John Clifton Huffman

John Clifton Huffman's AcademicInfluence.com Rankings

Chemistry

#1572

World Rank

#2329

Historical Rank

Polymer Chemistry

#32

World Rank

#35

Historical Rank

Inorganic Chemistry

#56

World Rank

#64

Historical Rank

chemistry Degrees

Download Badge

Chemistry

John Clifton Huffman's Degrees

PhD Chemistry Stanford University
Bachelors Chemistry University of California, Berkeley

Why Is John Clifton Huffman Influential?

(Suggest an Edit or Addition)

(See a Problem?)

John Clifton Huffman's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Molecular Design of Single-Site Metal Alkoxide Catalyst Precursors for Ring-Opening Polymerization Reactions Leading to Polyoxygenates. 1. Polylactide Formation by Achiral and Chiral Magnesium and Zinc Alkoxides, (η3-L)MOR, Where L = Trispyrazolyl- and Trisindazolylborate Ligands (2000) (350)
Structural and Magnetic Properties of [Ni4(.mu.3-OMe)4(dbm)4(MeOH)4] and [Ni4(.eta.1,.mu.3-N3)4(dbm)4(EtOH)4]. Magnetostructural Correlations for [Ni4X4]4+ Cubane Complexes (1995) (274)
Preparation and physical properties of trinuclear oxo-centered manganese complexes of general formulation [Mn3O(O2CR)6L3]0,+ (R = methyl or phenyl; L = a neutral donor group) and the crystal structures of [Mn3O(O2CMe)6(pyr)3](pyr) and [Mn3O(O2CPh)6(pyr)2(H2O)].cntdot.0.5MeCN (1987) (241)
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds? (2007) (215)
Crystal Structure of a Silyl Cation with No Coordination to Anion and Distant Coordination to Solvent (1993) (211)
Preparation and properties of the triply bridged, ferromagnetically coupled dinuclear copper(II) complexes [Cu2(OAc)3(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2 (1990) (188)
The molecular structures of Thiele's and Chichibabin's hydrocarbons. (1986) (185)
Monomeric metal alkoxides and trialkyl siloxides: (BDI)Mg(OtBu)(THF) and (BDI)Zn(OSiPh3)(THF). Comments on single site catalysts for ring-opening polymerization of lactides (2001) (181)
Modeling the photosynthetic water oxidation center. Preparation and properties of tetranuclear manganese complexes containing [Mn4O2]6+,7+,8+ cores, and the crystal structures of Mn4O2(O2CMe)6(bipy)2 and [Mn4O2(O2CMe)7(bipy)2](ClO4) (1989) (174)
Reactions of Metal-Metal Multiple Bonds. 10. Reactions of Mo2(OR)6 (M Triple Bond M) and (M(OR)4)x Compounds with Molecular Oxygen. Preparation and Characterization of Oxo-Alkoxides of Formula MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4 and Mo6O10(OR)12. (1984) (169)
Single-molecule magnets: a new class of tetranuclear manganese magnets. (2000) (169)
A new active catalyst species for enantioselective alkylation by phase-transfer catalysis (1994) (157)
Three-coordinate zinc amide and phenoxide complexes supported by a bulky Schiff base ligand. (2001) (156)
Molecular spin frustration in the [Fe4O2]8+ core: synthesis, structure, and magnetochemistry of tetranuclear iron-oxo complex [Fe4O2(O2CR)7(bpy)2](C1O4) (R = Me, Ph) (1991) (151)
Potential building blocks for molecular ferromagnets: [Mn12O12(O2CPh)16(H2O)4] with a S = 14 ground state (1988) (151)
Alcohol adducts of alkoxides: intramolecular hydrogen bonding as a general structural feature (1990) (150)
An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3 (1990) (145)
The synthesis, reactions and molecular structure of zirconocene-alkyne complexes (1987) (145)
Manganese carboxylate clusters: from structuralaesthetics to single-molecule magnets fn1 fn1 Dedicated to Professor Jack Lewis on the occasion ofhis 70 th birthday. (1998) (128)
Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II). Structural and spectroscopic evidence for molybdenum-to-bipyridyl .pi.* bonding (1981) (127)
Metal-metal multiple bonds in ordered assemblies. 1. Tetranuclear molybdenum and tungsten carboxylates involving covalently linked metal-metal quadruple bonds. Molecular models for subunits of one-dimensional stiff-chain polymers (1991) (119)
Modeling the dinuclear sites of iron biomolecules: synthesis and properties of Fe2O(OAc)2Cl2(bipy)2 and its use as an alkane activation catalyst (1988) (118)
Structural, spectroscopic, and theoretical elucidation of a redox-active pincer-type ancillary applied in catalysis. (2008) (118)
Trimethylphosphine adduct of the zirconocene-benzyne complex: synthesis, reactions, and x-ray crystal structure (1986) (118)
Novel, Efficient, Palladium-Based System for the Polymerization of Norbornene Derivatives: Scope and Mechanism (2001) (112)
Neutral and zwitterionic low-coordinate titanium complexes bearing the terminal phosphinidene functionality. Structural, spectroscopic, theoretical, and catalytic studies addressing the Ti-P multiple bond. (2006) (106)
Evidence for the existence of a terminal imidoscandium compound: intermolecular C-H activation and complexation reactions with the transient Sc=NAr species. (2008) (105)
Single-molecule magnets: two-electron reduced version of a Mn12 complex and environmental influences on the magnetization relaxation of (PPh4)(2)[Mn(12)O(12)(O(2)CCHCl2)(16)(H2O)4]. (2003) (101)
Assessment and understanding of pain in patients with dementia. (2000) (99)
Syntheses and structures of a series of very low coordinate barium compounds: Ba[N(SiMe3)2]2(THF)2, {Ba[N(SiMe3)2)]2(THF)}2, and {Ba[N(SiMe3)2]2}2 (1991) (98)
Tetranuclear and Octanuclear Manganese Carboxylate Clusters: Preparation and Reactivity of (NBu(n)(4))[Mn(4)O(2)(O(2)CPh)(9)(H(2)O)] and Synthesis of (NBu(n)(4))(2)[Mn(8)O(4)(O(2)CPh)(12)(Et(2)mal)(2)(H(2)O)(2)] with a "Linked-Butterfly" Structure. (1996) (95)
Molecular structure of (.eta.5-C5H5)2Ti(OC2H5)Cl and [(.eta.5-C5H5)Cl2Ti]2O2C2(CH3)4. A structural basis for deoxygenation using titanium (1980) (94)
Single-Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn−Teller Isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4] (2001) (94)
A new class of single-molecule magnets: mixed-valent [Mn4(O2CMe)2(Hpdm)6][ClO4]2 with an S = 8 ground state (1999) (90)
Synthesis of (.+-.)-10,22-dioxokopsane and (.+-.)-kopsanone, heptacyclic indole alkaloids. Synthetic and mechanistic studies (1984) (90)
A fluorobenzene adduct of Ti(IV), and catalytic carboamination to prepare α,β-unsaturated imines and triaryl-substituted quinolines (2005) (90)
Intermolecular C−H Bond Activation Reactions Promoted by Transient Titanium Alkylidynes. Synthesis, Reactivity, Kinetic, and Theoretical Studies of the Ti⋮C Linkage (2007) (86)
Addition Polymerization of Norbornene-Type Monomers. High Activity Cationic Allyl Palladium Catalysts (2002) (86)
Intermolecular C-H bond activation promoted by a titanium alkylidyne. (2005) (84)
Single-molecule magnets: novel Mn(8) and Mn(9) carboxylate clusters containing an unusual pentadentate ligand derived from pyridine-2,6-dimethanol. (2002) (84)
Structures of ionic decamethylmetallocenes: crystallographic characterization of bis(pentamethylcyclopentadienyl)calcium and -barium and a comparison with related organolanthanide species (1990) (83)
Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene, and Imide Functionalities (2005) (83)
Single-molecule magnets: preparation and properties of mixed-carboxylate complexes. (2001) (83)
PI -STABILIZED, YET REACTIVE, HALF-SANDWICH CP*RU(PR3)X COMPOUNDS : SYNTHESIS, STRUCTURE, AND BONDING (1995) (82)
Homogeneous hydrogenation of carbon monoxide. [Using the cyclopentadienyl compound Cp/sub 2/Ti(CO)/sub 2/] (1977) (81)
Use of tetra-n-butylammonium permanganate for inorganic syntheses in nonaqueous solvents. Preparation and structure of a manganese(III) dimer containing bridging phenoxo oxygen atoms (1986) (81)
Electrochemical oxidation-reduction of organometallic complexes. Effect of the oxidation state on the pathways for reductive elimination of dialkyliron complexes (1982) (80)
Synthesis of a remarkably stable bicyclo[7.3.1]diynene esperamicin A1/calicheamicin .gamma. system. Structural requirements for facile formation of a 1,4-diyl (1988) (80)
A Co2N2 diamond-core resting state of cobalt(I): a three-coordinate CoI synthon invoking an unusual pincer-type rearrangement. (2006) (80)
Synthesis, Properties, and X-ray Structures of the Lanthanide .eta.6-Arene-Bridged Aryloxide Dimers Ln2(O-2,6-i-Pr2C6H3)6 and Their Lewis Base Adducts Ln(O-2,6-i-Pr2C6H3)3(THF)2 (Ln = Pr, Nd, Sm, Gd, Er, Yb, Lu) (1994) (77)
Metal alkoxides: models for metal oxides. 4. Alkyne adducts of ditungsten hexaalkoxides and evidence for an equilibrium between dimetallatetrahedrane and methylidynemetal complexes: W2(.mu.-C2H2) .dblharw. 2W.tplbond.CH (1984) (77)
Intramolecular coupling of .eta.2-iminoacyl and .eta.2-acyl functions at Group 4 and Group 5 metal centers: structure and spectroscopic properties of the resulting enamidolate and enediamide complexes (1987) (75)
A Nickel(II) Azide Cubane: Characterization of the Magnetic Exchange Interactions Mediated by a Triply Bridging Azide Group Bound End‐On (1995) (74)
The chemistry of sterically crowded aryl oxide ligands. III: Crystal and molecular structure and spectroscopic properties of mixed benzyl-aryl oxide compounds of zirconium (1985) (73)
Computational and Experimental Test of Steric Influence on Agostic Interactions: A Homologous Series for Ir(III) (1999) (73)
Organofluorine binding to sodium and thallium(I) in molecular fluoroalkoxide compounds (1993) (73)
High-Spin Molecules: Hexanuclear MnIII Clusters with [Mn6O4X4]6+ (X = Cl-, Br-) Face-Capped Octahedral Cores and S = 12 Ground States (1999) (72)
A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper (1986) (72)
Uranium(VI) organoimido complexes (1990) (72)
ISOELECTRONIC MOLECULES WITH TRIPLE BONDS TO METAL ATOMS (M = MO, W): CRYSTAL AND MOLECULAR STRUCTURES OF TRI-TERT-BUTOXYTUNGSTEN ETHYLIDYNE AND NITRIDE (1983) (71)
Synthesis, structure and spectroscopic properties of early transition metal .eta.2-iminoacyl complexes containing aryl oxide ligation. (1987) (71)
Ion pairing in [bis(trimethylsilyl)amido]potassium: The x-ray crystal structure of unsolvated [KN(SiMe3)2]2 (1990) (71)
Four-coordinate phosphinidene complexes of titanium prepared by alpha-H-migration: phospha-Staudinger and phosphaalkene-insertion reactions. (2003) (71)
Preparation, structure, and magnetochemistry of hexanuclear manganese oxide complexes: chemically and thermally induced aggregation of aquahexakis(benzoato)oxobis(pyridine)trimanganese forming products containing the [Mn6O2]10+ core (1989) (69)
A dinuclear Ni(I) system having a diradical Ni2N2 diamond core resting state: synthetic, structural, spectroscopic elucidation, and reductive bond splitting reactions. (2008) (68)
Structure of a zirconoxyborane having a zirconium-fluorine-carbon bridge (1993) (67)
Preparation and X-ray Structures of K[Ln(O-2,6-i-Pr2C6H3)4] (Ln = La, Nd, Er). Extended Chain Structures of Lanthanide Tetrakis(Aryloxide) Anions Bridged by Potassium-.eta.-Arene Interactions (1994) (67)
Uranium alkoxide chemistry. 1. Synthesis and the novel dimeric structure of the first homoleptic uranium(III) aryloxide complex (1988) (67)
Indole-2,3-quinodimethan route to Aspidosperma alkaloids: synthesis of dl-aspidospermidine (1982) (66)
Metal-metal multiple bonds. Part 17. Syntheses, structures, and molecular orbital analysis of hydridotris(pyrazolyl)borate (Tp) molybdenum carbonyls: paramagnetic TpMo(CO)3 and triply bonded Tp2Mo2(CO)4 (Mo.tplbond.Mo) (1986) (66)
Modelling the photosynthetic water oxidation center: preparation and physical properties of a tetranuclear oxide bridged manganese complex corresponding to the native S2 state (1987) (66)
Solid state and solution structural investigation of homoleptic tin(IV) alkoxide compounds. Part I. Sn(O—t-Bu)4 and [Sn(O—i-Pr)4•HO—i-Pr]2 (1991) (66)
Intramolecular activation of aliphatic carbon-hydrogen bonds at tantalum(V) metal centers: a comparison of activation by methyl and methylidene functional groups (1986) (65)
Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality (2005) (65)
Influence of the d-Electron Count on CO binding by three-coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni. (2008) (64)
Synthesis and structural characterization of porphyrinic enediynes: geometric and electronic effects on thermal and photochemical reactivity. (2003) (64)
A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced alpha-hydrogen abstraction. (2003) (64)
A donor semibridge? Molecular structures of dicyclopentadienyldivanadiumtetracarbonyltriphenylphosphine and dicyclopentadienyldivanadiumpentacarbonyl (1980) (63)
Isolation and molecular structure of unusual oxochromium(V) cations for the catalytic epoxidation of alkenes (1983) (63)
Nonanuclear oxide-bridged manganese complex. Preparation, structure, and magnetic properties of [Mn9O4(O2CPh)8(sal)4(salH)2(pyr)4] (salH2 = salicylic acid; pyr = pyridine) (1988) (61)
Synthetic and structural studies of pentamethylcyclopentadienyl complexes of lanthanum and cerium (1987) (61)
Models of the manganese catalase enzymes. Dinuclear manganese(III) complexes with the [Mn2(.mu.-O)(.mu.-O2CR)2]2+ core and terminal monodentate ligands: preparation and properties of [Mn2O(O2CR)2X2(bpy)2] (X = chloride, azide, water) (1993) (60)
Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) (1995) (60)
Carbon−Oxygen Bond Cleavage Promoted by a Scandium Borohydride Complex (2003) (60)
Pentacyclic systems of indole alkaloids. Formation of the C11-C12 bond. Two syntheses of (.+-.)-aspidospermidine (1983) (59)
Ambient temperature activation of haloporphyrinic-enediynes: electronic contributions to bergman cycloaromatization. (2003) (59)
Alcohol elimination chemistry of tetrakis(tert-butoxocopper) (1990) (59)
Terminal and four-coordinate vanadium(IV) phosphinidene complexes. A pseudo Jahn-Teller effect of second order stabilizing the V-P multiple bond. (2004) (59)
Early actinide alkoxide chemistry. Synthesis, characterization, and molecular structures of Th(IV) and U(IV) aryloxide complexes (1992) (59)
Highly Enantioselective 1,2-Addition of Lithium Acetylide-Ephedrate Complexes: Spectroscopic Evidence for Reaction Proceeding via a 2:2 Tetramer, and X-ray Characterization of Related Complexes (2000) (58)
Reactivity at the beta-diketiminate ligand Nacnac- on titanium(IV) (Nacnac- = [Ar]NC(CH3)CHC(CH3)N[Ar], Ar = 2,6-[CH(CH3)2]2C6H3). Diimine-alkoxo and bis-anilido ligands stemming from the Nacnac- skeleton. (2003) (56)
Gallium-68 1,1,1-tris (5-methoxysalicylaldiminomethyl) ethane: a potential tracer for evaluation of regional myocardial blood flow. (1985) (55)
Reductive elimination pathways to low valent titanium aryl oxide complexes (1987) (55)
IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS [V2CL3(THF)6]2[ZN2CL6] (1984) (54)
Trialkoxynitridomolybdenum compounds: (RO)3Mo.ident.N. Preparation, structures (R = tert-Bu and iso-Pr), and comparisons with a tungsten analog (R = tert-Bu) (1986) (54)
Crystal and molecular structure of hexakis(tert-butoxo)dialuminum. Comments on the extent of M-O .pi. bonding in Group 6 and Group 13 alkoxides (1991) (54)
Structural relationships between mono- and dimeric bis(alkoxides) and bis(aryloxides) of calcium and barium. X-ray crystal structures of M(OC6H2-tert-Bu2-2,6-Me-4)2(THF)3.(THF) (M = calcium, barium) and [Ca(.mu.-OR)(OR)(THF)]2.2(toluene) [R = C(C6H5)2CH2C6H4Cl-4] (1992) (54)
Terminal Zirconium Imides Prepared by Reductive C−N Bond Cleavage (2004) (53)
Mononuclear, three-coordinate metal thiolates: Preparation and crystal structures of [NBun4][Hg(SPh)3] and [NPrn4] [Pb(SPh)3] (1984) (53)
Room Temperature Ring-Opening Metathesis of Pyridines by a Transient Ti⋮C Linkage (2006) (53)
Single-molecule magnets: control by a single solvent molecule of Jahn-Teller isomerism in [Mn12O12(O2CCH2Bu(t))16(H2O)4]. (2003) (51)
Incorporation of barium for the synthesis of heterometallic alkoxides: synthesis and structures of [BaZr2(O-iso-Pr)10]2 and Ba{Zr2(O-iso-Pr)9}2 (1991) (51)
Intermolecular activation of C-X (X = H, O, F) bonds by a TiCt\Bu linkage. (2007) (50)
Metal alkoxides: models for metal oxides. 17. Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-tert-Bu)12 and W4(.mu.4-C)(O)(O-i-Pr)12 (1992) (50)
Synthesis, structure, spectroscopic properties, and electrochemical behavior of group 4 metal derivatives containing bulky aryloxide ligands (1985) (49)
METAL ALKOXIDES - MODELS FOR METAL OXIDES. 1. PREPARATIONS AND STRUCTURES OF HEXADECAALKOXYTETRATUNGSTEN COMPOUNDS, W4(OR)16, WHERE R = ME AND ET, AND OCTAOXOTETRAISOPROPOXYTETRAPYRIDINOTETRAMOLYBDENUM, MO4(O)4(μ-O)2(μ3-O)2(O-I-PR)2(μ (1982) (49)
Solution Studies of Ru2(O2CR)4n+ Complexes (n = 0, 1; O2CR = Octanoate, Crotonate, Dimethylacrylate, Benzoate, p-Toluate) and Solid-State Structures of Ru2(O2C-p-tolyl)4(THF)2, [Ru2(O2C-p-tolyl)4(THF)2]+[BF4]-, and Ru2(O2C-p-tolyl)4(CH3CN)2: Investigations of the Axial Ligation of the Ru2 Core (1996) (49)
Soluble zinc bis(aryloxides) (1986) (49)
Dinuclear elimination as a route to unusual bridging carbonyls and acetyls in heterobimetallic complexes (1982) (48)
Conformational effects on retinoid receptor selectivity. 1. Effect of 9-double bond geometry on retinoid X receptor activity. (1993) (48)
Molecular design of single site catalyst precursors for the ring-opening polymerization of cyclic ethers and esters. 2.1 Can ring-opening polymerization of propylene oxide occur by a cis-migratory mechanism? (2001) (48)
The structure of tetramethyldistibine (1984) (48)
Crystallographic evidence of the three-centre bond in hexamethyldialuminium (1971) (47)
A bridging acetyl group from the reaction of a dinuclear methyl complex with carbon monoxide (1981) (47)
Formation and reactions of mono- and bis(peralkylcyclopentadienyl) complexes of calcium and barium. The x-ray crystal structure of [cyclic][(Me4EtC5)Ca(.mu.-NSiMe2CH2CH2SiMe2)]2 (1992) (47)
Tetrameric lanthanide neopentoxide complexes with agostic Ln-H-C interactions. X-ray crystal structures of Ln[sub 4](OCH[sub 2]-t-Bu)[sub 12] (Ln = La, Nd) (1993) (46)
Reactivity of the molecular hydrogen complex [IrH4(PMe2Ph)3]BF4 towards olefins. The origin of stereochemical rigidity of M(PR3)3(olefin)2 species (1990) (46)
Insertion of Cr(CO)3 into As 73⊖ to Form [As7Cr(CO)3]3⊖: An Inorganic Nortricyclane‐to‐Norbornadiene Conversion (1989) (46)
Tetranuclear manganese carboxylate complexes with a trigonal pyramidal metal topology via controlled potential electrolysis. (2000) (46)
RuX(CO)(NO)L2 and Ru(CO)(NO)L2+: Ru(0) or Ru(II) or In Between? (1997) (46)
CHEMISTRY OF DITHIA-, SELENATHIA-, AND DISELENABORANES (1980) (45)
MOLECULAR STRUCTURE AND CHARGE TRANSFER EXCITATION OF ELECTRON DONOR-ACCEPTOR COMPLEXES. ION PAIRS FROM ARENES AND MERCURY(II) (1982) (45)
Photodimerization of Lewis acid complexes of cinnamate esters in solution and the solid state (1984) (45)
Tetranuclear manganese(III)-oxo-carboxylate complexes possessing terminal phenoxide or alkoxide ligands (1992) (45)
Coordinated carbenes from electron-rich olefins on RuHCl(PPr3i)2 (2000) (45)
Controlled aggregation and deaggregation of a polynuclear oxido-bridged manganese complex: utility to synthesis of the Jahn-Teller effect in high-spin manganese(III) (1993) (44)
Metal alkoxides models for metal oxides. 5. Coupling of alkyne ligands in reactions involving ditungsten hexaalkoxides: an alternative to the metathesis reaction M.tplbond.M + C.tplbond.C- .fwdarw. 2M.tplbond.C (1984) (44)
Synthesis of ternary metal sulfide arrays (1976) (44)
Reactions of M-M triple bonds with carbon-nitrogen triple bonds: adduct formation (M = molybdenum) and metathesis (M = tungsten) as seen in the reactions between dimethylcyanamide and hexaalkoxides of dimolybdenum and ditungsten (1983) (43)
Vanadium(IV) thiolate chemistry: preparation, structure, and properties of [VE(SCH2CH2S)2]2- (E = O,S) (1985) (43)
Multiple Bonds between Metal Atoms in Ordered Assemblies. 2. Quadrupole Bonds in the Mesomorphic State (1994) (43)
Aryl isocyanate, carbodiimide, and isocyanide prepared from carbon dioxide. A metathetical group-transfer tale involving a titanium-imide zwitterion. (2006) (43)
Tetranuclear manganese complexes with dimer-of-dimer and ladder structures from the use of a bis-bipyridyl ligand. (2002) (43)
Crystal structure and magnetic susceptibility of the dinuclear manganese(IV) complex Mn2O2(pic)4.cntdot.MeCN (picH = picolinic acid) (1989) (43)
Chloro(dimethylamido) compounds of tantalum(V): Preparations, properties, and structures of [Ta(NMe2)3Cl2]2, TaCl3(NMe2)2(HNMe2), Ta(NMe2)3Cl2(HNMe2), and [TaCl2(NMe2)2(HNMe2)]2O (1981) (42)
Terminal vanadium-neopentylidyne complexes and intramolecular cross-metathesis reactions to generate azametalacyclohexatrienes. (2004) (42)
Accelerated Bergman cyclization of porphyrinic-enediynes. (2003) (42)
Tetranuclear and Pentanuclear Vanadium(IV/V) Carboxylate Complexes: [V4O8(NO3)(O2CR)4]2- and [V5O9X(O2CR)4]2- (X = Cl-, Br-) Salts (1996) (42)
The First η2-CH2Cl2 Adduct of Ru(II):[RuH(η2-CH2Cl2)(CO)(PtBu2Me)2][BAr‘4] (Ar‘ = 3,5-C6H3(CF3)2) and Its RuH(CO)(PtBu2Me)2+ Precursor (1997) (42)
Preparation and x-ray crystal structure of potassium tetrakis(2,6-diisopropoxyphenolato)neodymate(1-): a one-dimensional chain of lanthanide aryloxide anions joined by bis(.eta.6-arene)-potassium interactions (1992) (42)
Metal alkoxides: models for metal oxides. 2. Addition of ethyne, propyne, and 2-butyne to Mo2(OR)6 (M.tplbond.M) compounds (R = tert-Bu, iso-Pr, and neopentyl). Characterization of .mu.-alkyne and .mu.-C4H4 adducts and an evaluation of their role in alkyne oligomerization reactions (1982) (42)
(NBu4)[Mn4O2(H2O)(O2CPh)9], a Butterfly Complex with Bound H2O, and Its Use to Prepare Octanuclear and Undecanuclear Metal Complexes† (1991) (41)
Synthesis, structure, and bonding of mononuclear aryloxide derivatives of niobium in oxidation states +5, +3, +2, and +1 (1989) (41)
Activation of atmospheric nitrogen and azobenzene N=N bond cleavage by a transient Nb(III) complex. (2006) (41)
Crystal and molecular structures of tert-butyltetrakis(dimethylamido)tantalum(V), bromo(p-tolyl)tris(dimethylamido)tantalum(V), and [(trimethylsilyl)methyl]tetrakis(N,N-dimethylcarbamato)tantalum(V). Evidence for stabilization of .sigma.-alkyl ligands by strongly .pi.-donating ligands in early trans (1982) (40)
Two classes of alongside charge-transfer interactions defined in one [2]catenane. (2007) (40)
Metalladiboranes of the iron subgroup: K[M(CO)4(.eta.2-B2H5)] (m- iron, ruthenium, osmium) and M'(.eta.5-C5H5) (CO)2(.eta.2-B2H5) (M' = iron, ruthenium). Analogs of metal-olefin complexes (1989) (40)
Structure, Magnetochemistry and Biological Relevance of [Mn4O3Cl4(OAc)3(py)3], a Complex with S = 9/2 Ground State (1988) (40)
Polynuclear manganese complexes with the dicarboxylate ligand m-phenylenedipropionate: a hexanuclear mixed-valence (3Mn(III), 3Mn(IV)) complex. (2004) (40)
Synthetic Models for Low-Molecular-Weight Chromium-Binding Substance: Synthesis and Characterization of Oxo-Bridged Tetranuclear Chromium(III) Assemblies (1994) (39)
Reaction of Nitrogen Chelates with the [Rh(2)](4+) Core: Bis-Chelate Products and Demonstration of Reversible, Chelate-Based Reduction Processes. (1997) (39)
Photothermally induced Bergman cyclization of metalloenediynes via near-infrared ligand-to-metal charge-transfer excitation. (2003) (39)
Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu (1987) (39)
Synthesis and crystallographic characterization of (Me5C5)2Ca(Me3SiC.tplbond.C-C.tplbond.CSiMe3): the first monomeric diyne complex of a main-group element (1990) (39)
Synthetic and mechanistic aspects of intramolecular aliphatic carbon-hydrogen bond activation by titanium(IV) and zirconium(IV) metal centers (1985) (39)
Snapshots of an alkylidyne for nitride triple-bond metathesis. (2007) (39)
SYNTHESIS AND CHARACTERIZATION OF VANADIUM(II,III,IV) COMPLEXES OF PYRIDINE-2-THIOLATE (1995) (38)
Metal/sulfide/thiolate chemistry for an early 3d transition metal: variation of product identity as a function of vanadium:sulfur reaction ratio and structure and redox properties of discrete vanadium sulfido ethanedithiolato complexes (1988) (38)
Instrument Monitoring, Data Sharing, and Archiving Using Common Instrument Middleware Architecture (CIMA) (2006) (38)
Primary steps in the hydrolyses of two heterometallic alkoxides. Characterization of lithium-titanium and barium-zirconium isopropoxides [LiTiO(O-iso-Pr)3]4 and BaZr4(OH)(O-iso-Pr)17 (1993) (38)
Chemical and electrochemical reduction of titanium(IV) aryloxides (1985) (37)
A high nuclearity, mixed-valence manganese(III,IV) complex: [Mn21O24(OMe)8(O2CCH2tBu)16(H2O)10]. (2002) (37)
Transition-metal-mediated hydrogenation of carbon monoxide to olefins: intermediacy of coordinated carbenes (1981) (37)
Pyridine-2-thiolato Complexes of VII, VIII, and VIV with Unusual Structural Features† (1992) (37)
Modelling the photosynthetic water oxidation centre: synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(biphy)2ClO4]·3H2O (bipy = 2,2′-bipyridine) (1987) (37)
Synthesis of a monopentamethylcyclopentadienyl halide complex of calcium. The x-ray crystal structure of [(Me5C5)Ca(.mu.-I)(THF)2]2 (1989) (37)
Chemistry of sterically crowded aryloxide ligands. 4. Synthesis and structure of mixed chloro aryloxides of tantalum (1984) (37)
An unprecedented ligand set and coordination geometry for copper(I) (1983) (37)
Preparation and characterization of dinuclear copper(II) complexes containing the [Cu2(μ-OAc)2]2+ core (1992) (37)
Multiple structural variants of LnCuI(.mu.-X)2CuILn (n = 1, 2). Influence of halide on a "soft" potential energy surface (1992) (37)
New hexanuclear and octanuclear iron(III) oxide clusters: octahedral [Fe6O2](14+) species and core isomerism in [Fe8O4](16+) complexes (2000) (37)
OSH5(PME2PH)3+ : STRUCTURE, REACTIVITY, AND ITS USE AS A CATALYST PRECURSOR FOR OLEFIN HYDROGENATION AND HYDROFORMYLATION (1994) (36)
Preparation and Characterization of Mono-cyclopentadienylvanadium Dihalide Bis-phosphine Complexes; Crystal Structure of (η5-C5H5)VCl2(PMe3)2 (1983) (36)
Acetylene isomerization by manganese(I): preparation and structure of (C5H5)2Mn2(CO)4CCH2 (1979) (36)
New tetranuclear metal carboxylate clusters with the [M4(µ3-O)2]8+ (M = MnIII or FeIII) cores: crystal structures and properties of [Mn4O2Cl2(O2CC6H3F2-3,5)6(py)4], [Fe4O2Cl2(O2CMe)6(bpy)2] and [NBun4][Fe4O2(O2CMe)7(pic)2]† (1998) (36)
Intramolecular C−H Activation Reactions Derived from a Terminal Titanium Neopentylidene Functionality. Redox-Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions (2005) (36)
Remarkable influence of terminal alkoxy groups on carbonyl ligands as seen in the new compounds Mo(OBut)2(CO)2(py)2 and Mo2(OPri)8(CO)2 (1979) (35)
Preparation, crystal and molecular structure of a hydrocarbon soluble, volatile oxo-alkoxide of barium: H4Ba6(µ6-O)(OCH2CH2OCH3)14 (1990) (35)
Preparation and properties of mononuclear and ferromagnetically coupled dinuclear manganese complexes with 2,2'-biphenoxide (1991) (35)
Template-directed synthesis of 1: 1 layered complexes of α,ω-dinitriles and urea: Packing efficiency versus specific functional group interactions (1994) (35)
Reactions of metal-metal multiple bonds. 7. Addition of the halogens chlorine, bromine and iodine and diisopropyl peroxide to hexaisopropoxydimolybdenum (M.tplbond.M). Dinuclear oxidative-addition reactions accompanied by metal-metal bond-order changes from 3 to 2 to 1 (1981) (34)
Chemical and structural studies of azaboranes (1986) (34)
Synthesis, structure, and electrochemistry of platinum(II) metallacyclobutanes (1982) (34)
Transition metal hydrides as electron donors. Formation, detection, and dimerization of transient, paramagnetic radical cations from the electrochemical oxidation of tungstenocene hydrides and the crystal structure of the binuclear (Cp2W)2H3+ product (1980) (34)
SYNTHESIS, STRUCTURE, AND SYNTHETIC UTILITY OF THALLIUM(I) TRICYANOVINYLCYCLOPENTADIENIDE (1977) (34)
Synthesis and structural characterization of the alkaline earth aryloxide aggregates H[sub 2]Ba[sub 8]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6] and H[sub 2]Sr[sub 6]Ba[sub 2]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6]. A new structural type displaying metal ion site selectivity (1993) (34)
Reactions involving the triple bond in dimolybdenum and ditungsten hexa-alkoxides and C–C, C–N, and C–O triple bonds (1985) (34)
One-dimensional polymerization of M2(OAc)4 (M = Cu, Rh) units using 2-(aminomethyl)pyridine: preparation and characterization of [Rh2(OAc)4(amp)]n and [Cu4(OAc)8(amp)2]n (1994) (34)
Quadruple bonds between molybdenum atoms supported by alkoxide ligands (1984) (34)
Cationic and neutral four-coordinate alkylidene complexes of vanadium(IV) containing short V=C bonds. (2004) (34)
Tetrakisdimethylamidozirconium and its dimethylamido lithium adduct: Structures of [zr(nme2)4]2 and zr(nme2)6li2(thf)2 (1988) (33)
Crystal Structures of Potassium Tetratellurite, K2Te4O9, and Potassium Ditellurite, K2Te2O5, and Structural Trends in Solid Alkali Tellurites (1997) (33)
Triangular phenoxide aggregates of calcium, strontium, and barium : a comparison (1993) (33)
Metal-metal bonded complexes of the early transition metals. 9. Synthesis and properties of ditungsten(II) tetracarboxylates (1985) (33)
Isolation and structure of bis(ethane-1,2-dithiolato)(trimethylsilyloxy)vanadate(1-), an intermediate in the conversion of [VO(edt)2]2- to [VS(edt)2]2- (edt2 = ethane-1,2-dithiolate) with (Me3Si)2S. EPR characterization of the series [VE(LL)2]z- (E = O, S, OSiMe3, LL = edt; E = O, LL = propane-1,3-d (1986) (33)
Reactions of metal-metal multiple bonds. 14. Synthesis and characterization of triangulo-W3 and -Mo2W oxo-capped alkoxide clusters. Conproportionation of M-M triple bonds and .sigma.2.pi.4 and d0 metal-oxo groups: M.tplbond.M + M.tplbond.O .fwdarw. M3(.mu.3-O) (1985) (33)
Crystal structure and sodium environments in sodium tetratellurite, Na2Te4O9, and sodium tellurite, Na2TeO3, by X-ray crystallography and sodium-23 NMR (1994) (32)
Solid-phase synthesis of multiple classes of peptidomimetics from versatile resin-bound aldehyde intermediates. (2007) (32)
Synthesis and Characterization of Novel Oxo-Bridged Dinuclear and Hydroxo-Bridged Trinuclear Chromium(III) Assemblies. (1997) (32)
Structures, semi-empirical calculations and thermolyses of some five- and six-membered chelate organotin mercaptide complexes (2000) (32)
Stability of organogold(III) complexes. Isolation and crystal structure of dimethylgold trifluoromethanesulfonate (1977) (32)
Reaction of 2,2'−bipyridine (bpy) with dirhodium carboxylates : mono-bpy products with variable chelate binding modes and insights into the reaction mechanism (1993) (32)
Allene adducts of ditungsten hexaalkoxides. Three modes of allene coordination to dinuclear centers as seen in the structures of W2(OBu-tert)6(C3H4), W2(OBu-tert)6(C3H4)2, and W2(OBu-tert)6(C3H4)(CO)2 (1991) (32)
Preparation and Crystal Structure of (Ph4P)2Te4 · 2 CH3OH (1984) (32)
Synthetic and mechanistic features of alcohol elimination between gold alkoxides and rhenium polyhydrides. Metal polyhedron reconstruction upon protonation (1987) (32)
Enhanced reactivity from noninnocent behavior by an alkoxide ligand in Cp*RuP(OR): toward the mechanism of alcohol elimination (1992) (32)
Formation of a heterometallic carbon dioxide complex with concurrent reduction of carbon dioxide (1986) (32)
Preparation, crystal structure and chelate substitution reactions of [Mn4O2(O2CPh)6(dpm)2] (dpm=the anion of dipivaloylmethane) (2001) (32)
Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene (2003) (31)
Complete carboxylate removal from [Mn12O12(OAc)16(H2O)4].cntdot.2HOAc.cntdot.4H2O) with chlorotrimethylsilane: synthesis and characterization of polymeric (2,2'-bipyridine)trichloromanganese and an improved synthesis of bis(tetraethylammonium) pentachloromanganate(2-) (1991) (31)
Reactions of metal-metal multiple bonds. 8. Forming molybdenum-molybdenum quadruple bonds by reductive elimination (alkyl group disproportionation) in the reactions of 1,2-Mo2R2(NMe2)4 compounds (M.tplbond.M) with carbon dioxide and 1,3-diaryltriazines (1982) (31)
Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. (2007) (31)
Insertion reactions of chromium-carbene complexes with organic nitriles and a diastereoselective alkylation of a resulting imino-carbene complex (1988) (31)
A bimetallic vanadium (I) polyhydride (1983) (31)
1,2-Dibenzyl- and 1,2-diaryltetrakis(dimethylamido)dimolybdenum and -ditungsten compounds: M2R2(NMe2)4 (M.tplbond.M). Structural effects of Me2N-to-M .pi. bonding (1983) (31)
Hydride-rich zirconium-osmium and zirconium-rhenium dimers (1984) (31)
Synthesis and reactivity of a heterometallic carbon dioxide complex (1990) (31)
HIGH-SPIN MOLECULES : HEXANUCLEAR MN6O4CL4(ME2DBM)6 (ME2DBMH = 4,4'-DIMETHYLDIBENZOYLMETHANE) WITH A NEAR TETRAHEDRAL MN6O4CL46+ CORE AND A S = 12 GRO UND STATE (1998) (31)
Reactivity studies of mononuclear and dinuclear vanadium-sulfide-thiolate compounds (1993) (31)
A novel coordination mode for oxygen: preparation and properties of (NBun4)2[V4O(edt)2Cl8] containing a square-planar oxide bridge (1989) (30)
Ti(NMe2)4 and [HNMe2Ph][B(C6F5)4]: A Convenient Blend for Effective Catalytic Carboamination of Alkynes (2006) (30)
Cyclometalation of 2,6-di-tert-butylphenoxide ligands by tantalum aryl groups: aliphatic carbon-hydrogen bond activation and aryl isomerization via benzyne (o-phenylene) intermediates (1987) (30)
Reactions involving alkynes and tungsten-tungsten triple bonds supported by alkoxide ligands (1987) (30)
Spring-Loading at the Molecular Level: Relaxation of Guest-Induced Strain in Channel Inclusion Compounds (1999) (30)
Mixed valence manganese-(II, III) and -(III, IV) dinuclear complexes: preparation, structure, magnetochemistry, and e.s.r. spectra of Mn2(biphen)2(biphenH)(bpy)2 and Mn2O2Cl2(OAc)(bpy)2(biphenH2= 2,2′-biphenol, bpy = 2,2′-bipyridine) (1988) (30)
Structure and bonding of (.mu.-dicarbido)hexa-tert-butoxyditungsten, (tert-BuO)3W.tplbond.CC.tplbond.W(O-tert-Bu)3 (1992) (30)
CONCERNING THE STRUCTURE AND STABILITY OF A COPPER(I) ALKOXY CARBONYL (1983) (30)
The chemistry of sterically crowded aryloxide ligands—VII. Synthesis, structure and spectroscopic properties of some group 4 and group 5 metal derivatives of 2,6-diphenylphenoxide (1987) (30)
Characterisation of nanoscopic (Mn12O12(O2CR)16(H2O)4) single-molecule magnets: physicochemical properties and LDI- and MALDI-TOF mass spectrometry{ (2002) (30)
Silver(I) and thallium(I) complexes of a PNP ligand and their utility as PNP transfer reagents. (2007) (29)
Synthesis of tin-tellurium polyanions: structure of (Me4N)4Sn2Te6 (1984) (29)
A planar oxocuprate(II) array via heterometallic alkoxide chemistry (1990) (29)
Characterization of bis(2,2'-bipyridine) and bis(1,10-phenanthroline) derivatives of molybdenum and tungsten carbonyls. Crystal and molecular structure of cis-dicarbonylbis(2,2'-bipyridine)molybdenum(0) (1984) (29)
Characterization and structure of some four-coordinate methylcopper(I) compounds (1989) (29)
Dynamics and structure of some tricarbonylferrole-iron tricarbonyl derivatives (1976) (29)
Octahedral Mo6 Clusters Supported by Methoxide Ligands. (1984) (29)
Doubly-hydrated hexafluoroacetylacetone as a tetradentate ligand: Synthesis, magnetochemistry, and thermal transformations of a Mn[sup III][sub 2] complex (1993) (29)
Synthetic and structural studies of the lolium alkaloids (1981) (29)
Synthesis of the heptacyclic indole alkaloid (.+-.)-kopsine and related studies (1989) (29)
Zwitterionic and Cationic Titanium and Vanadium Complexes Having Terminal M−C Multiple Bonds. The Role of the β-Diketiminate Ligand in Formation of Charge-Separated Species (2009) (29)
Aliphatic neodymium alkoxides with sterically demanding ligands. Preparation and x-ray crystal structures of Nd2(OCH-iso-Pr2)6L2 (L = THF, py) and [Nd2(OCH-iso-Pr2)6(.mu.-DME)].infin. (1993) (29)
The synthesis, structure and spectroscopic properties of the di- and tri-nuclear Ni(II) thiolate complexes (1987) (28)
Structure/Volatility Correlation of Sodium and Zirconium Fluoroalkoxides (1995) (28)
Synthesis and crystallographic characterization of a gallium salicylaldimine complex of radiopharmaceutical interest (1984) (28)
Reaction of ninhydrin with β-dicarbonyl compounds (1995) (28)
Isolation of 12-hydroxycaryophyllene-4,5-oxide, a sesquiterpene from Lactarius camphoratus (1981) (28)
Single-Molecule Magnets: Characterization of Complexes Exhibiting Out-of-Phase AC Susceptibility Signals (1997) (28)
pi. Complexes of nickel(0) and ketones. Mechanism of formation and the crystal structure of (benzophenone)bis(triethylphosphine)nickel (1979) (28)
Manganese(III) thiolate chemistry: new structural types, including the first mixed-valence metal thiolate (1985) (28)
Tetranuclear carbidotungsten and nitridomolybdenum clusters supported by alkoxide ligands: W4(C)(OCHMe2)12(NMe) and Mo4(N)2(OCHMe2)12 (1985) (28)
Dinuclear copper(II) complexes with the new [Cu2(μ-OR)(μ-OAc)2]+ (R = alkyl) core: preparation and characterization of [Cu2(OR)(OAC)2(bpy)2]+ (R = Me, Et, Prn) salts (1995) (28)
Terminal Titanium(IV) (Trimethylsilyl)imides Prepared by Oxidatively Induced Trimethylsilyl Abstraction (2006) (27)
Metal alkoxides: models for metal oxides. 7. Trinuclear and tetranuclear alkylidyne clusters of tungsten supported by alkoxide ligands (1985) (27)
Signal-amplifying resonance energy transfer: a dynamic multichromophore array for allosteric switching. (2007) (27)
Paramagnetic monocyclopentadienyl hydrocarbyl and borohydride compounds of vanadium(II) and vanadium(III). Synthesis, structure, and reactivity (1987) (27)
Multiple mixed-metal condensation leading to the trigonal bipyramidal iridium copper hexahydride Ir2Cu3H6(MeCN)3(PMe2Ph)63+ (1985) (27)
Dinuclear manganese-oxide complexes as models for manganese catalase (1988) (27)
A tetranuclear manganese carboxylate cluster with bis(2-pyridyl)amine ligation: [Mn4O2(O2CEt)7(bpya)2](ClO4) (2002) (27)
Px ligands with a maximum of electron-donating ability: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF] (1993) (27)
Metal-metal bonded complexes of the early transition metals. 2. Synthesis of quadruply bonded tungsten(II) trifluoroacetate complexes (1981) (27)
Instruments and Sensors as Network Services : Making Instruments First Class Members of the Grid (2003) (27)
Potassium triphenylsiloxide “-ate” compounds of tin(II): Molecular and separated ion forms and variable potassium coordination numbers (1992) (27)
Syntheses and structural characterization of 2,2′-methylene-bis(6-t-butyl-4-methyl-phenoxide complexes of titanium, zirconium and tantalum (1997) (27)
Cambridge Data File in organic chemistry. Applications to transition-state structure, conformational analysis, and structure/activity studies (1980) (27)
Oligomerization and structural variation of alkali metal silyloxides (1991) (26)
Synthesis and reactivity of silyl vinylketenes: a formal interrupted Dötz benzannulation with unexpected silyl migration. (2001) (26)
MoMo Quadruple Bonds Bridged by 1,8‐Naphthyridinyl‐2,7‐Dioxide: an Insight into the Nature of a Parallel‐Linked Stiff‐Chain Polymer: (1991) (26)
CO-Induced C(sp2)/C(sp) Coupling on Ru and Os: A Comparative Study (1998) (26)
Crystal and molecular structure of chlorotri(3-butenyl)phosphinerhodium(I), RhClP(CH2CH2CH = CH2)3 (1974) (26)
Conversion of Ethylene to Hydride and Ethylidyne by an Amido Rhenium Polyhydride (2003) (26)
Insertion of boron into an osmium-carbonyl bond. Preparation and structure of the carbonyl borylidyne (.mu.-H)3(CO)9Os3BCO (1983) (26)
Reductive C–N bond cleavage of the NCCCN β-diketiminate backbone: A direct approach to azabutadienyl and alkylidene-anilide scaffolds (2007) (26)
Binding of 2,2'-bipyridine to the dirhodium(II) tetraacetate core: unusual structural features and biological relevance of the product Rh2(OAc)4(bpy) (1991) (26)
Synthesis of [Cu3Os3H9(PMe2Ph)9], a Bimetallic Raft, by Reductive Elimination of Alcohol or H2 (1986) (26)
P=N bond formation via incomplete N-atom transfer from a ferrous amide precursor. (2008) (26)
Three-coordinate NiII: tracing the origin of an unusual, facile Si-C(sp3) bond cleavage in [(tBu2PCH2SiMe2)2N]Ni+. (2011) (26)
Intermolecular rhodium-catalyzed [2+2+2] carbocyclization reactions of 1,6-enynes with symmetrical and unsymmetrical alkynes. (2005) (26)
Alkyne reactions with rhenium(V) oxo alkyl phosphine complexes-phosphine displacement versus apparent Re-P insertion (1993) (26)
Nucleo- and electrophilicity of (C5H5)2Mn2(CO)4(.mu.-.eta.1-CCH2). New paths to carbyne and allene ligands (1980) (26)
Synthesis, structure, and spectroscopic properties of octahedral complexes of tungsten(VI), -(V), and -(IV) containing 2,6-diphenylphenoxide ligation (1989) (25)
Preparation and structure of (NEt4)2[V4S2(SCH2CH2S)6] and its structural and electronic relationship to the LixVS2 phases (1987) (25)
Intramolecular coupling of .eta.2-iminoacyl functions at Group 4 metal centers (1985) (25)
CONTROLLED STOICHIOMETRIC INCORPORATION OF TI(IV) INTO A ZR(IV) PINACOLATE (1998) (25)
IAN Amines: Chiral C2-Symmetric Zirconium(IV) Complexes from Readily Modified Axially Chiral C1-Symmetric β-Diketimines (2004) (25)
Metal-metal-bonded complexes of the early transition metals. 7. The ditungsten tetracarboxylate story (1983) (25)
Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(II) and Os (2002) (25)
{H(3-(t)Bupz)B(3-(t)Bupz)(2)-eta(2)}AlEt(2) and {H(3-(t)Bupz)B(3-(t)Bupz)(5-(t)Bupz)-eta(2)}AlEt(2). Structure, Dynamic Solution Behavior, and the 1,2-Borotropic Shift. (1996) (25)
Cyclopentadienylvanadium(III) and -vanadium(II) Methyl, Phenyl, and Borohydride Compounds (1985) (25)
Dinuclear and Hexanuclear Iron(III) Oxide Complexes with a Bis(bipyridine) Ligand: A New [Fe(6)(&mgr;(3)-O)(4)](10+) Core. (1998) (25)
Metal alkoxides. Models for metal oxides. 15. Carbon-carbon and carbon hydrogen bond activation in the reactions between ethylene and ditungsten hexaalkoxides: W2(OCH2-t-Bu)6(.eta.2-C2H4)2, W2(OR)6(CH2)4(.eta.2-C2H4), and W2(OR)6(.mu.-CCH2CH2CH2) (where R = Ch2-t-Bu, i-Pr, c-C5H9, and c-C6H11). Prep (1989) (24)
Tl(I), Fe(II), and Co(II) complexes supported by a monoanionic N,N,N'-heteroscorpionate ligand bis(3,5-di-tertbutylpyrazol-1-yl)-1-CH2NAr (Ar = 2,6-iPr2C6H3). (2006) (24)
Hexaisopropoxyditungsten and dodecaisopropoxytetratungsten: W2(O-i-Pr)6 and W4(O-i-Pr)12. 1. Preparation, structure, and bonding. The first example of a metal-metal triple bond and its 12-electron cluster. Analogies with ethyne and cyclobutadiene (1987) (24)
Metal-to-metal triple bonds-to cluster or not to cluster? Structural characterization of octakis(tert-butoxy)tetrakis(.mu.-fluoro)-tetramolybdenum and octakis(tert-butoxy)tris(.mu.-fluoro)-(.mu.-dimethylamido)-tetramolybdenum (1979) (24)
Dimetal Hepta- and Octaalkoxide Anions of Molybdenum and Tungsten, M2(OR)7- and M2(OR)82- (M.tplbond.M). Preparation, Structures, Oxidation, and a Study of the Thermal Decomposition of W2(OR)7- to Give W2(H)(O)(OR)6- Where R = tBu and iPr (1995) (24)
Synthesis of (.pi.-arene)metallacarbaboranes containing ruthenium or osmium and a (.pi.-cyclohexadienyl)cobaltacarbaborane. Crystal structure of 2,5,6-(.eta.-C6H6)RuC2B7H11 (1985) (24)
Understanding and predicting distorted T- versus Y-geometries for neutral chromous complexes supported by a sterically encumbering beta-diketiminate ligand. (2008) (24)
CP CO(P4)CP CO)2(MU -CO) (CP =ETA 5-C5H3TBU2) : A COMPLEX WITH A P4 UNIT ON THE WAY TO A P1 AND A P3 LIGAND (1995) (24)
Preparation and characterization of triply-bridged dinuclear copper(II) complexes containing the [Cu2(μ-OH)(μ-X)(μ-OAc)]+ core (X = Cl, Br), and the crystal structure of [Cu2(OH)Cl(OAc)(bpy)2](ClO4) · H2O (1991) (24)
Double C(sp3) dehydrogenation as a route to coordinated Arduengo carbenes: experiment and computation on comparative ?-acidityElectronic supplementary information (ESI) available: crystallographic data. See http://www.rsc.org/suppdata/nj/b3/b305249d/ (2003) (24)
&mgr;-Benzene in a Heterobimetallic Fluoroalkoxide: CH.FC Hydrogen Bonding? (1997) (24)
An alkylidyne analogue of Tebbe's reagent: trapping reactions of a titanium neopentylidyne by incomplete and complete 1,2-additions. (2007) (24)
Oxidatively Induced α-Hydrogen Abstraction. A Mild Protocol to Generate Terminal Titanium Alkylidenes Containing a β-Hydrogen (2006) (24)
Square and butterfly, 12-electron molybdenum (Mo4) clusters formed by coupling molybdenum-molybdenum triple bonds (1982) (24)
Metal alkoxides-models for metal oxides. 9. Hydridoditungsten alkoxides: W2(H)(O-iso-Pr)8Na.cntdot.diglyme and W2(H)(I)(OCH2-tert-Bu)6(H2NMe). Further investigations of the reaction between W2(NMe2)6(M.tplbond.M) and iso-PrOH leading to W4(H)2(O-iso-Pr)14 (1986) (24)
A manganese(IV) complex with phenoxide- and carboxylate-like ligation: preparation and structure of [Mn(sal)2(bipyl)](H2sal = salicylic acid; bipy = 2,2′-bipyridine) (1986) (24)
Syntheses of nido-9,11-X2-7,8-C2B9H10 − anions (X=Cl, Br or I) and the synthesis and structural characterization of N(C2H5)4[commo-3,3′-Co(4,7-Br2-3,1,2-CoC2B9H9)2] (2000) (24)
Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines. (1997) (23)
The synthesis and characterization of radical cation salts of bis(ethylenedithio)tetraselenafulvalene (1993) (23)
Reactivity of tantalum η2-iminoacyl groups: intramolecular coupling, reduction, and dealkylation (1986) (23)
Aluminium alkyls and transition-metal hydrides: Nonclassicaladduct structure and catalysis of hydrogen migration (1984) (23)
Oxotrimolybdenum(IV) alkoxides: Mo3(.mu.3-O)(.mu.3-OR)(.mu.2-OR)3(OR)6, where R = isopropyl and neopentyl. Synthetic considerations (1981) (23)
Synthesis of helical poly-.beta.-pyrroles. Multiple atropisomerism resulting in helical enantiomorphic conformations (1990) (23)
Dinuclear elimination from rhenium hydrides and trimethylaluminum: rhenium/aluminum polyhydrides (1984) (23)
Bimetallic halides. Crystal structure of and ethylene polymerization by vanadium(II) chloride-zinc chloride-tetrahydrofuran (VCl2.ZnCl2.4THF) (1985) (23)
Intramolecular addition of an aliphatic C-H bond to a tantalum-carbon double bond (1982) (23)
The molybdenum-molybdenum triple bond. 11. 1,1- and 1,2-Disubstituted dimolybdenum compounds of formula Mo2X2(CH2SiMe3)4. Observation of rotation about the triple bond Mo.tplbond.Mo (1982) (23)
Compounds in which the Mo24+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands (1999) (23)
Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 2.(1) Derivatives of 2,2'-Methylenebis(6-tert-butyl-4-methylphenoxide). Direct Observation of the Conversion of Bridged to Chelate Isomers (M = Mo) and Reversible Carbon-Hydrogen Bond Oxidative Addition (M = W). (1997) (23)
The tungsten-tungsten triple bond. 13. Bisalkyl tetracarboxylates of dimolybdenum and ditungsten. Triple bonds between metal atoms with the valence molecular orbital description .pi.4.delta.2 (1987) (23)
A general synthesis for ditungsten tetracarboxylates. Preparation of WW quadruple bonds by reductive-elimination (alkyl group disproportionation) from 1,2-diethyl compounds with WW triple bonds (1984) (23)
PHOTOCHEMISTRY OF TRANSITION-METAL POLYHYDRIDES: DIMERIZATION OF TRIS(DIMETHYLPHENYLPHOSPHINE)PENTAHYDRORHENIUM FOLLOWING PHOTODISSOCIATION OF PHOSPHINE (1981) (23)
Preparation and Characterization of 1,2-Dialkyl Compounds of Dimolybdenum an Ditungsten of Formula M2R2(NMe2)4 M-Triple bond-M. (1981) (23)
Solid state structure of bis(pentamethylcyclopentadienyl)barium, (Me5C5)2Ba; the first X-ray crystal structure of an organobarium complex (1988) (22)
The first homoleptic alkoxide dimers of rhenium(V) and tungsten(V). Stereochemical consequences of metal-metal bonding in edge-shared bioctahedra (1991) (22)
Ligand Scavenging and Catalytic Utilization of the Phototransient ReH5(PMe2Ph)2 (1981) (22)
An unbridged triple bond uniting d6 Mo(0) and d2 Mo(IV) atoms: bis[bis(dimethylphosphino)ethane]tetraisopropoxodimolybdenum (1987) (22)
Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand (2002) (22)
Halide abstraction from TiCl3 by ZnCl2 (1984) (22)
Coupling of acyl and iminoacyl groups on zirconium and .sigma.2,.pi.-coordination of the resulting enamidolate ligand (1985) (22)
The chemistry of the Euphorbiaceae. A new diterpene from Croton californicus. (1976) (22)
Synthesis, superconductivity, X-ray structure and electronic band structure of λ-(BETS)2GaCl4 (1994) (22)
PALLADIUM-MEDIATED SUBSTITUTION REACTIONS OF POLYHEDRAL BORANE ANIONS (1994) (22)
N7, O6 bridging 9-ethylguanine (9-EtGH) groups in dinuclear metal–metal bonded complexes with bond orders of one, two or four (1996) (22)
Solution and solid–gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda=Me2NC2H4NMe2) (2000) (22)
Alkylation of osmium(VI) nitrido complexes: reaction of [Os(N)R4][NBu4] with [Me3O][BF4] and the x-ray crystal structures of [Os(N)(CH2SiMe3)4] [NBu4] and [Os(NMe)(CH2SiMe3)4] (1986) (22)
Contributions to the Chemistry of Boron, LXXXII. The Crystal and Molecular Structure of B,B′ -bis(1,3-dimethyl-1,3,2-diazaborolidin-2-yl) (1976) (22)
A new core topology in hexanuclear iron(III) carboxylate chemistry: [Fe6O3(O2CMe)9(OEt)2(bpy)2](ClO4) (2000) (21)
Influence of Lead(II) Lone Pairs on the Serpentine Structures for Heterometallic Alkoxides (1995) (21)
CYCLOBUTENE DERIVATIVES AS ISOPRENE EQUIVALENTS IN TERPENE SYNTHESIS. 3. BICYCLO(2.2.0)HEXANES (1980) (21)
Selective monophenylation of an active methylene compound (1989) (21)
Versatile Modes of Allene Bonding in the Structures of [W2(OtBu)6(C3H4)], [W2(OtBu)6(C3H4)(CO)2], and [W2(OtBu)6(C3H4)2] (1989) (21)
A binuclear vanadium(III) complex containing the linear [VOV]4+ unit: preparation, structure, and properties of tetrakis(dimethylaminoethanethiolato)oxodivanadium (1987) (21)
Stereoselective approach to acyclic systems via condensations of .alpha.-lithiosulfinyl carbanions and aldehydes (1981) (21)
A third isolated oxidation state for the family of [Mn12O12(O2CR)16(H2O)4] compounds. Synthesis, characterization and single-molecule magnetism properties of (PPh4)2[Mn12O12(O2CR)16(H2O)x] (x=3 or 4) (2001) (21)
Evidence for Equilibria between μ‐Alkyne and Alkylidyne Complexes of Tungsten Alkoxides: [W2(OR)6(μ‐C2R′2)] ⇌ 2[(RO)3W ≡ CR′] (1986) (21)
Molecular structure and dynamic solution behavior of the bridging 1,3-dimetallaallyl ligand in (Me3SiCH2)4W2(.mu.-CSiMe3)(.mu.-C3R2SiMe3) compounds (R = hydrogen, methyl, or phenyl) formed by insertion of alkynes into a bridging (.mu.2) ligand (1984) (21)
Heterometallic alkoxides of zirconium with tin(II) or lead(II) (1996) (20)
Aggregation and solvation of a lithium aryloxide (1984) (20)
Discrete metal-sulfide-thiolate complexes of an early-3d-transition metal (1986) (20)
Monocyclopentadienyl zirconium(IV) complexes (1981) (20)
Samarium alkyl-aryloxide complex containing a trigonal bipyramidal carbon atom. X-ray structure of [Li(THF)][sub 2][Sm(O-2,6-i-Pr[sub 2]C[sub 6]H[sub 3])[sub 3] CH[sub 2]SiMe[sub 3][sub 2]] (1994) (20)
Copper(I) and silver(I) diiridium polyhydrides (1984) (20)
Reactions of metal-metal multiple bonds. 9. .alpha.-Diketone adducts of ditungsten hexaalkoxides: W2(OR)6(O2C2R'2)2 (M-M) (1983) (20)
A short synthesis of dl-epi-pyroangolensolide and dl-pyroangolensolide: confirmation of the structures of pyroangolensolide and calodendrolide (1985) (20)
The molecular structure of the cubanelike compound, [Mo(NC6H4CH3)(.mu.3-S)(S2P(OC2H5)2)]4, and a description of its bonding (1981) (20)
Relationship of adduct formation to bimolecular reductive elimination from rhodium polyhydrides (1986) (20)
Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside. (2006) (20)
(η3-P3)W(OCH2But)3(HNMe2) formed by cleavage of the WW bond in the reaction between W2(OCH2But)6(HNMe2)2 and P4 (1987) (20)
Acidolysis of rhodium complexes [MeC(CH2PPh2)3]Rh(CH3)n: controlled creation of unsaturation (1991) (20)
Synthesis and solid state structure of tetra(2,6-di-isopropylphenoxy)-hexamethoxy-di-tantalum(V), Ta2(OC6H3Pri2)4(OCH3)6 (1986) (20)
Study of the formation of a .sigma.,.pi.-vinyl ligand by hydrogen atom transfer from a coordinated dimethylamide to a perpendicularly bonded ethyne ligand. Preparation and characterization of (PMe2Ph)Cl2W(.mu.-NMe2)(.mu.-.eta.1,.eta.2-CHCH2)(.mu.-.eta.2,.eta.1-CH2NMe)WCl(NMe2)(PMe2Ph) (1986) (20)
Facile olefin hydrogenation with an osmium dihydrogen complex (1989) (19)
A comparison of the influences of alkoxide and thiolate ligands on the electronic structure and reactivity of molybdenum(3+) and tungsten(3+) complexes. preparation and structures of M(2)(O(T)Bu)(2)(S(t)Bu)(4), [Mo(S(t)Bu)(3)(NO)](2), and W(S(t)Bu)(3)(NO)(py). (2001) (19)
Synthesis of tetranuclear and pentanuclear vanadium-oxide-carboxylate aggregates (1989) (19)
A synthetic model approach to the manganese(III) acid phosphatase and its iron(III)-substituted form (1986) (19)
Metal alkoxides: models for metal oxides. 8. Monocarbonyl adducts of ditungsten hexaalkoxides (M.tplbond.M) (RO = t-BuO, i-PrO and t-BuCH2O) and the dimer [W2(O-i-Pr)6(.mu.-CO)]2 (1985) (19)
Dinuclear and hexanuclear iron(III) carboxylate clusters with a bis(bipyridine) ligand: supramolecular aggregation of [Fe2O2] units to give a [Fe6O6] ladder structure (2000) (19)
Molecular distortions in sterically congested organometals. Crystal structure of bis(2,4,6-tri-tert-butylphenyl)mercury (1980) (19)
Synthetic and Mechanistic Studies of the Ring Opening and Denitrogenation of Pyridine and Picolines by Ti−C Multiple Bonds† (2010) (19)
Reactions involving carbon dioxide and mixed amido-phosphido dinuclear compounds. M2(NMe2)4(PR2)2(M.tplbond.M), where M = Mo and W. Comparative study of the insertion of carbon dioxide into metal-nitrogen and metal-phosphorus bonds (1989) (19)
Synthesis and structural characterization of tetraneopentyldioxodi-.mu.-oxodirhenium and the lithium(1+) and tetraethylammonium salts of the dineopentyldioxorhenate(1-) anion (1987) (19)
Addition of alkynes to hexaalkoxydimolybdenum (M.ident.M) compounds and structure of .mu.-ethyne-hexaisopropoxydipyridinodimolybdenum (1981) (19)
Boranes. XLV. Crystal and molecular structure, improved synthesis, and reactions of tridecaborane(19) (1976) (19)
A lipophilic salt of a transition-metal polyhydride: KOsH3(PMe2Ph)3 (1985) (19)
Dinuclear aryloxide chemistry. I: A direct comparison of aryloxide and alkoxide coordination to a dimetal center. Synthesis and structure of 1,2-bis(isopropoxy)tetrakis(2,6-dimethylphenoxy)dimolybdenum (Mo≡Mo) (1983) (19)
1,3-Ditungstacyclobutadienes. 1. Reactions with alkynes. Alkyne adducts and 1,3-dimetallaallyl derivatives (1985) (19)
Ein Nickel(II)-Azid-Cuban: Charakterisierung der durch end-on koordinierte μ3-Azidoliganden vermittelten magnetischen Austauschwechselwirkungen† (1995) (19)
Synthesis of π-(arene)metallocarboranes containing iron and ruthenium. Crystal structure of 3,1,2-(η6-1,3,5-(CH3)3C6H3)FeC2B9H11 (1982) (19)
PREPARATION OF MONO-PENTAMETHYLCYCLOPENTADIENYL URANIUM(IV) SULFIDO CLUSTERS THROUGH OXIDATION OF (ETA -C5ME5)UL2(THF)3. X-RAY STRUCTURAL CHARACTERIZA TION OF (ETA -C5ME5)3U3(MU 3-I)(MU 3-S)(MU 2-I)3I3 (1995) (19)
The synthesis and structure of Group 5 metal alkyl and alkylidene complexes containing 2,6-dialkylphenoxide ligands: X-ray crystal structures of [Ta(OC6H3Me2-2,6)2(CH2Ph)3], [Ta(OC6H3Me2-2,6)4Me], and [Ta(OC6H3But2-2,6)2(CHSiMe3)(CH2SiMe3)] (1987) (19)
Ring-Opening of σ-Thienyl and σ-Furyl Ligands at Ditungsten (M⋮M) Centers (1997) (18)
Oxide formation upon thermolysis of a Pb(II)/Zr(IV) alkoxide (1996) (18)
Site Selectivity in Electrophilic (H+, CH3+) Abstraction on Os(H)2X2(PiPr3)2 (1996) (18)
Synthesis and structure of [Mn6O2(O2CPh)10(EtOH)4(H2O)] ·. EtOH, a manganese aggregate containing three types of benzoate ligation. Isomerism in [Mn6O2(O2CPh)10] complexes (1992) (18)
20 K crystal structure, electrical transport, electronic band structure, scanning tunnelling microscopy and pressure–RF impedance studies on the organic conducting salt κ-(BEDT–TSF)2Cu[N(CN)2]Br (1995) (18)
The origin of structural variety of alkyne complexes of d8 metals. An example of structural isomerism (1990) (18)
Metal alkoxides - models for metal oxides. 11. Synthesis and properties of mixed alkyl/aryl/benzyl alkoxides of formula 1,2-W2R2(OR')4 and W2R(OR')5(M.tplbond.M) (1986) (18)
Preparation, structure, and bonding of Mo2(OCH2CMe3)6(.mu.-.eta.1,.eta.2-NCNMe2) (1987) (18)
Preparation and x-ray and neutron diffraction structure determination of the chlorotrihydroborate ion, [BH3Cl]- (1985) (18)
[2.1.1]-(2,6)-Pyridinophane(L)-controlled alkane C–H bond cleavage: (L)PtMe2H+ as a precursor to the geometrically “tense” transient (L)PtMe+ (2003) (18)
Preparation and Wittig reactions of an α-keto amino acid derivative (1990) (18)
Synthesis and structure of ReO(PMe3)(CH2SiMe3)3 and reaction with carbon monoxide (1987) (18)
Synthesis and properties of (C5H5Co)B9H9C.N(CH3)3 and related derivatives (1979) (18)
Hydroxycarbene complexes from paramagnetic acylmetals. Electrochemistry of benzoylchromium(0) and -tungsten(0) carbonyls (1981) (18)
Structural and Magnetochemical Properties of Mono-, Di-, and Trinuclear Manganese(III) Dithiolate Complexes. (1998) (18)
Conversion of carbon dioxide to carbonate using a rhodium .mu.-hydroxy species (1987) (18)
A new fluorinated tetraalkoxide ligand derived from the hydration of hexafluoroacetylacetone (1992) (18)
Use of the dicarboxylate ligand m -phenylenedipropionate for the synthesis of new Mn/O clusters. Synthesis, characterization and magnetic properties (2001) (18)
The chemistry of sterically crowded aryl-oxide ligands. Part 2. Cyclotantalation of 2,6-di-tert-butylphenoxide (1982) (18)
Synthetic and mechanistic investigation of the rearrangement of .eta.2-iminoacyl ligands of group 4 metals to vinylamido groups via a facile 1,2-hydrogen shift (1990) (18)
Preparation and properties of mononuclear vanadium thiolates: structural characterization of the [V(SBu-tert)4]0,- pair and carbon-sulfur bond cleavage in V(SBu-tert)4 in the gas phase (1991) (18)
Oxidation and acidolysis of MoH/sub 4/(PR/sub 3/)/sub 4/ (1982) (18)
Solution study of the ambient temperature monomer-dimer equilibrium Th{sub 2}(OR){sub 8}{rightleftharpoons} 2Th(OR){sub 4} (R = CH-i-Pr{sub 2}) and X-ray crystal structures of Th{sub 2}(OCH-i-Pr{sub 2}){sub 8}, Th(OCH-i-Pr{sub 2}){sub 4}(quin), and ThI(OCH-i-Pr{sub 2}){sub 3}(py){sub 2} (1995) (18)
Tetranuclear halide-alkoxide clusters of molybdenum formed by the coupling of M-M triple-bonded dinuclear compounds. Synthesis, characterization, and molecular structures of Mo4F2(O-iso-Pr)10, Mo4X3(O-iso-Pr)9, and Mo4X4(O-iso-Pr)8 (X = chloride, bromide, iodide) (1988) (18)
Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 1. Alkyne-promoted metal-to-metal alkyl migrations, W.tplbond.W/C.tplbond.C bond metathesis, and metallacyclopropene formation (1989) (18)
The molybdenum-molybdenum triple bond. 14. Preparation and characterization of mixed alkoxy-thiolate compounds of formula Mo2(OR)2(SAr)4 (M.tplbond.M) (1984) (17)
Studies of stereochemical control using α-lithiosulfinyl carbanions (1986) (17)
Reinvestigation of the condensation of 2‐hydrazinobenzothiazole with ethyl acetoacetate (1988) (17)
Metal alkoxides: models for metal oxides. 3. Further studies of the carbonylation of hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M) and characterization of M2(O-i-Pr)6(py)2(μ-CO)(M:M) compounds (1982) (17)
Preparation, structure, and chemistry of (O-acyl imidato)- and (O-alkyl imidato)carbene pentacarbonyl complexes of chromium (1989) (17)
A new class of electron-rich unsaturated molecules: Ru2HnX4-n(PiPr3)4, X = anion. (2000) (17)
Vanadium thiolate chemistry: preparation and structures of [NMe4]Na[VO(SCH2CH2S)2]·2EtOH and [Ph4P]2[V2(SCH2CH2S)4] (1983) (17)
Reactions of metal-metal multiple bonds. 15. Reactions of M2(OR)6(M.ident.M) compounds (M = molybdenum, cobalt) with 9,10-phenanthrenequinone and tetrachloro-1,2-benzoquinone (1988) (17)
Linear vs. Bent Nitrosyl Ligands in Pseudotetrahedral Nitrosyl Complexes. Low-Temperature Structure of CoI(NO)2(P(C6H5)3) (1983) (17)
A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But) (2002) (17)
Hindered-ligand systems. 9. Structure of the cis,cis-1,3,5-tris(pyridine-2-carboxaldimino)cyclohexane complexes of cobalt(II) and zinc(II) ions (1982) (17)
Support from model studies for the proposed existence of an S–1 oxidation level in the manganese assembly of the photosynthetic water oxidation centre (1987) (17)
Synthesis of some 10-, 11-, and 12-atom phosphaboranes. Crystal structure of 2-(trimethylamine)-1-PB11H10 (1993) (17)
Understanding the role of an easy-to-prepare aldimine–alkyne carboamination catalyst, [Ti(NMe2)3(NHMe2)][B(C6F5)4] (2011) (17)
Cu(II)-mediated intramolecular carbene cation radical formation: relevance to unimolecular metal-ligand radical intermediates. (2002) (17)
Tetrahydroborate complexes of tantalum: synthesis, characterization, and reactivity of Ta(BH4)H2(PMe3)4 (1985) (17)
Synthesis and thermal and hydrolytic conversion of heterometallic copper oxide-alkoxides (1994) (17)
The synthesis and chemistry of icosahedral bis(phosphine)metalladiarsaboranes and -distibaboranes containing nickel and palladium. Crystal and molecular structures of closo-1,1-(Me2PPh)2-1,2,3-PdAs2B9H9, closo-1,6-Cl2-1,5-(Me2PPh)2-1,2,3-PdAs2B9H7.CH2Cl2, and closo-1,1-(Me2PPh)2-1,2,3-PdSb2B9H9 (1993) (16)
Synthesis and intramolecular coupling of tantalum η2-iminoacyl (η2-RNCR′) and η2-imine (η2-RNCR′2) functional groups (1989) (16)
Observation of a facile isomerization of an early-transition-metal .eta.2-iminoacyl group via a 1,2-hydrogen shift (1987) (16)
Preparation and characterization of [Mn11O10Cl2(OAc)11(bpy)2(MeCN)2(H2O)2](ClO4)2·8MeCN, a mixed-valence manganese(III/IV) aggregate with rare undecanuclearity (bpy = 2,2′-bipyridyl) (1991) (16)
The tungsten-tungsten triple bond. 17. Mixed amido-phosphido compounds for formula M2(PR2)2(NMe2)4. Comparisons of amido and phosphido ligation and bridged and unbridged isomers (1992) (16)
Stepwise reductive acidolysis of tetrahydrotris(dimethylphenylphosphine)osmium (OsH4(PMe2Ph)3). Mechanism of hydrogen elimination/ligand addition (1984) (16)
Origin of Different Coordination Polyhedra forCu[CF3C(O)CHC(O)CF3]2L, (L = H2O, NH3) (1995) (16)
Notable features in the molecular structure of W2(OCH2-t-Bu)6(NCNMe2)3: Three different modes of bonding for NCNMe2(2-) ligands (1984) (16)
Tetrakis(2,6-di-t-butylphenoxy)uranium(IV): The first structurally characterized neutral homoleptic aryloxide complex of uranium(IV) (1989) (16)
Metal-metal-bonded complexes of the early transition metals. 4. Synthesis and characterization of the tantalum (II) dimer Ta/sub 2/Cl/sub 6/(PMe/sub 3/)/sub 4/ (1982) (16)
Molecular structure and solution dynamics of (.eta.5-C5H5)Ni(PPh3)S2COC2H5 (1980) (16)
Feasibility of a "building-block" approach to higher nuclearity manganese/oxygen/RCO2- aggregates: directed conversion of an [Mn4O2] to an [Mn8O4] complex (1990) (16)
Preparation and reactivity of monomeric (tolylimido)molybdenum(V) complexes and structure of mer-trichloro-trans-bis(ethyldiphenylphosphine)(p-tolylimido)molybdenum(V), Mo(Ntol)Cl3(EtPh2P)2 (1986) (16)
Reaction of organocalcium and -barium complexes with pyrazines. X-ray structural characterization of [(Me5C5)2Ba]2(μ-C4H4N2) (1992) (16)
Metal Alkoxides - Models for Metal Oxides. 18. Polynuclear Metal Hydrido Alkoxides. Reactions of W4(H)2(O-i-Pr)14 and W2(H)(O-c-C5H9)7(HNMe2) with Carbon-Carbon, Carbon-Oxygen, and Carbon-Nitrogen Multiple Bonds (1995) (16)
Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide (2003) (16)
Halide abstraction from titanium(III) chloride by zinc chloride (1984) (16)
Isolation and molecular structures of dinuclear [Mo(NC6H4CH3)(.mu.-S)(S2CN(iso-C4H9)2)]2 and cubanelike [Mo(NC6H4CH3)(.mu.3-S)(S2CN(iso-C4H9)2)]4, two oligomers in equilibrium (1983) (16)
SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR TANTALUM HYDRIDE COMPLEXES (1987) (16)
Simultaneous photodissociation of hydrogen and dimethylphenylphosphine from OsH4(PMe2Ph)3: production of dimeric and paramagnetic osmium polyhydrides (1990) (16)
Salicylate‐Mediated Assembly of the Diserete Mixed‐Valence Nonanuclear Manganese Complex [Mn9O4(O2CPh)8(sal)4(salH)2(py)4] (salH2 = salicylic acid, py = pyridine) (1987) (16)
Metal-metal multiple bonds. 15. Syntheses and structures of the 17-electron radical TpMo(CO)3 and the triply bonded dimer Tp2Mo2(CO)4(Mo.tplbond.Mo) (Tp = hydridotris(pyrazolyl)borate) (1983) (16)
Metal-metal bonded complexes of the early transition metals. 3. Synthesis, structure, and reactivity of hydrobis(trimethylphosphine)dichlorotantalum dimer (Ta2Cl4(PMe3)4H2 (Ta:Ta)) (1982) (15)
Deoxygenation of oxovanadium(IV) complexes under mild conditions: Synthesis and structural characterization of cis- dihalobis(diakyldithiocarbamato)vanadium(IV) (1991) (15)
Synthesis and characterization of a new series of .eta.6-arene compounds of molybdenum and tungsten: M(OC6H3Ph-.eta.6-C6H5)(X)(L)2 (M = Mo, W; X = H, Cl) compounds containing chelated 2,6-diphenylphenoxide ligands (1989) (15)
Contributions to the Chemistry of Boron, LXXV The Crystal and Molecular Structure of a Tetraazadiborine: 3,6-Bis(dimethylamino)-1,2,4,5-tetramethyl-1,2,4,5,3,6-tetraazadiborine (1976) (15)
Dicarbonyl and tricarbonyl adducts of (W {triple_bond} V W){sup 6+}- containing complexes. Preparation and structures of W{sub 2}(OCMe{sub 2}CF{sub 3}){sub 6}(CO){sub 2} and W{sub 2}(OCMe(CF{sub 3}){sub 2}){sub 4}(NMe{sub 2}){sub 2}(CO){sub 3} (1995) (15)
Addition of carboxylic acids to [Mo(NC6H4CH3)(.mu.3-S)(S2P(OC2H5)2)]4 and molecular structure of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu.-S)(.mu.-SH)(.mu.-O2CCF3) (1983) (15)
A new class of bipyridine-ligated metal carboxylate complexes: characterization of the triply-bridged ferromagnetically-coupled complexes [Cu2(OAc)3(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2 (1990) (15)
New d4 dihydrides of Ru(IV) and Os(IV) with π-donor ligands: M(H)2(chelate)(PiPr3)2 with chelate =ortho-XYC6H4 with X, Y = O, NR; R = H or CH3 (2005) (15)
Solution and Solid-State Structure of Ru(CO)2(Bu2PtC2H4PtBu2): Square Planar and Monomeric? (1999) (15)
Allene formation within the coordination sphere. Synthesis and crystal structure of (C5H5)2Mn2(CO)3(H2CCCH2) (1980) (15)
Hexadecamethoxy- and hexadecaethoxy-tetratungsten: preparation and X-ray crystal and molecular structure of W4(OEt)16 (1981) (15)
Synthesis and crystallographic characterization of [CsHN(SiMe3)]4, a cesium-based heterocubane (1992) (15)
Heterometallic species containing Cp2MH2 (MMo and W) and Cu+ or Ag+ are inner sphere redox intermediates (1992) (15)
Amido/phosphine pincer hydrides of ruthenium (2003) (15)
Double silyl migration converting ORe[N(SiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] substructures (2002) (15)
Heterocycles. 10. A facile synthesis of 7-hydroxy-6,7-dihydro-5H-pyrrolo[1,2-a]imidazole† (1987) (15)
Fluorination studies of the [commo-3,3′-Co(3,1,2-CoC2B9H11)2−1] ion (2000) (15)
Palladium-mediated substitution of the closo-B12H12(−2) and nido-7,8-C2B9H12(−1) ions by PMe2Ph: The single-crystal structure studies of 1,7-(PMe2Ph)2-closo-B12H10 and 9-PMe2Ph-nido-7,8-C2B9H11 (2007) (15)
[K([18]crown‐6)]+ [Mo4(μ4‐H) (OCH2tBu)12]−, the First Alkoxidohydrido Cluster of Molybdenum, Evidence for a Rare, if not the First, Example of a μ4‐Hydride (1994) (15)
Latent low-coordinate titanium imides supported by a sterically encumbering beta-diketiminate ligand. (2005) (15)
.beta.-Hydrogen effects in alkylalkoxides of dimolybdenum (M.tplbond.M) (1983) (15)
Aqueous intermolecular diels-alder chemistry: novel products derived from substituted benzoquinone-diene carboxylate adducts via tandem Michael reactions (1984) (15)
On the nature of the olefination reaction involving ditungsten hexaalkoxides and aldehydes or ketones (1992) (15)
STRUCTURAL CHARACTERIZATION AND REACTIVITY STUDIES OF THE SAMARIUM ARYLOXIDE COMPLEX SM(O-2,6-PR2IC6H3)3(THF)2 (1996) (15)
Bis[tris(dimethylphosphinomethyl)ethane]hydridochromium(1+) tetraethylborate(1-): the first synthesis of a cationic hydride complex from triethylborate(1-) (1987) (15)
Further synthetic studies of B9H11NH. The crystal structure of 1-(.eta.5-C5H5)-1,2-CoNHB9H9 (1988) (15)
Rational construction of mixed-metal alkoxides (1990) (15)
Synthesis of the hexacyclic indole alkaloid (.+-.)-kopsijasmine (1988) (15)
New pathway for the reaction of difluorocarbene with imines (1987) (15)
Reaction of dialkylamido and alkylimido derivatives of molybdenum and tungsten with o-arylphenols: intramolecular activation of aromatic carbon-hydrogen bonds by Mo-NR2 groups (1989) (14)
The molecular structure of indium oxine. (1988) (14)
Oligomerization of Metal-Oxygen Bonds in Thorium Alkoxide Chemistry: X-ray Crystal Structures of Th4(O-i-Pr)16(py)2 and Th2(OCHEt2)8(py)2 (1994) (14)
Quassinoids from the twigs and thorns of Castela polyandra. (1999) (14)
Synthesis and X-ray structure of 4-azanonaborane(13)(4-NB8H13) (1975) (14)
Effect of Lewis acidity on the synthesis of RuHCl(CO)(phosphine)(2): subtle influence of steric and electronic effects among P(i)Pr(3), P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3)), and P(i)Pr(2)Me. (2001) (14)
Coordination chemistry of tripyridinedimethane. (2002) (14)
The molecular structure of a substituted 2-norbornyl cation, 2-methoxy-1,7,7-trimethylbicyclo[2.2.1]hept-2-ylium fluoroborate (1987) (14)
Borohydride/ethanol reduction of RuCl3(PMe2Ph)3 (1984) (14)
Synthesis and single-crystal x-ray structural investigation of 1,1-bis(pentacarbonylmanganio)-3,4-dimethylgermacyclopent-3-ene and bis[1-(tetracarbonylferrio)-3,4-dimethylgermacyclopent-3-ene]: the first evidence for a puckered ground-state conformation in germacyclopent-3-enes (1990) (14)
The tungsten-tungsten triple bondXVI. Bis(cyclopentadienyl)- and bis(indenyl)tetradimethylamidoditungsten (WW) (1988) (14)
Intramolecular activation of arene carbon-hydrogen bonds by tungsten(II) metal centers and the possible role of metal .pi.-arene intermediates (1989) (14)
Highly cooperative valence detrapping of mixed-valence [Mn3O(O2CCH3)6(py)3](py) in the solid state (1989) (14)
Direct synthesis of VE2+ (E = S, Se) complexes using elemental chalcogens. Preparation, structure and properties of tetrakis(benzenethiolato)thiovanadate(2-) and bis(ethane-1,2-dithiolato)selenovanadate(2-) (1987) (14)
Crystal Structure of Sodium Ditellurite, Na4Te4O10. (1997) (14)
Dinuclear aryloxide chemistry. 4. Effect of aryloxide ancillary ligands on the chemistry of molybdenum-molybdenum and tungsten-tungsten multiple metal-metal bonds (1985) (14)
Pyridine, isocyanide, carbodiimide and allene adducts of hexakis (trifluoromethyl t-botoxy) ditungsten. A comparison of ligand binding to W2(OtBu)6 and W2(OCMe2CF3)6 (1998) (14)
The Common Instrument Middleware Architecture (2009) (14)
Thermally stable allylzirconium halide compounds. Synthesis, crystal structure, and dynamics of (.eta.5-C5Me5)(.eta.3-1,2,3-trimethylallyl)ZrBr2 and (.eta.5-C5Me5)(.eta.3-1,1,2-trimethylallyl)ZrBr2 (1987) (14)
Metal alkoxides. Models for metal oxides. 18. Structure, bonding and dynamic behavior of bis(.eta.2-ethylene)hexakis(neopentoxy)ditungsten. Studies of the reversible addition of carbon-carbon double bonds to a tungsten-tungsten triple bond (1992) (14)
The molybdenum-molybdenum triple bond. 12. Preparation and characterization of bis(tert-butyl mercaptido)tetrakis(dimethylamido)dimolybdenum(M.tplbond.M) (1983) (14)
Synthesis of a Metallaborane Complex Containing Pd(III) and the First Doubly Charge Compensated Ollide Ion. X-ray Crystal Structure of 1,4-Br(2)-1,2,5-(PMe(2)Ph)(3)-closo-1-PdB(11)H(8). (1998) (14)
A convenient synthesis of trialkylalkylidyne tungsten (6+) compounds and the X-ray crystal structure of (Me3CCH2)3WCPh(py) (1990) (14)
Interconverting edge-sharing and face-sharing bioctahedral dinuclear tungsten(III) phosphine complexes. Preparations, properties, and structures of W2Cl6L4, where L = PMe3, PEt3, and P(n-Bu)3, W2Cl6L3, where L = PEt3 and P(n-Bu)3, and [HPEt3]+[W2Cl7(PEt3)2]- (1993) (14)
Cycloalkyne ligands formed by the coupling of polymethylene-bridged alkylidynes: LnM.tplbond.C(CH2)nC.tplbond.MLn .fwdarw. L2nM2[.mu.-C2(CH2)n] (1991) (14)
Facile C(sp(2))/OR bond cleavage by Ru or Os. (2001) (14)
Preparation and characterization of the heptachlorobis(tetrahydrofuran)ditungstate and octachloro(tetrahydrofuran)ditungstate anions: [Ph4P][W2Cl7(THF)2] and [Ph4P][W2Cl8(THF)] (1988) (14)
Partial hydrolysis of [Mo(NR)(.mu.3-S)(S2P(OR')2)]4 and molecular structures of Mo2O(NC6H4CH3)(.mu.-S)2(S2P(OCH3)2)2 and cubanelike [Mo2O(NC6H5)(.mu.3-S)2(S2P(OC2H5)2)2]2 (1983) (14)
Tricyclization of an Epoxypolyene Utilizing Zeolites as Next-Generation Biomimetic Cyclization Promoters: Evidence of Surface and Pore Selectivity in the Cyclization Process† (1998) (14)
Derivatives of the (arene)M(CO)2 (M = Mn or Re) fragment. The molecular structure of (.eta.6-C6Me6)Mn(CO)2Cl (1986) (14)
The conversion of chelated .eta.6-arene to .sigma.-aryl coordination at tungsten metal centers (1988) (14)
A diphosphide adduct of ditungsten-hexaisopropoxide: X-ray crystal structure of W2(OPri)6(py)(μ-P2) (1985) (14)
Picosecond spectroscopy of charge-transfer processes. Photochemistry of anthracene-tetranitromethane EDA complexes (1984) (13)
Synthesis and Structure of a Resonance Stabilized (Trimethylphosphonio)metallapropenide (1988) (13)
Irida-, rhoda-, nickela-, and cuprapentaboranes derived from the arachno-[B4H9]- ion. Crystal structure of [Ir(.eta.4-B4H9)(CO){P(CH3)2C6H5}2], an analog of arachno-B5H11 and [Ir(.eta.4-C4H6)(CO){P(CH3)2C6H5}2]+ (1984) (13)
Metal-metal bonded complexes of the early transition metals: synthesis of a binuclear tantalum(III) trimethylphosphine complex and its reactions with hydrogen and ethylene (1980) (13)
Reactions between certain trialkoxytungsten alkylidyne complexes and carbon monoxide. Competitive carbon-carbon bond formation leading to alkyne or ketenyl complexes (1989) (13)
Unsaturated Ru(0) species with a constrained bis-phosphine ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]. (2000) (13)
Encapsulated alkaline earth metallocenes. 3: Structural influences on phase transformations alkaline earth complexes (1994) (13)
Structural determination of [(C5H5)2Mo(H)CO][(C5H5)Mo(CO)3] (1979) (13)
Reactions of metal-metal multiple bonds. 11. A comparison of the reactivity of M2(OR)6 (M.tplbond.M) and M2(OR)4(R'COCHCOR')2 (M.tplbond.M) compounds (M = Mo, W) with the .pi.-acid ligands CO, RC.tplbond.CR and RNC (1984) (13)
Bis(benzyl)- and bis(neopentyl)tetra(propionato)ditungsten (M .tplbond. M). Axial ligation and unprecedentedly short tungsten-tungsten distances for the RW .tplbond. WR unit (1984) (13)
Synthesis and Properties of Copper and Nickel Complexes of the General Formula (B11H11)2Mn-. Crystal Structure of [(n-Bu)4N]3[Cu(B11H11)2] (1994) (13)
HX elimination from Ir(H)2X(PBu2tPh)2 promoted by CO coordination: assessment of X ligand influence (1998) (13)
Nature of the catalytically inactive cobalt hydride formed upon hydrogenation of aromatic substrates. Structure and characterization of the binuclear cobalt hydride [{iso-Pr2P(CH2)3PPr-iso2}Co]2(H)(.mu.-H)3 (1991) (13)
FLUORO-LIGAND PROMOTION OF C-H ACTIVATION (1997) (13)
The remarkable role of steric factors in the reactions of alkynes (HCCH and MeCCMe)with ditungsten hexa-alkoxides: crystal and molecular structures of W2(OPri)6(py)2(µ-C2H2), W2(OCH2But)6(py)2(µ-C2Me2), and W2(OPri)6(µ-C4R4)(C2R2), where R = H and Me (py = pyridine) (1983) (13)
The preparation and characterization of M2(OEPh3)2(NMe2)4,where M = Mo and W and E = C and Si. The x-ray crystal structures of gauche-W2(OCPh3)2(NMe2)4, anti-Mo2(OCPh3)2(NMe2)4 and anti-W2(OSiPh3)2(NMe2)4 (1991) (13)
Incorporating metal-metal multiple bonds into heterometallic chains: bis[tris(trimethylstanyl)tin]tetrakis(dimethylamido)dimolybdenum and -ditungsten and related compounds (1983) (13)
Structural distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and their influence on intramolecular fluxionality and quantum exchange coupling. (2000) (13)
Generation and reactivity of unsaturated iridium and rhodium dimethyl complexes (1990) (13)
A titanium alkoxide (pinacolate) complex incorporating a 10-membered ring (1988) (13)
Comparison of the relative .pi.-donor abilities of amido and phosphido ligands. 1,2-Bis(di-tert-butylphosphido)tetrakis(dimethylamido)dimolybdenum and -ditungsten: 1,2-M2(P(tert-Bu)2)2(NMe2)4(M.tplbond.M) (1987) (13)
CRYSTAL AND MOLECULAR STRUCTURE OF A (DIBENZYLIDENEACETONE)PLATINUM DIMER WITH PARTIAL PT OCCUPANCY (1992) (13)
Solid-state structure and fluxional solution behavior of the ambident organometallic nucleophiles (. eta. sup 3 -C sub 7 H sub 7 )M(CO) sub 3 sup minus (M = Ru, Os) (1990) (13)
Carbon-nitrogen bond formation in the reaction between tetrakis(dimethylamido)molybdenum(IV) and 2,6-dimethylphenyl isocyanide. Preparation and characterization of the first homoleptic metallaamidine complex: Mo(.eta.2-Me2NC:NC6H3Me3-2,6)4. (1986) (12)
An unexpected carbon-carbon bond formation in the reaction between Mo2(ONp)6(.mu.-NCNEt2) and 2-butyne (1986) (12)
Factors determining allyl hapticity in early-transition-metal allyl complexes: synthesis, structure, and dynamics of Cp2(.eta.3-1,2,3-trimethylallyl)ZrBr and Cp2(.eta.1-1,1,2-trimethylallyl)ZrBr (1988) (12)
Monoisocyanide adducts of ditungsten hexaalkoxides. Synthetic, structural, and theoretical investigations into the nature of C.tplbond.N bond order reduction (1987) (12)
SYNTHESIS AND CHARACTERIZATION OF VOLATILE SODIUM YTTRIUM FLUOROALKOXIDES.STRUCTURE OF NA3Y(OCH(CF3)2)6(THF)3 AND NA2Y(OCME(CF3)2)5(THF)3 (1995) (12)
Synthesis and Characterization of Radical Cation Salts Derived from Tetraselenafulvalene and Bis(Ethy1enedithio)tetraselenafulvalene (1992) (12)
A CASE OF C-H ACTIVATION (ORTHO METALATION) WHICH IS REVERSIBLE AT 25 C (1997) (12)
Metal alkoxides: models for metal oxides. XIII: NMR spectroscopic and theoretical investigations into the reduction of alkynes bonded to hexaalkoxides of dimolybdenum and ditungsten (1988) (12)
Triple bonds between molybdenum and tungsten atoms supported by thiolate ligands: (RS)3MM(SR)3 (1985) (12)
Oxidative-additions to (W.tplbond.W)6+ centers: the influence of Lewis base association reactions (1983) (12)
Pyrido[2′1′:2,3]imidazo[4,5‐c]isoquinoline and the alkylation of pyrido[2′,1′:2,3]imidazo[4,5‐c]isoquinolin‐5(6H)‐one (1987) (12)
Organoimido complexes of Mo(IV), Mo(V) and Mo(VI): preparation, structure and reactivity (1986) (12)
Preparation and structural characterisation of [NEt4]2[Mn2(SCH2CH2S)4], a stable manganese(III)–thiolate dimer (1983) (12)
New boron hydride. Tetradecaborane(20) (1975) (12)
Alcoholysis of Titanium Alkoxides by Fluoroalcohols. Synthesis, Characterization and X-Ray Crystal Structure of [Ti (O-i-Pr)2{OCH(CF3)2}2]2 (1993) (12)
Organometallic chemistry of fluorocarbon acids. Structure of hexakis(isopropoxo)bis[bis(trifluoromethylsulfonyl)methanato)dititanium: an example of an oxygen-bonded HC(SO2CF3)2 ligand (1990) (12)
HALIDE ABSTRACTION FROM VANADIUM TRICHLORIDE BY ZINC CHLORIDE. CRYSTAL STRUCTURE OF VANADIUM TRICHLORIDE.ZINC CHLORIDE.4 TETRAHYDROFURAN.2 WATER (1985) (12)
New Methodology for the Synthesis of a,a-Dialkylamino Acids Using the "Self-Regeneration of Stereocenters" Method: a-Ethyl-a-phenylglycine (1997) (12)
M2(hpp)4Cl2 and M2(hpp)4, where M = Mo and W: preparations, structure and bonding, and comparisons with C2, C2H2, and C2Cl2 and the hypothetical molecules M2(hpp)4(H)2. (2003) (12)
Direct observation of ligand migration in the reversible addition of trimethylphosphine to 1,2-Mo2(CH2Ph)2(OPr-iso)4 and structural characterization of (Me3P)(PhCH2)2(iso-PrO)Mo.tplbond.Mo(OPr-iso)3 and 1,2-Mo2(CH2Ph)2(OPr-iso)4(dmpm), where dmpm = bis(dimethylphosphino)methane (1992) (12)
Tungsten-carbon, carbon-carbon and carbon-hydrogen bond activations in the chemistry of W2R2(OR')4(W.tplbond.W) complexes. 3. Competitive .alpha.-hydrogen versus .beta.-hydrogen eliminations and ethylene-to-acetylene hydrogen transfers (1989) (12)
Diallyl- and bis(2-methylallyl)tetrakis(dimethylamino)ditungsten: W2(.mu.-.eta.3-C3H5)2(NMe2)4 and W2(.mu.1-C4H7)2(NMe2)4 (M.tplbond.M). Comments on ligand-metal .pi.-interactions at (W.tplbond.W)6+ centers (1988) (12)
Towards functional models of the photosynthetic water oxidation centre: synthesis and structure of the asymmetric complex [Mn2O(O2CMe)2(bpy)2(H2O)(S2O8)]·H2O (bpy = 2,2′-bipyridine), containing coordinated H2O and S2O82– (1991) (12)
Metal alkoxides - models for metal oxides. 6. The linking of alkyne and nitrile fragments at ditungsten centers. Preparation and characterization of W2(O-tert-Bu)6(CHCHC(Ph)N), W2(O-iso-Pr)7(CH2CHC(Ph)N), W2(OCH2-tert-Bu)6(N(CMe)4N)(py), and W2(O-iso-Pr)7(NHC(Me)CHCHC(Me)N) (1984) (12)
RECENT DEVELOPMENTS IN VANADIUM SULPHUR AND OXYGEN CHEMISTRY (1989) (12)
Thermal reactivities of isostructural d10 metalloenediynes: metal-dependent Bergman cyclization (2001) (12)
A quassinoid (peninsularinone) and a steroid from Castela peninsularis (1994) (12)
The molybdenum-molybdenum triple bond. 16. Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum(M.tplbond.M). An example of a nonbridged dinuclear bis(carbene) complex (1985) (11)
Organogold(III) complexes. Structure of monomethyldibromogold (1977) (11)
Mechanism of Ethylene Hydrogenation by the Molecular Hydrogen Complex [Ir(H)2(H2)(PMe2Ph)3]⊕—Characterization of Intermediates (1988) (11)
Strategy for synthesis of an yttrium/copper(I) complex with an oxo ligand environment (1992) (11)
The First Observation of the Equilibrium 2 MM ⇄ M4 (M = Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer (1986) (11)
Cyclopentadienyl(allyl)(butadiene)hafnium compounds. Synthesis, crystal structure, and dynamics of cyclopentadienyl(1,2,3-trimethylallyl)(1,2-dimethylbutadiene)hafnium and cyclopentadienyl(1,1,2-trimethylallyl)(2,3-dimethylbutadiene)hafnium (1991) (11)
Hexakis(2,4,6-trimethylbenzenethiolato)dimolybdenum (Mo2(SC6H2Me3)6). The first example of a compound containing a molybdenum-molybdenum triple bond supported by six mercaptido ligands (1983) (11)
Bis[benzylbis(dimethylamido)molybdenum] and -tungsten (M.tplbond.M) compounds and their reactions with carbon dioxide and 1,3-diaryltriazenes. A radical difference (1982) (11)
X-Ray crystal and molecular structure of the nido-carborane B7C2H7Me2 (1972) (11)
X-ray crystal structures of [(Me3SiCH2)2InCl]2 and [(Me3SiCH2)InCl2]∞ (1994) (11)
Dissolution of uranium metal using iodine and 2-propanol. Synthesis and X-ray crystal structure of tetraiodotetraisopropoxybis(2-propanol-)diuranium (1992) (11)
Insertion reactions of hexaalkoxydimolybdenum and -ditungsten compounds with organic isocyanates. Syntheses and structures of W2(OCMe3)4[N(C6H5)C(O)OCMe3]2 and Mo2(O-i-Pr)4[N(C6H5)C(O)O-i-Pr] (1984) (11)
Addition of 1,3-butadiene to a metal-metal triple bond. Preparation and structure of tungsten complex W2(OCH2-tert-Bu)6(py)(C4H6) (1991) (11)
Deoxygenation of oxovanadium(IV) complexes under mild conditions: conversion of vanadyl species to the corresponding dihalides with carboxylic acid halides (1993) (11)
A heterometallic cluster with extreme hydride content: H24Cu6Re4(PPh3)82+ (1992) (11)
Stereospecific syntheses of the four diastereomeric 2-amino-5-phenoxycyclopentanols (1985) (11)
Organometallic consequences of a redox reaction: Terminal trimethylsilylmethylidene titanium complexes prepared by a one-electron oxidation step (2007) (11)
Studies of boranes. 47. Synthesis and x-ray crystallographic study of tetradecaborane(20) (1981) (11)
Broken bond-bending constraints and glass formation in the oxides. (1995) (11)
Crystal and molecular structure of allyl(bromo)bis(triethylphosphine)platinum(II). An example of .sigma. bonding of an .eta.1-allyl group (1977) (11)
The molybdenum-molybdenum triple bond—XVII. Syntheses, spectroscopic and structural characterizations of Mo4F4(O—t-Bu)8 and Mo2F2(O—t-Bu)4(PMe3)2 (MoMo) (1985) (11)
Facile cleavage of the molybdenum.tplbond.molybdenum bond in reactions between Mo2(OBut)6 and aryl azides and molecular oxygen (1981) (11)
Synthesis, structural characterization and magnetic properties of mixed-valent bis-bipyridine manganese carboxylate clusters (2001) (11)
[N.1.1]-(2,6)-Pyridinophanes: a new ligand type imposing unusual metal coordination geometries. (2002) (11)
Crystal and molecular structure of monochlorotris (2,6-di-t-butylphenoxo)hafnium (1982) (11)
Phosphinecarboxylate ligands formed by the insertion of carbon dioxide into metal−phosphido bonds. Preparation and structural characterization of tetrakis(di-tert-butylphosphinecarboxylato) dimolybdenum (1987) (11)
Isolation and structure of stephalic acid, a new clerodane diterpene from Stevia polycephala ☆ (1982) (11)
Synthesis of the 1- and 2-dimethyl sulfide.cntdot.undecaborane (13) isomers. Crystal structures of 2-Me2S.cntdot.B11H13 and 7-Me2S.cntdot.B11H13 (1993) (11)
Hexakis(tert-butyldimethylsiloxy)ditungsten and its reaction with ethyne. Hydrogen atom transfer reactions involving bridging ethynyl, ethyne, vinyl and ethylidyne ligands. Crystal structures of [W2(OSiButMe2)6], [W2(OSiButMe2)6(µ-C2H2)(C5H5N)] and [W2(OSiButMe2)5(µ-CCH)] (1991) (11)
Reactions of W2(H)(OR)7, W2(OR)6(py)2 and W4(OCH2cC4H7)12 compounds (R = Pri, CH2But, cC5H9) with azobenzene, 1,2-diphenylhydrazine and 1,1-dimethylhydrazine (1997) (11)
Crystal and molecular structure of bis(tetraphenylphosphonium) bis(1,2-dicyanoethylene-1,2-dithiolato)oxovanadate(IV): its single-crystal electron spin resonance as a pure compound and diluted in the isomorphous molybdenum(IV) compound (1988) (11)
Preparation and characterization of M2(SeAr′)6 and mixed ligand M2(OR)2(SeAr′)4 species (M = Mo, W) (1990) (11)
Metal-metal bonded complexes of the early transition metals. 5. Direct hydrogenation of a metal-metal multiple bond (1982) (11)
New example of Jahn-Teller isomerism in [Mn12O12(O2CR)16 (H2O)4] complexes (2003) (11)
Syntheses, crystal structures and properties of mononuclear chromium(III) and dinuclear vanadium(III) and copper(II) complexes with a bis-bipyridyl ligand† (1999) (11)
The molybdenum-molybdenum triple bond. 13. Preparations and characterization of bis(.beta.-diketonato)tetraalkoxydimolybdenum and -ditungsten compounds (1984) (10)
Alkyne adducts of mixed chloro-dimethylamido ditungsten compounds (1986) (10)
The first structurally characterised homoleptic thorium alkoxide: X-ray crystal structure of [Th(OCHPri2)4]2, and NMR evidence for a monomer–dimer equilibrium (1992) (10)
The tungsten-tungsten triple bond18. Bridging and terminal allyl ligands in complexes of the formula W2(R)2(NMe2)4, where R C3H5 and C4H7 (1992) (10)
A novel metalloenediyne coordination polymer: serpentine structure of [Cu(OAc) 4 (daed)] n (2001) (10)
Phosphines Functionalized with Crown Ether Groups: Synthesis and Study of Systems Incorporating 1,3-Xylyl-18-Crown-5 Units (1998) (10)
Kinetic and mechanistic studies on the formation and reactions of early-transition-metal-ketene complexes (1988) (10)
Correlation among alkoxide .fwdarw. tungsten .pi.-bonding, spin state, and reactivity in W(OCH2CF3)2Cl2(PMe2Ph)2 (1994) (10)
Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n (1993) (10)
Synthesis and Characterization of Paramagnetic Trinickel-Molybdenum and Trinickel-Tungsten Clusters (1989) (10)
Synthesis and X-ray crystal structures of [Me2NH2]+[Al(OSiMe3)4]− and Al2(OSiMe3)6 (1991) (10)
Nitro-substituted benzoates of dimolybdenum: the Mo24+ δ to ligand charge transfer band (1996) (10)
Competitive carbon-carbon bond formation and cleavage and cluster formation in the reaction between 3-hexyne and hexaisopropoxyditungsten (1986) (10)
Further studies of the reactions involving ethyne and M2(OBut)6, where M Mo and W. Polyacetylene formation versus formation of ethyne adducts and CC coupled products (1997) (10)
Synthesis and structure of hexabenzyl-dimolybdenum (MoMo) (1986) (10)
Halide abstraction from VCl3 by ZnCl2. crystal structure of VCl3.ZnCl2.4THF.2H2O (1984) (10)
Preparation and reactions of niobium(V) sulphide complexes (1989) (10)
Iodide Complexes of Decaborane(14) and 2,4-Diiododecaborane(14). The X-ray Crystal Structure of [P(C6H5)3CH3][2,4-I2B10H12I] (1995) (10)
Reaction between bis(benzyl)tetraisopropoxyditungsten(WW) and but-2-yne: W2(CH2Ph)2(OPri)4(η2-C2Me2)2 and W2(H)(OPri)4(µ-CPh)(µ-C4Me4). A terminal metal hydride with a 1H n.m.r. resonance 20 p.p.m. downfield of Me4Si (1985) (10)
Palladium-Assisted Cyano Substitution Reactions of (PMe2Ph)2Pd(B9H9As2) and (PMe2Ph)2Pd(B9C2H11). X-ray Crystal and Molecular Structures of 5-CN-1,1-(PMe2Ph)2-closo-1,2,3-PdAs2B9H8, 1-tBuNC-5-CN-1-(PMe2Ph)-closo-1,2,3-PdAs2B9H8, and 4,5-(CN)2-1,1-(PMe2Ph)2-closo-1,2,3-PdC2B9H9 (1995) (10)
Alkyne adducts of ditungsten hexaneopentoxide and alkylidyne-capped tritungsten compounds supported by neopentoxide ligands (1986) (10)
The solution dynamics of some Fe2(CO)6(L–L′) complexes (1978) (10)
Influence of the Alkoxide Moiety on Heterometallic Compound Formation: Structure and Dynamics of KZr2(OtBu)9 and K2Zr2(OtBu)10 (1994) (10)
SYNTHESIS AND STRUCTURE OF THE NONAHYDRO(TRISELENO)UNDECABORATE(2-) ION (1979) (10)
Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 2. Metal-carbon bond homolysis and competitive alkane and dihydrogen eliminations in double .alpha.-hydrogen activation processes (1989) (10)
Monoindenyl halides of zirconium and hafnium. The preparation of [(η5-C9H7)ZrCl3]n and [(η5-C9H7)HfCl2(μ-Cl)]2 and the crystal structure of [(η5-C9H7)HfCl2(μ-Cl)]2 (1995) (10)
Zinc-containing heterometallic hydride compounds: observation of terminal and bridging ZnN (SiMe3)2 groups (1988) (10)
A mixed halo / n-alkyl compound of chromium(III): synthesis, structure, and reactivity of Cr(n-Bu)2Cl[(Me2PCH2)3CMe] (1989) (10)
Stereoselective synthesis of complex polycyclic aziridines: use of the Brønsted acid-catalyzed aza-Darzens reaction to prepare an orthogonally protected mitomycin C intermediate with maximal convergency. (2011) (10)
CHARACTERIZATION AND STRUCTURE OF OSH(OH)(CO)(PTBU2ME)2 (1999) (9)
Cyclopentoxyditungsten compounds and crystal and molecular structures and dynamic solution behavior of W sub 2 (. mu. -H)(O-c-C sub 5 H sub 9 ) sub 7 (HNMe sub 2 ) (1991) (9)
Structure of the B10H13– ion (1972) (9)
Zirconium compounds of hexamethyldisiloxane. Synthesis and structure of (.eta.5-C5H5)2Zr(CH2SiMe2OSiMe3)2 and (.eta.5-C5Me5)ZrCl2(.eta.2-CH2SiMe2OSiMe3) and their reactivity with methyl isocyanide (1993) (9)
Tris(N,N'-dimethylethylenediamido)dimolybdenum (M.tplbond.M). A metallopropellane with a near-eclipsed central molybdenum nitride (Mo2N6) moiety (1980) (9)
Low symmetry in the crystal structure of (octapentylphthalocyaninato)(methyl)rhodium(III) (1993) (9)
Preparation and Characterization of 1,3-Butadiene and Isoprene Complexes, W2(OCH2tBu)6(diene)(py), and Studies of the Selective Hydrogenation of 1,3-Dienes (1999) (9)
How Do Two CC Double Bonds Add to One MM Triple Bond? Structure and Bonding in Bis (η2-ethylene)hexakis(neopentoxy)ditungsten†‡ (1990) (9)
Carbene transposition involving double dehydrogenation of an sp3 carbon (2001) (9)
Stereochemical activity of the metal-centered lone electron pair in group 14 metallocenes. Crystal structure of the linear sandwich complex [C5(iPr)3H2]2Pb. (2000) (9)
CHARACTERIZATION OF A FIVE-COORDINATE RU(II) SPECIES DEVOID OF PI-DONOR LIGANDS (1993) (9)
The tungsten-tungsten triple bond. 14. Factors influencing triple bonds between tungsten atoms having valence molecular orbital configurations of .sigma.2.pi.4 and .pi.4.delta.2 and preparation and characterization of bis(neopentyl)bis(acetato)bis(diethyldithiocarbamato)ditungsten (1987) (9)
Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand (2005) (9)
The first example of a niobium–sulphide–thiolate cluster: metal–metal bonding and µ4-sulphide groups in tetranuclear [Nb4S2(SPH)12]4– (1987) (9)
Trigonal prismatic co-ordination in the cis,cis-1,3,5-tris(pyridine-2-carboxaldimino)cyclohexanezinc(II) ion (1969) (9)
Synthesis and reactivity of a neutral tungsten(0) alkyl complex. Insertion of CO2 into the W-CH3 bond of trans,trans-W(CH3)(CO)2(NO)(PPh3)2 and the structural characterization of trans-W(.eta.2-O2CCH3)(CO)(NO)(PPh3)2 (1987) (9)
Dimolybdenum bis((S,S,S)-triisopropanolaminate(3-)): a blue compound with an unusual Mo-Mo triple bond. (2000) (9)
Metal-metal-bonded complexes of the early transition metals. 8. Tertiary alkylphosphine adducts of W2(O2CCF3)4 (W::W) (1984) (9)
The Molecular Structures of Thiele′s and Chichibabin′s Hydrocarbons (1987) (9)
A new structure type for a 6-electron triangulo tungsten cluster: W3(.mu.3-CMe)(.mu.-O-iso-Pr)3(O-iso-Pr)6 (1985) (9)
Hexaisopropoxybis(dimethylamino)dinitrosyldimolybdenum (1980) (9)
Synthesis and crystal and molecular structures of M(OAr')2(CH2-py-6Me)2 [M = Hf, Th; OAr' = 2,6-di-tert-butylphenoxide; CH2-py-6Me = 2-(6-methylpyridyl)methyl], complexes containing two carbon-nitrogen chelating pyridylmethyl ligands (1987) (9)
Two different terminal nitrate bonding modes in [Fe2O(NO3)4(C7H7N3)4] (1994) (9)
((Bu2PCH2SiMe2)-Bu-t)(2)N RuMe2: Synthesis and reactivity of an unsaturated ruthenium dialkyl radical species (2006) (9)
Dihydrogen addition to (PiPr3) 2OsXnH4−n (1997) (9)
The preparation of the mixed alkali metal silanolate K4Li4(OSiMe3)x(OCMe3)8−x (8⩾x⩾5.7) and the effects of mixed alkali metals on the anion induced ring opening polymerization of octamethylcyclotetrasiloxane (1996) (8)
Thioether coordinated metalloenediynes: Syntheses, structures and thermal reactivity comparison (2006) (8)
A boroxine-supported triosmium oxymethylidyne cluster system, [(µ-H)3(CO)9Os3CO]3(B3O3): its structure and its conversion into halogeno- and phenyl-methylidyne complexes (1984) (8)
1,2-Bis(di-tert-butylarsenido)tetrakis(dimethylamido)dimolybdenum and -ditungsten. Synthesis, structures, and solution behavior (1987) (8)
Reactions of metal-metal multiple bonds. 13. Reactions of diazoalkanes with hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M). Preparation and characterization of Mo2(O-iso-Pr)6(N2CPh2)2(py), W2(O-tert-Bu)6(N2C(p-tol)2)2, and Mo(O-tert-Bu)4(N2CPh2) (1984) (8)
Synthesis, Characterization, and Molecular Structure of the New S2O Complex Mo(S2O)(S2CNEt2)3.cntdot.1/2Et2O (1994) (8)
Preparation and X-ray structure of the N-benzyl derivative of 10-aza-7,8-dicarba-nido-undecaborane(11)(10-PhCh2-10-N-7,8-C2B8H10) (1975) (8)
Synthesis of quinuclidine–benzyl(ethylcarbamoyl)borane: the first boron analogue of a phenylanine derivative (1989) (8)
Reactions of MO2(O2CMe)4with amines and diamines: A structural and thermal study of stepwise acetate displacement and hydrogen bonding (1991) (8)
The first hydrocarbyl trinuclear and tetranuclear clusters of tungsten: W3O(CH2Ph)(O-i-Pr)9 and W3O(R)2(O-i-Pr)8 where R = CH2Ph,Ph, and W4(p-tolyl)2(O-i-Pr)10 (1987) (8)
Common Molecules: Bringing Research and Teaching Together Through an Online Collection (2003) (8)
CHARACTERIZATION OF THE ELECTROCRYSTALLIZATION PRODUCTS OF BIS(ETHYLENEDITHIO)TETRASELENAFULVALENE (BETS) AND TETRABUTYLAMMONIUM TETRACHLOROGALLATE (1996) (8)
The synthesis and structure of nido-Me3NCB10H10PR derivatives (1978) (8)
The crystal structure of octachlorodibenzodioxin: Experimental and calculated (1988) (8)
Conversion of L3Mo.tplbond.MoL3 type compounds to L3Mo(.mu.-L)3MoL3 type compounds and mechanistic implications (1983) (8)
Synthetic approaches to Fe(II) complexes of the bulky phosphine PtBu2Me (1999) (8)
Unbridged and bridged isomers of W2(PCy2)2(NMe2)4: preparations, characterizations, and comments on thermodynamic and activation parameters for the closing of phosphido bridges in d3-d3 dinuclear compounds (1988) (8)
Tungsten-Carbon, Carbon-Carbon, and Carbon-Hydrogen Bond Activations in the Chemistry of 1,2-W2R2(OR')4 (W.tplbond.W) Complexes. 4. Phosphine- and Amine-Promoted Ligand Migrations and .alpha.-CH Activations in the Formation of Alkylidynehydridoditungsten Compounds (1995) (8)
The stereochemistry of disulfides. The crystal structure of 1α,5α‐epidithioandrostane‐3α,17β‐diol (C19O2S2H30) (1977) (8)
The Molybdenum-Molybdenum Triple Bond. 9. Bis(1,3-di-p-Tolyltriazenido)bis(Dimethylamido)Dimethyldimolybdenum. (1980) (8)
Synthesis and substitution reactions of dinuclear molybdenum complexes containing Mo-Mo quadruple bonds and labile solvent ligands (1992) (8)
The molybdenum-molybdenum triple bond. 7. Bis(1,3-di-p-tolyltriazenido)tetrakis(dimethylamido)dimolybdenum (1981) (8)
SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF A LEAD ARYL OXIDE DIMER, Pb2((-O-2,6-Ph2C6H3)2(O-2,6-Ph2C6H3)2 (1998) (8)
Attempted preparation of a dimetallabenzyne. Preparation and crystal structure of W2(.mu.-C3Ph3)(.mu.-CPh)(NMe2)4 (M-M) (1992) (8)
Ene-yne couplings at a ditungsten center to give alkylidene hydrido complexes supported by siloxide ligands (1993) (8)
Triple bonds between molybdenum and tungsten atoms supported by selenolate ligands: M2(SeAr)6 and M2(OPri)2(SeAr)4(Ar = mesityl) (1990) (8)
SYNTHETIC STUDIES ON QUASSINOIDS : SYNTHESIS OF ()-SHINJUDILACTONE AND ()-13-EPI-SHINJUDILACTONE (1998) (7)
11a-Chlorination of the Shemyakin tricyclic ketone (1982) (7)
Mo[sub 4](H)[sub 3]/(O-t-Bu)[sub 7](HNMe[sub 2]). A novel hydrido cluster of molybdenum (1993) (7)
Synthesis, characterization, low-temperature (50 K) neutron diffraction structure, and reactivity of chlorodihydridotetrakis(trimethylphosphine)tantalum (III) (1987) (7)
Oxidative addition of 1,4-diisopropyl-1,4-diazabutadiene to hexakisisopropoxydimolybdenum (MM). Mo2(Opri)6(PriNCHCHNPri and Mo2(OPri)5(PriNCHCHNPri)2 (1989) (7)
Electrochemical synthesis and molecular structure of coordinatively unsaturated platinacyclobutanes (1981) (7)
Di-, hexa- and poly-nuclear molybdenum(II) carboxylatescontaining quadruply bonded [Mo2]4+units: crystal structures of[Mo2(O2CCHF2)2(bpy)2(MeCN)(BF4)][BF4] and[Mo6(O2CCHF2)12(bpy)4] (bpy = 2,2′-bipyridine) (1997) (7)
THE CHEMISTRY OF THE EUPHORBIACEAE. A NEW DITERPENE FROM CROTON CALIFORNICUS (1976) (7)
Studies of mono substituted compounds of formula M2(NMe2)5X (M.tplbond.M), where M = molybdenum and tungsten and X = iodine, alkyl, aryl, and diphenylphosphido, and the bridged-1,1'-ferrocenyl complex W2(NMe2)(.mu.-(C5H4)2Fe) (1993) (7)
Di-tert-butoxybis(arylimido)molybdenum(VI) compounds, [Mo(O-tert-Bu)2(NAr)(.mu.-NAr)]2, where Ar = phenyl and p-tolyl (1982) (7)
Synthese und Struktur eines resonanzstabilisierten (Trimethylphosphonio)metallapropenids (1988) (7)
Hydride transfer from transition metal hydrides to dihapto acyl ligands (1985) (7)
Dioxododecaisopropoxytetratungsten. Oxygen atom abstraction from acetone in reactions with hexaisopropoxyditungsten (WW) (1984) (7)
Double bonds between molybdenum atoms supported by dimethylamido ligands: Mo2(NMe2)4(OR)4 compounds, where R 4- methylcyclohexyl and diisopropylmethyl (1989) (7)
Complexes of the platinum metals. Part 25. Reactions of ruthenium and osmium nitrosyls [MH(NO)(PPh3)3] and [M(NO)2(PPh3)2] with perfluorocarboxylic acids: X-ray crystal structure determination of nitrosyl(trifluoroacetato)(trifluoroacetohydroximato-OO′)bis(triphenylphosphine)osmium(II)–dichlorometha (1985) (7)
Reduction of α,β-unsaturated ketones and aldehydes by tungsten–tungsten triple bonds: formation of 1,2 and 1,4 adducts as opposed to CO cleavage (1991) (7)
SYNTHESIS AND STUDY OF PHOSPHINES INCORPORATING 2-CYANOPHENYL GROUPS AND THE X-RAY STRUCTURE OF TRIS(2-CYANOPHENYL)PHOSPHINE (1999) (7)
The cyclometallation of 2,6-diphenylphenoxide (OAr-2,6Ph2) ligands at niobium(V) and tantalum(V) metal centres: The solid state structures of the monocyclometallated compounds Ta(OC6H3Ph-C6H4)(OAr-2,6Ph2)2(R) (R = CH3, n-C4H9) and Nb(OC6H3Ph-C6H4)(OAr-2,6Ph2)2(Cl) (1990) (7)
Could one have five? The synthesis and structure of Re2H4(PMe2Ph)4[P(OCH2)3CEt]2 and its conjugate acid (1982) (7)
Reactions of metal-metal multiple bonds. 12. Reactions of organic halides (chloride, bromide, iodide) with hexaalkoxydimolybdenum and -ditungsten (M.tplbond.M) compounds. Preparation and characterization of hexaneopentoxydibromo(pyridine)dimolybdenum (M:M) (1984) (7)
Synthetic and mechanistic features of dinuclear reductive elimination between Re2H8(PMe2Ph)4 and several tin(II) reagents (1988) (7)
Syntheses and characterization of nickel thiolate complexes: X-ray structure of [Ni(SCH2CH2S)(PPh2CHCHPPh2)] (2002) (7)
Two new structural types for d3-d3 dimers of molybdenum and tungsten: [K(18-crown-6)]+[Mo2(OCH2But)7]− and [W2{P(c-hexyl)2}3(OCH2But)3{HP(c-hexyl)2}] (1993) (7)
THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 8. BIS(6-METHYL-2-PYRIDYL)METHYLTETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM (1981) (7)
Heterometallic Polyhydride Raft Formation: A Comparison of Syntheses using Alkoxides of Copper and Gold† (1987) (7)
.pi.-Interactions in the structures of 1- and 2-methylpentaborane and 1- and 2-silylpentaborane. Electron diffraction study (1975) (7)
Tris(N,N'-dimethylethylenediaminato)dimolybdenum and tris(N,N'-dimethylethylenediaminato)ditungsten. A comparison of eclipsed and staggered triple bonds, .sigma.2.pi.4, between molybdenum and tungsten atoms in X3M.ident.MX3 compounds (1987) (7)
Synthetic Model Approach to the Manganese(III) Acid Phosphatase and Its Iron(III)-Substituted Form. (1986) (7)
Photoinitiated intramolecular hydrogen transfer from rhenium polyhydrides to C8 cyclopolyolefins (1985) (7)
TETRANUCLEAR DIALKYLDITHIOPHOSPHATE COMPLEXES OF MOLYBDENUM(V) WITH NITRIDE LIGANDS (1982) (7)
Preparation, luminescence studies, and solution behaviour of a cerium–tungsten heterobimetallic compound (1988) (7)
Preparation and Physical Properties of Trinuclear Oxo-Centered Manganese Complexes of the General Formulation (Mn30(02CR)6L3)09+ (R = Me or Ph; (1987) (7)
Hindered ligand systems. VIII. Syntheses of the iron(III), cobalt(III), and nickel(II) compounds of cis,cis-1,3,5-tris(salicylaldimino)cyclohexane and the crystal and molecular structure of the cobalt(III) complex (1975) (7)
Silyl reagents (Me3Si-X) efficiently transfer X to Ir(H)2F(PtBuP2Ph)2 (1998) (7)
The tungsten-tungsten triple bond. 19. Preparation and characterization of W26+-containing compounds supported by amide/alkoxide and trifluoromethanesulfonate ligands (1992) (7)
Reactions of Mo2(OR)6 (M.tplbond.M) compounds (R = iso-Pr and tert-Bu) with benzoyl peroxide (1983) (7)
Structure of chlorotris(triphenylphosphine)copper(I)–tetrahydrofuran (1/3) (1987) (7)
Isolable paramagnetic hydride complexes of niobium(IV) and tantalum(IV) (1984) (6)
The tungsten-tungsten triple bond. 11. Ligand redistribution reactions involving chloride and dimethylamide ligands at dimolybdenum and ditungsten (M.tplbond.M) centers induced by added tertiary phosphines. Preparations and characterizations of W2Cl2(NMe2)4(Me2PCH2PMe2), W2Cl3(NMe2)3(PMe2Ph)2, and W (1985) (6)
Diamagnetic anisotropy of MM bonded molecules for MMo or W: how much π is there and how do we slice it? (1987) (6)
Synthesis and characterization of VCl3(PMePh2)2 (1985) (6)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 9. α-DIKETONE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES: W2(OR)6(O2C2R′2)2 (M-M) (1984) (6)
Carbonylation of (ButO)3W≡CNMe2 and (PriO)3(py)2W≡CNMe2 (py=pyridine): two different modes of carbon−carbon bond formation (1986) (6)
Synthesis and reactivity of compounds of formula W(S)(OR)4 (1987) (6)
METAL‐METAL BONDED COMPLEXES OF THE EARLY TRANSITION METALS: SYNTHESIS OF A BINUCLEAR TANTALUM(III) TRIMETHYLPHOSPHINE COMPLEX AND ITS REACTIONS WITH HYDROGEN AND ETHYLENE (1981) (6)
THE SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURE OF ANTI-W2(GEPH3)2(NME2)4 (1991) (6)
HYBRID PHOSPHINE-CROWN ETHER LIGANDS: THE STUDY OF BENZO-15-CROWN-5 AND N-PHENYLAZA-15-CROWN-5 AND -18-CROWN-6 FUNCTIONALIZED WITH Ph2P- (1995) (6)
Mechanism of the carbonylation of dicyclopentadienylmolybdenum dihydride (1979) (6)
Reactivity of a bridging sulfhydryl ligand, S-alkylation of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu.-S)(.mu.-SH)(.mu.-O2CCF3), and structure of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu.-S)(.mu.-SCH3)(.mu.-O2CCF3) (1984) (6)
Synthesis and crystal structure of a covalently hydrated 8-thia-1,4-diazacycl[3.3.2]azine (1979) (6)
Non-quassinoid constituents from the twigs and thorns of Castela polyandra. (1999) (6)
W2(n-Pr)2(.eta.2-C2Me2)2(O-iso-Pr)4, W2(.mu.-C2Me2)2(O-iso-Pr)4, and W4(.mu.-CEt)2(.mu.-C2Me2)2(.eta.2-C2Me2)2(O-iso-Pr)6. Competitive .alpha.- and .beta.-carbon-hydrogen activation pathways at a dimetal center (1987) (6)
Cyclotantalation of 2,6-diphenylphenoxide; x-ray crystal structure of Ta(OC6H3PhC6H4)(OAr-2,6Ph2)2Me (1988) (6)
A skewed bridging alkyne adduct of a d3-d3 tungsten dimer: W2(.mu.-NMe2)2(.mu.-C2Me2)Cl4(py)2 (1985) (6)
Mo(NMe2)6Li2(THF)2 (1988) (6)
Metal alkoxides - models for metal oxides. 1. Preparations and structures of hexadecaalkoxytetratungsten compounds, W4(OR)16, where R = Me and Et, and octaoxotetraisopropoxytetrapyridinotetramolybdenum, Mo4(O)4(.mu.-O)2(.mu.3-O)2(O-i-Pr)2(.mu.-O-i-Pr)2(py)4 (1981) (6)
A heterometallic alkoxide combining hard and soft Lewis acids (Et3PO)2 Ba2Cu4(OtBu)8 (1997) (6)
A linear trinuclear chromium(III) complex with mixed thiolate/alkoxide ligation: Preparation and properties of (PPh4)2(Na)[Cr3(SCH2CH2O)6] (1991) (6)
Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum (M.tplbond.M) (1982) (6)
The chemistry of transition metal–germanium compounds. Part 2. Synthesis, characterization, structure and reactivity of transition-metal carbonyl-substituted germacyclopent-3-enes (1991) (6)
The synthesis and crystal structures of triphenyl(1,2,3-trimethylallyl)tin and triphenyl( 1,1,2-trimethylallyl)tin (1987) (6)
The molybdenum-molybdenum triple bond. 10. Bis(1,3-diphenyltriazenido)- and bis(2-oxy-6-methylpyridino)tetraisopropoxydimolybdenum (1981) (6)
MOLECULAR STRUCTURE OF MO(NC6H4CH3)(S2P(OC2H5)2)3, A COMPOUND WITH A DANGLING DITHIOPHOSPHATE LIGAND (1982) (6)
Synthetic studies on quassinoids: one-step transformation of .alpha.-hydroxy ketones into O-methyl-protected diosphenols (1981) (6)
Preparation, structure, and properties of [NEt4][Mn(edt)2(Him)](H2edt = ethane-1,2-dithiol; Him = imidazole), a mononuclear manganese(III) thiolate possessing a rare manganese(III)-imidazole bond (1985) (6)
Twelve-electron tetranuclear tungsten alkoxide clusters are not tetrahedral. Preparation, structure and bonding in W4(O)(OPri)10 and W4(O)(Cl)(OPri)9. Comparisons with the bonding in carbonyl clusters (1990) (6)
All in a day's work: advancing data-intensive research with the data capacitor (2006) (6)
[As7Cr(CO)3]3⊖ aus As 73⊖ – eine anorganische Nortriclan‐Norbornadien‐Umwandlung (2006) (6)
Bis(dimethylamine)tetrakis(tert-butylmercaptido)di-.mu.-sulfido-dimolybdenum(IV) (1982) (6)
1,3-Ditungstacyclobutadienes. 4. 1:1 Diphenyldiazomethane adducts W2(.mu.-CSiMe3)2X4.cntdot.(N2CPh2). A comparison of the effects of the supporting ligands, X = (trimethylsilyl)methyl versus isopropoxyl (1989) (6)
Mo3[C(O)NMe2]6(CO)6(HNMe2)2. An unexpected product formed in the carbonylation of Mo(NMe2)4 displaying three distinct modes of carbamoyl molybdenum bonding (1987) (5)
COUPLING OF ACYL AND IMINOACYL GROUPS ON ZIRCONIUM AND Σ2,Π-COORDINATION OF THE RESULTING ENAMIDOLATE LIGAND (1985) (5)
The tellurium analogue of the hydroxide ion: Syntheses and structure of (PPh4)TeH (1989) (5)
Polynuclear metal hydrido alkoxides. Preparation and characterization of Mo4(µ-H)3(OBut)7(HNMe2) and [K(18-crown-6)][Mo4(µ4-H)(OR)12] (R = Pri or CH2But) (1998) (5)
A single bond covalent radius for IrIII: Crystal and molecular structure of fac-Ir(CH3)3(PMe2Ph)3 (1988) (5)
Evaluation of energies of isomeric SO2 complexes (2003) (5)
1,2-dimetallacyclo-1,2-hexyne compounds of molybdenum and tungsten (1985) (5)
Crystal structure of tridecaborane(19) (1973) (5)
Tetranuclear molybdenum compounds containing a .mu.4-disulfide linkage (1988) (5)
Further Studies on the Substitutional Behavior of 1,2-Mo2Br2(CH2SiMe3)4. Alkyl, Amide, Phosphide, Alkoxide, and Thiolate for Bromide Exchange and Isomerizations of 1,1- and 1,2-Mo2X2(CH2SiMe3)4 Compounds† (2000) (5)
Synthesis and Properties of Phenyl Phosphines with Meta-Positioned Methyl Groups and the X-ray Structure of Tris(3,5-dimethyl-4-methoxyphenyl)phosphine (2000) (5)
Structure, synthesis, and characterization of chiral secondary diphosphine platinum(II) mono- and dimeric complexes: molecular structure of [Pt2Cl4(SMe2)2{(R*,R*)-.mu.-HtBuPCH2PtBuH}] (1989) (5)
Reversible carbon-hydrogen bond oxidative addition across a W—W multiple bond (1997) (5)
4′ DIPHENYLPHOSPHINO AND BROMO DERIVATIVES OF 10-PHENYL-1,4,7-TRITHIA-10-AZA-CYCLODODECANE 4-R- C6H4 N(CH2CH2S)2CH2CH2SCH2CH2 (1997) (5)
A study of the reaction between Mo2(OCH2CMe3)6(μ-η1,η2-NCNR2) compounds (R = Me and Et) and 2-butyne (1988) (5)
Photochechemistry of transition-metal polyhydrides: dimerization of OsH4 (PMe2Ph)3 following photodissociation of dihydrogen (1983) (5)
An organoimido molybdenum(VI) complex: preparation and structure of (p-tolylN)-MoCl4(thf) (1984) (5)
Synthesis and crystal structure of B10H10(C6H11)S(CH3)2CNH(tert-C4H9) (1987) (5)
Diastereoselective sulfur ylide promoted aldol/epoxidation (2006) (5)
Monoindenyl titanium alkyl halides. The synthesis and molecular structures of (η5-C9H7)TiBr3, (η5-C9H7)Ti(CH3)Br2, and (η5-C9H7)Ti(CH3)Cl2 (1999) (5)
The tungsten-tungsten triple bond. 9. Bis(1,3-diphenyltriazenido)tetrakis(dimethylamido)ditungsten (1979) (5)
Synthesis and preliminary characterization of new conducting salts derived from bis(ethylenedithio)tetraselenafulvalene (BETS) (1997) (4)
Addition of diphenyldiazomethane to hexa-alkoxydimolybdenum(MM) compounds: characterization of Mo2(OPri)6(N2CPh2)2(pyridine) by X-ray crystallography (1981) (4)
Conventional Lithium Bases as Unconventional Sources of Methyl Anion: Facile Me−Si and Me−C Bond Cleavage in RLi, R2NLi, and BR4-by an Electrophilic Osmium Dihydride (2002) (4)
Coupling C≡C, C≡N, and W≡W bonds. Preparation, and crystal and molecular structure of hexaneopentoxy(pyridine)[2-amido(2―)-W1,W1-5-amido(2-)-W2-3,4-dimethylhexa-2,4-diene]ditungsten W2(OCH2But)6-(py)(N[CMe]4N) (1983) (4)
THE SCHMIDT REACTION ON 3A,4,5,6-TETRAHYDROSUCCINIMIDO(3,4-B)ACENAPHTHEN-10-ONE AND ITS ALKYLATED DERIVATIVES (1981) (4)
Instruments and Sensors as Web Services (2004) (4)
Some studies of the substitution chemistry of [Rh2(OAc)2(CH3CN)4][BF4]2 with monodentate and bidentate tertiary phosphines (2000) (4)
W2Cl3(NMe2)3(PMe2Ph)2 and its reaction with ethyne to give (PMe2Ph)Cl2W(µ-NMe2)(µ-σ,η2–CHCH2)(µ-η2,σ-CH2NMe)WCl(NMe2)(PMe2Ph): a compound containing an azadimetallabicyclobutane core and a σ,π-vinyl ligand (1985) (4)
Structure of 1,4,7,10,13-pentaoxa-16-thiacyclooctadecane at 101 K (1981) (4)
Synthesis and characterization of seven-co-ordinate TaX(CO)3(PMe3)3 complexes (X = Cl, Br, I) (1985) (4)
Cyclobutene derivatives as isoprene equivalents in terpene synthesis. 3. Bicyclo[2.2.0]hexanes (1979) (4)
Structure and reactions of a thiazolino[3,2‐a]pyrimidine carbinolamine (1981) (4)
Heterobimetallic Carbon Monoxide Hydrogenation: Hydrogen Transfer to Coordinated Acyls: The Molecular Structure of (C5H5)2Re[(C5H5)2ZrCH3](OCHCH3) (1981) (4)
Metal alkoxides: models for metal oxides. 14. Carbonylation of an ethylidyne-capped tritungsten alkoxide cluster to form W3(.mu.-CMe)(OCHMe2)9(CO)2: preparation, properties, and structure (1989) (4)
Synthesis of Zr-Re-containing polyhydrides by amine elimination (1989) (4)
Spectroscopic study of dehydrochlorination and exchange with D{sub 2} in WH{sub 2}Cl{sub 2}(PMe{sub 2}Ph){sub 4}: Unexpected stereochemical rigidity of dodecahedra containing both hydride and chloride ligands. Crystal and molecular structure of W(H){sub 3}({eta}{sup 2}-C{sub 6}H{sub 4}PMe{sub 2})(PM (1994) (4)
Synthetic studies toward quassinoids: anomalous results from the metal-ammonia reduction of phenanthrenone derivatives (1985) (4)
Preparation and Molecular Structure of the Unconventional Tantalum Chloride Complex [(eta(5)-C(9)H(7))(2)TaCl(2)][TaCl(6)]. (1997) (4)
The tungsten-tungsten triple bond. XV. Synthesis, structure and reactivity of 1,2-W2[CH(SiMe3)2]2(NMe2)4: the remarkable inertness of a sterically-encumbered tungsten-amido complex (1988) (4)
Single-Molecule Magnets: Preparation and Properties of Mixed-Carboxylate Complexes [Mn12O12(O2CR)8(O2CR')8(H2O)4] (2001) (4)
The molybdenum-molybdenum triple bond. 6. Bis(2-oxy-6-methylpyridine)tetrakis(dimethylamido)dimolybdenum (1981) (4)
6,7-Dihydro-5-[[(cis-2-hydroxy-trans-3-phenoxycyclopentyl)amino] methyl]-2-methylbenzo[b]thiophen-4(5H)-one: a novel alpha 1-adrenergic receptor antagonist and renal vasodilator. (1985) (4)
Modelling the Photosynthetic Water Oxidation Center: Preparation and Physical Properties of a Tetranuclear Oxide Bridged Mn Complex Corresponding to the Native S2 State. (1988) (4)
Crystal and molecular structure of Mo6O10(OPri)12: a serpentine chain of molybdenum atoms and observation of semibridging alkoxy-ligands (1982) (3)
Preparation and characterization of mixed amido-phosphido compounds of molybdenum(IV). A comparison of π-donating ligands in Mo(NMe2)4, Mo(PCy2)4 and [Mo(NMe2)2(PPh2)2] based on X-ray studies (1989) (3)
Carbon-carbon coupling of a .mu.-ethynyl ligand with an isocyanide at a ditungsten center. Preparation and structure of W2(.mu.-CCCNHXyl)(OSiMe2But)5(CNXyl)4, where Xyl = 2,6-Me2C6H3 (1993) (3)
A diiron-ditungsten cluster supported by carbonyl and alkoxide ligands: Fe2W2(OPri)6(CO)5(py) (1989) (3)
d3–d3 Diolates of dimolybdenum and ditungsten: Part 4. Molybdenum derivatives of S(−)-1,1-diphenyl-1,2-propanediol, S(−)-1,1,2-triphenyl-1,2-ethanediol and (1R, 2R)-(−)-1,2-dicyclohexyl-1,2-ethanediol (2000) (3)
Extending the family of reduced [Mn12O12(O2CR)16(H2O)x]n− complexes, and their sensitivity to environmental factors (2020) (3)
A new structural type in iron carboxylate cluster chemistry via use of bis-bipyridine ligands: [Fe6O4Cl4(O2CPh)4L2][FeCl4]2 (1998) (3)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 13. REACTIONS OF DIAZOALKANES WITH HEXAALKOXIDES OF DIMOLYBDENUM AND DITUNGSTEN (MM). PREPARATION AND CHARACTERIZATION OF MO2(O-ISO-PR)6(N2CPH2)2(PY), W2(O-TERT-BU)6(N2C(P-TOL)2)2, AND MO(O-TE (1984) (3)
Paramagnetic 1,3-dimetallacyclobutadienes of tungsten(VI): -2,4-bis(trimethylsilyl)-1,3-dihalogeno-l,1,3,3-tetrakis(trimethylsilylmethyl)-1,3-ditungstacyclobutadienes (1985) (3)
A novel synthetic route to 1,2‐dimethyl‐5‐phenyl‐1H‐imidazo[4,5‐b]pyridin‐7‐ol (1990) (3)
A NEW BORON HYDRIDE, TETRADECABORANE(20) (1975) (3)
Structure, synthesis and characterization of chiral, phosphido-phosphine, diphosphine platinum(II) mono- and dimeric complexes: The molecular structure of both [PT2Cl3{(R*)-μ-iPrPCH2PiPr2}{(R*)-HiPrPCH2PiPr2}] and [PT2Cl3{(R*)-μ-iPrPCH2PiPR2}{(S*,S*)-μ-HiPrPCH2PiPrH}] (1989) (3)
MOLECULAR STRUCTURE AND SOLUTION DYNAMICS OF (η5-C5H5)NI(PPH3)S2COC2H5 (1980) (3)
Comments on the Molecular Structure and Bonding In [W4Cl(O)(OiPr)9] and [W4(O)(OiPr)10]. Analogies with Tetranuclear Carbonyl Clusters (1989) (3)
Modelling the Photosynthetic Water Oxidation Center. Preparation and Properties of Tetranuclear Manganese Complexes Containing (Mn4O2)6+,7+,8+ Cores and the Crystal Structures of Mn4O2(O2CMe)6(bipy)2 and (Mn4O2(O2CMe)7(bipy)2)(ClO4). (1989) (3)
A tetranuclear tungsten carbido alkoxide cluster with a hydride ligand: W4(μ-C)(NMe)(OCH2But)11(H) (1993) (3)
Carbonylation of [.eta.6-C6(CH3)6]Mn(CO)2H (1986) (3)
Synthesis and structure of (PPh4)2Na[Cr3(SCH2CH2O)6] containing a linear chromium(III) trimer with terminal thiolate and bridging alkoxide linkages (1985) (3)
Searching for transition metal coordination compounds, which complex carbohydrates in water solution; synthesis, X-ray crystal structure and u.v.-vis. spectra of oxo-bis[bis-acetonitriletrichlororuthenium] (1995) (3)
ADDITION OF ALKYNES TO HEXAALKOXYDIMOLYBDENUM (MM) COMPOUNDS AND STRUCTURE OF μ-ETHYNE-HEXAISOPROPOXYDIPYRIDINODIMOLYBDENUM (1981) (3)
Cationic d3-d3 dinuclear compounds of tungsten: [W2(O2CBut)5]+X−, where X−=BF4− and CF3SO3− (1993) (3)
The chloromethylation of 1-bromo-2-methoxynaphthalene. A revised structure for the product (1984) (3)
Nature of the phase change in solid bis(isopropyl alcohol)octakis(isopropoxo)dicerium, as determined by variable-temperature x-ray diffraction and deuterium NMR spectroscopy (1991) (3)
Quantitative formation of coordinated hydroxamate (2−) ligands by attack of perfluorocarboxylic acids on [Os(NO)2(PPh3)2]; the X-ray crystal structure of [Os{ON:C(O)CF3}(O2CCF3)(NO)(PPh3)2] (1982) (3)
W3(O-i-Pr)9(Cl)2(.mu.3-CMe). An unexpected mode of .mu.3-ethylidyne bonding and dynamic solution behavior (1988) (3)
A New Active Catalyst Species for Enantioselective Alkylation by Phase- Transfer Catalysis. (1994) (3)
Octakis(trimethylsilylmethyl)dioxotetramolybdenum. A novel tetranuclear compound with two localized metalmetal triple bonds (2000) (2)
A reaction converting a w-w triple bond to a double bond: tetrakis-diethyldithiophosphate-disulfide-ditungsten, preparation and characterization (1987) (2)
Conducting salts of the new donor bis(ethylenedithio)tetrathionaphthalene (EDNA) (1999) (2)
REACTIVITY OF A BRIDGING SULFHYDRYL LIGAND, S-ALKYLATION OF (MO(NC6H4CH3)(S2P(OC2H5)2))2(μ-S)(μ-SH)(μ-O2CCF3), AND STRUCTURE OF (MO(NC6H4CH3)(S2P(OC2H5)2))2(μ-S)(μ-SCH3)(μ-O2CCF3) (1984) (2)
BIS(BENZYLBIS(DIMETHYLAMIDO)MOLYBDENUM) AND -TUNGSTEN (MM) COMPOUNDS AND THEIR REACTIONS WITH CARBON DIOXIDE AND 1,3-DIARYLTRIAZENES. A RADICAL DIFFERENCE (1982) (2)
A Cu ‐ (μ‐H) Bond Can Be Stronger Than an Intramolecular P→Cu Bond. Synthesis and Structure of Cu2(μ‐H)2(η2‐CH3C(CH2PPh2)3)2. (1986) (2)
Reaction of Ninhydrin with β-Dicarbonyl Compounds. (2010) (2)
Potential Building Blocks for Molecular Ferromagnets: (Mn12O12(O2CPh)16(H2O)4) with a S = 14 Ground State. (1989) (2)
The molecular structure of [Mo(S2P(OEt)2)3]2(μ-p-NC6H4N), a derivative of p-phenylenediamine (1984) (2)
Molecular Routes to Tin Oxides (1992) (2)
Preparation and Characterization of NaW2Cl7(THF)5. A Synthetically Useful Precursor for X3WWX3 Compounds Where X: CH2-tBu, NMe2, and O-t-Bu. (1988) (2)
SILICON IN SYNTHESIS. 19. 1-(TRIMETHYLSILYL)-1-(PHENYLTHIO)ETHYLENE AND 1-(TRIMETHYLSILYL)-2-(PHENYLTHIO)ETHYLENE: REAGENTS FOR THIOPHENYL-FUNCTIONALIZED CYCLOPENTENONE ANNULATIONS (1982) (2)
Single-molecule magnets: ligand-induced core distortion and multiple Jahn-Teller isomerism in [Mn(12)O(12)(O(2)CMe)(8)(O(2)PPh(2))(8)(H(2)O)(4)]. (2001) (2)
Facile Olefin Hydrogenation with an Osmium Dihydrogen Complex. (1989) (2)
Integral heats of solution of some electrolytes and water in ethylenediamine at 25.00.deg.C (1969) (2)
Regiochemical and mechanistic studies of the addition of tin hydride and oxide to substituted ketenes (1990) (2)
Stepwise reductive acidolysis of OsH4(PMe2Ph)3: mechanism of hydrogen elimination/ligand addition (1984) (2)
Synthesis and Study of Triphenylphosphines Functionalized at the 4-Positions through the Nitrogen Atoms in 1,4,7,10-Tetraoxa-13-azacyclopentadecane and the X-ray Structure of the Oxide of the Molecule Substituted at All Three Positions (2001) (2)
Unexpected products formed by the addition of halogens [X2 (= I2 or Br2)] to W2(O2CBut)4 (MM): The x=ray crystal structures of [W2(O2CBut)5·2ButCONMe2]+[W2I4(O2CBut)2]− and W2Br2(O2CBut)3·2THF (1986) (2)
Synthesis and characterization of bis(neopentyl)-tetrakis(acetato)dimolybdenum. A notably short metal-metal distance for a d3-d3 dinuclear compound containing a M-M triple bond of valence molecular orbital configuration π4 δ2 (1986) (2)
Hafnium halide compounds of methyl substituted allyl ligands. Synthesis, crystal structure and dynamics of (η5-C5Me5)(η3-1,2,3-Me3allyl)HfBr2 and (η5-C5Me5)(η3-1,1,2-Me3allyl)HfBr2 (1991) (2)
Structural changes upon oxidation of a linear, trinuclear iron-molybdenum complex (1994) (2)
COULD ONE HAVE FIVE? THE SYNTHESIS AND STRUCTURE OF RE2H4(PME2PH)4(P(OCH2)3CET)2 AND ITS CONJUGATE ACID (1982) (2)
Crystal Structures of Potassium Tetratellurite, K2Te4O9, and Potassium Ditellurite, K2Te2O5, and Structural Trends in Solid Alkali Tellurites. (1998) (2)
An osmium hydrido methyl species via an unconventional methyl transfer (2000) (2)
An Unbridged Triple Bond Uniting d6 Mo(0) and d2 Mo(IV) Atoms: Mo2(O-iPr)4(dmpe)2. (1987) (2)
Molecular structure of an extremely crowded iron(II) dihydride complex: FeH2(PMePh2)4 (1984) (2)
Additions and Corrections - Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II), Structural and Spectroscopic Evidence for Molybdenum-to-Bipyridyl π* Bonding (1983) (2)
PREPARATION AND CHARACTERIZATION OF 1,2-DIALKYL COMPOUNDS OF DIMOLYBDENUM AND DITUNGSTEN OF FORMULA M2R2(NME2)4 (MM) (1981) (2)
Synthesis and crystal and molecular structure of Mo4O(OCH2But)10(py): A 12-electron butterfly cluster (1992) (2)
Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(μ4-C)(OCH2-c-C5H9)14 (1990) (2)
METAL ALKOXIDES MODELS FOR METAL OXIDES. 5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES: AN ALTERNATIVE TO THE METATHESIS REACTION MM + CC- → 2MC (1985) (1)
Di--chloro-bis[chloro(? 5 -indenyl)methylhafnium(IV)] (1998) (1)
Syntheses and Structures of a Series of Very Low Coordinate Barium Compounds: Ba(N(SiMe3)2)2(THF)2, (Ba(N(SiMe3)2)2(THF))2, and (Ba(N( SiMe3)2)2)2. (1991) (1)
Reactivity of the Molecular Hydrogen Complex (IrH4(PMe2Ph)3)BF4 Toward Olefins. The Origin of Stereochemical Rigidity of M(PR3)3(olefin)2 Species. (1990) (1)
Pyrido(2′,1′:2,3)imidazo(4,5-c)isoquinoline and the Alkylation of Pyrido(2′,1′:2,3)imidazo(4,5-c)isoquinolin-5(6H)-one. (1988) (1)
Metal-Metal Multiple Bonds. Part 17. Syntheses, Structures, and Molecular Orbital Analysis of Hydridotris(pyrazolyl)borate (Tp) Molybdenum Carbonyls: Paramagnetic TpMo(CO)3and Triply Bonded Tp2Mo2(CO)4(Mo ≡ Mo). (1986) (1)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 10. REACTIONS OF MO2(OR)6 (MM) AND (MO(OR)4)X COMPOUNDS WITH MOLECULAR OXYGEN. PREPARATION AND CHARACTERIZATION OF OXO ALKOXIDES OF MOLYBDENUM: MOO2(OR)2, MOO2(OR)2(BPY), MOO(OR)4, MO3O(OR)10, (1984) (1)
SYNTHESIS AND CRYSTAL STRUCTURE OF A COVALENTLY HYDRATED 8-THIA-1,4-DIAZACYCL(3.3.2)AZINE (1979) (1)
INSERTION REACTIONS OF HEXAALKOXYDIMOLYBDENUM AND -DITUNGSTEN COMPOUNDS WITH ORGANIC ISOCYANATES. SYNTHESES AND STRUCTURES OF W2(OCME3)4(N(C6H5)C(O)OCME3)2 AND MO2(O-I-PR)4(N(C6H5)C(O)O-I-PR) (1985) (1)
Chemical Vapor Deposition of Binary Metal Germanides (1990) (1)
Reinvestigation of a 5H-Dibenzo(d,h)(1,3,6)triazonine Synthesis. (1990) (1)
A NEW STRUCTURE TYPE FOR A 6-ELECTRON TRIANGULO TUNGSTEN CLUSTER: W3(μ3-CME)(μ-O-ISO-PR)3(O-ISO-PR)6 (1985) (1)
Synthesis and Structural Characterization of (Re2(μ-O)2O2(CH2CMe3)4) and the Li+ and (NEt4)+ Salts of the d2(ReO2(CH2CMe3)2)- Anion. (1988) (1)
Room Temperature Ring-Opening Metathesis of Pyridines by a Transient Ti⋮C Linkage [J. Am. Chem. Soc. 2006, 128, 6798−6799]. (2007) (1)
The first example of a d3–d3 dinuclear compound containing four-co-ordinate metal atoms sharing a pair of bridging ligands: [(ButO)2W(µ-PPh2)]2 (1987) (1)
Alcohol Elimination Chemistry of (CuOtBu)4. (1991) (1)
The structural relationship of phorbol and cortisol: A possible mechanism for the tumor promoting activity of phorbol (1976) (1)
Crystal Structure and Sodium Environments in Sodium Tetratellurite, Na2Te4O9, and Sodium Tellurite, Na2TeO3, by X-Ray Crystallography and Sodium-23 NMR. (1995) (1)
CHEMISTRY OF STERICALLY CROWDED ARYLOXIDE LIGANDS. 4. SYNTHESIS AND STRUCTURE E OF MIXED CHLORO ARYLOXIDES OF TANTALUM (1984) (1)
Reinvestigation of a 5H‐dibenzo[d,h][1,3,6]triazonine synthesis (2009) (1)
TRANSITION METAL HYDRIDES AS ELECTRON DONORS. FORMATION, DETECTION, AND DIMERIZATION OF TRANSIENT, PARAMAGNETIC RADICAL CATIONS FROM THE ELECTROCHEMICAL OXIDATION OF TUNGSTENOCENE HYDRIDES AND THE CRYSTAL STRUCTURE OF THE BINUCLEAR (C (1980) (1)
Uranium Alkoxide Chemistry. Part 1. Synthesis and the Novel Dimeric Structure of the First Homoleptic Uranium(III) Aryloxide Complex. (1988) (1)
A New Fluorinated Tetraalkoxide Ligand Derived from the Hydration of Hexafluoroacetylacetone. (1993) (1)
Isolation and Structure of (V(OSiMe3)(edt)2)- (edt2-: Ethane-1,2-dithiolate), an Intermediate in the Conversion of (VO(edt)2)2- to (VS(edt)2)2- with (Me3Si)2S. EPR Characterization of the Series (VE(LL)2)z- (E: O, S, OSiMe3, LL: edt; (1987) (1)
METAL ALKOXIDES: MODELS FOR METAL OXIDES. 4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES: W2(μ-C2H2) ⇌ 2WCH (1985) (1)
ALUMINUM ALKYLS AND TRANSITION METAL HYDRIDES: “NONCLASSICAL” ADDUCT STRUCTURE AND CATALYSIS OF HYDROGEN MIGRATION (1984) (1)
A Comparison of Teacher and Student Absenteeism in Three School Districts of Different Size (1984) (1)
Tungsten - Tungsten Triple Bond. Part 12. Bis(1,3-diaryltriazenido)bis(dimethylamido)diethylditungsten (M ≡ M) Compounds. (1986) (1)
INCORPORATING METAL-METAL MULTIPLE BONDS INTO HETEROMETALLIC CHAINS: BIS(TRIS(TRIMETHYLSTANYL)TIN)TETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM AND -DITUNGSTEN AND RELATED COMPOUNDS (1983) (1)
IRIDA-, RHODA-, NICKELA-, AND CUPRAPENTABORANES DERIVED FROM THE ARACHNO-(B4H9)- ION. CRYSTAL STRUCTURE OF (IR(η4-B4H9)(CO)(P(CH3)2C6H5)2), AN ANALOG OF ARACHNO-B5H11 AND (IR(η4-C4H6)(CO)(P(CH3)2C6H5)2)+ (1985) (1)
Intramolecular Coupling of η2-Iminoacyl and η2-Acyl Functions at Group 4 and Group 5 Metal Centers: Structure and Spectroscopic Properties of the Resulting Enamidolate and Enediamide Complexes. (1988) (1)
Primary Steps in the Hydrolyses of Two Heterometallic Alkoxides. Characterization of (LiTiO(OiPr)3)4 and BaZr4(OH)(OiPr)17 (1993) (1)
Preparation, Structure, and Magnetochemistry of Hexanuclear Manganese Oxide Complexes: Chemically and Thermally Induced Aggregation of Mn3O(O2CPh)6(py)2(H2O) Forming Products Containing the (Mn6O2)10+ Core. (1989) (1)
The John-e-Box: fostering innovation, inclusion, and collaboration through accessible advanced visualization (2005) (1)
Reactions of Metal-Metal Multiple Bonds. Part 15. Reactions of M2(OR)6(MM) Compounds (M: Mo, W) with 9,10-Phenanthrenequinone and Tetrachloro-1,2-benzoquinone. (1988) (1)
Trimethylphosphine Adduct of the Zirconocene-Benzyne Complex: Synthesis, Reactions, and X-Ray Crystal Structure. (1987) (1)
New Methodology for the Synthesis of α,α-Dialkylamino Acids Using the “Self-Regeneration of Stereocenters” Method: α-Ethyl-α-phenylglycine. (1998) (1)
Synthesis and Reactivity of a Heterometallic CO2 Complex. (1990) (1)
NEW METHODOLOGY FOR THE SYNTHESIS OF ALPHA ,ALPHA -DIALKYLAMINO ACIDS USING THE SELF-REGENERATION OF STEREOCENTERS METHOD : ALPHA -ETHYL-ALPHA -PHEN YLGLYCINE (1997) (1)
Synthesis of Helical Poly-β-pyrroles. Multiple Atropisomerism Resulting in Helical Enantiomorphic Conformations. (1990) (1)
Reactions Involving Carbon Dioxide and Mixed Amido-Phosphido Dinuclear Compounds: M2(NMe2)4(PR2)2(MM), Where M: Mo and W. Comparative Study of the Insertion of Carbon Dioxide into Metal-Nitrogen and Metal-Phosphorus Bonds. (1990) (0)
THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 13. PREPARATIONS AND CHARACTERIZATION OF BIS(β-DIKETONATO)TETRAALKOXYDIMOLYBDENUM AND -DITUNGSTEN COMPOUNDS (1984) (0)
Synthesis of Quinuclidine-Benzyl(ethylcarbamoyl)borane: The First Boron Analogue of a Phenylalanine Derivative. (1989) (0)
Synthesis, Structure, and Bonding of Mononuclear Aryloxide Derivatives of Niobium in Oxidation States +5, +3, +2, and +1. (1989) (0)
Alcoholysis of Titanium Alkoxides by Fluoro Alcohols. Synthesis, Characterization, and X‐Ray Crystal Structure of (Ti(O‐i‐Pr)2(OCH(CF3) 2)2)2. (1993) (0)
Structure, Synthesis and Characterization of Chiral, Phosphido-Phosphine, Diphosphine Platinum(II) Mono- and Dimeric Complexes: The Molecular Structure of Both (Pt2Cl3((R*)-μ-iPrPCH2PiPr2)((R*)-HiPrPCH2PiPr2)) and (Pt2Cl3((R*)-μ-iPrPC (1990) (0)
Oxotrimolybdenum (IV) Alkoxides: Mo3(micron 3-O)(micron 3-OR)(micron 2-OR)3(OR)6, Where R = i-Pr and CH2CMe3 - from Serendipitous Discovery to Total Synthesis. (1981) (0)
Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(O-iPr)6 and W4(O-iPr)12. Part 1. Preparation, Structure, and Bonding. The First Example of a Metal-Metal Triple Bond and Its 12-Electron Cluster. Analogies with Ethyne and (1988) (0)
Crystal Structure and Magnetic Susceptibility of the Dinuclear Manganese(IV) Complex Mn2O2(pic)4·MeCN (picH: Picolinic Acid). (1990) (0)
Contributions to the Chemistry of Boron. Part 75. The Crystal and Molecular Structure of a Tetraazadiborine: 3,6-Bis(dimethylamino)-l,2,4,5-tetramethyl-l,2,4,5,3,6-tetraazadiborine. (1976) (0)
A fluorobenzene adduct of Ti(IV), and catalytic carboamination to prepare alpha,beta-unsaturated imines and triaryl-substituted quinolines. (2005) (0)
The Synthesis and Crystal Structures of Triphenyl(1,2,3-trimethylallyl)tin and Triphenyl(1,1,2-trimethylallyl)tin. (1988) (0)
Carbon-Nitrogen Bond Formation in the Reactions of Unsaturated Molecules with Mo(NMe 2 ) 4 (1987) (0)
Preparation and Structure of (NEt4)2(V4S2(SCH2CH2S)6) and Its Structural and Electronic Relationship to the LixVS2 Phases. (1987) (0)
Synthesis of Polyhedral Phosphaboranes. Crystal Structure of 6-(C2H5)3N·2 PB9H8. (1989) (0)
METAL ALKOXIDES - MODELS FOR METAL OXIDES. 6. THE LINKING OF ALKYNE AND NITRILE FRAGMENTS AT DITUNGSTEN CENTERS. PREPARATION AND CHARACTERIZATION OF W2(O-TERT-BU)6(CHCHC(PH)N), W2(O-ISO-PR)7(CH2CHC(PH)N), W2(OCH2-TERT-BU)6(N(CME)4N)(P (1985) (0)
Heterocycles. Part 10. A Facile Synthesis of 7-Hydroxy-6,7-dihydro-5H- pyrrolo(1,2-a)imidazole. (1988) (0)
Diastereoselective Sulfur Ylide Promoted Aldol/Epoxidation. (2007) (0)
PREPARATION AND X-RAY STRUCTURE OF THE N-BENZYL DERIVATIVE OF 10-AZA-7,8-DICARBA-NIDO-UNDECABORANE(II) (1976) (0)
INTRAMOLECULAR ADDITION OF AN ALIPHATIC CARBON-HYDROGEN BOND TO A TANTALUM-CARBON DOUBLE BOND (1983) (0)
SYNTHESIS OF (.+‐.)‐10,22‐DIOXOKOPSANE AND (.+‐.)‐KOPSANONE, HEPTACYCLIC INDOLE ALKALOIDS. SYNTHETIC AND MECHANISTIC STUDIES (1984) (0)
Preparation, structure, and chemistry of (O-acyl imidato)- and (O-alkyl imidato)carbene pentacarbonyl complexes of chromium [Erratum to document cited in CA111(13):115462e] (1990) (0)
BOROHYDRIDE/ETHANOL REDUCTION OF TRIS(DIMETHYLPHENYLPHOSPHINE)TRICHLORORUTHENIUM (1985) (0)
Synthetic Studies Toward Quassinoids: Anomalous Results from the Metal- Ammonia Reduction of Phenanthrenone Derivatives. (1986) (0)
Highly Cooperative Valence Detrapping of Mixed-Valence (Mn3O(O2CCH3)6(py)3)(py) in the Solid State. (1990) (0)
CALORIMETRY IN ANHYDROUS ETHYLENEDIAMINE. Progress Report (1966) (0)
The Photosynthetic Water Oxidation Center : Spin Frustration in Distorted Cubane Mn 1 VMn 1113 Model Complexes (2001) (0)
Heavier Main-group Atoms as Ligands to Transition-metal Centers (1987) (0)
SC|07 Bandwidth Challenge award-winning project: Using the Data Capacitor for Remote Data Collection, Analysis, and Visualization (2007) (0)
PARTIAL HYDROLYSIS OF (MO(NR)(μ3‐S)(S2P(OR′)2))4 AND MOLECULAR STRUCTURES OF MO2O(NC6H4CH3)(μ‐S)2(S2P(OCH3)2)2 AND CUBANELIKE (MO2O(NC6H5)(μ3‐S)2(S2P(OC2H5)2)2)2 (1984) (0)
Preparation and Physical Properties of Trinuclear Oxo-Centered Manganese Complexes of the General Formulation (Mn3O(O2CR)6L3)0,+ (R: Me or Ph; L: a Neutral Donor Group) and the Crystal Structures of (Mn3O(O2CMe)6(pyr)3)(pyr) and (Mn3O (1988) (0)
Diallyl- and Bis(2-methylallyl)tetrakis(dimethylamido)ditungsten: W2(.mu±eta.3-C3H5)2(NMe2)4 and W2(η1-C4H7)2(NMe2)4 (MM). Comments on Ligand-Metal π-Interactions at (WW)6+ Centers. (1988) (0)
Structures of ionic decamethylmetallocenes: crystallographic characterization of bis(pentamethylcyclopentadienyl)calcium and -barium and a comparison with related organolanthanide species [Erratum to document cited in CA112(19):179058f] (1990) (0)
Homogeneous hydrogenation of carbon monoxide (2002) (0)
DINUCLEAR ARYLOXIDE CHEMISTRY. 2. SYNTHESIS AND STRUCTURE OF 2,6-DIMETHYLPHENOXIDE COMPLEXES OF DIMOLYBDENUM (MOMO) (1984) (0)
Intramolecular Activation of Aliphatic Carbon - Hydrogen Bonds at Tantalum(V) Metal Centers: A Comparison of Activation by Methyl and Methylidene Functional Groups. (1986) (0)
METAL-METAL-BONDED COMPLEXES OF THE EARLY TRANSITION METALS. 4. SYNTHESIS AND D CHARACTERIZATION OF THE TANTALUM(III) DIMER TA2CL6(PME3)4 (1982) (0)
Synthesis and Structure of (Mo4(OMe)2(OiPr)10); Why Does (W2(OiPr)6) Dimerize, While (Mo2(OiPr)6) Does Not? (1987) (0)
Tungsten-Tungsten Triple Bond. Part 11. (1986) (0)
Stereospecific Syntheses of the Four Diastereomeric 2-Amino-5-phenoxycyclopentanols. (1986) (0)
Crystal and Molecular Structure of Octachlorostyrene, C8C18, a Great Lakes Pollutant (1983) (0)
ONE-DIMENSIONAL POLYMERIZATION OF M,(OAc), (M = Cu, Rh) UNITS USING 2-(AMINOMETHYL)PYRIDINE: PREPARATION AND CHARACTERIZATION OF FWOAcMawOL AND IC~WWdawMn (1994) (0)
Magnetostructural Correlations for [ Ni 4 X 4 I 4 + Cubane Complexes (2001) (0)
Double silyl migration converting ORe[N(SiMe(2)CH(2)PCy(2))(2)] to NRe[O(SiMe(2)CH(2)PCy(2))(2)] substructures. (2002) (0)
Evidence for Equilibrium Between μ-Alkyne and Alkylidyne Complexes of Tungsten Alkoxides: [W2(OR)6(μ-C2R2′)] ↔ 2[(RO)3W ≡ CR′]. (1986) (0)
MOLECULAR DISTORTIONS IN STERICALLY CONGESTED ORGANOMETALS. CRYSTAL STRUCTURE OF BIS(2,4,6‐TRI‐TERT‐BUTYLPHENYL)MERCURY (1980) (0)
6,7-DIHYDRO-5-(((CIS-2-HYDROXY-TRANS-3-PHENOXYCYLOPENTYL)AMINO)METHYL)-2-METHYLBENZO(B)THIOPHEN-4(5H)-ONE: A NOVEL α1-ADRENERGIC RECEPTOR ANTAGONIST AND RENAL VASODILATOR (1985) (0)
Characterisation of nanoscopic [ Mn 12 O 12 ( O 2 CR ) 16 ( H 2 O ) 4 ] single-molecule magnets : physicochemical properties and LDI-and MALDI-TOF mass spectrometry { (2002) (0)
METAL ALKOXIDES: MODELS FOR METAL OXIDES. 2. ADDITION OF ETHYNE, PROPYNE, AND 2-BUTYNE TO MO2(OR)6 (MM) COMPOUNDS (R = TERT-BU, ISO-PR, AND NEOPENTYL). CHARACTERIZATION OF μ-ALKYNE AND μ-C4H4 ADDUCTS AND AN EVALUATION OF THEIR ROLE I (1982) (0)
Tetranuclear Molybdenum Compounds Containing a μ4-Disulfide Linkage. (1988) (0)
Metal Alkoxides - Metal Alkoxides - Models for Metal Oxides. Part 9. Hydridoditungsten Alkoxides: W2(H)(O-iPr)8Na·diglyme and W2(H)(I)(OCH2-tBu)6(H2NMe). Further Investigations of the Reaction Between W2(NMe2)6(M≡M) and iPrOH Leading to W4(H)2(O-iPr)14. (1986) (0)
Reactions of Metal-Metal Multiple Bonds. Part 16. Tetranuclear Halide-Alkoxide Clusters of Molybdenum Formed by the Coupling of M-M Triple-Bonded Dinuclear Compounds. Synthesis, Characterization, and Molecular Structures of Mo4F2(O-iP (1988) (0)
THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 15. COMPOUNDS WITH CHAINS OF METAL ATOMS HAVING M-M SINGLE AND TRIPLE BONDS: M2(M′(M′ME3)3)2(NME2)4 (MM) WHERE M = MO AND W AND M′ = SI AND SN (1985) (0)
1,2-Bis(di-tert-butylarsenido)tetrakis(dimethylamido)dimolybdenum and -ditungsten. Synthesis, Structures, and Solution Behavior. (1988) (0)
Vanadium in heavy crude oil refining (1993) (0)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 8. FORMING MOLYBDENUM-MOLYBDENUM QUADRUPLE BONDS BY REDUCTIVE ELIMINATION (ALKYL GROUP DISPROPORTIONATION) IN THE REACTIONS OF 1,2-MO2R2(NME2)4 COMPOUNDS (MM) WITH CARBON DIOXIDE AND 1,3-DIARY (1982) (0)
Irida-, Rhoda-, Nickela-, and Cuprapentaboranes Derived from the arachno-(B4H9)(-) Ion. Crystal Structure of Iridaborane Complex One Butadiene Complex, an Analogue of arachno-B5H11 and Iridium Complex One Three Butadiene Complex Cation, (1984) (0)
β-HYDROGEN EFFECTS IN ALKYLALKOXIDES OF DIMOLYBDENUM (MM) (1983) (0)
Chemical and Electrochemical Reduction of Titanium(IV) Aryloxides. (1986) (0)
Molecular Structure of a Substituted 2-Norbornyl Cation, 2-Methoxy-1,7,7-trimethylbicyclo(2.2.1)hept-2-ylium Fluoroborate (1987) (0)
A Titanium Alkoxide (Pinacolate) Complex Incorporating a 10-Membered Ring. (1988) (0)
Double C ( sp 3 ) dehydrogenation as a route to coordinated Arduengo carbenes : experiment and computation on comparative p-acidity y (2003) (0)
Structure, Synthesis, and Characterization of Chiral Secondary Diphosphine Platinum(II) Mono- and Dimeric Complexes: Molecular Structure of (Pt2Cl4(SMe2)2((R*,R*)-μ-HtBuPCH2PtBuH)). (1989) (0)
Preparation, Structure, and Chemistry of (O-Acyl imidato)- and (O-Alkyl imidato)carbene Pentacarbonyl Complexes of Chromium. (1989) (0)
Synthesis, properties and solid state structure of 5‐diphenylphosphino‐2‐hydroxy‐1,3‐xylyl‐18‐crown‐5 (2006) (0)
PI‐INTERACTIONS IN THE STRUCTURES OF 1‐ AND 2‐METHYLPENTABORANE AND 1‐ AND 2‐SILYLPENTABORANE, AN ELECTRON DIFFRACTION STUDY (1975) (0)
Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4 Compounds (M triple bond M) with Carbon Dioxide and 1,3-Diaryltriazenes. (1981) (0)
Novel transformations in the quassin series (1981) (0)
Synthesis and Crystallographic Characterization of (CsHN(SiMe3))4, a Cesium-Based Heterocubane. (1992) (0)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 12. REACTIONS OF ORGANIC HALIDES (CHLORIDE, BROMIDE, IODIDE) WITH HEXAALKOXYDIMOLYBDENUM AND -DITUNGSTEN (MM) COMPOUNDS. PREPARATION AND CHARACTERIZATION OF HEXANEOPENTOXYDIBROMO(PYRIDINE)DIMO (1984) (0)
The Synthesis, Reactions, and Molecular Structure of Zirconocene-Alkyne Complexes. (1987) (0)
Synthesis and Properties of Copper and Nickel Complexes of the General Formula (B11H11)2Mn‐. Crystal Structure of ((n‐Bu)4N)3(Cu(B11H11)2). (1995) (0)
Vanadium(IV) Thiolate Chemistry: Preparation, Structure, and Properties of [VE(SCH2CH2S)2]2-(E: O, S). (1986) (0)
GEM-NITRONITROSO DIANION RADICALS R-C (NO2)(NO)2- FORMED IN THE REACTION BETWEEN SODIUM NITRITE/ASCORBATE AND THE SULFUR COMPOUNDS METHIONINE, (METHYL THIO)ACETIC ACID AND S-METHYLCYSTEINE STUDIED BY EPR SPECTROSCOPY (1997) (0)
Use of Tetra-n-butylammonium Permanganate for Inorganic Syntheses in Nonaqueous Solvents. (1986) (0)
Reinvestigation of the Condensation of 2-Hydrazinobenzothiazole with Ethyl Acetoacetate. (1988) (0)
Using the Data Capacitor for Remote Data Collection, Analysis, and Visualization (2007) (0)
Characterization of the organic superconductor, {lambda}-(BETS){sub 2}GaCl{sub 4} (1995) (0)
Manganese carboxylate aggregates as models of the photosynthetic water oxidation centre (1991) (0)
Tetrakis(2,6-di-t-butylphenoxy)uranium(IV): The First Structurally Characterized Neutral Homoleptic Aryloxide Complex of Uranium(IV). (1989) (0)
Synthesis of the Heptacyclic Indole Alkaloid (.+‐.)‐Kopsine and Related Studies. (1989) (0)
STRUCTURAL DETERMINATION OF ((C5H5)2MO(H)CO)((C5H5)MO(CO)3) (1980) (0)
METAL-TO-METAL TRIPLE BONDS-TO CLUSTER OR NOT TO CLUSTER? STRUCTURAL CHARACTERIZATION OF OCTAKIS(TERT-BUTOXY)TETRAKIS(μ-FLUORO)-TETRAMOLYBDENUM AND OCTAKIS(TERT-BUTOXY)TRIS(μ-FLUORO)-(μ-DIMETHYLAMIDO)-TETRAMOLYBDENUM (2002) (0)
Low-valent niobium aryloxide chemistry (1985) (0)
Formation of a σ,π-Vinyl Ligand by Hydrogen Atom Transfer from a Coordinated Di- methylamide to a Perpendicularly Bonded Ethyne Ligand. (1986) (0)
Phosphinecarboxylate Ligands Formed by the Insertion of Carbon Dioxide into Metal-Phosphido Bonds. Preparation and Structural Characterization of Tetrakis(di-tert-butylphosphinecarboxylato)dimolybdenum. (1988) (0)
Rational Syntheses of Copper Polyhydride Complexes (1986) (0)
Synthesis , characterization and single-molecule magnetism properties of ( PPh 4 ) 2 [ Mn 12 O 12 ( O 2 CR ) (2001) (0)
Synthesis and Characterization of Bis(neopentyl)tetrakis(acetato)dimolybdenum. (1986) (0)
CRYSTAL AND MOLECULAR STRUCTURE OF ALLYL(BROMO)BIS(TRIETHYLPHOSPHINE)PLATINUM(II). AN EXAMPLE OF Σ BONDING OF AN η1‐ALLYL GROUP (2002) (0)
(η3-P3)W(OCH2tBu)3(HNMe2) Formed by Cleavage of the WW Bond in the Reaction Between W2(OCH2tBu)6(HNMe2)2 and P4. (1988) (0)
Manganese(III) Thiolate Chemistry: New Structural Types, Including the First Mixed-Valence Metal Thiolate. (1986) (0)
THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 12. PREPARATION AND CHARACTERIZATION OF BIS(TERT-BUTYL MERCAPTIDO)TETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM(MM) (1983) (0)
Salicylate Initiated Formation of the Discrete, Mixed-Valent, Nonanuclear Manganese Complex (Mn9O4(O2CPh)8(sal)4(salH)2(py)4) (salH2: salicyclic acid, py: pyridine). (1987) (0)
A Novel Coordination Mode for Oxygen: Preparation and Properties of (NBu4)2(V4O(edt)2Cl8) Containing a Square-Planar Oxide Bridge. (1990) (0)
OXIDATIVE-ADDITIONS TO (WW)6+ CENTERS: THE INFLUENCE OF LEWIS BASE ASSOCIATION REACTIONS (1983) (0)
A Convenient Synthesis of Trialkylalkylidyne Tungsten (6+) Compounds and the X-Ray Crystal Structure of (Me3CCH2)3WCPh(py). (1990) (0)
Anomalies in the Density Curves of Alkyldiamine-Water Systems (1965) (0)
Synthesis, Structure, and Spectroscopic Properties of Early Transition Metal η2-Iminoacyl Complexes Containing Aryl Oxide Ligation. (1987) (0)
The Crystal and Molecular Structure of Oxysanguinarine Obtained from Sanguinaria canadensis L., Papaveraceae (1985) (0)
The Tungsten-Tungsten Triple Bond. Part 14. Factors Influencing Triple Bonds Between Tungsten Atoms Having Valence Molecular Orbital Configurations of σ2π4 and π4δ2 and Preparation and Characterization of Bis(neopentyl)bis(acetato)bis (1988) (0)
A Binuclear Vanadium(III) Complex Containing the Linear (VOV)4+ Unit: Preparation, Structure, and Properties of (V2O(SCH2CH2NMe2)4). (1987) (0)
A Binuclear Vanadium ( II 1 ) Complex Containing the Linear [ V 0 Vl 4 + Unit : Preparation , Structure , and Properties of [ V 20 ( SCH 2 CH 2 NMe 2 ) 4 ] (2001) (0)
Solution Studies of Ru 2 ( O 2 CR ) 4 n + Complexes ( n ) 0 , 1 ; O 2 CR ) (2003) (0)
Studies of Stereochemical Control Using α-Lithiosulfinyl Carbanions. (1986) (0)
Oxidation and acidolysis of MoH4(PR3)4 (2002) (0)
An Interative Program for the Interpretation of Patterson Functions and Its Uses (1982) (0)
Four-coordinate alkylidene, alkylidyne and phosphinidene complexes of vanadium: One and two-electron oxidatively-induced alpha-hydrogen abstraction reactions (2004) (0)
Insertion Reactions of Chromium-Carbene Complexes with Organic Nitriles and a Diastereoselective Alkylation of a Resulting Imino-Carbene Complex. (1988) (0)
Crystal and Molecular Structure of Bis(tetraphenylphosphonium) Bis(1,2-dicyanoethylene-1,2-dithiolato)oxovanadate(IV). Its Single-Crystal ESR as a Pure Compound and Diluted in the Isomorphous Molybdenum(IV) Compound (1988) (0)
Selective Monophenylation of an Active Methylene Compound. (1990) (0)
Preparation and Wittig Reactions of an α-Keto Amino Acid Derivative. (1990) (0)
Syntheses, structures, and properties of [Mn4O2]8+ - and [Mn4O3X]6+-containing complexes with predominantly oxygen ligation (1993) (0)
Synthesis, Structure, and Spectroscopic Properties of Octahedral Complexes of Tungsten(VI), -(V), and -(IV) Containing 2,6-Diphenylphenoxide Ligation. (1989) (0)
The Chemistry of Transition Metal-Germanium Compounds. Part 2. Synthesis, Characterization, Structure and Reactivity of Transition- Metal Carbonyl-Substituted Germacyclopent-3-enes. (1991) (0)
IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS (V2CL3(THF)6)2(ZN2CL6) (1984) (0)
Double Bonds Between Molybdenum Atoms Supported by Dimethylamido Ligands: Mo2(NMe2)4(OR)4 Compounds, Where R: 4-Methylcyclohexyl and Diisopropylmethyl. (1989) (0)
Metal/Sulfide/Thiolate Chemistry for an Early 3d Transition Metal: Variation of Product Identity as a Function of V:S Reaction Ratio and Structure and Redox Properties of Discrete V/S/edt Complexes. (1988) (0)
COMPLEXES OF THE PLATINUM METALS. PART 25. REACTIONS OF RUTHENIUM AND OSMIUM NITROSYLS (MH(NO)(PPH3)3) AND (M(NO)2(PPH3)2) WITH PERFLUOROCARBOXYLIC ACIDS: X-RAY CRYSTAL STRUCTURE DETERMINATION OF NITROSYL(TRIFLUOROACETATO)(TRIFLUOROAC (1985) (0)
Additions and Corrections - Oxotrimolybdenum(IV) Alkoxides, Mo3(μ3·O)(μ3·OR)(μ2·OR)3(OR)6 (R = CH(CH3)2 and CH2C(CH3)3). Synthetic Considerations (1982) (0)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 11. A COMPARISON OF THE REACTIVITY OF M2(OR)6 (MM) AND M2(OR)4(R′COCHCOR′)2 (MM) COMPOUNDS (M = MO, W) WITH THE Π-ACID LIGANDS CO, RCCR AND RNC (1984) (0)
THE MOLECULAR STRUCTURE OF (MO(S2P(OET)2)3)2(μ-P-NC6H4N), A DERIVATIVE OF P-PHENYLENEDIAMINE (1984) (0)
The Tellurium Analogue of the Hydroxide Ion: Syntheses and Structure of (PPh4)TeH. (1989) (0)
A Novel Synthetic Route to 1,2-Dimethyl-5-phenyl-1H-imidazo(4,5-b)pyridin-7-ol. (1990) (0)
The molybdenum-molybdenum triple bond. 7. 1 bis(1,3-di-p-tolyltriazenido)tetrakis(dimethylamido)dimolybdenum. Technical report (1980) (0)
Ab Initio Studies of Lithium Bonded Complexes with HaO M 이 ecule (2020) (0)
Formation of a Heterometallic Carbon Dioxide Complex with Concurrent Reduction of CO2. (1987) (0)
Further Synthetic Studies of B9H11NH. The Crystal Structure of 1-(η5-C5H5)-1,2-CoNHB9H9. (1989) (0)
MONOINDENYL HALIDES OF ZIRCONIUM AND HAFNIUM. THE PREPARATION OF (ETA 5-C9H7)ZRCL3N AND (ETA 5-C9H7)HFCL2(MU -CL)2 AND THE CRYSTAL STRUCTURE OF (ETA 5 -C9H7)HFCL2(MU -CL)2 (1995) (0)
DIMOLYBDENUM COMPOUND (ISO-PRO)3MOMO(CH2PH)2(O-ISO-PR)(PME3): THE FIRST EXAMPLE OF A COMPOUND CONTAINING A TRIPLE BOND UNITING THREE- AND FOUR-COORDINATE MOLYBDENUM ATOMS AND THE OBSERVATION OF PHOSPHINE-PROMOTED, REVERSIBLE BENZYL-A (1984) (0)
PREPARATION AND CRYSTAL STRUCTURE OF TETRAPHENYLPHOSPHONIUM TELLURIDE-2 METHANOL ((PH4P)2TE4.2CH3OH) (1985) (0)
Molybdenum-molybdenum triple bond. 9. Bis(1,3-di-p-tolyltriazenido)bis(dimethylamido)dimethyldimolybdenum (1981) (0)
Reductive Elimination Pathways to Low-Valent Titanium Aryloxide Complexes. (1987) (0)
New Pathway for the Reaction of Difluorocarbene with Imines. (1987) (0)
STEREOSELECTIVE APPROACH TO ACYCLIC SYSTEMS VIA CONDENSATIONS OF α-LITHIOSULFINYL CARBANIONS AND ALDEHYDES (1982) (0)
Nature of the Olefination Reaction Involving Ditungsten Hexaalkoxides and Aldehydes or Ketones. (1992) (0)
(As7Cr(CO)3)3- from As3- 7 - An Anorganic Nortricyclane-Norbornadiene Rearrangement. (1989) (0)
PHOTOCHEMISTRY OF TRANSITION-METAL POLYHYDRIDES: DIMERIZATION OF OSH4(PME2PH)3 FOLLOWING PHOTODISSOCIATION OF DIHYDROGEN (1983) (0)
Regiochemical and Mechanistic Studies of the Addition of Tin Hydride and Oxide to Substituted Ketenes. (1990) (0)
THE MOLECULAR STRUCTURE OF THE CUBANELIKE COMPOUND, (MO(NC6H4CH3)(μ3-S)(S2P(OC2H5)2))4, AND A DESCRIPTION OF ITS BONDING (1981) (0)
SYNTHESIS OF Π‐(ARENE)METALLOCARBORANES CONTAINING IRON AND RUTHENIUM. CRYSTAL STRUCTURE OF 3,1,2‐(η6‐1,3,5‐ME3C6H3)FEC2B9H11 (1982) (0)
Synthesis and Reactivity of Silyl Vinylketenes: A Formal Interrupted Doetz Benzannulation with Unexpected Silyl Migration. (2002) (0)
THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 14. PREPARATION AND CHARACTERIZATION OF MIXED ALKOXY-THIOLATE COMPOUNDS OF FORMULA MO2(OR)2(SAR)4 (MM) (1984) (0)
CONVERSION OF L3MOMOL3 TYPE COMPOUNDS TO L3MO(μ-L)3MOL3 TYPE COMPOUNDS AND MECHANISTIC IMPLICATIONS (1984) (0)
Relationship of Adduct Formation to Bimolecular Reductive Elimination from Rhodium Polyhydrides. (1986) (0)
Zirconium Compounds of Hexamethyldisiloxane. Synthesis and Structure of (η5-C5H5)2Zr(CH2SiMe2OSiMe3)2 and (η5-C5Me5)ZrCl2(η2- CH2SiMe2OSiMe3) and Their Reactivity with Methyl Isocyanide. (1993) (0)
Versatile Modes of Allene Bonding in the Structures of (W2(O-tBu)6(C3H4)), (W2(O-tBu)6(C3H4)(CO)2), and (W2(O-tBu)6(C3H4)2). (1990) (0)
Preparation and X-Ray and Neutron Diffraction Structure Determination of the Chlorotrihydroborate Ion, [BH3Cl]-. (1986) (0)
Preparation and Physical Properties of Trinuclear Oxo-Centered Manganese Complexes of the General Formulation [ Mn 30 ( 02 CR ) 6 L 3 ] 09 (0)
Preparation, Crystal, and Molecular Structure of a Hydrocarbon Soluble, Volatile Oxoalkoxide of Barium: H4Ba6(μ6‐O)(OCH2CH2OCH3)14. (1991) (0)
HEXADECAMETHOXY- AND HEXADECAETHOXYTETRATUNGSTEN: PREPARATION AND X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF HEXADECAETHOXYTETRATUNGSTEN (1981) (0)
Synthesis, Characterization, Low-Temperature (50 K) Neutron Diffraction Structure, and Reactivity of Chlorodihydridotetrakis(trimethylphosphine)tantalum(III). (1987) (0)
Synthesis and Structure of Group 5 Metal Alkyl and Alkylidene Complexes Containing 2,6-Dialkylphenoxide Ligands: X-Ray Crystal Structures of (Ta(OC6H3Me2-2,6)2(CH2Ph)3), (Ta(OC6H3Me2-2,6)4Me), and (Ta(OC6H3tBu2-2,6)2(=CHSiMe3)(CH2SiMe (1987) (0)
A BIMETALLIC VANADIUM(I) POLYHYDRIDE (1983) (0)
STRUCTURE AND REACTION OF A THIAZOLINO(3,2-A)PYRIMIDINE CARBINOLAMINE (1981) (0)
Intermolecular Rhodium-Catalyzed [2 + 2 +2] Carbocyclization Reactions of 1,6-Enynes with Symmetrical and Unsymmetrical Alkynes. (2005) (0)
Direct Synthesis of VE2+ (E = S, Se) Complexes Using Elemental Chalcogens. Preparation, Structure, and Properties of (VS(SPh)4)2- and (VSe(edt)2)2- (edt2- = Ethane-1,2-dithiolate). (1987) (0)
OXOTRIMOLYBDENUM(IV) ALKOXIDES: MO3(μ3-O)(μ3-OR)(μ2-OR)3(OR)6, WHERE R = ISOPROPYL AND NEOPENTYL. SYNTHETIC CONSIDERATIONS (1982) (0)
Metalladiboranes of the Iron Subgroup: K(M(CO)4(η2-B2H5)) (M: Fe, Ru, Os) and M′(η5-C5H5)(CO)2(η2-B2H5) (M′: Fe, Ru). Analogues of Metal-Olefin Complexes. (1990) (0)
Synthetic and Mechanistic Features of Alcohol Elimination Between Gold Alkoxides and Rhenium Polyhydrides. Metal Polyhedron Reconstruction Upon Protonation. (1987) (0)
Synthetic Studies on Quassinoids: Synthesis of (.+-.)-Shinjudilactone and (.+-.)-13-epi-Shinjudilactone. (1999) (0)
Intermolecular C-H bond activation reactions promoted by transient titanium alkylidynes. Synthesis, reactivity, kinetic, and theoretical studies of the Ti[triple bond]C linkage. (2007) (0)
Soluble Zinc Bis(aryloxides). (1986) (0)
Synthesis of Cu3Os3H9(PMe2Ph)9, a Bimetallic Raft, by Reductive Elimination of Alcohol or H2. (1986) (0)
Additions and Corrections - Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4Compounds (M≡M) with Carbon Dioxide and 1,3-Diaryltriazines (1982) (0)
HCr((Me2PCH2)3CMe)+ 2BEt- 4: The First Synthesis of a Cationic Hydride Complex from HBEt- 3. (1987) (0)
SYNTHESIS OF (Π-ARENE)METALLACARBABORANES CONTAINING RUTHENIUM OR OSMIUM AND A (Π-CYCLOHEXADIENYL)COBALTACARBABORANE. CRYSTAL STRUCTURE OF 2,5,6-(η-C6H6)RUC2B7H11 (1985) (0)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 7. ADDITION OF THE HALOGENS CHLORINE, BROMINE AND IODINE AND DIISOPROPYL PEROXIDE TO HEXAISOPROPOXYDIMOLYBDENUM (MM). DINUCLEAR OXIDATIVE-ADDITION REACTIONS ACCOMPANIED BY METAL-METAL BOND-ORD (1981) (0)
Synthesis and Solid State Structure of Tetra(2,6‐di‐isopropylphenoxy)hexamethoxy‐di‐tantalum(V), Ta2(OC6H3iPr2)4(OCH3)6. (1987) (0)
Cyclometalation of 2,6-Di-tert-butylphenoxide Ligands by Tantalum Aryl Groups: Aliphatic Carbon-Hydrogen Bond Activation and Aryl Isomerization via Benzyne (o-Phenylene) Intermediates. (1988) (0)
Reactions of Mo2(OR)6 (M triple bond M) Compounds (R = Pr(i) and Bu(t) with Benzoyl Peroxide. (1982) (0)
Reactions of Metal-Metal Multiple Bonds. 14. Synthesis and Characterization of Triangulo-W3 and Mo2W-oxo Capped Alkoxide Clusters. Comproportionation of M-M Triple Bonds, sigma(2)pi(4) and d(o) Metal-oxo Groups: M Triple Bond M + M Triple Bond O Yields M3(micron 3-O). (1984) (0)
Rhodium-Catalyzed N-Allylation of Thymine (2006) (0)
Nonanuclear Oxide-Bridged Manganese Complex. Preparation, Structure, and Magnetic Properties of (Mn9O4(O2CPh)8(sal)4(salH)2(pyr)4) (salH2 = Salicylic Acid; pyr = Pyridine). (1988) (0)
Synthesis and Single-Crystal X-Ray Structural Investigation of 1,1-Bis(pentacarbonylmanganio)-3,4-dimethylgermacyclopent-3-ene and Bis(1-(tetracarbonylferrio)-3,4-dimethylgermacyclopent-3-ene): The First Evidence for a Puckered Ground (1990) (0)
Preparation and Structure of ( NEt 4 ) 2 [ V 4 S 2 ( SCH 2 CH 2 S ) 6 ] and Its Structural and Electronic Relationship to the Li , VS 2 Phases (0)
The Tungsten-Tungsten Triple Bond. Part 15. Synthesis, Structure and Reactivity of 1,2-W2(CH(SiMe3)2)2(NMe2)4: the Remarkable Inertness of a Sterically-Encumbered Tungsten-Amido Complex. (1988) (0)
CHARACTERIZATION OF BIS(2,2′-BIPYRIDINE) AND BIS(1,10-PHENANTHROLINE) DERIVATIVES OF MOLYBDENUM AND TUNGSTEN CARBONYLS. CRYSTAL AND MOLECULAR STRUCTURE OF CIS-DICARBONYLBIS(2,2′-BIPYRIDINE)MOLYBDENUM(0) (1984) (0)
CRYSTAL AND MOLECULAR STRUCTURES OF TERT-BUTYLTETRAKIS(DIMETHYLAMIDO)TANTALUM(V), BROMO(P-TOLYL)TRIS(DIMETHYLAMIDO)TANTALUM(V), AND ((TRIMETHYLSILYL)METHYL)TETRAKIS(N,N-DIMETHYLCARBAMATO)TANTALUM(V). EVIDENCE FOR STABILIZATION OF Σ-AL (1982) (0)
1,2-Dibenzyltetradimethylamido-Dimolybdenum and -Ditungsten (M=M) Compounds and Their Reactions with Carbon Dioxide and 1,3-Diaryltriazines. A Radical Difference. (1982) (0)
REACTIONS OF MO2(OR)6 (MM) COMPOUNDS (R = ISO-PR AND TERT-BU) WITH BENZOYL PEROXIDE (1983) (0)
QUANTITATIVE FORMATION OF COORDINATED HYDROXAMATE(2-) LIGANDS BY ATTACK OF PERFLUOROCARBOXYLIC ACIDS ON (OS(NO)2(PPH3)2); THE X-RAY CRYSTAL STRUCTURE OF (OS(ON:C(O)CF3)(O2CCF3)(NO)(PPH3)2) (1983) (0)
Comments on the Molecular Structure and Bonding in W4Cl(O)(OiPr)9 and W4(O)(OiPr)10; Analogies with Tetranuclear Carbonyl Clusters. (1990) (0)
Synthesis of the 1- and 2-Me2S×B11H13 Isomers. Crystal Structures of 2-Me2S×B11H13 and 7-Me2S×B11H13. (1994) (0)
ADDITION OF CARBOXYLIC ACIDS TO (MO(NC6H4CH3)(μ3-S)(S2P(OC2H5)2))4 AND MOLECULAR STRUCTURE OF (MO(NC6H4CH3)(S2P(OC2H5)2))2(μ-S)(μ-SH)(μ-O2CCF3) (1983) (0)
Synthesis and Crystal Structure of B10H10(C6H11)S(CH3)2CNH(t‐C4H9). (1987) (0)
Organometallic Chemistry of Fluorocarbon Acids. Structure of Ti2(iPrO)4(μ-iPrO)2(HC(SO2CF3)2-O,O)2, an Example of an Oxygen-Bonded HC(SO2CF3)2 Ligand. (1990) (0)
SYNTHESIS AND X-RAY STRUCTURE OF 4-AZANONABORANE(13) (1976) (0)
1,2-Dibenzyl and -Diaryltetradimethylamido-dimolybdenum and -Ditungsten Compounds: M2R2(NMe2)4 (M=M). Structural Effects of Me2N-to-M Alpha-Bonding. (1982) (0)
THE SOLUTION DYNAMICS OF SOME FE2(CO)6(L-L′) COMPLEXES (1978) (0)
Metal Alkoxides. Models for Metal Oxides. Part 15. Carbon-Carbon and Carbon-Hydrogen Bond Activation in the Reactions Between Ethylene and Ditungsten Hexaalkoxides: W2(OCH2-tBu)6(η2-C2H4)2, W2(OR)6(CH2)4(η2-C2H4), and W2(OR)6(μ-CCH2CH (1989) (0)
Structure, Magnetochemistry and Biological Relevance of (Mn4O3Cl4(OAc)3(Py)3), a Complex with S = 9/2 Ground State. (1989) (0)
Preparation and Characterization of the Heptachlorobis(tetrahydrofuran)ditungstate and Octachloro(tetrahydrofuran)ditungstate Anions: (Ph4P) (W2Cl7(THF)2) and (Ph4P) (W2Cl8(THF)). (1988) (0)
Reactions of Metal-Metal Triple Bonds. 7. Addition of the Halogens (Cl2, Br2 and I2) and Diisopropylperoxide to Hexaisopropoxydimolybdenum (M-M). Dinuclear Oxidative-Addition Reactions Accompanied by Metal-Metal Bond Order Changes from Three to Two to One. (1980) (0)
Synthesis and Structure of a Resonance Stabilized (Trimethylphosphonio)metallapropenide. (1988) (0)
Tetranuclear and Pentanuclear Vanadium(IV/V) Carboxylate Complexes: [V(4)O(8)(NO(3))(O(2)CR)(4)](2-) and [V(5)O(9)X(O(2)CR)(4)](2-) (X = Cl(-), Br(-)) Salts. (1996) (0)
Unbridged and Bridged Isomers of W2(PCy2)2(NMe2)4: Preparations, Characterizations, and Comments on Thermodynamic and Activation Parameters for the Closing of Phosphido Bridges in d3-d3 Dinuclear Compounds. (1989) (0)
Synthetic and Mechanistic Features of Dinuclear Reductive Elimination Between Re2H8(PMe2Ph)4 and Several Tin(II) Reagents. (1988) (0)
Synthesis and characterization of Mn4O2(O2CR)6Cl2(py)4 and [Mn4O2(O2CPh)6(Et2mal)(H2O)]2−2 (R = 3,5-F2-Ph). Variations on the [Mn4O2] butterfly ligand set and potential biological relevance. (1993) (0)
Synthetic and Mechanistic Aspects of Intramolecular Aliphatic CH Bond Activation by Ti(IV) and Zr(IV) Metal Centers. (1986) (0)
Facile Cleavage of the Mo=Mo Bond in Reactions between (Mo2(OBut)6 and Aryl Azides and Molecular Oxygen. (1980) (0)
Stereoselective Synthesis of Complex Polycyclic Aziridines (XI): Use of the Broensted Acid-Catalyzed Aza-Darzens Reaction to Prepare an Orthogonally Protected Mitomycin C Intermediate with Maximal Convergency. (2011) (0)
Discrete Metal-Sulfide-Thiolate Complexes of an Early 3d Transition Metal. (1987) (0)
Chemical and Structural Studies of Azaboranes. (1987) (0)
Heteronuclear Polyhydride Raft Formation - A Comparison of Syntheses Using Alkoxides of Copper and Gold. (1987) (0)
Tris(N,N′-dimethylethylenediaminato)dimolybdenum and Tris(N,N′-dimethylethylenediaminato)ditungsten. A Comparison of Eclipsed and Staggered Triple Bonds σ2π4, Between Molybdenum and Tungsten Atoms in X3MMX3 Compounds. (1987) (0)
The Tungsten-Tungsten Triple Bond. Part 13. Bisalkyl Tetracarboxylates of Dimolybdenum and Ditungsten. Triple Bonds Between Metal Atoms with the Valence Molecular Orbital Description π4δ2. (1988) (0)
Models of the Manganese Catalase Enzymes . Dinuclear Manganese ( 111 ) Complexes with the [ Mn 2 ( ~ ~-0 ) ( ~ ~-02 CR ) zl ~ + Core and Terminal Monodentate Ligands : Preparation and Properties of (2001) (0)
Decanuclear manganese complexes with different levels of protonation. (1999) (0)
REACTIONS OF METAL-METAL MULTIPLE BONDS. 14. SYNTHESIS AND CHARACTERIZATION OF TRIANGULO-W3 AND -MO2W OXO-CAPPED ALKOXIDE CLUSTERS. CONPROPORTIONATION OF M-M TRIPLE BONDS AND Σ2Π4 AND D0 METAL-OXO GROUPS: MM + MO → M3(μ3-O) (1985) (0)
Comparison of the Relative π-Donor Abilities of Amido and Phosphido Ligands. 1,2-Bis(di-tert-butylphosphido)tetrakis(dimethylamido)dimolybdenum and -ditungsten: 1,2-M2(P(t-Bu)2)2(NMe2)4(MM). (1987) (0)
Synthesis of the Hexacyclic Indole Alkaloid (.+‐.)‐Kopsijasmine (I). (1989) (0)
Synthesis of manganese compounds using bidentate ligands with alkoxo donor atoms. (1991) (0)
Modeling the Dinuclear Sites of Iron Biomolecules: Synthesis and Properties of Fe2O(OAc)2Cl2(bipy)2 and Its Use as an Alkane Activation Catalyst. (1989) (0)
Conversion of Carbon Dioxide to Carbonate Using a Rhodium μ‐Hydroxy Species. (1987) (0)
Trialkoxynitridomolybdenum Compounds: (RO)3MN. Preparation, Structures (R: tBu and iPr), and Comparisons with a Tungsten Analogue (R: tBu). (1987) (0)
Hydrogenation of Ethylene by the H2 Complex (Ir(H)2(H2)(PMe2Ph)3)+ - Mechanism and Characterization of Intermediates. (1988) (0)
The First Hydrocarbyl Trinuclear and Tetranuclear Clusters of Tungsten: W3O(CH2Ph)(O-iPr)9 and W3O(R)2(O-iPr)8 Where R: CH2Ph, Ph, and W4(p-tolyl)2(O-iPr)10. (1987) (0)
Synthesis and Characterization of Paramagnetic Trinickel‐Molybdenum and Trinickel‐Tungsten Clusters. (1989) (0)
The First Observation of the Equilibrium 2 MM ⇄ M4 (M: Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer. (1987) (0)
Carbon-Nitrogen Bond Formation in the Reaction Between Tetrakis(dimethylamido)molybdenum(IV) and 2,6-Dimethylphenyl Isocyanide. Preparation and Characterization of the First Homoleptic Metallaamidine Complex: Mo(η2-Me2NCN-2,6-Me2C6H3) (1987) (0)
How Do Two C-C Double Bonds Add to One M-M Triple Bond? Structure and Bonding in Bis(η2-ethylene)hexakis(neopentoxy)ditungsten. (1990) (0)
Room temperature ring-opening metathesis of pyridines by a transient Ti[triple bond]C linkage. (2006) (0)
Direct comparison of aryloxide and alkoxide coordination to a dimetal center. Synthesis and structure of bis[isopropoxybis(2,6-dimethylphenoxy)molybdenum(III)](Mo-Mo) (1984) (0)
A Tetranuelear Tungsten Carbido Alkoxide Cluster with a Hydride Ligand: W 4( t-C)(NMe )(OCH z But)11 (H) (0)
Synthesis and Crystallographic Characterization of (Me5C5)2Ca(Me3SiCC-CCSiMe3): The First Monomeric Diyne Complex of a Main-Group Element. (1990) (0)
Synthesis of a Remarkably Stable Bicyclo(7.3.1)diynene Esperamicin A1/Calicheamicin γ System. Structural Requirements for Facile Formation of a 1,4-Diyl. (1989) (0)

This paper list is powered by the following services:

What Schools Are Affiliated With John Clifton Huffman?

John Clifton Huffman is affiliated with the following schools:

University of Cádiz
University of Southern Denmark
University of Bath
Indiana University
University College London
University of Tokyo

John Clifton Huffman's Academic­Influence.com Rankings

John Clifton Huffman's Degrees

Why Is John Clifton Huffman Influential?

John Clifton Huffman's Published Works

Published Works

What Schools Are Affiliated With John Clifton Huffman?

John Clifton Huffman's AcademicInfluence.com Rankings