Keisuke Suzuki

Keisuke Suzuki's AcademicInfluence.com Rankings

Keisuke Suzuki

Chemistry

#4174

World Rank

#5239

Historical Rank

Organic Chemistry

#672

World Rank

#767

Historical Rank

chemistry Degrees

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Chemistry

Keisuke Suzuki's Degrees

PhD Chemistry University of Tokyo
Masters Chemistry University of Tokyo
Bachelors Chemistry University of Tokyo

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Keisuke Suzuki's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Enantioface-differentiating (asymmetric) addition of alkyllithium and dialkylmagnesium to aldehydes by using (2S,2'S)-2-hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidines as chiral ligands (1979) (199)
New glycosidation reaction 1: Combinational use of Cp2ZrCl2-AgClO4 for activation of glycosyl fluorides and application to highly β-selective gylcosidation of D-mycinose (1988) (182)
Total synthesis of the gilvocarcins (1994) (177)
Catalytic enantioselective crossed aldehyde-ketone benzoin cyclization. (2006) (169)
Total Synthesis of Aryl C-Glycoside Natural Products: Strategies and Tactics. (2017) (141)
New approach to C-aryl glycosides starting from phenol and glycosyl fluoride. Lewis acid-catalyzed rearrangement of O-glycoside to C-glycoside (1988) (132)
Catalytic intramolecular crossed aldehyde--ketone benzoin reactions: a novel synthesis of functionalized preanthraquinones. (2003) (125)
An improved procedure for metallocene-promoted glycosidation. Enhanced reactivity by employing 1:2-ratio of Cp2HfCl2-AgClO4 (1989) (115)
Total Synthesis and Absolute Stereochemical Assignment of Gilvocarcin M. (1992) (109)
New glycosidation reaction 2. preparation of 1-fluoro-d-desosamine derivative and its efficient glycosidation by the use of Cp2HfCl2-AgClO4 as the activator (1988) (106)
4-O-Benzyl-23-O-isopropylidene-L-threose: A useful building block for stereoselective synthesis of monosaccharides (1990) (104)
Modified chiral triazolium salts for enantioselective benzoin cyclization of enolizable keto-aldehydes: synthesis of (+)-sappanone B. (2007) (96)
New efficient protocol for aryne generation. Selective synthesis of differentially protected 1,4,5-naphthalenetriols (1991) (89)
Epoxy silyl ether rearrangements: a new, stereoselective approach to the synthesis of .beta.-hydroxy carbonyl compounds (1986) (84)
Cp2ZrCl2AgBF4 in Benzene: A new reagent system for rapid and highly selective α-mannoside synthesis from tetra-O-benzyl-d-mannosyl fluoride (1989) (78)
On the stereochemistry of aryl C-glycosides: Unusual behavior of bis-TBDPS protected aryl C-olivosides (1996) (76)
Convergent total synthesis of vineomycinone B2 methyl ester and its C(12)-epimer (1991) (75)
Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds. (2018) (72)
The Enantioselective Michael Addition of Thiols to Cycloalkenones by Using (2S, 4S)-2-Anilinomethyl-1-ethyl-4-hydroxypyrrolidine as Chiral Catalyst (1982) (71)
Oligomeric catechins: an enabling synthetic strategy by orthogonal activation and C(8) protection. (2004) (65)
Strain-induced regioselectivities in reactions of benzyne possessing a fused four-membered ring. (2003) (62)
Concise total synthesis and structure assignment of TAN-1085. (2004) (59)
Synthetic study toward vineomycins. Synthesis of c-aryl glycoside sector via Cp2HfCl2AgClO4-promoted tactics (1989) (59)
Stereocontrolled asymmetric total synthesis of protomycinolide IV (1986) (59)
Two-directional annelation: dual benzyne cycloadditions starting from bis(sulfonyloxy)diiodobenzene. (2006) (58)
Total Synthesis of Pradimicinone, the Common Aglycon of the Pradimicin-Benanomicin Antibiotics. (1999) (57)
Stereochemical relay via axially chiral styrenes: asymmetric synthesis of the antibiotic TAN-1085. (2009) (57)
Thiazolium Ylide-Catalyzed Intramolecular AldehydeKetone Benzoin-Forming Reactions: Substrate Scope (2004) (56)
Total synthesis and absolute configuration of macrocidin A, a cyclophane tetramic acid natural product. (2010) (56)
From Axial Chirality to Central Chiralities: Pinacol Cyclization of 2,2'-Biaryldicarbaldehyde to trans-9,10-Dihydrophenanthrene-9,10-diol. (1999) (54)
Catalytic generation of arynes and trapping by nucleophilic addition and iodination. (2012) (54)
A "hot, energized" benzyne. (2013) (54)
[2+2] Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to Benzocyclobutenones (1995) (53)
Cp2ZrCl2-AgClO4: Efficient promoter for the Friedel-Crafts approach to C-aryl glycosides (1989) (52)
Lactols in stereoselection 2. Stereoselective synthesis of disubstituted cyclic ethers. (1987) (50)
Regio- and stereocontrolled total synthesis of benanomicin B. (2005) (49)
Block copolymer of 2-methyl-2-oxazoline with silica gel an organic-inorganic hybrid polymer (1991) (49)
Total synthesis of ravidomycin: revision of absolute and relative stereochemistry (2000) (48)
Facile Access to Versatile Polyaromatic Building Blocks: Selectively Protected Benzocyclobutenedione Derivatives via Regioselective [2+2] Cycloaddition of α‐Alkoxybenzyne and Ketene Silyl Acetal (2002) (47)
On the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone Remarkable Effect of Trialkylsilyl Substituent (1993) (47)
Total Synthesis of the Furaquinocins (1998) (47)
Dodecamethoxy- and hexaoxotricyclobutabenzene: synthesis and characterization. (2006) (47)
On the use of epoxy alcohol-aldol rearrangement for stereoselective construction of quarternary carbon centers (1987) (46)
First total synthesis of mycinamicin IV and VII.: Successful application of new glycosidation reaction (1988) (46)
Grignard-type addition of alkenyl- and alkylzirconocene chloride to aldehyde: Remarkable catalytic acceleration effect of AgClO4 (1992) (45)
ENANTIOSELECTIVE ADDITION OF ACETYLENE TO ALDEHYDE. PREPARATION OF OPTICALLY ACTIVE ALKYNYL ALCOHOLS (1979) (45)
Amine-promoted cyclocondensation of highly substituted aromatic nitrile oxides with diketones (2003) (45)
STEREOSPECIFICITY IN 2+2 CYCLOADDITION OF BENZYNE AND KETENE SILYL ACETAL (1995) (44)
Synthetic study of aquayamycin. Part 3: First total synthesis (2000) (43)
Hydrogen-bond control in axially chiral styrenes: selective synthesis of enantiomerically pure C2-symmetric paracyclophanes. (2009) (43)
Poly-oxygenated tricyclobutabenzenes via repeated [2 + 2] cycloaddition of benzyne and ketene silyl acetal. (2006) (42)
Total synthesis and absolute stereochemistry of seragakinone A. (2011) (42)
First stereoselective total synthesis of FD-594 aglycon. (2009) (41)
Concise three-component synthesis of defucogilvocarcin M. (2004) (41)
Total synthesis and structure assignment of the anthrone C-glycoside cassialoin. (2008) (40)
Total synthesis of antibiotic C104: Benzyne-Furan cycloaddition approach to the angucyclines (1995) (39)
Novel Migrating Group in 1,2-Anionotropic Reactions: Cobalt Complexation Facilitates 1,2-Shift of Alkynyl Groups (1996) (39)
Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization (2002) (37)
Total synthesis of aryl C-glycoside antibiotics (1994) (37)
Structure-activity relationships of lysophosphatidylserine analogs as agonists of G-protein-coupled receptors GPR34, P2Y10, and GPR174. (2015) (36)
General synthesis route to benanomicin-pradimicin antibiotics. (2007) (36)
AgAsF6 as safe alternative to AgClO4 for generating cationic zirconocene species: Utilities in lewis acid-promoted selective CC bond forming reactions (1995) (35)
Integrated synthetic strategy for higher catechin oligomers. (2011) (35)
Facile construction and divergent transformation of polycyclic isoxazoles: direct access to polyketide architectures. (2003) (35)
Benzyne-Furan Cycloaddition Approach to the Angucyclines: First Total Synthesis of Antibiotic C104 (1995) (35)
Stereoselective Synthesis of Cyclopropanes via Homoallylic Participation (1995) (34)
Catalytic version of epoxy silyl ether rearrangements (1987) (33)
Solvent-controlled leaving-group selectivity in aromatic nucleophilic substitution. (2008) (33)
Asymmetric synthesis of optically pure α-methyl-β,γ-unsaturated ketones via triethylaluminum-mediated stereospecific pinacol rearrangement of alkenyl groups (1984) (33)
Silicon-directed stereoselective synthesis of 2-vinyl-1,3-diols (1988) (32)
Tandem ring expansion of alkenyl benzocyclobutenol derivatives into substituted naphthols. (2006) (32)
Novel Lewis acid catalysis in organic synthesis (1994) (32)
Recent Progress in O-Glycoside Synthesis-Methodological Aspects (1992) (31)
ASYMMETRIC ADDITION OF ACETYLIDE TO ALIPHATIC ALDEHYDES—PREPARATION OF OPTICALLY ACTIVE 5-OCTYL-2(5H)-FURANONE— (1980) (30)
Synthesis of the pluramycins 2: total synthesis and structure assignment of saptomycin B. (2014) (30)
THE STEREOSELECTIVE SYNTHESIS OF D-RIBULOSE (1981) (30)
Two- and four-carbon homologation of aldehyde by AgClO4-catalyzed addition of alkoxyalkenylzirconocene chloride (1993) (30)
Convergent synthesis of the ABCDEF-ring system of yessotoxin and adriatoxin. (2002) (30)
Stereocontrolled Convergent Total Synthesis of (.+-.)-Furaquinocin D (1995) (29)
Asymmetric pinacol-type rearrangement of α-hydroxy methanesulfonates promoted by triethylaluminum — preparation of optically pure α-aryl and α-vinyl ketones — (1983) (29)
Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C. (2017) (29)
Isoxazole-directed pinacol rearrangement: stereocontrolled approach to angular stereogenic centers. (2007) (28)
Unexpected outcome of NbCl5-promoted Sakurai reaction: Mechanistic implications relevant to C4H7+ species (1995) (28)
Lactols in stereoselection 1. Highly selective 1,4- and 1,5-asymmetric induction (1987) (28)
Stereo-divergent asymmetric total synthesis of avenaciolide and isoavenaciolide. Complete reversal of stereoselectivity in reduction of 2-vinyl aldols with / without trimethylsilyl directing group (1986) (27)
Hexaradialenes by successive ring openings of tris(alkoxy-tricyclobutabenzenes): synthesis and characterization. (2010) (27)
Enantio- and diastereo-controlled synthesis of (+) - and (−) - eldanolide based on asymmetric pinacol-type rearrangement (1985) (27)
A new synthetic strategy for catechin-class polyphenols: concise synthesis of (-)-epicatechin and its 3-O-gallate. (2012) (27)
C-Glycosyl juglone in angucycline synthesis: Total synthesis of galtamycinone, common aglycon of C-glycosyl naphthacenequinone-type angucyclines (1997) (26)
Synthesis of the pluramycins 1: two designed anthrones as enabling platforms for flexible bis-C-glycosylation. (2014) (26)
Ring selectivity: successive ring expansion of two benzocyclobutenes for divergent access to angular and linear benzanthraquinones. (2008) (26)
ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF DIALKYLMAGNESIUM TO ALDEHYDES BY USING THE LITHIUM SALT OF (2S, 2′S)-2-HYDROXYMETHYL-1-[(1-METHYLPYRPOLIDIN-2-YL)METHYL]PYRROLIDINE AS A CHIRAL LIGAND (1978) (25)
Formation of alpha-hydroxy-beta-diketones through hydroxylation of isoxazolium salts: stereoselective approach to angular cis-diols in polycyclic systems. (2008) (25)
MAO-Catalyzed Allylzirconation of 1-Alkynes (1997) (25)
Convenient Procedure for One-pot Conversion of Azides to N-Monomethylamines (2001) (24)
A FORMAL TOTAL SYNTHESIS OF POLYOXIN J USING 4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE AS A COMMON CHIRAL BUILDING BLOCK (1984) (24)
Synthetic study of aquayamycin. Part 1: Synthesis of 3-(phenylsulfonyl)phthalides possessing a β-C-olivoside (2000) (24)
Enantio- and diastereomerically pure threo-homoallylic alcohols via highly stereoselective reduction of α-methyl-β,γ-unsaturated ketones (1984) (24)
Photoredox Reactions of Quinones. (2018) (23)
General synthesis of epi-series catechins and their 3-gallates: reverse polarity strategy. (2010) (23)
Asymmetric synthesis of chiral synthons bearing alkynyl group via organoaluminum-promoted pinacol-type rearrangement (1986) (23)
Total synthesis of the antibiotic BE-43472B. (2013) (23)
Hydrozirconation of Allenylstannane for Generating Bimetallic Three-Carbon Species: Synthesis of (E)-1,3-Dienes from Carbonyl Compounds (1993) (23)
Further study on SmI2-induced reductive intramolecular cyclization: synthesis of polycyclic ethers having an angular methyl group (2002) (22)
BASE-PROMOTED RING EXPANSION OF 2-ALKOXY-2-VINYLBENZOCYCLOBUTENOL INTO SUBSTITUTED NAPHTHALENE DERIVATIVES (1998) (22)
threo‐3‐Alkyl‐ and ‐Arylglutamic Acid Derivatives by Michael Additions of Boc‐BMI Li‐Enolates to 2,6‐Di‐t‐butyl‐4‐methoxyphenyl Alkenoates on the Diastereoselectivity of the Coupling of Trigonal Centers Involving Heterocyclic Li‐Enolates (1992) (22)
Lessons from total synthesis of hybrid natural products. (2010) (22)
First total synthesis of BE-12406 A (1994) (22)
Synthesis and determination of the absolute configuration of cavicularin by a symmetrization/asymmetrization approach. (2013) (22)
Annulation approach to doubly linked (A-type) oligocatechins: syntheses of (+)-procyanidin A₂ and (+)-cinnamtannin B₁. (2014) (22)
Synthesis of hindered 1-arylnaphthalene derivatives via ring expansion of benzocyclobutenones. (2002) (21)
Stereochemical anomaly in the thermal conversion of 7,8-dioxy-7-alkenylbenzocyclobutenes to dihydronaphthalenes. (2002) (21)
Reductive pinacol-type rearrangement of chiral α-mesyloxy ketones promoted by organoaluminum compounds (1985) (21)
Total Synthesis of (+)-Vicenin-2. (2016) (21)
Rapid O-glycosidation of phenols with glycosyl fluoride by using the combinational activator, Cp2HfCl2-AgClO4 (1989) (21)
Concise Synthesis of (±)-γ-Indomycinone (2006) (20)
New and highly (E)-selective synthesis of terminal 1,3-diene via three-carbon elongation of aldehyde (1992) (20)
Model Reactions for the Enantioselective Synthesis of γ-Rubromycin: Stereospecific Intramolecular Photoredox Cyclization of an ortho-Quinone Ether to a Spiroacetal. (2018) (19)
Reaction of 1-iodoalkynes with allylzirconiums: Generation of alkylidene carbenoid via allylzirconation (1999) (19)
Procyanidins Negatively Affect the Activity of the Phosphatases of Regenerating Liver (2015) (19)
Intramolecular Photoredox Reaction of Naphthoquinone Derivatives (2017) (19)
Stereoselective convergent synthesis of a trans-fused polycyclic ether ring system including a 4-hydroxy-5-methyl-tetrahydropyran ring. (2002) (19)
Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement (1984) (19)
General and Convenient Approach to Flavan-3-ols: Stereoselective Synthesis of (−)-Gallocatechin (2006) (19)
Unusual Regioselectivity in the Reductive Coupling of Alkynes and Allenes by Hydrozirconation and Zinca‐Claisen Rearrangement (1997) (18)
HIGHLY ENANTIOSELECTIVE MICHAEL ADDITION OF THIOLS TO 2-CYCLOHEXENONE BY USING (2S,4S)-2-(ANILINOMETHYL)-1-ETHYL-4-HYDROXYPYRRQLIPINE AS A CHIRAL CATALYST (1981) (18)
Total synthesis and structure revision of deacetylravidomycin M (2011) (18)
First Total Syntheses of Tetracenomycins C and X. (2017) (18)
Isochroman-3-ones via site-selective ring opening of benzocyclobutenones promoted by lithium tetramethylpiperidide and reaction with aromatic aldehydes (1997) (18)
TOTAL SYNTHESES OF BE-12406 A AND ITS C(8)-VINYL ANALOG (1996) (17)
Toward Naphthocyclinones: Doubly Connected Octaketide Dimers with a Bicyclo[3.2.1]octadienone Core by Thiolate-Mediated Cyclization. (2015) (17)
Synthetic study of aquayamycin. Part 2: Synthesis of the AB ring fragment (2000) (17)
First synthesis of astilbin, biologically active glycosyl flavonoid isolated from Chinese folk medicine (2000) (17)
Lactols in stereoselection 3 (1989) (17)
Convenient Synthesis of Phthalides via Regioselective Baeyer-Villiger Oxidation of Benzocyclobutenones (1995) (17)
Siloxy(trialkoxy)ethene undergoes regioselective [2+2] cycloaddition to ynones and ynoates en route to functionalized cyclobutenediones. (2010) (17)
4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE —A NEW AND USEFUL BUILDING BLOCK FOR THE SYNTHESES OF L-SUGARS— (1982) (16)
Synthesis and Stereochemical Assignment of Angucycline Antibiotic, PD-116740 (2008) (16)
Assessment of macrocyclic triamine ligands as synthons for organometallic 99mTc radiopharmaceuticals. (2008) (16)
Total Synthesis of Actinorhodin. (2019) (16)
Stereocontrolled first total synthesis of mycinolide IV (1987) (16)
Total Synthesis of Galtamycinone, the Common Aglycon of the C-Glycosyl Naphthacenequinone Antibiotics (1996) (15)
Convenient Procedure for Selective Generation of Allylzirconocene Chlorides via Hydrozirconation of Allenes (1994) (15)
Concise Synthesis of Riccardin C, Macrocyclic Bisbibenzyl Natural Product (2011) (15)
Stereoselective synthesis of C(1)–C(9) and C(11)–C(17)fragments of protomycinolide iv based on asymmetric pinacol-typerearrangement (1985) (15)
A domino pericyclic route to polysubstituted salicylic acid derivatives: four sequential processes from enynones and ketene silyl acetals. (2011) (14)
A NOVEL METHOD FOR THE SYNTHESIS OF 2-DEOXYDISACCHARIDE BY STEREOSELECTIVE CYCLIZATION OF THE ACYCLIC PRECURSOR (1982) (14)
Structural incongruities of coleophomone natural products: insights by total synthesis of a semi-synthetic derivative (2003) (14)
Total Synthesis of Carthamin, a Traditional Natural Red Pigment. (2019) (14)
Isoxazole --> benzisoxazole rearrangement promoted cascade reactions affording stereodefined polycycles. (2003) (14)
Unified approach to catechin hetero-oligomers: first total synthesis of trimer EZ-EG-CA isolated from Ziziphus jujuba. (2012) (14)
Synthesis of isoxazoles en route to semi-aromatized polyketides: dehydrogenation of benzonitrile oxide-para-quinone acetal cycloadducts. (2012) (14)
First regiocontrolled synthesis of procyanidin B6, a catechin dimer with rare connectivity: a halo-capping strategy for formation of 4,6-interflavan bonds. (2013) (14)
“Dibutyltin diperchlorate” for activation of glycosyl fluoride (1993) (14)
Lewis Acid Promoted Reaction of Secondary Phosphines with Carbonyl Compounds: Remarkable Effect of Niobium(V) Chloride in Promoting an Intramolecular Oxidation-Reduction Process (1992) (14)
Cationic zirconocene- or hafnocene-based Lewis acids in organic synthesis: glycoside–flavonoid analogy (2004) (14)
Preparation of enaminones by two-carbon homologation of amides with lithium (triphenylsilyl)acetylide (1987) (13)
Regioselectivity of MAO-catalyzed allylmetallation of conjugated enynes with allylzirconiums (1998) (13)
Pinacol rearrangement for constructing asymmetric centers adjacent to heterocycles (2002) (13)
Stereoselective substitution of flavan skeletons: synthesis of dryopteric acid (2002) (13)
Impact of Green Tea Catechin ECG and Its Synthesized Fluorinated Analogue on Prostate Cancer Cells and Stimulated Immunocompetent Cells (2018) (13)
Synthesis of 2-vinyl-1,3-diols via highly stereoselective reduction of 2-vinyl aldols using trimethylsilyl stereo-directing group (1986) (13)
Stereocontrolled Total Syntheses of (-)-Rotenone and (-)-Dalpanol by 1,2-Rearrangement and SN Ar Oxycyclizations. (2017) (13)
Synthetic Study on Carthamin: Problem and Solution for Oxidative Dearomatization Approach to Quinol C-Glycoside (2016) (12)
Synthetic Study on Carthamin. 2. Stereoselective Approach to C-Glycosyl Quinochalcone via Desymmetrization. (2017) (12)
Semi-pinacol strategy for constructing b-ring of pradimicin-benanomicin antibiotics (2002) (11)
Sc(OTf)3-catalyzed C-glycosylation of β-diketones. A facile access to useful precursors of heteroaromatic C-glycosides (2005) (11)
Sc(OTf)3 as Efficient Catalyst for Aryl C-Glycoside Synthesis (2004) (11)
First Total Synthesis of Dermocanarin 2 (2016) (11)
New Methods in Glycoside Synthesis by Using Early Transition Metal-Derived Reagent (1993) (11)
Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide. (2017) (11)
Synthesis and Chiroptical Properties of π-Conjugated Polymer Consisting of Dihydropentahelicene Units with Axial Chirality (2010) (11)
Ortho-metallation of anthracene derivative: problem and solution (1991) (11)
Stereochemical Dichotomy in Two Competing Cascade Processes: Total Syntheses of Both Enantiomers of Spiroxin A. (2019) (11)
Enantioselective total synthesis of (-)-euxanmodin B: an axially chiral natural product with an anthraquinone-xanthone composite structure. (2011) (11)
Construction of Bridged Polycyclic Systems by Polyene Cyclization. (2015) (11)
C-Glycosylation-Cycloaddition Approach to C-Glycosyl Juglones. Versatile Intermediates toward Aryl C-Glycoside Antibiotics (1995) (10)
Stereocontolled Synthesis of (−)-Afzelechin: General Route to Catechin-class Polyphenols by Solving an SN2 vs. SN1 Problem (2009) (10)
Preparation of L-vancosamine-related glycosyl donors (2013) (10)
Synthetic study of ravidomycin, a hybrid natural product (2000) (10)
Conformational effects in organoaluminum-promoted pinacol-type rearrangement (1985) (10)
Regioselective alkylzirconation of internal alkynes (2001) (10)
Cobalt-Complexation Makes 2-(1-Alkynyl)propenes Good Ene Donors in Carbonyl-Ene Reaction (1995) (9)
Synthesis and Structure Revision of Goupiolone A: A Benzotropolone Natural Product (2012) (9)
Recent advances in the chemistry of zirconocenes (2004) (9)
Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative (1985) (9)
Pleospdione, A Tricyclic Natural Product with Dense Oxygenation at the A-Ring: Total Synthesis and Incongruity of the Originally Assigned Structure and its C3-Epimer (2016) (9)
Regioselective Approach to Multisubstituted Benzenes (2011) (9)
The isolation and structure of siccanochromenes (1968) (9)
O → C-Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl C-Glycosides (1991) (9)
Peri-selectivity in Thermolysis of Acyloxybenzocyclobutenes Possessing α,β-Unsaturated Carbonyl Group: Synthesis of 2-Benzoxocin Derivatives (2006) (9)
Isoxazole-assisted direct substitution of the hydroxy group in alpha-ketols: introduction of angular substituents in a polycyclic system. (2008) (9)
Divergent behavior of cobalt- complexed enynehaving a leaving group (1999) (9)
Enantiopure Acetals of α-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile (1997) (8)
Efficient method for introducing vineomycin-fridamycin-type side chain. Total synthesis of fridamycin E (1991) (8)
Intramolecular Benzyne-Phenolate [4+2] Cycloadditions. (2020) (8)
Highly Selective Acyclic Stereocontrol Based on 1, 2-Rearrangement (1988) (8)
Synthesis of amphiphilic silane coupling agents based on poly(2-ethyl-2-oxazoline) and their reactions with tetraethoxysilane (1993) (8)
Impressive changeover of reaction course in ring expansion of styrylbenzocyclobutenol under alkoxide-forming conditions (2006) (8)
ALKYLZIRCONATION OF ALKYNES CATALYZED BY TRIPHENYLCARBENIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE (1999) (8)
Stereoselective construction of three-and four-contiguous asymmetric centers : novel possibility by alkylative rearrangement of epoxy silyl ethers (1990) (8)
The flavan-isoflavan rearrangement: bioinspired synthetic access to isoflavonoids via 1,2-shift-alkylation sequence. (2015) (8)
(E)-stereoselective synthesis of vinylglycines from (R)-serine via organocopper–BF3 and related reagents (1994) (8)
Hydrozirconation of Allenyl Sulfide for Generating γ-Thio-substituted Allylzirconium Species and Its Reaction with Carbonyl Compounds (1996) (8)
Ambipolar transistor properties of 2,2′-binaphthosemiquinones (2015) (8)
Synthesis of Benzocyclooctene Derivatives via Thermal Ring Expansion of Dienylbenzocyclobutenes (2002) (8)
Intramolecular photoredox reactions of 1,2-naphthoquinone derivatives. (2018) (7)
Convergence in [2+2+2] synthesis of β-phenylnaphthalene motif in polyaromatic natural products (2006) (7)
ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(p-t-BUTYLPHENYLTHIO) CYCLOHEXAN-1-ONE (1982) (7)
Dioxanone-fused dienes enable highly endo-selective intramolecular Diels-Alder reactions. (2015) (7)
Oxidative Ring Opening of Benzocyclobutenone Oximes: Novel Access to Stable Nitrile Oxides (2017) (7)
2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05518a (2019) (7)
Efficient Bis-C-Aminoglycosylation toward the Synthesis of the Pluramycins (2010) (6)
Total Synthesis of Bis-anthraquinone Antibiotic BE-43472B (2018) (6)
Stereoselective reduction of α-cyclopropyl ketones and α-cyclopropyl aldols. Stereo-directing effect by α-trimethylsilyl group (1989) (6)
Stereospecific 1,2-rearrangement of cyclopropyl group. Synthesis of chiral α-cyclopropyl ketones and α-cyclopropyl aldols (1989) (6)
Total Synthesis of the Proposed Structure of Ardimerin, and Proposal for its Structural Revision (2016) (6)
Synthesis of β-Hydroxynaphthoate Derivatives from Ketodioxinones via Benzyne Acyl-Alkylation and Aldol Condensation Cascade (2016) (6)
Mukaiyama Aldol Reaction of Ester Acceptors: Organoaluminums Catalyze Nucleophilic Addition of Ketene Silyl Acetals (2007) (6)
Isoxazole Platform for Polyketide Assembly: Cycloaddition of Stable Benzonitrile Oxides to Stable ortho-Quinone Monoacetals and Dehydrogenation (2014) (6)
Synthesis of 1,3-bis(diphenylphosphinoyl)alkanes via double addition of diphenylphosphine to α,β-unsaturated carbonyl compounds : sequential 1,4- and 1,2-addition promoted by NbCl5-BF3.OEt2 (1992) (6)
Short-Step Total Synthesis of a Cyclopropane-Containing Eicosanoid (1995) (6)
Stereocontrolled Synthesis of Planar Chiral Carba-Paracyclophanes via Modular Assembly (2016) (6)
Lipase-Catalyzed Asymmetrization of Diacetate of Meso-2-(2-Propynyl)cyclohexane-1,2,3-triol toward the Total Synthesis of Aquayamycin (2001) (6)
Catalytic Intramolecular Crossed Aldehyde—Ketone Benzoin Reactions: A Novel Synthesis of Functionalized Preanthraquinones. (2003) (5)
2,5-Dihydroxyterephthalates, 2,5-Dichloro-1,4-benzoquinone-3,6-dicarboxylates,and Polymorphic 2,5-Dichloro-3,6-dihydroxyterephthalates (2008) (5)
Hybrid Natural Products (2014) (5)
C(2)-stereocontrol of δ-lactones via acid-catalyzed cyclization of ketene dithioacetal having an internal hydroxyl group (1986) (5)
Silicon-Directed Regioselective [2+2] Cycloaddition of α-Alkoxybenzyne and Ketene Silyl Acetals (2000) (5)
Hydroxylamine-Mediated Anthrapyranone Formation, Solving 5-exo/6-endo Issue toward Synthesis of Pluramycin-Class Antibiotics. (2019) (5)
Glycosylation study on pradimicin–benanomicin antibiotics (2000) (5)
Transmission of axial chirality to spiro center chirality, enabling enantiospecific access to erythrinan alkaloids (2004) (5)
Synthetic Study on Naphthospironone A: Construction of Benzobicyclo[3.2.1]octene Skeleton with Oxaspirocycle. (2015) (5)
anti-Selective Vinylogous Aldol Reaction by Silylated Alkyldioxinone Dienolate (2010) (5)
Total Synthesis of Selligueain A, a Sweet Flavan Trimer. (2018) (5)
[3+1] Synthetic Route Toward Synthesis of Cyclobutane/butene Derivatives Based on the Large α-Cation-Stabilizing Effect of Cyclopropane1 (1993) (5)
Stereogenic tert-alcohols via group-selective hydroalumination: further scope (2002) (5)
Annulation Approach to Doubly Linked (A-Type) Oligocatechins: Syntheses of (+)-Procyanidin A2 and (+)-Cinnamtannin B1. (2015) (5)
Total Syntheses of Pusilatins A-C, Liverwort-Derived Macrocyclic Bisbibenzyl Dimers. (2018) (5)
Synthesis of Optically Active Polymers Using P-Chiral Bisphosphines as Anionic Initiators (2009) (5)
Linearly Fused Dicyclobutabenzenes via Dual, Regioselective Cycloadditions of 1,4-Benzdiyne Equivalent and Ketene Silyl Acetals (2008) (5)
Cationic Zirconocene Species in Organic Synthesis (2003) (5)
Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions. (2013) (5)
Stereochemical Dichotomy in Two Competing Cascade Processes: Total Syntheses of Both Enantiomers of Spiroxin A (2019) (5)
Synthetic Study on Acremoxanthone A: Construction of Bicyclo [3.2.2]nonane CD Skeleton and Fusion of AB Rings (2016) (4)
Expeditious Modular Assembly of Multisubstituted Cyclohexanes via Dioxanone–Dienes (2011) (4)
Synthesis of functionalized biaryl compounds via ring expansion of alkenylcyclobutenones (2003) (4)
Bis-C-Glycosylation of Resorcinol Derivatives by an O→C-Glycoside Rearrangement (2006) (4)
Ring Expansion of Cyclopropylbenzocyclobutenes En Route to Benzocycloheptenes (2011) (4)
Regioselective remote functionalization of biaryl framework via tethered ortho-quinol intermediate. (2011) (4)
Lessons from Total Synthesis of Hybrid Natural Products (2011) (4)
Total Synthesis of Antibiotic C104: Benzyne-Furan Cycloaddition Approach to the Angucyclines. (1995) (4)
Synthesis of Tetraoxygenated Terephthalates via a Dichloroquinone Route: Characterization of Cross-Conjugated Liebermann Betaine Intermediates (2017) (4)
Synthesis of Enantiopure C2-Symmetric Anthracenophane and Dimerization En Route to Multiple-Bridged Cyclophanes. (2020) (4)
Facile one-pot synthesis of resorcinol bis-C-glycosides possessing two identical sugar moieties (2006) (4)
Enantiodivergent Synthesisof Tetra-ortho-Substituted Biphenylsby Enzymatic Desymmetrization (2009) (4)
A seco-catechin cyclization approach to 4→6-linked catechin dimers. (2014) (4)
Synthetic Approaches on the Pluramycin-Class Antibiotics (2019) (4)
Single-Step Synthesis of Cyclooctadienone Derivatives by Reaction of Alkenylcyclobutenones with Alkenyllithiums: Enhanced Reactivity of 8π Cyclization by Acetylating the Intermediary Lithium Tetraenolate (2002) (4)
Synthesis of Functionalized Cyclobutene Derivatives via Selective SN2’ Reaction of Dichlorocyclobutenes (2002) (4)
3.11 Pinacol Coupling Reactions (2014) (4)
Preparation of 2-Substituted 3-Methoxycarbonyl-4-methoxyfurans that Allow Access to Highly Functionalized Naphthalenes via Regioselective Cycloaddition with Alkoxybenzyne (2017) (4)
Total Synthesis of Ravidomycin: Revision of Absolute and Relative Stereochemistry. (2000) (4)
Synthesis of (′)-lotthanongine, a novel natural product with a flavan-indole hybrid structure (2005) (3)
Selective Conversion of Benzylic Phosphates into Diarylmethanes Through Al(OTf)3 -Catalyzed Friedel-Crafts-Type Benzylation (2020) (3)
Synthesis of Oxygenated ortho-Methylbenzaldehydes via Aryne [2+2] Cycloaddition and Benzocyclobutenol Ring Opening. (2018) (3)
Novel One-Pot Synthesis of Xanthones via Sequential Fluoride Ion-Promoted Fries-Type Rearrangement and Nucleophilic Aromatic Substitution (2013) (3)
Two isolable conformers of dihydropentahelicenediol derivatives : Stereochemical property and its utility for asymmetric reactions (2007) (3)
Total Syntheses of Perenniporides. (2015) (3)
Stereoselective Access to Functionalized Dihydrophenanthrenes via Reductive Cyclization of Biaryl Ene-Aldehydes (2007) (3)
New Glycosidation Reaction. Part 1. Combinational Use of Cp2ZrCl2-AgClO4 for Activation of Glycosyl Fluorides and Application to Highly β-Selective Glycosidation of D-Mycinose. (1988) (3)
First Total Synthesis of (+)-11-Hydroxyerythratidine (2009) (3)
Sc(OTf)3 as Efficient Catalyst for Aryl C-Glycoside Synthesis. (2004) (3)
Single Step Synthesis of Cyclooctadienone Derivatives by Reaction of Cyclobutenones with Dienyllithium. (2002) (3)
Hf‐Centered Lewis Acids in Organic Chemistry (2008) (3)
General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual SNAr Cyclizations of Aryl Fluorides (2019) (3)
An Alternative Synthetic Route to the C(11)-C(17)-Fragment of Mycinolide IV (1992) (3)
Cu(II)-mediated stereoselective michael addition of a methyl group to an α,β-unsaturated ester as the C2-side chain in 3-(t-butyldimethylsilyloxy)tetrahydropyrans (2005) (3)
Cp2MCl2-AgX (M=Zr, Hf) : A Reagent for Glycosidation (1990) (3)
Zr- and Hf-Centered Lewis Acids in Organic Synthesis (1999) (3)
Studies on Organic Synthesis Inspired by Carbohydrates (2007) (3)
Molecular Sieve (MS 4A) Promoted Cyclocondensation of Hindered, Aromatic Nitrile Oxides and Cyclic Diketones under Mild Conditions (2003) (3)
Benzyne-Furan Cycloaddition Approach to the Angucyclines: First Total Synthesis of Antibiotic C104. (1995) (3)
Toward Pluramycins with Epoxy Side Chain: Syntheses of Kidamycinone and Epoxykidamycinone (Saptomycinone H). (2020) (2)
First Synthesis of Astilbin, Biologically Active Glycosyl Flavonoid Isolated from Chinese Folk Medicine. (2000) (2)
Ring Expansion Approach to Azaspiro[4.5]decane Skeletons via Electrophilic Activation of Benzocyclobutenols Bearing Pyridyl Group (2011) (2)
Cover Picture: Integrated Synthetic Strategy for Higher Catechin Oligomers (Angew. Chem. Int. Ed. 21/2011) (2011) (2)
Epoxy Silyl Ether Rearrangements: A New, Stereoselective Approach to the Synthesis of β-Hydroxy Carbonyl Compounds. (1986) (2)
Photoredox Reaction of Naphthoquinone C ‐Glycoside Revisited: Insight into Stereochemical Aspect (2021) (2)
Facile one-pot procedure for Et3Al-Promoted asymmetric pinacol-type rearrangement (2003) (2)
Corrigendum to: “Structural incongruities of coleophomone natural products: insights by total synthesis of a semi-synthetic derivative” (2003) (2)
A Novel Approach to Erythrinan Alkaloids by Utilizing Substituted Biphenyl as Building Block (2004) (2)
Implication and improvement of stereoselective methylenation of a chiral aldehyde related to total synthesis of the furaquinocins (1997) (2)
Concise Synthesis of Riccardin C, Macrocyclic Bisbibenzyl Natural Product. (2012) (2)
Convergent Total Synthesis of Vineomycinone B2 Methyl Ester and Its C( 12)-Epimer. (2010) (2)
Synthesis of L-vancosamine derivatives from methyl α-D-mannopyranoside (2006) (2)
Stereoselective Substitution of Flavan Skeletons: Synthesis of Dryopteric Acid. (2003) (2)
Syntheses of doubly linked proanthocyanidins using free flavan units as nucleophiles: insight into the origin of the high regioselectivity of annulation. (2019) (2)
Total Synthesis of Galtamycinone, the Common Aglycon of the C-Glycosyl Naphthacenequinone Antibiotics. (1996) (2)
Arene Analogs of the Heck Reaction (2003) (2)
Preparation of Benzocyclobutenone Derivatives Based on an Efficient Generation of Benzynes (2007) (2)
Convenient Procedure for One‐Pot Conversion of Azides to N‐Monomethylamines. (2001) (2)
Synthesis of (.+-.)-Lotthanongine, a Novel Natural Product with a Flavan—Indole Hybrid Structure. (2005) (2)
Efficient Synthetic Route to Ravidosamine Derivatives. (2005) (2)
Total Syntheses of Atrovenetin and Atrovenetinone: A Naphthalene-Annulation Approach to a Discoid Tricycle Using Allenic Acid (2017) (2)
Intramolecular Photoredox Reaction of Naphthoquinone Derivatives (2017) (1)
trans-1,3-Bis(diphenylphosphinoyl)cyclohexane (1992) (1)
Sc(OTf)3‐Catalyzed C‐Glycosylation of β‐Diketones. A Facile Access to Useful Precursors of Heteroaromatic C‐Glycosides. (2006) (1)
Facile Synthesis of Stereodefined α-Iodovinyl Sulfoxides, Versatile Platform to Trisubstituted Olefins (2016) (1)
Facile One‐Pot Procedure for Et3Al‐Promoted Asymmetric Pinacol‐Type Rearrangement (2003) (1)
Linearly Fused Dicyclobutabenzenes via Dual, Regioselective Cycloadditions of 1,4‐Benzdiyne Equivalent and Ketene Silyl Acetals. (2008) (1)
Convenient Synthesis of Phthalides via Regioselective Baeyer-Villiger Oxidation of Benzocyclobutenones. (1995) (1)
Thiolate-mediated Reductive Cyclizations: Scope, Limitation and Novel Mechanistic Insights (2020) (1)
Grignard Type Addition of Alkenyl- and Alkylzirconocene Chloride to Aldehyde: Remarkable Catalytic Acceleration Effect of AgClO4. (1993) (1)
Highly stereoselective synthesis of .ALPHA.-D-glucopyranosides by the N-iodosuccinimide-promoted internal cyclization. (1982) (1)
Facile One‐Pot Synthesis of Resorcinol Bis‐C‐Glycosides Possessing Two Identical Sugar Moieties. (2007) (1)
Synthesis of FD-594 Aglycon (2009) (1)
Hydrozirconation of Allenylstannane for Generating Bimetallic Three‐ Carbon Species: Synthesis of (E)‐1,3‐Dienes from Carbonyl Compounds. (1994) (1)
Intramolecular Benzyne–Phenolate [4+2] Cycloadditions (2020) (1)
Formation of α-Hydroxy-β-diketones Through Hydroxylation of Isoxazolium Salts: Stereoselective Approach to Angular cis-Diols in Polycyclic Systems. (2009) (1)
First Total Synthesis of Oxirapentyn D, a Highly Oxidized Chromene Natural Product (2018) (1)
Short-Step Total Synthesis of a Cyclopropane-Containing Eicosanoid. (1996) (1)
Total Synthesis of Pradimicinone, the Common Aglycon of the Pradimicin—Benanomicin Antibiotics. (1999) (1)
Stereocontrolled Synthesis of (—)‐Afzelechin: General Route to Catechin‐Class Polyphenols by Solving an SN2 vs. SN1 Problem. (2010) (1)
Pseudo‐C3‐Symmetric Tertiary Alcohol Building Block via Group‐Selective Hydroalumination: A Synthesis of (‐)‐Malyngolide. (2001) (1)
α-L-Vancosamine Aryl C-Glycosides, Less Stable Anomers: A Problem in Synthesis of Pluramycin-Class Antibiotics (2020) (1)
Transmission of Axial Chirality to Spiro Center Chirality, Enabling Enantiospecific Access to Erythrinan Alkaloids. (2004) (1)
Total Synthesis and Structure Assignment of the Anthrone C‐Glycoside Cassialoin. (2008) (1)
THE STEREOSELECTIVE SYNTHESIS OF D‐RIBULOSE (1982) (1)
Strain‐Induced Regioselectivities in Reactions of Benzyne Possessing a Fused Four‐Membered Ring. (2004) (1)
Two‐ and Four‐Carbon Homologation of Aldehyde by AgClO4‐Catalyzed Addition of Alkoxyalkenylzirconocene Chloride. (1993) (1)
Synthetic Study of Aquayamycin. Part 3. First Total Synthesis. (2001) (1)
Model Study toward Total Synthesis of Dimeric Pyranonaphthoquinones: Synthesis of Hemi-Actinorhodin (2021) (1)
2,5-Dihydroxyterephthalates, 2,5-Dichloro-1,4-benzoquinone-3,6-dicarboxylates, and Polymorphic 2,5-Dichloro-3,6-dihydroxyterephthalates. (2008) (1)
Enantioselective Total Syntheses of Preussomerins: Control of Spiroacetal Stereogenicity by Photochemical Reaction of a Naphthoquinone through 1,6‐Hydrogen Atom Transfer (2022) (1)
Group-Selective Approaches to Complex Natural Product Synthesis: Three Examples of Diastereotopos-Selective Reactions (2021) (1)
Synthesis of ent-SeragakinoneA (2011) (1)
Preparation of enaminones by two-carbon homologation of amides with lithium (triphenylsilyl)acetylide [Erratum to document cited in CA107(7):58827U] (1988) (1)
THE STEREOSELECTIVE SYNTHESIS OF L-TAGATOSE - AN APPLICATION OF ZINC(II) MEDIATED HIGHLY STEREOSELECTIVE ADDITION OF 2-FURYLLITHIUM TO POLYOXYGENATED ALDEHYDE (1983) (1)
Amine‐Promoted Cyclocondensation of Highly Substituted Aromatic Nitrile Oxides with Diketones. (2003) (1)
O C-Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl C-Glycosides. (1992) (1)
Mutant deletions in Escherichia coli affect the cellular levels of undecaprenyl phosphate and undecaprenyl diphosphate (2013) (1)
COMPLETELY STEREOSPECIFIC 1,2‐MIGRATION OF ALKYL GROUPS IN DIETHYLALUMINUM CHLORIDE (ET2ALCL) PROMOTED PINACOL‐TYPE REARRANGEMENT (1985) (1)
On the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone. Remarkable Effect of Trialkylsilyl Substituent. (1994) (1)
Novel Migrating Group in 1,2-Anionotropic Reactions: Cobalt Complexation Facilitates 1,2-Shift of Alkynyl Groups. (1997) (1)
Synthesis of Highly Functionalized Isoxazoles via Base‐Promoted Cyclocondensation of Stable Nitrile Oxides with Active Methylene Compounds. (2008) (1)
General Synthesis Route to Benanomicin‐Pradimicin Antibiotics (2008) (1)
Synthetic Study of Aquayamycin. Part 1. Synthesis of 3‐(Phenylsulfonyl)phthalides Possessing a β‐C‐Olivoside. (2001) (1)
Divergent Behavior of Cobalt‐Complexed Enyne Having a Leaving Group. (1999) (1)
Synthesis of Highly Functionalized Isoxazoles via Base-Promoted Cyclocondensation of Stable Nitrile Oxides with Active Methylene Compounds (2007) (1)
ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(P-TERT-BUTYLPHENYLTHIO)CYCLOHEXAN-1-ONE (1982) (0)
C‐Glycosyl Juglone in Angucycline Synthesis: Total Synthesis of Galtamycinone, Common Aglycon of C‐Glycosyl Naphthacenequinone‐Type Angucyclines. (1998) (0)
Dioxanone‐Fused Dienes Enable Highly endo‐Selective Intramolecular Diels—Alder Reactions. (2015) (0)
Synthesis and Stereochemical Assignment of Angucycline Antibiotic, PD‐116740. (2008) (0)
A process for preparing flavonoid (2001) (0)
Silicon-Directed Regioselective [2 + 2] Cycloaddition of α-Alkoxybenzyne and Ketene Silyl Acetals. (2000) (0)
PB163 Stereocontrolled Total Synthesis of Mycinamicin IV (1988) (0)
A method for producing a flavanderivats (2007) (0)
Cp2ZrCl2-AgClO4: Efficient Promoter for the Friedel-Crafts Approach to C-Aryl Glycosides. (1989) (0)
Highly Selective Acyclic Stereocontrol Based on 1,2-Rearrangement (1988) (0)
Silicon-Directed Stereoselective Synthesis of 2-Vinyl-1,3-diols. Stereo-Divergence with and without the Silyl Group Related to the Synthesis of Avenaciolide and Isoavenaciolide. (1988) (0)
Single-Step Synthesis of Cyclooctadienone Derivatives by Reaction of Alkenylcyclobutenones with Alkenyllithiums: Enhanced Reactivity of 8π Cyclization by Acetylating the Intermediary Lithium Tetraenolate. (2003) (0)
Dichlorobis(cyclopentadienyl)hafnium–Silver(I) Salts (2001) (0)
Molecular Sieve (MS 4A) Promoted Cyclocondensation of Hindered, Aromatic Nitrile Oxides and Cyclic Diketones under Mild Conditions. (2004) (0)
Thiolate-mediated reductive cyclization: asymmetric total synthesis of (+)-engelharquinone (2019) (0)
trans-1,3-Bis(diphenylphosphinoyl)cyclohexane. (1992) (0)
Synthesis of Antibiotic TAN-1085 (2010) (0)
New Approach to C-Aryl Glycosides Starting from Phenol and Glycosyl Fluoride. Lewis Acid-Catalyzed Rearrangement of O-Glycoside to C-Glycoside. (1989) (0)
P-273 Synthetic Study of the Pluramycins (2006) (0)
Ring Expansion of Cyclopropylbenzocyclobutenes En Route to Benzocycloheptenes. (2012) (0)
ASYMMETRIC PINACOL-TYPE REARRANGEMENT OF α-HYDROXYMETHANESULFONATES PROMOTED BY TRIETHYLALUMINUM. PREPARATION OF OPTICALLY PURE α-ARYL AND α-VINYL KETONES (1984) (0)
Lactols in Stereoselection. Part 2. Stereoselective Synthesis of Disubstituted Cyclic Ethers. (1988) (0)
CCDC 1052978: Experimental Crystal Structure Determination (2016) (0)
4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE. A NEW AND USEFUL BUILDING BLOCK FOR THE SYNTHESES OF L-SUGARS (1982) (0)
Isoxazole→Benzisoxazole Rearrangement Promoted Cascade Reactions Affording Stereodefined Polycycles. (2003) (0)
Isochroman-3-ones via Site-Selective Ring Opening of Benzocyclobutenones Promoted by Lithium Tetramethylpiperidide and Reaction with Aromatic Aldehydes. (1998) (0)
Stereochemical Anomaly in the Thermal Conversion of 7,8‐Dioxy‐7‐alkenylbenzocyclobutenes to Dihydronaphthalenes. (2002) (0)
Two‐Directional Anellation: Dual Benzyne Cycloadditions Starting from Bis(sulfonyloxy)diiodobenzene. (2007) (0)
Lewis Acid-Promoted Reaction of Secondary Phosphines with Carbonyl Compounds: Remarkable Effect of Niobium(V) Chloride in Promoting an Intramolecular Oxidation-Reduction Process. (1992) (0)
Efficient Synthetic Route to Ravidosamine Derivatives (2005) (0)
Cationic Zirconocene- or Hafnocene-Based Lewis Acids in Organic Synthesis: Glycoside—Flavonoid Analogy. (2004) (0)
Reaction of 1-Iodoalkynes with Allylzirconiums: Generation of Alkylidene Carbenoid via Allylzirconation. (1999) (0)
A Novel Method for the Synthesis of 2-Deoxydisaccharide by Stereoselective Cyclization of the Acyclic Precursor. (1982) (0)
Synthetic Strategies and Tactics for Catechin and Related Polyphenols (2014) (0)
Dichlorobis(cyclopentadienyl)hafnium (2008) (0)
Synthetic Study on Acremoxanthone A, Part 2: Model Study on the EFG Xanthone Moiety through a Nitrile Oxide Cycloaddition–SNAr Sequence (2020) (0)
Synthesis of Functionalized Cyclobutene Derivatives via Selective SN2′ Reaction of Dichlorocyclobutenes. (2010) (0)
C(2)-Stereocontrol of δ-Lactones via Acid-Catalyzed Cyclization of Ketene Dithioacetal having an Internal Hydroxyl Group. (1986) (0)
Dodecamethoxy- and Hexaoxotricyclo-butabenzene (2006) (0)
Additions and Corrections. Epoxy Silyl Ether Rearrangements: A New, Stereoselective Approach to the Synthesis of β-Hydroxy Carbonyl Compounds (1986) (0)
Cobalt Complexation Makes 2‐(1‐Alkynyl)propenes Good Ene Donors in Carbonyl‐Ene Reaction. (1996) (0)
Highly Stereoselective Approach to Chiral Building Block Possessing Three Contiguous Asymmetric Centers. Three Continuous Asymmetric Centers. Preparation of Four Possible Diastereomers of β,β′-Di-methyl-bis-homoallylic Alcohol Derivat (1985) (0)
Synthesis of Functionalized Biaryl Compounds via Ring Expansion of Alkenylcyclobutenones. (2003) (0)
(2 + 2) Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to Benzocyclobutenones. (1995) (0)
Two Isolable Conformers of Dihydropentahelicenediol Derivatives: Stereochemical Property and Its Utility for Asymmetric Reactions. (2007) (0)
Unusual Regioselectivity in the Reductive Coupling of Alkynes and Allenes by Hydrozirconation and Zinca‐Claisen Rearrangement. (1998) (0)
Concise Total Synthesis and Structure Assignment of TAN‐1085. (2004) (0)
Total Synthesis and Structure Revision of Deacetylravidomycin M. (2011) (0)
Total Synthesis of Parameritannin A2, a Branched Epicatechin Tetramer with Two Double Linkages (2022) (0)
Lactols in Stereoselection. Part 1. Highly Selective 1,4- and 1,5-Asymmetric Induction. (1988) (0)
ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF ALKYLLITHIUM AND DIALKYLMAGNESIUM TO ALDEHYDES BY USING (2S,2′S)-2-HYDROXYMETHYL-1-((1-ALKYLPYRROLIDIN-2-YL)METHYL)PYRROLIDINES AS CHIRAL LIGANDS (1979) (0)
anti-Selective Vinylogous Aldol Reaction by Silylated Alkyldioxinone Dienolate. (2011) (0)
Conformational Effects in Organoaluminum-Promoted Pinacol-Type Rearrangement. (1986) (0)
Revival and Last Spurt of My Research Career (2020) (0)
Catalytic Version of Epoxy Silyl Ether Rearrangements. (1988) (0)
THE STEREOSELECTIVE SYNTHESIS OF 2,3‐CIS‐DIHYDROXY‐Γ‐BUTYROLACTONES BY THE OXIDATION OF Γ‐BUTENOLIDES WITH POTASSIUM PERMANGANATE‐CROWN ETHER (1983) (0)
CCDC 812001: Experimental Crystal Structure Determination (2011) (0)
Proanthocyanidin Oligomers with Doubly Linked (A‐Type) Interflavan Connectivity (2021) (0)
Recent Progress in O-Glycoside Synthesis. Methodological Aspects (1992) (0)
Diethyl[dimethyl(phenyl)silyl]aluminum (2001) (0)
Aldehyde–Ketone Benzoin Cyclizations (2012) (0)
Regioselectivity of MAO‐Catalyzed Allylmetalation of Conjugated Enynes with Allylzirconiums. (1999) (0)
peri‐Selectivity in Thermolysis of Acyloxybenzocyclobutenes Possessing α,β‐Unsaturated Carbonyl Group: Synthesis of 2‐Benzoxocin Derivatives. (2006) (0)
Base‐Promoted Ring Expansion of 2‐Alkoxy‐2‐vinylbenzocyclobutenol into Substituted Naphthalene Derivatives. (2010) (0)
Mukaiyama Aldol Reaction of Ester Acceptors: Organoaluminums Catalyze Nucleophilic Addition of Ketene Silyl Acetals. (2007) (0)
On the Use of Epoxy Alcohol-Aldol Rearrangement for Stereoselective Construction of Quaternary Carbon Centers. (1988) (0)
Regioselective Alkylzirconation of Internal Alkynes. (2001) (0)
Applications of Benzynes in Natural Product Synthesis (2021) (0)
Stereoselective Construction of Three- and Four-Contiguous Asymmetric Centers: Novel Possibility by Alkylative Rearrangement of Epoxy Silyl Ethers. (1991) (0)
Stereocontrolled First Total Synthesis of Mycinolide IV (I). (1987) (0)
New and Highly E‐Selective Synthesis of Terminal 1,3‐Diene via Three‐ Carbon Elongation of Aldehyde. (1993) (0)
ASYMMETRIC ADDITION OF ACETYLIDE TO ALIPHATIC ALDEHYDES. PREPARATION OF OPTICALLY ACTIVE 5-OCTYL-2(5H)-FURANONE (1980) (0)
ENANTIO- AND DIASTEREO-CONTROLLED SYNTHESIS OF (+)- AND (-)-ELDANOLIDE BASED ON ASYMMETRIC PINACOL-TYPE REARRANGEMENT (1985) (0)
P-245 Axially Chiral Styrene : Key for the Asymmetric Total Synthesis of TAN-1085 (2006) (0)
Total Synthesis and Structure Assignment of Saptomycin H. (2022) (0)
(E)-Stereoselective Synthesis of Vinylglycines from (R)-Serine via Organocopper-BF3 and Related Reagents. (1995) (0)
Ring Expansion Approach to Azaspiro[4.5]decane Skeletons via Electrophilic Activation of Benzocyclobutenols Bearing Pyridyl Group. (2011) (0)
Total Synthesis of Carthamin, a Traditional Natural Red Pigment (2019) (0)
First Total Synthesis of BE-12406 A. (1994) (0)
Frontispiece: Photoredox Reactions of Quinones (2018) (0)
Reversible Redox Behavior of Quinone-Based Molecule with Activated Carbon Slurry Electrode (2020) (0)
Synthesis of (+)-Macrocidin A (2010) (0)
Total Synthesis of the Furaquinocins. (1999) (0)
Asymmetric Synthesis of Chiral Synthons Bearing Alkynyl Group via Organoaluminum-Promoted Pinacol-Type Rearrangement. (1986) (0)
Synthesis of (+)-11-Hydroxyerythratidine (2009) (0)
Regioselective Approach to Multisubstituted Benzenes. (2012) (0)
Implication and Improvement of Stereoselective Methylenation of a Chiral Aldehyde Related to Total Synthesis of the Furaquinocins. (1997) (0)
Stereoselective Synthesis of C(1)-C(9) and C(11)-C(17) Fragments of Protomycinolide IV Based on Asymmetric Pinacol-Type Rearrangement. (1985) (0)
Concise Synthesis of ()-?-Indomycinone (2007) (0)
MAO-Catalyzed Allylzirconation of 1-Alkynes. (1997) (0)
4-O-Benzyl-2,3-O-isopropylidene-L-threose: A Useful Building Block for Stereoselective Synthesis of Monosaccharides. (1990) (0)
Synthetic Strategy toward Dearomatized Polycyclic Polyketide Natural Products (2019) (0)
Arene Substitution via Addition—Elimination (2003) (0)
Procedure for One-pot Conversion of Azides to N-Mono-methylamines (2001) (0)
Stereospecificity in (2 + 2) Cycloaddition of Benzyne and Ketene Silyl Acetal. (1995) (0)
THE ENANTIOSELECTIVE MICHAEL ADDITION OF THIOLS TO CYCLOALKENONES BY USING (2S,4S)‐2‐(ANILINOMETHYL)‐1‐ETHYL‐4‐HYDROXYPYRROLIDINE AS CHIRAL CATALYST (1981) (0)
Synthetic Study on Carthamin, Part 4. Improved Synthesis of a C-Glycosyl Quinochalcone by Installation of a Side Chain through Regioselective De-O-methylation and Acyl Rearrangement (2021) (0)
Synthesis of 2-Vinyl-1,3-diols via Highly Stereoselective Reduction of 2-Vinyl Aldols Using Trimethylsilyl Stereo-Directing Group. (1987) (0)
Synthetic Study of Aquayamycin. Part 2. Synthesis of the AB Ring Fragment. (2001) (0)
Hydrozirconation of Allenyl Sulfide for Generating γ-Thio- Substituted Allylzirconium Species and Its Reaction with Carbonyl Compounds. (2010) (0)
Diethyl(tributylstannyl)aluminum (2001) (0)
Hafnium-Centered Lewis Acids in Organic Chemistry (2003) (0)
De novo synthesis of dimerization-ready flavan unit via intramolecular Pummerer/Friedel-Crafts cascade. (2022) (0)
P-281 A Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization and Its Application to Natural Product Synthesis (2006) (0)
General and Convenient Approach to Flavan‐3‐ols: Stereoselective Synthesis of (‐)‐Gallocatechin. (2007) (0)
Titelbild: Integrated Synthetic Strategy for Higher Catechin Oligomers (Angew. Chem. 21/2011) (2011) (0)
Convenient Procedure for Selective Generation of Allylzirconocene Chlorides via Hydrozirconation of Allenes. (2010) (0)
Asymmetric Intramolecular Crossed Aldehyde-Ketone Benzoin Cyclization (2006) (0)
The Flavan—Isoflavan Rearrangement: Bioinspired Synthetic Access to Isoflavonoids via 1,2-Shift—alkylation Sequence. (2015) (0)
Alkylzirconation of Alkynes Catalyzed by Triphenylcarbenium Tetrakis(pentafluorophenyl)borate. (2000) (0)
Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization. (2002) (0)
Preparation of Enaminones by Two-Carbon Homologation of Amides with Lithium (Triphenylsilyl)acetylide. (1988) (0)
Isoxazole‐Assisted Direct Substitution of the Hydroxy Group in α‐Ketols: Introduction of Angular Substituents in a Polycyclic System. (2009) (0)
Tris(trimethylsilyl)aluminum (2001) (0)
Glycosylation Study on Pradimicin—Benanomicin Antibiotics. (2000) (0)
Facile One-Pot Synthesis of Resorcinol Bis-C-Glycosides Possessing Two Identical Sugar Moieties Facile One-Pot Synthesis of Resorcinol Bis-C-Glycosides (2006) (0)
Expeditious Modular Assembly of Multisubstituted Cyclohexanes via Dioxanone—Dienes. (2012) (0)
Pinacol Rearrangement for Constructing Asymmetric Centers Adjacent to Heterocycles. (2002) (0)
Synthesis of Benzocyclooctene Derivatives via Thermal Ring Expansion of Dienylbenzocyclobutenes. (2002) (0)
Siloxy(trialkoxy)ethene Undergoes Regioselective [2 + 2] Cycloaddition to Ynones and Ynoates en route to Functionalized Cyclobutenediones. (2010) (0)
Lactols in Stereoselection. Part 3. Highly anti-Cram Selective 1,2-Asymmetric Induction. (1989) (0)
Synthetic Study on Lactonamycins, Part 2: Stereoselective Access to ABCD-Ring System (2020) (0)
P-462 Synthetic Approach to Polyketide-Derived Polycyclic Natural Products with Stereogenic Center at Angular Position (2006) (0)
Stereo-Divergent Asymmetric Total Synthesis of Avenaciolide and Isovenaciolide. Complete Reversal of Stereoselectivity in Reduction of 2-Vinyl Aldols with/without Trimethylsilyl Directing Group. (1987) (0)
New Glycosidation Reaction. Part 2. Preparation of 1-Fluoro-D-Desosamine Derivative (V) and Its Efficient Glycosidation by the Use of Cp2HfCl2-AgClO4 as the Activator. (1988) (0)
Enantiopure Acetals of α-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile. (2010) (0)
P-559 Convergent Approach to Oligocatechins based on the Flavonoid-Sugar Analogy (2006) (0)
Stereocontrolled Asymmetric Total Synthesis of Protomycinolide IV (XIII). (1986) (0)
A Novel Approach to Erythrinan Alkaloids by Utilizing Substituted Biphenyl as Building Block. (2004) (0)

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