Jennifer Schomaker
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Chemistry researcher
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Jennifer Schomakerchemistry Degrees
Chemistry
#5175
World Rank
#6308
Historical Rank
#960
USA Rank
Organic Chemistry
#949
World Rank
#1066
Historical Rank
#133
USA Rank
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Chemistry
Jennifer Schomaker's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Jennifer Schomaker Influential?
(Suggest an Edit or Addition)According to Wikipedia, Jennifer Schomaker is an American chemist who is a professor at the University of Wisconsin–Madison. Her research considers the total synthesis of natural and unnatural products. She was selected as an American Chemical Society Arthur C. Cope Scholar Awardee in 2021.
Jennifer Schomaker's Published Works
Published Works
- Arylation of halogenated pyrimidines via a Suzuki coupling reaction. (2001) (111)
- Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination (2014) (106)
- Tunable, Chemo- and Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts. (2017) (105)
- Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies. (2016) (101)
- Tunable, chemoselective amination via silver catalysis. (2013) (97)
- Mechanistic Aspects and Synthetic Applications of Radical Additions to Allenes. (2019) (70)
- Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration. (2012) (67)
- Diastereomerically and enantiomerically pure 2,3-disubstituted pyrrolidines from 2,3-aziridin-1-ols using a sulfoxonium ylide: a one-carbon homologative relay ring expansion. (2007) (66)
- Modular functionalization of allenes to aminated stereotriads. (2012) (63)
- Allene functionalization via bicyclic methylene aziridines. (2011) (60)
- Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide. (2004) (60)
- The conversion of allenes to strained three-membered heterocycles. (2014) (56)
- α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines. (2012) (56)
- Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of Sulfoxonium Ylides with 2-Amino Heterocycles. (2016) (54)
- A Stereoselective [3+1] Ring Expansion for the Synthesis of Highly Substituted Methylene Azetidines. (2017) (53)
- Synthesis of propargylic and allenic carbamates via the C-H amination of alkynes. (2012) (45)
- One-pot regio- and stereoselective cyclization of 1,2,n-triols. (2005) (45)
- A General Catalyst for Site-Selective C(sp(3))-H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp(3))-H Bonds. (2016) (44)
- Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity (2017) (42)
- Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer. (2017) (42)
- Mechanistic studies of copper(I)-catalyzed 1,3-halogen migration. (2015) (40)
- Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations. (2017) (39)
- Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes (2016) (39)
- Development of N-Heterocyclic Carbene–Copper Complexes for 1,3-Halogen Migration (2015) (38)
- Chemoselective allene aziridination via Ag(I) catalysis. (2013) (38)
- Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs. (2017) (37)
- C–H amination/cyclocarbonylation of allene carbamates: a versatile platform for the synthesis of α,β-unsaturated γ-lactams (2011) (34)
- Chemoselective silver-catalyzed nitrene insertion reactions (2014) (34)
- Direct lactonization of alkenols via osmium tetroxide-mediated oxidative cleavage. (2003) (34)
- Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins. (2008) (33)
- 1,4-Diazaspiro[2.2]pentanes as a flexible platform for the synthesis of diamine-bearing stereotriads. (2012) (32)
- Total synthesis of haterumalides NA and NC via a chromium-mediated macrocyclization. (2008) (32)
- Nitrene transfer catalysts for enantioselective C–N bond formation (2021) (31)
- Synthesis, Characterization, and Variable-Temperature NMR Studies of Silver(I) Complexes for Selective Nitrene Transfer. (2017) (31)
- Beyond benzyl grignards: facile generation of benzyl carbanions from styrenes. (2012) (30)
- Tunable catalyst-controlled syntheses of β- and γ-amino alcohols enabled by silver-catalysed nitrene transfer (2019) (29)
- Ring Expansion of Bicyclic Methyleneaziridines via Concerted, Near-Barrierless [2,3]-Stevens Rearrangements of Aziridinium Ylides. (2018) (29)
- Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination Through Rational Ligand Design. (2020) (28)
- Organometallics Roundtable 2011 (2012) (28)
- Synthesis of 1,3-diaminated stereotriads via rearrangement of 1,4-diazaspiro[2.2]pentanes. (2012) (28)
- Total synthesis of (+)-tanikolide via oxidative lactonization. (2004) (27)
- Stereocontrolled Syntheses of Seven-Membered Carbocycles by Tandem Allene Aziridination/[4+3] Reaction. (2016) (26)
- The synthesis of substituted phenylpyrimidines via suzuki coupling reactions (2006) (23)
- Tetrasubstituted pyrrolidines via a tandem aza-Payne/hydroamination reaction. (2007) (22)
- Formal Dyotropic Rearrangements in Organometallic Transformations (2015) (21)
- Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines. (2009) (21)
- Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes. (2010) (21)
- Complete stereodivergence in the synthesis of 2-amino-1,3-diols from allenes (2014) (20)
- Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy. (2016) (19)
- Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration. (2014) (19)
- α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation. (2018) (17)
- Oxidative allene amination for the synthesis of azetidin-3-ones. (2015) (17)
- Triple, Mutually Orthogonal Bioorthogonal Pairs through the Design of Electronically Activated Sulfamate-Containing Cycloalkynes. (2020) (14)
- Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions. (2017) (14)
- Selectivity in the addition reactions of organometallic reagents to aziridine-2-carboxaldehydes: the effects of protecting groups and substitution patterns. (2011) (13)
- 2,4,6‐trichloropyrimidine. Reaction with anilines (2000) (12)
- Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines (2014) (12)
- Stereocontrolled Synthesis of 1,3‐Diamino‐2‐ols by Aminohydroxylation of Bicyclic Methylene‐Aziridines (2013) (11)
- Rh-Catalyzed Aziridine Ring Expansions to Dehydropiperazines. (2020) (11)
- Intermolecular [3+3] ring expansion of aziridines to dehydropiperi-dines through the intermediacy of aziridinium ylides (2019) (11)
- Site-Selective, Catalyst-Controlled Alkene Aziridination (2018) (11)
- 1,3-Halogen migration as an entry to aryl coppers from an unintuitive starting material. (2014) (10)
- Investigation of transition metal-catalyzed nitrene transfer reactions in water. (2018) (9)
- Divergent reactivity of allene-containing α-diazoesters using Cu and Rh catalysis (2013) (9)
- Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer. (2019) (8)
- Biomimetic 2-Imino-Nazarov Cyclizations via Eneallene Aziridination. (2020) (7)
- Aziridinium Ylides: Underutilized Intermediates for Complex Amine Synthesis. (2020) (7)
- 2,4,6‐Trichloropyrimidine. Reaction with sodium amide (1999) (7)
- Activating Group Recycling: A Fresh Approach to Arene Functionalization (2012) (6)
- Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes. (2017) (6)
- Regioselective intramolecular allene amidation enabled by an EDA complex. (2020) (6)
- Sequential Reduction of Nitroalkanes Mediated by CS2 and Amidine/Guanidine Bases: A Controllable Nef Reaction. (2019) (6)
- Tunable Aziridinium Ylide Reactivity: Non-covalent Interactions Enable Divergent Product Outcomes. (2021) (6)
- 2,4,6-Trifluoropyrimidine. Reactions with nitrogen nucleophiles (2004) (6)
- Rigidifying Ag(I) Complexes for Selective Nitrene Transfer (2020) (6)
- Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols. (2017) (6)
- Recent Developments and Strategies for Mutually Orthogonal Bioorthogonal Reactions (2021) (5)
- Fluorinated Amine Stereotriads via Allene Amination. (2017) (5)
- Polymorphism of 5-(pyridin-2-ylmethylene)-3-phenyl-2-methylthio-3,5-dihydro-4H-imidazole-4-one (2011) (5)
- Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand. (2017) (5)
- Synthesis of Diastereomerically and Enantiomerically Pure 2,3‐Disubstituted Tetrahydrofurans Using a Sulfoxonium Ylide. (2005) (5)
- Origins of Catalyst-Controlled Selectivity in Ag-Catalyzed Regiodivergent C-H Amination. (2022) (5)
- Silver‐Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions (2019) (4)
- Aminosugar motifs via an allene aziridination strategy (2014) (4)
- Method for Small-Scale Production of Deuterochloroform. (2018) (4)
- Additions of N, O, and S heteroatoms to metal-supported carbenes: Mechanism and synthetic applications in modern organic chemistry (2021) (3)
- Synthetic Applications of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization Modifications. (2017) (3)
- Taming Nitrene Reactivity with Silver Catalysts (2020) (3)
- Allene Trifunctionalization via Amidyl Radical Cyclization and TEMPO Trapping. (2021) (2)
- Pd-catalyzed Heck-type Reactions of Allenes for Stereoselective Syntheses of Substituted 1,3-Dienes. (2021) (2)
- Synthesis of Propargylic and Allenic Carbamates via the C—H Amination of Alkynes. (2012) (2)
- Copper‐Catalyzed Recycling of Halogen Activating Groups via 1,3‐Halogen Migration. (2013) (2)
- Strategies for the Syntheses of Pactamycin and Jogyamycin. (2020) (2)
- Stereodivergent Metal-Catalyzed Allene Cycloisomerizations (2020) (2)
- An Enantiotropic Disorder–Partial Order Solid-State Transformation in a Molecular Solid Involving a Phase with Z′ = 12 (2017) (2)
- A General Catalyst for Site‐Selective C(sp3)—H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp3)—H Bonds. (2016) (2)
- Stereocontrolled Synthesis of the Aminocyclopentitol Core of Jogyamycin via an Ichikawa Rearrangement Reaction. (2019) (2)
- Oxidative allene amination for the synthesis of nitrogen-containing heterocycles. (2018) (2)
- 1,2-Azide Migration Enables Synthesis of β-Difluoroalkyl Azides (2020) (1)
- Correction to "Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination through Rational Ligand Design". (2021) (1)
- Allene Aziridination as a Tool for the Synthesis of Complex Amines (2018) (1)
- Silver-catalyzed enantioselective functionalizations of alkenes and alkynes: A short review (2021) (1)
- Re-Evaluation of Product Outcomes in the Rh-Catalyzed Ring Expansion of Aziridines with N-Sulfonyl-1,2,3-Triazoles. (2022) (1)
- Retraction of "Rh-Catalyzed Aziridine Ring Expansions to Dehydropiperazines". (2022) (1)
- Stereocontrolled Synthesis of 1,3‐Diamino‐2‐ols by Aminohydroxylation of Bicyclic Methylene‐Aziridines. (2013) (1)
- Re-evaluation of the mechanism of cytotoxicity of dialkylated lariat ether compounds (2020) (1)
- The Conversion of Allenes to Strained Three-Membered Heterocycles (2014) (1)
- The Synthesis of Substituted Phenylpyrimidines via Suzuki Coupling Reactions. (2006) (1)
- Scope and mechanistic investigations of Pd-catalyzed coupling/cyclizations and cycloisomerizations of allenyl malonates. (2021) (1)
- Dimethyldioxirane (DDO) (2021) (0)
- Back to basics (2022) (0)
- Synthetic ion channels: functional characterization of benzo-crown ether based derivatives (2022) (0)
- Chemoselective Silver‐Catalyzed Nitrene Insertion Reactions. (2014) (0)
- Acylated and alkylated benzo(crown-ethers) form ion-dependent ion channels in biological membranes (2022) (0)
- Enantioselective Synthesis of C2 and C1 Dienes (2011) (0)
- Divergent C-H Amidations and Imidations by Tuning Electrochemical Reaction Potentials. (2022) (0)
- C—H Amination/Cyclocarbonylation of Allene Carbamates: A Versatile Platform for the Synthesis of α,β‐Unsaturated γ‐Lactams. (2011) (0)
- Stereoselective Synthesis of Pyrrolidines from Aziridinols (2007) (0)
- Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines. (2014) (0)
- 1,3-Halogen Migration as an Entry to Aryl Coppers from an Unintuitive Starting Material (2014) (0)
- Enantiotropic phase transition in a molecular solid involving Z′ = 12 (2017) (0)
- 2,4,6‐Trichloropyrimidine. Reaction with Anilines. (2001) (0)
- α,β‐Unsaturated Imines via Ru‐Catalyzed Coupling of Allylic Alcohols and Amines. (2012) (0)
- 1,2-Azide Migration Enables Synthesis of b -Difluoroalkyl Azides (2020) (0)
- Ruthenium-Catalyzed Stereocontrolled Synthesis of Aminodiols (2014) (0)
- Direct Lactonization of Alkenols via Osmium Tetroxide Mediated Oxidative Cleavage. (2003) (0)
- Intermolecular [3+3] ring expansion of aziridines to dehydropiperi-dines through the intermediacy of aziridinium ylides (2020) (0)
- Synthesis of Haterumalide NC (2009) (0)
- Chiral amine synthesis refashioned (2022) (0)
- One‐Pot Regio‐ and Stereoselective Cyclization of 1,2,n‐Triols. (2005) (0)
- Aminosugar Motifs via an Allene Aziridination Strategy. (2014) (0)
- 2,4,6-Trichloropyrimidine. Reaction with Sodium Amide. (2000) (0)
- Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of SulfoxoniumYlides with 2-Amino Heterocycles. (2016) (0)
- Modular SNO-OCT scaffolds for multiple, rapid bioorthogonal labeling (2020) (0)
- Corrigendum: Rigidifying Ag(I) Complexes for Selective Nitrene Transfer (2021) (0)
- Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with α,β- Unsaturated Ketones and Imines (2009) (0)
- Total Synthesis of (+)‐Tanikolide via Oxidation Lactonization. (2004) (0)
- Unnatural α-amino acid synthesis (2023) (0)
- 2,4,6-Trifluoropyrimidine. Reactions with Nitrogen Nucleophiles. (2005) (0)
- PROFILE: Early Excellence in Physical Organic Chemistry (Jennifer Schomaker) (2014) (0)
- Triple, Mutually Orthogonal Cycloadditions Through the Design of Electronically Activated SNO-OCTs (2020) (0)
- Divergent Reactivity of Allene‐Containing α‐Diazoesters Using Cu and Rh Catalysis. (2013) (0)
- Biomimetic2‑Imino-Nazarov Cyclizations viaEneallene Aziridination (2020) (0)
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