Karl Wieghardt
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German chemist
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Karl Wieghardtchemistry Degrees
Chemistry
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Inorganic Chemistry
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Chemistry
Karl Wieghardt's Degrees
- PhD Chemistry University of Göttingen
Why Is Karl Wieghardt Influential?
(Suggest an Edit or Addition)According to Wikipedia, Karl Wieghardt is a German inorganic chemist and emeritus director of the Max Planck Institute for Chemical Energy Conversion in Mülheim. He was active in the preparation and detailed characterization of models for iron and manganese metalloenzymes, metal complexes of noninnocent ligands, and magnetic interactions in polynuclear metal complexes.
Karl Wieghardt's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Radical Ligands Confer Nobility on Base-Metal Catalysts (2010) (696)
- The Active Sites in Manganese‐Containing Metalloproteins and Inorganic Model Complexes (1989) (531)
- Handbook of metalloproteins (2006) (499)
- Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd). The art of establishing physical oxidation states in transition-metal complexes containing radical ligands. (2001) (446)
- Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study. (2006) (379)
- Führer durch die Strömungslehre (1990) (341)
- Synthesis, crystal structures, reactivity, and magnetochemistry of a series of binuclear complexes of manganese(II), -(III), and -(IV) of biological relevance. The crystal structure of [L'MnIV(.mu.-O)3MnIVL'](PF6)2.H2O containing an unprecedented short Mn.cntdot..cntdot..cntdot.Mn distance of 2.296 (1988) (338)
- Aerobic Oxidation of Primary Alcohols (Including Methanol) by Copper(II)− and Zinc(II)−Phenoxyl Radical Catalysts (1999) (308)
- Joint spectroscopic and theoretical investigations of transition metal complexes involving non-innocent ligands. (2007) (247)
- An Octahedral Coordination Complex of Iron(VI) (2006) (235)
- Molecular and electronic structures of bis(pyridine-2,6-diimine)metal complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn). (2000) (235)
- Theoretical evidence for the singlet diradical character of square planar nickel complexes containing two o-semiquinonato type ligands. (2002) (234)
- Analysis and interpretation of metal-radical coupling in a series of square planar nickel complexes: correlated Ab initio and density functional investigation of [Ni(L(ISQ))(2)] (L(ISQ)=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-)). (2003) (215)
- Electronic structure of square planar bis(benzene-1,2-dithiolato)metal complexes [M(L)(2)](z) (z = 2-, 1-, 0; M = Ni, Pd, Pt, Cu, Au): an experimental, density functional, and correlated ab initio study. (2005) (214)
- Neutral bis(alpha-iminopyridine)metal complexes of the first-row transition ions (Cr, Mn, Fe, Co, Ni, Zn) and their monocationic analogues: mixed valency involving a redox noninnocent ligand system. (2008) (214)
- Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst. (1999) (214)
- Mononuclear (nitrido)iron(V) and (oxo)iron(IV) complexes via photolysis of [(cyclam-acetato)FeIII(N3)]+ and ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in water/acetone mixtures. (2000) (212)
- From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols. (1998) (199)
- Molecular and electronic structures of bis-(o-diiminobenzosemiquinonato)metal(II) complexes (Ni, Pd, Pt), their monocations and -anions, and of dimeric dications containing weak metal-metal bonds. (2003) (178)
- Magnetic properties of an octanuclear iron(III) cation (1993) (173)
- Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations. (2007) (172)
- On the turbulent friction layer for rising pressure (1951) (170)
- Molecular and electronic structure of four- and five-coordinate cobalt complexes containing two o-phenylenediamine- or two o-aminophenol-type ligands at various oxidation levels: an experimental, density functional, and correlated ab initio study. (2004) (170)
- Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: ligand versus metal reduction. (2010) (153)
- Dithiolene Radicals: Sulfur K-Edge X-Ray Absorption Spectroscopy and Harry's Intuition (2011) (151)
- Structural, spectroscopic, and computational study of an octahedral, non-heme [Fe-NO](6-8) Series: [Fe(NO)(cyclam-ac)]2+/+/0. (2004) (146)
- Electronic structure of 2,2'-bipyridine organotransition-metal complexes. Establishing the ligand oxidation level by density functional theoretical calculations. (2011) (144)
- Molecular and electronic structure of octahedral o-aminophenolato and o-iminobenzosemiquinonato complexes of V(V), Cr(III), Fe(III), and Co(III). Experimental determination of oxidation levels of ligands and metal ions. (2001) (143)
- Photolysis of cis- and trans-[FeIII(cyclam)(N3)2]+ Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species (1999) (143)
- Synthesis and characterization of (.mu.-hydroxo)bis(.mu.-acetato)diiron(II) and (.mu.-oxo)bis(.mu.-acetato)diiron(III) 1,4,7-trimethyl-1,4,7-triazacyclononane complexes as models for binuclear iron centers in biology; properties of the mixed valence diiron(II,III) species (1987) (142)
- Moderately strong intramolecular magnetic exchange interaction between the copper(II) ions separated by 11.25 .ANG. in [L2Cu2(OH2)2(.eta.-terephthalato)](ClO4)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1988) (139)
- The electronic structure of the isoelectronic, square-planar complexes [FeII(L)2]2- and [CoIII(L Bu)2]- (L2- and (L Bu)2-=benzene-1,2-dithiolates): an experimental and density functional theoretical study. (2005) (138)
- Synthesis and electronic structure of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes: evaluation of redox activity in single-component ethylene polymerization catalysts. (2010) (134)
- Experiments in Granular Flow (1975) (131)
- Phenoxyl Radical Complexes of Zinc(II) (1997) (128)
- Electronic and molecular structures of the members of the electron transfer series [Cr(tbpy)3]n (n = 3+, 2+, 1+, 0): an X-ray absorption spectroscopic and density functional theoretical study. (2011) (119)
- Experimental evidence for the noninnocence of o-aminothiophenolates: coordination chemistry of o-iminothionebenzosemiquinonate(1-) pi-radicals with Ni(II), Pd(II), Pt(II). (2001) (119)
- Metallocorroles with Formally Tetravalent Iron (1994) (118)
- Dinuclear and mononuclear manganese(IV)-radical complexes and their catalytic catecholase activity. (2004) (118)
- 1,4,7-Triazacyclononane-N,N',N''-triacetate (TCTA), a new hexadentate ligand for divalent and trivalent metal ions. Crystal structures of [CrIII(TCTA)], [FeIII(TCTA)], and Na[CuII(TCTA)].bul.2NaBr.bul.8H2O (1982) (117)
- Spin exchange coupling in asymmetric heterodinuclear complexes containing the .mu.-oxo-bis(.mu.-acetato)dimetal core (1992) (116)
- [L2Mn2(.mu.-O)2(.mu.-O2)](ClO4)2. The first binuclear (.mu.-peroxo)dimanganese(IV) complex (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). A model for the S4 .fwdarw. S0 transformation in the oxygen-evolving complex in photosynthesis (1990) (115)
- Kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to aquated iron(II). An undergraduate text book reaction revisited. (2002) (115)
- Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex. (2012) (114)
- Coordination chemistry of the bimacrocyclic, potentially binucleating ligand 1,2-bis(1,4,7-triaza-1-cyclononyl)ethane (dtne). Electrochemistry of its first transition series metal(II,III) complexes. Characterization of the new hemerythrin model complex [Fe2(dtne)(.mu.-O)(.mu.-CH3CO2)2]Br2.H2O (1985) (113)
- On the Resistance of Screens (1953) (113)
- Single‐Atom O‐Bridged Urea in a Dinickel(II) Complex together with NiII4, CuII2 and CuII4 Complexes of a Pentadentate Phenol‐Containing Schiff Base with (O,N,O,N,O)‐Donor Atoms (2003) (111)
- Metal-to-ligand electron transfer in diiminopyridine complexes of Mn-Zn. A theoretical study. (2001) (111)
- The geometric and electronic structure of [(cyclam-acetato)Fe(N)]+: a genuine iron(v) species with a ground-state spin S = 1/2. (2005) (111)
- A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. (2008) (110)
- Experimental fingerprints for redox-active terpyridine in [Cr(tpy)2](PF6)n (n = 3-0), and the remarkable electronic structure of [Cr(tpy)2]1-. (2012) (109)
- Excited-State Contributions to Ground-State Properties of Mixed-Valence Dimers: Spectral and Electronic-Structural Studies of [Fe2(OH)3(tmtacn)2]2+ Related to the [Fe2S2]+ Active Sites of Plant-Type Ferredoxins (1996) (104)
- Bis(imino)pyridine iron dinitrogen compounds revisited: differences in electronic structure between four- and five-coordinate derivatives. (2012) (104)
- Exchange Coupling in Homo- and Heterodinuclear Complexes CuIIM [M = Cr(III), Mn(III), Mn(II), Fe(III), Co(III), Co(II), Ni(II), Cu(II), Zn(II)]. Synthesis, Structures, and Spectroscopic Properties (1994) (103)
- Control of Iron(II) Spin States in 2,2′:6′,2″‐Terpyridine Complexes through Ligand Substitution (1999) (101)
- Redox potentials of bis(1,4,7-triazacyclononane complexes of some first transition series metals(II,III). Preparation of bis(1,4,7-triazacyclononane)nickel(III) perchlorate (1983) (100)
- The Electronic Structures of an Isostructural Series of Octahedral Nitrosyliron Complexes {Fe−NO}6,7,8 Elucidated by Mössbauer Spectroscopy (2000) (99)
- [{(C6H15N3)Fe}2(μ‐O)(μ‐CH3CO2)2]2+ a Dinuclear Iron, (III)Complex with a Metazidohemerythrin‐Type Structure (1983) (99)
- o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity (2010) (99)
- Electronic Structure of Antiferromagnetically Coupled Dinuclear Manganese (MnIIIMnIV) Complexes Studied by Magnetic Resonance Techniques (1998) (98)
- Square planar vs tetrahedral coordination in diamagnetic complexes of nickel(II) containing two bidentate pi-radical monoanions. (2005) (97)
- o-Iminobenzosemiquinonato(1-) and o-amidophenolato(2-) complexes of palladium(II) and platinum(II): a combined experimental and density functional theoretical study. (2002) (96)
- Phenylthiyl radical complexes of gallium(III), iron(III), and cobalt(III) and comparison with their phenoxyl analogues. (2001) (95)
- Mono- and dinuclear zinc(II) complexes of biological relevance. Crystal structures of [L2Zn](PF6)2, [L'Zn(O2CPh)2(H2O)], [L'2Zn2(.mu.-OH)2](ClO4)2, and [L'2Zn2(.mu.-OH)(.mu.-CH3CO2)2](ClO4).cntdot.H2O (L = 1,4,7-triazacyclononane, L' = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1992) (93)
- Mössbauer and electron paramagnetic resonance study of the double-exchange and Heisenberg-exchange interactions in a novel binuclear Fe(II/III) delocalized-valence compound (1990) (91)
- Hidden noninnocence: theoretical and experimental evidence for redox activity of a β-diketiminate1- ligand. (2011) (90)
- The S3 state of photosystem II: differences between the structure of the manganese complex in the S2 and S3 states determined by X-ray absorption spectroscopy. (1990) (90)
- Neutral-ligand complexes of bis(imino)pyridine iron: synthesis, structure, and spectroscopy. (2007) (89)
- Reduced N-alkyl substituted bis(imino)pyridine cobalt complexes: molecular and electronic structures for compounds varying by three oxidation states. (2010) (89)
- Tuning the oxidation level, the spin state, and the degree of electron delocalization in homo- and heteroleptic bis(alpha-diimine)iron complexes. (2009) (88)
- Biomimetic metal-radical reactivity: aerial oxidation of alcohols, amines, aminophenols and catechols catalyzed by transition metal complexes (2005) (87)
- Assembly and structural characterization of binuclear µ-oxo-di-µ-acetato bridged complexes of manganese(III). Analogues of the di-iron(III) centre in hemerythrin (1985) (86)
- New triply hydroxo-bridged complexes of chromium(III), cobalt(III), and rhodium(III): crystal structure of tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triiodide trihydrate (1982) (86)
- Die aktiven Zentren in manganhaltigen Metalloproteinen und anorganische Modellkomplexe (1989) (86)
- Synthesis and electronic structure determination of N-alkyl-substituted bis(imino)pyridine iron imides exhibiting spin crossover behavior. (2011) (86)
- Tetradentate bis(o-iminobenzosemiquinonate(1-)) pi radical ligands and their o-aminophenolate(1-) derivatives in complexes of nickel(II), palladium(II), and copper(II). (2004) (84)
- Nitridocyanometalates of CrV, MnV, and MnVI † (1998) (83)
- (.mu.-Hydroxo)bis(.mu.-carboxylato)diruthenium and (.mu.-oxo)bis(.mu.-carboxylato)diruthenium Complexes Containing Weatk Intramolecular Ru.cntdot..cntdot..cntdot.Ru interactions (1989) (83)
- Why Does the Active Form of Galactose Oxidase Possess a Diamagnetic Ground State? (1998) (83)
- Phenoxyl radical complexes of gallium, scandium, iron and manganese. (1997) (82)
- Bis(α-diimine)nickel Complexes: Molecular and Electronic Structure of Three Members of the Electron-Transfer Series [Ni(L)2]z (z = 0, 1+, 2+) (L = 2-Phenyl-1,4-bis(isopropyl)-1,4-diazabutadiene). A Combined Experimental and Theoretical Study (2007) (81)
- Neue μ‐Hydroxo‐Übergangsmetallkomplexe, I. Darstellung und Struktur des trans‐Diaqua‐di‐μ‐hydroxo‐bis[(1,4,7‐triazacyclononan)cobalt(III)]‐Kations; Kinetik und Mechanismus seiner Bildung (1979) (79)
- Phenoxyl-copper(II) complexes: models for the active site of galactose oxidase (1997) (79)
- Redox-noninnocence of the S,S'-coordinated ligands in bis(benzene-1,2-dithiolato)iron complexes. (2005) (78)
- Bis(alpha-diimine)iron complexes: electronic structure determination by spectroscopy and broken symmetry density functional theoretical calculations. (2008) (77)
- Electronic structure of the [tris(dithiolene)chromium](z) (z = 0, 1-, 2-, 3-) electron transfer series and their manganese(IV) analogues. An X-ray absorption spectroscopic and density functional theoretical study. (2009) (77)
- Magnetic exchange interactions in some novel .mu.-azido-bridged copper(II) dimers. Crystal structures of [L2Cu2(.mu.-N3)(N3)2](ClO4).cntdot.H2O, LCu(N3)2, [L2Cu2(.mu.-N3)2(ClO4)2], and L'Cu(N3)2 (L = N,N',N"-trimethyl-1,4,7-triazacyclononane and L' = 1,4,7-triazacyclononane) (1986) (77)
- 1,2-bis(pyridine-2-carboxamido)benzenate(2-), (bpb)2-: a noninnocent ligand. Syntheses, structures, and mechanisms of formation of [(n-Bu)4N][FeIV2(mu-N)(bpb)2(X)2] (X = CN-, N3-) and the electronic structures of [MIII(bpbox1)(CN)2] (M = Co, Fe). (2000) (76)
- Intramolecular Spin Interactions in Bis(phenoxyl)metal Complexes of Zinc(II) and Copper(II) (1999) (76)
- Vibrational markers for the open-shell character of transition metal bis-dithiolenes: an infrared, resonance raman, and quantum chemical study. (2006) (76)
- .mu.-Oxalato-cobalt(III) complexes (1973) (75)
- A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni). (2011) (75)
- Molecular and electronic structures of tetrahedral complexes of nickel and cobalt containing N,N'-disubstituted, bulky o-diiminobenzosemiquinonate(1-) π-radical ligands (2006) (75)
- The Chemistry of 1,4,7‐Triazacyclononane and Related Tridentate Macrocyclic Compounds (2007) (75)
- o-Iminobenzosemiquinonato complexes of Mn(III) and Mn(IV). Synthesis and characterization of [Mn(III)(L(ISQ))(2)(L(AP))] (S(t) = 1) and [Mn(IV)(L(ISQ))(2)(L(AP)-H)] (S(t) = 1/2). (2002) (74)
- Electronic Structures of the Electron Transfer Series [M(bpy)3]n, [M(tpy)2]n, and [Fe(tbpy)3]n (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1–): A Mössbauer Spectroscopic and DFT Study (2012) (74)
- [Tris(o-iminosemiquinone)cobalt(III)]—a radical complex with an St = 3/2 ground state (1999) (74)
- Syntheses, electrochemistry, and spectroscopic and magnetic properties of new mononuclear and binuclear complexes of vanadium(III), -(IV, and -(V) containing the tridentate macrocycle 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of [L2V2(acac)2(.mu.-O)]I2.2H2O, [L2V2O4(.mu.-O)].14 (1990) (74)
- Phenoxyl Radical Complexes (2002) (73)
- Syntheses, properties, and electrochemistry of transition-metal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-pyramidal PdIIN5 core (1986) (72)
- Nitridomanganese(V) and -(VI) Complexes Containing Macrocyclic Amine Ligands (1998) (72)
- Noninnocence of the ligand glyoxal-bis(2-mercaptoanil). The electronic structures of [Fe(gma)]2, [Fe(gma)(py)] x py, [Fe(gma)(CN)]1-/0, [Fe(gma)I], and [Fe(gma)(PR3)(n)] (n = 1, 2). Experimental and theoretical evidence for "excited state" coordination. (2003) (70)
- Exchange and Double-Exchange Phenomena in Linear Homo- and Heterotrinuclear Nickel(II,III,IV) Complexes Containing Six μ2-Phenolato or μ2-Thiophenolato Bridging Ligands (1996) (69)
- Tuning the Electronic Structure of Halidobis(o-imino-benzosemiquinonato)iron(III) Complexes. (2001) (69)
- Tuning the electronic structure of octahedral iron complexes [FeL(X)] (L = 1-alkyl-4,7-bis(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane, X = Cl, CH(3)O, CN, NO). The S = 1/2 <==>3/2 Spin equilibrium of [FeL(Pr)(NO)]. (2002) (69)
- Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions (2015) (68)
- Nonoxovanadium(IV) and oxovanadium(V) complexes with mixed O, X, O-donor ligands (X = S, Se, P, or PO). (2004) (68)
- Electron-transfer barriers in cobalt(III) and cobalt(II) bis complexes of 1,4,7-triazacyclononane (tacn) and 1,4,7-trithiacyclononane (ttcn). Crystal structures of [CoII(tacn)2]I2.H2O and of [CoIII(ttcn)2](ClO4)3 (1986) (67)
- [L2Fe 2II(μ‐OH)(μ‐CH3CO2)2](ClO4)·H2O, a Model Compound for the Diiron Centers in Deoxyhemerythrin (1985) (67)
- Tris(pyridinealdoximato)metal complexes as ligands for the synthesis of asymmetric heterodinuclear Cr(III)M species [M = Zn(II), Cu(II), Ni(II), Fe(II), Mn(II), Cr(II), Co(III)]: a magneto-structural study. (2001) (67)
- Accessing the different redox states of alpha-iminopyridines within cobalt complexes. (2009) (66)
- Do S,S'-coordinated o-dithiobenzosemiquinonate(1-) radicals exist in coordination compounds? the [AuIII(1,2-C6H4S2)2]1 -/0 couple. (2003) (66)
- Dinuclear Manganese(II,III,IV) Model Complexes for the Active Center of the Metalloprotein Photosystem II: Synthesis, Magnetism, and Crystal Structure of [LMnIII(μ‐O)(μ‐CH3CO2)2MnIVL][ClO4]3 (L = N,N′N″‐Trimethyl‐1,4,7‐triazacyclononane) (1986) (66)
- Synthesis of a Tetranuclear Manganese(IV) Cluster with Adamantane Skeleton: [(C6H15N3)4Mn4O6]4+ (1983) (65)
- Phenoxyl radical complexes of chromium(III), manganese(III), cobalt(III), and nickel(II) (2000) (64)
- Competing Exchange Interactions and Ground-State Variability: Linear Homo- and Heterotrinuclear Manganese(III, IV) Complexes with Tris(dimethylglyoximato)metalate(II) Tetraanions as Bridging Ligands (1998) (64)
- Über den Balken auf nachgiebiger Unterlage (64)
- Anilino Radical Complexes of Cobalt(III) and Manganese(IV) and Comparison with Their Phenoxyl Analogues (2000) (63)
- Reduction chemistry of aryl- and alkyl-substituted bis(imino)pyridine iron dihalide compounds: molecular and electronic structures of [(PDI)2Fe] derivatives. (2009) (63)
- Structural characterization of four members of the electron-transfer series [PdII(L)2)2]n (L = o-Iminophenolate derivative; n = 2-, 1-, 0, 1+, 2+). ligand mixed valency in the monocation and monoanion with S = (1)/(2) ground states. (2005) (62)
- Molecular and Electronic Structure of Five-Coordinate Complexes of Iron(II/III) Containing o-Diiminobenzosemiquinonate(1−) π Radical Ligands (2005) (61)
- A structural model for the water-oxidizing manganese cluster in photosystem II (1994) (61)
- Crown Thioether Complexes of AgI and CuI: The Crystal Structures of [{Ag3L3}AgL{AgL2}](ClO4)4 and [LCuI] (L = 1, 4, 7‐Trithiacyclononane) (1987) (60)
- Molecular and Electronic Structure of Nitridochromium(V) Complexes with Macrocyclic Amine Ligands (1998) (60)
- Coordinated o-dithio- and o-iminothiobenzosemiquinonate(1-) pi radicals in [MII(bpy)(L*)](PF6) complexes. (2003) (60)
- Synthesis and characterization of tris(bipyridyl)ruthenium(II)-modified mono-, di-, and trinuclear manganese complexes as electron-transfer models for photosystem II. (2000) (59)
- Electronic structures of tris(dioxolene)chromium and tris(dithiolene)chromium complexes of the electron-transfer series [Cr(dioxolene)(3)](z) and [Cr(dithiolene)(3)](z) (z = 0, 1-, 2-, 3-). A combined experimental and density functional theoretical study. (2007) (59)
- De novo design and characterization of copper centers in synthetic four-helix-bundle proteins. (2001) (59)
- Ruthenium Complexes Containing “Noninnocent” o-Benzoquinone Diimine/o-Phenylenediamide(2−) Ligands. Synthesis and Crystal Structure of the Nitrido-Bridged Complex [{LRu(o-C6H4(NH)2)}2(μ-N)](PF6)2·3CH3CN·C6H5CH3 (1998) (58)
- Characterization of a genuine iron(V)-nitrido species by nuclear resonant vibrational spectroscopy coupled to density functional calculations. (2007) (58)
- Octahedral (cis-cyclam)iron(III) complexes with O,N-coordinated o-iminosemiquinonate(1-) pi radicals and o-imidophenolate(2-) anions. (2002) (58)
- Mixed-Valent {FeIV(μ-O)(μ-carboxylato)2FeIII}3+ Core (2003) (57)
- Intramolecular Electron Transfer from Mn or Ligand Phenolate to Photochemically Generated RuIII in Multinuclear Ru/Mn Complexes. Laser Flash Photolysis and EPR Studies on Photosystem II Models (1999) (57)
- S = (3)/(2) <= => S = (1)/(2) spin crossover behavior in five-coordinate halido- and pseudohalido-bis(o-iminobenzosemiquinonato)iron(III) complexes. (2003) (57)
- Ligand-Based Redox Isomers of [Zn(II)(C(28)H(40)NO(2))(2)]: Molecular and Electronic Structures of a Diamagnetic Green and a Paramagnetic Red Form. (1999) (57)
- Electronic Structure of Linear Thiophenolate-Bridged Heterotrinuclear Complexes [LFeMFeL]n+ (M = Cr, Co, Fe; n = 1−3): Localized vs Delocalized Models (1999) (56)
- Molecular and electronic structure of square-planar gold complexes containing two 1,2-Di(4-tert-butylphenyl)ethylene-1,2-dithiolato ligands: [Au(2L)2]1+/0/1-/2-. A combined experimental and computational study. (2007) (56)
- Weak Pd…︁S Interactions in Palladium(II) Complexes with 1,4,7‐Trithiacyclononane as Ligand (1986) (56)
- Synthesis and Characterization of Mononuclear Octahedral Titanium(IV) Complexes Containing Ti:O, Ti(O2), and Ti(OCH3)x (x = 1-3) Structural Units (1994) (56)
- An electron-transfer series of high-valent chromium complexes with redox non-innocent, non-heme ligands. (2008) (55)
- Synthesis and coordination chemistry of the hexadentate ligands 1,4,7-tris(2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L1) and 1,4,7-tris(3-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L2). Crystal structures of [HL1CuII] and [L2FeIII]acacH (1990) (55)
- Scrutinizing low-spin Cr(II) complexes. (2012) (54)
- Tuning of spin transition in radical-containing iron(III) complexes by remote ligand substituents. (2005) (54)
- Resonance Raman Spectroscopic Study of Phenoxyl Radical Complexes (1998) (53)
- Model compounds for the oxidized uteroferrin-phosphate complex. Syntheses, crystal structures, and magnetic properties of .mu.-phosphato-, .mu.-arsenato-, and .mu.-chromato-bridged binuclear iron(III) complexes (1989) (52)
- Bioinorganic model complexes for the active site in manganese containing catalases. The crystal structures of [L2MnII2(μ-OH)(μ-O2CCH3)2] (PF6)·CH3OH and [L′2MnIII2(μ-O)(μ-O2CCH3)2] (I3)I·H2O (1989) (52)
- Six-membered electron transfer series [V(dithiolene)(3)](z) (z = 1+, 0, 1-, 2-, 3-, 4-). An X-ray absorption spectroscopic and density functional theoretical study. (2010) (52)
- Crystallographic study of the low-spin iron(II) and iron(III) bis complexes of 1,4,7-triazacyclononane (1985) (52)
- Monoanionic molybdenum and tungsten tris(dithiolene) complexes: a multifrequency EPR study. (2011) (51)
- Polynuclear complexes of the pendent-arm ligand 1,4,7-tris(acetophenoneoxime)-1,4,7-triazacyclononane. (2002) (51)
- Syntheses and magnetic properties of a heteropolyoxotungsten(VI)iron(III) cation and [LFeIII(.mu.-MO4)3FeIIIL] complexes (M = chromium(VI), molybdenum(VI)). Crystal structures of L2Fe2(CrO4)3.cntdot.H2O and [L3Fe3W4O14(OCH3)3](ClO4)2.cntdot.0.5H2O (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1988) (51)
- Cobalt(II)/(III) Complexes Containingo-Iminothiobenzosemiquinonato(1−) ando-Iminobenzosemiquinonato(1−) π-Radical Ligands (2002) (51)
- Vom Strukturmodell der Galactose‐Oxidase zur homogenen Katalyse: effiziente aerobe Oxidation von Alkoholen (1998) (50)
- Structural characteristics of redox-active pyridine-1,6-diimine complexes: Electronic structures and ligand oxidation levels (2019) (50)
- The novel mixed-valence, exchange-coupled, class III dimer [L2Fe2(µ-OH)3]2+(L =N,N′,N″-trimethyl-1,4,7-triazacyclononane) (1989) (49)
- The [Mn 2IV(μ‐O)(μ‐PhBO2)2]2+ Unit: A New Structural Model for Manganese‐Containing Metalloproteins (1996) (49)
- Aerial oxidation of primary alcohols and amines catalyzed by Cu(II) complexes of 2,2'-selenobis(4,6-di-tert-butylphenol) providing [O,Se,O]-donor atoms. (2004) (49)
- Characterization and electronic structures of five members of the electron transfer series [Re(benzene-1,2-dithiolato)3](z) (z = 1+, 0, 1-, 2-, 3-): a spectroscopic and density functional theoretical study. (2009) (48)
- Redox noninnocence of nitrosoarene ligands in transition metal complexes. (2011) (48)
- Ruthenium(II) and osmium(II) complexes bearing bipyridine and the N-heterocyclic carbene-based C^N^C pincer ligand: an experimental and density functional theory study. (2013) (48)
- The monofunctionalized 1,4,7-triazacyclononane derivatives 1,4,7-triazacyclononane-N-acetate (L1) and N-(2-hydroxybenzyl-1,4,7-triazacyclononane (HL2) and their complexes with vanadium(IV)/(V). Localized and delocalized electronic structures in compounds containing the mixed valent [OVIVOVVO]3+ core (1995) (48)
- The electronic structure of non-heme iron(III)-hydroperoxo and iron(III)-peroxo model complexes studied by Mössbauer and electron paramagnetic resonance spectroscopies. (2001) (48)
- The (.mu.-oxo)bis[trichloroferrate(III)] dianion revisited (1993) (47)
- General route to .mu.-hydroxo-bis(.mu.-acetato)-bridged heterometal dinuclear complexes. Syntheses, magnetic and redox properties, electronic spectra, and molecular structures of the [Cr(III)-Co(II)] and [Cr(III)-Fe(II)] species (1987) (47)
- The First μ(OH)‐Bridged Model Complex for the Mixed‐Valent FeIIFeIII Form of Hemerythrin (1996) (47)
- Synthesis and Electronic Structure of Reduced Bis(imino)pyridine Manganese Compounds (2012) (47)
- [{Fe(tim)}2]: an Fe-Fe dimer containing an unsupported metal-metal bond and redox-active N4 macrocyclic ligands. (2009) (47)
- Excited-State Distortions and Electron Delocalization in Mixed-Valence Dimers: Vibronic Analysis of the Near-IR Absorption and Resonance Raman Profiles of [Fe(2)(OH)(3)(tmtacn)(2)](2+). (1996) (47)
- Macrocyclic complexes of indium(III): novel .mu.-hydroxo- and .mu.-oxo-bridged complexes. Crystal structures of [L4In4(.mu.-OH)6](S2O6)3.4H2O and [L2In2(CH3CO2)4(.mu.-O)].2NaClO4 (L = 1,4,7-triazacyclononane) (1986) (46)
- Metallocorrole mit formal vierwertigem Eisen (1994) (46)
- Preparation, Magnetism, and Crystal Structures of the Tautomers [LCu(μ2-OH)2CuL](ClO4)2 (Blue) and [LCu(μ2-OH2)(μ2-O)CuL](ClOμ4)μ2 (Green): μ-Aqua-μ-oxo vs. Di-μ-hydroxo Linkage (1985) (46)
- Intramolecular Long-Range Exchange Coupling in Dinuclear Copper(II) Complexes with Cu…Cu Separations Greater than 10Å (1995) (45)
- Molecular and electronic structure of nitridocyanometalates of chromium(V) and manganese(V): a combined experimental and DFT study. (2000) (45)
- Variable-temperature single-crystal electron spin resonance study and crystal structure of bis(1,4,7-triazacyclononane)copper(2+) tricyanocuprate(2-) dihydrate at 110 and 293 K. Static and dynamic Jahn-Teller distortions in the CuN6 polyhedron (1986) (45)
- Syntheses of [LRe(CO)3]+ and [LRe(NO)(CO)2]2+ and their oxidative decarbonylation product [LReO3]+. Crystal structure of [LReO3]Cl (L = 1,4,7-triazacyclononane) (1986) (45)
- Metal- versus Ligand-Centered Oxidations in Phenolato-Vanadium and -Cobalt Complexes: Characterization of Phenoxyl-Cobalt(III) Species. (1997) (45)
- Electronic structure of a weakly antiferromagnetically coupled Mn(II)Mn(III) model relevant to manganese proteins: a combined EPR, 55Mn-ENDOR, and DFT study. (2011) (45)
- Mono- and dinuclear (o-thioetherphenolato)-copper(II) complexes. Structural models for galactose oxidase (2002) (45)
- Linkage isomerism in exchange coupled dinuclear Ni(II) complexes with three azide bridges; tris(μ-1,1-azido) versus tris(μ-1,3-azido) binding. Crystal structures of [L2Ni2(μ-1,1-N3)3]ClO4 and [L2Ni2(N3)2-(μ-1,3-N3)2] (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1996) (44)
- Exchange Coupling in Symmetrically syn,syn-Mono(carboxylato)-Bridged Dinuclear Copper(II) Complexes. (1996) (44)
- Electronic structure of neutral and monoanionic tris(benzene-1,2-dithiolato)metal complexes of molybdenum and tungsten. (2007) (44)
- Electronic structures of homoleptic [tris(2,2'-bipyridine)M]n complexes of the early transition metals (M = Sc, Y, Ti, Zr, Hf, V, Nb, Ta; n = 1+, 0, 1-, 2-, 3-): an experimental and density functional theoretical study. (2013) (44)
- Synthesis and Characterization of Six-Coordinate Nitrido Complexes of Vanadium(V), Chromium(V), and Manganese(V). Isolation of a Dinuclear, Mixed-Valent &mgr;-Nitrido Chromium(III)/Chromium(V) Species. (1996) (44)
- Spin-Dependent Delocalization in Three Isostructural Complexes [LFeNiFeL](2+/3+/4+) (L = 1,4,7-(4-tert-Butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane). (1999) (43)
- Exchange Coupling in an Isostructural Series of Face-Sharing Bioctahedral Complexes [LM(II)(&mgr;-X)(3)M(II)L]BPh(4) (M = Mn, Fe, Co, Ni, Zn; X = Cl, Br; L = 1,4,7-Trimethyl-1,4,7-triazacyclononane). (1997) (43)
- Reversible electron transfer coupled to spin crossover in an iron coordination salt in the solid state. (2008) (43)
- The Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane and Its Complexes with Zinc(II), Cadmium(II), and Mercury(II) in Solution and in the Solid State (1995) (43)
- A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration (1992) (43)
- Molecular and Electronic Structures of Homoleptic Six-Coordinate Cobalt(I) Complexes of 2,2':6',2″-Terpyridine, 2,2'-Bipyridine, and 1,10-Phenanthroline. An Experimental and Computational Study. (2015) (43)
- Ferromagnetic intramolecular interactions in a bis(.mu.-bromo)-bridged copper(II) dimeric compound: crystal structure and molecular structure determination, electron paramagnetic resonance studies, and magnetic susceptibility measurements on bis(.mu.-bromo)bis(diethylenetriamine)copper(II)] perchlor (1985) (42)
- Mono- and dinuclear titanium(III)/titanium(IV) complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of a compositionally disordered green and a blue form of [LTiCl3]. Structures of [LTi(O)(NCS)2], [LTi(OCH3)Br2](ClO4), and [L2Ti2(O)2F2(.mu.-F)](PF6) (1992) (42)
- Molecular and electronic structures of oxo-bis(benzene-1,2-dithiolato)chromate(V) monoanions. A combined experimental and density functional study. (2006) (42)
- Macrocyclic complexes of lead(II): crystal structures of LPb(ClO4)2 and LPb(NO3)2 (L = 1,4,7-triazacyclononane) (1986) (42)
- Mono- and Dinuclear Transition Metal Complexes of the Hexadentate Ligand Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane (L). (1996) (42)
- PREPARATION AND CHARACTERIZATION OF DIPICOLINATOVANADIUM(V) COMPLEXES. KINETICS AND MECHANISM OF THEIR REACTION WITH HYDROGEN PEROXIDE IN ACIDIC MEDIA (1978) (41)
- Charakterisierung von Distorsionsisomeren der Anionen Pentacyano‐oxo‐molybdat(IV) sowie Tetracyano‐oxo‐aqua‐molybdat(IV) im festen Zustand. Kristallstrukturen von [(C6H5)4P]3[MoO(CN)5] · 7 H2O(grün), [(C6H5)4As]2 [MoO(OH2)(CN)4] · 4 H2O (blau) und [(C6H5)4P]2[MoO(OH2)(CN)4] · 4 H2O (grün) (1983) (41)
- Molecular and electronic structures of the members of the electron transfer series [Mn(bpy)3]n (n = 2+, 1+, 0, 1-) and [Mn(tpy)2]m (m = 4+, 3+, 2+, 1+, 0). An experimental and density functional theory study. (2014) (41)
- Molecular and electronic structures of six-coordinate "low-valent" [M((Me)bpy)3]0 (M = Ti, V, Cr, Mo) and [M(tpy)2]0 (M = Ti, V, Cr), and seven-coordinate [MoF((Me)bpy)3](PF6) and [MX(tpy)2](PF6) (M = Mo, X = Cl and M = W, X = F). (2013) (41)
- Octahedral non-heme non-oxo Fe(IV) species stabilized by a redox-innocent N-methylated cyclam-acetate ligand. (2005) (41)
- (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III) : a model for the iron-sulfur center in nitrile hydratase from Brevibacterium, sp. (1993) (41)
- A unique series of dinuclear transition metal-polyradical complexes with a m-phenylenediamine spacer and their catalytic reactivity. (2003) (40)
- Preparation and magnetism of the binuclear iron(II) complexes [{Fe(C9H21N3)X2}2](X = NCS, NCO, or N3) and their reaction with NO. Crystal structures of [{Fe(C9H21N3)(NCS)2}2] and [Fe(C9H21N3)(NO)(N3)2] (1987) (40)
- Reactions of low valent transition metal complexes with hydrogen peroxide. Are they "Fenton-like" or not? 4. The case of Fe(II)L, L = edta; hedta and tcma. (1995) (40)
- A Magnetostructural and Electrochemical Study of CuII and FeIII Complexes Containing a Tetradentate Aminebis(phenolate) Ligand with a Pendent Tetrahydrofuran Group (2007) (40)
- Mononuclear and dinuclear ruthenium complexes containing the LRu(acac) fragment. Crystal structures of [LRuIII(acac)(OH)]PF6.cntdot.H2O, [{LRuIII(acac)}2(.mu.-O2H3)](PF6)3, and [{LRuIII(acac)}2(.mu.-O)](PF6)2. Characterization of the mixed-valence species [{LRu(acac)}2(.mu.-O)](PF6)3 (L = 1,4,7-trim (1993) (40)
- Manganese complexes of mixed O, X, O-donor ligands (X = S or Se): synthesis, characterization and catalytic reactivity (2003) (40)
- Preparation and electrochemical investigation of monomeric complexes of molybdenum(0-VI) with the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structure of [MoIVLBr3](PF6) (1985) (39)
- (Alpha-diimine)chromium complexes: molecular and electronic structures; a combined experimental and density functional theoretical study. (2008) (39)
- Phenoxyl radical complexes of chromium(III) (1996) (39)
- Neutral bis(1,4-diaza-1,3-butadiene)nickel complexes and their corresponding monocations: molecular and electronic structures. A combined experimental and density functional theoretical study. (2007) (39)
- The trivalent copper complex of a conjugated bis-dithiocarbazate Schiff base: stabilization of Cu in three different oxidation states. (2013) (39)
- A novel mixed-valent MnIII–MnIV-dimer, [L2Mn2(µ-O)2(µ-MeCO2)][BPh4]2·MeCN: crystal structure, magnetic properties, and e.s.r. spectrum (L = 1,4,7-triazacyclononane) (1987) (39)
- Crown thioether chemistry of iron(II/III). Synthesis and characterization of low-spin bis(1,4,7-trithiacyclononane)iron(III) and crystal structure of [FeII([9]aneS3)([9]aneS3(O))](ClO4)2.2NaClO4.H2O (1987) (39)
- One- and two-electron reduced 1,2-diketone ligands in [CrIII(L*)3] (S = 0) and Na2(Et2O)2[VIV(LRed)3] (S = 1/2). (2008) (39)
- Electronic structures of the [V(tbpy)3]z (z = 3+, 2+, 0, 1-) electron transfer series. (2012) (38)
- Characterization of three members of the electron-transfer series [Fe(pda)2]n (n=2-, 1-, 0) by spectroscopy and density functional theoretical calculations [pda=redox non-innocent derivatives of N,N'-bis(pentafluorophenyl)-o-phenylenediamide(2-, 1.-, 0)]. (2008) (38)
- Reactivity of the [Fe2(μ2‐O)(μ‐acetato)2] Unit in Methemerythrin Model Compounds towards N 3⊖ and NCS⊖ (1985) (38)
- Ein Side-on-Superoxonickel-Komplex [LNi(O2)] mit quadratisch- planarem, vierfach koordinierten Nickel(II)-Zentrum und seine Umwandlung in [LNi(μ-OH)2NiL]† (2008) (38)
- From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond. (2008) (38)
- Syntheses and spectroscopic and magnetic properties of novel binuclear vanadium(III)/(IV) complexes. Crystal structures of [L2V2(.mu.-O)(.mu.-CH3CO2)2]I2.cntdot.2H2O and [L2V2O2(.mu.-CH3CO2)2]I2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1988) (38)
- Reaction between hydroxylamine and molybdate(VI): preparation of the complexes [Mo(NO)(CN)5]2-, [Mo(NO)(H2NO)Cl4]2-, and [Mo(NO)(H2NO)(N3)4]2-. Crystal structure of [(C6H5)4P]2[Mo(NO)(H2NO)(N3)4].H2O (1983) (38)
- The Monoanionic π-Radical Redox State of α-Iminoketones in Bis(ligand)metal Complexes of Nickel and Cobalt (2007) (37)
- Effect of N-methylation of macrocyclic amine ligands on the spin state of iron(III): a tale of two fluoro complexes. (2006) (37)
- The Molecular and Electronic Structure of Octahedral Tris(phenolato)iron(III) Complexes and Their Phenoxyl Radical Analogues: A Mössbauer and Resonance Raman Spectroscopic Study (1999) (37)
- Molecular and Electronic Structures of Iron Complexes Containing N,S-Coordinated, Open-Shell o-Iminothionebenzosemiquinonate(1−) π Radicals (2003) (37)
- Crystal structure of bis[bis(1,4,7-triazacyclononane)nickel(III)] dithionate heptahydrate and its single-crystal EPR spectrum (1986) (36)
- Redox reactivity of bis(1,4,7-triazacyclononane)iron(II/III) complexes in alkaline solution and characterization of a deprotonated species: amidoiron(III) vs aminyliron(II) ground-state formulation. EPR, kinetic, pulse radiolysis, and laser photolysis study (1988) (36)
- Dinuclear cyano complexes of cobalt(III) and Iron(III) containing noninnocent 1,2,4,5-tetrakis(2-pyridinecarboxamido)benzene bridging ligands. (2003) (36)
- Hydrolyseprodukte des monomeren Aminkomplexes (C6H15N3)FeCl3: Die Struktur des octameren Eisen(III)-Kations von {[(C6H15N3)6Fe8(μ3-O)2(μ2-OH)12] Br7(H2O)} Br•8H2O (1984) (36)
- The methanol-methanolate CH(3)OH...OCH3(-) bridging ligand: tuning of exchange coupling by hydrogen bonds in dimethoxo-bridged dichromium(III) complexes. (2002) (35)
- AEROBE OXIDATION PRIMARER ALKOHOLE MIT EINEM NEUEN EINKERNIGEN CUII-RADIKAL-KATALYSATOR (1999) (35)
- A Hemerythrin Model Complex with Catalase Activity (1993) (35)
- Kronenthioetherkomplexe des Blei(II), Zink(II) und Cadmium (II) und Cadmium(II). Die Kristallstrukturen von [PbL2(ClO4)2] und [ZnL2](ClO4)2 · CH3CN (L = 1,4,7 - Trithiacyclononan) (1989) (35)
- First-row transition metal complexes of the hexadentate macrocycle 1,4,7-tris(5-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (LH3). Crystal structures of [LTiIV]BPh4, [LCrIII], [LFeIII], and [(LH)2FeIII2](ClO4)2.2H2O (1993) (35)
- A new tetranuclear oxohydroxoiron(III) cluster: crystal structure, magnetic properties, and EXAFS investigation of [L4Fe4(.mu.-O)2(.mu.-OH)4]I4.cntdot.3H2O (L = 1,4,7-triazacyclononane) (1989) (35)
- Coordination chemistry of rhenium(V), -(IV), and -(III) with the macrocyclic ligands 1,4,7-triazacyclononane (L) and its N-methylated derivative (L'). Crystal structures of [LReCl3]Cl, [L2Re2Cl2(.mu.-Cl)(.mu.-OH)]I2.cntdot.2H2O, [L2Re2I2(.mu.-O)2]I2.cntdot.2H2O, and [L'2Re2Cl4(.mu.-O)]ZnCl4. Effect (1991) (35)
- Syntheses, magnetic properties, and crystal structures of the dimers [LNi(µ-N3)3NiL](ClO4) and [L′2Ni2(N3)2(µ-N3)2](L =N,N′,N″-trimethyl-1,4,7-triazacyclononane; L′= 1,5,9-triazacyclododecane); µ-triazido-vs. µ-diazido-bridging (1985) (35)
- Linear trinuclear oximato-bridged complexes MnIII,IVMIIMnIII,IV (M = Zn, Cu or Mn): synthesis, structure, redox behaviour and magnetism‡ (1997) (35)
- Spectroscopic identification of different types of copper centers generated in synthetic four-helix bundle proteins. (2004) (35)
- Synthesis, crystal structures, Moessbauer, susceptibility, and EPR studies of a series of spin exchange coupled complexes containing the (.mu.-oxo)bis(.mu.-acetato)rutheniummetal core and its hydroxo-bridged analog (metal = vanadium, chromium, manganese, iron, cobalt) (1992) (34)
- Anion dependent redox changes in iron bis-terdentate nitroxide {NNO} chelates. (2011) (34)
- Asymmetric mixed valence manganese complexes containing the [MnIII(µ-O)2(µ-MeCo2)MnIV]2+ core and their catalase reactivity (1992) (34)
- A Paramagnetic Copper(III) Complex Containing an Octahedral CuIII S6 Coordination Polyhedron. (1999) (34)
- Octahedral non-heme oxo and non-oxo Fe(IV) complexes: an experimental/theoretical comparison. (2006) (33)
- Dimerization processes of square planar [PtII(tbpy)(dithiolato*)]+ radicals. (2007) (33)
- Synthesis and crystal structure of bis(.mu.-hydroxo)bis[oxo(1,4,7-triazacyclononane)vanadium(IV)] dibromide, a .mu.-hydroxo-bridged cation with antiferromagnetically coupled vanadium(IV) centers (1984) (33)
- ON SPLITTING AND CRACKING OF ELASTIC BODIES (1995) (33)
- Synthesis, magnetic properties, redox behaviour, and crystal structure of the bridged binuclear nickel(II) complex [Ni2(µ-OH)(µ-CH3CO2)2L2]ClO4·H2O (1988) (32)
- Synthesis and x-ray and neutron structures of anti-dihydridodi-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dirhodium(2+) hexafluorophosphate and a related species containing a syn-[Rh2(H)2(.mu.-H)2]2+ core. Isolation of tri-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)diiron(1 (1993) (32)
- Trivalent iron and ruthenium complexes with a redox noninnocent (2-mercaptophenylimino)-methyl-4,6-di-tert-butylphenolate(2-) ligand. (2009) (32)
- Electronic Structures of “Low-Valent” Neutral Complexes [NiL2]0 (S = 0; L = bpy, phen, tpy) – An Experimental and DFT Computational Study (2015) (32)
- (Photo)ionization of tris(phenolato)iron(III) complexes: generation of phenoxyl radical as ligand (1993) (32)
- Asymmetric Heterodinuclear FeIIIMII (M = Zn, Cu, Ni, Fe, Mn), CoIIIFeII and FeIICoIII Species: Synthesis, Structure, Redox Behavior, and Magnetism (2004) (32)
- Molecular and electronic structures of iron(II)/(III) complexes containing N,S-coordinated, closed-shell o-aminothiophenolato(1-) and o-iminothiophenolato(2-) ligands. (2003) (32)
- Hydroxylamido(1-)-Komplexe des Titan(IV) und Zirkonium(IV) Die Kristall- und Molekülstruktur von Tetrakis-(N,N-diethylhydroxylamido(1-)-O,N)titan(IV) (1982) (31)
- Kronenthioetherkomplexe von AgI und CuI: Die Kristallstrukturen von [{Ag3L3}{AgL2}](ClO4)4 und [LCuI] (L=1,4,7-Trithiacyclononan) (1987) (31)
- New complexes of chromium(III) containing organic π-radical ligands: an experimental and density functional theory study. (2013) (31)
- Synthesis, magnetism and crystal structure of [V2O2(μ-OH)2(tpen)]I2·4H2O; a binuclear complex containing the syn-{VO(μ-OH)2VO}2+ core (tpen = tetrakis(2-pyridylmethyl)ethylenediamine) (1988) (31)
- Ligating properties of monomeric cis-trioxometal(VI) complexes of molybdenum(VI) and tungsten(VI). Preparation and spectroscopic characterization of LMO3 and [(LMO3)4CoII](ClO4)2 (M=Mo, W; L=Cyclic triamine) (1987) (30)
- Pendent arm macrocyclic complexes: crystal structures of AI(TCTA) and In(TS-TACN) (1993) (30)
- High‐field EPR investigations of MnIIIMnIV and MnIIMnIII states of dimanganese catalase and related model systems (2005) (30)
- μ‐Oxodiiron(III) Complexes of Porphycenes (1994) (30)
- Switching the mechanism of spin-exchange coupling in (.mu.-oxo)bis(.mu.-carboxylato)divanadium(III) complexes by protonation of the oxo bridge (1991) (29)
- The Molecular and Electronic Structure of Symmetrically and Asymmetrically Coordinated, Non‐Heme Iron Complexes Containing [FeIII(μ‐N)FeIV]4+ (S=3/2) and [FeIV(μ‐N)FeIV]5+ (S=0) Cores (1999) (29)
- Spectroscopic and magnetic properties of pseudooctahedral copper(2+) and cobalt(2+) complexes with 1,4,7-triazacyclononane and its monooxa and trithia analogs as ligands (1987) (29)
- Study of intradimer and interdimer exchange interactions in [Cu2(dien)2Cl2](ClO4)2 by electron paramagnetic resonance and magnetic susceptibility measurements (1985) (28)
- N,N-coordinated pi radical anions of S-methyl-1-phenyl-isothiosemicarbazide in two five-coordinate ferric complexes [Fe III(L Me*)(2)X] (X = CH3S-, Cl-). (2004) (28)
- A structural and magnetochemical study of some copper(II) complexes containing the ligands 1,4,7-triazacyclononane-N-acetate (L1) and N-(2-hydroxybenzyl)-1,4,7-triazacyclononane (HL2) (1996) (28)
- SYNTHESIS, STRUCTURE, MAGNETISM, AND SPECTROSCOPIC PROPERTIES OF SOME MONO- AND DINUCLEAR NICKEL COMPLEXES CONTAINING NONINNOCENT PENTANE-2,4-DIONE BI S(S-ALKYLISOTHIOSEMICARBAZONATE)-DERIVED LIGANDS (1997) (27)
- Square planar bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal complexes of Cr(II), Co(III), and Rh(II): an experimental and density functional theoretical study. (2009) (27)
- Monomeric complexes of tungsten(0-VI) containing the ligand N,N',N″-trimethyl-1,4,7-triazacyclononane and their electrochemical properties. Preparation of [L2W2O5](PF6)2 and identification of its mixed-valence tungsten(VI)/tungsten(V) complex (1985) (27)
- Exchange coupling in tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triperchlorate trihydrate (1983) (27)
- Polynuclear complexes containing the redox noninnocent Schiff base ligand 2-[(E)-2-mercaptophenylimino]methyl-4,6-di-tert-butylphenolate(2-) (2009) (27)
- Molecular and Electronic Structures of Mononuclear and Dinuclear Titanium Complexes Containing π-Radical Anions of 2,2'-Bipyridine and 1,10-Phenanthroline: An Experimental and DFT Computational Study. (2015) (27)
- Molecular and electronic structure of the square planar bis(o-amidobenzenethiolato)iron(III) anion and its bis(o-quinoxalinedithiolato)iron(III) analogue. (2008) (27)
- Transition-metal complexes with singly reduced 1,2-diketone radical ligands. (2008) (27)
- Electronic structures of five-coordinate complexes of iron containing zero, one, or two pi-radical ligands: a broken-symmetry density functional theoretical study. (2007) (27)
- Preparation and characterization of binuclear complexes of molybdenum(III) and molybdenum(V) via oxidative decarbonylation. Reactions of LMo(CO)3 (L = 1,5,9-triazacyclododecane) and crystal structure of anti-[L2Mo2O4](ClO4)2.2H2O (1985) (27)
- Hydroxylamido(1-)-O,N-Komplexe des Molybdäns(VI) mit terminalen Oxo-, Sulfido- und Selenido-Liganden Die Kristallstrukturen von [MoO2(C5H10NO)2] und von [MoS2(C5H10NO)2] (1982) (27)
- Long-range exchange interactions and integer-spin S(t) = 2 EPR spectra of a Cr(III)Zn(II)Cr(III) species with multiplet mixing. (2001) (26)
- Dependence of the Magnetic Superexchange on the CrċCr Distance in Dinuclear Chromium (II) Complexes (1990) (26)
- A trinuclear complex containing MnII MnIII MnIV, radicals, quinone and chloride ligands potentially relevant to PS II. (2006) (26)
- Stable cationic 17-electron [LM(CO)3]+ species (L = 1,4,7-tribenzyl-1,4,7-triazacyclononane ; M = Cr, Mo, W) : synthesis, spectroscopic properties, and reactivity. Crystal structure of [LMo(CO)3](PF6)•dmf (1990) (26)
- Complexes of (hydroxylamido-O,N)molybdenum(VI). Preparation and crystal structures of [MoO(H(CH3)NO)2(HNC(S)N(CH3)O)] and [MoO(H(CH3)NO)(HNC(S)N(CH3)O)(H2NC(S)N(CH3)O)].H2O (1980) (26)
- Synthesis and crystal structure of bis(1,4,7-triazacyclononane-NN′)platinum(II) dibromide dehydrate and its facile oxidation by oxygen: characterisation of bis(1,4,7-triazacyclononane-NN′N″)platinum(IV) tetraperchtorate (1983) (26)
- Novel cofacial bioctahedral complexes of ruthenium: syntheses and properties of the mixed-valence species [LRu2.5(.mu.-X)3Ru2.5L]2+ (X = Cl, Br, I, OH). Crystal structures of [LRu2.5(.mu.-OH)3Ru2.5L](PF6)2.cntdot.H2O and [LRuIV(.mu.-O)3RuIVL](PF6)2.cntdot.H2O (L = 1,4,7-trimethyl-1,4,7-triazacyclono (1990) (26)
- μ‐Nitridodiiron Complexes with Asymmetric [FeIVN‐FeIII]4+ and Symmetric [FeIVNFeIV]5+ Structural Elements (1995) (25)
- Reactions of Molybdate(VI) with Hydroxylamine and N‐Methylhydroxylamine (1979) (25)
- Co-ordination chemistry of 1,4,7-triazacyclononane (L) and its N-methylated derivative (L′) with silver(I) and mercury(II). The crystal structures of [AgL′2]PF6 and [AgL′(SCN)] (1991) (25)
- Electron paramagnetic resonance and electron nuclear double resonance investigation of the diradical bis(alpha-iminopyridinato)zinc complex. (2009) (25)
- Complexes of thallium(I) and -(III) containing 1,4,7-triazacyclononane (L) ligands. Kinetics and mechanism of the reduction of [L2TlIII]3+. Crystal structure of (N,N',N"-trimethyl-1,4,7-triazacyclononane)thallium(I) hexafluorophosphate (1986) (25)
- Reaktionen von Hydroxylamin mit Molybdän(VI): Synthese von (Hydroxylamido‐O,N)nitrosylmolybdän‐Komplexen. Die Struktur des [(Hydroxylamido‐O,N)nitrosylbis(1,10‐phenanthrolin)molybdän]‐Kations (1980) (25)
- Electronic structures and spectroscopy of the electron transfer series [Fe(NO)L2]z (z = 1+, 0, 1-, 2-, 3-; L = dithiolene). (2011) (25)
- Synthese von N‐phenolat‐funktionalisierten Makrocyclen des 1,4,7‐Trazacyclononans sowie des 1‐Oxa‐4,7‐diazacyclononans und ihre Komplexchemie mit Eisen(III) (1992) (25)
- The rhenium tris(dithiolene) electron transfer series: calibrating covalency. (2011) (25)
- The Crystal Structure and Magnetic Behavior of [Cu2(dien)2CI2](CIO4)2 (1984) (25)
- Redox Chemistry of (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7- triazacyclononane)ruthenium(III), [Ru(III)L]: Synthesis and Characterization of [Ru(II)(2)(L-L)](BPh(4))(4).10CH(3)CN and [LRuRuRuL](PF(6))(2).H(2)O. (1999) (24)
- Noninnocent Behavior of Nitrosoarene–Pyridine Hybrid Ligands: Ruthenium Complexes Bearing a 2-(2-Nitrosoaryl)Pyridine Monoanion Radical (2013) (24)
- Molecular and electronic structure of square planar complexes [PdII(tbpy)(L N,O IP)]0, [PdII(tbpy)(LN,O ISQ)](PF6), and [PdII(tbpy)(L N,O IBQ)](PF6)(BF4).2CH2Cl2: an o-iminophenolato based ligand centered, three-membered redox series. (2007) (24)
- A structural, spectroscopic and computational study of the molecular and electronic structure of a [bis(alpha-diiminato)manganese(II)] pi radical complex. (2008) (24)
- Dipicolinato(hydroxylamido‐O,N)(nitrosyl)aquavanadate—A Nitrosyl Complex of Vanadium with “side on” Coordinated Hydroxylamine (1978) (24)
- Structural and Spectroscopic Characterization of Rhenium Complexes Containing Neutral, Monoanionic, and Dianionic Ligands of 2,2'-Bipyridines and 2,2':6,2″-Terpyridines: An Experimental and Density Functional Theory (DFT)-Computational Study. (2016) (24)
- Coordination of 4,7-bis(2-hydroxybenzyl)-1-oxa-4,7-diazacyclononane (LH2) with manganese(II) and -(III) and zinc(II). Crystal structure of [(LH)2Zn2(.mu.-OH)](PF6).cntdot.0.5CH3OH (1992) (24)
- Synthesis and co-ordination chemistry of the macrocycle 1,4,7-triisopropyl-1,4,7-triazacyclononane (1993) (24)
- Trivalent Transition Metal Complexes [MIII(L-3H)] (M = Fe, Co) of the Triply Deprotonated Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane (L). Crystal Structure of [MnIV(L-3H)]BPh4 (1995) (23)
- Über einen Energiesatz zur Berechnung laminarer Grenzschichten (1948) (23)
- Synthesis, electrochemistry, and magnetic properties of binuclear cobalt complexes containing the Co2(µ-X)(µ-carboxylato)2n+core (X = OH, Cl, or Br; n= 1–3). The crystal structures of [Co2II(µ-ClH2CCO2)2(µ-Cl)L2]PF6and [CoIICoIII(µ-MeCO2)2(µ-OH)L2][ClO4]2·0.5H2O (L =N,N′,N″-trimethyl-1,4,7-triazacyc (1990) (23)
- Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states. (2009) (23)
- First-row transition-metal complexes of mixed ‘pendant-arm’ derivatives of 1,4,7-triazacyclononane containing phenolate and carboxylate functional groups (1996) (23)
- How “Innocent” Are Pentane‐2,4‐dionebis(S‐alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes? (1993) (23)
- Stabilization of high-valent Fe(IV)S6-cores by dithiocarbamate(1-) and 1,2-dithiolate(2-) ligands in octahedral [Fe(IV)(Et2dtc)(3-n)(mnt)(n)]((n-1)-) complexes (n=0, 1, 2, 3): a spectroscopic and density functional theory computational study. (2010) (22)
- Moderately strong antiferromagnetic exchange coupling in a dinuclear complex containing a µ-hydroxo-µ-carboxylatodicopper(II) core (1996) (22)
- Sn(III) and Ge(III) in the thiophenolato-bridged complexes [LFeSnFeL](n+) and [LFeGeFeL](n+) (n=2, 3; L=1,4,7-(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane) (1999) (22)
- New mono- and dinuclear titanium(III) complexes. The crystal structure of and exchange coupling in [{LTiIII(NCO)2}2(.mu.-O)] (L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1994) (22)
- O,N-Coordinated o-iminobenzoquinone and o-iminobenzosemiquinonato(1−) ligands in complexes of Ni(II), Co(III) and Fe(III) (2003) (22)
- The electrochemistry of a dimeric and two monomeric cis-trioxomolybdenum(VI) complexes containing cyclic triamine ligands in protic and aprotic media: model compounds for the active site informate dehydrogenase (1986) (22)
- Divalent Transition-Metal Complexes (LM(II))(ClO4)(2) (M=mn,Fe,Co,Ni,Cu,Pd) of the Hexadentate Ligand 1,4,7-Tris(O-Aminobenzyl)-1,4,7-Triazacyclononane(L) (1995) (22)
- Syntheses of Monomeric, Dimeric, and Trimeric Complexes of Tungsten(VI), (V), (IV), and (III) with the 1,4,7‐Triazacyclononane (L) Ligand. Crystal Structures of Dimeric [W2L2(μ2OH)2Br2]Br2 · 2H2O and of Trimeric [W3L3(μ30)(μ2‐0)3][ZnBr4]2 (1985) (21)
- Electronic structure of mononuclear bis(1,2-diaryl-1,2-ethylenedithiolato)iron complexes containing a fifth cyanide or phosphite ligand: a combined experimental and computational study. (2006) (21)
- Syntheses and characterization of stable pseudo-octahedral tris-phenolato complexes of vanadium-(III), -(IV), and -(V) (1990) (21)
- Kinetics and mechanism of the outer-sphere electron-transfer-induced formation of cis-dioxovanadium(V) species from vanadyl(IV) complexes. Crystal structures of [VO(TCDA)].cntdot.H2O and [VO2(TCDAH)].cntdot.2H2O (TCDA = 1,4,7-triazacyclononane-N,N'-diacetate) (1988) (21)
- Complexes of (hydroxylamido-O,N)molybdenum(VI). Preparation and crystal structures of dicesium bis(benzohydroximato)-cis-dioxomolybdate(VI) hydrate and of (benzohydroxamato)(benzohydroximato)(N,N-dimethylhydroxylamido-O,N)oxomolybdenum(VI) (1981) (20)
- Koordinierte o‐Dithio‐ und o‐Iminothiobenzosemichinonat(1−)‐π‐Radikale in [MII(bpy)(L.)](PF6)‐Komplexen (2003) (20)
- Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals. (2015) (20)
- Distortional Isomers of [LWOCl2]+ in the Solid State and in Solution; Crystal Structures of the Blue and Green Forms of [LWOCl2]PF6 (1985) (20)
- Dinuclear Bis(1,2-diaryl-1,2-ethylenedithiolato)iron complexes: [FeIII2(L)4]n (n = 2-, 1-, 0, 1+). (2006) (20)
- [L2FeII2(μ‐OH)(μ‐CH3CO2)2](CIO4)·H2O, eine Modellverbindung der Dieisenzentren in Desoxyhämerythrin (1985) (20)
- μ‐Hydroxo‐ and μ‐Oxobis(μ‐acetato)diruthenium Complexes with Weak Intramolecular RuċRu Interactions (1988) (20)
- Die [Mn2IV(μ‐O)(μ‐PhBO2)2]2+‐Einheit: ein neues Strukturmodell für manganhaltige Metalloproteine (1996) (19)
- LUDWIG PRANDTL AND HIS KAISER-WILHELM -INSTITUT (1987) (19)
- Reaktionen von Molybdat(VI) mit Hydroxylamin und N‐Methylhydroxylamin (1979) (19)
- Coordination chemistry of 2-(8-aminoquinolino)-4,6-di-tert-butylphenol with manganese(IV), iron(III), and cobalt(II/III):N,O-coordinated o-iminobenzosemiquinonate(1-) pi radical monoanions vs.o-iminophenolate(2-) dianions. (2004) (19)
- 1,4,7-Triazacyclononane and N,N'N''-trimethyl-1,4,7-triazacyclononane - two versatile macrocycles for the synthesis of monomeric and oligomeric metal complexes (1988) (19)
- The Cation Di‐μ‐oxo‐trans‐dioxobis[(1,4,7‐triazacyclononane)molybdenum(V)](Mo—Mo) and its Acid‐Catalyzed cis‐Isomerization (1983) (19)
- Elektronentransferbarrieren als Funktion der Ligandenstruktur in CoN63+/CoN62+-Paaren Beziehungen zwischen der Struktur und der Redoxreaktivität (1987) (19)
- Synthesis of low spin [MnII(L2)2]I2·2MeOH and [CuIII(L1)]via condensation of S-methylisothiosemicarbazide and pentane-2,4-dione in the presence of air (1993) (19)
- Preparation, molecular structure, and magnetism of bis(.mu.-carbonate)-.mu.-oxobis[1,4,7-trimethyl-1,4,7-triazacyclononane]diiron 4.25 hydrate (1989) (19)
- Electronic structures of [Ru(II)(cyclam)(Et(2)dtc)](+), [Ru(cyclam)(tdt)](+), and [Ru(cyclam)(tdt)](2+): an X-ray absorption spectroscopic and computational study (tdt = toluene-3,4-dithiolate; Et(2)dtc = N,N-diethyldithiocarbamate(1-)). (2009) (19)
- Neue μ‐Hydroxo‐Übergangsmetallkomplexe, II. Darstellung mehrkerniger Komplexe des Chroms(III) mit dreizähnigen Amin‐Liganden. Struktur des μ[cis‐Dihydroxo(O,O′)‐hydroxo(l,4,7‐triazacyclononan)chrom(III)]‐di‐μ‐hydroxobis[(1,4,7‐triazacyclononan)chrom(III)]‐Kations (1979) (19)
- The molecular and electronic structure of [FeIII2(t-buLISQ)4(μ-O)]—a dinuclear ferric complex containing four, O,N-coordinated o-iminobenzosemiquinonate(1−)π radical anions (2003) (19)
- Kinetics and mechanism of some reactions of chelated complexes of titanium(IV) with hydrogen peroxide. Synthesis and crystal structure of cesium tetra-.mu.-oxo-tetrakis[(nitrilotriacetato)titanate(IV)] hexahydrate (1980) (18)
- The reactivity of the {Mn2(μ-O)(μ-CH3CO2)2}2+ core. The crystal structures of [LMn(N3)3] and [L′Mn(S4)(H2O)] (L = 1,4,7-triazacyclononane, L′= N,N′,N″-trimethyl-1,4,7-triazacyclononane) (1987) (18)
- Neue μ‐Hydroxo‐Übergangsmetallkomplexe, III. Darstellung zweikerniger Komplexe des Rhodiums(III) mit einer μ‐Acetato‐ und μ‐Carbonato‐Brücke. Die Struktur des trans‐Diaqua‐di‐μ‐hydroxo‐bis[(1,4,7‐triazacyclononan)rhodium(III)]‐Kations (1980) (18)
- NMR spectra of dinuclear manganese and iron compounds containing 1,4,7-triazacyclononane and 1,4,7-trimethyl-1,4,7-triazacyclononane (1998) (18)
- Synthese von Wolframkomplexen des Typs [LW(CO)3X]+ (X = H, F, Br; L = 1,4,7-Triazacyclononan). Die Kristallstrukturen von [LW(CO)3Br]BF4 und [LW(CO)3H]2[WOCl5]·H2O / Synthesis of Tungsten Complexes of the Type [LW(CO)3X]+ (X=H, F, Br; L=1,4,7-triazacyclononane). The Crystal Structures of [LW(CO)3Br] (1987) (18)
- Influence of the redox active ligand on the reactivity and electronic structure of a series of Fe(TIM) complexes. (2010) (18)
- The First Mononuclear Nitrosyl(oxo)molybdenum Complex: Side‐On Bonded and μ3‐Bridging NO Ligands in [{MoL(NO)(O)(OH)}2]NaPF6·H2O (1994) (18)
- Octahedral monodithiolene complexes of cobalt(III) and chromium(III). Spectroscopic and density functional theoretical characterization of S,S'-coordinated benzene-1,2-dithiolate(1-) pi radicals. (2009) (18)
- The Chemistry of 1,4,7-Triazacyclononane and Related Tridentate Macrocyclic Compounds (1988) (18)
- Electronic structure of nitric oxide adducts of bis(diaryl-1,2-dithiolene)iron compounds: four-membered electron-transfer series [Fe(NO)(L)2]z (z = 1+, 0, 1-, 2-). (2007) (18)
- New .mu.-disulfido and .mu.-diselenido complexes of ruthenium(III). Crystal structure of [{LRuIII(acac)}2(.mu.-S2)](PF6)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; acac = pentane-2,4-dionate) (1993) (18)
- Preparation and crystal structure of tetrameric [Ti4(C6H15N3)4(μ-O)6]Br4·4H2O containing an adamantane Ti4O6 Core (1985) (17)
- Herstellung, Magnetismus und Kristallstrukturen der Tautomere [LCu(μ2‐OH)2CuL](CIO4)2 (blau) und [LCu(μ2‐OH2)(μ2‐O)CuL](CIO4)2 (grün): μ‐Aqua‐μ‐oxo‐ vs. Di‐μ‐hydroxo‐Verknüpfung (1985) (17)
- A theoretical study of zero-field splitting in Fe(IV)S6 (S = 1) and Fe(III)S6 (S = 1/2) core complexes, [FeIV(Et2dtc)3−n(mnt)n](n−1)− and [FeIII(Et2dtc)3−n(mnt)n]n− (n = 0, 1, 2, 3): The origin of the magnetic anisotropy (2013) (17)
- Zur Koordinationschemie von cis‐Trioxowolfram(VI)‐Komplexen. Die Kristallstrukturen von LWO3 · 3 H2O, [L′WO2(OH)]Br, [LWO2Br]Br, [L2W2O5](S2O6) · 4 H2O und [LWO2(μ‐O)WO(O2)2(OH2)] (L = 1,4,7‐Triazacyclononan; L′ = 1,4,7‐Trimethyl‐1,4,7‐triazacyclononan) (1990) (17)
- Synthesis and kinetics of the decarboxylation of two carbonate-bridged complexes of chromium(III) and rhodium(III). Crystal structure of .mu.-carbonato-di-.mu.-hydroxo-bis[(1,4,7-triazacyclononane)chromium(III)] diiodide hydrate (1980) (17)
- 2,2'-Bipyridine compounds of group 14 elements: a density functional theory study. (2013) (17)
- Interactive shape optimization of continuum structures (1997) (16)
- The molecular and electronic structures of monomeric cobalt complexes containing redox noninnocent o -aminobenzenethiolate ligands (2010) (16)
- Dipicolinato(hydroxylamido‐O,N)(nitrosyl)aquavanadat — ein Nitrosylkomplex des Vanadiums mit „side on”︁ koordiniertem Hydroxylamin (1978) (16)
- Schwingungsspektren und kristallgitter von hexamminchrom(III)- und hexamminkobalt(III)-hexafluoro-metallaten(III) (1971) (16)
- Über einige Versuche an Strömungen in Sand (1952) (16)
- Molecular and Electronic Structure of [MnVN(cyclam−acetato)]PF6. A Combined Experimental and DFT Study (2001) (16)
- Synthese von [LRe(CO)3]+-Komplexen mit makrocyclischen Liganden Die Kristallstrukturen von 1,4,7-Triazacyclononan-tricarbonylrhenium( I)-thiocyanat und 1,4,7-Trithiacyclononan-tricarbonylrhenium( I) -bromid-hemihydrat / Synthesis of [LRe(CO)3]+ Complexes with Macrocyclic Ligands The Crystal Structur (1988) (16)
- Synthese und Kristallstruktur des homoleptischen Thioether‐Rutheniumkomplexes [Ru(1,4,7‐trithiacyclononan)2](BPh4)2 · 2 Me2SO (1987) (16)
- Octahedral monodithiolene complexes of iron: characterization of S,S'-coordinated dithiolate(1-) pi radical monoanions: a spectroscopic and density functional theoretical investigation. (2009) (16)
- A Binuclear, Mixed‐Valence MoVI/V‐Complex; The Crystal Structure of [(C9H21N3)2Mo2VIO5](Br3)2 (1984) (16)
- 95Mo NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum (VI) (1983) (16)
- Iron complexes of new pentadentate ligands containing the 1,4,7-triazacyclononane-1,4-diacetate motif. spectroscopic, electro-, and photochemical studies. (2007) (16)
- Warum hat die aktive Form der Galactose-Oxidase einen diamagnetischen Grundzustand? (1998) (15)
- Synthesen mit (Hydroxylamido(1–)–O,N)molybdän(VI)‐Komplexen und Alkylcyaniden. Die Strukturen von Bis(N‐hydroxy‐Nmethylacetamidinato(1–)‐O,N′)(N‐methyl‐hydroxylamido(1–)‐O,N)oxomolybdän(VI)‐perchlorat und von μ‐Oxo‐bis[N‐hydroxy‐N‐methylacetamidinato(1–)‐O, N′→ Mo1;O → Mo2‐cis‐dioxo]dimolybdän(VI) (1981) (15)
- Molecular Recognition of Hexaaqua Transition Metal(II) Ions (1993) (15)
- The reactivity of cationic [trioxo-(1,4,7-triazacyclononane) rhenium(VII)] and oxorhenium(V) complexes containing triazamacrocycles (1988) (15)
- The ReRe Bond in Binuclear Di‐μ‐oxorhenium Complexes Containing the 1,4,7–Triazacyclononane Ligand (1990) (15)
- Exchange coupling across multiple-atom bridges: crystal structure and magnetic properties of a chloranilate bridged dicopper(II) complex (1998) (15)
- Magnetic interactions in dinuclear Mn(III)Mn(IV) complexes covalently tethered to organic radicals: spectroscopic models for the S(2)Y(z)(*) state of photosystem II. (2005) (15)
- Studies of distortional isomers. II: Evidence that green [LWOCl2]PF6 is a ternary mixture (1994) (15)
- Molecular and electronic structures of new iron complexes containing N,S-coordinated o-iminothionebenzosemiquinonate(1-) π radical ligands: An experimental and density functional theoretical study (2011) (15)
- Übergangsmetallkomplexe der Pyrazin‐2,6‐dicarbonsäure und der Pyridin‐2,6‐dicarbonsäure: Synthesen und Elektrochemie. Die Kristallstruktur von NH4[RuCl2(dipicH)2] (1985) (14)
- [{Fe(tim)}2]: ein Fe‐Fe‐Dimer mit einer unverbrückten Metall‐Metall‐Bindung und redoxaktiven N4‐makrocyclischen Liganden (2009) (14)
- An unusual CuII-promoted desulphurisation of thiourea: synthesis and crystal structure of di-µ-hydrogencyanamido(1–)-bis[(N,N′,N″-trimethyl-1,4,7-triazacyclononane)copper(II)] di-perchlorate monohydrate (1985) (14)
- Komplexe des Chroms mit 1,5,9-Triazacyclododecan: Darstellung, Magnetismus und Kristallstruktur von Tri-μ-hydroxo-bis[(1,5,9-triazacyclododecan)chrom(III)] tribromid Dihydrat; Kinetik und Mechanismus der Brückenspaltung mit Hydroxidionen (1985) (14)
- Di‐μ‐sulfato‐μ‐hydroxo‐bis[triamminkobalt(III)]‐ und Di‐μ‐selenato‐μ‐hydroxo‐bis[triamminkobalt(III)]‐Komplexe (1971) (14)
- Preparation and characterization of polynuclear cobalt(III) complexes with bridging carboxylato-ligands (1974) (14)
- One- and two-electron reduced 1,2-diketone ligands in [Zn(II)(L*)2(Et2O)], [Co(II)(L*)2(Et2O)], and Na2(Et2O)4[Co(II)(LRed)2]. (2008) (13)
- Kinetic and Electron Spin Resonance spectroscopic evidence for a chemical mechanism in the chromium(II) reduction of two (pyrazinecarboxylato)amminecobalt(III) complexes (1977) (13)
- Synthesis, properties and crystal structures of [RuIII2(tacn)2(µ-OH)2(µ-CO3)]Br2·3.75H2O and [Ru3.52(dtne)(µ-O)2(µ-CO3)]PF6·5H2O [tacn = 1,4,7-triazacyclononane, dtne = 1,2-bis(1,4,7-triazacyclononan-1-yl)ethane] (1994) (13)
- Temperature Dependence of the Electron Transfer in a Mn(II)Mn(III)(&mgr;-OH) Mixed-Valence Manganese Complex. (1996) (13)
- Schwache Pd ··· S‐Wechselwirkungen in Palladium (II)‐Komplexen mit 1,4,7‐Trithiacyclononan als Ligand (1986) (13)
- Mössbauer Spectroscopy of Spin-Coupled Iron−Chromium Complexes: μ-Hydroxo−Bis(μ-acetato)-Bridged Iron(2+)−Chromium(3+) and μ-Oxo−Bis(μ-acetato)-Bridged Iron(3+)−Chromium(3+) (1996) (13)
- [(TMEDA)Co(NO)2][BPh4]: A versatile synthetic entry point to four and five coordinate {Co(NO)2}10 complexes (2011) (13)
- Synthese eines Hydroxylamido(2 – )‐O, N‐(nitrosyl)‐molybdän‐Komplexes (1979) (13)
- Kronenthioetherkomplexe des Cobalt(III): Ligandenstruktur und Redoxreaktivität Struktur, Elektrochemie und Kinetik des Elektronenaustausches von [Co(tacn)(ttcn)]Br3 · 3 H2O (tacn = 1,4,7-Triazacyclononan, ttcn = 1,4,7-Trithiacyclononan) (1989) (13)
- Determining the Electronic Structure of a Series of [(phen)3M]0 (M = Ti, V, Mo) and [(pdi)2M]n+ (M = Cr, Mo) Complexes: Coordination of Neutral Ligands vs. π‐Radical Anions (2015) (13)
- Säure-Base-Eigenschaften des zyklischen Triamins N,N′,N″-Trimethyl-1,4,7-triazacyclononan: Die Kristallstruktur seiner monoprotonierten Form [C9H22N3]ClO4) / Acid-Base Properties of the Cyclic Triamine N,N′,N″-Trimethyl-1,4,7-triazacyclononane and Crystal Structure of its Monoprotonated Form [C9H22N (1987) (13)
- Synthesis and reactivity of tricarbonyl(1,4,7-trithiacyclononane)manganese(1+): kinetics and mechanism of its formation and the crystal structure of [LMn(CO)3]3(PF6)2Br.2H2O (L = 1,4,7-trithiacyclononane) (1989) (13)
- Forces in granular flow (1974) (13)
- Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence (2014) (13)
- Über die turbulente Strömung im Rohr und längs einer Platte (1944) (13)
- Reaction sequence in the hydroxo-bridge cleavage of the tri-.mu.-hydroxo-bis[triamminecobalt(III)] complex. Identification of an isomerization step (1977) (12)
- Intramolekulare Elektronenübertragung koordinierter Pyrazincarboxylato-Radikale zu Cobalt(III): Eine pulsradiolytische Untersuchung† (1978) (12)
- Structure–Magnetism Relationship in [TiIII‐OTiIII]4⊕ Complexes (1990) (12)
- Nucleophilic behaviour of monomeric cis-trioxotungsten(VI) complexes LWO3 (L = tridentate N-macrocycle) (1989) (12)
- Electronic structure of linear thiophenolate-bridged heteronuclear complexes [LFeMFeL](n)(+) (M = Cr, Co, Fe; n = 1-3): a combination of kinetic exchange interaction and electron delocalization. (2003) (12)
- Intramolecular Electron Transfer of Coordinated Pyrazinecarboxylato Radicals to Cobalt(III): A Pulse Radiolytic Study (1978) (12)
- Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+) (1984) (12)
- EPR and 55Mn cw-ENDOR study of an antiferrogmagnetically coupled dinuclear manganese (MnIII MnIV) complex (1996) (12)
- Coordination of the macrocyclic thioether 1,4,7-trithiacyclononane (TTCN) to chromium(3+) and to dimolybdenum(2+) di-acetato bridged molecules (1989) (12)
- Schwingungsspektrum und Kristallstruktur des fünffach-koordinierten cis-Dioxo-dipicolinato-vanadat(V)-Anions / Vibrational Spectrum and Crystal Structure of the cis-Dioxo-dipicolinato-vanadium(V) Anion (1978) (12)
- Configurational Isomerization of N,N‐Disubstituted Hydroxylamido(1‐)‐O,N‐Molybdenum(VI) Complexes (1981) (11)
- Magnetic exchange coupling in a nearly linear iron(III)nickel(II)nickel(II)iron(III) complex (1995) (11)
- Exchange Interactions and Covalency in Dinuclear Complexes of Iron(III) and Gallium(III) Containing the Redox‐Noninnocent Ligand 1,2‐Bis(3,5‐di‐tert‐butyl‐2‐hydroxyphenyl)oxamide (2003) (11)
- The missing link in the series [L2MIII2(µ-O)(µ-MeCO2)2]2+(M = Ti, V, Cr, Mn, Fe). Synthesis, crystal structure and magnetism of [L2CrIII2(µ-O)(µ-MeCO2)2][BPh4]2 (1990) (11)
- Reactions of hydroxylamido-(O,N) complexes of vanadium(V) and of molybdenum(VI) with oxalic acid. Crystal structure of (Et2NHOH)2[Mo2O4(Et2NO)2(C2O4)2]: a .mu.-dioxo complex containing two pentagonal-bipyramidal molybdenum(VI) ions (1981) (11)
- Redox-noninnocence of N,N'-bis(6-methyl-2-pyridylmethylene)ethane-1,2-diamine (L): synthesis and characterization of diamagnetic [Ni(II)2(L**)2] and [Zn(II)2(L)Cl4]((L**)2- pi diradical dianion of L). (2009) (11)
- Activation energies for an intramolecular electron transfer reaction (1980) (11)
- Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH3CO2)2](ClO4)(BF4).cntdot.H2O and of the mixed-val (1989) (10)
- Distorsionsisomere vom [LWOCl2]+ im festen Zustand und in Lösung; Kristallstrukturen der blauen und der der grünen Form von [LWOCl2]PF6 (1985) (10)
- Mehrkernige Kobalt(III)‐Ammin‐Komplexe mit Oxalat als zwei‐ und dreizähnigem Liganden (1972) (10)
- Reductive Nitrosylation of V2O5 and MoO3 with Hydroxylamine in the Presence of 1,4,7-Triazacyclononane (2001) (10)
- Synthesis, properties and crystal structures of [MoVL(O)l2]PF6′[MoIVL(O)l2], [MoVL(O)(OMe)2]PF6′[MoVILO2(OMe)]BPh4 and [Mo2L2O3(µ-O)l][BPh4]2(L = 1,4,7-trimethyl-1,4,7-triazacyclononane) (1993) (10)
- Eine neue Struktur‐Magnetismus‐Beziehung für flächenverknüpfte Übergangsmetallkomplexe mit d3‐d3‐Elektronenkonfiguration (1992) (10)
- Die Kristallstrukturen von Hexamminchrom(III)-Hexafluoromanganat(III) und Hexamminchrom(III)-Hexafluoroferrat(III) (1972) (10)
- Ein Strukturmodell für den wasseroxidierenden Mangancluster im Photosystem II (1994) (10)
- Zur Kenntnis der Hexafluoromanganate(III) (1971) (10)
- Synthesis, e.s.r. spectrum and magnetic properties of a heterobinuclear complex containing the {FeIII(µ-O)(µ-MeCO2)2MnIII}2+ core (1989) (10)
- Feineinstellung der Elektronenstruktur in Halogenobis(o‐iminobenzosemichinonato)eisen(III)‐Komplexen (2001) (10)
- The symmetry-broken formalism applied to the electronic structure of an iminosemiquinone copper(II) catalyst: a key to the qualitative understanding of its reactivity. (2001) (10)
- Exchange interactions in a trigonal chromium (III) dimer. Optical spectroscopy of tris-(μ-hydroxo)-bis-[(1,4,7-trimethyl-1, 4,7-triazacyclononane) chromium(III)] triperchlorate (1984) (10)
- Integer‐Spin Multifrequency EPR Spectroscopy of a Ferromagnetically Coupled, Oxo‐Bridged MnIVMnIV Model Complex (2000) (9)
- Intramolecular Electron Transfer Through a Bridging Carboxylate Group Coordinated to Two Cobalt(III)‐Ions: A Pulse Radiolytic Study (1978) (9)
- Synthesis, molecular and electronic structure of complexes [LNaMIVNaL](MRu,Os; H3L = 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane) (1994) (9)
- The Novel Complex [LRuIV(μ‐O)3RuIVL][PF6]2·H2O–a Molecular Section of the Structures of BaRuIVO3 (High‐Pressure Phase) and Ba5/6Sr1/6RuIVO3 (1989) (9)
- Preparation, characterization, and electrochemistry of novel, air-stable nitrosyl complexes of molybdenum and tungsten of the type {M-NO}6,5,4 containing the ligand N,N',N"-trimethyl-1,4,7-triazacyclononane (1985) (9)
- Synthesis, Crystal Structure and Electrochemistry of μ-Acetatodi-μ-hydroxo-bis[(1,4,7-triazacyclononane)ruthenium(III)]-tris-iodide. Characterization of Some Ru(II)—Ru(III) Mixed Valence Species (1984) (9)
- [WL(NO)(O)(CH3)]— An Unusual Nitrosyltungsten Complex (1995) (9)
- Long-distance magnetic interaction between a Mn(III)Mn(IV) (S=1/2) core and an organic radical: a spectroscopic model for the S(2)Y(Z). state of photosystem II. (2002) (9)
- Asymmetric Heterodinuclear [L′Ru(μ‐O)(μ‐CH3CO2)2ML]2⊕ Complexes (M Fe, Mn, V): Electronic Structure and Magnetic Properties (1990) (9)
- Di-μ-oxo-bridged binuclear manganese-complexes: Models for photosystem II (1991) (9)
- THERMAL INTRAMOLECULAR COBALT(III)-IRON(II) AND COBALT(III)-TITANIUM(III) ELECTRON-TRANSFER REACTIONS INVOLVING OUTER-SPHERE AND INNER-SPHERE PRECURSOR COMPLEXES (1979) (9)
- Some Reactions of Complexes of Vanadium(V) with Hydroxylamin: Formation of nitrosyl‐ and Hydroxylamido(1−)‐complexes (1979) (9)
- Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives. (2012) (9)
- Die Reaktivität des [Fe2(μ2‐O)(μ‐acetato)2]‐Strukturelements in Methämerythrin‐Modellverbindungen gegenüber N⊖3 und NCS⊖ (1985) (9)
- Komplexchemie des Gallium(III) mit makrozyklischen Liganden Darstellung und Kristallstruktur von Di‐μ‐hydroxo‐μ‐acetato‐bis[(1,4,7‐triazacyclononan)gallium(III)]triiodid · Monohydrat (1986) (9)
- Die Ligandeneigenschaften der Komplexe LMO3 (M = Mo(VI), W(VI), L = cyclisches Triamin). Die Kristallstrukturen von [(LMoO3)4Co][BPh4]2 · C2H5OH, (LMoO3)4Fe][BPh4]3 · NaBPh4, [LWO3BPh3] und [(LWO3)2BPh2][BPh4] / The Ligating Properties of LMO3-Complexes (M = Mo(VI), W(VI), L = Cyclic Triamine). The (1990) (9)
- 1,4,7‐TRIAZACYCLONONANE‐N,N′,N′′‐TRIACETATE (TCTA), A NEW HEXADENTATE LIGAND FOR DIVALENT AND TRIVALENT METAL IONS. CRYSTAL STRUCTURES OF (CRIII(TCTA)), (FEIII(TCTA)), AND NA(CUII(TCTA))·2NABR·8H2O (1983) (9)
- Titanium(III) reductions of binuclear and tetranuclear .mu.-carboxylato cobalt(III)-ammine complexes. Evidence for remote attack of titanium(III) at an unprotonated carboxylate (1978) (9)
- (μ-Hydroxo)bis(μ-acetato)dimetal complexes: structural and magnetochemical characterization of the Cr(III)Ni(II) and the Cr(III)Cr(III) species (2002) (9)
- Spontaneous self assembly of the {M2(µ-O)(µ-MeCO2)2}2+ core. Synthesis, structure, and properties of the binuclear vanadium(III) complex (1986) (9)
- The molecular and electronic structure of the asymmetric, trinuclear complex [LFeIII(μ-O) (μ-piv)2FeIII(μ-OH)(μ-piv)2FeIII(piv)2]·C6H5CH3 (L=1,4,7-trimethyl-1,4,7-triazacyclononane, piv=pivalate(1-)) (1999) (8)
- STUDY OF INTRADIMER AND INTERDIMER EXCHANGE INTERACTIONS IN DICHLOROBIS(DIETHYLENETRIAMINE)DICOPPER PERCHLORATE ((CU2(DIEN)2CL2)(CLO4)2) BY ELECTRON PARAMAGNETIC RESONANCE AND MAGNETIC SUSCEPTIBILITY MEASUREMENTS (1985) (8)
- Mössbauer study of a novel binuclear Fe(II/III) delocalized-valence compound (1990) (8)
- μ‐Nitridodieisenkomplexe mit asymmetrischem [FeIVNFeIII]4+ ‐ und symmetrischen [FeIVNFeIV]5+‐Strukturelement (1995) (8)
- Optical absorption and luminescence spectroscopy of bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dichromium(3+) perchlorate and bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)chromiumzinc(2+) perchlorate hemihydrate (1988) (8)
- Synthesis and reactivity of [LRe(NO)(CO)(NCO)]+ (L = 1,4,7-triazacyclononane). Kinetics and mechanisms of its formation and transformation of [LRe(NO)(CO)X]n+ (X = NH3, Cl, HCO2-, CF3SO3-) and other species. Crystal structure of [LRe(NO)(CO)(NH3)]Br2 (1988) (8)
- Kinetics and mechanism of the equilibration reaction between (2,2′,2″-nitrilotriethoxy)nitrosylvanadate(1–) and cyanide. Crystal structures of sodium (2,2′,2″-nitrilotriethoxy)nitrosylvanadate(I)–sodium perchlorate tetrahydrate and of barium cyano(2,2′,2″-nitrilotriethoxy)nitrosylvanadate(I) pentahy (1985) (8)
- Unusual solid-state reaction of [{CrL(acac)}2(µ-H3O2)][PF6]3. Isolation and crystal structures of [CrL(acac)F]PF6 and [CrL(acac)(O2PF2)]PF6(L = 1,4,7-trimethyl-1,4,7-triazacyclononane, acac = pentane-2,4-dionate) (1994) (8)
- Self-assembly of a novel 14-membered metallamacrobicycle containing two chromium(III) ions as part of the ring skeleton (1995) (8)
- (L2Mn2(μ-O)2(μ-O2))(ClO4)2: The First Binuclear (μ-Peroxo)dimanganese(IV) Complex (L: 1,4,7-Trimethyl-1,4,7-triazacyclononane). A Model for the S4 → S0 Transformation in the Oxygen-Evolving Complex in Photosynthesis. (1990) (8)
- Synthesis of a Hydroxylamido(2−)-O,N-(nitrosyl)molybdenum Complex (1979) (8)
- Switching the mechanism of spin-exchange coupling in a (.mu.-oxo)bis(.mu.-acetato)chromium(III)vanadium(III) complex by protonation of the oxo bridge (1993) (8)
- SYNTHESIS AND CRYSTAL STRUCTURE OF BIS(μ-HYDROXO)BIS(OXO(1,4,7-TRIAZACYCLONONANE)VANADIUM(IV)) DIBROMIDE, A μ-HYDROXO-BRIDGED CATION WITH ANTIFERROMAGNETICALLY COUPLED VANADIUM(IV) CENTERS (1984) (8)
- Co-ordination chemistry of 1,4-bis(o-aminobenzyl)-1,4-diazacyclohexane (L) with nickel(II), copper(II) and palladium(II) (1996) (8)
- KINETICS OF THE DIPEROXOVANADATE(V)-MONOPEROXOVANADATE(V) CONVERSION IN PERCHLORIC ACID MEDIA (1979) (8)
- C–H Activation of co-ordinated crowns thioethers: deprotonation and ring-opening of [M([9]aneS3)2]3+(M = Co, Rh, Ir). Crystal structure of [Rh(H2CCHS(CH2)2S(CH2)2S)([9]aneS3)](PF6)2([9]aneS3= 1,4,7-trithiacyclononane) (1989) (8)
- Wie „unschuldig”︁ sind Pentan‐2,4‐dion‐bis(S‐alkylisothiosemicarbazonato)‐Liganden in biomimetischen FeII‐ und FeIV‐Komplexen? (1993) (8)
- Konfigurationsisomerisierung an N,N‐disubstituierten Hydroxylamido(1‐)‐O,N‐molybdän(VI)‐Komplexen (1981) (8)
- cis-Tricyanotriamminkobalt(III) (1971) (8)
- Outer-sphere electron-transfer reactions of binuclear complexes of cobalt(III): assessment of an inductive effect on the rates. A linear relationship between the selectivity of redox reactions and the reduction potentials of the reductants (1980) (8)
- Synthesis and reactivity of air-stable (LRe(NO)(CO)(CH/sub 3/))/sup +/ (L = 1,4,7-triazacyclononane). Kinetics and mechanism of its reactions with HX (X = Cl, Br, NO/sub 3/). Formation of ((LRe(NO)(CO))/sub 2/(. mu. -CH/sub 2/OCH/sub 2/))I/sub 2/ containing a bridging 2-oxapropane-1,3-diide (1988) (8)
- Zweikerniger, gemischtvalenter MoVI/V-Komplex; Kristallstruktur von [(C9H21N3)2Mo2VI O5](Br3)2 (1984) (8)
- Die Re‐Re‐Bindung in zweikernigen Di‐μ‐oxorheniumkomplexen mit dem Liganden 1,4,7‐Triazacyclononan (1990) (7)
- μ‐Hydroxo‐ und μ‐Oxo‐bis(μ‐acetato)diruthenium‐Komplexe mit schwachen intramolekularen Ru … Ru‐Wechselwirkungen (1988) (7)
- Elektronentransfer bei Übergangsmetallkomplexen (1979) (7)
- Acid-catalyzed anti .fwdarw. syn isomerization of the {WV2O4}2+ core. Crystal structures of anti-tetraoxobis(1,4,7-triazacyclononane)ditungsten(2+) diiodide and syn-bis[tetraoxobis(1,4,7-triazacyclononane)ditungsten(2+)] dithionate diiodide dihydrate (1988) (7)
- The electron transfer series [Mo(III)(bpy)3](n) (n = 3+, 2+, 1+, 0, 1-), and the dinuclear species [{Mo(III)Cl((Me)bpy)2}2(μ2-O)]Cl2 and [{Mo(IV)(tpy·)2}2(μ2-MoO4)](PF6)2⋅4 MeCN. (2014) (7)
- Zum Bildungsmechanismus von Vanadium Nitrosyl-Komplexen aus Hydroxylamin:Reversible, intramolekulare Umwandlung eines Nitrosylliganden in einen Hydroxylamido(1 —)-Liganden / On the Mechanism of the Formation of Nitrosylvanadium Complexes from Hydroxylamine: Reversible, Intramolecular Conversion of C (1981) (7)
- The Mixed-Valent (μ-Nitrido)dimanganese Complex Anion [(CN)5MnV(μ-N)MnII(CN)5]6− (1999) (7)
- Cover Picture: Description of the Ground‐State Covalencies of the Bis(dithiolato) Transition‐Metal Complexes from X‐ray Absorption Spectroscopy and Time‐Dependent Density‐Functional Calculations (Chem. Eur. J. 10/2007) (2007) (7)
- Chloride ligation in inorganic manganese model compounds relevant to Photosystem II studied using X-ray absorption spectroscopy (2004) (7)
- Kinetics and mechanisms of the reductions of three isomeric .mu.-pyridinecarboxylato-di-.mu.-hydroxo-bis[triamminecobalt(III)] complexes by chromium(II) and vanadium(II) (1976) (7)
- Syntheses and crystal structures of complexes [L′O(H2O)V(µ-O)WO2L]Cl(ClO4) and [L′(acac)MoIII(µ-O)MoVIO2L′][BPh4]2(L,L′= 1,4,7-triazacyclononane and its 1,4,7-trimethyl derivative; acac = pentane-2,4-dionate) (1991) (7)
- Site-selective luminescence and excitation spectroscopy in tris(μ-hydroxo)bis(1,5,9-triazacyclododecane)chromium(III)] tribromide dihydrate (1987) (7)
- Synthesis of novel trimeric µ-oxo-bridged manganese(IV) complexes: [L3Mn3IV(µ2-O)3(µ3-XO4)]Br3(X = P, As, or VV; L = 1,4,7-triazacyclononane) (1988) (6)
- Bioanorganische Modellkomplexe für Metalloproteine des Eisen(III) und Mangan(III): Synthese, Magnetismus und Kristallstrukturen von [L2Fe2(acac)2(μ-O)](ClO4)2, [L'Mn(acac)(OC2H5)]BPh4 und [L'Mn(acac)(OH2)](ClO4)2 (L = 1,4,7-Triazacyclononan, L' = N,N',N"-Trimethyl-1,4,7-triazacyclononan) (1988) (6)
- Synthesis and characterization of the asymmetrically coordinated dinuclear complex [{L(Ph2acac)FeIII}(μ-O){FeIII(Cl4-cat)L}](ClO4) and its one-electron reduced and oxidized forms. Models for dinuclear non-heme active sites (1998) (6)
- Die Molekül- und Kristallstruktur von Di-μ-sulfato-μ-hydroxo- bis[triamminkobalt(III)]sulfat-8-Hydrat (1971) (6)
- Synthese eines vierkernigen Mangan(IV)‐Clusters mit Adamantan‐Skelett: [C6H15N3)4Mn4O6]4+ (2006) (6)
- Thermally assisted resonant quantum tunneling of magnetization in Fe8 clusters (1999) (6)
- Synthesis and structural characterization of the trinuclear mixed-valence complex [{(tiptacn)MoVO(.mu.-O)2}2MoIV(bpy)](PF6)2.cntdot.0.25CH3NO2 (tiptacn = 1,4,7-tris(2-propyl)-1,4,7-triazacyclononane) (1993) (6)
- Hydroxylamine complexes of chromium. The crystal structure of diaquanitrosyl(pyridine-2,6-dicarboxylato)chromium (1984) (6)
- Synthesis and properties of binuclear [LTiCl2(µ-O)TiCl2L]n+(n= 0, 1, 2; L = 1,4,7-trimethyl-1,4,7-triazacyclononane) complexes. The crystal structure of the mixed valence compound [L2Ti2Cl4(µ-O)]Cl·2H2O (1990) (6)
- The molecular and electronic structure of the electron transfer series [Fe2(NO)2(S2C2R2)3](z) (z = 0, -1, -2; R = phenyl, p-tolyl, p-tert-butylphenyl). (2007) (6)
- The redox chemistry of LMO3·3H2O (MMo(VI), W(VI); L=1,4,7-triazacyclononane). The crystal structures of anti-[L2W2Cl2(μ-O)(μ-OH)]ZnCl4·2H2O and [L3Mo3O4] [Zn(Cl,Br)4]2·H2O (1993) (6)
- The Mechanism of Substitution Reactions at [LRe(NO)(CO)(CH3)]⊕ in Acid Solution and the Structure of [{LRe(NO)(CO)}2(μ-CH2OCH2)]I2 (L = 1,4,7-Triazacyclononane)† (1987) (6)
- Ein paramagnetischer Kupfer(III)‐Komplex mit oktaedrischem CuIIIS6‐Koordinationspolyeder (1999) (6)
- Zur Berechnung ebener und drehsymmetrischer Grenzschichten mit kontinuierlicher Absaugung (1954) (6)
- Reduction of cobalt(III) complexes by intramolecular electron transfer from bound free radicals. A pulse radiolytic study (1982) (5)
- Intramolecular electron-transfer reactions in bridged polynuclear ruthenium(II)-cobalt(III) complexes containing a (.mu.-carboxylato)bis(.mu.-hydroxo)bis[(amine)cobalt(III)] and a pentaammineruthenium(II) structural unit (1984) (5)
- Coordination Modes, Oxidation, and Protonation Levels of 2,6-Pyridinediimine and 2,2':6',2'́-Terpyridine Ligands in New Complexes of Cobalt, Zirconium, and Ruthenium. An Experimental and Density Functional Theory Computational Study. (2018) (5)
- [{(C6H15N3)Fe}2(μ‐O) (μ‐CH3CO2)2]2+, ein zweikerniger Eisen(III)‐Komplex vom Strukturtyp des Metazidohämerythrins (2006) (5)
- Baseninduzierte intramolekulare Bildung einer Mo–Mo‐Bindung in [L2MoIII2(μ‐OH)(μ‐CH3CO2)2]3⊕ (L=N,N′N″‐Trimethyl‐1,4,7‐triazacyclononan) (1988) (5)
- Adiabatic intramolecular electron transfer in pyrazine-2,6-dicarboxylato-bridged complexes of cobalt(III)-ruthenium(II) and of cobalt(III)-iron(II): comparison of inner-sphere vs. outer-sphere activated complexes (1984) (5)
- Synthesis and Characterization of (μ‐Hydroxo)bis(μ‐acetato)diiron(II) and (μ‐Oxo)bis(μ‐acetato)diiron(III) 1,4,7‐Trimethyl‐1,4,7‐triazacyclononane Complexes as Models for Binuclear Iron Centers in Biology; Properties of the Mixed Valence Diiron(II,III) Species. (1988) (5)
- Der erste μ(OH)‐verbrückte Modellkomplex für die gemischtvalente FeIIFeIII‐Form des Hämerythrins (1995) (5)
- Reactions of µ-hydroxo-dicobalt(III) complexes. Part XII. Equilibrium and kinetic studies on hydroxo-bridge cleavage reactions of two triply-bridged dicobalt(III) complexes in aqueous perchloric acid solutions (1974) (5)
- Molecular and Electronic Structure of Two Linear Thiophenolate‐Bridged Heterotrinuclear Complexes [LFeRuFeL]2+/3+ (L = 1,4,7‐Tris(4‐tert‐butyl‐2‐mercaptobenzyl)‐1,4,7‐triazacyclononane) (2000) (5)
- Notizen: Raman - Spektren einiger Hexafluorometallate(III) (1970) (5)
- HYDROLYSIS PRODUCTS OF MONOMERIC (C6H15N3)FECL3 AMINE COMPLEX: STRUCTURE OF THE OCTAMERIC IRON(III) CATION OF (((C6H15N3)6FE8(μ3-O)2(μ2-OH)12)BR7(H2O))BR.8H2O (1984) (5)
- Syntheses, Electrochemistry, and Spectroscopic and Magnetic Properties of New Mononuclear and Binuclear Complexes of Vanadium(III), -(IV), and -(V) Containing the Tridentate Macrocycle 1,4,7-Trimethyl-1,4,7-triazacyclononane (L). Crys (1990) (5)
- MECHANISTIC STUDIES INVOLVING HYDROXYLAMINE (1985) (5)
- Synthesis and crystal structures of the dinuclear complexes [{LM(acac)2}2O](ClO4)2 (MZr(IV), Hf(IV); L=1,4,7-triazacyclononane) containing μ-oxo bridged eight-coordinate metal(IV) ions (1992) (4)
- μ‐Oxodieisen(III)‐Komplexe von Porphycenen (1994) (4)
- The reaction of cis-dioxo-bis(N-methylhydroxylamido(1-)-(O,N))molybdenum(VI) with alkyl-isocyanates. Crystal structure of cis-dioxo-bis(N-tert.butyl-N′-methyl-N′-oxo-ureato(1-)-(O,O′))molybdenum(VI) (1984) (4)
- Abhängigkeit des magnetischen Superaustausches vom Cr…︁ Cr‐Abstand in zweikernigen Chrom(III)‐Komplexen (1990) (4)
- η2-Koordination eines Hydroxylamid(2-)Anions: Die Kristallstruktur von [Mo(NO)(terpy)(CN)(HNO)] 2H2O / η2-Coordination of a Hydroxylamido(2-) Anion: The Crystal Structure of [Mo(NO)(terpy)(CN)(HNO)]2H2O (1982) (4)
- Intramolekulare Oxidation isomerer Dihydroxybenzoesäuren durch Kobalt(III): Kinetik und Mechanismus (1978) (4)
- Bioanorganische Modellkomplexe - ein schillerndes Schlagwort? (1985) (4)
- Der neue Komplex [LRuIV (μ‐O)3RuIVL][PF6]2 · H2O–ein molekularer Ausschnitt der Strukturen von BaRuIVO3 (Hochdruckphase) und Ba5/6Sr1/6RuIVO3 (1989) (4)
- Crystal structure of di-µ-hydroxo-trans-diaquo-bis[triamminecobalt(III)] tetranitrate dihydrate, and a possible mechanism for the formation of the cation (1973) (4)
- Base‐Induced Intramolecular Formation of a MoMo Bond in [L2Mo 2IIIμ‐OH(μ‐CH3CO2)2]3⊕(L = N,N′,N″‐Trimethyl‐1,4,7‐triazacyclononane) (1988) (4)
- The structure of the S6-symmetric methanol hexamer assembled in a supramolecular hydrophobic cavity (1998) (4)
- Notizen: Die Kristallstruktur von [LFe]Br3 · 4 H2O — ein low-spin-Hexamineisen(III)-Komplex (L = 1,2-Bis(1,4,7-triaza-1-cyclononyl)ethan) / The Crystal Structure of [LFe]Br3 · 4 H2O — a Low Spin Hexamineiron(III) Complex (L = 1,2-Bis(1,4,7-triaza-1-cyclononyl)ethane) (1989) (4)
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- THE CHROMIUM(2+) AND VANADIUM(2+) REDUCTION OF μ-CARBOXYLATO DICOBALT(III) AMMINE COMPLEXES. PART VIII. THE MECHANISM OF REDUCTION OF THE DI-μ-HYDROXO-μ-OXALATO-BIS(TRIAMMINECOBALT(III)) COMPLEX (1977) (0)
- Asymmetric homo- and heterodinuclear complexes as models for the metalloenzyme catalase: EPR-spectroscopy and electrochemical investigations (1997) (0)
- REACTIVITY OF THE (FE2(μ2-O)(μ-ACETATO)2) STRUCTURAL ELEMENT IN METHEMERYTHRIN MODEL COMPOUNDS WITH AZIDE AND ISOTHIOCYANATE (NCS-) (1985) (0)
- Asymmetric Heterodinuclear Complexes (L′Ru(μ-O)(μ-CH3CO2)2ML)2+ (M: Fe, Mn, V): Electronic Structure and Magnetic Properties. (1990) (0)
- The Mixed‐Valent (μ‐Nitrido)dimanganese Complex Anion [(CN)5MnV(μ‐N)MnII(CN)5] 6‐. (1999) (0)
- Einkernige Ruthenium(III)-Komplexe des Typs LRuX3 (X=Cl-, NCO-, NCS-, N3-; L=1,4,7-Trimethyl-1,4,7-triazacyclononan) (1994) (0)
- Über Reibungsschichten bei Druckanstieg (1955) (0)
- Schwingungsspektrum und Kristallstruktur des fünffach-koordinierten cis-Dioxo-dipicolinato-vanadat(V)-Anions (1978) (0)
- Über den Reibungswiderstand der Platte (1973) (0)
- Strömung mit erheblichen Dichteänderungen (Gasdynamik) (1990) (0)
- Darstellung und Kristallstruktur von Bis-(N-Methymydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)-oxo-molybdän(VI) (1981) (0)
- C. C. Lin, Turbulent Flows and Heat Transfer. XV + 549 S. m. zahlr. Abb. Princeton, New Jersey 1959. Princeton University Press. Preis geb. $ 15.00 (1960) (0)
- Zur Belüftung von Auto‐ und U‐Bahn‐Tunneln (1965) (0)
- CIS‐TRICYANOTRIAMMINKOBALT(III) (1971) (0)
- Aerodynamisches und hydrodynamisches Versuchswesen (1990) (0)
- Überblick über die Strömungslehre (1961) (0)
- SCHWINGUNGSSPEKTRUM UND KRISTALLSTRUKTUR DES FUENFFACH-KOORDINIERTEN CIS-DIOXODIPICOLINATO-VANADAT(V)-ANIONS (1978) (0)
- MOLEKUEL- UND KRISTALLSTRUKTUR VON RAC.-CIS-TETRA-MY-HYDROXO-DICYANO-BIS-(TETRAAMMINKOBALT(III))-KOBALT(III)-DI-MY-HYDROXO-MY-NITRO-(O,N)-BIS-(TRINITROCOBALTAT(III)) (1971) (0)
- Measurements in the Field of Flow on Two Afterbody Models (Messungen im Stroemungsfeld on Zwel Hinterschiffsmodellen) (1959) (0)
- Strömungen im Ozean (1990) (0)
- Metall–Ionen in Lösung: Metal Ions in Solution. Von John Burgess. Verlag Ellis Horwood Limited, Chichester, Sussex, England 1978. 480 S., zahlr. Abb. und Tab., geb. £ 25,– (1979) (0)
- Reaktionstypen in der Anorganischen Chemie. Von I. Fritz. Akademie‐Verlag, Berlin 1982. 429 S., 103 Abb., 100 Tab., DM 58, – (1983) (0)
- Zum Aussengesetz inkompressibler, turbulenter Grenzschichten (1991) (0)
- MEHRKERNIGE KOBALT(III)‐AMMIN‐KOMPLEXE MIT OXALAT ALS ZWEI‐ UND DREIZAEHNIGEM LIGANDEN (1972) (0)
- Synthese, Magnetismus und Kristallstruktur des trinuklearen Cu(II)-Komplexes [(LCu)2Cu(H2O)](ClO4)2.2H2O (L=4,7-Bis(2-hydroxybenzyl)-1-oxa-4,7-diazacyclononan) (1991) (0)
- Lüftungsversuche im Straßenbautunnel Klosterwall - Glockengießerwall (1966) (0)
- Artifizielle Photosynthese und Wasserspaltung – eine Herausforderung an Wissenschaft und Technik (2009) (0)
- Der neue Windkanal des Instituts für Schiffbau (1966) (0)
- Flugkörper, Antriebe und Strömungsmaschinen (1990) (0)
- Über den Reibungswiderstand von Platten (1955) (0)
- Messungen im Strömungsfeld an zwei Hinterschiffsmodellen (1957) (0)
- Zweikernige Komplexe des Molybdän (III): die Kristallstruktur von μ-Bromo-μ-hydroxy-bis-[bromo(1,4,7-triazacyclononan) molybdän (III)] dibromid•Tetrahydrat (1984) (0)
- DARSTELLUNG EINES DREIKERNIGEN RH(III), CO(III)-KOMPLEXES MIT OXALAT ALS DREIZAEHLIGEM LIGAND (1975) (0)
- Strömungen in der Atmosphäre (1990) (0)
- Bemerkungen zum geplanten Umbau des Windkanals des Instituts für Schiffbau (1957) (0)
- Die Kristallstruktur von [LFe]Br3•4H2O ― ein low-spin-Hexamineisen(III)-Komplex (L=1,2-Bis(1,4,7-triaza-1-cyclononyl)ethan) (1989) (0)
- Bemerkungen zu zwei Methoden zur Verringerung des Reibungswiderstandes (1965) (0)
- Neue μ-Hydroxo-Übergangsmetallkomplexe. 3. Mitt. Darstellung zweikerniger Komplexe des Rhodiums(III) mit einer μ-Acetato- und μ-Carbonato-Brücke. Die Struktur des trans-Diaqua-di-μ-hydroxo-bis[(1,4,7-triazacyclononan)rhodium(III)]-Kat (1980) (0)
- Zur Kinematik von Strömungen (1985) (0)
- Eigenschaften der Flüssigkeiten und Gase. Gleichgewichtszustand (1990) (0)
- Bioanorganische Modellkomplexe für Metalloproteine des Eisen(III): Synthese, Kristallstrukturen und Magnetismus der zweikernigen Komplexe [L2Fe2III(μ-O)(μ-SO4)2]•3H2O und [L2Fe2III(μ-O)(μ-SO3)2]•5/3 NaClO4•(H2O)3.67 (L=N,N',N″-Trimethyl-1,4,7-triazacyclononan) (1989) (0)
- Bewegung zäher Flüssigkeiten, Turbulenz, Widerstände, Technische Anwendungen (1990) (0)
- Konvektive Wärme- und Stoffübertragung; Grenzschichten bei hohen Geschwindigkeiten (1990) (0)
- Schiffsmodelle im Windkanal (1955) (0)
- Strömungen mit mehreren Phasen (1990) (0)
- Monomere Komplexe des Vanadium(III) und -(IV) mit den Liganden 1,4,7-triazacyclononan (L) und 1,4,7-trimethyl-1,4,7-triazacyclononan (L'). Die Kristallstrukturen von [L'VF3].4H2O und [L'V(acac)O](ClO4) (1991) (0)
- Kinematik der Flüssigkeiten. Dynamik der reibungsfreien Flüssigkeit (1990) (0)
- MOLEKUEL- UND KRISTALLSTRUKTUR VON DI-MY-SULFATO-MY-HYDROXO-BIS-(TRIAMMINKOBALT(III))-SULFAT-8-HYDRAT (1972) (0)
- ET — doch von dieser Welt (1983) (0)
- Dear JBIC reader (1999) (0)
- Der Widerstand einer Kreisscheibe in einem Gemisch von Polystyrol-Sand und Wasser (1977) (0)
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