John A. Gladysz
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American organometallic chemist
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John A. Gladyszchemistry Degrees
Chemistry
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#3114
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#698
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Inorganic Chemistry
#94
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#104
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#26
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Chemistry
John A. Gladysz's Degrees
- PhD Chemistry Stanford University
Why Is John A. Gladysz Influential?
(Suggest an Edit or Addition)According to Wikipedia, John A. Gladysz, an organometallic chemist, is a Distinguished Professor and holds the Dow Chair in Chemical Invention at Texas A&M University. Professor Gladysz is a native of the Kalamazoo, Michigan area. He obtained his B.S. degree from the University of Michigan and his Ph.D. degree from Stanford University . He subsequently held faculty positions at UCLA and the University of Utah . He then accepted the Chair of Organic Chemistry at the University of Erlangen-Nuremberg in Germany. In 2008, he returned to North America as a distinguished professor and holder of the Dow Chair in Chemical Invention at Texas A&M University.
John A. Gladysz's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Handbook of fluorous chemistry (2004) (610)
- Carbon in one dimension: structural analysis of the higher conjugated polyynes. (2003) (299)
- Introduction: recoverable catalysts and reagents-perspective and prospective. (2002) (297)
- Update 1 of: Carbon in one dimension: structural analysis of the higher conjugated polyynes. (2006) (223)
- Fluorous chemistry: From biphasic catalysis to a parallel chemical universe and beyond (2002) (188)
- Recoverable catalysts. Ultimate goals, criteria of evaluation, and the green chemistry interface (2001) (187)
- Consanguineous Families of Coordinated Carbon: A ReC4Re Assembly That Is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC⋮CC⋮CRe and +ReCCCCRe+ Adducts and a Radical Cation in Which Charge Is Delocalized between Rhenium Termini (1997) (158)
- Chemistry in fluorous media: a user's guide to practical considerations in the application of fluorous catalysts and reagents (1999) (152)
- Frontiers in Metal-Catalyzed Polymerization: Designer Metallocenes, Designs on New Monomers, Demystifying MAO, Metathesis Déshabillé. (2000) (149)
- Fluorous catalysis under homogeneous conditions without fluorous solvents: a "greener" catalyst recycling protocol based upon temperature-dependent solubilities and liquid/solid phase separation. (2003) (147)
- Highly active thermomorphic fluorous palladacycle catalyst precursors for the Heck reaction; evidence for a palladium nanoparticle pathway. (2002) (127)
- Convenient one-flask synthesis of dialkyl selenides and diselenides via lithium triethylborohydride reduction of Sex (1978) (127)
- Thermomorphic fluorous imine and thioether palladacycles as precursors for highly active Heck and Suzuki catalysts; evidence for palladium nanoparticle pathways (2003) (126)
- Fluorous catalysis without fluorous solvents: a friendlier catalyst recovery/recycling protocol based upon thermomorphic properties and liquid/solid phase separation. (2001) (123)
- A Step‐Growth Approach to Metal‐Capped One‐Dimensional Carbon Allotropes: Syntheses of C12, C16, and C20 μ‐Polyynediyl Complexes (1996) (121)
- Molecular gyroscopes: [Fe(CO)(3)] and [Fe(CO)(2)(NO)](+) rotators encased in three-spoke stators; facile assembly by alkene metatheses. (2004) (116)
- A synthetic breakthrough into an unanticipated stability regime: a series of isolable complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 polyynediyl chains span two platinum atoms. (2006) (113)
- Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes (1999) (113)
- Gyroscope-like molecules consisting of PdX2/PtX2 rotators encased in three-spoke stators: synthesis via alkene metathesis, and facile substitution and demetalation. (2006) (104)
- Synthesis and electrophile-induced disproportionation of the neutral formyl triphenylphosphinenitrosyl-.eta.-cyclopentadienylrhenium formyl ((.eta.-C5H5)Re(NO)(PPh3)(CHO)) (2002) (99)
- Are teflon "ponytails" the coming fashion for catalysts? (1994) (98)
- Synthesis, structure, and reactivity of sp carbon chains with bis(phosphine) pentafluorophenylplatinum endgroups: butadiynediyl (C4) through hexadecaoctaynediyl (C16) bridges, and beyond. (2003) (97)
- Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroboration (1997) (92)
- A synthetic breakthrough into an unanticipated stability regime: readily isolable complexes in which C16-C28 polyynediyl chains span two platinum atoms. (2005) (88)
- Syntheses, properties, and x-ray crystal structures of stable methylidene complexes of the formula [(.eta.-C5Me5)Re(NO)(L)(:CH2)]+ PF6- (1983) (85)
- A NEW FORM OF COORDINATED CARBON: AN UNSUPPORTED LINEAR C3 CHAIN SPANNING TWO DIFFERENT TRANSITION METALS (1993) (85)
- Synthesis, Structure, and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M', and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CLi) and (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CC.tplbond.CLi) (1995) (85)
- Additions of PH(3) to Monosubstituted Alkenes of the Formula H(2)C=CH(CH(2))(x)()(CF(2))(y)()CF(3): Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkylphosphines with Modulated Electronic Properties and Fluorous Phase Affinities. (1998) (84)
- A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated tetrayne. (2012) (81)
- Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts. (2012) (79)
- Highly selective detection of silver in the low ppt range with ion-selective electrodes based on ionophore-doped fluorous membranes. (2010) (78)
- Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates (1979) (74)
- New families of coordinated carbon: oxidative coupling of an ethynyl complex to isolable and crystallographically characterized MC.tplbond.CC.tplbond.CM and +M:C:C:C:C:M+ assemblies (1993) (73)
- Gyroscopes and the chemical literature: 1852–2002☆ (2007) (73)
- sp carbon chains surrounded by sp(3) carbon double helices: coordination-driven self-assembly of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages. (2007) (73)
- New Forms of Coordinated Carbon: Wirelike Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer (1998) (72)
- Bonding and electronic structure in consanguineous and conjugal iron and rhenium sp carbon chain complexes [MC4M'](n)+: computational analyses of the effect of the metal. (2003) (71)
- Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities (1997) (70)
- Transition Metal Formyl Complexes (1982) (69)
- Phase transfer of enantiopure Werner cations into organic solvents: an overlooked family of chiral hydrogen bond donors for enantioselective catalysis. (2008) (69)
- "Catalyst-on-a-tape"-Teflon: a new delivery and recovery method for homogeneous fluorous catalysts. (2005) (68)
- New methodology for the introduction of sulfur into organic molecules (1979) (67)
- Molecular wires in single-molecule junctions: charge transport and vibrational excitations. (2010) (65)
- Sp carbon chains surrounded by sp3 carbon double helices: a class of molecules that are accessible by self-assembly and models for "insulated" molecular-scale devices. (2002) (65)
- C8 and C12 sp Carbon Chains That Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11-Hexayne (1999) (65)
- A promising new catalyst family for enantioselective cycloadditions involving allenes and imines: chiral phosphines with transition metal–CH2–P: linkages (2006) (65)
- Aldehyde and ketone ligands in organometallic complexes and catalysis (1988) (65)
- "Giant" gyroscope-like molecules consisting of dipolar Cl-Rh-CO rotators encased in three-spoke stators that define 25-27-membered macrocycles. (2006) (64)
- sp carbon chains surrounded by sp(3) carbon double helices: directed syntheses of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages via alkene metathesis. (2007) (63)
- Binuclear and mixed metal formyl complexes: isolation, characterization, and chemistry (1978) (61)
- Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((CC)n-p-C6H4Me) (1999) (59)
- Organometallic reactivity patterns in fluorocarbons and implications for catalysis: Synthesis, structure, solubility, and oxidative additions of a fluorous analogue of Vaska's complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2) 5CF3)3]2 (1998) (59)
- Bent and stretched but not yet to the breaking point: C(8)-C(16) sp carbon chains that span two platinum atoms and the first structurally characterized 1,3,5,7,9,11,13,15-octayne. (2001) (59)
- A VERSATILE NEW ROUTE TO CARBON COMPLEXES OF THE FORMULA LNMC.TPLBOND.CM'L'N': DEPROTONATION AND METALATION OF THE TERMINAL ACETYLIDE COMPLEX (.ETA.5-C5ME5)RE(NO)(PPH3)(C.TPLBOND.CH) (1992) (59)
- Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumulenic C5 Chain that Mediates Charge Transfer between Rhenium and Manganese Termini† (1994) (59)
- Synthesis, structure, dynamic behavior, and reactivity of rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PR2): the gauche effect in transition-metal chemistry (1988) (57)
- Cubic nonlinear optical properties of platinum-terminated polyynediyl chains. (2008) (57)
- Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis (2015) (57)
- Transition metal catalysis in fluorous media: Application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes (1998) (55)
- Potentiometric sensors based on fluorous membranes doped with highly selective ionophores for carbonate. (2011) (55)
- Synthesis of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers: a convenient one-flask preparation of metal alkyls, metal acyls, and mixed-metal compounds (1979) (54)
- Syntheses and reactivities of disubstituted and trisubstituted fluorous pyridines with high fluorous phase affinities: solid state, liquid crystal, and ionic liquid-phase properties. (2002) (54)
- Electrophile-induced disproportionation of the neutral formyl (.eta.-C5H5)Re(PPh3)(NO)(CHO). Generation of cationic rhenium carbenes of the formula [(.eta.-C5H5)Re(PPh3)(NO)(CHX)]+ (X = hydrogen, methoxy, hydroxy) (1979) (53)
- Electronic Structure and Chain‐Length Effects in Diplatinum Polyynediyl Complexes trans,trans‐[(X)(R3P)2Pt(CC)nPt(PR3)2(X)]: A Computational Investigation (2004) (52)
- How to insulate a reactive site from a perfluoroalkyl group: photoelectron spectroscopy, calorimetric, and computational studies of long-range electronic effects in fluorous phosphines P((CH(2))(m)(CF(2))(7)CF(3))(3). (2002) (52)
- Catalysis of Intramolecular Morita–Baylis–Hillman and Rauhut–Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Protocols Involving Precipitation, Teflon® Tape, and Gore‐Rastex® Fiber (2008) (51)
- Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age. (2003) (49)
- Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands. (2004) (48)
- Gyroscope-like molecules consisting of three-spoke stators that enclose "switchable" neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species. (2006) (48)
- Introduction: Enantioselective Catalysis (2003) (48)
- Tris(1,2-diphenylethylenediamine)cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds. (2016) (48)
- Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nu (1988) (48)
- Synthesis and properties of [(.eta.-C5H5)Re(NO)(PPh3)(:CHC6H5)]+PF6-: a benzylidene complex that is formed by a stereospecific .alpha.-hydride abstraction, exists as two geometric isomers, and undergoes stereospecific nucleophilic attack (1982) (48)
- Octahedral Gyroscope-Like Molecules with M(CO)3(X) Rotators Encased in Three-Spoked Diphosphine Stators: Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities (2007) (48)
- Synthetic approaches to the chiral, pyramidal, transition-metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+X-. Generation, characterization, and reactions of a dichloromethane adduct (1989) (47)
- Fluorous membrane ion-selective electrodes for perfluorinated surfactants: trace-level detection and in situ monitoring of adsorption. (2013) (47)
- Synthesis, optical resolution, and absolute configuration of pseudotetrahedral organorhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(X) (1982) (47)
- Syntheses and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Trialkylphosphanes: Precision Tuning of Electronic Properties, Including Insulation of the Perfluoroalkyl Groups (2000) (46)
- Syntheses and reactivity of analogues of grubbs' second generation metathesis catalyst with fluorous phosphines : A new phase-transfer strategy for catalyst activation (2007) (46)
- Synthesis and reactivity of fluorous and nonfluorous aryl and alkyl iodine(III) dichlorides: new chlorinating reagents that are easily recycled using biphasic protocols. (2009) (45)
- Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Ponytails; New Candidates for Phase Transfer Catalysts and Ionic Liquids (2006) (45)
- Cleavage of the rhenium-methyl bond of (.eta.-C5H5)Re(NO)(PPh3)(CH3) by protic and halogen electrophiles: stereochemistry at rhenium (1984) (45)
- Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Substitution on the Efficiencies of Macrocyclizations That Join trans Positions of Square-Planar Platinum Complexes (2003) (45)
- Syntheses, chemical properties, and x-ray crystal structures of rhenium formaldehyde and thioformaldehyde complexes (1983) (44)
- Strategy and design in fluorous phase immobilization:a systematic study of the effect of ‘pony tails’ (CH2)3(CF2) n−1CF3 on the partition coefficients of benzenoid compounds (2000) (44)
- Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen-Bond-Donor Catalysts for Highly Enantioselective Michael Additions. (2016) (43)
- An isolable organometallic cation radical in which a C4 chain conducts charge between two chiral and configurationally stable rhenium termini (1993) (43)
- SYNTHESIS AND CRYSTAL STRUCTURE OF THE CONJUGATED TETRAYNE (ETA 5-C5ME5)RE(NO)(PPH3)(C=CC=CC=CC=CSIME3) : APPLICATION OF THE CADIOT-CHODKIEWICZ COUPLI NG REACTION TO THE CHAIN EXTENSION OF METAL-CAPPED SP-CARBON WIRES (1997) (43)
- Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition (1983) (41)
- Syntheses of Enantiopure Bifunctional 2‑Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon−Carbon Bond Forming Reactions (2014) (40)
- Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands (2012) (40)
- Fluorophilic ionophores for potentiometric pH determinations with fluorous membranes of exceptional selectivity. (2008) (40)
- Syntheses of gyroscope-like molecules via three-fold ring closing metatheses of bis(phosphine) complexes trans-LyM(P((CH2)nCHCH2)3)2, and extensions to bis(phosphite) complexes trans-Fe(CO)3(P(O(CH2)nCHCH2)3)2 (2008) (40)
- Selective binding and activation of one aldehyde enantioface by a chiral transition-metal Lewis acid: synthesis, structure, and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-O:CHR)]+X- (1990) (40)
- Fluorous phase-transfer activation of catalysts: application of a new rate-enhancement strategy to alkene metathesis. (2006) (40)
- Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells. (2014) (39)
- Synthesis, structure, and alkylation of chiral vinylrhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(CX:CHR) (X = H, OCH3). A mechanistic study of 1,3-asymmetric induction from rhenium to carbon (1987) (39)
- Toward Permetalated Alkyne/Azide 3 + 2 or “Click” Cycloadducts (2012) (39)
- Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts. (2016) (38)
- Convenient syntheses of fluorous aryl iodides and hypervalent iodine compounds: ArI(L)n reagents that are recoverable by simple liquid/liquid biphase workups, and applications in oxidations of hydroquinones. (2003) (38)
- Synthesis, structure, and reactivity of allene complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1992) (38)
- Selective activation of one methyl ketone enantioface via .sigma.-binding to a chiral transition-metal template: synthesis, structure, and reactivity of rhenium ketone complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(CH3)R)]+X- (1990) (37)
- Synthesis, Structure, and Oxidative Additions of a Fluorous Analogue of Vaska's Complex, trans‐[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2]— Altered Reactivity in Fluorocarbons and Implications for Catalysis (1997) (37)
- Gyroscope-Like Complexes Based on Dibridgehead Diphosphine Cages That Are Accessed by Three-Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)(+), and Fe(CO)3(H)(+) Rotators. (2016) (36)
- Phase Transfer Activation of Fluorous Analogs of Grubbs’ Second-Generation Catalyst: Ring-Opening Metathesis Polymerization (2012) (36)
- Introduction to frontiers in transition metal catalyzed reactions (and a brief adieu). (2011) (36)
- Structural, physical, and chemical properties of fluorous compounds. (2012) (36)
- Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations (2002) (35)
- Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction (1983) (35)
- Gyroscope-like molecules consisting of PdX₂/PtX₂ rotators within three-spoke dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties. (2014) (35)
- Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n = 6, 8, 10) (2001) (35)
- .alpha.-Silyloxy and .alpha.-hydroxy manganese alkyls. Generation via a new five-membered metallocycle (1978) (34)
- Structures and unexpected dynamic properties of phosphine oxides adsorbed on silica surfaces. (2014) (34)
- Deprotonation and anionic rearrangements of organometallic compounds. 5. Kinetic vs. thermodynamic deprotonation in reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases (1986) (34)
- Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes (2000) (34)
- Longitudinally Extended Molecular Wires Based upon PtC⋮CC⋮CC⋮CC⋮C Repeat Units: Iterative Syntheses of Functionalized Linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt Assemblies (2004) (33)
- Highly Active Families of Catalysts for the Ring-Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole (2014) (33)
- One-flask preparation of analytically pure dipotassium tetracarbonylferrate (1978) (33)
- Generation and reactions of chiral, pyramidal, transition-metal Lewis acids, .eta.5-cyclopentadienylnitrosyl(triphenylphosphine)rhenium(1+) complexes (1986) (33)
- Olefin metatheses in metal coordination spheres: versatile new strategies for the construction of novel monohapto or polyhapto cyclic, macrocyclic, polymacrocyclic, and bridging ligands. (2001) (33)
- Dibridgehead diphosphines that turn themselves inside out. (2011) (33)
- Metal-Templated Hydrogen Bond Donors as “Organocatalysts” for Carbon–Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes (2014) (33)
- Synthesis, structure, and reactivity of transition metal/main group metal bridging carboxylate complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb) (1987) (33)
- Transition metal catalysis in fluorous media: extension of a new immobilization principle to biphasic and monophasic rhodium-catalyzed hydrosilylations of ketones and enones (1999) (32)
- “Click” Chemistry in Metal Coordination Spheres: Copper(I)-Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol3P)2Pt(C≡C)nH (n = 2−6) (2009) (32)
- Synthesis and reactivity of metallacyclic manganese .alpha.-(silyloxy)alkyl complexes [cyclic] (CO)4MnC(R)(OSi(CH3)3)P(C6H5)2. A new thermodynamic driving force for carbonyl insertion (1986) (32)
- New mechanistic probes of hydride abstraction from rhenium-alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) by Ph3C+ PF6-. Evidence for initial electron transfer (1987) (32)
- ChemInform Abstract: Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Precursors to Highly Active Catalysts for the Suzuki Coupling. (2002) (32)
- A Metal-Capped Conjugated Polyyne Threaded through a Phenanthroline-Based Macrocycle. Probing beyond the Mechanical Bond to Interactions in Interlocked Molecular Architectures (2013) (32)
- Synthesis, structure, and reactivity of functionalized germyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(GePh2X): equilibria involving the germylene complex [(.eta.5-C5H5)Re(NO)(PPh3)(:GePh2)]+ TfO- (1991) (32)
- Synthesis and chemistry of chiral rhenium acyls (.eta.-C5H5)Re(NO)(PPh3)(COR) (1983) (31)
- Generation and reactions of ruthenium phosphido complexes [(eta5-C5H5)Ru(PR'3)2(PR2)]: remarkably high phosphorus basicities and applications as ligands for palladium-catalyzed Suzuki cross-coupling reactions. (2005) (31)
- Synthesis, structure, and spectroscopic properties of chiral rhenium aromatic aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(O:CHAr)]+X-: equilibria between .pi. and .sigma. aldehyde binding modes (1993) (31)
- Generation and reactivity of substitution-labile dichloromethane and chlorobenzene adducts of the chiral Pentamethylcyclopentadienyl rhenium Lewis acid [(η5-C5Me5)Re(NO)(PPh3)]+ (1994) (31)
- sp Carbon chains surrounded by sp3 carbon double helices: wire-like Pt(CC)nPt moieties that are spanned by two α,ω-diphosphines that bear heteroatoms or alkyl substituents (2007) (31)
- Three-fold intramolecular ring-closing metatheses involving square-planar platinum complexes with cis-phosphorus donor ligands: syntheses, structures, and properties of parachute-like complexes. (2008) (31)
- New families of coordinated carbon: oxidative coupling and cross-coupling of a transition metal butadiynyl complex to bimetallic M–CCCCCCCC–M and M–CCCCCC–M adducts (1994) (31)
- Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles (2014) (30)
- Strained Organic Compounds: Introduction (1989) (30)
- Mechanism of equilibration of diastereomeric chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4-. The metal traverses between alkene enantiofaces without dissociation! (1992) (30)
- A versatile new synthesis of organic compounds with chiral methyl groups: stereochemistry of protolytic rhenium-carbon bond cleavage in chiral alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) (1987) (30)
- Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions: A New Strategy for High-Activity Systems (2005) (30)
- Hydrogen bonding motifs in structurally characterized salts of the tris(ethylenediamine) cobalt trication, [Co(en)3]3+; An interpretive review, including implications for catalysis (2017) (30)
- Olefin metatheses in metal coordination spheres: A new approach to steric shielding in dirhenium sp carbon chain complexes of the formula (η5-C5Me5)-Re(NO)(PR3) (C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5) (2002) (30)
- Mechanism of isomerization of rhenium alkylidene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(:CRCHR'R'')]+X- to alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(RHC:CR'R'')]+X-: an organometallic Wagner-Meerwein-type rearrangement (1991) (29)
- Syntheses of kinetically unstable neutral formyl complexes via Li(C2H5)3BH and "transformylation" reactions of metal carbonyl cations (1982) (29)
- Olefin Metatheses in Metal Coordination Spheres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds (1999) (29)
- Coordination-driven self-assembly, structures, and dynamic properties of diplatinum hexatriynediyl and butadiynediyl complexes in which the sp carbon chains are shielded by sp3 carbon chains: towards endgroup-endgroup interactions. (2008) (29)
- Organometallics Roundtable 2011 (2012) (28)
- Synthesis, crystal structure, and reactions of the 17-valence-electron rhenium methyl complex [(η5-C5Me5)Re(NO)(P(4-C6H4CH3)3)(CH3)]+ B(3,5-C6H3(CF3)2)4−: experimental and computational bonding comparisons with 18-electron methyl and methylidene complexes (2000) (28)
- Oxidations of secondary alcohols to ketones using easily recyclable bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)(n-1)I(OCOCF3)2. (2006) (28)
- Attaching Metal‐Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5‐C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate (1998) (28)
- Synthesis, structure, and reactivity of chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)PPh3)(H2C:CHR)]+ X- (1990) (28)
- Divergent kinetic and thermodynamic acidity in organotransition-metal hydride complexes: synthesis, structure, and reactivity of the rhenium anion of Li+ [(.eta.-C5H5)Re(NO)(PPh3)]-. (1988) (28)
- Highly bulky and electron-rich terminal ruthenium phosphido complexes: new donor ligands for palladium-catalyzed suzuki cross-couplings. (2002) (27)
- Reactions of benzaldehyde with trialkylsilyl metal carbonyl complexes (1979) (27)
- Synthesis, structure, and reactivity of stable alkyl and aryl iodide complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(IR)] +BF4 - (1989) (27)
- Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, in Which the sp Carbon Chains Are Shielded by sp3 Carbon Chains (2004) (27)
- Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Secondary, and Tertiary Aliphatic Amines NH3−x[(CH2)m(CF2)7CF3]x(m = 3−5; x = 1−3) − Fine Tuning of Basicities and Fluorous Phase Affinities (2000) (27)
- Alkylation and acylation of the iron carbonyl anion [(CO)4FeSi(CH3)3]-. Evidence for 1,3-silatropic shifts from iron to acyl oxygen (1984) (26)
- Synthesis of fluorous sulfur/carbon/sulfur pincer ligands and palladium complexes: New catalyst precursors for the Heck reaction (2008) (26)
- Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex (1984) (26)
- Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3‐butadiynyl) Complexes: A New Approach to Steric Shielding in (sp‐Carbon chain)dirhenium Complexes [(η5‐C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5‐C5Me5)] (2003) (26)
- New strategies for enantioselective syntheses of 1-alkyl- and 1,4-dialkyl-1,2,3,4-tetrahydroisoquinolines: diastereoselective additions of nucleophiles and electrophiles to isoquinoline mediated by an easily resolved and recycled chiral transition metal auxiliary (1993) (26)
- Synthesis, structure, and reactivity of chiral rhenium alkyne complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(RC.tplbond.CR')]+BF4- (1991) (26)
- Synthesis and decarboxylation mechanism of the chiral rhenium formate (.eta.-C5H5)Re(NO)(PPh3)(OCHO) (1983) (26)
- A general class of stable alkyl halide complexes: Synthesis, structure, and reactivity of alkyl iodide complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(IR)] +BF4- (1987) (26)
- Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CX): Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C4H3 and C4H4 Species (1995) (26)
- Synthesis and chemistry of chiral vinylrhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(CH:CHR'). Stereoselective reactions with electrophiles and a spontaneous alkylidene to olefin rearrangement (1983) (26)
- Photophysics of diplatinum polyynediyl oligomers: chain length dependence of the triplet state in sp carbon chains. (2008) (26)
- An easily accessed class of recyclable hypervalent iodide reagents for functional group oxidations: bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)n−1I(OCOCF3)2 (2005) (25)
- Enantioselective Synthesis of Organosulfur Compounds via [2,3] Rearrangements of Ylides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary (1995) (25)
- Theoretical study on the spin-state energy splittings and local spin in cationic [Re]-Cn-[Re] complexes. (2005) (25)
- Crystal structure of an unusual bis(fluorous phosphine) ruthenium(III) complex derived from a fluorous Grubbs’ catalyst (2007) (25)
- A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon a Chiral Rhenium Template Containing Two Phosphido Substituents (1987) (25)
- Organometallics Roundtable 2013–2014 (2014) (24)
- A new asymmetric synthesis of cyanohydrins and oxygen-functionalized derivatives: stereoselective addition of cyanide to chiral rhenium aldehyde and ketone complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(O:CRR')]+BF4- (1991) (24)
- Synthesis, structure, and dynamic behavior of rhenium sulfide and sulfoxide complexes of the formula [(.eta.5-C5H5)Re(NO)(L)(XRR')]+X'- (X = S, SO) (1991) (24)
- Convenient syntheses of "heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails. (2004) (24)
- Deprotonation of rhenium terminal acetylide complexes (.eta.5-C5R5)Re(NO)(PPh3)(C.tplbond.CH): generation and reactivity of rhenium/lithium C2 complexes (1992) (24)
- Epimerization of secondary alcohols by new homogeneous, low oxidation-state metal catalysts: carbon-hydrogen bond activation in rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR') (1992) (24)
- High-pressure cycloadditions of pyrones: synthesis of highly functionalized six-membered rings by inhibition of carbon dioxide loss (1977) (24)
- Synthesis and reactivity of functionalized rhenium silyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic rearrangements leading to the disilametallacycle [cyclic] [.eta.5-C5H4Si(CH3)2]Re(NO)(PPh3)[Si(CH3)2] (1988) (23)
- Synthesis and reactivity of stable metallacyclic manganese and rhenium .alpha.-hydroxyalkyl complexes of the formula [cyclic] (CO)4MP(C6H5)2(o-C6H4CHOH) (1986) (23)
- Tungsten-Catalyzed Alkyne Metatheses in Transition-Metal Coordination Spheres: Versatile New Syntheses of Metallamacrocycles (2003) (23)
- 29Si NMR spectra of metal carbonyl silanes by the selective population transfer method (1979) (23)
- Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages. (2006) (23)
- Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5‐C5H5)Re(NO)(PPh3)(NRR') (1992) (23)
- A convenient synthesis of [3.3]paracyclophane (1977) (23)
- Synthesis, properties, and reactions of enantiomerically pure, chiral fluorous phosphines of the formula (menthyl)P(CH2CH2(CF2)n−1CF3)2 (n=6, 8) (1999) (23)
- Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization (2011) (22)
- A general method for the selective binding and activation of one aldehyde enantioface. Synthesis and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-RCHO)]+ PF6- (1986) (22)
- REACTIONS OF (CO)5MNSI(CH3)3 WITH ORGANIC CARBONYL COMPOUNDS (1981) (22)
- Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH2)4CH═CH2 Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses (2010) (22)
- Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone: New cyclometalation and catalyst design strategies. (2006) (22)
- Crystal structure and computational investigation of an analogue of Grubbs' second generation catalyst with a fluorous phosphine. (2012) (22)
- Ionic transformations in extremely nonpolar fluorous media: easily recoverable phase-transfer catalysts for halide-substitution reactions. (2008) (22)
- Synthesis, structure, and reactivity of the thioformaldehyde complex [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-H2C:S)]+ PF6- (1986) (22)
- Three rational syntheses of new stable metal .alpha.-hydroxyalkyl complexes (1981) (22)
- Ionic transformations in extremely nonpolar fluorous media: phase transfer catalysis of halide substitution reactions. (2007) (22)
- Nonenzymic nitrogen fixation by an iron-molybdenum model for nitrogenase. (1973) (21)
- Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula ; Facile Vinylic Deprotonation of a Coordinated Alkene (1991) (21)
- Deprotonation and anionic rearrangements of organometallic compounds. 1. Reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases (1984) (21)
- Reactions of benzylrhenium complexes (.eta.5-C5H5)Re(NO)(L)(CH2Ar) with Ph3C+PF6. Analysis of the Re-C.alpha. rotamers involved in .alpha.-hydride abstraction (1984) (21)
- A convenient preparation of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers; observation and reactions of a bimetallic manganese-formyl intermediate (1977) (21)
- Octahedral Gyroscope-like Molecules Consisting of Rhenium Rotators within Cage-like Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties. (2017) (21)
- Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts Derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3. (2017) (21)
- SYNTHESIS, STRUCTURE, AND REACTIVITY OF POLYMETALLIC C3OME COMPLEXES OF THE FORMULA (ETA 5-C5ME5)RE(NO)(PPH3)(C=CC(OME)=)MM(CO)N (M/M/N = RE/2/9, OS/3 /11) : A NEW FORM OF COORDINATED CARBON IN WHICH A C3 CHAIN LINKS TWO METAL S AND SPANS A THIRD (1997) (20)
- Synthesis and reactivity of metal .alpha.-hydroxyalkyl complexes; generation of (CO)5MCH(C6H5)OH (M = Mn, Re) (1986) (20)
- New method for the activation of metal-bound methyl groups. Oxidative disproportionation to coordinated ethylene and methane (1987) (20)
- Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer complexes derived from P(CH2)5P backbones (2006) (20)
- Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R) (1980) (20)
- "Heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails: facile syntheses from polybromocyclopentadienyl complexes, phase properties, and electronic effects. (2005) (20)
- Synthesis and properties of fluorous arenes and triaryl phosphorus compounds with branched fluoroalkyl moieties (“split pony tails”) (2003) (20)
- Metal–metal interactions across bridging elemental carbon chains: a computational study of odd-carbon complexes (2001) (20)
- Facile separations of enantiomers of chiral organometallic compounds with a Bakerbond Chiralcel HPLC column (1991) (20)
- Syntheses and Structures of Tetraplatinum Bis(polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains (2004) (20)
- Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrangements of Ylides of Diallyl and Dipropargyl Sulfonium Salts. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition-Metal Auxiliary (1994) (19)
- Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties. (2016) (19)
- Launching Werner Complexes into the Modern Era of Catalytic Enantioselective Organic Synthesis. (2020) (19)
- Enantioselective Additions of Stabilized Carbanions to Imines Generated from α-Amido Sulfones By Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt(III) Trications as Hydrogen Bond Donor Catalysts (2017) (19)
- Syntheses and reactions of rhenium vinylidene and acetylide complexes. Unprecedented chirality transfer through a C.tplbond.C triple bond (1982) (19)
- Syntheses and structures of complexes of .alpha.,.beta.-unsaturated carbonyl compounds and the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: divergent kinetic and thermodynamic O:C/C:C and O:C/C.tplbond.C binding selectivities (1993) (19)
- Optical rotation measurements of organometallic compounds: caveats and recommended procedures (1993) (19)
- Towards multistranded molecular wires: syntheses, structures, and reactivities of tetraplatinum bis(polyynediyl) complexes with [upper bond 1 start]Pt-C(x)-Pt-(P(CH2)3P)2-Pt-C(x)-Pt-(P(CH2)3P[upper bond 1 end])2 cores (x = 4, 6, 8). (2010) (19)
- Reactions of organorhenium complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+ PF6-; analysis of the energetics of α-hydride abstraction (1986) (19)
- Reactions of (CO)5MnSiMe3 and CO with aldehydes and cyclic ethers. Syntheses of functionalized pentacarbonylmanganese acyls and homologated organic compounds (1984) (19)
- Generation and reactivity of the chiral rhenium chlorobenzene complex [(η5-C5H5)Re(NO)(PPh3)(ClC6H5)]+BF−4: an improved functional equivalent of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+BF−4 (1990) (19)
- π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Complexes [(η5‐C5H5)Re(NO)(PPh3)(O CHAr)]X (1990) (18)
- Chemistry via metal atom cocondensation: isomerization and complexation reactions of organocyclopropanes and spirocycles (1980) (18)
- Mononuclear anionic formyl complexes; synthesis and properties (1981) (18)
- Direct conversion of aldehydes, esters, and 1,2-oxides to alkanes with carbon skeleton preservation (1974) (18)
- Deoxygenation of epoxides by metal atom co-condensation (1976) (18)
- Analogs of Grubbs' second generation catalyst with hydrophilic phosphine ligands: phase transfer activation of ring closing alkene metathesis. (2011) (18)
- A new form of coordinated carbon : a C3 chain that is anchored by a transition metal on each end and spanned by a third (1993) (18)
- Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer ligands and metal complexes. (2005) (18)
- Substitution and Catalytic Chemistry of Gyroscope‐Like Complexes Derived from Cl–Rh–CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands (2015) (18)
- New C1-Symmetric Ph2C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Propylene Polymerization: Synthetic Approach via Activated Fulvenes† (2010) (18)
- Structures and Dynamics of Secondary and Tertiary Alkylphosphine Oxides Adsorbed on Silica. (2019) (17)
- A New Family of Chelating Diphosphines with Transition-Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System (2002) (17)
- Ring opening metathesis polymerization of an η4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments. (2012) (17)
- New media for classical coordination chemistry: phase transfer of Werner and related polycations into highly nonpolar fluorous solvents. (2013) (17)
- Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten‐ and Molybdenum‐Catalyzed Syntheses of Novel Metallamacrocycles (2004) (17)
- Enantioselective syntheses of organosulfur compounds via [2,3] sigmatropic rearrangements of ylides derived from di(allyl), di(propargyl), and di(benzyl) sulfide complexes; Control of carbon configuration by an easily resolved and recycled rhenium auxiliary (1996) (17)
- Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π‐Aldehyde Complexes [(η5‐C5H5)Re(NO)(PPh3)(η2‐OCHAr)]BF4 (1990) (17)
- New synthetic chemistry of transition metal trialkylsilane complexes (1984) (17)
- Fluorous Solvents and Related Media (2005) (17)
- Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1994) (16)
- Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl2 Species (M = Pt, Pd, Ni). (2017) (16)
- Chiral Tricationic Tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Carbon/Metal Configurations; Matched/Mismatched Effects upon Enantioselectivities with Enantiomeric Chiral Counter Anions (2020) (16)
- Synthesis, conformation, and reactivity of the rhenium phosphide complex (diphenylphosphido)(triphenylphosphine)nitrosyl(.eta.5-cyclopentadienyl)rhenium. The "Gauche effect" in transition metal chemistry (1985) (16)
- Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(CC)zPtLn (2002) (16)
- Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines That Can Turn Themselves Inside Out (2011) (16)
- Synthesis, structure, dynamic behavior, and reactivity of chiral rhenium primary phosphine and phosphido complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(PRH2)]+X- and (.eta.5-C5H5)Re(NO)(PPh3) [P(:)RH] (1992) (15)
- Synthesis, structure, and dynamic behavior of symmetrical cis- and trans-alkene complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: binding selectivities and isomerization processes (1993) (15)
- Introduction of sulphur into organic molecules via lithium triethylborohydride reduction of S8 (1978) (15)
- A new family of chelating diphosphines with a transition metal stereocenter in the backbone: novel applications of "chiral-at-rhenium" complexes in rhodium-catalyzed enantioselective alkene hydrogenations. (2001) (15)
- Deoxygenation and desulfurization of organic compounds via transition metal atom cocondensation (1980) (15)
- Monophasic and biphasic hydrosilylations of enones and ketones using a fluorous rhodium catalyst that is easily recycled under fluorous-organic liquid-liquid biphasic conditions (2005) (15)
- Synthesis, structure, and reactivity of the nitrosyl ligand/Lewis acid adduct (.eta.5-C5H5)Re(NO-BCl3)(PPh3)(SiMe2Cl) (1990) (15)
- Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+. Enantioselective Syntheses of 3-Substituted Cycloalkanones (1995) (15)
- Mono- and disubstitution reactions of gyroscope like complexes derived from Cl Pt Cl rotators within cage like dibridgehead diphosphine ligands (2016) (15)
- Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring-Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR (2016) (15)
- Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands. (2015) (15)
- Origin of Shielding and Deshielding Effects in NMR Spectra of Organic Conjugated Polyynes. (2019) (15)
- Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5‐C5H5)Re(NO)(PPh3)(SiMe2X); New Base‐Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base‐Free Silylene Complexes (1991) (14)
- New Chiral Cyclopentadienylrhenium Lewis Acids Featuring Fluorinated Triarylphosphanes and Enhanced Acceptor Abilities − An Unusual Carbon−Fluorine Bond Activation in a Metal Coordination Sphere (2001) (14)
- Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1988) (14)
- Metal complexes of sulfur-containing ligands. Synthesis and properties of a series of rhenium-substituted sulfonium salts [(.eta.5-C5H5)Re(NO)(PPh3)(CH2)]nS+(CH3)3-n(n = 1-3) (1986) (14)
- Bimetallic anionic formyl complexes: synthesis and properties (1983) (14)
- Transition metal formyl complexes: Synthesis by trialkylborohydride attack on metal carbonyl acyls (1978) (14)
- Configurational processes in coordinated ligands. Extremely facile phosphorus inversion in the pyramidal terminal phosphide complexes (.eta.5-C5H5)Re(NO)(PPh3)(PRR') (1985) (14)
- Synthesis, structure, and reactivity of bridging halide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)]2X+ BF4-. Preferential binding of one enantiomer of halide complexes (.eta.5-C5H5)Re(NO)(PPh3)(X) by the chiral Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1989) (14)
- Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts (2020) (14)
- Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3 (2010) (14)
- The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents (2018) (14)
- Main-Group Chemistry: Introduction (1990) (14)
- Stereoselective addition of cyanide ion to chiral rhenium π-aldehyde complexes of the formulae [(η5-C5H5)Re(NO)(PPh3)(η2-OCHR)]+ BF4− (1989) (14)
- Organic transformations via metal silane reagents: syntheses of vinyl ethers from dimethyl ketals and (CO)5MnSi(CH3)3 (1982) (14)
- Configurational equilibria in amido and lithioamido complexes of formulas ({eta}{sup 5}-C{sub 5}H{sub 5})Re(NO)(PAr{sub 3})(NHCHRR`) and ({eta}{sup 5}-C{sub 5}H{sub 5})Re(NO)(PAr{sub 3})(NLiR``): Epimerization occurs at rhenium via phosphine dissociation (1996) (13)
- The Experimental Assay of Catalyst Recovery: General Concepts (2009) (13)
- Substituent effects upon alkyl migration to coordinated CO. Syntheses and carbonylation studies of (CO)5MnCH2I and (CO)5MnCH2OSiMe3 (1982) (13)
- Syntheses, Structures, and Electronic and Photophysical Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C 6 F 5 )(R 3 P) 2 Pt, ( p -tol)(R 3 P) 2 Pt, and (Ph 3 P)Au End-Groups (2008) (13)
- Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes (2010) (13)
- Fluorous to the Core (2006) (13)
- Synthesis, structure, and reactivity of (pentamethylcyclopentadienyl)rhenium aldehyde complexes [(.eta.5-C5Me5)Re(NO)(PPh3)(.eta.2-O:CHR)]+ BF4-: highly diastereoselective deuteride additions (1992) (13)
- A Nontemplated Route to Macrocyclic Dibridgehead Diphosphorus Compounds: Crystallographic Characterization of a "Crossed-Chain" Variant of in/out Stereoisomers. (2018) (13)
- Facile and Selective Carbonylation of Methane in Superacids (2002) (13)
- Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1992) (13)
- Reactions of the rhenium cyanomethyl complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) and ylide complex [(.eta.5-C5H5)Re(NO)(PPh3)(CH2P(p-tol)3))]+PF6- with n-BuLi/TMEDA: generation, stereospecific alkylation, and basicity of transition-metal-substituted carbanions and ylides (1990) (13)
- Pyrrolyl-N and pyrrolyl-C complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: synthesis, protonation, and rearrangement chemistry (1993) (13)
- Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactions (1991) (13)
- Synthesis and properties of chiral rhenium ether complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(OR2)]+ X- (1990) (13)
- Synthesis, structure, and reactivity of .eta.2-1,3-diene and enyne complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: ozonolysis within a metal coordination sphere (1993) (13)
- Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope-like Iron Carbonyl Complexes Based on Dibridgehead Diarsine Cages (2016) (13)
- Monophosphine and diphosphine ligands for diplatinum polyynediyl complexes: Efficient syntheses of new functionality-containing systems and model compounds (2007) (13)
- Crystallographic and theoretical analyses of the structures of rhenium formyl and acyl complexes of the formula (.eta.5-C5H5)Re(NO)(PR3)(COR') (1987) (13)
- Reactions of rhenium cyclopentadienyl and indenyl dichloromethane complexes of the formula [(.eta.5-CxHy)Re(NO)(PPh3)(ClCH2Cl)]+BF4- with ketones: substitution rates and mechanism (1993) (13)
- Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts (2020) (13)
- Synthesis and reactivity of metallacyclic manganese .alpha.-hydroxyalkyl complexes containing aliphatic bridges and phosphorus and nitrogen donor atoms; first carbonylation of an isolable .alpha.-hydroxyalkyl complex (1986) (13)
- X-Ray crystal structure and chemical transformations of the neutral metal formyl [(η-C5H5)Re(PPh3)(NO)(CHO)] (1979) (12)
- Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate (1980) (12)
- Lipophilic chiral cobalt (III) complexes of hexaamine ligands: Efficacies as enantioselective hydrogen bond donor catalysts (2019) (12)
- Synthesis, structure, and reactivity of chiral rhenium imine and methyleneamido complexes of the formulas [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-NR'':CRR')]+ TfO- and (.eta.5-C5H5)Re(NO)(PPh3)(N:CRR') (1993) (12)
- A new route to metal alkylidene complexes. Synthesis of ylide adducts (CO)4Fe-CH(R)P+Ar3 from aldehydes, triarylphosphines, and [cyclo] (CO)4FeSi(CH3)2CH2CH2Si(CH3)2 (1983) (12)
- Reactions of t-BuOK and Dibenzyl, Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Highly Diastereoselective or Chemoselective [2,3]-Sigmatropic Rearrangements (1996) (12)
- En route to diplatinum polyynediyl complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold tales, including end-group strategies (2008) (12)
- Reactions of (cyclopentadienyl)rhenium halide complexes (η5-C5H5)Re(NO)(PPh3)(X) with n-BuLi/TMEDA; generation and methylation of lithio- and dilithiocyclopentadienyl ligands (1988) (12)
- Synthesis, structure, and reactivity of chiral rhenium carboxylic and carbonic acid ester complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(X)X')]+ X''- (1992) (12)
- Enantioselective Synthesis: Introduction (1992) (12)
- Synthesis and Structure of σ-Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles (1992) (12)
- Synthesis, structure, and reactivity of the chiral rhenium phenyl complex (.eta.5-C5H5)Re(NO)(PPh3)(C6H5) (1990) (12)
- A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and Are Catalyst Precursors for Heck Reactions (2005) (12)
- An Analogue of Grubbs Third‐Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase‐Transfer Activation of Ring‐Closing Alkene Metathesis (2016) (12)
- Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH2) mCH═CH2)3 (X = -, m = 5-10; X = O, m = 3-5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes. (2018) (12)
- Generation of trans-spanning diphosphine ligands via alkene metathesis: Synthesis, structure, and dynamic behavior of a missing link in a series of square-planar platinum complexes (2006) (12)
- Activation of organic carbonyl compounds by Lewis acids: relative reactivities of .sigma. and .pi. adducts toward nucleophiles and implications for enantioselective addition reactions (1992) (12)
- Simplified in situ syntheses of anhydrous pentacarbonylhydromanganese (1979) (11)
- A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines (2018) (11)
- A Search for pi/sigma Equilibria in Chiral Rhenium Imine Complexes of the Formula [(eta(5)-C(5)H(5))Re(NO)(PPh(3))(N(H)=C(CF(3))X)](+)TfO(-): Investigation of Electronic Effects upon the Binding Mode. (1996) (11)
- A new organometallic photoreaction: interconversion of metal-alkylidene geometric isomers (1982) (11)
- New deoxygenative transformations; reactions of (CO)4Fe[Si(CH3)3]2 with acyclic ethers (1981) (11)
- Electrochemical oxidation of rhenium alkyl complexes of the type [Re(.eta.-C5H5)(NO)(PPh3)R]: implications for the mechanism of hydride abstraction by Ph3C+PF6- (1985) (11)
- Synthesis, Structure, and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Diastereoselective Electrophilic Additions (1994) (11)
- Syntheses, Structures, and Thermal Properties of Gyroscope-like Complexes Consisting of PtCl2 Rotators Encased in Macrocyclic Dibridgehead Diphosphines P((CH2)n)3P with Extended Methylene Chains (n = 20/22/30) and Isomers Thereof (2018) (11)
- Deoxygenation of nitro and nitroso arenes via chromium atom cocondensation (1977) (11)
- An Air and Water Stable Hydrogen Bond Donor Catalyst for the Enantioselective Generation of Quarternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters. (2020) (11)
- Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions (2014) (11)
- Cyclotrimerization of cyclic diynes via metal atom cocondensation; revised structure for the reported “percyclophane-4” (1977) (11)
- Preparation and properties of (η-C5H5)2ZrCl[Si(CH3)3] and (η-C5H5)2Zr[Si(CH3)3]2; trimethylsilyl group transfer from mercury to zirconium (1980) (11)
- Generation of the dichloromethane complex [(η5-C5Me5) Re (NO) (PPh3) (ClCH2Cl)]+ BF4−, and its conversion to the oxidative addition product [(η5-C5Me5) Re (NO) (PPh3) (Cl) (CH2Cl)]+ BF4- (1988) (11)
- Methods for attaching metal-capped sp carbon chains to metalclusters: synthesis, structure and reactivity of rhenium–triosmiumcarbon complexes[(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)10H] (1997) (11)
- Reactions of organocyclopropanes and spirocycles with metal atoms (1979) (11)
- Syntheses and Structures of Unsymmetrically 1,1- and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Enantioface Binding Selectivities and Conformational Equilibria (1994) (10)
- A new carbon-hydrogen bond activation reaction: stereospecific abstraction of vinylic protons from rhenium alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+ BF4- by the base tert-BuO-K+ (1990) (10)
- Synthesis and Reactivity of 1,2‐ and 1,3‐Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo‐DMPE and ‐DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis (2005) (10)
- Cyclopentadienyl Rhenium Complexes (2007) (10)
- Partition Coefficients Involving Fluorous Solvents (2005) (10)
- A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI COMPLEXES OF AROMATIC ALDEHYDES AND A CHIRAL TRANSITION METAL LEWIS ACID : ENANTIOFACE BINDING SEL ECTIVITIES IN SOLUTION CORRELATE TO DISTANCES BETWEEN METAL AND CARBON STER EOCENTERS IN THE SOLID STATE (1996) (10)
- Over four hundred million characters served: 99 volumes, 2567 articles, 85623 pages, and more than 85 million words. (2000) (10)
- Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphosphines that Contain a Rhenium Stereocenter in the Backbone (2002) (10)
- Synthesis, structure, and reactivity of chiral rhenium amine complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(NRR'R'')]+ TfO- (1991) (10)
- Reactions of chiral (.alpha.-methoxyvinyl)rhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(C(OCH3)=CHR) with alkyl halides. Efficient 1,3-asymmetric induction (1985) (10)
- Synthesis and reactivity of chiral rhenium indenyl complexes of the formula [(.eta.5-C9H7)Re(NO)(PPh3)(X)]n+ (1993) (10)
- Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors. (2016) (10)
- Thermodynamic Enantioface‐Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition ‐Metal Lewis Acid; equilibration of diastereoisomeric (cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium complexes ([Re(η5–C5H5)(CH2 = CHR)(NO) (PPh3)]+BF 4−) (1992) (10)
- Werner‐Komplexe mit ω‐Dimethylaminoalkyl‐substitutierten Ethylendiaminliganden: bifunktionale H‐Brückendonor‐Katalysatoren für hoch enantioselektive Michael‐Additionen (2016) (10)
- Delocalized electronic interactions in chiral cyclopentadienylrhenium halide complexes. Valence photoelectron spectra of CpRe(NO)(L)X (Cp=η5-C5H5, η5-C5(CH3)5 ; L=CO, P(C6H5)3; X=Cl, Br, I) (1991) (10)
- Steric control of the in/out sense of bridgehead substituents in macrobicyclic compounds: isolation of new "crossed chain" variants of in/out isomers. (2015) (10)
- Fluorous Chemistry: Scope and Definition (2005) (10)
- Convenient syntheses of fluorous phenols of the formula HOC6H5−n((CH2)3(CF2)7CF3)n (n=1, 2) and the corresponding triarylphosphites (2003) (10)
- New perfluorocarbon system for multilayer growth of anchorage-dependent mammalian cells. (2002) (10)
- Exploratory organometal-sulfur chemistry; syntheses and unusual properties of rhenium CH2SR, CHSRR′, and CHSR]+ complexes (1981) (9)
- Reaction of the cyanomethyl rhenium complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) with n-BuLi/TMEDA; generation, stereospecific alkylation, and basicity of a transition-metal substituted carbanion (1985) (9)
- New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform (2019) (9)
- A computational study of hydrogen bonding motifs in halide, tetrafluoroborate, hexafluorophosphate, and tetraarylborate salts of chiral cationic ruthenium and cobalt guanidinobenzimidazole hydrogen bond donor catalysts; acceptor properties of the “BArf” anion (2020) (9)
- Additions of carbon nucleophiles to acyclic imine complexes of the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3]+: controlling factors in 1,3-asymmetric induction and syntheses of non-racemic organic amines (1998) (9)
- Phase-Transfer Activation of Transition Metal Catalysts. (2015) (9)
- Syntheses of cyclic imine complexes of the chiral rhenium Lewis acid [(ν5-C5H5) Re(NO)(PPh3)]+ by hydride ion abstraction from amido complexes (1994) (9)
- Synthesis of iron carbonyl trimethylsilanes: preparations and interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+[(CO)4FeSi(CH3)3]-, and trans- [Fe(CO)4Si(CH3)3]2 (1981) (9)
- An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2‐Substituted Benzimidazoles (2014) (9)
- Potentiometric Selectivities of Ionophore-Doped Ion-Selective Membranes: Concurrent Presence of Primary Ion or Interfering Ion Complexes of Multiple Stoichiometries. (2019) (9)
- Structures and energies of 10-azatriquinacene and its hydrogenation products: a computational study. (2001) (9)
- Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(η5-C5Me5)Re(NO)(PPh3)(CCCCCAr2)]+BF4− (CAr2=9-fluorenylidene) (2000) (9)
- Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents (2010) (8)
- Optical resolution and absolute configuration of the chiral pentamethylcyclopentadienylrhenium carbonyl complex [(η5-C5Me5)Re(NO)(PPh3)(CO)]+ BF4− (1990) (8)
- The role of virtual halogen d orbitals in the stability and reactivity of rhenium alkyl halide complexes of the form [(.eta.5-C5H5)Re(NO)(PPh3)(XR)]+ (1989) (8)
- Rendering classical hydrophilic enantiopure Werner salts [M(en)3]n+nX- lipophilic (M/n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge. (2020) (8)
- HYDRIDE TRANSFER REACTIONS OF ANIONIC METAL FORMYL COMPLEXES: A MECHANISTIC TEST (1978) (8)
- Synthesis and structure of chiral rhenium allyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CH2C(R') = CHR) (1989) (8)
- Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids: Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements To Give Thiolate Complexes with New Carbon Stereocenters (1996) (8)
- Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes (2005) (8)
- Ponytails: Structural and Electronic Considerations (2005) (8)
- π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(OCRR′)]+X−; a marked electronic effect upon the binding mode (1991) (8)
- Reactions of ketals and acetals with (CO)5MnSi(CH3)3. A new vinyl ether synthesis (1982) (8)
- Preparation and alkylation reactions of K+[(CO)4FeSi(CH3)3]−; Reductive elimination of tetramethylsilane from isolable (CO)4FeRSi(CH3)3 complexes (1981) (8)
- Stereospecific and chemospecific interconversions of the rhenium alkylidene [(η-C5H5)Re(NO)(PPh3)(CHC6H5)]+PF6− and the alkylrhenium (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5) (1980) (8)
- Surfaces and Interfaces: Introduction (1988) (8)
- Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [η5-C5H5)Re(NO)(PPh3)]+ (1992) (8)
- Triisopropylsilyl (TIPS) Alkynes as Building Blocks for Syntheses of Platinum Triisopropylsilylpolyynyl and Diplatinum Polyynediyl Complexes (2019) (8)
- Synthesis and reactivity of functionalized rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PXX'): an unusual carbon tetrachloride 1,3-addition leading to an exo-substituted .eta.4-cyclopentadiene complex (1989) (8)
- Synthesis of a series of ω-dimethylaminoalkyl substituted ethylenediamine ligands for use in enantioselective catalysis (2015) (8)
- Λ-[Co((S,S)-dpen)3]3+ 2I-B(C6F5)4-: A Second Generation Air- and Water-Stable Chiral Solvating Agent for Chirality Sensing (dpen = NH2CHPhCHPhNH2). (2020) (8)
- Temperature-Controlled Catalyst Recycling: New Protocols Based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid/Liquid Phase Separations (2006) (8)
- A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of the Chiral Cationic Rhenium Alkene Complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4- (1995) (8)
- Thione Complexes of Group Vib Pentacarbonyls (1975) (8)
- Gyroscopes and the Chemical Literature, 2002-2020: Approaches to a Nascent Family of Molecular Devices. (2021) (7)
- Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5‐C5H5)Re(NO)(PPh3)(ROH)]⊕BF4⊖ (1990) (7)
- Regiospecific, diastereospecific and enantiospecific nucleophilic additions to chiral monosubstituted alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4− (1990) (7)
- Thermomorphic fluorous phosphines as organocatalysts for Michael addition reactions (2010) (7)
- Photophysics of platinum tetrayne oligomers: delocalization of triplet exciton. (2014) (7)
- A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprotonation of a Chiral, Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon (1995) (7)
- Ene reactions of β-pinene at room temperature and 40 kbar pressure (1978) (7)
- New methods for metal–carbon bond formation; reactions of (OC)5MnSiMe3 with cyclic ethers (1980) (7)
- Synthesis and reactivity of chiral rhenium amine and amide complexes of the formulas [(.eta.5-C5H5)Re(NO)PPh3)(NHRR')]+TfO- and (.eta.5C5H5)Re(NO)(PPh3)NRR') (1990) (7)
- Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η5-C5R5)Re(NO)(PPh3)CN(Ph3P)(ON)Re(η5-C5R‘5)]+TfO- (R, R‘ = H, Me) (1997) (7)
- Synthesis and oxidation of chiral rhenium phosphine methyl complexes of the formula (η5-C5Me5)Re(NO)(PR3)(CH3): in search of radical cations with enhanced kinetic stabilities (2000) (7)
- Ligand wrapping around chromium: Reactions of diphenylmethane, 1,4-diphenylbutane, benzyl ether, and benzyl sulfide with chromium atoms (1978) (6)
- Nucleophilic additions to the chiral rhenium alkene complexes [Re(η5-C5H5)(NO)(PPh3)(H2CCHR)]BF4(R = H, Me, CH2CH2Me, Ph or CH2Ph): regio-, diastereo- and enantio-selectivities (1995) (6)
- Partially Shielded Fe(CO)3 Rotors: Syntheses, Structures, and Dynamic Properties of Complexes with Doubly trans Spanning Diphosphines, trans-Fe(CO)3(PhP((CH2)n)2PPh) (2017) (6)
- New author guidelines for 2014: A format for computational structural data that can be opened with freely available programs such as "mercury"1 (2014) (6)
- Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese; Synthesis of the Ylide Complexes and a New Driving Force for CO Insertion (1984) (6)
- Multifold Ring‐Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities (2014) (6)
- Mechanism of equilibration of diastereomeric rhenium amide complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(NHCHRR'): rhenium versus carbon epimerization (1990) (6)
- Liquid/solid phase transfer activation of Grubbs-type alkene metathesis catalysts; application of silver salts of sulfonated polystyrene (2014) (6)
- Role of chlorides in reactivation of contaminant nickel on fluid catalytic cracking (FCC) catalysts (2021) (6)
- Cleaning of pH Selective Electrodes with Ionophore‐doped Fluorous Membranes in NaOH Solution at 90 °C (2018) (6)
- Introduction: Natural Product Synthesis (2005) (6)
- Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene): “Catalyst-on-a-Tape” (2017) (6)
- Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation (2005) (6)
- Synthesis and structure of the rhenium phenylamido complex re(η5-C5H5)(NO)(PPh3)(NHPh); an unprecedented pyramidal amido ligand (1991) (5)
- Electrochemical oxidation of rhenium alkyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(R): evidence for one-electron charge transfer (1987) (5)
- Vibrational progressions in the valence ionizations of transition metal hydrides: evaluation of metal-hydride bonding and vibrations in (eta(5)-C(5)R(5))Re(NO)(CO)H [R = H, CH(3)]. (2002) (5)
- Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes (2009) (5)
- The selective activation of one methyl ketone enantioface viaσ-binding to a chiral metal template: synthesis and reactivity of rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(η1-Me(R)CO)]+PF6– (1988) (5)
- Award-Winning Organometallic Chemistry and the Adolf-von-Baeyer-Denkmünze of the GDCh (2011) (5)
- Synthesis and reactivity of bimetallic bridging haloalkyl complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)X(CH2)xM(CO)5]+ BF4- (X = iodo, bromo, chloro; M = rhenium, manganese; x = 1, 4) (1993) (5)
- Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions (2021) (5)
- Award-Winning Organometallic Chemistry: the Alfred-Stock-Gedächtnispreis of the GDCh (2011) (5)
- New approaches to high-activity transition-metal catalysts for carbon-carbon bond forming reactions. Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-couplings. (2002) (5)
- Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies (2010) (5)
- Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula [(η5‐C5H5)Re(NO)(PPh3)(CHR)]+ PF −6 A Versatile and Highly Stereoselective Route to Alkene Complexes (1995) (5)
- Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives (2005) (5)
- Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3 (2015) (5)
- A Quest for Atropisomerism in Cojoined Square‐Planar Metal Complexes: Synthesis and Structures of Sterically Congested Diplatinum Ethynediyl Adducts (2017) (5)
- Syntheses and structural analyses of chiral rhenium containing amines of the formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR′) (n = 0, 1) (2010) (5)
- Syntheses, Structures, and Spectroscopic Properties of 1,10-Phenanthroline Based Macrocycles threaded by PtC8Pt, PtC12Pt, and PtC16Pt Axles: Metal-capped Rotaxanes as Insulated Molecular Wires. (2019) (5)
- Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+ (1993) (5)
- Reaction of the ylide complex [(η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3)]PF6– with η-butyl-lithium–tetramethylenediamine; generation and stereospecific alkylation of a transition metal-substituted Wittig reagent (1986) (5)
- Award-Winning Organometallic Chemistry: the Israeli Chemical Society (ICS) Outstanding Young Scientist Prize (2011) (5)
- A phase based approach to insulated molecular wires: Diplatinum octatetraynediyl complexes bearing fluorous trialkylphosphine ligands (2016) (5)
- Transition-Metal Organometallic Chemistry: Introduction (1988) (5)
- An unexpected insertion of acetone into the silicon-carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes (2002) (5)
- Reactions of the terminal rhenium acetylide complex Re(η5-C5H5)(NO)(PPh3)(CCH) and butyllithium; generation, alkylation and stannylation of lithiocarbide complexes of the formula Re(η5-C5H4)(NO)(PPh3)(CCLi)(X = H, Li) (1991) (4)
- Metal‐Catalyzed Olefin Metathesis in Metal Coordination Spheres (2008) (4)
- Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhenium Fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+ (1994) (4)
- The Future of Organometallic Chemistry (2011) (4)
- Surface reactivity studies of bimetallic complexes, (η5-C5Me5)Re(NO)(PPh3)(CC)n(Ph3P)(ON)Re(η5-C5Me5) (n=2,4,6): candidates for molecular wires (2000) (4)
- Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2PAr2) (2007) (4)
- Trapping of Terminal Platinapolyynes by Copper(I) Catalyzed Click Cycloadditions; Probes of Labile Intermediates in Syntheses of Complexes with Extended sp Carbon Chains, and Crystallographic Studies. (2021) (4)
- Synthesis, Structure, and Reactivity of Chiral Rhenium N‐Pyrrolyl Complexes Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon‐Ligated Species (1995) (4)
- Chapter 3. Fluorous Solvents (2007) (4)
- Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η5-C5R5)Re(NO)(CO)(PPh3)]+: Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6 (1997) (4)
- Π complexes of fluorous alkynes, cyclobutadienes, and benzenes : Syntheses and phase properties of cobalt and chromium tricarbonyl adducts (2006) (4)
- 5,6-dehydro[3.3]Paracyclophane: Bridged benzobarrelene formation by intramolecular trapping of a novel aryne (1976) (4)
- Synthesis, structure, and interconversion of chiral rhenium oxygen- and sulfur-bound sulfoxide complexes of formula [(η5-C5H5)Re(NO)(PPh3)(OS(Me)R)]+ X−; diastereoselective oxidations of coordinated methyl alkyl sulfides (2001) (4)
- Convenient protocols for Mizoroki-Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m-dash]CH(CF2)n-1CF3 (n = 8, 10). (2016) (4)
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- Synthesis, structure, and reactivity of doubly trans-spanning bis(dialkyl selenide) complexes; a new route to diselenamacrocycles via alkene metathesis in metal coordination spheres (2018) (3)
- Fluorous Chemistry and Technology—A Symposium Showcases Ever‐Broadening Frontiers (2005) (3)
- Award-Winning Organometallic Chemistry: Le Grand Prix Achille Le Bel of the Societé Chimique de France (SCF) (2011) (3)
- Award Winning Green Organometallic Chemistry: The Presidential Green Chemistry Challenge (2011) (3)
- Syntheses and structures of σ-pyridine, quinoline, and isoquinoline complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(NCxHy)]+ CF3SO3− (1990) (3)
- The inaugural 2012 Organometallics symposium (2012) (3)
- Macrocyclic Complexes Derived from Four cis-L2 Pt Corners and Four Butadiynediyl Linkers; Syntheses, Electronic Structures, and Square versus Skew Rhombus Geometries. (2021) (3)
- Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtCCCCCCCC]mPtX segments; iterative syntheses and functionalization for measurements of single molecule properties (2019) (3)
- Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity (2017) (3)
- Award-Winning Organometallic Chemistry:1 The 2013 Yao Zeng Award in Organometallic Chemistry (2013) (3)
- Reactions of (CO)5MnSi(CH3)3 with .alpha.-bromo carbonyl and related organic compounds. Facile reductive silylation (1985) (3)
- Award-Winning Organometallic Chemistry: The 2011 RSC Organometallic Chemistry Award (and More) (2013) (3)
- Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives (1989) (3)
- Synthesis and characterization of chiral rhenium σ-ketone complexes. Binding properties of symmetrical ketones and alkylcyclohexanones (1991) (3)
- Synthesis and reactivity of functionalized rhenium germyl complexes (η5-C5H5)Re(NO)(PPh3)(GePh2X); dynamic equilibria with germylene complex [(η5-C5H5)Re(NO)(PPh3)(GePh2)]+X− (1988) (3)
- Electrochemistry - An Introduction (1990) (3)
- Another Great Day for Organometallic Chemistry (2010) (2)
- Crystal structures of diastereomeric styrene complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+: effect of ligating enantioface upon bonding and conformation (1995) (2)
- Synthesis and chemistry of secondary alkyl iodide complexes of the formula[(η5-C5H5)Re(NO)(PPh3)(ICHRR′)]+BF4− (1991) (2)
- Award-Winning Organometallic Chemistry: The 2011 ACS Award in Organometallic Chemistry (2011) (2)
- Award-Winning Organometallic Chemistry:1 The 2012 RSC Sir Geoffrey Wilkinson Award (2013) (2)
- INTRODUCTION OF SULFUR INTO ORGANIC MOLECULES VIA LITHIUM TRIETHYLBOROHYDRIDE REDUCTION OF S8 (1979) (2)
- Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)2(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators (2022) (2)
- Award-Winning Organometallic Chemistry: The Year 2012 Israel Prize (2012) (2)
- Deprotonation and anionic rearrangements of organometallic compounds. Reactions of the hydride complex (η5-C5H5)Re(NO)(PPh3)(H) with n-butyl-lithium–tetramethylethylenediamine (1985) (2)
- Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Precursors to Highly Active Catalysts for the Suzuki Coupling. (2002) (2)
- Carbon reducers for the processes of ferroalloy production in the electric furnace (2008) (2)
- Current situation on the production market of FeMn and FeCr (2012) (2)
- How Do the Electronic Structures of Low-Symmetry Metal−Hydride and −Alkyl Complexes Compare? Photoelectron Spectroscopy and Computational Studies of (η5-C5R5)Re(NO)(L)R‘ (L = CO, P(C6H5)3; R, R‘ = H, CH3) (2002) (2)
- Convenient and Convergent Syntheses of Long‐Chain α,ω‐Dibromides and Diphosphines of the Formula X(CH2)nX (n = 18—32). (2003) (2)
- Computational Investigation of Dichloromethane Ligand Substitution in the Enantiopure Cation [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+, a Functional Equivalent of a Chiral Lewis Acid (2021) (2)
- Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(GeMe2X); Equilibria Involving the Dimethylgermylene Complex [(η5-C5H5)Re(NO)(PPh3)(=GeMe2)]• TfO− (1994) (2)
- Award-Winning Organometallic Chemistry: The 2011 Blaise Pascal Medal of the European Academy of Sciences (2012) (2)
- SYNTHESIS AND PROPERTIES OF ((η-C5H5)RE(NO)(PPH3)(:CHC6H5))+PF6-: A BENZYLIDENE COMPLEX THAT IS FORMED BY A STEREOSPECIFIC α-HYDRIDE ABSTRACTION, EXISTS AS TWO GEOMETRIC ISOMERS, AND UNDERGOES STEREOSPECIFIC NUCLEOPHILIC ATTACK (1982) (2)
- A new catalyst for the epimerization of secondary alcohols: carbon-hydrogen bond activation in the rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR') (1991) (2)
- Efficient syntheses of fluorous primary phosphines that do not require PH3 (2005) (2)
- Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 2,7-Dihydroxynaphthalene (2017) (2)
- Syntheses, rearrangements, and structural analyses of unsaturated nitrogen donor ligands derived from diphenyldiazomethane and the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3)]. (2022) (2)
- Cyclometallapolysulfanes (and Selanes) of Bis(η5‐Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV) (2007) (2)
- Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis (2018) (2)
- Tracking Energy Transfer across a Platinum Center (2022) (1)
- Deprotonation and anionic rearrangements of organometallic compounds: III. The first carbon-carbon bond-forming reaction of an η1-formyl ligand (1985) (1)
- Award-Winning Organometallic Chemistry: The Centennial Sacconi Medal (2012) (1)
- Synthesis, Structure, and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(IR))+BF- 4. (1989) (1)
- Thermomorphic Fluorous Palladacycles (2008) (1)
- Syntheses of Enantiopure 1,2-Ethylenediamines with Tethered Secondary Amines of the Formula H2NCH2CH[(CH2) n NHMe]NH2 (n = 1–4) from α-Amino Acids: New Agents for Asymmetric Catalysis (2020) (1)
- Award-Winning Organometallic Chemistry: The 2012 Klung-Wilhelmy-Weberbank-Preis (2013) (1)
- Fluorous Phase‐Transfer Activation of Catalysts: Application of a New Rate‐Enhancement Strategy to Alkene Metathesis. (2006) (1)
- Synthesis and Reactivity of Metal α-Hydroxyalkyl Complexes; Generation of (CO)5MCH(C6H5)OH (M: Mn, Re). (1986) (1)
- Award-Winning Organometallic Chemistry: The 2012 ACS Award in Organometallic Chemistry (2013) (1)
- Associate Editors, Past, Present, and Future: A Warm Welcome to Professor Deryn E. Fogg (2013) (1)
- Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]C]mPtX segments; iterative syntheses and functionalization for measurements of single molecu (2019) (1)
- Award-Winning Organometallic Chemistry: The 2012 Strem Chemicals Award for Pure or Applied Inorganic Chemistry of the Canadian Society for Chemistry1 (2013) (1)
- Platinum complexes containing or derived from olefinic phosphines P(X)((CH2)6CH CH2)2 (X = OH, Ph, (CH2)6CH CH2); ring closing metatheses, structures, and trans/cis isomerizations (2019) (1)
- Platinum(II) alkyl complexes of chelating dibridgehead diphosphines P((CH2)n)3P (n = 14, 18, 22); facile cis/trans isomerizations interconverting gyroscope and parachute like adducts. (2021) (1)
- Syntheses and structures of square planar diplatinum butadiynediyl complexes with two different monophosphine ligands on each terminus; probing the feasibility of a new type of inorganic atropisomerism ☆ ☆☆ (2017) (1)
- Festschrift in Honor of István T. Horváth (2018) (1)
- Acetylpentacarbonylmanganese and Acetylpentacarbonylrhenium (2007) (1)
- New Perspectives in Coordination Chemistry: Introduction (1993) (1)
- Tranistion Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium‐Catalyzed Hydroboration. (1997) (1)
- Shortwave infrared fluorofluorophores for multicolor in vivo imaging. (2022) (1)
- Announcement: Organometallics Symposium, 2012 (Philadelphia ACS Meeting, August 19–23) (2011) (1)
- Award-Winning Organometallic Chemistry:1 The 2013 Robert Robinson Award of the RSC (2014) (1)
- A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives: Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3) (O=CRR′))+BF4-. (1992) (1)
- Syntheses, Structures, Reactivities, and Basicities of Quinolinyl and Isoquinolinyl Complexes of an Electron Rich Chiral Rhenium Fragment and Their Electrophilic Addition Products. (2021) (1)
- Cover Picture: Molecular Gyroscopes: {Fe(CO)3} and {Fe(CO)2(NO)}+ Rotators Encased in Three‐Spoke Stators; Facile Assembly by Alkene Metatheses (Angew. Chem. Int. Ed. 41/2004) (2004) (1)
- Convenient and Convergent Syntheses of Long-Chain α,ω-Dibromides and Diphosphines of the Formula X(CH2)nX (n = 18-32) (2003) (1)
- Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors. (2015) (1)
- Convenient Syntheses of Fluorous Phenols of the Formula HOC6H5‐n((CH2)3 (CF2)7CF3)n (n = 1,2) and the Corresponding Triarylphosphites. (2003) (1)
- Electronic structure and chain-length effects in diplatinum polyynediyl complexes trans,trans-[(X)(R3P)2Pt(C triple bond C)(n)Pt(PR3)2(X)]: a computational investigation. (2004) (1)
- Deprotonation and Anionic Rearrangements of Organometallic Compounds. (1986) (1)
- Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+. (1988) (1)
- Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes (2004) (1)
- Rhodium(III) Werner Complexes with 1,2‐Diphenylethylenediamine Ligands: Syntheses, Structures, and Applications as Chiral Hydrogen Bond Donor Catalysts and Agents for Enantiomer Purity Determinations (2022) (1)
- Additions of PH3 to Monosubstituted Alkenes of the Formula H2C=CH(CH2)x (CF2)yCF3: Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkylphosphines with Modulated Electronic Properties and Fluorous Phase Affinities. (1999) (1)
- Cover Picture: Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)] (Eur. J. Inorg. Chem. 12/2003) (2003) (1)
- SYNTHESIS AND ELECTROPHILE-INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL TRIPHENYLPHOSPHINENITROSYL-η-CYCLOPENTADIENYLRHENIUM FORMYL ((η-C5H5)RE(NO)(PPH3)(CHO)) (1982) (1)
- Inaugural Schlenk Lecture at the University of Tübingen (2012) (1)
- Reaction: Toward Organic-Solvent-free Synthetic Chemistry (2018) (1)
- Cover Picture: A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 Polyynediyl Chains Span Two Platinum Atoms (Chem. Eur. J. 25/2006) (2006) (1)
- Synthesis, Structure, and Reactivity of Transition-Metal/Main-Group-Metal Bridging Carboxylate Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(CO2MLn) (M: Li, K, Ge, Sn, Pb). (1987) (1)
- Reactive Intermediates: Introduction (1991) (1)
- CLEAVAGE OF THE RHENIUM-METHYL BOND OF (η-C5H5)RE(NO)(PPH3)(CH3) BY PROTIC AND HALOGEN ELECTROPHILES: STEREOCHEMISTRY AT RHENIUM (1985) (1)
- Chiral Recognition in π‐Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids. Development of a General Model for Enantioface Binding Selectivities (1997) (1)
- A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups: Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R). (1987) (1)
- TRANSITION METAL FORMYL COMPLEXES. SYNTHESIS BY TRIALKYLBOROHYDRIDE ATTACK ON METAL CARBONYL ACYLS (1978) (1)
- Metal‐Catalyzed Synthesis of cis‐[Re(CO)4LI] [L = P(OMe)3, PMe2Ph, PPh3] (2007) (1)
- UNPRECEDENTED REGIOSPECIFICITY AND STEREOSPECIFICITY IN REACTIONS OF PH3C+PF6- WITH RHENIUM ALKYLS OF THE FORMULA (η-C5H5)RE(NO)(PPH3)(CH2R) (1980) (1)
- Award-Winning Organometallic Chemistry: The 2012 Werner Prize of the Swiss Chemical Society (2012) (1)
- Co ( NH 2 CHPhCHPhNH 2 ) 3 ] 3 + is a progenitor of broadly applicable chirality and prochirality sensing agents † (2018) (0)
- New Approaches to High-Activity Transition-Metal Catalysts for Carbon—Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Couplings. (2002) (0)
- Reactions of rhenium halide complexes (η5-C5H5)Re(NO)(PPh3)(X) and organocopper nucleophiles; new routes to racemic and optically active hydrocarbyl complexes (η5-C5H5)Re(NO)(PPh3)(R) (1992) (0)
- Chemistry. Fluorous to the core. (2006) (0)
- Structural, Physical, and Chemical Properties of Fluorous Compounds (2012) (0)
- Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts ((η5-C5H5)Re(NO)(PPh3)(CH2-))nS+(CH3)3-n (n = 1-3). (1987) (0)
- Book Reviews 10/99 (1999) (0)
- HIGH-PRESSURE CYCLOADDITIONS OF PYRONES- SYNTHESIS OF HIGHLY FUNCTIONALIZED SIX-MEMBERED RINGS BY INHIBITION OF CARBON DIOXIDE LOSS (1978) (0)
- cis‐[Acetyltetracarbonyl(1‐Hydroxy‐Ethylidene)Rhenium] (cis‐Diacetyltetracarbonylrhenium Hydrogen) (2007) (0)
- Azide- and Fluorine-Containing Polystyrenes as Potential ″Phosphine Sponges″ Based upon Staudinger Reactions: Application to the Phase Transfer Activation of Grubbs’ Catalyst (2022) (0)
- Tails and Steeds Versus Heads and Beads the Case for Fluorous Phase Methodology in Combinatorial and Parallel Syntheses (2001) (0)
- Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(ROH))+BF- 4. (1990) (0)
- Associate Editors Past and Present: A Warm Welcome to Professor Daniel J. Mindiola, and Heartfelt Thanks to Professor Tobin J. Marks (2014) (0)
- Preparations: Sections 11.41 – 11.50 (2005) (0)
- Novel electron impact-induced hydrogen rearrangements in the mass spectra of organorhenium hydrides and alkyls (1986) (0)
- Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η5-C5H5)Re(NO)(PPh3)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands. (1988) (0)
- Title: Analytical Chemistry (2007) (0)
- SYNTHESIS AND CHEMISTRY OF CHIRAL VINYLRHENIUM COMPLEXES (η-C5H5)RE(NO)(PPH3)(CH:CHR′). STEREOSELECTIVE REACTIONS WITH ELECTROPHILES AND A SPONTANEOUS ALKYLIDENE TO OLEFIN REARRANGEMENT (1983) (0)
- Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic Rearrangements Leading to the Disilametallacycle Cyclic (η5-C5H4Si(CH3)2)Re(NO)(PPh3)(Si(CH3)2). (1989) (0)
- Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PR2). The “Gauche Effect” in Transition-Metal Chemistry. (1988) (0)
- Bis[1,3‐Bis(Trifluoromethyl)Benzene] Chromium‐(0), [1,3‐(Cf3)2C6h4]2Cr (2007) (0)
- Preparation and characterization of ligand types intermediate in the metal catalyzed conversion of coal to methane, methanol, and higher alkanes and alcohols. Second technical progress report, September 1, 1979-February 28, 1981 (1980) (0)
- A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η2-RCH=O))+PF- 6. (1987) (0)
- A surprise landing on the terra incognita of macrocyclic dibridgehead diorganoarsines: syntheses, structures, and reactivities. (2022) (0)
- Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η5-C5H5)Re(NO)(PPh3)(PRR′). (2002) (0)
- Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out (2022) (0)
- SYNTHESIS, CONFORMATION, AND REACTIVITY OF THE RHENIUM PHOSPHIDE COMPLEX (DIPHENYLPHOSPHIDO)(TRIPHENYLPHOSPHINE)NITROSYL(η5-CYCLOPENTADIENYL)RHENIUM# . THE “GAUCHE EFFECT” IN TRANSITION METAL CHEMISTRY (1985) (0)
- Thermodynamic Aldehyde Enantiofacial Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η 2-O=CH-Ar))BF4. (1991) (0)
- Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties (“Split Pony Tails”). (2004) (0)
- Cover Picture: Dibridgehead Diphosphines that Turn Themselves Inside Out (Angew. Chem. Int. Ed. 29/2011) (2011) (0)
- Synthesis and characterization of platinum molecular squares comprised of Pt(II) corners and butadiynediyl linkers (0)
- Dedication to the Special Volume for Dietmar Seyferth (2010) (0)
- A Promising New Catalyst Family for Enantioselective Cycloadditions Involving Allenes and Imines: Chiral Phosphines with Transition Metal—CH2—P: Linkages. (2006) (0)
- Divergent Kinetic and Thermodynamic Acidity in Organo‐Transition‐Metal Hydride Complexes: Synthesis, Structure, and Reactivity of the Rhenium Anion of Li+((η5‐C5H5)Re(NO)(PPh3))‐. (1988) (0)
- Book Review, Synthetic Methods of Organometallic and Inorganic Chemistry (1997) (0)
- Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium α-Hydroxyalkyl Complexes of the Formula (CO)4MP(C6H5)2(o-C6H4CHOH). (1986) (0)
- New Mechanistic Probes of Hydride Abstraction from Rhenium-Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R) by Ph3C+PF- 6; Evidence for Initial Electron Transfer. (1987) (0)
- Transition Metal‐Based Fluorous Catalysts (2008) (0)
- Theoretical aspects of platinum (II) polyyne polygons (0)
- A Novel Heterodinuclear Catalyst for Asymmetric Hydrogenation - a Biphosphido Ligand Containing a Stereogenic Rhenium Center. (1987) (0)
- Reactions of Organorhenium Complexes (η5‐C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+PF6‐; Analysis of the Energetics of α‐Hydride Abstraction. (1986) (0)
- Monocyclopentadienyl‐Based Phosphines: Chiral Phosphorous Donor Ligands Containing Monocyclopentadienyl Metal Fragments (2009) (0)
- A General Class of Stable Alkyl Halide Complexes: Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(IR))+BF- 4. (1988) (0)
- REACTION OF THE CYANOMETHYL RHENIUM COMPLEX (η5‐C5H5)RE(NO)(PPH3)(CH2CN) WITH N‐BULI/TMEDA; GENERATION, STEREOSPECIFIC ALKYLATION, AND BASICITY OF A TRANSITION‐METAL SUBSTITUTED CARBANION (1985) (0)
- An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2‐Substituted Benzimidazoles. (2015) (0)
- Building Blocks for Molecular Polygons Based on Platinum Vertices and Polyynediyl Edges (2023) (0)
- Synthesis, Structure, and Alkylation of Chiral Vinylrhenium Complexes (η5-C5H5)Re(NO)(PPh3)(CX=CHR) (X: H, OCH3). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium to Carbon. (1988) (0)
- Isomerization of diastereoisomeric alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+; the alkene enantioface bound to the metal can ‘flip’ without alkene dissociation (1990) (0)
- Book Reviews from Paradise (2011) (0)
- An Unprotected Gearbox is Extremely Hazardous (2019) (0)
- SYNTHESIS OF IRON CARBONYL TRIMETHYLSILANES: PREPARATIONS AND INTERCONVERSIONS OF CIS-(CO)4FE(SI(CH3)3)2, M+((CO)4FESI(CH3)3)-, AND TRANS- (FE(CO)4SI(CH3)3)2 (1982) (0)
- Selective Activation of One Methyl Ketone Enantioface via σ‐ Binding to a Chiral Transition‐Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes ((η5‐C5H5)Re(NO)(PPh3)(. eta.1‐O=C(CH3)R))+X‐. (1991) (0)
- Theoretical investigations of =CH2 coupling of [(η5-C5H5)Re(NO)(PPh3)(=CH2)]+: Remarkable enantiomer self-recognition (2021) (0)
- New flourous media and processes for cleaner and safer chemistry (2004) (0)
- Enantioselective Syntheses of Organosulfur Compounds via (2,3) Sigmatropic Rearrangements of Ylides of Di(allyl) and Di(propargyl) Sulfonium Salts. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition-Metal Auxiliary. (1994) (0)
- Ligand intermediates in metal-catalyzed reactions; Annual technical report, August 1, 1992--August 1, 1993 (1993) (0)
- A crystallographic map of chiral recognition in π complexes of aromatic aldehydes and a chiral transition metal Lewis acid: enantioface binding selectivities in solution correlate to distances between metal and carbon stereocentres in the solid state (1995) (0)
- REACTIONS OF DIPHENYLPHOSPHINOTRIMETHYLSILANE WITH ALKYLPENTACARBONYLMANGANESE; SYNTHESIS OF YLIDE COMPLEXES AND A NEW THERMODYNAMIC DRIVING FORCE FOR THE INSERTION OF CARBON MONOXIDE (1984) (0)
- Correction to The Future of Organometallic Chemistry (2011) (0)
- NEW METHODS FOR METAL-CARBON BOND FORMATION; REACTIONS OF TRIMETHYLSILYLMANGANESEPENTACARBONYL WITH CYCLIC ETHERS (1981) (0)
- Electrophile-Induced Disproportionation of the Neutral Formyl (η-C5H5)Re(NO)(PPh3)(CHO): Isolation and Properties of the Rhenium Methylidene [(η-C5M5)Re(NO)(PPh3)(CH2)]+PF6- (1981) (0)
- Toward Frameworks with Multiple Aligned and Interactive Fe(CO)3 Rotators: Syntheses and Structures of Diiron Complexes Linked by Two trans-Diaxial α,ω-Diphosphine Ligands Ar2P(CH2)nPAr2. (2021) (0)
- Introduction to the Review by Wright, Turrell, and Pickett in This Issue of Organometallics, and a Tip-of-the-Hat to Arnold (Arnie) Rheingold (2010) (0)
- Award-Winning Organometallic Chemistry:1 The 2013 RSC Sir Edward Frankland Fellowship (2014) (0)
- Emerging Organic Reactions: Introduction (1989) (0)
- ORGANIC TRANSFORMATIONS VIA METAL SILANE REAGENTS: SYNTHESES OF VINYL ETHERS FROM DIMETHYL KETALS AND PENTACARBONYL(TRIMETHYLSILYL)MANGANESE (1982) (0)
- A New Form of Coordinated Carbon: An Unsupported C3 Chain Spanning Two Different Transition Metals. (1993) (0)
- Correction to Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity. (2020) (0)
- Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid ((η5‐C5H5)Re(NO)(PPh3))+. Enantioselective Syntheses of 3‐Substituted Cycloalkanones. (1995) (0)
- Frontispiece: Macrocyclic Complexes Derived from Four cis ‐L 2 Pt Corners and Four Butadiynediyl Linkers; Syntheses, Electronic Structures, and Square versus Skew Rhombus Geometries (2021) (0)
- Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions of Chiral Monosubstituted Alkene Complexes of the Formula ((. eta.5‐C5H5)‐Re‐(NO)(PPh3)(H2C=CHR))+ BF4‐. (1991) (0)
- REACTIONS OF PHOSPHORUS ELECTROPHILES WITH ((η5-C5ME5)FE(CO)2)-; SPECTROSCOPIC EVIDENCE FOR A PHOSPHINIDENE COMPLEX (1985) (0)
- Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry. (2022) (0)
- LIGAND WRAPPING AROUND CHROMIUM- REACTIONS OF DIPHENYLMETHANE, 1,4-DIPHENYLBUTANE, BENZYL ETHER, AND BENZYL SULFIDE WITH CHROMIUM ATOMS (1978) (0)
- Theoretical study of enantioselection in carbon-carbon bond forming reactions of ruthenium guanidinobenzimidazole second coordination sphere hydrogen bond donor catalysts (0)
- Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(SiMe2X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base- Free Silylene Complexes. (1991) (0)
- π/σ-Equilibria in Metal Complexes of Organic Carbonyl Compounds: Synthesis and Structure of Chiral Rhenium Complexes ((η 5-C5H5)Re(NO)(PPh3)(O=CH-Ar))X. (1991) (0)
- ELECTROPHILE-INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL (η-C5H5)RE(PPH3)(NO)(CHO). GENERATION OF CATIONIC RHENIUM CARBENES OF THE FORMULA ((η-C5H5)RE(PPH3)(NO)(CHX))+ (X = HYDROGEN, METHOXY, HYDROXY) (1979) (0)
- Synthesis and reactivity of functionalized rhenium phosphido complexes (η5-C5H5)Re(NO)(PPh3)(PXX'): an unusual CCl4 1,3-addition leading to an exo-substituted η4-cyclopentadiene complex (1990) (0)
- A new supramolecular bonding motif involving NH bonds of ammonium salts and macrocycles derived from platinum corners and butadiynediyl linkers. (2022) (0)
- Frontispiece: An Air‐ and Water‐Stable Hydrogen‐Bond‐Donor Catalyst for the Enantioselective Generation of Quaternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters (2020) (0)
- A New Associate Editor, and an Appreciation (2010) (0)
- Organometallics (Roundtable 2011) (2012) (0)
- PREPARATION AND ALKYLATION REACTIONS OF K+((CO)4FESI(CH3)3)-; REDUCTIVE ELIMINATION OF TETRAMETHYLSILANE FROM ISOLABLE (CO)4FERSI(CH3)3 COMPLEXES (1981) (0)
- New Strategies for Enantioselective Syntheses of 1‐Alkyl‐ and 1,4‐ Dialkyl‐1,2,3,4‐tetrahydroisoquinolines: Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary. (1994) (0)
- Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds (1978) (0)
- BINUCLEAR AND MIXED METAL FORMYL COMPLEXES- ISOLATION, CHARACTERIZATION, AND CHEMISTRY (1978) (0)
- Frontiers in Biological Chemistry: Introduction (1987) (0)
- Fluorous Phase‐transfer Catalysts (2009) (0)
- Probing inherent helical preferences in Pt-beanpole complexes using molecular mechanics (2005) (0)
- α‐SILYLOXY AND α‐HYDROXY MANGANESE ALKYLS. GENERATION VIA A NEW FIVE‐MEMBERED METALLOCYCLE (1979) (0)
- Ligand intermediates in metal-catalyzed reactions. Annual technical report, September 1, 1990--August 31, 1991 (1991) (0)
- Synthetic Approaches to the Chiral, Pyramidal, Transition-Metal Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+X-. Generation, Characterization, and Reactions of a Dichloromethane Adduct. (1989) (0)
- Phase‐Transfer Activation of Transition Metal Catalysts (2016) (0)
- Award-Winning Organometallic Chemistry:1 The 2014 RSC Main Group Chemistry Award (2014) (0)
- C8 and C12 sp Carbon Chains that Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11‐Hexayne. (1999) (0)
- Book Review: Organometallics. A Concise Introduction. By C. Elschenbroich and A. Salzer (1990) (0)
- Optical Resolution and Absolute Configuration of the Chiral Pentamethylcyclopentadienylrhenium Carbonyl Complex ((η5-C5Me5)Re(NO)(PPh3)(CO))+BF- 4. (1990) (0)
- Ligand Intermediates in Metal-Catalyzed Reactions (1999) (0)
- A Review of: “ORGANIC SYNTHESIS BY MEANS OF TRANSITION METAL COMPLEXES, by J. Tsuji (Tokyo Institute of Technology). Springer-Verlag, Berlin-Heidelberg-New York, 1975. ix - 199 pp. $27.90” (1977) (0)
- A NEW ROUTE TO METAL ALKYLIDENE COMPLEXES. SYNTHESIS OF YLIDE ADDUCTS (CO)4FE-CH(R)P+AR3 FROM ALDEHYDES, TRIARYLPHOSPHINES, AND (CYCLO) (CO)4FESI(CH3)2CH2CH2SI(CH3)2 (1984) (0)
- A New Method for the Activation of Metal‐Bound Methyl Groups. Oxidative Disproportionation to Coordinated Ethylene and Methane. (1988) (0)
- CYCLOTRIMERIZATION OF CYCLIC DIYNES VIA METAL ATOM COCONDENSATION, REVISED STRUCTURE FOR THE REPORTED ′PERCYCLOPHANE-4′ (1977) (0)
- Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae ((η5-C5H5)Re(NO)(PPh3)(η2-O=CHR))+ BF4-. A New Synthesis of Optically Active Cyanohydrin Derivatives. (1990) (0)
- Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems - A New Approach for Green Catalyst Design (2011) (0)
- Rethinking premedical education (2022) (0)
- Condensed-Phase Dynamics: Introduction (1990) (0)
- Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+ by K((s-C4H9)3BH). Synthesis of Optically Active Secondary Alcohols and Derivatives. (1990) (0)
- SYNTHESES AND REACTIONS OF RHENIUM VINYLIDENE AND ACETYLIDE COMPLEXES. UNPRECEDENTED CHIRALITY TRANSFER THROUGH A CC TRIPLE BOND (1982) (0)
- The 2014 Organometallics Symposium (2014) (0)
- Olefin Metathesis Gyroscope-Like Molecules Consisting of PdX 2 / PtX 2 Rotators within Three-Spoke Dibridgehead Diphosphine Stators : Syntheses , Substitution Reactions , Structures , and Dynamic Properties (2014) (0)
- Upcoming Changes in Cover, Table of Contents, and Structural Graphics (2010) (0)
- Reaction of the Ylide Complex ((η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3))PF6- with n-Butyl-lithium - Tetramethylethylenediamine. Generation and Stereospecific Alkylation of a Transition Metal-Substituted Wittig Reagent. (1987) (0)
- cis‐[Acetyl(1‐Aminoethylidene)‐Tetracarbonylrhenium][cis‐(Acetimidoyl)(Acetyl)‐Tetracarbonylrhenium Hydrogen] (2007) (0)
- Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium‐Catalyzed Hydrosilylations of Ketones and Enones. (2000) (0)
- SYNTHESES, PROPERTIES, AND X-RAY CRYSTAL STRUCTURES OF STABLE METHYLIDENE COMPLEXES OF THE FORMULA ((η-C5ME5)RE(NO)(L)(:CH2))+ PF6- (1983) (0)
- Award-Winning Organometallic Chemistry: The 2012 “Prix de l’Etat” and “Médaille Berthelot” of the French Academy of Sciences (2013) (0)
- Synthesis, Structure, and Reactions of Chiral Rhenium Vinylidene and Acetylide Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(X))n+: Vinylidene Complexes That Are Formed by Stereospecific Cβ Electrophilic Attack, Exist as Two Re=C=C (1988) (0)
- CCDC 1515535: Experimental Crystal Structure Determination (2017) (0)
- Editors’ Comments on the Addition/Correction to “Synthesis, Structure, and Catalytic Studies of Palladium and Platinum Bis-Sulfoxide Complexes” (2014) (0)
- Exploratory High Pressure Chemistry. (1982) (0)
- Cyclopentadienyl(3,5‐dimethoxybenzyl)(nitrosyl)(triphenylphosphine)rhenium (2001) (0)
- A CONVENIENT PREPARATION OF METAL CARBONYL MONOANIONS BY TRIALKYLBOROHYDRIDE CLEAVAGE OF METAL CARBONYL DIMERS, OBSERVATION AND REACTIONS OF A BIMETALLIC MANGANESE-FORMYL INTERMEDIATE (1978) (0)
- Reactions of (CO)5MnSi(CH3)3with α-Bromo Carbonyl and Related Organic Compounds. (1986) (0)
- A New Carbon‐Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes ((η5‐ C5H5)Re(NO)(PPh3)(H2C=CHR))+BF‐ 4 by the Base tBuO‐K+. (1991) (0)
- Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age (2003) (0)
- Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladium Catalyzed Suzuki Cross‐Coupling Reactions. (2014) (0)
- A Versatile New Route to Carbon Complexes of the Formula LnMC CM′L′n′: Deprotonation and Metalation of the Terminal Acetylide Complex (η5‐C5Me5)Re(NO)(PPh3)(CCH). (1992) (0)
- Generation and Reactions of Chiral, Pyramidal, Transition-Metal Lewis Acids of the Formula [(η5-C5H5)Re(NO)(PPh3)]+ X- . (1986) (0)
- A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of “Chiral-at-Rhenium” Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations. (2002) (0)
- Correction to Award-Winning Organometallic Chemistry:1 The 2013 Yao Zeng Award in Organometallic Chemistry (2014) (0)
- Award-Winning Organometallic Chemistry: The 2013 Yao Zeng Award in Organometallic Chemistry (2014) (0)
- Solvent Free Enantioselective Catalysis with Chiral Cobalt(III) Werner Complexes via Ball Milling (2021) (0)
- Selective Binding and Activation of One Aldehyde Enantioface by a Chiral Transition-Metal Lewis Acid: Synthesis, Structure, and Reactivity of Rhenium Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η2-O=CHR))+X-. (1990) (0)
- 5,6-DEHYDRO(3.3)PARACYCLOPHANE- BRIDGED BENZOBARRELENE FORMATION BY INTRAMOLECULAR TRAPPING OF A NOVEL ARYNE (1977) (0)
- Book Review, Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 1 (1996) (0)
- MECHANISM OF COUPLING OF METHYLIDENE TO ETHYLENE AT A HOMOGENEOUS (TRIPHENYLPHOSPHINE)NITROSYL(η-CYCLOPENTADIENYL)RHENIUM(+) ((η-C5H5)RE(NO)(PPH3))+ CENTER. REMARKABLE ENANTIOMER SELF-RECOGNITION (1983) (0)
- Book Review, Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 9 (2001) (0)
- Epimerization of Secondary Alcohols by New Homogeneous, Low Oxidation State Metal Catalysts: Carbon-Hydrogen Bond Activation in Rhenium Alkoxide Complexes (η5-C5R5)Re(NO)(PPh3)(OCHRR′). (1992) (0)
- Theoretical investigation of dichloromethane ligand substitution in [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+, a functional equivalent of a chiral Lewis acid (0)
- Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity. (2022) (0)
- Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(OR2))+X-. (1990) (0)
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