Keith Usherwood Ingold
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Canadian research chemist
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(Suggest an Edit or Addition)According to Wikipedia, Keith Usherwood Ingold was a British-Canadian chemist. Life and career Keith Usherwood Ingold was born to Sir Christopher Ingold and Dr. Hilda Usherwood, and studied for a BSc in Chemistry at the University of London, completing his degree in 1949. He continued his higher education with a PhD in chemistry at Oxford University, which he completed in 1951. Soon after graduation he moved to Canada to begin work with the National Research Council, followed by two years of post-doctoral research at the University of British Columbia. He returned to work for the NRC in 1955 as a research officer, followed by a promotion to head of the Free Radical Chemistry Section. He was awarded the 1968 Petroleum Chemistry Award, the 1988 Linus Pauling Award, and both the Davy Medal and Royal Medal of the Royal Society, the latter for "elucidating the mechanism of reactions involving free radicals". In 1995 he was made an officer of the Order of Canada. He has received honorary degrees from the universities of Guelph, Mount Allison, St Andrews, Carleton, McMaster and Dalhousie.
Keith Usherwood Ingold's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- beta-Carotene: an unusual type of lipid antioxidant. (1984) (2101)
- Autoxidation of biological molecules. 1. Antioxidant activity of vitamin E and related chain-breaking phenolic antioxidants in vitro (1981) (992)
- Vitamin E: application of the principles of physical organic chemistry to the exploration of its structure and function (1986) (969)
- The relative contributions of vitamin E, urate, ascorbate and proteins to the total peroxyl radical-trapping antioxidant activity of human blood plasma. (1987) (886)
- Is vitamin E the only lipid-soluble, chain-breaking antioxidant in human blood plasma and erythrocyte membranes? (1983) (769)
- Autoxidation of biological molecules. 4. Maximizing the antioxidant activity of phenols (1985) (702)
- Quantitative measurement of the total, peroxyl radical‐trapping antioxidant capability of human blood plasma by controlled peroxidation (1985) (626)
- Vitamin E in human low-density lipoprotein. When and how this antioxidant becomes a pro-oxidant. (1992) (496)
- Free-radical clocks (1980) (486)
- Solvent effects on the rates and mechanisms of reaction of phenols with free radicals. (2007) (486)
- Vitamin E as an in Vitro and in Vivo Antioxidant a (1989) (473)
- Antioxidant and co-antioxidant activity of vitamin C. The effect of vitamin C, either alone or in the presence of vitamin E or a water-soluble vitamin E analogue, upon the peroxidation of aqueous multilamellar phospholipid liposomes. (1985) (400)
- Human plasma and tissue alpha-tocopherol concentrations in response to supplementation with deuterated natural and synthetic vitamin E. (1998) (382)
- Abnormal solvent effects on hydrogen atom abstractions. 1. The reactions of phenols with 2,2-diphenyl-1-picrylhydrazyl (dpph*) in alcohols. (2003) (375)
- Rate constants for the reactions of free radicals with oxygen in solution (1983) (364)
- Abnormal solvent effects on hydrogen atom abstraction. 2. Resolution of the curcumin antioxidant controversy. The role of sequential proton loss electron transfer. (2004) (346)
- Persistent carbon-centered radicals (1976) (329)
- Advances in radical-trapping antioxidant chemistry in the 21st century: a kinetics and mechanisms perspective. (2014) (319)
- Inhibition of the Autoxidation of Organic Substances in the Liquid Phase. (1961) (310)
- Autoxidation of lipids and antioxidation by alpha-tocopherol and ubiquinol in homogeneous solution and in aqueous dispersions of lipids: unrecognized consequences of lipid particle size as exemplified by oxidation of human low density lipoprotein. (1993) (294)
- FIRST PROOF THAT VITAMIN E IS MAJOR LIPID-SOLUBLE, CHAIN-BREAKING ANTIOXIDANT IN HUMAN BLOOD PLASMA (1982) (282)
- Kinetics of nitroxide radical trapping. 1. Solvent effects (1992) (260)
- Vitamin E remains the major lipid-soluble, chain-breaking antioxidant in human plasma even in individuals suffering severe vitamin E deficiency. (1987) (243)
- Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydride (1981) (239)
- Impaired ability of patients with familial isolated vitamin E deficiency to incorporate alpha-tocopherol into lipoproteins secreted by the liver. (1990) (234)
- Self-reaction of sec-butylperoxy radicals. Confirmation of the Russell mechanism (1968) (231)
- Absolute rate constants for hydrocarbon autoxidation. VI. Alkyl aromatic and olefinic hydrocarbons (1967) (214)
- RRR- and SRR-alpha-tocopherols are secreted without discrimination in human chylomicrons, but RRR-alpha-tocopherol is preferentially secreted in very low density lipoproteins. (1990) (214)
- Kinetics of nitroxide radical trapping. 2. Structural effects (1992) (213)
- Absolute Rate Constants for Hydrocarbon Autoxidation. XXI. Activation Energies for Propagation and the Correlation of Propagation Rate Constants with Carbon–Hydrogen Bond Strengths (1972) (210)
- Autoxidation of biological molecules. 2. Autoxidation of a model membrane. Comparison of the autoxidation of egg lecithin phosphatidylcholine in water and in chlorobenzene (1981) (207)
- Discrimination between forms of vitamin E by humans with and without genetic abnormalities of lipoprotein metabolism. (1992) (201)
- Theoretical Calculation of Substituent Effects on the O−H Bond Strength of Phenolic Antioxidants Related to Vitamin E (1997) (195)
- Autoxidation of micelles and model membranes. Quantitative kinetic measurements can be made by using either water-soluble or lipid-soluble initiators with water-soluble or lipid-soluble chain-breaking antioxidants (1984) (189)
- Solvent effects on the competitive .beta.-scission and hydrogen atom abstraction reactions of the cumyloxyl radical. Resolution of a long-standing problem (1993) (187)
- Absolute rate constants for the reactions of some carbon-centered radicals with 2,2,6,6-tetramethyl-1-piperidinoxyl (1988) (183)
- Studies on lipid peroxidation in normal and tumour tissues. The Novikoff rat liver tumour. (1986) (178)
- The antioxidant efficiency of vitamin C is concentration-dependent. (1986) (168)
- Abnormal solvent effects on hydrogen atom abstraction. 3. Novel kinetics in sequential proton loss electron transfer chemistry. (2005) (159)
- Critical re-evaluation of the O-H bond dissociation enthalpy in phenol. (2005) (157)
- The Unexpected Role of Vitamin E (α-Tocopherol) in the Peroxidation of Human Low-Density Lipoprotein1 (1999) (153)
- Kinetic Solvent Effects on Hydroxylic Hydrogen Atom Abstractions Are Independent of the Nature of the Abstracting Radical. Two Extreme Tests Using Vitamin E and Phenol (1995) (152)
- Calibration of a new horologery of fast radical clocks. Ring-opening rates for ring- and .alpha.-alkyl-substituted cyclopropylcarbinyl radicals and for the bicyclo[2.1.0]pent-2-yl radical (1991) (151)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl (1976) (143)
- Kinetics and rate constants for the reduction of alkyl halides by organotin hydrides (1968) (143)
- Mechanism of inhibition of lipid peroxidation by gamma-terpinene, an unusual and potentially useful hydrocarbon antioxidant. (2003) (143)
- Vitamin E as an antioxidant in vitro and in vivo. (1983) (143)
- A Radical Account of “Oxygenated Fenton Chemistry” 1 (1998) (136)
- Reaction of phenols with the 2,2-diphenyl-1-picrylhydrazyl radical. Kinetics and DFT calculations applied to determine ArO-H bond dissociation enthalpies and reaction mechanism. (2008) (136)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 36. Stereoelectronic effects in hydrogen atom abstraction from ethers (1981) (135)
- The Titanium(IV)‐Catalyzed Epoxidation of Alkenes by tert‐Alkyl Hydroperoxides (1996) (132)
- Naphthalene diols: a new class of antioxidants intramolecular hydrogen bonding in catechols, naphthalene diols, and their aryloxyl radicals. (2002) (131)
- On the antioxidant activity of melatonin. (1999) (129)
- Garlic: source of the ultimate antioxidants--sulfenic acids. (2009) (128)
- The Complex Chemistry of Peroxynitrite Decomposition: New Insights1 (1998) (123)
- A putative monooxygenase mimic which functions via well-disguised free radical chemistry (1997) (117)
- Dramatic Solvent Effects on the Absolute Rate Constants for Abstraction of the Hydroxylic Hydrogen Atom from tert-Butyl Hydroperoxide and Phenol by the Cumyloxyl Radical. The Role of Hydrogen Bonding (1995) (114)
- Spectroscopic and kinetic characteristics of aroyloxyl radicals. 2. Benzoyloxyl and ring-substituted aroyloxyl radicals (1988) (113)
- Antioxidant activity of vitamin E and related phenols. Importance of stereoelectronic factors (1980) (112)
- Lipid Peroxidation and Lipid Antioxidants in Normal and Tumor Cells (1984) (112)
- Myocardial free-radical injury after cardioplegia. (1989) (111)
- Absolute rate constants for reaction of phenyl, 2,2-dimethylvinyl, cyclopropyl, and neopentyl radicals with tri-n-butylstannane. Comparison of the radical trapping abilities of tri-n-butylstannane and -germane (1985) (108)
- Carbon tetrachloride toxicity as a model for studying free-radical mediated liver injury. (1985) (107)
- The Surprisingly High Reactivity of Phenoxyl Radicals (1994) (107)
- The unusual reaction of semiquinone radicals with molecular oxygen. (2008) (104)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. III. SELF-REACTIONS OF DIALKYL NITROXIDE RADICALS. (1971) (100)
- A Mechanistic Probe for Oxygen Activation by Metal Complexes and Hydroperoxides and Its Application to Alkane Functionalization by [FeIIICl2tris(2-pyridinylmethyl)amine]+ BF4- (1995) (99)
- Estimation of the location of natural α-tocopherol in lipid bilayers by 13C-NMR spectroscopy☆ (1985) (99)
- Myocardial salvage with trolox and ascorbic acid for an acute evolving infarction. (1989) (98)
- THE INHIBITED AUTOXIDATION OF STYRENE: PART II. THE RELATIVE INHIBITING EFFICIENCIES OF META- AND PARA-SUBSTITUTED PHENOLS (1963) (98)
- Nascent VLDL from liver perfusions of cynomolgus monkeys are preferentially enriched in RRR- compared with SRR-alpha-tocopherol: studies using deuterated tocopherols. (1990) (97)
- Antioxidant activity of phenols related to vitamin E. Are there chain-breaking antioxidants better than .alpha.-tocopherol? (1983) (97)
- New insights into the mechanism of amine/nitroxide cycling during the hindered amine light stabilizer inhibited oxidative degradation of polymers. (2012) (96)
- A radical clock investigation of microsomal cytochrome P-450 hydroxylation of hydrocarbons. Rate of oxygen rebound (1991) (96)
- Spectroscopic and kinetic characteristics of aroyloxyl radicals. 1. The 4-methoxybenzoyloxyl radical (1988) (95)
- Biological Antioxidants [and Discussion] (1985) (93)
- A mild, rapid, and efficient method of lipid extraction for use in determining vitamin E/lipid ratios (2006) (91)
- Absolute rate constants for hydrocarbon autoxidation. V. The hydroperoxy radical in chain propagation and termination (1967) (91)
- Absolute Rate Constants for Some Reactions of Perfluoro-n-alkyl Radicals in Solution (1993) (90)
- Bond strengths of toluenes, anilines, and phenols: to hammett or not. (2004) (90)
- Cage-Escape of Geminate Radical Pairs Can Produce Peroxynitrate from Peroxynitrite under a Wide Variety of Experimental Conditions1 (1999) (88)
- Biokinetics of and discrimination between dietaryRRR- andSRR-α-tocopherols in the male rat (1987) (88)
- Biokinetics of and discrimination between dietary RRR- and SRR-alpha-tocopherols in the male rat. (1987) (87)
- Allylcarbinyl-cyclopropylcarbinyl rearrangement (1980) (87)
- On the mechanism of the nitric oxide synthase-catalyzed conversion of N omega-hydroxyl-L-arginine to citrulline and nitric oxide. (1994) (87)
- Calorimetric and equilibrium studies on some stable nitroxide and iminoxy radicals. Approximate oxygen-hydrogen bond dissociation energies in hydroxylamines and oximes (1973) (87)
- The inhibited autoxidation of styrene. Part VII. Inhibition by nitroxides and hydroxylamines (1967) (87)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 34. RATE CONSTANTS FOR SPIN TRAPPING. 2. SECONDARY ALKYL RADICALS (1978) (86)
- Substituent effects on the bond dissociation enthalpies of aromatic amines. (2002) (83)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 26. Quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals (1976) (80)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 35. The search for a dialkylaminyl rearrangement. Ring opening of N-cyclobutyl-N-n-propylaminyl (1980) (80)
- Effects of Solvation on the Enthalpies of Reaction of tert-Butoxyl Radicals with Phenol and on the Calculated O-H Bond Strength in Phenol (1995) (80)
- The role of hydrogen bonding on the h-atom-donating abilities of catechols and naphthalene diols and on a previously overlooked aspect of their infrared spectra. (2002) (78)
- Solvent Effects on the Antioxidant Activity of Vitamin E(1). (1999) (77)
- Kinetics of the reaction of a secondary alkyl radical with tri-n-butylgermanium hydride and calibration of a secondary alkyl radical clock reaction (1987) (77)
- Biokinetics of dietaryRRR-α-tocopherol in the male guinea pig at three dietary levels of vitamin C and two levels of vitamin E. Evidence that vitamin C does not “spare” vitamin Ein vivo (1990) (76)
- Oxygen activation by metal complexes and alkyl hydroperoxides. Applications of mechanistic probes to explore the role of alkoxyl radicals in alkane functionalization (1997) (76)
- Free-Radical Rearrangements (1980) (75)
- Absolute rate constants for the addition of triethylsilyl radicals to various unsaturated compounds (1983) (75)
- Kinetic Solvent Effects on Hydrogen Atom Abstraction from Phenol, Aniline, and Diphenylamine. The Importance of Hydrogen Bonding on Their Radical-Trapping (Antioxidant) Activities1 (1996) (75)
- Lipid peroxidation in regenerating rat liver (1986) (74)
- THE INHIBITED AUTOXIDATION OF STYRENE: PART III. THE RELATIVE INHIBITING EFFICIENCIES OF ORTHO-ALKYL PHENOLS (1963) (70)
- The frequently overlooked importance of solvent in free radical syntheses. (2011) (70)
- Biokinetics of dietary RRR-alpha-tocopherol in the male guinea pig at three dietary levels of vitamin C and two levels of vitamin E. Evidence that vitamin C does not "spare" vitamin E in vivo. (1990) (69)
- Kinetic applications of electron paramagnetic resonance spectroscopy. V. Self-reactions of some group IV radicals (1972) (69)
- Cytochrome P450 hydroxylation of hydrocarbons: variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probes. (1993) (69)
- THE INHIBITED AUTOXIDATION OF STYRENE: PART I.THE DEUTERIUM ISOTOPE EFFECT FOR INHIBITION BY 2,6-DI-tert-BUTYL-4-METHYLPHENOL (1962) (68)
- Application of Photoacoustic Calorimetry to the Measurement of the O−H Bond Strength in Vitamin E (α- and δ-Tocopherol) and Related Phenolic Antioxidants1 (1996) (67)
- Vitamin E for coronary bypass operations. A prospective, double-blind, randomized trial. (1994) (66)
- Absolute Rate Constant for the Reaction of Aryl Radicals with Tri-n-butyltin Hydride(1). (1996) (66)
- Nitric Oxide Cheletropic Traps (NOCTs) with Improved Thermal Stability and Water Solubility (1994) (65)
- Laser Flash Photolysis Studies on the First Superoxide Thermal Source. First Direct Measurements of the Rates of Solvent-Assisted 1,2-Hydrogen Atom Shifts and a Proposed New Mechanism for This Unusual Rearrangement1 (2000) (65)
- ABSOLUTE RATE CONSTANTS FOR THE REACTIONS OF TRIBUTYLGERMYL AND TRIBUTYLSTANNYL RADICALS WITH CARBONYL COMPOUNDS, OTHER UNSATURATED MOLECULES, AND ORGANIC HALIDES (1984) (65)
- Kinetics of the oxidation of quercetin by 2,2-diphenyl-1-picrylhydrazyl (dpph•). (2011) (64)
- Kinetic applications of electron paramagnetic resonance spectroscopy. I. Self-reactions of diethyl nitroxide radicals (1971) (63)
- Kinetic applications or electron paramagnetic resonance spectroscopy. X. Reactions of some alkylamino radicals in solution (1973) (63)
- Free Radicals by Mass Spectrometry. V. The Ionization Potentials of Methyl, Allyl, and Benzyl Radicals (1954) (63)
- Absolute rate constants for hydrocarbon autoxidation. XIII. Aldehydes: photo-oxidation, co-oxidation, and inhibition (1969) (62)
- Absolute kinetics of hydrogen abstraction from .alpha.-tocopherol by several reactive species including an alkyl radical (1992) (62)
- Oxygen-carbon bond dissociation enthalpies of benzyl phenyl ethers and anisoles. An example of temperature dependent substituent effects. (2001) (62)
- Absolute rate constants for the reaction of triethylsilyl radicals with organic halides (1982) (62)
- Absolute rate constants for hydrocarbon oxidation. VIII. The reactions of cumylperoxy radicals (1968) (62)
- Antioxidant Activities of Vitamin E Analogues in Water and a Kamlet−Taft β-Value for Water1 (1996) (61)
- The Unexpected Role of Vitamin E (α-Tocopherol) in the Peroxidation of Human Low-Density Lipoprotein (1999) (60)
- Formation, decay, and spectral characterization of some alkyl- and aryl-substituted carbon-, silicon-, germanium-, and tin-centered radicals (1983) (59)
- A theoretical study of the iminoxyl/oxime self-exchange reaction. A five-center, cyclic proton-coupled electron transfer. (2005) (58)
- Kinetic and Spectroscopic Studies on Acyl Radicals in Solution by Time-Resolved Infrared Spectroscopy (1995) (58)
- KINETIC STUDY OF THE PHOTOCHLORINATION OF 2,3-DIMETHYLBUTANE AND OTHER ALKANES IN SOLUTION IN THE PRESENCE OF BENZENE. FIRST MEASUREMENTS OF THE ABSOLUTE RATE CONSTANTS FOR HYDROGEN ABSTRACTION BY THE “FREE” CHLORINE ATOM AND THE CHLO (1985) (57)
- RATE CONSTANTS FOR THE SELF-REACTIONS OF N- AND SEC-BUTYLPEROXY RADICALS AND CYCLOHEXYLPEROXY RADICALS. THE DEUTERIUM ISOTOPE EFFECT IN THE TERMINATION OF SECONDARY PEROXY RADICALS. (1968) (57)
- Metal Complexes as Antioxidants. I. The Reaction of Zinc Dialkyldithiophosphates and Related Compounds with Peroxy Radicals (1973) (56)
- Studies on lipid peroxidation in normal and tumour tissues. The Yoshida rat liver tumour. (1988) (55)
- Absolute rate constants for the decarbonylation of the phenylacetyl radical (1983) (54)
- Conformation and rotational barriers in sym-tetra-tert-butylethane and sym-tetra(trimethylsilyl)ethane (1977) (54)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 25. Radicals formed by spin trapping with di-tert-butyl thioketone (1976) (53)
- Antioxidant activity of 1-thio-.alpha.-tocopherol and related compounds. EPR, ENDOR, and UV-visible absorption spectra of some of the derived phenoxyl radicals (1988) (53)
- THE OXIDATION OF PHENOLS: III. THE STOICHIOMETRIES FOR THE OXIDATION OF SOME SUBSTITUTED PHENOLS WITH PEROXY RADICALS (1966) (53)
- Conformation of .beta.-substituted ethyl radicals (1974) (52)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION: I. STYRENE (1965) (51)
- Cytochrome P450-catalyzed hydroxylation of hydrocarbons: kinetic deuterium isotope effects for the hydroxylation of an ultrafast radical clock. (1994) (50)
- ELECTRONIC ABSORPTION SPECTRA OF SOME ALKOXYL RADICALS. AN EXPERIMENTAL AND THEORETICAL STUDY (1995) (49)
- Calibration of a fast benzylic radical clock reaction (1992) (49)
- Chiral effects on the carbon-13 resonances of .alpha.-tocopherol and related compounds. A novel illustration of Newman's "rule of six" (1989) (49)
- Lipid antioxidants and products of lipid peroxidation as potential tumour protective agents. (1983) (49)
- Configuration of the tert-butyl radical (1978) (49)
- Biological antioxidants. (1985) (48)
- Autoxidation of a model membrane. A comparison of the autoxidation of egg lecithin phosphatidylcholine in water and in chlorobenzene (1980) (48)
- Paradoxical Impact of Antioxidants on Post-Amadori Glycoxidation (2003) (48)
- First spectroscopic and absolute kinetic studies on (alkoxycarbonyl)oxyl radicals and an unsuccessful attempt to observe carbamoyloxyl radicals (1988) (48)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 32. Further studies of quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals (1978) (48)
- Electron paramagnetic resonance and the art of physical-organic chemistry (1980) (47)
- Tetramethyl‐Ortho‐quinodimethane, First Member of a Family of Custom‐Tailored Cheletropic Spin Traps for Nitric Oxide (1992) (47)
- Thermolyses of O-phenyl oxime ethers. A new source of iminyl radicals and a new source of aryloxyl radicals. (2004) (47)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XV. Iminyl radicals (1974) (47)
- Protonated nitroxide radicals (1973) (47)
- Acid Is Key to the Radical-Trapping Antioxidant Activity of Nitroxides. (2016) (47)
- Melatonin does not "directly scavenge hydrogen peroxide": demise of another myth. (2003) (47)
- A new vitamin E analogue more active than α‐tocopherol in the rat curative myopathy bioassay (1986) (47)
- Structure and dynamics of alpha-tocopherol in model membranes and in solution: a broad-line and high-resolution NMR study. (1988) (47)
- Studies on the hyperplasia ('regeneration') of the rat liver following partial hepatectomy. Changes in lipid peroxidation and general biochemical aspects. (1990) (47)
- Absolute rate constants for the reactions of tert-butoxyl radicals and some ketone triplets with silanes (1982) (47)
- Does β-Carotene Really Protect Vitamin E from Oxidation? (1997) (46)
- THE METAL-CATALYZED AUTOXIDATION OF TETRALIN: II. THE COBALT-CATALYZED AUTOXIDATION OF UNDILUTED TETRALIN AND OF TETRALIN IN CHLOROBENZENE (1963) (45)
- Why Quantum-Thermochemical Calculations Must Be Used with Caution to Indicate ‘a Promising Lead Antioxidant’ (2005) (45)
- Kinetic applications of electron paramagnetic resonance spectroscopy. VII. Self-reactions of iminoxy radicals (1972) (45)
- Kinetics of cyclopropyl radical reactions. 1. Absolute rate constants for some addition and abstraction reactions (1984) (45)
- Conformational studies by dynamic NMR. 7. Stereochemical processes in 2,3-dimethylbutane (1977) (45)
- Extraordinary Kinetic Behavior of the .alpha.-Tocopheroxyl (Vitamin E) Radical (1995) (44)
- Kinetics of the 1,2-migration of carbon-centered groups in 2-substituted 2,2-dimethylethyl radicals (1984) (44)
- Absolute rate constants for hydrocarbon oxidation. XI. The reactions of tertiary peroxy radicals (1968) (44)
- Electron Spin Resonance Spectra of Organic Oxy Radicals (1964) (43)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION: IV. TETRALIN, CYCLOHEXENE, DIPHENYLMETHANE, ETHYLBENZENE, AND ALLYLBENZENE (1966) (43)
- Influence of "remote" intramolecular hydrogen bonds on the stabilities of phenoxyl radicals and benzyl cations. (2010) (43)
- THE METAL-CATALYZED AUTOXIDATION OF TETRALIN: IV. THE EFFECT OF SOLVENT AND TEMPERATURE (1964) (43)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION. XVI. REACTIONS OF PEROXY RADICALS AT LOW TEMPERATURES (1969) (43)
- THE INFRARED FREQUENCIES AND INTENSITIES OF THE HYDROXYL BAND IN ORTHO-SUBSTITUTED PHENOLS (1961) (43)
- Quantitative studies on the peroxidation of human low-density lipoprotein initiated by superoxide and by charged and neutral alkylperoxyl radicals. (2001) (43)
- Invention of the First Azo Compound To Serve as a Superoxide Thermal Source under Physiological Conditions: Concept, Synthesis, and Chemical Properties1 (1997) (43)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 16, CYCLIZATION OF THE 5-HEXENYL RADICAL (1974) (42)
- Understanding Trends in C-H, N-H, and O-H Bond Dissociation Enthalpies (2000) (42)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XXIII. Cyanomethyl radicals (1976) (42)
- Intramolecular and intermolecular hydrogen bond formation by some ortho-substituted phenols: some surprising results from an experimental and theoretical investigation. (2009) (42)
- Kinetic application of electron paramagnetic resonance spectroscopy. IX. Preparation and properties of di-tert-butyliminoxy (1973) (42)
- Free radicals by mass spectrometry. Part II.—The thermal decomposition of ethylene oxide, propyline oxide, dimethyl ether, and dioxane (1953) (41)
- Kinetic applications of electron paramagnetic resonance spectroscopy. II. Self-reactions of N-alkyl nitroxides and N-phenyl nitroxide (1971) (41)
- The unusual and the unexpected in an old reaction. The photochlorination of alkanes with molecular chlorine in solution (1990) (41)
- Rate constants and Arrhenius parameters for the reaction of a primary alkyl radical with tributylgermanium hydride (1983) (41)
- Mechanisms of reaction of aminoxyl (nitroxide), iminoxyl, and imidoxyl radicals with alkenes and evidence that in the presence of lead tetraacetate, N-hydroxyphthalimide reacts with alkenes by both radical and nonradical mechanisms. (2005) (41)
- Absolute rate constants for hydrocarbon autoxidation. XVII. The oxidation of some cyclic ethers (1969) (40)
- THE OXIDATION OF PHENOLS: I. THE OXIDATION OF 2,6-DI-t-BUTYL-4-METHYLPHENOL, 2,6-DI-t-BUTYLPHENOL, AND 2,6-DIMETHYLPHENOL WITH PEROXY RADICALS (1966) (40)
- Absolute rate constants for some intermolecular and intramolecular reactions of .alpha.-, .beta.-, and .gamma.-silicon-substituted radicals (1988) (40)
- A novel procedure for generating both nitric oxide and superoxide in situ from chemical sources at any chosen mole ratio. First application: tyrosine oxidation and a comparison with preformed peroxynitrite. (2000) (40)
- THE INFRARED FREQUENCIES AND INTENSITIES OF THE HYDROXYL GROUP IN 2,6-DI-tert-BUTYL-4-SUBSTITUTED PHENOLS (1960) (39)
- THE INHIBITED AUTOXIDATION OF STYREN: PART IV. SOLVENT EFFECTS (1964) (39)
- First direct detection of transient organic free radicals in solution by time-resolved infrared spectroscopy. Kinetic studies on some acyl radicals (1991) (39)
- Ultraviolet/visible spectra of halogen molecule/arene and halogen atom/arene .pi.-molecular complexes (1989) (39)
- The structure of amidyl radicals. Evidence for the .pi.-electronic ground state and for twist about the acyl-nitrogen bond by electron paramagnetic resonance spectroscopy (1981) (39)
- Conformational studies by dynamic NMR. V. The stereodynamics of hindered aliphatic hydrazones (1976) (38)
- Inhibition of Autoxidation (1968) (38)
- Absolute rate constants for the addition of triethylsilyl radicals to the carbonyl group (1982) (38)
- Absolute rate constants for hydrocarbon autoxidation. XV. The induced decomposition of some t-hydroperoxides (1969) (38)
- THE METAL-CATALYZED AUTOXIDATION OF TETRALIN: I. INTRODUCTION. THE COBALT-CATALYZED AUTOXIDATION IN ACETIC ACID (1963) (38)
- Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase (1993) (37)
- The Bimolecular Self-reactions of Secondary Peroxy Radicals. Product Studies (1973) (37)
- O-H bond dissociation enthalpies in oximes: order restored. (2004) (36)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 30. REARRANGEMENT OF THE BENZOYLMETHYL RADICAL (1977) (36)
- The contrasting kinetics of peroxidation of vitamin E-containing phospholipid unilamellar vesicles and human low-density lipoprotein. (2002) (36)
- THE METAL-CATALYZED AUTOXIDATION OF TETRALIN III. CATALYSIS BY MANGANESE, COPPER, NICKEL, AND IRON, (1964) (36)
- Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation. (2016) (35)
- An improved procedure for the isolation of ghost membranes from human red blood cells (1981) (35)
- Mechanism of rearrangement of .beta.-acyloxyalkyl radicals (1984) (35)
- Pentamethyldisilyl radical: absolute rate constants for its formation and for some halogen abstraction and addition reactions (1986) (34)
- Kinetic solvent effects on proton and hydrogen atom transfers from phenols. Similarities and differences. (2006) (34)
- Vitamin E in vivo (1990) (34)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XIII. Di-tert-butylmethyl and related radicals (1973) (33)
- Bond strengths: the importance of hyperconjugation. (2006) (33)
- How should xanthine oxidase-generated superoxide yields be measured? (2000) (33)
- alpha-Tocopheryl quinone is converted into vitamin E in man. (1997) (32)
- Measurement of N-H Bond Strengths in Aromatic Amines by Photoacoustic Calorimetry(1). (1997) (32)
- Solvent Effects on the Reactivity and Free Spin Distribution of 2,2-Diphenyl-1-picrylhydrazyl Radicals(1). (1996) (32)
- Chemically induced dynamic electron polarization of the diethoxyphosphonyl radical: a case of mixed S-T0 and S-T− radical pair polarization (1985) (32)
- Application of deuterated alpha-tocopherols to the biokinetics and bioavailability of vitamin E. (1990) (32)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 38. Rearrangement of .beta.-(acyloxy)alkyl and .beta.-(benzoyloxy)alkyl radicals (1982) (31)
- Direct observation and chemistry of biradicals from photochemical decarbonylation of .alpha.-perphenylated cycloalkanones (1985) (31)
- Free Radicals by Mass Spectrometry. VI. The Bond Dissociation Energies of Some Methyl, Allyl, and Benzyl Compounds by Electron Impact (1954) (31)
- Absolute rate constants for some reactions of the triethylamine-boryl radical and the borane radical anion (2001) (31)
- EPR spectra of some .alpha.-tocopherol model compounds. Polar and conformational effects and their relation to antioxidant activities (1983) (31)
- Comparison of free α-tocopherol and α-tocopheryl acetate as sources of vitamin E in rats and humans (1988) (31)
- THE OXIDATION OF PHENOLS: II. THE OXIDATION OF 2,4-DI-t-BUTYLPHENOL WITH PEROXY RADICALS (1966) (30)
- Absolute rate constants for hydrocarbon autoxidation. XVIII. Oxidation of some acyclic ethers (1970) (30)
- INHIBITION OF OIL OXIDATION BY 2,6-DI-t-BUTYL-4-SUBSTITUTED PHENOLS (1960) (30)
- Strand cleavage of supercoiled DNA by water-soluble peroxyl radicals. The overlooked importance of peroxyl radical charge. (2000) (29)
- Color benzyloxyl and cumyloxyl orange and 4-methoxycumyloxyl blue. Unexpected discovery that arylcarbinyloxyl radicals have strong absorptions in the visible (1992) (29)
- New insight into solvent effects on the formal HOO. + HOO. reaction. (2005) (29)
- Oxidative Degradation of β-Carotene and β-Apo-8′-carotenal. (1993) (29)
- Studies on the spiro[2.5]octadienyl radical and the 2-phenylethyl rearrangement (1980) (29)
- Abstraction of the hydroxylic hydrogen of alcohols by alkoxy radicals (1974) (28)
- THE KINETICS OF THE INHIBITED AUTOXIDATION OF TETRALIN (1964) (28)
- Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals1. (1996) (28)
- Absorption and transport of deuterium-substituted 2R,4′R,8′R-α-tocopherol in human lipoproteins (1988) (28)
- Kinetics of cyclopropyl radical reactions. 2. Studies on the inversion of cyclopropyl and 1-methylcyclopropyl radicals and on the kinetics of some addition and abstraction reactions of 1-methylcyclopropyl and 1-methoxycyclopropyl radicals. (1986) (28)
- REACTIONS OF ALKOXY RADICALS: I. HYDROGEN ATOM ABSTRACTION FROM SUBSTITUTED TOLUENES (1966) (28)
- Anchimeric assistance in carbon-hydrogen bond homolysis. Reaction of tert-butoxyl radicals with tetraethyl Group IV compounds (1985) (28)
- 5-Endo Closure of the 2-Formylbenzoyl Radical (1994) (28)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION: II. DEUTERO STYRENES AND RING-SUBSTITUTED STYRENES (1965) (28)
- Absolute Rate Constants for the Reactions of Some Carbon-Centered Radicals with 2,2,6,6-Tetramethylpiperidine-N-oxyl. (1988) (28)
- First absolute rate constants for some hydrogen atom abstractions and addition reactions of an aroyloxyl radical: 4-methoxybenzoyloxyl (1987) (28)
- Structural interpretation of non-exponential hydrogen transfer in glassy methanol☆ (1985) (28)
- Cyclization of the 4-cyanobutyl radical (1979) (27)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 18, PERSISTENT VINYL, ALKYL, AND ALLYL RADICALS (1975) (27)
- THE INHIBITED AUTOXIDATION OF STYRENE: PART V. THE KINETICS AND DEUTERIUM ISOTOPE EFFECT FOR INHIBITION BY DIPHENYLAMINE, PHENYL-α-NAPHTHYLAMINE, AND PHENYL-β-NAPHTHYLAMINE (1966) (27)
- Electron spin resonance spectrum of oxygen-17 enriched tert-alkylperoxy radicals (1970) (27)
- Distinguishing between abstraction and addition as the first step in the reaction of a nitroxyl radical with cyclohexene. (2004) (27)
- Kinetics of the reduction of tert-butyl chloride and tert-butyl bromide by organotin hydrides (1968) (27)
- The ring-opening reactions of cyclobutylmethyl and cyclobutenylmethyl radicals (1981) (27)
- Free Radicals by Mass Spectrometry. IV. The Rate of Combination of Methyl Radicals (1953) (27)
- Reversible dimerization and some solid-state properties of two bicyclic nitroxides (1973) (26)
- Vitamin E for coronary bypass operations (1994) (26)
- Mass Spectrometric Investigation of the Hydrogen‐Oxygen and Methyl‐Oxygen Reactions (1956) (26)
- Unusually long-lived .alpha.-aminoalkyl radicals (1974) (26)
- The 5-hexenyl cyclization (1979) (26)
- Vitamin E in young and old human red blood cells . (1986) (25)
- FREE RADICALS BY MASS SPECTROMETRY: III. RADICALS IN THE THERMAL DECOMPOSITION OF SOME BENZENE DERIVATIVES (1953) (25)
- EXPERIMENTAL AND THEORETICAL STUDIES ON THE REACTIVITIES OF PARTIALLY AND FULLY FLUORINATED PRIMARY ALKYL RADICALS φ φIssued as NRC No. 40813 (1997) (25)
- THE EFFECT OF SUBSTITUENTS ON THE RELATIVE RATES OF REACTION OF tert-BUTOXY RADICALS WITH PHENOLS IN CARBON TETRACHLORIDE AND IN CHLOROBENZENE (1963) (25)
- Di-tert-butyliminoxy, a free radical of moderate stability (1971) (25)
- Magnetic field effects on the decay of ketyl-aryloxy radical pairs in micellar solution (1988) (25)
- The L-type calcium channel blockers, hantzsch 1,4-dihydropyridines, are not peroxyl radical-trapping, chain-breaking antioxidants. (2006) (24)
- Homolytic organometallic reactions. Part II. The kinetics and rate constants for the autoxidation of organoboron compounds in solution (1971) (24)
- A study of transient phenomena in the reactions of alkoxy radicals with triphenylphosphine and triphenylborane (1979) (24)
- Rate constants for spin trapping. Primary alkyl radicals (1977) (24)
- MECHANISM OF HYDROXYLATION OF ALKANES BY DIMETHYLDIOXIRANE. A RADICAL-CLOCK STUDY (1995) (23)
- Formation of diphenyl nitroxide in diphenylamine inhibited autoxidations (1969) (23)
- Absolute rate constants of alkene addition reactions of a fluorinated radical in water. (2002) (23)
- "Spontaneous" formation of radicals from nitroso compounds. Inadvertent photolysis vs. molecule assisted homolysis (1981) (23)
- Competition H(D) kinetic isotope effects in the autoxidation of hydrocarbons. (2015) (23)
- Kinetic solvent effects on the reaction of an aromatic ketone pi,pi* triplet with phenol. rate-retarding and rate-accelerating effects of hydrogen-bond acceptor solvents. (2007) (23)
- Calibration of the bicyclo[2.1.0]pent-2-yl radical ring opening and an oxygen rebound rate constant for cytochrome P-450 (1989) (23)
- The conformation of 2-alkoxytetrahydropyran-2-yl radicals (1979) (23)
- Further spectroscopic and kinetic studies on carbonyloxyl radicals (1991) (23)
- An electron paramagnetic resonance study of free-radical additions to trithiocarbonates and of the formation and destruction of tetrathiafulvalene by free-radical processes (1978) (23)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XVI. Cyclization of the 5-hexenyl radical (1974) (23)
- α-Tocopheroxyl decay: lack of effect of oxygen (1984) (23)
- Evaluation of reaction rate constants in media where they show dispersion: Hydrogen abstraction by methyl radicals in a methanol glass (1984) (23)
- The inhibited autoxidation of styrene. Part VI. The relative efficiencies and the kinetics for inhibition by N-aryl anilines and N-alkyl anilines (1967) (23)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 28. N-ALKOXY-N-ALKYLAMINO, N-ALKOXYAMINO, AND N-ALKOXYANILINO RADICALS (1976) (22)
- Rate constants for the bimolecular self‐reactions of ethyl, isopropyl, and tert‐butyl radicals in solution. A direct comparison (1974) (22)
- Absolute rate constants for hydrocarbon oxidation. XII. Rate constants for secondary peroxy radicals (1968) (22)
- THE INFRARED FREQUENCIES AND INTENSITIES OF THE HYDROXYL BAND OF ORTHO-ALKYL PHENOLS IN THE VAPOR PHASE (1962) (22)
- Free-radical substitution reactions : bimolecular homolytic substitutions (Sh2 reactions) at saturated multivalent atoms (1971) (22)
- An electron spin resonance study of pentadienyl and related radicals: homolytic fission of cyclobut-2-enylmethyl radicals (1981) (22)
- The structure of amidyl radicals. An investigation by variable-temperature electron paramagnetic resonance spectroscopy (1980) (22)
- Synthesis of α- and γ-tocopherols selectively labelled with deuterium† (1990) (21)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 40. INTRAMOLECULAR REACTIONS OF SOME N-ALKYLCARBOXAMIDYL RADICALS (1982) (21)
- Kinetic studies on the formation and decay of some sulfonium radicals (1983) (21)
- Revised Structure for the Diphenylaminyl Radical: The Importance of Theory in the Assignment of Electronic Transitions in Ph2X• (X = CH, N) and PhY• (Y = CH2, NH, O) (2002) (21)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 42. Some reactions of the bis(trifluoromethyl)aminoxyl radical (1984) (21)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XXII. Dialkylaminothiyl radicals (1976) (21)
- Is methyl-branching in alpha-tocopherol's "tail" important for its in vivo activity? Rat curative myopathy bioassay measurements of the vitamin E activity of three 2RS-n-alkyl-2,5,7,8-tetramethyl-6-hydroxychromans. (1990) (21)
- Autoxidation of alkylnaphthalenes. 2. Inhibition of the autoxidation of n-hexadecane at 160.degree.C (1992) (21)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XX. 2,4,6-Tri(tert-butyl)benzyl, -anilino, -phenoxy, and -phenylthiyl radicals (1975) (21)
- Effect of orally administered alpha-tocopheryl acetate on human myocardial alpha-tocopherol levels (1991) (20)
- ANTIOXIDANT ACTIVITY OF PHENOLS RELATED TO VITAMIN E. ARE THERE CHAIN-BREAKING ANTIOXIDANTS BETTER THAN α-TOCOPHEROL? (1983) (20)
- Absolute rate constants for some intermolecular reactions of alpha-aminoalkylperoxyl radicals. Comparison with alkylperoxyls. (2008) (20)
- Reactions of bicyclic nitroxides involving reduction of the nitrosyl group (1973) (20)
- A Radical Account of “Oxygenated Fenton Chemistry” (1998) (20)
- Isomerization of triphenylmethoxyl: the Wieland free-radical rearrangement revisited a century later. (2010) (20)
- THE EFFECT OF SOLVENT AND TEMPERATURE ON THE CIS–TRANS ISOMERISM OF ORTHO-tert-ALKYL PHENOLS (1961) (20)
- EPR SPECTRA OF SOME α-TOCOPHEROL MODEL COMPOUNDS. POLAR AND CONFORMATIONAL EFFECTS AND THEIR RELATION TO ANTIOXIDANT ACTIVITIES (1984) (20)
- Hyperconjugation in .beta.-substituted ethyl radicals. Does it determine conformation (1973) (20)
- Two conformations of the pentadienyl radical (1979) (20)
- Comparison of free alpha-tocopherol and alpha-tocopheryl acetate as sources of vitamin E in rats and humans. (1988) (20)
- Synthesis of 2-substituted 5,7,8-trimethyl-6-hydroxythiochromans and purported syntheses of sulfur-containing analogs of vitamin E (1986) (20)
- Permanganate oxidation of N-aryl-2-naphthylamines (1968) (19)
- Temperature and site dependence of the rate of hydrogen and deuterium abstraction by methyl radicals in methanol glasses (1984) (19)
- Further studies of a new vitamin E analogue more active than α‐tocopherol in the rat curative myopathy bioassay (1990) (19)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XI. Aminium radicals (1973) (19)
- Synthesis of a novel radical trapping and carbonyl group trapping anti-AGE agent: a pyridoxamine analogue for inhibiting advanced glycation (AGE) and lipoxidation (ALE) end products. (2003) (19)
- Rate constants for some reactions of oxy radicals (1967) (19)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 14, 1,1-DIALKYLHYDRAZYL RADICALS (1974) (19)
- Evidence for reversible ring-opening of the α-cyclopropylbenzyl radical (1990) (19)
- Hydrogen atom abstraction by peroxy radicals (1967) (19)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XIX. Persistent cyclohexadienyls and related radicals (1975) (19)
- Di- and tri-tert-butylmethyl, two aliphatic radicals of unusual stability (1973) (19)
- Reaction of Phenols with Peroxy Radicals (1962) (19)
- Reactions of alkoxy radicals. IV. Kinetics and absolute rate constants for some tert-butyl hypochlorite chlorinations (1967) (18)
- Effect of ring substitution on the S-H bond dissociation enthalpies of thiophenols. An experimental and computational study. (2006) (18)
- SOLVENT EFFECTS ON HYDROCARBON AUTOXIDATIONS (1964) (18)
- HYPERCONJUGATION IN BETA-SUBSTITUTED ETHYL RADICALS, DOES IT DETERMINE CONFORMATION (1973) (18)
- Absolute rate constants for hydrocarbon autoxidation. XIV. Termination rate constants for tertiary peroxy radicals (1969) (18)
- Oxidation of amines with peroxy radicals. I. N-phenyl-2-naphthylamine (1969) (18)
- Kinetic applications of electron paramagnetic resonance spectroscopy. VIII. Tetraalkoxyphosphoranyl radicals (1972) (18)
- Reaction of organotin hydrides with acid chlorides: mechanism of aldehyde and ester formation (1984) (17)
- Influence of aromatic solvents on the selectivity for photochlorination of 2,3-dimethylbutane with molecular chlorine (1989) (17)
- Direct measurement of the rate constant for .beta.-scission of the cumyloxyl radical by laser flash photolysis with time-resolved IR detection (1989) (17)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 41. Diethoxyphosphonyl radicals (1983) (17)
- Measurement of Equilibrium Constants for Complex Formation between Phenol and Hydrogen-Bond Acceptors by Kinetic Laser Flash Photolysis1 (1996) (17)
- Electron paramagnetic resonance spectroscopic study of the radicals formed during the photodecomposition of some bis(alkenoyl) peroxides, a bis(alkenoyl) peroxide and some peroxydicarbonates (1990) (17)
- Carbon-13 and proton hyperfine splittings and their variation with temperature for some alkoxyalkyl radicals (1977) (17)
- Photoinduced electron transfer from dialkyl nitroxides to halogenated solvents (1990) (16)
- An E.S.R. study of the structure of phosphorus centred radicals in solution (1973) (16)
- Reaction of Methyl Radicals with Nitric Oxide (1955) (16)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XXIV. Neophyl rearrangements (1976) (16)
- Autoxidation of alkylnaphthalenes. 1. Self-inhibition during the autoxidation of 1- and 2-methylnaphthalenes puts a limit on the maximum possible kinetic chain length (1992) (16)
- HALOGENATED WITH N-HALOAMINES IN STRONG ACIDS. I. THE NATURE OF THE CHAIN PROPAGATING RADICAL, (1970) (16)
- Chiral discrimination in the exchange of α-tocopherol stereoisomers between plasma and red blood cells (1987) (16)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 37. The reaction of bis(trifluoromethyl)nitroxide with toluene. Evidence for quantum-mechanical tunneling in an intermolecular hydrogen-atom abstraction (1981) (16)
- Absolute rate constants for the reactions tri-n-butylgermyl and tri-n-butylstannyl radicals with carbonyl compounds, other unsaturated molecules, and organic halides (1984) (16)
- Novel routes to new, long-lived 1,1,2,2-tetrasubstituted ethyl radicals of unusual conformation (1974) (16)
- BILE SALT-MODULATED STEREOSELECTION IN THE CHOLESTEROL ESTERASE-CATALYZED HYDROLYSIS OF ALPHA -TOCOPHERYL ACETATES (1991) (16)
- Isomerization of triphenylmethoxyl and 1,1-diphenylethoxyl radicals. Revised assignment of the electron-spin resonance spectra of purported intermediates formed during the ceric ammonium nitrate mediated photooxidation of aryl carbinols. (2006) (16)
- THE REACTION OF tert-BUTOXY RADICALS WITH 2,6-Di-tert-BUTYL-4-METHYLPHENOL AND 2,6-Di-tert-BUTYLPHENOL (1963) (15)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION: III. α-METHYLSTYRENE, β-METHYLSTYRENE, AND INDENE (1966) (15)
- RADICAL ADDITIONS TO DI-TERT-BUTYLSULFUR DIIMIDE AND DI-TERT-BUTYLCARBODIIMIDE (1976) (15)
- Why are organotin hydride reductions of organic halides so frequently retarded? Kinetic studies, analyses, and a few remedies. (2015) (15)
- First EPR spectroscopic detection of photochemically generated carbonyloxyl radicals in solution under steady-state conditions (1988) (15)
- Influence of micellar size on the decay of triplet-derived radical pairs in micelles (1992) (15)
- Formation of radicals in the amine inhibited decomposition of t-butyl hydroperoxide (1969) (15)
- Electron paramagnetic resonance spectra of some radicals from O-alkyl thioesters and O-alkyl selenoesters (1977) (15)
- Cyclizations of 5-Hexenyl, 6-Heptenyl, 7-Octenyl, and 8-Nonenyl Radicals. The Kinetic and Regiochemical Impact of Fluorine and Oxygen Substituents‖ (1999) (15)
- Absolute rate constants for some reactions involving triethylsilyl radicals in solution (1981) (15)
- Determination of Rate Constants for the Self-Reactions of Peroxy Radicals by Electron Spin Resonance Spectroscopy (1968) (15)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XVIII. Persistent vinyl, alkyl, and allyl radicals (1975) (15)
- Inversion of the oxiranyl radical occurs by quantum-mechanical tunneling (1988) (14)
- Kinetic and mechanistic studies of free radical reactions in the 21st century (1997) (14)
- Rate constants for hydrogen abstraction from alkoxides by a perfluoroalkyl radical. An oxyanion accelerated process. (2004) (14)
- Accurate O-H bond dissociation energy differences of hydroxylamines determined by EPR spectroscopy: computational insight into stereoelectronic effects on BDEs and EPR spectral parameters. (2011) (14)
- REACTION OF ACYL HALIDES WITH ORGANOTIN HYDRIDES. MECHANISM OF ALDEHYDE FORMATION (1983) (14)
- The Rate of Combination of Methyl Radicals (1953) (14)
- Kinetic analysis of alkane polychlorination with molecular chlorine. Chlorine atom/monochloride geminate pairs and the effect of reactive cage walls on the competition between monochloride rotation and chlorine atom escape (1988) (14)
- Kinetics of Nitroxide Radical Trapping. Part 1. Solvent Effects. (1992) (14)
- Hydrogen abstraction by methyl radicals in glasses (1984) (14)
- Electron spin resonance (ESR) investigation of the structure of methyl radical trapping sites in methanol glass (1987) (14)
- Self-reaction of diethylnitroxide radicals (1970) (14)
- Generation and Study of the Reactivity of α-Ammonium Distonic Radical Cations in Solution (1996) (14)
- Nitroxydes 105: cinetique de reduction d'un radical nitroxyde par l'acide ascorbique en presence de β-cyclodextrine (1985) (14)
- Cycloalkylmethyl radicals. 5. 6- to 15-membered rings: ESR studies of ring conformations and stereodynamics (1987) (14)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 29. Free radical chemistry of aliphatic selenium compounds (1977) (13)
- Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals. An experimental and theoretical study. (2004) (13)
- Kinetic studies on stilbazulenyl-bis-nitrone (STAZN), a nonphenolic chain-breaking antioxidant in solution, micelles, and lipid membranes. (2004) (13)
- Calibration of a New Horologery of Fast Radical “Clocks”. Ring-Opening Rates for Ring- and α-Alkyl-Substituted Cyclopropylcarbinyl Radicals and for the Bicyclo(2.1.0)pent-2-yl Radical. (1991) (13)
- Interaction of synapsin I with membranes. (2003) (13)
- Kinetics of cyclopropyl radical reactions. 3. Study of some 1-substituted cyclopropyl radicals by EPR spectroscopy. The inversion barrier for 1-methylcyclopropyl (1987) (13)
- Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (2000) (13)
- Absolute rate constants for the autoxidation of organometallic compounds. Part II. Benzylboranes and 1-phenylethylboranes (1972) (13)
- Mechanism of Inhibitors in Oil Oxidation - Influence of Acids and Bases on the Efficiency of Inhibitors (1959) (13)
- Probing ring conformations with EPR spectroscopy (1989) (12)
- Clocking Tertiary Cyclopropylcarbinyl Radical Rearrangements1 (1997) (12)
- Cis-Alkylcarbamoyl radicals. The overlooked conformer (1981) (12)
- Absolute rate constants for the reaction of triethylsilyl radicals with ring-substituted benzyl chlorides (1987) (12)
- Solvolysis of para-substituted cumyl chlorides. Brown and Okamoto's electrophilic substituent constants revisited using continuum solvent models. (2004) (12)
- THE INHIBITION OF AUTOXIDATION BY 2,4,6-TRI-TERTBUTYL SUBSTITUTED PHENOL, ANILINE, AND THIOPHENOL, (1964) (12)
- Hydrolysis of stereoisomeric α-tocopheryl acetates catalyzed by bovine cholesterol esterase (1987) (12)
- Absolute rate constants for the reactions of primary alkyl radicals with aromatic amines (1996) (12)
- The free-radical reaction of tri-n-butyltin hydride with peroxides† (1970) (12)
- Overlooked difference between hydrogen bonds of equal strength formed between catechol and an oxygen or nitrogen base. Experiments and DFT calculations. (2003) (12)
- Kinetics and rate constants for the reaction of tri‐n‐butylgermanium hydride with methyl iodide and carbon tetrachloride. The combination of methyl and trichloromethyl radicals in solution. (1969) (11)
- Oxime-iminoxy radical reaction (1973) (11)
- Well‐Resolved ESR Spectra of Arenecarboxyl Radicals in Solution (1989) (11)
- Infrared and Raman spectra of N,N-bis(trifluoromethyl)hydroxylamine and bis(trifluoromethyl) nitroxide (1981) (11)
- Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer? (2011) (11)
- Absorption and transport of deuterium-substituted 2R,4'R,8'R-alpha-tocopherol in human lipoproteins. (1988) (11)
- Benzylchlorocarbene: Origins of Arrhenius Curvature in the Kinetics of the 1,2-H Shift Rearrangement (1998) (11)
- Kinetic applications of electron paramagnetic resonance spectroscopy. VI. Phosphoranylperoxy radicals (1972) (11)
- (Diphenylphosphinoyl)oxyl: an extremely reactive oxygen-centered radical (1990) (11)
- The sensitized photodecomposition of Di-ert-butyl peroxide. A simple method for increasing radical concentrations in certain EPR experiments (1980) (11)
- Hydrophobic/hydrophilic effects on the titanium(IV)- catalyzed epoxidation of cyclohexene by tert-alkyl hydroperoxides: 2-methyl-1-phenyl-2-propyl hydroperoxide (MPPH) versus tert-butyl hydroperoxide (TBHP) (1997) (11)
- Estimation of the location of natural alpha-tocopherol in lipid bilayers by 13C-NMR spectroscopy. (1985) (11)
- Perfluoro-tert-butyl, a reactive, neutral, electrophilic carbon-centered radical par excellence (1996) (11)
- Cycloalkylmethyl radicals. 6. The unexpectedly high barrier to the rotation of axial CH2.cntdot. groups in cyclohexylmethyl radicals (1988) (11)
- THE INFLUENCE OF ALKALI ON THE OXIDATION OF TETRALIN (1956) (11)
- Electron paramagnetic resonance spectra of radical adducts to di-tert-butyl selenoketone (1976) (11)
- Triplet quenching by diacyl peroxides (1984) (11)
- Chemically induced dynamic electron polarization of dialkoxyphosphonyl radicals (1983) (11)
- Reactions of alkoxy radicals. III. Kinetics of the tert-butyl hypochlorite chlorination of toluene (1967) (11)
- Intramolecular and intermolecular reactions of alkenylsilyl radicals (1983) (11)
- Thermal decomposition of O-benzyl ketoximes; role of reverse radical disproportionation. (2004) (11)
- Absolute rate constants for some hydrogen atom abstraction reactions by a primary fluoroalkyl radical in water. (2004) (11)
- Conformational analysis and stereodynamics of primary acyclic alkyl radicals by EPR spectroscopy (1986) (11)
- The conformations of cycloalkylmethyl radicals and barriers to internal rotation (1982) (10)
- A kinetic study of the reaction of adamantanethione with 2-adamantanethiol (1976) (10)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. XXI. MONO-, DI-, AND TRIALKYLHYDRAZYLS (1975) (10)
- Calibration of very fast alkyl radical 'clock' rearrangements using nitroxides (1990) (10)
- Nonequivalent methylene protons in neopentylamines and benzylamines (1970) (10)
- Unexpected superoxide dismutase antioxidant activity of ferric chloride in acetonitrile. (2003) (10)
- Superoxide, amine buffers and tetranitromethane: A novel free radical chain reaction (2000) (10)
- ELECTRON PARAMAGNETIC AND NUCLEAR MAGNETIC RESONANCE SPECTRA OF DI-TERT-BUTYLIMINOXY AND DI(1-ADAMANTYL)IMINOXY (1975) (10)
- Reactions of Alkoxy Radicals. II. The Absolute Rate Constant for the Combination of t-Butoxy Radicals1 (1966) (10)
- 2,4,6-Tri-tert-butylphenyl radical (1974) (10)
- Carbon-13 hyperfine splittings in the electron paramagnetic resonance spectra of .beta.-substituted ethyl radicals (1976) (10)
- Di-(1-adamantyl)iminoxy. Preparation and Dipole Moment (1974) (10)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XII. Self-reactions of some phosphorus centered radicals (1974) (10)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 33. Diazirinyl radicals (1979) (9)
- Bis(trifluoromethyl)aminyl and bis(trifluoromethyl) nitroxide (1980) (9)
- Revised assignment of the electron spin resonance spectrum obtained by photolysis of tetrasulfur tetranitride-bis(norbornene) (1979) (9)
- Electron paramagnetic resonance spectra of 1,1-dialkylhydrazyl radicals in solution (1973) (9)
- AN ELECTRON SPIN RESONANCE STUDY OF PENTADIENYL AND RELATED RADICALS: HOMOLYTIC FISSION OF CYCLOBUT‐2‐ENYLMETHYL RADICALS (1981) (9)
- A homoallyl radical rearrangement. Kinetics of the isomerization of the 2,2-dimethyl-3-buten-1-yl radical to the 1,1-dimethyl-3-buten-1-yl radical (1983) (9)
- Selectivity in the photochlorination of 2,3-dimethylbutane with molecular chlorine in noncomplexing solvents (1988) (9)
- Cycloalkylmethyl radicals. 2. Axial and equatorial cyclohexylmethyl and (4-alkylcyclohexy)methyl radicals. First determination of the conformational free energy difference of the CH2.cntdot. group (1985) (9)
- Bimolecular homolytic substitution of dialkyl selenides and tellurides with tri-n-butyltin radicals (1976) (9)
- Dimers of delocalised radicals: pentamethylcyclopentadienyl and pentadienyl (1993) (9)
- The kinetics of the thermal decomposition of normal paraffin hydrocarbons - V. Order of reaction over extended ranges of pressure (1952) (9)
- ELECTRON PARAMAGNETIC RESONANCE SPECTRA OF ALKYLHYDRAZYL RADICALS IN SOLUTION (1974) (9)
- Identification of a New Type of Molecular Asymmetry (1962) (8)
- The inhibition of autoxidation by aromatic amines (1970) (8)
- Radical reactions of bicyclo[2.1.0]pentane (1980) (8)
- Characterization of equatorial and axial six-membered-ring peroxyl radicals. (2007) (8)
- A kinetic study of the thermal decomposition of pentabenzyltantalum (1978) (8)
- CYCLOPROPENYL, DIMETHYLCYCLOPROPENYL, AND TRIMETHYLCYCLOPROPENYL RADICALS (1982) (8)
- A meta effect in nonphotochemical processes: the homolytic chemistry of m-methoxyphenol. (2008) (8)
- CALORIMETRIC AND EQUILIBRIUM STUDIES ON SOME STABLE NITROXIDE AND IMINOXY RADICALS, APPROXIMATE O-H BOND DISSOCIATION ENERGIES IN HYDROXYLAMINES AND OXIMES (1974) (8)
- Kinetic applications of electron paramagnetic resonance spectroscopy. 39. Bimolecular self-reactions of some N-alkylcarboxyamidyl, N-alkylsulfonamidyl, and N-alkyl-N-(alkoxycarbonyl)aminyl radicals. Intermolecular hydrogen atom abstraction by N-ethylpropionamidyl radical (1982) (8)
- EPR detection of free radicals from N-hydroxypyridine-2-thione esters (1988) (8)
- The effects of hyperfine interaction and radical concentration on the relative contributions of ST0 and ST_ mixing in CIDEP (1989) (8)
- The benzoyloxy radical: attempted photochemical generation for kinetic studies and some relative rate constants (1985) (8)
- N‐TERT‐BUTOXY‐N‐TERT‐ALKYLAMINYLS. A NEW CLASS OF PERSISTENT RADICALS (1980) (8)
- Small, strained bicycloalkyl radicals and some homolytic reactions involving their parent bicycloalkanes (1986) (8)
- Bicyclo[1.1.1]pent-1-yl: A tertiary alkyl radical with enhanced reactivity☆ (1996) (8)
- Cycloalkylmethyl radicals. Part 8. A conformational study of dioxa- and dithia-cyclohexylmethyl radicals by EPR spectroscopy (1991) (8)
- Solvent effects on the spin-trapping of primary alkyl radicals (1978) (8)
- The EPR Spectra of Hydrazyl and Some 1-Substituted Hydrazyl Radicals in Solution (1974) (8)
- Inversion of the dioxolanyl radical: an experimental and theoretical study (1990) (8)
- Experimental analysis of .gamma.-hydrogen hyperfine splittings in acyclic aliphatic radicals. Confirmation of theoretical predictions (1982) (8)
- 5-Endo closure of the 2-formylbenzoyl radical. [Erratum to document cited in CA120:190772] (1994) (7)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XIV. 1,1-Dialkylhydrazyl radicals (1974) (7)
- Reactions of water-soluble alkylperoxyl radicals and superoxide with DNA, lipoproteins and phospholipid vesicles: the role played by electrostatic forces. (2003) (7)
- Electron paramagnetic resonance spectra and structure of some vinyl radicals in solution (1975) (7)
- Persistent cyclopropyl radicals with novel configurations (1978) (7)
- Dimerization of nortropane N-oxyl (1972) (7)
- Do spin-adducts of 5,5-dimethylpyrroline-N-oxide dimerize? (1982) (7)
- Another Unprecedented Wieland Mechanism Confirmed: Hydrogen Formation from Hydrogen Peroxide, Formaldehyde, and Sodium Hydroxide. (2018) (7)
- Simon metabolites of alpha-tocopherol are not formed via a rate-controlling scission of the 3'C-H bond. (1990) (7)
- Oxidative damage to a supercoiled DNA by water soluble peroxyl radicals characterized with DNA repair enzymes. (2003) (7)
- An electron spin resonance study of radical intermediates from 1,6,6aλ4-triheterapentalenes (1982) (7)
- Kinetic studies of some free radical reactions (1984) (6)
- N-tert-butoxy-N-tert-alkylaminyls. A new class of persistent radicals (1980) (6)
- N-alkylformamidyl radicals. Identification and electronic structure (1981) (6)
- Radical additions to di-t-butyl selenoketone (1976) (6)
- Kinetic applications of electron paramagnetic resonance spectroscopy. IV. Self-reactions of diethylamino and diisopropylamino radicals (1971) (6)
- Modulation of cholesterol esterase's diastereoselectivity by chiral auxiliaries. The very large effect of a dihydroxy bile salt on the hydrolysis of .alpha.-tocopheryl acetates (1994) (6)
- Hindered Rotation and Intramolecular Hydrogen Exchange in N-Phenyl-o-hydroxybenzylamines (1971) (6)
- Absolute Rate Constants for the Combination of Trichloromethyl Radicals and for Their Reaction with t-Butyl Hypochlorite1 (1966) (6)
- A method for thermal generation of aryloxyl radicals at ambient temperatures: application to low-density lipoprotein (LDL) oxidation. (2002) (6)
- Persistent radicals from di-tert-butyldiazomethane and di-tert-butylketene (1978) (6)
- Alkylperoxy radical stabilization by cobalt ions (1972) (6)
- Barriers to rotation in ortho-alkylphenyl substituted 1,3-benzoxazines (1969) (6)
- Additions and Corrections - Rate Constants for the Self-Reactions ofn- andsec- Butylperoxy Radicals and Cyclohexylperoxy Radicals. The Deuterium Isotope Effect in the Termination of Secondary Peroxy Radicals. (1968) (5)
- Di-t-alkyl tetroxides (1969) (5)
- Hindered rotation of the trifluoromethyl group in tert-butoxy trifluoromethyl nitroxide (1982) (5)
- The kinetics and rate constants for the autoxidation of s-butylboronic anhydride (1969) (5)
- Total synthesis of 1-thio-α-tocopherol: A sulfur-containing analogue of vitamin E. (1986) (5)
- Hydrolysis of stereoisomeric alpha-tocopheryl acetates catalyzed by bovine cholesterol esterase. (1987) (5)
- 382. The kinetics of the thermal decomposition of olefins. Part I. Propylene (1951) (5)
- On the mechanism of reaction of tert‐butoxyl radicals with dialkylphosphites (1975) (5)
- The Only Stable Organic Sigma Radicals: Di‐tert‐Alkyliminoxyls (2010) (5)
- The rate constant for the self-reaction of trimethylsilyl radicals (1970) (5)
- A homopropargyl radical rearrangement. Kinetics of the rearrangement of the 2,2,5,5,-tetramethyl-3-hexyn-1-yl radical (1980) (5)
- Halogenation with N-haloamines in strong acids. II. Kinetics and rate constants (1970) (5)
- Reply to W Cohn (1999) (5)
- Cycloalkylmethyl radicals. Part 3. Dynamic stereochemistry of axial and equatorial cyclohexylmethyl and 4-alkylcyclohexylmethyl radicals (1986) (5)
- Vitamin E: Or Why We Don't Go Rancid† (1992) (4)
- On the radicals produced by the photolysis of azobenzene in cumene (1973) (4)
- Vitamin E and related ether-phenols: A low-temperature dielectric relaxation study (1985) (4)
- The reaction of t-butoxyl radicals with diborane (1973) (4)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 12, SELF-REACTIONS OF SOME PHOSPHORUS CENTERED RADICALS (1974) (4)
- The kinetics of the thermal decomposition of normal paraffin hydrocarbons IV. Modes of rupture of the carbon chain (1951) (4)
- Unusually large long range interactions in the electron paramagnetic resonance spectra of 2,2,4,4,6,6-hexamethylcyclohexyl and 2,2,4,6,6-pentamethylcyclohexyl radicals (1974) (4)
- A reexamination of the decay kinetics of diethyl nitroxide in aqueous solution by EPR spectroscopy (1980) (4)
- On the epr spectra of hydrazyl and hydrazoxyl radicals (1973) (4)
- Configurational characterization of the 1-(trimethylsilyl)cyclopropyl radical (1986) (4)
- Antioxidant Activity of 1-Thio-α-tocopherol and Related Compounds. EPR, ENDOR, and UV-Visible Absorption Spectra of Some of the Derived Phenoxyl Radicals. (1989) (4)
- The kinetics of the thermal decomposition of normal paraffin hydrocarbons III. Activation energies and possible mechanisms of molecular reactions (1950) (4)
- A Radical Clock Investigation of Microsomal Cytochrome P-450 Hydroxylation of Hydrocarbons. Rate of Oxygen Rebound. (1991) (4)
- Line intensity ratios in electron spin resonance spectra. A remarkable change accompanying saturation (1978) (3)
- Some Applications of ESR Spectroscopy to the Study of Substituent Effects (1986) (3)
- Biodiscrimination of Tocopherols (1993) (3)
- Condensation of some substituted phenols and anilines with formaldehyde. Formation of 2-phenyl-1,3-benzoxazines and N-(2-hydroxybenzyl)-anilines (1970) (3)
- Lipid Peroxidation, Antioxidants and Regenerating Rat Liver (1988) (3)
- Competition between hydrogen and deuterium abstraction by methyl radicals in isotopomerically mixed methanol glasses (1993) (3)
- Configuration and conformation of alkoxyalkyl and hydroxyalkyl trifluoromethyl nitroxides. Anomeric effects and nitroxide conformations (1981) (3)
- 5-endo Closure of the 2-Formylbenzoyl Radical. (1994) (3)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 26. QUANTUM‐MECHANICAL TUNNELING IN THE ISOMERIZATION OF STERICALLY HINDERED ARYL RADICALS (1977) (3)
- The side-chain halogenation of alkylaromatic hydrocarbons with 4-bromo-2,5- cyclohexadienones (1967) (3)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 17, SECONDARY DEUTERIUM ISOTOPE EFFECT AND THE ABSENCE OF A ′MEMORY′ IN THE BETA SCISSION OF A TETRA‐TERT‐BUTOXYPHOSPHORANYL (1975) (3)
- E.s.r. study of the homolytic ring fission of cyclobutenylmethyl radicals (1980) (3)
- Revision of the αH2 value for N,N-dialkylhydroxylamines based on kinetic and spectroscopic measurements (2001) (3)
- Vitamin E Activity of 1-Thio-α-Tocophero as Measured by the Rat Curative Myopathy Bioassay (1990) (3)
- ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION. VII. REACTIVITIES OF PEROXY RADICALS TOWARD HYDROCARBONS AND HYDROPEROXIDES (1967) (3)
- Exploring Iron-Plus-Hydroperoxide-Based “Oxygen Activation” Systems. Or: It’s Hard to Keep a Good Radical Down! (1997) (3)
- Synthesis of 2-Substituted 5,7,8-Trimethyl-6-hydroxythiochromans and Purported Syntheses of Sulfur-Containing Analogues of Vitamin E. (1986) (3)
- Photochemical reaction of 2,2,4,4-tetramethylpentan-3-imine [But2CNH) with triethylborane: a photo-reaction sensitized by conjugated dienes (1975) (2)
- Conformational analysis of the 2,2-dimethylbutyl radical by EPR spectroscopy (1985) (2)
- A new vitamin E analogue more active than alpha-tocopherol in the rat curative myopathy bioassay. (1986) (2)
- THE EFFECT OF AMINES AND PHENOLS ON THE GAS-PHASE OXIDATION OF n-BUTANE AND ISOBUTANE (1959) (2)
- Bond Strengths of Toluenes, Anilines, and Phenols: To Hammett or Not (2004) (2)
- Kinetics or reduction of a nitroxide radical by ascorbic acid in the presence of β-cyclodextrin. Determination of the radical/β-cyclodextrin association constant and rate constants for reaction of the free and complexed nitroxide radical (1985) (2)
- The unexpected desulfurization of 4-aminothiophenols. (2007) (2)
- Reaction of bis(trifluoromethyl)aminoxyl with cyclopropane (1983) (2)
- Hanns Fischer: Radical Pioneer (2006) (2)
- A theoretical and experimental investigation of some unusual intermolecular hydrogen-bond IR bands — Appearances can be deceptive (2006) (2)
- Oxidation of dopamine by peroxyl radicals--a commentary on the site of radical attack. (2007) (2)
- Reaction of free radicals with 1,6,6aλ4-trithiapentalenes (1979) (2)
- Kinetics for the Reaction of a Secondary Alkyl Radical with Tri-n-butylgermanium Hydride and Calibration of a Secondary Alkyl Radical Clock Reaction. (1988) (2)
- Is the oxygen side-on , or end-on and fluctional, in peroxyl radicals with magnetically equivalent oxygen atoms? (2010) (2)
- Cleavage of supercoiled DNA by horseradish peroxidase plus tert-butyl hydroperoxide is not due to tert-butylperoxyl radicals. (2002) (2)
- Attempted spin trapping of tert-butylperoxyl radical by trifluoronitrosomethane (1982) (2)
- Vibrational analysis by electron paramagnetic resonance spectroscopy. Trifluoromethyl (1982) (2)
- Additions and Corrections - Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. XXIV. Neophyl Rearrangements. (1976) (1)
- Competitive Uptake of Deuterium‐Labeled α‐Tocopherols in Male Rats (1989) (1)
- Formation of molecular hydrogen in the bimolecular self-reaction of hydroperoxyl radicals in the gas phase. Comments (1988) (1)
- HYDROGEN ATOM ABSTRACTION FROM HEXAMETHYL (DEWAR BENZENE), HEXAMETHYLPRISMANE, AND A 1,3-HYDROGEN-SHIFTED ISOMER OF HEXAMETHYLBENZVALENE. A STUDY BY ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY (1981) (1)
- First Absolute Rate Constants for Some Hydrogen Atom Abstractions and Addition Reactions of an Aroyloxyl Radical: 4-Methoxybenzoyloxyl. (1987) (1)
- MECHANISM OF REARRANGEMENT OF β-ACYLOXYALKYL RADICALS (1984) (1)
- Nitrogen-Centered Radicals, Aminoxyls and Related Radicals (1994) (1)
- UV/VIS Spectra of Halogen Molecule/Arene and Halogen Atom/Arene π-Molecular Complexes. (1989) (1)
- Is vitamin E the only lipid-soluble, chain-breaking antioxidant in human blood plasma and erythrocyte membranes? (2022) (1)
- The spiropentyl radical and some homolytic reactions of spiropentane (1982) (1)
- (Diphenylphosphinoyl)oxyl: an extremely reactive oxygen-centered radical [Erratum to document cited in CA112(7):56112m] (1990) (1)
- EXPERIMENTAL ANALYSIS OF Γ-HYDROGEN HYPERFINE SPLITTINGS IN ACYCLIC ALIPHATIC RADICALS. CONFIRMATION OF THEORETICAL PREDICTIONS (1982) (1)
- Interpretation of .beta.-hydrogen hyperfine splittings in the electron spin resonance spectrum of the 3-methyl-3-phenylbut-1-yl radical (1984) (1)
- THE STRUCTURE OF AMIDYL RADICALS. EVIDENCE FOR THE Π-ELECTRONIC GROUND STATE AND FOR TWIST ABOUT THE ACYL-NITROGEN BOND BY ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY (1981) (1)
- Absolute Rate Constants for Some Intermolecular and Intramolecular Reactions of α-, β-, and γ-Silicon-Substituted Radicals. (1988) (1)
- Custom Design of Better in vivo Antioxidants Structurally Related to Vitamin E (1993) (1)
- REACTIONS OF BICYCLIC NITROXIDES INVOLVING REDUCTION OF THE NO GROUP (1973) (1)
- Special International Symposium on Free Radical Chemistry Lanzhou University, Lanzhou, People’s Republic of China; 5–9 September 1985 (1986) (1)
- Spectroscopic and Kinetic Characteristics of Aroyloxyl Radicals. Part 2. Benzoyloxyl and Ring-Substituted Aroyloxyl Radicals. (1988) (1)
- Quantum Mechanical Tunneling of Hydrogen Atoms in Some Simple Chemical Systems (2007) (1)
- Autoxidation of Alkylnaphthalenes. Part 1. Self‐Inhibition During the Autoxidation of 1‐ and 2‐Methylnaphthalenes Puts a Limit on the Maximum Possible Kinetic Chain Length (1993) (1)
- Mechanism of Hydroxylation of Alkanes by Dimethyldioxirane. A Radical‐ Clock Study. (1996) (1)
- Quinuclidin-4-yl (1979) (1)
- Autoxidation of Biological Molecules. Part 4. Maximizing the Antioxidant Activity of Phenols. (1986) (1)
- “SPONTANEOUS” FORMATION OF RADICALS FROM NITROSO COMPOUNDS. INADVERTENT PHOTOLYSIS VS. MOLECULE ASSISTED HOMOLYSIS (1981) (1)
- Autoxidation of Alkylnaphthalenes. Part 2. Inhibition of the Autoxidation of n‐Hexadecane at 160 °C (1993) (1)
- THE OXIDATION OF AMINES WITH PEROXY RADICALS. N-PHENYL-2-NAPTHYLAMINE, (1969) (1)
- First Spectroscopic and Absolute Kinetic Studies on (Alkoxycarbonyl)oxyl Radicals (II) and an Unsuccessful Attempt to Observe Carbamoyloxyl Radicals (1989) (0)
- Experimental and Theoretical Studies on the Reactivities of Partially and Fully Fluorinated Primary Alkyl Radicals. (1997) (0)
- DI-(1-ADAMANTYL)IMINOXY, PREPARATION AND DIPOLE MOMENT (1975) (0)
- Dimers of Delocalized Radicals: Pentamethylcyclopentadienyl and Pentadienyl. (1993) (0)
- Kinetics of Cyclopropyl Radical Reactions. Part 3. Study of Some 1-Substituted Cyclopropyl Radicals (II) by EPR Spectroscopy. The Inversion Barrier for 1-Methylcyclopropyl. (1987) (0)
- Additions and Corrections - Self-Reactions of Diethylamino and Diisopropylamino Radicals (1972) (0)
- ON THE CONFORMATION OF BETA-SUBSTITUTED ETHYL RADICALS (1974) (0)
- First Direct Detection of Transient Organic Free Radicals in Solution by Time-Resolved IR Spectroscopy. Kinetic Studies on Some Acyl Radicals (1991) (0)
- Absorption and Transport of Vitamin E (1993) (0)
- Cycloalkylmethyl Radicals. Part 6. The Unexpectedly High Barrier to the Rotation of Axial CH· 2 Groups in Cyclohexylmethyl Radicals (1989) (0)
- OXIM-IMINOXY-RADIKAL-REAKTION (1973) (0)
- Cycloalkylmethyl Radicals. Part 3. Dynamic Stereochemistry of Axial and Equatorial Cyclohexylmethyl and 4‐Alkylcyclohexylmethyl Radicals (1986) (0)
- RADICAL REACTIONS OF BICYCLO(2.1.0)PENTANE (1980) (0)
- Bicyclo(1.1.1)pent‐1‐yl: A Tertiary Alkyl Radical with Enhanced Reactivity. (1997) (0)
- First EPR Spectroscopic Detection of Photochemically Generated Carbonyloxyl Radicals in Solution Under Steady-State Conditions. (1988) (0)
- Chain Reactions: Liquid-Phase Oxidation of Hydrocarbons . Nikolai Markovich Emanuel, Evgenii Timofeevich Denisov, and Zinaida Kushelevna Maizus. Translated from the Russian edition (Moscow, 1965) by B. J. Hazzard. Plenum Press, New York, 1967. 364 pp., illus. $22.50. (1967) (0)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 35. THE E SEARCH FOR A DIALKYLAMINYL REARRANGEMENT. RING OPENING OF N-CYCLOBUTYL-N-N-PROPYLAMINYL (1980) (0)
- REACTION OF ORGANOTIN HYDRIDES WITH ACID CHLORIDES. MECHANISM OF ALDEHYDE AND ESTER FORMATION (1984) (0)
- Vitamin E activity of 1-thio-alpha-tocopherol as measured by the rat curative myopathy bioassay. (1990) (0)
- High Resolution ESR Spectra of Arenecarboxyl Radicals in Solution (1989) (0)
- Barriers to rotation in ovtho-alkylphenyl substituted 1,3-benzoxazinesl (1969) (0)
- Solvent Effects on the Rates and Mechanisms of Reaction of Phenols with Free Radicals (2007) (0)
- 60 Years of Research on Free Radical Physical Organic Chemistry (2015) (0)
- Disturbances of Lipid Peroxidation in Rat Liver Cancer Cells and in Normal Regenerating Rat Liver (1993) (0)
- THE 2,4,6-TRI-TERT.-BUTYLPHENYL RADICAL (1974) (0)
- Cycloalkylmethyl Radicals. Part 8. A Conformational Study of Dioxa‐ and Dithiacyclohexylmethyl Radicals by EPR Spectroscopy. (1992) (0)
- SOME UNUSUALLY LONG‐LIVED ALPHA‐AMINOALKYL RADICALS (1974) (0)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 37. THE E REACTION OF BIS(TRIFLUOROMETHYL)NITROXIDE WITH TOLUENE. EVIDENCE FOR QUANTUM-MECHANICAL TUNNELING IN AN INTERMOLECULAR HYDROGEN-ATOM ABSTRACTION (1981) (0)
- Confidence in both techniques is thereby enhanced. An up—to—date, comprehensive listing of absolute (1984) (0)
- Configurational Characterization of the 1-(Trimethylsilyl)cyclopropyl Radical. (1986) (0)
- Absolute Rate Constants for the Reactions of Primary Alkyl Radicals with Aromatic Amines(1). (1996) (0)
- The use of deuterated tocopherols to investigaste the uptake and turnover of vitamin E in neural tissues (1990) (0)
- Tetramethyl-ortho-quinodimethane, First Member of a Family of Custom- Tailored Cheletropic Spin Traps for Nitric Oxide. (1992) (0)
- Cover Picture: Isomerization of Triphenylmethoxyl: The Wieland Free-Radical Rearrangement Revisited a Century Later (Angew. Chem. Int. Ed. 34/2010) (2010) (0)
- Spectroscopic and Kinetic Characteristics of Aroyloxyl Radicals. Part 1. The 4-Methoxybenzoyloxyl Radical (1988) (0)
- Additions and Corrections - Dimerization of Northopane-N-oxyl (1973) (0)
- Anchimeric assistance in C-H bond homolysis. Reaction of tert-butoxyl radicals with tetraethyl group 4 compounds (1985) (0)
- Cycloalkylmethyl Radicals. Part 5. 6- to 15-Membered Rings (I): EPR Studies of Ring Conformations and Stereodynamics. (1988) (0)
- Direct Measurement of the Rate Constant for β-Scission of the Cumyloxyl Radical (II) by Laser Flash Photolysis with Time-Resolved IR Detection. (1990) (0)
- Conformational Analysis of the 2,2-Dimethylbutyl Radical by EPR Spectroscopy. (1986) (0)
- Cleaving CC Bonds in Cyclopropenium Ions (1980) (0)
- Di-(1-adamanty1)iminoxy. Preparation and Dipole Moment1 (1974) (0)
- Additions and Corrections - Calorimetric and Equilibrium Studies on Some Stable Nitroxide and Imonoxy Radicals. Approximate O-H Bond Dissociation Energies in Hydroxylamines and Oximes. (1974) (0)
- Absolute Rate Constants for the Reaction of Triethylsilyl Radicals with Ring-Substituted Benzyl Chlorides. (1987) (0)
- DI- AND TRI-TERT.-BUTYLMETHYL, TWO ALIPHATIC RADICALS OF UNUSUAL STABILITY (1973) (0)
- Titelbild: Isomerization of Triphenylmethoxyl: The Wieland Free‐Radical Rearrangement Revisited a Century Later (Angew. Chem. 34/2010) (2010) (0)
- METAL COMPLEXES AS ANTIOXIDANTS PART 1, THE REACTION OF ZINC DIALKYLDITHIOPHOSPHATES AND RELATED COMPOUNDS WITH PEROXY RADICALS (1973) (0)
- Selectivity in the Photochlorination of 2,3-Dimethylbutane with Molecular Chlorine in Noncomplexing Solvents. (1989) (0)
- Stabilisation and Stereodynamics of Free Radicals (1988) (0)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 15, IMINYL RADICALS (1974) (0)
- DIRECT OBSERVATION AND CHEMISTRY OF BIRADICALS FROM PHOTOCHEMICAL DECARBONYLATION OF α-PERPHENYLATED CYCLOALKANONES (1985) (0)
- The non-catalytic oxidation of olefins to epoxides with molecular oxygen (1964) (0)
- Quantum Mechanical Tunneling in Free Radical Reactions (1981) (0)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. 39. BIMOLECULAR SELF-REACTIONS OF SOME N-ALKYLCARBOXYAMIDYL, N-ALKYLSULFONAMIDYL, AND N-ALKYL-N-(ALKOXYCARBONYL)AMINYL RADICALS. INTERMOLECULAR HYDROGEN ATOM ABSTRA (1983) (0)
- Revised assignment of the electron spin resonance spectrum obtained during photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide. The bis(methylthiomethyl) nitroxide radical (1977) (0)
- Cycloalkylmethyl Radicals. Part 2. Axial and Equatorial Cyclohexylmethyl and (4‐Alkylcyclohexyl)methyl Radicals. (1986) (0)
- Kinetic Analysis of Alkane Polychlorination with Molecular Chlorine. Chlorine Atom/Monochloride Geminate Pairs and the Effect of Reactive “Cage Walls” on the Competition Between Monochloride Rotation and Chlorine Atom Escape (1988) (0)
- Application of Photoacoustic Calorimetry to the Measurement of the O-H Bond Strength in Vitamin E (alpha- and delta-Tocopherol) and Related Phenolic Antioxidants(1). (1996) (0)
- KINETIK APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 19, PERSISTENT CYCLOHEXADIENYLS AND RELATED RADICALS (1975) (0)
- Back Cover: Another Unprecedented Wieland Mechanism Confirmed: Hydrogen Formation from Hydrogen Peroxide, Formaldehyde, and Sodium Hydroxide (Angew. Chem. Int. Ed. 29/2018) (2018) (0)
- Reaction of t-butoxy radicals with diborane (1973) (0)
- Perfluoro-tert-butyl, a Reactive, Neutral, Electrophilic Carbon- Centered Radical par Excellence (1997) (0)
- Isomerisation of decatetraenes and dimethyldecatetraenes via pentadienyl and 3-methylpentadienyl radicals (1993) (0)
- Cyclizations of 5‐Hexenyl, 6‐Heptenyl, 7‐Octenyl, and 8‐Nonenyl Radicals. The Kinetic and Regiochemical Impact of Fluorine and Oxygen Substituents. (1999) (0)
- Structural Effects on the Rates of Autoxidation of Liquid Hydrocarbons (1967) (0)
- The Benzoyloxy Radical: Attempted Photochemical Generation for Kinetic Studies (1986) (0)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPEKTROSKOPY PART 10, REACTIONS OF SOME ALKYLAMINO RADICALS IN SOLUTION (1973) (0)
- Studies on Some Trifluoromethyl Nitroxide Radicals by EPR Spectroscopy (1981) (0)
- Pentamethyldisilyl Radical: Absolute Rate Constants for Its Formationand for Some Halogen Abstraction and Addition Reactions. (1987) (0)
- EPR Spectroscopic Study of the Radicals Formed During the Photodecomposition of Some Bis(alkenoyl) Peroxides, a Bis(alkynoyl) Peroxide and Some Peroxydicarbonates. (1991) (0)
- Nitric Oxide Cheletropic Traps (NOCTs) with Improved Thermal Stability and Water Solubility. (1994) (0)
- Kinetics of Cyclopropyl Radical Reactions. Part 2. Studies on the Inversion of Cyclopropyl und 1-Methylcyclopropyl Radicals and on the Kinetics of Some Addition und Abstraction Reactions of 1-Methylcyclopropyl and 1-Methoxycyclopropyl (1986) (0)
- Influence of Aromatic Solvents on the Selectivity for Photochlorination of 2,3-Dimethylbutane with Molecular Chlorine. (1989) (0)
- SOME APPLICATIONS OF FREE RADICAL REARRANGEMENTS (1978) (0)
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