Kenneth G. Caulton
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American inorganic chemist
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Kenneth G. Caultonchemistry Degrees
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Chemistry
Kenneth G. Caulton's Degrees
- PhD Inorganic Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Kenneth G. Caulton Influential?
(Suggest an Edit or Addition)According to Wikipedia, Kenneth G. Caulton is an inorganic chemist who works on, and has made significant contributions to, projects dealing with transition metal hydrides. He is currently Distinguished Professor at Indiana University. Specifically, Caulton has worked on the chemistry of paramagnetic organometallic complexes, metal polyhydride complexes and the dihydrogen ligand, catalytic activation of carbon monoxide and carbon dioxide, and alkoxide chemistry. Caulton's work with transition metal complexes is ultimately aimed to create complexes that exhibit unexpected and novel reactivities.
Kenneth G. Caulton's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Synthesis, structural principles and reactivity of heterometallic alkoxides (1990) (410)
- Solution structure and dynamics of five-coordinate d6 complexes (1975) (199)
- THE INFLUENCE OF PI -STABILIZED UNSATURATION AND FILLED/FILLED REPULSIONS IN TRANSITION METAL CHEMISTRY (1994) (173)
- Chemistry of yttrium triisopropoxide revisited. Characterization and crystal structure of Y5(.mu.5-O)(.mu.3-OPr-iso)4(.mu.2-OPr-iso)4(OPr-iso)5 (1989) (152)
- Alcohol adducts of alkoxides: intramolecular hydrogen bonding as a general structural feature (1990) (150)
- Synthetic methods in transition metal nitrosyl chemistry (1975) (150)
- An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3 (1990) (145)
- Systematics and Future Projections Concerning Redox-Noninnocent Amide/Imine Ligands (2012) (104)
- Structure of tetra-n-butyratodiruthenium chloride, a compound with a strong metal-metal bond (1969) (101)
- A dinuclear cobalt complex featuring unprecedented anodic and cathodic redox switches for single-molecule magnet activity. (2013) (98)
- Syntheses and structures of a series of very low coordinate barium compounds: Ba[N(SiMe3)2]2(THF)2, {Ba[N(SiMe3)2)]2(THF)}2, and {Ba[N(SiMe3)2]2}2 (1991) (98)
- Molecular structure of (.eta.5-C5H5)2Ti(OC2H5)Cl and [(.eta.5-C5H5)Cl2Ti]2O2C2(CH3)4. A structural basis for deoxygenation using titanium (1980) (94)
- Soluble copper hydrides: solution behavior and reactions related to carbon monoxide hydrogenation (1981) (94)
- Three-coordinate Co(I) provides access to unsaturated dihydrido-Co(III) and seven-coordinate Co(V). (2006) (89)
- PI -STABILIZED, YET REACTIVE, HALF-SANDWICH CP*RU(PR3)X COMPOUNDS : SYNTHESIS, STRUCTURE, AND BONDING (1995) (82)
- Homogeneous hydrogenation of carbon monoxide. [Using the cyclopentadienyl compound Cp/sub 2/Ti(CO)/sub 2/] (1977) (81)
- Electronic structure and bonding in hexacarbonylvanadium(1-), hexacarbonylchromium, hexacarbonylmanganese(1+) (1968) (76)
- A Method for Molecular Orbital Calculations for Metal Complexes (1966) (75)
- Characterization of aluminium isopropoxide and aluminosiloxanes (1991) (73)
- Organofluorine binding to sodium and thallium(I) in molecular fluoroalkoxide compounds (1993) (73)
- Computational and Experimental Test of Steric Influence on Agostic Interactions: A Homologous Series for Ir(III) (1999) (73)
- A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper (1986) (72)
- RuHX(CO)(PR3)2: Can .nu.CO Be a Probe for the Nature of the Ru-X Bond? (1994) (71)
- Facile and Reversible Cleavage of C−F Bonds. Contrasting Thermodynamic Selectivity for RuCF2H vs FOsCFH (2000) (70)
- Mechanism of heterolysis of H2 by an unsaturated d8 nickel center: via tetravalent nickel? (2010) (68)
- Hydride Is Not a Spectator Ligand in the Formation of Hydrido Vinylidene from Terminal Alkyne and Ruthenium and Osmium Hydrides: Mechanistic Differences (1998) (67)
- Inertness of the Aryl−F Bond toward Oxidative Addition to Osmium and Rhodium Complexes: Thermodynamic or Kinetic Origin? (1998) (66)
- 14-Electron Four-Coordinate Ru(II) Carbyl Complexes and their Five-Coordinate Precursors : Synthesis, Double Agostic Interactions, and Reactivity (1999) (66)
- Reexamination of the reactions of Ph2P(CH2)nPPh2 (n = 1-4) with RuCl2(PPh3)3 (1984) (65)
- Coordination chemistry of the manganese and rhenium fragments (C5H5)M(CO)2 (1981) (64)
- Influence of the d-Electron Count on CO binding by three-coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni. (2008) (64)
- Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes (1993) (63)
- C−D0 (D0 = π-donor, F) Cleavage in H2CCH(D0) by (Cp2ZrHCl)n: Mechanism, Agostic Fluorines, and a Carbene of Zr(IV) (2001) (63)
- A donor semibridge? Molecular structures of dicyclopentadienyldivanadiumtetracarbonyltriphenylphosphine and dicyclopentadienyldivanadiumpentacarbonyl (1980) (63)
- A facile approach to a d4 RuN: moiety. (2005) (61)
- Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) (1995) (60)
- Alcohol elimination chemistry of tetrakis(tert-butoxocopper) (1990) (59)
- Spectroscopic assessment of the degree of .pi.-stabilization of unsaturation in ruthenium complex, RuH(X)CO(P-tert-Bu2Me)2 (1992) (57)
- Four-coordinate, planar RuII. A triplet state as a response to a 14-valence electron configuration. (2003) (55)
- IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS [V2CL3(THF)6]2[ZN2CL6] (1984) (54)
- A cis-divacant octahedral and mononuclear iron(IV) imide. (2014) (54)
- Silver(I)-Catalyzed Insertion of Carbene into Alkane C–H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe (2012) (52)
- Incorporation of barium for the synthesis of heterometallic alkoxides: synthesis and structures of [BaZr2(O-iso-Pr)10]2 and Ba{Zr2(O-iso-Pr)9}2 (1991) (51)
- Operationally unsaturated pincer/rhenium complexes form metal carbenes from cycloalkenes and metal carbynes from alkanes. (2007) (51)
- Computational Evidence of the Importance of Substituent Bulk on Agostic Interactions in Ir(H)2(PtBu2Ph)2 (1998) (51)
- Factors governing the equilibrium between metalalkyl, alkylidene and alkylidyne: MCX2R, XMCXR and X2MCR (2001) (50)
- Soluble zinc bis(aryloxides) (1986) (49)
- An .eta.4-benzene species mediates acetylene cyclotrimerization (1991) (49)
- Hydrogen binding to and fluxional behavior of Ir(H)2X(P-tert-Bu2R)2 (X = Cl, Br, I; R = Me, Ph) (1994) (48)
- Dinuclear elimination as a route to unusual bridging carbonyls and acetyls in heterobimetallic complexes (1982) (48)
- A bridging acetyl group from the reaction of a dinuclear methyl complex with carbon monoxide (1981) (47)
- Redox chemistry of the triplet complex (PNP)Co(I). (2008) (47)
- Reductive nitrosylation of Group VIIIb compounds (1973) (46)
- RuX(CO)(NO)L2 and Ru(CO)(NO)L2+: Ru(0) or Ru(II) or In Between? (1997) (46)
- Reactivity of the molecular hydrogen complex [IrH4(PMe2Ph)3]BF4 towards olefins. The origin of stereochemical rigidity of M(PR3)3(olefin)2 species (1990) (46)
- Coordinated carbenes from electron-rich olefins on RuHCl(PPr3i)2 (2000) (45)
- [(tBu2PCH2SiMe2)2N]RhI? Rapidly Reversible H−C(sp3) and H−C(sp2) Bond Cleavage by Rhodium(I) (2008) (45)
- Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba6(O)(OBut)11(OCEt2CH2O)(thf)3](thf = tetrahydrofuran) (1990) (45)
- NEW ENTRIES TO AND NEW REACTIONS OF FLUOROCARBON LIGANDS (1997) (45)
- Facile hydrogenation of N2O by an operationally unsaturated osmium polyhydride. (2007) (45)
- Carbon-oxygen bond scission in heterometallic alkoxides: formation and structure of K4Zr2O(OCHMe2)10 (1990) (45)
- Osmium Converts Terminal Olefins to Carbynes: α-Hydrogen Migration Redox Isomers with Reversed Stability for Ruthenium and for Osmium (1998) (44)
- Dinuclear barium alkoxides and siloxides displaying variable coordination numbers and asymmetric dispositions of ligands (1992) (44)
- Low-temperature infrared study of d0 carbonyl complexes (1980) (44)
- Angular ligand constraint yields an improved olefin aziridination catalyst. (2003) (43)
- R-Group reversal of isomer stability for RuH(X)L2(CCHR) s. Ru(X)L2(CCH2R): access to four-coordinate ruthenium carbenes and carbynes (2000) (43)
- New Access to Vinylidenes from Ruthenium Polyhydrides (1997) (43)
- Yttrium and lanthanum silyloxide complexes (1991) (42)
- Facile synthesis and structural principles of the strontium phenoxide Sr4(OPh)8(PhOH)2(THF)6 (1990) (42)
- The First η2-CH2Cl2 Adduct of Ru(II):[RuH(η2-CH2Cl2)(CO)(PtBu2Me)2][BAr‘4] (Ar‘ = 3,5-C6H3(CF3)2) and Its RuH(CO)(PtBu2Me)2+ Precursor (1997) (42)
- Spin state, structure, and reactivity of terminal oxo and dioxygen complexes of the (PNP)Rh moiety. (2008) (42)
- Photoreduction of cerium (IV) in Ce sub 2 (O sup i Pr) sub 8 ( sup i PrOH) sub 2. Characterization and structure of Ce sub 4 O(O sup i Pr) sub 13 ( sup i PrOH) (1991) (41)
- A comprehensive view of M–H addition across the RCCH bond: frustration culminating in ultimate union (2001) (41)
- A 14-Electron Ruthenium(II) Hydride, [RuH(CO)(PtBu2Me)2]BAr‘4 (Ar‘ = 3,5-(C6H3)(CF3)2): Synthesis, Structure, and Reactivity toward Alkenes and Oxygen Ligands (2000) (39)
- Exploring the reactivity of four-coordinate PNPCoX with access to three-coordinate spin triplet PNPCo. (2007) (39)
- Primary steps in the hydrolyses of two heterometallic alkoxides. Characterization of lithium-titanium and barium-zirconium isopropoxides [LiTiO(O-iso-Pr)3]4 and BaZr4(OH)(O-iso-Pr)17 (1993) (38)
- The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis (1994) (38)
- .eta.3-MeC(CH2PPh2)3/rhodium complexes utilize phosphine arm dissociation mechanisms at 25.degree. (1990) (37)
- Synthesis and Structure of [Ba3(OSiPh3)6(THF)] · 0.5 THF, a Trinuclear Barium Siloxide Containing Low‐Coordinate Barium Ions (1990) (37)
- Multiple structural variants of LnCuI(.mu.-X)2CuILn (n = 1, 2). Influence of halide on a "soft" potential energy surface (1992) (37)
- An unprecedented ligand set and coordination geometry for copper(I) (1983) (37)
- Distinct structures for ruthenium and osmium hydrido halides: Os(H)3X(PiPr3)2 (X = Cl, Br, I) are nonoctahedral classical trihydrides with exchange coupling (1994) (37)
- Comparison of carbon monoxide and nitrogen as ligands in transition metal complexes (1970) (37)
- Transition-metal-mediated hydrogenation of carbon monoxide to olefins: intermediacy of coordinated carbenes (1981) (37)
- Assessment of the electronic structure of 2,2'-pyridylpyrrolides as ligands. (2011) (37)
- C-(Halide) Oxidative Addition Routes to Ruthenium Carbenes. (1999) (37)
- Oxidation of coordinated nitric oxide by free nitric oxide (1974) (37)
- Aromatic vs aliphatic C-H cleavage of alkyl-substituted pyridines by (PNPiPr)Re compounds. (2004) (36)
- Acetylene isomerization by manganese(I): preparation and structure of (C5H5)2Mn2(CO)4CCH2 (1979) (36)
- OSH5(PME2PH)3+ : STRUCTURE, REACTIVITY, AND ITS USE AS A CATALYST PRECURSOR FOR OLEFIN HYDROGENATION AND HYDROFORMYLATION (1994) (36)
- Probing the steric and electronic characteristics of a new bis-pyrrolide pincer ligand. (2014) (36)
- Preparation and Characterization of Mono-cyclopentadienylvanadium Dihalide Bis-phosphine Complexes; Crystal Structure of (η5-C5H5)VCl2(PMe3)2 (1983) (36)
- CHARACTERIZATION AND REACTIVITY OF AN UNPRECEDENTED UNSATURATED ZERO-VALENT RUTHENIUM SPECIES : ISOLABLE, YET HIGHLY REACTIVE (1996) (36)
- Synthesis, molecular structures, properties and reactions of halo- and carbonyl(amine)copper(I) complexes (2010) (35)
- Modulation of reactivity and stereochemistry of substrate binding by the group X in RuHX(CO)(P-tert-Bu2Me)2 (1993) (35)
- Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design. (2015) (35)
- A Soluble Alkoxide of Barium with a Cubane Structure (1994) (35)
- Preparation, crystal and molecular structure of a hydrocarbon soluble, volatile oxo-alkoxide of barium: H4Ba6(µ6-O)(OCH2CH2OCH3)14 (1990) (35)
- TERT-BUTYL IS SUPERIOR TO PHENYL AS AN AGOSTIC DONOR TO 14-ELECTRON IR(III) (1997) (34)
- Multiplying the electron storage capacity of a bis-tetrazine pincer ligand. (2014) (34)
- Transformation of acyclic alkenes to hydrido carbynes by (PNP(R))Re complexes. (2004) (34)
- Reversible opening and closing of hetero trimetallic units in (C5H5)2Y(THF)Re2H7(PMe2Ph)4 and (C5H5)2LuRe2H7(PMe2Ph)4 (1990) (34)
- Synthesis and structural characterization of the alkaline earth aryloxide aggregates H[sub 2]Ba[sub 8]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6] and H[sub 2]Sr[sub 6]Ba[sub 2]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6]. A new structural type displaying metal ion site selectivity (1993) (34)
- Cleavage of H−C(sp2) and C(sp2)−X Bonds (X = Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl(PiPr3)2]2 (2000) (34)
- Structure and H(2)-Loss Energies of OsHX(H(2))(CO)L(2) Complexes (L = P(t-Bu)(2)Me, P(i-Pr)(3); X = Cl, I, H): Attempted Correlation of (1)J(H-D), T(1min), and DeltaG(). (1996) (34)
- Reactivity of (dihydrogen)dihydridotris(triphenylphosphine)ruthenium. Dimerization to form (PPh3)2(H)Ru(.mu.-H)3Ru(PPh3)3 and decarbonylation of ethanol under mild conditions (1991) (33)
- Triangular phenoxide aggregates of calcium, strontium, and barium : a comparison (1993) (33)
- Enhanced reactivity from noninnocent behavior by an alkoxide ligand in Cp*RuP(OR): toward the mechanism of alcohol elimination (1992) (32)
- Vinyl C-F cleavage by Os(H)3Cl(P(i)Pr3)2. (2002) (32)
- Alkoxide .pi.-donation to iridium(III) (1991) (32)
- Synthetic and mechanistic features of alcohol elimination between gold alkoxides and rhenium polyhydrides. Metal polyhedron reconstruction upon protonation (1987) (32)
- Acetaldehyde hydration by zinc-hydroxo complexes: Coordination number expansion during catalysis. Methylation of zinc bound thiolates: A model for cobalamine independent methionine synthase (1999) (32)
- Crystal and molecular structure of bis(triphenyylphosphine)tetrakis(dimethylglyoximato)dirhodium. Length of a rhodium(II)-to-rhodium(II) single bond (1971) (32)
- Formation of a heterometallic carbon dioxide complex with concurrent reduction of carbon dioxide (1986) (32)
- Ligand redistribution and carbonyl insertion: The effect of competitive π-donation (1980) (32)
- Anhydrous yttrium acetylacetonate and the course of thermal dehydration' of Y(acac)[sub 3][center dot]3H[sub 2]O (1993) (32)
- Cleavage of F–C(sp2) bonds by MHR(CO)(PtBu2Me)2 (M = Os and Ru; R = H, CH3 or Aryl): Product dependence on M and R (2006) (31)
- A comparative study of olefin or acetylene insertion into Ru–H or Os–H of MHCl(CO)(phosphine)2 (2001) (31)
- Synthesis and reactivity of a heterometallic carbon dioxide complex (1990) (31)
- Reactivity of the hydrido/nitrosyl radical MHCl(NO)(CO)(P(i)Pr(3))(2), M = Ru, Os. (2004) (31)
- A bimetallic vanadium (I) polyhydride (1983) (31)
- Yttrium-89 and silicon-29 NMR spectra as probes of solution dynamics: ligand and metal polyhedral rearrangements in yttrium aggregates (1992) (31)
- CARBENE COMPLEXES FROM OLEFINS, USING RUHCL(PIPR3)2. INFLUENCE OF THE OLEFIN SUBSTITUENT (1998) (31)
- Hydride-rich zirconium-osmium and zirconium-rhenium dimers (1984) (31)
- Reducing power of three-coordinate cobalt(I). (2006) (31)
- Structure and bonding of (.mu.-dicarbido)hexa-tert-butoxyditungsten, (tert-BuO)3W.tplbond.CC.tplbond.W(O-tert-Bu)3 (1992) (30)
- CONCERNING THE STRUCTURE AND STABILITY OF A COPPER(I) ALKOXY CARBONYL (1983) (30)
- Synthesis and molecular structure of a mononuclear barium aryloxide-ethanolamine complex, Ba(2,6-tert-Bu2C6H3O)2(HOCH2CH2NMe2)4.cntdot.2C7H8, exhibiting extensive hydrogen bonding (1991) (30)
- Synthesis, structure and applications of transition-metal polyhydride anions (1989) (30)
- An Infrared Study of Monosulfatopentaaquochromium(III) Chloride (1965) (29)
- Triple benzylic dehydrogenation by osmium in an amide ligand environment (2006) (29)
- Spectroscopic investigation of the reactivity of Cp*Ru(PPr-iso2Ph)X toward molecular hydrogen and silanes: formation in solution of Cp*Ru(PPr-iso2Ph)(H)3 and Cp*Ru(PPr-iso2Ph)(H)2Y (Y = halide, OR, and SiR'3) (1993) (29)
- Doubly-hydrated hexafluoroacetylacetone as a tetradentate ligand: Synthesis, magnetochemistry, and thermal transformations of a Mn[sup III][sub 2] complex (1993) (29)
- Intramolecular rearrangements of M(bidentate phosphine)2XY species (1975) (29)
- Energy Levels, Spin Densities, and the Nephelauxetic Effect in Metal Hexafluorides (1966) (29)
- Characterization and structure of some four-coordinate methylcopper(I) compounds (1989) (29)
- Competition between Steric and Electronic Control of Structure in Ru(CO)2L2L‘ Complexes (1997) (29)
- Deprotonation of uncharged transition-metal dihydrogen complexes with copper alkoxides, characterization of the heterometallic complexes (PR3)xMHyCu(PR3) (M = iron, tungsten), and x-ray crystal structure of (PEtPh2)3FeH3Cu(PEtPh2) (1991) (29)
- Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems. (2004) (28)
- Structure/Volatility Correlation of Sodium and Zirconium Fluoroalkoxides (1995) (28)
- [Ni{N(SiMe2CH2PtBu2)2}]+: direct observation of transannular Si-C(sp3) bond coordination. (2008) (28)
- Reactivity of [RuHCl(PiPr3)2]2 with functionalized vinyl substrates. The H2 ligand as a sensitive probe of electronic structure. (2000) (28)
- Reversible dehydrogenation of a heterobimetallic polyhydride compound (1992) (28)
- Nonlinear coordination of NO in Mo(NO)2Cl2(PPh3)2 (1972) (28)
- Reactions of (PiPr3)2OsH6 Involving Addition of Protons and Removal of Electrons. Characterization of (PiPr3)2Os(NCMe)xHyz+ (x = 0, 2, 3; y = 1, 2, 3, 4, 7; z = 1, 2), Including Dicationic .eta.2-H2 Complexes (1995) (28)
- Low-pressure chemical vapor deposition of tungsten carbide (WC) thin films (1991) (28)
- Isolable, Unsaturated Ru(0) in Ru(CO)2(PtBu2Me)2: Not Isostructural with Rh(I) in Rh(CO)2(PR3)2+ (1995) (27)
- STRUCTURAL AND DYNAMIC PROPERTIES OF OSH2X2L2 (X=CL, BR, I; L=PIPR3) COMPLEXES : INTERCONVERSION BETWEEN REMARKABLE NON-OCTAHEDRAL ISOMERS (1995) (27)
- Direct observation of .alpha.-hydrogen transfer from alkyl to alkylidyne ligands in (Me3CCH2)3W:CSiMe3. Kinetic and mechanistic studies of alkyl-alkylidyne exchange (1991) (27)
- Paramagnetic monocyclopentadienyl hydrocarbyl and borohydride compounds of vanadium(II) and vanadium(III). Synthesis, structure, and reactivity (1987) (27)
- Oxidatively Induced Reductive Elimination from Ru(C2Ph)2(CO)(PtBu2Me)2 and Ru(CHCHPh)(C2Ph)(CO)(PtBu2Me)2 (1995) (27)
- Multiple mixed-metal condensation leading to the trigonal bipyramidal iridium copper hexahydride Ir2Cu3H6(MeCN)3(PMe2Ph)63+ (1985) (27)
- A π-Basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand (2003) (27)
- O/C bond cleavage of CO2 by NiI. (2008) (27)
- SOLUTION BEHAVIOR OF TRIPHENYLPHOSPHINE COMPLEXES OF RUTHENIUM(II) (1974) (27)
- Potassium triphenylsiloxide “-ate” compounds of tin(II): Molecular and separated ion forms and variable potassium coordination numbers (1992) (27)
- HETEROBIMETALLIC HYDROGEN TRANSFER IN THE REDUCTION OF METAL ACYL COMPLEXES (1980) (26)
- Conversion of Ethylene to Hydride and Ethylidyne by an Amido Rhenium Polyhydride (2003) (26)
- Nucleo- and electrophilicity of (C5H5)2Mn2(CO)4(.mu.-.eta.1-CCH2). New paths to carbyne and allene ligands (1980) (26)
- CO-Induced C(sp2)/C(sp) Coupling on Ru and Os: A Comparative Study (1998) (26)
- Büchner Reactions Catalyzed by a Silver(I) Pyridylpyrrolide: Understanding Arene C═C Insertion Selectivity (2013) (26)
- Three-coordinate NiII: tracing the origin of an unusual, facile Si-C(sp3) bond cleavage in [(tBu2PCH2SiMe2)2N]Ni+. (2011) (26)
- Synthesis of [Cu3Os3H9(PMe2Ph)9], a Bimetallic Raft, by Reductive Elimination of Alcohol or H2 (1986) (26)
- Quantum Exchange Coupling: A Hypersensitive Indicator of Weak Interactions (1997) (26)
- Oligomerization and structural variation of alkali metal silyloxides (1991) (26)
- Diminishing π-Stabilization of an Unsaturated Metal Center: Hydrogen Bonding to OsHCl(CO)(PtBu2Me)2 (1998) (25)
- Cyclopentadienylvanadium(III) and -vanadium(II) Methyl, Phenyl, and Borohydride Compounds (1985) (25)
- Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(II) and Os (2002) (25)
- Mechanistic features of carbon-hydrogen bond activation by the rhenium complex ReH7[P(C6H11)3]2 (1984) (25)
- Pentahydridorhenium: crystal and molecular structure of ReH5(PMePh2)3 (1985) (25)
- Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply β-diketiminate variants. (2012) (25)
- CONTROLLED STOICHIOMETRIC INCORPORATION OF TI(IV) INTO A ZR(IV) PINACOLATE (1998) (25)
- &mgr;-Benzene in a Heterobimetallic Fluoroalkoxide: CH.FC Hydrogen Bonding? (1997) (24)
- [Ru(Ph)(CO)(PtBu2Me)2]+: A Unique 14-Electron Ru11 Complex with Two Agostic Interactions† (1997) (24)
- Double C(sp3) dehydrogenation as a route to coordinated Arduengo carbenes: experiment and computation on comparative ?-acidityElectronic supplementary information (ESI) available: crystallographic data. See http://www.rsc.org/suppdata/nj/b3/b305249d/ (2003) (24)
- Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines. (1997) (23)
- Radical (NO) and nonradical (N(2)O) reagents convert a ruthenium(IV) nitride to the same nitrosyl complex. (2007) (23)
- Bimetallic halides. Crystal structure of and ethylene polymerization by vanadium(II) chloride-zinc chloride-tetrahydrofuran (VCl2.ZnCl2.4THF) (1985) (23)
- Geminal dehydrogenation of a C(sp3) CH2 group by unsaturated Ru(II) or Os(II) (2000) (23)
- The first double oxidative addition of CH2Cl2to a metal complex: facile synthesis of[Ru(CH2)Cl2{P(C6H11)3}2] (1997) (23)
- Dinuclear elimination from rhenium hydrides and trimethylaluminum: rhenium/aluminum polyhydrides (1984) (23)
- Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. (2008) (23)
- New approaches to functionalizing metal-coordinated N2. (2013) (23)
- PHOTOCHEMISTRY OF TRANSITION-METAL POLYHYDRIDES: DIMERIZATION OF TRIS(DIMETHYLPHENYLPHOSPHINE)PENTAHYDRORHENIUM FOLLOWING PHOTODISSOCIATION OF PHOSPHINE (1981) (23)
- Aluminium alkyls and transition-metal hydrides: Nonclassicaladduct structure and catalysis of hydrogen migration (1984) (23)
- Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand (2002) (22)
- New Features of Bis(phosphinimine)-“carbene” Binding to RuII (2005) (22)
- Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium (1992) (22)
- Redox and Lewis Acid Reactivity of Unsaturated OsII (2010) (22)
- Structure, dynamics, and comparative stability of a mixed-ligand compound of tin(II) (1989) (22)
- Mechanism of N/O bond scission of N2O by an unsaturated rhodium transient. (2011) (22)
- THERMAL AND PHOTOCHEMICAL REACTIVITY OF BIS(CYCLOPENTADIENYL)PENTACARBONYLDIVANADIUM (1980) (22)
- Ligand Scavenging and Catalytic Utilization of the Phototransient ReH5(PMe2Ph)2 (1981) (22)
- Halide abstraction from TiCl3 by ZnCl2 (1984) (22)
- Tetraethylborate as an ethyl transfer reagent (1990) (22)
- Solution and solid–gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda=Me2NC2H4NMe2) (2000) (22)
- Coordination and electronic characteristics of a nitrogen heterocycle pincer ligand (2016) (21)
- N-PtIV-H/N-H...PtII intramolecular redox equilibrium in a product of H-C(sp2) cleavage and unusual alkane/arene C-H bond selectivity of ([2.1.1]pyridinophane)PtII(CH3)+. (2003) (21)
- Multifunctional Behavior by a Bis-(phosphinimino)methanide Ligand: η2- vs η3-coordination vs Bronsted Basicity (2004) (21)
- 16-Electron Ruthenium(0) Complexes Containing the Ru(NO)L2+ Substructure: Planar RuCH3(NO)L2 vs Sawhorse [Ru(NO)(CC(SiMe3)2)L2]+ (2000) (21)
- Characterization of PtH3(PtBu3)2+ as the First Dihydrogen Complex of d8, Pt(II) (1994) (21)
- A triangular heterometallic siloxide containing barium (1991) (21)
- Dealkylation of zirconium(IV) by borane: the intimate mechanism of an alkyl transfer reaction (1982) (21)
- Influence of Lead(II) Lone Pairs on the Serpentine Structures for Heterometallic Alkoxides (1995) (21)
- A Multifunctional Pincer Ligand Supports Unsaturated Cobalt: Five Functionalities in One Pincer. (2017) (21)
- Nitrosyl transfer reactions (1973) (21)
- Synthesis and thermal decomposition of copper(I) silyloxide complexes. X-ray crystal structures of [Cu(OSiPh3)]4 and [Cu(OSiPh3)(PMe2Ph)]2 (1992) (21)
- Acidolysis of rhodium complexes [MeC(CH2PPh2)3]Rh(CH3)n: controlled creation of unsaturation (1991) (20)
- Monocyclopentadienyl zirconium(IV) complexes (1981) (20)
- Aggregation and solvation of a lithium aryloxide (1984) (20)
- Synthesis of tris(triphenylsiloxy)yttrium and derivatives: Crystal structure of (Y(OSiPh sub 3 ) sub 3 (THF sub 3 ))ter dot THF (1989) (20)
- Copper(I) and silver(I) diiridium polyhydrides (1984) (20)
- Eta-6 bonding of benzene to potassium in [(C6H6)KOSiMe2Ph]4 (1991) (20)
- Relationship of adduct formation to bimolecular reductive elimination from rhodium polyhydrides (1986) (20)
- New approach to Ru(II) pincer ligand chemistry. Bis(tert-butylaminomethyl)pyridine coordinated to ruthenium(II). (2000) (20)
- Heterometallic alkoxides of zirconium with tin(II) or lead(II) (1996) (20)
- An electron-excessive nitrosyl complex: reactivity of a ligand-centered radical leading to coordinated HNO. (2002) (20)
- Hydrogen Migration and HCl Elimination Promoted by Metal-Centered Nucleophilic Attack on Osmium Hydrido−Carbynes (1998) (20)
- Metal clusters in catalysis: Hydrocarbon reactions. (1976) (20)
- The transient radical tris(dimethylphenylphosphine)trihydridoiridium(1+): a Bronsted acid (1991) (19)
- Facile olefin hydrogenation with an osmium dihydrogen complex (1989) (19)
- Control of H-C(sp3) bond cleavage stoichiometry: clean reversible alkyl ligand exchange with alkane in [LPt(Alk)(H)2]+ (L=[2.1.1]-(2,6)-pyridinophane). (2002) (19)
- Coupling of terminal alkynes by RuHXL2 (X = Cl or N(SiMe3)2, L = PiPr3) (2008) (19)
- Spectra and structure of tri-.mu.-triphenylphosphinimine-bis(tricarbonylmolybdenum). New bonding mode for phosphinimines (1974) (19)
- N2 provides insight into the mechanism of H-C(sp3) bond cleavage. (2005) (19)
- A lipophilic salt of a transition-metal polyhydride: KOsH3(PMe2Ph)3 (1985) (19)
- Oxide formation upon thermolysis of a Pb(II)/Zr(IV) alkoxide (1996) (18)
- X-ray diffraction and fluorine-19 and thallium-205 NMR evidence for electrophile binding to an organofluorine substituent (1992) (18)
- [2.1.1]-(2,6)-Pyridinophane(L)-controlled alkane C–H bond cleavage: (L)PtMe2H+ as a precursor to the geometrically “tense” transient (L)PtMe+ (2003) (18)
- Design and synthesis of tridentate facially chelating ligands of the [2.n.1]-(2,6)-pyridinophane family. (2003) (18)
- The origin of structural variety of alkyne complexes of d8 metals. An example of structural isomerism (1990) (18)
- Oxidation and acidolysis of MoH/sub 4/(PR/sub 3/)/sub 4/ (1982) (18)
- Alkyne hydrogenation by a dihydrogen complex: synthesis and structure of an unusual iridium-butyne complex (1989) (18)
- A comparison of heterometallic alkoxide molecules containing copper(I) or copper(II) and zirconium (1993) (18)
- Site Selectivity in Electrophilic (H+, CH3+) Abstraction on Os(H)2X2(PiPr3)2 (1996) (18)
- Ligand influence on metal aggregation: a unique bonding mode for pyridylpyrrolides. (2010) (18)
- Conversion of carbon dioxide to carbonate using a rhodium .mu.-hydroxy species (1987) (18)
- GAS/SOLID REACTIVITY OF UNSATURATED RUTHENIUM-CONTAINING MOLECULAR SOLIDS (1997) (17)
- 2,2'-Pyridylpyrrolide ligand redistribution following reduction. (2013) (17)
- A new class of electron-rich unsaturated molecules: Ru2HnX4-n(PiPr3)4, X = anion. (2000) (17)
- Protonation of W (CO)3(PCy3)2 (1991) (17)
- Synthesis and thermal and hydrolytic conversion of heterometallic copper oxide-alkoxides (1994) (17)
- Reactivity of the terminal oxo species (((t)Bu2PCH2SiMe2)2N)RhO. (2013) (17)
- Chemical Vapor Deposition of Metal Fluorides Using Sodium and Zirconium Fluoroalkoxides (1994) (17)
- Conformational stability and ring-size integrity of cyclic polyphosphines (1975) (17)
- Identification of an elusive catalyst: IrH(η2-C6H4PtBu2) (Cl)(PtBu2Ph) as a precursor for C=C bond migration (1996) (17)
- Ligand Design toward Multifunctional Substrate Reductive Transformations. (2017) (17)
- Silyl Migration of Me3SiCCPh Coordinated to [RuH(CO)(PtBu2Me)2]BAr‘4 Can Be Reversed: Synthesis and Structure of [Ru(CHC(SiMe3)(Ph))(CO)(PtBu2Me)2]BAr‘4 (1999) (17)
- Si-N bond hydrolysis furnishes a planar 4-coordinate 14-electron Ru(II) complex with a triplet ground state. (2006) (16)
- The effect of one valence electron: contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to understand the half-bent NiNO unit. (2008) (16)
- Electronic spectra of hexanitrometallates (1967) (16)
- Attempted oxidative generation of a dihydrogen complex (1993) (16)
- Facile C(sp2)/O2CR bond cleavage by Ru or Os (2003) (16)
- Influence of chelate substituents on the structure and spin state of unsaturated [N(SiMe2CH2PtBu2)2]Ru-X. (2007) (16)
- Structure and dynamics of catenated phosphorus(III) dianions (1975) (16)
- Origin of Different Coordination Polyhedra forCu[CF3C(O)CHC(O)CF3]2L, (L = H2O, NH3) (1995) (16)
- Synthesis, structural characterization, thermolysis and volatility study of the Schiff base complex Cu[CH3C(O)CHC(NCH2CH2OCH3)CH3]2 (2001) (16)
- Mechanistic and thermodynamic aspects of methylene transfer from CH2N2 to MHCl(CO)L2 (M=Ru, Os; L=tertiary phosphine): non-least motion behavior and extreme dependence on phosphine identity (1998) (16)
- Phosphine Dissociation Mediates C−H Cleavage of Fluoroarenes by OsH(C6H5)(CO)(PtBu2Me)2 (1999) (16)
- Simultaneous photodissociation of hydrogen and dimethylphenylphosphine from OsH4(PMe2Ph)3: production of dimeric and paramagnetic osmium polyhydrides (1990) (16)
- Stepwise reductive acidolysis of tetrahydrotris(dimethylphenylphosphine)osmium (OsH4(PMe2Ph)3). Mechanism of hydrogen elimination/ligand addition (1984) (16)
- Halide abstraction from titanium(III) chloride by zinc chloride (1984) (16)
- Analysis of the ligand field spectrum of pentacyanocobaltate(II) (1968) (16)
- Molecular structure and solution dynamics of (.eta.5-C5H5)Ni(PPh3)S2COC2H5 (1980) (16)
- Tris(dimethylphenylphosphine)tetrahydridoiridium(1+) ion: its characteristic reactivity and use as a catalyst for isomerization of tris(dimethylphenylphosphine)trihydridoiridium (1985) (15)
- Bis[tris(dimethylphosphinomethyl)ethane]hydridochromium(1+) tetraethylborate(1-): the first synthesis of a cationic hydride complex from triethylborate(1-) (1987) (15)
- Nitrogen-ligated iron complexes: photolytic approach to the FeN+ moiety. (2008) (15)
- Synthesis and oxidative reactivity of 2,2'-pyridylpyrrolide complexes of Ni(II). (2013) (15)
- Solution and Solid-State Structure of Ru(CO)2(Bu2PtC2H4PtBu2): Square Planar and Monomeric? (1999) (15)
- Heterometallic species containing Cp2MH2 (MMo and W) and Cu+ or Ag+ are inner sphere redox intermediates (1992) (15)
- New d4 dihydrides of Ru(IV) and Os(IV) with π-donor ligands: M(H)2(chelate)(PiPr3)2 with chelate =ortho-XYC6H4 with X, Y = O, NR; R = H or CH3 (2005) (15)
- Redox-active ligand controlled selectivity of vanadium oxidation on Au(100) (2018) (15)
- Isomeric Hydrido/Vinylidene, MH(halide)(CCH2)L2, and Ethylidyne, M(halide)(C−CH3)L2 (M = Os, Ru; L = Phosphine), Are Energetically Similar but Not Interconverting (1998) (15)
- Double silyl migration converting ORe[N(SiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] substructures (2002) (15)
- Allene formation within the coordination sphere. Synthesis and crystal structure of (C5H5)2Mn2(CO)3(H2CCCH2) (1980) (15)
- Amido/phosphine pincer hydrides of ruthenium (2003) (15)
- Surprising isomer preference on Ir(III), favoring facile H-C(sp(3)) bond cleavage. (2009) (15)
- Rational construction of mixed-metal alkoxides (1990) (15)
- Transition metal chlorides are Lewis acids toward terminal chloride attached to late transition metals. (2014) (15)
- Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides (2004) (15)
- Further studies on the molecular dynamics of the four-electron bridging carbonyl (1982) (14)
- A Multifunctional Pincer Ligand for Cobalt-Promoted Oxidation by N2 O. (2018) (14)
- Facile C(sp(2))/OR bond cleavage by Ru or Os. (2001) (14)
- A PNNH Pincer Ligand Allows Access to Monovalent Iron. (2018) (14)
- An iridium-pyridylpyrrolide complex exhibiting reversible binding of H2. (2012) (14)
- Synthesis and thermolytic behavior of mixed-valence homo- and heterometallic group 14 alkoxides (1998) (14)
- Deprotonation, Chloride Abstraction, and Dehydrohalogenation as Synthetic Routes to Bis‐Pyrazolate Pyridyl Iron(II) Complexes (2017) (14)
- HINDERED ROTATION ABOUT SINGLE BONDS IN RUHX(CO)(PTBU2ME)2 AND IRHCL2(PTBU2ME)2 (1995) (14)
- Coordination chemistry of tripyridinedimethane. (2002) (14)
- Borohydride/ethanol reduction of RuCl3(PMe2Ph)3 (1984) (14)
- Reactivity of RuCl(2)(CO)(P(t)()Bu(2)Me)(2) toward H(2) and Brønsted Acids: Aggregation Triggered by Protonation and Phosphine Loss. (1996) (14)
- Molecular Routes to Metal−Carbides, −Nitrides, and −Oxides. 3.1 Chemical Vapor Deposition Employing X3W⋮*CCMe3, Where X = CH2CMe3, OtBu, and OtBu-d9 and *C = 12C or 13C, and a Comparison with the Chemistry of (tBuO)3W⋮N (1998) (14)
- Effect of Lewis acidity on the synthesis of RuHCl(CO)(phosphine)(2): subtle influence of steric and electronic effects among P(i)Pr(3), P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3)), and P(i)Pr(2)Me. (2001) (14)
- Mechanistic Understanding of a Silver Pyridylpyrrolide as a Catalyst for 3 + 2 Cyclization of a Nitrile with Diazo Ester (2014) (13)
- Preparation and Structures of Arylmolybdenum(6+) Nitrido Compounds: (2,4,6-Me3C6H2)3Mo.tplbond.N and (2-Me2NCH2C6H4)2(tBuO)Mo.tplbond.N (1995) (13)
- Generation and reactivity of unsaturated iridium and rhodium dimethyl complexes (1990) (13)
- Structural distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and their influence on intramolecular fluxionality and quantum exchange coupling. (2000) (13)
- An evaluation of monovalent osmium supported by the PNP ligand environment. (2011) (13)
- HX elimination from Ir(H)2X(PBu2tPh)2 promoted by CO coordination: assessment of X ligand influence (1998) (13)
- Unusual selectivity of a (pincer)Ni-hydride reacting with CO2. (2009) (13)
- Rhodium(II)-to-rhodium(II) single bond in bis(triphenylphosphine)tetrakis(dimethylglyoximato)dirhodium (1969) (13)
- MECHANISTIC STUDY OF IR(H)2-ASSISTED TRANSFORMATIONS OF ETHYNE : CYCLOTRIMERIZATION, COOLIGOMERIZATION WITH ETHENE, AND REDUCTIVE COUPLING (1995) (13)
- FLUORO-LIGAND PROMOTION OF C-H ACTIVATION (1997) (13)
- Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron Complexes. (2020) (13)
- Unexpected selectivity in electrophilic attack on (PNP)RuN (2010) (13)
- Low-coordinate yttrium in an oxygen ligand environment. Solid-state and solution characterization of hexakis(triphenylsiloxo)diyttrium (1991) (13)
- Unsaturated Ru(0) species with a constrained bis-phosphine ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]. (2000) (13)
- A loss of innocence? Charge-transfer interactions with bis(triphenylphosphoranylidene)ammonium cation (Ph3PNPPh3+) as electron acceptor (1993) (13)
- Oxidative Addition of a Si−C(sp) Bond to Ruthenium: Synthesis and Reactivity of Ru(SiMe3)(C⋮CSiMe3)(CO)(PtBu2Me)2 (1997) (13)
- Structural determination of [(C5H5)2Mo(H)CO][(C5H5)Mo(CO)3] (1979) (13)
- Hydrocarbyl ligand "tuning" of the PtII/IV redox potential. (2004) (13)
- Activation and stoichiometric reduction of carbon monoxide (1981) (13)
- A CASE OF C-H ACTIVATION (ORTHO METALATION) WHICH IS REVERSIBLE AT 25 C (1997) (12)
- Exceptionally facile CO addition to a saturated ruthenium complex. (2005) (12)
- Dehydrohalogenation for facile generation of unsaturated ruthenium(0) (1993) (12)
- Condensation of 2-Pyridylmethyllithium Nucleophiles and Pyridine Electrophiles as a Convenient Synthetic Route to Polydentate Chelating N-Donor Ligands (2002) (12)
- Intramolecular rearrangement of pentacoordinate nitrosyl complexes (1973) (12)
- ?-Donor olefin substituents alter olefin binding to CpFe(CO)2+Electronic supplementary information available: selected bond lengths and angles in CpFe(CO)2(H2C?CHNMe2)+ and CpFe(CO)2(H2C?CHOEt)+; calculated orbital occupancies and natural charges in the iron-olefin complex and the free olefin. See h (2003) (12)
- An Unusual Example of CH Oxidative Addition following Phosphine Association: Mechanism of Formation and Reactivity of Cp*Ru(.mu.-H)(.mu.-.eta.3,.eta.1-iPrNC(Me)CHHagostic)RuCp* (1995) (12)
- The reactivity of Cp2V2(CO)5 towards alkynes (1983) (12)
- SYNTHESIS AND CHARACTERIZATION OF VOLATILE SODIUM YTTRIUM FLUOROALKOXIDES.STRUCTURE OF NA3Y(OCH(CF3)2)6(THF)3 AND NA2Y(OCME(CF3)2)5(THF)3 (1995) (12)
- Assessment of the Bonding in CpRu(PR3)X (X = F, Cl, OSiH3, OCH3) (1994) (12)
- HALIDE ABSTRACTION FROM VANADIUM TRICHLORIDE BY ZINC CHLORIDE. CRYSTAL STRUCTURE OF VANADIUM TRICHLORIDE.ZINC CHLORIDE.4 TETRAHYDROFURAN.2 WATER (1985) (12)
- Facile Insertion of Terminal Acetylenes into the RuII−NR2 Bond of a 14-Valence-Electron Complex (2004) (12)
- Terminal Acetylenes React to Increase Unsaturation in [(tBu2PCH2SiMe2)2N]Re(H)4 (2004) (12)
- Fate of CH2CHE (E = H, OMe) in the Presence of Unsaturated Ru(X)(H)L2q+(X = Cl,q= 0; X = CO,q= 1): Highly Sensitive to X and E (2000) (12)
- Os(H)2NO(PiPr3)2+: Mechanism and Energetics of a Room Temperature Reversible Ethyl/Hydridoethylene Equilibrium and Contrasting Double Insertion of Acetylene (2001) (12)
- Mechanism of alkyne conversion to carbyne by 14- or 16-electron Os(H)2ClL2X (L = PiPr3; X = OTf or B(C6H3(CF3)2)4) (2008) (11)
- [(tBu2PCH2SiMe2)2N]RuCH3: the origin of extremely facile, double H-C(sp3) activation generating a "hydrido-carbene" complex. (2005) (11)
- Strategy for synthesis of an yttrium/copper(I) complex with an oxo ligand environment (1992) (11)
- Mechanism of Ethylene Hydrogenation by the Molecular Hydrogen Complex [Ir(H)2(H2)(PMe2Ph)3]⊕—Characterization of Intermediates (1988) (11)
- CONFORMATIONAL STABILITY AND RING‐SIZE INTEGRITY OF CYCLIC POLYPHOSPHINES (1975) (11)
- [N.1.1]-(2,6)-Pyridinophanes: a new ligand type imposing unusual metal coordination geometries. (2002) (11)
- A heterometallic cluster with extreme hydride content: H24Cu6Re4(PPh3)82+ (1992) (11)
- Hydrolytic Synthesis of Lead Oxo Isopropoxides and Their Reaction with M(OiPr)4 (M = Ti, Zr): Comparisons and Contrasts (1998) (11)
- Alkoxide Attack on Coordinated Olefin Can Be Reversible (1996) (11)
- Reductive nitrosylation of Group VIIIB metals (1973) (11)
- 16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2tPh)2+ and 18-electron Ir(H)2(H2)2(PBu2tPh)2+: fluxionality and H/D exchange as independent processes (1998) (11)
- DEHYDROHALOGENATION AS A SOURCE OF OSHNCL(PPH3)3 (N = 1, 3) (1999) (11)
- Zinc-containing heterometallic hydride compounds: observation of terminal and bridging ZnN (SiMe3)2 groups (1988) (10)
- Structure and reactivity of ReH4(PMe2Ph)4 (1989) (10)
- Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms. (2018) (10)
- Halide abstraction from VCl3 by ZnCl2. crystal structure of VCl3.ZnCl2.4THF.2H2O (1984) (10)
- Estimating the effective steric impact of PtBu2Me, PiPr3, and PCy3 (1996) (10)
- Correlation among alkoxide .fwdarw. tungsten .pi.-bonding, spin state, and reactivity in W(OCH2CF3)2Cl2(PMe2Ph)2 (1994) (10)
- A mixed halo / n-alkyl compound of chromium(III): synthesis, structure, and reactivity of Cr(n-Bu)2Cl[(Me2PCH2)3CMe] (1989) (10)
- Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n (1993) (10)
- Influence of the Alkoxide Moiety on Heterometallic Compound Formation: Structure and Dynamics of KZr2(OtBu)9 and K2Zr2(OtBu)10 (1994) (10)
- Tetrazine Assists Reduction of Water by Phosphines: Application in the Mitsunobu Reaction. (2016) (10)
- Stepwise metal-assisted reduction of .eta.4-coordinated benzene to cyclohexene (1992) (10)
- Dihydrogen addition to (PiPr3) 2OsXnH4−n (1997) (9)
- In search of redox non-innocence between a tetrazine pincer ligand and monovalent copper. (2014) (9)
- ((Bu2PCH2SiMe2)-Bu-t)(2)N RuMe2: Synthesis and reactivity of an unsaturated ruthenium dialkyl radical species (2006) (9)
- UNEXPECTED COEXISTENCE OF ISOMERIC FORMS AND UNUSUAL STRUCTURES OF RU(CO)2L3 (1996) (9)
- A chain copolymer from WCl2(PMe2Ph)4 and [TlOCH2CF3]4 (1993) (9)
- Fluxionality and basicity of bis(cyclopentadienyl)pentacarbonyldirhenium (1981) (9)
- CHARACTERIZATION OF A FIVE-COORDINATE RU(II) SPECIES DEVOID OF PI-DONOR LIGANDS (1993) (9)
- Carbene transposition involving double dehydrogenation of an sp3 carbon (2001) (9)
- Protonation of Chloride in Os(H)2Cl2(PiPr3)2: Synthesis of [(PiPr3)2H2Os(.mu.-Cl)3OsH2(PiPr3)2]CF3SO3 (1995) (9)
- CHARACTERIZATION AND STRUCTURE OF OSH(OH)(CO)(PTBU2ME)2 (1999) (9)
- The barrier to ring inversion in tetrahedral complexes of N,N,N′,N′ - tetramethylethylenediamine (1973) (8)
- Structure and reactivity of chromium(4+) tert-butoxide (1989) (8)
- Kinetic characteristics of the four-electron bridging carbonyl (1976) (8)
- Mixed-ligand five-coordinate complexes of iridium(I) (1975) (8)
- Synthetic approaches to Fe(II) complexes of the bulky phosphine PtBu2Me (1999) (8)
- .beta.- and .gamma.-Dehydrogenation of diisopropylamide in the formation of the azaallyl (Cp*Ru)2(iso-PrNC3H5)(.mu.-H) (1993) (8)
- L′ = CO vs Cl- transposition: Remarkable consequences for the product of (L′)-Ru(L)2-(H) and vinyl ether (1999) (8)
- Selectivity of attack on a Si–C(sp3) sigma bond coordinated to NiII (2011) (8)
- Ethylene hydrogenation by the hydride alkoxide species Ir(H)2(OCH2CF3)(PtBu2Ph)2. Ethylene-induced reductive elimination of alcohol from IrIII (1993) (8)
- A YBa2 Cluster Based on Simple Ligands (OtBu) (1996) (8)
- Electrophilic abstractions on Os(H)2X(NO)L2: selective access to new unsaturated cationic Os(II) hydrides (1998) (8)
- Chemical implications of incompatible ligand versus metal coordination geometry preferences. (2014) (8)
- Influence of the [2.1.1]-(2,6)-pyridinophane macrocycle ring size constraint on the structure and reactivity of copper complexes. (2004) (8)
- Is π-donation the only way? Unprecedented unsaturated Ru(II) species devoid of π-donor ligands (1997) (8)
- Metal-dependent reactivity differences for transients formed by flash photolysis of (PNP)M(CO), M = Co and Rh. (2007) (8)
- A nonrigid mixed-chelate complex of iron(0) (1975) (8)
- Electron and Oxygen Atom Transfer Chemistry of Co(II) in a Proton Responsive, Redox Active Ligand Environment. (2018) (8)
- Synthesis of zirconium pinacolate and mechanism of its thermal transformation to ZrO2 : Impact of a vicinal diol ligand (1998) (8)
- Heterometallic Fluoroalkoxides of Barium and Copper(I). Syntheses and Structures of [(Me3NO)2Ba2Cu4(TFTB)8] and [(THF)2Ba2Cu2(HFTB)6] (1997) (8)
- Bis(1,1,1,3,3,3‐Hexamethyldisilazanato)‐Bis(Tetrahydrofuran)Barium (2007) (8)
- Could one have five? The synthesis and structure of Re2H4(PMe2Ph)4[P(OCH2)3CEt]2 and its conjugate acid (1982) (7)
- Phosphorus-31 nuclear magnetic resonance spectra of catalytically active nitrosyl complexes (1974) (7)
- HB(3,5-Me2pyrazolyl)3− as an encapsulating ligand for BaII (1993) (7)
- A substituent-tolerant synthetic approach to N/P-"loaded" heteroarenes. (2018) (7)
- Structure of chlorotris(triphenylphosphine)copper(I)–tetrahydrofuran (1/3) (1987) (7)
- Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands. (2009) (7)
- Preparation and characterization of .mu.-hydroxy-.mu.-sulfatooctaaquodichromium(III) (1968) (7)
- Reactivity of the Radical NO with a Masked Form of 14 Valence Electron (PNP)Rh: Forming Rh(0, I or II)? (2008) (7)
- Reductive Silylation Using a Bis-silylated Diaza-2,5-cyclohexadiene. (2019) (7)
- The photochemistry of rhenium hydrides. A flash photolytic investigation of the transients in the photochemistry of tris(dimethylphenylphosphine)pentahydridorhenium(V) (1983) (7)
- Chemistry of Yttrium Triisopropoxide Revisited. Characterization and Crystal Structure of Y5(μ5‐O)(μ3‐OiPr)4(μ2‐OiPr)4(OiPr)5. (1989) (7)
- MOBILITY OF THE μ3:η2-CARBONYL LIGAND IN TRIS(CYCLOPENTADIENYL)HEPTACARBONYLTRINIOBIUM (1981) (7)
- Redox Isomeric Surface Structures Are Preferred over Odd-Electron Pt1. (2018) (7)
- Hydride transfer from transition metal hydrides to dihapto acyl ligands (1985) (7)
- Synthetic and mechanistic features of dinuclear reductive elimination between Re2H8(PMe2Ph)4 and several tin(II) reagents (1988) (7)
- RELATIONSHIP OF HYDRIDE FLUXIONALITY IN IR(H)2L(PHOSPHINE)2N+ TO PROPERTIES OF L : AN EXCEPTIONAL RANGE OF BARRIER HEIGHTS (1998) (7)
- Multi-electron Reduction Capacity and Multiple Binding Pockets in Metal-Organic Redox Assembly at Surfaces. (2019) (7)
- Photoinitiated intramolecular hydrogen transfer from rhenium polyhydrides to C8 cyclopolyolefins (1985) (7)
- Silyl reagents (Me3Si-X) efficiently transfer X to Ir(H)2F(PtBuP2Ph)2 (1998) (7)
- Heterometallic Polyhydride Raft Formation: A Comparison of Syntheses using Alkoxides of Copper and Gold† (1987) (7)
- Is the allylpalladium structure altered between solid and solutions? (2004) (7)
- Di- and trivalent chromium bis(pyrazol-3-yl)pyridine pincer complexes with good leaving groups (2019) (7)
- A reagent for heteroatom borylation, including iron mediated reductive deoxygenation of nitrate yielding a dinitrosyl complex. (2020) (6)
- Synthesis and Reactivity of Ru(II)/Chloro/Hydrido/Carbonyls with Cis Bulky Phosphines: An Unsaturated Ru(II) Monohydride (1999) (6)
- Modification of the reactivity of polyhydrides with Lewis acids. Synthesis and reactivity of {IrH5[P(iso-C3H7)3]2}2Cu(CF3SO3). X-ray crystal structure of {IrH2(MeCN)2[P(iso-C3H7)3]2}(BF4) (1990) (6)
- A heterometallic alkoxide combining hard and soft Lewis acids (Et3PO)2 Ba2Cu4(OtBu)8 (1997) (6)
- The fate of nitric oxide in its reaction with the 14-valence-electron planar species [(tBu2PCH2SiMe2)2N]RuCl (2004) (6)
- Synthesis, Structural Principles, and Reactivity of Heterometallic Alkoxides (2010) (6)
- Nitrogen oxyanion reduction by Co(ii) augmented by a proton responsive ligand: recruiting multiple metals. (2020) (6)
- Reactivity of ˙NO with an osmium polyhydride: Reductive elimination and reductive nitrosylation on the path from odd- to even-electron molecules (2007) (6)
- 2-Electron reduction of N2O yields a new ligand binding mode: N-Nitrosoimide (2007) (6)
- A bis-Pyrazolate Pincer on Reduced Cr Deoxygenates CO2 : Selective Capture of the Derived Oxide by CrII. (2019) (6)
- Synthesis, characterization and reactivity of some rhenium phosphite complexes (1986) (6)
- Mechanism of the carbonylation of dicyclopentadienylmolybdenum dihydride (1979) (6)
- Synthesis and characterization of VCl3(PMePh2)2 (1985) (6)
- Assay of hydride or volatile ligands via outer-sphere oxidation (1986) (6)
- Reactivity of an Unusual Divalent Chromium Aggregate Supported by a Multifunctional Bis(pyrazolate) Pincer Ligand (2019) (5)
- Seeking Redox Activity in a Tetrazinyl Pincer Ligand: Installing Zerovalent Cr and Mo. (2018) (5)
- Lewis base adducts of barium/copper tert-butoxides : Synthesis and thermolysis of [BaCu2(OtBu)4]n and [L2Ba2Cu4(OtBu)8] (L = Me3NO and Et3PO). X-ray crystal structure of [(Me3No)2Ba2Cu4(OtBu)8] (1997) (5)
- Ligand (L) Influence on CO Binding Enthalpies to Ru(CO)2L2 (1997) (5)
- Photochechemistry of transition-metal polyhydrides: dimerization of OsH4 (PMe2Ph)3 following photodissociation of dihydrogen (1983) (5)
- Evaluation of energies of isomeric SO2 complexes (2003) (5)
- A single bond covalent radius for IrIII: Crystal and molecular structure of fac-Ir(CH3)3(PMe2Ph)3 (1988) (5)
- Selective hydrogenation of acenapthylene by ReH7(PCy3)2 (1985) (5)
- Mobility of the .mu.3:.eta.2-carbonyl ligand in tris(cyclopentadienyl)heptacarbonyltriniobium (1980) (5)
- Evaluating the reducing power of 3-coordinate T-shaped NiI ☆ (2011) (5)
- Nonplanar Rh(I) in Rh(PMe2Ph)4+: Magnitude and origin of the distortion (1989) (5)
- Conventional Lithium Bases as Unconventional Sources of Methyl Anion: Facile Me−Si and Me−C Bond Cleavage in RLi, R2NLi, and BR4-by an Electrophilic Osmium Dihydride (2002) (4)
- ROMP using heterocyclic carbenes bearing a hydride ligand. An improved synthesis of RuCl2(PR3)2(CHMe) (2001) (4)
- A proton-responsive ligand becomes a dimetal linker for multisubstrate assembly via nitrate deoxygenation. (2021) (4)
- Probing Redox Noninnocence of Copper and Zinc Bis-pyridylpyrrolides (2018) (4)
- Heterobimetallic Carbon Monoxide Hydrogenation: Hydrogen Transfer to Coordinated Acyls: The Molecular Structure of (C5H5)2Re[(C5H5)2ZrCH3](OCHCH3) (1981) (4)
- Stereochemically rigid d8 (diene) ML3 complexes (1992) (4)
- Spectroscopic study of dehydrochlorination and exchange with D{sub 2} in WH{sub 2}Cl{sub 2}(PMe{sub 2}Ph){sub 4}: Unexpected stereochemical rigidity of dodecahedra containing both hydride and chloride ligands. Crystal and molecular structure of W(H){sub 3}({eta}{sup 2}-C{sub 6}H{sub 4}PMe{sub 2})(PM (1994) (4)
- A new face for bis(pyrazol-3-yl)pyridine: Incompatible geometric preferences dictates unprecedented pincer ligand connectivity (2019) (4)
- Synthesis of Zr-Re-containing polyhydrides by amine elimination (1989) (4)
- The Influence of Nucleophilic and Redox Pincer Character, and Alkali Metals, on Capture of Oxygen Substrates: The Case of Chromium(II). (2020) (3)
- A new access route to dimetal sandwich complexes, including a radical anion. (2018) (3)
- MOLECULAR STRUCTURE AND SOLUTION DYNAMICS OF (η5-C5H5)NI(PPH3)S2COC2H5 (1980) (3)
- A Dimeric Chromium(II) Pincer as an Electron Shuttle for N=N Bond Scission. (2020) (3)
- LIGAND REDISTRIBUTION REACTIONS OF FIVE-COORDINATE D6 SPECIES : RUHX(CO)P2,IRH2XP2, AND CP*RUXP (1994) (3)
- Low Temperature Multinuclear NMR Study of the Mechanism of Protonation of W(H)2Cl2(PMe2Ph)4 (1995) (3)
- Nature of the phase change in solid bis(isopropyl alcohol)octakis(isopropoxo)dicerium, as determined by variable-temperature x-ray diffraction and deuterium NMR spectroscopy (1991) (3)
- Selectivity in multiple methylation of MCln(Pr3)m compounds (1989) (3)
- A Redox-active Tetrazine-based Pincer Ligand for the Reduction of N-oxyanions Using a Redox-inert Metal. (2021) (3)
- Reactivity patterns of the unsaturated Os(0) species Os(NO)(CO)(PBut2Me)2 (1999) (3)
- Evolving approaches to integration of computational with experimental chemistry: an example from osmium hydrido (η1/η2-)nitrosyl/nitroxyl chemistry (2002) (3)
- Gauging the Redox Non-Innocence of a Highly Pi-Acidic Bis-Tetrazine Pincer Ligand (2019) (2)
- Intramolecular Hydrogen Site Exchange in an HRu(SiHPh(2)) Moiety. (1996) (2)
- An Improved Interpretation of a Lead Oxo Isopropoxide. (1999) (2)
- Facile Olefin Hydrogenation with an Osmium Dihydrogen Complex. (1989) (2)
- Synthesis of Monochloropentaaquochromium(III) Ion by Displacement Ion Exchange (1964) (2)
- C-D(0) (D(0) = pi-donor, F) Cleavage in H(2)C=CH(D(0)) by (Cp(2)ZrHCl)(n): mechanism, agostic fluorines, and a carbene of Zr(IV). (2001) (2)
- Stepwise reductive acidolysis of OsH4(PMe2Ph)3: mechanism of hydrogen elimination/ligand addition (1984) (2)
- NO binds to unsaturated Os(IV) polyhydrides as a redox reagent (2007) (2)
- Methyl transfer in the reaction of IrMe3(PMe2Ph)3 with Cu(NCMe)4 (1988) (2)
- [Cr(pincer2-)]2 as an electron shuttle for reductively promoted hydrazine disproportionation. (2019) (2)
- Protonation of cationic hydride and alkyl complexes of Ir(III) (1992) (2)
- Electrophile Recruitment as a Structural Element in Bis‐Pyrazolate Pyridine Complex Aggregation (2018) (2)
- COULD ONE HAVE FIVE? THE SYNTHESIS AND STRUCTURE OF RE2H4(PME2PH)4(P(OCH2)3CET)2 AND ITS CONJUGATE ACID (1982) (2)
- A redox cascade of NOx− complexes: Structures and nitrogen deoxygenation thermodynamics (2021) (2)
- Assessing isomeric structures of pincer-ligated ruthenium and osmium polyhydrides using density functional calculations (2002) (2)
- An Integrated View of Nitrogen Oxyanion Deoxygenation in Solution Chemistry and Electrospray Ion Production. (2021) (2)
- An osmium hydrido methyl species via an unconventional methyl transfer (2000) (2)
- Molecular structure of an extremely crowded iron(II) dihydride complex: FeH2(PMePh2)4 (1984) (2)
- Mechanistic studies on the oxidation of an anionic rhenium polyhydride complex: Generation and reactivity of the transient radical [ReH6(PMePh2)2] (1986) (2)
- A Cu ‐ (μ‐H) Bond Can Be Stronger Than an Intramolecular P→Cu Bond. Synthesis and Structure of Cu2(μ‐H)2(η2‐CH3C(CH2PPh2)3)2. (1986) (2)
- η3-MeC(CH2PPh2)3/Rhodium Complexes Utilize Phosphine Arm Dissociation Mechanisms at 25 °C. (1990) (1)
- A multimetal-ligand cooperative approach to CO2 activation (2018) (1)
- Terminal Acetylenes React to Increase Unsaturation in [ ( tBu 2 PCH 2 SiMe 2 ) 2 N ] Re ( H ) 4 (1)
- Synthesis and Reactivity of a Heterometallic CO2 Complex. (1990) (1)
- Primary Steps in the Hydrolyses of Two Heterometallic Alkoxides. Characterization of (LiTiO(OiPr)3)4 and BaZr4(OH)(OiPr)17 (1993) (1)
- Synthesis of Tris(triphenylsiloxy)yttrium and Derivatives: Crystal Structure of (Y(OSiPh3)3(THF)3)·THF. (1989) (1)
- Facile Synthesis and Structural Principles of the Strontium Phenoxide Sr4(OPh)8(PhOH)2(THF)6. (1990) (1)
- ALUMINUM ALKYLS AND TRANSITION METAL HYDRIDES: “NONCLASSICAL” ADDUCT STRUCTURE AND CATALYSIS OF HYDROGEN MIGRATION (1984) (1)
- Alcohol Elimination Chemistry of (CuOtBu)4. (1991) (1)
- Reactivity of the Molecular Hydrogen Complex (IrH4(PMe2Ph)3)BF4 Toward Olefins. The Origin of Stereochemical Rigidity of M(PR3)3(olefin)2 Species. (1990) (1)
- Anion metathesis and chlorination of late transition metal pincer complexes: Comparing Co, Rh and Zn (2020) (1)
- Pincers with diverse donors and their interconversion: application to Ni(II) (2021) (1)
- Heterobimetallic Hydride Complexes (2007) (1)
- Syntheses and Structures of a Series of Very Low Coordinate Barium Compounds: Ba(N(SiMe3)2)2(THF)2, (Ba(N(SiMe3)2)2(THF))2, and (Ba(N( SiMe3)2)2)2. (1991) (1)
- Electrooxidation as a Route to Dihydrogen Complexes (1993) (0)
- STRUCTURAL DETERMINATION OF ((C5H5)2MO(H)CO)((C5H5)MO(CO)3) (1980) (0)
- PHOSPHORUS-31 NUCLEAR MAGNETIC RESONANCE SPECTRA OF CATALYTICALLY ACTIVE NITROSYL COMPLEXES (I)-(II) (1974) (0)
- A Titanium Alkoxide (Pinacolate) Complex Incorporating a 10-Membered Ring. (1988) (0)
- A BIMETALLIC VANADIUM(I) POLYHYDRIDE (1983) (0)
- THE MECHANISTIC ROLE OF WATER AND THE LIGAND IN THECHEMICAL-VAPOR-DEPOSITIONREACTIONS OFBIS-(1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONATO) COPPER(II) (1995) (0)
- Preparation, Crystal, and Molecular Structure of a Hydrocarbon Soluble, Volatile Oxoalkoxide of Barium: H4Ba6(μ6‐O)(OCH2CH2OCH3)14. (1991) (0)
- Control of HC(sp 3 ) Bond Cleavage Stoichiometry: Clean Reversible Alkyl Ligand Exchange with Alkane in (LPt(Alk)(H)2) þ (L ¼ (2002) (0)
- Book Review: Industrial Inorganic Chemistry. By W. Büchner, R. Schliebs, G. Winter and K. H. Büchel. Translated by D. R. Terrell (1990) (0)
- Synthesis and Structure of (Ba3(OSiPh3)6(THF))×0.5THF, a Trinuclear Barium Siloxide Containing Low‐Coordinate Barium Ions. (1991) (0)
- Structure and Reactivity of Cr(OCMe3)4. (1989) (0)
- Low-Pressure Chemical Vapor Deposition of Tungsten Carbide Thin Films (1991) (0)
- Facile Addition of B-H and B-B Bonds to an Iron(IV) Nitride Complex. (2022) (0)
- Relationship of Adduct Formation to Bimolecular Reductive Elimination from Rhodium Polyhydrides. (1986) (0)
- Double silyl migration converting ORe[N(SiMe(2)CH(2)PCy(2))(2)] to NRe[O(SiMe(2)CH(2)PCy(2))(2)] substructures. (2002) (0)
- SPECTRA AND STRUCTURE OF MO2(CO)6(MU-PH3PNH)3, A NEW BONDING MODE FOR PHOSPHINIMINES (1974) (0)
- [The molecular precursor strategy for the production of superconducting oxides]. Progress report (1993) (0)
- Carboxylic Acid Ligand Substituent Impacts Hydrosilylation Activity of Platinum Single Atom Catalysts on Ceria (2022) (0)
- Back donation, intramolecular electron transfer and N-O bond scission targeting nitrogen oxyanion reduction: how can a metal complex assist? (2021) (0)
- Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes. (2022) (0)
- Design and Synthesis of Tridentate Facially Chelating Ligands of the [2.n.1]‐(2,6)‐Pyridinophane Family. (2003) (0)
- Structure and Reactivity of ReH4(PMe2Ph)+ 4. (1990) (0)
- PHOTOCHEMISTRY OF TRANSITION-METAL POLYHYDRIDES: DIMERIZATION OF OSH4(PME2PH)3 FOLLOWING PHOTODISSOCIATION OF DIHYDROGEN (1983) (0)
- A Two‐Step Low Pressure Chemical Vapor Deposition Process for the Production of Tungsten Metal Thin Films. (1998) (0)
- Assay of Hydride or Volatile Ligands via Outer-Sphere Oxidation. (1987) (0)
- Nickel-mediated N–N bond formation and N2O liberation via nitrogen oxyanion reduction (2021) (0)
- Nonplanar Rh(I) in Rh(PMe2Ph)+ 4: Magnitude and Origin of the Distortion. (1989) (0)
- Synthetic and Mechanistic Features of Dinuclear Reductive Elimination Between Re2H8(PMe2Ph)4 and Several Tin(II) Reagents. (1988) (0)
- Hydrogenation of Ethylene by the H2 Complex (Ir(H)2(H2)(PMe2Ph)3)+ - Mechanism and Characterization of Intermediates. (1988) (0)
- Oxidation and acidolysis of MoH4(PR3)4 (2002) (0)
- 2CdCH(D0) by (Cp2ZrHCl)n: Mechanism, Agostic Fluorines, and a Carbene of Zr(IV) (0)
- IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS (V2CL3(THF)6)2(ZN2CL6) (1984) (0)
- Heteronuclear Polyhydride Raft Formation - A Comparison of Syntheses Using Alkoxides of Copper and Gold. (1987) (0)
- A tale of hydrogen abstraction, initially detected via X-ray diffraction. (2014) (0)
- Gross rearrangement of Fe(II) aggregate structure by replacement of two H+ by two Li+: Visualizing altered structure of acid versus conjugate base (2019) (0)
- Formation of a Heterometallic Carbon Dioxide Complex with Concurrent Reduction of CO2. (1987) (0)
- BOROHYDRIDE/ETHANOL REDUCTION OF TRIS(DIMETHYLPHENYLPHOSPHINE)TRICHLORORUTHENIUM (1985) (0)
- Progress in Inorganic Chemistry. Volume 28 (1982) (0)
- Conversion of Carbon Dioxide to Carbonate Using a Rhodium μ‐Hydroxy Species. (1987) (0)
- Correction to 2,2′-Pyridylpyrrolide Ligand Redistribution Following Reduction (2013) (0)
- Low-Coordinate Yttrium in an Oxygen Ligand Environment. Solid-State and Solution Characterization of Y2(OSiPh3)6. (1991) (0)
- Transient Radical H3Ir(PMe2Ph)+ 3: A Broensted Acid. (1991) (0)
- Structure, Dynamics, and Comparative Stability of a Mixed-Ligand Compound of Tin(II). (1990) (0)
- The molecular precursor strategy for the production of superconducting oxides (1993) (0)
- INTERMOLECULAR REARRANGEMENTS OF M(BIDENTATE PHOSPHINE)2XY SPECIES (1975) (0)
- Multifunctional behavior by a Bis-(phosphinimino)methanide ligand: eta 2- vs eta 3-coordination vs Bronsted basicity. (2004) (0)
- The fate of nitric oxide in its reaction with the 14-valence-electron planar species [ ( t Bu 2 PCH 2 SiMe 2 ) 2 N ] RuCl (2004) (0)
- Synthesis and structural characterization of tricarbomethoxymethanate complexes of copper(II) and barium(II) and evaluation of their suitability for MOCVD applications (2001) (0)
- A pi-basic rhenium center that effects cyclohexene isomerization to a beta-agostic carbene ligand. (2003) (0)
- Tetraethylborate as an Ethyl Transfer Reagent. (1990) (0)
- Double C ( sp 3 ) dehydrogenation as a route to coordinated Arduengo carbenes : experiment and computation on comparative p-acidity y (2003) (0)
- Soluble Zinc Bis(aryloxides). (1986) (0)
- REACTIVITY PATTERNS OF TRANSITION METAL POLYHYDRIDES (1983) (0)
- Factors Governing the Equilibrium Between Metal—Alkyl, Alkylidene and Alkylidyne: MCX2R, X—M=CXR and X2MCR (2001) (0)
- Alkyne Hydrogenation by a Dihydrogen Complex: Synthesis and Structure of an Unusual Iridium/Butyne Complex. (1989) (0)
- HCr((Me2PCH2)3CMe)+ 2BEt- 4: The First Synthesis of a Cationic Hydride Complex from HBEt- 3. (1987) (0)
- p-Donor olefin substituents alter olefin binding to CpFe ( CO ) 2 + y (2003) (0)
- Electrophilic (Li+) acceleration of C–H reductive elimination and oxidative addition reactions of Os(II)/Os(0) nitrosyl complexesElectronic supplementary information (ESI) available: full experimental and computational details. See http://www.rsc.org/suppdata/nj/b2/b200180m/ (2002) (0)
- Heptahydridobis(Triphenylphosphine)‐Rhenium(VII) and Octahydridotetrakis‐(Triphenylphosphine)Dirhenium(IV) (2007) (0)
- Synthetic and Mechanistic Features of Alcohol Elimination Between Gold Alkoxides and Rhenium Polyhydrides. Metal Polyhedron Reconstruction Upon Protonation. (1987) (0)
- C-O Bond Scission in Heterometallic Alkoxides: Formation and Structure of K4Zr2O(OiPr)10. (1991) (0)
- Homogeneous hydrogenation of carbon monoxide (2002) (0)
- Synthesis of Cu3Os3H9(PMe2Ph)9, a Bimetallic Raft, by Reductive Elimination of Alcohol or H2. (1986) (0)
- New precursors for metallic copper based on ethanolaminecomplexes of Cu(hfacac)(2) (1996) (0)
- Condensation of 2‐Pyridylmethyllithium Nucleophiles and Pyridine Electrophiles as a Convenient Synthetic Route to Polydentate Chelating N‐Donor Ligands. (2003) (0)
- Rational Syntheses of Copper Polyhydride Complexes (1986) (0)
- Synthesis, Structure, and Applications of Transition-Metal Polyhydride Anions. (1990) (0)
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