Luis Oro
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Professor of Chemistry at the University of Zaragoza
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Chemistry
Luis Oro's Degrees
- PhD Chemistry University of Zaragoza
Why Is Luis Oro Influential?
(Suggest an Edit or Addition)According to Wikipedia, Luis Antonio Oro Giral has been professor of chemistry at the University of Zaragoza since 1982. His main research interests are in organometallic chemistry and homogeneous catalysis with a special interest in reaction mechanisms. He has coauthored well over 500 scientific papers being co-author or co-editor of several books. He has received numerous national and international awards and honors, and is member of several international scientific academies. He has been President of the European Association for Chemical and Molecular Sciences and President of the Spanish Royal Society of Chemistry . He has also served in high-level positions in the Spanish public administration with responsibilities for science.
Luis Oro's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Metal clusters in chemistry (1999) (485)
- Transition metal liquid crystals: advanced materials within the reach of the coordination chemist (1992) (371)
- Dihydrogen Complexes as Homogeneous Reduction Catalysts. (1998) (147)
- Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts. (2012) (142)
- Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts (2008) (141)
- Iridium Complexes with N-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation (2005) (138)
- Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I) (2007) (129)
- The emergence of transition-metal-mediated hydrothiolation of unsaturated carbon-carbon bonds: a mechanistic outlook. (2013) (129)
- Homogeneous catalytic reduction of CO2 with hydrosilanes (2014) (125)
- Effective fixation of CO2 by iridium-catalyzed hydrosilylation. (2012) (121)
- Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts (2011) (117)
- Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands (1992) (108)
- Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(Pr3)2 (Pr3 = P-i-Pr3, PMe-t-Bu2) (1991) (103)
- Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR3)2 [PR3 = PMe-tert-Bu2 and P-i-Pr3] (1989) (91)
- Indenyl complexes of ruthenium(II). Crystal structure of [Ru(CO)(PPh3)2(η5-C9H7)]ClO4·CH2Cl2 (1985) (89)
- Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands. (2015) (81)
- Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity. (2005) (77)
- (PYRAZOLATO)GOLD COMPLEXES SHOWING ROOM-TEMPERATURE COLUMNAR MESOPHASES. SYNTHESIS, PROPERTIES, AND STRUCTURAL CHARACTERIZATION (1998) (72)
- Homogeneous Catalytic Reduction of CO2 with Silicon‐Hydrides, State of the Art (2018) (71)
- Pyrazolate bridged dinuclear rhodium complexes. X-ray structure of [Rh(Pz)(CO)P(OPh) 3 ] 2 (1981) (69)
- Recent advances in homogeneous enantioselective Diels–Alder reactions catalyzed by chiral transition-metal complexes (2000) (69)
- Enhanced Hydrogen-Transfer Catalytic Activity of Iridium N-Heterocyclic Carbenes by Covalent Attachment on Carbon Nanotubes (2013) (68)
- An alternative mechanistic paradigm for the β-Z hydrosilylation of terminal alkynes: the role of acetone as a silane shuttle. (2013) (66)
- A deceptively simple case of selective hydrogenation of phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complex (1992) (65)
- Trimerisation of the Cationic Fragments [(η-ring)M(Aa)]+ ((η-ring) M=(η5-C5Me5)Rh, (η5-C5Me5)Ir, (η6-p-MeC6H4iPr)Ru; Aa=α-amino acidate) with Chiral Self-Recognition: Synthesis, Characterisation, Solution Studies and Catalytic Reactions of the Trimers [{(η-ring)M(Aa)}3](BF4)3 (1999) (65)
- Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η6-p-cymene)Ru(amino acidato)Cl] and [(η6-p-cymene)Ru(amino acidato)]3(BF4)3 complexes (2000) (64)
- The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein. (2004) (64)
- Iridium complexes in organic synthesis (2008) (64)
- Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts. (2011) (63)
- Pyrazolate “Golden” Rings: Trinuclear Complexes That Form Columnar Mesophases at Room Temperature (1996) (60)
- Versatility of Cyclooctadiene Ligands in Iridium Chemistry and Catalysis (2003) (58)
- Homogeneous Catalysis by Osmium Complexes. A Review (1995) (57)
- Exclusive formation of cis-PhCH:CH(SiEt3) by addition of triethylsilane to phenylacetylene catalyzed by ruthenium complex [(Me2CH)3P]2RuHCl(CO) (1993) (57)
- Reactivity of OsH4(CO)(PiPr3)2 toward terminal alkynes: synthesis and reactions of the alkynyl-dihydrogen complexes OsH(C2R)(.eta.2-H2)(CO)(PiPr3)2 (R = Ph, SiMe3) (1993) (55)
- Direct access to parent amido complexes of rhodium and iridium through N-H activation of ammonia. (2011) (53)
- Rhodium(I) complexes with bis(pyrazolyl)methane ligands. Crystal structure of [Rh(COD)(CH2(Pz)2)]ClO4· C2H4Cl2 (1984) (52)
- Coordination of H2 and O2 to [OsHCl(CO)(PiPr3)2]: A Catalytically Active M(η2‐H2) Complex (1988) (52)
- A leap forward in iridium-NHC catalysis: new horizons and mechanistic insights. (2018) (52)
- Five-Coordinate Complex [RuHCl(CO)(PPri3)2] as a Precursor for the Preparation of New Cyclopentadienylruthenium Compounds Containing Unsaturated η1-Carbon Ligands† (1996) (52)
- Outer‐Sphere Ionic Hydrosilylation Catalysis (2014) (51)
- CO2 Activation and Catalysis Driven by Iridium Complexes (2013) (51)
- Chiral ruthenium complexes as catalysts in enantioselective Diels–Alder reactions. Crystal structure of the Lewis acid–dienophile adduct (1997) (50)
- Cationic rhodium(I) organic complexes with nitrogen donors and their carbonylation products (1976) (50)
- MHCl(CO)(PiPr3)2 (M = Ru, Os) complexes as catalyst precursors for the reduction of unsaturated substrates (1988) (49)
- A hexanuclear iridium chain. (2003) (49)
- Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes (1993) (48)
- Reactions of diamidonaphthalene-bridged diiridium tetrahydrides with alkynes : Hydrogenation, vinylidene formation, and catalytic C-C coupling (2005) (48)
- Cationic Rhodium Complexes with Hemilabile Phosphine Ligands as Polymerization Catalyst for High Molecular Weight Stereoregular Poly(phenylacetylene) (2009) (48)
- Half‐Sandwich Complexes with Aminocarboxylate Ligands and Their Use as Enantioselective Hydrogen Transfer Catalysts (2002) (47)
- Hydroxo–Rhodium–N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation (2013) (47)
- Reactions of the Dihydrogen Complex OsCl2(.eta.2-H2)(CO)(PiPr3)2 with Terminal Alkynes: Synthesis of Carbene, Vinylcarbene, and .mu.-Bis-carbene Osmium (II) Derivatives (1995) (46)
- Tris(pyrazol-1-yl)methane-rhodium(I) and -iridium(I) complexes; cyrstal structure of [Rh(COD)(tpzm)][RhCl2(COD)]·3CHCl3 (1988) (46)
- Synthesis, molecular structure, and reactivity of octahedral alkylhydridoosmium(II) complexes [OsH(R)(CO)2(PR'3)2] (1992) (46)
- Hydrosilylation of phenylacetylene via an Os(SiEt3)(.eta.2-H2) intermediate catalyzed by OsHCl(CO)(PPr-iso3)2 (1991) (45)
- On the Sense of the Enantioselection in Hydrogen Transfer Reactions from 2-Propanol to Ketones (2002) (44)
- A synthon for a 14-electron Ir(III) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes. (2012) (43)
- From Platinum Blues to Rhodium and Iridium Blues (1999) (43)
- Catalytic transfer hydrogenation by cationic rhodium(I) complexes (1981) (43)
- Rhodium(I)-N-heterocyclic carbene catalyst for selective coupling of N-vinylpyrazoles with alkynes via C-H activation (2014) (43)
- Optically active pseudoctahedral rhodium(III), iridium(III), and ruthenium(II) complexes with α-amino acidato ligands. Crystal structures of RIrSCSN- and SIrSCSN-[(C5Me5)Ir(pro)Cl] · H2O (Hpro = l-proline) (1990) (43)
- Synthesis, Characterization, Properties, and Asymmetric Catalytic Diels−Alder Reactions of Chiral-at-Metal Imino−Iridium(III) Complexes (1998) (42)
- Bis-alkynyl- and hydrido-alkynyl-osmium(II) and ruthenium(II) complexes containing triisopropylphosphine as ligand (1989) (42)
- Mechanistic investigations of imine hydrogenation catalyzed by dinuclear iridium complexes. (2006) (42)
- IMINO-RHODIUM(III) AND -RUTHENIUM(II) COMPOUNDS WITH STEREOGENIC METAL CENTERS (1999) (41)
- Tetranuclear Complexes as Intermediates in Transannular Oxidative‐Addition Reactions. Structure of the First Tetrairidium Linear Cluster (1988) (40)
- Efficient catalysts for telomerization of butadiene with amines (2007) (40)
- Rhodium wires based on binuclear acetate-bridged complexes (2001) (39)
- Solvent‐Free Iridium‐Catalyzed Reactivity of CO2 with Secondary Amines and Hydrosilanes (2015) (39)
- Cooperative Bimetallic Effects on New Iridium(III) Pyrazolate Complexes: Hydrogen−Hydrogen, Carbon−Hydrogen, and Carbon−Chlorine Bond Activations (1998) (38)
- Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups (2015) (38)
- Hydrogenation of benzylideneacetone catalyzed by OsHCl(CO)(PR{sub 3}){sub 2} (PR{sub 3} = P-i-Pr{sub 3}, PMe-t-Bu{sub 2}): New roles of dihydrogen complexes in homogeneous catalytic hydrogenation (1992) (37)
- Hydrosilylation of terminal alkynes catalyzed by a ONO-pincer iridium(III) hydride compound: Mechanistic insights into the hydrosilylation and dehydrogenative silylation catalysis (2016) (37)
- Indirect cooperative effects leading to synergism in bimetallic homogeneous catalysts containing azolates as bridging ligands (1991) (37)
- Pyridine-enhanced head-to-tail dimerization of terminal alkynes by a rhodium-N-heterocyclic-carbene catalyst. (2013) (37)
- Synthesis and Reactivity of the Unusual Five-Coordinate Hydrido−Hydroxo Complex OsH(OH)(CO)(PiPr3)2 (1997) (36)
- Synthesis, X-ray structure, and nuclear magnetic resonance (1H and 13C) studies of ruthenium(II) complexes containing pyrazolyl ligands (1990) (35)
- Half-Sandwich Complexes of Osmium(II) with l-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity (2012) (35)
- Prototropism in (Pentamethylcyclopentadienyl)iridium Complexes with Pyrazole Ligands (1986) (35)
- Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation (2012) (35)
- Rhodium complexes of the binucleating ligands pyridine-2-thiolate and benzothiazole-2-thiolate. Crystal structures of [{Rh(µ-SC5H4N)(CO)2}2] and [{Rh(µ-SC5H4N)(tfbb)}2]·Me2CO (tfbb = tetrafluorobenzobarrelene) (1989) (35)
- Synthesis and properties of rhodium(I) chloranilate and 2,5-dihydroxy-1,4-benzoquinonate complexes. Crystal structures of the binuclear [Rh2(.mu.-CA)(cod)2] and tetranuclear [Rh4(.mu.-CA)2(cod)4] complexes (CA = chloranilate anion) (1993) (34)
- The chemical and catalytic reactions of hydrido-chloro-carbonylbis (triisopropylphosphine)osmium(II) and its major derivatives (2001) (34)
- Alkene hydrogenation on an 11-vertex rhodathiaborane with full cluster participation. (2008) (34)
- The reactions of [Ru3(CO)12] with nitrogen-containing heterocycles. Crystal structures of [Ru3(µ-H)(µ3-ppy)(CO)9] and [Ru3(µ-napy)(µ-CO)3(CO)7] (1988) (34)
- Alcohol activation by [Ir(COD)(tris(pyrazol-1-yl)methane)]+ and [Ir(COD) (tris(pyrazol-1-yl)ethanel+ cations: formation of alkoxycarbonyl derivatives [(tpzm)IrH(CO2R′)(CO)]+ and [(tpze)IrH(CO2R′)]+ (R′ = Me, Et, i-Pr) (1989) (33)
- The reduction of α,β-unsaturated ketones and cyclohexadienes catalyzed by mhcl(CO)(PiPr3)2 (M = Ru, Os) complexes (1989) (33)
- Mechanistic Insights into Transfer Hydrogenation Catalysis by [Ir(cod)(NHC)2]+ Complexes with Functionalized N-Heterocyclic Carbene Ligands (2015) (33)
- Pyrazolate thiocarbonylrhodium complexes. X-ray structure of [Rh(μ-3,5-Me2Pz)(CS)(PPh3)]2 (1982) (33)
- Übergangsmetallvermittelte Hydrothiolierung ungesättigter Kohlenstoff-Kohlenstoff-Bindungen: ein mechanistischer Ausblick† (2013) (33)
- Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketones (1991) (32)
- Competitive Reaction Pathways in the Addition of Phenylacetylene to Diamidonaphthalene-Bridged Diiridium Complexes† (1999) (32)
- Chiral rhodium complexes as catalysts in Diels–Alder reactions (1996) (32)
- Dehalogenation of Polychloroarenes with HSiEt3 Catalyzed by an Homogeneous Rhodium−Triphenylphosphine System (1999) (31)
- Rhodium and Iridium Pyrazolato Blues. (1998) (31)
- CARBON-CARBON COUPLING AND CARBON-HYDROGEN ACTIVATION REACTIONS IN BIS(TRIISOPROPYLPHOSPHINE)OSMIUM COMPLEXES (1996) (31)
- Preparation and catalytic activity of cationic rhodium tetrafluorobenzobarrelene complexes with nitrogen and phosphorus donor ligands (1980) (31)
- Solvent-free iridium-catalyzed CO2 hydrosilylation: experiments and kinetic modeling (2015) (31)
- Chiral Half‐Sandwich Ruthenium(II) Complexes as Catalysts in 1,3‐Dipolar Cycloaddition Reactions of Nitrones with Methacrolein (2006) (31)
- Oxidative Addition of Group 14 Element Hydrido Compounds to OsH(2)(eta(2)-CH(2)=CHEt)(CO)(P(i)Pr(3))(2): Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV). (1996) (31)
- Synthesis and x-ray structural characterization of heterobimetallic rhodium-platinum and rhodium-palladium benzothiazole-2-thiolate compounds. The first binuclear complexes having two short-bite anionic bridging ligands in a trans disposition (1992) (31)
- Reactions of OsHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of (Vinylcarbene)osmium(II) Complexes (1994) (30)
- Reversible ethylene dihydrogen mediated 11-vertex nido --> closo --> nido conversion in a metallathiaborane cluster. (2008) (30)
- Mechanism of the hydrogenation of phenylacetylene catalyzed by [Ir(COD)(.eta.2iso-Pr2PCH2CH2OMe)]BF4 (1993) (30)
- Reactions of the Square-Planar Compounds Ir(C2Ph)L2(PCy3) (L2 = 2 CO, TFB) with HSiR3 (R = Et, Ph) and Hx+1SiPh3-x (x = 1, 2): Stoichiometric and Catalytic Formation of Si−C Bonds (1996) (30)
- Non-classical hydrosilane mediated reductions promoted by transition metal complexes (2019) (30)
- Reactions of Osmium Hydride Complexes with Terminal Alkynes: Synthesis and Catalytic Activity of OsH(.eta.2-O2CCH3)(C:CHPh)(PiPr3)2 (1994) (30)
- Liquid Crystal Derivatives of Transition Metals (I): Tetracoordinated Copper (II) Complexes Derived From Schiffs Bases (1989) (30)
- Synthesis, Characterization, Properties, and Asymmetric Catalytic Diels−Alder Reactions of Chiral-at-Metal Phosphinooxazoline-Rhodium(III) and −Iridium(III) Complexes§ (2002) (30)
- Quantum Mechanical Exchange Coupling in Trihydridoosmium Complexes Containing Azole Ligands (1996) (30)
- Hydride Exchange Processes in the Coordination Sphere of Transition Metal Complexes: The OsH3(BH4)(PR3)2 System (1996) (30)
- Liquid-crystal behavior in ionic complexes of silver(I): Molecular structure-mesogenic activity relationship (1990) (30)
- Cyclopentadienylruthenium complexes with chelating diamines and diolefins. Crystal structures of [Ru(nbd)(PPh3)(ϑ-C5H5)]ClO4 and [Ru{(η6-C6H5)Ph2PO}(η-C5H5)]ClO4. A new mode of coordination of triphenylphosphine oxide (1983) (30)
- Synthesis and hydroformylation reaction of dinuclear rhodium(I) complexes with mixed bridging ligands. X-Ray structure of [Rh2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2] (1988) (29)
- Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand. (2016) (29)
- Discrete iridium pyridonate chains with variable metal valence: nature and energetics of the Ir-Ir bonding from DFT calculations. (2005) (29)
- Iridium and rhodium complexes with tetrafluorobenzobarrelene diolefins (1999) (29)
- Synthesis and reactions of dihydrido(triethylsilyl)(1,5-cyclooctadiene)-iridium(III) complexes: catalysts for dehydrogenative silylation of alkenes (1986) (29)
- Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes (2015) (29)
- Reactions of RuHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of Ruthenium(II) Hydroxyvinyl and Vinylcarbene Complexes (1994) (29)
- Asymmetric 1,3-Dipolar Cycloaddition Reaction between α,β-Unsaturated Aldehydes and Nitrones Catalyzed by Well-Defined Iridium or Rhodium Catalysts (2007) (29)
- Reactivity of MH([eta][sup 2]-H[sub 2]BH[sub 2])(CO)(PiPr[sub 3])[sub 2] (M = Os, Ru) toward electrophiles: Synthesis of new hydridocarbonylosmium(II) and -ruthenium(II) complexes containing triisopropylphosphine as ligand (1992) (29)
- Preferential α‐Hydrosilylation of Terminal Alkynes by Bis‐N‐Heterocyclic Carbene Rhodium(III) Catalysts (2015) (28)
- Hydroformylation of 1-hexene under mild conditions catalyzed by various μ-pyrazolato dirhodium(I) complexes (1985) (28)
- Synthesis, reactivity, and catalytic activity of triangular ZrM2 (M = Rh, Ir) early-late heterobimetallic complexes (2003) (28)
- Arene-iridium(i) complexes. Crystal structures of [Ir(TFB)(arene)]BF4 (TFB = tetrafluorobenzobarrelene; arene = 1,4-Me2C6H4 or C6Me6) (1983) (28)
- Preparation, reactions and catalytic activity of complexes of the type [Ir(COD){P(p-RC6H4)3}2]A (R Cl, F, H, CH3 OR CH3O; A ClO4− OR B(C6H5)4−) (1980) (28)
- Catalytic activity of some fluorothiolate derivatives of rhodium(I). Crystal structure of [Rh(μ-SC6H4F)(CO)2]2 (1990) (28)
- Reactions of Ir(acac)(cyclooctene)(PCy3) with H2, HC⋮CR, HSiR3, and HSnPh3: The Acetylacetonato Ligand as a Stabilizer for Iridium(I), Iridium(III), and Iridium(V) Derivatives (1996) (28)
- Tuning PCP-Ir complexes: the impact of an N-heterocyclic olefin. (2015) (28)
- Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues The generous financial support from DGES and MCyT-PNI (Projects PB98-641 and BQU2000-1170) is gratefully acknowledged. (2001) (28)
- Formation of Diiridium(II) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex (1987) (27)
- Terminal and bridging parent amido 1,5-cyclooctadiene complexes of rhodium and iridium. (2013) (27)
- The dehydrogenation of alcohols through a concerted bimetallic mechanism involving an amido-bridged diiridium complex. (2012) (27)
- Crescent-shaped rhodium(I) complexes with bis(o-carboxymethylphenyl)triazenide. (2004) (27)
- Synthesis and catalytic activity of some cationic complexes of rhodium(I) with norbornadiene and group Vb ligands (1979) (27)
- Preparation, properties, and reactivity of dihydridosilyl(.eta.4-cycloocta-1,5-diene)iridium(III) complexes. X-ray crystal structures of the dihydrido silyl complex IrH2(SiEt3)(.eta.4-C8H12)(AsPh3) and the cyclooctenyl derivative Ir(1-.sigma.,4,5-.eta.2-C8H13)(CO)2(AsPh3) (1987) (27)
- Dynamic Behavior in Solution of the Trans‐Hydridodihydrogen Complex [OsHCl(n2‐H2)(CO)(PiPr3)2]: Ab Initio and NMR Studies (1996) (27)
- (Pentamethylcyclopentadienyl)bis(pyrazolato)(pyrazole)iridium(III) as a metal-complex ligand. Synthesis, characterization, and reactivity of heterodinuclear IrM [M = copper(I), silver(I), gold(I), rhodium(I)] and heterotrinuclear IrAg2 and IrRhAg derivatives (1991) (27)
- Cationic rhodium tetrafluorobenzobarrelene complexes with diolefin or arene ligands, crystal structures of [Rh(TFB)(arene)] ClO4, (arene = C6Me6, C6H3Me3, C6H4Me2) (1981) (27)
- C−H Activation and C−C Coupling Reactions in 2-Vinylpyridine Cationic Complexes of Iridium (2004) (27)
- The Five-Coordinate Hydrido−Dihydrogen Complex [OsH(η2-H2)(CO)(PiPr3)2]BF4 Acting as a Template for the Carbon−Carbon Coupling between Methyl Propiolate and 1,1-Diphenyl-2-propyn-1-ol (1998) (27)
- Synthesis and reactions of new hydridosilyliridium(III) complexes containing the diolefin tetrafluorobenzobarrelene (1993) (27)
- Nematic phases in ionic melts: Mesogenic ionic complexes of silver(I) (1989) (27)
- Hydride-rhodium(III)-N-heterocyclic carbene catalysts for vinyl-selective H/D exchange: a structure-activity study. (2014) (27)
- Synthesis of Poly(silyl ether)s by Rhodium(I)–NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis (2013) (26)
- Mechanistic Insights on the Reduction of CO2 to Silylformates Catalyzed by Ir-NSiN Species. (2017) (26)
- Hydrosilylation of alkenes by iridium complexes (1986) (26)
- Convenient Methods for the Synthesis of a Library of Hemilabile Phosphines (2009) (26)
- Cationic rhodium cyclooctadiene complexes with nitrile ligands (1979) (26)
- Dynamic Behavior, Redistribution Reactions, and Intermetallic Distances of Dinuclear Bis(μ-pyrazolato)rhodium(I) Complexes (1996) (26)
- Imidazolate bridged polynuclear rhodium(I) complexes. X-ray structure of [Rh(2-Meimidazolate)(CO)2]4 (1982) (26)
- Arene-rhodium(I) complexes with trimethyltetrafluorobenzobarrelene. Crystal structure of [Rh(Me3TFB)(1,4-C6H4Me2)]ClO4 (1982) (26)
- Graphene-NHC-iridium hybrid catalysts built through -OH covalent linkage (2015) (26)
- Addition of CH3CO2H and HBF4 to alkynyl complexes of ruthenium(II) and osmium(II) (1994) (26)
- Rhodium(I) complexes with pyridazine, 4,6-dimethyl-pyrimidine, 4,6-bis(3,5-dimethylpyrazol-1-yl)pyrimidine, 3,6-bis(3,5-dimethylpyrazol-1-yl)pyridazine and 3-(3,5-dimethylpyrazol-1-yl)-6-chloropyridazine (1984) (26)
- Bis(diphenylphosphino)amine and their dichalcogenide derivatives as ligands in rhodium(III), iridium(III), and ruthenium(II) complexes. Crystal structures of [(η5-C5Me5)MCl{η2-(SePPh2)2N}] (M=Rh, Ir) (2000) (26)
- REACTION OF OSHCL(CO)(PIPR3)2 WITH CYCLOHEXYLACETYLENE : FORMATION OF A HYDRIDO-VINYLIDENE COMPLEX VIA A 1,3-HYDROGEN SHIFT (1995) (25)
- Synthesis and catalytic activity of heterodinuclear Ru-Ir and Ru-Rh complexes. Crystal structure of [H(CO)(PPh3)2Ru(μ-Cl)(μ-pz)Ir(TFB)] (pz = pyrazolate, TFB = tetrafluorobenzobarrelene) (1990) (25)
- Dimetallic dioxygen activation leading to a doubly oxygen-bridged dirhodium complex. (2005) (25)
- Design of Highly Selective Alkyne Hydrothiolation RhI-NHC Catalysts: Carbonyl-Triggered Nonoxidative Mechanism (2017) (25)
- DEPROTONATION OF CP2TI(SH)2 WITH MONONUCLEAR RHODIUM AND IRIDIUM COMPOUNDS: A NEW ROUTE TO TRINUCLEAR EARLY-LATE HETEROBIMETALLIC COMPLEXES (1999) (25)
- Transition Metal Carbonyl Compounds (2004) (25)
- Iridium-catalyzed hydrosilylation of hex-1-yne: the unusual formation of 1-triethylsilylhex-1-yne (1988) (25)
- Controlling the molecular architecture of low nuclearity rhodium and iridium complexes using bridging NCX (X=N, O, S) ligands (1999) (25)
- A new access to 4 H-quinolizines from 2-vinylpyridine and alkynes promoted by rhodium-N-heterocyclic-carbene catalysts. (2013) (25)
- Synthesis and Stereochemistry of Half-Sandwich Alkynyl Amino Acidate Complexes of Rhodium(III), Iridium(III), and Ruthenium(II) (2000) (25)
- Rhodium and iridium complexes containing the anion of 1-phenyl-3-methyl-4-benzoyl- pyrazolone-5, a sophisticated analogue of β-diketones (1985) (25)
- Hydrosilylation of phenylacetylene catalyzed by [Ir(COD)(η2-iPr2PCH2CH2OMe)][BF4] (1995) (25)
- Effect of structural differences of carbon nanotubes and graphene based iridium-NHC materials on the hydrogen transfer catalytic activity (2016) (25)
- Oxo Sulfido Heteronuclear Titanium−Rhodium Clusters with an Incomplete Doubly-Fused Cubane Structure (1998) (25)
- Synthesis of mononuclear complexes of Ru and Os and heterobimetallic M–M′(M = Ru or Os; M′= Rh, Ir, or Au) compounds with pyrazolate or imidazolate type ligands. X-Ray crystal structure of [(Ph3P)2(OC)HRu(µ-bim)Rh(cod)](bim = dianion of 2,2′-bi-imidazole, cod = cyclo-octa-1,5-diene) (1990) (25)
- Key factors determining the course of methyl iodide oxidative addition to diamidonaphthalene-bridged diiridium(I) and dirhodium(I) complexes. (2000) (24)
- Rhodium(I) and Iridium(I) Complexes Containing β-Diketonate or Pyrazole Ligands. Liquid Crystal and Nonlinear Optical Properties (1999) (24)
- Cationic rhodium(I) diolefin complexes (1980) (24)
- A Paramagnetic, Mononuclear Organometallic Iridium(II) Complex: [Ir(C6Cl5)2(cod)] (1992) (24)
- Synthesis and Reactivity of Mononuclear (Pentachlorophenyl)rhodium(II) Complexes. Structural Relevance of Rhodium−o-Chlorine Secondary Bonding (1997) (24)
- Synthesis, characterization and molecular structure of the hydroperoxo complex [(η5C5Me5)Ir(µ-pz)3Rh(OOH)(dppe)][BF4]; Hpz = pyrazole, dppe β 1,2-bis(diphenylphosphino)ethane (1994) (24)
- Trans additions of silanes to 1-alkynes catalyzed by ruthenium complexes: Role of in situ formed polynuclear aggregates (2002) (24)
- PREPARATION AND SPECTROSCOPIC AND THEORETICAL CHARACTERIZATION OF THE TETRAHYDROBORATE COMPLEX OSH3(ETA 2-H2BH2)(P-I-PR3)2 (1994) (23)
- Di‐(μ‐amido)dirhodium Complexes: Structure of [Rh2(μ‐(NH)2naphth)I2(CO)2(PPh3)2] (1984) (23)
- Half-sandwich rhodium (and iridium) complexes as enantioselective catalysts for the 1,3-dipolar cycloaddition of 3,4-dihydroisoquinoline N-oxide to methacrylonitrile. (2007) (23)
- Syntheses, spectroscopic characterizations, and X-ray structures of new Os({eta}{sup 2}-H{sub 2}) compounds containing azole ligands (1994) (23)
- Binuclear Oxidative Addition of Hydrogen in Diamidonaphthalene‐Bridged Diiridium Complexes (1998) (23)
- Benzamidinatorhodium complexes. X-Ray structures of [Rh{CPh(NPh)2}(cod)] and [Rh2{µ-CPh(NPh)2}2(tfbb)2] (1985) (23)
- Rectangular and hexagonal columnar mesophases in dinuclear rhodium (II) (alkyloxy)benzoate complexes (1992) (23)
- New Dihydride− and Alkene−η6-Arene Complexes of Iridium (2001) (23)
- Activation of a vinyl carbon–hydrogen bond in a tris(pyrazolyl)boratoiridium complex. The X-ray crystal structure of [IrH{HB(pz)3}(σ-C8H13)(η2-C8H14)] (1989) (23)
- Labile Hydrido Complexes of Iridium(III): Synthesis, Dynamic Behavior in Solution, and Reactivity toward Alkenes (1999) (23)
- Bimetallic Reactivity of Dirhodium Compounds Leading to Functionalized Methylene-Bridged Compounds† (2001) (23)
- 2,2′-biimidazole, 2,2′-bibenzimidazole and imidazoles as ligands in cationic rhodium(I) complexes (1981) (23)
- Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines. (2015) (23)
- Reversible CO2 Fixation by Iridium(I) Complexes Containing Me2PhP as Ligand (2010) (23)
- Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrelene) (1990) (23)
- Synthesis of Butadiene-Osmium(0) and -Ruthenium(0) complexes by reductive Carbon-Carbon coupling of two alkenyl fragments (1995) (23)
- A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights (2017) (22)
- Mononuclear and dinuclear bromo bridged iridium(I) complexes with N-allyl substituted imidazolin-2-ylidene ligands (2006) (22)
- Argentotropism in (pentamethylcyclopentadienyl)iridium complexes with pyrazole ligands : multinuclear DNMR esperiments (1994) (22)
- Mononuclear rhodium(I) complexes of 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole. Crystal structure of [Rh(CO)2(NH2bpt)]ClO4 (1986) (22)
- Reactions of the cis-dicarbonyl compound Ir(η1-OC(O)CH3)(CO)2(PCy3) with HSnPh3, HSiR3 (R = Ph, Et), and Hx+1SiPh3-x (x = 1, 2) (1994) (22)
- Early-Late Heterotetranuclear Complexes (TiRh3) with Bridging Sulfido Ligands: Ligand Replacement Reactions and Catalytic Activity in Hydroformylation of Olefins (1999) (22)
- Synthesis, X-ray structure, and protonation of [Os(C2Ph){NH:C(Ph)C6H4}(CO)(PPr-i3)2] (1995) (22)
- Binuclear hydroxo-, methoxo-, and pyrazolate-bridged complexes of ruthenium(II). Molecular structure of [{(p-cymene)Ru}2(μ-pz)(μ-OH)2]BF4 (p-cymene = p-MeC6H4CHMe2, pz = pyrazolate) (1992) (22)
- Oxidative Addition of HSnR3 (R = Ph, Bu) to the Square-Planar Iridium(I) Compounds Ir(XR)(TFB)(PCy3) (XR = OMe, OEt, OCHMe2, OPh, SPr) and Ir(C2Ph)L2(PCy3) (L2 = TFB, 2CO) (1995) (22)
- Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes. (2011) (22)
- Hydrogenation of benzylideneacetone catalyzed by chlorodihydridobis(diisopropylphosphine)iridium: kinetic evidence for the participation of an iridium-.eta.2-dihydrogen complex in the activation of molecular hydrogen (1992) (22)
- Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O (1984) (22)
- Pentamethylcyclopentadienyl-iridium(III) complexes with pyridylamino ligands: synthesis and applications as asymmetric catalysts for Diels-Alder reactions. (2007) (22)
- A homoleptic mononuclear iridium(II) organometallic complex : synthesis and X-ray structure of [Ir(C6Cl5)4]2- (1993) (21)
- Synthesis and reactivity of alkoxy(.eta.4-cycloocta-1,5-diene)iridium(I) and -rhodium(I) M(OR)(cod)(PCy3) compounds. X-ray crystal structure of the alkynyl Ir(C.tplbond.CPh)(cod)(PCy3) complex (1989) (21)
- Rhodium(I) complexes containing 4-pyridylmethylene-4′-alkoxyanilines as ligands: Formation of rhodium containing liquid crystals by coordination of non-mesogenic organic ligands (1990) (21)
- Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts. (2012) (21)
- Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu) (1987) (21)
- Metal Basicity of Dirhodium and Diiridium Complexes Induced by Isocyanide Ligands. Model for the Oxidative-Addition Reaction of Methyl Iodide with Dinuclear Complexes (1997) (21)
- Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene) (1988) (21)
- Synthesis of a Square-Planar Rhodium Alkylidene N-Heterocyclic Carbene Complex and Its Reactivity Toward Alkenes (2011) (21)
- Iridium(III) Complexes Bearing Chelating Bis‐NHC Ligands and Their Application in the Catalytic Reduction of Imines (2016) (21)
- Paramagnetic mononuclear rhodium(II) organometallic complexes. X-ray structure of [Rh(C6Cl5)2{P(OPh)3}2] (1993) (21)
- Selective CH Bond Functionalization of 2‐(2‐Thienyl)pyridine by a Rhodium N‐Heterocyclic Carbene Catalyst (2014) (21)
- Heterobi- and Heterotetranuclear RuRh and RuIr Complexes with 2,2'-Biimidazolate and 2,2'-Bibenzimidazolate Anions as Bridging Ligands (1995) (21)
- Synthesis, reactivity and crystal structure of [Rh(C6H5Me){P(OPh)3}2]ClO4 (1980) (21)
- Bis-bridged dirhodium or diiridium complexes derived from diamine- or dihydroxy-naphthalenes (1985) (21)
- Supported Metal Complexes (1994) (21)
- Pyrazolate rhodium complexes as hydroformylation catalyst precursors (1982) (21)
- Sulfido-Bridged Tetranuclear Titanium−Iridium Complexes with an Unconventional Tetrahedral Iridium Center (1999) (21)
- Sequential C-H activation and dinuclear insertion of ethylene promoted by a diiridium complex. (2002) (21)
- Selective protonation of the styryl ligand of RuMe{(E)-CH:CHPh}(CO)2(PiPr3)2 and migratory CO insertion in the methyl group of [RuMe(CO)2(PiPr3)2]BF4 (1995) (21)
- Synthesis of Rhodium, Iridium, and Palladium Tetranuclear Complexes Directed by 2,6-Dimercaptopyridine. X-ray Crystal Structure of [Rh4(μ-PyS2)2(cod)4] (cod = 1,5-Cyclooctadiene) (1996) (21)
- Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes (1981) (21)
- Transmission of trans effects in dinuclear complexes. (2001) (20)
- [CpTi(μ3-S)3{Rh(tfbb)}3]: An early-late heterometallic complex as molecular model for the deactivation of metal sulphide catalysts (1996) (20)
- Di(μ-pyrazolate)bis(pentamethylcyclopentadienyl)rhodium complexes. Molecular structure of [{Rh(C5Me5)(pz)} 2(μ-pz = pyrazolate) (1985) (20)
- Oxidation of Substrates by an Iridium Dioxygen Complex: Intramolecular Oxidation of Carbon Monoxide and Activation of a Carbonyl Group by Attack of a Heterocyclic Nitrogen (1995) (20)
- Synthesis and Protonation of the Dithioformato Complex OsH(.eta.2-S2CH)(CO)(PiPr3)2 (1994) (20)
- Half-sandwich organometallic complexes with stereogenic metal centres: Synthesis and characterization of diastereomeric [(ηn-ring)M(Aa)X] (Aa = α-amino carboxylate) compounds (2012) (20)
- Rhodium complexes containing 1-(4-pyridylmethylene)-4-alkoxyanilines as ligands: crystal structure of an unusual square-planar cluster of 64 electrons, Rh4(OOCCH3)4(CO)4(NC5H4CH:NC6H4OC14H29)4 (1991) (20)
- Asymmetric 1,3-dipolar cycloaddition reaction of α,β-unsaturated nitriles with nitrones catalyzed by chiral-at-metal rhodium or iridium complexes (2009) (20)
- Theoretical Studies on the Mechanism of Iridium-Catalyzed Alkene Hydrogenation by the Cationic Complex [IrH2(NCMe)3(PiPr3)]+ (2014) (20)
- Tuning the activity and selectivity of iridium-NSiN catalyzed CO2 hydrosilylation processes (2016) (20)
- Asymmetric hydrogenation of 2-benzamido(acetamido)-3-(2-thienyl)-2-propenoic acids catalyzed by rhodium-diop complexes (1982) (20)
- Reactions of [RuH(η3C3H5)(CO)(PiPr3)2] and [Ru(η2C2Ph2)(CO)(PiPr3)2] with terminal alkynes: synthesis and characterization of new five- and six-coordinate bis(alkynyl) and alkynyl(vinyl) derivatives of ruthenium(II) (1995) (20)
- N-Heterocyclic olefins as ancillary ligands in catalysis: a study of their behaviour in transfer hydrogenation reactions. (2016) (20)
- Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene) (1991) (20)
- Mono- and polynuclear rhodium(I) complexes with nitrogen-donor ligands (1981) (20)
- Durene-rhodium(I) complexes. Crystal structures of the complexes [Rh(durene)(diolefin)]ClO4 (diolefin tetrafluorobenzobarrelene or trimethyltetrafluorobenzobarrelene) (1982) (19)
- Tetraphenylborate complexes of rhodium(I) (1978) (19)
- Thermally Activated Site Exchange and Quantum Exchange Coupling Processes in Unsymmetrical Trihydride Osmium Compounds. (1999) (19)
- Substitution and oxidative addition reactions of the monoolefin complex Rh(acac)(cyclooctene)(PCy3) including the X-ray structure analyses of Rh(acac)(PCy3)2 and [Rh(acac){(E)-CH=CHCy}(PCy3)2]BF4 (1996) (19)
- Pyridine versus acetonitrile coordination in rhodium-N-heterocyclic carbene square-planar complexes. (2015) (19)
- Synthesis, molecular structure and reactivity of the octahedral iridium(III) compound [IrH(.eta.1,.eta.3-C8H12)(dppm)] [dppm = bis(diphenylphosphino)methane] (1992) (19)
- Rhodium(I) complexes with the 2,2′-bipyrimidine ligand (1987) (19)
- Effects of the heterocycle and its substituents on structure and fluxionality in rhodium(I) and iridium(I) complexes with the hindered thiolates 6-tert-butylpyridine-2-thiolate and 1-alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl and tert-butyl) (2006) (19)
- Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis (2017) (19)
- 1,2,4-Triazolate (tz) complexes of rhodium(I), iridium(I), and palladium(II). Crystal structure of [Rh3(µ3-tz)(µ-Cl)Cl(η4-tfbb)(CO)4]·0.5CH2Cl2(tfbb = tetrafluorobenzobarrelene), a trinuclear complex with extended metal–metal interactions (1986) (19)
- One-electron versus two-electron mechanisms in the oxidative addition reactions of chloroalkanes to amido-bridged rhodium complexes. (2007) (19)
- Dinuclear rhodium and iridium complexes with mixed amido/methoxo and amido/hydroxo bridges. (2002) (19)
- Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Rhodium Complexes: Mechanistic Considerations (2000) (19)
- Synthesis and Characterization of Heterodinuclear IrCo, RuCo, IrNi, and RuNi Complexes Containing Pyrazolate and Pyrazolylborate Ligands. (1996) (19)
- Chiral iridium(III) α-amino acidato complexes (RIr,SN,SC)- and (SIr,SN,SC)-[(η5-C5Me5)Ir(L-prolinate)(CCCMe3)] (1993) (19)
- Synthesis of ruthenium-palladium and ruthenium-rhodium complexes linked by pyrazolate groups and chlorine atoms. Crystal structure of [(p-cymene)ClRu(μ-Cl)(μ-pz)Pd(C8H11)] (1987) (19)
- Labile rhodium(I)-N-heterocyclic carbene complexes (2013) (19)
- Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers. (2005) (19)
- Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers. (2016) (18)
- NEW PERSPECTIVE ON THE FORMATION AND REACTIVITY OF METAL-METAL-BONDED DINUCLEAR RHODIUM AND IRIDIUM COMPLEXES (1997) (18)
- Five coordinate rhodium(I) complexes containing the thihalogenotin group (1980) (18)
- Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation (2014) (18)
- Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands (2018) (18)
- Stereoselective oxidative additions of iodoalkanes and activated alkynes to a sulfido-bridged heterotrinuclear early-late (TiIr2) complex. (2003) (18)
- Rational design of efficient rhodium catalysts for the anti-Markovnikov oxidative amination of styrene. (2010) (18)
- A Trithiol Protio-Ligand and Its Fixation to the Periphery of a Carbosilane Dendrimer as Scaffolds for Polynuclear Rhodium and Iridium Complexes and Metallodendrimers (2005) (18)
- Supramolecular structures and columnar mesophase induction in nondiscoid pyrazoles by complexation to rhodium(I). (2006) (18)
- Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[-(3,5-dimethylpyrazolato-NN?)-tricarbonylruthenium(I)](Ru?Ru) and bis[-(3,5-dimethylpyrazolato-NN?)]--iodo-bis[tricarbonylruthenium(II)]tri-iodide (1989) (18)
- Synthesis, Molecular Structure and Catalytic Activity of Six-Coordinate Chloro(hydrido)- and Dihydridoruthenium(II) and -osmium(II) Complexes with the Chiral Ligands PiPr2NH(Me)Ph, (S,S)-Chiraphos and (S,S,)-Diop (2004) (18)
- Syntheses and Reactivity of Functionalized (η5-Tetramethylcyclopentadienyl) Rhenium Complexes: Molecular Structures of (η5:η2-C5Me4CH2CH2CHCH2)Re(CO)2 and (η5-C5Me4CH2-2-C4H3S)Re(CO)2(PMe3) (2003) (18)
- Influence of the heterocyclic ring on the asymmetric synthesis of .beta.-hetarylalanines by homogeneous catalytic hydrogenation (1984) (17)
- Rhodium(I) indazole and indazolate complexes (1982) (17)
- Di- and tetra-nuclear mixed-valence complexes of rhodium(III,I) and rhodium(III)–iridium(I) with the 2,2′-bi-imidazolate(2–) anion (bim) as bridging ligand. Crystal structure of [{(η-C5Me5)[P(OEt)3]Rh(bim)Rh(nbd)}2][ClO4]2 (1986) (17)
- Tris(pyrazolyl)borate carbosilane dendrimers and metallodendrimers. (2006) (17)
- C-H bond activations by new labile η6-arene complexes of iridium (1999) (17)
- A flexible framework obtained from oxidative additions upon the binuclear complex [Ir2(-pz)(-SBut)(CO)2{P(OMe)3}2]: preparation and X-ray structures of [Ir2(-pz)(-SBut)(-L)(CO)2{P(OMe)3}2] and [Ir2(-pz)(-SBut)(-L)I2(CO)2-{P(OMe)3}2](Hpz = pyrazole, L = dimethyl acetylenedicarboxylate) (1990) (17)
- Mixed-bridged bimetallic d8 complexes. Crystal and molecular structure of (η3-C3H5)Pd(μ-pz)(μ-N3)Rh(CO)2, heterobinuclear complex with extended Rh⋯Rh interactions (1987) (17)
- 2-Pyridonate (OPy) rhodium complexes. Crystal structure of [Rh(μ-OPy)(CO)22]; a chain-forming complex with alternate short and long metal-metal distances (1989) (17)
- Reactions of chloroform and gem-dichlorocarbons with binuclear rhodium complexes leading to functionalized methylene-bridged compounds (1992) (17)
- Novel Anionic Aryl Complexes of RhIII: [Rh(C6F5)5]2⊖ and [Rh(C6F5)4(CO)2]⊖ (1988) (17)
- Preparation of IrH(diene)L2 compounds via methoxyiridium complexes: Catalysts for hydrogen transfer reactions (1986) (17)
- Alkyne-promoted H2 loss in a metallaborane: nido-to-closo cluster transformation and sp C-H bond oxidative addition. (2009) (17)
- Iridium(I) complexes with tetrafluorobenzobarrelene (1984) (17)
- Synthesis and characterization of heterodinuclear RuPt and IrPt complexes containing pyrazolate bridging ligands. Crystal structure of [(η5-C5Me5)Ir(μ-pz)3PtMe3] (pz=pyrazolate) (2000) (17)
- Enantioselective Friedel–Crafts alkylations catalysed by well-defined iridium and rhodium half-sandwich complexes (2011) (17)
- SYNTHESIS OF RH(ACAC)H(GEET3)(PCY3) AND RH(ACAC)H(SNPH3)(PCY3) AND THEIR REACTIONS WITH ALKYNES (1996) (17)
- Koordination von H2 und O2 an [OsHCl(CO)(PiPr3]2: Ein katalytisch wirksamer M(η2‐H2)‐Komplex (1988) (17)
- Reactions of phosphine ligands with iridium complexes leading to C(sp3)-H bond activation (2005) (17)
- Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Iridium Complexes: The Detection of Tautomeric Equilibria and Their Implications on the Reactivity (2000) (17)
- Pyrazolato-iridium(III) complexes (1994) (17)
- Trinuclear pyrazolate complexes. Crystal structure of [(OC)2Rh(µ-pz)2Pd(µ-pz)2Rh(CO)2] (1989) (17)
- Barreleneiridium(I) complexes. Crystal structures of [Ir(Me3TFB)(η6-C6H4Me2)]ClO4 and [Ir(TFB)(η5-PhNPh2)]BF4·CH2Cl2 (TFB = tetrafluorobenzobarrelene) (1984) (17)
- Reversible C-H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers. (2000) (17)
- Unusual 1‐Alkyne Dimerization/Hydrogenation Sequences Catalyzed by [Ir(H)2(NCCH3)3(P‐i‐Pr3)]BF4: Evidence for Homogeneous‐Like Mechanism in Imidazolium Salts (2003) (17)
- Reversible capture of small molecules on bimetallaborane clusters: synthesis, structural characterization, and photophysical aspects. (2011) (16)
- C-H activations at iridium(I) square-planar complexes promoted by a fifth ligand. (2005) (16)
- Mononuclear rhodium and iridium compounds with pyridyl-pyrazole ligands (2005) (16)
- The Mechanisms of Homogeneous Hydrogenation (1994) (16)
- 2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3 (1983) (16)
- Unsaturated Iridium(III) Complexes Supported by a Quinolato–Carboxylato ONO Pincer-Type Ligand: Synthesis, Reactivity, and Catalytic C–H Functionalization (2013) (16)
- Encapsulation of Thallium(I) by Tetranuclear Rhodium or Iridium Complexes: Synthesis and Molecular Structure of Heterobimetallic Complexes Stabilized by s2−d8 Bonding Interactions (1999) (16)
- Chiral transition-metal complexes as Brønsted-acid catalysts for the asymmetric Friedel-Crafts hydroxyalkylation of indoles. (2014) (16)
- Protonation reactions of dinuclear pyrazolato iridium(I) complexes. (2003) (16)
- Stepwise Construction of Polynuclear Complexes of Rhodium and Iridium Assisted by Benzimidazole-2-thiol. NMR and X-ray Diffraction Studies. (1996) (16)
- Synthesis, Structure, and Bonding of the Unusual μ-σ,σ-Allenylidene Complex [Rh2(μ-OOCCH3)(μ-σ,σ-CCCPh2)(CO)2(PCy3)2]BF4 (1996) (16)
- Square-planar rhodium(I) complexes partnered with [arachno-6-SB(9)H(12)]- : a route toward the synthesis of new rhodathiaboranes and organometallic/thiaborane salts. (2007) (16)
- Chiral pyridylamino-ruthenium(II) complexes: synthesis, structure and catalytic properties in Diels-Alder reactions. (2008) (16)
- N-Substituted imidazole derivatives of rhodium(I) and iridium(I) with and without metal-metal interaction. Crystal structure of cis-(CO)2RhCl(N-methylimidazole) (1989) (16)
- Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed by [Rh(NBD)(PPh3)2]BF4 in dichloromethane: a kinetic and spectroscopic investigation (2000) (16)
- Hydrogen-transfer catalytic synergism in binuclear complexes containing 2,2'-biimidazolate as a bridging ligand (1992) (16)
- Kinetic studies on the selective hydrogenation of phenylacetylene catalyzed by [Rh(NBD)(PPh3)2]BF4 (NBD=2,5-norbornadiene) (1998) (16)
- Complexes of rhodium and iridium derived from 2,5-bis(pyrazol-1'-yl)-1,4-dihydroxybenzene (1994) (15)
- Structural and dynamic studies on amido-bridged rhodium and iridium complexes. (2002) (15)
- Reversible Isomerization of the Dinuclear Complex [(η6‐p‐cymene)RuCl(μ‐pz)2 Ir(CO)2] with Formation of a Ruthenium‐Iridium Bond (1991) (15)
- Rhodium-Catalyzed Polymerization of Phenylacetylene and its Derivatives (2013) (15)
- New Cyclopentadienylosmium Derivatives Prepared from the Five-Coordinate Complex [OsHCl(CO)(PPri3)2] (1996) (15)
- Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes. (1998) (15)
- IrCl2H(PiPr3)2 as catalyst precursor for the reduction of unsaturated substrates (1993) (15)
- Iridium liquid crystal complexes by co-ordination of non-mesogenic orgainic ligands (1989) (15)
- Vierkernige Komplexe als Zwischenstufen transanularer oxidativer Additionsreaktionen; Struktur des ersten linearen Tetrairidiumclusters (1988) (15)
- Cationic iridium(I) complexes with 1,5-cyclooctadiene and nitrogen ligands (1983) (15)
- Chiral Brønsted Acid Catalysts. Activation of Methyl 3,3,3-Trifluoropyruvate by Hydroxymethylpyridine-Containing Half-Sandwich Complexes (2014) (15)
- Benzotriazole and benzotriazolate complexes of rhodium(I) (1985) (15)
- Tri-, bi- and mononuclear rhodium complexes with the anionic polydentate ligands 1,8-naphthyridine-2-one and 5,7-dimethyl-1,8-naphthyridine-2-one (1986) (15)
- The rhodium and iridium co-ordination chemistry of the hemilabile hybrid ligand 1-(2′-pyridyl)-3-dimethylamino-2-propen-1-one (2003) (15)
- P-H activation of secondary phosphanes on a parent amido diiridium complex. (2014) (14)
- Preparation and properties of some cationic norbornadiene rhodium(I) complexes with triarylphosphines (1981) (14)
- Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium: II. Oxidative-addition reactions of halogens and halocarbons to [{Ir(μ-aza)(CO)2}2]☆☆☆ (1993) (14)
- Synthesis and Reactivity of Mononuclear Anionic Pentafluorophenyl Compounds of Rhodium(I) and Iridium(I). X-ray Structure of [{P(OPh)3}2(C6F5)2RhAg(PPh3)] (1995) (14)
- N-substituted imidazole derivatives of rhodium(I) and iridium(I). Crystal structure of the head-to-head dinuclear compound [Ir2(μ-N-benzylimidazolato-N3,C2)2(CO)4] (1994) (14)
- Alkene C-H activations at dinuclear complexes promoted by oxidation. (2002) (14)
- New Early Zirconium‐Sulfido Metallaligands for Late Transition Metals; Synthesis and Reactivity of [Cptt2Zr(SH)2] and [Cptt2Zr(SH)(OTf)] (1999) (14)
- Surface‐bound organometallic rhodium precursors for 1‐hexene hydrogenation (1990) (14)
- Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands (1996) (14)
- Tetrazolate rhodium(I) complexes. Crystal structures of the trinuclear complexes [Rh3(µ3-ttz)(µ-Cl)Cl(cod)2(CO)2](ttz = tetrazolate, cod = cyclo-octa-1,5-diene) and [Rh3(µ3-ttz)(µ-Cl)Cl(CO)6], an unusual example of metal–metal interactions (1988) (14)
- Bidentate amine N-oxides and phosphine oxides as ligands in rhodium(I) chemistry (1982) (14)
- Heterobinuclear pyrazolate-bridged ruthenium(II)―rhodium(I), iridium(III)―rhodium(I), and rhodium(III)―iridium(I) complexes: crystal structure of [(p-cymene)Ru(μ-Cl)2(μ-pz)Rh(tetrafluorobenzo[5.6]bicyclo[2.2.2]octan-2,5,7-triene)] (1985) (14)
- Rhodium(I) complexes with pyridine-2-aldehyde and related Schiff-base ligands (1983) (14)
- A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin (2018) (14)
- Impact of Protic Ligands in the Ir-Catalyzed Dehydrogenation of Formic Acid in Water (2018) (14)
- Dinuclear pyrazolate-lridium hydride complexes. Crystal structure of [{Ir(C5Me5)}2(μ-H)2(μ-pz)]BF4 (px = pyrazolate) (1986) (14)
- Rhodium carbonyl complexes with tropolones, salicylaldehyde and salicylaldimine schiff bases (1981) (14)
- 1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2] (1985) (14)
- An insight into transfer hydrogenation reactions catalysed by iridium(III) bis-N-heterocyclic carbenes (2015) (14)
- New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes (1983) (14)
- Synthesis and crystal structure of [Ir(acac-C3)(COD)(phen)] (1983) (14)
- Synthesis and molecular structure of [[(HBpz(3))Rh(PPh(3))(mu-Cl)(2)](2)Ag]BF(4) (Hpz = pyrazole), a heterotrinuclear Rh(2)Ag compound with square-planar silver(I). (2002) (14)
- Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles (2018) (14)
- Chiral-at-metal ruthenium(II) complexes as catalysts in the asymmetric cyclopropanation reaction (2005) (13)
- New iridathiaboranes with reversible isonido <--> nido cluster flexibility. (2010) (13)
- Cationic rhodium(I) complexes with norbornadiene and nitrogen donors (1976) (13)
- Mechanistic studies on the N-alkylation of amines with alcohols catalysed by iridium(I) complexes with functionalised N-heterocyclic carbene ligands (2018) (13)
- Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2 (1986) (13)
- The influence of various azolate bridging ligands on the catalytic activity of dinuclear rhodium(I) precursors in the hydroformylation reaction (1987) (13)
- SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF HETERODINUCLEAR RUM (M=CU(I), AG(I), AU(I), RH(I), AND IR(I) AND HETEROTRINUCLEAR RUAG2 AND RURHAG COMP OUNDS DERIVED FROM THE METAL-COMPLEX LIGAND BIS((PYRAZOLATO)(P-CYMENE)(PYRA ZOLE)RUTHENIUM(II) (1995) (13)
- Arene–Ruthenium Chemistry and Brønsted Acid Catalysis of a Chiral Phosphane-Hydroxyl Ligand (2014) (13)
- Mechanistic Studies on the Catalytic Oxidative Amination of Alkenes by Rhodium(I) Complexes with Hemilabile Phosphines (2013) (13)
- Synthesis and structure of Ru{Ph6Sn3(.mu.-OMe)2}(.eta.2-H2)(CO)(PiPr3) containing a tridentate tin donor ligand and coordinated dihydrogen (1995) (13)
- A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene)). (2015) (13)
- The π-(Hydroxyalkenyl)germane Complexes Rh(acac){η2-(E)-Et3GeCHCHC(OH)R2}(PCy3) (R = Me, Ph) as Intermediates in the Hydrogermylation of Alkynols Catalyzed by Rh(acac)(cyclooctene)(PCy3) (1999) (13)
- Hydrogenation of 1-hexene by rhodium catalysts (1981) (13)
- A C-H activation-CO(2)-carboxylation reaction sequence mediated by an 'Iridium(dppm)' species. Formation of the anionic ligand (Ph(2)P)(2)C-COOH. (2008) (13)
- REACTIVITY OF OSH2CL2(PIPR3)2 TOWARD DIOLEFINS : NEW REACTIONS INVOLVING C-H AND C-C ACTIVATION AND C-C AND C-P BOND FORMATION PROCESSES (1997) (13)
- Iridium-catalysed homogeneous hydrogenation of prochiral enamides containing tetrasubstituted alkene moieties (1983) (13)
- Novel Neutral and Anionic Rhodium Complexes Containing Imido Ligands (1996) (13)
- Enhancing the hydrogen transfer catalytic activity of hybrid carbon nanotube-based NHC–iridium catalysts by increasing the oxidation degree of the nanosupport (2016) (13)
- A DFT study of the role of water in the rhodium-catalyzed hydrogenation of acetone. (2016) (13)
- Synthesis, Characterization, and Theoretical Studies on Heterobinuclear (p-cymene)Os(μ-pz)2M (M = Ir, Rh; Hpz = Pyrazole) Complexes (2000) (13)
- Oxidative-Addition Reactions of Diiodine to Dinuclear Rhodium Pyrazolate Complexes. (1999) (13)
- Iridium complexes as catalysts in the hydrogen transfer of isopropanol to acetophenone: Ligand effects and DFT studies (2015) (13)
- Synthesis of transition-metal complexes with heterodifunctional ligands derived of NH(PPh2)2. Crystal structure of [(η5-C5Me5)RhCl{η2-P,Se-Ph2PNP(Se)Ph2}]·CH2Cl2 (2001) (13)
- Binuclear dirhodium(I) complexes with phenyl(2-pyridyl)amido ligands. Crystal and molecular structure of [{Rh(μ-N,N′-PhNPy)(nbd)}2]·H2O (nbd = 2,5-norbomadiene) (1987) (13)
- Preparation and x-ray structure of [(C5Me5)Rh(μ-pz)2(μ-CO)Rh(dppp)] BPh4(pz = pyrazolate; dppp = 1,3-bisdiphenylphosphinopropane) (1986) (12)
- Synthesis, molecular structure, and reactivity of Iridium(I) and Iridium(III) complexes formed by coordination and C−H activation of the substituted arenes C6H5CH2CH2PiPr2 and C6H5OCH2CH2PtBu2 (2003) (12)
- Mixed-valence pyrazolate rhodium complexes. Molecular structure of [(C5Me5)ClRhCl(pz)Rh(tfb)]·CH2Cl2(Hpz = pyrazole; tbf = tetrafluorobenzobarrelene) (1986) (12)
- Synthesis and catalytic activity of trihalotin-iridium complexes (1980) (12)
- Determination of the free activation energy for the breaking of the 31P107(109)Ag bond in [(η6-p-cymene)Ru(μ-pz)3Ag(PPh3)] (1994) (12)
- Effect of the CO2-pressure on the hydrosilylation of CO2 catalyzed by [Ir(NSiN)] species (2015) (12)
- Hydride mobility in trinuclear sulfido clusters with the core [Rh3(μ-H)(μ3-S)2]: molecular models for hydrogen migration on metal sulfide hydrotreating catalysts. (2011) (12)
- NOVEL TYPES OF PYRAZOLYL AMIDINE COMPLEXES : MECHANISTIC ASPECTS OF THEIR SYNTHESES AND EXCHANGE REACTIONS WITH ACETONITRILE (1996) (12)
- Unusual Tautomers in Dinuclear Metal Chemistry and Their Role in Oxidative-Addition Reactions of Chlorocarbons (1998) (12)
- Facile [N]C−H Activation by a (P,N)‐Chelate [3]Ferrocenophane−Ruthenium System (2004) (12)
- Hydroformylation of styrene using thiolato–pyrazolate bridge rhodium catalysts modified with phosphorous ligands (1998) (12)
- Synthesis and X-ray Structure of the Unusual Cysteine-Complex OsH2{OC(=O)CH[NHC(=O)CH3]CH2S}(PiPr3)2 (1995) (12)
- Binuclear pentamethylcyclopentadienylrhodium(III) phosphido-pyrazolate complexes: X-ray structure of [{C5Me5)Rh}2(μ-pz)2(μ-PPh2)]BF4 (pz= pyrazolate) (1989) (12)
- Rhodium(I) complexes containing triphenylphosphite ligands (1979) (12)
- Tetrafluorobenzobarreleneiridium complexes with 1,10- phenanthroline,2,2′-bipyridine and diketonate ligands. Crystal structure of [IrI2(TFB)(phen)]ClO4·(CH32CO (TFB = 5,6,7,8- tetrafluoro-1,4-dihydro-1,4-ethenonapthalene, phen = 1,10- phenanthroline) (1986) (12)
- 8-Oxyquinolate iridium(I) complexes and their oxidative-addition reactions (1981) (12)
- REDUCTIVE ELIMINATION OF PH2C=C=CHPR3BF4 FROM THE RHODIUM(III)-ALLENYL DERIVATIVES RH(ACAC)CH=C=CPH2(PR3)2BF4 (PR3 = PCY3, PIPR3) (1997) (12)
- Bi-imidazole (H2bim) and bibenzimidazole η3-allylic complexes of palladium(II). Mono- and tetra-nuclear palladium(II) and heteronuclear palladium(II)–rhodium(I) complexes. Crystal structure of [Pd4(η3-C3H5)4(µ-bim)2]·CH2Cl2 (1983) (12)
- Preparation of Cationic Complexes [Rh(diolefin)L2]C104 and Their Carbonylation Reactions (1979) (12)
- Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands (2003) (12)
- Cationic organocomplexes of rhodium(I) as homogeneous hydroformylation catalysts (1978) (12)
- Synthesis, Separation, and Stereochemical Studies of Chiral-at-Metal Rhodium(III) Complexes. Crystal Structure of (SRh,RC)-[(η5-C5Me5)RhCl{Ph2PCH(Me)CH2PPh2}]BF4 (1996) (12)
- Heteronuclear rhodium, palladium, platinum, and gold organoimido complexes from dinuclear organoamido rhodium precursors. (2004) (12)
- Ir-catalyzed selective reduction of CO2 to the methoxy or formate level with HSiMe(OSiMe3)2 (2019) (12)
- Chemistry of 11-vertex rhodathiaboranes: reactions with monodentate phosphines. (2011) (12)
- Rhodium(I) Complexes with Hemilabile Phosphines: Rational Design for Efficient Oxidative Amination Catalysts (2012) (12)
- The chemical and electrochemical one-electron oxidation of diamidonaphthalene-bridged complexes; paramagnetic [Rh2]3+-containing A-frames (1989) (12)
- Unprecedented Rhodium-Mediated Trimerization of Alkynes HC⋮CR (R = Ph, p-Tolyl) Leading to (η4-Cyclobutadiene)rhodium Complexes (1996) (12)
- Synthesis and characterization of IrH2{Si(OTf)Ph2}(TFB)(PR3) (PR3 = PiPr3, PCy3): First base-stabilized silylene complexes of iridium (1996) (12)
- Oxidative Addition of the N–H Bond of Ammonia to Iridium Bis(phosphane) Complexes: A Combined Experimental and Theoretical Study (2016) (12)
- Azavinylidene and azavinylidene-bridged compounds of iridium and rhodium (1994) (12)
- Selective formation of cis-PhCHCH (SiEt3) by reaction of PhCCH with the stoichiometric amount of HSiEt3, in the presence of ruthenium catalysts (1995) (12)
- Mechanistic insight into the pyridine enhanced α-selectivity in alkyne hydrothiolation catalysed by quinolinolate–rhodium(I)–N-heterocyclic carbene complexes (2016) (12)
- Reactivity of Ir–NSiN Complexes: Ir‐Catalyzed Dehydrogenative Silylation of Carboxylic Acids (2018) (11)
- Azulene as a ligand in cationic rhodium and iridium complexes. Crystal structure of [Rh(TFB)(az)]PF6 (1984) (11)
- Synthesis and reactivity of[OsH{C6H4(CHCHH)}(CO)(PPri3)2] and the formatocompounds[Os{(E )-CHCHPh}(η2-O2CH)(CO)(PPri3)2] and[OsH(η2-O2CH)(CO)(PPri3)2]* (1997) (11)
- Synthesis of alkoxycarbonyl complexes by reaction of the heterobinuclear complex [(.eta.6-p-cymene)RuCl(.mu.-pz)2Rh(CO)2] with alcohols (1993) (11)
- Oxidative addition of methyl iodide and iodine to new binuclear rhodium(I) and iridium(I) compounds containing diaminoanthraquinonate-bridging ligands. Crystal structure of [Rh2(μ-1,4-DA)(CO)2(PPh3)2] (1,4-H2DA = 1,4-diaminoanthraquinone) (1998) (11)
- New methoxo-, hydroxo-, and pyrazolate-bridged complexes of rhodium(III). Crystal structures of [{Rh(C5Me5)}2(mpz)(OMe)2][ClO4](mpz = 3-methylpyrazolate), [{Rh(C5Me5)}2(Hdmpz)2(OH)2][BF4]2(Hdmpz = 3,5-dimethylpyrazole), and [{Rh(C5Me5)}2(pz)2(OH)]-[ClO4](pz = pyrazolate) (1984) (11)
- Enantioselective Catalysts for the Diels–Alder Reaction between Methacrolein and Cyclopentadiene Based on the Chiral Fragment (η5-C5Me5)M(chiral diphosphane) (M = Rh, Ir) (2011) (11)
- Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts. (2015) (11)
- Synthesis and reactivity of new benzophenone imine derivatives containing the Ru(CO)(PiPr3)2 unit (1996) (11)
- Poly(1-pyrazolyl)boratoiridium and tris(1-pyrazolylmethyl)aminoiridium and -rhodium complexes (1991) (11)
- Grafting of Copper(I)–NHC Species on MCM‐41: Homogeneous versus Heterogeneous Catalysis (2015) (11)
- Synthesis, structural characterization, and ligand replacement reactions of gem-dithiolato-bridged rhodium and iridium complexes. (2008) (11)
- Enantioselective Catalytic Diels–Alder Reactions with Enones As Dienophiles (2012) (11)
- Heterobinuclear IrRh, RuRh and Rulr complexes with pyrazolate bridging ligands: reactivity towards chelating diphosphines; crystal structure of [(C5Me5)Ir(µ-pz)2(µ-CO)-Ir(CO)(dppen)]BPh4·0.5MeOH [pz = pyrazolate, dppen =cis-1,2-bis(diphenylphosphino)ethylene] (1991) (11)
- Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes. (2005) (11)
- Reactivity of binuclear heterobridged iridium complexes with SnCl2 (1992) (11)
- Preparation and X-ray structure of a rhodium(III)–rhodium(I) pyrazolate complex with a mercury atom asymmetrically bridging the metal atoms (1984) (11)
- Synthesis of [Ir2(μ-Pz)2(CH3)(CO)2(PiPr3)2]+. A key intermediate in SN2 oxidative addition of halocarbons to dinuclear complexes (1998) (11)
- Mono- and dinuclear cationic rhodium(I) complexes with phosphine oxides and related ligands (1982) (11)
- Carbon monoxide activation by poly(1-pyrazolyl)boratoiridium complexes (1992) (11)
- «Goldene» Pyrazolatringe – Dreikernkomplexe, die bei Raumtemperatur columnare Mesophasen bilden† (1996) (11)
- Rhodium(I) and rhodium(III) arene complexes with N-carbazolyltriphenylphosphinegold(I) and other polycyclic arene ligands (1984) (11)
- Synthesis and characterization of Ru(II), Rh(III) and Ir(III) complexes of the “Daniphos” ligands and their application in the hydrogen transfer catalysis (2004) (11)
- Oxidative addition of I2, MeI, and CH2I2 to the naphthalene-1,8-diamide bridged complex [Ir2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]. X-Ray crystal structure of [Ir2I2(µ-CH2){µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]·CH2Cl2 (1990) (11)
- Binuclear rhodium and iridium complexes containing pentamethylcyclopentadienyl and pyrazolate ligands (1987) (11)
- ONO dianionic pincer-type ligand precursors for the synthesis of σ,π-cyclooctenyl iridium(III) complexes: formation mechanism and coordination chemistry (2013) (11)
- Oxidative-addition reactions on planar chloranilate rhodium systems. Crystal structure of [Rh2(µ-C6Cl2O4)Me2I2(CO)2(PPh3)2] (1996) (11)
- Cationic rhodium(I) complexes with diolefin and substituted pyridine N-oxides as ligands (1981) (11)
- New pyrazolate-, hydroxo- and methoxo-bridged complexes of ruthenium(II). Crystal structure of [{Ru(η-p-MeC64CHMe2)}2(pz)2(OH)]BPh4 (1985) (11)
- Synthesis and Characterisation of New Iridium Complexes with the (4S)‐2‐[2‐(Diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline Ligand That Catalyse Asymmetric Michael Reactions (2005) (11)
- Organometallic complexes of Rh(I) with the group 5-methyl oxyquinolate (1981) (10)
- η3-Allyl rhodium complexes with azolate ligands. Crystal structures of the trinuclear 1,2,4-triazolate (tz) complexes [Rh3(µ-tz)3(η3-C3H5)6] and [Rh3(µ3-tz)(µ-Cl)Cl(η3-C3H5)2(CO)4]·0.5C2H4Cl2 (1986) (10)
- Oxidative Addition Reactions to Novel Heterotrinuclear Iridium Complexes with Mixed Bridging Ligands. Crystal Structure of [{Ir(.mu.-pz)(.mu.-StBu)I2(CO)[P(OMe)3]}2Pd] (1995) (10)
- Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO (1990) (10)
- A WAY TO NOVEL HETEROMETALLIC RAFT-LIKE CLUSTERS FROM NEUTRAL PRECURSORS (1997) (10)
- The dyciclopentadienyl-gadolinium and ytterbium chlorides (1975) (10)
- Preparation and properties of thiophosphinito-bridged rhodium complexes. Crystal structure of [Rh2(μ-SPPh2)2(COD)2] (1988) (10)
- Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System (2012) (10)
- Mechanistic investigations of imine hydrogenation catalyzed by cationic iridium complexes. (2006) (10)
- On the synthesis and chemical behaviour of the elusive bis(hydrosulfido)-bridged dinuclear rhodium(I) complexes [{Rh(mu-SH)(CO)(PR(3))}(2)]. (2009) (10)
- Rhodium(I) complexes with the polydentate ligand 3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazole (1991) (10)
- Rhodium complexes of 4,5-dicyano-1,2,3-triazole (1988) (10)
- Chiral octahedral phosphano-oxazoline iridium(III) complexes as catalysts in asymmetric cycloaddition reactions (2013) (10)
- Carbon monoxide activation in [Ir(HBPz3)(CO)2]: Formation of carbamoyl complexes by direct reaction with amines (1992) (10)
- Synthesis, characterization, and reactivity of rhodium carboxylate dimers [Rh(.mu.-OOCCR3)(CO)(PCy3)]2 (R = H, F). X-ray crystal structure of [Rh2(.mu.-OOCCH3)(.mu.-.eta.1:.eta.2-C2Ph)(CO)2(PCy3)2] (1993) (10)
- REVERSIBLE FORMATION OF RAFTLIKE ORGANOIMIDOTETRARHODIUM CLUSTERS BY THE MIGRATION OF RHLN+ FRAGMENTS (1996) (10)
- Degradation and Oxidation of 1,1,1-Trichloroethane-Mediated Rhodium Compounds. A New Entry in the Synthesis of Bridging Vinylidene and .eta.1-Chlorovinyl Complexes (1994) (10)
- Synthesis and x-ray structure of the heterotrinuclear complex [Pd{(μ-Cl)(η2-μ-P(O)(OMe)2)Rh(cod)}2]. An unusual bridging coordination mode involving phosphonate ligands (1988) (10)
- Dicarboxylate rhodium complexes with diolefins and carbon monoxide (1985) (10)
- Synthesis and nuclear magnetic resonance studies of some ethylene and ethyltris(pyrazolyl)boratoiridium complexes (1993) (10)
- Hydrogenation catalysts based on pentamethylcyclopentadienyl rhodium complexes with pyrazole-type ligands (1987) (10)
- Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening. (2013) (10)
- Reaction of [Rh2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2] with [M(PPh3)]+(M = Au, Ag, or Cu): formation of unusual 44-electron Rh2M clusters. Crystal structure of [Rh2{µ-Au(PPh3)}{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]ClO4·2CH2Cl2 (1989) (10)
- Synthesis, reactivity and catalytic activity of [RuH(η1-OCMe2)(CO)2(PPri3)2]BF4 (1995) (10)
- Reactions of [IrH2(Me2CO)(Hpz)(PPh3)2]BF4 with alkynes: synthesis of new hydride-vinyl iridium(III) complexes (1994) (10)
- New dinuclear and heterotrinuclear complexes containing the M2(μ-az) (μ-PPh2) core (MRh or Ir; az = azolate) (1996) (10)
- Synthesis and characterization of new hydridoiridium complexes containing carboxylate ligands (1994) (10)
- Hydroformylation of oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorus donor ligands (2009) (10)
- Addition of H2SiPh2 to Ir(acac)(.eta.2-CH3O2C-C.tplbond.C-CO2CH3)(PR3): Synthesis and Characterization of [cyclic] Ir(acac){C[CH(OCH3)OSiPh2]:CHCO2CH3}(PR3) (R = CHMe2, cyclohexyl) (1995) (10)
- Duroquinonerhodium(I) complexes. Crystal structure of [Rh(DQ)(C6H5Me)]PF6 (1985) (9)
- Polynuclear rhodium(I) complexes with 3,3′,5,5′-tetramethyl-4,4′-bipyrazole and 4,4′-methylen-bis(3,5-dimethylpyrazole) (1982) (9)
- Modification of [8,8,8-(H)(PPh 3)2-9-(Py)-nido -8,7-RhSB 9H 9], Py = NC 5H 5, with monodentate phosphines: Reactivity and mechanistic insights (2012) (9)
- CH activation of methyl vinyl ketone in Ir(acac){η2-CH2CHC(O)CH3}(PCy3) (1998) (9)
- Synthesis and structure of chiral-at-metal complexes with the ligand (S) -2 -[ (Sp) -2 -(diphenylphosphino )ferrocenyl ] -4 -isopropyloxazoline (2006) (9)
- Synthesis of paramagnetic tetranuclear rhodium and iridium complexes with the 2,6-pyridinedithiolate ligand. Redox-induced degradation to diamagnetic triiridium compounds. (2001) (9)
- Arene carbonyl rhodium(I) complexes (1982) (9)
- Metal–Nitroalkene and aci-Nitro Intermediates in Catalytic Enantioselective Friedel–Crafts Reactions of Indoles with trans-β-Nitrostyrenes (2014) (9)
- Synthesis and reactivity of mono- and hetero-nuclear rhodium(I) or iridium(I) complexes with 2-(2′-pyridyl)benzimidazole (1983) (9)
- Synthesis of [M(η2-C2Ph2)(CO)(PiPr3)2] (MOs or Ru) and X-ray crystal structure of the osmium derivative (1994) (9)
- Diolefin rhodium(I) complexes with tropolone and related ligands (1981) (9)
- New rhodium(I) complexes with the bridging 1,8-naphthyridine-2-one ligand (1984) (9)
- Pyridinethiolate Titanocene Metalloligands and Their Self-Assembly Reactions To Yield Early–Late Metallamacrocycles (2016) (9)
- Binuclear pentamethylcyclopentadienyl dirhodium complexes with pyrazolato and diphenylphosphido bridging ligands (1994) (9)
- Pentamethylcyclopentadienylrhodium complexes with the pyridazine ligand. Molecular structure of [{Rh(C5Me5)}2(µ-Cl)2(µ-pydz)][ClO4]2·H2O (pydz = pyridazine) (1986) (9)
- Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine (2003) (9)
- Oxidative-addition reactions of Mel or CH2I2 to [M2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2](M = Rh or Ir) complexes. X-Ray structure of [Ir2(µ-pz)(µ-SBut)(µ-CH2)I2(CO)2{P(OMe)3}2](pz = pyrazolate) (1991) (9)
- Preparation and properties of new triply-bridged di-μ-pyrazolate (μ-carbonyl)dirhodium complexes with pentamethylcyclopentadienyl and diphosphine ligands (1986) (9)
- Hydroformylation catalysis by a [Rh(NBD)Cl]2/PPh3 system (1978) (9)
- Coordination features of a hybrid scorpionate/phosphane ligand exemplified with Iridium. (2008) (9)
- Dinuclear rhodium(I) compounds containing diolefins and the 1,6-bis(2′-benzimidazolyl)-2,5-dithiahexane ligand (1983) (9)
- Synthesis and Characterization of the Allenylidene Compounds [Ir(diene)(CCCPh2)(PR3)]BF4 (diene = 1,5-Cyclooctadiene, PR3 = PCy3; diene = Tetrafluorobenzobarrelene, PR3 = PCy3, PiPr3): The First Mixed-Ligand Complexes of the Type [Ir(diene)L(PR3)]+ Containing an Unsaturated η1-Carbon Ligand (1997) (9)
- A DFT and crystallographic reinvestigation of the [L2RuC2B7H9] and [L3RuC2B7H9] ‘hypercloso’ and closo systems (2011) (9)
- Heterodinuclear Iridium Cyclooctadiene Complexes with the [(η5-C5H5)Fe(η6-(1,1-di(2-propenyl)-3-butenyl)benzene)]+ Ligand (2002) (9)
- Novel gem‐Dithiolato‐Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry (2007) (9)
- Reactivity of rhodium(III) complexes containing chelating pentachlorophenyl ligands. Molecular structures of fac-[Rh(C6Cl5)3(py)] and mer-[Rh(C6Cl5)3(tBuNC)3] (2000) (8)
- Steric Effects in the Oxidative Addition of MeI to a Sulfido-Bridged ZrRh2 Early–Late Heterobimetallic Compound (2012) (8)
- Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro amino acid derivatives catalysed by iridium complexes (1988) (8)
- Proton-assisted hydrogen activation on polyhedral cations. (2013) (8)
- Weak intermetallic bonding in unusual trinuclear complexes: crystal structure of [Rh3(µ3-tz)(µ2-Cl)Cl(η4-tfb)(CO)4]·½CH2Cl2 and [Rh3(µ3-tz)(µ2-Cl)Cl(η3-C3H5)2(CO)4]·½C2H4Cl2(Htz = 1,2,4-triazole; tfb = tetrafluorobenzonarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene) (1984) (8)
- Bioorganometallic chemistry: Part 15. A novel molecular recognition process of host, trans-[Cp*Rh(η1(N3)-1-methylcytosine)(μ-OH)]2(OTf)2, with l-aromatic amino acid guests: selective hydrogen bonding to the μ-OH groups and the 1-methylcytosine ligands (2003) (8)
- Reversible opening of the triangular structure of a sulfido-bridged ZrRh2 early-late heterobimetallic complex induced by Bis-(diphenylphosphino)methane (2007) (8)
- From Methyl to Acetyl Complexes. An Example of Alkyl Migration in Heterotrinuclear Systems. Crystal and Molecular Structure of [{Rh(.mu.-pz)(.mu.-StBu)I(COMe)P(OMe)3}2Pd] (1995) (8)
- Cationic rhodium(I) thiocarbonyl complexes with triphenylphosphine and n-donor ligands (1978) (8)
- Heteronuclear and heterovalent diphenylphosphido-bridged complexes of rhodium, iridium and ruthenium. Crystal structure of [(C5Me5)ClRh(μ-Cl)(μ-PPh2)Rh(COD)]•Et2O (COD = 1,5-cyclooctadiene) (1991) (8)
- Hydride–Rhodium(III)-N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C–H Activation (2019) (8)
- Synthesis of the first metal dihydrogen M(.eta.2-H2) complexes containing sulfur-donor ligands (1993) (8)
- Rhodium(I) and iridium(I) complexes of 2,2′-dipyridylamine and its deprotonated form (1986) (8)
- C-NH2 bond formation mediated by iridium complexes. (2014) (8)
- Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene) (1984) (8)
- Bimetallic reactivity: unusual change in the coordination mode of the bridging ligands arising from an oxidative addition process (1994) (8)
- An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane. (2010) (8)
- 2-Pyridonate (Opy) rhodium(I) carbonyl complexes. Crystal structure of the unusual tetranuclear complex [Rh4(µ-Opy)4(µ-CO)2(CO)4] (1987) (8)
- Synthesis of trinuclear complexes with mixed bridging ligands. X-Ray structure of [Pd{Rh(µ-pz)(µ-SBut)(CO)2}2](pz = pyrazolate) (1991) (8)
- Preparation and reactivity of dinuclear complexes having the M2(μ-Pz)(μ-SBut)(μ-dppm) core (M=Rh, Ir; Pz=pyrazolate) (1990) (8)
- Stereoselective oxidative-addition reaction of molecular iodine and mercury(II) halides to rhodium dithiolate compounds. Crystal structure of [Rh2{µ-S(CH2)2S}Cl2(CO)2(PPh3)2] (1994) (8)
- Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates (2018) (8)
- The unexpected synthesis of rhodium(I) complexes with the 1-( 2 ′ -pyridyl)-3-oxo-1-propenoxide anionic ligand (2002) (8)
- Mechanistic Aspects of Dihydrogen Activation and Catalysis by Dinuclear Complexes (2001) (8)
- Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant. (2016) (8)
- Facile two-electron reduction of a closo-rhodathiadecaborane. (2012) (8)
- Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/Antimony Complex Featuring Pyridine-2-Thiolate Ligands. (2017) (8)
- Rhodium(I) and iridium(I) π-arene complexes of indole and of N-indolylgold(I) derivatives. X-ray structure of [(Me3TFB)Rh(η6-HIn)]ClO4 (TFB = tetrafluorobenzobarrelene) (1983) (8)
- Chemical evidence of polynuclear intermediates in a ligand redistribution equilibrium between dinuclear rhodium complexes. X-ray structure of [Rh2(μ-bzta)2(CO)3(PPh3)] (bzta = benzothiazole-2-thiolate) (1993) (8)
- Dinuclear pyridine-4-thiolate-bridged rhodium and iridium complexes as ditopic building blocks in molecular architecture. (2014) (8)
- Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate) (1986) (7)
- Ein paramagnetischer, einkerniger metallorganischer Iridium(II)-Komplex: [Ir(C6Cl5)2(cod)]† (1992) (7)
- Diiridium(II)-Komplexe durch lichtunterstützte oxidative Additionsreaktionen: Struktur eines stabilen zweikernigen Iodo(iodmethyl)iridium(II)-Komplexes† (1987) (7)
- Synthesis of the homoleptic rhodium(III) complex [Rh(C6Cl5)3]. Molecular structures of [Rh(C6Cl5)3] and [Rh(C6Cl4–C6Cl4)(C6Cl5)(SC4H8)2] (1998) (7)
- Reversible Small‐Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters (2017) (7)
- Enantioselective Diels–Alder Reactions Catalyzed by Well-Defined Arene–Ruthenium Complexes. Relationship between Catalyst Structure and Enantioselectivity (2011) (7)
- Vinylidene-based polymers by Rh(I)-NHC catalyzed thiol–yne click polymerization: synthesis, characterization and post-polymerization modification (2018) (7)
- Thiocarbonylrhodium complexes with pyrazolate-type ligands (1981) (7)
- Synthesis and characterization of an unusual heterobridged di-rhodium complex. X-ray molecular structure of [Rh2(μ-pz)2I2(CO)2(μ-dppm)] (1985) (7)
- Di(μ-amido)dirhodium-Komplexe und Struktur von [Rh2(μ-(NH)2naphth)I2(CO)2(PPh3)2] (1984) (7)
- Reactions of 11-vertex rhodathiaboranes with HCl: synthesis and reactivity of new Cl-ligated clusters. (2013) (7)
- CO adsorption on rhodium(i) and on metallic rhodium supported on titanium dioxide (1990) (7)
- Hydroformylation of Hex-1-ene by a Dinuclear gem-Dithiolato-bridged Rhodium Catalyst Under CO/H2O Conditions (2009) (7)
- Preparation and structural studies of diphenylthiophosphinito rhodium(III) complexes. X-ray structure analysis of [{(C5Me5)Rh}2(µ-Cl)2(µ-Ph2PS)][BPh4] (1989) (7)
- Diolefin cationic rhodium complexes with sulfur donors. X-ray structure of [Rh(NBD)2(SEt2)]CIO4 (1983) (7)
- Tetra- and tri-nuclear rhodiumpalladium complexes with the 1,2,4-triazolate ligand. Crystal structure of (η3-C3H5)2Pd2Rh2(μ3-tz)2Cl2(CO)4 (1985) (7)
- Preparation and Properties of RhI and IrI Ethylene Complexes Containing the Chiral P,N-Chelate Ligand (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline (2002) (7)
- Neue anionische Arylkomplexe von RhIII: [Rh(C6F5)5]2○- und [Rh(C6F5)4(CO)2]○- (1988) (7)
- Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: its role in the catalytic hydrosilylation of ketones (2015) (7)
- Dinuclear Phosphine-Amido [Rh2(diene){μ-NH(CH2)3PPh2}2] Complexes as Efficient Catalyst Precursors for Phenylacetylene Polymerization (2019) (7)
- Syntheses and characterization of binuclear Rh2, Ir2 and RhIr complexes containing dimethyl phosphonate and pyrazolate bridging ligands (1996) (7)
- Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium: I. Characterization of isomers by H,H-COSY NMR spectroscopy (1993) (7)
- Tris(pentafluorophenyl) neutral and anionic five-co-ordinate complexes of rhodium(III). Crystal structures of [Rh(C6F5)3(PEt3)2] and [Rh(C6F5)3(AsPh3)2] (1990) (7)
- Hydroformylation of 1-heptene by a [Rh(NBD)Cl]2/PPh3 system. A kinetic approach (1982) (6)
- Binuclear Di-μ-hydroxo- and diμ-methoxo-pentamethylcyclopentadienyl derivatives of rhodium and iridium with pyridine type ligands. Crystal structure of [(C5Me5)Rh(py)2(μ-OH)2][CIO4]2 (py = pyridine) (1986) (6)
- Tris(diphenylthiophosphinoyl)methanide as tripod ligand in rhodium(III), iridium(III) and ruthenium(II) complexes. Crystal structures of [(η5-C5Me5)Ir{η3-(SPPh2)3C-S,S′,S″}]BF4 and [(η6-MeC6H4Pri)Ru{η3-(SPPh2)3C-S,S′,S″}]BPh4 (1997) (6)
- Monocarbonyl cationic rhodium(I) complexes (1981) (6)
- Neuartige neutrale und anionische Rhodium-Komplexe mit Imidoliganden† (1996) (6)
- Different Reactivity Patterns in Dinuclear Pyrazolate-Bridged Complexes: Stereoselective Formation of Ketonic Carbonyls (2000) (6)
- Diastereoselective formation of chiral iridium hydrides containing the chiral P,N-chelate ligand (4S)-2-(2-(diphenylphosphino)phenyl)-4-isopropyl-1,3-oxazoline. (2002) (6)
- Formation of a dithiophosphinate rhodium(III) complex from the unstable three-membered ring species [(η5-C5Me5)(η1-PSPh2)RhPh2PS]. Crystal structure of [(η5-C5Me5)(η1-PSPh2)RhPh2SPS] (1988) (6)
- Trinuclear mixed-valence complexes with the linear [Rh3]4+ core (1989) (6)
- Pyrazolate A-frame rhodium complexes. Crystal structures of [Rh2(µ-dmpz)(CO)2(µ-dppm)2][ClO4] and [Rh2(µ-dmpz)I2(CO)2(µ-dppm)2][ClO4] (1985) (6)
- Hydridorhodathiaboranes: Synthesis, characterization, and reactivity (2014) (6)
- Preparation and Oxidative Addition Reactions of 8-Oxyquinolate Rhodium(I) Complexes (1986) (6)
- Preparation of rhodium–phyllosilicate catalysts without leaching in liquid‐phase 1‐hexene hydrogenation (1989) (6)
- Synthesis and reactivity of binuclear complexes having the Rh(μ-pz)(μ-SR)Rh framework (pz = pyrazolate, R = But, Ph) (1992) (6)
- Intermolecular hydroamination versus stereoregular polymerization of phenylacetylene by rhodium catalysts based on N–O bidentate ligands (2014) (6)
- NH3-promoted ligand lability in eleven-vertex rhodathiaboranes. (2014) (6)
- The Anions [Cptt2Zr(μ-S)2M(CO)2]- (M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds† (2007) (6)
- Cationic complexes of rhodium(I) with phenanthroline type ligands (1982) (6)
- Prototropien in (Pentamethylcyclopentadienyl)iridium‐Komplexen mit Pyrazol‐Liganden (1986) (6)
- Reactivity of the Chiral Metallic Brønsted Acid [(η6-p-MeC6H4iPr)Ru(κ3P,O,O′-POH)][SbF6]2 (POH = (SC1,RC2)-Ph2PC(Ph)HC(OH)HCH2OMe) toward Aldimines (2014) (6)
- Heterogenized rhodium complexes as hydrogen transfer catalysts (1982) (6)
- Reactivity of binuclear pyrazolate-bridged rhodium complexes with isocyanides. Molecular structure of [Rh2(µ-pz)I2(CNBut)2–(µ-Ph2PCH2PPh2)2]BF4(pz = pyrazolate) (1989) (6)
- Preparation and reactions of five-coordinate Rh(NBD)[P(p-Cl-C6H4)3]2X complexes (1979) (6)
- P-CYMENE RUTHENIUM(II) COMPLEXES WITH 3-SUBSTITUTED PYRAZOLE LIGANDS (1994) (5)
- Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe2Ph catalyzed by iridium complexes. (2019) (5)
- Homo- and hetero-bridged mixed-valence dinuclear complexes which contain the fragment ‘Rh(C6F5)3’ (1996) (5)
- INFLUENCE OF THE HETEROCYCLIC RING ON THE ASYMMETRIC SYNTHESIS OF β-HETARYLALANINES BY HOMOGENEOUS CATALYTIC HYDROGENATION (1984) (5)
- Iridium-Catalyzed 1,3-Dipolar Cycloadditions (2011) (5)
- Inventing Reactions (2013) (5)
- Intramolecular C-H oxidative addition to iridium(I) in complexes containing a N,N'-diphosphanosilanediamine ligand. (2014) (5)
- Trinuclear aggregates of rhodium and iridium supported by thiolate bridges: synthesis and crystal structure (1992) (5)
- Π-Cyclopentadienyl (carvone) iridium(I) (1977) (5)
- Energetics of the oxidative addition of I2 to [Ir(Μ-L)(CO)2]2 (L=StBu, 3,5-Me2pz,7-aza) complexes. X-ray structures of Ir(Μ-StBu)(I)(CO)2]2 and [Ir(Μ-3,5-Me2pz)(I)(CO)2]2 (1996) (5)
- Synthesis, Reactivity, Molecular Structure, and Catalytic Activity of the Novel Dichlorodihydridoosmium(IV) Complexes OsH2Cl2(PR3)2 (PR3: P- iPr3, PMe-tBu2). (1991) (5)
- Synthesis and catalytic activity of some cationic rhodium(I) complexes with substituted quinolines (1982) (5)
- Amides of rhodium and iridium derived from 2-aminothiophenol and diaminonaphthalene: X-ray crystal structure of Rh2(μ-1,8-(NH)2C10H6)(CO)4 (1989) (5)
- Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues. (2001) (5)
- Reactions of IrXL2(PR3)(X = Cl, OTf; L2= TFB, 2CO) with HSnR3(R = Ph, nBu) (1997) (5)
- Iridium–NSiN catalyzed formation of silylphosphinecarboxylates from the reaction of CO2 with P(SiMe3)R2 (R = Ph, Cy) (2017) (5)
- The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond (1994) (5)
- Tetranuclear [Rh4(mu-PyS2)2(diolefin)4] complexes as building blocks for new inorganic architectures: synthesis of coordination polymers and heteropolynuclear complexes with electrophilic d8 and d10 metal fragments. (2004) (5)
- Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]– as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2 (1992) (5)
- Bi-edge condensation of imido–rhodium clusters leading to novel planar hexametallic structures (1999) (5)
- Synthesis of tetranuclear rhodium and iridium complexes directed by 6-mercaptopyridin-2-ol: electrochemical behavior, chemical oxidation, and coordination chemistry. (2009) (5)
- Synthesis, structure, and kinetic studies on [RuCl2(NCCH3)2(cod)] (2012) (5)
- Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes (2019) (5)
- Synthesis and reactions of phenylacetylide iridium(I) and rhodium(I) complexes (1990) (5)
- Rhodium- und Iridium-Pyrazolatblau (1998) (5)
- Pentafluorophenyl compounds of rhodium(III) with bidentate phosphorus or nitrogen ligands (1992) (5)
- Binuclear pentamethylcyclopentadienyl rhodium(III) compounds with pyrazolate and thiolate bridging ligands (1998) (4)
- Rhodium–Rhodium Bonds in Edge‐Sharing Coplanar Dinuclear Complexes (2000) (4)
- N-indolyltriarylphosphinegold(I) derivatives as η6-arene ligands in pentamethylcyclopentadienylrhodium(III) complexes. X-ray structure of [(C5Me5)Rh(μ-In)AuP(C6H5)3](ClO4)2·CH2Cl2 (1983) (4)
- Methylene- and diamidonaphthalene-bridged diiridium(III) complexes (2003) (4)
- Mono- and dinuclear rhodium(I) complexes containing the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole (1992) (4)
- C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds (2008) (4)
- Synthesis and structure of the unusual 30-electron homobinuclear vinylidene-bridged rhodium complexes [Rh2(.mu.-OOCCH3)(.mu.-C:CHR)(CO)2(PCy3)2]BF4 (1993) (4)
- Gezielte Synthese von Early‐late‐Zr‐Ir‐Rh‐Heterotrimetallverbindungen durch Metallaustausch (1999) (4)
- Synthesis and characterization of the alkoxycarbonyl complexes [(C5Me5)M(µ-pz)(µ-I)2Rhl(CO2R)(CO)](M = Rh, R = Me or Et; M = Ir, R = Me; pz = pyrazolate). Molecular structure of [(C5Me5)Ir(µ-pz)(µ-I)2Rhl(CO2Me)(CO)] (1990) (4)
- The synthesis and structure determination of a novel η6-arenerhodium(III) complex, [(Me2SiC6H5)4Rh2H2], and the synthesis of [(Me2SiC6H5)4Ir2H2] (1987) (4)
- Rhodium(I)-NHC Complexes Bearing Bidentate Bis-Heteroatomic Acidato Ligands as gem-Selective Catalysts for Alkyne Dimerization. (2020) (4)
- Binuclear Iridium Complexes in Catalysis (2015) (4)
- Bond Activation and Catalysis (2013) (4)
- π-Cyclopentadienyl(butadiene)iridium(I) (1977) (4)
- Experimental and Computational Studies on the Reactivity and Binding Mode of Thiophene with N-Heterocyclic Carbene Iridium Complexes (2016) (4)
- The coordination behaviour of the squarate anion in rhodium(I) chemistry (1997) (4)
- Homogeneous Transfer Hydrogenation Catalysed by Metal Complexes (1994) (4)
- Synthesis and characterization of new 10- and 12-vertex CO-ligated metallathiaboranes (2012) (4)
- Recent developments on hydride iridium triisopropylphosphine complexes: [IrH2(NCCH3)3(PiPr3)]BF4 as hydrogenation catalyst (2003) (4)
- Five coordinate complexes of the type Rh(SnCl3)(NBD)L2 (1983) (4)
- Synthesis, X-ray Structure, and Catalytic Activity of the Unusual Complex [Ir(TFB)(PiPr3)2]BF4(TFB = Tetrafluorobenzobarrelene) (1997) (3)
- Reversible Bildung eines Organoimido‐tetrarhodium‐Clusters mit floßartiger Struktur durch Wanderung eines RhLn+‐Komplexfragmentes (1996) (3)
- Spectroscopic and electrochemical properties of Rh(I) complexes containing diene (norbornadiene or cyclooctadiene) and diimine (bipyrimidine) type ligands (1990) (3)
- Kinetic and spectroscopic study of the hydrogen-transfer reaction from 2-propanol to cyclohexanone catalyzed by [IrH2(pz)(Hpz)(PPh3)2] (Hpzpyrazole) (1994) (3)
- Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes (2015) (3)
- Chapter 3:Hydrogenation Reactions (2006) (3)
- Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η(2)-C2H4)(PPh3)RhSB8H7(PPh3)]. (2015) (3)
- Hydroxymethylpyridine containing half-sandwich complexes of Rh(III), Ir(III) or Ru(II). (2014) (3)
- Amide rhodium and iridium complexes derived from Z-N-phenyl,β-(amino)-4-methylstyryldiphenylphospha-1 λ5-azene (1987) (3)
- Methylpyridine and methoxypyridine cationic rhodium(I) complexes with norbornadiene (1980) (3)
- 2,5‐Norbornadiene C–C Coupling Reactions Mediated by Iridium Complexes (2016) (3)
- Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes (1982) (3)
- Unusual cationic rhodathiaboranes: synthesis and characterization of [8,8,8-(H)(PR3)2-9-(Py)-nido-8,7-RhSB9H10]⁺ and [1,3-μ-(H)-1,1-(PR3)2-3-(Py)-isonido-1,2-RhSB9H8]⁺. (2014) (3)
- The (NHEt3)[Rh(C6Cl2O4)(CO)2] complex: an example of the adverse counterion influence in the formation of metallic stacks (1999) (3)
- Rhodium Catalysts for C–S Bond Formation (2016) (3)
- [1,1-(η(2)-dppe)-3-(NC5H5)-closo-1,2-RhSB9H8]: conformational lability and reactivity with H2 upon protonation. (2015) (3)
- Exclusive formation of cis-PhCH=CH(SiEt3) by addition of HSiEt3 to PhC≡CH catalyzed by RuHCl(CO)(PiPr3)2 (1993) (3)
- Thiocarbonyl rhodium complexes with tricyclohexylphosphine and other nitrogen and phosphorus donor ligands (1980) (3)
- New thiocarbonyl iridium and rhodium complexes with azolate type ligands (1985) (3)
- A Bimetallic Iridium(II) Catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3‐bis(2,6‐diisopropylphenylimidazol‐2‐ylidene)) (2015) (3)
- Nematic phases in ionic melts: mesogenic ionic complexes of silver(I) [Erratum to document cited in CA111(16):144535m] (1991) (3)
- Dinuclear pentafluorophenyl compounds of rhodium(III) with anionic bridging ligands. Molecular structures of [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-SCN)2] and [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-CO3)] (1995) (3)
- Reactivity of [TiM2] (M = Rh, Ir) and [TiIr3] early-late heterobimetallic sulfido-bridged clusters (2016) (3)
- Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C-H bonds. (2016) (3)
- C–N Bond Coupling Reactions of Ammonia with Acetone Promoted by Iridium and Rhodium Complexes: Experimental and DFT Studies (2016) (2)
- REACTION OF TETRAMENTHYLFULVENE RHENIUM COMPLEXES (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) WITH ALKYL PHOSPHINES AND TRIMETHYLPHOSPHITE: X-RAY STRUCTURE OF [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I- (2004) (2)
- Reversible Isomerisierung des zweikernigen Komplexes [(η6‐p‐Cymol)RuCl(μ‐pz)2Ir(CO)2] unter Bildung einer Ruthenium‐Iridium‐Bindung (1991) (2)
- Diastereoselective synthesis of chiral octahedral iridium(III) phosphano-oxazoline complexes (2013) (2)
- Selective C—H Bond Functionalization of 2-(2-Thienyl)pyridine by a Rhodium N-Heterocyclic Carbene Catalyst. (2015) (2)
- Rhodium tetraflurobenzobarrelene or trimethyltetrafluorobenzobarrelene complexes with arene ligands. Crystal structures of [Rh(diolefin)(arene)]ClO4, (diolefin = TFB, arene = 1,2,4-C6H3Me3; diolefin = Me3TFB, arene = 1,2,4-C6H3Me3, C6Me6) (1985) (2)
- Synthesis and dynamic behaviour of zwitterionic [M(η(6)-C6H5-BPh3)(coe)2] (M = Rh, Ir) cyclooctene complexes. (2014) (2)
- Hydroformylation of Synthetic Naphtha Catalyzed by a Dinuclear gem-Dithiolato-Bridged Rhodium(I) Complex (2010) (2)
- Comprar Iridium Complexes in Organic Synthesis | Luis A. Oro | 9783527319961 | Wiley (2008) (2)
- 3-Pyridylacetonitrile-ligated 11-vertex rhodathiaboranes: synthesis, characterization, and X-ray crystal structure (2014) (2)
- Ruthenium Catalysts and Fine Chemistry. Edited by C. Bruneau, P. H. Dixneuf (2005) (2)
- Efficient Rhodium‐Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines. (2016) (2)
- Bis(hydrosulfido)-bridged dinuclear rhodium(I) complexes as a platform for the synthesis of trinuclear sulfido aggregates with the core [MRh2(μ3-S2)] (M = Rh, Ir, Pd, Pt, Ru). (2013) (2)
- Hydrogenation in Aqueous Systems (1994) (2)
- Benzene-1,2-dithiolate-induced assembly of reactive iridium fragments into tetranuclear octahydride complexes ☆ (2004) (2)
- Divergent Reactivity of 2-Vinylpyridine and 1-Vinylpyrazole in Rhodium-Phosphine Systems: C-H Activation and Dinuclear Chemistry (2017) (2)
- Local structure of Iridium organometallic catalysts covalently bonded to carbon nanotubes. (2016) (2)
- Dinuclear rhodium-rhodium and rhodium-palladium complexes with different bridging ligands. Crystal structure of [Rh2(μ-SPPh2)(μ-Cl)(COD)2] (1996) (2)
- Chemists Creating a European Identity through Conferences and Journals. (2016) (1)
- SYNTHESIS, REACTIVITY AND CRYSTAL STRUCTURE OF (RH(C6H5ME)(P(OPH)3)2)CLO4 (1980) (1)
- Iridium catalysts featuring amine-containing ligands for the dehydrogenation of formic acid (2020) (1)
- Pyrazolate iridium complexes as catalyst precursors for the hydroformylation of alkynes (1984) (1)
- Enantioselective catalysts based on the chiral fragment (η5-C5Me5)Ir(Prophos) for Diels–Alder reactions (2014) (1)
- gem-Selective Cross-Dimerization and Cross-Trimerization of Alkynes with Silylacetylenes Promoted by a Rhodium-Pyridine-N-Heterocyclic Carbene Catalyst. (2015) (1)
- Synthesis and reactivity at the Ir-MeTpm platform: from κ1-N coordination to κ3-N-based organometallic chemistry. (2019) (1)
- Tris(pentafluorophenyl) Neutral and Anionic Five‐Coordinate Complexes of Rhodium(III). Crystal Structures of (Rh(C6F5)3(PEt3)2) and (Rh(C6F5)3(AsPh3)2). (1990) (1)
- Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2 = 2,6-dimercaptopyridine) (2000) (1)
- A Synthon for a 14‐Electron Ir(III) Species: Catalyst for Highly Selective β‐(Z) Hydrosilylation of Terminal Alkynes. (2013) (1)
- Chiral Rhodium Complexes as Catalysts in Diels-Alder Reactions. (1996) (1)
- Hydrogen Activation in Biological Systems (1994) (1)
- Molecular metal clusters (1999) (1)
- Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning. (2016) (1)
- Coordination of H2 and O2 to (OsHCl(CO)(PiPr3)2): A Catalytically Active M(η2-H2) Complex. (1989) (1)
- Pyrazolate‐Bridged Ruthenium(I) Carbonyl Complexes (1997) (1)
- Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis (2009) (1)
- Celebrating the 150th Anniversary of the Periodic Table of Chemical Elements: 5th EuChemS Inorganic Chemistry Conference (2019) (1)
- New Editorial Board Members: Refreshing our Catalyst! (2013) (1)
- Binuclear Dirhodium(I) Complexes with Phenyl(2-pyridyl)amido Ligands. Crystal and Molecular Structure of ((Rh(μ-N,N′-PhNPy)(nbd))2)·H2O (nbd: 2,5-norbornadiene). (1987) (0)
- Reactivity of the parent amido complexes of iridium with olefins: C-NH2 bond formation versus C-H activation. (2017) (0)
- Selective C – H Bond Functionalization of 2-( 2-Thienyl ) pyridine by a Rh-NHC Catalyst (2016) (0)
- Mononuclear Rhodium(I) Complexes of 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole. Crystal Structure of (Rh(CO)2(NH2bpt))ClO4. (1987) (0)
- Novel Imido Rhodium Clusters: Synthesis and Perspectives (2008) (0)
- [RhCl(CO)(PPh3)]2. A precursor for the synthesis of cationic rhodium complexes with nitrogen donor ligands (1981) (0)
- Nematic Phases in Ionic Melts: Mesogenic Ionic Complexes of Silver(I). (1990) (0)
- 0 cc 00525 h Rational Design of Efficient Rhodium Catalysts for the Anti-Markovni-kov Oxidative Amination of Styrene (2012) (0)
- Synthesis and characterization of stable NHC-Rh(III)-alkenyl complexes as key intermediate in the aminocarbonylation of alkynes (2018) (0)
- Tri-, Bi- and Mononuclear Rhodium Complexes with the Anionic Polydentate Ligands 1,8-Naphthyridine-2-one and 5,7-Dimethyl-1,8-naphthyridine-2-one. (1987) (0)
- New Methoxo-, Hydroxo-, and Pyrazolate-bridged Complexes of Rhodium(III). Crystal Structures of [{Rh(C5Me5)2}(mpz)(OMe)2][ClO4] (mpz = 3-methylpyrazolate), [{Rh(C5Me5)}2(Hdmpz)2(OH)2][BF4]2 (Hdmpz = 3,5-dimethylpyrazole), and [{Rh(C5M (1984) (0)
- The local structure of Rh in new catalysts based on Rhodium N-heterocycled carbenes located on graphene surfaces (2018) (0)
- (PR 3 ) 2 -3-(Py)-isonido-1,2-RhSB 9 H 8 ) + (2014) (0)
- CCDC 770467: Experimental Crystal Structure Determination (2011) (0)
- Heterotrinuclear Angular Aggregates of Rhodium, Iridium, Palladium and Group 11 Metals. X-Ray Structure of the Complex ((cod)2Rh2(μ3- C7H4NS2)2Ag(O2ClO2)) (cod: cycloocta-1,5-diene). (1991) (0)
- Structural aspects of pyridyl-pyrazole dinuclear Rh and Ir complexes (2005) (0)
- Catalytic Hydrodechlorination of Benzyl Chloride promoted by Rh-NHC Catalysts (2015) (0)
- Pentamethylcyclopentadienylrhodium Complexes with the Pyridazine Ligand. Molecular Structure of ((Rh(C5Me5))2(μ-Cl)2(μ-pydz))(ClO4)2·H2O (pydz = pyridazine). (1987) (0)
- The Chemical and Catalytic Reactions of Hydrido-chloro-carbonylbis(triisopropylphosphine)osmium(II) and Its Major Derivatives (2001) (0)
- 2003, a very special year for Spanish chemistry (2003) (0)
- CCDC 770465: Experimental Crystal Structure Determination (2011) (0)
- Reaction of (Rh2(μ-1,8-(NH)2C10H6)(CO)2(PPh3)2) with (M(PPh3))+ (M: Au, Ag, or Cu): Formation of Unusual 44-Electron Rh2M Clusters. Crystal Structure of (Rh2(μ-Au(PPh3))(μ-1,8-(NH)2C10H6)(CO)2(PPh3)2)ClO4·2 CH2Cl2. (1989) (0)
- New Rhodium(I) Complexes with the Bridging 1,8-Naphthyridine-2-one Ligand. (1984) (0)
- Correction to: Iridium Catalysts for Organic Reactions (2021) (0)
- Rhodium Complexes of the Binucleating Ligands Pyridine-2-thiolate and Benzothiazole-2-thiolate. Crystal Structures of ((Rh(μ-SC5H4N)(CO)2)2) and ((Rh(μ-SC5H4N)(tfbb))2)·Me2CO (tfbb: tetrafluorobenzobarrelene). (1989) (0)
- Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR sub 3 ) sub 2 (PR sub 3 = PMe-t-Bu sub 2 and P-i-Pr sub 3 ) (1989) (0)
- CCDC 770463: Experimental Crystal Structure Determination (2011) (0)
- Synthesis of Titanium and Zirconium Complexes with 2‐Pyridonate and 2, 6‐Pyridinedithiolate Ligands (2015) (0)
- Hydroxo-pentamethylcyclopentadienylrhodium(III) complexes with the pyridazine ligand (1986) (0)
- Determination of the free activation energy for the breaking of the 31P_107(109) Ag bond in [( $-p-cymene)Ru( CL-pz) ,Ag(PPh,)] (2001) (0)
- [ 1 , 1-( η 2-dppe )-3-( NC 5 H 5 )-closo-1 , 2-RhSB 9 H 8 ] : conformational lability and reactivity with H 2 upon protonation † (2018) (0)
- HC – Ir ( III ) catalyst for the silylation of aromatic C – H bonds : substrate survey and mechanistic insights † (2017) (0)
- Structural aspects of chiral-at-metal complexes: on the origin of stereoselectivity (2007) (0)
- 1,2,4-Triazolate (tz) Complexes of Rhodium(I), Iridium(I), and Palladium(II). Crystal Structure of [Rh3(μ3-tz)(μ-Cl)Cl(η4-tfbb)(CO)4] . 0.5 CH2Cl2 (tfbb: tetrafluoro-benzobarrelene), a Trinuclear Complex with Extended Metal-Metal Inte (1986) (0)
- Enantioselective Friedel—Crafts Alkylations Catalyzed by Well‐Defined Iridium and Rhodium Half‐Sandwich Complexes. (2011) (0)
- Intra- and inter-molecular interactions for the understanding of stereoselective catalytic properties of chiral metal complexes (2015) (0)
- Syntheses and X-ray structures of [Rh2(μ-SC5H4N)2(tfb)2]•Me2CO and [Rh3(μ-SC5H4N)2(CO)6][ClO4]•1/2CH2Cl2(tfb=tetrafluorobenzobarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene): two unusual Bi- and trinuclear complexes of the pyridine-2-thiolato ligand showing three different co-ordina (1986) (0)
- CCDC 770462: Experimental Crystal Structure Determination (2011) (0)
- Synthesis , structure and kinetic studies on [ RuCl 2 ( NCCH 3 ) 2 ( cod ) ] (2016) (0)
- Trinuclear Mixed-Valence Complexes with the Linear (Rh3)4+ Core. (1989) (0)
- BISIMIDAZOLE (H2BIM) AND BIBENZIMIDAZOLE η3-ALLYLIC COMPLEXES OF PALLADIUM(II). MONO- AND TETRANUCLEAR PALLADIUM(II) AND HETERONUCLEAR PALLADIUM(II)-RHODIUM(I) COMPLEXES. CRYSTAL STRUCTURE OF (PD4(η3-C3H5)4(μ-BIM)2).CH2CL2 (1983) (0)
- Synthesis and Characterization of New Iridium Complexes with the (4S)‐2‐[2‐(Diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline Ligand that Catalyze Asymmetric Michael Reactions. (2005) (0)
- THIOCARBONYLRHODIUM COMPLEXES WITH TRICYCLOHEXYLPHOSPHINE AND OTHER NITROGEN AND PHOSPHORUS DONOR LIGANDS (1981) (0)
- Catalytic activity of iridium NHC complexes covalently bonded to carbon nanotubes and graphene oxide (2015) (0)
- Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement (2021) (0)
- Dinuclear Pyrazolate-Iridium Hydride Complexes. Crystal Structure of [{Ir(C5Me5)}2(μ-H)2(μ-pz)]BF4(pz: pyrazolate). (1986) (0)
- Is the trans effect an applicable concept in di- and polynuclear metal complexes? (2002) (0)
- IrCl2H(PiPr3)2 as Catalyst Precursor for the Reduction of Unsaturated Substrates. (1993) (0)
- Homogeneous Hydrogenation of Tetrasubstituted Alkene Moieties in Prochiral Didehydro Amino Acid Derivatives Catalyzed by Iridium Complexes. (1988) (0)
- Cover Feature: Homogeneous Catalytic Reduction of CO 2 with Silicon‐Hydrides, State of the Art (ChemCatChem 1/2019) (2019) (0)
- Synthesis and Reactivity of Alkoxy(η4-cycloocta-1,5-diene)iridium(I) and -rhodium(I) M(OR)(cod)(PCy3) Compounds. X-Ray Crystal Structure of the Alkynyl Ir(CCPh)(cod)(PCy3) Complex. (1989) (0)
- Correction to Enantioselective Catalytic Diels–Alder Reactions with Enones As Dienophiles (2016) (0)
- 1.4 – Pyridopyridine Ligands (2003) (0)
- Functionalized carbon nanotubes as support of Iridium-NHC complexes for catalysis applications (2013) (0)
- DINUCLEAR PENTAFLUOROPHENYL COMPOUNDS OF RHODIUM(III) WITH ANIONIC BRIDGING LIGANDS. MOLECULAR STRUCTURES OF P(CH2PH)PH32RH(C6F5)32(MU -SCN)2 AND P(CH 2PH)PH32RH(C6F5)32(MU -CO3) (1995) (0)
- Synthesis and Hydroformylation Reaction of Dinuclear Rhodium(I) Complexes with Mixed Bridging Ligands. X-Ray Structure of (Rh2(μ-pz)(μ-StBu)(CO)2(P(OMe)3)2). (1988) (0)
- Mixed-valence Pyrazolate Rhodium Complexes. Molecular Structure of [(C5Me5)ClRhCl(pz)Rh(tfb)]·CH2Cl2(Hpz: Pyrazole; tbf: Tetrafluorobenzobarrelene) (1986) (0)
- En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond. (2016) (0)
- Pushing the Boundaries of Catalysis (2009) (0)
- Formation of Diiridium(II) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex. (1987) (0)
- Structural analysis of new early-late heterobimetallic tetranuclear metallomacrocycles (2005) (0)
- Oxidative Addition of I2, MeI, and CH2I2 to the Naphthalene-1,8-diamide Bridged Complex (Ir2(μ-1,8-(NH)2C10H6)(CO)2(PPh3)2) (I). X-Ray Crystal Structure of (Ir2I2(μ-CH2)(μ-1,8-(NH)2C10H6)(CO)2(PPh3)2)·CH2Cl2. (1990) (0)
- Rhodium-Catalyzed Polymerization of Phenylacetylene and its Derivatives (2013) (0)
- Enantioselective Hydride Transfer Hydrogenation of Ketones Catalyzed by [(η6-p-Cymene)Ru(aminoacidato)CI] and [(η6-p-Cymene)Ru(aminoacidato)] 3(BF4)3 Complexes. (2000) (0)
- CCDC 1538222: Experimental Crystal Structure Determination (2017) (0)
- η3‐Allyl Rhodium Complexes with Azolate Ligands. Crystal Structures of the Trinuclear 1,2,4‐Triazolate (tz) Complexes (Rh3(μ‐tz)3(η3‐C3H5)6) and (Rh3(μ3‐tz)(μ‐Cl)Cl(η3‐C3H5)2(CO)4)·0.5 C2H4Cl2. (1987) (0)
- Reactivity of Binuclear Pyrazolate-Bridged Rhodium Complexes with Isocyanides. Molecular Structure of (Rh2(μ-pz)I2(CNtBu)2(μ-Ph2PCH2PPh2)2)BF4 (pz: pyrazolate). (1989) (0)
- Homogeneous Hydrogenation in Organic Synthesis (1994) (0)
- Catálisis llama a Catálisis—Catalysis Calls to Catalysis (2013) (0)
- Novel homogeneous Ir-catalysts: Ligand design, applications and mechanisms (2018) (0)
- Rhodium(I) and Iridium(I) Complexes of 2,2′-Dipyridylamine and Its Deprotonated Form. (1986) (0)
- PREPARATION OF CATIONIC COMPLEXES (RH(DIOLEFIN)L2)CLO4 AND THEIR CARBONYLATION REACTIONS (1980) (0)
- Outer-Sphere Ionic Hydrosilylation Catalysis (2014) (0)
- Hydroxylic functionalization of graphene oxides with iridium N-heterocyclic carbenes to be used for catalysts in the hydrogen (2014) (0)
- Hydrosilylation of Phenylacetylene via an Os(SiEt3)(η2‐H2) Intermediate Catalyzed by OsHCl(CO)(PiPr3)2. (1991) (0)
- Title: Reactivity of Ir-NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids Authors: (2017) (0)
- DI(μ-PYRAZOLATO)BIS(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM COMPLEXES. MOLECULAR STRUCTURE OF ((RH(C5ME5)(PZ))2(μ-PZ)2) (PZ = PYRAZOLATO) (1985) (0)
- Iridium-Catalyzed Silylation (2020) (0)
- Convenient Methods for the Synthesis of a Library of Hemilabile Phosphines. (2009) (0)
- Binuclear Rhodium and Iridium Complexes Containing Pentamethylcyclopentadienyl and Pyrazolate Ligands. (1987) (0)
- Activation of a Vinyl Carbon-Hydrogen Bond in a Tris(pyrazolyl)boratoiridium Complex. The X-Ray Crystal Structure of (IrH(HB(pz)3)(σ-C8H13)(η2-C8H14)). (1990) (0)
- Mechanistic studies on rhodium-N-heterocyclic carbene catalysts (2016) (0)
- Tetrazolate Rhodium(I) Complexes. Crystal Structures of the Trinuclear Complexes (Rh3(μ3-ttz)(μ-Cl)Cl(cod)2(CO)2) (ttz: tetrazolate, cod: cycloocta-1,5-diene) and (Rh3(μ3-ttz)(μ-Cl)Cl(CO)6), an Unusual Example of Metal-Metal Interacti (1988) (0)
- PREPARATION, REACTIONS AND CATALYTIC ACTIVITY OF COMPLEXES OF THE TYPE (IR(COD)(P(P-RC6H4)3)2)A (R = CL, F, H, CH3 OR CH3O; A = CLO4- OR B(C6H5)4-) (1980) (0)
- Preparation and X-Ray Structure of [(C5Me5)Rh(μ-pz)2(μ-CO)Rh(dppp)]BPh4(pz: pyrazolate; dppp: 1,3-bisdiphenylphosphinopropane) (1986) (0)
- Corrigendum to “Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline” [J. Organomet. Chem. 691 (2006) 5560–5566] (2008) (0)
- lH-Pyrrolo[2,3-b]pyridine (HL) Ligands in Rhodium(I) and Iridium(I) Chemistry. (1986) (0)
- Correction to: Chapters (2020) (0)
- CCDC 770464: Experimental Crystal Structure Determination (2011) (0)
- CCDC 809837: Experimental Crystal Structure Determination (2011) (0)
- Dinuclear Rhodium(I) Compounds Containing Diolefins and the 1,6-Bis(2′-benzinlidazolyl)-2,5-dithiahexane Ligand. (1983) (0)
- Preparation and X-Ray Structure of a Trinuclear Rhodium Complex with the Polydentate 1,8-Naphthyridine-2-one (Onapy) Ligand: [Rh3(μ3-Onapy)2(CO)2(cod)2](ClO4)·1.5 C2H4Cl2. (1986) (0)
- Unexpected Formal Insertion of a Carbonyl Group into a Heterocyclic N‐ Ir Bond. (1994) (0)
- 2-Pyridonate (Opy) Rhodium(I) Carbonyl Complexes. Crystal Structure of the Unusual Tetranuclear Complex (Rh4(μ-Opy)4(μ-CO)2(CO)4). (1987) (0)
- Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide (2020) (0)
- Catalysis and dynamics and physical properties of metal clusters (1999) (0)
- Preparation and Structural Studies of Diphenylthiophosphinito Rhodium(III) Complexes. X-Ray Structure Analysis of (((C5Me5)Rh)2(μ-Cl)2(μ-Ph2PS))(BPh4). (1990) (0)
- THE DICYCLOPENTADIENYL-GADOLINIUM AND YTTERBIUM CHLORIDES (1975) (0)
- PYRAZOLATE A-FRAME RHODIUM COMPLEXES. CRYSTAL STRUCTURES OF BIS-μ-(BIS(DIPHENYLPHOSPHINO)METHANE)-μ-(3,5-DIMETHYLPYRAZOLATO-N,N′)BIS(# CARBONYLRHODIUM(I)) PERCHLORATE AND BIS-μ-(BIS(DIPHENYLPHOSPHINO)METHANE)-μ-(3,5-DIMETHYLPYRAZOLATO (1985) (0)
- Chemical and Electrochemical One-Electron Oxidation of Diamidonaphthalene-Bridged Complexes; Paramagnetic (Rh2)3+-Containing A Frames. (1989) (0)
- Origin of the Ir-Si bond shortening in Ir-NSiN complexes. (2021) (0)
- CCDC 1538223: Experimental Crystal Structure Determination (2017) (0)
- CCDC 1569683: Experimental Crystal Structure Determination (2018) (0)
- Tetranuclear Complexes as Intermediates in Transannular Oxidative Addition Reactions. Structure of the First Linear Tetrairidium Cluster. (1988) (0)
- PREPARATION AND REACTIONS OF FIVE-COORDINATE HALOBIS(TRIS(P-CHLOROPHENYL)PHOSPHINE)(NORBORNADIENE)RHODIUM COMPLEXES (1979) (0)
- NEW PYRAZOLATE-, HYDROXO- AND METHOXO-BRIDGED COMPLEXES OF RUTHENIUM(II). CRYSTAL STRUCTURE OF ((RU(η-P-MEC6H4CHME2))2(PZ)2(OH))BPH4 (1985) (0)
- Covalent functionalization of graphene oxides for catalysis applications (2013) (0)
- Prototropism in (Pentamethylcyclopentadienyl)iridium Complexes with Pyrazole Ligands. (1987) (0)
- CCDC 809839: Experimental Crystal Structure Determination (2011) (0)
- Effective Fixation of CO 2 by Iridium-Catalysed (2016) (0)
- Mixed-Bridged Bimetallic d8 Complexes. Crystal and Molecular Structure of (η3-C3H5)Pd(μ-pz)(μ-N3)Rh(CO)2, Heterobinuclear Complex with Extended Rh···Rh Interactions. (1987) (0)
- COMPLEXES OF RHODIUM(I) WITH 1,8-NAPHTHYRIDINE AND RELATED LIGANDS. CRYSTAL STRUCTURE OF BIS(μ-1,8-NAPHTHYRIDINE-N,N′)BIS((η-2,5-NORBORNADIENE)RHODIUM(I))(RH-RH) DIPERCHLORATE MONOHYDRATE (1984) (0)
- Synthesis and X-Ray Structure of the Heterotrinuclear Complex (Pd((μ-Cl)(η2-μ-P(O)(OMe)2)Rh(cod))2). An Unusual Bridging Coordination Mode Involving Phosphonate Ligands. (1989) (0)
- Structural aspects of new n -heterocyclic carbene-rhodium catalysts (2011) (0)
- 2,2′-BIBENZIMIDAZOLATE ANIONS AS BRIDGING LIGANDS IN CATIONIC HETERONUCLEAR GOLD(I)-RHODIUM(I) COMPLEXES. CRYSTAL STRUCTURE OF (1,1′-BIS(TRIPHENYLPHOSPHINEAURIO)-2,2′-DIBENZIMIDAZOLE-N3,N3′)(η-CYCLOOCTA# -1,5-DIENE)RHODIUM PERCHLORATE (1983) (0)
- CCDC 1538221: Experimental Crystal Structure Determination (2017) (0)
- Nanomaterials and solid-state cluster chemsitry (1999) (0)
- Un ligando σ-dador/aceptor confuso (tipo L/Z) basado en antimonio en la esfera de coordinación del rodio (2014) (0)
- Di- and Tetra-nuclear Mixed-valence Complexes of Rhodium(III,I) and Rhodium(III) (1986) (0)
- Back Cover: Synthesis of Poly(silyl ether)s by Rhodium(I)–NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis (ChemCatChem 5/2013) (2013) (0)
- Playing around with alkynes and late transition homogeneous catalysts: following Roberto Sanchez Delgado's footsteps (2016) (0)
- CCDC 217423: Experimental Crystal Structure Determination (2003) (0)
- Trinuclear Angular Aggregates of Rhodium: Synthesis and Crystal Structures of (Rh3(μ3‐SC5H4N)2(CO)6)(ClO4) (SC5H4N: pyridine‐2‐thiolate) and (Rh3(μ3‐C7H4NS2)2(CO)2(PPh3)2(tfbb))(ClO4) (C7H4NS2: benzothiazole‐2‐thiolate, tfbb: tetrafluorobenzobarrelene). (1990) (0)
- Chiral Half-Sandwich Ruthenium(II) Complexes as Catalysts in 1,3-Dipolar Cycloaddition Reactions of Nitrones with Methacrolein (Eur. J. Inorg. Chem. 16/2006) (2006) (0)
- Kinetic and Mechanistic Investigation of the Sequential Hydrogenation of Phenylacetylene Catalyzed by OsHCl(CO)(PR3)2 (PR3: PMe-tBu2 and P-iPr3). (1990) (0)
- Rhodium(I)-N-Heterocy clic Carbene Catalyst for Selec- tive Coupling of N-Vinylpy razoles with Alkynes via C -H Activation (2016) (0)
- Binuclear Pentamethylcyclopentadienylrhodium(III) Phosphido-Pyrazolate Complexes. X-Ray Structure of (((C5Me5)Rh)2(μ-pz)2(μ-PPh2))BF4 (pz = pyrazolate). (1989) (0)
- Synthesis and Characterisation of New Iridium Complexes with the (4S)‐2‐[2‐(Diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline Ligand That Catalyse Asymmetric Michael Reactions (Eur. J. Inorg. Chem. 9/2005) (2005) (0)
- CCDC 863202: Experimental Crystal Structure Determination (2012) (0)
- Structural chemistry of new Rh and Ir metallathiaboranes - understanding cluster flexibility (2010) (0)
- TETRA- AND TRINUCLEAR RHODIUM-PALLADIUM COMPLEXES WITH THE 1,2,4-TRIAZOLATE (TZ) LIGAND. CRYSTAL STRUCTURE OF (η3-C3H5)2PD2RH2(μ3-TZ)2CL2(CO)4 (1985) (0)
- Catalysts in Petroleum Refining & Petrochemicals Iridium homogeneous catalysts following outer-sphere mechanisms (2013) (0)
- Novel Anionic Aryl Complexes of Rh(III): (Rh(C6F5)5)2‐ and (Rh(C6F5)4(CO)2)‐. (1989) (0)
- Rhodium (I)-N-heterocyclic carbene catalyst for selective coupling of aromatic heterocycles with olefins and alkynes by C-H activation (2015) (0)
- Reactions of (Ru3(CO)12) with Nitrogen-Containing Heterocycles. Crystal Structures of (Ru3(μ-H)(μ3-ppy)(CO)9) and (Ru3(μ-napy)(μ-CO)3(CO)7). (1988) (0)
- Solvent‐Free Iridium‐Catalyzed Reactivity of CO2 with Secondary Amines and Hydrosilanes. (2016) (0)
- SYNTHESIS AND CHARACTERIZATION OF AN UNUSUAL HETEROBRIDGED DIRHODIUM COMPLEX. X-RAY MOLECULAR STRUCTURE OF (RH2(μ-PZ)2I2(CO)2(μ-DPPM)) (1985) (0)
- CCDC 809838: Experimental Crystal Structure Determination (2011) (0)
- N-H activation of ammonia by M(d8) organometallic complexes: reactivity and catalysis (2017) (0)
- SYNTHESIS AND REACTIVITY OF OSHC6H4(CH=CHH)(CO)(PPR3I)2 AND THE FORMATO COMPOUNDS OS(E)-CH=CHPH(ETA 2-2-O2CH)-(CO)(PPR3I)2 AND OSH(ETA 2-O2CH)(CO)(PP R3I)2 (1997) (0)
- Dihydrogen Complexes as Homogeneous Reduction Catalysts (1998) (0)
- Early (Ti, Zr)‐late (Rh, Ir) Heteronuclear Complexes with Bridging Sulfido Ligands (2004) (0)
- Interview with Professor Usón (1999) (0)
- CCDC 746439: Experimental Crystal Structure Determination (2011) (0)
- Preferential α‐Hydrosilylation of Terminal Alkynes by Bis‐N‐heterocyclic Carbene Rhodium(III) Catalysts. (2015) (0)
- NEW UNSATURATED-DITHIOLATE-BRIDGED RHODIUM COMPLEXES (1996) (0)
- The Emergence of Transition‐Metal‐Mediated Hydrothiolation of Unsaturated Carbon—Carbon Bonds: A Mechanistic Outlook (2013) (0)
- CCDC 746440: Experimental Crystal Structure Determination (2011) (0)
- Die Chemiker schaffen durch Tagungen und Zeitschriften eine europäische Identität (2016) (0)
- Oxidation and β‐Alkylation of Alcohols Catalyzed by Iridium(I) Complexes with Functionalized N‐Heterocyclic Carbene Ligands. (2016) (0)
- Iridium homogeneous catalysts following outer-sphere mechanisms (2013) (0)
- Di‐ and Trinuclear Rhodium and Iridium Complexes as Building Blocks for the Construction of Unusual Organometallic Architectures (2010) (0)
- Preparation of coke-based graphenes and their application in batteries and catalysis (2014) (0)
- Addition to Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}-Thiodecaborane Fragment System (2012) (0)
- Amides of Rhodium and Iridium Derived from 2-Aminothiophenol and Diaminonaphthalene: X-Ray Crystal Structure of Rh2(μ-1,8-(NH)2C10H6)(CO)4. (1989) (0)
- CCDC 746438: Experimental Crystal Structure Determination (2011) (0)
- BENZAMIDINATORHODIUM COMPLEXES. X-RAY STRUCTURES OF (RH(CPH(NPH)2)(COD)) AND (RH2(μ-CPH(NPH)2)2(TFBB)2) (1985) (0)
- CCDC 770466: Experimental Crystal Structure Determination (2011) (0)
- Dehydrogenation of Alcohols Mediated by an Amido-Bridged Diiridium Complex : A Case of a Concerted Bimetallic Mechanism (2015) (0)
- Iridium‐Catalyzed 1,3‐Dipolar Cycloadditions (2011) (0)
- DI(μ-AMIDO)DIRHODIUM COMPLEXES AND STRUCTURE OF RH2(μ-L)I2(CO)2(PPH3)2 (1985) (0)
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