Kenneth Karlin
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American professor of chemistry at Johns Hopkins University
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Kenneth Karlin chemistry Degrees
Chemistry
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#2515
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Inorganic Chemistry
#93
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#103
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#25
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Chemistry
Kenneth Karlin 's Degrees
- PhD Inorganic Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Kenneth Karlin Influential?
(Suggest an Edit or Addition)According to Wikipedia, Kenneth D. Karlin was born on October 30, 1948, in Pasadena, California, a professor of chemistry at Johns Hopkins University in Baltimore, Maryland. Research in his group focuses on coordination chemistry relevant to biological and environmental processes, involving copper or heme complexes. Of particular interest are reactivities of such complexes with nitrogen oxides, O2, and the oxidation of substrates by the resultant compounds. He is also the Editor-in-Chief of the book series Progress in Inorganic Chemistry.
Kenneth Karlin 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Bioinorganic Chemistry of Copper (1993) (467)
- Metalloenzymes, structural motifs, and inorganic models. (1993) (427)
- Reversible reaction of O2 (and CO) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(μ-1,2-peroxo)dicopper(II) product (1993) (325)
- Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry. (2002) (320)
- Synthetic models for heme-copper oxidases. (2004) (302)
- Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction (1997) (273)
- A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System (1988) (266)
- Copper-mediated hydroxylation of an arene ― model system for the action of copper monooxygenases: structures of a binuclear Cu(I) complex and its oxygenated product (1984) (255)
- Oxidant types in copper–dioxygen chemistry: the ligand coordination defines the Cun-O2 structure and subsequent reactivity (2004) (236)
- Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. (2012) (197)
- Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). (2009) (189)
- Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6 (1982) (180)
- Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. (2008) (178)
- Copper-dioxygen chemistry: a bioinorganic challenge (1989) (168)
- Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands (1993) (138)
- A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols. (2007) (131)
- Activation of dioxygen by copper metalloproteins and insights from model complexes (2017) (128)
- Targeted strand scission of DNA substrates by a tricopper(II) coordination complex. (2002) (126)
- Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. (2003) (126)
- Cupric superoxo-mediated intermolecular C-H activation chemistry. (2011) (124)
- Chemistry of Pentacoordinate [LCuII-Cl]+ Complexes with Quinolyl Containing Tripodal Tetradentate Ligands L (1994) (121)
- Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands. (2001) (120)
- Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties. (2002) (120)
- Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. (2008) (119)
- Peroxo-, Oxo-, and Hydroxo-Bridged Dicopper Complexes: Observation of Exogenous Hydrocarbon Substrate Oxidation (1998) (118)
- Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses and Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System (1994) (118)
- Heme-copper/dioxygen adduct formation, properties, and reactivity. (2007) (113)
- Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex. (2009) (112)
- Mononuclear copper complex-catalyzed four-electron reduction of oxygen. (2010) (112)
- Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function. (2018) (112)
- Dioxygen-copper reactivity. Reversible binding of O2 and CO to a phenoxo-bridged dicopper(I) complex (1987) (112)
- The extended environment of mononuclear metal centers in protein structures. (1997) (108)
- Catecholate coordination to copper: structural characterization of a tetrachloro-o-catecholate-bridged dicopper(II) complex as a model for intermediates in copper-catalyzed oxidation of catechols (1985) (104)
- Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric–Superoxo Complex (2014) (101)
- Copper(I)/Dioxygen Reactivity of Mononuclear Complexes with Pyridyl and Quinolyl Tripodal Tetradentate Ligands: Reversible Formation of Cu:O2 = 1:1 and 2:1 Adducts (1994) (99)
- Models for methemocyanin derivatives: Structural and spectroscopic comparisons of related azido-coordinated (N3 -) mono- and dinuclear copper(II) complexes (1987) (97)
- Mechanism of aromatic hydroxylation in a copper monooxygenase model system. 1,2-methyl migrations and the NIH shift in copper chemistry (1992) (95)
- Reactivity patterns and comparisons in three classes of synthetic copper-dioxygen {Cu2-O2} complexes: implication for structure and biological relevance (1991) (95)
- Aryl hydroxylation from a mononuclear copper-hydroperoxo species. (2007) (91)
- Reactions of dioxygen (O2) with mononuclear copper(I) complexes: temperature-dependent formation of peroxo- or oxo- (and dihydroxo-) bridged dicopper(II) complexes (1992) (91)
- Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species. (2006) (90)
- Dioxygen−copper reactivity: generation, characterization, and reactivity of a hydroperoxo−dicopper(II) complex (1988) (90)
- Dioxygen-copper reactivity ― models for hemocyanin: reversible O2 and CO binding to structurally characterized dicopper(I) complexes containing hydrocarbon-linked bis[2-(2-pyridyl)ethyl]amine units (1988) (89)
- Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights (2011) (89)
- Spectroscopic studies of the charge transfer and vibrational features of binuclear copper(II) azide complexes: comparison to the coupled binuclear copper active site in met azide hemocyanin and tyrosinase (1989) (87)
- Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation. (2015) (87)
- (F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation. (2001) (86)
- Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state. (2010) (85)
- Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling. (2010) (85)
- Spectroscopic and theoretical studies of an end-on peroxide-bridged coupled binuclear copper(II) model complex of relevance to the active sites in hemocyanin and tyrosinase (1991) (84)
- Vibrational, electronic, and resonance Raman spectral studies of [Cu2(YXL-O-)O2]+, a copper(II) peroxide model complex of oxyhemocyanin (1987) (84)
- Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. (2005) (83)
- A new trinuclear copper complex and its reactions with plasmid DNA (1996) (83)
- Copper coordination chemistry : biochemical & inorganic perspectives (1983) (80)
- Binding and Activation of Molecular Oxygen by Copper Complexes (1988) (80)
- Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. (2015) (79)
- Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group. (2013) (77)
- Dioxygen-copper reactivity and functional modeling of hemocyanins. Reversible binding of O2 and CO to dicopper(I) complexes [CuI2(L)]2+ (L = dinucleating ligand) and the structure of a bis(carbonyl) adduct, [CuI2(L)(CO)2]2+ (1992) (77)
- Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry. (2007) (75)
- One is lonely and three is a crowd: two coppers are for methane oxidation. (2010) (75)
- Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction. (2015) (73)
- Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex (2002) (72)
- Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes. (2012) (72)
- Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations (2006) (71)
- Peroxide coordination to a dicopper(II) center. Dioxygen binding to a structurally characterized phenoxide-bridged binuclear copper(I) complex (1984) (70)
- Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities. (2001) (69)
- Spectroscopic and Theoretical Studies of Oxygenated Dicopper(I) Complexes Containing Hydrocarbon-Linked Bis[2-(2-pyridyl)ethyl]amine Units: Investigation of a Butterfly [Cu2(μ-η2:η2)(O2)]2+ Core (1999) (69)
- X-ray Structure and Physical Properties of the Oxo-Bridged Complex [(F8-TPP)Fe-O-Cu(TMPA)]+, F8-TPP = Tetrakis(2,6-difluorophenyl)porphyrinate(2-), TMPA = Tris(2-pyridylmethyl)amine: Modeling the Cytochrome c Oxidase Fe-Cu Heterodinuclear Active Site (1994) (69)
- Nitric Oxide Reductase from Paracoccus denitrificans Contains an Oxo-Bridged Heme/Non-Heme Diiron Center (2000) (69)
- Substrate oxidation by copper-dioxygen adducts: mechanistic considerations. (2005) (68)
- Synthetic heme/copper assemblies: toward an understanding of cytochrome c oxidase interactions with dioxygen and nitrogen oxides. (2015) (67)
- Facile amide hydrolysis effected by dinuclear copper complexes (1993) (67)
- Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry. (2007) (67)
- Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. (2012) (67)
- Superoxo, μ-peroxo, and μ-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: Copper ligand influences in cytochrome c oxidase models (2003) (66)
- Dioxygen-activating bio-inorganic model complexes. (1999) (66)
- Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species. (2008) (65)
- Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. (2013) (64)
- Copper(I) Complexes with Pyridyl- and Imidazoyl-Containing Tripodal Tetradentate Ligands and Their Reactions with Dioxygen (1994) (64)
- Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes. (2002) (64)
- Formation, characterization, and reactivity of bis(mu-oxo)dinickel(III) complexes supported by a series of bis[2-(2-pyridyl)ethyl]amine ligands. (2001) (63)
- Chemistry and structural studies on the dioxygen-binding copper-1,2-dimethylimidazole system (1993) (63)
- Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions. (2006) (62)
- Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity (2012) (62)
- Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. (2013) (61)
- Functional modeling of copper nitrite reductases: reactions of NO2- or nitric oxide with copper(I) complexes (1991) (61)
- Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics. (2003) (61)
- NMR and Electronic Relaxation in Paramagnetic Dicopper(II) Compounds (1997) (61)
- A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+). (2002) (61)
- Recognition and strand scission at junctions between single- and double-stranded DNA by a trinuclear copper complex. (2001) (60)
- One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina (2016) (60)
- Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes. (2003) (59)
- Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry. (2003) (58)
- Three-coordinate binuclear copper(I) complex: model compound for the copper sites in deoxyhemocyanin and deoxytyrosinase (1982) (58)
- A dinuclear zinc hydroxide complex which traps atmospheric carbon dioxide: formation of a tri-zinc complex with a triply bridging carbonate group (1993) (57)
- A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. (2015) (57)
- Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. (2012) (56)
- Fluoride as a terminal and bridging ligand for copper: isolation and x-ray crystallographic characterization of copper monomeric and dimeric complexes [CuII(TMPA)F]nn+ (n = 1 or 2; TMPA = tris[(2-pyridyl)methyl]amine) (1991) (56)
- Unsymmetrical dicopper complexes. Direct observation of reversible O2 binding in a copper monooxygenase model system (1991) (55)
- Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. (2010) (55)
- X-ray absorption studies of three-coordinate dicopper(I) complexes and their dioxygen adducts (1988) (54)
- Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. (2012) (54)
- Kinetic, thermodynamic, and spectral characterization of the primary copper-oxygen (Cu-O2) adduct in a reversibly formed and structurally characterized peroxo-dicopper(II) complex (1991) (54)
- Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. (2004) (53)
- Models for met-hemocyanin derivatives: structural and spectroscopic comparisons of analogous phenolate and X (X = OH-, OMe-, N3-, Cl-, OAc-, OBz-) doubly bridged dinuclear copper(II) complexes (1987) (53)
- A new copper-oxo player in methane oxidation (2009) (53)
- Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase. (2005) (53)
- Reversible O2 Binding to a Dinuclear Copper(I) Complex with Linked Tris(2-pyridylmethyl)amine Units: Kinetic-Thermodynamic Comparisons with Mononuclear Analogs (1995) (52)
- Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms. (2016) (51)
- Dioxygen reactivity of mononuclear heme and copper components yielding a high-spin heme-peroxo-cu complex. (2001) (51)
- Kinetic and thermodynamic studies on the reaction of oxygen with two dinuclear copper(I) complexes (1988) (51)
- Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. (2018) (51)
- X-RAY ABSORPTION-EDGE SPECTROSCOPY OF COPPER(I) COMPLEXES - COORDINATION GEOMETRY OF COPPER(I) IN THE REDUCED FORMS OF COPPER PROTEINS AND THEIR DERIVATIVES WITH CARBON-MONOXIDE (1989) (50)
- A trinuclear copper(I) complex: Reaction with dioxygen and the formation of a hexanuclear copper(II) cluster (1990) (50)
- One-Step Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide Catalysed by Copper Complexes Incorporated into Mesoporous Silica-Alumina. (2015) (50)
- Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. (2008) (49)
- Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. (2013) (49)
- XAS Structural Comparisons of Reversibly Interconvertible Oxo- and Hydroxo-Bridged Heme-Copper Oxidase Model Compounds (1996) (48)
- Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate. (2009) (48)
- Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. (2008) (48)
- Computational study of the activated OH state in the catalytic mechanism of cytochrome c oxidase (2013) (48)
- Copper(I)-dioxygen reactivity. 2. Reaction of a three-coordinate copper(I) complex with dioxygen, with evidence for a binuclear oxo-copper(II) species: structural characterization of a parallel-planar dihydroxo-bridged dimer (1984) (48)
- Dioxygen-copper reactivity. Comparisons of the reactions of electrophiles and other reagents with three classes of peroxo-dicopper(II), {Cu2-O2}n+, species (1989) (47)
- Synthesis and structure of Fe(L'H)(NO)2, a tetracoordinate complex having a twelve-membered chelate ring, and its conversion to pentacoordinate FeL'(NO) through formal loss of "HNO" (L' = SCH2CH2NMeCH2CH2CH2NMeCH2CH2S-) (1980) (47)
- Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu(2)((UN-O-)(OOH)](2+). (1998) (47)
- Hydrogen peroxide and dioxygen activation by dinuclear copper complexes in aqueous solution: hydroxyl radical production initiated by internal electron transfer. (2008) (47)
- Activation of O2 by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; X-ray crystal structure of [Cu2{OC6H3[CH2N(CH2CH2py)2]2-2,6}(OMe)](py = 2-pyridyl) (1981) (47)
- Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex. (2013) (47)
- Copper-Oxygen Chemistry: Karlin/Copper-Oxygen Chemistry (2011) (46)
- Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts. (2000) (46)
- Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues. (2007) (45)
- Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects. (2006) (45)
- The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes. (2003) (44)
- A peroxynitrite complex of copper: formation from a copper–nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration (2009) (44)
- Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage. (2012) (44)
- Bioinorganic chemical modeling of dioxygen-activating copper proteins (1985) (44)
- Formation of a Copper-Dioxygen Complex (cu2-o2) Using Simple Imidazole Ligands (1991) (43)
- Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. (2003) (43)
- New thermally stable hydroperoxo- and peroxo-copper complexes (1992) (43)
- Nitric Oxide in Biological Denitrification: Fe/Cu Metalloenzyme and Metal Complex NOx Redox Chemistry (2002) (43)
- Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. (2015) (42)
- Dioxygen-copper reactivity: x-ray structure and characterization of an (acylperoxo)dicopper complex (1987) (42)
- Structure and reactions of an eight-coordinate Mn(II) complex: [Mn(TMPA)2](ClO4)2 (TMPA=tris[(2-pyridyl)methyl]amine) (1993) (41)
- Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. (2014) (40)
- Isolation and x-ray structure of a dinuclear copper-nitrosyl complex (1990) (40)
- Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase. (2012) (40)
- Formation and Characterization of a High-Spin Heme-Copper Dioxygen (Peroxo) Complex (1999) (40)
- A Study of Solid [{Cu(MePY2)}2O2]2+ Using Resonance Raman and X-ray Absorption Spectroscopies: An Intermediate Cu2O2 Core Structure or a Solid Solution? (1999) (40)
- Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). (2009) (39)
- Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. (2010) (39)
- Oxo- and hydroxo-bridged (porphyrin)iron(III)-copper(II) species as cytochrome c oxidase models: acid-base interconversions and x-ray structure of the Fe(III)-(O2-)-Cu(II) complex (1993) (39)
- Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. (2013) (39)
- Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. (2016) (39)
- Crystal structure and electron spin echo envelope modulation study of [Cu(II)(TEPA)(NO2)]PF6 (TEPA = tris[2-(2-pyridyl)ethyl]amine): a model for the purported structure of the nitrite derivative of hemocyanin (1993) (39)
- L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes. (2013) (38)
- X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding. (2008) (38)
- Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation. (2017) (38)
- Dioxygen-copper reactivity. Reversible oxygen and carbon monoxide binding by a new series of binuclear copper(I) complexes (1985) (38)
- Heme/copper assembly mediated nitrite and nitric oxide interconversion. (2012) (37)
- Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity. (2003) (37)
- Bioinorganic chemistry: Model offers intermediate insight (2010) (37)
- Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. (2013) (35)
- Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link. (2005) (35)
- Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. (2009) (35)
- Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex. (2005) (35)
- Synthesis, structure, and characterization of a phenolate-bridged dimanganese(II) complex of a dinucleating phenol ligand (1992) (35)
- Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. (2011) (35)
- A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate. (2013) (35)
- Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. (2004) (34)
- Sulfur-bridged binuclear iron(II) complexes. Effect of ligand constraints on their physical properties; reactions with carbon monoxide and alkyl isocyanides (1976) (34)
- Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity. (2017) (34)
- Copper-oxygen chemistry (2011) (34)
- Mononuclear Copper(II)-Acylperoxo Complexes (1995) (34)
- Heterobinucleating Ligand-Induced Structural and Chemical Variations in [(L)FeIII−O−CuII]+ μ-Oxo Complexes (1998) (33)
- A dinuclear mixed-valence Cu(I)/Cu(II) complex and its reversible reactions with dioxygen: generation of a superoxodicopper(II) species (1992) (33)
- Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry. (2017) (33)
- Dioxygen—Copper Reactivity: Hydroxylation-induced Methyl Migration in a Copper Monooxygenase Model System (1987) (33)
- Redox behavior of blue copper model complexes. Redox potentials and electron-transfer kinetics of some copper(II)-copper(I) complexes with nitrogen and thioether donors (1984) (32)
- Inferences from the 1H-NMR Spectroscopic Study of an Antiferromagnetically Coupled Heterobinuclear Fe(III)−(X)−Cu(II) S = 2 Spin System (X = O2-, OH-) (1997) (32)
- Formation and Interconversion of End-on and Side-on μ-Peroxo−Dicopper(II) Complexes (1996) (32)
- Binuclear Copper Complexes Based on the 6,6'-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine Ligand. (1997) (32)
- Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate. (1999) (32)
- Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation. (2006) (32)
- Solvent Effects on the Conversion of Dicopper(II) μ-η2:η2-Peroxo to Bis-μ-oxo Dicopper(III) Complexes: Direct Probing of the Solvent Interaction (2004) (32)
- Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands. (2019) (31)
- Biological & inorganic copper chemistry : proceedings of the Second Conference on Copper Coordination Chemistry held at the State University of New York at Albany, July 23-27, 1984 (1986) (31)
- Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex. (2009) (31)
- Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species. (2010) (31)
- Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. (2015) (30)
- CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism. (2010) (30)
- Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. (2005) (30)
- Dioxygen Reactivity of Fully Reduced [LFeII···CuI]+ Complexes Utilizing Tethered Tetraarylporphyrinates: Active Site Models for Heme-Copper Oxidases (1999) (30)
- Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity. (2007) (30)
- Synthesis and x-ray structural characterization of Cu(I) and Cu(II) derivatives of a new symmetric tripodal ligand N(CH2CH2-py)3, (py = 2-pyridyl) (1982) (29)
- Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. (2017) (29)
- A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species. (2017) (29)
- Enhanced Rates of C-H Bond Cleavage by a Hydrogen Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex. (2019) (29)
- Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex. (1997) (29)
- Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands. (2006) (29)
- A “Naked” FeIII-(O22–)-CuII Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes (2015) (29)
- Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analysis of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4][pma2-pyridylmethylbis-(2-ethylthioethyl)amine] (1980) (29)
- OXO- AND HYDROXO-BRIDGED HEME-COPPER ASSEMBLIES FORMED FROM ACID-BASE OR METAL-DIOXYGEN CHEMISTRY (1999) (28)
- Copper-mediated hydroxylation of an arene: kinetics and mechanism of the reaction of a dicopper(II) m-xylyl-containing complex with H2O2 to yield a phenoxodicopper(II) complex (1988) (28)
- An iron-peroxo porphyrin complex: new synthesis and reactivity toward a Cu(II) complex giving a heme-peroxo-copper adduct. (2003) (28)
- Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues. (2003) (28)
- Reaction of organic halides with [CuI(TMPA)CH3CN]PF6 (1991) (27)
- A μ‐η2:η2‐Disulfide Dicopper(II) Complex from Reaction of S8 with a Copper(I) Precursor: Reactivity of the Bound Disulfur Moiety (2006) (27)
- Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. (2011) (26)
- Dioxygen reactivity of new bispidine-copper complexes. (2012) (26)
- Synthesis and X-ray crystal structure of a trinuclear copper(I) cluster (1989) (26)
- Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes. (2005) (26)
- Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen. (1999) (25)
- Copper dioxygen complexes stable at ambient temperature:optimization of ligand design and solvent (1997) (25)
- Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation. (2016) (25)
- Copper–Peptide Complex Structure and Reactivity When Found in Conserved His-Xaa-His Sequences (2014) (25)
- Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions. (2006) (25)
- Dioxygen–copper reactivity: a hydroperoxo–dicopper(II) complex (1987) (24)
- Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry. (2007) (24)
- Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. (2004) (24)
- Copper(I)/Dioxygen Reactivity with Dinuclear Compounds: Catalytic Oxygenation and Oxo-Transfer to a Ketone. (1996) (24)
- Dioxygen-copper reactivity: EXAFS studies of a peroxo-dicopper(II) complex (1987) (24)
- A Peroxynitrite Dicopper Complex: Formation via Cu-NO and Cu-O2 Intermediates and Reactivity via O-O Cleavage Chemistry. (2016) (23)
- Copper(I) and copper(II) complexes of new chelating pterins (1992) (23)
- Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals. (2005) (23)
- Carbon-halogen bond activation mechanism by copper(I) complexes of (2-pyridyl)alkylamine ligands. (2005) (23)
- Novel molecular receptors capable of formingCu2–O2 complexes. Effect of preorganization onO2 binding (1997) (23)
- Electrocatalytic four-electron reductions of O2 to H2O with cytochrome c oxidase model compounds (2003) (23)
- Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs. (2015) (23)
- Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction Reactivity. (2020) (23)
- Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. (2008) (23)
- Kinetic Preference without Thermodynamic Stabilization in the Intra- vs Intermolecular Formation of Copper-Dioxygen Complexes (1994) (23)
- Probing metal-mediated O2 activation in chemical and biological systems (2006) (22)
- An electron spin echo envelope modulation (ESEEM) study of electron-nuclear hyperfine and nuclear quadrupole interactions of dz2 ground state copper(II) complexes with substituted imidazoles (1993) (22)
- Synthesis, Structure, and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands (1999) (22)
- Copperdioxygen complexes: Functional models for proteins (1998) (21)
- Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety. (2008) (21)
- Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex. (2004) (21)
- Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4). (2005) (21)
- Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex. (2003) (20)
- Rates of electron transfer and redox potentials of some copper(II) thioether complexes (1981) (20)
- A molecular pinwheel multicopper(I) cluster, [(LS-)6CuI13(S2-)2]3+ with μ4-sulfido, μ3-thiolato and nitrogen ligands (2006) (20)
- Modeling of End-On (&mgr;-Peroxo)dicopper(II) Complexes. (1997) (20)
- REDOX COMPARISONS OF PSEUDOTETRAHEDRAL COPPER(I) COMPLEXES CONTAINING TRIPOD LIGANDS (1982) (20)
- Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species. (2003) (19)
- Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex (2001) (19)
- Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems. (2009) (19)
- Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity. (2016) (19)
- Isocyanides as Ligand-Directed Indicators of Cu(I) Coordination in Copper Proteins. Probing the Inequivalence of the Cu(I) Centers in Reduced Dopamine-.beta.-monooxygenase (1995) (19)
- Studies on a model copper mono-oxygenase system: peroxo–CuII binuclear intermediates in the hydroxylation of an aromatic ring (1984) (19)
- An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion. (2014) (18)
- Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex. (2010) (18)
- A cytochrome c oxidase reactivity model: generation of a peroxo-bridged iron/copper dinuclear complex (1992) (18)
- Progress in Inorganic Chemistry: Karlin/Inorganic Chemistry 54 (2005) (17)
- Low-temperature UV-visible and NMR spectroscopic investigations of O(2) binding to ((6)L)Fe(II), a ferrous heme bearing covalently tethered axial pyridine ligands. (2002) (17)
- Ligand Identity Induced Generation of Enhanced Oxidative HAT Reactivity for a CuII2(O2•¬-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H Bond. (2019) (17)
- Addition of nitrosonium ion to mercaptide-bridged binuclear iron(II) and cobalt(II) complexes (1974) (17)
- Bioinorganic chemistry: Redox control of oxoiron(IV). (2010) (16)
- Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc) (2001) (16)
- Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates. (2019) (16)
- Tricarbonyl[8-acetyl 2-4:6-7-η-bicyclo[3.2.1]octadienylium]iron, a novel rearrangement in the acylation of η-C8H8Fe(CO)3 (1977) (16)
- 9:Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site (2009) (16)
- Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O22−)-CuII]+ (2004) (16)
- Nitrogen Monoxide and Nitrous Oxide Binding and Reduction (2006) (16)
- Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates. (2015) (16)
- Further Insights into the Spectroscopic Properties, Electronic Structure, and Kinetics of Formation of the Heme−Peroxo−Copper Complex [(F8TPP)FeIII−(O22-)−CuII(TMPA)]+ (2007) (16)
- Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition. (2007) (15)
- Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase. (2019) (15)
- Oxo-bridged haem/non-haem iron complexes (1996) (15)
- Synthetic Models for Heme—Copper Oxidases (2004) (15)
- A dicopper(I) complex and its oxygenation chemistry using a dinucleating ligand with a pendant alkene group (1993) (15)
- Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex. (2012) (15)
- 3.07 – Copper Enzymes (2013) (14)
- Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine. (2007) (14)
- A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity. (2021) (14)
- Kinetic and thermodynamic parameters of copper-dioxygen interaction with different oxygen binding modes (1997) (14)
- Synthesis and characterization of the pentacoordinate mononitrosyliron complexes Fe(NO)[SCH2CH2N(CH3)(CH2)nN(CH3)CH2CH2S], n = 2,3 (1977) (14)
- Dioxygen–copper reactivity at trinuclear centers: formation of hexanuclear and mixed-valent adducts (1999) (14)
- Dioxygen and nitric oxide reactivity of a reduced heme/non-heme diiron(II) complex [(5L)FeII⋯FeIICl]+. Using a tethered tetraarylporphyrin for the development of an active site reactivity model for bacterial nitric oxide reductase (2000) (14)
- Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes. (2016) (14)
- Aluminum halide promoted carbonylation reactions: facile synthesis of bicyclo[3.2.1]oct-2-ene-4,8-dione from cyclohexadiene (tricarbonyl)iron (1978) (14)
- X-ray Structure Analysis of a Dicopper Complex of a New Binucleating Ligand Containing a para-Xylyl Connecting Group; Large Cu…Cu Separation in [(CuCl2C18H20N3)2]·2H2O (1981) (14)
- Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release. (2019) (14)
- Formation, Structure, and Reactivity of Copper Dioxygen Complexes (1999) (14)
- Model for the possible 'endogenous' bridge in oxy-hemocyanin: a di-μ-(OR)2-bridged dicopper(II) complex (R = H, alkyl) with low-energy charge-transfer absorption (1990) (13)
- PROGRESS IN INORGANIC CHEMISTRY (2008) (13)
- Extended metal environments of cytochrome c oxidase structures. (1998) (12)
- Copper-dioxygen chemistry and modeling the Fe-Cu center in cytochrome c oxidase (1995) (12)
- Dioxygen-copper reactivity: intermediacy of a peroxo-dicopper(II) (dioxygen-copper) complex in the hydroxylation reaction of a model mono-oxygenase system (1986) (12)
- Copper Ion Complexes with Derivatized Chelating Pterin Ligands (1997) (12)
- X-ray Absorption Spectroscopic Studies of the Copper(I) Complexes of Crown Ether Appended Bis{(2-pyridyl)ethyl}amines and Their Dioxygen Adducts. (1999) (12)
- Oxidative dehalogenation during a copper complex mediated hydroxylation reaction (1990) (12)
- Model complexes for ligand probes of met-hemocyanin and met-tyrosinase derivatives. Structure of a novel 1,1-azido bridged binuclear copper(II) complex (1983) (12)
- Synthesis and structure of a mono-chloro bridged copper(II) dimer containing a linear CuII-Cl-CuII bridge (1984) (12)
- Vibrational spectroscopic studies of a hydroxo-bridged dinuclear copper complex, a potential model for multicopper proteins (1992) (11)
- Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach. (2017) (11)
- SULFUR‐BRIDGED BINUCLEAR IRON(II) COMPLEXES. EFFECT OF LIGAND CONSTRAINTS ON THEIR PHYSICAL PROPERTIES, REACTIONS WITH CARBON MONOXIDE AND ALKYL ISOCYANIDES (1977) (11)
- Resonance raman studies of phenolate-bridged binuclear copper complexes. relevance to hemocyanin and tyrosinase (1984) (11)
- EPR OF COPPER(II) COMPLEXES WITH TRIPODAL LIGANDS: DYNAMICAL PROPERTIES (1984) (11)
- Cu(I)-dioxygen reactivity: structural characterization of a bridged-binuclear Cu(II) complex formed by oxidation of a new binuclear Cu(I) compound (1984) (11)
- Peroxide (O22−) as a bridging ligand for copper(II): strong exchange coupling in complexes derived from copper(I) and dioxygen (1991) (11)
- Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome c oxidase inspired low-spin heme–peroxo–copper complexes (2019) (11)
- Oxidative addition of nitrosonium ion to sulfur-bridged binuclear iron(II) and cobalt(II) complexes (1977) (11)
- End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy. (2022) (11)
- Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations. (2012) (10)
- Phosphate ester coordination to dicopper(II) compounds; X-ray structure of a bis(4-nitrophenyl)phosphato bridged dicopper(II) complex (1993) (10)
- Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition. (2019) (10)
- Distorted tetrahedral complexes of copper(I) and copper(II) displaying N2S2 co-ordination. X-Ray crystal structure of [2-(2-pyridyl)ethyl]bis[2-(ethylthio)ethyl]aminecopper(I) tetraphenylborate (1979) (10)
- Synthesis and characterization of PY2- and TPA-appended diphenylglycoluril receptors and their bis-CuI complexes (2006) (10)
- Copper-dioxygen complexes and their roles in biomimetic oxidation reactions (2003) (10)
- Synthesis and Characterization of New Trinuclear Copper Complexes. (2012) (9)
- Photoinduced carbon monoxide migration in a synthetic heme-copper complex. (2005) (9)
- Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. (2014) (9)
- Reversible carbon monoxide photodissociation from Cu(I) coordination compounds. (2001) (9)
- Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity (2014) (9)
- Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization (2016) (9)
- New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins. (2013) (9)
- Orbitally dependent exchange in two sulfur-bridged binuclear iron(II) complexes. Magnetic exchange in transition metal complexes. 11 (1976) (8)
- Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes. (2004) (8)
- Functional Models for Hemocyanin and Copper Monooxygenases (1993) (8)
- Synthesis and structure of a CO-containing phenoxo-bridged dicopper(I) complex (1988) (8)
- Models of Copper Enzymes and Heme-Copper Oxidases (2000) (8)
- Models for Methemocyanin Derivatives: Structural and Spectroscopic Comparisons of Related Azido‐Coordinated (N‐ 3) Mono‐ and Dinuclear Copper(II) Complexes. (1987) (8)
- Kinetic stability of the cysteine adduct with [tris(2-(2-pyridyl)ethyl)amine]copper(II) (1986) (8)
- Progress in Inorganic Chemistry: Karlin/Chemistry V57 (2011) (8)
- Aluminum trihalide interactions with polyolefin tricarbonyliron compounds (1978) (7)
- Reactions of a heme-superoxo complex toward a cuprous chelate and •NO(g): CcO and NOD chemistry. (2015) (7)
- Synthesis and characterization of a novel dicopper(I) complex of a thiaether containing meta-xylyl binucleating ligand (1983) (7)
- Copper mediated hydroxylation of a modified monooxygenase model system (1988) (7)
- Preliminary communicationAluminium trihalide interactions with polyolefin tricarbonyliron compounds (1979) (7)
- The environment of multinuclear copper metal linkages in protein structures (1998) (7)
- Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions. (2019) (7)
- Reaction of halides with tricarbonylcyclohexadienyliron cation: Preparation of tricarbonyl(5exo-Fluorocyclohexa-1,3-diene)iron (1978) (6)
- Oxidation of (hydroxyethyl)ferrocene by [2-pyridylmethylbis(2-ethylthioethyl)/amine]copper(II) (1987) (6)
- Oxidant Types in Copper—Dioxygen Chemistry: The Ligand Coordination Defines the Cun‐O2 Structure and Subsequent Reactivity (2005) (6)
- Copper-Dioxygen Reactivity Using Dinucleating Ligands with Activated Methylene or Ketone Function (2007) (6)
- Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H-atom Transfer (HAT). (2020) (6)
- Ligand Influences in Heme–Copper O2-Chemistry as Synthetic Models for Cytochrome c Oxidase (2004) (5)
- Investigations of dioxygen reactivity with synthetic models of the metalloproteins hemocyanin and cytochrome c oxidase (1993) (5)
- Dimethylanilinic N-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species. (2019) (5)
- Solving 21st Century Problems in Biological Inorganic Chemistry Using Synthetic Models. (2015) (5)
- A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization (2018) (5)
- Dioxygen Reactivity in Copper Proteins and Complexes (1995) (5)
- ORBITALLY DEPENDENT EXCHANGE IN TWO SULFUR‐BRIDGED BINUCLEAR IRON(II) COMPLEXES. MAGNETIC EXCHANGE IN TRANSITION METAL COMPLEXES. 11 (1977) (5)
- Heme-Cu Binucleating Ligand Supports Heme/O2 and FeII-CuI/O2 Reactivity Providing High- and Low-Spin FeIII-Peroxo-CuII Complexes. (2019) (5)
- Pyridine ligand donor substituent effects upon structure, redox properties and O2 reactivity of xylyl dinuclear copper(I) complexes (1993) (5)
- The structure of the copper(II) analogue of a pseudotetrahedral copper(I) thioether complex (1981) (5)
- Progress in Inorganic Chemistry Volume 58 (2014) (5)
- Heme—Copper/Dioxygen Adduct Formation, Properties, and Reactivity (2007) (5)
- Copper–dioxygen reactivity involved in the formation of µ-oxo [(por)FeIII–O–CuIIL]+ heterodinuclear complexes (por = porphyrinate, L = tetradentate ligand), and novel synthesis of square-planar FeII(por) species (1995) (5)
- Dioxygen-Copper Reactivity. Reversible Binding of O2 and CO to a Phenoxo-Bridged Dicopper(I) Complex. (1987) (4)
- Kinetic Stability of the Cysteine Adduct with [Tris(2-(2-pyridyl)ethyl)amine]copper(II). (1986) (4)
- Unprecedented direct cupric-superoxo conversion to a bis-μ-oxo dicopper(III) complex and resulting oxidative activity. (2019) (4)
- Synthesis and characterization of copper(II) complexes of a tetradentate N3O ligand: Mononuclear analogs for phenolate-bridged dinuclear complexes (1985) (4)
- Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. (2009) (4)
- Ligand Influences in Copper—Dioxygen Complex Formation and Substrate Oxidations (2009) (4)
- Model complexes for the active sites of reduced and oxidized sites of hemocyanin and tyrosinase. Structures of binuclear Cu(I) and Cu(II) complexes and characterization of a model copper monooxygenase reaction (1983) (4)
- Biomimetic Copper-Dioxygen Chemistry: Reversible O2-Binding and Mechanistic Insights into Cu(I)/O2-Mediated Arene Hydroxylation and Amide Hydrolysis (1996) (3)
- Structure and properties of a monomeric copper(II) complex with a N3 tridentate unit containing 2-thio-1-methylimidazole (1984) (3)
- A Cu2-O2 Complex. Crystal Structure and Characterization of a Reversible Dioxygen Binding System. (1988) (3)
- Copper Peroxide Bioinorganic Chemistry: From Metalloenzymes to Bioinspired Synthetic Systems (2014) (3)
- Intermolecular versus intramolecular electron-/atom- (Cl) transfer in heme-iron and copper pyridylalkylamine complexes (2008) (3)
- Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+. (2004) (3)
- Functional biomimics for copper proteins involved in reversible O2-binding, substrate oxidation/oxygenation and nitrite reduction. (1994) (3)
- Bio-inorganic chemistry New advances, new directions and new investigators (2001) (3)
- Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction. (2021) (3)
- Cytochrome c Oxidase and Models (2011) (3)
- SYNTHESIS AND STRUCTURE OF A NOVEL DICOPPER(I) COMPLEX OF A NEW BINUCLEATING LIGAND (1982) (3)
- Investigation of copper(I) and copper(II) complexes of new pterin chelates. (1992) (2)
- Vibrational, Electronic, and Resonance Raman Spectral Studies of (Cu2(XYL‐O‐)O2)+ (I), a Copper(II) Peroxide Model Complex of Oxyhemocyanin. (1987) (2)
- Biomimetic Binding and Activation of Dioxygen with Copper Complexes (1991) (2)
- Dioxygen-Copper Reactivity: Generation, Characterization, and Reactivity of a Hydroperoxo-Dicopper(II) Complex. (1989) (2)
- Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase. (2020) (2)
- Copper—Dioxygen Complexes: Functional Models for Proteins (1998) (2)
- The Society of Biological Inorganic Chemistry (2005) (2)
- Thioether S-Ligation in a Side-on μ-η:η-Peroxo Dicopper(II) Complex (2009) (2)
- Dioxygen activation by copper(I) complexes: Electronic effects on the formation and substrate reactivity of the Cu202 core (2003) (1)
- EPR of trigonal bipyramidal copper(II) complexes with tripod ligands (1983) (1)
- Isolation and X-Ray Structure of a Dinuclear Copper-Nitrosyl Complex. (1990) (1)
- Some synthetic and structural aspects of neutral organocuprate reagents CunLimRn+m; the asymmetric bonding configuration of the bridging organo group (1987) (1)
- Reactivity models for cytochrome C oxidase: Synthesis and characterization of peroxo-bridged iron-copper bimetallic complexes (1992) (1)
- Copper ligand influences in synthetic model reactivity studies of the cytochrome c oxidase binuclear active site (2003) (1)
- Coordination chemistry of copper-sulphur complexes of physiological relevance (1979) (1)
- Models for Copper Proteins: Reversible Binding and Activation of Dioxygen and the Reactivity of Peroxo and Hydroperoxo Dicopper(II) Complexes (1988) (1)
- ESR spectra of new dicopper(II) complexes of novel binucleating ligands (1982) (1)
- X-Ray Absorption Studies of Three-Coordinate Dicopper(I) Complexes and Their Dioxygen Adducts. (1988) (1)
- Models for Met-Hemocyanin Derivatives: Structural and Spectroscopic Comparisons of Analogous Phenolate and X (X: OH-, OMe-, N- 3, Cl-, OAc-, OBz-) Doubly Bridged Dinuclear Copper(II) Complexes. (1987) (1)
- The Society of Biological Inorganic Chemistry (2006) (1)
- Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a Cu II2 (O 2•− ) Complex Driven by Formation of a Cu II2 ( − OOH) Compound with a Strong O–H Bond (2019) (1)
- A note from the President (2005) (1)
- Copper-oxygen complexes for biomimetic oxidation catalysis (2001) (1)
- Progress in Inorganic Chemistry, Volume 56 (2002) (1)
- A review of “METAL IONS IN BIOLOGICAL SYSTEMS. VOL. 13: COPPER PROTEINS. Helmut Siqel, ed., Marcel Oekker, Inc., 270 Madison Ave., New York, NY 10016, 424 PP., 1981, $59.75” (1982) (1)
- Comprar Progress in Inorganic Chemistry, Volume 56 | Kenneth D. Karlin | 9780470395479 | Wiley (2009) (1)
- Dioxygen Reactivity Models for Cytochrome C Oxidase: Synthesis and Characterization of Oxo and Hydroxo-Bridged Porphyrin-Iron/Copper Dinuclear Complexes (1993) (1)
- Spectroscopic and computational characterization of Cu II – OOR ( R = H or cumyl ) complexes bearing a Me 6-tren ligand † (2012) (1)
- Copper-dioxygen complexes: Functional models for proteins (1997) (1)
- Macrocyclic Ligands Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu 2 O 2 Core with Unexpected Structure and Reactivity (2016) (1)
- X-ray diffraction study of a low-temperature copper(I)/dioxygen adduct: a solid solution (2008) (0)
- Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity (2014) (0)
- COPPER(I)-DIOXYGEN REACTIVITY: STRUCTURAL CHARACTERIZATION OF A BRIDGED-BINUCLEAR COPPER(II) COMPLEX FORMED BY OXIDATION OF A NEW BINUCLEAR COPPER(I) COMPOUND (1984) (0)
- Thioether ligand containing copper complexes; Modeling PHM and DβH proteins (2003) (0)
- Fourth international conference on bioinorganic chemistry : Massachusetts Institute of Technology (MIT), Cambridge, MA, U.S.A., July 24-28, 1989 (1988) (0)
- Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+. (2007) (0)
- Highlights and Directions in Copper-Dioxygen Chemistry of Bioinorganic Relevance (特集 生物無機化学のこれから) (2013) (0)
- A Note from the President (2003) (0)
- Dioxygen-Copper Reactivity. Models for Hemocyanin: Reversible O2 and CO Binding to Structurally Characterized Dicopper(I) Complexes Containing Hydrocarbon-Linked Bis(2-(2-pyridyl)ethyl)amine Units. (1988) (0)
- Cumulative Index, Volumes 1-44 (1996) (0)
- TRICARBONYL(8-ACETYL 2-4-6-7-η-BICYCLO(3.2.1)OCTADIENYLIUM)IRON, A NOVEL REARRANGEMENT IN THE ACYLATION OF TRICARBONYL((1,2,3,4-η)-1,3,5,7-CYCLOOCTATETRAENE)IRON (1977) (0)
- Dioxygen-Copper Reactivity: Intermediacy of a Peroxo-Dicopper(II) (Dioxygen-Copper) Complex in the Hydroxylation Reaction of a Model Mono-Oxygenase System. (1987) (0)
- Copper(I) and copper(II) complexes with tetradentate tripod ligands (1989) (0)
- Cumulative Index, Volumes 1-56 (2009) (0)
- Cumulative Index, Volumes 1-57 (2011) (0)
- Intramolecular exchange within tripodal pyridyl copper(I) complexes (1992) (0)
- Reaction of dioxygen with a mixed-valence copper(I)-copper(II) dinuclear complex (1992) (0)
- A Note from the President (2005) (0)
- Copper Enzymes Involved in Multi-Electron Processes (2020) (0)
- Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. (2004) (0)
- PostersSynthesis, characterization and reactivity of monomeric Cu(II)-peroxo compounds, [LCu(II)-OOR]n+ (1989) (0)
- Dioxygen-Copper Reactivity: Hydroxylation-Induced Methyl Migration in a Copper Monooxygenase Model System. (1988) (0)
- Small molecule activation and synthetic analogues: general discussion. (2022) (0)
- Reactions of dinuclear copper complexes with nitrogen oxides (1992) (0)
- A Note from the President (2004) (0)
- Cumulative Index, Volumes 1-53 (2005) (0)
- Cumulative Index, Volumes 1-47 (1997) (0)
- Oxidative Dehalogenation During a Copper Complex Mediated Hydroxylation Reaction. (1991) (0)
- Amide hydrolysis mediated by a dinuclear copper complex with terminal CuOH ligation (1993) (0)
- Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species En Route to a Cupric Hyponitrite Intermediate. (2023) (0)
- Activation of dioxygen by copper metalloproteins and insights from model complexes (2016) (0)
- TETRAGONAL VS. TRIGONAL COORDINATION IN COPPER(II) COMPLEXES WITH TRIPOD LIGANDS: STRUCTURES AND PROPERTIES OF (CU(C21H24N4)CL)PF6 AND (CU(C18H18N4)CL)PF6 (1983) (0)
- A Note from the President (2005) (0)
- Time resolved spectroscopic determination of a sub-microsecond, 1:1 copper dioxygen interaction in which the rate exceeds that for hemes (2003) (0)
- SYNTHESIS AND STRUCTURE OF FE(L′H)(NO)2, A TETRACOORDINATE COMPLEX HAVING A TWELVE-MEMBERED CHELATE RING, AND ITS CONVERSION TO PENTACOORDINATE FEL′(NO) THROUGH FORMAL LOSS OF “HNO” (L′ = SCH2CH2NMECH2CH2CH2NMECH2CH2S-) (1980) (0)
- The rate of dioxygen and carbon monoxide binding to copper(I) complexes of various ligands: Extension of the "flash-and-trap" technique (2008) (0)
- A mu-eta2:eta2-disulfide dicopper(II) complex from reaction of S8 with a copper(I) precursor: reactivity of the bound disulfur moiety. (2006) (0)
- Dioxygen-Copper Reactivity: X-Ray Structure and Characterization of an (Acylperoxo)dicopper Complex. (1988) (0)
- A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands. (2006) (0)
- Synthesis and Structure of a CO-Containing Phenoxo-bridged Dicopper(I) Complex. (1988) (0)
- The Society of Biological Inorganic Chemistry (2006) (0)
- Cumulative Index, Volumes 1-49 (2001) (0)
- Copper: Hemocyanin/Tyrosinase Models (2014) (0)
- Cover Picture: Synthesis and Characterization of PY2‐ and TPA‐Appended Diphenylglycoluril Receptors and Their Bis‐CuI Complexes (Eur. J. Org. Chem. 10/2006) (2006) (0)
- Cumulative Index, Volumes 1-58 (2014) (0)
- Celebrating Ed Solomon (2016) (0)
- CCDC 1430274: Experimental Crystal Structure Determination (2016) (0)
- Supramolecular Cu2:O2 complexes; Towards biomimetic and selective oxygenation of exogeneous substrates (1995) (0)
- SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF COPPER(I) AND COPPER(II) DERIVATIVES OF A NEW SYMMETRIC TRIPODAL LIGAND N(CH2CH2-PY)3, (PY = 2-PYRIDYL) (1982) (0)
- Comprar Progress in Inorganic Chemistry, Volume 55 | Kenneth D. Karlin | 9780471682424 | Wiley (2007) (0)
- Dioxygen-Copper Reactivity. Comparisons of the Reactions of Electrophiles and Other Reagents with Three Classes of Peroxo-Dicopper(II), (Cu2-O2)n+, Species. (1989) (0)
- Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization (2016) (0)
- Wiley End User License Agreement (2014) (0)
- Cumulative Index, Volumes 1-59 (2014) (0)
- Oxygenation kinetics of iron and copper protein active site model complexes (2003) (0)
- Synthesis and Characterisation of PY2- and TPA-Appended Diphenylglycoluril Receptors and Their Bis-Cu(I) Complexes (2017) (0)
- Copper-O22 reactivity. Involvement of oxodicopper(II) in amine oxidations and reduction of O2 using porphyrin-iron(II) and copper(I) (1993) (0)
- A Note from the President (2004) (0)
- Reactivity of LCu(I)n (n = 1,2) and dioxygen-dicopper complexes with small molecules or substrates (1989) (0)
- Announcement: Eighth International Conference on Bioinorganic Chemistry (1996) (0)
- The crystal structure of hypoxanthinium nitrate monohydrate: Intercalation of water between purines (1982) (0)
- Copper‐Mediated Hydroxylation of an Arene: Kinetics and Mechanism of the Reaction of a Dicopper(II) m‐Xylyl‐Containing Complex with H2O2 to Yield a Phenoxodicopper(II) Complex. (1988) (0)
- Structure, electrochemistry and reactivity of copper(I) complexes containing tripodal tetradentate ligands. (1992) (0)
- onheme { FeNO } 6 complex : synthesis and structural and spectroscopic characterization † (2018) (0)
- REACTION OF HALIDES WITH TRICARBONYLCYCLOHEXADIENYLIRON CATION- PREPARATION OF TRICARBONYL(5-EXO-FLUOROCYCLOHEXA-1,3-DIENE)IRON (1979) (0)
- Copper Enzymes/Models (2010) (0)
- A Note from the President (2004) (0)
- Additions and Corrections - Orbitally Dependent Exchange in Two Sulfur-Bridged Binuclear Iron(II) Complexes. Magnetic Exchange in Transition Metal Complexes. (1977) (0)
- The Society of Biological Inorganic Chemistry (2002) (0)
- Modelling the binuclear site of cytochrome oxidase: Examples of μ-oxo and μ-hydroxo bridged ferric-cupric complexes (1993) (0)
- Dioxygen reactivity with new di- and trinuclear copper(I) complexes (1992) (0)
- Cumulative Index, Volumes 1-46 (1997) (0)
- Cumulative Index, Volumes 1-42 (1994) (0)
- Dinuclear Cu(I) complexes containing two connected tripodal tetradentate subunits. (1992) (0)
- Cumulative Index, Volumes 1-55 (2007) (0)
- Progress in Inorganic Chemistry: Volume 59 (2014) (0)
- ALUMINUM HALIDE PROMOTED CARBONYLATION REACTIONS- FACILE SYNTHESIS OF BICYCLO(3.2.1)OCT-2-ENE-4,8-DIONE FROM CYCLOHEXADIENE(TRICARBONYL)IRON (1978) (0)
- A Note from the President (2005) (0)
- Design and synthesis of model systems for oxygen binding and activation in dinuclear copper proteins. (1992) (0)
- Copper: Hemocyanin/Tyrosinase ModelsBased in part on the article Copper: Hemocyanin/Tyrosinase Models by Nobumasa Kitajima which appeared in the Encyclopedia of Inorganic Chemistry, First Edition. (2006) (0)
- Electron transfer, spectroscopy and theory: general discussion. (2022) (0)
- Natural and artificial enzymes and medicinal aspects: general discussion. (2022) (0)
- Concluding remarks: discussion on natural and artificial enzymes including synthetic models. (2022) (0)
- Peroxo and superoxo copper complexes: Electronic structure contributions to reactivity (1995) (0)
- Copper-dioxygen (Cu2O2) complexes: Synthesis, structure and biological relevance (1991) (0)
- Cumulative Index, Volumes 1-43 (1995) (0)
- Cumulative Index, Volumes 1-41 (1994) (0)
- EPR of mixed valence copper dimers (1989) (0)
- Kinetic and Thermodynamic Studies on the Reaction of O2 with Two Dinuclear Copper(I) Complexes. (1989) (0)
- Crystal structure end electron spin echo modulation (ESEEM) study of [Cu(II)(TEPA)NO2]PF6Crystal structure end electron spin echo modulation (ESEEM) study of [Cu(II)(TEPA)NO2]PF6 (TEPA)=Tris[2-(2-pyridyl)ethyl]amine): A model for the purported structure of the nitrite derivative of hemocyanin (TEPA) (1993) (0)
- Cumulative Index, Volumes 1-54 (2005) (0)
- SYNTHESIS AND CHARACTERIZATION OF A NOVEL DICOPPER(I) COMPLEX OF A THIA ETHER CONTAINING M-XYLYL BINUCLEATING LIGAND (1983) (0)
- Oxo-bridged FeCu and heme/non-heme iron complexes as heme-copper oxidase models (1995) (0)
- Protagonists in Chemistry (2008) (0)
- Cumulative Index, Volumes 1–51 (2002) (0)
- Cumulative Index, Volumes 1-45 (1996) (0)
- Cumulative Index, Volumes 1-48 (1999) (0)
- Catecholate Coordination to Copper: Structural Characterization of a Tetrachloro- o-catecholate-Bridged Dicopper(II) Complex as a Model for Intermediates in Copper-Catalyzed Oxidation of Catechols. (1986) (0)
- A note from the President (2002) (0)
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Other Resources About Kenneth Karlin
What Schools Are Affiliated With Kenneth Karlin ?
Kenneth Karlin is affiliated with the following schools:
- University of California, Berkeley
- University at Albany, SUNY
- University of Marburg
- Ewha Womans University
- University of Tsukuba
- University of Basel
- Osaka University
- Columbia University
- University of Helsinki
- Osaka Metropolitan University
- Stanford University
- Johns Hopkins University
- Delft University of Technology
- University of Florence
