John M. Torkelson
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John M. Torkelsonchemistry Degrees
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Chemistry
John M. Torkelson's Degrees
- PhD Chemistry University of California, Berkeley
- Masters Chemical Engineering Stanford University
Why Is John M. Torkelson Influential?
(Suggest an Edit or Addition)According to Wikipedia, John Mark Torkelson is an American physicist. Torkelson earned his bachelor's degree from the University of Wisconsin–Madison in 1978 and doctorate at the University of Minnesota in 1983. He holds the Walter P. Murphy Professorship in Chemical and Biological Engineering and Materials Science and Engineering at Northwestern University. In 1999, Torkelson was elected a fellow of the American Physical Society "[f]or imaginative and successful applications of fluorescence spectroscopy to polymer physics issues ranging from free volume to free radical polymerization."
John M. Torkelson's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The distribution of glass-transition temperatures in nanoscopically confined glass formers (2003) (931)
- Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between (2005) (602)
- Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites. (2007) (572)
- Spin coating of thin and ultrathin polymer films (1998) (469)
- Crumpled Graphene Nanosheets as Highly Effective Barrier Property Enhancers (2010) (424)
- Polymer–nanoparticle interfacial interactions in polymer nanocomposites: Confinement effects on glass transition temperature and suppression of physical aging (2006) (362)
- Polymer−Graphite Nanocomposites: Effective Dispersion and Major Property Enhancement via Solid-State Shear Pulverization (2008) (283)
- Impacts of polystyrene molecular weight and modification to the repeat unit structure on the glass transition-nanoconfinement effect and the cooperativity length scale (2005) (259)
- On measuring the distribution of local free volume in glassy polymers by photochromic and fluorescence techniques (1987) (233)
- Eliminating the Enhanced Mobility at the Free Surface of Polystyrene: Fluorescence Studies of the Glass Transition Temperature in Thin Bilayer Films of Immiscible Polymers (2007) (190)
- Uniquely Broad Glass Transition Temperatures of Gradient Copolymers Relative to Random and Block Copolymers Containing Repulsive Comonomers (2006) (152)
- Confinement and processing effects on glass transition temperature and physical aging in ultrathin polymer films: Novel fluorescence measurements (2002) (150)
- Vitrimers Designed Both To Strongly Suppress Creep and To Recover Original Cross-Link Density after Reprocessing: Quantitative Theory and Experiments (2018) (135)
- Dispersion and Major Property Enhancements in Polymer/Multiwall Carbon Nanotube Nanocomposites via Solid-State Shear Pulverization Followed by Melt Mixing (2008) (127)
- Fragility is a Key Parameter in Determining the Magnitude of Tg-Confinement Effects in Polymer Films (2013) (125)
- Rotational reorientation dynamics of disperse red 1 in polystyrene: α ‐relaxation dynamics probed by second harmonic generation and dielectric relaxation (1994) (123)
- Sensing the glass transition in thin and ultrathin polymer films via fluorescence probes and labels (2002) (122)
- The roles of phase separation mechanism and coarsening in the formation of poly(methyl methacrylate) asymmetric membranes (1990) (118)
- Confinement effects on glass transition temperature, transition breadth, and expansivity: Comparison of ellipsometry and fluorescence measurements on polystyrene films (2009) (116)
- Dramatic reduction of the effect of nanoconfinement on the glass transition of polymer films via addition of small-molecule diluent. (2004) (114)
- Gradient copolymers with broad glass transition temperature regions: Design of purely interphase compositions for damping applications (2008) (105)
- Orientation and Second Harmonic Generation in Doped Polystyrene and Poly(Methyl Methacrylate) Films (1988) (102)
- Polypropylene-graphite nanocomposites made by solid-state shear pulverization: Effects of significantly exfoliated, unmodified graphite content on physical, mechanical and electrical properties (2010) (100)
- Effect of nanoscale confinement on the glass transition temperature of free‐standing polymer films: Novel, self‐referencing fluorescence method (2008) (100)
- Physical Aging of Ultrathin Polymer Films above and below the Bulk Glass Transition Temperature: Effects of Attractive vs Neutral Polymer−Substrate Interactions Measured by Fluorescence (2005) (98)
- Polymer Blend Compatibilization by Gradient Copolymer Addition during Melt Processing: Stabilization of Dispersed Phase to Static Coarsening (2005) (98)
- Selectively probing the glass transition temperature in multilayer polymer films : Equivalence of block copolymers and multilayer films of different homopolymers (2007) (98)
- Effects of Nanoscale Confinement and Interfaces on the Glass Transition Temperatures of a Series of Poly(n-methacrylate) Films (2007) (97)
- Influence of solvent and molecular weight on thickness and surface topography of spin‐coated polymer films (1990) (97)
- Coarsening effects on microstructure formation in isopycnic polymer solutions and membranes produced via thermally induced phase separation (1994) (95)
- Distribution of Glass Transition Temperatures in Free-Standing, Nanoconfined Polystyrene Films: A Test of de Gennes’ Sliding Motion Mechanism (2011) (95)
- Coarsening effects on the formation of microporous membranes produced via thermally induced phase separation of polystyrene-cyclohexanol solutions (1995) (92)
- Novel Strategy for Polymer Blend Compatibilization: Solid-State Shear Pulverization (2000) (91)
- Cellular structures of carbon nanotubes in a polymer matrix improve properties relative to composites with dispersed nanotubes (2008) (88)
- Second harmonic generation in corona poled, doped polymer films as a function of corona processing (1990) (88)
- Glass transition breadths and composition profiles of weakly, moderately, and strongly segregating gradient copolymers: experimental results and calculations from self-consistent mean-field theory (2009) (86)
- Translation-rotation paradox for diffusion in glass-forming polymers: The role of the temperature dependence of the relaxation time distribution (1997) (85)
- Dopant Orientation Dynamics in Doped Second-Order Nonlinear Optical Amorphous Polymers. 1. Effects of Temperature Above and Below Tg in Corona-Poled Films (1990) (85)
- Glass transition and alpha -relaxation dynamics of thin films of labeled polystyrene. (2007) (84)
- Evidence for the molecular-scale origin of the suppression of physical ageing in confined polymer: fluorescence and dielectric spectroscopy studies of polymer–silica nanocomposites (2007) (84)
- Cellulose nanocrystal/polyolefin biocomposites prepared by solid- state shear pulverization: Superior dispersion leading to synergistic property enhancements (2015) (82)
- Confinement, composition, and spin-coating effects on the glass transition and stress relaxation of thin films of polystyrene and styrene-containing random copolymers: Sensing by intrinsic fluorescence (2006) (82)
- Achievement of quasi-nanostructured polymer blends by solid-state shear pulverization and compatibilization by gradient copolymer addition (2006) (82)
- Recyclable Crosslinked Polymer Networks via One‐Step Controlled Radical Polymerization (2016) (81)
- Reprocessable Polymer Networks via Thiourethane Dynamic Chemistry: Recovery of Cross-link Density after Recycling and Proof-of-Principle Solvolysis Leading to Monomer Recovery (2019) (79)
- Ultrathin polymer films near the glass transition: Effect on the distribution of α-relaxation times as measured by second harmonic generation (1997) (76)
- Biobased Reprocessable Polyhydroxyurethane Networks: Full Recovery of Crosslink Density with Three Concurrent Dynamic Chemistries (2019) (75)
- Fluorescence studies of confinement in polymer films and nanocomposites: Glass transition temperature, plasticizer effects, and sensitivity to stress relaxation and local polarity (2007) (75)
- Reprocessable polyhydroxyurethane networks exhibiting full property recovery and concurrent associative and dissociative dynamic chemistry: Via transcarbamoylation and reversible cyclic carbonate aminolysis (2017) (75)
- Photophysics of polymers (1987) (74)
- Synthesis and Glass Transition Behavior of High Molecular Weight Styrene/4-Acetoxystyene and Styrene/4-Hydroxystyrene Gradient Copolymers Made via Nitroxide-Mediated Controlled Radical Polymerization (2004) (71)
- Reprocessable Polyhydroxyurethane Network Composites: Effect of Filler Surface Functionality on Cross-link Density Recovery and Stress Relaxation. (2019) (71)
- Physical aging effects on molecular-scale polymer relaxations monitored with mobility-sensitive fluorescent molecules (1993) (70)
- Synthesis and application of styrene/4-hydroxystyrene gradient copolymers made by controlled radical polymerization: Compatibilization of immiscible polymer blends via hydrogen-bonding effects (2006) (69)
- Polyethylene/starch blends with enhanced oxygen barrier and mechanical properties: Effect of granule morphology damage by solid-state shear pulverization (2007) (68)
- Stabilization of dispersed phase to static coarsening: Polymer blend compatibilization via solid-state shear pulverization (2002) (68)
- Well-mixed blends of HDPE and ultrahigh molecular weight polyethylene with major improvements in impact strength achieved via solid-state shear pulverization (2014) (67)
- A critical experimental examination of the gel effect in free radical polymerization: Do entanglements cause autoacceleration? (1996) (67)
- Importance of superior dispersion versus filler surface modification in producing robust polymer nanocomposites: The example of polypropylene/nanosilica hybrids (2015) (66)
- Effect of spatial confinement on the glass-transition temperature of patterned polymer nanostructures. (2007) (66)
- Nonisocyanate Thermoplastic Polyhydroxyurethane Elastomers via Cyclic Carbonate Aminolysis: Critical Role of Hydroxyl Groups in Controlling Nanophase Separation. (2016) (65)
- Rotational reorientation dynamics of nonlinear optical chromophores in rubbery and glassy polymers: .alpha.-relaxation dynamics probed by second harmonic generation and dielectric relaxation (1993) (64)
- Green composites of polypropylene and eggshell: Effective biofiller size reduction and dispersion by single-step processing with solid-state shear pulverization (2014) (64)
- Novel thermoplastic polyhydroxyurethane elastomers as effective damping materials over broad temperature ranges (2016) (64)
- Breadth of glass transition temperature in styrene/acrylic acid block, random, and gradient copolymers: Unusual sequence distribution effects (2007) (63)
- Microphase Separation and Shear Alignment of Gradient Copolymers: Melt Rheology and Small-Angle X-Ray Scattering Analysis (2008) (61)
- Photochromic and fluorescent probe studies in glassy polymer matrices. 3. Effects of physical aging and molar weight on the size distribution of local free volume in polystyrene (1988) (61)
- Miscibility and phase separation in poly(methyl methacrylate)/poly(vinyl chloride) blends: study of thermodynamics by thermal analysis (1992) (59)
- Modeling Insight into the Diffusion-Limited Cause of the Gel Effect in Free Radical Polymerization (1999) (57)
- Solid-State Shear Pulverization of Plastics: A Green Recycling Process (1999) (55)
- Major Impact of Cyclic Chain Topology on the Tg-Confinement Effect of Supported Thin Films of Polystyrene (2016) (55)
- Photocurable bioresorbable adhesives as functional interfaces between flexible bioelectronic devices and soft biological tissues (2021) (54)
- Coupling of Probe Reorientation Dynamics and Rotor Motions to Polymer Relaxation as Sensed by Second Harmonic Generation and Fluorescence (1995) (53)
- Nanoscale Confinement and Temperature Effects on Associative Polymers in Thin Films: Fluorescence Study of a Telechelic, Pyrene-Labeled Poly(dimethylsiloxane) (2002) (53)
- Small molecule probe diffusion in thin polymer films near the glass transition: A novel approach using fluorescence nonradiative energy transfer (1996) (53)
- Direct Use of Natural Antioxidant-rich Agro-wastes as Thermal Stabilizer for Polymer: Processing and Recycling (2016) (52)
- Small molecule probe diffusion in thin and ultrathin supported polymer films (1998) (52)
- Suppression of theTg-Nanoconfinement Effect in Thin Poly(vinyl acetate) Films by Sorbed Water (2010) (52)
- Non-Isocyanate Polyurethane Thermoplastic Elastomer: Amide-Based Chain Extender Yields Enhanced Nanophase Separation and Properties in Polyhydroxyurethane (2017) (51)
- Preparation and characterization of multiwalled carbon nanotube dispersions in polypropylene: Melt mixing versus solid‐state shear pulverization (2009) (47)
- Comparison of polyolefin biocomposites prepared with waste cardboard, microcrystalline cellulose, and cellulose nanocrystals via solid-state shear pulverization (2015) (47)
- Comparison of critical micelle concentrations of gradient copolymer and block copolymer in homopolymer: Novel characterization by intrinsic fluorescence (2007) (47)
- Polystyrene-Grafted Silica Nanoparticles: Investigating the Molecular Weight Dependence of Glass Transition and Fragility Behavior (2017) (47)
- Compatibilized polymer blends with nanoscale or sub-micron dispersed phases achieved by hydrogen-bonding effects : Block copolymer vs blocky gradient copolymer addition (2008) (46)
- Methacrylate-based polymer films useful in lithographic applications exhibit different glass transition temperature-confinement effects at high and low molecular weight (2014) (46)
- MICROPOROUS POLY(METHYL METHACRYLATE) MEMBRANES : EFFECT OF A LOW-VISCOSITY SOLVENT ON THE FORMATION MECHANISM (1990) (45)
- Maleic anhydride functionalization of polypropylene with suppressed molecular weight reduction via solid-state shear pulverization (2013) (45)
- An Evaluation of Free Volume Approaches to Describe the Gel Effect in Free Radical Polymerization (1998) (45)
- Streamlined ellipsometry procedure for characterizing physical aging rates of thin polymer films (2009) (45)
- Kinetics of multifunctional thiol-epoxy click reactions studied by differential scanning calorimetry: Effects of catalysis and functionality (2015) (44)
- Dopant orientation dynamics in doped second-order nonlinear optical amorphous polymers. 2. Effects of physical aging on poled films (1990) (44)
- Synthesis and Functionalization of ROMP-Based Gradient Copolymers of 5-Substituted Norbornenes (2004) (44)
- Fragility-Confinement Effects: Apparent Universality as a Function of Scaled Thickness in Films of Freely Deposited, Linear Polymer and Its Absence in Densely Grafted Brushes (2016) (43)
- Sub-micron dispersed-phase particle size in polymer blends: overcoming the Taylor limit via solid-state shear pulverization (2003) (43)
- Processing-Structure-Property Relationships in Solid-State Shear Pulverization: Parametric Study of specific energy (2012) (43)
- Phase-Separated Thiol–Epoxy–Acrylate Hybrid Polymer Networks with Controlled Cross-Link Density Synthesized by Simultaneous Thiol–Acrylate and Thiol–Epoxy Click Reactions (2016) (43)
- Cooperative Catalysis of Cyclic Carbonate Ring Opening: Application Towards Non‐Isocyanate Polyurethane Materials (2015) (41)
- Polyurethane/polyhydroxyurethane hybrid polymers and their applications as adhesive bonding agents (2016) (41)
- Modulus, confinement, and temperature effects on surface capillary wave dynamics in bilayer polymer films near the glass transition. (2012) (39)
- Large enhancement of second harmonic generation in polymer films by microcavities (1999) (39)
- Effect of Gradient Sequencing on Copolymer Order–Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers (2011) (38)
- Substantial spatial heterogeneity and tunability of glass transition temperature observed with dense polymer brushes prepared by ARGET ATRP (2015) (38)
- Sustainable Green Hybrids of Polyolefins and Lignin Yield Major Improvements in Mechanical Properties When Prepared via Solid-State Shear Pulverization (2015) (37)
- In Situ Block Copolymer Formation during Solid-State Shear Pulverization: An Explanation for Blend Compatibilization via Interpolymer Radical Reactions (2002) (37)
- Retardation of rotational reorientation dynamics in polymers near the glass transition: a novel study over eleven decades in time using second-order non-linear optics (1994) (37)
- Second harmonic generation in doped glassy polymer films as a function of physical ageing and dopant size (1989) (37)
- Binary mixture pyrolysis of polypropylene and polystyrene: A modeling and experimental study (2005) (37)
- Polystyrene fluorescence: effects of molecular weight in various solvents (1981) (36)
- Novel, synergistic composites of polypropylene and rice husk ash: Sustainable resource hybrids prepared by solid‐state shear pulverization (2013) (36)
- Mobility‐sensitive fluorescence probes for quantitative monitoring of water sorption and diffusion in polymer coatings (1995) (36)
- Dramatic Tunability of the Glass Transition Temperature and Fragility of Low Molecular Weight Polystyrene by Initiator Fragments Located at Chain Ends (2016) (35)
- Limitations in the Synthesis of High Molecular Weight Polymers via Nitroxide-Mediated Controlled Radical Polymerization: Experimental Studies (2003) (35)
- Residual stress relaxation and stiffness in spin-coated polymer films: Characterization by ellipsometry and fluorescence (2015) (35)
- Tuning nanophase separation behavior in segmented polyhydroxyurethane via judicious choice of soft segment (2017) (35)
- Critical micelle concentrations of block and gradient copolymers in homopolymer: Effects of sequence distribution, composition, and molecular weight (2008) (34)
- Compatibilizing effects of block copolymer mixed with immiscible polymer blends by solid-state shear pulverization: stabilizing the dispersed phase to static coarsening (2005) (33)
- Fluorescence and absorbance of polystyrene in dilute and semidilute solutions (1983) (33)
- Efficient mixing of polymer blends of extreme viscosity ratio : Elimination of phase inversion via solid-state shear pulverization (2000) (33)
- Probe translational and rotational diffusion in polymers near Tg: roles of probe size, shape, and secondary bonding in deviations from Debye–Stokes–Einstein scaling (1998) (33)
- Combined Effects of Carbonate and Soft-Segment Molecular Structures on the Nanophase Separation and Properties of Segmented Polyhydroxyurethane (2017) (33)
- Role of neighboring domains in determining the magnitude and direction of Tg-confinement effects in binary, immiscible polymer systems (2015) (33)
- Influence of cure via network structure on mechanical properties of a free-radical polymerizing thermoset (2002) (32)
- Shear-Induced Orientation in Well-Exfoliated Polystyrene/Clay Nanocomposites (2012) (32)
- Shear-induced orientation in polymer/clay dispersions via in situ X-ray scattering (2010) (32)
- Molecular-scale asymmetry and memory behavior in poly(vinyl acetate) monitored with mobility-sensitive fluorescent molecules (1992) (31)
- Dielectric Relaxation Spectroscopy of Gradient Copolymers and Block Copolymers: Comparison of Breadths in Relaxation Time for Systems with Increasing Interphase (2010) (31)
- Small molecule diffusion in a rubbery polymer near Tg: Effects of probe size, shape, and flexibility (1996) (30)
- Interpolymer radical coupling reactions during sonication of polymer solutions (2003) (30)
- Enhanced Tg-Confinement Effect in Cross-Linked Polystyrene Compared to Its Linear Precursor: Roles of Fragility and Chain Architecture (2016) (30)
- Suppression of the Fragility-Confinement Effect via Low Molecular Weight Cyclic or Ring Polymer Topology (2017) (30)
- Green polypropylene/waste paper composites with superior modulus and crystallization behavior: Optimizing specific energy in solid-state shear pulverization for filler size reduction and dispersion (2016) (30)
- Behavior of gradient copolymers at liquid/liquid interfaces. (2010) (29)
- Two-dimensional coarsening and phase separation in thin polymer solution films (1997) (29)
- Differences in enthalpy recovery of gradient and random copolymers of similar overall composition: styrene/4-methylstyrene copolymers made by nitroxide-mediated controlled radical polymerization (2004) (29)
- Arresting Elevated-Temperature Creep and Achieving Full Cross-Link Density Recovery in Reprocessable Polymer Networks and Network Composites via Nitroxide-Mediated Dynamic Chemistry (2021) (29)
- Reprocessable Polymer Networks Designed with Hydroxyurethane Dynamic Cross‐links: Effect of Backbone Structure on Network Morphology, Phase Segregation, and Property Recovery (2019) (28)
- Poly(methyl methacrylate) nanotubes in AAO templates: Designing nanotube thickness and characterizing the Tg-confinement effect by DSC (2016) (28)
- Photochromic and fluorescent probe studies in glassy polymer matrices. 5. Effects of physical aging on bisphenol A polycarbonate and poly(vinyl acetate) as sensed by a size distribution of photochromic probes (1992) (27)
- Stiffness of thin, supported polystyrene films: Free-surface, substrate, and confinement effects characterized via self-referencing fluorescence (2016) (27)
- Photochromic and fluorescent probe studies in glassy polymer matrices. 4. Effects of physical aging on poly(methyl methacrylate) as sensed by a size distribution of photochromic probes (1992) (26)
- Tg and Tg breadth of poly(2,6-dimethyl-1,4-phenylene oxide)/polystyrene miscible polymer blends characterized by differential scanning calorimetry, ellipsometry, and fluorescence spectroscopy (2015) (26)
- Quantitative analysis of rotational dynamics in doped polymers above and below the glass transition temperature: a novel application of second-order nonlinear optics (1992) (26)
- Styrene/4-hydroxystyrene random, block and gradient copolymers modified with an organic dye: Synthesis by controlled radical polymerization and characterization of electrorheological properties (2006) (25)
- Small-molecule probe diffusion in polymer solutions: Studies by Taylor dispersion and phosphorescence quenching (1996) (25)
- Stiffness Gradients in Glassy Polymer Model Nanocomposites: Comparisons of Quantitative Characterization by Fluorescence Spectroscopy and Atomic Force Microscopy (2017) (25)
- A reconsideration of the measurement of polymer interdiffusion by fluorescence nonradiative energy transfer (1994) (25)
- The role of solution structure in apparent thickening behavior of dilute peo/water systems (1988) (24)
- Ester Functionalization of Polypropylene via Controlled Decomposition of Benzoyl Peroxide during Solid-State Shear Pulverization (2013) (24)
- Dynamic Covalent Polyurethane Networks with Excellent Property and Cross-Link Density Recovery after Recycling and Potential for Monomer Recovery (2020) (24)
- Recyclable polymer networks containing hydroxyurethane dynamic cross-links: Tuning morphology, cross-link density, and associated properties with chain extenders (2019) (24)
- Novel synthesis of branched polypropylene via solid-state shear pulverization (2015) (24)
- Translational and Rotational Diffusion of Probe Molecules in Polymer Films near Tg: Effect of Hydrogen Bonding (1999) (23)
- Glass Transition Temperature of a Component near Infinite Dilution in Binary Polymer Blends: Determination via Fluorescence Spectroscopy (2011) (23)
- Measuring interphase stiffening effects in styrene-based polymeric thin films (2015) (23)
- Monitoring the molecular scale effects of physical aging in polymer glasses with fluorescence probes (1990) (22)
- Ellipsometry measurements of glass transition breadth in bulk films of random, block, and gradient copolymers (2010) (22)
- Self-referencing fluorescence sensor for monitoring conversion of nonisothermal polymerization and nanoscale mixing of resin components (2003) (22)
- Gel effect in free radical polymerization: Model discrimination of its cause (1998) (22)
- Tuning the properties of segmented polyhydroxyurethanes via chain extender structure (2017) (22)
- Segmented Thermoplastic Polymers Synthesized by Thiol–Ene Click Chemistry: Examples of Thiol–Norbornene and Thiol–Maleimide Click Reactions (2018) (22)
- Trace levels of mechanochemical effects in pulverized polyolefins (2001) (22)
- Determining multiple component glass transition temperatures in miscible polymer blends: Comparison of fluorescence spectroscopy and differential scanning calorimetry (2012) (21)
- Covalent Adaptive Networks for Enhanced Adhesion: Exploiting Disulfide Dynamic Chemistry and Annealing during Application (2020) (21)
- Phase separation of oligomeric polystyrene-polybutadiene blends as studied by excimer fluorescence (1988) (21)
- Relative contribution of the electric-field-induced third-order effect to second-harmonic generation in poled, doped, amorphous polymers (1994) (21)
- Major Roles of Blend Partner Fragility and Dye Placement on Component Glass Transition Temperatures: Fluorescence Study of Near-Infinitely Dilute Species in Binary Blends (2012) (21)
- Imaging of phase segregation in gradient copolymers: Island and hole surface topography (2012) (20)
- In situ monitoring of sorption and drying of polymer films and coatings: self-referencing, nearly temperature-independent fluorescence sensors (2004) (19)
- Relationship between Chain Length and the Concentration Dependence of Polymer and Oligomer Self-Diffusion in Solution (2002) (19)
- Isolating the effect of polymer-grafted nanoparticle interactions with matrix polymer from dispersion on composite property enhancement: The example of polypropylene/halloysite nanocomposites (2019) (19)
- Fluorescence energy transfer studies of styrene-isoprene diblock copolymer solutions† (1990) (18)
- Dispersion and Property Enhancements in Polyolefin/Soy Flour Biocomposites Prepared via Melt Extrusion Followed by Solid-State Shear Pulverization (2015) (18)
- Large melting point depression of 2-3-nm length-scale nanocrystals formed by the self-assembly of an associative polymer: Telechelic, pyrene-labeled poly(dimethylsiloxane) (2004) (17)
- Photochromic and Fluorescent Probe Studies in Glassy Polymer Matrices. 2. Isomerizable Planar Probe Molecules Lacking an Inversion Center of Symmetry (1987) (17)
- Molecular probe techniques for studying diffusion and relaxation in thin and ultrathin polymer films (1997) (17)
- Crystallization and Enthalpy Relaxation of Physically Associating, End-Linked Polymer Networks: Telechelic Pyrene-Labeled Polydimethylsiloxane (2004) (16)
- Determination of interpenetration of polystyrene in solution and film by energy-transfer techniques (1987) (16)
- Tuning the Tg-confinement effect in thin polymer films via minute levels of residual surfactant which “cap” the free surface (2016) (16)
- Influence of initiator fragments as chain ends on the Tg-confinement effect and dewetting of thin films of ultralow molecular weight polymer (2015) (16)
- Recyclable Polymethacrylate Networks Containing Dynamic Dialkylamino Disulfide Linkages and Exhibiting Full Property Recovery (2020) (15)
- In situ monitoring of free‐radical polymerization by fluorescence quenching of fluorene and reactive derivatives (1994) (15)
- Functionalization of hydroxyl groups in segmented polyhydroxyurethane eliminates nanophase separation (2017) (15)
- Fluorescence energy-transfer studies of bulk styrene-isoprene diblock copolymers and their blends with polyisoprene: applications to microphase separation (1990) (15)
- Molecular weight dependence of the intrinsic size effect on Tg in AAO template-supported polymer nanorods: A DSC study. (2017) (14)
- Optical and electrical properties of polymers (1991) (14)
- Hybrid thiol-acrylate-epoxy polymer networks: Comparison of one-pot synthesis with sequential reactions and shape memory properties (2016) (13)
- Molecular Weight Dependence of the Glass Transition Temperature (Tg)-Confinement Effect in Well-Dispersed Poly(2-vinyl pyridine)–Silica Nanocomposites: Comparison of Interfacial Layer Tg and Matrix Tg (2020) (13)
- Synthesis, characterization and photophysical properties of benzil-labelled polymers for studies of diffusion-limited interactions by phosphorescence quenching (1990) (13)
- Reprocessable and Recyclable Chain-Growth Polymer Networks Based on Dynamic Hindered Urea Bonds. (2022) (13)
- Birefringence and second-order nonlinear optics as probes of polymer cooperative segmental mobility: Demonstration of Debye-type relaxation (1999) (12)
- Tg-confinement effects in strongly miscible blends of poly(2,6-dimethyl-1,4-phenylene oxide) and polystyrene: Roles of bulk fragility and chain segregation (2017) (12)
- Porod scattering study of coarsening in immiscible polymer blends (2005) (12)
- Simultaneous Determination of Critical Micelle Temperature and Micelle Core Glass Transition Temperature of Block Copolymer–Solvent Systems via Pyrene-Label Fluorescence (2013) (12)
- A New Polymer Processing Technology for Polymer Blends with Unmatched Viscosity: Solid-State Shear Pulverization (S3P) (2000) (11)
- Recent advances in the understanding of the gel effect in free-radical polymerization (1997) (11)
- Tenfold increase in the photostability of an azobenzene guest in vapor-deposited glass mixtures. (2018) (10)
- Polystyrene-methylcyclohexane solutions undergoing phase separation: a study by fluorescence spectroscopy (1984) (9)
- Influence of Molecular Weight and Composition on the Morphology and Mechanical Properties of SBS-Polystyrene-Mineral Oil Blends (1992) (9)
- Effect of chain length on rates of diffusion‐limited small molecule‐polymer and polymer‐polymer reactions: Phosphorescence quenching studies (1996) (9)
- Fluorescence of Vinyl Aromatic Polyelectrolytes: Effects of Conformation, Concentration, and Molecular Weight of Sodium Poly(styrenesulfonate) (1986) (9)
- Erratum: Dramatic Reduction of the Effect of Nanoconfinement on the Glass Transition of Polymer Films via Addition of Small-Molecule Diluent (Physical Review Letters (2004) 92 (095702)) (2004) (9)
- Reprocessable covalent adaptable networks with excellent elevated-temperature creep resistance: facilitation by dynamic, dissociative bis(hindered amino) disulfide bonds (2021) (9)
- Reprocessable polyhydroxyurethane networks reinforced with reactive polyhedral oligomeric silsesquioxanes (POSS) and exhibiting excellent elevated temperature creep resistance (2022) (8)
- Novel Effects of Confinement and Interfaces on the Glass Transition Temperature and Physical Aging in Polymer Films and Nanocomposites (2008) (8)
- Enhanced glass transition temperature of low molecular weight poly(methyl methacrylate) by initiator fragments located at chain ends (2017) (8)
- Ecoresorbable and bioresorbable microelectromechanical systems (2022) (8)
- Bulk physical aging behavior of cross-linked polystyrene compared to its linear precursor: Effects of cross-linking and aging temperature (2017) (8)
- Enhancement of Surface Wettability by Incorporating Polar Initiator Fragments at Chain Ends of Low-Molecular-Weight Polymers. (2017) (8)
- Effects of process method and quiescent coarsening on dispersed-phase size distribution in polymer blends: comparison of solid-state shear pulverization with intensive batch melt mixing (2015) (7)
- The concentration dependence of excimer fluorescence in polystyrene solutions (1988) (7)
- Apparatus with an elastic barrier for radial compression of liquid supported monolayers (1992) (7)
- Kaolin–epoxy‐based nanocomposites: A complementary study of the epoxy curing by FTIR and fluorescence (2010) (7)
- Functional enzyme–polymer complexes (2022) (7)
- Remarkable glass transition breadths up to 120 K exhibited by block-gradient copolymers and by gradient copolymers plasticized by oligomer (2018) (6)
- On the proper use of concentration profiles for determining polymer diffusion coefficients via fluorescence nonradiative energy transfer (1997) (6)
- Photoresponsive Behavior of Methyl Methacrylate/Trans-4-Stilbene Methacrylate Statistical Copolymers in Solution and the Solid State (1990) (6)
- Diffusion-controlled polymer-polymer reactions in bulk: Novel strategy for model experiments and reactive compatibilization using polymers synthesized via controlled radical polymerization (2002) (6)
- Atmospheric effects on corona poling of nonlinear optical doped polymer films (1990) (6)
- Rigid amorphous fraction and crystallinity in cold-crystallized syndiotactic polystyrene: Characterization by differential scanning calorimetry (2021) (5)
- Use of Taylor dispersion for the measurement of probe diffusion in polymer solutions (1996) (5)
- Apparent thickening behavior of dilute polystyrene solutions in extensional flows (1988) (5)
- Correlations in polymer melts and solutions as investigated by fluorescence nonradiative energy transfer: a novel comparison of theory to experiment by fluorescence intensity decay measurements (1993) (5)
- Some viscosity properties of lignosulfonates isolated by ultrafiltration (1977) (5)
- Monohydroxy-hydrazone-functionalized Thermally Crosslinked Polymers for Nonlinear Optics (2004) (4)
- Second Order Nonlinear Optics and Polymer Physics of Corona Poled, Doped Polymer Materials (1989) (4)
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- Confinement and interfacial effects on the alpha relaxation dynamics of thin polymer films (2007) (0)
- Effective Mixing of UHMWPE with Polyethylene: Rheological, Mechanical and Crystallization Behavior of Novel Blends Made by Solid-State Shear Pulverization (2013) (0)
- Isolating the effect of polymer-filler interaction on polymer composite property enhancement: The example of polypropylene/halloysite hybrids (2018) (0)
- Recyclable crosslinked polymer networks with full property recovery made via one-step controlled radical polymerization (2017) (0)
- Glass transition temperature and its distribution in nanoconfined free-standing polymer films (2010) (0)
- Maximizing or eliminating the effects of nanoscale confinement on the glass transition in freely standing, supported, and multilayer polymer films (2008) (0)
- Overcoming the achilles' heel of processing of polymer nanocomposites: Achieving well-dispersed polymer-graphite, polymer-carbon nanotube, polymer-carbon nanofiber, and polymer-graphene nanocomposites with major property enhancements by solid-state shear pulverization (2012) (0)
- Stiffness Gradients in Supported Thin Polymer Films and in Polymer Model Nanocomposites: Evaluation via a Novel Fluorescence Method with Comparison to AFM Results (2018) (0)
- Novel fluorescence techniques for characterizing the glass transition temperature and relaxation dynamics of nanoscopically confined polymers (2002) (0)
- Lateral diffusion of single poly(ethylene oxide) chains on the surfaces of glassy and molten polymer films. (2021) (0)
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