxido-reduction (1979) (8)
- ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE IN WEAKLY PROTIC MEDIUM (1979) (7)
- Mixed-valent states in the redox chemistry of double- and triple-decker-sandwich free base and copper porphyrins (1993) (7)
- Perfluoroalkylation of purine and pyrimidine bases by electrochemically induced SRN1 substitution. (1992) (7)
- Coefficients of Thermal Expansion (1987) (7)
- BARRIERS TO INTERNAL ROTATION IN 1,3,5-TRINEOPENTYLBENZENES. IX. FORCE FIELD CALCULATIONS AND CARBON-13 AND DEUTERON NMR RELAXATION MEASUREMENTS ON 1,3,5-TRINEOPENTYLBENZENE (1981) (7)
- Relationship between reduction potentials and anion radical cleavage rates in aromatic molecules (1984) (7)
- Homogeneous redox catalysis (1991) (7)
- Improvement and estimation of precision in the cyclic voltammetric determination of rate constants and activation parameters of coupled homogeneous second order reactions. Reaction of n-butyl bromide with anthracene anion radicals (1993) (6)
- Single Electron Transfer at an Electrode (2006) (6)
- Dynamics of Proton Transfer from Cation Radicals. Kinetic and Thermodynamic Acidities of Cation Radicals of NADH Analogues (1992) (6)
- Reactions occurring during mixing. Basic reaction schemes and examples in solvated electron reductions (1993) (6)
- Dynamics of proton transfer at nonactivated carbons from laser flash electron photoinjection experiments. (2002) (6)
- Redox Reltionship between Carbeneiron and σ‐Alkyliron Porphyrins (1981) (6)
- Homogeneous chemical catalysis of electrochemical reactions (1978) (6)
- Product distribution in preparative-scale electrolysis: Part VIII. Transition between fast and slow chemical kinetics. Application to mechanisms involving one or two first-order consecutive chemical steps (1987) (6)
- Investigating the Dynamics of Carbanion Protonation by Means of Laser Flash Electron Photoinjection from an Electrode (2003) (6)
- The Dimerization of 9-Cyanoanthracene Anion Radicals. A One- or Two-Step Reaction? (1988) (6)
- Dimerization of aryl radicals as a termination step in SRN1 aromatic nucleophilic substitution (1992) (6)
- Formal oxidation potentials of aromatic hydrocarbons in N,N '-dimethylformamide: Correlation with vertical ionization potentials (1990) (6)
- Origin of activation barriers in the dimerization of neutral radicals: a "nonperfect synchronization" effect? (2005) (6)
- Integrated molecular systems: fixation of carbon monoxide on iron(I) in simple and superstructured porphyrins (1985) (6)
- Comparison of u.v.–visible spectra of iron(I)–porphyrin– and iron(II)–porphyrin (thiolato)-(thiocarbonyl) and -(carbene) complexes. Relevance to ferrous cytochrome P450 complexes (1981) (6)
- Ohmic drop correction in electrochemical techniques. Multiple potential step chronoamperometry at the test bench (2020) (5)
- Physical organic chemistry. Electron transier chemistry. Molecular electrochemistry (1997) (5)
- Mechanism of the Electrochemical Reduction of Vitamin B 12r (1976) (5)
- Application of convolution procedures to chronopotentiometry (1977) (5)
- Metal Alkylation of Electrochemically Generated Low-Valent Metalloporphyrins. Is There Something Special with Rhodium? (1998) (5)
- Electrochemical Reduction of 3-(Trimethylstannyl)adamant-1-yl and 4-(Trimethylstannyl)bicyclo[2.2.2]oct-1-yl Bromides and Iodides. (1996) (5)
- Double fragmentation in cation radicals. An example in the NADH analogues series (1998) (5)
- Synthesis of the erythro and threo Forms of 1,2-Bis(4-hydroxy-3-methoxyphenyl)-1,3-propanediol. (1980) (5)
- Outer-Sphere and Inner-Sphere Processes in Reductive Elimination. Direct and Indirect Electrochemical Reduction of Vicinal Dibromoalkanes. (1990) (4)
- Supramolecular effects in redox chemistry. Local solvation in basket-handle iron porphyrins containing an increasing number of secondary amide groups (1987) (4)
- Compared selectivities of redox-catalyzed and direct electrochemical processes Part 1. Reactions in which product selection involves competition between dimerization and first-order reactions (1995) (4)
- A Stable Surface Modified Platinum Electrode Prepared by Coating with Electroactive Polymer (2001) (4)
- σ-Acyl iron porphyrins from the reaction of carboxylic anhydrides with electrochemically generated iron(“0”) and iron(I) porphyrins (1988) (4)
- Avidin–Biotin Assembling of Horseradish Peroxidase Multi-Monomolecular Layers on Electrodes (2006) (4)
- Electron-transfer dynamics in highly reduced states of simple and superstructured metalloporphyrins (1992) (4)
- Catalysis of Electrochemical Reactions at Redox Polymer Coated Electrodes. Mediation of the Fe(III)/Fe(II) Oxido-Reduction by a Polyvinylpyridine Polymer Containing Coordinatively Attached Bisbipyridine Chlororuthenium Redox Centers. (1987) (4)
- Preparative organic electroreductions with a hydrogen anode in non-aqueous medium (1977) (4)
- Electrodimerization III. E.p.r. detection of transient immonium radicals (1970) (3)
- Electrochemical Induction of SRN1 Nucleophilic Substitution (1992) (3)
- Thermodynamic and kinetic basicities of the carbon and oxygen ends of enolates. Their role in the reductive cleavage electrochemistry of α-substituted acetophenones (1999) (3)
- Current Issues in Molecular Catalysis Illustrated by Iron Porphyrins as Catalysts of the CO2‐to‐CO Electrochemical Conversion (2016) (3)
- Electrochemistry of vitamin B12. Alkyl cobalamins and cobinamides (1979) (3)
- Chronopotentiometry of systems involving follow-up chemical reactions (1978) (3)
- Supramolecular entropy gains: simple and superstructured iron porphyrins (1992) (3)
- Dissociative Electron Transfers (2015) (3)
- Quantum yields lower than unity in photo- induced dissociative electron transfers: the reductive cleavage of carbon tetrachloride. (2000) (3)
- Supramolecular Effects in the Redox and Coordination Chemistry of Superstructured Iron Porphyrins (1988) (2)
- Proton Relays in Molecular Catalysis of Electrochemical Reactions (2018) (2)
- Electrodimerization IV. Formation of substituted pinacols in the reduction of α-substituted carbonyl compounds (1970) (2)
- Successive removal of chloride ions from organic polychloride pollutants. Mechanisms of reductive electrochemical elimination in aliphatic gem-polychlorides, alpha,beta-polychloroalkenes, and alpha,beta-polychloroalkanes in mildly protic medium. (2003) (2)
- Compared selectivities of redox-catalyzed and direct electrochemical processes Part 2. Reactions in which product selection involves competition between dimerization and deactivation followed by further reduction (or oxidation) (1996) (2)
- Enzymatic Catalysis of Electrochemical Reactions (2006) (2)
- Electrochemically Catalyzed Aromatic Nucleophilic Substitution. (1986) (1)
- Mediated electrochemical induction of chemical reactions: Competition with a first order deactivation of the operating intermediate (1991) (1)
- Application of Direct and Indirect Electrochemical Techniques to the Investigation of Fast Kinetics (1991) (1)
- Jacques Moiroux (1943–2002) (2002) (1)
- Electrochemically Induced Nucleophilic Substitution of Perfluoroalkyl Halides. An Example of a Dissociative Electron-Transfer-Induced Chemical Reaction. (1991) (1)
- Aromatic anion radicals and di-anions: redox reagents and/or nucleophiles? partial inversion of configuration in the electrochemical and chemical reductive akylation of anthracene (1985) (1)
- ELECTRODIMERIZATION PART 11, COUPLING MECHANISM OF AN ACTIVATED OLEFIN, P-METHYLBENZYLIDENE-MALONONITRILE AS STUDIED BY CONVOLUTION POTENTIAL SWEEP VOLTAMMETRY (1975) (1)
- Single Electron Transfer and Nucleophilic Substitution. Reaction of Alkyl Bromides with Aromatic Anion Radicals and Low Oxidation State Iron Porphyrins. (1989) (1)
- Ligation of iron(II) by bromide ions in the redox chemistry of iron porphyrins: Effect of molecular superstructures (1987) (1)
- Correction to “Proton-Coupled Electron Transfers: pH-Dependent Driving Forces? Fundamentals and Artifacts” (2014) (1)
- Molecular Catalysis of Electrochemical Reactions by Low Valent Transition Metal Complexes: Metalloporphyrins (1993) (1)
- Controlling Factors of Stepwise Versus Concerted Reductive Cleavages. Illustrative Examples in the Electrochemical Reductive Breaking of Nitrogen‐Halogen Bonds in Aromatic N‐Halosultams. (1993) (1)
- Aryl Radicals from Electrochemical Reduction of Aryl Halides. Addition on Olefins. (1991) (1)
- A method for modifying the surface of carbon materials by electrochemical reduction of diazonium salts in particular for the production of composite materials, and in this way modified carbon materials. (1992) (1)
- NUCLEOPHILIC SUBSTITUTION OF AROMATIC HALIDES BY ELECTROGENERATED SUPEROXIDE IONS (1981) (1)
- A Convenient Synthesis of Perfluoroalkylated and Fluorinated-Aryl Nitrogen Bases by Electrochemically Induced SRN1 Substitution. (2010) (0)
- Ultrashort‐lived excited state of tert‐Butyl‐BNAH, a synthetic analogue of NADH: Ultrafast photodissociation? (2008) (0)
- ELECTROCHEMICAL CYCLIZATION. CATHODIC REDUCTION OF SOME BIS-ACTIVATED OLEFINS (1977) (0)
- Supramolecular effects in superstructured iron porphyrins: Entropic and enthalpic effects (1989) (0)
- Outer-Sphere Dissociative Electron Transfer to Organic Molecules: A Source of Radicals or Carbanions? Direct and Indirect Electrochemistry of Perfluoroalkyl Bromides and Iodides. (1990) (0)
- Chemical vs. Redox Catalysis of Electrochemical Reactions. Reduction of trans-1,2-Dibromocyclohexane (I) by Electrogenerated Aromatic Anion Radicals and Low Oxidation State Metalloporphyrins (1988) (0)
- Phenoxide Ions as Nucleophiles in SRN1 Aromatic Nucleophilic Substitution. (1988) (0)
- Oxidation of 10‐Methylacridan, a Synthetic Analogue of NADH, and Deprotonation of Its Cation Radical. Convergent Application of Laser Flash Photolysis and Direct and Redox Catalyzed Electrochemistry to the Kinetics of Deprotonation of the Cation Radical. (1991) (0)
- Synthese de trifluoromethanesulfinates (1988) (0)
- ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE. COMMENTS (1985) (0)
- CHEMICAL CATALYSIS OF THE ELECTROCHEMICAL REDUCTION OF ALKYL HALIDES. COMPARISON BETWEEN COBALT-TETRAPHENYL PORPHIN AND VITAMIN B12 DERIVATIVES (1979) (0)
- Electron Transfer Catalyzed Reactions. Electrochemical Induction of the Hydrogen Atom Transfer Oxidation of Alcohols and Other Substrates by Aromatic Halides. (1987) (0)
- A New Convenient Synthesis of 5‐Aryl Uracils Using SRN1 Aromatic Nucleophilic Substitution. (1993) (0)
- Erratum to “Kinetic control by the substrate and the cosubstrate in electrochemically monitored redox enzymatic immobilized systems. Catalytic responses in cyclic voltammetry and steady state techniques” [J. Electroanal. Chem. 521 (2002) 8–15] (2002) (0)
- A process for the electrochemical production of carbon material whose surface is modified with functional groups, modified new carbon material and surfactant, and use of this material (1998) (0)
- New Complexes of Ruthenium(II) with a Tetrapyrazolic Macrocycle. (1986) (0)
- Electrochemically-Induced SRN1 Aromatic Nucleophilic Substitution. Monoanions of β-Dicarbonyl and α-Cyanocarbonyl Compounds as Nucleophiles. (1989) (0)
- Dissociative Electron Transfer. Homogeneous and Heterogeneous Reductive Cleavage of the Carbon (1986) (0)
- PRODUCT DISTRIBUTION IN PREPARATIVE SCALE ELECTROLYSIS. PART V. EC REACTION SCHEMES FOLLOWED BY COMPETITION BETWEEN DIMERIZATION AND FIRST-ORDER DEACTIVATION OR FURTHER ELECTRON TRANSFER (1981) (0)
- Additions and Corrections - Diffucsional Pathways for Multiply Charged Ions Incorporated in Polyelectrolyte Coatings on Graphite Electrodes. Co(C2O4)33- in coatings of Pronated Polylyaine (1983) (0)
- Electron Transfer and Bond Breaking — Recent Advances (2006) (0)
- Process for electrochemically embodiment of a carbonaceous material, whose surface is modified with functionalized groups, new modified carbonaceous material surface and application of this material. (1998) (0)
- PRODUCT DISTRIBUTION IN PREPARATIVE SCALE ELECTROLYSIS. PART VI. COMPETITION BETWEEN DIMERIZATION AND FIRST-ORDER DEACTIVATION (1981) (0)
- NUCLEOPHILIC REACTIONS OF THE SUPEROXIDE ION. SUBSTITUTION OF ARYL HALIDES (1984) (0)
- Outer-Sphere and Inner-Sphere Processes in Organic Chemistry. Reaction of Trifluoromethyl Bromide with Electrochemically Generated Aromatic Anion Radicals and Sulfur Dioxide Anion Radicals. (1990) (0)
- Electrochemically Induced SRN1 Substitution of Fluorinated Aryl Halides. Application to the Synthesis of Fluorinated-Aryl Heterocycles. (1997) (0)
- MOLECULAR ENVIRONMENT EFFECTS IN REDOX CHEMISTRY. ELECTROCHEMISTRY OF ETHER-LINKED BASKET-HANDLE AND AMIDE-LINKED BASKET-HANDLE AND PICKET-FENCE IRON PORPHYRINS (1984) (0)
- Electrochemical Approach to Organic Electron-Transfer Chemistry (1988) (0)
- New Ligand-Bridged Polyruthenium(II) Complexes with Cofacial Tetrapyrazolic Macrocycles. (1986) (0)
- Electron transfer associated to bond breaking: Passage from sequential mechanism to dissociative electron transfer as a function of molecular structure, environment and energy of the incoming electron (2008) (0)
- THERMODYNAMICS OF SUCCESSIVE ELECTRON TRANSFERS, INTERNAL AND SOLVATION ENTHALPY AND ENTROPY VARIATIONS IN A SERIES OF POLYNITRO COMPOUNDS (1973) (0)
- Electrochemically Catalyzed Aromatic Nucleophilic Substitution. Phenoxide Ion as Nucleophile. (1988) (0)
- Molecular Environment Effects in Redox and Coordination Chemistry. Protection Against Solvation, Local Solvation, and Steric Hindrance to Ligation in the Electrochemistry of Basket-Handle Iron Porphyrins. (1987) (0)
- Electrochemistry of NADH/NAD+ Analogues. A Detailed Mechanistic Kinetic and Thermodynamic Analysis of the 10-Methylacridan/10-Methylacridinium Couple in Acetonitrile (1990) (0)
- Electron-transfer rates measured on ultra-microelectrodes in highly reduced states of simple and superstructured metalloporphyrins. (1993) (0)
- Electrochemistry of Hanging-Base Basket-Handle Iron Porphyrins. Coordination of Iron(II) by the Base and Dioxygen. (1987) (0)
- Process for producing electrochemically a carbon material whose surface is modified by groups functionalized, new carbon material modifies the surface and application of this material (1997) (0)
- ELECTROLYTIC REDUCTION OF P-BROMOBENZOPHENONE IN THE PRESENCE OF BENZENETHIOLATE, AN ELECTROCHEMICALLY CATALYSED AROMATIC NUCLEOPHILIC SUBSTITUTION (1975) (0)
- channel by electrochemical production method of a carbon material whose surface is modified with organic groups, use of the material modifies (1997) (0)
- Supporting Information Energy Storage. Pseudocapacitance in Prospect (2019) (0)
- ELECTROCHEMISTRY OF VITAMIN B12. 2. REDOX AND ACID-BASE EQUILIBRIA IN THE B12A B12R SYSTEM (1977) (0)
- Correction to Hydrogen-Bond Relays in Concerted Proton–Electron Transfers (2013) (0)
- ELECTROCHEMISTRY OF VITAMIN B12. I. ROLE OF THE BASE‐ON BASE‐OFF REACTION IN THE OXIDOREDUCTION MECHANISM OF THE B12R‐B12S SYSTEM (1976) (0)
- The Dimerization of 9‐Cyanoanthracene Anion Radicals. A One‐ or Two‐Step Reaction? (1989) (0)
- ELECTRODIMERIZATION. PART XII. COUPLING MECHANISM OF ACTIVATED OLEFINS AT PREPARATIVE SCALE CONCENTRATIONS (1977) (0)
- Mechanisms and Reactivity in Organic Electrochemistry. Recent Advances (1990) (0)
- A Simple Model for the Kinetics of Dissociative Electron Transfer in Polar Solvents. Application to the Homogeneous and Heterogeneous Reduction of Alkyl Halides. (1988) (0)
- Electrochemically Induced Aromatic Substitution. The 2-Nitropropane Anion, a Powerful Nucleophile in SRN1 Aromatic Substitution. (1987) (0)
- Molecular Fe Catalyst Electroreduction to CO by a 2 A Local Proton Source Enhances CO (2013) (0)
- Observation of the Cation Radicals of Pyrrole and of Some Substituted Pyrroles (I) and (II) in Fast‐Scan Cyclic Voltammetry. Standard Potentials and Lifetimes. (1990) (0)
- Glossary of Symbols (2006) (0)
- Outer-Sphere Electron-Transfer Reduction of Alkyl Halides. A Source of Alkyl Radicals or of Carbanions? Reduction of Alkyl Radicals. (1989) (0)
- Surface Modifications with Heteropoly and Isopoly Oxometalates. Part 2. Electrocatalytic Behaviour of Glassy Carbon Surfaces Modified with 17-Tungsto, 1-Molybdo-diphosphate. (1988) (0)
- ELECTROCHEMICAL CYCLIZATION PART 2, INTRAMOLECULAR PINACOLIZATION OF 1,3-DIBENZOYLPROPANE IN ACETONITRILE (1974) (0)
- Use of laser pulse photoinjection of electrons from metal electrodes to the detection and the measurement of reduction potentials of organic radicals in aprotic solvents (2008) (0)
- ELECTROCHEMICAL CARBOXYLATION OF ACTIVATED OLEFINS (1979) (0)
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