John F. Hartwig
#16,186
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American chemist
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John F. Hartwigchemistry Degrees
Chemistry
#109
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#267
Historical Rank
#51
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Organic Chemistry
#11
World Rank
#20
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#5
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Chemistry
John F. Hartwig's Degrees
- PhD Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is John F. Hartwig Influential?
(Suggest an Edit or Addition)According to Wikipedia, John F. Hartwig is an American organometallic chemist who holds the position of Henry Rapoport Professor of Chemistry at the University of California, Berkeley. His laboratory traditionally focuses on developing transition metal-catalyzed reactions. Hartwig is known for helping develop the Buchwald–Hartwig amination, a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides.
John F. Hartwig's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- C-H activation for the construction of C-B bonds. (2010) (1903)
- Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. (2008) (1372)
- On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. (2012) (1283)
- Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism. (1998) (1227)
- Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides (1998) (782)
- Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. (2002) (756)
- Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. (2012) (733)
- Carbon–heteroatom bond formation catalysed by organometallic complexes (2008) (731)
- Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles (2003) (651)
- Organotransition Metal Chemistry: From Bonding to Catalysis (2009) (639)
- Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers (2011) (608)
- Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides (1994) (561)
- Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents (1995) (549)
- Regioselectivity of the borylation of alkanes and arenes. (2011) (545)
- Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings (2002) (533)
- Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand. (1999) (520)
- A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. (2006) (513)
- Evolution of C-H Bond Functionalization from Methane to Methodology. (2016) (496)
- Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. (2010) (445)
- Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities (2016) (427)
- Palladium-catalyzed amination of aromatic C-H bonds with oxime esters. (2010) (426)
- Catalytic Silylation of Unactivated C-H Bonds. (2015) (398)
- Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex (1997) (390)
- Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. (2001) (389)
- A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides. (2011) (378)
- A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2 (1996) (341)
- Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. (2005) (338)
- Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes. (2007) (322)
- Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol (2014) (316)
- Zur Interpretation des kinetischen Isotopeneffekts bei der Funktionalisierung von C‐H‐Bindungen durch Übergangsmetallkomplexe (2012) (316)
- Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. (2011) (308)
- Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance (1999) (305)
- Discovery and understanding of transition-metal-catalyzed aromatic substitution reactions (2006) (300)
- Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates. (2006) (299)
- Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex (2005) (298)
- Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers (1999) (297)
- A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature. (2002) (296)
- Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol (2012) (294)
- Copper-mediated difluoromethylation of aryl and vinyl iodides. (2012) (283)
- Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships. (2008) (280)
- Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. (2007) (280)
- Abiological catalysis by artificial haem proteins containing noble metals in place of iron (2016) (278)
- Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles. (2005) (271)
- Unusual in Situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C−O Bond Formation (2000) (270)
- Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. (2006) (270)
- Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization (2014) (270)
- Catalytic organometallic reactions of ammonia. (2011) (268)
- Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. (2002) (266)
- Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates (1998) (259)
- Palladium-Catalyzed C−N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes (1998) (250)
- Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. (2002) (247)
- Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles. (2010) (245)
- Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. (2014) (244)
- A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. (2012) (244)
- Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines (2000) (242)
- Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. (2008) (242)
- Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides. (2008) (240)
- Übergangsmetall‐katalysierte Synthese von Arylaminen und Arylethern aus Arylhalogeniden und ‐triflaten: Anwendungen und Reaktionsmechanismus (1998) (240)
- Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. (2003) (236)
- Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes. (2005) (236)
- High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. (2000) (235)
- An artificial metalloenzyme with the kinetics of native enzymes (2016) (226)
- Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols. (2006) (224)
- Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. (2009) (221)
- Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. (2001) (218)
- Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates (2002) (214)
- Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. (2006) (211)
- A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. (2006) (210)
- A Fluorescence-Based Assay for High-Throughput Screening of Coupling Reactions. Application to Heck Chemistry (1999) (209)
- Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction. (2004) (209)
- A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. (2012) (203)
- Development of catalysts for the hydroamination of olefins (2004) (202)
- Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design (1997) (201)
- Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. (2014) (201)
- Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. (2003) (200)
- Carbon−Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity (2004) (198)
- Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles (1998) (197)
- Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation (1998) (197)
- Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes. (2009) (196)
- Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation. (2010) (189)
- Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III) (1996) (186)
- A Simple, Multidimensional Approach to High-Throughput Discovery of Catalytic Reactions (2011) (186)
- Selective functionalization of alkanes by transition-metal boryl complexes (1997) (184)
- Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent. (2003) (180)
- Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. (2002) (179)
- Palladium-Catalyzed α-Arylation of Esters and Amides under More Neutral Conditions (2003) (178)
- Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes (2014) (177)
- From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. (2013) (175)
- Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes (1997) (174)
- Cyanation of arenes via iridium-catalyzed borylation. (2010) (173)
- Copper-mediated fluorination of aryl iodides. (2012) (173)
- Multistep One-Pot Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis (2013) (171)
- Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium. (2009) (170)
- Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )-H Bonds in Natural Products. (2018) (168)
- Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. (2002) (167)
- Selective C-H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction (2013) (166)
- Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. (2008) (165)
- Palladium-Catalyzed α-Arylation of Esters and Protected Amino Acids (2001) (164)
- Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. (2012) (162)
- Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. (2002) (161)
- Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis (2018) (160)
- Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. (2003) (158)
- Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. (2002) (158)
- A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. (2002) (158)
- Pd-Catalyzed α-Arylation of α,α-Difluoroketones with Aryl Bromides and Chlorides. A Route to Difluoromethylarenes (2014) (157)
- Structural Characterization and Simple Synthesis of {Pd[P(o-Tol)3]2}. Spectroscopic Study and Structural Characterization of the Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides and Their Reactivity with Amines (1995) (156)
- Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex (2014) (156)
- Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. (2013) (156)
- Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. (2017) (154)
- Palladium‐Catalyzed Amination of Aryl Halides and Related Reactions (2003) (154)
- Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. (2003) (153)
- Iridium-catalyzed silylation of aryl C-H bonds. (2015) (151)
- Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. (2001) (150)
- Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. (2008) (150)
- Iridium-Catalyzed Allylic Substitution (2011) (150)
- Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. (2013) (149)
- Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. (2001) (148)
- Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds. (2006) (147)
- Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. (2008) (146)
- Palladium-Catalyzed Intermolecular α-Arylation of Zinc Amide Enolates under Mild Conditions (2006) (146)
- Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. (2003) (144)
- Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes. (2003) (143)
- Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands. (2005) (143)
- Sterically controlled, palladium-catalyzed intermolecular amination of arenes. (2013) (142)
- Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst. (2004) (142)
- Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. (2007) (142)
- Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. (2006) (142)
- Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a Two-Coordinate Palladium(0) Complex, Bis(tri-o-tolylphosphine)Palladium(0) (1995) (141)
- Kumada coupling of aryl and vinyl tosylates under mild conditions. (2005) (140)
- Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate (1997) (140)
- Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides (1996) (139)
- A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. (2002) (138)
- Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds. (2005) (138)
- Reductive elimination of aryl halides from palladium(II). (2001) (137)
- Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines (2001) (137)
- Discrete High Molecular Weight Triarylamine Dendrimers Prepared by Palladium-Catalyzed Amination (1997) (137)
- Hydrocarbon Functionalization by Transition Metal Boryls (1995) (136)
- Iridium‐Catalyzed Direct Borylation of Five‐Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions (2003) (135)
- A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides. (2009) (135)
- Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II) (2003) (135)
- Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides. (2007) (135)
- Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. (2010) (133)
- Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. (2013) (133)
- Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides. (2012) (132)
- Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. (2008) (131)
- Systematic Variation of Bidentate Ligands Used in Aryl Halide Amination. Unexpected Effects of Steric, Electronic, and Geometric Perturbations (1998) (131)
- True Metal-Catalyzed Hydroboration with Titanium (1996) (130)
- Catalyst-Controlled Site-Selective Bond Activation. (2017) (130)
- Mechanistic Studies of the Palladium-Catalyzed Amination of Aryl Halides and the Oxidative Addition of Aryl Bromides to Pd(BINAP)2 and Pd(DPPF)2: An Unusual Case of Zero-Order Kinetic Behavior and Product Inhibition (2000) (129)
- Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids. (2007) (128)
- Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. (2005) (128)
- Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines. (2003) (127)
- Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. (2004) (126)
- PALLADIUM-CATALYZED SYNTHESIS OF PURE, REGIODEFINED POLYMERIC TRIARYLAMINES (1999) (125)
- Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. (2011) (125)
- Mild palladium-catalyzed selective monoarylation of nitriles. (2005) (124)
- Iridium-catalyzed regio- and enantioselective N-allylation of indoles. (2009) (123)
- Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation. (2003) (123)
- A Route to Pdo from PdII Metallacycles in Animation and Cross-Coupling Chemistry† (1996) (122)
- Synthesis, Characterization, and Reactivity of Arylpalladium Cyanoalkyl Complexes: Selection of Catalysts for the α-Arylation of Nitriles (2002) (121)
- Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction To Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone. (1998) (121)
- Regioselective and enantioselective iridium-catalyzed allylation of enamines. (2007) (118)
- A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis. (2005) (116)
- Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. (2012) (116)
- Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates. (2005) (116)
- Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling. (2007) (114)
- Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones (2005) (114)
- Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. (2009) (113)
- Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. (2014) (113)
- Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. (2014) (112)
- Hydroaminoalkylation of unactivated olefins with dialkylamines. (2008) (112)
- Synthesis of difluoromethyl ethers with difluoromethyltriflate. (2013) (111)
- Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. (2011) (111)
- Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. (2012) (110)
- Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. (2012) (110)
- Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. (2016) (109)
- Copper(I) phenoxide complexes in the etherification of aryl halides. (2010) (108)
- Carbon-Heteroatom Bond-Forming Reductive Elimination. Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects during Formation of Aryl Sulfides (1995) (108)
- Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. (2010) (108)
- Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives. (2004) (108)
- Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction. (2010) (107)
- Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis. (2018) (106)
- Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. (2016) (105)
- Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. (2017) (105)
- Tertiary building units: synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). (2001) (105)
- Functionalization of Alkanes by Isolated Transition Metal Boryl Complexes (2000) (104)
- Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration. (2016) (104)
- Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. (2010) (103)
- Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation (1999) (103)
- Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. (2015) (103)
- Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. (2014) (102)
- Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. (2002) (102)
- Iridium-catalyzed C-H borylation of cyclopropanes. (2013) (102)
- Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. (2015) (102)
- [(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides. (2008) (101)
- One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes. (2007) (101)
- Catecholborane Bound to Titanocene. Unusual Coordination of Ligand σ-Bonds (1996) (100)
- C−H Activation and Functionalization of Unsaturated Hydrocarbons by Transition-Metal Boryl Complexes (1999) (100)
- Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes. (2005) (99)
- C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. (2001) (98)
- The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. (2009) (98)
- Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes. (2004) (97)
- Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system. (2015) (97)
- Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. (2014) (96)
- Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates. (2007) (96)
- Synthesis and Late-Stage Functionalization of Complex Molecules through C–H Fluorination and Nucleophilic Aromatic Substitution (2014) (96)
- Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization. (2008) (95)
- Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent. (2006) (95)
- PALLADIUM-CATALYZED FORMATION OF DIARYL ETHERS FROM ARYL BROMIDES. ELECTRON POOR PHOSPHINES ENHANCE REACTION YIELDS (1997) (95)
- Direct Observation of β-Aryl Eliminations from Rh(I) Alkoxides (2006) (94)
- Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF (2014) (94)
- Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen. (2014) (93)
- Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides. (2005) (93)
- Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. (2007) (92)
- Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. (2008) (91)
- Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes. (2010) (91)
- Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. (2016) (91)
- Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. (2002) (91)
- Palladium-catalyzed asymmetric allylic alkylations of polynitrogen-containing aromatic heterocycles. (2011) (90)
- Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation. (2011) (90)
- Transmetalation, Involving Organotin Aryl, Thiolate, and Amide Compounds. An Unusual Type of Dissociative Ligand Substitution Reaction (1995) (89)
- One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate. (2010) (89)
- Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. (2006) (89)
- Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols. (2008) (88)
- Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). (2006) (87)
- Pd-Catalyzed α-Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides (2014) (87)
- A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates. (2012) (86)
- Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes. (2011) (85)
- Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols. (2015) (84)
- Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. (2003) (84)
- Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates. (2007) (84)
- Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality. (2004) (83)
- σ-Borane Complexes of Manganese and Rhenium (2000) (83)
- Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study. (2003) (83)
- Mechanism of the rhodium-catalyzed silylation of arene C-H bonds. (2014) (82)
- Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane. (2013) (81)
- Reductive elimination of aryl halides upon addition of hindered alkylphosphines to dimeric arylpalladium(II) halide complexes (2004) (81)
- Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates. (2010) (81)
- A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by Three-Coordinate Intermediates (1995) (80)
- Mechanism of aryl chloride amination: base-induced oxidative addition. (2001) (80)
- Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. (2017) (80)
- Transition metal boryl complexes: structure and reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2 (1993) (79)
- Enantioselective, iridium-catalyzed monoallylation of ammonia. (2009) (79)
- Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. (2002) (79)
- Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. (2001) (79)
- Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism (2004) (79)
- A Continuum Resulting from Equilibrium between Two Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes. .pi.-Bonding in a d2 Boryl System and the First d0 Boryl Complex (1994) (78)
- Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes. (2004) (78)
- A decarboxylative approach for regioselective hydroarylation of alkynes. (2016) (77)
- Femtosecond excitation energy transport in triarylamine dendrimers. (2002) (77)
- Migratory insertion of alkenes into metal-oxygen and metal-nitrogen bonds. (2013) (77)
- Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters (2014) (77)
- Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes. (2007) (77)
- Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes (2014) (76)
- Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes (2008) (76)
- Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). (2008) (76)
- Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. (2014) (76)
- Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. (2012) (75)
- Palladium-catalyzed alpha-arylation of esters with chloroarenes. (2008) (75)
- Titanocene Borane σ-Complexes (1999) (75)
- Accurate Borane Sequential Bond Dissociation Energies by High-Level ab Initio Computational Methods (1996) (74)
- Late Stage Azidation of Complex Molecules (2016) (74)
- Palladium-Catalyzed α-Arylation of Azlactones to Form Quaternary Amino Acid Derivatives (2003) (73)
- Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions (2020) (73)
- DNA binding properties of [Pt(NH3)(C6H11NH2)Cl2], a metabolite of an orally active platinum anticancer drug (1992) (72)
- Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. (2013) (71)
- Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile (2016) (70)
- Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis. (2019) (70)
- Katalytische metallorganische Reaktionen von Ammoniak (2011) (70)
- Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. (2016) (69)
- Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. (2011) (69)
- Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides (1997) (69)
- Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. (2010) (68)
- Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen (2016) (67)
- Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts (2014) (67)
- Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation. (2013) (67)
- Direct measurement of the thermodynamics of vinylarene hydroamination. (2006) (66)
- Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2. (2008) (66)
- Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions (2017) (66)
- Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. (2012) (66)
- Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes. (2004) (66)
- Diverse functionalization of strong alkyl C–H bonds by undirected borylation (2020) (65)
- Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes (2017) (64)
- Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres. (2003) (63)
- Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers. (2016) (62)
- Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd(PtBu3)2. (2007) (62)
- Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups. (2005) (62)
- Pd-catalyzed alpha-arylation of trimethylsilyl enol ethers with aryl bromides and chlorides: a synergistic effect of two metal fluorides as additives. (2006) (62)
- Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and β-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes (2008) (62)
- Polaron delocalization in ladder macromolecular systems. (2005) (62)
- Catalytic Hydroxylation of Polyethylenes (2005) (61)
- Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts. (2019) (60)
- Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism. (2012) (60)
- Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic CuI Intermediates. (2018) (60)
- Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones. (2016) (59)
- Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates (2014) (59)
- Slow reductive elimination from arylpalladium parent amido complexes. (2010) (59)
- Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification. (2013) (59)
- Synthesis and chemistry of ruthenium hydrido aryloxides and arylamides. An investigation of structure, nitrogen-hydrogen and oxygen-hydrogen elimination processes, proton-catalyzed exchange reactions, and relative Ru-X bond strengths (1991) (58)
- A Heck-Type Reaction Involving Carbon−Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides with N-Pyrazyl Aldimines (2000) (58)
- Tetraazacyclophanes by Palladium-Catalyzed Aromatic Amination. Geometrically Defined, Stable, High-Spin Diradicals (1999) (58)
- Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. (2014) (56)
- Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope. (2013) (56)
- Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. (2015) (56)
- Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. (2001) (56)
- Mechanistic Studies on Oxidative Addition of Aryl Halides and Triflates to Pd(BINAP)2 and Structural Characterization of the Product from Aryl Triflate Addition in the Presence of Amine (2002) (55)
- One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. (2013) (54)
- Catalyzed carbon-heteroatom bond formation (2011) (54)
- Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols. (2018) (54)
- Selective, Nickel‐Catalyzed Hydrogenolysis of Aryl Ethers. (2011) (54)
- Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands. (2017) (53)
- Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds. (2016) (53)
- Structure, synthesis, and chemistry of ruthenium complex (PMe3)4Ru(.eta.2-benzyne). Reactions with arenes, alkenes, and heteroatom-containing organic compounds. Synthesis and structure of a monomeric hydroxide complex (1991) (52)
- Understanding the coupling of heteroaromatic substrates: Synthesis, structures, and reductive eliminations of heteroarylpalladium amido complexes (2003) (52)
- Synthesis of a highly reactive (benzyne)ruthenium complex: C-C, C-H, N-H, and O-H activation reactions (1989) (52)
- Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands. (2017) (52)
- Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. (2013) (51)
- Palladium-Catalyzed Arylation of Fluoroalkylamines. (2015) (51)
- Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. (2012) (51)
- Regiodefined Poly(N-arylaniline)s and Donor−Acceptor Copolymers via Palladium-Mediated Amination Chemistry (1998) (50)
- Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene. (2006) (49)
- N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes. (2010) (49)
- Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds. (2017) (49)
- Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation. (2017) (49)
- Catalysis with Platinum-Group Alkylamido Complexes. The Active Palladium Amide in Catalytic Aryl Halide Aminations As Deduced from Kinetic Data and Independent Generation (1996) (48)
- Boryls Bound to Iron Carbonyl. Structure of a Rare Bis(boryl) Complex, Synthesis of the First Anionic Boryl, and Reaction Chemistry That Includes the Synthetic Equivalent of Boryl Anion Transfer (1996) (48)
- Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. (2015) (47)
- Development of a One-Pot Tandem Reaction Combining Ruthenium-Catalyzed Alkene Metathesis and Enantioselective Enzymatic Oxidation To Produce Aryl Epoxides (2015) (47)
- Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. (2001) (46)
- Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex†‡ (1997) (46)
- Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. (2016) (46)
- Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. (2013) (45)
- Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions (1991) (45)
- Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds (1991) (45)
- Structure and reactions of oxametallacyclobutanes and oxametallacyclobutenes of ruthenium (1991) (45)
- Energetics and Mechanism of Alkylamine N−H Bond Cleavage by Palladium Hydroxides: N−H Activation by Unusual Acid−Base Chemistry (1997) (45)
- Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones. (2014) (44)
- Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination. (2004) (44)
- Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides. (2007) (44)
- Synthesis of monomeric ruthenium hydroxo complexes (PMe3)4Ru(R)(OH) (R = H, Me) and a unique dimeric ruthenium hydroxo-water complex [trans-Ru(H)(OH)(DMPE)2.cntdot.H2O]2 (1993) (44)
- C(sp(3))-N bond-forming reductive elimination of amines: reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes. (2010) (43)
- Iridium-Catalyzed, β-Selective C(sp3)-H Silylation of Aliphatic Amines To Form Silapyrrolidines and 1,2-Amino Alcohols. (2018) (43)
- Relative rates for the amination of η3-allyl and η3-benzyl complexes of palladium (2006) (42)
- Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis. (2019) (42)
- Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles. (2016) (42)
- Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes. (2005) (42)
- Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide. (2006) (41)
- Addition of Catecholborane to a Ruthenium-Alkyl: Evidence for .sigma.-Bond Metathesis with a Low-Valent, Late Transition Metal (1994) (41)
- Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts (1996) (41)
- Trimethylphosphate as a Methylating Agent for Cross Coupling: A Slow-Release Mechanism for the Methylation of Arylboronic Esters. (2018) (41)
- Site-Selective Functionalization of (sp3)C-H Bonds Catayzed by Artificial Metalloenzymes Containing an Iridium-Porphyrin Cofactor. (2019) (41)
- β-Aryl Eliminations from Rh(I) Iminyl Complexes (2005) (41)
- Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds. (2009) (40)
- Katalytische, regiospezifische Funktionalisierung von Alkanen in terminaler Position: photochemisch induzierte, rheniumkatalysierte Borierung (1999) (40)
- Palladium‐Catalyzed Amination of Aryl Halides and Sulfonates (2004) (39)
- Recent advances in the discovery of organometallic catalysts using high-throughput screening assays. (2003) (39)
- Forcieren der σ-Donorstärke in Iridium-Pinzettenkomplexen: Bis(silylen)- und Bis(germylen)-Liganden sind stärkere Donoren als Bis[phosphor(III)]-Liganden† (2012) (38)
- C(sp3)-O bond-forming reductive elimination of ethers from bisphosphine-ligated benzylpalladium(II) aryloxide complexes. (2011) (38)
- A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. (2017) (38)
- Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C-H and N-H Bonds to Ir(I) Complexes. (2016) (37)
- Synthesis of ruthenium enolate (PMe3)4Ru(Me)(OC(CH2)Me) as an equilibrium mixture of oxygen- and carbon-bound transition-metal enolates. Thermal elimination of methane to form an .eta.4-oxatrimethylenemethane complex (1990) (37)
- Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions. (2002) (37)
- Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals. (2010) (36)
- First Transition Metal-Boryl Bond Energy and Quantitation of Large Differences in Sequential Bond Dissociation Energies of Boranes (1994) (36)
- General N−H Activation of Primary Alkylamines by a Late Transition-Metal Complex (1996) (36)
- Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling. (2016) (36)
- Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation. (2018) (35)
- Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. (2014) (34)
- Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion (2020) (34)
- The Largest Discrete Oligo(m-aniline). An Exponential Growth Strategy Using Palladium-Catalyzed Amination of Aryl Sulfonates (1998) (34)
- Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. (2018) (33)
- Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]. (2016) (33)
- Übergangsmetall‐katalysierte selektive Funktionalisierung von C(sp3)‐H‐Bindungen in Naturstoffen (2018) (33)
- Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydrobo-ration of Disubstituted Alkenes. (2020) (32)
- Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium. (2009) (32)
- Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines. (2009) (32)
- Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin). (2010) (32)
- Palladium-catalyzed equilibrium addition of acidic OH groups across dienes. (2003) (31)
- Reductive elimination from arylpalladium cyanide complexes. (2012) (31)
- A Short Synthesis of Tetraalkoxydiborane(4) Reagents (2003) (31)
- Desymmetrization of difluoromethylene groups by C–F bond activation (2020) (31)
- Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen. (2004) (30)
- Von PdII-Metallacyclen zu Pd0-Komplexen in Aminierungen und Kreuzkupplungen† (1996) (30)
- Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals. (2017) (30)
- Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. (2003) (30)
- Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates. (2017) (29)
- Structural and Reaction Chemistry of Tungstenocene Boryl Complexes (1996) (29)
- Reactivity of Tungstenocene with BB and BH Bonds versus CH Bonds (1996) (29)
- Catalytic Asymmetric Addition of an Amine N-H Bond Across Internal Alkenes (2020) (29)
- Catalytic hydroxylation of polypropylenes. (2005) (28)
- Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions (2004) (28)
- Palladium‐Catalyzed Synthesis of Aryl Ethers and Related Compounds Containing S and Se (2003) (28)
- Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides. (2017) (27)
- Imine insertion into a late metal-carbon bond to form a stable amido complex. (2004) (27)
- Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds. (2019) (27)
- Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds. (2017) (26)
- A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins. (2019) (26)
- Raising the Bar for the "Perfect Reaction" (2002) (25)
- Mechanistic study of beta-hydrogen elimination from organoplatinum(II) enolate complexes. (2008) (25)
- Mechanism of the carbon-carbon cleavage of acetone by the ruthenium benzyne complex (PMe3)4Ru(.eta.2-C6H4): formation and reactivity of an oxametallacyclobutane complex (1990) (25)
- A Stoichiometric Aromatic C—H Borylation Catalyzed by Iridium(I)/2,2′‐Bipyridine Complexes at Room Temperature. (2002) (24)
- Alkyl, aryl, hydrido, and acetate complexes of (DMPM)2Ru [DMPM = bis(dimethylphosphino)methane]: reductive elimination and oxidative addition of carbon-hydrogen bonds (1991) (24)
- Carbon—Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides (1999) (24)
- Iridium-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes. (2018) (24)
- Palladium-catalyzed oxidation of β-C(sp3)-H bond of primary alkylamines through a rare four-membered palladacycle intermediate. (2020) (24)
- Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives (2017) (23)
- Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. (2019) (23)
- Synthesis of heteroaromatic trifluoromethyl ethers with trifluoromethyl triflate as the source of the trifluoromethoxy group. (2018) (22)
- Palladium‐Catalyzed Synthesis of Arylamines from Aryl Halides. Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. (1995) (22)
- Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy. (2019) (22)
- Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. (2016) (22)
- Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers (2018) (21)
- Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)-H Bonds. (2020) (21)
- A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2 (1990) (21)
- Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes. (2020) (21)
- Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. (2012) (21)
- Inter- and intramolecular carbon-hydrogen bond forming and cleavage reactivity of two different types of poly(trimethylphosphine)ruthenium intermediates (1991) (20)
- Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP). (2006) (20)
- Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers (2019) (20)
- Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. (2016) (19)
- A photochemical source of dibromo- and dichlorocarbene (1986) (19)
- Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. (2015) (19)
- Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters. (2019) (19)
- Migratorische Insertion von Alkenen in Metall‐Sauerstoff‐ und Metall‐Stickstoff‐Bindungen (2013) (18)
- Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation (2008) (18)
- Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers. (2020) (18)
- Migratorische Insertion von Alkenen in Metall‐Sauerstoff‐ und Metall‐Stickstoff‐Bindungen (2013) (18)
- Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes. (2017) (18)
- Unnatural Biosynthesis by an Engineered Microorganism with Heterologously Expressed Natural Enzymes and an Artificial Metalloenzyme (2021) (18)
- Iridium-Catalyzed Silylation of Unactivated C-H Bonds. (2019) (18)
- Adsorption of butachlor to soils (1987) (18)
- Site-Selective Silver-Catalyzed C-H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals. (2021) (18)
- Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides (2009) (18)
- Synthese, Struktur und Reaktivität von [Cp2Ti(HBcat)(PMe3)]: ein Monoboran‐σ‐Komplex (1997) (17)
- Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. (2016) (16)
- Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules. (2017) (16)
- Chapter 7. Palladium-Catalyzed Amination of Aryl Halides and Sulfonates (2007) (16)
- Abiotic reduction of ketones with silanes catalyzed by carbonic anhydrase through an enzymatic zinc hydride (2021) (15)
- Synthesis of Anilines (2007) (15)
- Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. (2016) (15)
- Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds. (2020) (14)
- Catalytic deconstruction of waste polyethylene with ethylene to form propylene (2022) (14)
- Transition Metal Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines. (2001) (13)
- Oxidative Addition and Reductive Elimination Reactions of trans-[Ir(PPh3)2(CO)(NC4H4)] and trans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)], Including N−H Bond-Forming Reductive Elimination of Pyrrole (1998) (13)
- Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis. (2021) (12)
- Palladium‐Catalyzed α‐Arylation of Carbonyl Compounds and Nitriles (2003) (11)
- REAKTIVITAT VON WOLFRAMOCEN GEGENUBER B-B- UND B-H-BINDUNGEN IM VERGLEICH ZU C-H-BINDUNGEN (1996) (11)
- Regioselectivity of the Borylation of Alkanes and Arenes (2011) (11)
- Synthesis and DNA binding properties of a cisplatin analog containing a tethered dansyl group (1992) (11)
- Air‐Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium‐Catalyzed C—C, C—N, and C—O Bond‐Forming Cross‐Couplings. (2003) (11)
- Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction. (2020) (10)
- Borylation of Arenes with Bis(hexylene glycolato)diboron (2013) (10)
- Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings. (2002) (10)
- Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure—Activity Relationships. (2008) (10)
- Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups. (2020) (9)
- Palladium-Catalyzed Oxidative Dehydrosilylation for Contra-Thermodynamic Olefin Isomerization (2020) (9)
- Reductive Elimination from Phosphine-Ligated Alkylpalladium(II) Amido Complexes To Form sp3 Carbon-Nitrogen Bonds. (2018) (9)
- Efficient Synthesis of α‐Aryl Esters by Room‐Temperature Palladium‐Catalyzed Coupling of Aryl Halides with Ester Enolates. (2003) (9)
- Development of Chiral Ligands for the Transition Metal-catalyzed Enantioselective Silylation and Borylation of C-H Bonds. (2021) (9)
- Enantioselective hydroamination of unactivated terminal alkenes. (2022) (8)
- Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C-C Bond Formation. (2021) (8)
- Sequential Xanthalation and O-Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl-trifluoromethyl Ethers. (2019) (8)
- Iridium‐Catalyzed Borylation of Secondary C—H Bonds in Cyclic Ethers. (2013) (8)
- Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates J. Am. Chem. Soc. 1998, 120, 7369−7370 (1998) (8)
- Site Selective Chlorination of C(sp3)-H Bonds Suitable for Late-Stage Functionalization. (2021) (8)
- New "Cats" in the House: Chemistry Meets Biology in Artificial Metalloenzymes and Repurposed Metalloenzymes. (2019) (8)
- Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization. (2019) (8)
- Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C(sp3)-H Bonds with Zhdankin's λ3-Azidoiodane. (2021) (7)
- Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoro-ethyl Complexes of Substituted Bipyridines. (2019) (7)
- Palladium‐Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design (1997) (7)
- Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine. (2020) (7)
- Ruthenium-Catalyzed, Chemoselective and Regioselective Oxidation of Polyisobutene. (2021) (7)
- In Praise of Basic Research as a Vehicle to Practical Applications: Palladium-Catalyzed Coupling to Form Carbon-Nitrogen Bonds. (2020) (7)
- Catalytic Silylation of Unactivated C-H Bonds (2015) (7)
- Cyanation of Arenes via Iridium‐Catalyzed Borylation. (2011) (7)
- Artificial Biosynthetic Pathway for an Unnatural Terpenoid with an Iridiumcontaining P450 (2020) (7)
- Synthetic chemistry: Recipes for excess (2005) (7)
- Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. (2020) (7)
- Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds (2019) (7)
- Broensted Acid-Catalyzed Intramolecular Hydroamination of Protected Alkenylamines. Synthesis of Pyrrolidines and Piperidines. (2002) (7)
- Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes. (2009) (6)
- Reductive Elimination to Form C(sp3)–N Bonds from Palladium(II) Primary Alkyl Complexes (2018) (6)
- Identification of an Activated Catalyst in the Iridium‐Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity. (2004) (6)
- Palladium‐Catalyzed Amination of Aromatic C—H Bonds with Oxime Esters. (2010) (6)
- Metal Complexes as Catalysts for CarbonHeteroatom Cross-Coupling Reactions (2003) (6)
- Improved Catalysts for the Palladium‐Catalyzed Synthesis of Oxindoles by Amide α‐Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric Transformations. (2010) (6)
- Enantioselective α-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel. (2008) (6)
- Multistep One‐Pot Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis (2014) (6)
- [(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides. (2009) (5)
- Copper‐Catalyzed Dehydrogenative Amidation of Light Alkanes (2021) (5)
- Iridium‐Catalyzed C—H Coupling Reaction of Heteroaromatic Compounds with Bis(pinacolato)diboron: Regioselective Synthesis of Heteroarylboronates. (2002) (5)
- Palladium‐Catalyzed Arylation of Fluoroalkylamines. (2015) (5)
- Enantioselective Functionalization of Allylic C—H Bonds Following a Strategy of Functionalization and Diversification. (2014) (5)
- Palladium‐Catalyzed Hydroamination of 1,3‐Dienes: A Colorimetric Assay and Enantioselective Additions. (2001) (5)
- gem-Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity. (2021) (5)
- Asymmetric Allylic Alkylation of Diverse Nitrogen-ContainingHeterocycles (2011) (5)
- Rhodium‐Catalyzed Intermolecular C—H Silylation of Arenes with High Steric Regiocontrol. (2014) (4)
- Sterically Controlled Iodination of Arenes via Iridium-Catalyzed C—H Borylation. (2013) (4)
- Scope and Mechanism of Palladium‐Catalyzed Amination of Five‐Membered Heterocyclic Halides. (2003) (4)
- Directed Evolution of Artificial Metalloenzymes in Whole Cells. (2021) (4)
- Iridium‐Catalyzed Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH. (2014) (4)
- Discovery and Understanding of Transition‐Metal‐Catalyzed Aromatic Substitution Reactions (2006) (4)
- Iridium-Catalyzed C—H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism. (2014) (4)
- Catalytic, Thermal, Regioselective Functionalization of Alkanes and Arenes with Borane Reagents (2004) (4)
- Synthese, Struktur und Reaktionen eines Palladium‐Hydrazonatokomplexes – neuartige reduktive Eliminierung unter Knüpfung von C‐N‐Bindungen sowie katalytische Arylierung von Benzophenonhydrazon (1998) (4)
- Regiospecific Functionalization of Methyl C—H Bonds of Alkyl Groups in Reagents with Heteroatom Functionality. (2005) (4)
- A General and Long‐Lived Catalyst for the Palladium‐Catalyzed Coupling of Aryl Halides with Thiols. (2006) (4)
- Screening of Homogeneous Catalysts by Fluorescence Resonance Energy Transfer. Identification of Catalysts for Room‐Temperature Heck Reactions. (2001) (4)
- Iridium-Catalyzed, Silyl-Directed, peri -Borylation of C−H Bonds in Fused Polycyclic Arenes and Heteroarenes (2018) (4)
- Silyl‐Directed, Iridium‐Catalyzed ortho‐Borylation of Arenes. A One‐Pot ortho‐Borylation of Phenols, Arylamines, and Alkylarenes. (2008) (4)
- Iridium‐Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles. (2014) (4)
- Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. (2008) (4)
- Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N‐Alkyl Arylamines. (2008) (4)
- Iridium‐Catalyzed, Silyl‐Directed Borylation of Nitrogen‐Containing Heterocycles. (2010) (4)
- Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes. (2021) (3)
- Palladium‐Catalyzed Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of α‐Aryl Carboxylic Acid Derivatives. (2004) (3)
- A Heck‐Type Reaction Involving Carbon—Heteroatom Double Bonds. Rhodium(I)‐Catalyzed Coupling of Aryl Halides with N‐Pyrazyl Aldimines. (2001) (3)
- Unparalleled Rates for the Activation of Aryl Chlorides . Coupling with Amines and Boronic Acids in Minutes at Room Temperature (2002) (3)
- Iridium‐Catalyzed Silylation of Aryl C—H Bonds. (2015) (3)
- Iridium‐Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids. (2007) (3)
- Carbon—Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation. (1999) (3)
- Palladium‐Catalyzed Amination of Aryl Halides (2019) (3)
- Palladium‐Catalyzed γ‐Arylation of α,β‐Unsaturated Esters from Silyl Ketene Acetals. (2010) (3)
- C—C Bond-Forming Reductive Elimination of Ketones, Esters, and Amides from Isolated Arylpalladium(II) Enolates. (2001) (3)
- Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance. (1999) (3)
- Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C—H Bonds. (2005) (3)
- Enantioselecitve Iridium‐Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. (2008) (3)
- Palladium-Catalyzed C-O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination to Form the C-O Bond in Diaryl Ethers. (1999) (3)
- Progress, Challenges, and Opportunities with Artificial Metalloenzymes in Biosynthesis. (2022) (3)
- C-H Transformation at Unfunctionalized Alkanes (2008) (3)
- α-Arylation of Esters Catalyzed by the Pd(I) Dimer {[P(t-Bu)3]PdBr}2. (2008) (3)
- Mechanistic Insight into Iridium-Catalyzed Asymmetric Allylations (2007) (3)
- α‐Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t‐Bu)3Pd(μ‐Br)]2 (2012) (3)
- Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds†‡ (2020) (3)
- Ruthenium‐Catalyzed anti‐Markovnikov Hydroamination of Vinylarenes. (2004) (3)
- Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds. [Erratum to document cited in CA115(11):114728s] (1992) (3)
- Iridium‐Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. (2004) (3)
- Rhodium-Catalyzed Enantioselective Silylation of Arene C—H Bonds: Desymmetrization of Diarylmethanols. (2015) (3)
- Assembly and Evolution of Artificial Metalloenzymes within E. coli Nissle 1917 for Enantioselective and Site-Selective Functionalization of C─H and C═C Bonds. (2022) (2)
- Iridium‐Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. (2016) (2)
- Carbon(sp3)-nitrogen bond-forming reductive elimination from phosphine-ligated alkylpalladium(II) amide complexes: A DFT study (2019) (2)
- Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride. (2019) (2)
- Copper-Catalyzed Allylic Substitution (2010) (2)
- Catalytic, Regiospecific End‐Functionalization of Alkanes: Rhenium‐Catalyzed Borylation under Photochemical Conditions. (2000) (2)
- Aqueous Hydroxide as a Base for Palladium‐Catalyzed Amination of Aryl Chlorides and Bromides. (2003) (2)
- Nickel- and Palladium-Catalyzed Cross-Couplings That Form Carbon—Heteroatom and Carbon—Element Bonds (1998) (2)
- Iridium‐Catalyzed C—H Borylation of Cyclopropanes. (2013) (2)
- Palladium‐Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent. (2001) (2)
- Palladium-Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes. (2022) (2)
- Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. (2003) (2)
- Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides. (1997) (2)
- Sterically Controlled Alkylation of Arenes Through Iridium‐Catalyzed C—H Borylation. (2013) (2)
- Metal Complexes as Catalysts for Carbon—Heteroatom Cross‐Coupling Reactions (2004) (2)
- Hydrocarbon synthesis: Ringing the chains. (2011) (2)
- Correction to “Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex” (2017) (2)
- Direct, Iridium‐Catalyzed Enantioselective and Regioselective Allylic Etherification with Aliphatic Alcohols. (2008) (2)
- Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates. (2010) (1)
- Palladium‐Catalyzed Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Anion Equivalent. (2007) (1)
- Iridium-Catalyzed Arene ortho-Silylation by Formal Hydroxyl-Directed C—H Activation. (2011) (1)
- Iridium‐Catalyzed, Hydrosilyl‐Directed Borylation of Unactivated Alkyl C—H Bonds. (2016) (1)
- Iridium-Catalyzed Allylation of Carbamates (2009) (1)
- Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts. (2015) (1)
- Synthesis, Characterization, and Reactivity of Arylpalladium Cyanoalkyl Complexes: Selection of Catalysts for the α-Arylation of Nitriles. (2002) (1)
- Palladium‐Catalyzed Intermolecular α‐Arylation of Zinc Amide Enolates under Mild Conditions. (2006) (1)
- Catalytic Organometallic Reactions of Ammonia (2011) (1)
- Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. (2003) (1)
- Iridium-Catalyzed Borylation of Secondary Benzylic C—H Bonds Directed by a Hydrosilane. (2013) (1)
- Palladium‐Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines Enhance Reaction Yields. (1998) (1)
- Erratum: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds (Chemical Communications (2009) (5603-5605) DOI: 10.1039/b913949d) (2009) (1)
- Undirected, Homogeneous CH Bond Functionalization: Challenges and Opportunities (2016) (1)
- A C—H Borylation Approach to Suzuki—Miyaura Coupling of Typically Unstable 2—Heteroaryl and Polyfluorophenyl Boronates. (2012) (1)
- Iridium-Catalyzed Borylation of Primary Benzylic C—H Bonds Without a Directing Group: Scope, Mechanism, and Origins of Selectivity. (2015) (1)
- Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes (2023) (1)
- Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydroboration and Dehydroboration. (2022) (1)
- Iridium-Catalyzed N-Allylation of Indoles (2009) (1)
- Enantioselective Monoallylation of Ammonia (2009) (1)
- Mild, Rhodium‐Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Alkenes with Primary and Secondary Amines. (2008) (1)
- Direct, Intermolecular, Enantioselective, Iridium‐Catalyzed Allylation of Carbamates to Form Carbamate‐Protected, Branched Allylic Amines. (2009) (1)
- Transition‐Metal‐Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C–C Bond Formation (2021) (1)
- Palladium‐Catalyzed α‐Arylation of Esters and Protected Amino Acids. (2002) (1)
- Difluorphos Complexes of Palladium and Nickel-Catalyzed α-Arylation of Ketones (2008) (1)
- Iridium-Catalyzed Asymmetric Allylic Etherification (2008) (1)
- Nickel‐Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts. (2015) (1)
- Chemical synthesis. Raising the bar for the "perfect reaction". (2002) (1)
- Enantioselective Total Syntheses of (‐)‐Taiwaniaquinone H (I) and (‐)‐Taiwaniaquinol B (II) by Iridium‐Catalyzed Borylation and Palladium‐Catalyzed Asymmetric α‐Arylation. (2011) (1)
- Palladium-Catalyzed α-Arylation of Esters (2008) (1)
- Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. (2002) (0)
- E ff ects of ligands on the migratory insertion of alkenes into rhodium – oxygen bonds †‡ EDGE ARTICLE (2020) (0)
- Hydrocarbon Functionalization by Late‐Metal Boryls and Chemistry of Titanocene‐Bound Catecholborane (1997) (0)
- Copper‐Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF. (2014) (0)
- A Photochemical Source of Dibromo- and Dichlorocarbene. A Cautionary Tale Regarding the Stereochemistry of Dibromocarbene Addition Reactions. (1987) (0)
- Berichtigung: Palladium‐Catalyzed γ‐Arylation of α,β‐Unsaturated Esters from Silyl Ketene Acetals (2010) (0)
- CCDC 1579924: Experimental Crystal Structure Determination (2017) (0)
- Nickel-Catalyzed Anti-Markovnikov Hydroarylation of Unactivated Alkenes with Unactivated Arenes Facilitated by non-Covalent Interactions (2019) (0)
- A Second‐Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by ( dppf)PdCl2 (2010) (0)
- Control of Diastereoselectivity for Iridium‐Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion. (2013) (0)
- Palladium‐Catalyzed C—N(sp2) Bond Formation: N‐Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes. (1998) (0)
- Controlling First‐Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP‐Ligated Single‐Component Ni(0) Complex. (2014) (0)
- Iridium‐Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α‐Alkoxy Ketones. (2016) (0)
- CCDC 1579922: Experimental Crystal Structure Determination (2017) (0)
- Mild Pd-Catalyzed Amination of Aryl and Heteroaryl Tosylates (2009) (0)
- Special Award in Synthetic Organic Chemistry, Japan: K. Nakanishi / Nauta Pharmacochemistry Award for Medicinal Chemistry and Chemical Biology: C. E. Müller / UCB-Ehrlich Award for Excellence in Medicinal Chemistry: A. Nelson / John C. Bailar Jr. Medal: J. F. Hartwig. (2018) (0)
- Pd-Catalyzed α-Arylation of Zinc Amide Enolates (2006) (0)
- Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N-H Addition. (2023) (0)
- Complete integration of carbene-transfer chemistry into biosynthesis. (2023) (0)
- Palladium-Catalyzed α-Arylation of Esters with Chloroarenes. (2008) (0)
- Asymmetric Allylic Amination with Ammonia Equivalents (2007) (0)
- Palladium‐Catalyzed Arylation of Malonates and Cyanoesters Using Sterically Hindered Trialkyl‐ and Ferrocenyldialkylphosphine Ligands. (2002) (0)
- Iridium-Catalyzed Allylic Amination of Allylic Alcohols (2007) (0)
- Iridium‐Catalyzed Regioselective Silylation of Aromatic and Benzylic C—H Bonds Directed by a Secondary Amine. (2015) (0)
- Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. (2006) (0)
- Selective C—H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction. (2014) (0)
- Rhodium‐Catalyzed Intramolecular, anti‐Markovnikov Hydroamination. Synthesis of 3‐Arylpiperidines. (2006) (0)
- Correction to "Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles". (2016) (0)
- CCDC 1579920: Experimental Crystal Structure Determination (2017) (0)
- Recent Advances in the Discovery of Organometallic Catalysts Using High-Throughput Screening Assays (2004) (0)
- Synthesis of Tropenes by Pd-Catalyzed Double Hydroamination (2006) (0)
- Regio- and Enantioselective Iridium-Catalyzed Allylation of Enamines (2007) (0)
- Borylation, Silylation, Fluorination and Fluoroalkylation (2013) (0)
- Evolution of C-H Bond Functionalization from Methane to Methodology (2016) (0)
- Lawrence Berkeley National Laboratory Recent Work Title Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes Permalink (2014) (0)
- Ru-Catalyzed Regiospecific Borylation of Methyl C-H Bonds (2007) (0)
- Conversion of 1,3-Disubstituted Arenes to Chiral α,α-Diaryl Methylammonium Chlorides Using Arene Borylation. (2009) (0)
- Copper‐Mediated Fluorination of Aryl Iodides. (2012) (0)
- Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis (2018) (0)
- Synthesis and reactivity of compounds containing ruthenium-carbon, -nitrogen, and -oxygen bonds (1990) (0)
- Palladium‐Catalyzed α‐Arylation of Azlactones to Form Quaternary Amino Acid Derivatives. (2003) (0)
- Chemistry of Complexes with Transition Metal Heteroatom Bonds Novel Insertion Chemistry and XH Bond Activation (2012) (0)
- Thioethers from Aryl Halides via Palladium-Catalyzed C-SCross-Coupling (2009) (0)
- A Phosphorus-Carbon Bond Cleavage Reaction of Coordinated Trimethylphosphine in (PMe3)4Ru(OC6H4Me)2. (1990) (0)
- Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines. (2001) (0)
- Iridium-Catalyzed Allylic Substitution with Aromatic andAliphatic Sulfinates (2010) (0)
- Palladium-Catalyzed r-Arylation of Carbonyl Compounds and (2003) (0)
- Iridium‐Catalyzed Regioselective Silylation of Secondary Alkyl C—H Bonds for the Synthesis of 1,3‐Diols. (2014) (0)
- Ir-Catalyzed Borylation and Sequential Functionalization of Arenes (2007) (0)
- Highly Efficient Intermolecular Hydroamination of BicyclicAlkenes (2008) (0)
- Ir(I)/Phosphoramidite-Catalyzed Asymmetric Allylic Amination (2006) (0)
- Ruthenium-Catalyzed Cyclization of Diols to Lactones (2005) (0)
- Direct Amination of Aromatic C-H Bonds Using OximeEsters (2010) (0)
- Lawrence Berkeley National Laboratory Recent Work Title Chemoselective , Enzymatic C – H Bond Amination Catalyzed by a Cytochrome P 450 Containing an Ir ( Me )-PIX Cofactor Permalink (2017) (0)
- Engineering novel tandem catalytic reactions using organometallic catalysts and metalloenzymes (2013) (0)
- Procede de synthese d'arylamines par reaction d'un compose aromatique avec de l'ammoniac ou un amide metallique (2007) (0)
- Ta(V)-Catalyzed Hydroaminoalkylation of Olefins with Dialkylamines (2009) (0)
- CCDC 1566647: Experimental Crystal Structure Determination (2017) (0)
- Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate. (1997) (0)
- Palladium‐Catalyzed Synthesis of Pure, Regiodefined Polymeric Triarylamines. (1999) (0)
- Syn-Selective anti-Markovnikov Intramolecular Hydroamination (2006) (0)
- Chemo‐ and Regioselective Hydrogenolysis of Diaryl Ether C—O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin‐Related Fragments. (2016) (0)
- Regioselective Borylation of the C—H Bonds in Alkylamines and Alkyl Ethers. Observation and Origin of High Reactivity of Primary C—H Bonds β to Nitrogen and Oxygen. (2015) (0)
- Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium. (2006) (0)
- Palladium‐Catalyzed Inter‐ and Intramolecular α‐Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles. (1999) (0)
- CCDC 1840468: Experimental Crystal Structure Determination (2018) (0)
- Site-Selective C-H Fluorination of Pyridines and Diazines with AgF2 (2018) (0)
- Development of Chiral Ligands for the Transition Metal‐catalyzed Enantioselective Silylation and Borylation of C‐H Bonds (2021) (0)
- Directed Evolution of Artificial Metalloenzymes in Whole Cells (2021) (0)
- CCDC 621938: Experimental Crystal Structure Determination (2006) (0)
- Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities (2016) (0)
- Cation Control of Diastereoselectivity in Iridium‐Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H‐Oxazol‐4‐ones and 5H‐Thiazol‐4‐ones. (2014) (0)
- Copper‐Mediated Difluoromethylation of Aryl and Vinyl Iodides. (2012) (0)
- Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C—N Bond Formation with a Commercial Ligand. (2010) (0)
- Desymmetrization of difluoromethylene groups by C–F bond activation (2020) (0)
- Highly Reactive, General, and Long‐Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles. (2005) (0)
- Lawrence Berkeley National Laboratory Recent Work Title Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles , Pyrroles , Benzofurans , and Furans Catalyzed by a Nickel –-Heterocyclic Carbene System Permalink (2015) (0)
- Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction to Form C—N Bonds and Catalytic Arylation of Benzophenone Hydrazone. (1998) (0)
- Corrigendum: Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals (2010) (0)
- Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Equivalent (2007) (0)
- Efficient Amination of Heteroaryl and Aryl Halides Using [(CyPF-t-Bu)PdCl2] (2008) (0)
- Pd-Catalyzed γ-Arylation of α,β-Unsaturated Estersfrom Silyl Ketene Acetals (2010) (0)
- A Highly Efficient Catalyst for Pd-Catalyzed Amination ofAryl Halides (2008) (0)
- Iridium Catalyzed Allylic Substitutions: Mechanism and Catalysts Improvements by Rational Design (2020) (0)
- Nickel and Palladium-Catalyzed Cross-Couplings that Form Carbon-Heteroatom and Carbon-Element Bonds (1997) (0)
- Synthesis of a Highly Reactive (Benzyne)ruthenium Complex: C-C, C-H, N-H, and O-H Activation Reactions. (1989) (0)
- Direct observation of beta-aryl eliminations from Rh(I) alkoxides. (2006) (0)
- Regio‐ and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium—Phosphoramidite Complex. (2003) (0)
- Palladium-catalyzed alpha-arylation of azlactones to form quaternary amino acid derivatives. (2003) (0)
- Iridium-Catalyzed ortho-Silylationof Arenes by Hydroxyl-Directed C-H Activation (2011) (0)
- Regioselective Synthesis of sec - and tert -Allylamines (2007) (0)
- Palladium‐Catalyzed Direct α‐Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex. (1998) (0)
- CCDC 1579921: Experimental Crystal Structure Determination (2017) (0)
- Cover Picture: Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides: A Synergistic Effect of Two Metal Fluorides as Additives (Angew. Chem. Int. Ed. 35/2006) (2006) (0)
- Palladium-catalyzed alpha-arylation of esters and protected amino acids. (2001) (0)
- Kinetic Asymmetric Substitution of Racemic Allylic Esters (2010) (0)
- Design and Serendipity in the Discovery and Development of Homogeneous Catalysts for Organic Synthesis (2010) (0)
- Iridium‐Catalyzed Diborylation of Benzylic C—H Bonds Directed by a Hydrosilyl Group: Synthesis of 1,1‐Benzyldiboronate Esters. (2014) (0)
- Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III). (1997) (0)
- Catalyst for aromatic co, cn and CC bond formation (2001) (0)
- CCDC 1579923: Experimental Crystal Structure Determination (2017) (0)
- Mechanistic and structural characterization of an iridium-containing cytochrome reveals kinetically relevant cofactor dynamics (2023) (0)
- E ff ects of ligands on the migratory insertion of alkenes into rhodium – oxygen bonds †‡ ChemicalScience EDGE ARTICLE (2020) (0)
- True Metal‐Catalyzed Hydroboration with Titanium. (1996) (0)
- Palladium‐Catalyzed Addition of Mono‐ and Dicarbonyl Compounds to Conjugated Dienes. (2005) (0)
- Beta-aryl eliminations from Rh(I) iminyl complexes. (2005) (0)
- Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers (2006) (0)
- Unusual in situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C—O Bond Formation. (2001) (0)
- Palladium‐Catalyzed α‐Arylation of Esters and Amides under More Neutral Conditions. (2004) (0)
- Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. (2004) (0)
- 1-Adamantyl di-tert-Butylphosphine (2008) (0)
- Pd(0)/Ir(I)-Catalyzed Sequential Allylic Isomerization and Substitution (2006) (0)
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