Karen Goldberg
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American chemist
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Chemistry
Karen Goldberg's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Karen Goldberg Influential?
(Suggest an Edit or Addition)According to Wikipedia, Karen Ila Goldberg is an American chemist, currently the Vagelos Professor of Energy Research at University of Pennsylvania. Goldberg is most known for her work in inorganic and organometallic chemistry. Her most recent research focuses on catalysis, particularly on developing catalysts for oxidation, as well as the synthesis and activation of molecular oxygen. In 2018, Goldberg was elected to the National Academy of Sciences.
Karen Goldberg's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist (2010) (2528)
- A soluble copper-bipyridine water-oxidation electrocatalyst. (2012) (601)
- Efficient catalysis of ammonia borane dehydrogenation. (2006) (504)
- Activation and functionalization of C-H bonds (2004) (231)
- Characterization of a Rhodium(I) σ-Methane Complex in Solution (2009) (210)
- Reactions of late transition metal complexes with molecular oxygen. (2012) (154)
- Kinetic studies of raindrop chemistry: 1. Inorganic and organic processes (1983) (150)
- Iridium-catalyzed dehydrogenation of substituted amine boranes: kinetics, thermodynamics, and implications for hydrogen storage. (2008) (128)
- Insertion of molecular oxygen into a palladium(II) hydride bond. (2006) (127)
- HOMOGENEOUS HYDROCARBON CH BOND ACTIVATION AND FUNCTIONALIZATION WITH PLATINUM (2003) (122)
- Mechanisms of C-C and C-H alkane reductive eliminations from octahedral Pt(IV): reaction via five-coordinate intermediates or direct elimination? (2003) (112)
- Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexes. (2001) (109)
- Energetics and Mechanisms of Carbon-Carbon and Carbon-Iodide Reductive Elimination from a Pt(IV) Center (1995) (105)
- C−H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides (1997) (98)
- Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex. (2009) (98)
- C-H bond activation by rhodium(I) hydroxide and phenoxide complexes. (2007) (96)
- C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water (2008) (91)
- Insertion of molecular oxygen into a palladium(II) methyl bond: a radical chain mechanism involving palladium(III) intermediates. (2009) (90)
- Sigma-borane complexes of iridium: synthesis and structural characterization. (2008) (88)
- Catalytic disproportionation of formic acid to generate methanol. (2013) (86)
- Hydrogenation of carboxylic acids catalyzed by half-sandwich complexes of iridium and rhodium. (2013) (84)
- C-H functionalization. (2012) (80)
- Insertion of dioxygen into a platinum-hydride bond to form a novel dialkylhydroperoxo Pt(IV) complex (1999) (79)
- Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexes. (2007) (78)
- Five-Coordinate Intermediates in Carbon−Carbon Reductive Elimination Reactions from Pt(IV) (2000) (77)
- Direct Observation of C−O Reductive Elimination from Pt(IV) (1999) (77)
- Synthesis, characterization, and reactivity of nickel hydride complexes containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) pincer ligands. (2009) (77)
- Reductive elimination of ethane from five-coordinate platinum(IV) alkyl complexes. (2007) (75)
- Large-Scale Selective Functionalization of Alkanes. (2017) (75)
- Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes. (2008) (71)
- Reductive Elimination and Dissociative β-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes (2009) (71)
- A stable five-coordinate platinum(IV) alkyl complex. (2001) (71)
- Preparation of a dihydrogen complex of cobalt. (2011) (70)
- Reactions of Pd and Pt complexes with molecular oxygen. (2014) (68)
- Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds. (2005) (67)
- Reductive elimination/oxidative addition of carbon-hydrogen bonds at Pt(IV)/Pt(II) centers: mechanistic studies of the solution thermolyses of Tp(Me2)Pt(CH3)2H. (2003) (66)
- Binuclear copper(II) complexes of 2-hydroxyacetophenone 4N-substituted thiosemicarbazones (1995) (66)
- Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) trans-Dihydride Complex (2006) (65)
- Competitive C−H Bond Activation and β-Hydride Elimination at Platinum(II) (2007) (65)
- Competitive Carbon-Carbon Reductive Elimination and Carbon-Iodide Bond Formation from a Pt(IV) Complex (1994) (65)
- Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex (2009) (62)
- Catalytic Arene H/D Exchange with Novel Rhodium and Iridium Complexes (2012) (61)
- Mechanism of direct molecular oxygen insertion in a palladium(II)-hydride bond. (2006) (61)
- Five-coordinate platinum(IV) complex as a precursor to a novel Pt(II) olefin hydride complex for alkane activation. (2002) (59)
- Hydrogenolysis of palladium(II) hydroxide and methoxide pincer complexes. (2009) (57)
- β-Diiminate Platinum Complexes for Alkane Dehydrogenation (2003) (55)
- OXIDATION OF DIMETHYLPLATINUM(II) COMPLEXES WITH DIOXYGEN (1998) (54)
- Hydrogenolysis of palladium(II) hydroxide, phenoxide, and alkoxide complexes. (2011) (53)
- Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System (2019) (50)
- Generation and structural characterization of a gold(III) alkene complex. (2013) (50)
- Alkane Dehydrogenation by C–H Activation at Iridium(III) (2013) (49)
- The Importance of Steric Factors in Iridium Pincer Complexes (2015) (49)
- Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides. (2010) (48)
- Five-Coordinate Platinum(IV) Complexes (2011) (48)
- Metal−Ligand Cooperativity in O2 Activation: Observation of a “Pt−O−O−C” Peroxo Intermediate§ (2010) (47)
- Synthesis, Structure, and Reactivity of Iridium NHC Pincer Complexes (2011) (47)
- Syntheses and Characterization of Palladium Complexes with a Hemilabile “PCO” Pincer Ligand (2011) (44)
- Iridium, Rhodium, and Ruthenium Catalysts for the “Aldehyde–Water Shift” Reaction (2014) (43)
- Partial Deoxygenation of Glycerol Catalyzed by Iridium Pincer Complexes (2013) (42)
- Autoxidation of platinum(IV) hydrocarbyl hydride complexes to form platinum(IV) hydrocarbyl hydroperoxide complexes. (2009) (39)
- Effects of Trifluoromethyl Substituents in a Tris(pyrazolyl)borate Ligand: A Structural and Spectroscopic Study of Analogous Platinum(IV) Trimethyl Complexes (2000) (38)
- The Key Role of the Hemiaminal Intermediate in the Iron-Catalyzed Deaminative Hydrogenation of Amides (2018) (38)
- The gem-Dialkyl Effect as a Test for Preliminary Diphosphine Chelate Opening in a Reductive Elimination Reaction† (2005) (35)
- Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C–H Activation (2015) (34)
- Partial Deoxygenation of 1,2-Propanediol Catalyzed by Iridium Pincer Complexes (2012) (32)
- Unsymmetrical (R)PNP(R') pincer ligands and their group 10 complexes. (2011) (32)
- Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones (2016) (32)
- Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen (2013) (31)
- Electrophilic Organoiridium(III) Pincer Complexes on Sulfated Zirconia for Hydrocarbon Activation and Functionalization. (2019) (31)
- Synthesis of dialkyl- and alkyl(acyl)rhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution (1989) (30)
- Organometallic C-H Bond Activation: An Introduction (2005) (30)
- Structural study of two N(4)-substituted thiosemicarbazones prepared from 1-phenyl-1,2-propanedione-2-oxime and their binuclear nickel(II) complexes (2002) (30)
- Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding. (2008) (30)
- Platinum(II) olefin hydroarylation catalysts: tuning selectivity for the anti-Markovnikov product. (2014) (30)
- Pincer Complexes as Catalysts for Amine Borane Dehydrogenation (2013) (29)
- Methylplatinum(II) and Molecular Oxygen: Oxidation to Methylplatinum(IV) in Competition with Methyl Group Transfer To Form Dimethylplatinum(IV) (2014) (29)
- Regeneration of an Iridium(III) Complex Active for Alkane Dehydrogenation Using Molecular Oxygen (2014) (28)
- Hydrogen Addition to (pincer)IrI(CO) Complexes:The Importance of Steric and Electronic Factors (2016) (28)
- β-Hydride Elimination and C-H Activation by an Iridium Acetate Complex, Catalyzed by Lewis Acids. Alkane Dehydrogenation Cocatalyzed by Lewis Acids and [2,6-Bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl]iridium. (2017) (27)
- Synthesis and structures of two N,N′-bis(2-pyridinyl)thioureas and N-(2-pyridinyl)-N′-(benzoyl)thiourea (2002) (27)
- Structural, spectral and thermal studies of N-2-(4,6-lutidyl)-N′-chlorophenylthioureas (2002) (27)
- Understanding the Effect of Ancillary Ligands on Concerted Metalation–Deprotonation by (dmPhebox)Ir(OAc)2(H2O) Complexes: A DFT Study (2014) (26)
- Existence of binuclear .pi.-bonded dinitrogen complexes (1982) (25)
- Organometallics Roundtable 2013–2014 (2014) (24)
- Reaction of a Palladium(II) Complex Chelated by a Tridentate PNC Ligand with Water to Produce a [(PN)Pd(μ-OH)]22+ Dimer: A Rare Observation of a Well-Defined Hydrolysis of a Pd(II)−Aryl Compound (2001) (24)
- C-H bond activation by cationic iridium (III) NHC complexes: A combined experimental and computational study (2012) (24)
- Structural Studies of 2,6-Diacetyl- and 2,6-Diformylpyridine Bis(thiosemicarbazones) (2002) (23)
- Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex (1988) (22)
- Oxygen-promoted C-H bond activation at palladium. (2014) (21)
- High Catalytic Efficiency Combined with High Selectivity for the Aldehyde–Water Shift Reaction using (para-cymene)Ruthenium Precatalysts (2016) (21)
- Palladium(II) and platinum(II) complexes of 6-methyl-2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazones: A structural and spectral study (1999) (20)
- A unique three-dimensional coordination cluster based on a silver carbene complex. (2011) (20)
- Structural, spectral and thermal studies of substituted N -(2-pyridyl)- N ′-phenylthioureas (2002) (20)
- C–H activation of benzene by platinum(II) complexes with cyclometalated phosphine ligands (2011) (18)
- Arene Activation at Iridium Facilitates C–O Bond Cleavage of Aryl Ethers (2014) (16)
- Synthesis, Characterization, and Reactivity of Arene-Stabilized Rhodium Complexes (2011) (16)
- Photolysis of Pincer-Ligated PdII–Me Complexes in the Presence of Molecular Oxygen (2017) (15)
- Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer PdII and PtII Hydrides (2014) (15)
- η6-Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium (2012) (14)
- Synthesis and characterization of a dinuclear Ni complex containing a bridging CNC pincer ligand (2010) (14)
- Detection of an Iridium-Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation. (2017) (14)
- Direct Formation of Carbon(sp3)-Heteroatom Bonds from RhIII To Produce Methyl Iodide, Thioethers, and Alkylamines. (2017) (13)
- Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure, and Reactivity (2009) (12)
- Reaction of a monomeric titanium hydride with dioxygen does not produce a stable titanium hydroperoxide (2011) (11)
- Experimental and Computational Investigation of the Aerobic Oxidation of a Late Transition Metal-Hydride. (2019) (11)
- Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes. (2014) (11)
- Structural, thermal and spectral studies of N-2-pyridyl-, N-2-picolyl- and N-2-(4,6-lutidyl)- N'-(3-methoxyphenyl)thioureas (2002) (11)
- Structural, spectral and thermal studies of N -2-(picolyl)- N ′-4-chlorophenylthioureas (2002) (11)
- Structural, spectral and thermal studies of N-2-(4-picolyl)- and N-2-(6-picolyl)-N′-(2-chlorophenyl)thioureas and N-2-(6-picolyl)-N′-(2-bromophenyl)thiourea (2002) (11)
- An unprecedented bonding mode for potassium within a PCP-pincer palladium hydride–K-Selectride® complex (2008) (10)
- Synthesis and physical properties of a dinuclear tantalum/cobalt radical with spin localized at one metal center (1988) (9)
- Structural studies of N-2-(6-picolyl)-N′-tolylthioureas (2002) (9)
- A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination. (2021) (8)
- {2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II) (2008) (8)
- Developing Molecular Copper Complexes for Water Oxidation (2014) (8)
- Insertion of Molecular Oxygen into the Metal–Methyl Bonds of Platinum(II) and Palladium(II) 1,3-Bis(2-pyridylimino)isoindolate Complexes (2018) (7)
- Oxidation of heterocyclic thioureas to form benzothiazoles and their copper(II) complexes (2003) (7)
- Structural and spectral studies of N-2-(pyridyl)-, N-2-(3-, 4-, 5-, and 6-picolyl)- and N-2-(4,6-lutidyl)-N'-2-thiomethoxyphenylthioureas (2001) (7)
- Structural, spectral and thermal studies of N-2-(pyridyl)- and N-2-(picolyl)-N′-(3-chlorophenyl)thioureas (2002) (7)
- Structural studies of N-2-(3-picolyl)- and N-2-(4-picolyl)-N′-tolylthioureas (2002) (6)
- Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination. (2020) (6)
- Electrophilic alkylation of an acyl metalate complex at the metal center leading to a stable methylacetylrhenium complex. Photochemical decomposition to give 2,3-butanedione via a mechanism involving carbonylation of free methyl radicals (1987) (6)
- Structural studies of N-2-(6-aminopyridine)- N'-arylthioureas (2003) (6)
- Homogeneous Hydrocarbon C—H Bond Activation and Functionalization with Platinum (2004) (5)
- Synthesis and Characterization of Iridium(I) and Iridium(III) Complexes Containing Dialkylbiphenylphosphines (2013) (5)
- Reactions of Square‐Planar d8 Pincer Complexes with Oxygen and Hydrogen (2014) (4)
- Valence orbital energetics as a tool for organometallic synthesis: On the scarcity of two-legged piano-stool complexes (1990) (4)
- Oxidative addition of iodine to (tBu)4(POCOP)Ir(CO) complexes (2017) (4)
- The Effect of the cis-donor in pincer ligands on hydrogenolysis of Pd-OH: A DFT study (2017) (3)
- Virtual Issue on Research in the Center for Enabling New Technologies Through Catalysis (CENTC) (2014) (3)
- [2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3 P,C 1,P′](nitrato-κO)nickel(II) (2008) (3)
- Preparation and Reactivity of Bimetallic (pincer)Ir Complexes (2020) (3)
- Mechanisms of Reactions Related to Selective Alkane Oxidation by Pt Complexes (2005) (3)
- Synthesis and Reactivity of PtII Methyl Complexes Supported by Pyrazolate Pincer Ligands (2020) (3)
- A Convenient One-Pot Synthesis of Di-t-butylphosphinic Chloride (2008) (3)
- Reactions of Pd and Pt Complexes with Molecular Oxygen (2015) (2)
- Hydrogenolysis of dinuclear PCNR ligated PdII μ-hydroxides and their mononuclear PdII hydroxide analogues. (2019) (2)
- VI.B.4 DOE Chemical Hydrogen Storage Center of Excellence (2005) (2)
- Lowering the Barrier to C–H Activation at IrIII through Pincer Ligand Design (2021) (2)
- Mono- and Dinuclear Binding Modes of the 2,5-Bis(α-pyridyl)pyrrolate Ligand in Platinum(II) Complexes (2021) (1)
- Comparing Square-Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity (2022) (1)
- (Hexamethylbenzene)Ru catalysts for the Aldehyde-Water Shift reaction (2021) (1)
- Beta-diiminate platinum complexes for alkane dehydrogenation. (2003) (1)
- Mechanism of molecular oxygen insertion in a Pd(II)-H Bond. (2007) (0)
- Synthesis and Physical Properties of a Dinuclear Tantalum-Cobalt Radical with Spin Localized at One Metal Center. (1988) (0)
- Synthesis of Dialkyl- and Alkylacylrhenium Complexes by Alkylation of Anionic Rhenium Complexes at the Metal Center. Mechanism of a Double Carbonylation Reaction That Proceeds via the Formation of Free Methyl Radicals in Solution. (1989) (0)
- Bond Activation by Metal Complexes: Special Issue in Honor of the 2017 Wolf Prize Laureate in Chemistry, Professor Robert G. Bergman (2017) (0)
- Metal-Ligand-Anion Cooperation in C-H Bond Formation at Platinum(II). (2022) (0)
- DMF (2018) (0)
- CCDC 812752: Experimental Crystal Structure Determination (2011) (0)
- LDRD Final Report on New Homogeneous Catalysts for Direct Olefin Epoxidation (LDRD 52591) (2006) (0)
- The underappreciated influence of ancillary halide on metal–ligand proton tautomerism (2022) (0)
- CCDC 812749: Experimental Crystal Structure Determination (2011) (0)
- DESIGNING NEW HOMOGENEOUS TRANSITION METAL CATALYSTS FOR AEROBIC OXIDATIONS (2018) (0)
- Structural investigations of Ir pincer complexes relevant to catalytic H2 release from the chemical hydrogen storage material H3BNH3 (2009) (0)
- Direct Epoxidations Using Molecular Oxygen. (2006) (0)
- Formanilide (2018) (0)
- CCDC 645129: Experimental Crystal Structure Determination (2007) (0)
- Rapid, Reversible Intramolecular C-H Oxidative Addition and Hydrogen Exchange in a Heterodinuclear “Early-Late” Transition-Metal Complex. (1988) (0)
- Catalyst (2018) (0)
- BINUCLEAR COPPER(II) COMPLEXES OF 2- HYDROXYACETOPHEN ONE 4N-SUBSTITUTED THIOSEMICARBAZON ES (1995) (0)
- Competitive C-H bond activation and beta-hydride elimination at platinum(II). (2007) (0)
- The_Key_Role_of_the_Hemiaminal_Intermediate_in_the_Iron-Catalyze (2018) (0)
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