John T. Groves
#63,147
Most Influential Person Now
American chemist
John T. Groves's AcademicInfluence.com Rankings
John T. Groveschemistry Degrees
Chemistry
#1009
World Rank
#1618
Historical Rank
#416
USA Rank
Inorganic Chemistry
#77
World Rank
#86
Historical Rank
#24
USA Rank
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Chemistry
John T. Groves's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Davis
Why Is John T. Groves Influential?
(Suggest an Edit or Addition)According to Wikipedia, John T. Groves is an American chemist, and Hugh Stott Taylor Chair of Chemistry, at Princeton University. Biography Groves received an undergraduate degree in chemistry at Massachusetts Institute of Technology, where he worked with Frederick Greene. In 1965, he began his doctoral studies under the direction of Professor Ronald Breslow at the Columbia University. During this time, he focused on the synthesis and characterization of cyclopropenyl cation, the simplest aromatic system and the first aromatic compound prepared with other than six electrons in a ring.
John T. Groves's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene (1979) (677)
- High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450 (1981) (529)
- High-valent iron in chemical and biological oxidations. (2006) (479)
- Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins (2017) (470)
- Aliphatic hydroxylation by highly purified liver microsomal cytochrome P-450. Evidence for a carbon radical intermediate. (1978) (408)
- Epoxidation reactions catalyzed by iron porphyrins. Oxygen transfer from iodosylbenzene (1983) (397)
- Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin (2012) (386)
- Catalytic asymmetric epoxidations with chiral iron porphyrins (1983) (361)
- Aliphatic hydroxylation via oxygen rebound. Oxygen transfer catalyzed by iron (1976) (360)
- Aerobic epoxidation of olefins with ruthenium porphyrin catalysts (1985) (351)
- Detection and Characterization of an Oxomanganese(V) Porphyrin Complex by Rapid-Mixing Stopped-Flow Spectrophotometry (1997) (316)
- Hydrocarbon Oxidations with Oxometalloporphinates. Isolation and Reactions of a (Porphinato)manganese(V) Complex (1981) (310)
- Aliphatic hydroxylation catalyzed by iron porphyrin complexes (1983) (306)
- Key elements of the chemistry of cytochrome P-450: The oxygen rebound mechanism (1985) (303)
- The role of structure, energy landscape, dynamics, and allostery in the enzymatic function of myoglobin (2001) (288)
- Manganese Catalyzed C-H Halogenation. (2015) (286)
- Potent Metalloporphyrin Peroxynitrite Decomposition Catalyst Protects Against the Development of Doxorubicin-Induced Cardiac Dysfunction (2003) (278)
- Peroxynitrite rapidly permeates phospholipid membranes. (1997) (270)
- Asymmetric hydroxylation, epoxidation, and sulfoxidation catalyzed by vaulted binaphthyl metalloporphyrins (1990) (257)
- Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base (2013) (255)
- The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies (2003) (247)
- Reactive iron porphyrin derivatives related to the catalytic cycles of cytochrome P-450 and peroxidase. Studies of the mechanism of oxygen activation (1988) (244)
- Synthesis, characterization, and reactivity of oxomanganese(IV) porphyrin complexes (1988) (231)
- Manganese porphyrins catalyze selective C-H bond halogenations. (2010) (223)
- Biomimetic Synthesis of Macroscopic-Scale Calcium Carbonate Thin Films. Evidence for a Multistep Assembly Process (1998) (214)
- Manganese-catalyzed late-stage aliphatic C-H azidation. (2015) (206)
- Unusual Kinetic Stability of a Ground-State Singlet Oxomanganese(V) Porphyrin. Evidence for a Spin State Crossing Effect (1999) (199)
- Peroxynitrite: reactive, invasive and enigmatic. (1999) (191)
- Influence of porphyrin structure on anion selectivities of manganese(III) porphyrin based membrane electrodes. (1988) (185)
- Hydroxylation by cytochrome P-450 and metalloporphyrin models: evidence for allylic rearrangement (1984) (183)
- Part I: Pathogenetic Role of Peroxynitrite in the Development of Diabetes and Diabetic Vascular Complications: Studies With FP15, A Novel Potent Peroxynitrite Decomposition Catalyst (2002) (178)
- Manganese-catalyzed oxidative benzylic C-H fluorination by fluoride ions. (2013) (178)
- Late stage benzylic C-H fluorination with [¹⁸F]fluoride for PET imaging. (2014) (174)
- Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation (2016) (173)
- Nitric oxide synthase: models and mechanisms. (2000) (171)
- Continuous crystalline carbonate apatite thin films. A biomimetic approach. (2001) (169)
- Activation and transfer of nitrogen from a nitridomanganese(V) porphyrin complex. Aza analog of epoxidation (1983) (159)
- Asymmetric hydroxylation by a chiral iron porphyrin (1989) (159)
- The mechanism of olefin epoxidation by oxo-iron porphyrins. Direct observation of an intermediate. (1986) (155)
- Preparation and Reactivity of Oxoiron(IV) Porphyrins (1994) (154)
- Role for nitrosative stress in diabetic neuropathy: evidence from studies with a peroxynitrite decomposition catalyst (2005) (153)
- Olefin epoxidation by manganese (IV) porphyrins: evidence for two reaction pathways (1987) (151)
- The genome sequence of Desulfatibacillum alkenivorans AK-01: a blueprint for anaerobic alkane oxidation. (2012) (150)
- Preparation and characterization of an oxoporphinatochromium(V) complex (1979) (149)
- A highly reactive p450 model compound I. (2009) (143)
- Langmuir−Blodgett Films of Regioregular Poly(3-hexylthiophene) as Field-Effect Transistors (2000) (141)
- MECHANISMS OF IRON PORPHYRIN REACTIONS WITH PEROXYNITRITE (1998) (133)
- Manganese porphyrins as redox-coupled peroxynitrite reductases (1998) (131)
- Mycobactin-mediated iron acquisition within macrophages (2005) (129)
- Trans-dioxo manganese(V) porphyrins. (2007) (124)
- Regioselective Oxidation Catalysis in Synthetic Phospholipid Vesicles. Membrane-Spanning Steroidal Metalloporphyrins (1989) (123)
- Models and Mechanisms of Cytochrome P450 Action (2005) (123)
- Role of nitrosative stress in early neuropathy and vascular dysfunction in streptozotocin-diabetic rats. (2007) (122)
- Oxomanganese(IV) porphyrins identified by resonance Raman and infrared spectroscopy. Weak bonds and the stability of the half-filled t2g subshell (1988) (120)
- Enzymatic C-H bond activation: Using push to get pull. (2014) (119)
- Rapid Catalytic Oxygenation of Hydrocarbons by Ruthenium Pentafluorophenylporphyrin Complexes: Evidence for the Involvement of a Ru(III) Intermediate (1996) (119)
- Tetraphilin : a four-helix proton channel built on a tetraphenylporphyrin framework (1992) (118)
- Immune-modulating enzyme indoleamine 2,3-dioxygenase is effectively inhibited by targeting its apo-form (2018) (118)
- Models of oxidized heme proteins. Preparation and characterization of a trans-dioxoruthenium(VI) porphyrin complex (1984) (117)
- Cytochrome c causes pore formation in cardiolipin-containing membranes (2013) (115)
- Revisiting the mechanism of P450 enzymes with the radical clocks norcarane and spiro[2,5]octane. (2002) (113)
- Detection and kinetic characterization of a highly reactive heme-thiolate peroxygenase compound I. (2012) (112)
- Selective hydroxylation of alkanes by an extracellular fungal peroxygenase (2011) (108)
- A peroxynitrite decomposition catalyst counteracts sensory neuropathy in streptozotocin-diabetic mice. (2007) (107)
- Taming Azide Radicals for Catalytic C–H Azidation (2016) (101)
- Oxygen Activation by Metalloporphyrins. Formation and Decomposition of an Acylperoxymanganese(III) Complex (1983) (100)
- Targeted fluorination with the fluoride ion by manganese-catalyzed decarboxylation. (2015) (99)
- Stereospecific aliphatic hydroxylation by iron-hydrogen peroxide. Evidence for a stepwise process (1976) (96)
- Radical intermediates in monooxygenase reactions of rieske dioxygenases. (2007) (96)
- Oxygen activation by metalloporphyrins related to peroxidase and cytochrome P-450. Direct observation of the oxygen-oxygen bond cleavage step. (1986) (90)
- Preparation and Characterization of a Dialkoxyiron(IV) Porphyrin (1985) (87)
- Reactivity and mechanisms of metalloporphyrin‐ catalyzed oxidations (2000) (87)
- Peroxynitrite mediates active site tyrosine nitration in manganese superoxide dismutase. Evidence of a role for the carbonate radical anion. (2010) (86)
- Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation. (2006) (84)
- A "push-pull" mechanism for heterolytic o-o bond cleavage in hydroperoxo manganese porphyrins. (2010) (83)
- Rapid, Reversible Oxygen Atom Transfer between an Oxomanganese(V) Porphyrin and Bromide: A Haloperoxidase Mimic with Enzymatic Rates. (2000) (83)
- Peroxynitrite-Induced DNA Strand Scission Mediated by a Manganese Porphyrin (1995) (81)
- Synthesis, Characterization, and Molecular Structure of Oxo(porphyrinato)chromium(IV) Complexes (1982) (79)
- Mechanisms of peroxynitrite decomposition catalyzed by FeTMPS, a bioactive sulfonated iron porphyrin. (2001) (79)
- Chameleon States: High-Valent Metal-Oxo Species of Cytochrome P450 and Its Ruthenium Analogue. (2001) (79)
- Membrane-spanning steroidal metalloporphyrins as site-selective catalysts in synthetic vesicles (1987) (76)
- Fast catalytic hydroxylation of hydrocarbons with ruthenium porphyrins. (2006) (74)
- Intermediate Q from soluble methane monooxygenase hydroxylates the mechanistic substrate probe norcarane: evidence for a stepwise reaction. (2001) (72)
- Cyclopropenyl Cation. Synthesis and Characterization (1970) (72)
- Mechanisms of peroxynitrite interactions with heme proteins. (2010) (70)
- Stereospecific aliphatic hydroxylation by an iron-based oxidant (1974) (69)
- Alkane-oxidizing metalloenzymes in the carbon cycle. (2011) (68)
- Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (2000) (67)
- Characterization of an oxoruthenium(IV) porphyrin complex (1987) (67)
- Nitrosative stress and peripheral diabetic neuropathy in leptin-deficient (ob/ob) mice (2007) (67)
- HYDROGEN-DEUTERIUM EXCHANGE DURING PROPYLENE EPOXIDATION BY CYTOCHROME P-450 (1986) (66)
- Metalloporphyrin Models for Cytochrome P-450 (1986) (66)
- Nitrous Oxide Activation by a Ruthenium Porphyrin (1995) (66)
- Heme-thiolate ferryl of aromatic peroxygenase is basic and reactive (2015) (66)
- Heterolytic and homolytic oxygen-oxygen bond cleavage reactions of acylperoxomanganese(III) porphyrins (1986) (65)
- The non-heme diiron alkane monooxygenase of Pseudomonas oleovorans (AlkB) hydroxylates via a substrate radical intermediate [12] (2000) (65)
- Self-assembled monolayers from a designed combinatorial library of de novo β-sheet proteins (2001) (65)
- Porphyrin Amphiphiles as Templates for the Nucleation of Calcium Carbonate (1997) (64)
- Peroxynitrite and protein nitration in the pathogenesis of diabetic peripheral neuropathy (2014) (64)
- Membrane affinity of the amphiphilic marinobactin siderophores. (2002) (64)
- Synthesis and molecular structure of a nitrido(porphyrinato)chromium(V) complex (1983) (64)
- Dynamics of Carbon Monoxide Binding to Cystathionine β-Synthase* (2006) (60)
- Single vesicle observations of the cardiolipin-cytochrome C interaction: induction of membrane morphology changes. (2011) (60)
- A conformational switch to beta-sheet structure in cytochrome c leads to heme exposure. Implications for cardiolipin peroxidation and apoptosis. (2007) (59)
- Enzymic regioselectivity in the hydroxylation of cholesterol catalyzed by a membrane-spanning metalloporphyrin (1988) (59)
- Chlorocyclopropenes, chlorocyclopropenyl cations, and cyclopropenone (1970) (59)
- Rapid decomposition of peroxynitrite by manganese porphyrin-antioxidant redox couples (1997) (58)
- Dynamics of Carbon Monoxide Binding to CooA* (2004) (58)
- Driving force for oxygen-atom transfer by heme-thiolate enzymes. (2013) (57)
- Mössbauer effect study of tight spin coupling in oxidized chloro-5,10,15,20-tetra(mesityl)porphyrinatoiron(III) (1983) (57)
- The peroxynitrite decomposition catalyst FP15 improves ageing-associated cardiac and vascular dysfunction (2007) (56)
- Direct detection of the oxygen rebound intermediates, ferryl Mb and NO2, in the reaction of metmyoglobin with peroxynitrite. (2009) (55)
- Ferryl protonation in oxoiron(IV) porphyrins and its role in oxygen transfer. (2015) (54)
- Sequence-specific cleavage of DNA by oligonucleotide-bound metal complexes (1993) (52)
- Rapid amide hydrolysis mediated by copper and zinc (1979) (51)
- Multi-Heme Self-Assembly in Phospholipid Vesicles (1996) (50)
- Selective CH functionalization of methane, ethane, and propane by a perfluoroarene iodine(III) complex. (2014) (48)
- Models of zinc-containing proteases. Catalysis of cobalt(III)-mediated amide hydrolysis by a pendant carboxylate (1989) (48)
- Hydroxylation and expoxidation reactions catalyzed by synthetic metalloporphyrinates. Models related to the active oxygen species of cytochrome P-450 (1980) (48)
- Electrochemical Generation of an Iron(IV) Porphyrin (1986) (48)
- The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry. (2017) (47)
- Selective C-H Halogenation with a Highly Fluorinated Manganese Porphyrin. (2018) (47)
- Models of zinc-containing proteases. Rapid amide hydrolysis by an unusually acidic Zn2+-OH2 complex (1985) (47)
- Geometrical and Stereochemical Factors in Metal-Promoted Amide Hydrolysis (1984) (46)
- Dehalogenations with sodium borohydride. Evidence for a free radical reaction (1974) (45)
- Additions and Corrections - Catalysis of Superoxide Dismutation by Iron-Ethylenediaminetetraacetic Acid Complexes. Mechanism of the Reaction and Evidence for the Direct Formation of an Iron(III)-Ethyl-enediaminetetraacetic Acid Peroxo Complex from the Reaction of Superoxide with Iron(II) - Ethylened (1977) (45)
- Mn(III)—porphyrin‐based thiocyanate‐selective membrane electrodes: Characterization and application in flow injection determination of thiocyanate in saliva (1989) (45)
- Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes. (2004) (44)
- Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediate. (2011) (44)
- Evaluation of the peroxynitrite decomposition catalyst Fe(III) tetra-mesitylporphyrin octasulfonate on peripheral neuropathy in a mouse model of type 1 diabetes. (2007) (44)
- Parallel and competitive pathways for substrate desaturation, hydroxylation, and radical rearrangement by the non-heme diiron hydroxylase AlkB. (2012) (43)
- Amphiphilic peroxynitrite decomposition catalysts in liposomal assemblies. (1997) (43)
- Enzymatic tailoring of enterobactin alters membrane partitioning and iron acquisition. (2006) (43)
- Alkyl Isocyanates via Manganese-Catalyzed C-H Activation for the Preparation of Substituted Ureas. (2017) (42)
- Catalytic generation of chlorine dioxide from chlorite using a water-soluble manganese porphyrin. (2011) (42)
- Preparation and characterization of an iron(III) porphyrin N-oxide. (1986) (42)
- Reaction mechanisms of non-heme diiron hydroxylases characterized in whole cells. (2005) (42)
- Site-selective 18F fluorination of unactivated C–H bonds mediated by a manganese porphyrin (2017) (41)
- Financial impact of palliative care consultation in a public hospital. (2008) (40)
- Cis-trans isomerization of epoxides catalyzed by ruthenium(II) porphyrins (1988) (40)
- Fast Hydrogen Atom Abstraction by a Hydroxo Iron(III) Porphyrazine. (2017) (40)
- Selective monooxidation of light alkanes using chloride and iodate. (2014) (40)
- Modeling the haloperoxidases: reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin. (2007) (39)
- Probing the C–O Bond-Formation Step in Metalloporphyrin-Catalyzed C–H Oxygenation Reactions (2017) (38)
- Oxidative aliphatic C-H fluorination with manganese catalysts and fluoride ion (2013) (38)
- Membrane dynamics of the amphiphilic siderophore, acinetoferrin. (2005) (36)
- Intercalation of aminophenyl- and pyridinium-substituted porphyrins into zirconium hydrogen phosphate : evidence for substituent-derived orientational selectivity (1993) (36)
- Evidence for a weak Mn=O bond and a non-porphyrin radical in manganese-substituted horseradish peroxidase compound I (1991) (36)
- Preparation and characterization of an (acylperoxo)iron(III) porphyrin (1987) (35)
- Flavins inhibit human cytomegalovirus UL80 protease via disulfide bond formation. (1996) (34)
- Chemistry in the Center for Catalytic Hydrocarbon Functionalization: An Energy Frontier Research Center (2011) (34)
- Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds. (2012) (33)
- Dissection of the mechanism of manganese porphyrin-catalyzed chlorine dioxide generation. (2011) (32)
- Cage escape competes with geminate recombination during alkane hydroxylation by the diiron oxygenase AlkB. (2008) (31)
- Models of Nitric Oxide Synthase: Iron(III) Porphyrin-Catalyzed Oxidation of Fluorenone Oxime to Nitric Oxide and Fluorenone (1999) (30)
- Synthesis, structure, and molecular dynamics of gallium complexes of schizokinen and the amphiphilic siderophore acinetoferrin. (2004) (30)
- Oxidative cyclization of farnesyl acetate by a free radical path (1968) (30)
- The diagnostic substrate bicyclohexane reveals a radical mechanism for bacterial cytochrome P450 in whole cells. (2006) (30)
- DNA cleavage by a metal chelating tricationic porphyrin (1989) (29)
- Profiling mechanisms of alkane hydroxylase activity in vivo using the diagnostic substrate norcarane. (2007) (28)
- Xylene monooxygenase, a membrane-spanning non-heme diiron enzyme that hydroxylates hydrocarbons via a substrate radical intermediate (2003) (28)
- Remarkable aliphatic hydroxylation by the diiron enzyme toluene 4-monooxygenase in reactions with radical or cation diagnostic probes norcarane, 1,1-dimethylcyclopropane, and 1,1-diethylcyclopropane. (2004) (27)
- Dynamics of carbon monoxide binding to cystathionine beta-synthase. (2006) (26)
- Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin (1990) (25)
- Biocompatible catalysis. Enzymic reduction of metalloporphyrin catalysts in phospholipid bilayers (1990) (25)
- Hindered rotation of axially coordinated 2-methylimidazoles in tetramesitylporphyrinato-iron(III) complexes (1988) (24)
- Synthesis of trithiolanes and tetrathianes from thiiranes catalyzed by ruthenium salen nitrosyl complexes. (2002) (24)
- Fishing for peroxidase protons (2014) (23)
- Artificial enzymes: The importance of being selective (1997) (23)
- Iron(IV) porphyrins from iron(III) porphyrin cation radicals (1984) (22)
- Polarized x-ray absorption near-edge structure of highly oxidized chromium porphyrins (1986) (22)
- Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand. (2014) (21)
- Substrate specificity and reaction mechanism of purified alkane hydroxylase from the hydrocarbonoclastic bacterium Alcanivorax borkumensis (AbAlkB). (2013) (20)
- E.s.r. evidence for chromium (V) porphyrinates (1981) (20)
- Studies of the Mechanism of Oxygen Activation and Transfer Catalyzed by Cytochrome P 450 (1980) (19)
- Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection (2018) (19)
- The Mechanism of Propylene Oxidation to Acrolein over Bismuth Molybdate, Copper Oxide, and Rhodium Catalysts (1983) (18)
- 9 Molecular Mechanism of Oxygen Activation by P-450 (1992) (18)
- Catalytic peroxynitrite decomposition improves reperfusion injury after heart transplantation. (2012) (18)
- Partial oxidation of light alkanes by periodate and chloride salts. (2015) (18)
- A general method for coupling unprotected peptides to bromoacetamido porphyrin templates (1994) (17)
- Oxometalloporphyrins in Oxidative Catalysis (2003) (17)
- Potent Activation of Indoleamine 2,3-Dioxygenase by Polysulfides. (2019) (17)
- Electronic and steric factors in regioselective hydroxylation catalyzed by purified cytochrome P-450. (1979) (16)
- Identity and mechanisms of alkane-oxidizing metalloenzymes from deep-sea hydrothermal vents (2013) (16)
- Manganese-Catalyzed Desaturation of N-Acyl Amines and Ethers (2019) (16)
- α-Bromocyclopropyl trifluoroacetates as cyclopropanone precursors (1974) (16)
- Self-assembled monolayers from a designed combinatorial library of de novo beta-sheet proteins. (2001) (15)
- Tricyclo[5.4.0.04,11]undeca-2,6,9-trien-8-one via a homobullvalenyl cation (1972) (14)
- A novel oxidative terpene cyclization (1966) (14)
- Geometrical and Stereochemical Factors in Metal-Promoted Amide Hydrolysis. (1984) (14)
- Enhanced peroxynitrite decomposition protects against experimental obliterative bronchiolitis. (2003) (14)
- Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin. (2006) (13)
- Hemodextrin: a self-assembled cyclodextrin-porphyrin construct that binds dioxygen. (2003) (13)
- Paramagnetic 1H-NMR relaxation probes of stereoselectivity in metalloporphyrin catalyzed olefin epoxidation. (1998) (13)
- Diaziridinones(2,3-diazacyclopropanones). Structure (x-ray). Thermal decomposition via a nitrenoid fragment (1978) (13)
- Theoretical study of reductive functionalization of methyl ligands of group 9 complexes supported by two bipyridyl ligands: A key step in catalytic hydrocarbon functionalization (2014) (13)
- Biological Strategies for the Manipulation of Dioxygen (1986) (13)
- Metalloporphyrins in Oxidative Catalysis. Oxygen Transfer Reactions of Oxochromium Porphyrins (1985) (12)
- Directed Multi-Heme Self-Assembly and Electron Transfer in a Model Membrane (1994) (12)
- A reevaluation of iron binding by Mycobactin J (2018) (11)
- Effects of FP15, a peroxynitrite decomposition catalyst on cardiac and pulmonary function after cardiopulmonary bypass. (2012) (11)
- Faculty Opinions recommendation of Heme enzymes. Neutron cryo-crystallography captures the protonation state of ferryl heme in a peroxidase. (2015) (10)
- Directive effects in free radical oxidation by iron(III). Reductive decarboxylation of peracids (1975) (10)
- Manganese Catalyzed C‐H Halogenation (2015) (10)
- On the Mechanism of Epoxidation and Hydroxylation Catalyzed by Iron Porphyrins. Evidence for Non-Intersecting Reaction Pathways (1995) (9)
- Host-guest interactions of cyclodextrins and metalloporphyrins: supramolecular building blocks toward artificial heme proteins (2004) (9)
- Cytochrome P450 enzymes: understanding the biochemical hieroglyphs (2015) (9)
- Faculty Opinions recommendation of Iron(IV)hydroxide pK(a) and the role of thiolate ligation in C-H bond activation by cytochrome P450. (2015) (9)
- Electrochemical Generation of an Iron(IV) Porphyrin. (1986) (9)
- Manganese-Catalyzed Late-Stage Aliphatic C—H Azidation. (2015) (9)
- DFT Mechanistic Study of Methane Mono-Esterification by Hypervalent Iodine Alkane Oxidation Process (2019) (9)
- Dehalogenation reactions catalyzed by tri-n-butyltin chloride. Competition for carbon radicals by borohydride and tin hydride (1978) (9)
- Synthesis of seleno-toluidine blue. (1974) (9)
- Taking steps for safety's sake. (1977) (8)
- Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride (2019) (8)
- Perspex slides for roller culture of human cells. (1956) (8)
- Low power interstitial Nd-YAG laser photocoagulation in normal rabbit brain (1992) (8)
- Carbon cluster compounds. Generation and reorganization of the homobullvalenyl cation, an 11-fold degenerate species (1977) (7)
- Smart materials systems through mesoscale patterning (1996) (7)
- Zinc-coordination oligomers of phenanthrolinylporphyrins. (2003) (7)
- Stereospecific aliphatic hydroxylation upon photoreduction of iron (III) (1975) (7)
- Rapid catalytic oxygenation of hydrocarbons with perhalogenated ruthenium porphyrin complexes (1997) (6)
- Kinetic Selectivity in the N-Alkylation of 2-Pyridyl Porphyrins: A Facile Approach to the ααββ Scaffold (2007) (6)
- Mechanism of Olefin Epoxidation by Oxo - Iron Porphyrins. Direct Observation of an Intermediate. (1986) (6)
- OXO- AND PEROXO-TRANSITION METAL SPECIES IN CHEMICAL AND BIOCHEMICAL OXIDATIONS. POSSIBLE MODELS FOR THE OXYGEN ACTIVATION AND TRANSFER CATALYZED BY CYTOCHROME P-4501 (1979) (6)
- Synthesis and structural modeling of the amphiphilic siderophore rhizobactin-1021 and its analogs. (2005) (5)
- Degeneracy and stability of the homobullvalenyl cation (1975) (5)
- Conformational analysis with lanthanide shift reagents. A new determination of the cyclohexanol a-valoe (1975) (5)
- Shape Selective Oxygen Transfer to Olefins Catalyzed by Sterically Hindered Iron Porphyrins (1994) (5)
- Synthesis of iron-binding oligonucleotides and their reactions with single-stranded DNA (1993) (5)
- Designed double-strand DNA cleavage with chelate-appended porphyrins (1996) (5)
- Manganese Catalyzed Partial Oxidation of Light Alkanes (2022) (4)
- Heterolytic and Homolytic O-O Bond Cleavage Reactions of (Acylperoxo)manganese(III) Porphyrins (1987) (4)
- SYNTHESIS OF SELENO‐TOLUIDINE BLUE (1974) (4)
- Olefin Epoxidation by Manganese(IV) Porphyrins: Evidence for Two Reaction Pathways. (1987) (3)
- Synthesis and solvolysis of tricyclo[4.3.2.02,5]undeca-3,8,10-trien-7-ol. Unusual [CH]11+ rearrangement (1975) (3)
- Photoinduced charge flow inside an iron porphyrazine complex. (2019) (3)
- Aerobic Partial Oxidation of Alkanes Using Photodriven Iron Catalysis. (2021) (3)
- Reactivity and Mechanisms of Metalloporphyrin‐Catalyzed Oxidations (2000) (3)
- A STEREOCHEMICAL PROBE OF THE FATE OF CARBON RADICALS OXIDIZED BY METALS (1975) (3)
- Cytochrome P450 enzymes: understanding the biochemical hieroglyphs (version 1; referees: 3 approved) (2015) (3)
- Faculty of 1000 evaluation for Spectroscopic features of cytochrome P450 reaction intermediates. (2015) (2)
- ON THE MECHANISM OF OXYGEN INSERTION CATALYZED BY CYTOCHROME P-450. HYDROXYLATION WITH PARTIAL ALLYLIC REARRANGEMENT (1980) (2)
- Details to Attend to When Managing High-Risk Cattle. (2020) (2)
- Manganese Catalyzed C−H Halogenation Published as part of the Accounts of Chemical Research special issue "Earth Abundant Metals in Homogeneous Catalysis". (2015) (2)
- Rearrangements of C11H10O ketones catalyzed by boron trifluoride (1975) (2)
- Taming Azide Radicals for Catalytic C—H Azidation (2016) (2)
- Biomimetic fabrication of materials: the minimalist approach (1996) (2)
- Enzymatic Regioselectivity in the Hydroxylation of Cholesterol Catalyzed by a Membrane-Spanning Metalloporphyrin. (1989) (2)
- Energy Landscape for the Electrocatalytic Oxidation of Water by a Single-Site Oxomanganese(V) Porphyrin. (2022) (1)
- Porphyrins and metalloporphyrins in synthetic bilayer membranes. (1994) (1)
- Remembering Edward I. Stiefel (2007) (1)
- Oxygen activation and transfer catalyzed by ruthenium porphyrins (1990) (1)
- How Forces of a Complex Adaptive System Affect Ability to Control Bovine Respiratory Disease in Feeder Cattle. (2022) (1)
- Models of Metalloenzymes: Carboxypeptidase A (1983) (1)
- SYNTHESIS AND SOLVOLYSIS OF TRICYCLO(4,3,2,0(2,5))UNDECA-3,8,10-TRIEN-7-OL, AN UNUSUAL (CH)11(+) REARRANGEMENT (1975) (1)
- Toxicity of the iron siderophore mycobactin J in mouse macrophages: Evidence for a hypoxia response. (2021) (1)
- Synthesis, Characterization, and Reactivity of Oxomanganese(IV) Porphyrin Complexes. (1989) (1)
- Aerobic Epoxidation of Olefins with Ruthenium Porphyrin Catalysts. (1986) (1)
- Announcement: Metals in Biology Gordon Research Conference (1997) (1)
- Concise Modular Synthesis and NMR Structural Determination of Gallium Mycobactin T. (2021) (1)
- “Oh by the Way, Flight Nursing Is Part of Your Job.” (2007) (1)
- Models of Metalloenzymes: Peroxidase and Cytochrome P-450 (1983) (1)
- Membrane-Spanning Steroidal Metalloporphyrins as Site-Selective Catalysts in Synthetic Vesicles. (1987) (1)
- Oxygen Activation by Metalloporphyrins Related to Peroxidase and Cytochrome P-450. Direct Observation of the O-O Bond Cleavage Step. (1987) (1)
- Synthesis of CaCO3 Thin Films via a Bioinspired Strategy: Cooperative Template-Inhibition (2000) (1)
- CATALYSIS OF SUPEROXIDE DISMUTATION (1977) (1)
- An Amorphous to Crystalline Transition in the Formation of CaCO3 Thin Films (2000) (1)
- On the reorganization of homobullvalenyl carbonium ions: A convenient synthesis of homobullvalenone (1973) (1)
- Faculty Opinions recommendation of Nature of the ferryl heme in compounds I and II. (2015) (0)
- Multi-Dimensional Analysis of Fluorescence Fluctuation Spectroscopy of Lipid Anchored Proteins in Live Cells Reveal Complex Organization in the Plasma Membrane (2014) (0)
- Production de proteines captives (2005) (0)
- Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation (2016) (0)
- Berichtigung: Targeted Fluorination with the Fluoride Ion by Manganese-Catalyzed Decarboxylation (2015) (0)
- Corrigendum: Targeted Fluorination with the Fluoride Ion by Manganese-Catalyzed Decarboxylation. (2015) (0)
- Combat Commanderʼs Observations (2007) (0)
- Manganese-Catalyzed Oxidative Benzylic C—H Fluorination by Fluoride Ions. (2013) (0)
- Retrospective: Edward I. Stiefel (1942-2006). (2006) (0)
- A Direct Route to Prepare Isocyanates via C-H Activation for Drug Discovery (2017) (0)
- Faculty of 1000 evaluation for Unusual cytochrome p450 enzymes and reactions. (2015) (0)
- Catalytic, Aerobic Oxygenations with Metalloporphyrin Catalysts. New Structural Insights into Stereoselectivity (1993) (0)
- Self-Assembly, Catalysis and Electron Transfer with Metalloporphyrins in Phospholipid Membranes (1995) (0)
- Asymmetric Hydroxylation, Epoxidation, and Sulfoxidation Catalyzed by Vaulted Binaphthyl Metalloporphyrins. (1990) (0)
- Announcment: Gordon Research Conference “Metals in Biology” (1995) (0)
- Kinetic selectivity in the N-alkylation of 2-pyridyl porphyrins: a facile approach to the alphaalphabetabeta scaffold. (2007) (0)
- Moduls kor nitric oxidk synthase (1997) (0)
- Oxomanganese(IV) Porphyrins Identified by Resonance Raman and IR Spectroscopy: Weak Bonds and the Stability of the Half-Filled t2g Subshell. (1988) (0)
- Synthetic models of metalloenzymes (1983) (0)
- Photolytic conversion of light alkanes to alkyl esters by iodine oxides and chloride salts in non-superacidic media (2018) (0)
- DEHALOGENATIONS WITH SODIUM BOROHYDRIDE, EVIDENCE FOR A FREE RADICAL REACTION (1974) (0)
- Characterization of an Oxoruthenium(IV) Porphyrin Complex. (1988) (0)
- EVIDENCE FOR A DIALKOXYIRON(IV) PORPHYRIN (1985) (0)
- Biocompatible catalysis. Forging a link between redox enzymes and synthetic metalloporphyrin catalysts in phospholipid bilayers (1991) (0)
- Selective Fluorination of Drug Molecules for Higher Potency, Improved Pharmacology and Lower Metabolic Burden (2013) (0)
- Faculty Opinions recommendation of Oxoiron(IV) in chloroperoxidase compound II is basic: implications for P450 chemistry. (2015) (0)
- Cis-Trans Isomerization of Epoxides Catalyzed by Ruthenium(II) Porphyrins. (1988) (0)
- A Green, Efficient, and Catalytic Method to Produce Chlorine Dioxide for the Purification and Treatment of Water (2011) (0)
- Studies of C–H Activation and Functionalization: Combined Computational and Experimental Efforts to Elucidate Mechanisms, Principles, and Catalysts (2021) (0)
- ON THE REORGANIZATION OF HOMOBULLVALENYL CARBONIUM IONS, A CONVENIENT SYNTHESIS OF HOMOBULLVALENONE (1974) (0)
- Faculty Opinions recommendation of Identifying the elusive sites of tyrosyl radicals in cytochrome c peroxidase: implications for oxidation of substrates bound at a site remote from the heme. (2015) (0)
- Partial Oxidation of Methane Enabled by Decatungstate Photocatalysis Coupled to Free Radical Chemistry (2023) (0)
- Biomimetic porphyrins in phospholipid vesicles. Toward a semi-synthetic redox membrane (1989) (0)
- A reevaluation of iron binding by Mycobactin J (2018) (0)
- Conversion of light alkanes to alkyl esters and chlorides using iodine oxides and chlorides: Radical versus non-radical pathways (2018) (0)
- Interaction of Peroxynitrite with MetMb probed by Fluorescein (2005) (0)
- New books (1976) (0)
- ALPHA-BROMOCYCLOPROPYL TRIFLUOROACETATES AS CYCLOPROPANONE PRECURSORS (1974) (0)
- DOWN WITH CARE PLANS (2008) (0)
- Host—Guest Interactions of Cyclodextrins and Metalloporphyrins: Supramolecular Building Blocks Toward Artificial Heme Proteins (2005) (0)
- Taking Young People to War (2007) (0)
- The Society of Biological Inorganic Chemistry (2002) (0)
- A Review of: “Zinc Enzymes. Volume 5 in the Metals in Biology Series; T. G. Spiroed., Wiley-Interscience, New York, 1983, ix + 359 pp., $89.95.” (1984) (0)
- EXAFS and XANES Studies of High-Valent Metal-Oxo Porphyrins Relevant to Horseradish Peroxidase (1987) (0)
- Selective partial oxidation of light alkanes using iodine oxides and halides (2017) (0)
- Targeted Fluorination with the Fluoride Ion by Manganese‐Catalyzed Decarboxylation. (2015) (0)
- Hydrogen-Deuterium Exchange During Propylene Epoxidation by Cytochrome P- 450. (1986) (0)
- Hypervalent iodine oxides and chloride for the conversion of light alkanes to mono-functionalized products: A radical-based process for selective partial oxidation (2018) (0)
- Preparation and Characterization of an (Acylperoxo)iron(III) Porphyrin. (1987) (0)
- A unique deuterium/proton exchange during cytochrome P-450 mediated expoxidation of propene and butene. (1988) (0)
- Personal Stories and Lessons Learned in a Combat Support Hospital in Baghdad (2007) (0)
- Directed multi-heme self-assembly and electron transfer in model phospholipid membranes (1995) (0)
- STEREOSPECIFIC ALIPHATIC HYDROXYLATION UPON PHOTOREDUCTION OF IRON(III) (1975) (0)
- Mechanism and Catalytic Potential of a Cytochrome P450 (OleT) that Catalyzes C‐C Bond Scission (2016) (0)
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