Keisuke Suzuki
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Keisuke Suzukichemistry Degrees
Chemistry
#4174
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Organic Chemistry
#672
World Rank
#767
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Chemistry
Keisuke Suzuki's Degrees
- PhD Chemistry University of Tokyo
- Masters Chemistry University of Tokyo
- Bachelors Chemistry University of Tokyo
Why Is Keisuke Suzuki Influential?
(Suggest an Edit or Addition)Keisuke Suzuki's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Enantioface-differentiating (asymmetric) addition of alkyllithium and dialkylmagnesium to aldehydes by using (2S,2'S)-2-hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidines as chiral ligands (1979) (199)
- New glycosidation reaction 1: Combinational use of Cp2ZrCl2-AgClO4 for activation of glycosyl fluorides and application to highly β-selective gylcosidation of D-mycinose (1988) (182)
- Total synthesis of the gilvocarcins (1994) (177)
- Catalytic enantioselective crossed aldehyde-ketone benzoin cyclization. (2006) (169)
- Total Synthesis of Aryl C-Glycoside Natural Products: Strategies and Tactics. (2017) (141)
- New approach to C-aryl glycosides starting from phenol and glycosyl fluoride. Lewis acid-catalyzed rearrangement of O-glycoside to C-glycoside (1988) (132)
- Catalytic intramolecular crossed aldehyde--ketone benzoin reactions: a novel synthesis of functionalized preanthraquinones. (2003) (125)
- An improved procedure for metallocene-promoted glycosidation. Enhanced reactivity by employing 1:2-ratio of Cp2HfCl2-AgClO4 (1989) (115)
- Total Synthesis and Absolute Stereochemical Assignment of Gilvocarcin M. (1992) (109)
- New glycosidation reaction 2. preparation of 1-fluoro-d-desosamine derivative and its efficient glycosidation by the use of Cp2HfCl2-AgClO4 as the activator (1988) (106)
- 4-O-Benzyl-23-O-isopropylidene-L-threose: A useful building block for stereoselective synthesis of monosaccharides (1990) (104)
- Modified chiral triazolium salts for enantioselective benzoin cyclization of enolizable keto-aldehydes: synthesis of (+)-sappanone B. (2007) (96)
- New efficient protocol for aryne generation. Selective synthesis of differentially protected 1,4,5-naphthalenetriols (1991) (89)
- Epoxy silyl ether rearrangements: a new, stereoselective approach to the synthesis of .beta.-hydroxy carbonyl compounds (1986) (84)
- Cp2ZrCl2AgBF4 in Benzene: A new reagent system for rapid and highly selective α-mannoside synthesis from tetra-O-benzyl-d-mannosyl fluoride (1989) (78)
- On the stereochemistry of aryl C-glycosides: Unusual behavior of bis-TBDPS protected aryl C-olivosides (1996) (76)
- Convergent total synthesis of vineomycinone B2 methyl ester and its C(12)-epimer (1991) (75)
- Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds. (2018) (72)
- The Enantioselective Michael Addition of Thiols to Cycloalkenones by Using (2S, 4S)-2-Anilinomethyl-1-ethyl-4-hydroxypyrrolidine as Chiral Catalyst (1982) (71)
- Oligomeric catechins: an enabling synthetic strategy by orthogonal activation and C(8) protection. (2004) (65)
- Strain-induced regioselectivities in reactions of benzyne possessing a fused four-membered ring. (2003) (62)
- Concise total synthesis and structure assignment of TAN-1085. (2004) (59)
- Synthetic study toward vineomycins. Synthesis of c-aryl glycoside sector via Cp2HfCl2AgClO4-promoted tactics (1989) (59)
- Stereocontrolled asymmetric total synthesis of protomycinolide IV (1986) (59)
- Two-directional annelation: dual benzyne cycloadditions starting from bis(sulfonyloxy)diiodobenzene. (2006) (58)
- Total Synthesis of Pradimicinone, the Common Aglycon of the Pradimicin-Benanomicin Antibiotics. (1999) (57)
- Stereochemical relay via axially chiral styrenes: asymmetric synthesis of the antibiotic TAN-1085. (2009) (57)
- Thiazolium Ylide-Catalyzed Intramolecular AldehydeKetone Benzoin-Forming Reactions: Substrate Scope (2004) (56)
- Total synthesis and absolute configuration of macrocidin A, a cyclophane tetramic acid natural product. (2010) (56)
- From Axial Chirality to Central Chiralities: Pinacol Cyclization of 2,2'-Biaryldicarbaldehyde to trans-9,10-Dihydrophenanthrene-9,10-diol. (1999) (54)
- Catalytic generation of arynes and trapping by nucleophilic addition and iodination. (2012) (54)
- A "hot, energized" benzyne. (2013) (54)
- [2+2] Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to Benzocyclobutenones (1995) (53)
- Cp2ZrCl2-AgClO4: Efficient promoter for the Friedel-Crafts approach to C-aryl glycosides (1989) (52)
- Lactols in stereoselection 2. Stereoselective synthesis of disubstituted cyclic ethers. (1987) (50)
- Regio- and stereocontrolled total synthesis of benanomicin B. (2005) (49)
- Block copolymer of 2-methyl-2-oxazoline with silica gel an organic-inorganic hybrid polymer (1991) (49)
- Total synthesis of ravidomycin: revision of absolute and relative stereochemistry (2000) (48)
- Facile Access to Versatile Polyaromatic Building Blocks: Selectively Protected Benzocyclobutenedione Derivatives via Regioselective [2+2] Cycloaddition of α‐Alkoxybenzyne and Ketene Silyl Acetal (2002) (47)
- On the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone Remarkable Effect of Trialkylsilyl Substituent (1993) (47)
- Total Synthesis of the Furaquinocins (1998) (47)
- Dodecamethoxy- and hexaoxotricyclobutabenzene: synthesis and characterization. (2006) (47)
- On the use of epoxy alcohol-aldol rearrangement for stereoselective construction of quarternary carbon centers (1987) (46)
- First total synthesis of mycinamicin IV and VII.: Successful application of new glycosidation reaction (1988) (46)
- Grignard-type addition of alkenyl- and alkylzirconocene chloride to aldehyde: Remarkable catalytic acceleration effect of AgClO4 (1992) (45)
- ENANTIOSELECTIVE ADDITION OF ACETYLENE TO ALDEHYDE. PREPARATION OF OPTICALLY ACTIVE ALKYNYL ALCOHOLS (1979) (45)
- Amine-promoted cyclocondensation of highly substituted aromatic nitrile oxides with diketones (2003) (45)
- STEREOSPECIFICITY IN 2+2 CYCLOADDITION OF BENZYNE AND KETENE SILYL ACETAL (1995) (44)
- Synthetic study of aquayamycin. Part 3: First total synthesis (2000) (43)
- Hydrogen-bond control in axially chiral styrenes: selective synthesis of enantiomerically pure C2-symmetric paracyclophanes. (2009) (43)
- Poly-oxygenated tricyclobutabenzenes via repeated [2 + 2] cycloaddition of benzyne and ketene silyl acetal. (2006) (42)
- Total synthesis and absolute stereochemistry of seragakinone A. (2011) (42)
- First stereoselective total synthesis of FD-594 aglycon. (2009) (41)
- Concise three-component synthesis of defucogilvocarcin M. (2004) (41)
- Total synthesis and structure assignment of the anthrone C-glycoside cassialoin. (2008) (40)
- Total synthesis of antibiotic C104: Benzyne-Furan cycloaddition approach to the angucyclines (1995) (39)
- Novel Migrating Group in 1,2-Anionotropic Reactions: Cobalt Complexation Facilitates 1,2-Shift of Alkynyl Groups (1996) (39)
- Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization (2002) (37)
- Total synthesis of aryl C-glycoside antibiotics (1994) (37)
- Structure-activity relationships of lysophosphatidylserine analogs as agonists of G-protein-coupled receptors GPR34, P2Y10, and GPR174. (2015) (36)
- General synthesis route to benanomicin-pradimicin antibiotics. (2007) (36)
- AgAsF6 as safe alternative to AgClO4 for generating cationic zirconocene species: Utilities in lewis acid-promoted selective CC bond forming reactions (1995) (35)
- Integrated synthetic strategy for higher catechin oligomers. (2011) (35)
- Facile construction and divergent transformation of polycyclic isoxazoles: direct access to polyketide architectures. (2003) (35)
- Benzyne-Furan Cycloaddition Approach to the Angucyclines: First Total Synthesis of Antibiotic C104 (1995) (35)
- Stereoselective Synthesis of Cyclopropanes via Homoallylic Participation (1995) (34)
- Catalytic version of epoxy silyl ether rearrangements (1987) (33)
- Solvent-controlled leaving-group selectivity in aromatic nucleophilic substitution. (2008) (33)
- Asymmetric synthesis of optically pure α-methyl-β,γ-unsaturated ketones via triethylaluminum-mediated stereospecific pinacol rearrangement of alkenyl groups (1984) (33)
- Silicon-directed stereoselective synthesis of 2-vinyl-1,3-diols (1988) (32)
- Tandem ring expansion of alkenyl benzocyclobutenol derivatives into substituted naphthols. (2006) (32)
- Novel Lewis acid catalysis in organic synthesis (1994) (32)
- Recent Progress in O-Glycoside Synthesis-Methodological Aspects (1992) (31)
- ASYMMETRIC ADDITION OF ACETYLIDE TO ALIPHATIC ALDEHYDES—PREPARATION OF OPTICALLY ACTIVE 5-OCTYL-2(5H)-FURANONE— (1980) (30)
- Synthesis of the pluramycins 2: total synthesis and structure assignment of saptomycin B. (2014) (30)
- THE STEREOSELECTIVE SYNTHESIS OF D-RIBULOSE (1981) (30)
- Two- and four-carbon homologation of aldehyde by AgClO4-catalyzed addition of alkoxyalkenylzirconocene chloride (1993) (30)
- Convergent synthesis of the ABCDEF-ring system of yessotoxin and adriatoxin. (2002) (30)
- Stereocontrolled Convergent Total Synthesis of (.+-.)-Furaquinocin D (1995) (29)
- Asymmetric pinacol-type rearrangement of α-hydroxy methanesulfonates promoted by triethylaluminum — preparation of optically pure α-aryl and α-vinyl ketones — (1983) (29)
- Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C. (2017) (29)
- Isoxazole-directed pinacol rearrangement: stereocontrolled approach to angular stereogenic centers. (2007) (28)
- Unexpected outcome of NbCl5-promoted Sakurai reaction: Mechanistic implications relevant to C4H7+ species (1995) (28)
- Lactols in stereoselection 1. Highly selective 1,4- and 1,5-asymmetric induction (1987) (28)
- Stereo-divergent asymmetric total synthesis of avenaciolide and isoavenaciolide. Complete reversal of stereoselectivity in reduction of 2-vinyl aldols with / without trimethylsilyl directing group (1986) (27)
- Hexaradialenes by successive ring openings of tris(alkoxy-tricyclobutabenzenes): synthesis and characterization. (2010) (27)
- Enantio- and diastereo-controlled synthesis of (+) - and (−) - eldanolide based on asymmetric pinacol-type rearrangement (1985) (27)
- A new synthetic strategy for catechin-class polyphenols: concise synthesis of (-)-epicatechin and its 3-O-gallate. (2012) (27)
- C-Glycosyl juglone in angucycline synthesis: Total synthesis of galtamycinone, common aglycon of C-glycosyl naphthacenequinone-type angucyclines (1997) (26)
- Synthesis of the pluramycins 1: two designed anthrones as enabling platforms for flexible bis-C-glycosylation. (2014) (26)
- Ring selectivity: successive ring expansion of two benzocyclobutenes for divergent access to angular and linear benzanthraquinones. (2008) (26)
- ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF DIALKYLMAGNESIUM TO ALDEHYDES BY USING THE LITHIUM SALT OF (2S, 2′S)-2-HYDROXYMETHYL-1-[(1-METHYLPYRPOLIDIN-2-YL)METHYL]PYRROLIDINE AS A CHIRAL LIGAND (1978) (25)
- Formation of alpha-hydroxy-beta-diketones through hydroxylation of isoxazolium salts: stereoselective approach to angular cis-diols in polycyclic systems. (2008) (25)
- MAO-Catalyzed Allylzirconation of 1-Alkynes (1997) (25)
- Convenient Procedure for One-pot Conversion of Azides to N-Monomethylamines (2001) (24)
- A FORMAL TOTAL SYNTHESIS OF POLYOXIN J USING 4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE AS A COMMON CHIRAL BUILDING BLOCK (1984) (24)
- Synthetic study of aquayamycin. Part 1: Synthesis of 3-(phenylsulfonyl)phthalides possessing a β-C-olivoside (2000) (24)
- Enantio- and diastereomerically pure threo-homoallylic alcohols via highly stereoselective reduction of α-methyl-β,γ-unsaturated ketones (1984) (24)
- Photoredox Reactions of Quinones. (2018) (23)
- General synthesis of epi-series catechins and their 3-gallates: reverse polarity strategy. (2010) (23)
- Asymmetric synthesis of chiral synthons bearing alkynyl group via organoaluminum-promoted pinacol-type rearrangement (1986) (23)
- Total synthesis of the antibiotic BE-43472B. (2013) (23)
- Hydrozirconation of Allenylstannane for Generating Bimetallic Three-Carbon Species: Synthesis of (E)-1,3-Dienes from Carbonyl Compounds (1993) (23)
- Further study on SmI2-induced reductive intramolecular cyclization: synthesis of polycyclic ethers having an angular methyl group (2002) (22)
- BASE-PROMOTED RING EXPANSION OF 2-ALKOXY-2-VINYLBENZOCYCLOBUTENOL INTO SUBSTITUTED NAPHTHALENE DERIVATIVES (1998) (22)
- threo‐3‐Alkyl‐ and ‐Arylglutamic Acid Derivatives by Michael Additions of Boc‐BMI Li‐Enolates to 2,6‐Di‐t‐butyl‐4‐methoxyphenyl Alkenoates on the Diastereoselectivity of the Coupling of Trigonal Centers Involving Heterocyclic Li‐Enolates (1992) (22)
- Lessons from total synthesis of hybrid natural products. (2010) (22)
- First total synthesis of BE-12406 A (1994) (22)
- Synthesis and determination of the absolute configuration of cavicularin by a symmetrization/asymmetrization approach. (2013) (22)
- Annulation approach to doubly linked (A-type) oligocatechins: syntheses of (+)-procyanidin A₂ and (+)-cinnamtannin B₁. (2014) (22)
- Synthesis of hindered 1-arylnaphthalene derivatives via ring expansion of benzocyclobutenones. (2002) (21)
- Stereochemical anomaly in the thermal conversion of 7,8-dioxy-7-alkenylbenzocyclobutenes to dihydronaphthalenes. (2002) (21)
- Reductive pinacol-type rearrangement of chiral α-mesyloxy ketones promoted by organoaluminum compounds (1985) (21)
- Total Synthesis of (+)-Vicenin-2. (2016) (21)
- Rapid O-glycosidation of phenols with glycosyl fluoride by using the combinational activator, Cp2HfCl2-AgClO4 (1989) (21)
- Concise Synthesis of (±)-γ-Indomycinone (2006) (20)
- New and highly (E)-selective synthesis of terminal 1,3-diene via three-carbon elongation of aldehyde (1992) (20)
- Model Reactions for the Enantioselective Synthesis of γ-Rubromycin: Stereospecific Intramolecular Photoredox Cyclization of an ortho-Quinone Ether to a Spiroacetal. (2018) (19)
- Reaction of 1-iodoalkynes with allylzirconiums: Generation of alkylidene carbenoid via allylzirconation (1999) (19)
- Procyanidins Negatively Affect the Activity of the Phosphatases of Regenerating Liver (2015) (19)
- Intramolecular Photoredox Reaction of Naphthoquinone Derivatives (2017) (19)
- Stereoselective convergent synthesis of a trans-fused polycyclic ether ring system including a 4-hydroxy-5-methyl-tetrahydropyran ring. (2002) (19)
- Completely stereospecific 1,2-migration of alkyl groups in Et2AlCl promoted pinacol-type rearrangement (1984) (19)
- General and Convenient Approach to Flavan-3-ols: Stereoselective Synthesis of (−)-Gallocatechin (2006) (19)
- Unusual Regioselectivity in the Reductive Coupling of Alkynes and Allenes by Hydrozirconation and Zinca‐Claisen Rearrangement (1997) (18)
- HIGHLY ENANTIOSELECTIVE MICHAEL ADDITION OF THIOLS TO 2-CYCLOHEXENONE BY USING (2S,4S)-2-(ANILINOMETHYL)-1-ETHYL-4-HYDROXYPYRRQLIPINE AS A CHIRAL CATALYST (1981) (18)
- Total synthesis and structure revision of deacetylravidomycin M (2011) (18)
- First Total Syntheses of Tetracenomycins C and X. (2017) (18)
- Isochroman-3-ones via site-selective ring opening of benzocyclobutenones promoted by lithium tetramethylpiperidide and reaction with aromatic aldehydes (1997) (18)
- TOTAL SYNTHESES OF BE-12406 A AND ITS C(8)-VINYL ANALOG (1996) (17)
- Toward Naphthocyclinones: Doubly Connected Octaketide Dimers with a Bicyclo[3.2.1]octadienone Core by Thiolate-Mediated Cyclization. (2015) (17)
- Synthetic study of aquayamycin. Part 2: Synthesis of the AB ring fragment (2000) (17)
- First synthesis of astilbin, biologically active glycosyl flavonoid isolated from Chinese folk medicine (2000) (17)
- Lactols in stereoselection 3 (1989) (17)
- Convenient Synthesis of Phthalides via Regioselective Baeyer-Villiger Oxidation of Benzocyclobutenones (1995) (17)
- Siloxy(trialkoxy)ethene undergoes regioselective [2+2] cycloaddition to ynones and ynoates en route to functionalized cyclobutenediones. (2010) (17)
- 4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE —A NEW AND USEFUL BUILDING BLOCK FOR THE SYNTHESES OF L-SUGARS— (1982) (16)
- Synthesis and Stereochemical Assignment of Angucycline Antibiotic, PD-116740 (2008) (16)
- Assessment of macrocyclic triamine ligands as synthons for organometallic 99mTc radiopharmaceuticals. (2008) (16)
- Total Synthesis of Actinorhodin. (2019) (16)
- Stereocontrolled first total synthesis of mycinolide IV (1987) (16)
- Total Synthesis of Galtamycinone, the Common Aglycon of the C-Glycosyl Naphthacenequinone Antibiotics (1996) (15)
- Convenient Procedure for Selective Generation of Allylzirconocene Chlorides via Hydrozirconation of Allenes (1994) (15)
- Concise Synthesis of Riccardin C, Macrocyclic Bisbibenzyl Natural Product (2011) (15)
- Stereoselective synthesis of C(1)–C(9) and C(11)–C(17)fragments of protomycinolide iv based on asymmetric pinacol-typerearrangement (1985) (15)
- A domino pericyclic route to polysubstituted salicylic acid derivatives: four sequential processes from enynones and ketene silyl acetals. (2011) (14)
- A NOVEL METHOD FOR THE SYNTHESIS OF 2-DEOXYDISACCHARIDE BY STEREOSELECTIVE CYCLIZATION OF THE ACYCLIC PRECURSOR (1982) (14)
- Structural incongruities of coleophomone natural products: insights by total synthesis of a semi-synthetic derivative (2003) (14)
- Total Synthesis of Carthamin, a Traditional Natural Red Pigment. (2019) (14)
- Isoxazole --> benzisoxazole rearrangement promoted cascade reactions affording stereodefined polycycles. (2003) (14)
- Unified approach to catechin hetero-oligomers: first total synthesis of trimer EZ-EG-CA isolated from Ziziphus jujuba. (2012) (14)
- Synthesis of isoxazoles en route to semi-aromatized polyketides: dehydrogenation of benzonitrile oxide-para-quinone acetal cycloadducts. (2012) (14)
- First regiocontrolled synthesis of procyanidin B6, a catechin dimer with rare connectivity: a halo-capping strategy for formation of 4,6-interflavan bonds. (2013) (14)
- “Dibutyltin diperchlorate” for activation of glycosyl fluoride (1993) (14)
- Lewis Acid Promoted Reaction of Secondary Phosphines with Carbonyl Compounds: Remarkable Effect of Niobium(V) Chloride in Promoting an Intramolecular Oxidation-Reduction Process (1992) (14)
- Cationic zirconocene- or hafnocene-based Lewis acids in organic synthesis: glycoside–flavonoid analogy (2004) (14)
- Preparation of enaminones by two-carbon homologation of amides with lithium (triphenylsilyl)acetylide (1987) (13)
- Regioselectivity of MAO-catalyzed allylmetallation of conjugated enynes with allylzirconiums (1998) (13)
- Pinacol rearrangement for constructing asymmetric centers adjacent to heterocycles (2002) (13)
- Stereoselective substitution of flavan skeletons: synthesis of dryopteric acid (2002) (13)
- Impact of Green Tea Catechin ECG and Its Synthesized Fluorinated Analogue on Prostate Cancer Cells and Stimulated Immunocompetent Cells (2018) (13)
- Synthesis of 2-vinyl-1,3-diols via highly stereoselective reduction of 2-vinyl aldols using trimethylsilyl stereo-directing group (1986) (13)
- Stereocontrolled Total Syntheses of (-)-Rotenone and (-)-Dalpanol by 1,2-Rearrangement and SN Ar Oxycyclizations. (2017) (13)
- Synthetic Study on Carthamin: Problem and Solution for Oxidative Dearomatization Approach to Quinol C-Glycoside (2016) (12)
- Synthetic Study on Carthamin. 2. Stereoselective Approach to C-Glycosyl Quinochalcone via Desymmetrization. (2017) (12)
- Semi-pinacol strategy for constructing b-ring of pradimicin-benanomicin antibiotics (2002) (11)
- Sc(OTf)3-catalyzed C-glycosylation of β-diketones. A facile access to useful precursors of heteroaromatic C-glycosides (2005) (11)
- Sc(OTf)3 as Efficient Catalyst for Aryl C-Glycoside Synthesis (2004) (11)
- First Total Synthesis of Dermocanarin 2 (2016) (11)
- New Methods in Glycoside Synthesis by Using Early Transition Metal-Derived Reagent (1993) (11)
- Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide. (2017) (11)
- Synthesis and Chiroptical Properties of π-Conjugated Polymer Consisting of Dihydropentahelicene Units with Axial Chirality (2010) (11)
- Ortho-metallation of anthracene derivative: problem and solution (1991) (11)
- Stereochemical Dichotomy in Two Competing Cascade Processes: Total Syntheses of Both Enantiomers of Spiroxin A. (2019) (11)
- Enantioselective total synthesis of (-)-euxanmodin B: an axially chiral natural product with an anthraquinone-xanthone composite structure. (2011) (11)
- Construction of Bridged Polycyclic Systems by Polyene Cyclization. (2015) (11)
- C-Glycosylation-Cycloaddition Approach to C-Glycosyl Juglones. Versatile Intermediates toward Aryl C-Glycoside Antibiotics (1995) (10)
- Stereocontolled Synthesis of (−)-Afzelechin: General Route to Catechin-class Polyphenols by Solving an SN2 vs. SN1 Problem (2009) (10)
- Preparation of L-vancosamine-related glycosyl donors (2013) (10)
- Synthetic study of ravidomycin, a hybrid natural product (2000) (10)
- Conformational effects in organoaluminum-promoted pinacol-type rearrangement (1985) (10)
- Regioselective alkylzirconation of internal alkynes (2001) (10)
- Cobalt-Complexation Makes 2-(1-Alkynyl)propenes Good Ene Donors in Carbonyl-Ene Reaction (1995) (9)
- Synthesis and Structure Revision of Goupiolone A: A Benzotropolone Natural Product (2012) (9)
- Recent advances in the chemistry of zirconocenes (2004) (9)
- Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative (1985) (9)
- Pleospdione, A Tricyclic Natural Product with Dense Oxygenation at the A-Ring: Total Synthesis and Incongruity of the Originally Assigned Structure and its C3-Epimer (2016) (9)
- Regioselective Approach to Multisubstituted Benzenes (2011) (9)
- The isolation and structure of siccanochromenes (1968) (9)
- O → C-Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl C-Glycosides (1991) (9)
- Peri-selectivity in Thermolysis of Acyloxybenzocyclobutenes Possessing α,β-Unsaturated Carbonyl Group: Synthesis of 2-Benzoxocin Derivatives (2006) (9)
- Isoxazole-assisted direct substitution of the hydroxy group in alpha-ketols: introduction of angular substituents in a polycyclic system. (2008) (9)
- Divergent behavior of cobalt- complexed enynehaving a leaving group (1999) (9)
- Enantiopure Acetals of α-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile (1997) (8)
- Efficient method for introducing vineomycin-fridamycin-type side chain. Total synthesis of fridamycin E (1991) (8)
- Intramolecular Benzyne-Phenolate [4+2] Cycloadditions. (2020) (8)
- Highly Selective Acyclic Stereocontrol Based on 1, 2-Rearrangement (1988) (8)
- Synthesis of amphiphilic silane coupling agents based on poly(2-ethyl-2-oxazoline) and their reactions with tetraethoxysilane (1993) (8)
- Impressive changeover of reaction course in ring expansion of styrylbenzocyclobutenol under alkoxide-forming conditions (2006) (8)
- ALKYLZIRCONATION OF ALKYNES CATALYZED BY TRIPHENYLCARBENIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE (1999) (8)
- Stereoselective construction of three-and four-contiguous asymmetric centers : novel possibility by alkylative rearrangement of epoxy silyl ethers (1990) (8)
- The flavan-isoflavan rearrangement: bioinspired synthetic access to isoflavonoids via 1,2-shift-alkylation sequence. (2015) (8)
- (E)-stereoselective synthesis of vinylglycines from (R)-serine via organocopper–BF3 and related reagents (1994) (8)
- Hydrozirconation of Allenyl Sulfide for Generating γ-Thio-substituted Allylzirconium Species and Its Reaction with Carbonyl Compounds (1996) (8)
- Ambipolar transistor properties of 2,2′-binaphthosemiquinones (2015) (8)
- Synthesis of Benzocyclooctene Derivatives via Thermal Ring Expansion of Dienylbenzocyclobutenes (2002) (8)
- Intramolecular photoredox reactions of 1,2-naphthoquinone derivatives. (2018) (7)
- Convergence in [2+2+2] synthesis of β-phenylnaphthalene motif in polyaromatic natural products (2006) (7)
- ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(p-t-BUTYLPHENYLTHIO) CYCLOHEXAN-1-ONE (1982) (7)
- Dioxanone-fused dienes enable highly endo-selective intramolecular Diels-Alder reactions. (2015) (7)
- Oxidative Ring Opening of Benzocyclobutenone Oximes: Novel Access to Stable Nitrile Oxides (2017) (7)
- 2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05518a (2019) (7)
- Efficient Bis-C-Aminoglycosylation toward the Synthesis of the Pluramycins (2010) (6)
- Total Synthesis of Bis-anthraquinone Antibiotic BE-43472B (2018) (6)
- Stereoselective reduction of α-cyclopropyl ketones and α-cyclopropyl aldols. Stereo-directing effect by α-trimethylsilyl group (1989) (6)
- Stereospecific 1,2-rearrangement of cyclopropyl group. Synthesis of chiral α-cyclopropyl ketones and α-cyclopropyl aldols (1989) (6)
- Total Synthesis of the Proposed Structure of Ardimerin, and Proposal for its Structural Revision (2016) (6)
- Synthesis of β-Hydroxynaphthoate Derivatives from Ketodioxinones via Benzyne Acyl-Alkylation and Aldol Condensation Cascade (2016) (6)
- Mukaiyama Aldol Reaction of Ester Acceptors: Organoaluminums Catalyze Nucleophilic Addition of Ketene Silyl Acetals (2007) (6)
- Isoxazole Platform for Polyketide Assembly: Cycloaddition of Stable Benzonitrile Oxides to Stable ortho-Quinone Monoacetals and Dehydrogenation (2014) (6)
- Synthesis of 1,3-bis(diphenylphosphinoyl)alkanes via double addition of diphenylphosphine to α,β-unsaturated carbonyl compounds : sequential 1,4- and 1,2-addition promoted by NbCl5-BF3.OEt2 (1992) (6)
- Short-Step Total Synthesis of a Cyclopropane-Containing Eicosanoid (1995) (6)
- Stereocontrolled Synthesis of Planar Chiral Carba-Paracyclophanes via Modular Assembly (2016) (6)
- Lipase-Catalyzed Asymmetrization of Diacetate of Meso-2-(2-Propynyl)cyclohexane-1,2,3-triol toward the Total Synthesis of Aquayamycin (2001) (6)
- Catalytic Intramolecular Crossed Aldehyde—Ketone Benzoin Reactions: A Novel Synthesis of Functionalized Preanthraquinones. (2003) (5)
- 2,5-Dihydroxyterephthalates, 2,5-Dichloro-1,4-benzoquinone-3,6-dicarboxylates,and Polymorphic 2,5-Dichloro-3,6-dihydroxyterephthalates (2008) (5)
- Hybrid Natural Products (2014) (5)
- C(2)-stereocontrol of δ-lactones via acid-catalyzed cyclization of ketene dithioacetal having an internal hydroxyl group (1986) (5)
- Silicon-Directed Regioselective [2+2] Cycloaddition of α-Alkoxybenzyne and Ketene Silyl Acetals (2000) (5)
- Hydroxylamine-Mediated Anthrapyranone Formation, Solving 5-exo/6-endo Issue toward Synthesis of Pluramycin-Class Antibiotics. (2019) (5)
- Glycosylation study on pradimicin–benanomicin antibiotics (2000) (5)
- Transmission of axial chirality to spiro center chirality, enabling enantiospecific access to erythrinan alkaloids (2004) (5)
- Synthetic Study on Naphthospironone A: Construction of Benzobicyclo[3.2.1]octene Skeleton with Oxaspirocycle. (2015) (5)
- anti-Selective Vinylogous Aldol Reaction by Silylated Alkyldioxinone Dienolate (2010) (5)
- Total Synthesis of Selligueain A, a Sweet Flavan Trimer. (2018) (5)
- [3+1] Synthetic Route Toward Synthesis of Cyclobutane/butene Derivatives Based on the Large α-Cation-Stabilizing Effect of Cyclopropane1 (1993) (5)
- Stereogenic tert-alcohols via group-selective hydroalumination: further scope (2002) (5)
- Annulation Approach to Doubly Linked (A-Type) Oligocatechins: Syntheses of (+)-Procyanidin A2 and (+)-Cinnamtannin B1. (2015) (5)
- Total Syntheses of Pusilatins A-C, Liverwort-Derived Macrocyclic Bisbibenzyl Dimers. (2018) (5)
- Synthesis of Optically Active Polymers Using P-Chiral Bisphosphines as Anionic Initiators (2009) (5)
- Linearly Fused Dicyclobutabenzenes via Dual, Regioselective Cycloadditions of 1,4-Benzdiyne Equivalent and Ketene Silyl Acetals (2008) (5)
- Cationic Zirconocene Species in Organic Synthesis (2003) (5)
- Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions. (2013) (5)
- Stereochemical Dichotomy in Two Competing Cascade Processes: Total Syntheses of Both Enantiomers of Spiroxin A (2019) (5)
- Synthetic Study on Acremoxanthone A: Construction of Bicyclo [3.2.2]nonane CD Skeleton and Fusion of AB Rings (2016) (4)
- Expeditious Modular Assembly of Multisubstituted Cyclohexanes via Dioxanone–Dienes (2011) (4)
- Synthesis of functionalized biaryl compounds via ring expansion of alkenylcyclobutenones (2003) (4)
- Bis-C-Glycosylation of Resorcinol Derivatives by an O→C-Glycoside Rearrangement (2006) (4)
- Ring Expansion of Cyclopropylbenzocyclobutenes En Route to Benzocycloheptenes (2011) (4)
- Regioselective remote functionalization of biaryl framework via tethered ortho-quinol intermediate. (2011) (4)
- Lessons from Total Synthesis of Hybrid Natural Products (2011) (4)
- Total Synthesis of Antibiotic C104: Benzyne-Furan Cycloaddition Approach to the Angucyclines. (1995) (4)
- Synthesis of Tetraoxygenated Terephthalates via a Dichloroquinone Route: Characterization of Cross-Conjugated Liebermann Betaine Intermediates (2017) (4)
- Synthesis of Enantiopure C2-Symmetric Anthracenophane and Dimerization En Route to Multiple-Bridged Cyclophanes. (2020) (4)
- Facile one-pot synthesis of resorcinol bis-C-glycosides possessing two identical sugar moieties (2006) (4)
- Enantiodivergent Synthesisof Tetra-ortho-Substituted Biphenylsby Enzymatic Desymmetrization (2009) (4)
- A seco-catechin cyclization approach to 4→6-linked catechin dimers. (2014) (4)
- Synthetic Approaches on the Pluramycin-Class Antibiotics (2019) (4)
- Single-Step Synthesis of Cyclooctadienone Derivatives by Reaction of Alkenylcyclobutenones with Alkenyllithiums: Enhanced Reactivity of 8π Cyclization by Acetylating the Intermediary Lithium Tetraenolate (2002) (4)
- Synthesis of Functionalized Cyclobutene Derivatives via Selective SN2’ Reaction of Dichlorocyclobutenes (2002) (4)
- 3.11 Pinacol Coupling Reactions (2014) (4)
- Preparation of 2-Substituted 3-Methoxycarbonyl-4-methoxyfurans that Allow Access to Highly Functionalized Naphthalenes via Regioselective Cycloaddition with Alkoxybenzyne (2017) (4)
- Total Synthesis of Ravidomycin: Revision of Absolute and Relative Stereochemistry. (2000) (4)
- Synthesis of (′)-lotthanongine, a novel natural product with a flavan-indole hybrid structure (2005) (3)
- Selective Conversion of Benzylic Phosphates into Diarylmethanes Through Al(OTf)3 -Catalyzed Friedel-Crafts-Type Benzylation (2020) (3)
- Synthesis of Oxygenated ortho-Methylbenzaldehydes via Aryne [2+2] Cycloaddition and Benzocyclobutenol Ring Opening. (2018) (3)
- Novel One-Pot Synthesis of Xanthones via Sequential Fluoride Ion-Promoted Fries-Type Rearrangement and Nucleophilic Aromatic Substitution (2013) (3)
- Two isolable conformers of dihydropentahelicenediol derivatives : Stereochemical property and its utility for asymmetric reactions (2007) (3)
- Total Syntheses of Perenniporides. (2015) (3)
- Stereoselective Access to Functionalized Dihydrophenanthrenes via Reductive Cyclization of Biaryl Ene-Aldehydes (2007) (3)
- New Glycosidation Reaction. Part 1. Combinational Use of Cp2ZrCl2-AgClO4 for Activation of Glycosyl Fluorides and Application to Highly β-Selective Glycosidation of D-Mycinose. (1988) (3)
- First Total Synthesis of (+)-11-Hydroxyerythratidine (2009) (3)
- Sc(OTf)3 as Efficient Catalyst for Aryl C-Glycoside Synthesis. (2004) (3)
- Single Step Synthesis of Cyclooctadienone Derivatives by Reaction of Cyclobutenones with Dienyllithium. (2002) (3)
- Hf‐Centered Lewis Acids in Organic Chemistry (2008) (3)
- General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual SNAr Cyclizations of Aryl Fluorides (2019) (3)
- An Alternative Synthetic Route to the C(11)-C(17)-Fragment of Mycinolide IV (1992) (3)
- Cu(II)-mediated stereoselective michael addition of a methyl group to an α,β-unsaturated ester as the C2-side chain in 3-(t-butyldimethylsilyloxy)tetrahydropyrans (2005) (3)
- Cp2MCl2-AgX (M=Zr, Hf) : A Reagent for Glycosidation (1990) (3)
- Zr- and Hf-Centered Lewis Acids in Organic Synthesis (1999) (3)
- Studies on Organic Synthesis Inspired by Carbohydrates (2007) (3)
- Molecular Sieve (MS 4A) Promoted Cyclocondensation of Hindered, Aromatic Nitrile Oxides and Cyclic Diketones under Mild Conditions (2003) (3)
- Benzyne-Furan Cycloaddition Approach to the Angucyclines: First Total Synthesis of Antibiotic C104. (1995) (3)
- Toward Pluramycins with Epoxy Side Chain: Syntheses of Kidamycinone and Epoxykidamycinone (Saptomycinone H). (2020) (2)
- First Synthesis of Astilbin, Biologically Active Glycosyl Flavonoid Isolated from Chinese Folk Medicine. (2000) (2)
- Ring Expansion Approach to Azaspiro[4.5]decane Skeletons via Electrophilic Activation of Benzocyclobutenols Bearing Pyridyl Group (2011) (2)
- Cover Picture: Integrated Synthetic Strategy for Higher Catechin Oligomers (Angew. Chem. Int. Ed. 21/2011) (2011) (2)
- Epoxy Silyl Ether Rearrangements: A New, Stereoselective Approach to the Synthesis of β-Hydroxy Carbonyl Compounds. (1986) (2)
- Photoredox Reaction of Naphthoquinone C ‐Glycoside Revisited: Insight into Stereochemical Aspect (2021) (2)
- Facile one-pot procedure for Et3Al-Promoted asymmetric pinacol-type rearrangement (2003) (2)
- Corrigendum to: “Structural incongruities of coleophomone natural products: insights by total synthesis of a semi-synthetic derivative” (2003) (2)
- A Novel Approach to Erythrinan Alkaloids by Utilizing Substituted Biphenyl as Building Block (2004) (2)
- Implication and improvement of stereoselective methylenation of a chiral aldehyde related to total synthesis of the furaquinocins (1997) (2)
- Concise Synthesis of Riccardin C, Macrocyclic Bisbibenzyl Natural Product. (2012) (2)
- Convergent Total Synthesis of Vineomycinone B2 Methyl Ester and Its C( 12)-Epimer. (2010) (2)
- Synthesis of L-vancosamine derivatives from methyl α-D-mannopyranoside (2006) (2)
- Stereoselective Substitution of Flavan Skeletons: Synthesis of Dryopteric Acid. (2003) (2)
- Syntheses of doubly linked proanthocyanidins using free flavan units as nucleophiles: insight into the origin of the high regioselectivity of annulation. (2019) (2)
- Total Synthesis of Galtamycinone, the Common Aglycon of the C-Glycosyl Naphthacenequinone Antibiotics. (1996) (2)
- Arene Analogs of the Heck Reaction (2003) (2)
- Preparation of Benzocyclobutenone Derivatives Based on an Efficient Generation of Benzynes (2007) (2)
- Convenient Procedure for One‐Pot Conversion of Azides to N‐Monomethylamines. (2001) (2)
- Synthesis of (.+-.)-Lotthanongine, a Novel Natural Product with a Flavan—Indole Hybrid Structure. (2005) (2)
- Efficient Synthetic Route to Ravidosamine Derivatives. (2005) (2)
- Total Syntheses of Atrovenetin and Atrovenetinone: A Naphthalene-Annulation Approach to a Discoid Tricycle Using Allenic Acid (2017) (2)
- Intramolecular Photoredox Reaction of Naphthoquinone Derivatives (2017) (1)
- trans-1,3-Bis(diphenylphosphinoyl)cyclohexane (1992) (1)
- Sc(OTf)3‐Catalyzed C‐Glycosylation of β‐Diketones. A Facile Access to Useful Precursors of Heteroaromatic C‐Glycosides. (2006) (1)
- Facile Synthesis of Stereodefined α-Iodovinyl Sulfoxides, Versatile Platform to Trisubstituted Olefins (2016) (1)
- Facile One‐Pot Procedure for Et3Al‐Promoted Asymmetric Pinacol‐Type Rearrangement (2003) (1)
- Linearly Fused Dicyclobutabenzenes via Dual, Regioselective Cycloadditions of 1,4‐Benzdiyne Equivalent and Ketene Silyl Acetals. (2008) (1)
- Convenient Synthesis of Phthalides via Regioselective Baeyer-Villiger Oxidation of Benzocyclobutenones. (1995) (1)
- Thiolate-mediated Reductive Cyclizations: Scope, Limitation and Novel Mechanistic Insights (2020) (1)
- Grignard Type Addition of Alkenyl- and Alkylzirconocene Chloride to Aldehyde: Remarkable Catalytic Acceleration Effect of AgClO4. (1993) (1)
- Highly stereoselective synthesis of .ALPHA.-D-glucopyranosides by the N-iodosuccinimide-promoted internal cyclization. (1982) (1)
- Facile One‐Pot Synthesis of Resorcinol Bis‐C‐Glycosides Possessing Two Identical Sugar Moieties. (2007) (1)
- Synthesis of FD-594 Aglycon (2009) (1)
- Hydrozirconation of Allenylstannane for Generating Bimetallic Three‐ Carbon Species: Synthesis of (E)‐1,3‐Dienes from Carbonyl Compounds. (1994) (1)
- Intramolecular Benzyne–Phenolate [4+2] Cycloadditions (2020) (1)
- Formation of α-Hydroxy-β-diketones Through Hydroxylation of Isoxazolium Salts: Stereoselective Approach to Angular cis-Diols in Polycyclic Systems. (2009) (1)
- First Total Synthesis of Oxirapentyn D, a Highly Oxidized Chromene Natural Product (2018) (1)
- Short-Step Total Synthesis of a Cyclopropane-Containing Eicosanoid. (1996) (1)
- Total Synthesis of Pradimicinone, the Common Aglycon of the Pradimicin—Benanomicin Antibiotics. (1999) (1)
- Stereocontrolled Synthesis of (—)‐Afzelechin: General Route to Catechin‐Class Polyphenols by Solving an SN2 vs. SN1 Problem. (2010) (1)
- Pseudo‐C3‐Symmetric Tertiary Alcohol Building Block via Group‐Selective Hydroalumination: A Synthesis of (‐)‐Malyngolide. (2001) (1)
- α-L-Vancosamine Aryl C-Glycosides, Less Stable Anomers: A Problem in Synthesis of Pluramycin-Class Antibiotics (2020) (1)
- Transmission of Axial Chirality to Spiro Center Chirality, Enabling Enantiospecific Access to Erythrinan Alkaloids. (2004) (1)
- Total Synthesis and Structure Assignment of the Anthrone C‐Glycoside Cassialoin. (2008) (1)
- THE STEREOSELECTIVE SYNTHESIS OF D‐RIBULOSE (1982) (1)
- Strain‐Induced Regioselectivities in Reactions of Benzyne Possessing a Fused Four‐Membered Ring. (2004) (1)
- Two‐ and Four‐Carbon Homologation of Aldehyde by AgClO4‐Catalyzed Addition of Alkoxyalkenylzirconocene Chloride. (1993) (1)
- Synthetic Study of Aquayamycin. Part 3. First Total Synthesis. (2001) (1)
- Model Study toward Total Synthesis of Dimeric Pyranonaphthoquinones: Synthesis of Hemi-Actinorhodin (2021) (1)
- 2,5-Dihydroxyterephthalates, 2,5-Dichloro-1,4-benzoquinone-3,6-dicarboxylates, and Polymorphic 2,5-Dichloro-3,6-dihydroxyterephthalates. (2008) (1)
- Enantioselective Total Syntheses of Preussomerins: Control of Spiroacetal Stereogenicity by Photochemical Reaction of a Naphthoquinone through 1,6‐Hydrogen Atom Transfer (2022) (1)
- Group-Selective Approaches to Complex Natural Product Synthesis: Three Examples of Diastereotopos-Selective Reactions (2021) (1)
- Synthesis of ent-SeragakinoneA (2011) (1)
- Preparation of enaminones by two-carbon homologation of amides with lithium (triphenylsilyl)acetylide [Erratum to document cited in CA107(7):58827U] (1988) (1)
- THE STEREOSELECTIVE SYNTHESIS OF L-TAGATOSE - AN APPLICATION OF ZINC(II) MEDIATED HIGHLY STEREOSELECTIVE ADDITION OF 2-FURYLLITHIUM TO POLYOXYGENATED ALDEHYDE (1983) (1)
- Amine‐Promoted Cyclocondensation of Highly Substituted Aromatic Nitrile Oxides with Diketones. (2003) (1)
- O C-Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl C-Glycosides. (1992) (1)
- Mutant deletions in Escherichia coli affect the cellular levels of undecaprenyl phosphate and undecaprenyl diphosphate (2013) (1)
- COMPLETELY STEREOSPECIFIC 1,2‐MIGRATION OF ALKYL GROUPS IN DIETHYLALUMINUM CHLORIDE (ET2ALCL) PROMOTED PINACOL‐TYPE REARRANGEMENT (1985) (1)
- On the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone. Remarkable Effect of Trialkylsilyl Substituent. (1994) (1)
- Novel Migrating Group in 1,2-Anionotropic Reactions: Cobalt Complexation Facilitates 1,2-Shift of Alkynyl Groups. (1997) (1)
- Synthesis of Highly Functionalized Isoxazoles via Base‐Promoted Cyclocondensation of Stable Nitrile Oxides with Active Methylene Compounds. (2008) (1)
- General Synthesis Route to Benanomicin‐Pradimicin Antibiotics (2008) (1)
- Synthetic Study of Aquayamycin. Part 1. Synthesis of 3‐(Phenylsulfonyl)phthalides Possessing a β‐C‐Olivoside. (2001) (1)
- Divergent Behavior of Cobalt‐Complexed Enyne Having a Leaving Group. (1999) (1)
- Synthesis of Highly Functionalized Isoxazoles via Base-Promoted Cyclocondensation of Stable Nitrile Oxides with Active Methylene Compounds (2007) (1)
- ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(P-TERT-BUTYLPHENYLTHIO)CYCLOHEXAN-1-ONE (1982) (0)
- C‐Glycosyl Juglone in Angucycline Synthesis: Total Synthesis of Galtamycinone, Common Aglycon of C‐Glycosyl Naphthacenequinone‐Type Angucyclines. (1998) (0)
- Dioxanone‐Fused Dienes Enable Highly endo‐Selective Intramolecular Diels—Alder Reactions. (2015) (0)
- Synthesis and Stereochemical Assignment of Angucycline Antibiotic, PD‐116740. (2008) (0)
- A process for preparing flavonoid (2001) (0)
- Silicon-Directed Regioselective [2 + 2] Cycloaddition of α-Alkoxybenzyne and Ketene Silyl Acetals. (2000) (0)
- PB163 Stereocontrolled Total Synthesis of Mycinamicin IV (1988) (0)
- A method for producing a flavanderivats (2007) (0)
- Cp2ZrCl2-AgClO4: Efficient Promoter for the Friedel-Crafts Approach to C-Aryl Glycosides. (1989) (0)
- Highly Selective Acyclic Stereocontrol Based on 1,2-Rearrangement (1988) (0)
- Silicon-Directed Stereoselective Synthesis of 2-Vinyl-1,3-diols. Stereo-Divergence with and without the Silyl Group Related to the Synthesis of Avenaciolide and Isoavenaciolide. (1988) (0)
- Single-Step Synthesis of Cyclooctadienone Derivatives by Reaction of Alkenylcyclobutenones with Alkenyllithiums: Enhanced Reactivity of 8π Cyclization by Acetylating the Intermediary Lithium Tetraenolate. (2003) (0)
- Dichlorobis(cyclopentadienyl)hafnium–Silver(I) Salts (2001) (0)
- Molecular Sieve (MS 4A) Promoted Cyclocondensation of Hindered, Aromatic Nitrile Oxides and Cyclic Diketones under Mild Conditions. (2004) (0)
- Thiolate-mediated reductive cyclization: asymmetric total synthesis of (+)-engelharquinone (2019) (0)
- trans-1,3-Bis(diphenylphosphinoyl)cyclohexane. (1992) (0)
- Synthesis of Antibiotic TAN-1085 (2010) (0)
- New Approach to C-Aryl Glycosides Starting from Phenol and Glycosyl Fluoride. Lewis Acid-Catalyzed Rearrangement of O-Glycoside to C-Glycoside. (1989) (0)
- P-273 Synthetic Study of the Pluramycins (2006) (0)
- Ring Expansion of Cyclopropylbenzocyclobutenes En Route to Benzocycloheptenes. (2012) (0)
- ASYMMETRIC PINACOL-TYPE REARRANGEMENT OF α-HYDROXYMETHANESULFONATES PROMOTED BY TRIETHYLALUMINUM. PREPARATION OF OPTICALLY PURE α-ARYL AND α-VINYL KETONES (1984) (0)
- Lactols in Stereoselection. Part 2. Stereoselective Synthesis of Disubstituted Cyclic Ethers. (1988) (0)
- CCDC 1052978: Experimental Crystal Structure Determination (2016) (0)
- 4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE. A NEW AND USEFUL BUILDING BLOCK FOR THE SYNTHESES OF L-SUGARS (1982) (0)
- Isoxazole→Benzisoxazole Rearrangement Promoted Cascade Reactions Affording Stereodefined Polycycles. (2003) (0)
- Isochroman-3-ones via Site-Selective Ring Opening of Benzocyclobutenones Promoted by Lithium Tetramethylpiperidide and Reaction with Aromatic Aldehydes. (1998) (0)
- Stereochemical Anomaly in the Thermal Conversion of 7,8‐Dioxy‐7‐alkenylbenzocyclobutenes to Dihydronaphthalenes. (2002) (0)
- Two‐Directional Anellation: Dual Benzyne Cycloadditions Starting from Bis(sulfonyloxy)diiodobenzene. (2007) (0)
- Lewis Acid-Promoted Reaction of Secondary Phosphines with Carbonyl Compounds: Remarkable Effect of Niobium(V) Chloride in Promoting an Intramolecular Oxidation-Reduction Process. (1992) (0)
- Efficient Synthetic Route to Ravidosamine Derivatives (2005) (0)
- Cationic Zirconocene- or Hafnocene-Based Lewis Acids in Organic Synthesis: Glycoside—Flavonoid Analogy. (2004) (0)
- Reaction of 1-Iodoalkynes with Allylzirconiums: Generation of Alkylidene Carbenoid via Allylzirconation. (1999) (0)
- A Novel Method for the Synthesis of 2-Deoxydisaccharide by Stereoselective Cyclization of the Acyclic Precursor. (1982) (0)
- Synthetic Strategies and Tactics for Catechin and Related Polyphenols (2014) (0)
- Dichlorobis(cyclopentadienyl)hafnium (2008) (0)
- Synthetic Study on Acremoxanthone A, Part 2: Model Study on the EFG Xanthone Moiety through a Nitrile Oxide Cycloaddition–SNAr Sequence (2020) (0)
- Synthesis of Functionalized Cyclobutene Derivatives via Selective SN2′ Reaction of Dichlorocyclobutenes. (2010) (0)
- C(2)-Stereocontrol of δ-Lactones via Acid-Catalyzed Cyclization of Ketene Dithioacetal having an Internal Hydroxyl Group. (1986) (0)
- Dodecamethoxy- and Hexaoxotricyclo-butabenzene (2006) (0)
- Additions and Corrections. Epoxy Silyl Ether Rearrangements: A New, Stereoselective Approach to the Synthesis of β-Hydroxy Carbonyl Compounds (1986) (0)
- Cobalt Complexation Makes 2‐(1‐Alkynyl)propenes Good Ene Donors in Carbonyl‐Ene Reaction. (1996) (0)
- Highly Stereoselective Approach to Chiral Building Block Possessing Three Contiguous Asymmetric Centers. Three Continuous Asymmetric Centers. Preparation of Four Possible Diastereomers of β,β′-Di-methyl-bis-homoallylic Alcohol Derivat (1985) (0)
- Synthesis of Functionalized Biaryl Compounds via Ring Expansion of Alkenylcyclobutenones. (2003) (0)
- (2 + 2) Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to Benzocyclobutenones. (1995) (0)
- Two Isolable Conformers of Dihydropentahelicenediol Derivatives: Stereochemical Property and Its Utility for Asymmetric Reactions. (2007) (0)
- Unusual Regioselectivity in the Reductive Coupling of Alkynes and Allenes by Hydrozirconation and Zinca‐Claisen Rearrangement. (1998) (0)
- Concise Total Synthesis and Structure Assignment of TAN‐1085. (2004) (0)
- Total Synthesis and Structure Revision of Deacetylravidomycin M. (2011) (0)
- Total Synthesis of Parameritannin A2, a Branched Epicatechin Tetramer with Two Double Linkages (2022) (0)
- Lactols in Stereoselection. Part 1. Highly Selective 1,4- and 1,5-Asymmetric Induction. (1988) (0)
- ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF ALKYLLITHIUM AND DIALKYLMAGNESIUM TO ALDEHYDES BY USING (2S,2′S)-2-HYDROXYMETHYL-1-((1-ALKYLPYRROLIDIN-2-YL)METHYL)PYRROLIDINES AS CHIRAL LIGANDS (1979) (0)
- anti-Selective Vinylogous Aldol Reaction by Silylated Alkyldioxinone Dienolate. (2011) (0)
- Conformational Effects in Organoaluminum-Promoted Pinacol-Type Rearrangement. (1986) (0)
- Revival and Last Spurt of My Research Career (2020) (0)
- Catalytic Version of Epoxy Silyl Ether Rearrangements. (1988) (0)
- THE STEREOSELECTIVE SYNTHESIS OF 2,3‐CIS‐DIHYDROXY‐Γ‐BUTYROLACTONES BY THE OXIDATION OF Γ‐BUTENOLIDES WITH POTASSIUM PERMANGANATE‐CROWN ETHER (1983) (0)
- CCDC 812001: Experimental Crystal Structure Determination (2011) (0)
- Proanthocyanidin Oligomers with Doubly Linked (A‐Type) Interflavan Connectivity (2021) (0)
- Recent Progress in O-Glycoside Synthesis. Methodological Aspects (1992) (0)
- Diethyl[dimethyl(phenyl)silyl]aluminum (2001) (0)
- Aldehyde–Ketone Benzoin Cyclizations (2012) (0)
- Regioselectivity of MAO‐Catalyzed Allylmetalation of Conjugated Enynes with Allylzirconiums. (1999) (0)
- peri‐Selectivity in Thermolysis of Acyloxybenzocyclobutenes Possessing α,β‐Unsaturated Carbonyl Group: Synthesis of 2‐Benzoxocin Derivatives. (2006) (0)
- Base‐Promoted Ring Expansion of 2‐Alkoxy‐2‐vinylbenzocyclobutenol into Substituted Naphthalene Derivatives. (2010) (0)
- Mukaiyama Aldol Reaction of Ester Acceptors: Organoaluminums Catalyze Nucleophilic Addition of Ketene Silyl Acetals. (2007) (0)
- On the Use of Epoxy Alcohol-Aldol Rearrangement for Stereoselective Construction of Quaternary Carbon Centers. (1988) (0)
- Regioselective Alkylzirconation of Internal Alkynes. (2001) (0)
- Applications of Benzynes in Natural Product Synthesis (2021) (0)
- Stereoselective Construction of Three- and Four-Contiguous Asymmetric Centers: Novel Possibility by Alkylative Rearrangement of Epoxy Silyl Ethers. (1991) (0)
- Stereocontrolled First Total Synthesis of Mycinolide IV (I). (1987) (0)
- New and Highly E‐Selective Synthesis of Terminal 1,3‐Diene via Three‐ Carbon Elongation of Aldehyde. (1993) (0)
- ASYMMETRIC ADDITION OF ACETYLIDE TO ALIPHATIC ALDEHYDES. PREPARATION OF OPTICALLY ACTIVE 5-OCTYL-2(5H)-FURANONE (1980) (0)
- ENANTIO- AND DIASTEREO-CONTROLLED SYNTHESIS OF (+)- AND (-)-ELDANOLIDE BASED ON ASYMMETRIC PINACOL-TYPE REARRANGEMENT (1985) (0)
- P-245 Axially Chiral Styrene : Key for the Asymmetric Total Synthesis of TAN-1085 (2006) (0)
- Total Synthesis and Structure Assignment of Saptomycin H. (2022) (0)
- (E)-Stereoselective Synthesis of Vinylglycines from (R)-Serine via Organocopper-BF3 and Related Reagents. (1995) (0)
- Ring Expansion Approach to Azaspiro[4.5]decane Skeletons via Electrophilic Activation of Benzocyclobutenols Bearing Pyridyl Group. (2011) (0)
- Total Synthesis of Carthamin, a Traditional Natural Red Pigment (2019) (0)
- First Total Synthesis of BE-12406 A. (1994) (0)
- Frontispiece: Photoredox Reactions of Quinones (2018) (0)
- Reversible Redox Behavior of Quinone-Based Molecule with Activated Carbon Slurry Electrode (2020) (0)
- Synthesis of (+)-Macrocidin A (2010) (0)
- Total Synthesis of the Furaquinocins. (1999) (0)
- Asymmetric Synthesis of Chiral Synthons Bearing Alkynyl Group via Organoaluminum-Promoted Pinacol-Type Rearrangement. (1986) (0)
- Synthesis of (+)-11-Hydroxyerythratidine (2009) (0)
- Regioselective Approach to Multisubstituted Benzenes. (2012) (0)
- Implication and Improvement of Stereoselective Methylenation of a Chiral Aldehyde Related to Total Synthesis of the Furaquinocins. (1997) (0)
- Stereoselective Synthesis of C(1)-C(9) and C(11)-C(17) Fragments of Protomycinolide IV Based on Asymmetric Pinacol-Type Rearrangement. (1985) (0)
- Concise Synthesis of ()-?-Indomycinone (2007) (0)
- MAO-Catalyzed Allylzirconation of 1-Alkynes. (1997) (0)
- 4-O-Benzyl-2,3-O-isopropylidene-L-threose: A Useful Building Block for Stereoselective Synthesis of Monosaccharides. (1990) (0)
- Synthetic Strategy toward Dearomatized Polycyclic Polyketide Natural Products (2019) (0)
- Arene Substitution via Addition—Elimination (2003) (0)
- Procedure for One-pot Conversion of Azides to N-Mono-methylamines (2001) (0)
- Stereospecificity in (2 + 2) Cycloaddition of Benzyne and Ketene Silyl Acetal. (1995) (0)
- THE ENANTIOSELECTIVE MICHAEL ADDITION OF THIOLS TO CYCLOALKENONES BY USING (2S,4S)‐2‐(ANILINOMETHYL)‐1‐ETHYL‐4‐HYDROXYPYRROLIDINE AS CHIRAL CATALYST (1981) (0)
- Synthetic Study on Carthamin, Part 4. Improved Synthesis of a C-Glycosyl Quinochalcone by Installation of a Side Chain through Regioselective De-O-methylation and Acyl Rearrangement (2021) (0)
- Synthesis of 2-Vinyl-1,3-diols via Highly Stereoselective Reduction of 2-Vinyl Aldols Using Trimethylsilyl Stereo-Directing Group. (1987) (0)
- Synthetic Study of Aquayamycin. Part 2. Synthesis of the AB Ring Fragment. (2001) (0)
- Hydrozirconation of Allenyl Sulfide for Generating γ-Thio- Substituted Allylzirconium Species and Its Reaction with Carbonyl Compounds. (2010) (0)
- Diethyl(tributylstannyl)aluminum (2001) (0)
- Hafnium-Centered Lewis Acids in Organic Chemistry (2003) (0)
- De novo synthesis of dimerization-ready flavan unit via intramolecular Pummerer/Friedel-Crafts cascade. (2022) (0)
- P-281 A Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization and Its Application to Natural Product Synthesis (2006) (0)
- General and Convenient Approach to Flavan‐3‐ols: Stereoselective Synthesis of (‐)‐Gallocatechin. (2007) (0)
- Titelbild: Integrated Synthetic Strategy for Higher Catechin Oligomers (Angew. Chem. 21/2011) (2011) (0)
- Convenient Procedure for Selective Generation of Allylzirconocene Chlorides via Hydrozirconation of Allenes. (2010) (0)
- Asymmetric Intramolecular Crossed Aldehyde-Ketone Benzoin Cyclization (2006) (0)
- The Flavan—Isoflavan Rearrangement: Bioinspired Synthetic Access to Isoflavonoids via 1,2-Shift—alkylation Sequence. (2015) (0)
- Alkylzirconation of Alkynes Catalyzed by Triphenylcarbenium Tetrakis(pentafluorophenyl)borate. (2000) (0)
- Facile and Highly Enantioselective Synthesis of Axially Chiral Biaryls by Enzymatic Desymmetrization. (2002) (0)
- Preparation of Enaminones by Two-Carbon Homologation of Amides with Lithium (Triphenylsilyl)acetylide. (1988) (0)
- Isoxazole‐Assisted Direct Substitution of the Hydroxy Group in α‐Ketols: Introduction of Angular Substituents in a Polycyclic System. (2009) (0)
- Tris(trimethylsilyl)aluminum (2001) (0)
- Glycosylation Study on Pradimicin—Benanomicin Antibiotics. (2000) (0)
- Facile One-Pot Synthesis of Resorcinol Bis-C-Glycosides Possessing Two Identical Sugar Moieties Facile One-Pot Synthesis of Resorcinol Bis-C-Glycosides (2006) (0)
- Expeditious Modular Assembly of Multisubstituted Cyclohexanes via Dioxanone—Dienes. (2012) (0)
- Pinacol Rearrangement for Constructing Asymmetric Centers Adjacent to Heterocycles. (2002) (0)
- Synthesis of Benzocyclooctene Derivatives via Thermal Ring Expansion of Dienylbenzocyclobutenes. (2002) (0)
- Siloxy(trialkoxy)ethene Undergoes Regioselective [2 + 2] Cycloaddition to Ynones and Ynoates en route to Functionalized Cyclobutenediones. (2010) (0)
- Lactols in Stereoselection. Part 3. Highly anti-Cram Selective 1,2-Asymmetric Induction. (1989) (0)
- Synthetic Study on Lactonamycins, Part 2: Stereoselective Access to ABCD-Ring System (2020) (0)
- P-462 Synthetic Approach to Polyketide-Derived Polycyclic Natural Products with Stereogenic Center at Angular Position (2006) (0)
- Stereo-Divergent Asymmetric Total Synthesis of Avenaciolide and Isovenaciolide. Complete Reversal of Stereoselectivity in Reduction of 2-Vinyl Aldols with/without Trimethylsilyl Directing Group. (1987) (0)
- New Glycosidation Reaction. Part 2. Preparation of 1-Fluoro-D-Desosamine Derivative (V) and Its Efficient Glycosidation by the Use of Cp2HfCl2-AgClO4 as the Activator. (1988) (0)
- Enantiopure Acetals of α-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile. (2010) (0)
- P-559 Convergent Approach to Oligocatechins based on the Flavonoid-Sugar Analogy (2006) (0)
- Stereocontrolled Asymmetric Total Synthesis of Protomycinolide IV (XIII). (1986) (0)
- A Novel Approach to Erythrinan Alkaloids by Utilizing Substituted Biphenyl as Building Block. (2004) (0)
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