Mary Rakowski DuBois
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American inorganic chemist
Mary Rakowski DuBois's AcademicInfluence.com Rankings
Mary Rakowski DuBoischemistry Degrees
Chemistry
#5500
World Rank
#6691
Historical Rank
#1004
USA Rank
Inorganic Chemistry
#314
World Rank
#330
Historical Rank
#43
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Chemistry
Mary Rakowski DuBois's Degrees
- PhD Chemistry California Institute of Technology
- Masters Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Mary Rakowski DuBois Influential?
(Suggest an Edit or Addition)According to Wikipedia, Mary Rakowski DuBois is an inorganic chemist, now retired from Pacific Northwest National Laboratory . She made multiple contributions to inorganic and organometallic chemistry, focusing on synthetic and mechanistic studies. In recognition of her scientific contributions, she received several awards.
Mary Rakowski DuBois's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s−1 for H2 Production (2011) (882)
- [Ni(P(Ph)2N(C6H4X)2)2]2+ complexes as electrocatalysts for H2 production: effect of substituents, acids, and water on catalytic rates. (2011) (310)
- Nature of hydrogen interactions with Ni(II) complexes containing cyclic phosphine ligands with pendant nitrogen bases (2007) (273)
- Catalytic applications of transition-metal complexes with sulfide ligands (1989) (249)
- Molybdenum-sulfur dimers as electrocatalysts for the production of hydrogen at low overpotentials. (2005) (165)
- Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere (2008) (144)
- Mechanistic insights into catalytic h(2) oxidation by ni complexes containing a diphosphine ligand with a positioned amine base. (2009) (141)
- Studies of a series of [Ni(P(R)2N(Ph)2)2(CH3CN)]2+ complexes as electrocatalysts for H2 production: substituent variation at the phosphorus atom of the P2N2 ligand. (2011) (124)
- Characterization of reactions of hydrogen with coordinated sulfido ligands (1980) (115)
- Near-Field Deformation from the El Mayor-Cucapah Earthquake Revealed by Differential LIDAR (2012) (114)
- Comprehensive thermodynamic characterization of the metal-hydrogen bond in a series of cobalt-hydride complexes. (2002) (106)
- Pendant bases as proton relays in iron hydride and dihydrogen complexes. (2006) (96)
- [Ni(PPh2NBn2)2(CH3CN)]2+ as an Electrocatalyst for H2 Production: Dependence on Acid Strength and Isomer Distribution (2011) (94)
- Comparison of Cobalt and Nickel Complexes with Sterically Demanding Cyclic Diphosphine Ligands: Electrocatalytic H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2† (2010) (92)
- Free-Energy Relationships between the Proton and Hydride Donor Abilities of [HNi(diphosphine)2]+ Complexes and the Half-Wave Potentials of Their Conjugate Bases (2001) (81)
- Synthesis of inequivalently bridged cyclopentadienyl dimers of molybdenum and a comparison of their reactivities with unsaturated molecules and with hydrogen (1983) (78)
- Syntheses, structures, and reactions of molybdenum complexes with sulfido and disulfido ligands (1981) (70)
- Stabilization of Nickel Complexes with Ni0•••H-N Bonding Interactions Using Sterically Demanding Cyclic Diphosphine Ligands (2012) (66)
- The role of pendant bases in molecular catalysts for H2 oxidation and production (2008) (65)
- Fast and efficient molecular electrocatalysts for H2 production: Using hydrogenase enzymes as guides (2011) (64)
- The role of the second coordination sphere of [Ni(PCy2NBz2)2](BF4)2 in reversible carbon monoxide binding. (2008) (59)
- Characterization and reaction studies of dimeric molybdenum(III) complexes with bridging dithiolate ligands. Catalytic reduction of acetylene to ethylene (1979) (55)
- Hydride Transfer from Rhodium Complexes to Triethylborane (2006) (52)
- HRh(dppb)2, a Powerful Hydride Donor (2002) (51)
- Stereochemical Control of Iron(II) Complexes Containing a Diphosphine Ligand with a Pendant Nitrogen Base (2005) (46)
- Homogeneous reductions of nitrogen-containing substrates catalyzed by molybdenum(IV) complexes with .mu.-sulfido ligands (1986) (41)
- Activation of hydrogen by cationic cyclopentadienyl molybdenum dimers with sulfido ligands. I: Cationic complexes derived from protonation of 1,2-alkenedithiolate ligands (1986) (39)
- A study of ionic and radical reactivities of bridging sulfido ligands in dimeric cyclopentadienyl complexes of molybdenum (1985) (37)
- Structure and reactivity of [CpFeS2]2 (1985) (37)
- Free energy landscapes for S-H bonds in Cp*2Mo2S4 complexes. (2009) (35)
- Kinetic studies and a molecular orbital interpretation of reactions at bridging sulfur ligands in dimeric molybdenum complexes (1981) (34)
- Studies of structural effects on the half-wave potentials of mononuclear and dinuclear nickel(II) diphosphine/dithiolate complexes. (2007) (33)
- Protonation of coordinated N2 on tungsten with H2 mediated by sulfido-bridged dinuclear molybdenum complexes. (2001) (31)
- Synthesis and reactivity of a dimeric molybdenum(III) complex with a bridging hydrosulfido ligand (1986) (30)
- Activation of hydrogen by cationic cyclopentadienylmolybdenum dimers with sulfido ligands. 2. Cationic complexes derived from reactions with vinyl halides (1986) (30)
- Determination of S−H Bond Strengths in Dimolybdenum Tetrasulfide Complexes (2009) (28)
- Facile reductive cleavage of the C=O bond of acyl halides and the C identical with N bond of nitriles by hydrogen in the presence of sulfido-bridged molybdenum complexes (1987) (27)
- Syntheses and structural characterizations of iron(II) complexes containing cyclic diphosphine ligands with positioned pendant nitrogen bases (2007) (26)
- Structural characterization of 1:2 tris(.mu.-benzenethiolato)bis[(hexamethylbenzeneruthenium] chloride-chloroform (1992) (26)
- Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation (2010) (25)
- Syntheses and Reactivities of Indole and Indolyl Complexes of (Cymene)Ru(II) (1995) (24)
- A study of sulfur ligand reactivity in dimeric dithiolate complexes of vanadium and tungsten (1984) (23)
- Carbon-chalcogen bond cleavage reactions characterized for dinuclear sulfur-bridged cyclopentadienyl molybdenum complexes (1997) (22)
- Reactions of a sulfido-bridged dinuclear molybdenum complex with nitriles and isonitriles under hydrogen: facile C.tplbond.N bond cleavage (1990) (22)
- Structures and reactivities of cyclopentadienylmolybdenum complexes with oxo and sulfido ligands (1988) (22)
- Mechanistic study of hydrogen activation by cationic dinuclear (.mu.-sulfido)molybdenum complexes (1992) (22)
- Syntheses and Reactions of Iron(II) Complexes Containing Diphosphine Ligands with Pendant Nitrogen Bases (2007) (21)
- Characterization of reversible reactions of isocyanides with molybdenum dithiolate complexes (1980) (20)
- The activation of η5-pyrrole complexes toward nucleophilic attack (1998) (19)
- REACTIONS OF METAL-DISULFUR COMPLEXES WITH NUCLEOPHILES AND ELECTROPHILES (1979) (19)
- Syntheses and structures of new molybdenum complexes with dithiobenzoate and dimercaptotoluene ligands. Structural comparisons in a series of dithiolate-bridged dimers of molybdenum(III) (1983) (19)
- SYNTHESES OF DINUCLEAR RHENIUM COMPLEXES WITH DISULFIDO AND SULFIDO LIGANDS (1997) (19)
- Syntheses and characterization of organometallic molybdenum-iron-sulfur and molybdenum-cobalt-sulfur clusters (1987) (18)
- HOMOGENEOUS HYDROGENOLYSIS OF CARBON DISULFIDE CATALYZED BY A MOLYBDENUM DIMER WITH SULFIDO LIGANDS (1983) (18)
- Electrochemical oxidation of H2 catalyzed by ruthenium hydride complexes bearing P2N2 ligands with pendant amines as proton relays (2014) (17)
- Synthesis and characterization of mononuclear indoline complexes. Studies of {sigma} and {pi} bonding modes (1997) (17)
- Activation of hydrogen by cationic cyclopentadienyl complexes with sulfido ligands. 3. Cationic complexes derived from reactions with halo esters, halo ketones, and acyl halides (1987) (16)
- Synthesis and structural characterization of an organometallic Mo2Fe2S4 cluster (1983) (16)
- Absorption and EPR spectral characterization of tetrasulfur-bridged mixed-valence dimers of molybdenum(III/IV). EPR evidence for tight ion pair formation in anionic systems (1986) (15)
- Reactivity of tetramethylpyrrole complexes of ruthenium and osmium (1994) (15)
- Dinuclear cyclopentadienylmolybdenum complexes containing thioether ligands. Ligand substitution and desulfurization reactions (1993) (15)
- Sites of electrophilic attack in neutral dithiolate-bridged molybdenum complexes (1992) (14)
- Molecular and Polymeric Compounds Resulting from Lewis Acid Interactions with [CpMo(.mu.-S)N-t-Bu]2 (1994) (14)
- Kinetic Studies of Olefin Binding to Sulfido Sites in Dinuclear Molybdenum Complexes (1995) (13)
- Molybdenum-95 NMR spectroscopy and its relation to the structure and reactivity of sulfur-bridged cyclopentadienylmolybdenum dimers (1987) (13)
- Substitution reactions of a .mu.-thioether ligand in dinuclear cyclopentadienylmolybdenum complexes (1995) (13)
- Iridium(I) Complexes Containing the η1-N-Bonded Indolyl Ligand (1997) (11)
- Reactivity studies of sulfur-bridged molybdenum dimers containing electron-withdrawing dithiolate substituents (1993) (11)
- Synthesis of a Rhenium(V) Polysulfide Complex and a Study of Its Reactivity with Hydrogen (2001) (11)
- Deuterium substitution of thiophenes by D2: catalytic role of a hydrosulfido-bridged molybdenum complex (1991) (11)
- Cleavage of saturated oxygen heterocycles by a dinuclear molybdenum complex containing sulfido and hydrosulfido ligands (1989) (11)
- Formation and reactivity of a persistent radical in a dinuclear molybdenum complex. (2008) (10)
- Synthesis of water soluble sulfur-bridged molybdenum dimers with substituted cyclopentadienyl ligands (1994) (10)
- Reactions of Thiiranes and a Thietane with a High Valent Metal Chloride (2000) (10)
- Regioselective Electrophilic Substitution and Addition Reactions at an N-Coordinated Pyrrolyl Ligand in (PMe2Ph)3Cl2Re(NC4H4) (1999) (10)
- Role of molybdenum complex [Cp*Mo(.mu.-S)]2S2CH2 in dichloromethane hydrogenolysis (1991) (10)
- DINUCLEAR MU -SULFIDO COMPLEXES OF MOLYBDENUM WITH (DIMETHYLAMINO)ETHYL-SUBSTITUTED CYCLOPENTADIENYL LIGANDS (1997) (9)
- Reactions of Sulfido-Bridged Molybdenum Dimers with Diynes as a Route to Multinuclear Dithiolene Complexes (2005) (9)
- Syntheses and structures of bis(thioether)-bridged rhodium complexes and their catalytic reactions with alkynes (1987) (9)
- Insertions of unactivated olefins into the hydrosulfido ligand of a cationic cyclopentadienylmolybdenum complex (1990) (9)
- Analyzing harvesting equipment investments using reverse capital budgeting techniques (1999) (8)
- Nucleophilic Substitution of η5-Pyrrolyl Ligands in Ruthenium(II) Complexes (1997) (8)
- Synthesis and reactivity of an unusual oxidation product of bis[(.mu.-mercapto)(.mu.-thio)cyclopentadienylmolybdenum] (1988) (8)
- Electrophilic Substitution of Nitrogen Heterocycles by Molybdenum Sulfide Complexes (2000) (8)
- Syntheses and structures of dinuclear molybdenum complexes containing reactive .mu.-thiolate-thioether ligands (1991) (8)
- Expansion of the molybdenum coordination sphere in dinuclear tetrasulfur-bridged complexes with the Cp2Mo2S4 core (1987) (8)
- Mononuclear Indoline Complexes. 2. Synthesis, Structure, and Reactivity of [(Cymene)Ru(η1-N-indoline)(CH3CN)2](OTf)2 (1998) (6)
- A Modular Approach to the Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals (2010) (6)
- Reactions of cationic dinuclear molybdenum complexes containing μ-sulfido and μ-thiolate ligands (1996) (6)
- Reactions of a cationic molybdenum complex with olefins. II: Oligomerization of 1,1-disubstituted olefins (1994) (5)
- Characterization of new tungsten(VI) amide complexes (1993) (5)
- Syntheses, Structures, and Reactions of Cyclopentadienyl Metal Complexes with Bridging Sulfur Ligands (1997) (4)
- Electrochemical Properties of Electrodes Modified with Polymers Containing a Sulfur Bridged Dinuclear Molybdenum Complex (1989) (4)
- Synthesis of a Re-Pt2 Complex with Bridging Sulfido Ligands (2003) (4)
- SYNTHESIS AND CHARACTERIZATION OF A SERIES OF THIOBENZOATE COMPLEXES OF MOLYBDENUM(V) (1978) (4)
- A molecular orbital comparison of molybdenum-sulfur dimers with sulfido ligands bridged by CH2 and FeCp fragments (1993) (4)
- Dual functions of NifEN : insights into the evolution and mechanism of nitrogenase (2010) (3)
- 10. Polynuclear Cyclopentadienyliron Complexes Containing the S2 Ligand (2007) (3)
- Activation of hydrogen by cationic cyclopentadienyl molybdenum dimers with sulfido ligands. 4. A cationic complex with an allyl thiolate ligand (1988) (2)
- DITHIOLATO AND HYDROSULFIDO BRIDGED DIMERS OF CYCLOPENTADIENYLMOLYBDENUM (1986) (2)
- Mixed Valence Dinuclear Molybdenum Complexes (1989) (2)
- Carbon-Chalcogen Bond Cleavage Reactions Characterized for Dinuclear Sulfur-Bridged Cyclopentadienyl-Molybdenum Complexes (1997) (1)
- Mechanistic study of hydrogen activation by cationic dinuclear (.mu.-sulfido)molybdenum complexes. [Erratum to document cited in CA117(5):48806d] (1992) (1)
- Reactions of Dithiolate Ligands in Mononuclear Complexes of Rhenium(V). 2. Cp‘ ‘ReCl2(η2-SC3H6S) and Related Derivatives† (2003) (1)
- Molybdenum‐Sulfur Cluster Chelates (2007) (1)
- Activation of Hydrogen by Cationic Cyclopentadienyl Molybdenum Dimers with Sulfido Ligands. Part 1. Cationic Complexes Derived from Protonation of 1,2-Alkenedithiolate Ligands. (1987) (1)
- Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine (2010) (1)
- Synthesis and reactions of ruthenium pyrrole complexes (1993) (0)
- 95Mo NMR Spectroscopic and Its Relation to the Structure and Reactivity of Sulfur-Bridged Cyclopentadienylmolybdenum Dimers. (1987) (0)
- Molecular nickel diphosphine electrocatalysts for hydrogen oxidation and production: The function of proton relays in the secondary coordination sphere (2011) (0)
- A United States Patent ( 19 ) 11 Patent Number : 5 , 430 , 225 (2017) (0)
- Iron(II) Complexes Containing a Diphosphine Ligand with an Internal Nitrogen Base (2005) (0)
- Structures and Reactivities of Cyclopentadienylmolybdenum Complexes with Oxo and Sulfido Ligands. (1988) (0)
- Activation of Hydrogen by Cationic Cyclopentadienyl Molybdenum Dimers with Sulfido Ligands. Part 2. Cationic Complexes Derived from Reactions with Vinyl Halides. (1987) (0)
- Role of proton relays in molecular electrocatalysts for hydrogen oxidation and production (2011) (0)
- η3‐Allylhydridobis[Ethylenebis (Diphenylphosphine)]Molybdenum(II) (2007) (0)
- Facile Reductive Cleavage of the C=O Bond of Acyl Halides and the CN Bond of Nitriles by Hydrogen in the Presence of Sulfido-Bridged Molybdenum Complexes. (1987) (0)
- Electrocatalytic oxidation and production of hydrogen using cobalt and nickel complexes containing diphospine ligands with pendant nitrogen bases (2008) (0)
- Expansion of the Molybdenum Coordination Sphere in Dinuclear Tetrasulfur‐Bridged Complexes with the Cp2Mo2S4 Core. (1987) (0)
- Catalysis by Sulfidobridged Dimolybdenum Complexes (1998) (0)
- CCDC 874532: Experimental Crystal Structure Determination (2012) (0)
- Synthesis and Reactivity of an Unusual Oxidation Product of (C5H5Mo(μ-S)(μ-SH))2. (1988) (0)
- Role of the first coordination sphere in hydrogen oxidation/production, hydrogen storage, and carbon dioxide reduction catalysts (2007) (0)
- showcasing the latest research on all aspects of hydrogen generation, storage and activation (2010) (0)
- Synthesis and Reactivity of a Dimeric Molybdenum(III) Complex with a Bridging Hydrosulfido Ligand. (1987) (0)
- Modular approach to molecular electrocatalysts for H2 production and oxidation (2010) (0)
- Absorption and EPR Spectral Characterization of Tetrasulfur‐Bridged Mixed‐Valence Dimers of Molybdenum(III/ IV) (I)‐(V). (1986) (0)
- The Activation of η5‐Pyrrole Complexes Toward Nucleophilic Attack (1999) (0)
- Iconography : The role of pendant bases in molecular catalysts for H 2 oxidation and production (2008) (0)
- Reactions of a Sulfido-Bridged Dinuclear Molybdenum Complex with Nitriles and Isonitriles Under Hydrogen: Facile CN Bond Cleavage. (1990) (0)
- Proton Delivery and Removal in [Ni(P<sup>R</sup><sub>2</sub>N<sup>R<sup></sup></sup><sub>2</sub>)<sub>2</sub>]<sup>2+</sup> Hydrogen Production and Oxidation Catalysts (2012) (0)
- Reactions of Cationic Dinuclear Molybdenum Complexes Containing μ‐ Sulfido and μ‐Thiolate Ligands (1997) (0)
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