Lauri Vaska
Estonian chemist
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Chemistry
Lauri Vaska's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of Tartu
Why Is Lauri Vaska Influential?
(Suggest an Edit or Addition)According to Wikipedia, Lauri Vaska was an Estonian-American chemist who has made noteworthy contributions to organometallic chemistry. Vaska was born in Rakvere, Estonia. He was educated at the Baltic University in Hamburg, Germany and subsequently at the University of Göttingen , where he received his Vordiplom . He emigrated to the United States in 1952 and pursued his Ph.D. in inorganic chemistry at the University of Texas . He was a postdoctoral fellow at Northwestern University where he conducted research on magnetochemistry. In 1957 he took a position as Fellow at the Mellon Institute in Pittsburgh, where he remained until 1964. During that time, the Mellon Institute housed a number of future chemists, including Paul Lauterbur and R. Bruce King. Vaska moved as an associate professor to Clarkson University in Potsdam, New York, where, from 1990 to his death, he was professor emeritus of chemistry. His brother is a philosopher. He died in Basking Ridge, New Jersey in 2015, aged 90.
Lauri Vaska's Published Works
Published Works
- Dioxygen-metal complexes: toward a unified view (1976) (359)
- Reversible activation of covalent molecules by transition-metal complexes. The role of the covalent molecule (1968) (279)
- CARBONYL AND HYDRIDO-CARBONYL COMPLEXES OF IRIDIUM BY REACTION WITH ALCOHOLS. HYDRIDO COMPLEXES BY REACTION WITH ACID (1961) (217)
- Activation of Hydrogen by a Transition Metal Complex at Normal Conditions Leading to a Stable Molecular Dihydride (1962) (165)
- Oxygen-Carrying Properties of a Simple Synthetic System (1963) (162)
- Homogeneous Catalytic Hydrogenation of Ethylene and Acetylene with Four-Coordinated Iridium and Rhodium Complexes. Reversible Catalyst-Substrate Adducts1 (1965) (78)
- Infrared spectra and structures of hydridocarbonyl complexes of transition metals. (1966) (75)
- A New Series of Four-, Five-, and Six-Coordinated Iridium Complexes (1966) (71)
- Hydridocarbonyl Complexes of Osmium by Reaction with Alcohols (1964) (67)
- Reversible Addition of Sulfur Dioxide to Four-Coordinated Metal Complexes1 (1966) (62)
- Complex Carbonyl Hydrides of Osmium and Ruthenium (1961) (61)
- Electronic spectral studies of planar rhodium(I) and iridium(I) complexes containing .pi.-acceptor ligands (1976) (60)
- HYDRIDO COMPLEXES OF IRIDIUM (1961) (46)
- Oxygenation and related addition reactions of isostructural d8 complexes of cobalt, rhodium, and iridium. Quantitative assessment of the role of the metal (1971) (44)
- Molecular Perchlorato Complexes of Iridium(I), Rhodium(I), and Cobalt(I) (1971) (43)
- On the Origin of Hydrogen in Metal Hydride Complexes Formed by Reaction With Alcohols (1962) (43)
- Steric effects inhibiting reactivity. Crystal and molecular structure, spectra, and chemistry of trans-chlorocarbonylbis(tri-o-tolylphosphine)iridium(I), and related complexes (1975) (43)
- Stereospecific Addition of Hydrogen Halides to Tetragonal d8 Complexes (1966) (40)
- A simple synthetic route to d8 complexes of rhodium and iridium. An electronegativity scale for anionic ligands (1971) (39)
- Homogeneous catalytic production of hydrogen and other molecules from water—DMF solutions (1990) (38)
- Molecular oxygen binding in a monomeric cobalt complex. Crystal and molecular structure of dioxygen-bis[cis-1,2-bis(diphenylphosphino)ethylene]cobalt tetrafluoroborate (1972) (34)
- Oxygen-Carrying Iridium Complexes: Kinetics, Mechanism, and Thermodynamics (1971) (32)
- Carbon dioxide fixation leading to stable molecular bicarbonato complexes of d8 metals (1973) (31)
- Carbon Dioxide Reduction via Homogeneous Catalytic Synthesis and Hydrogenation of N,N-Dimethylformamide. (1988) (30)
- Activation of covalent molecules by some noble metal complexes: The role of the metal (1971) (30)
- Reversible Combination of Carbon Monoxide with a Synthetic Oxygen Carrier Complex (1966) (29)
- Homogeneous catalysis by five- and six-coordinated metal hydride complexes (1,2) (1965) (29)
- Reversible Homogeneous Catalysis of Carbon Dioxide Hydrogenation/Reduction at Room Temperature and Low Pressures Mediated by Platinum(O)-Diphosphine Cluster Complex in Solution. (1987) (28)
- Catalytic hydrogenolysis of molecular oxygen by transition metal complexes in nonaqueous solution (1971) (24)
- Reversible oxygenation of metal complexes: electronic and steric factors (1971) (23)
- Lewis acid adducts of planar four-coordinated d8 complexes. Boron trifluoride-chlorocarbonylbis(triphenylphosphine) iridium and related systems (1968) (23)
- Catalytic Reduction of Carbon Dioxide to Methane and Other Species via Formamide Intermediation: Synthesis and Hydrogenation of HC(O)NH2 in the Presence of (Ir(Cl)CO)(Ph3P)2) (1989) (20)
- Reversible coordination of carbon monoxide to bivalent iron. Dissociative mechanism for monosubstitution in spin-paired (d6) octahedral ferrous complexes (1971) (19)
- The Mechanism of Chemisorption: Hydrogen on Nickel at Elevated Pressures (1958) (17)
- Reversible addition of carbon dioxide to rhodium and iridium complexes (1974) (17)
- Five-Coordinate Hydrido-Carbonyl Complexes of Rhodium and Iridium and their Analogy with CoH(CO)4 (2002) (17)
- ACTIVATION OF MOLECULAR HYDROGEN BY METAL COMPLEXES: MECHANISM AND SOME CONTROLLING FACTORS * † (1971) (17)
- para-Hydrogen conversion and hydrogen-deuterium equilibration catalyzed by diamagnetic iridium, platinum, and ruthenium complexes in nonaqueous solution (1) (1982) (15)
- Cyanotrihydroborato- and tetrahydroborato-complexes of rhodium and iridium (1971) (13)
- Oxygenation of meso-tetrakis(2,4,6-alkoxyphenyl)porphinato complexes of Iron(II): Some unusual observations (1975) (9)
- Catalytic reduction of nitric oxide and molecular oxygen by carbon monoxide in the presence of a platinum(0)diphosphine complex in solution at ambient conditions (1978) (8)
- Luminescence of d8 complexes of iridium and rhodium, and its quenching by molecular oxygen and other gases (1974) (8)
- Reversible addition of nitric oxide to a solid ferric porphinato complex. Thermodynamics of formation and characterization of a peculiar nitric oxide adduct (1973) (6)
- The synthesis of bromopentammineosmium(III) halides (1958) (6)
- Homogeneous catalytic activation of O–H and N–H bonds in organic molecules by ruthenium, osmium, rhodium, and iridium complexes (1972) (6)
- Catalytic activation of carbon dioxide by metal complexes (1988) (6)
- Interaction of Alkali Metals and Liquid Ammonia (1954) (5)
- Decisive solvent effects in homogeneous catalysis: Oxidation of carbon monoxide to carbon dioxide in the presence of a rhodium cluster in dimethylformamide solution at ambient conditions (1978) (5)
- The interaction of ammonium and potassium hexabromoösmate(IV) and liquid ammonia at 25°—I. The ammonia-insoluble product (1958) (5)
- Notizen: Univalent Osmium: Osmium Complexes with Triphenylphosphine and Triphenylarsine (1960) (5)
- The interaction of ammonium and potassium hexabromoösmate(IV) and liquid ammonia at −34 and 90° (1958) (4)
- REVERSIBLE ADDITION OF NITRIC OXIDE TO A SOLID FERRIC PORPHINATO COMPLEX, THERMODYNAMICS OF FORMATION AND CHARACTERIZATION OF A PECULIAR NO ADDUCT (1973) (3)
- Fluoro Complexes of Rhodium(I) and Iridium(I) (2007) (2)
- Homogeneous Catalytic Production of Hydrogen and Other Molecules from Water-DMF (N-Dimethylformamide) Solutions (1988) (2)
- Oxygenation of metal complexes: On mechanistic details of initial interaction (1978) (2)
- The Role of Phosphorus Ligands in the Reversible Activation of Small Molecules By Metal Complexes (1990) (1)
- Homogeneous Activation of Molecular Hydrogen by Four-, Five-, and Six-Coordinate Transition Metal Complexes (1964) (1)
- Hydrido–deuterio-complexes of iridium (1966) (1)
- Physical Properties of Octahedral Iron (II) Complexes of Vicinal-Dioximes (1980) (0)
- Covalent Perchlorato Complexes of Iridium and Rhodium (2007) (0)
- OXYGENATION OF METAL COMPLEXES- ON MECHANISTIC DETAILS OF INITIAL INTERACTION (1979) (0)
- Trans‐carbonyl(cyanotrihydridoborato)bis‐(triphenylphosphine)rhodium(I) (2007) (0)
- CO2 FIXATION LEADING TO STABLE MOLECULAR BICARBONATO COMPLEXES OF D(8) METALS (1973) (0)
- Kinetics of Reversible CO Binding to Octahedral Ferrous Furil-${\alpha}$-dioximato Complex (1981) (0)
- Tetracarbonylbis‐μ‐(2‐Methyl‐2‐Propane‐Thiolato)‐Dhridium(I) (2007) (0)
- CATALYTIC REDUCTION OF NITRIC OXIDE AND MOLECULAR OXYGEN BY CARBON MONOXIDE IN THE PRESENCE OF A PLATINUM(0)-DIPHOSPHINE COMPLEX IN SOLUTION AT AMBIENT CONDITIONS (1979) (0)
- Magnetic Property of ${\mu}$-Peroxo-bis[bis(diphenylglyoximato)iron(III)] (1980) (0)
- A STERICALLY OBSTRUCTED PORPHINE DERIVATIVE, UNUSUAL CHEMICAL BEHAVIOR OF MESO-TETRAKIS(2,4,6-TRIMETHOXYPHENYL)PORPHINATO IRON COMPLEXES (1974) (0)
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