Kensō Soai
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Japanese chemist
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Chemistry
Kensō Soai's Degrees
- PhD Chemistry Hokkaido University
Why Is Kensō Soai Influential?
(Suggest an Edit or Addition)According to Wikipedia, is a Japanese organic chemist. He is a university lecturer in the Applied Chemistry Department of Tokyo University of Science. Soai studied at the University of Tokyo, where he received his Ph.D. in 1979 in organic synthesis under Teruaki Mukaiyama and was a fellow of the Japan Society for the Promotion of Science. He conducted his postdoctoral studies with Ernest L. Eliel at the University of North Carolina. In 1981, he became a lecturer at Tokyo University of Science, and was promoted to associate professor and full professor .
Kensō Soai's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Enantioselective Addition of Organozinc Reagents to Aldehydes (1992) (952)
- Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule (1995) (781)
- Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes using chiral pyrrolidinylmethanols and their metal salts (1987) (250)
- d- and l-Quartz-Promoted Highly Enantioselective Synthesis of a Chiral Organic Compound (1999) (246)
- Enantioselective automultiplication of chiral molecules by asymmetric autocatalysis. (2000) (232)
- Enantioface-differentiating (asymmetric) addition of alkyllithium and dialkylmagnesium to aldehydes by using (2S,2'S)-2-hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidines as chiral ligands (1979) (199)
- Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light. (2005) (185)
- Chiral N,N-dialkylnorephedrines as catalysts of the highly enantioselective addition of dialkylzincs to aliphatic and aromatic aldehydes. The asymmetric synthesis of secondary aliphatic and aromatic alcohols of high optical purity (1991) (184)
- Asymmetric synthesis of pyrimidyl alkanol without adding chiral substances by the addition of diisopropylzinc to pyrimidine-5-carbaldehyde in conjunction with asymmetric autocatalysis (2003) (182)
- Amplification of chirality from extremely low to greater than 99.5 % ee by asymmetric autocatalysis. (2003) (178)
- Asymmetric Autocatalysis Triggered by Carbon Isotope (13C/12C) Chirality (2009) (171)
- Amplification of a Slight Enantiomeric Imbalance in Molecules Based on Asymmetric Autocatalysis: The First Correlation between High Enantiomeric Enrichment in a Chiral Molecule and Circularly Polarized Light (1998) (156)
- The Michael Reaction of Silyl Enol Ethers with α,β-Unsaturated Eetones and Acetals in the Presence of Titanium Tetraalkoxide and Titanium Tetrachloride (1976) (148)
- Asymmetric Induction by Helical Hydrocarbons: [6]‐ and [5]Helicenes (2001) (144)
- Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol (1996) (136)
- Practically Perfect Asymmetric Autocatalysis with (2-Alkynyl-5-pyrimidyl)alkanols. (1999) (128)
- Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride (1986) (114)
- Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality. (2014) (112)
- Asymmetric self-catalytic reaction. Self-production of chiral 1-(3-pyridyl)alkanols as chiral self-catalysts in the enantioselective addition of dialkylzinc reagents to pyridine-3-carbaldehyde (1990) (101)
- Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess (2003) (96)
- Catalytic asymmetric synthesis of optically active alkynyl alcohols by enantioselective alkynylation of aldehydes and by enantioselective alkylation of alkynyl aldehydes (1990) (95)
- Enantioselective addition of dialkylzincs to aldehydes using heterogeneous chiral catalysts immobilized on alumina and silica gel (1990) (92)
- Highly enantioselective synthesis of organic compound using right- and left-handed helical silica (2003) (91)
- Achiral nucleobase cytosine acts as an origin of homochirality of biomolecules in conjunction with asymmetric autocatalysis. (2008) (89)
- Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis. (2006) (88)
- Highly Enantioselective Synthesis Induced by Chiral Primary Alcohols Due to Deuterium Substitution (2000) (86)
- Polymer-bound ephedrine as an efficient chiral catalyst for the enantioselective addition of dialkylzincs to aldehydes (1988) (83)
- Asymmetric Autocatalysis with Amplification of Chirality (2007) (81)
- Asymmetric synthesis utilizing circularly polarized light mediated by the photoequilibrium of chiral olefins in conjunction with asymmetric autocatalysis. (2004) (75)
- THE NEW MICHAEL REACTION (1974) (72)
- Practical procedure for the chemoselective reduction of esters by sodium borohydride. Effect of the slow addition of methanol (1984) (71)
- Chiral discrimination of cryptochiral saturated quaternary and tertiary hydrocarbons by asymmetric autocatalysis. (2006) (70)
- Discovery of asymmetric autocatalysis with amplification of chirality and its implication in chiral homogeneity of biomolecules. (2006) (70)
- Asymmetric synthesis of optically active β-substituted ketones by highly enantioselective catalytic conjugate addition of dialkylzinc reagents to enones using a catalyst system of nickel(II)-chiral ligand–achiral ligand in acetonitrile/toluene (1989) (69)
- Discovery and Development of Asymmetric Autocatalysis (2004) (69)
- Enantioselective synthesis induced by tetrathia-[7]-helicenes in conjunction with asymmetric autocatalysis (2006) (68)
- The origins of homochirality examined by using asymmetric autocatalysis. (2014) (68)
- Asymmetric autocatalysis and its application to chiral discrimination. (2002) (66)
- Asymmetric amplification using chiral cocrystals formed from achiral organic molecules by asymmetric autocatalysis. (2005) (66)
- An enantioselective Baylis–Hillman reaction catalyzed by chiral phosphines under atmospheric pressure (1998) (65)
- Highly enantioselective alkylation of carbon–nitrogen double bonds. Catalytic and stoichiometric asymmetric synthesis of optically active amines by the enantioselective addition of dialkylzinc reagents to N-diphenylphosphinoylimines (1992) (64)
- A new chiral catalyst for the highly enantioselective addition of dialkylzinc reagents to aliphatic aldehydes (1987) (61)
- Catalytic asymmetric induction in enantioselective conjugate addition of dialkylzincs to enones (1988) (58)
- Asymmetric autocatalysis and the origin of chiral homogeneity in organic compounds. (2002) (57)
- Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes using N,N-Dialkylnorephedrines as Chiral Catalysts (1994) (56)
- Chiral piperazine as a new chiral catalyst for the enantioselective addition of dialkyl zincs to aryl aldehydes (1987) (56)
- Asymmetric Synthesis of an Organic Compound with High Enantiomeric Excess Induced by Inorganic Ionic Sodium Chlorate (2000) (55)
- Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol (2001) (54)
- Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess (2015) (53)
- The distribution of chiral asymmetry in meteorites: An investigation using asymmetric autocatalytic chiral sensors (2006) (51)
- Enantioselective conjugate addition of diethylzinc to enones using chiral β-aminoalcohol as chiral catalyst or ligand (1991) (51)
- Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis (2011) (51)
- Generation of Absolute Controlled Crystal Chirality by the Removal of Crystal Water from Achiral Crystal of Nucleobase Cytosine (2010) (50)
- Asymmetric autocatalysis: triggered by chiral isotopomer arising from oxygen isotope substitution. (2011) (49)
- Sodium Borohydride-t-butyl Alcohol-Methanol as an Efficient System for the Selective Reduction of Esters (1982) (48)
- One-pot asymmetric autocatalytic reaction with remarkable amplification of enantiomeric excess (1997) (48)
- Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis. (2006) (47)
- Asymmetric synthesis of β-hydroxyesters by the enantioselective reformatsky reaction in the presence of chiral aminoalcohols (1991) (45)
- ENANTIOSELECTIVE ADDITION OF ACETYLENE TO ALDEHYDE. PREPARATION OF OPTICALLY ACTIVE ALKYNYL ALCOHOLS (1979) (45)
- ASYMMETRIC AUTOCATALYTIC REACTION OF 3-QUINOLYLALKANOL WITH AMPLIFICATION OF ENANTIOMERIC EXCESS (1996) (45)
- Highly enantioselective asymmetric autocatalysis induced by chiral ionic crystals of sodium chlorate and sodium bromate (2004) (43)
- Asymmetric autocatalysis induced by cinnabar: observation of the enantioselective adsorption of a 5-pyrimidyl alkanol on the crystal surface. (2013) (43)
- Mechanistic insights in the reversal of enantioselectivity of chiral catalysts by achiral catalysts in asymmetric autocatalysis. (2008) (43)
- Catalytic asymmetric synthesis of chiral diol, bis[2-(1-hydroxyalkyl)-phenyl]ether, an asymmetric autocatalytic reaction (1994) (42)
- Small amounts of achiral beta-amino alcohols reverse the enantioselectivity of chiral catalysts in cooperative asymmetric autocatalysis. (2005) (41)
- Enantioselective synthesis of chiral 5-carbamoyl-3-pyridyl alcohols by asymmetric autocatalytic reaction (1996) (41)
- Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess. (2015) (39)
- New polymer bound chiral catalyst with methylene spacer for the enantioselective addition of diethylzinc to aldehydes (1991) (39)
- The Preparation of N-Protected Amino Alcohols and N-Protected Peptide Alcohol by Reduction of the Corresponding Esters with Sodium Borohydride. An Improved Procedure Involving a Slow Addition of a Small Amount of Methanol (1984) (38)
- Enantioface-differentiating Reactions Using (2S,2′S)-2-Hydroxymethyl-1-[(1-alkyl-2-pyrrolidinyl)methyl]pyrrolidines as Chiral Ligands. Addition of Lithium Derivatives of Methyl Phenyl Sulfide, Acetonitrile, N-Nitrosodimethylamine, and 2-Methylthiothiazoline to Aldehydes (1979) (38)
- Reduction of Symmetric and Mixed Anhydrides of Carboxylic Acids by Sodium Borohydride with Dropwise Addition of Methanol (1987) (37)
- Highly enantioselective synthesis of a chiral 3-quinolylalkanol by an asymmetric autocatalytic reaction (1996) (37)
- Complementary catalytic asymmetric induction in the enantioselective addition of diethylzinc to aldehydes (1987) (37)
- Asymmetric alkenylation of chiral and prochiral aldehydes catalysed by chiral or achiral amino alcohols: catalytic diastereoselective synthesis of protected erythro-sphingosine and enantioselective synthesis of chiral diallyl alcohols (1994) (37)
- Chiral amino alcohols bound to diimines, diamines and dendrimers as chiral ligands for the enantioselective ethylation of N-diphenylphosphinylimines (1997) (36)
- Spontaneous absolute asymmetric synthesis promoted by achiral amines in conjunction with asymmetric autocatalysis (2010) (36)
- Asymmetric Autocatalysis Triggered by Chiral Crystals Formed from Achiral Compounds and Chiral Isotopomers (2012) (35)
- Catalytic chirally self-replicating molecule. Asymmetric autocatalytic reaction of a zinc alkoxide of chiral 1-ferrocenyl-2-methylpropan-1-ol (1995) (35)
- Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis† †Electronic supplementary information (ESI) available: The asymmetric autocatalysis induced by bis(phenol) 5. See DOI: 10.1039/b912813a Click here for additional data file. (2009) (34)
- Asymmetric Autocatalysis Induced by Chiral Crystals of Achiral Tetraphenylethylenes (2010) (34)
- Asymmetric synthesis using chiral piperazines. Part 3. Enantioselective addition of dialkylzincs to aryl aldehydes catalysed by chiral piperazines (1991) (34)
- Synthesis of chiral dendrimers with a hydrocarbon backbone and application to the catalytic enantioselective addition of dialkylzincs to aldehydes (2000) (34)
- Asymmetric Induction by a Nitrogen 14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis (2016) (33)
- Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules. (2012) (33)
- Enantioselective addition of dialkylzincs to pyridine-carbaldehyde in the presence of chiral aminoalcohols asymmetric synthesis of pyridylalkyl alcohols (1989) (32)
- Asymmetric autocatalysis of a pyrimidyl alkanol induced by chiral monosubstituted [2.2]paracyclophanes. (2001) (32)
- Asymmetric synthesis of functionalized tertiary homoallyl alcohols by diastereoselective allylation of chiral .alpha.-keto amides derived from (S)-proline esters: control of stereochemistry based on saturated coordination of Lewis acid (1986) (31)
- Amplification of Chirality as a Pathway to Biological Homochirality (2010) (31)
- Asymmetric autocatalysis triggered by oxygen isotopically chiral glycerin. (2013) (31)
- Polymer-bound N-alkylnorephedrines as efficient chiral catalysts for the enantioselective addition of dialkylzincs to both aromatic and aliphatic aldehydes (1989) (30)
- Highly stereoselective asymmetric synthesis of (R)-(−)-mevalolactone (1981) (30)
- Determination of absolute configurations of amino acids by asymmetric autocatalysis of 2-alkynylpyrimidyl alkanol as a chiral sensor (2007) (30)
- Enantioselective addition of diethylzinc to aldehydes using chiral polymer catalysts possessing a methylene spacer (1994) (30)
- Enantioselective Synthesis Induced by Compounds with Chirality Arising from Partially Deuterated Methyl Groups in Conjunction with Asymmetric Autocatalysis (2011) (30)
- Highly enantioselective synthesis of β-hydroxy nitriles by the cyanomethylation of aldehydes using DPMPM as a chiral catalysts or ligand (1992) (30)
- Enantioselective synthesis utilizing enantiomorphous organic crystal of achiral benzils as a source of chirality in asymmetric autocatalysis. (2008) (30)
- Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis. (2017) (28)
- Asymmetric autocatalysis of pyrimidyl alkanol and related compounds. Self-replication, amplification of chirality and implication for the origin of biological enantioenriched chirality (2018) (28)
- Highly enantioselective asymmetric autocatalysis of pyrimidin-5-yl alkanol induced by chiral 1,3-disubstituted hydrocarbon allenes (2002) (28)
- Asymmetric autocatalysis of a ferrocene-containing chiral compound with amplification of chirality (2006) (28)
- Asymmetric autocatalysis of 5-carbamoyl-3-pyridyl alkanols with amplification of enantiomeric excess (2000) (28)
- Design of Chiral Catalysis and Asymmetric Autocatalysis for the Enantioselective Additions of Organozinc Reagents (1997) (28)
- Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine (2012) (27)
- Catalytic asymmetric synthesis of γ-hydroxy ketones and aromatic hydroxy ketones by the chemo- and enantio-selective alkylation of keto aldehydes with dialkylzincs (1994) (27)
- Enantioselective C–C Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single-Crystal Face upon Treatment with a Dialkyl Zinc Vapor** (2011) (27)
- Enantioselective synthesis induced by chiral organic–inorganic hybrid silsesquioxane in conjunction with asymmetric autocatalysis (2004) (26)
- Chiral dialkyl thiophosphoramidates as highly enantioselective catalysts for the alkylation of aldehydes (1993) (25)
- Asymmetric synthesis of chiral diols by the catalytic enantioselective dialkylation of tere-, iso-, and phthalaldehydes and by a catalytic enantioselective autoinductive reaction (1996) (25)
- ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF DIALKYLMAGNESIUM TO ALDEHYDES BY USING THE LITHIUM SALT OF (2S, 2′S)-2-HYDROXYMETHYL-1-[(1-METHYLPYRPOLIDIN-2-YL)METHYL]PYRROLIDINE AS A CHIRAL LIGAND (1978) (25)
- Solvent-free catalytic enantioselective addition of diethylzinc to aldehydes (2000) (24)
- Inter- and Intramolecular Carbonylative Alkyne–Alkyne Coupling Reaction Mediated by Cobalt Carbonyl Complex (2000) (24)
- Reduction of Azides to Amines with Sodium Borohydride in Tetrahydrofuran with Dropwise Addition of Methanol (1987) (24)
- Highly enantioselective addition of dialkylzincs to aldehydes using dendritic chiral catalysts with flexible carbosilane backbones (2002) (24)
- Highly enantioselective addition of diethylzinc to N-diphenylphosphinylimines using dendritic chiral ligands with hydrocarbon backbones (2000) (24)
- Enantioselective synthesis induced by chiral crystal composed of DL-serine in conjunction with asymmetric autocatalysis. (2011) (24)
- Enantioselective phenylation of prochiral aldehydes using a kinetically formed chiral complex between Grignard–zinc halide reagent and N,N-dibutylnorephedrine (1991) (24)
- Amplification of Chirality (2008) (23)
- Self-replication and amplification of enantiomeric excess of chiral multifunctionalized large molecules by asymmetric autocatalysis. (2014) (23)
- N-alkyl-N-vinylbenzylnorephedrines and their copolymers as chiral ligands for the highly enantioselective ethylation of N-diphenylphosphinylimine (1996) (23)
- Highly enantioselective asymmetric autocatalysis induced by chiral cobalt complexes due to the topology of the coordination of achiral ligands (2001) (23)
- Enantioselective reformatsky reaction with ketones. Asymmetric synthesis of β-(tert-hydroxy)esters (1993) (23)
- Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules (2019) (22)
- Asymmetric synthesis of optically active threo- and erythro-pyrrolidinylbenzyl alcohol by the highly stereospecific arylation of (S)-proline and the subsequent highly diastereoselective reduction of the α-amino ketone (1987) (22)
- Enantioselective Addition of Diethylzinc to Aldehydes Catalized by Chiral Diamino-diols Derived from Ephedrine (1987) (22)
- Chemoselective Reduction of Diaryl Bisulfides to Thiols with Sodium Borohydride in Mixed Solvent Containing Methaxol (1986) (22)
- Asymmetric Synthesis of N-(Diphenylphosphinyl)amines Promoted by Chiral Carbosilane Dendritic Ligands in The Enantioselective Addition of Dialkylzinc Compounds to N-(Diphenylphosphinyl)imines (2002) (22)
- ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF ALKYLLITHIUM TO ALDEHYDES BY USING (2S, 2′S)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)METHYL] PYRROLIDINE AS CHIRAL LIGAND (1978) (22)
- Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate (2015) (21)
- Enantiodivergent formation of a chiral cytosine crystal by removal of crystal water from an achiral monohydrate crystal under reduced pressure (2013) (21)
- Highly enantioselective asymmetric autocatalysis of 2-alkenyl- and 2-vinyl-5-pyrimidyl alkanols with significant amplification of enantiomeric excess. (2002) (21)
- Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis (2015) (21)
- Remarkable effect of alkylbenzenes as solvents in enantioselective alkylation of N-diphenylphosphinonylimines with diethylzinc using polystyrene supported ephedrine (1994) (20)
- Asymmetric autocatalysis initiated by finite single-wall carbon nanotube molecules with helical chirality. (2014) (20)
- Enantioselective Synthesis Induced by the Helical Molecular Arrangement in the Chiral Crystal of Achiral Tris(2-hydroxyethyl) 1,3,5-Benzenetricarboxylate in Conjunction with Asymmetric Autocatalysis (2013) (20)
- Asymmetric Autocatalysis Induced by Octahedral Tris(acetylacetonato)chromium(III) Complex as a Homogeneous Chiral Initiator (2007) (20)
- Asymmetric reduction of prochiral 3-aryl-3-oxoesters with lithium borohydride using N,N′-dibenzoylcystine as a chiral auxiliary (1985) (20)
- Enantioselective furylation of prochiral aldehydes by difurylzinc in the presence of a chiral amino alcohol: asymmetric synthesis of 2-furylmethanols (1990) (20)
- Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds (2019) (20)
- Asymmetric Self-Replication of Chiral 1,2-Amino Alcohols by Highly Enantioselective Autoinductive Reduction†‡ (1997) (20)
- A catalytic and enantioselective cyclopropylation of aldehydes using dicyclopropylzinc (1998) (20)
- Asymmetric synthesis of N-(diphenylphosphinyl)-ferrocenylamine by the enantioselective alkylation of ferrocenylimine (1996) (20)
- Volatile CVD precursor for Ni film: cyclopentadienylallylnickel (2005) (20)
- Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc (1999) (19)
- NEW SYNTHETIC REACTIONS BASED ON 1-METHYL-2-FLUOROPYRIDINIUM SALTS. STEREOSPECIFIC PREPARATION OF PRIMARY AMINES FROM ALCOHOLS (1977) (19)
- Chiral secondary alcohol-induced asymmetric autocatalysis: correlation between the absolute configuration of the chiral initiators and the product (2007) (19)
- Chemo- and Regioselective Reduction of Epoxides with Sodium Borohydride in Mixed Solvent Containing Methanol (1987) (19)
- Catalytic asymmetric synthesis of 2- and 3-furylcarbinols (1989) (18)
- Approaches Toward the Origin of Homochirality Using the Synthetic Organic Chemistry ^|^mdash;Asymmetric Autocatalysis with Amplification of Enantiomeric Excess^|^mdash; (2013) (18)
- Asymmetric Autocatalysis of Pyrimidyl Alkanol (2012) (18)
- Chiral quaternary ammonium salts as solid state catalysts for the enantioselective addition of diethylzinc to aldehydes (1990) (17)
- Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines (2001) (17)
- Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator. (2009) (16)
- The asymmetric power of chiral ligands determined by competitive asymmetric autocatalysis. (2004) (16)
- Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation. (2012) (16)
- Enantioselective synthesis induced by chiral epoxides in conjunction with asymmetric autocatalysis (2004) (16)
- Asymmetric synthesis of 2-aryl substituted oxetanes by enantioselective reduction of β-halogenoketones using lithium borohydride modified with N,N′-dibenzoylcystine (1986) (16)
- ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE FLUORINE-CONTAINING ALCOHOLS BY THE CATALYTIC ENANTIOSELECTIVE ALKYLATION OF ALDEHYDES (1997) (15)
- Catalytic asymmetric synthesis of hydroxyketones by chemo- and enantio-selective alkylation of ketoaldehydes (1989) (15)
- Chapter 11 – Asymmetric Autocatalysis and Biomolecular Chirality (1999) (15)
- A General Method for the Formation of Zinc Enolate Equivalents from Iodoacetates by Diisopropylzinc-Iodine Exchange Reaction: Preparation of β-Hydroxy Esters (2000) (15)
- Nonlinear relationship between the enantioselectivities for asymmetric reactions of monofunctional and bifunctional substrates. Synthesis of practically optically pure diols by the catalytic enantioselective diethylation of terephthalaldehyde (1992) (14)
- Reversal of the sense of enantioselectivity between 1- and 2-aza[6]helicenes used as chiral inducers of asymmetric autocatalysis. (2017) (14)
- Asymmetric autocatalysis of pyrimidyl alkanol induced by optically active 1,1′-binaphthyl, an atropisomeric hydrocarbon, generated from spontaneous resolution on crystallization (2002) (14)
- Enantioselective Automultiplication of Chiral Molecules by Asymmetric Autocatalysis (2000) (14)
- Asymmetric synthesis with a chiral catalyst generated from asymmetric autocatalysis. (2001) (14)
- Asymmetric autocatalysis induced by chiral hydrocarbon [2.2]paracyclophanes. (2003) (13)
- Enantioselective addition of dialkylzincs to N-diphenylphosphinylimines using polymer-supported N,N-dialkylnorephedrines as chiral ligands (1997) (13)
- Enantioselective alkylation of n‐diphenylphosphinylimine with dialkylzincs using copolymerized chiral ligands (1999) (13)
- Asymmetric conjugate addition of organometallic reagents in the presence of tertiary amines to chiral α,β-unsaturated amido carboxylic acids. Addition order of reagents as an unprecedented factor in the determination of the sense of asymmetric induction (1986) (12)
- A Chemoselective One-Step Reduction of β-Ketoesters to 1,3-Diols (1984) (12)
- Highly enantioselective synthesis of optically active hydroxyaldehydes using a chiral catalyst (1990) (12)
- Asymmetric synthesis using chiral piperazine. I: Asymmetric synthesis of 2-substituted alcohol and carboxylic acid by diastereoselective alkylation of chiral diamides derived from piperazines (1987) (12)
- Elucidation of the Structures of Asymmetric Autocatalyst Based on X-ray Crystallography (2016) (12)
- Asymmetric Autocatalysis. Automultiplication of Chiral Molecules (2011) (12)
- Highly Enantioselective Addition of Dialkylzincs to Aromatic Aldehydes Using 1-Phenyl-2-(1-pyrrolidinyl)-1-propanol as a Chiral Catalyst (1999) (12)
- Unusual reversal of enantioselectivity in the asymmetric autocatalysis of pyrimidyl alkanol triggered by chiral aromatic alkanols and amines. (2017) (12)
- Chiral catalyst controlled addition of dialkylzincs to chiral α-siloxyaldehydes; asymmetric synthesis of either diastereoisomer of mono-protected vicinal diols (1994) (12)
- A reversal phenomenon of enantioface selectivity by the cooperative operation of two chiral catalysts. (2011) (12)
- Direct synthesis of cyclopentadienones by cobalt carbonyl-mediated carbonylative alkyne-alkyne coupling reaction (1998) (12)
- Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol. (1996) (11)
- Asymmetric Synthesis of the Both Enantiomers of Tertiary Aryl Homoallyl Alcohols and Diols by Diastereoselective Addition of Allyltrimethylsilane to Chiral α-Keto Imides (1987) (11)
- Asymmetric Autocatalysis Initiated by Chiral Ephedrine Immobilized on Silica Gel in a Diisopropylzinc Addition to Pyrimidine-5-carbaldehyde (2004) (11)
- HfO2 and Hf1-xSixO2 thin films grown by metal-organic CVD using tetrakis(diethylamido)hafnium (2006) (11)
- Highly Enantioselective Asymmetric Synthesis by the Design of Asymmetric Catalysts and Reaction Media (2004) (11)
- A Facile One-pot Synthesis of N-Substituted Phthalimides Using a Catalytic Amount of Crown Ether (1982) (11)
- Asymmetric Amplification and Autocatalysis (2010) (10)
- Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid-vapor phase conditions. (2019) (10)
- ASYMMETRIC REDUCTION OF ALKYL ARYL KETONES WITH LITHIUM BOROHYDRIDE USING N-BENZOYLCYSTEINE AS CHIRAL LIGAND (1984) (10)
- Application of asymmetric autocatalysis to the determination of absolute configurations of amino acids with low enantiomeric excesses. (2001) (10)
- Asymmetric conjugate addition of Grignard reagents in the presence of tertiary amines to α,β-unsaturated amides derived from (S)-2-(1-hydroxy-1-methylethyl)pyrrolidine or (S)-prolinol (1985) (10)
- Synthesis of Hydroxy Ketones by Chemoselective Alkylation of Keto Aldehydes with Dialkylzincs Catalyzed by Amino Alcohol, Diamine, or Dilithium Salt of Piperazine (1989) (10)
- Asymmetric synthesis of optically active fluorine-containing alcohols using chiral catalysts (1992) (9)
- Asymmetric Autocatalysis of Pyrimidyl Alkanol and Its Application to the Study on the Origin of Homochirality (2015) (9)
- Asymmetric conjugate addition to unsaturated chiral amido alcohols using Grignard reagents co-ordinated with tertiary amines or DBU. Preparation of optically active 3-substituted carboxylic acids and (S)-(–)-citronellol (1987) (9)
- Catalytic asymmetric synthesis of optically active alkynyl alcohols. (1989) (9)
- The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines (2003) (9)
- Stereoselective synthesis of optically active syn- and anti-1,3-diols by the catalytic alkylation of a β-alkoxy aldehyde (1992) (9)
- Reversal in enantioselectivity induced by achiral alcohols in asymmetric autocatalysis in the presence of a chiral diol as a chiral initiator (2012) (8)
- Stereoselectivity in the reduction of cyclic ketones with sodium borohydride. Effect of the ratio of the components of a mixed solvent of tetrahydrofuran and methanol. (1985) (8)
- Chemoselective Reductions with Sodium Borohydride and Lithium Borohydride in Mixed Solvents (1987) (8)
- Highly stereospecific arylation of (S)proline and complementary highly diastereoselective reduction of the α-amino ketone. Asymmetric synthesis of (1S,2′S)- and (1R,2′S)-phenyl(2′-pyrrolidinyl)methanol (1986) (8)
- Enantioselective Synthesis of Substituted 3-Quinolyl Alkanols and Their Application to Asymmetric Autocatalysis. (2004) (8)
- Effect of Tertiary Amines on Diastereo-Selectivity of the Asymmetric Conjugate Addition of n-Butyllithium to α,β-Unsaturated Amide Derived from (S)-Proline (1983) (8)
- Chapter 29 – Asymmetric Autocatalysis, Absolute Asymmetric Synthesis and Origin of Homochirality of Biomolecules (2004) (8)
- Novel functional group selectivity in reductions with lithium borohydride in mixed solvents containing methanol (1983) (8)
- Asymmetric automultiplication of chiral compounds by asymmetric autocatalysis (2002) (8)
- Catalytic asymmetric synthesis of optically active secondary alcohols deuterated on the secondary carbon by the enantioselective alkylation of aldehydes (1992) (8)
- Alkylation of Carbonyl Groups (2000) (7)
- Asymmetric Synthesis of Chiral Tertiary Alcohols in High Enantiomeric Excess (1982) (7)
- Highly enantioselective addition of diethylzinc to aldehydes catalyzed by chiral s-amino-t-alcohols (1991) (7)
- Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal (2016) (7)
- Asymmetric synthesis of 3-quinolylalkylamine by enantioselective alkylation of w-diphenyl-phosphinyl-3-quinolylimine using chiral β-amino alcohols (1998) (7)
- Synthesis of (2S,5S)-2,5-Bis(phenylmethyl)piperazine by the Reduction with Sodium Borohydride Using Titanium Tetrachloride. (1986) (7)
- Absolute Structure Determination of Chiral Crystals Consisting of Achiral Benzophenone with Single-crystal X-ray Diffraction and Its Correlation with Solid-state Circular Dichroism (2016) (7)
- Can the analyte-triggered asymmetric autocatalytic Soai reaction serve as a universal analytical tool for measuring enantiopurity and assigning absolute configuration? (2016) (7)
- Asymmetric synthesis of pyridylethanols and amino alcohols by enantioselective reduction with lithium borohydride modified with N,N'-dibenzoylcystine (1987) (7)
- Synthesis of (2S,5S)-2,5-bis(phenylmethyl)-1,4-diazabicyclo[2.2.2]octane (1992) (7)
- ASYMMETRIC AUTOCATALYSIS AND HOMOCHIRALITY OF BIOMOLECULES (2002) (6)
- Synthesis of Chiral α-Acetoxy-N-acetylamides from Chiral Pyrimidylalkanols by the Oxidative Cleavage of Pyrimidine Ring (2000) (6)
- Asymmetric Synthesis using N, N-Dialkylnorephedrines and Pyrrolidinylmethanol Derivatives as Chiral Catalysts and Ligands (1995) (6)
- 1-Phenyl-2-(1-pyrrolidinyl)-1-propanol as a Chiral Catalyst for the Highly Enantioselective Addition of Dialkylzincs to Five-membered Heterocyclic Aldehydes (1999) (6)
- Asymmetric synthesis of optically active alcohols with two chiral centres from a racemic aldehyde by the selective addition of dialkylzinc reagents using chiral catalysts (1991) (6)
- Asymmetric Induction by Helical Hydrocarbons: (2001) (6)
- Achiral amino acid glycine acts as an origin of homochirality in asymmetric autocatalysis. (2019) (5)
- Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker. (2017) (5)
- Convenient method for the chemoselective and regioselective reduction of oxiranes with sodium borohydride in single solvent (1988) (5)
- Enantioselective Addition of Dialkylzincs to Aldehydes Using Heterogeneous Chiral Catalysts Immobilized on Alumina and Silica Gel. (1991) (5)
- Asymmetric Autocatalytic Reaction of 3-Quinolylalkanol with Amplification of Enantiomeric Excess. (1996) (5)
- Mixed Solvents Containing Methanol as Useful Reaction Media for Unique Chemoselective Reductions with Lithium Borohydride. (1987) (5)
- N,N′-dibenzoylcystine as an efficient chiral auxiliary for asymmetric reduction of ketones with lithium borohydride (1984) (5)
- Asymmetric Autocatalysis and the Origin of Homochirality (2006) (5)
- Stereospecific transformation of a chiral pyrimidyl alkanol into L-valine (1998) (5)
- Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon–carbon bond cleavage (2001) (5)
- Diastereoselective asymmetric allylation of chiral α-keto-amides with allyltrimethylsilane. Preparation of protected homoallylic alcohols (1984) (4)
- Diastereoselective reduction of chiral α-ketoamides derived from (S)-proline esters with sodium borohydride. Preparation of optically active α-hydroxy acids (1985) (4)
- Asymmetric Autocatalysis and the Origin of Homochirality of Biomolecules (2005) (4)
- Asymmetric autocatalysis - Discovery and development (2001) (4)
- Synthesis of 1,3-thiazolidine-2-thione and (4R)-methoxycarbonyl-1,3-thiazolidine-2-thione using N,N'-thiocarbonyldiimidazole (1984) (4)
- Enantioselective Synthesis of Substituted 3-Quinolyl Alkanols and Their Application to Asymmetric Autocatalysis (2004) (4)
- Asymmetric synthesis of optically active halohydrins and oxiranes by enantioselective reduction of prochiral α-haloketones with chirally modified lithium borohydride (1985) (4)
- Asymmetric Synthesis of the Both Enantiomers of α-Hydroxy Acids by the Diastereoselective Reduction of Chiral α-Keto Amides with (Complex) Metal Hydrides in the Presence of Metallic Salt (1986) (4)
- A NOVEL PROCEDURE FOR THE REDUCTION OF EPOXIDES WITH SODIUM BOROHYDRIDE (1982) (4)
- Asymmetric Autocatalysis and the Origins of Homochirality of Organic Compounds. An Overview (2017) (4)
- Asymmetric synthesis of alcohols with two chiral centres from a racemic aldehyde by the selective addition of dialkylzinc reagents using (1S,2R)-(−)-N,N-dibutylnorephedrine and (S)-(+)-diphenyl-(1-methylpyrrolidin-2-yl)methanol as chiral catalysts (1990) (4)
- Unusual effect of a mixed solvent on the asymmetric reduction of chiral α-keto-amides with sodium borohydride (1982) (4)
- Surface reactions in Ni MOCVD using cyclopentadienylallylnickel as a precursor (2005) (3)
- Highly Diastereoselective 1,2-Asymmetric Addition of Dialkylzincs to Chiral 2-Phenylpropanal Catalyzed by Amino Alcohol (1990) (3)
- Asymmetric Autocatalysis and Its Application to Chiral Discrimination (2003) (3)
- Asymmetric Autocatalysis as a Link Between Crystal Chirality and Highly Enantioenriched Organic Compounds (2021) (3)
- Catalytic Asymmetric Synthesis of Chiral 4-Pyrazolylalkanols by the Enantioselective Alkylation of Pyrazole-4-carbaldehydes with Dialkylzincs (2000) (3)
- Highly Enantioselective Synthesis of Organic Compound Using Right‐ and Left‐Handed Helical Silica. (2003) (3)
- Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field. (2021) (3)
- Rational Design of Chiral Catalysis for the Enantioselective Addition Reaction of Dialkylzincs (2000) (3)
- Catalytic enantioselective alkylation of aldehydes using chiral hydrogen phosphoramidates and hydrogen phosphinamides and their thio analogs (2010) (3)
- Design and Synthesis of the Chiral Ligands for the Highly Enantioselective Asymmetric Reactions of Carbonyl Compounds (1989) (3)
- Catalytic Asymmetric Synthesis of Optically Active Alkynyl Alcohols by Enantioselective Alkynylation of Aldehydes and by Enantioselective Alkylation of Alkynyl Aldehydes. (1990) (2)
- Synthesis of Pyrimidine-Terminated Chiral Large Molecular Architectures with Functions of Self-Replication and Self-Improvement by Asymmetric Autocatalysis (2017) (2)
- Catalytic Asymmetric Synthesis and Asymmetric Autocatalysis of Chiral 5,5'-(3,3'-Bipyridyl)dialkanediol (2000) (2)
- Asymmetric synthesis of various chiral 5-pyrimidyl-alkanols by the enantios elective alkylation of pyrimidine-5-carbaldehydes with dialkylzincs in the presence of chiral amino alcohols (1997) (2)
- Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol. (2021) (2)
- Synthesis of Chiral α-Acetoxy-N-acetylamides from Chiral Pyrimidylalkanols by the Oxidative Cleavage of Pyrimidine Ring. (2000) (2)
- Enantioselective Addition of Organozinc Compounds (2009) (2)
- Asymmetric Synthesis of Chiral Secondary Alcohols with Isopropyl Substituents by the Catalytic Enantioselective Addition of Diisopropylzinc to Aldehydes Using N,N-Dialkylnorephedrines as Chiral Catalysts. (1995) (2)
- Highly Enantioselective Addition of Dialkylzincs to Aldehydes Using Dendritic Chiral Catalysts with Flexible Carbosilane Backbones. (2002) (2)
- Asymmetric Autocatalysis with Amplification of Chirality and Origin of Chiral Homogeneity of Biomolecules (2006) (2)
- Enantioselective Addition of Dialkylzincs to Pyridinecarbaldehyde in the Presence of Chiral Amino Alcohols: Asymmetric Synthesis of Pyridylalkyl Alcohols. (1990) (2)
- Catalytic Enantioselective Conjugate Addition of Dialkylzincs to α,β‐Unsaturated Ketones Using Nickel Bromide ‐ N,N‐Dibutylnorephedrine. (1989) (2)
- Inter- and Intramolecular Carbonylative Alkyne—Alkyne Coupling Reaction Mediated by Cobalt Carbonyl Complex. (2001) (2)
- 1-Phenyl-2-(1-pyrrolidinyl)-1-propanol as a Chiral Catalyst for the Highly Enantioselective Addition of Dialkylzincs to Five-Membered Heterocyclic Aldehydes. (2000) (2)
- (S)‐Diphenyl(1‐methylpyrrolidin‐2‐yl)methanol (2008) (1)
- The Soai reaction and its implications with the life's characteristic features of self-replication and homochirality (2022) (1)
- Structural Study of Asymmetric Autocatalysis by X-Ray Crystallography (2017) (1)
- Chiral Piperazine as a New Chiral Catalyst for the Enantioselective Addition of Dialkylzincs to Aryl Aldehydes. (1988) (1)
- Highly Enantioselective Addition of Diethylzinc to N-Diphenylphosphinylimines Using Dendritic Chiral Ligands with Hydrocarbon Backbones. (2000) (1)
- Direct Synthesis of Cyclopentadienones by Cobalt Carbonyl-Mediated Carbonylative Alkyne—Alkyne Coupling Reaction. (1998) (1)
- Enantioselective Synthesis Induced by Compounds with Chirality Arising from Partially Deuterated Methyl Groups in Conjunction with Asymmetric Autocatalysis. (2011) (1)
- Chiral Dialkyl Thiophosphoramidates as Highly Enantioselective Catalysts for the Alkylation of Aldehydes. (1993) (1)
- Asymmetric Autocatalysis Initiated by Chiral Ephedrine Immobilized on Silica Gel in a Diisopropylzinc Addition to Pyrimidine‐5‐carbaldehyde. (2004) (1)
- Asymmetric Synthesis of Optically Active threo- and erythro-Pyrrolidinylbenzyl Alcohol by the Highly Stereospecific Arylation of (S)-Proline and the Subsequent Highly Diastereoselective Reduction of the α-Amino Ketone. (1987) (1)
- THE MICHAEL REACTION OF SILYL ENOL ETHERS WITH α,β-UNSATURATED KETONES AND ACETALS IN THE PRESENCE OF TITANIUM TETRAALKOXIDE AND TITANIUM TETRACHLORIDE (1976) (1)
- Chiral Amino Alcohols Bound to Diimines, Diamines, and Dendrimers as Chiral Ligands for the Enantioselective Ethylation of N-Diphenylphosphinylimines. (1998) (1)
- NOVEL FUNCTIONAL-GROUP SELECTIVITY IN REDUCTIONS WITH LITHIUM BOROHYDRIDE IN MIXED SOLVENTS CONTAINING METHANOL (1983) (1)
- Catalytic Asymmetric Synthesis of a Chiral Diol, Bis(2-(1-hydroxyalkyl) phenyl)ether, an Asymmetric Autocatalytic Reaction. (1994) (1)
- Asymmetric Autocatalysis of 5‐Carbamoyl‐3‐pyridyl Alkanols with Amplification of Enantiomeric Excess. (2001) (1)
- Asymmetric Autocatalysis Initiated by Crystal Chirality of Achiral Compounds (2017) (1)
- Asymmetric Synthesis of N-Diphenylphosphinoylamines by Solvent-Free Enantioselective Addition of Dialkylzincs to N-Diphenylphosphinoylimines. (2010) (0)
- Asymmetric Synthesis of the Both Enantiomers of Tertiary Aryl Homoallyl Alcohols and Diols by Diastereoselective Addition of Allyltrimethylsilane to Chiral α-Keto Imides. (1987) (0)
- Asymmetric Autocatalysis and the Elucidation of the Origin of Homochirality (2023) (0)
- Asymmetric Synthesis of 3-Quinolylalkylamine by Enantioselective Alkylation of N-Diphenylphosphinyl-3-quinolylimine Using Chiral β-Amino Alcohols. (1998) (0)
- Complementary Catalytic Asymmetric Induction in the Enantioselective Addition of Diethylzinc to Aldehydes. (1987) (0)
- Synthesis of (2S,5S)-2,5-Bis(phenylmethyl)-1,4-diazabicyclo(2.2.2) octane. (1992) (0)
- Catalytic Asymmetric Synthesis of Optically Active Secondary Alcohols Deuterated on the Secondary Carbon by the Enantioselective Alkylation of Aldehydes. (1992) (0)
- A CHEMOSELECTIVE ONE-STEP REDUCTION OF β-KETO ESTERS TO 1,3-DIOLS (1984) (0)
- Highly Stereospecific Arylation of (S)-Proline and Complementary Highly Diastereoselective Reduction of the α-Amino Ketone. (1986) (0)
- Asymmetric Conjugate Addition to Unsaturated Chiral Amido Alcohols Using Grignard Reagents Coordinated with Tertiary Amines or DBU. Preparation of Optically Active 3-Substituted Carboxylic Acids and (S)-(-)-Citronellol. (1987) (0)
- Chemoselective Reduction of Diaryl Disulfides to Thiols with Sodium Borohydride in Mixed Solvent Containing Methanol. (1986) (0)
- Chiral Catalyst Controlled Addition of Dialkylzincs to Chiral α- Siloxyaldehydes; Asymmetric Synthesis of Either Diastereoisomer of Mono-Protected Vicinal Diols. (1994) (0)
- Asymmetric Reduction of Prochiral 3-Aryl-3-oxoesters with Lithium Borohydride Using N,N′-Dibenzoylcystine as a Chiral Auxiliary. (1985) (0)
- Asymmetric Synthesis of Optically Active Alcohols with Two Chiral Centres from a Racemic Aldehyde by the Selective Addition of Dialkylzinc Reagents Using Chiral Catalysts. (2010) (0)
- Asymmetric Alkenylation of Chiral and Prochiral Aldehydes Catalyzed by Chiral or Achiral Amino Alcohols: Catalytic Diastereoselective Synthesis of Protected erythro-Sphingosine and Enantioselective Synthesis of Chiral Diallyl Alcohols. (1994) (0)
- Alkylation of C=O (2004) (0)
- Asymmetric Autocatalysis Induced by Octahedral Tris(acetylacetonato)chromium(III) Complex as a Homogeneous Chiral Initiator. (2007) (0)
- Asymmetric Autocatalysis Initiated by Finite Single‐Wall Carbon Nanotube Molecules with Helical Chirality. (2014) (0)
- Reduction of Symmetric and Mixed Anhydrides of Carboxylic Acids by Sodium Borohydride with Dropwise Addition of Methanol. (1987) (0)
- Remarkable Effect of Alkylbenzenes as Solvents in Enantioselective Alkylation of N-Diphenylphosphinoylimines with Diethylzinc Using Polystyrene Supported Ephedrine. (1994) (0)
- (1R,2S)‐Ephedrine (2005) (0)
- THE NATURE AND DISTRIBUTION OF THE ORGANIC COMPOUNDS IN CARBONACEOUS CHONDRITES : NEW PERSPECTIVES ON THEIR POSSIBLE PREBIOTIC SIGNIFICANCE(Chemical Evolution, International Symposium on Origins of Life and Astrobiology) (2005) (0)
- Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Chiral Diamino Diols Derived from Ephedrine. (1988) (0)
- Asymmetric Synthesis of Various Chiral 5‐Pyrimidyl Alkanols by the Enantioselective Alkylation of Pyrimidine‐5‐carbaldehydes with Dialkylzincs in the Presence of Chiral Amino Alcohols. (1998) (0)
- HIGHLY STEREOSELECTIVE ASYMMETRIC SYNTHESIS OF (R)-(-)-MEVALOLACTONE (1981) (0)
- Asymmetric Synthesis of the Both Enantiomers of α-Hydroxy Acids by the Diastereoselective Reduction of Chiral α-Keto Amides with (Complex) Metal Hydrides in the Presence of Metallic Salt. (1987) (0)
- (2S,4S)‐2‐(Anilinomethyl)‐1‐ethyl‐4‐hydroxypyrrolidine (2001) (0)
- (S)‐4‐Anilino‐3‐methylamino‐1‐butanol (2001) (0)
- Highly Diastereoselective 1,2-Asymmetric Addition of Dialkylzincs to Chiral 2-Phenylpropanal Catalyzed by Amino Alcohol. (1990) (0)
- An Enantioselective Baylis—Hillman Reaction Catalyzed by Chiral Phosphines under Atmospheric Pressure. (2010) (0)
- Asymmetrie Synthesis of 2-Aryl Substituted Oxetanes by Enantioselective Reduction of β-Halogenoketones Using Lithium Borohydride Modified with N,N′-Dibenzoylcystine. (1986) (0)
- Asymmetric Self‐Replication of Chiral 1,2‐Amino Alcohols by Highly Enantioselective Autoinductive Reduction. (1998) (0)
- A Catalytic and Enantioselective Cyclopropylation of Aldehydes Using Dicyclopropylzinc. (1998) (0)
- Catalytic Enantioselective Alkylation of Aldehydes Using Chiral Hydrogen Phosphoramidates and Hydrogen Phosphinamides and Their Thio Analogues. (1995) (0)
- Catalytic Asymmetric Synthesis of Chiral 4‐Pyrazolylalkanols by the Enantioselective Alkylation of Pyrazole‐4‐carbaldehydes with Dialkylzincs. (2000) (0)
- N-Alkyl-N-vinylbenzylnorephedrines and Their Copolymers as Chiral Ligands for the Highly Enantioselective Ethylation of N- Diphenylphosphinylimine. (2010) (0)
- DIRECT IRRADIATION OF CIRCULARLY POLARIZED LIGHT AND ASYMMETRIC AUTOCATALYSIS AS A POSSIBLE ORIGIN OF HOMOCHIRALITY(Chiral Homogeneity and D-Amino Acids, International Symposium on Origins of Life and Astrobiology) (2005) (0)
- Catalytic Asymmetric Synthesis of Alkyl‐Substituted Lactones by Enantioselective and Chemoselective Alkylation of Formyl Esters with Dialkylzincs Using N,N‐Dibutylnorephedrine. (1988) (0)
- Solvent-Free Catalytic Enantioselective Addition of Diethylzinc to Aldehydes. (2001) (0)
- circularly polarized light (2020) (0)
- Titelbild: Asymmetric Induction by a Nitrogen 14 N/15 N Isotopomer in Conjunction with Asymmetric Autocatalysis (Angew. Chem. 49/2016) (2016) (0)
- Asymmetric Synthesis of N‐(Diphenylphosphinyl)amines Promoted by Chiral Carbosilane Dendritic Ligands in the Enantioselective Addition of Dialkylzinc Compounds to N‐(Diphenylphosphinyl)imines. (2003) (0)
- STEREOSELECTIVITY IN THE REDUCTION OF CYCLIC KETONES WITH SODIUM BOROHYDRIDE. EFFECT OF THE RATIO OF THE COMPONENTS OF A MIXED SOLVENT OF TETRAHYDROFURAN AND METHANOL (1985) (0)
- Responses and Responsibilities of Giants (2016) (0)
- Cover Picture: Asymmetric Induction by a Nitrogen 14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis (Angew. Chem. Int. Ed. 49/2016) (2016) (0)
- New Polymer Bound Chiral Catalyst with Methylene Spacer for the Enantioselective Addition of Diethylzinc to Aldehydes. (2010) (0)
- EFFECT OF TERTIARY AMINES ON DIASTEREOSELECTIVITY OF THE ASYMMETRIC CONJUGATE ADDITION OF N-BUTYLLITHIUM TO α,β-UNSATURATED AMIDE DERIVED FROM (S)-PROLINE (1983) (0)
- Enantioselective Synthesis of Chiral 5-Carbamoyl-3-pyridyl Alcohols by Asymmetric Autocatalytic Reaction. (1997) (0)
- Catalytic Asymmetric Synthesis of Hydroxy Ketones by Chemo‐ and Enantioselective Alkylation of Keto Aldehydes. (1989) (0)
- UNUSUAL EFFECT OF A MIXED SOLVENT ON THE ASYMMETRIC REDUCTION OF CHIRAL α-KETO AMIDES WITH SODIUM BOROHYDRIDE (1983) (0)
- Trajectory of the Discovery of Asymmetric Autocatalysis and the Study on the Origin of Homochirality (2019) (0)
- A General Method for the Formation of Zinc Enolate Equivalents from Iodoacetates by Diisopropylzinc—Iodine Exchange Reaction: Preparation of β‐Hydroxy Esters. (2001) (0)
- SODIUM BOROHYDRIDE-TERT-BUTYL ALCOHOL-METHANOL AS AN EFFICIENT SYSTEM FOR THE SELECTIVE REDUCTION OF ESTERS (1982) (0)
- ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) ADDITION OF ALKYLLITHIUM AND DIALKYLMAGNESIUM TO ALDEHYDES BY USING (2S,2′S)-2-HYDROXYMETHYL-1-((1-ALKYLPYRROLIDIN-2-YL)METHYL)PYRROLIDINES AS CHIRAL LIGANDS (1979) (0)
- DIASTEREOSELECTIVE ASYMMETRIC ALLYLATION OF CHIRAL α-KETO AMIDES WITH ALLYLTRIMETHYLSILANE. PREPARATION OF PROTECTED HOMOALLYLIC ALCOHOLS (1984) (0)
- Highly Enantioselective Synthesis of Optically Active Hydroxyaldehydes Using a Chiral Catalyst. (1991) (0)
- The Origin and Amplification of Chirality Leading to Biological Homochirality (2018) (0)
- Symmetry Breaking in Asymmetric Autocatalysis of Pyrimidyl Alkanol (2008) (0)
- Synthesis of Hydroxy Ketones by Chemoselective Alkylation of Keto Aldehydes with Dialkylzincs Catalyzed by Amino Alcohol, Diamine, or Dilithium Salt of Piperazine. (1989) (0)
- Asymmetric Synthesis of Optically Active Fluorine‐Containing Alcohols by Catalytic Enantioselective Alkylation of Aldehydes. (1997) (0)
- Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate. (2015) (0)
- Polymer-Bound N-Alkylnorephedrines as Efficient Chiral Catalysts for the Enantioselective Addition of Dialkylzincs to Both Aromatic and Aliphatic Aldehydes. (1989) (0)
- Highly Enantioselective Synthesis of a Chiral 3-Quinolylalkanol by an Asymmetric Autocatalytic Reaction. (1996) (0)
- Asymmetric Synthesis of Pyridylethanols and Amino Alcohols by Enantioselective Reduction with Lithium Borohydride Modified with N,N′-Dibenzoylcystine. (1987) (0)
- Asymmetric Conjugate Addition of Organometallic Reagents in the Presence of Tertiary Amines to Chiral α,β-Unsaturated Amido Carboxylic Acids. (1986) (0)
- Asymmetric Synthesis of Optically-Active β-Substituted Ketones (III) by Highly Enantioselective Catalytic Conjugate Addition of Dialkylzinc Reagents (II) to Enones (I) Using a Catalyst System of Nickel(II)-Chiral Ligand-Achiral Ligand (1989) (0)
- Asymmetric Synthesis of Alcohols with Two Chiral Centres from a Racemic Aldehyde by the Selective Addition of Dialkylzinc Reagents Using (1S,2R)-(-)-N,N-Dibutylnorephedrine and (S)-(+)-Diphenyl-(1-methylpyrrolidin-2-yl)methanol as Chi (1990) (0)
- Asymmetric Self‐Catalytic Reaction. Self‐Production of Chiral 1‐(3‐ Pyridyl)alkanols (‐)‐(III) as Chiral Self‐Catalysts in the Enantioselective Addition of Dialkylzinc Reagents (II) to Pyridine‐3‐ carbaldehyde (I). (1991) (0)
- Enantioselective Addition of Dialkylzincs to N‐Diphenylphosphinylimines Using Polymer‐Supported N,N‐Dialkylnorephedrines as Chiral Ligands. (2010) (0)
- Stereoselective Synthesis of Optically Active syn- and anti-1,3-Diols by the Catalytic Alkylation of a β-Alkoxy Aldehyde. (1992) (0)
- Contribution From Asymmetric Catalyst to Asymmetric Autocatalyst (1999) (0)
- Enantioselective Furylation of Prochiral Aldehydes by Difurylzinc in the Presence of a Chiral Amino Alcohol: Asymmetric Synthesis of 2‐ Furylmethanols. (1991) (0)
- (2S,2′S)‐2‐Hydroxymethyl‐1‐[(1‐methylpyrrolidin‐2‐yl)methyl]pyrrolidine (2001) (0)
- Asymmetric Synthesis Using Chiral Piperazine. Part 1. Asymmetric Synthesis of 2-Substituted Alcohol and Carboxylic Acid by Diastereoselective Alkylation of Chiral Diamides Derived from Piperazines. (1988) (0)
- Unusual Chemoselective Addition of Diisopropylzinc to 2,2′-Bipyridine-5,5′-dicarbonyl Compounds in the 2-Position and Autoxidative Reconversion with Carbon—Carbon Bond Cleavage. (2001) (0)
- Chiral N,N‐Dialkylnorephedrines as Catalysts of the Highly Enantioselective Addition of Dialkylzincs to Aliphatic and Aromatic Aldehydes. The Asymmetric Synthesis of Secondary Aliphatic and Aromatic Alcohols of High Optical Purity. (1991) (0)
- The Origins of Homochirality Examined by Using Asymmetric Autocatalysis (2014) (0)
- Asymmetric Synthesis of Functionalized Tertiary Homoallyl Alcohols by Diastereoselective Allylation of Chiral α-Keto Amides Derived from (S)-Proline Esters. Control of Stereochemistry Based on Saturated Coordination of Lewis Acid. (1987) (0)
- Catalytic Asymmetric Induction in Enantioselective Conjugate Addition of Dialkylzincs to Enones. (1989) (0)
- Convenient Method for the Chemoselective and Regioselective Reduction of Oxiranes with Sodium Borohydride in Single Solvent. (1988) (0)
- Catalytic Asymmetric Synthesis of 2- and 3-Furylcarbinols. (1990) (0)
- Asymmetric Synthesis Using Chiral Piperazines. Part 3. Enantioselective Addition of Dialkylzincs to Aryl Aldehydes Catalyzed by Chiral Piperazines. (1992) (0)
- Enantioselective Reformatsky Reaction with Ketones. Asymmetric Synthesis of β‐(tert‐Hydroxy) Esters. (1993) (0)
- Erratum: Enantioselective addition of dialkylzincs to N-diphenylphosphinylimines using polymer-supported N,N-dialkylnorephedrines as chiral ligands (Journal of Chemical Society Perkin Transactions 1 (1997) (2757)) (2002) (0)
- Generation of Chirality by Crystallization of Achiral Organic Compounds and Asymmetric Autocatalysis Induced by Chiral Organic Crystals (2011) (0)
- Synthesis of Chiral Dendrimers with a Hydrocarbon Backbone and Application to the Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes. (2000) (0)
- Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds (2022) (0)
- Enantioselective Conjugate Addition of Diethylzinc to Enones Using Chiral β-Amino Alcohol as Chiral Catalyst or Ligand. (1991) (0)
- Asymmetric Synthesis of Chiral Diols by the Catalytic Enantioselective Dialkylation of Tere, Iso‐, and Phthalaldehydes and by a Catalytic Enantioselective Autoinductive Reaction. (1997) (0)
- Chiral Quaternary Ammonium Salts as Solid State Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes. (1990) (0)
- (1R,2S)‐N‐Methylephedrine (2001) (0)
- Asymmetric Synthesis of N‐(Diphenylphosphinyl)ferrocenylamine by the Enantioselective Alkylation of Ferrocenylimine. (1997) (0)
- Catalytic Enantioselective Synthesis of Optically Active Phthalides. (1991) (0)
- PB155 ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE LACTONES BY CATALYTIC ENANTIOSELECTIVE ALKYLATION OF FORMYLESTERS (1988) (0)
- Reduction of Azides (I) to Amines (II) with Sodium Borohydride in Tetrahydrofuran with Dropwise Addition of Methanol. (1987) (0)
- From Asymmetric Catalyst to Asymmetric Autocatalyst (2004) (0)
- (S)‐2‐(Anilinomethyl)pyrrolidine (2014) (0)
- ENANTIOFACE-DIFFERENTIATING REACTIONS USING (2S,2′S)-2-(HYDROXYMETHYL)-1-((1-ALKYL-2-PYRROLIDINYL)METHYL)PYRROLIDINES AS CHIRAL LIGANDS. ADDITION OF LITHIUM DERIVATIVES OF METHYL PHENYL SULFIDE, ACETONITRILE, N-NITROSODIMETHYLAMINE, A (1980) (0)
- Polymer Supported N- Alkylnorephedrines as Highly Enantioselective Chiral Catalysts for The Addition of Dialkylzincs to Aldehydes (1995) (0)
- Highly Enantioselective Alkylation of Carbon-Nitrogen Double Bonds. Catalytic and Stoichiometric Asymmetric Synthesis of Optically Active Amines by the Enantioselective Addition of Dialkylzinc Reagents to N- Diphenylphosphinoylimines. (1992) (0)
- Polymer-Bound Ephedrine as an Efficient Chiral Catalyst for the Enantioselective Addition of Dialkylzincs to Aldehydes. (1988) (0)
- Asymmetric Synthesis of Optically Active Fluorine‐Containing Alcohols Using Chiral Catalysts. (1993) (0)
- Asymmetric Additions Using Diorganozincs (1999) (0)
- Catalytic Asymmetric Induction. Highly Enantioselective Addition of Dialkylzincs to Aldehydes Using Chiral Pyrrolidinylmethanols and Their Metal Salts. (1988) (0)
- Asymmetric Autocatalysis of Pyrimidyl Alkanol Induced by Optically Active 1,1′‐Binaphthyl, an Atropisomeric Hydrocarbon, Generated from Spontaneous Resolution on Crystallization. (2002) (0)
- Highly Enantioselective Synthesis of β-Hydroxy Nitriles by the Cyanomethylation of Aldehydes Using DPMPM as a Chiral Catalyst or Ligand. (2010) (0)
- REACTION OF 3-ACYLTHIAZOLIDINE-2-THIONE WITH THIOLS; PREPARATION OF THIOL ESTERS (1983) (0)
- Enantioselective Addition of Diethylzinc to Aldehydes Using Chiral Polymer Catalysts Possessing a Methylene Spacer. (1994) (0)
- Carbon Isotope Chirality Initiated Asymmetric Autocatalysis (2009) (0)
- A New Chiral Catalyst for the Highly Enantioselective Addition of Dialkylzinc Reagents to Aliphatic Aldehydes. (1988) (0)
- A Reversal Phenomenon of Enantioface Selectivity by the Cooperative Operation of Two Chiral Catalyst. (2011) (0)
- Highly Enantioselective Addition of Dialkylzincs to Aromatic Aldehydes Using 1-Phenyl-2-(1-pyrrolidinyl)-1-propanol as a Chiral Catalyst. (2000) (0)
- Catalytic Asymmetric Synthesis of γ‐Hydroxy Ketones and Aromatic Hydroxy Ketones by the Chemo‐ and Enantioselective Alkylation of Keto Aldehydes with Dialkylzincs. (1995) (0)
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