Manfred T. Reetz
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German chemist
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Manfred T. Reetzchemistry Degrees
Chemistry
#238
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#487
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Organic Chemistry
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#57
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Chemistry
Manfred T. Reetz's Degrees
- PhD Chemistry University of Marburg
Why Is Manfred T. Reetz Influential?
(Suggest an Edit or Addition)According to Wikipedia, Manfred Theodor Reetz is a German chemist and professor of organic chemistry, who served as director of the Max Planck Institute for Coal Research from 1991 until 2011. His research focuses on directed evolution, enzymes in organic chemistry, and stereoselective biocatalysis.
Manfred T. Reetz's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Bacterial biocatalysts: molecular biology, three-dimensional structures, and biotechnological applications of lipases. (1999) (1113)
- Microbial lipases form versatile tools for biotechnology. (1998) (1047)
- Size-Selective Synthesis of Nanostructured Transition Metal Clusters (1994) (671)
- Iterative saturation mutagenesis (ISM) for rapid directed evolution of functional enzymes (2007) (650)
- Ligand-free Heck reactions using low Pd-loading. (2004) (524)
- Lipases as practical biocatalysts. (2002) (502)
- Chelation or Non‐Chelation Control in Addition Reactions of Chiral α‐ and β‐ Alkoxy Carbonyl Compounds [New Synthetic Methods (44)] (1984) (495)
- Biocatalysis in organic chemistry and biotechnology: past, present, and future. (2013) (479)
- Laboratory evolution of stereoselective enzymes: a prolific source of catalysts for asymmetric reactions. (2011) (452)
- Combinatorial and Evolution-Based Methods in the Creation of Enantioselective Catalysts. (2001) (440)
- Iterative saturation mutagenesis on the basis of B factors as a strategy for increasing protein thermostability. (2006) (436)
- Expanding the range of substrate acceptance of enzymes: combinatorial active-site saturation test. (2005) (397)
- Addressing the Numbers Problem in Directed Evolution (2008) (387)
- Efficient immobilization of lipases by entrapment in hydrophobic sol‐gel materials (2000) (357)
- Directed evolution of enantioselective enzymes: iterative cycles of CASTing for probing protein-sequence space. (2006) (328)
- Creation of Enantioselective Biocatalysts for Organic Chemistry by In Vitro Evolution (1997) (319)
- Regio- and stereoselectivity of P450-catalysed hydroxylation of steroids controlled by laboratory evolution (2011) (299)
- Controlling the enantioselectivity of enzymes by directed evolution: practical and theoretical ramifications. (2004) (284)
- Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands. (2000) (274)
- Gold‐Catalyzed Hydroarylation of Alkynes (2003) (261)
- Visualization of Surfactants on Nanostructured Palladium Clusters by a Combination of STM and High-Resolution TEM (1995) (250)
- New Approaches to the Use of Amino Acids as Chiral Building Blocks in Organic Synthesis [New Synthetic Methods (85)] (1991) (244)
- Entrapment of biocatalysts in hydrophobic sol‐gel materials for use in organic chemistry (1997) (241)
- A Method for High-Throughput Screening of Enantioselective Catalysts. (1999) (238)
- Directed evolution of an enantioselective lipase. (2000) (233)
- Synthesis and diastereoselective reactions of n,n-dibenzylamino aldehydes and related compounds. (1999) (220)
- Utility of B-Factors in Protein Science: Interpreting Rigidity, Flexibility, and Internal Motion and Engineering Thermostability. (2019) (219)
- Systhesis and Catalytic Activity of Dendritic Diphosphane Metal Complexes (1997) (219)
- Reducing codon redundancy and screening effort of combinatorial protein libraries created by saturation mutagenesis. (2013) (214)
- Efficient Heterogeneous Biocatalysts by Entrapment of Lipases in Hydrophobic Sol–Gel Materials (1995) (214)
- Iterative saturation mutagenesis accelerates laboratory evolution of enzyme stereoselectivity: rigorous comparison with traditional methods. (2010) (204)
- Combinatorial transition-metal catalysis: mixing monodentate ligands to control enantio-, diastereo-, and regioselectivity. (2008) (201)
- Organotitanium Reagents in Organic Synthesis (1986) (201)
- Second Generation Sol‐Gel Encapsulated Lipases: Robust Heterogeneous Biocatalysts (2003) (197)
- Stereoselective Synthesis of-Amino Alcohols from Optically Activea-Amino Acids (1987) (191)
- A new principle in combinatorial asymmetric transition-metal catalysis: mixtures of chiral monodentate P ligands. (2003) (190)
- The Crucial Role of Methodology Development in Directed Evolution of Selective Enzymes. (2020) (190)
- Chelat- oder Nicht-Chelat-Kontrolle bei Additionsreaktionen von chiralen α- und β-Alkoxycarbonyl-Verbindungen† (1984) (188)
- Directed Evolution of an Enantioselective Enzyme through Combinatorial Multiple-Cassette Mutagenesis. (2001) (186)
- Surface Spectroscopic Study of the Stabilization Mechanism for Shape-Selectively Synthesized Nanostructured Transition Metal Colloids (2000) (179)
- Time-Resolved IR-Thermographic Detection and Screening of Enantioselectivity in Catalytic Reactions. (1998) (176)
- Methanol oxidation on Pt, PtRu, and colloidal Pt electrocatalysts: a DEMS study of product formation (2001) (175)
- Copper-phthalocyanine conjugates of serum albumins as enantioselective catalysts in Diels-Alder reactions. (2006) (160)
- Directed Evolution of an Enantioselective Enoate-Reductase: Testing the Utility of Iterative Saturation Mutagenesis (2009) (160)
- Biocatalysis in ionic liquids: batchwise and continuous flow processes using supercritical carbon dioxide as the mobile phase. (2002) (157)
- Crown Ethers with a Lewis Acidic Center: A New Class of Heterotopic Host Molecules (1991) (152)
- Super-High-Throughput Screening of Enantioselective Catalysts by Using Capillary Array Electrophoresis. (2000) (151)
- Solubility of hydrogen in single-sized palladium clusters (2001) (150)
- Directed evolution and the creation of enantioselective biocatalysts (2001) (148)
- Directed evolution of hybrid enzymes: Evolving enantioselectivity of an achiral Rh-complex anchored to a protein. (2006) (148)
- β‐Cyclodextrin‐Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts (1997) (146)
- Greatly reduced amino acid alphabets in directed evolution: making the right choice for saturation mutagenesis at homologous enzyme positions. (2008) (145)
- PipPhos and MorfPhos: privileged monodentate phosphoramidite ligands for rhodium-catalyzed asymmetric hydrogenation. (2005) (144)
- Structural, mechanistic, and theoretical aspects of chelation-controlled carbonyl addition reactions (1993) (143)
- Enhancing the enantioselectivity of an epoxide hydrolase by directed evolution. (2004) (143)
- Redox‐Controlled Size‐Selective Fabrication of Nanostructured Transition Metal Colloids (1999) (142)
- Kombinatorische und evolutionsgesteuerte Methoden zur Bildung enantioselektiver Katalysatoren (2001) (140)
- New methods for the high-throughput screening of enantioselective catalysts and biocatalysts. (2002) (140)
- An efficient catalyst system for the asymmetric transfer hydrogenation of ketones: remarkably broad substrate scope. (2006) (139)
- Directed evolution as a method to create enantioselective cyclohexanone monooxygenases for catalysis in Baeyer-Villiger reactions. (2004) (138)
- The importance of additive and non-additive mutational effects in protein engineering. (2013) (137)
- Increasing the stability of an enzyme toward hostile organic solvents by directed evolution based on iterative saturation mutagenesis using the B-FIT method. (2010) (137)
- Laboratory evolution of robust and enantioselective Baeyer-Villiger monooxygenases for asymmetric catalysis. (2009) (134)
- Directed evolution of an enantioselective epoxide hydrolase: uncovering the source of enantioselectivity at each evolutionary stage. (2009) (134)
- Organotitanium Reagents In Organic Synthesis A Simple Means to Adjust Reactivity and Selectivity of Carbanions (1982) (132)
- Dyotropic Rearrangements, a New Class of Orbital‐Symmetry Controlled Reactions. Type I (1972) (132)
- Enantioselective catalysis and analysis on a chip. (2006) (132)
- Lewis Acid Induced α‐Alkylation of Carbonyl Compounds (1982) (130)
- Expanding the substrate scope of enzymes: combining mutations obtained by CASTing. (2006) (128)
- 2,15-Dihydroxy-hexahelicene (HELIXOL): synthesis and use as an enantioselective fluorescent sensor (2001) (126)
- Tuning a p450 enzyme for methane oxidation. (2011) (125)
- Improved PCR method for the creation of saturation mutagenesis libraries in directed evolution: application to difficult-to-amplify templates (2008) (124)
- Converting Phenylacetone Monooxygenase into Phenylcyclohexanone Monooxygenase by Rational Design: Towards Practical Baeyer-Villiger Monooxygenases (2005) (124)
- Phosphanfreie Palladium‐katalysierte Kupplungen: die entscheidende Rolle von Pd‐Nanoteilchen (2000) (123)
- 1,3-Asymmetric induction in addition reactions of chiral .beta.-alkoxy aldehydes: efficient chelation control via Lewis acidic titanium reagents (1983) (122)
- Induced allostery in the directed evolution of an enantioselective Baeyer–Villiger monooxygenase (2010) (122)
- New Diphosphite Ligands for Catalytic Asymmetric Hydrogenation: The Crucial Role of Conformationally Enantiomeric Diols (1999) (121)
- Primary and secondary orbital effects in dyotropic rearrangements (1973) (120)
- BINOL-based diphosphonites as ligands in the asymmetric Rh-catalyzed conjugate addition of arylboronic acids. (2001) (119)
- Laboratory evolution of enantiocomplementary Candida antarctica lipase B mutants with broad substrate scope. (2013) (119)
- Enantioselective enzymes for organic synthesis created by directed evolution. (2000) (119)
- Biocatalysis in Organic Chemistry and Biotechnology: Past, Present, and Future (2013) (115)
- Continuous flow enzymatic kinetic resolution and enantiomer separation using ionic liquid/supercritical carbon dioxide media (2003) (114)
- Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites. (2006) (112)
- Gerichtete Evolution stereoselektiver Enzyme: Eine ergiebige Katalysator-Quelle f r asymmetrische Reaktionen (2011) (111)
- Coordination polymers constructed from o-phthalic acid and diamines: Syntheses and crystal structures of the phthalate-imidazole complexes {[Cu(Pht)(Im)2] · 1.5H2O}n and [Co(Pht)(Im)2]n and their application in oxidation catalysis (2006) (111)
- Phase transition and lattice expansion during hydrogen loading of nanometer sized palladium clusters (2003) (111)
- A New Method for the Preparation of Nanostructured Metal Clusters (1995) (110)
- Entrapment of lipases in hydrophobic magnetite-containing sol-gel materials: magnetic separation of heterogeneous biocatalysts (1998) (109)
- A light-driven stereoselective biocatalytic oxidation. (2007) (109)
- Mixtures of chiral and achiral monodentate ligands in asymmetric Rh-catalyzed olefin hydrogenation: reversal of enantioselectivity (2003) (109)
- Superior Biocatalysts by Directed Evolution (1999) (108)
- An artificial metalloenzyme: creation of a designed copper binding site in a thermostable protein. (2010) (108)
- Chiral Lewis acids for enantioselective CC bond formation (1986) (107)
- A highly active phosphine-free catalyst system for Heck reactions of aryl bromides (1998) (107)
- Structure and electronic nature of the benzaldehyde/boron trifluoride adduct. (1986) (107)
- Directed evolution of selective enzymes and hybrid catalysts (2002) (106)
- Directed evolution of cyclohexanone monooxygenases: enantioselective biocatalysts for the oxidation of prochiral thioethers. (2004) (106)
- Rhodium-catalyzed enantioselective hydrogenation using chiral monophosphonite ligands (2000) (106)
- Kinetic resolution in Pd-catalyzed allylic substitution using the helical PHelix ligand (2000) (106)
- Erzeugung enantioselektiver Biokatalysatoren für die Organische Chemie durch In‐vitro‐Evolution (1997) (104)
- Allylic Substitution with Dendritic Palladium Catalysts in a Continuously Operating Membrane Reactor (1999) (103)
- Size-selective electrochemical preparation of surfactant-stabilized Pd-, Ni- and Pt/Pd colloids. (2001) (102)
- Directed evolution of enantioselective enzymes for organic chemistry. (2000) (101)
- Mixtures of configurationally stable and fluxional atropisomeric monodentate P ligands in asymmetric Rh-catalyzed olefin hydrogenation. (2005) (101)
- Why are BINOL-based monophosphites such efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation? (2005) (99)
- Concerning the role of Lewis acids in chelation controlled addition to chiral alkoxy aldehydes (1984) (99)
- Light‐Driven Biocatalytic Oxidation and Reduction Reactions: Scope and Limitations (2008) (99)
- Electrochemical preparation of nanostructured bimetallic clusters (1995) (98)
- Erythro selective aldol condensation using titanium enolates (1982) (96)
- Neue Wege zur Nutzung von Aminosäuren als chirale Bausteine in der organischen Synthese (1991) (96)
- Learning from Directed Evolution: Further Lessons from Theoretical Investigations into Cooperative Mutations in Lipase Enantioselectivity (2007) (96)
- Complete reversal of enantioselectivity of an enzyme-catalyzed reaction by directed evolution (2001) (95)
- Dyotropic Rearrangements and Related σ-σ Exchange Processes (1977) (95)
- Towards the directed evolution of hybrid catalysts (2002) (94)
- Reshaping an enzyme binding pocket for enhanced and inverted stereoselectivity: use of smallest amino acid alphabets in directed evolution. (2015) (93)
- Overexpression, immobilization and biotechnological application of Pseudomonas lipases. (1998) (92)
- Designing new Baeyer-Villiger monooxygenases using restricted CASTing. (2006) (91)
- Catalytic Asymmetric Reduction of Difficult-to-Reduce Ketones: Triple Code Saturation Mutagenesis of an Alcohol Dehydrogenase (2016) (90)
- Enantioselective hydrogenation of enamides catalyzed by chiral rhodium–monodentate phosphite complexes (2002) (90)
- Microbial Baeyer-Villiger oxidation: stereopreference and substrate acceptance of cyclohexanone monooxygenase mutants prepared by directed evolution. (2006) (90)
- Quantum mechanical/molecular mechanical study on the mechanism of the enzymatic Baeyer-Villiger reaction. (2012) (89)
- P450-Catalyzed Regio- and Diastereoselective Steroid Hydroxylation: Efficient Directed Evolution Enabled by Mutability Landscaping (2018) (88)
- Stereoselective Addition of Organotitanium Reagents to Carbonyl Compounds (1985) (88)
- Hydrogen sorption in elastically soft stabilized Pd-clusters (1999) (87)
- Bacterial lipases for biotechnological applications (1997) (87)
- Towards Practical Baeyer–Villiger‐Monooxygenases: Design of Cyclohexanone Monooxygenase Mutants with Enhanced Oxidative Stability (2010) (87)
- Stereoselective Synthesis of Vicinal Diamines (1991) (87)
- Structure-Guided Triple-Code Saturation Mutagenesis: Efficient Tuning of the Stereoselectivity of an Epoxide Hydrolase (2016) (87)
- Eine Methode zum High‐Throughput‐Screening von enantioselektiven Katalysatoren (1999) (85)
- Stereoselektive Synthese von -Aminoalkoholen aus optisch aktiven a-Aminosuren (1987) (84)
- Directed evolution of enantioselective enzymes: an unconventional approach to asymmetric catalysis in organic chemistry. (2009) (83)
- Constructing and Analyzing the Fitness Landscape of an Experimental Evolutionary Process (2008) (82)
- Circular dichroism as a detection method in the screening of enantioselective catalysts. (2000) (82)
- Electrochemical growth of superparamagnetic cobalt clusters (1995) (82)
- Binol-derived monodentate phosphites and phosphoramidites with phosphorus stereogenic centers: novel ligands for transition-metal catalysis. (2005) (80)
- Enzyme promiscuity: first protein-catalyzed Morita-Baylis-Hillman reaction (2007) (80)
- Single-cell high-throughput screening to identify enantioselective hydrolytic enzymes. (2008) (80)
- Learning from Directed Evolution: Theoretical Investigations into Cooperative Mutations in Lipase Enantioselectivity (2004) (80)
- Manipulating the stereoselectivity of limonene epoxide hydrolase by directed evolution based on iterative saturation mutagenesis. (2010) (77)
- Mixtures of chiral phosphorous acid diesters and achiral p ligands in the enantio- and diastereoselective hydrogenation of ketimines. (2007) (76)
- A GC-based method for high-throughput screening of enantioselective catalysts (2001) (73)
- Assembly of Designed Oligonucleotides as an Efficient Method for Gene Recombination: A New Tool in Directed Evolution (2003) (72)
- Zeitaufgelöste IR‐thermographische Detektion und Screening von enantioselektiven katalytischen Reaktionen (1998) (72)
- Can Machine Learning Revolutionize Directed Evolution of Selective Enzymes? (2019) (71)
- Many Pathways in Laboratory Evolution Can Lead to Improved Enzymes: How to Escape from Local Minima (2012) (71)
- Hydrogen and Pd-clusters (2004) (70)
- Hoch enantioselektive Rh‐katalysierte Hydrierungen unter Verwendung von chiralen Monophosphit‐Liganden (2000) (70)
- Directed evolution of enantioselective hybrid catalysts: a novel concept in asymmetric catalysis (2007) (70)
- Iterative saturation mutagenesis: a powerful approach to engineer proteins by systematically simulating Darwinian evolution. (2014) (70)
- Biotechnological application of Pseudomonas aeruginosa lipase: efficient kinetic resolution of amines and alcohols (1996) (69)
- Shedding light on the efficacy of laboratory evolution based on iterative saturation mutagenesis. (2009) (68)
- Stereodivergent Protein Engineering of a Lipase To Access All Possible Stereoisomers of Chiral Esters with Two Stereocenters. (2019) (68)
- Directed Evolution of Enantioselective Enzymes as Catalysts for Organic Synthesis (2006) (68)
- Whole-Cell-Catalyzed Multiple Regio- and Stereoselective Functionalizations in Cascade Reactions Enabled by Directed Evolution. (2016) (68)
- Ein neuartiges Prinzip in der kombinatorischen asymmetrischen Übergangsmetall-Katalyse: Mischungen von chiralen einzähnigen P-Liganden† (2003) (66)
- Directed Evolution of Artificial Metalloenzymes: A Universal Means to Tune the Selectivity of Transition Metal Catalysts? (2019) (66)
- Mixtures of chiral monodentate phosphites, phosphonites and phosphines as ligands in Rh-catalyzed hydrogenation of N-acyl enamines: extension of the combinatorial approach (2004) (66)
- Kombinatorische Übergangsmetallkatalyse: Mischungen einzähniger Liganden zur Kontrolle der Enantio-, Diastereo- und Regioselektivität (2008) (65)
- Proton-Transfer-Dependent Reversible Phase Changes in the 4,4′-Bipyridinium Salt of Squaric Acid† (1994) (65)
- A machine learning approach for reliable prediction of amino acid interactions and its application in the directed evolution of enantioselective enzymes (2018) (64)
- Directed Evolution of Bacillus subtilis Lipase A by Use of Enantiomeric Phosphonate Inhibitors: Crystal Structures and Phage Display Selection (2006) (63)
- Second-generation MS-based high-throughput screening system for enantioselective catalysts and biocatalysts (2002) (62)
- Stereoselective cyanohydrin-forming reactions of chiral α-amino aldehydes (1988) (62)
- Chelation or Non‐Chelation Control in Stereoselective Reactions of Titanium Reagents with Chiral Alkoxycarbonyl Compounds (1983) (61)
- Enantioselective Rh-catalyzed hydrogenation of vinyl carboxylates with monodentate phosphite ligands. (2003) (61)
- Directed Evolution of Selective Enzymes: Catalysts for Organic Chemistry and Biotechnology (2016) (61)
- Investigation of Tetraalkylammonium Bromide Stabilized Palladium/Platinum Bimetallic Clusters Using Extended X-ray Absorption Fine Structure Spectroscopy (1996) (61)
- Alternate-site enzyme promiscuity. (2007) (61)
- Directed Evolution of an Enantioselective Bacillus subtilis Lipase (2003) (60)
- Deazaflavins as mediators in light-driven cytochrome P450 catalyzed hydroxylations. (2009) (59)
- What are the Limitations of Enzymes in Synthetic Organic Chemistry? (2016) (59)
- Aldol-additions t0eα- and β-alkoxy aldehydes: The effect of chelation on simple diastereoselectivity (1984) (58)
- Combinatorial approach to the asymmetric hydrogenation of β-acylamino acrylates: use of mixtures of chiral monodentate P-ligands (2004) (58)
- Enzymatic site-selectivity enabled by structure-guided directed evolution. (2017) (57)
- Mit β‐Cyclodextrin‐modifizierten Diphosphanen als Liganden zu supramolekularen Rhodiumkatalysatoren (1997) (57)
- A Robust Protein Host for Anchoring Chelating Ligands and Organocatalysts (2008) (57)
- The influence of mixtures of monodentate achiral ligands on the regioselectivity of transition-metal-catalyzed hydroformylation. (2005) (56)
- Heterotopic Host Molecules for Binding Two Different Guests (1991) (56)
- Gerichtete Evolution eines enantioselektiven Enzyms durch kombinatorische multiple Kassetten‐Mutagenese (2001) (56)
- Enhancing the Thermal Robustness of an Enzyme by Directed Evolution: Least Favorable Starting Points and Inferior Mutants Can Map Superior Evolutionary Pathways (2011) (55)
- Characterization of hydrophobic sol-gel materials containing entrapped lipases (1996) (55)
- Towards practical biocatalytic Baeyer-Villiger reactions: applying a thermostable enzyme in the gram-scale synthesis of optically-active lactones in a two-liquid-phase system (2005) (54)
- Controlled reversal of chemoselectivity in reactions of allyltitanium ate complexes with carbonyl compounds (1983) (54)
- A Practical NMR‐Based High‐Throughput Assay for Screening Enantioselective Catalysts and Biocatalysts (2002) (54)
- Multiparameter Optimization in Directed Evolution: Engineering Thermostability, Enantioselectivity, and Activity of an Epoxide Hydrolase (2016) (54)
- Enhancing the efficiency of directed evolution in focused enzyme libraries by the adaptive substituent reordering algorithm. (2012) (53)
- Carbon-carbon bond formation catalyzed by lithium perchlorate in dichloromethane (1993) (53)
- Asymmetric C-C bond formation using organometallic chemistry (1988) (53)
- A rapid injection NMR study of the chelation controlled Mukaiyama aldol addition: TiCl4 versus LiClO4 as the Lewis acid (1992) (52)
- Chelation- and non-chelation-controlled additions to 2-O-benzyl-3-O-(tert-butyldimethylsilyl)glyceraldehyde (1985) (52)
- Entrapment of Lipases in Hydrophobic Sol-Gel-Materials: Efficient Heterogeneous Biocatalysts in Aqueous Medium (2000) (51)
- Protein engineering of stereoselective Baeyer-Villiger monooxygenases. (2012) (51)
- Economical analysis of saturation mutagenesis experiments (2015) (50)
- Direct geminal dimethylation of ketones and exhaustive methylation of carboxylic acid chlorides using dichlorodimethyltitanium (1985) (50)
- Chemo- and Regioselective Dihydroxylation of Benzene to Hydroquinone Enabled by Engineered Cytochrome P450 Monooxygenase. (2018) (50)
- Supercritical Carbon Dioxide as a Reaction Medium and Reaction Partner (1993) (49)
- Non-racemizing synthesis and stereoselective reduction of chiral α-amino ketones (1990) (49)
- A genetic selection system for evolving enantioselectivity of enzymes. (2008) (49)
- Simultaneous engineering of an enzyme's entrance tunnel and active site: the case of monoamine oxidase MAO-N† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05381e (2017) (49)
- Synthese und katalytische Wirkung von dendritischen Diphosphan-Metallkomplexen (1997) (49)
- Extreme synergistic mutational effects in the directed evolution of a baeyer-villiger monooxygenase as catalyst for asymmetric sulfoxidation. (2014) (49)
- Biophysical characterization of mutants of Bacillus subtilis lipase evolved for thermostability: Factors contributing to increased activity retention (2012) (49)
- Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation. (2006) (48)
- Stereoselective Synthesis of γ‐Aminocarboxylates (1989) (48)
- In situ fixation of lipase-containing hydrophobic sol–gel materials on sintered glass—highly efficient heterogeneous biocatalysts (1996) (48)
- Cobalt-catalyzed partial oxidation of olefins and ethers using molecular oxygen (1995) (48)
- Artificial metalloenzymes as catalysts in stereoselective Diels-Alder reactions. (2012) (48)
- Directed Evolution by Using Iterative Saturation Mutagenesis Based on Multiresidue Sites (2013) (47)
- Chemo‐ and Diastereoselective Addition of Alkyl‐ and Aryltitanium(IV) Compounds to Aldehydes and Ketones (1980) (47)
- Super‐Hochdurchsatz‐Screening von enantioselektiven Katalysatoren mittels parallelisierter Kapillarelektrophorese (2000) (47)
- Neue Methoden für das Hochdurchsatz-Screening von enantioselektiven Katalysatoren und Biokatalysatoren (2002) (46)
- Fabrication of Metallic and Bimetallic Nanostructures by Electron Beam Induced Metallization of Surfactant Stabilized Pd and Pd/Pt Clusters (1997) (46)
- Water-Soluble Colloidal Adams Catalyst: Preparation and Use in Catalysis (1999) (45)
- A practical high-throughput screening system for enantioselectivity by using FTIR spectroscopy. (2003) (45)
- Kronenether mit einem Lewis‐sauren Zentrum, eine neue Klasse heterotoper Wirtmoleküle (1991) (45)
- Designer cells for stereocomplementary de novo enzymatic cascade reactions based on laboratory evolution. (2013) (45)
- Noble Metal Nanoparticles Incorporated in Mesoporous Hosts (2002) (45)
- Helical triskelion monophosphites as ligands in asymmetric catalysis. (2009) (45)
- CH3Li/TiCl4: A non-basic and highly selective grignard analogue (1986) (45)
- Directed evolution of stereoselective enzymes based on genetic selection as opposed to screening systems. (2014) (44)
- Mischungen konfigurationsstabiler und fluxionaler atropisomerer einzähniger P-Liganden in der asymmetrischen Rh-katalysierten Olefin-Hydrirung (2005) (44)
- tert-Alkylation of Ketones and Aldehydes† (1978) (43)
- Electrochemical Preparation of Nanostructured Titanium Clusters: Characterization and Use in McMurry‐Type Coupling Reactions (1996) (43)
- Creation of an amino acid network of structurally coupled residues in the directed evolution of a thermostable enzyme. (2009) (43)
- Speeding up directed evolution: Combining the advantages of solid-phase combinatorial gene synthesis with statistically guided reduction of screening effort. (2015) (42)
- The First Direct Evidence for a Cram Chelate (1987) (41)
- Copper-catalyzed enantioselective conjugate addition of diethylzinc to α,β-unsaturated carbonyl compounds using diphosphonites as chiral ligands ☆ (2002) (41)
- Stereoselectivity and Relative Reactivity in the Reaction of Organotitanium and ‐zirconium Reagents with Carbonyl Compounds (1982) (41)
- Artificial cysteine-lipases with high activity and altered catalytic mechanism created by laboratory evolution (2019) (41)
- Chemo‐ und diastereoselektive Addition von Alkyl‐ und Aryltitan(IV)‐Verbindungen an Aldehyde und Ketone (1980) (41)
- Chiral ionic phosphites and diamidophosphites: A novel group of efficient ligands for asymmetric catalysis (2007) (40)
- Directed evolution and axial chirality: optimization of the enantioselectivity of Pseudomonas aeruginosa lipase towards the kinetic resolution of a racemic allene. (2007) (39)
- A thermostable variant of P. aeruginosa cold-adapted LipC obtained by rational design and saturation mutagenesis (2012) (39)
- A New Strategy in Heterogeneous Catalysis: The Design of Cortex Catalysts (1996) (39)
- Selective reactions of organotitanium reagents (1985) (39)
- Nonlinear effects in Rh-catalyzed asymmetric olefin hydrogenation using mixtures of chiral monodentate P ligands. (2006) (38)
- Exploring substrate scope and stereoselectivity of P450 peroxygenase OleTJE in olefin-forming oxidative decarboxylation. (2016) (38)
- Reagent control in the aldol addition of chiral boron enolates based on the 2,5-diphenylborolane ligand system (1990) (38)
- New approaches to supramolecular transition metal catalysis (1997) (37)
- Application of directed evolution in the development of enantioselective enzymes (2000) (37)
- 3,3′-dinitro-octahydrobinaphthol: A new chiral ligand for metal-catalyzed enantioselective reactions (1997) (37)
- Structural and Computational Insight into the Catalytic Mechanism of Limonene Epoxide Hydrolase Mutants in Stereoselective Transformations. (2018) (37)
- Reduction of α,β-Unsaturated Ketones by Old Yellow Enzymes: Mechanistic Insights from Quantum Mechanics/Molecular Mechanics Calculations. (2015) (37)
- Computer Image Processing of Transmission Electron Micrograph Pictures as a Fast and Reliable Tool To Analyze the Size of Nanoparticles (2000) (37)
- Regio‐ and Stereoselective Steroid Hydroxylation at C7 by Cytochrome P450 Monooxygenase Mutants (2020) (37)
- Increasing the activity and enantioselectivity of lipases by sol-gel immobilization: further advancements of practical interest. (2014) (36)
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- Thermische umlagerung von quadratsäure-bis(trimethylsilyl)ester (1975) (36)
- Protective group tuning in the stereoselective conversion of α-amino aldehydes into aminoalkyl epoxides (1989) (36)
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- Supramolecular transition metal catalysts in two-phase systems (1998) (34)
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- BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis (2005) (34)
- New non-C2-symmetric phosphine-phosphonites as ligands in asymmetric metal catalysis (1999) (34)
- Chelation‐Controlled Stereoselective Synthesis of Cyanohydrins (1985) (34)
- Directed Evolution of Artificial Metalloenzymes (2015) (33)
- Trimethylsilyl cyanide promoted cyanation of tertiary alkyl chlorides and other SN1 active compounds (1983) (33)
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- Non-chelation-controlled nucleophilic addition to chiral α-siloxyketones (1986) (30)
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- Synthesis of a phosphine-modified cyclodextrin and its rhodium complex (1993) (29)
- Nanostructured nickel-clusters as catalysts in [3+2]cycloaddition reactions (1998) (29)
- Directed Evolution of Stereoselective Hybrid Catalysts (2009) (29)
- Stereoselective epoxidation of chiral electron-poor γ-aminoolefins (1991) (29)
- Methylenebicyclo[4.2.1]nona‐2,4,7‐triene (1973) (29)
- A redox-mediated Kemp eliminase (2017) (29)
- Direct geminal dimethylation of ketones using dimethyltitanium dichloride (1981) (29)
- Carbon-Carbon Bond Formation Using Alkyl-Titanium-(IV) Compounds (1981) (29)
- New supramolecular transition metal catalysts (1998) (28)
- Metallfreie Carbanionensalze als Initiatoren für die anionische Polymerisation von Acryl‐ und Methacrylsäureestern (1988) (28)
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- Ligand effects in selective carbonyl addition reactions of organomanganese and cerium reagents (1992) (28)
- Directed evolution of phenylacetone monooxygenase as an active catalyst for the baeyer–villiger conversion of cyclohexanone to caprolactone (2015) (28)
- Beating Bias in the Directed Evolution of Proteins: Combining High‐Fidelity on‐Chip Solid‐Phase Gene Synthesis with Efficient Gene Assembly for Combinatorial Library Construction (2018) (28)
- IR‐Thermographie‐Screening von thermoneutralen oder endothermen Reaktionen: die Ringschluss‐Olefin‐Metathese (2000) (28)
- Multiplex‐PCR‐Based Recombination as a Novel High‐Fidelity Method for Directed Evolution (2005) (27)
- Manipulating the Expression Rate and Enantioselectivity of an Epoxide Hydrolase by Using Directed Evolution (2011) (27)
- Direct geminal dialkylation of ketones using organotitanium reagents. A simple entry into synthetic tetrahydrocannabinoids (1983) (27)
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- Titanium-Mediated Stereoselective Knoevenagel Condensation of Ethyl (Diethoxyphosphoryl)acetate with Aldehydes (1987) (26)
- Boosting the efficiency of site-saturation mutagenesis for a difficult-to-randomize gene by a two-step PCR strategy (2018) (26)
- tert‐Alkylierung von Ketonen und Aldehyden (1978) (26)
- Catalysis by lithium perchlorate in dichloromethane: Diels-Alder reactions and 1,3-Claisen rearrangements (1993) (26)
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- Reversal of diastereoselectivity in the BF3-promoted addition of halobis(cyclopentadienyl)crotyltitanium compounds to aldehydes (1984) (26)
- Statistical Analysis of the Benefits of Focused Saturation Mutagenesis in Directed Evolution Based on Reduced Amino Acid Alphabets (2019) (26)
- Enantioselective addition of chirally modified methyltitanium reagents to aromatic aldehydes (1986) (25)
- Heterotope Wirtmoleküle zur Einlagerung von zwei verschiedenen Gästen (1991) (25)
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- Der erste direkte Nachweis eines Cram‐Chelats (1987) (25)
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- Directed Evolution as a Means to Create Enantioselective Enzymes for Use in Organic Chemistry (2002) (25)
- Asymmetric Catalytic Reactions Using P*‐Mono‐, P*,N‐ and P*,P*‐Bidentate Diamidophosphites with BINOL Backbones and 1,3,2‐Diazaphospholidine Moieties: Differences in the Enantioselectivity (2010) (25)
- Enantioselective Grignard-type addition of allyltitanium reagents having the center of chirality at titanium (1984) (24)
- Cycloaddition reactions of λ-amino α,β-didehydro amino acid esters: a test case for the principle of 1,3-allylic strain (1992) (24)
- Assembly of Designed Oligonucleotides: a useful tool in synthetic biology for creating high-quality combinatorial DNA libraries. (2014) (24)
- Infrared-thermographic screening of the activity and enantioselectivity of enzymes (2001) (24)
- Molecular Recognition of Primary Amines by Three-Point Binding with Boron-Containing Host Molecules. (1992) (23)
- Bicyclofulvene, I. Darstellung von Methylenbicyclo[2.2.1]heptadien und Methylenbicyclo[4.2.1]nonatrien (1975) (23)
- Stereoselective α-alkylation of ketones and esters using chromiumtricarbonyl-complexed benzyl acetates (1983) (23)
- Geminale Dialkylierung von Ketonen mit Grignard‐Verbindungen und Methyltitan(IV)‐chloriden (1980) (23)
- Electron-beam lithography with metal colloids: Direct writing of metallic nanostructures (1998) (23)
- Directed Evolution as a Means to Engineer Enantioselective Enzymes (2008) (23)
- α-Alkylthio-nitriles via cyanation of thio-acetals and ketals (1984) (23)
- Lewis‐Säure‐bedingte α‐tert‐Alkylierung von Carbonsäuren und Carbonsäureestern (1983) (23)
- Die Bedeutung von additiven und nicht‐additiven Mutationseffekten beim Protein‐Engineering (2013) (23)
- NANOSTRUCTURED METAL OXIDE CLUSTERS BY OXIDATION OF STABILIZED METAL CLUSTERS WITH AIR (1996) (23)
- Exploring productive sequence space in directed evolution using binary patterning versus conventional mutagenesis strategies (2016) (23)
- Metal, ligand and protective group tuning as a means to control selectivity (1992) (23)
- Der Einfluß von Mischungen achiraler einzähniger Liganden auf die Regioselektivität der übergangsmetallkatalysierten Hydroformylierung (2005) (23)
- Asymmetric dihydroxylation of chiral γ-amino α,β-unsaturated esters: Turning the mismatched into the matched case via protective group tuning (1996) (23)
- Immobilization of chiral enzyme inhibitors on solid supports by amide-forming coupling and olefin metathesis (2002) (23)
- General Synthesis of Potentially Antiviral α‐Adamantyl Carbonyl Compounds (1979) (23)
- Analysis of Enantioselective Biotransformations Using a Few Hundred Cells on an Integrated Microfluidic Chip. (2016) (23)
- Inducing high activity of a thermophilic enzyme at ambient temperatures by directed evolution. (2017) (23)
- An Economical Large-Scale Synthesis of Titanium Tetrakis[diethylamide] and Chlorotitanium Tris[diethylamide] (1983) (22)
- Focused rational iterative site-specific mutagenesis (FRISM). (2020) (22)
- Kinetic studies of the addition of methyltitanium reagents to carbonyl compounds (1987) (21)
- A mild and variable synthesis of α-ketoesters (1984) (21)
- Chemoselective in situ protection of aldehydes and ketones using titanium tetrakis(dialkylamides) (1983) (21)
- Directed Evolution of Proteins Based on Mutational Scanning. (2018) (21)
- Stereoselective synthesis of -amino hydroxylamines (1994) (21)
- An overview of high-throughput screening systems for enantioselective enzymatic transformations. (2003) (21)
- Cram selectivity in the reaction of 2-phenylpropanal with alkyllithium reagents: Myth and reality (1992) (21)
- A screening system for enantioselective enzymes based on differential cell growth. (2002) (20)
- P450-BM3-Catalyzed Sulfoxidation versus Hydroxylation: A Common or Two Different Catalytically Active Species? (2020) (20)
- Einfache Darstellung von Lithiumdiisopropylamid in molarem Maßstab (1980) (20)
- The Kharasch reaction revisited: CuX3Li2-catalyzed conjugate addition reactions of Grignard reagents (1995) (20)
- Chemo‐ and Stereoselective Cytochrome P450‐BM3‐Catalyzed Sulfoxidation of 1‐Thiochroman‐4‐ones Enabled by Directed Evolution (2017) (20)
- Chemical and Biocatalytic Routes to Arbutin † (2019) (20)
- Lewis‐Säure‐bedingte α‐Alkylierung von Carbonylverbindungen, VI. Optimierung des Verfahrens zur α‐tert‐Alkylierung von Ketonen und Aldehyden (1980) (20)
- A novel receptor for ditopic binding of alkali metal halides (1994) (20)
- Exploiting Designed Oxidase–Peroxygenase Mutual Benefit System for Asymmetric Cascade Reactions (2019) (20)
- Stereoselektive Synthese von vicinalen Diaminen (1991) (20)
- Stereoselective [2,3]-sigmatropic rearrangement of chiral amine oxides derived from amino acids (1991) (19)
- Rapid and Error-Free Site-Directed Mutagenesis by a PCR-Free In Vitro CRISPR/Cas9-Mediated Mutagenic System. (2018) (19)
- Practical protocols for lipase immobilization via sol-gel techniques. (2013) (19)
- Chemoselektive und positionsspezifische Methylierung von tert‐Alkylhalogeniden mit Methyltitan(IV)‐chloriden (1980) (19)
- Stereoselektive Synthese von ?-Aminocarbonsureestern (1989) (19)
- Strategies for the development of enantioselective catalysts (1999) (19)
- Chemoselective and Position Specific Methylation of tert-Alkyl Halides with Methyltitanium(IV) Chlorides† (1980) (18)
- KINETISCHE EINFLUSSE AUF DIE ENANTIOSELEKTIVITAT VON NICHTDIASTEREOMERENREINEN KATALYSATORMISCHUNGEN (1999) (18)
- Non-chelation-control in nucleophilic additions to chiral α- and β-alkoxy aldehydes (1984) (18)
- Assembly of Designed Oligonucleotides as an Efficient Method for Gene Recombination: A New Tool in Directed Evolution. (2003) (18)
- 1-Butanol as a Solvent for Efficient Extraction of Polar Compounds from Aqueous Medium: Theoretical and Practical Aspects. (2018) (18)
- Stereoselective Hydride Elimination from Organo‐Lithium and ‐Magnesium Compounds (1977) (18)
- Stereoselective Addition of Lithiated Heterocycles to Chiral a-Amino Aldehydes (1989) (18)
- Tandem aldolization/lactonization/dyotropic rearrangement of α-amino-aldehydes (1989) (18)
- A General Procedure for Intramolecular α-tert-Alkylation of Carbonyl Compounds† (1981) (18)
- Laboratory Evolution of Stereoselective Enzymes: A Prolific Source of Catalysts for Asymmetric Reactions (2011) (17)
- Solid‐Phase Gene Synthesis for Mutant Library Construction: The Future of Directed Evolution? (2018) (17)
- Efficient coupling of tertiary alkyl halides with dialkylzinc and titanium compounds (1981) (17)
- α-Methylation of ketones via manganese-enolates: Absence of undesired polyalkylation (1993) (17)
- Solid-phase enzymatic synthesis of oligonucleotides. (1999) (17)
- Massenspektrometrische untersuchungen zu dyotropen umlagerungen (1976) (17)
- Ligand effects in selective addition reactions of organoindium reagents with carbonyl compounds (1997) (17)
- Die zentrale Rolle der Methodenentwicklung in der gerichteten Evolution selektiver Enzyme (2020) (16)
- Diels‐Alder‐Reaktionen von 2,3‐Bis(trimethylsilyloxy)‐1,3–dienen (1979) (16)
- Facile Hydride Ion Abstraction from Enamines, Allylamines and Imines (1981) (16)
- Stereoselective synthesis of α,β-diamino nitriles from amino acids (1994) (16)
- Octahedral Titanium(IV)-Reagents in Organic Synthesis (1981) (16)
- Preparation of Enantiomerically Pure α‐N,N‐Dibenzylamino Aldehydes: S‐2‐(N,N‐Dibenzylamino)‐3‐Phenylpropanal (2003) (16)
- Nucleophile Substitution von Vinyl‐Wasserstoffatomen durch Carbanionen (1977) (16)
- Theoretical studies of organometallic compounds. II. All electron and pseudopotential calculations of M(CH3)nCl4 − n (M = C, Si, Ge, Sn, Pb; n = 0–4) (1992) (16)
- First Direct NMR Spectroscopic Observation of a Cram-Chelate Involving a Chiral α-Alkoxy Aldehyde (1993) (16)
- Tunneling conduction in Co-cluster/tetraoctylammonium bromide/poly(phenyl-p-phenylenevinylene) nanocomposites (1995) (16)
- Regioselektive Lewis‐Säure‐bedingte α‐sek‐Alkylierung von Carbonylverbindungen (1984) (16)
- Regio‐ and Stereoselective Carbosulfenylation of Olefins (1987) (16)
- Platinum-nanoparticles on different types of carbon supports: Correlation of electrocatalytic activity with carrier morphology (2004) (16)
- Lewis and mediated α-alkylation of ketones using SN1 reactive alkylating agents (1979) (16)
- Lewis‐Säure‐bewirkte α‐Alkylierung von Carbonylverbindungen (2006) (15)
- Einzelzellbasierte Hochdurchsatz-Durchmusterung zur Identifizierung enantioselektiver hydrolytischer Enzyme† (2008) (15)
- Stereoselective Nucleophilic Addition Reactions of Reactive Pseudopeptides (1992) (15)
- Mixtures of monodentate P-ligands as a means to control the diastereoselectivity in Rh-catalyzed hydrogenation of chiral alkenes (2005) (15)
- Manipulating the stereoselectivity of the thermostable Baeyer-Villiger monooxygenase TmCHMO by directed evolution. (2017) (15)
- Umlagerung von (Trimethylsilyl)methyl‐Allyl‐Äthern, eine dyotrope Reaktion? (1974) (15)
- Nickel(II) and copper(II) complexes with amidrazone-based ligands: Structure and catalytic activity (1995) (15)
- Preparation of novel HIV-protease inhibitors (1998) (15)
- Synthese von ,?- und a,-ungesttigten Ketonen mittels Allyltitan-Agenzien (1985) (14)
- Quervernetzte Scandium‐haltige Dendrimere: eine neue Klasse heterogener Katalysatoren (2000) (14)
- Stereoselective α-alkylation of carbonyl compounds using tricarbonylchromium-complexed benzyl acetates (1990) (14)
- High-throughput screening system for assaying the enantioselectivity of enzymes (2006) (14)
- Structure of carbanions having carbocations as counterions (1993) (14)
- Dyotrope Umlagerungen, VII: Synthese und thermische Umlagerung von (Silyl) methyl‐silyl‐äthern (1976) (14)
- Chiral phosphoric acid diesters as ligands in asymmetric transition metal catalyzed hydrogenation (2003) (14)
- Ligandeneffekte bei Grignard‐Additionen (1992) (14)
- High-throughput selection system for assessing the activity of epoxide hydrolases. (2006) (14)
- Dyotrope Umlagerungen, X. Synthese und thermische Umlagerung von Allyl‐(silylmethyl)‐ethern (1977) (13)
- Thermisches Verhalten von Allyloxy-carbenen (1972) (13)
- Elektronenstoßinduzierte Etherspaltung durch anchimere Beteiligung von Silyl‐ und Germylgruppen (1976) (13)
- Fabrication of Metallic and Bimetallic Nanostructures by Electron Beam Induced Metallization of Surfactant Stabilized Pd and Pd/Pt Clusters. (1997) (13)
- An Improved Synthesis of Cyanotrimethylsilane (1982) (13)
- Stereoselective synthesis of β-amino nitriles and 1,3-diamines (1994) (13)
- ber den Ursprung der diastereofacialen Selektivitt bei Additionsreaktionen an Cyclohexanone (1991) (13)
- Hinge-Type Dimerization of Proteins by a Tetracysteine Peptide of High Pairing Specificity. (2018) (13)
- Asymmetric Hydrogenation of β-Keto Esters Using Chiral Diphosphonites (2006) (12)
- Clarifying the Difference between Iterative Saturation Mutagenesis as a Rational Guide in Directed Evolution and OmniChange as a Gene Mutagenesis Technique (2018) (12)
- Recent Advances in Directed Evolution of Stereoselective Enzymes (2017) (12)
- Challenges in the directed evolution of stereoselective enzymes for use in organic chemistry (2011) (12)
- Extending the concept of mixtures of chiral monodentate P-ligands in asymmetric Rh-catalyzed olefin-hydrogenation: Use of oxazaphospholidines (2006) (12)
- Methodology Development in Directed Evolution: Exploring Options when Applying Triple‐Code Saturation Mutagenesis (2018) (12)
- Gruppentransfer‐Polymerisation von Acrylsäureestern mit Alkylthio‐ oder Arylthiosilanen als Initiatoren (1986) (11)
- New uses of amino acids as chiral building blocks in organic synthesis. (2001) (11)
- One hundred years of the Max-Planck-Institut für Kohlenforschung. (2014) (11)
- Eine neue Strategie in der heterogenen Katalyse: das Design von Cortex-Katalysatoren (1995) (11)
- Unprecedented stereoselectivity in the addition of organoiron(II) reagents to cyclohexanone derivatives (1993) (11)
- A simple synthetic route to statine and statine analogues (1989) (11)
- Rhodium-catalyzed enantioselective hydrogenation of β,β-disubstituted α-acetamido acrylates using cheap monodentate P-ligands (2005) (11)
- Select protocols of high-throughput ee-screening systems for assaying enantioselective enzymes. (2003) (11)
- Rearrangement of (Trimethylsilyl)methyl Allyl Ethers, A Dyotropic Reaction?† (1974) (11)
- Anchimer beschleunigte Homolysen, II: Synthese, Thermolyse und Photolyse von Alkyl‐(silylmethyl)‐ethern (1978) (11)
- Dyotrope Umlagerung von (Silyl)methyl‐Silyl‐Äthern (1974) (11)
- CuX3Li2-catalysed conjugate addition of dialkylmagnesium reagents to α,β-unsaturated carbonyl compounds (1994) (11)
- Learning lessons from directed evolution of stereoselective enzymes (2016) (11)
- Magnetic Properties Of Cobalt-Cluster Dispersions Generated In An Electrochemical Cell (1996) (10)
- Ligand-Free Heck Reactions Using Low Pd-Loading (2004) (10)
- Deprotonation‐Hydride Elimination as a Method of Dehydrogenation (1978) (10)
- Electrochemical Methods in the Synthesis of Nanostructured Transition Metal Clusters (2007) (10)
- Dyotrope Umlagerungen, VIII: Mechanismus der Umlagerung von (Silyl)methyl‐silyl‐äthern (1976) (10)
- Thermal Rearrangement of Silylmethyl Acetates (1977) (10)
- Cyanation of Tertiary Alkyl Chlorides: A Novel Method for the Geminal Dialkylation of Ketones (1981) (10)
- Correction: Simultaneous engineering of an enzyme’s entrance tunnel and active site: the case of monoamine oxidase MAO-N (2017) (10)
- Structural study of titanated phosphonoacetates: reagents for stereoconvergent Knoevenagel condensations (1987) (10)
- Erythro-selective Aldol-type Addition of Titanated Aldehyde-Hydrazones† (1982) (10)
- Machine Learning Enables Selection of Epistatic Enzyme Mutants for Stability Against Unfolding and Detrimental Aggregation (2020) (10)
- A cell-based adrenaline assay for automated high-throughput activity screening of epoxide hydrolases. (2008) (10)
- Chelat‐kontrollierte stereoselektive Synthese von Cyanhydrinen (1985) (10)
- Synthesis of a gold(I) complex with a (thio)phosphine-modified β -cyclodextrin (2002) (10)
- Regioselektive Lewis‐Säure‐bedingte α‐tert‐Alkylierung von Acyloinen und Glycolsäure (1983) (9)
- Stereoselective reductive amination of chiral N,N-dibenzylamino ketones (1999) (9)
- Hydrideliminierungen, IX. Aromatisierung von Arenocyclohexanonen (1980) (9)
- The Unexplored Importance of Fleeting Chiral Intermediates in Enzyme-Catalyzed Reactions (2021) (9)
- Untersuchungen über Heterocarbene, XIII1) Brom‐, Jod‐ und Chlor‐äthoxycarbonylcarben aus Brom‐, Jod‐ und Chlor‐diazoessigsäure‐äthylester (1973) (9)
- Borylated lyxofuranosides as selective host molecules for amines (1994) (9)
- Tuning lipase activity with perfluro carboxylic acids as additives (2012) (9)
- Intermolekulare Silylgruppen‐Wanderung bei (Trimethylsiloxy)‐enonen (1981) (9)
- Allgemeines Verfahren zur intramolekularen α‐tert‐Alkylierung von Carbonylverbindungen (1981) (9)
- Synthesis and structure of metallomacrocycles based on isothiosemicarbazides (1995) (9)
- Dyotrope Umlagerungen, XI. Mechnismus der thermischen Umlagerung von Allyl‐(silymethyl)‐ethern (1977) (9)
- Dyotrope Umlagerungen, XIII. Fluoridionen‐katalysierte Umlagerungen von Allyl‐ und Benzyl‐(silylmethyl)‐ethern (1977) (9)
- Methylen-bicyclo[4.2.1] nona-2,4,7-trien (1973) (9)
- Direct Geminal Dimethylation of Aromatic Aldehydes with Dichlorodimethyltitanium (1987) (9)
- Mixed bidentate ligands: the first chiral phosphonite-phosphite (2000) (9)
- Stereoselective reactions of chiral α-amino aldehydes (1988) (9)
- Manipulating the stereoselectivity of a thermostable alcohol dehydrogenase by directed evolution for efficient asymmetric synthesis of arylpropanols (2018) (9)
- Stereoselective synthesis of α,γ-diamino-β-hydroxy amino acid esters: A new class of amino acids (1990) (9)
- Anchimerically Accelerated Bond Homolyses (1979) (9)
- Electron Impact Induced Ether Cleavage by Anchimeric Participation of Silyl and Germyl Groups (1976) (9)
- Chiral Monophosphites and Monophosphonites as Ligands in Asymmetric Transition Metal Catalysis (2003) (8)
- An efficient method for mutant library creation in Pichia pastoris useful in directed evolution (2010) (8)
- Thermische Umlagerung von (Silyl)methyl‐acetaten (1977) (8)
- Directed evolution of enantioselective enzymes: An unceasing catalyst source for organic chemistry (2010) (8)
- New Concepts for Increasing the Efficiency in Directed Evolution of Stereoselective Enzymes (2016) (8)
- Adamantene in the Gas Phase (1979) (8)
- Stereoselective Grignard-type reactions of chiral N,N-dibenzylamino ketones (1999) (8)
- Allgemeine Synthese potentiell antiviral wirksamer α‐Adamantyl‐carbonylverbindungen (1979) (8)
- Adamanten in der Gasphase (1979) (8)
- Combinatorial methods in catalysis by metal complexes (2004) (8)
- Organotitan–Agenzien zur Modifizierung der Carbanionen–Selektivität (1981) (8)
- Synthesis and properties of cyclopropanone hydrazones (1986) (8)
- Directed Evolution by Random Mutagenesis: A Critical Evaluation (2004) (8)
- Novel 1,4-asymmetric induction in nucleophilic 1,2-additions to chiral γ-amino enals (1991) (7)
- Hydrideliminierungen, VII. Deprotonierung‐Hydrideliminierung als Methode zur Aromatisierung (1978) (7)
- α-Alkylation of carbonyl compounds using 1-acetoxy-1-ferrocenylethane (1987) (7)
- Regio- und stereoselektive Carbosulfenylierung von Olefinen†‡ (1987) (7)
- Lewis‐Säure‐bedingte α‐Alkoxyalkylierung von Carbonyl‐verbindungen mit α‐Halogen‐ und α‐Acetoxyethern. Synthese von C‐Glycosiden (1983) (7)
- Lewis Acid Alkylation of Ketones Using SN1-reactive Acetates (1981) (7)
- Reversibler Protonentransfer‐bedingter Phasenübergang im 4,4′‐Bipyridiniumsalz der Quadratsäure (1994) (7)
- Deprotonierung‐Hydrideliminierung als Methode zur Dehydrierung (1978) (7)
- Stereoselektive nucleophile Additionsreaktionen an reaktiven Pseudopeptiden (1992) (7)
- Simultaneous Binding of Cations and Anions (1997) (7)
- Synthetic and mechanistic aspects of metal‐free polymerizations of acrylates (1996) (7)
- Dyotropic Rearrangement of (Silyl)methyl Silyl Ethers (1974) (7)
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- Cover Picture: Enantioselective Catalysis and Analysis on a Chip (Angew. Chem. Int. Ed. 15/2006) (2006) (0)
- Non-ipso Electrophilic Substitution of Vinylstannanes and Silanes. (1990) (0)
- Crystal structure of Bacillus subtilis Lipase A 7-fold mutant; the outcome of directed evolution towards thermostability (2012) (0)
- LEWIS ACID MEDIATED α-ALKYLATION OF CARBONYL COMPOUNDS. VII. REGIO AND POSITION SPECIFIC α-TERT-ALKYLATION OF KETONES (1981) (0)
- Metal, Ligand, and Protective Group Tuning as a Means to Control Selectivity (1992) (0)
- Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung (2001) (0)
- Structure of limonene epoxide hydrolase mutant - H-2-H5 complex with (S,S)-cyclohexane-1,2-diol (2016) (0)
- Structure of limonene epoxide hydrolase mutant - H-2-H5 (2016) (0)
- Reduction of Functional Groups (2009) (0)
- Asymmetric C‐C Bond Formation Using Organometallic Chemistry (1989) (0)
- α-Methylation of Ketones via Manganese Enolates: Absence of Undesired Polyalkylation. (1994) (0)
- STEREOSELECTIVITY AND RELATIVE REACTIVITY IN THE REACTION OF ORGANOTITANIUM AND -ZIRCONIUM REAGENTS WITH CARBONYL COMPOUNDS (1982) (0)
- THE TRANS STEREOSPECIFIC DEOXYGENATION OF EPOXIDES USING DIMETHYLPHENYLSILYLLITHIUM (1976) (0)
- TRIMETHYLSILYL CYANIDE-PROMOTED CYANATION OF TERTIARY ALKYL CHLORIDES AND OTHER SN1 ACTIVE COMPOUNDS (1983) (0)
- Carbon-Carbon Bond Formation Catalyzed by Lithium Perchlorate in Dichloromethane. (1993) (0)
- LEWIS ACID-MEDIATED α-ALKOXYALKYLATION OF CARBONYL COMPOUNDS USING α-HALO AND α-ACETOXY ETHERS. SYNTHESIS OF C-GLYCOSIDES (1984) (0)
- Octahedral Titanium(IV)-Reagents in Organic Synthesis. (1982) (0)
- PtOx/C-based catalysts with high metal loading prepared by instant-method for PEM fuel cell applications (2004) (0)
- Steuerung der Selektivität bei organisch-chemischen Synthesen (1994) (0)
- Novel 1,4‐Asymmetric Induction of Nucleophilic 1,2‐Additions to Chiral γ‐Amino Enals. (1992) (0)
- A lithographic method for the generation of nanostructures on surfaces (1996) (0)
- VARIABLE ADJUSTMENT OF CARBANION-SELECTIVITY BY CONVERSION INTO TITANIUM REAGENTS (1981) (0)
- Catalysis by Lithium Perchlorate in Dichloromethane: Diels‐Alder Reactions and 1,3‐Claisen Rearrangements. (1993) (0)
- A Simple Synthetic Route to Statine and Statine Analogues. (1990) (0)
- CASTing als effiziente Methode in der gelenkten Evolution selektiver Enzyme (2006) (0)
- Synthesis and Diastereoselective Reactions of N,N-Dibenzylamino Aldehydes and Related Compounds (2010) (0)
- REGIOSELECTIVE LEWIS ACID‐MEDIATED α‐TERT‐ALKYLATION OF ACYLOINS AND GLYCOLIC ACID (1984) (0)
- Enzymes, Directed Evolution (2009) (0)
- Crystal Structure of the L74F/M78F/L103V/L114V/I116V/F139V/L147V mutant of LEH complexed with (S,S)-cyclohexanediol (2015) (0)
- 1,2‐Diethoxy‐1,2‐bis(trimethylsilyloxy)ethylene (2001) (0)
- ADAMANTANE IN THE VAPOR PHASE (1980) (0)
- A process for the preparation of aromatic and heteroaromatic amines (2011) (0)
- Characterization of Catalytic Supports by Means of High-Resolution TEM and SEM in Combination with Shadow-Casting and Decoration Procedures (2006) (0)
- A Highly Active Phosphine-Free Catalyst System for Heck Reactions of Aryl Bromides. (1999) (0)
- THEREOF FOR THE STEREOSELECTIVE PREPARATION OF OPTICALLY ACTIVE BETA-AMNO ALCOHOLS (2017) (0)
- Nonlinear Effects in Rh-Catalyzed Asymmetric Olefin Hydrogenation (2006) (0)
- Copper-Catalyzed Enantioselective Conjugate Addition of Diethylzinc to α,β-Unsaturated Carbonyl Compounds Using Diphosphonites as Chiral Ligands. (2002) (0)
- Chelate‐Controlled Stereoselective Synthesis of Cyanohydrins. (1986) (0)
- 1H, 13C and 15N resonance assignments of wild-type Bacillus subtilis Lipase A and its mutant evolved towards thermostability (2012) (0)
- Mixed Bidentate Ligands: The First Chiral Phosphonite—Phosphite (2000) (0)
- A process for the preparation and identification of new hydrolases with improved properties (1998) (0)
- Gold-catalyzed hdroarylation of alkynes (2005) (0)
- HYDRIDE ELIMINATIONS. VIII. NOTE ON SITE-SPECIFIC TRANSITION METAL-LIMITED HYDRIDE ABSTRACTION FROM CARBANIONS (1980) (0)
- HYDRIDE ELIMINATIONS. 6. DEPROTONATION‐HYDRIDE ELIMINATION AS A METHOD FOR DEHYDROGENATION (1978) (0)
- Synthesis and Properties of Cyclopropanone Hydrazones. (1987) (0)
- Enzyme Engineering (2023) (0)
- The First Direct Evidence for a Cram Chelate. (1987) (0)
- DYOTROPIC REARRANGEMENTS, VII. SYNTHESIS AND THERMAL REARRANGEMENT OF (SILYL)METHYL SILYL ETHERS (1976) (0)
- SIMPLE SYNTHESIS OF NORTRICYCLYL CHLORIDE (1981) (0)
- Stereoselective Intramolecular Allylsilane Additions to Chiral Aldehydes. (1988) (0)
- Stereoselective Synthesis of α,β-Diamino Nitriles from Amino Acids. (1994) (0)
- AN AB INITIO STUDY OF ACYLOXY CATIONS (1975) (0)
- Stereoselective Nucleophilic Addition Reactions of Reactive Pseudopeptides. (1993) (0)
- Stereoselective Addition of Lithiated Heterocycles (II) to Chiral α‐Amino Aldehydes (I). (1989) (0)
- Asymmetric Hydrogenation of β‐Keto Esters Using Chiral Diphosphonites. (2006) (0)
- DIELS-ALDER REACTIONS OF 2,3-BIS(TRIMETHYLSILYLOXY)-1,3-DIENES (1979) (0)
- α-TERT-ALKYLATION OF CARBOXYLIC ACID ESTERS (1978) (0)
- Ligand Effects in Selective Carbonyl Addition Reactions of Organomanganese and Cerium Reagents. (2010) (0)
- Chelation- and Non-Chelation-Controlled Additions to 2-O-Benzyl-3-O- (tert-butyldimethylsilyl)glyceraldehyde. (1986) (0)
- STEREOSELECTIVE α-ALKYLATION OF KETONES AND ESTERS USING CHROMIUM TRICARBONYL-COMPLEXED BENZYL ACETATES (1983) (0)
- Cobalt-Catalyzed Partial Oxidation of Olefins and Ethers Using Molecular Oxygen. (1996) (0)
- Unprecedented Stereoselectivity in the Addition of Organoiron(II) Reagents to Cyclohexanone Derivatives. (1993) (0)
- Preparation of Novel HIV-Protease Inhibitors. (1999) (0)
- CuX3Li2-Catalyzed Conjugate Addition of Dialkylmagnesium Reagents to . alpha.,β-Unsaturated Carbonyl Compounds. (1995) (0)
- in‐vitro evolution of biocatalysts (2020) (0)
- DYOTROPIC REARRANGEMENTS AND RELATED .SIGMA±SIGMA. EXCHANGE PROCESSES (1978) (0)
- LEWIS ACID MEDIATED α-ALKYLATION OF CARBONYL COMPOUNDS. VI. OPTIMIZATION OF THE PROCEDURE FOR THE α-TERT-ALKYLATION OF KETONES AND ALDEHYDES (1981) (0)
- Ru(II)/Chiral Diphosphonite Asymmetric Keto Ester Hydrogenation (2006) (0)
- ANCHIMERICALLY ACCELERATED HOMOLYSES. V. THERMAL AND FLUORIDE ION‐CATALYZED REARRANGEMENTS OF BENZYL 9‐(TRIMETHYLGERMYL)‐9‐FLUORENYL ETHER (1980) (0)
- Cram Selectivity in the Reaction of 2‐Phenylpropanal with Alkyllithium Reagents: Myth and Reality. (1992) (0)
- 1H, 13C and 15N resonance assignments of Bacillus subtilis Lipase A mutant evolved towards thermostability (2012) (0)
- AR LCAO-HMO TRRATMRRT OF THE ACIDITY OF WSATURATED CARDOflDIC ACIDS (1967) (0)
- Dyotropic Rearrangements in Organic Solvents, in the Gas Phase, and in Enzyme Catalysis (2023) (0)
- Optimization of synthetic catalysts by directed evolution (2001) (0)
- Chiral Monophosphites and Monophosphonites as Ligands in Asymmetric Transition Metal Catalysis. (2003) (0)
- Mixtures of Chiral and Achiral Monodentate Ligands in Asymmetric Rh‐Catalyzed Olefin Hydrogenation: Reversal of Enantioselectivity. (2003) (0)
- Stereoselective Synthesis of γ-Aminocarboxylates. (1990) (0)
- Combinatorial and Evolution-Based Methods in the Creation of Enantioselective Catalysts (2001) (0)
- Tandem Aldolization/Lactonization/Dyotropic Rearrangement of α-Amino Aldehydes. (1990) (0)
- CONCERNING THE ROLE OF LEWIS ACIDS IN CHELATION-CONTROLLED ADDITION TO CHIRAL ALKOXY ALDEHYDES (1984) (0)
- titanium in catalysis (2020) (0)
- Phosphorodiamidite Derivatives of 1,1′-Bi-2-naphthol Containing Stereogenic Phosphorus Atoms as Ligands in Enantioselective Catalysis. (2011) (0)
- Titanium‐Mediated Stereoselective Knoevenagel Condensation of Ethyl (Diethoxyphosphoryl)acetate with Aldehydes. (1987) (0)
- Stereoselective Synthesis of β-Amino Hydroxylamines. (1995) (0)
- Publisher Correction: A machine learning approach for reliable prediction of amino acid interactions and its application in the directed evolution of enantioselective enzymes (2018) (0)
- DYOTROPIC REARRANGEMENTS, VIII. MECHANISM OF THE REARRANGEMENT OF (SILYL)METHYL SILYL ETHERS (1976) (0)
- SYNTHESIS OF β,Γ‐ AND α,β‐UNSATURATED KETONES USING ALLYLTITANIUM REAGENTS (1985) (0)
- Back Cover: Chemo‐ and Regioselective Dihydroxylation of Benzene to Hydroquinone Enabled by Engineered Cytochrome P450 Monooxygenase (Angew. Chem. Int. Ed. 3/2019) (2019) (0)
- Protective Group Tuning in the Stereoselective Conversion of α-Amino Aldehydes into Aminoalkyl Epoxides. (1990) (0)
- Publisher Correction: A machine learning approach for reliable prediction of amino acid interactions and its application in the directed evolution of enantioselective enzymes (2021) (0)
- 1H,13C,15N resonance assignment of wild-type Lipase A from Bacillus subtilis (2012) (0)
- Directed Evolution to Increase Pseudomonas sp. 42A2 LipC Thermostability (2010) (0)
- Reactions of 2-Lithio- and 2-Titanomethylquinoline Reagents: The Necessity of Using an Excess of Titanating Agents in Adjusting Molecular Recognition. (1991) (0)
- Electrochemical reduction of metal salt as controlling means for high dispersibility metal colloid and metal cluster fixed to base body by electrochemical reduction of metal salt (1995) (0)
- Crown Ethers with a Lewis-Acidic Center: A New Class of Heterotypic Host Molecules. (1992) (0)
- Engineering of a P450-based Kemp eliminase with a new mechanism (2023) (0)
- CH3Li/TiCl4: A Non-Basic and Highly Selective Grignard Analogue. (1986) (0)
- ANCHIMER ACCELERATED HOMOLYSES (1979) (0)
- HYDRIDE ELIMINATIONS. 2. STEREOSELECTIVE HYDRIDE ELIMINATION FROM ORGANIC LITHIUM AND MAGNESIUM COMPOUNDS (1977) (0)
- Nucleophilic Substitution of Vinylic Hydrogen Atoms by Carbanions (1977) (0)
- α‐tert‐Alkylation of Ketones: 2‐tert‐Pentylcyclopentanone (2003) (0)
- ANCHIMERICALLY ACCELERATED HOMOLYSES, II. SYNTHESIS, THERMOLYSIS, AND PHOTOLYSIS OF ALKYL (SILYLMETHYL) ETHERS (1978) (0)
- CARBON-CARBON BOND FORMATION USING ALKYLTITANIUM(IV) COMPOUNDS (1981) (0)
- Water-soluble nanostructured metal oxide colloids and methods for their preparation (1998) (0)
- Cationic Mono- and Bi-Nuclear Iron Complexes as Lewis Acid Catalysts in Mukaiyama Reactions. (2010) (0)
- Stereoselective Synthesis of α,γ-Diamino Acid Esters. (1993) (0)
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