Malcolm H. Chisholm
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Chemistry
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(Suggest an Edit or Addition)According to Wikipedia, Malcolm Harold Chisholm was a British inorganic chemist who worked mainly in North America, a Professor of Chemistry and Biochemistry, and Distinguished University Professor of Mathematical and Physical Sciences at Ohio State University who contributed to the synthesis and structural chemistry of transition metal complexes.
Malcolm H. Chisholm's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Molecular Design of Single-Site Metal Alkoxide Catalyst Precursors for Ring-Opening Polymerization Reactions Leading to Polyoxygenates. 1. Polylactide Formation by Achiral and Chiral Magnesium and Zinc Alkoxides, (η3-L)MOR, Where L = Trispyrazolyl- and Trisindazolylborate Ligands (2000) (350)
- Well-defined calcium initiators for lactide polymerization. (2004) (293)
- Lactide polymerization by well-defined calcium coordination complexes: comparisons with related magnesium and zinc chemistry. (2003) (275)
- Coordination chemistry and reactivity of monomeric alkoxides and amides of magnesium and zinc supported by the diiminato ligand CH(CMeNC(6)H(3)-2,6-(i)Pr(2))(2). A comparative study. (2002) (273)
- Comparative study of the coordination chemistry and lactide polymerization of alkoxide and amide complexes of zinc and magnesium with a beta-diiminato ligand bearing ether substituents. (2005) (182)
- New generation polymers: the role of metal alkoxides as catalysts in the production of polyoxygenates (2004) (181)
- Monomeric metal alkoxides and trialkyl siloxides: (BDI)Mg(OtBu)(THF) and (BDI)Zn(OSiPh3)(THF). Comments on single site catalysts for ring-opening polymerization of lactides (2001) (181)
- Reactions of Metal-Metal Multiple Bonds. 10. Reactions of Mo2(OR)6 (M Triple Bond M) and (M(OR)4)x Compounds with Molecular Oxygen. Preparation and Characterization of Oxo-Alkoxides of Formula MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4 and Mo6O10(OR)12. (1984) (169)
- Three-coordinate zinc amide and phenoxide complexes supported by a bulky Schiff base ligand. (2001) (156)
- Complexities in the ring-opening polymerization of lactide by chiral salen aluminum initiators. (2008) (130)
- Concerning the relative importance of enantiomorphic site vs. chain end control in the stereoselective polymerization of lactides: reactions of (R,R-salen)- and (S,S-salen)-aluminium alkoxides LAlOCH2R complexes (R = CH3 and S-CHMeCl). (2005) (127)
- Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II). Structural and spectroscopic evidence for molybdenum-to-bipyridyl .pi.* bonding (1981) (127)
- Reactions of metal-to-metal multiple bonds. 4. .mu.-Acetylene-bis(cyclopentadienyl)tetracarbonyldimolybdenum compounds. Preparations, properties, structural characterizations, and dynamical solution behavior (1978) (126)
- Concerning the mechanism of the ring opening of propylene oxide in the copolymerization of propylene oxide and carbon dioxide to give poly(propylene carbonate). (2004) (123)
- Binolate complexes of lithium, zinc, aluminium, and titanium; preparations, structures, and studies of lactide polymerization (2003) (121)
- Metal-metal multiple bonds in ordered assemblies. 1. Tetranuclear molybdenum and tungsten carboxylates involving covalently linked metal-metal quadruple bonds. Molecular models for subunits of one-dimensional stiff-chain polymers (1991) (119)
- Studies of electronic coupling and mixed valency in metal-metal quadruply bonded complexes linked by dicarboxylate and closely related ligands. (2007) (111)
- Poly(propylene carbonate). 1. More about Poly(propylene carbonate) Formed from the Copolymerization of Propylene Oxide and Carbon Dioxide Employing a Zinc Glutarate Catalyst (2002) (108)
- Transition-metal dialkylamides and disilylamides (1976) (108)
- Linking multiple bonds between metal atoms: clusters, dimers of "dimers", and higher ordered assemblies. (2005) (100)
- The influence of the metal (Al, Cr, and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 1. Aluminum chemistry. (2011) (98)
- Organoplatinum chemistry. Significance of metal-induced carbonium ions (1973) (96)
- Metal-Metal Bonds and Metal Carbon Bonds in the Chemistry of Molybdenum and Tungsten Alkoxides. (1983) (88)
- Reactions of transition metal-nitrogen .sigma. bonds. 3. Early transition metal N,N-dimethylcarbamates. Preparation, properties, and carbon dioxide exchange reactions (1977) (84)
- Binding of propylene oxide to porphyrin- and salen-M(III) cations, where M = Al, Ga, Cr, and Co. (2005) (81)
- Studies of Ring-Opening Reactions of Styrene Oxide by Chromium Tetraphenylporphyrin Initiators. Mechanistic and Stereochemical Considerations (2013) (81)
- The molybdenum-molybdenum triple bond. 1. Hexakis(dimethylamido)dimolybdenum and some homologs: preparation, structure, and properties (1976) (79)
- Metal alkoxides: models for metal oxides. 4. Alkyne adducts of ditungsten hexaalkoxides and evidence for an equilibrium between dimetallatetrahedrane and methylidynemetal complexes: W2(.mu.-C2H2) .dblharw. 2W.tplbond.CH (1984) (77)
- One-dimensional polymers and mesogens incorporating multiple bonds between metal atoms. (2000) (74)
- Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts (2010) (74)
- The influence of the metal (Al, Cr and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and cyclic anhydrides by porphyrin metal(III) complexes (2013) (72)
- Single-site metal alkoxide catalysts for ring-opening polymerizations. Poly(dilactide) synthesis employing {HB(3-Butpz)3}Mg(OEt) (1996) (71)
- Conformational effects in β-diiminate ligated magnesium and zinc amides. Solution dynamics and lactide polymerization (2003) (71)
- ISOELECTRONIC MOLECULES WITH TRIPLE BONDS TO METAL ATOMS (M = MO, W): CRYSTAL AND MOLECULAR STRUCTURES OF TRI-TERT-BUTOXYTUNGSTEN ETHYLIDYNE AND NITRIDE (1983) (71)
- Metalla-enes and Metalla-ynes—from Small Molecules to Infinite Polymers (1991) (71)
- The tungsten-tungsten triple bond. 8. Dinuclear alkoxides of tungsten(III) and structural characterization of hexaisopropoxybis(pyridine)ditungsten, the first compound with four-coordinated tungsten atoms united by a triple bond (1979) (69)
- Synthesis and X-ray crystal structures of the one-dimensional ribbon chains [MOBut·ButOH]∞ and the cubane species [MOBut]4 (M = K and Rb) (1991) (69)
- The tungsten-tungsten triple bond. 1. Preparation, properties, and structural characterization of hexakis(dimethylamido)ditungsten(III) and some homologs (1976) (69)
- Comparison of the bonding in zero- and divalent platinum-olefin and -acetylene complexes from carbon-13 nuclear magnetic resonance parameters. XXII (1972) (67)
- The molybdenum-molybdenum triple bond. 2. Hexakis(alkoxy)dimolybdenum compounds: preparation, properties and structural characterization of hexakis(neopentoxy)dimolybdenum (1977) (66)
- Cationic acetylenic platinum(II) compounds and their derivatives. III. Reactions of platinum(II) stabilized carbonium ions (1972) (65)
- Reactions of transition metal-nitrogen .sigma. bonds. 4. Mechanistic studies of carbon dioxide insertion and carbon dioxide exchange reactions involving early transition metal dimethylamido and N,N-dimethylcarbamato compounds (1977) (64)
- The coordination chemistry of dinuclear molybdenum(III) and tungsten(III): d3-d3 dimers (1990) (64)
- Carbon-13 nuclear magnetic resonance studies. 35. Carbon-13 nuclear magnetic resonance studies of organometallic compounds. I. trans-Methylplatinum(II) derivatives (1973) (63)
- Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) (1995) (60)
- Chemistry of magnesium alkyls supported by 1,5,9-trimesityldipyrromethene and 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. A comparative study (2012) (60)
- M2δ to ligand π-conjugation: testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems. (2011) (59)
- Molecular Routes to Metal Carbides, Nitrides, and Oxides. 2. Studies of the Ammonolysis of Metal Dialkylamides and Hexamethyldisilylamides (1996) (58)
- A Comparative Study in the Ring-Opening Polymerization of Lactides and Propylene Oxide (2001) (57)
- Early transition metal clusters with π-donor ligands (1995) (56)
- Crystal and molecular structure of hexakis(tert-butoxo)dialuminum. Comments on the extent of M-O .pi. bonding in Group 6 and Group 13 alkoxides (1991) (54)
- Trialkoxynitridomolybdenum compounds: (RO)3Mo.ident.N. Preparation, structures (R = tert-Bu and iso-Pr), and comparisons with a tungsten analog (R = tert-Bu) (1986) (54)
- Influence of the metal (Al, Cr, and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 2. Chromium chemistry. (2012) (54)
- Microstructure of Poly(lactide). Phase-Sensitive HETCOR Spectra of Poly(meso-lactide), Poly(rac-lactide), and Atactic Poly(lactide) (1999) (52)
- Metal alkoxides: models for metal oxides. 17. Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-tert-Bu)12 and W4(.mu.4-C)(O)(O-i-Pr)12 (1992) (50)
- Solution Studies of Ru2(O2CR)4n+ Complexes (n = 0, 1; O2CR = Octanoate, Crotonate, Dimethylacrylate, Benzoate, p-Toluate) and Solid-State Structures of Ru2(O2C-p-tolyl)4(THF)2, [Ru2(O2C-p-tolyl)4(THF)2]+[BF4]-, and Ru2(O2C-p-tolyl)4(CH3CN)2: Investigations of the Axial Ligation of the Ru2 Core (1996) (49)
- METAL ALKOXIDES - MODELS FOR METAL OXIDES. 1. PREPARATIONS AND STRUCTURES OF HEXADECAALKOXYTETRATUNGSTEN COMPOUNDS, W4(OR)16, WHERE R = ME AND ET, AND OCTAOXOTETRAISOPROPOXYTETRAPYRIDINOTETRAMOLYBDENUM, MO4(O)4(μ-O)2(μ3-O)2(O-I-PR)2(μ (1982) (49)
- Cyclic esters and cyclodepsipeptides derived from lactide and 2,5-morpholinediones (2006) (49)
- Trifluoromethylplatinum complexes and the nature of the platinum-trifluoromethyl bond (1972) (49)
- Molecular design of single site catalyst precursors for the ring-opening polymerization of cyclic ethers and esters. 2.1 Can ring-opening polymerization of propylene oxide occur by a cis-migratory mechanism? (2001) (48)
- Trispyrazolylborate ligands as ancillary ligands in the development of single-site metal alkoxide catalysts for ring-opening polymerization of cyclic esters (2009) (47)
- Chemistry of BDI*M2+ complexes (M = Mg, Zn) and their role in lactide polymerization where BDI* is the anion derived from methylenebis(C-(t)Bu, N-2,6-diisopropylphenyl)imine BDI*H. (2009) (46)
- Chemistry of compounds containing metal-to-metal triple bonds between molybdenum and tungsten. Technical report (1977) (46)
- Cationic acetylenic platinum(II) compounds and their derivatives. II. Acetylene and vinyl ether complexes (1971) (46)
- Reactions of metal-to-metal multiple bonds. 1. .mu.-Allene-bis(cyclopentadienyl)tetracarbonyldimolybdenum and -ditungsten compounds. Preparation, properties, and structural characterization (1978) (46)
- Dicyclopentadienyldi-tert-butoxydichromium. Preparation, properties, structure, and reactions with small unsaturated molecules (1979) (46)
- Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes (2011) (45)
- Metal Alkoxides - Models for Metal Oxides. (1982) (45)
- Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba6(O)(OBut)11(OCEt2CH2O)(thf)3](thf = tetrahydrofuran) (1990) (45)
- Reactions of metal-to-metal multiple bonds. 2. Reactions of bis(cyclopentadienyl)tetracarbonyldimolybdenum with small unsaturated molecules. Structural characterization of .mu.-dimethylaminocyanamide-bis(cyclopentadienyl)tetracarbonyldimolybdenum (1978) (45)
- Dinuclear barium alkoxides and siloxides displaying variable coordination numbers and asymmetric dispositions of ligands (1992) (44)
- Inorganic chemistry : toward the 21st century (1983) (44)
- The molybdenum-molybdenum triple bond. 4. Insertion reactions of hexakis(alkoxy)dimolybdenum compounds with carbon dioxide and single-crystal x-ray structural characterization of bis(tert-butylcarbonato)tetrakis(tert-butoxy)dimolybdenum (1978) (44)
- Cations M2(O2CtBu)4+, where M = Mo and W, and MoW(O2CtBu)4+. Theoretical, spectroscopic, and structural investigations. (2005) (44)
- NMR Assignments of Regioregular Poly(propylene oxide) at the Triad and Tetrad Level (2002) (44)
- Metal alkoxides models for metal oxides. 5. Coupling of alkyne ligands in reactions involving ditungsten hexaalkoxides: an alternative to the metathesis reaction M.tplbond.M + C.tplbond.C- .fwdarw. 2M.tplbond.C (1984) (44)
- Reactions of alkynyl- and alkenylplatinum(II) compounds. 1. Formation of alkoxycarbene ligands within the coordination sphere of platinum (1977) (44)
- Multiple Bonds between Metal Atoms in Ordered Assemblies. 2. Quadrupole Bonds in the Mesomorphic State (1994) (43)
- Reactions of M-M triple bonds with carbon-nitrogen triple bonds: adduct formation (M = molybdenum) and metathesis (M = tungsten) as seen in the reactions between dimethylcyanamide and hexaalkoxides of dimolybdenum and ditungsten (1983) (43)
- Cationic acetylenic platinum(II) compounds and their derivatives. I. Alkoxycarbene complexes (1971) (42)
- Facile synthesis and structural principles of the strontium phenoxide Sr4(OPh)8(PhOH)2(THF)6 (1990) (42)
- Chloro(dimethylamido) compounds of tantalum(V): Preparations, properties, and structures of [Ta(NMe2)3Cl2]2, TaCl3(NMe2)2(HNMe2), Ta(NMe2)3Cl2(HNMe2), and [TaCl2(NMe2)2(HNMe2)]2O (1981) (42)
- Metal alkoxides: models for metal oxides. 2. Addition of ethyne, propyne, and 2-butyne to Mo2(OR)6 (M.tplbond.M) compounds (R = tert-Bu, iso-Pr, and neopentyl). Characterization of .mu.-alkyne and .mu.-C4H4 adducts and an evaluation of their role in alkyne oligomerization reactions (1982) (42)
- Observation of 1MLCT and 3MLCT excited states in quadruply bonded Mo2 and W2 complexes. (2005) (41)
- Crystal and molecular structures of tert-butyltetrakis(dimethylamido)tantalum(V), bromo(p-tolyl)tris(dimethylamido)tantalum(V), and [(trimethylsilyl)methyl]tetrakis(N,N-dimethylcarbamato)tantalum(V). Evidence for stabilization of .sigma.-alkyl ligands by strongly .pi.-donating ligands in early trans (1982) (40)
- Long-range electronic coupling of MM quadruple bonds (M = Mo or W) via a 2,6-azulenedicarboxylate bridge. (2005) (40)
- Magnetic uniaxial alignment of the columnar superstructure of discotic metallomesogens over the centimetre length scale (2006) (40)
- Thienyl carboxylate ligands bound to and bridging MM quadruple bonds, M = Mo or W: models for polythiophenes incorporating MM quadruple bonds. (2004) (39)
- Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu (1987) (39)
- A study of the ring-opening polymerization (ROP) of L-lactide by Ph2SnX2 precursors (X = NMe2, OPri): the notable influence of initiator group (2003) (38)
- The remarkable influence of M2δ to thienyl π conjugation in oligothiophenes incorporating MM quadruple bonds (2008) (37)
- Synthesis and Structure of [Ba3(OSiPh3)6(THF)] · 0.5 THF, a Trinuclear Barium Siloxide Containing Low‐Coordinate Barium Ions (1990) (37)
- A study of the ring-opening of lactides and related cyclic esters by Ph2SnX2 and Ph3SnX compounds (X?=?NMe2, OR)Electronic supplementary information (ESI) available: preparation and characterization data for Ar3SnX, Ph2SnNMe2 and Ph2Sn(OPri)2 compounds [X?=?NMe2, OMe, OPri, OBut, OPh, OCH(CF3)2, PPh (2003) (37)
- Oxalate-bridged complexes of dimolybdenum and ditungsten supported by pivalate ligands: ((t)BuCO(2))(3)M(2)(mu-O(2)CCO(2))M(2)(O(2)C(t)Bu)(3). Correlation of the solid-state, molecular, and electronic structures with Raman, resonance Raman, and electronic spectral data. (2002) (37)
- Concerning the stereochemistry of poly(lactide), PLA. Previous assignments are shown to be incorrect and a new assignment is proposed (1997) (36)
- The σ2π4 Triple Bond between Molybdenum and Tungsten Atoms: Developing the Chemistry of an Inorganic Functional Group (1986) (35)
- Electronically coupled MM quadruply-bonded complexes (M = Mo or W) employing functionalized terephthalate bridges: toward molecular rheostats and switches. (2005) (35)
- Preparation, crystal and molecular structure of a hydrocarbon soluble, volatile oxo-alkoxide of barium: H4Ba6(µ6-O)(OCH2CH2OCH3)14 (1990) (35)
- Remarkable influence of terminal alkoxy groups on carbonyl ligands as seen in the new compounds Mo(OBut)2(CO)2(py)2 and Mo2(OPri)8(CO)2 (1979) (35)
- The synthesis and characterization of volatile lithium alkoxides, and the single crystal X-ray structure of [LiOCMe2Ph]6 (1991) (35)
- Reactions of metal-metal multiple bonds. 7. Addition of the halogens chlorine, bromine and iodine and diisopropyl peroxide to hexaisopropoxydimolybdenum (M.tplbond.M). Dinuclear oxidative-addition reactions accompanied by metal-metal bond-order changes from 3 to 2 to 1 (1981) (34)
- Reactions involving the triple bond in dimolybdenum and ditungsten hexa-alkoxides and C–C, C–N, and C–O triple bonds (1985) (34)
- Incorporation of Ru2(O2C(CH2)6CH3)4 into Extended Chains: Interaction of Ru2(O2C(CH2)6CH3)4 with Pyrazine, 4-Cyanopyridine, TCNE, and p-Benzoquinone (1997) (34)
- Quadruple bonds between molybdenum atoms supported by alkoxide ligands (1984) (34)
- Synthesis and structural characterization of the alkaline earth aryloxide aggregates H[sub 2]Ba[sub 8]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6] and H[sub 2]Sr[sub 6]Ba[sub 2]([mu][sub 5]-O)[sub 2](OPh)[sub 14](HMPA)[sub 6]. A new structural type displaying metal ion site selectivity (1993) (34)
- Reactions of metal-metal multiple bonds. 14. Synthesis and characterization of triangulo-W3 and -Mo2W oxo-capped alkoxide clusters. Conproportionation of M-M triple bonds and .sigma.2.pi.4 and d0 metal-oxo groups: M.tplbond.M + M.tplbond.O .fwdarw. M3(.mu.3-O) (1985) (33)
- Tetrakisdimethylamidozirconium and its dimethylamido lithium adduct: Structures of [zr(nme2)4]2 and zr(nme2)6li2(thf)2 (1988) (33)
- Triangular phenoxide aggregates of calcium, strontium, and barium : a comparison (1993) (33)
- Resonance Raman Spectra of [M(6)X(8)Y(6)](2)(-) Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I). (1996) (32)
- Allene adducts of ditungsten hexaalkoxides. Three modes of allene coordination to dinuclear centers as seen in the structures of W2(OBu-tert)6(C3H4), W2(OBu-tert)6(C3H4)2, and W2(OBu-tert)6(C3H4)(CO)2 (1991) (32)
- Nitrogen atom exchange between molybdenum, tungsten and carbon. A convenient method for N-15 labeling. (2003) (32)
- Reactions of metal-metal multiple bonds. 8. Forming molybdenum-molybdenum quadruple bonds by reductive elimination (alkyl group disproportionation) in the reactions of 1,2-Mo2R2(NMe2)4 compounds (M.tplbond.M) with carbon dioxide and 1,3-diaryltriazines (1982) (31)
- Organometallic Chemistry of Molybdenum and Tungsten Supported by Alkoxide Ligands (1988) (31)
- The tungsten-tungsten triple bond. 4. Structural characterization of hexakis(trimethylsilylmethyl)ditungsten and preparation of bis-.mu.-(trimethylsilylmethylidyne)-tetrakis(trimethylsilylmethyl)ditungsten (1976) (31)
- Molecular and electronic structure of tetrakis(dimethylamido)molybdenum(IV) (1978) (31)
- Amidinate-carboxylate complexes of dimolybdenum and ditungsten: M2(O2CR)2((NiPr)2CR')2. Preparations, molecular and electronic structures and reactions. (2008) (31)
- 1,2-Dibenzyl- and 1,2-diaryltetrakis(dimethylamido)dimolybdenum and -ditungsten compounds: M2R2(NMe2)4 (M.tplbond.M). Structural effects of Me2N-to-M .pi. bonding (1983) (31)
- Reactions of metal-to-metal multiple bonds. 3. Addition of nitric oxide to hexakis(alkoxy)dimolybdenum compounds. Preparation and properties of bis(nitrosyl)hexakis(alkoxy)dimolybdenum compounds and structural characterization of the isopropoxy derivative (1978) (31)
- Cationic acetylenic platinum(II) compounds and their derivatives. V. Comparative study with .pi.-olefinic complexes (1973) (31)
- Covalent compounds of quadrivalent transition metals. Part II. Chromium(IV) tertiary alkoxides and triethylsilyloxide (1971) (30)
- Electronic coupling in 1,4-(COS)2C6H4 linked MM quadruple bonds (M = Mo, W): the influence of S for O substitution. (2006) (30)
- Perfluoroterephthalate Bridged Complexes with M−M Quadruple Bonds: (tBuCO2)3M2(μ-O2CC6F4CO2)M2(O2CtBu)3, where M = Mo or W. Studies of Solid-State, Molecular, and Electronic Structure and Correlations with Electronic and Raman Spectral Data (2002) (30)
- (Trimethylsilyl)methylidene and (trimethylsilyl)methylidyne compounds of molybdenum and tungsten: (Me3SiCH2)3M.tplbond.CSiMe3 (M = molybdenum and tungsten) and (Me3SiCH2)3Mo:CHSiMe3 (1981) (30)
- Synthesis and molecular structure of a mononuclear barium aryloxide-ethanolamine complex, Ba(2,6-tert-Bu2C6H3O)2(HOCH2CH2NMe2)4.cntdot.2C7H8, exhibiting extensive hydrogen bonding (1991) (30)
- Structure and bonding of (.mu.-dicarbido)hexa-tert-butoxyditungsten, (tert-BuO)3W.tplbond.CC.tplbond.W(O-tert-Bu)3 (1992) (30)
- Reactions involving alkynes and tungsten-tungsten triple bonds supported by alkoxide ligands (1987) (30)
- Oxalate bridged MM (MM = Mo2, MoW, and W2) quadruply bonded complexes as test beds for current mixed valence theory: looking beyond the intervalence charge transfer transition. (2009) (29)
- Octahedral Mo6 Clusters Supported by Methoxide Ligands. (1984) (29)
- The tungsten-tungsten triple bond. 6. Hexakis(N,N-dimethylcarbamato)ditungsten and dimethyltetrakis(N,N-diethylcarbamato)ditungsten. Structures and dynamical solution behavior (1977) (29)
- A phosphido-capped tritungsten alkoxide cluster: W3(.mu.3-P)(.mu.-OCH2-tert-Bu)3(OCH2-tert-Bu)6 and speculation upon the existence of a reactive (tert-BuCH2O)3W.ident.P intermediate (1988) (29)
- Characterization of bis(2,2'-bipyridine) and bis(1,10-phenanthroline) derivatives of molybdenum and tungsten carbonyls. Crystal and molecular structure of cis-dicarbonylbis(2,2'-bipyridine)molybdenum(0) (1984) (29)
- Photophysical properties of MM quadruply bonded complexes supported by carboxylate ligands, MM = Mo2, MoW, or W2. (2013) (29)
- Tris(dimethylaminato)tris(N,N-dimethylcarbamato)tungsten(VI). Product of the remarkable reaction between hexakis(dimethylaminato)tungsten and carbon dioxide (1974) (29)
- Structure and bonding in octaisopropoxydimolybdenum(IV) (1978) (29)
- Solid‐State and Solution Structures of [{NW(OC(CH3)2CF3)3}3] and Factors Favoring the Metathesis of CN and WW Triple Bonds in Reactions Involving Organic Nitriles and Ditungsten Hexaalkoxides (1995) (28)
- Tetranuclear carbidotungsten and nitridomolybdenum clusters supported by alkoxide ligands: W4(C)(OCHMe2)12(NMe) and Mo4(N)2(OCHMe2)12 (1985) (28)
- The multidentate ligand (MeOMe2Si)3Si-: unusual coordination modes in alkali metal silanides. (2008) (28)
- Quadruply bonded dimetal units supported by 2,4,6-triisopropylbenzoates MM(TiPB)(4) (MM = Mo(2), MoW, and W(2)): preparation and photophysical properties. (2009) (28)
- Reactions of metal-to-metal multiple bonds. 6. Reversible carbonylation of hexakis(tert-butoxy)dimolybdenum (M.tplbond.M). A carbonyl-bridged metal-to-metal double bond, Mo2(OBu-t)6(CO) (M:M) (1979) (28)
- New metalloorganic compounds of tungsten(III) (1975) (28)
- Low-pressure chemical vapor deposition of tungsten carbide (WC) thin films (1991) (28)
- Px ligands with a maximum of electron-donating ability: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF] (1993) (27)
- Direct observation of .alpha.-hydrogen transfer from alkyl to alkylidyne ligands in (Me3CCH2)3W:CSiMe3. Kinetic and mechanistic studies of alkyl-alkylidyne exchange (1991) (27)
- Metal alkoxides: models for metal oxides. 7. Trinuclear and tetranuclear alkylidyne clusters of tungsten supported by alkoxide ligands (1985) (27)
- Syntheses and structural characterization of 2,2′-methylene-bis(6-t-butyl-4-methyl-phenoxide complexes of titanium, zirconium and tantalum (1997) (27)
- Mixed valency and metal–metal quadruple bonds (2013) (27)
- Arylzinc alkoxides: [ArZnOCHPr(i)2]2 and Ar2Zn3(OCHPr(i)2)4 when Ar = C6H5, p-CF3C6H4, 2,4,6-Me3C6H2, and C6F5. (2005) (27)
- The reductive cross-coupling of ketones and aldehydes to olefins by ditungsten hexaalkoxides (1989) (27)
- Ethyl 2-hydroxy-2-methylpropanoate derivatives of magnesium and zinc. The effect of chelation on the homo- and copolymerization of lactide and ε-caprolactone. (2014) (27)
- Hexaisopropoxyditungsten and dodecaisopropoxytetratungsten: W2(O-i-Pr)6 and W4(O-i-Pr)12. 2. Studies of cluster dynamics and the equilibrium between the 12-electron cluster and two metal-metal triple bonds. A symmetry-allowed [.pi.s2 + .pi.s2] cycloaddition reaction and comparisons with the chemistr (1989) (26)
- MoMo Quadruple Bonds Bridged by 1,8‐Naphthyridinyl‐2,7‐Dioxide: an Insight into the Nature of a Parallel‐Linked Stiff‐Chain Polymer: (1991) (26)
- Metal alkoxides: models for metal oxides. 16. Synthesis and characterization of a new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula M4(OR)12: structural characterization of Mo4(OCH2-c-Bu)12.cntdot.(HOCH2-c-Bu) (1989) (25)
- Electronic coupling between covalently linked metal-metal quadruple bonds of molybdenum and tungsten (1989) (25)
- Dimolybdenum and ditungsten derivatives of the trisilanol, [(c-C6H11)7Si7O9(OH)3]: [(c-C6H11)7Si7O12]2Mo2 (M.tplbond.M) and [(c-C6H11)7Si7O12]2W2(.mu.-H)(O-tert-Bu) (1991) (25)
- {H(3-(t)Bupz)B(3-(t)Bupz)(2)-eta(2)}AlEt(2) and {H(3-(t)Bupz)B(3-(t)Bupz)(5-(t)Bupz)-eta(2)}AlEt(2). Structure, Dynamic Solution Behavior, and the 1,2-Borotropic Shift. (1996) (25)
- Synthesis and coordination chemistry of TpC*MI complexes where M=Mg, Ca, Sr, Ba and Zn and TpC*=tris[3-(2-methoxy-1,1-dimethyl)pyrazolyl]hydroborate. (2009) (25)
- Single-site bismuth alkoxide catalysts for the ring-opening polymerization of lactide. (2013) (25)
- Reductive cleavage of ketonic carbon-oxygen bonds in the reactions between ketones and ditungsten hexaalkoxides. Structural characterization of a ditungsten .mu.-propylidene derivative (1990) (25)
- Nitrido Dimers and Trimers of Tungsten Supported by tBuMe2SiO and CF3Me2CO Ligands, Respectively. Factors Influencing the Reductive Cleavage of Nitriles by Tungsten–Tungsten Triple Bonds and An Analysis of the Structure of the Cyclotrimer (1999) (25)
- Oligothiophenes incorporating metal-metal quadruple bonds. (2005) (25)
- Preparations and photophysical properties of fused and nonfused thienyl bridged MM (M = Mo or W) quadruply bonded complexes. (2008) (25)
- Catalysis design for ring-opening polymerization of cyclic esters: 1. Group 1 metal and thallium(I) trispyrazolylborate complexes with hemilabile ligands. (2007) (24)
- Hexaisopropoxyditungsten and dodecaisopropoxytetratungsten: W2(O-i-Pr)6 and W4(O-i-Pr)12. 1. Preparation, structure, and bonding. The first example of a metal-metal triple bond and its 12-electron cluster. Analogies with ethyne and cyclobutadiene (1987) (24)
- A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of η3, η5, η6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions (2006) (24)
- Dinuclear Molybdenum and Tungsten Complexes with Metal−Metal Triple Bonds Supported by p-tert-Butylcalix[4]arene Ligands (1999) (24)
- Dimetal Hepta- and Octaalkoxide Anions of Molybdenum and Tungsten, M2(OR)7- and M2(OR)82- (M.tplbond.M). Preparation, Structures, Oxidation, and a Study of the Thermal Decomposition of W2(OR)7- to Give W2(H)(O)(OR)6- Where R = tBu and iPr (1995) (24)
- Multiple Bonds Between Metal Atoms in Ordered Assemblies: Liquid Crystals Containing MoMo Quadruple Bonds (1990) (24)
- Metal alkoxides. Models for metal oxides. 15. Carbon-carbon and carbon hydrogen bond activation in the reactions between ethylene and ditungsten hexaalkoxides: W2(OCH2-t-Bu)6(.eta.2-C2H4)2, W2(OR)6(CH2)4(.eta.2-C2H4), and W2(OR)6(.mu.-CCH2CH2CH2) (where R = Ch2-t-Bu, i-Pr, c-C5H9, and c-C6H11). Prep (1989) (24)
- Metal alkoxides-models for metal oxides. 9. Hydridoditungsten alkoxides: W2(H)(O-iso-Pr)8Na.cntdot.diglyme and W2(H)(I)(OCH2-tert-Bu)6(H2NMe). Further investigations of the reaction between W2(NMe2)6(M.tplbond.M) and iso-PrOH leading to W4(H)2(O-iso-Pr)14 (1986) (24)
- Electronically-coupled tungsten-tungsten quadruple bonds: comparisons of electron delocalization in 3,6-dioxypyridazine and oxalate-bridged compounds. (2004) (24)
- Some reactions of hexakis(dimethylamido)tungsten(VI) (1977) (24)
- CP CO(P4)CP CO)2(MU -CO) (CP =ETA 5-C5H3TBU2) : A COMPLEX WITH A P4 UNIT ON THE WAY TO A P1 AND A P3 LIGAND (1995) (24)
- The tetradecaisopropoxydihydridotetratungsten story (1981) (24)
- The Tungsten-to-Tungsten Triple Bond. 7. Replacement of Dimethylamido by Chloro Groups in Hexakis (dimethylamido)ditungsten and -dimolybdenum Compounds; the Preparation, Properties and Structure of Dichlorotetrakis-(dimethylamido)ditungsten and -dimolybdenum. (1977) (24)
- Square and butterfly, 12-electron molybdenum (Mo4) clusters formed by coupling molybdenum-molybdenum triple bonds (1982) (24)
- Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron. (2011) (24)
- Structure and magnetic alignment of metalloporphyrazine columnar aggregates in their mesophases and crystalline phases (2002) (24)
- The Synthesis and Structural Characterization of the Sterically Demanding Tris (3,5-di-t-butylpyrazolyl) hydroborato Ligand, [TpBut 2 ]: A Highly Twisted, Propeller-Like, Ligand System (1995) (24)
- Metal-to-metal triple bonds-to cluster or not to cluster? Structural characterization of octakis(tert-butoxy)tetrakis(.mu.-fluoro)-tetramolybdenum and octakis(tert-butoxy)tris(.mu.-fluoro)-(.mu.-dimethylamido)-tetramolybdenum (1979) (24)
- Ring-opening polymerization of l-lactide by organotin(IV)alkoxides, R2Sn(OPri)2: Estimation of the activation parameters (2007) (24)
- Compounds in which the Mo24+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands (1999) (23)
- Preparation and Characterization of 1,2-Dialkyl Compounds of Dimolybdenum an Ditungsten of Formula M2R2(NMe2)4 M-Triple bond-M. (1981) (23)
- Oxotrimolybdenum(IV) alkoxides: Mo3(.mu.3-O)(.mu.3-OR)(.mu.2-OR)3(OR)6, where R = isopropyl and neopentyl. Synthetic considerations (1981) (23)
- The molybdenum-molybdenum triple bond. 11. 1,1- and 1,2-Disubstituted dimolybdenum compounds of formula Mo2X2(CH2SiMe3)4. Observation of rotation about the triple bond Mo.tplbond.Mo (1982) (23)
- Carbon-13 nuclear magnetic resonance studies of organometallic compounds. VII. 1,5-Cyclooctadieneplatinum(II) derivatives (1975) (23)
- Comments on the substitutional lability of the dimetal carboxylates of molybdenum and rhodium. Effects of M-M MO configuration (1991) (23)
- Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 2.(1) Derivatives of 2,2'-Methylenebis(6-tert-butyl-4-methylphenoxide). Direct Observation of the Conversion of Bridged to Chelate Isomers (M = Mo) and Reversible Carbon-Hydrogen Bond Oxidative Addition (M = W). (1997) (23)
- Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines. (1997) (23)
- A general synthesis for ditungsten tetracarboxylates. Preparation of WW quadruple bonds by reductive-elimination (alkyl group disproportionation) from 1,2-diethyl compounds with WW triple bonds (1984) (23)
- The tungsten-tungsten triple bond. 13. Bisalkyl tetracarboxylates of dimolybdenum and ditungsten. Triple bonds between metal atoms with the valence molecular orbital description .pi.4.delta.2 (1987) (23)
- Detection of the singlet and triplet MM δδ* states in quadruply bonded dimetal tetracarboxylates (M = Mo, W) by time-resolved infrared spectroscopy. (2012) (22)
- Cationic platinum(II) acetylenic complexes and their derivatives. VI. Aminolysis and other reactions of cationic platinum(II) alkoxycarbene complexes (1975) (22)
- Reactions of metal-to-metal multiple bonds. 5. Addition of nitric oxide to hexa-tert-butoxyditungsten. Preparation, properties, and structural characterization of tri-tert-butoxy(nitrosyl)(pyridine)tungsten (1979) (22)
- Is it possible to stabilise complexes with a tungsten–phosphorus triple bond? (1995) (22)
- Photophysical studies of metal to ligand charge transfer involving quadruply bonded complexes of molybdenum and tungsten. (2015) (22)
- Low pressure chemical vapor deposition of metallic films of iron, manganese, cobalt, copper, germanium and tin employing bis(trimethyl)silylamido complexes, M(N(SiMe3)2)n (1995) (22)
- New metal-organic polygons involving MM quadruple bonds: M8(O2CtBu)4(mu-SC4H2-3,4-{CO2}2)6 (M=Mo, W). (2005) (22)
- An unbridged triple bond uniting d6 Mo(0) and d2 Mo(IV) atoms: bis[bis(dimethylphosphino)ethane]tetraisopropoxodimolybdenum (1987) (22)
- The molybdenum-molybdenum triple bond. 15. Compounds with chains of metal atoms having M-M single and triple bonds: M2(M'(M'Me3)3)2(NMe2)4 (M.tplbond.M) where M = Mo and W and M' = Si and Sn (1984) (22)
- On the electron delocalization in the radical cations formed by oxidation of MM quadruple bonds linked by oxalate and perfluoroterephthalate bridges. (2002) (22)
- Hexakis(dimethylaminato)- and hexakis(tert-butoxy)dimolybdenum(III) (1974) (22)
- Tetrakis(alkoxy) and tetrakis(trialkylsiloxy) compounds of molybdenum(IV) (1978) (22)
- Direct observation of a 1MLCT state by ultrafast transient absorption spectroscopy in Mo2(O2C-9-anthracene)4. (2006) (21)
- Molecular structure and dynamic solution behavior of the bridging 1,3-dimetallaallyl ligand in (Me3SiCH2)4W2(.mu.-CSiMe3)(.mu.-C3R2SiMe3) compounds (R = hydrogen, methyl, or phenyl) formed by insertion of alkynes into a bridging (.mu.2) ligand (1984) (21)
- The molybdenum-molybdenum triple bond. 3. A triple bond between two four-coordinated molybdenum(III) atoms. Structural characterization of the bis(dimethylamine) adduct of dimolybdenum hexatrimethylsiloxide (1978) (21)
- Reactions of transition metal-nitrogen .sigma.-bonds. II. Pentakis(N,N-dimethylcarbamato)niobium(V) and its facile exchange reaction with carbon dioxide (1975) (21)
- Versatile Modes of Allene Bonding in the Structures of [W2(OtBu)6(C3H4)], [W2(OtBu)6(C3H4)(CO)2], and [W2(OtBu)6(C3H4)2] (1989) (21)
- Electronic structure and bonding in monocarbonyl adducts of dimolybdenum and ditungsten hexaalkoxides: a theoretical and spectroscopic investigation into the mechanism of metal-metal and carbon-oxygen bond order reduction (1986) (21)
- New .sigma.-ethyl compounds of dimolybdenum (M.tplbond.M) and evidence for dinuclear reductive elimination with a concomitant metal-metal triple to quadruple bond transformation: Et-M.tplbond.M-Et .fwdarw. M::M + C2H4 + C2H6 (1978) (21)
- Metathesis of nitrogen atoms within triple bonds involving carbon, tungsten, and molybdenum. (2008) (21)
- Evidence for Equilibria between μ‐Alkyne and Alkylidyne Complexes of Tungsten Alkoxides: [W2(OR)6(μ‐C2R′2)] ⇌ 2[(RO)3W ≡ CR′] (1986) (21)
- Theoretical and experimental studies of the electronic structure of the Mo3(Micro3-0)(Micro3-OR)(Micro-OR)3(OR)6 type of triangulo metal atom cluster compound (1984) (20)
- Cationic acetylenic platinum(II) compounds and their derivatives. IV. Displacement reactions (1972) (20)
- Hexakis(dimethylamido)tungsten(VI) (1977) (20)
- Reactions of metal-metal multiple bonds. 9. .alpha.-Diketone adducts of ditungsten hexaalkoxides: W2(OR)6(O2C2R'2)2 (M-M) (1983) (20)
- Coupling of propylene oxide and lactide at a porphyrin chromium(III) center. (2015) (20)
- 2-Thienylcarboxylato and 2-thienylthiocarboxylato ligands bonded to MM quadruple bonds (M = Mo or W): a comparison of ground state, spectroscopic and photoexcited state properties. (2009) (20)
- (η3-P3)W(OCH2But)3(HNMe2) formed by cleavage of the WW bond in the reaction between W2(OCH2But)6(HNMe2)2 and P4 (1987) (20)
- Transition Metal Complexes of Bis(Trimethyl‐silyl)Amine (1,1,1,3,3,3‐Hexamethyldisilazane) (2007) (20)
- Reaction between benzophenone and ditungsten hexaalkoxides. Molecular structure and reactivity of W(OCH2-tert-Bu)4(py)(.eta.2-OCPh2) (1990) (20)
- .mu.-Allene-bis(cyclopentadienyl)tetracarbonyldimolybdenum; a bridging allene ligand (1977) (20)
- Quadruple Metal−Metal Bonds with Strong Donor Ligands. Ultraviolet Photoelectron Spectroscopy of M2(form)4 (M = Cr, Mo, W; form = N,N‘-diphenylformamidinate) (1999) (20)
- Study of the formation of a .sigma.,.pi.-vinyl ligand by hydrogen atom transfer from a coordinated dimethylamide to a perpendicularly bonded ethyne ligand. Preparation and characterization of (PMe2Ph)Cl2W(.mu.-NMe2)(.mu.-.eta.1,.eta.2-CHCH2)(.mu.-.eta.2,.eta.1-CH2NMe)WCl(NMe2)(PMe2Ph) (1986) (20)
- Dimolybdenum compound (iso-PrO)3Mo.tplbond.Mo(CH2Ph)2(O-iso-Pr)(PMe3): the first example of a compound containing a triple bond uniting three- and four-coordinate molybdenum atoms and the observation of phosphine-promoted, reversible benzyl-alkoxy migrations at the (M.tplbond.M)6+ center (1984) (19)
- Addition of alkynes to hexaalkoxydimolybdenum (M.ident.M) compounds and structure of .mu.-ethyne-hexaisopropoxydipyridinodimolybdenum (1981) (19)
- Gas-phase and solution-phase polymerization of epoxides by Cr(salen) complexes: evidence for a dinuclear cationic mechanism. (2004) (19)
- 1,3-Ditungstacyclobutadienes. 1. Reactions with alkynes. Alkyne adducts and 1,3-dimetallaallyl derivatives (1985) (19)
- Comments on the ring-opening polymerization of morpholine-2,5-dione derivatives by various metal catalysts and characterization of the products formed in the reactions involving R2SnX2, where X = OPr(i) and NMe2 and R = Bu(n), Ph and p-Me2NC6H4. (2006) (19)
- REACTIONS OF DIMETHYL ACETYLENEDICARBOXYLATE AND RELATED ACETYLENES WITH METHYLPLATINUM(II) COMPLEXES (1974) (19)
- M2(OR)6 compounds (M = Al, Mo, W; R = t-Bu, cy-Hex) as single-source precursors. Studies of thermolysis under helium flow (1991) (19)
- Reactions involving carbon dioxide and mixed amido-phosphido dinuclear compounds. M2(NMe2)4(PR2)2(M.tplbond.M), where M = Mo and W. Comparative study of the insertion of carbon dioxide into metal-nitrogen and metal-phosphorus bonds (1989) (19)
- A comparison of the influences of alkoxide and thiolate ligands on the electronic structure and reactivity of molybdenum(3+) and tungsten(3+) complexes. preparation and structures of M(2)(O(T)Bu)(2)(S(t)Bu)(4), [Mo(S(t)Bu)(3)(NO)](2), and W(S(t)Bu)(3)(NO)(py). (2001) (19)
- 18-membered cyclic esters derived from glycolide and lactide: preparations, structures and coordination to sodium ions. (2007) (19)
- Metal alkoxides: models for metal oxides. 8. Monocarbonyl adducts of ditungsten hexaalkoxides (M.tplbond.M) (RO = t-BuO, i-PrO and t-BuCH2O) and the dimer [W2(O-i-Pr)6(.mu.-CO)]2 (1985) (19)
- Alkoxide Clusters of Molybdenum and Tungsten as Templates for Organometallic Chemistry: Comparison with Carbonyl Clusters of the Later Transition Elements (1989) (19)
- Molecular dynamics and ligand exchange in magnesium complexes: evidence for both dissociative and associative ligand exchange. (2013) (18)
- Metal alkoxides - models for metal oxides. 11. Synthesis and properties of mixed alkyl/aryl/benzyl alkoxides of formula 1,2-W2R2(OR')4 and W2R(OR')5(M.tplbond.M) (1986) (18)
- Direct observation of the conversion of a tertiary butoxide ligand to hydrido-oxo ligands with the liberation of isobutylene at a ditungsten center (1994) (18)
- Detailed electronic description of triple bonds between transition metal atoms and verification by photoelectron spectroscopy. (1977) (18)
- Reactivity of Metal-Metal Bonds (1981) (18)
- The tungsten-tungsten triple bond. 5. Chlorine atom substitution reactions involving dichlorotetrakis(diethylamido)ditungsten. Preparation, properties, structures, and dynamical solution behavior of bis(trimethylsilylmethyl)-, dibromo- and diiodotetrakis(diethylamido)ditungsten (1977) (18)
- Tetradecaisopropoxydihydridotetratungsten(IV). Oxidative addition of PrO-H across a tungsten-to-tungsten triple bond (1979) (18)
- Ring-opening of lactides and related cyclic monomers by triaryltin(IV) alkoxides and amides (2001) (18)
- Developing the reactivity of multiple bonds between metal atoms: inorganic functional groups (1991) (18)
- Ring-Opening of σ-Thienyl and σ-Furyl Ligands at Ditungsten (M⋮M) Centers (1997) (18)
- Reactions of transition-metal-nitrogen .sigma.-bonds. 5. Carbonation of tetrakis(diethylamido)chromium(IV) to yield binuclear chromium(III) and -(II) carbamato complexes (1978) (18)
- Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 1. Alkyne-promoted metal-to-metal alkyl migrations, W.tplbond.W/C.tplbond.C bond metathesis, and metallacyclopropene formation (1989) (18)
- Preparation, structure, and bonding of Mo2(OCH2CMe3)6(.mu.-.eta.1,.eta.2-NCNMe2) (1987) (18)
- Hexakis(neopentoxy)dimolybdenum. Preparation, characterization, and reactions with Lewis bases and carbon dioxide (1977) (18)
- Tetranuclear halide-alkoxide clusters of molybdenum formed by the coupling of M-M triple-bonded dinuclear compounds. Synthesis, characterization, and molecular structures of Mo4F2(O-iso-Pr)10, Mo4X3(O-iso-Pr)9, and Mo4X4(O-iso-Pr)8 (X = chloride, bromide, iodide) (1988) (18)
- Preparation and characterization of hexacyclohexoxido- and trispinacolato-ditungsten (MM). A comparison of staggered and eclipsed ethane-like O3WWO3 units (1987) (17)
- Reactions of metal-metal multiple bonds. 15. Reactions of M2(OR)6(M.ident.M) compounds (M = molybdenum, cobalt) with 9,10-phenanthrenequinone and tetrachloro-1,2-benzoquinone (1988) (17)
- THE MOLYBDENUM‐MOLYBDENUM TRIPLE BOND. 4. INSERTION REACTIONS OF HEXAKIS(ALKOXY)DIMOLYBDENUM COMPOUNDS WITH CARBON DIOXIDE AND SINGLE‐CRYSTAL X‐RAY STRUCTURAL CHARACTERIZATION OF BIS(TERT‐BUTYLCARBONATO)TETRAKIS(TERT‐BUTOXY)DIMOLYBDENUM (1978) (17)
- A molecular model for the reductive cleavage of carbon monoxide to carbide and oxide on reduced metal oxides (1987) (17)
- Interconverting multiple bonds between molybdenum and tungsten atoms: oxidative-additions and reductive-eliminations from dinuclear centers (1986) (17)
- Reactions of ditungsten hexaalkoxides with alkynylplatinum(II) complexes: formation of heterometallic dicarbido complexes in competition with products derived from alkyne metathesis (1987) (17)
- Oxalate bridged triangles incorporating Mo2(4+) units. Electronic structure and bonding. (2010) (17)
- Reactions of triply bonded dimetal compounds. Reversible addition of carbon monoxide to a hexakis(alkoxy)dimolybdenum compound. A molecule with a carbonyl-bridged metal-metal double bond (1978) (17)
- Detailed structure of bis(.mu.-trimethylsilylmethylidyne)-tetrakis(trimethylsilylmethyl)ditungsten(W-W) (1978) (17)
- The molybdenum-molybdenum triple bond. 14. Preparation and characterization of mixed alkoxy-thiolate compounds of formula Mo2(OR)2(SAr)4 (M.tplbond.M) (1984) (17)
- Metal alkoxides: models for metal oxides. 3. Further studies of the carbonylation of hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M) and characterization of M2(O-i-Pr)6(py)2(μ-CO)(M:M) compounds (1982) (17)
- Thienyl carboxylate ligands bound to M2 quadruple bonds involving molybdenum and tungsten. Models for dimetallated polythiophenes. (2002) (17)
- Metal Alkoxides - Models for Metal Oxides. 18. Polynuclear Metal Hydrido Alkoxides. Reactions of W4(H)2(O-i-Pr)14 and W2(H)(O-c-C5H9)7(HNMe2) with Carbon-Carbon, Carbon-Oxygen, and Carbon-Nitrogen Multiple Bonds (1995) (16)
- Synthesis, structural characterization, thermolysis and volatility study of the Schiff base complex Cu[CH3C(O)CHC(NCH2CH2OCH3)CH3]2 (2001) (16)
- Origin of Different Coordination Polyhedra forCu[CF3C(O)CHC(O)CF3]2L, (L = H2O, NH3) (1995) (16)
- Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-carboethoxy-2-carboxylatoazulene ligands. (2007) (16)
- The tungsten-tungsten triple bond. 17. Mixed amido-phosphido compounds for formula M2(PR2)2(NMe2)4. Comparisons of amido and phosphido ligation and bridged and unbridged isomers (1992) (16)
- Insights into the metathesis reaction involving M-M, C-C, and M-C triple bonds from computations employing density functional theory on model compounds M2(OH)6 and M2(SH)6, where M = Mo and W. (2002) (16)
- Role of cationic trans intermediates in promoting the insertion of unsaturated hydrocarbons into platinum-hydrogen and platinum-carbon bonds. Insertion reaction involving compounds of the type trans-[methyl(.eta.2-allene)bis(dimethylphenylphosphine)platinum](1+)Z(1-) (1975) (16)
- Reactions of alkynyl- and alkenylplatinum(II) compounds. 2. Study of the reaction between anhydrous hydrogen chloride and diethynylbis(dimethylphenylphosphine)platinum(II). Evidence for platinum-stabilized vinyl cations (1977) (16)
- Photophysical properties of MM quadruply bonded complexes (M = Mo, W) supported by carboxylate ligands: charge delocalization and dynamics in S1 and T1 states. (2012) (16)
- Notable features in the molecular structure of W2(OCH2-t-Bu)6(NCNMe2)3: Three different modes of bonding for NCNMe2(2-) ligands (1984) (16)
- On the nature of the olefination reaction involving ditungsten hexaalkoxides and aldehydes or ketones (1992) (15)
- Modeling the catalyst resting state in aryl tin(IV) polymerizations of lactide and estimating the relative rates of transamidation, transesterification and chain transfer (2004) (15)
- Imino-ether complexes of platinum: cis-[PtCl2(NHC(OR)Me)2] and [PtCl4(NHC(OR)Me)2], where R = Me, Et and Pri. Preparation, characterization and X-ray structure for [PtCl4(NHC(OPri)Me)2]2 (1991) (15)
- Oxalate-bridged dinuclear M2 units: dimers of dimers, cyclotetramers, and extended sheets (m = Mo, W, Tc, Ru, and Rh). (2005) (15)
- .beta.-Hydrogen effects in alkylalkoxides of dimolybdenum (M.tplbond.M) (1983) (15)
- Ring-opening polymerization reactions of propylene oxide catalyzed by porphyrin metal 3+ complexes of aluminum, chromium and cobalt. (2013) (15)
- Dicarbonyl and tricarbonyl adducts of (W {triple_bond} V W){sup 6+}- containing complexes. Preparation and structures of W{sub 2}(OCMe{sub 2}CF{sub 3}){sub 6}(CO){sub 2} and W{sub 2}(OCMe(CF{sub 3}){sub 2}){sub 4}(NMe{sub 2}){sub 2}(CO){sub 3} (1995) (15)
- [K([18]crown‐6)]+ [Mo4(μ4‐H) (OCH2tBu)12]−, the First Alkoxidohydrido Cluster of Molybdenum, Evidence for a Rare, if not the First, Example of a μ4‐Hydride (1994) (15)
- Influence of the metal (Al, Cr, and Co) and substituents of the porphyrin in controlling reactions involved in copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 3. Cobalt chemistry. (2013) (15)
- Covalenty linked molybdenum-molybdenum quadruple bonds. Dioxypyridazine dianion and 2-imidazolinethionate as bridges between dimolybdenum fragments (1993) (15)
- The tungsten-tungsten triple bond. 3. Dimethyltetrakis(diethylamido)ditungsten. Structure and dynamical solution behavior (1976) (15)
- Hexadecamethoxy- and hexadecaethoxy-tetratungsten: preparation and X-ray crystal and molecular structure of W4(OEt)16 (1981) (15)
- A new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula [M4(OR)12] (1988) (15)
- The tungsten-tungsten triple bond. 2. Preparation, structure, and dynamical behavior of dichlorotetrakis(diethylamido)ditungsten (1976) (15)
- A convenient synthesis of trialkylalkylidyne tungsten (6+) compounds and the X-ray crystal structure of (Me3CCH2)3WCPh(py) (1990) (14)
- The tungsten-tungsten triple bondXVI. Bis(cyclopentadienyl)- and bis(indenyl)tetradimethylamidoditungsten (WW) (1988) (14)
- Modeling the chemistry of hydrotreating; the hydrodesulfurization, hydrodenitrogenation, hydrodeoxygenation and hydrodemetallation of fossil fuels (1997) (14)
- Cycloalkyne ligands formed by the coupling of polymethylene-bridged alkylidynes: LnM.tplbond.C(CH2)nC.tplbond.MLn .fwdarw. L2nM2[.mu.-C2(CH2)n] (1991) (14)
- Bonds Between Metal Atoms: A New Mode of Transition Metal Chemistry. (1982) (14)
- The molybdenum-molybdenum triple bond. 12. Preparation and characterization of bis(tert-butyl mercaptido)tetrakis(dimethylamido)dimolybdenum(M.tplbond.M) (1983) (14)
- Mo2 paddlewheel complexes functionalized with a single MLCT, S1 infrared-active carboxylate reporter ligand: preparation and studies of ground and photoexcited states. (2014) (14)
- Preparation and characterization of the heptachlorobis(tetrahydrofuran)ditungstate and octachloro(tetrahydrofuran)ditungstate anions: [Ph4P][W2Cl7(THF)2] and [Ph4P][W2Cl8(THF)] (1988) (14)
- 9,10-Anthracene dicarboxylate bridged complexes with M2 quadruply bonded dimetal units: [[M2(O2CtBu)3]2(mu-9,10-An(CO2)2)], where M = Mo or W. (2004) (14)
- Addition of dimethylcyanamide to hexakis(alkoxy)dimolybdenum compounds (1979) (14)
- Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4'-azodibenzoate and comparison with t2g 6-Ru(II) centers by 4,4'-azodiphenylcyanamido ligands. (2006) (14)
- Cationic acetylene, acetylide, and carbene complexes of platinum(II) (1970) (14)
- Metal-metal quadruple bonds supported by 5-ethynylthiophene-2-carboxylato ligands: preparation, molecular and electronic structures, photoexcited state dynamics, and application as molecular synthons. (2013) (14)
- Interconverting edge-sharing and face-sharing bioctahedral dinuclear tungsten(III) phosphine complexes. Preparations, properties, and structures of W2Cl6L4, where L = PMe3, PEt3, and P(n-Bu)3, W2Cl6L3, where L = PEt3 and P(n-Bu)3, and [HPEt3]+[W2Cl7(PEt3)2]- (1993) (14)
- A diphosphide adduct of ditungsten-hexaisopropoxide: X-ray crystal structure of W2(OPri)6(py)(μ-P2) (1985) (14)
- Sexithiophenes mediated by MM quadruple bonds: MM = Mo2, MoW, and W2. (2009) (14)
- Pyridine, isocyanide, carbodiimide and allene adducts of hexakis (trifluoromethyl t-botoxy) ditungsten. A comparison of ligand binding to W2(OtBu)6 and W2(OCMe2CF3)6 (1998) (14)
- Metal alkoxides. Models for metal oxides. 18. Structure, bonding and dynamic behavior of bis(.eta.2-ethylene)hexakis(neopentoxy)ditungsten. Studies of the reversible addition of carbon-carbon double bonds to a tungsten-tungsten triple bond (1992) (14)
- Molecular Routes to Metal−Carbides, −Nitrides, and −Oxides. 3.1 Chemical Vapor Deposition Employing X3W⋮*CCMe3, Where X = CH2CMe3, OtBu, and OtBu-d9 and *C = 12C or 13C, and a Comparison with the Chemistry of (tBuO)3W⋮N (1998) (14)
- Synthesis and characterization of trans-M2(T(i)PB)2(O2C-CH=CH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(T(i)PB)2L2, where T(i)PB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand. (2011) (13)
- The remarkable role of steric factors in the reactions of alkynes (HCCH and MeCCMe)with ditungsten hexa-alkoxides: crystal and molecular structures of W2(OPri)6(py)2(µ-C2H2), W2(OCH2But)6(py)2(µ-C2Me2), and W2(OPri)6(µ-C4R4)(C2R2), where R = H and Me (py = pyridine) (1983) (13)
- Reactions between certain trialkoxytungsten alkylidyne complexes and carbon monoxide. Competitive carbon-carbon bond formation leading to alkyne or ketenyl complexes (1989) (13)
- Third-order nonlinear optical properties of complexes with MM triple and quadruple bonds (M = Mo, W) at 1064 nm by degenerate four-wave mixing. (2002) (13)
- In search of metal-metal metathesis in the chemistry of compounds containing metal-to-metal triple bonds between molybdenum and tungsten atoms (1978) (13)
- Organometallic chemistry of d3d3 dimolybdenum and ditungsten (1990) (13)
- Incorporating metal-metal multiple bonds into heterometallic chains: bis[tris(trimethylstanyl)tin]tetrakis(dimethylamido)dimolybdenum and -ditungsten and related compounds (1983) (13)
- Tungsten(6+) Tris(pinacolate): Structure and Comments on the Preference for an Octahedral Geometry Relative to Trigonal Prismatic (D3h) for a d0 Complex in the Presence of Strong .pi.-Donor Ligands (1994) (13)
- Intriguing aspects of 1,2-dialkyldimolybdenum and -ditungsten (M.tplbond.M) chemistry (1979) (13)
- On the remarkable structural diversity and kinetic lability of TpC*CaX complexes (X = NSi2Me6, OC6H4-p-Me, TpC*) where TpC* = tris[3-(2-methoxy-1,1-dimethylethyl)pyrazolyl]hydroborate. (2009) (13)
- A UV photoelectron spectroscopic investigation of the bonding in some tri-, tetra-, and pentacoordinated dialkylamino compounds of chromium, molybdenum, niobium, and tantalum (1980) (13)
- The preparation and characterization of M2(OEPh3)2(NMe2)4,where M = Mo and W and E = C and Si. The x-ray crystal structures of gauche-W2(OCPh3)2(NMe2)4, anti-Mo2(OCPh3)2(NMe2)4 and anti-W2(OSiPh3)2(NMe2)4 (1991) (13)
- Covalent compounds of quadrivalent transition metals. Part IV. Niobium(IV) dialkylamides (1971) (13)
- Reductive cleavage of carbon monoxide by tetranuclear tungsten alkoxide clusters (1989) (13)
- Highly efficient metal(iii) porphyrin and salen complexes for the polymerization of rac-lactide under ambient conditions. (2019) (13)
- Reactions of metal-metal multiple bonds. 11. A comparison of the reactivity of M2(OR)6 (M.tplbond.M) and M2(OR)4(R'COCHCOR')2 (M.tplbond.M) compounds (M = Mo, W) with the .pi.-acid ligands CO, RC.tplbond.CR and RNC (1984) (13)
- Comparison of the relative .pi.-donor abilities of amido and phosphido ligands. 1,2-Bis(di-tert-butylphosphido)tetrakis(dimethylamido)dimolybdenum and -ditungsten: 1,2-M2(P(tert-Bu)2)2(NMe2)4(M.tplbond.M) (1987) (13)
- Preparation and Structures of Arylmolybdenum(6+) Nitrido Compounds: (2,4,6-Me3C6H2)3Mo.tplbond.N and (2-Me2NCH2C6H4)2(tBuO)Mo.tplbond.N (1995) (13)
- Reductive Cleavage of Aldehydes to Oxo−Alkylidene and Oxo−Alkylidyne Complexes in Their Reactions with W2(OCH2tBu)6(py)2 (2000) (13)
- Bis(benzyl)- and bis(neopentyl)tetra(propionato)ditungsten (M .tplbond. M). Axial ligation and unprecedentedly short tungsten-tungsten distances for the RW .tplbond. WR unit (1984) (13)
- Diallyl- and bis(2-methylallyl)tetrakis(dimethylamino)ditungsten: W2(.mu.-.eta.3-C3H5)2(NMe2)4 and W2(.mu.1-C4H7)2(NMe2)4 (M.tplbond.M). Comments on ligand-metal .pi.-interactions at (W.tplbond.W)6+ centers (1988) (12)
- An allene adduct of ditungsten hexa-tert-butoxide: prediction of a stabilized .mu.-.eta.3-CH2CCH2 moiety (1988) (12)
- Tungsten-carbon, carbon-carbon and carbon-hydrogen bond activations in the chemistry of W2R2(OR')4(W.tplbond.W) complexes. 3. Competitive .alpha.-hydrogen versus .beta.-hydrogen eliminations and ethylene-to-acetylene hydrogen transfers (1989) (12)
- Mechanism of the insertion of an acetylene into a methylplatinum(II) bond (1972) (12)
- M2(hpp)4Cl2 and M2(hpp)4, where M = Mo and W: preparations, structure and bonding, and comparisons with C2, C2H2, and C2Cl2 and the hypothetical molecules M2(hpp)4(H)2. (2003) (12)
- Mixed valence complexes involving MM quadruple bonds (M=Mo or W) (2008) (12)
- Factors influencing the reductive cleavage of C-x multiple bonds in their reactions with meal-meal multiple bonds (X = C, N, O, S). (2001) (12)
- Comparative studies on the electronic structures of tetraformatoditungsten and dimethyltetraformatoditungsten by the relativistic X.alpha.-SW method: a d3-d3 metal dimer with a quadruple metal-metal bond (1985) (12)
- Metal alkoxides - models for metal oxides. 6. The linking of alkyne and nitrile fragments at ditungsten centers. Preparation and characterization of W2(O-tert-Bu)6(CHCHC(Ph)N), W2(O-iso-Pr)7(CH2CHC(Ph)N), W2(OCH2-tert-Bu)6(N(CMe)4N)(py), and W2(O-iso-Pr)7(NHC(Me)CHCHC(Me)N) (1984) (12)
- Evaluating the Role of π-Donor Ligands in Transition Metal Chemistry. Applications of Fenske-Hall Molecular Orbital Calculations and Mulliken Population Analyses (1987) (12)
- Oxidative-additions to (W.tplbond.W)6+ centers: the influence of Lewis base association reactions (1983) (12)
- Photophysical properties of cis-Mo2 quadruply bonded complexes and observation of photoinduced electron transfer to titanium dioxide. (2014) (12)
- Direct observation of ligand migration in the reversible addition of trimethylphosphine to 1,2-Mo2(CH2Ph)2(OPr-iso)4 and structural characterization of (Me3P)(PhCH2)2(iso-PrO)Mo.tplbond.Mo(OPr-iso)3 and 1,2-Mo2(CH2Ph)2(OPr-iso)4(dmpm), where dmpm = bis(dimethylphosphino)methane (1992) (12)
- Thermochemistry of some metal-to-metal triple bonds (1978) (12)
- Reactions of alkynylplatinum(II) compounds with aprotic substrates (1977) (12)
- The relationships between 13C nuclear magnetic resonance parameters, trans-influences, and ligand reactivities for methylplatinum compounds (1971) (12)
- Monoisocyanide adducts of ditungsten hexaalkoxides. Synthetic, structural, and theoretical investigations into the nature of C.tplbond.N bond order reduction (1987) (12)
- Preparation and characterization of the kinetic and thermodynamic isomers of dinuclear molybdenum and tungsten complexes with metal–metal triple bonds supported by p-tert-butylcalix[4]arene anions† (1998) (12)
- The tungsten-tungsten triple bond. 10. Ditungsten hexapivalate (1985) (12)
- Bis(2,2′-bipyridyl)diisopropoxomolybdenum(II): A spin-state equilibrium for a complex of a second-row transition element (1985) (12)
- Molecular, electronic structure and spectroscopic properties of MM quadruply bonded units supported by trans-6-carboethoxy-2-carboxylatoazulene ligands. (2010) (12)
- Regioregular and Regioirregular Oligoether Carbonates: A 13C{1H} NMR Investigation (2004) (12)
- The remarkable alcoholysis reaction and structure of trans-bis(.alpha.-chlorovinyl)bis(dimethylphenylphosphine)platinum(II) (1976) (12)
- Triple bonds between molybdenum and tungsten atoms supported by thiolate ligands: (RS)3MM(SR)3 (1985) (12)
- Siloxide and triflate gallium(III) complexes supported by the BDI ligand. (2001) (12)
- Metal alkoxides: models for metal oxides. XIII: NMR spectroscopic and theoretical investigations into the reduction of alkynes bonded to hexaalkoxides of dimolybdenum and ditungsten (1988) (12)
- An unexpected carbon-carbon bond formation in the reaction between Mo2(ONp)6(.mu.-NCNEt2) and 2-butyne (1986) (12)
- Triple bonds between tungsten atoms with ancillary dimesitylboroalkoxide ligands. Preparations, properties and structures of W2(NMe2)4[OB(Mes)2]2 and W2(OBut)4[OB(Mes)2]2 (1993) (12)
- Carbon-nitrogen bond formation in the reaction between tetrakis(dimethylamido)molybdenum(IV) and 2,6-dimethylphenyl isocyanide. Preparation and characterization of the first homoleptic metallaamidine complex: Mo(.eta.2-Me2NC:NC6H3Me3-2,6)4. (1986) (12)
- A new series of alkyldimolybdenum M.tplbond.M compounds: direct observation of rotation about the triple bond and alkyl ligand transfer (1980) (12)
- Further investigation of the ring-opening polymerization of propylene oxide. Catecholate derivatives of Zn(II) and Al(III) (2003) (12)
- Hexakis(tert-butyldimethylsiloxy)ditungsten and its reaction with ethyne. Hydrogen atom transfer reactions involving bridging ethynyl, ethyne, vinyl and ethylidyne ligands. Crystal structures of [W2(OSiButMe2)6], [W2(OSiButMe2)6(µ-C2H2)(C5H5N)] and [W2(OSiButMe2)5(µ-CCH)] (1991) (11)
- Metal alkoxides - models for metal oxides. 10. Synthesis and properties of alkyl alkoxides of formula 1,2-Mo2R2(OR')4 and Mo2R(OR')5 (M.tplbond.M) (1986) (11)
- Hexakis(dimethylamido)ditungsten. First structurally characterized molecule with an unbridged triple bond between tungsten atoms (1975) (11)
- Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Mo₂ Quadruple Bonds: Suppression of the Photochemical Enol-to-Keto Transformation. (2015) (11)
- 1,3-Ditungstacyclobutadienes. II: The synthesis of alkoxide derivatives of W2(μ-CSiMe3)2(CH2SiMe3)4 and investigations of the electronic structures of the M2(μ-CSiMe3)2 core as a function of dn-dn interactions (N=0, M=Ta; n=1, M=W; n=2, M=Re) (1987) (11)
- POLYNUCLEAR METAL HYDRIDO ALKOXIDES. 2. HYDROGENATION OF 1,2-W2(IBU)2(OIPR)4. PREPARATION, CHARACTERIZATION, AND SOME REACTIONS OF W6H5(CIPR)(OIPR)12, W2(H)2(OIPR)4(DMPE)2, AND W4(H)4(DMPM)3, WHERE DMPE = BIS(DIMETHYLPHOSPHIN O)ETHANE AND DMPM = BIS(DIMETHYLPHOSPHINO)METHANE (1997) (11)
- Reactions of W2(H)(OR)7, W2(OR)6(py)2 and W4(OCH2cC4H7)12 compounds (R = Pri, CH2But, cC5H9) with azobenzene, 1,2-diphenylhydrazine and 1,1-dimethylhydrazine (1997) (11)
- Preparation and characterization of M2(SeAr′)6 and mixed ligand M2(OR)2(SeAr′)4 species (M = Mo, W) (1990) (11)
- The dimolybdenum pentapivalate anion: X-ray crystal structure and dynamic solution behaviour and comments on the substitutional lability of containing compounds (1993) (11)
- Kinetic control in the alcoholysis reaction involving hexakisdimethylamidodialuminium and tert-butanol. Preparation, crystal and molecular structures of Al(OBut)3(HNMe2) and Al2(NMe2)(OBut)5 (1990) (11)
- Facile cleavage of the molybdenum.tplbond.molybdenum bond in reactions between Mo2(OBut)6 and aryl azides and molecular oxygen (1981) (11)
- Hexakis(2,4,6-trimethylbenzenethiolato)dimolybdenum (Mo2(SC6H2Me3)6). The first example of a compound containing a molybdenum-molybdenum triple bond supported by six mercaptido ligands (1983) (11)
- The molybdenum-molybdenum triple bond—XVII. Syntheses, spectroscopic and structural characterizations of Mo4F4(O—t-Bu)8 and Mo2F2(O—t-Bu)4(PMe3)2 (MoMo) (1985) (11)
- Analogies between alkoxides and oxide structures in the chemistry of molybdenum and tungsten (1985) (11)
- Molybdenum–molybdenum quadruple bonds supported by 9,10-anthraquinone carboxylate ligands. Molecular, electronic, ground state and unusual photoexcited state properties (2014) (11)
- The Tetradecaisopropoxydihydridotetratungsten Story. (1980) (11)
- Electronic coupling between molybdenum or tungsten quadruple bonds linked by dicarboxylate ligands (2003) (11)
- A new route for the preparation of enriched iso-polylactide from rac-lactide via a Lewis acid catalyzed ring-opening of an epoxide. (2017) (11)
- Bis[benzylbis(dimethylamido)molybdenum] and -tungsten (M.tplbond.M) compounds and their reactions with carbon dioxide and 1,3-diaryltriazenes. A radical difference (1982) (11)
- X-Ray crystal structure of hexakis(dimethylamino)dimolybdenum. A new compound with a metal-to-metal triple bond (1974) (11)
- MM quadruple bonds supported by cyanoacrylate ligands. Extending photon harvesting into the near infrared and studies of the MLCT states (2013) (11)
- Substrate Uptake and Activation by Dimolybdenum and Ditungsten Hexaalkoxides–Factors Influencing the Cleavage of C–X Multiple Bonds in the Reactions Between [Mo2(OR)6] (R tBu or CH2tBu) and Ar2CS, Et2NCN, and P(nBu)3 (1996) (11)
- Addition of 1,3-butadiene to a metal-metal triple bond. Preparation and structure of tungsten complex W2(OCH2-tert-Bu)6(py)(C4H6) (1991) (11)
- The First Observation of the Equilibrium 2 MM ⇄ M4 (M = Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer (1986) (11)
- The Tungsten−Tungsten Triple Bond. 20.1 Synthesis and Characterization of Cyclooctatetraenyltetrakis(dimethylamido)ditungsten (1996) (11)
- Use of over the counter oral relief aids or dietary supplements for the ring-opening polymerization of lactide. (2013) (11)
- The molybdenum-to-molybdenum triple bond. 5. Preparation and structure of dimethyltetrakis(dimethylamido)dimolybdenum (1978) (11)
- An equilibrium involving edge- and face-shared bioctahedral d3-d3 ditungsten complexes: W2Cl6(PEt3)4 and W2Cl6(PEt3)3 (1989) (11)
- The molybdenum-molybdenum triple bond. 16. Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum(M.tplbond.M). An example of a nonbridged dinuclear bis(carbene) complex (1985) (11)
- Insertion reactions of hexaalkoxydimolybdenum and -ditungsten compounds with organic isocyanates. Syntheses and structures of W2(OCMe3)4[N(C6H5)C(O)OCMe3]2 and Mo2(O-i-Pr)4[N(C6H5)C(O)O-i-Pr] (1984) (11)
- Phosphinecarboxylate ligands formed by the insertion of carbon dioxide into metal−phosphido bonds. Preparation and structural characterization of tetrakis(di-tert-butylphosphinecarboxylato) dimolybdenum (1987) (11)
- Carbon dioxide exchange reactions involving early transition-metal NN-dimethylcarbamato compounds: reversible insertion of carbon dioxide into transition-metal–nitrogen σ-bonds (1975) (11)
- Selective hydrogenations of dienes and oiefins by [W2(OCH2But)6(py)2] (1995) (11)
- Reactions of platinum(II)-stabilised carbonium ions (1971) (10)
- Competitive carbon-carbon bond formation and cleavage and cluster formation in the reaction between 3-hexyne and hexaisopropoxyditungsten (1986) (10)
- W6(H)5(O-Pr-iso)13. A polynuclear-polyhydride tungsten complex supported exclusively by alkoxide ligands (1992) (10)
- Further studies of the reactions involving ethyne and M2(OBut)6, where M Mo and W. Polyacetylene formation versus formation of ethyne adducts and CC coupled products (1997) (10)
- Novel cyclobutadiene–platinum(II) and alkoxy-carbene–platinum(IV) cations (1971) (10)
- Organometallic Chemistry of [W2(OCH2tBu)8] (M=M): Substrate Uptake and Activation at a Tungsten–Tungsten Double Bond (1998) (10)
- The Physical and Electronic Structure of M2 Quadruply Bonded Complexes: A Density Functional Theory Study (2007) (10)
- Concerning the Mechanism of Ring-Opening Polymerization by Coordinate Catalysts: The 2D Homonuclear J-Resolved Spectrum of Poly(cyclohexene oxide) (1999) (10)
- Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 2. Metal-carbon bond homolysis and competitive alkane and dihydrogen eliminations in double .alpha.-hydrogen activation processes (1989) (10)
- M2δ-to-oxalate π* conjugation in oxalate-bridged complexes containing M–M quadruple bonds (2001) (10)
- Synthesis and X-ray crystal structures of [Me2NH2]+[Al(OSiMe3)4]− and Al2(OSiMe3)6 (1991) (10)
- Tristhiolatomolybdenum Nitrides, (RS)3Mo⋮N Where R = iPr and tBu, Preparation, Characterization and Comparisons with Related Trialkoxymolybdenumnitrides (2002) (10)
- Organometallic Chemistry of [W2(OCH2tBu)8] (1997) (10)
- Low co-ordination numbers for chromium in chromium(III) compounds (1968) (10)
- Nitro-substituted benzoates of dimolybdenum: the Mo24+ δ to ligand charge transfer band (1996) (10)
- Ditungsten hexaalkoxides: templates for organometallic chemistry and catalysis (1996) (10)
- A new structural type for an electron-precise, six-electron triangular metal cluster: W3O2(O-tert-Bu)8 (1992) (10)
- Alkyne adducts of ditungsten hexaneopentoxide and alkylidyne-capped tritungsten compounds supported by neopentoxide ligands (1986) (10)
- Preparation and Structure of [Mo4(OMe)2(OiPr)10]; Comments on Why [W2(OiPr)6] Dimerizes, Whereas [Mo2(OiPr)6] Does Not (1987) (10)
- The tungsten-tungsten triple bond18. Bridging and terminal allyl ligands in complexes of the formula W2(R)2(NMe2)4, where R C3H5 and C4H7 (1992) (10)
- Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n (1993) (10)
- Reaction between bis(benzyl)tetraisopropoxyditungsten(WW) and but-2-yne: W2(CH2Ph)2(OPri)4(η2-C2Me2)2 and W2(H)(OPri)4(µ-CPh)(µ-C4Me4). A terminal metal hydride with a 1H n.m.r. resonance 20 p.p.m. downfield of Me4Si (1985) (10)
- Electronic structure and excited-state dynamics of the molecular triads: trans-M2(T(i)PB)2[O2CC6H5-η6-Cr(CO)3]2, where M = Mo or W, and T(i)PB = 2,4,6-triisopropylbenzoate. (2012) (10)
- The molybdenum-molybdenum triple bond. 13. Preparations and characterization of bis(.beta.-diketonato)tetraalkoxydimolybdenum and -ditungsten compounds (1984) (10)
- Alkyne adducts of mixed chloro-dimethylamido ditungsten compounds (1986) (10)
- Tris(N,N'-dimethylethylenediamido)dimolybdenum (M.tplbond.M). A metallopropellane with a near-eclipsed central molybdenum nitride (Mo2N6) moiety (1980) (9)
- THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. (2013) (9)
- Preparation and Characterization of 1,3-Butadiene and Isoprene Complexes, W2(OCH2tBu)6(diene)(py), and Studies of the Selective Hydrogenation of 1,3-Dienes (1999) (9)
- Dimolybdenum bis((S,S,S)-triisopropanolaminate(3-)): a blue compound with an unusual Mo-Mo triple bond. (2000) (9)
- Metal to metal multiple bonds in ordered assemblies (2007) (9)
- Are internal flips of M-M multiple bonds within cubic or octahedral ligand fields symmetry allowed? (1991) (9)
- Catalytic formation of cyclic-esters and -depsipeptides and chemical amplification by complexation with sodium ions (2008) (9)
- Synthesis and characterization of M2(EPh3)2(NMe2)4 compounds (E = C, Si, Ge, Sn; M = Mo, W) (1993) (9)
- Alkyne adducts of ditungsten tetrapivalate: [W2(κ2-O2CtBu)4(μ-RCCR')2], where R = R' = Me, Et, Ph and R = Me, R' = Ph (2002) (9)
- Cyclopentoxyditungsten compounds and crystal and molecular structures and dynamic solution behavior of W sub 2 (. mu. -H)(O-c-C sub 5 H sub 9 ) sub 7 (HNMe sub 2 ) (1991) (9)
- Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 3.(1) Bridging and Chelating Isomers of M(2)(NMe(2))(2)(O approximately approximately CHMe approximately approximately O)(2), Where O approximately approximately CHMe approximately approximately O Is the Dianion of 2,2'-Ethylidenebi (1998) (9)
- Studies of Thermotropic Properties and the Mesophase of Mixtures of n-Alkanoates and Perfluoro-n-alkanoates of Dimolybdenum (MM) (1998) (9)
- Olefinic CC Double Bond Coordination to a MM Triple Bond: Bis(η2‐ethylene)hexakis (neopentyloxy)ditungsten (1987) (9)
- The tungsten-tungsten triple bond. 14. Factors influencing triple bonds between tungsten atoms having valence molecular orbital configurations of .sigma.2.pi.4 and .pi.4.delta.2 and preparation and characterization of bis(neopentyl)bis(acetato)bis(diethyldithiocarbamato)ditungsten (1987) (9)
- Coordination chemistry of complexes with metalmetal multiple bonds: Reversible coordination of cyanide ion by dimolybdenum and ditungsten hexaalkoxides (1994) (9)
- Photophysical studies of trans-bis(phenylethynyldiisopropylamidinato)bis(acetato)dimetal complexes involving MM quadruple bonds where M = Mo or W. (2010) (9)
- Hexaisopropoxybis(dimethylamino)dinitrosyldimolybdenum (1980) (9)
- Electronically-coupled MM quadruply-bonded complexes of molybdenum and tungsten. (2005) (9)
- Carbon-hydrogen bond activation and carbon-carbon bond formation in the reaction between ethylene and hexaisopropoxyditungsten (1987) (9)
- Oxygen atom transfer in the reaction between hexakis(dimethyl-tert-butylsiloxy)ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: ButO versus ButMe2SiO (1992) (9)
- On the mechanism of carboxylate ligand scrambling at Mo24+ centers: evidence for a catalyzed mechanism (1999) (9)
- How Do Two CC Double Bonds Add to One MM Triple Bond? Structure and Bonding in Bis (η2-ethylene)hexakis(neopentoxy)ditungsten†‡ (1990) (9)
- Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data. (2002) (9)
- A new structure type for a 6-electron triangulo tungsten cluster: W3(.mu.3-CMe)(.mu.-O-iso-Pr)3(O-iso-Pr)6 (1985) (9)
- Charge distribution in metal to ligand charge transfer states of quadruply bonded metal complexes (2015) (9)
- Unbridged and bridged isomers of W2(PCy2)2(NMe2)4: preparations, characterizations, and comments on thermodynamic and activation parameters for the closing of phosphido bridges in d3-d3 dinuclear compounds (1988) (8)
- Complexes with Polar WW Multiple Bonds: [W2(OiPr)4L(dmpe)2] (L = (H)2, CO) and [W2(O)4(μ-O){W(CO)(dmpe)2}2]†‡ (1995) (8)
- Heterogeneous electron-transfer rate constants for M2(O2CR)4(0)/+, where M = Mo, W, Ru, or Rh and R = alkyl or aryl. (2000) (8)
- Attempted preparation of a dimetallabenzyne. Preparation and crystal structure of W2(.mu.-C3Ph3)(.mu.-CPh)(NMe2)4 (M-M) (1992) (8)
- Tungsten-containing polyhedral oligosilasesquioxanes: synthesis, structure and reactivity of (c-C6H11)7Si7O9(O3W[NMe2]3) (1992) (8)
- 1,2-Bis(di-tert-butylarsenido)tetrakis(dimethylamido)dimolybdenum and -ditungsten. Synthesis, structures, and solution behavior (1987) (8)
- Bis(dimethylamido)tetrakis(N,N-dimethylcarbamato)dimolybdenum (1978) (8)
- CONCERNING THE FORMATION OF COMPOUNDS CONTAINING METAL-TO-METAL MULTIPLE BONDS. A STEREOSPECIFIC ALKYL-FOR-CHLORINE EXCHANGE REACTION INVOLVING COMPOUNDS WITH TUNGSTEN-TO-TUNGSTEN TRIPLE BONDS (1976) (8)
- Synthesis and substitution reactions of dinuclear molybdenum complexes containing Mo-Mo quadruple bonds and labile solvent ligands (1992) (8)
- The molybdenum-molybdenum triple bond. 7. Bis(1,3-di-p-tolyltriazenido)tetrakis(dimethylamido)dimolybdenum (1981) (8)
- Prospects for dinuclear transition metal chemistry illustrated by recent advances in the chemistry of dimolybdenum and ditungsten (1978) (8)
- Reactions of alkynyl- and alkenylplatinum(II) compounds. 3. Reactions of .alpha.-chlorovinylplatinum(II) compounds with protic acids (1977) (8)
- Reactions of metal-metal multiple bonds. 13. Reactions of diazoalkanes with hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M). Preparation and characterization of Mo2(O-iso-Pr)6(N2CPh2)2(py), W2(O-tert-Bu)6(N2C(p-tol)2)2, and Mo(O-tert-Bu)4(N2CPh2) (1984) (8)
- Ene-yne couplings at a ditungsten center to give alkylidene hydrido complexes supported by siloxide ligands (1993) (8)
- The first hydrocarbyl trinuclear and tetranuclear clusters of tungsten: W3O(CH2Ph)(O-i-Pr)9 and W3O(R)2(O-i-Pr)8 where R = CH2Ph,Ph, and W4(p-tolyl)2(O-i-Pr)10 (1987) (8)
- Metathetic reactions involving ditungsten hexapivalate. Preparation and structures of W2(O2CtBu)2(OtBu)2(NiPr2)2, W2(O2CtBu)4(NiPr2)2, W2(O2CtBu)2(OtBu)4 and Na2W4O4Cp2(O2CtBu)6 solvate where CpC5H5 (1995) (8)
- Insertion reactions of carbon dioxide with triply bonded ditungsten dialkylamido compounds. Structures and dynamic properties of the resulting carbamato complexes (1976) (8)
- Molecular Routes for the Synthesis of Metal Carbides, Nitrides, and Oxides. 1. Studies of the Thermal Decomposition of M2(OR)6 and M2(CH2Ph)2(OR)4 Compounds Where M = Mo and W (1995) (8)
- Molecular and electronic structures and photophysical properties of quadruply bonded dimetal complexes (M = Mo or W) supported by trans-arylethynylcarboxylate ligands where aryl = p-tolyl or 9-anthrancenyl. (2012) (8)
- Tetranuclear Phosphinidine, Phosphide, Arsenide, and Oxide Anionic Clusters of Molybdenum and Tungsten Supported by Neopentoxide Ligands: Na(18-crown-6)[M4(μ3-PSiMe3)(OCH2tBu)11], K(18-crown-6)[M4(μ3-E)(OCH2tBu)10] (E = P, As), K(18-crown-6)2[Mo4(μ3-O)(OCH2tBu)11] (1996) (8)
- Furan- and selenophene-2-carboxylato derivatives of dimolybdenum and ditungsten (M[quadruple bond]M): a comparison of their chemical and photophysical properties. (2012) (8)
- Metal-metal bonds. (1982) (8)
- New Routes to Alkylidyne‐Bridged Ditungsten Compounds Supported by Alkoxide or Siloxide Ligands by the Activation of Ethylene (1992) (8)
- Triple bonds between molybdenum and tungsten atoms supported by selenolate ligands: M2(SeAr)6 and M2(OPri)2(SeAr)4(Ar = mesityl) (1990) (8)
- Electronic coupling in covalently-linked MM quadruple bonds: M2δ to ligand π conjugation (2002) (8)
- Synthesis, Structure, and Bonding of [CpCoW2(OCH2tBu)6], and Comments on the Combining Properties of CO and CpCo (1992) (7)
- Dioxododecaisopropoxytetratungsten. Oxygen atom abstraction from acetone in reactions with hexaisopropoxyditungsten (WW) (1984) (7)
- Studies of mono substituted compounds of formula M2(NMe2)5X (M.tplbond.M), where M = molybdenum and tungsten and X = iodine, alkyl, aryl, and diphenylphosphido, and the bridged-1,1'-ferrocenyl complex W2(NMe2)(.mu.-(C5H4)2Fe) (1993) (7)
- Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 1. Preparation and Characterization of Complexes Derived from 2,5-Dimethylhexane-2,5-diol. (1997) (7)
- Spectroscopic Properties of a Series of Vinyl–Platinum Complexes (1973) (7)
- Tris(N,N'-dimethylethylenediaminato)dimolybdenum and tris(N,N'-dimethylethylenediaminato)ditungsten. A comparison of eclipsed and staggered triple bonds, .sigma.2.pi.4, between molybdenum and tungsten atoms in X3M.ident.MX3 compounds (1987) (7)
- Mixed alkoxide-anilide d3-d3 dimers of molybdenum and tungsten. The X-ray crystal structures of M2(OBut)4(HNPh)2(H2NPh)2 (M = Mo, W) (1991) (7)
- Carbon-13 nuclear magnetic resonance studies of organometallic compounds. VIII. Platinum(II) carbene derivatives (1975) (7)
- HB(3,5-Me2pyrazolyl)3− as an encapsulating ligand for BaII (1993) (7)
- TMPZnN(SiMe 3 ) 2 , [TMPZn( μ -O i Pr)] 2 and TMPZn[OCMe 2 C(O)OEt]. Their role in the ring-opening of rac -lactide and ε -caprolactone where TMP = 1,5,9-trimesityldipyrromethene (2016) (7)
- THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 8. BIS(6-METHYL-2-PYRIDYL)METHYLTETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM (1981) (7)
- The emerging chemistry of polynuclear metal hydrido alkoxides: HxMy(OR)z (1995) (7)
- Alkyne adducts of [W2(OCH2tBu)8]n (M = M): comparisons of bridging and terminal addition products. (2002) (7)
- Applications of Carbon‐13 NMR in Inorganic Chemistry (2007) (7)
- Reduction of α,β-unsaturated ketones and aldehydes by tungsten–tungsten triple bonds: formation of 1,2 and 1,4 adducts as opposed to CO cleavage (1991) (7)
- Bis(dimethylamido)tris(N,N-dimethylcarbamato)tantalum(V). Structure and dynamical solution behavior of a compound containing seven-coordinate tantalum (1978) (7)
- Tetranuclear tungsten cyclooctatetraenyl alkoxides [W2COT(OR)4]2, where R=Me, Et and Pr (2003) (7)
- Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten (2010) (7)
- Studies of oxalate-bridged MM quadruple bonds and their radical cations (M=Mo or W): on the matter of linkage isomers. (2005) (7)
- Concerning the ground state and S1 and T1 photoexcited states of the homoleptic quadruply bonded complexes Mo2(O2CC6H4-p-X)4, where X = C≡C-H or C≡N. (2013) (7)
- Preparation, characterization and electronic structure of W2(NMe2)2(ORf)4, where Rf = CMe2CF3, CMe(CF3)2 and C(CF3)3, as deduced by photoelectron spectroscopic studies and the single crystal X-ray structure for Rf = OCMe(CF3)2 (1998) (7)
- Oxidative addition of 1,4-diisopropyl-1,4-diazabutadiene to hexakisisopropoxydimolybdenum (MM). Mo2(Opri)6(PriNCHCHNPri and Mo2(OPri)5(PriNCHCHNPri)2 (1989) (7)
- Electroabsorption of dimers containing MM (M = Mo, W) quadruply bonded units: insights into the electronic structure of neutral coupled redox centers and their relationship with mixed valence ions. (2010) (7)
- Di-tert-butoxybis(arylimido)molybdenum(VI) compounds, [Mo(O-tert-Bu)2(NAr)(.mu.-NAr)]2, where Ar = phenyl and p-tolyl (1982) (7)
- Double bonds between molybdenum atoms supported by dimethylamido ligands: Mo2(NMe2)4(OR)4 compounds, where R 4- methylcyclohexyl and diisopropylmethyl (1989) (7)
- Reactions of Mo2(OR)6 (M.tplbond.M) compounds (R = iso-Pr and tert-Bu) with benzoyl peroxide (1983) (7)
- The tungsten-tungsten triple bond. 19. Preparation and characterization of W26+-containing compounds supported by amide/alkoxide and trifluoromethanesulfonate ligands (1992) (7)
- Mo[sub 4](H)[sub 3]/(O-t-Bu)[sub 7](HNMe[sub 2]). A novel hydrido cluster of molybdenum (1993) (7)
- Attack by allenes on a bridging alkylidyne ligand at a ditungsten centre: formation of a bridging allyl-η3-W1,σ-W2-alkylidene ligand (1985) (7)
- Reactions of metal-metal multiple bonds. 12. Reactions of organic halides (chloride, bromide, iodide) with hexaalkoxydimolybdenum and -ditungsten (M.tplbond.M) compounds. Preparation and characterization of hexaneopentoxydibromo(pyridine)dimolybdenum (M:M) (1984) (7)
- Preparation, Characterization, and Reactions of Dialkylamides and Alkoxides of Molybdenum and Tungsten (1976) (7)
- Substitution chemistry of MM quadruply bonded complexes (M = Mo or W) supported by the anion of 2-hydroxy-6-methylpyridine. (2007) (7)
- Two new structural types for d3-d3 dimers of molybdenum and tungsten: [K(18-crown-6)]+[Mo2(OCH2But)7]− and [W2{P(c-hexyl)2}3(OCH2But)3{HP(c-hexyl)2}] (1993) (7)
- Dimolybdenum bis-2,4,6-triisopropyl-benzoate bis-4-isonicotinate: a redox active analogue of 4,4'-bipyridine with ambivalent properties. (2008) (6)
- Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum (M.tplbond.M) (1982) (6)
- 1,3-Ditungstacyclobutadienes. 4. 1:1 Diphenyldiazomethane adducts W2(.mu.-CSiMe3)2X4.cntdot.(N2CPh2). A comparison of the effects of the supporting ligands, X = (trimethylsilyl)methyl versus isopropoxyl (1989) (6)
- THE SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURE OF ANTI-W2(GEPH3)2(NME2)4 (1991) (6)
- A skewed bridging alkyne adduct of a d3-d3 tungsten dimer: W2(.mu.-NMe2)2(.mu.-C2Me2)Cl4(py)2 (1985) (6)
- Metal alkoxides - models for metal oxides. 1. Preparations and structures of hexadecaalkoxytetratungsten compounds, W4(OR)16, where R = Me and Et, and octaoxotetraisopropoxytetrapyridinotetramolybdenum, Mo4(O)4(.mu.-O)2(.mu.3-O)2(O-i-Pr)2(.mu.-O-i-Pr)2(py)4 (1981) (6)
- Oxalate bridged heteronuclear compounds containing MM quadruple bonds (M = Mo and W) and their radical cations (2009) (6)
- REACTIONS OF METAL-METAL MULTIPLE BONDS. 9. α-DIKETONE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES: W2(OR)6(O2C2R′2)2 (M-M) (1984) (6)
- Further studies of the reactivity of cyclopentadienyl, substitutedcyclopentadienyl and indenyl ligands withM2Cl2(NMe2)4(M = Mo or W). Crystal and molecular structuresofMo2(C9H7)2(NMe2)4 andW2(C5H4Me)2(NMe2)4 (1997) (6)
- Hexakis(Dimethylamido)Ditungsten and Tungsten(IV) Chloride (2007) (6)
- Twelve-electron tetranuclear tungsten alkoxide clusters are not tetrahedral. Preparation, structure and bonding in W4(O)(OPri)10 and W4(O)(Cl)(OPri)9. Comparisons with the bonding in carbonyl clusters (1990) (6)
- The tungsten-tungsten triple bond. 11. Ligand redistribution reactions involving chloride and dimethylamide ligands at dimolybdenum and ditungsten (M.tplbond.M) centers induced by added tertiary phosphines. Preparations and characterizations of W2Cl2(NMe2)4(Me2PCH2PMe2), W2Cl3(NMe2)3(PMe2Ph)2, and W (1985) (6)
- The molybdenum-molybdenum triple bond. 10. Bis(1,3-diphenyltriazenido)- and bis(2-oxy-6-methylpyridino)tetraisopropoxydimolybdenum (1981) (6)
- Synthesis and reactivity of compounds of formula W(S)(OR)4 (1987) (6)
- A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W4(OCH2Pri)12(η2,μ4-CO)(CO)2 (1990) (6)
- Further comments on the lability of M2(O2CR)4 complexes and structural characterization of [Bu4nN]2+[Rh8(O2CBut)16(O2CMe)2(toluene)2]2− (1996) (6)
- Theoretical and spectroscopic investigations of the bonding and reactivity of (RO)3M[triple bond]N molecules, where M = Cr, Mo, and W. (2009) (6)
- Synthesis, X-ray crystal structure, and n.m.r. studies of trans-bis(dimethylpheylphosphine)bis[{dicarbido(4–)σ-Pt,σ-W1, η2-W2}-pentakis(t-butoxy)ditingsten(MM)]platinum(II) (1985) (6)
- Cyclooctatetraene ditungsten alkoxides: W2(μ-η5,η5-COT)(OR)4, where R = CH2tBu, iPr, and tBu (2002) (6)
- Diamagnetic anisotropy of MM bonded molecules for MMo or W: how much π is there and how do we slice it? (1987) (6)
- W2(n-Pr)2(.eta.2-C2Me2)2(O-iso-Pr)4, W2(.mu.-C2Me2)2(O-iso-Pr)4, and W4(.mu.-CEt)2(.mu.-C2Me2)2(.eta.2-C2Me2)2(O-iso-Pr)6. Competitive .alpha.- and .beta.-carbon-hydrogen activation pathways at a dimetal center (1987) (6)
- Hexaisopropoxydinitrosyldichromium and its reactions with nitrogen donor ligands (1980) (6)
- The tungsten-tungsten triple bond. 12. Bis(1,3-diaryltriazenido)bis(dimethylamido)diethylditungsten (M.tplbond.M) compounds (1986) (6)
- Bis(dimethylamine)tetrakis(tert-butylmercaptido)di-.mu.-sulfido-dimolybdenum(IV) (1982) (6)
- REACTIONS OF TRANSITION METAL‐NITROGEN Σ BONDS. 3. EARLY TRANSITION METAL N,N‐DIMETHYLCARBAMATES. PREPARATION, PROPERTIES, AND CARBON DIOXIDE EXCHANGE REACTIONS (1977) (6)
- Mo(NMe2)6Li2(THF)2 (1988) (6)
- On the molecular structure and bonding in a lithium bismuth porphyrin complex: LiBi(TPP)(2). (2014) (6)
- The non-perpendicular and non-parallel alkyne bridge in W2(μ-C2H2)(μ-OCH2tBu)2(OCH2tBu)61Dedicated to Professor Ken Wade, FRS, on the occasion of his 65th birthday.1 (1998) (6)
- Carbonylation of (ButO)3W≡CNMe2 and (PriO)3(py)2W≡CNMe2 (py=pyridine): two different modes of carbon−carbon bond formation (1986) (6)
- Correlating the magic numbers of inorganic nanomolecular assemblies with a fPd84g molecular-ring (2012) (6)
- [Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2″-terpyridine) Ruthenium (II)] (2+) Tetrafluoroborate. Preparation, Electronic Structure and Physical Properties (2008) (5)
- Chiral C2 and C1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior (2000) (5)
- Dioxobis(2,4‐Pentanedionato)Molybdenum(VI), MoO2(acac)2 and μ‐Oxodioxotetrakis(2,4‐Pentanedionato)Dimolybdenum)(V), Mo2O3 (acac)4 (2007) (5)
- Carbon-carbon and carbon-hydrogen bond activation at ditungsten centers supported by alkoxide ligands (1989) (5)
- Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide. (2013) (5)
- Formation and stability of 1,1- and 1,2-bis(dimethylamido)tetrakis(trimethylsiylmethyl)dimolybdenum(MoMo) (1980) (5)
- Further Studies on the Substitutional Behavior of 1,2-Mo2Br2(CH2SiMe3)4. Alkyl, Amide, Phosphide, Alkoxide, and Thiolate for Bromide Exchange and Isomerizations of 1,1- and 1,2-Mo2X2(CH2SiMe3)4 Compounds† (2000) (5)
- Polynuclear metal hydrido alkoxides. Preparation and characterization of Mo4(µ-H)3(OBut)7(HNMe2) and [K(18-crown-6)][Mo4(µ4-H)(OR)12] (R = Pri or CH2But) (1998) (5)
- Alkyne adducts of [W2(OCH2tBu)8]. Cases of perpendicular and skewed bridges in equilibrium with terminal bonded isomers (2003) (5)
- Modulating the M2δ-to-ligand charge transfer transition by the use of diarylboron substituents. (2013) (5)
- Reversible carbon-hydrogen bond oxidative addition across a W—W multiple bond (1997) (5)
- A study of the reaction between Mo2(OCH2CMe3)6(μ-η1,η2-NCNR2) compounds (R = Me and Et) and 2-butyne (1988) (5)
- On the solvatochromic properties of the oxalate-bridged complexes [(tBuCO2)3M2]2(μ-O2C2O2) where M=Mo or W (2004) (5)
- Femtosecond Study of Dimolybdenum Paddlewheel Compounds with Amide/Thioamide Ligands: Symmetry, Electronic Structure, and Charge Distribution in the 1MLCT S1 State. (2017) (5)
- Chalcogenide-bridged ditungsten (M–M) complexes: an experimental and theoretical study of the electronic structure and bonding in W2(μ-E)(μ-OCH2tBu)2(OCH2tBu)6, where E = O, S, Se or Te† (2001) (5)
- Foreword: Recent advances in metal alkoxide and amide chemistry (1998) (5)
- Coordination of N,N-chelated Re(CO)3Cl units across a Mo2 quadruple bond: synthesis, characterization, and photophysical properties of a Re-Mo2-Re triad and its component pieces. (2013) (5)
- The tungsten-tungsten triple bond. 9. Bis(1,3-diphenyltriazenido)tetrakis(dimethylamido)ditungsten (1979) (5)
- 1,2-dimetallacyclo-1,2-hexyne compounds of molybdenum and tungsten (1985) (5)
- Electronic structure and bonding in halide- and alkoxide-supported tetranuclear molybdenum clusters (1988) (5)
- Insights into the Schrock 'chop-chop' reaction gained from density functional theory and preparation and structure of W2(mu-PhCCPh)(SC6H4-2-Me)6. (2002) (5)
- Diolates of dimolybdenum and ditungsten (MM) with seven-, eight- and nine-membered rings (1991) (5)
- Molybdenum tetrahydroxiden+ (n = 0, 2), tetrahedral or square-planar? The dn-d10-n hole formalism for .pi.-donor and .pi.-acceptor ligand fields (1989) (5)
- Mo3[C(O)NMe2]6(CO)6(HNMe2)2. An unexpected product formed in the carbonylation of Mo(NMe2)4 displaying three distinct modes of carbamoyl molybdenum bonding (1987) (5)
- TMPMg n Bu(L), where L = THF, 2-MeTHF, pyridine and dimethylaminopyridine and TMP = 1,5,9-trimesityldipyrromethene: Reaction with lactide and ε -caprolactone (2017) (5)
- Electronic absorption spectra of M2L6 compounds containing metal-metal triple bonds of σ2π4 configuration (1987) (5)
- Concerning the photophysical properties of Re2(4+) and Re2(6+) carboxylate compounds. (2010) (5)
- 4-Nitrophenyl- and 4'-nitro-1,1'-biphenyl-4-carboxylates attached to Mo2 quadruple bonds: ground versus excited state M2δ-ligand conjugation. (2014) (5)
- Coupling C≡C, C≡N, and W≡W bonds. Preparation, and crystal and molecular structure of hexaneopentoxy(pyridine)[2-amido(2―)-W1,W1-5-amido(2-)-W2-3,4-dimethylhexa-2,4-diene]ditungsten W2(OCH2But)6-(py)(N[CMe]4N) (1983) (4)
- MM quadruply bonded complexes supported by vinylbenzoate ligands: synthesis, characterization, photophysical properties and application as synthons (2015) (4)
- Frank Albert Cotton. 9 April 1930 — 20 February 2007 (2008) (4)
- Concerning the reaction pathway of the metathesis reaction involving WW and CN triple bonds: a theoretical study. (2009) (4)
- Metal alkoxides: models for metal oxides. 14. Carbonylation of an ethylidyne-capped tritungsten alkoxide cluster to form W3(.mu.-CMe)(OCHMe2)9(CO)2: preparation, properties, and structure (1989) (4)
- W2Cl3(NMe2)3(PMe2Ph)2 and its reaction with ethyne to give (PMe2Ph)Cl2W(µ-NMe2)(µ-σ,η2–CHCH2)(µ-η2,σ-CH2NMe)WCl(NMe2)(PMe2Ph): a compound containing an azadimetallabicyclobutane core and a σ,π-vinyl ligand (1985) (4)
- Concerning the Relative Stabilities of Ferrocenyl and Platinum(II) Stabilized Carbonium Ions: Alcoholic Protonation of Trans-PtCL (Ethynylferrocene) (PMe2Ph)2 (1978) (4)
- Preparation and Characterization of (iPrO)4WW(η2-dmpe)2(CO), (η1-O2CH)(iPrO)4WW(η2-dmpe)2(H), [H(η2-dmpe)WWO2]2(μ-O), and W2(O)4(μ-O)[W(η2-dmpe)2CO]2(dmpe = Bisdimethylphosphinomethane), Compounds with W−W Bonds between Metal Atoms in Greatly Differing Oxidation States (1998) (4)
- Addition of anhydrous hydrogen chloride to bis(ethynyl)bis(dimethylphenyl-phosphine)platinum(II). A novel sequence of platinum(II) promoted addition–elimination reactions (1976) (4)
- Electronic coupling between molybdenum and tungsten quadruple bonds in molecular squares and extended chains linked by oxalate, acetylenedicarboxylate, and perfluoroterephthalate bridges (2001) (4)
- Reactions of [W2(OCH2tBu)8](MM) with diazobenzene and trimethylsilyldiazomethane. Preparation and structures of W2(OCH2tBu)8(NPh) and W2(OCH2tBu)8(N2C(H)SiMe3) (2003) (4)
- A study of the photochemical reaction between W2(OCH2 tBu) 6P4. Characterization of the phosphidocluster W4 (P) 2 (OCH2 tBu) 10 (1998) (4)
- Unexpected formation of anti-1,2-W2(SBut)2(NMe2)4 in the thiolysis of gauche-1,2-W2Cp2(NMe2)4 and W2COT(NMe2)4 with ButSH (2006) (4)
- The molybdenum-molybdenum triple bond. 6. Bis(2-oxy-6-methylpyridine)tetrakis(dimethylamido)dimolybdenum (1981) (4)
- Some studies of the substitution chemistry of [Rh2(OAc)2(CH3CN)4][BF4]2 with monodentate and bidentate tertiary phosphines (2000) (4)
- 2,5-Dianilinoterephthalate bridged MM quadruply bonded complexes of molybdenum and tungsten. (2007) (4)
- Stereoselective Polymerization of Lactide (2007) (4)
- The tungsten-tungsten triple bond. XV. Synthesis, structure and reactivity of 1,2-W2[CH(SiMe3)2]2(NMe2)4: the remarkable inertness of a sterically-encumbered tungsten-amido complex (1988) (4)
- Synthesis, Structure, and Photophysical Properties of Mo2(NN)4 and Mo2(NN)2(T(i)PB)2, Where NN = N,N'-Diphenylphenylpropiolamidinate and T(i)PB = 2,4,6-Triisopropylbenzoate. (2016) (4)
- Reactions of the 12-electron alkoxide-supported tungsten clusters W4(OR)12 (R = CH2-iso-Pr, cyclopentylmethyl) with isocyanides, nitriles, nitric oxide, and alkynes. Comparison with the reactivity of W2(OR)6 compounds (1992) (4)
- Addition of diphenyldiazomethane to hexa-alkoxydimolybdenum(MM) compounds: characterization of Mo2(OPri)6(N2CPh2)2(pyridine) by X-ray crystallography (1981) (4)
- Carbonyl adducts of dichlorotetrakis(dimethylamido)ditungsten and insertion of carbon monoxide into a tungsten-amido bond (1986) (4)
- The Use of Alkoxides and Related π-Donors in Organotransition Metal Chemistry as Illustrated by M2(OR)6 Compounds (M = Mo or W) (2014) (4)
- One‐pot regioselective and stereoselective terpolymerization of rac‐lactide, CO2 and rac‐propylene oxide with TPPMCl (M = Cr, Co, Al)/PPNCl binary catalyst (2018) (4)
- Comments on the Molecular Structure and Bonding In [W4Cl(O)(OiPr)9] and [W4(O)(OiPr)10]. Analogies with Tetranuclear Carbonyl Clusters (1989) (3)
- Oxygen atom abstraction from allylic alcohols and conjugated alkenyloxides (1992) (3)
- Cationic d3-d3 dinuclear compounds of tungsten: [W2(O2CBut)5]+X−, where X−=BF4− and CF3SO3− (1993) (3)
- Site-selective hydrogenolysis, hydrogenation and alcoholysis involving the homometallic cluster [W6H5(CPri)(OPri)12] (1996) (3)
- Mo2(OCH2tBu)6(Cp)Na(DME). Preparation, structure, and solution behavior (1996) (3)
- Mo2(O)(OCH2tBu)4(PMe3)4. Preparation and characterization of a partial hydrolysis product of Mo2(OCH2tBu)6 (1996) (3)
- d3–d3 Diolates of dimolybdenum and ditungsten: Part 4. Molybdenum derivatives of S(−)-1,1-diphenyl-1,2-propanediol, S(−)-1,1,2-triphenyl-1,2-ethanediol and (1R, 2R)-(−)-1,2-dicyclohexyl-1,2-ethanediol (2000) (3)
- Stepwise activation of σ-thienyl ligands at di-tungsten centres (1994) (3)
- Synthesis of core–shell (nano)particles involving TiO2, SiO2, Al2O3 and polylactide (2012) (3)
- Paramagnetic 1,3-dimetallacyclobutadienes of tungsten(VI): -2,4-bis(trimethylsilyl)-1,3-dihalogeno-l,1,3,3-tetrakis(trimethylsilylmethyl)-1,3-ditungstacyclobutadienes (1985) (3)
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- Carbon-carbon coupling of a .mu.-ethynyl ligand with an isocyanide at a ditungsten center. Preparation and structure of W2(.mu.-CCCNHXyl)(OSiMe2But)5(CNXyl)4, where Xyl = 2,6-Me2C6H3 (1993) (3)
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- Solution Studies of Ru 2 ( O 2 CR ) 4 n + Complexes ( n ) 0 , 1 ; O 2 CR ) (2003) (0)
- A Convenient Synthesis of Trialkylalkylidyne Tungsten (6+) Compounds and the X-Ray Crystal Structure of (Me3CCH2)3WCPh(py). (1990) (0)
- New precursors for metallic copper based on ethanolaminecomplexes of Cu(hfacac)(2) (1996) (0)
- Octa(isopropoxy)dimolybdenum and bis(nitrosyl)hexa(isopropoxy)dimolybdenum. Structure and bonding in compounds containing molybdenum atoms with fourteen valence shell electronic configurations. Technical report (1977) (0)
- METAL-TO-METAL TRIPLE BONDS-TO CLUSTER OR NOT TO CLUSTER? STRUCTURAL CHARACTERIZATION OF OCTAKIS(TERT-BUTOXY)TETRAKIS(μ-FLUORO)-TETRAMOLYBDENUM AND OCTAKIS(TERT-BUTOXY)TRIS(μ-FLUORO)-(μ-DIMETHYLAMIDO)-TETRAMOLYBDENUM (2002) (0)
- Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4 Compounds (M triple bond M) with Carbon Dioxide and 1,3-Diaryltriazenes. (1981) (0)
- Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(O-iPr)6 and W4(O-iPr)12. Part 2. Studies of Cluster Dynamics and the Equilibrium Between the 12-Electron Cluster and Two Metal-Metal Triple Bonds. A Symmetry-Allowed (π2 s (1989) (0)
- β-HYDROGEN EFFECTS IN ALKYLALKOXIDES OF DIMOLYBDENUM (MM) (1983) (0)
- Mo(OH)n+ 4 (n = 0, 2), Tetrahedral or Square-Planar? The dn-d10-n Hole Formalism for π-Donor and π-Acceptor Ligand Fields. (1989) (0)
- Electronic Structure and Bonding in Halide- and Alkoxide-Supported Tetranuclear Molybdenum Clusters. (1988) (0)
- MO,(OCH,~BU),(C~)N~(DME). Preparation, structure, and solution behavior (1996) (0)
- REACTIONS OF METAL-METAL MULTIPLE BONDS. 8. FORMING MOLYBDENUM-MOLYBDENUM QUADRUPLE BONDS BY REDUCTIVE ELIMINATION (ALKYL GROUP DISPROPORTIONATION) IN THE REACTIONS OF 1,2-MO2R2(NME2)4 COMPOUNDS (MM) WITH CARBON DIOXIDE AND 1,3-DIARY (1982) (0)
- An Equilibrium Involving Edge- and Face-Shared Bioctahedral d3-d3 Ditungsten Complexes: W2Cl6(PEt3)4 and W2Cl6(PEt3)3. (1989) (0)
- Metal Alkoxides - Metal Alkoxides - Models for Metal Oxides. Part 9. Hydridoditungsten Alkoxides: W2(H)(O-iPr)8Na·diglyme and W2(H)(I)(OCH2-tBu)6(H2NMe). Further Investigations of the Reaction Between W2(NMe2)6(M≡M) and iPrOH Leading to W4(H)2(O-iPr)14. (1986) (0)
- Substrate selective LPCVD of metallic films (1998) (0)
- QUADRUPLY BONDED M$_2$ COMPLEXES INCORPORATING THIENYLETHYNYL AND THIENYLVINYL CARBOXYLATES (2010) (0)
- METAL ALKOXIDES: MODELS FOR METAL OXIDES. 2. ADDITION OF ETHYNE, PROPYNE, AND 2-BUTYNE TO MO2(OR)6 (MM) COMPOUNDS (R = TERT-BU, ISO-PR, AND NEOPENTYL). CHARACTERIZATION OF μ-ALKYNE AND μ-C4H4 ADDUCTS AND AN EVALUATION OF THEIR ROLE I (1982) (0)
- Macromol. Chem. Phys. 8/2012 (2012) (0)
- Tungsten-Tungsten Triple Bond. Part 11. (1986) (0)
- (13)C NMR STUDIES PART 35, (13)C NUCLEAR MAGNETIC RESONANCE STUDIES OF ORGANOMETALLIC COMPOUNDS PART 1, TRANS-METHYLPLATINUM(II) DERIVATIVES (1974) (0)
- A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of eta3, eta5, eta6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions. (2006) (0)
- USING ELECTROABSORPTION SPECTROSCOPY TO GAIN INSIGHT INTO THE GROUND- AND EXCITED-STATE MIXED VALENCE PROPERTIES OF A SERIES OF DIMERS FORMED FROM METAL-METAL QUADRUPLY BONDED UNITS (2010) (0)
- Diallyl- and Bis(2-methylallyl)tetrakis(dimethylamido)ditungsten: W2(.mu±eta.3-C3H5)2(NMe2)4 and W2(η1-C4H7)2(NMe2)4 (MM). Comments on Ligand-Metal π-Interactions at (WW)6+ Centers. (1988) (0)
- CATIONIC PLATINUM(II) ACETYLENIC COMPLEXES AND THEIR DERIVATIVES PART 6, AMINOLYSIS AND OTHER REACTIONS OF CATIONIC PLATINUM(II) ALKOXYCARBENE COMPLEXES (1975) (0)
- Carbon-Nitrogen Bond Formation in the Reactions of Unsaturated Molecules with Mo(NMe 2 ) 4 (1987) (0)
- Survival special. Interview by Jennifer Trueland. (2003) (0)
- BONDS BETWEEN METAL ATOMS. A NEW MODE OF TRANSITION METAL CHEMISTRY (1982) (0)
- Oxotrimolybdenum (IV) Alkoxides: Mo3(micron 3-O)(micron 3-OR)(micron 2-OR)3(OR)6, Where R = i-Pr and CH2CMe3 - from Serendipitous Discovery to Total Synthesis. (1981) (0)
- Mechanistic studies aimed at the development of single site metal alkoxide catalysts for the production of polyoxygenates from renewable resources. (2015) (0)
- Factors Influencing the Reductive Cleavage of C—X Multiple Bonds in Their Reactions with Metal—Metal Multiple Bonds (X: C, N, O, S) (2002) (0)
- A Tetranuelear Tungsten Carbido Alkoxide Cluster with a Hydride Ligand: W 4( t-C)(NMe )(OCH z But)11 (H) (0)
- Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(O-iPr)6 and W4(O-iPr)12. Part 1. Preparation, Structure, and Bonding. The First Example of a Metal-Metal Triple Bond and Its 12-Electron Cluster. Analogies with Ethyne and (1988) (0)
- Reactions Involving Carbon Dioxide and Mixed Amido-Phosphido Dinuclear Compounds: M2(NMe2)4(PR2)2(MM), Where M: Mo and W. Comparative Study of the Insertion of Carbon Dioxide into Metal-Nitrogen and Metal-Phosphorus Bonds. (1990) (0)
- THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 13. PREPARATIONS AND CHARACTERIZATION OF BIS(β-DIKETONATO)TETRAALKOXYDIMOLYBDENUM AND -DITUNGSTEN COMPOUNDS (1984) (0)
- New Routes to Alkylidyne‐Bridged Ditungsten Compounds Containing Alkoxide or Siloxide Ligands by the Activation of Ethylene. (1992) (0)
- Oxygen Atom Abstraction from Allylic Alcohols and Conjugated Alkenyloxides. (1993) (0)
- METAL ALKOXIDES - MODELS FOR METAL OXIDES. 6. THE LINKING OF ALKYNE AND NITRILE FRAGMENTS AT DITUNGSTEN CENTERS. PREPARATION AND CHARACTERIZATION OF W2(O-TERT-BU)6(CHCHC(PH)N), W2(O-ISO-PR)7(CH2CHC(PH)N), W2(OCH2-TERT-BU)6(N(CME)4N)(P (1985) (0)
- Metal Alkoxides: Models for Metal Oxides. Part 16. Synthesis and Characterization of a New Class of Homoleptic 12-Electron Molybdenum and Tungsten Alkoxide Clusters of Formula M4(OR)12: Structural Characterization of Mo4(OCH2-c-Bu)12· (1989) (0)
- Heavier Main-group Atoms as Ligands to Transition-metal Centers (1987) (0)
- W6(H)5(O-i-Pr)12. A Polynuclear Polyhydride Supported Exclusively by Alkoxide Ligands. [Erratum to document cited in CA116:186641] (1995) (0)
- Detailed Structure of Bis-micron-(trimethylsilylmethylidyne)tetrakis-(trimethylsilylmethyl) ditungsten(W-W). (1977) (0)
- Alkoxide Clusters of Molybdenum and Tungsten (1996) (0)
- Chapter 8:Concerning the Solid State Packing of [(ButCO2)3M2]2(μ-9,10-anthracenedicarboxylate) Compounds (M = Mo or W) and Other Matters (2007) (0)
- Metallomesogens: Synthesis, Properties and Applications Edited by José Louis Serrano (University of Zaragoza). VCH: New York. 1996. xxii + 498 pp. $210.00. ISBN 3-527-29296-9. (1997) (0)
- Synthesis and Structure of (Ba3(OSiPh3)6(THF))×0.5THF, a Trinuclear Barium Siloxide Containing Low‐Coordinate Barium Ions. (1991) (0)
- Synthesis and Structure of (Mo4(OMe)2(OiPr)10); Why Does (W2(OiPr)6) Dimerize, While (Mo2(OiPr)6) Does Not? (1987) (0)
- Excited State Properties of Paddlewheel Complexes Involving Metal-Metal (m = MO, w) Quadruple Bonds Supported by Amidinate and Carboxylate Ligands (2010) (0)
- THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 15. COMPOUNDS WITH CHAINS OF METAL ATOMS HAVING M-M SINGLE AND TRIPLE BONDS: M2(M′(M′ME3)3)2(NME2)4 (MM) WHERE M = MO AND W AND M′ = SI AND SN (1985) (0)
- Contacting Organic and Organometallic Monolayers with Ferromagnetic Electrodes (2010) (0)
- Anything One Can Do, Two Can Do Too - And It's More Interesting. (1980) (0)
- Reactions of Metal-Metal Multiple Bonds. Part 16. Tetranuclear Halide-Alkoxide Clusters of Molybdenum Formed by the Coupling of M-M Triple-Bonded Dinuclear Compounds. Synthesis, Characterization, and Molecular Structures of Mo4F2(O-iP (1988) (0)
- Evidence for Equilibrium Between μ-Alkyne and Alkylidyne Complexes of Tungsten Alkoxides: [W2(OR)6(μ-C2R2′)] ↔ 2[(RO)3W ≡ CR′]. (1986) (0)
- NEW Σ-ETHYL COMPOUNDS OF DIMOLYBDENUM (MM) AND EVIDENCE FOR DINUCLEAR REDUCTIVE ELIMINATION WITH A CONCOMITANT METAL-METAL TRIPLE TO QUADRUPLE BOND TRANSFORMATION: ET-MM-ET → M::M + C2H4 + C2H6 (1978) (0)
- UTILIZING METAL TO LIGAND CHARGE TRANSFER STATES OF MM QUADRUPLY BONDED COMPLEXES FOR PHOTOVOLTAIC APPLICATIONS (2013) (0)
- POLYMERS FROM RENEWABLE RESOURCES: THE ROLE OF METAL ALKOXIDE CATALYSTS (2010) (0)
- EVOLUTION OF THE MLCT BAND FOLLOWING CHANGES IN OXIDATION STATE FOR HIGHLY COUPLED MIXED VALENCE COMPLEXES (2009) (0)
- 1,2-Bis(di-tert-butylarsenido)tetrakis(dimethylamido)dimolybdenum and -ditungsten. Synthesis, Structures, and Solution Behavior. (1988) (0)
- Tristhiolatomolybdenum nitrides, (RS)(3)Mo[triple bond]N where R = (i)Pr and (t)Bu, preparation, characterization and comparisons with related trialkoxymolybdenumnitrides. (2002) (0)
- REACTIONS OF METAL-METAL MULTIPLE BONDS. 12. REACTIONS OF ORGANIC HALIDES (CHLORIDE, BROMIDE, IODIDE) WITH HEXAALKOXYDIMOLYBDENUM AND -DITUNGSTEN (MM) COMPOUNDS. PREPARATION AND CHARACTERIZATION OF HEXANEOPENTOXYDIBROMO(PYRIDINE)DIMO (1984) (0)
- Phosphinecarboxylate Ligands Formed by the Insertion of Carbon Dioxide into Metal-Phosphido Bonds. Preparation and Structural Characterization of Tetrakis(di-tert-butylphosphinecarboxylato)dimolybdenum. (1988) (0)
- Formation of a σ,π-Vinyl Ligand by Hydrogen Atom Transfer from a Coordinated Di- methylamide to a Perpendicularly Bonded Ethyne Ligand. (1986) (0)
- Molecular ordering by halide–halide interactions in dimolybdenum p-halobenzoates (2015) (0)
- Synthesis and Characterization of Bis(neopentyl)tetrakis(acetato)dimolybdenum. (1986) (0)
- NMR Spectroscopic and Theoretical Investigation of the Bonding in W 3 (OR) 9 (µ 3 -CCH 3 ) and Its Comparison to CO 3 (CO) 9 ,(µ 3 -CCH 3 ) (1987) (0)
- ROLE OF CATIONIC TRANS INTERMEDIATES IN PROMOTING THE INSERTION OF UNSATURATED HYDROCARBONS INTO PLATINUM-HYDROGEN AND PLATINUM-CARBON BONDS, A STUDY OF THE INSERTION REACTION INVOLVING COMPOUNDS OF THE TYPE TRANS-(PTME(ETA(2)-C3H4)(P (1975) (0)
- A New Structural Type for an Electron‐Precise, Six‐Electron Triangular Metal Cluster: W3O2(O‐tBu)8. (1992) (0)
- THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 12. PREPARATION AND CHARACTERIZATION OF BIS(TERT-BUTYL MERCAPTIDO)TETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM(MM) (1983) (0)
- OXIDATIVE-ADDITIONS TO (WW)6+ CENTERS: THE INFLUENCE OF LEWIS BASE ASSOCIATION REACTIONS (1983) (0)
- THE TUNGSTEN-TUNGSTEN TRIPLE BOND. 1. PREPARATION, PROPERTIES, AND STRUCTURAL L CHARACTERIZATION OF HEXAKIS(DIMETHYLAMIDO)DITUNGSTEN(III) AND SOME HOMOLOGS (1976) (0)
- The Tungsten-Tungsten Triple Bond. Part 14. Factors Influencing Triple Bonds Between Tungsten Atoms Having Valence Molecular Orbital Configurations of σ2π4 and π4δ2 and Preparation and Characterization of Bis(neopentyl)bis(acetato)bis (1988) (0)
- Studies of Electronic Coupling and Mixed Valency in Metal—Metal Quadruply Bonded Complexes Linked by Dicarboxylate and Closely Related Ligands (2007) (0)
- The Tungsten-Tungsten Triple Bond. Part 10. Ditungsten Hexapivalate. (1986) (0)
- Additions and Corrections - Oxotrimolybdenum(IV) Alkoxides, Mo3(μ3·O)(μ3·OR)(μ2·OR)3(OR)6 (R = CH(CH3)2 and CH2C(CH3)3). Synthetic Considerations (1982) (0)
- The molybdenum-molybdenum triple bond. 7. 1 bis(1,3-di-p-tolyltriazenido)tetrakis(dimethylamido)dimolybdenum. Technical report (1980) (0)
- Collecting photo-generated charge carriers from metallo-organic materials (2009) (0)
- Ab Initio Studies of Lithium Bonded Complexes with HaO M 이 ecule (2020) (0)
- On the remarkable structural diversity and kinetic lability of TpC * CaX complexes ( X = NSi 2 Me 6 , OC 6 H 4 (2009) (0)
- The Molybdenum-to-Molybdenum Triple Bond. 5. Preparation and Structure of Dimethyltetrakis(dimethylamido)dimolybdenum. (1978) (0)
- New Generation Polymers from Renewable Resources: The Role of Metal Alkoxide Catalysts (2007) (0)
- Coordination of Ethylene to a Complex with M-M Triple Bonding: Bis(η2-ethylene)hexakis(neopentyloxy)ditungsten. (1987) (0)
- Incorporation of Ru(2)(O(2)C(CH(2))(6)CH(3))(4) into Extended Chains: Interaction of Ru(2)(O(2)C(CH(2))(6)CH(3))(4) with Pyrazine, 4-Cyanopyridine, TCNE, and p-Benzoquinone. (1997) (0)
- THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 14. PREPARATION AND CHARACTERIZATION OF MIXED ALKOXY-THIOLATE COMPOUNDS OF FORMULA MO2(OR)2(SAR)4 (MM) (1984) (0)
- Oligothiophenes incorporating metal-metal quadruple bonds (MM = Mo2, MoW and W2). A chemical approach for photon harvesting and spectral expansion (2009) (0)
- Versatile Modes of Allene Bonding in the Structures of (W2(O-tBu)6(C3H4)), (W2(O-tBu)6(C3H4)(CO)2), and (W2(O-tBu)6(C3H4)2). (1990) (0)
- A Two‐Step Low Pressure Chemical Vapor Deposition Process for the Production of Tungsten Metal Thin Films. (1998) (0)
- Preparation, Crystal, and Molecular Structure of a Hydrocarbon Soluble, Volatile Oxoalkoxide of Barium: H4Ba6(μ6‐O)(OCH2CH2OCH3)14. (1991) (0)
- REACTIONS OF TRANSITION-METAL-NITROGEN Σ-BONDS. 5. CARBONATION OF TETRAKIS(DIETHYLAMIDO)CHROMIUM(IV) TO YIELD BINUCLEAR CHROMIUM(III) AND -(II) CARBAMATO COMPLEXES (1979) (0)
- Efficient organic bulk heterojunction solar cells through near infrared absorbing metallated thiophene complexes (2009) (0)
- Additions and Corrections -13C Nuclear Resonance Studies of Organometallic Compounds. I. trans-Methylplatinum(II) Derivatives. (1975) (0)
- Dynamic and Static Stereochemistry in Dimolybdenum and Ditungsten Compounds Containing a Central (M Triple Bond M) +6 Unit. (1979) (0)
- OXOTRIMOLYBDENUM(IV) ALKOXIDES: MO3(μ3-O)(μ3-OR)(μ2-OR)3(OR)6, WHERE R = ISOPROPYL AND NEOPENTYL. SYNTHETIC CONSIDERATIONS (1982) (0)
- Magnetic and surface studies of transition metal complexes for molecular spintronics (2009) (0)
- REACTIONS OF METAL-TO-METAL MULTIPLE BONDS. 6. REVERSIBLE CARBONYLATION OF HEXAKIS(TERT-BUTOXY)DIMOLYBDENUM (MM). A CARBONYL-BRIDGED METAL-TO-METAL DOUBLE BOND, MO2(OBU-T)6(CO) (M:M) (1980) (0)
- Reactions of Mo2(OR)6 (M triple bond M) Compounds (R = Pr(i) and Bu(t) with Benzoyl Peroxide. (1982) (0)
- Tetradecaisopropoxydihydrido-tetratungsten. (IV). Oxidative Addition of PrO-H across a Tungsten-to-Tungsten Triple Bond. (1979) (0)
- Tungsten (6+) tris(pinacolate) : structure and comments on the preference for an octahedral geometry relative to trigonal prismatic (D3h) for a d0 complex in the presence of strong .pi.-donor ligands. [Erratum to document cited in CA120:123521] (1994) (0)
- CCDC 280871: Experimental Crystal Structure Determination (2006) (0)
- REACTIONS OF MO2(OR)6 (MM) COMPOUNDS (R = ISO-PR AND TERT-BU) WITH BENZOYL PEROXIDE (1983) (0)
- 1,2-Dibenzyltetradimethylamido-Dimolybdenum and -Ditungsten (M=M) Compounds and Their Reactions with Carbon Dioxide and 1,3-Diaryltriazines. A Radical Difference. (1982) (0)
- CHARACTERIZATION OF BIS(2,2′-BIPYRIDINE) AND BIS(1,10-PHENANTHROLINE) DERIVATIVES OF MOLYBDENUM AND TUNGSTEN CARBONYLS. CRYSTAL AND MOLECULAR STRUCTURE OF CIS-DICARBONYLBIS(2,2′-BIPYRIDINE)MOLYBDENUM(0) (1984) (0)
- Molybdenum-to-molybdenum triple bond. 5. preparation and structure of dimethyltetrakis(dimethylamido)dimolybdenum. Technical report (1978) (0)
- Comments on the Molecular Structure and Bonding in W4Cl(O)(OiPr)9 and W4(O)(OiPr)10; Analogies with Tetranuclear Carbonyl Clusters. (1990) (0)
- One‐Dimensional Polymers and Mesogens Incorporating Multiple Bonds Between Metal Atoms (2000) (0)
- Insights into the Schrock ???chop-chop??? reaction gained from density functional theory and preparation and structure of W2(??-PhCCPh)(SC6H4-2-Me)6Dedicated to Roald Hoffmann on the occasion of his 65th birthday. (2002) (0)
- Inorganic chemistry of the transition elements, Vol. 4, (A Specialist Periodical Report) : B.F.G. Johnson, senior reporter, The Chemical Society, London, 1976, xvi + 536 pp., $74.25, £27.00 (1976) (0)
- Reactivity of metal-metal bonds : based on a symposium sponsored by the Division of Inorganic Chemistry at the second chemical congress of the North American Continent (180th ACS national meeting), Las Vegas, Nevada, August 25-26, 1980 (1981) (0)
- Metal Alkoxides. Models for Metal Oxides. Part 15. Carbon-Carbon and Carbon-Hydrogen Bond Activation in the Reactions Between Ethylene and Ditungsten Hexaalkoxides: W2(OCH2-tBu)6(η2-C2H4)2, W2(OR)6(CH2)4(η2-C2H4), and W2(OR)6(μ-CCH2CH (1989) (0)
- Reactions of Metal-Metal Triple Bonds. 7. Addition of the Halogens (Cl2, Br2 and I2) and Diisopropylperoxide to Hexaisopropoxydimolybdenum (M-M). Dinuclear Oxidative-Addition Reactions Accompanied by Metal-Metal Bond Order Changes from Three to Two to One. (1980) (0)
- Unbridged and Bridged Isomers of W2(PCy2)2(NMe2)4: Preparations, Characterizations, and Comments on Thermodynamic and Activation Parameters for the Closing of Phosphido Bridges in d3-d3 Dinuclear Compounds. (1989) (0)
- Metal cluster compound (2014) (0)
- ELECTRONIC AND SPECTROSCOPIC PROPERTIES OF A REDOX ACTIVE ANALOG OF 4,4'-BIPYRIDINE INCORPORATING A METAL-METAL QUADRUPLE BOND (2010) (0)
- Facile Cleavage of the Mo=Mo Bond in Reactions between (Mo2(OBut)6 and Aryl Azides and Molecular Oxygen. (1980) (0)
- The Tungsten-Tungsten Triple Bond. Part 13. Bisalkyl Tetracarboxylates of Dimolybdenum and Ditungsten. Triple Bonds Between Metal Atoms with the Valence Molecular Orbital Description π4δ2. (1988) (0)
- CARBON-13 NUCLEAR MAGNETIC RESONANCE STUDIES OF ORGANOMETALLIC COMPOUNDS PART 8, PLATINUM(II) CARBENE DERIVATIVES (1975) (0)
- Stabilised Carbonium Ions in the Organic Chemistry of Platinum THE EVIDENCE FOR THEIR EXISTENCE (1975) (0)
- REACTIONS OF METAL-METAL MULTIPLE BONDS. 14. SYNTHESIS AND CHARACTERIZATION OF TRIANGULO-W3 AND -MO2W OXO-CAPPED ALKOXIDE CLUSTERS. CONPROPORTIONATION OF M-M TRIPLE BONDS AND Σ2Π4 AND D0 METAL-OXO GROUPS: MM + MO → M3(μ3-O) (1985) (0)
- PHOTOPHYSICS OF PADDLEWHEEL COMPLEXES INVOLVING MOLYBDENUM OR TUNGSTEN QUADRUPLE BONDS SUPPORTED BY AMIDINATE AND CARBOXYLATE LIGANDS (2009) (0)
- Reactions of Metal-to-Metal Multiple Bonds. Part 3. Addition of Nitric Oxide to Hexakis(alkoxy)dimolybdenum Compounds. Preparation and Properties of Bis-(nitrosyl)hexakis(alkoxy)dimolybdenum Compounds and Structural Characterization o (1978) (0)
- Trialkoxynitridomolybdenum Compounds: (RO)3MN. Preparation, Structures (R: tBu and iPr), and Comparisons with a Tungsten Analogue (R: tBu). (1987) (0)
- The First Observation of the Equilibrium 2 MM ⇄ M4 (M: Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer. (1987) (0)
- Carbon-Nitrogen Bond Formation in the Reaction Between Tetrakis(dimethylamido)molybdenum(IV) and 2,6-Dimethylphenyl Isocyanide. Preparation and Characterization of the First Homoleptic Metallaamidine Complex: Mo(η2-Me2NCN-2,6-Me2C6H3) (1987) (0)
- M2 delta-to-oxalate pi* conjugation in oxalate-bridged complexes containing M-M quadruple bonds. (2001) (0)
- THE MECHANISTIC ROLE OF WATER AND THE LIGAND IN THECHEMICAL-VAPOR-DEPOSITIONREACTIONS OFBIS-(1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONATO) COPPER(II) (1995) (0)
- Sheldon Shore (1930-2014). (2014) (0)
- Metal-to-Metal Bonds (1965) (0)
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