Matthew Sigman
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American chemist
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Chemistry
Matthew Sigman's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Matthew Sigman Influential?
(Suggest an Edit or Addition)According to Wikipedia, Matthew S. Sigman is an American chemist, focusing in Organic Synthesis & Asymmetric Catalysis. He is the Peter J. Christine S. Stang Presidential Endowed Chair and Distinguished Honors Professor at University of Utah and a Fellow of the American Association for the Advancement of Science.
Matthew Sigman's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners. (2011) (1491)
- SCHIFF BASE CATALYSTS FOR THE ASYMMETRIC STRECKER REACTION IDENTIFIED AND OPTIMIZED FROM PARALLEL SYNTHETIC LIBRARIES (1998) (662)
- Ligand-modulated palladium-catalyzed aerobic alcohol oxidations. (2006) (461)
- Exploiting non-covalent π interactions for catalyst design (2017) (427)
- Substrate channelling as an approach to cascade reactions. (2016) (426)
- Recent advances in homogeneous transition metal-catalyzed aerobic alcohol oxidations (2006) (356)
- Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant. (2009) (334)
- Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions. (2008) (321)
- Enantioselective Construction of Remote Quaternary Stereocenters (2014) (293)
- Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy (2012) (271)
- Applications of ortho-quinone methide intermediates in catalysis and asymmetric synthesis. (2011) (255)
- Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen. (2001) (243)
- A well-defined complex for palladium-catalyzed aerobic oxidation of alcohols: design, synthesis, and mechanistic considerations. (2003) (240)
- Enantioselective Addition of Hydrogen Cyanide to Imines Catalyzed by a Chiral (Salen)Al(III) Complex (1998) (240)
- The Development of Multidimensional Analysis Tools for Asymmetric Catalysis and Beyond. (2016) (216)
- Multidimensional steric parameters in the analysis of asymmetric catalytic reactions. (2012) (186)
- Palladium(II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: a pronounced effect of copper additives on enantioselectivity. (2007) (180)
- Synthesis and preliminary biological studies of 3-substituted indoles accessed by a palladium-catalyzed enantioselective alkene difunctionalization reaction. (2010) (180)
- Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids. (2013) (176)
- A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids. (2011) (173)
- Elucidating the significance of beta-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols. (2004) (171)
- Recent progress in Wacker oxidations: moving toward molecular oxygen as the sole oxidant. (2007) (164)
- Mechanistic questions about the reaction of molecular oxygen with palladium in oxidase catalysis. (2006) (158)
- Imparting catalyst control upon classical palladium-catalyzed alkenyl C-H bond functionalization reactions. (2012) (154)
- A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis (2015) (153)
- Three-Dimensional Correlation of Steric and Electronic Free Energy Relationships Guides Asymmetric Propargylation (2011) (153)
- Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines. (2017) (149)
- Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols (2014) (145)
- Palladium-catalyzed oxidative intermolecular difunctionalization of terminal alkenes with organostannanes and molecular oxygen. (2009) (141)
- Zebrafish screen identifies novel compound with selective toxicity against leukemia. (2012) (140)
- Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis. (2017) (140)
- A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature. (2002) (137)
- Parameterization of phosphine ligands reveals mechanistic pathways and predicts reaction outcomes (2016) (133)
- Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reaction. (2010) (128)
- Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications. (2017) (127)
- A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms (2019) (127)
- Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols. (2005) (123)
- Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically nonbiased olefins. (2011) (122)
- Predictive and mechanistic multivariate linear regression models for reaction development (2018) (116)
- Palladium-catalyzed enantioselective addition of two distinct nucleophiles across alkenes capable of quinone methide formation. (2009) (114)
- Holistic Prediction of Enantioselectivity in Asymmetric Catalysis (2019) (113)
- A highly selective and general palladium catalyst for the oxidative Heck reaction of electronically nonbiased olefins. (2010) (112)
- Palladium catalysts for aerobic oxidative kinetic resolution of secondary alcohols based on mechanistic insight. (2003) (109)
- Analyzing Site Selectivity in Rh2(esp)2-Catalyzed Intermolecular C–H Amination Reactions (2014) (109)
- Discovery of and mechanistic insight into a ligand-modulated palladium-catalyzed Wacker oxidation of styrenes using TBHP. (2005) (108)
- Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters. (2015) (108)
- Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes. (2013) (105)
- Using mechanistic and computational studies to explain ligand effects in the palladium-catalyzed aerobic oxidation of alcohols. (2005) (99)
- Interrogating selectivity in catalysis using molecular vibrations (2014) (98)
- Oxygen-induced ligand dehydrogenation of a planar bis-mu-chloronickel(I) dimer featuring an NHC ligand. (2005) (94)
- Systematically probing the effect of catalyst acidity in a hydrogen-bond-catalyzed enantioselective reaction. (2007) (92)
- A general and efficient catalyst system for a Wacker-type oxidation using TBHP as the terminal oxidant: application to classically challenging substrates. (2009) (92)
- Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization (2018) (90)
- High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries (2018) (89)
- Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones. (2007) (89)
- Palladium-catalyzed 1,1-difunctionalization of ethylene. (2012) (87)
- Hybrid enzymatic and organic electrocatalytic cascade for the complete oxidation of glycerol. (2014) (86)
- Discovery of a practical direct O2-coupled Wacker oxidation with Pd[(-)-sparteine]Cl2. (2006) (86)
- The renaissance of palladium(II)-catalyzed oxidation chemistry. (2004) (86)
- Palladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy. (2015) (86)
- Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion. (2016) (85)
- A Palladium-Catalyzed Three-Component-Coupling Strategy for the Differential Vicinal Diarylation of Terminal 1,3-Dienes (2014) (84)
- Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer. (2016) (81)
- Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol. (2006) (80)
- Dual role of (-)-sparteine in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols. (2002) (80)
- On the mechanism of the palladium-catalyzed tert-butylhydroperoxide-mediated Wacker-type oxidation of alkenes using quinoline-2-oxazoline ligands. (2011) (79)
- Palladium-catalyzed hydroarylation of 1,3-dienes with boronic esters via reductive formation of pi-allyl palladium intermediates under oxidative conditions. (2010) (77)
- Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols (2014) (76)
- Photophysics of 2'-Deoxyuridine (dU) Nucleosides Covalently Substituted with Either 1-Pyrenyl or 1-Pyrenoyl: Observation of Pyrene-to-Nucleoside Charge-Transfer Emission in 5-(1-Pyrenyl)-dU (1995) (76)
- Quantitatively correlating the effect of ligand-substituent size in asymmetric catalysis using linear free energy relationships. (2008) (76)
- Mechanistic investigations of the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols using (-)-sparteine. (2003) (76)
- Examination of the role of Taft-type steric parameters in asymmetric catalysis. (2009) (75)
- Predicting Electrocatalytic Properties: Modeling Structure-Activity Relationships of Nitroxyl Radicals. (2015) (75)
- Predicting and optimizing asymmetric catalyst performance using the principles of experimental design and steric parameters (2011) (74)
- Comparing quantitative prediction methods for the discovery of small-molecule chiral catalysts (2018) (74)
- Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systems. (2015) (74)
- Design of hydrogen bond catalysts based on a modular oxazoline template: application to an enantioselective hetero Diels-Alder reaction. (2005) (72)
- Palladium-catalyzed reductive coupling of styrenes and organostannanes under aerobic conditions. (2007) (72)
- Using physical organic parameters to correlate asymmetric catalyst performance. (2013) (71)
- Palladium-catalyzed allylic cross-coupling reactions of primary and secondary homoallylic electrophiles. (2012) (70)
- Palladium(II)-catalyzed aerobic hydroalkoxylation of styrenes containing a phenol. (2006) (70)
- Transition-metal-catalyzed laboratory-scale carbon-carbon bond-forming reactions of ethylene. (2013) (69)
- Palladium(II)-catalyzed enantio- and diastereoselective synthesis of pyrrolidine derivatives. (2012) (69)
- Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration. (2019) (69)
- Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes (2015) (69)
- Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters. (2008) (68)
- Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers. (2016) (67)
- Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis. (2017) (67)
- Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery. (2019) (65)
- Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted Homoallylic Alcohols. (2016) (65)
- Stereochemical diversity in chiral ligand design: discovery and optimization of catalysts for the enantioselective addition of allylic halides to aldehydes. (2005) (64)
- Asymmetric palladium-catalyzed hydroarylation of styrenes and dienes. (2011) (64)
- Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates. (2013) (64)
- Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates. (2017) (64)
- Developing a Modern Approach To Account for Steric Effects in Hammett-Type Correlations. (2016) (63)
- Unusual reactivity of molecular oxygen with pi-allylnickel(N-heterocyclic carbene) chloride complexes. (2003) (62)
- Quantitatively analyzing metathesis catalyst activity and structural features in silica-supported tungsten imido-alkylidene complexes. (2015) (62)
- Cobalt-Catalyzed Cyclotrimerization of Alkynes in Aqueous Solution (1998) (60)
- Prediction of catalyst and substrate performance in the enantioselective propargylation of aliphatic ketones by a multidimensional model of steric effects. (2013) (60)
- Pd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins. (2010) (60)
- Scope of enantioselective palladium(II)-catalyzed aerobic alcohol oxidations with (-)-sparteine. (2003) (57)
- Synthesis and preliminary biological study of bisindolylmethanes accessed by an acid-catalyzed hydroarylation of vinyl indoles (2012) (57)
- Evaluation of catalyst acidity and substrate electronic effects in a hydrogen bond-catalyzed enantioselective reaction. (2010) (56)
- Developing Comprehensive Computational Parameter Sets To Describe the Performance of Pyridine-Oxazoline and Related Ligands (2017) (54)
- Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization. (2017) (53)
- Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes. (2017) (53)
- Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis. (2017) (53)
- Wacker-type oxidation of internal alkenes using Pd(Quinox) and TBHP. (2013) (52)
- Designer substrate library for quantitative, predictive modeling of reaction performance (2014) (52)
- Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives. (2017) (51)
- Catalyst-controlled Wacker-type oxidation of protected allylic amines. (2010) (51)
- Experimental and computational study of a direct O2-coupled Wacker oxidation: water dependence in the absence of Cu salts. (2010) (51)
- Modular synthesis of amine-functionalized oxazolines. (2002) (50)
- Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol). (2010) (50)
- Advances in Transition Metal (Pd, Ni, Fe)‐Catalyzed Cross‐Coupling Reactions Using Alkyl‐Organometallics as Reaction Partners (2011) (48)
- TEMPO-Modified Linear Poly(ethylenimine) for Immobilization-Enhanced Electrocatalytic Oxidation of Alcohols (2015) (47)
- Palladium-catalyzed hydrofunctionalization of vinyl phenol derivatives with heteroaromatics. (2011) (47)
- Palladium-catalyzed aerobic oxidative kinetic resolution of alcohols with an achiral exogenous base. (2003) (46)
- Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles. (2018) (45)
- Catalytic Iron-Mediated [4 + 1] Cycloaddition of Diallenes with Carbon Monoxide (1996) (45)
- Catalytic iron-mediated carbon-oxygen and carbon-carbon bond formation in [4 + 1] assembly of alkylidenebutenolides (1993) (45)
- Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates. (2019) (44)
- Pd(II)-catalyzed conversion of styrene derivatives to acetals: impact of (-)-sparteine on regioselectivity. (2006) (44)
- Origin of enantioselection in chiral alcohol oxidation catalyzed by Pd[(-)-sparteine]Cl2. (2005) (43)
- Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams. (2018) (43)
- Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters. (2017) (43)
- Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines (2019) (42)
- Enantioselective construction of remote tertiary carbon–fluorine bonds (2019) (40)
- Steric effects in the aerobic oxidation of pi-allylnickel(II) complexes with N-heterocyclic carbenes. (2006) (40)
- Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-carbon sp3-sp3 bonds under oxidative conditions. (2009) (38)
- Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-Transfer of Aryl Diazonium Salts. (2017) (38)
- Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes. (2019) (38)
- Substrate Channeling in an Artificial Metabolon: A Molecular Dynamics Blueprint for an Experimental Peptide Bridge (2017) (38)
- Anti-Markovnikov hydroalkylation of allylic amine derivatives via a palladium-catalyzed reductive cross-coupling reaction. (2011) (37)
- A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions. (2017) (36)
- Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis (2021) (36)
- Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes (2018) (36)
- Development of a general Pd(II)-catalyzed intermolecular hydroalkoxylation reaction of vinylphenols by using a sacrificial alcohol as the hydride source. (2006) (36)
- A Comprehensive Discovery Platform for Organophosphorus Ligands for Catalysis (2021) (35)
- Development and investigation of a site selective palladium-catalyzed 1,4-difunctionalization of isoprene using pyridine–oxazoline ligands (2014) (35)
- The first iron-mediated catalytic carbon-nitrogen bond formation: [4 + 1] Cycloaddition of allenyl imines and carbon monoxide (1994) (34)
- A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation. (2019) (34)
- Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones. (2018) (34)
- Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element? (2019) (34)
- Diastereoselective synthesis of piperazines by manganese-mediated reductive cyclization. (2003) (33)
- Organometallic nonlinear optical polymers. 3. Copolymerization of bridged bis(ferrocenyl) and bis(cyanoacetate) monomers via the Knoevenagel condensation (1992) (33)
- Distinctive meta-directing group effect for iridium-catalyzed 1,1-diarylalkene enantioselective hydrogenation. (2013) (32)
- Catalyst-controlled Wacker-type oxidation of homoallylic alcohols in the absence of protecting groups. (2011) (32)
- Enantioselective Allenoate-Claisen Rearrangement using Chiral Phosphate Catalysts. (2020) (32)
- Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis. (2018) (30)
- Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization (2015) (30)
- Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction. (2020) (29)
- Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization. (2019) (29)
- Quantifying Structural Effects of Amino Acid Ligands in Pd(II)-Catalyzed Enantioselective C-H Functionalization Reactions (2017) (28)
- Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols. (2016) (28)
- Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines. (2017) (27)
- The development and mechanistic investigation of a palladium-catalyzed 1,3-aryl fl uorination of chromenes † (2017) (26)
- Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers. (2018) (26)
- Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction. (2019) (26)
- Coupling Pd-Catalyzed Alcohol Oxidation to Olefin Functionalization: Hydrohalogenation/Hydroalkoxylation of Styrenes. (2007) (26)
- The strategic generation and interception of palladium-hydrides for use in alkene functionalization reactions (2014) (25)
- Rapid chemiexcitation of phenoxy-dioxetane luminophores yields ultrasensitive chemiluminescence assays (2018) (25)
- N-Ammonium Ylide Mediators for Electrochemical C-H Oxidation. (2021) (24)
- Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides. (2020) (24)
- Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States. (2017) (23)
- Wacker Oxidation, The (2014) (23)
- Data Science Meets Physical Organic Chemistry. (2021) (22)
- Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate† †Electronic supplementary information (ESI) available: Experimental procedures and computational details are provided. CCDC 1408224. For ESI and crystallographic data in CIF or other el (2016) (21)
- A new approach to carbon-carbon bond formation: Development of aerobic Pd-catalyzed reductive coupling reactions of organometallic reagents and styrenes. (2009) (20)
- Peroxide-Mediated Wacker Oxidations for Organic Synthesis. (2012) (20)
- The Evolution of Data-Driven Modeling in Organic Chemistry (2021) (20)
- Relative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction. (2015) (20)
- LOW-TEMPERATURE STUDY OF THE IRON-MEDIATED 4 + 1 CYCLIZATION OF ALLENYL KETONES WITH CARBON MONOXIDE (1996) (19)
- Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for Enantioselective [3 + 2] Cycloaddition. (2020) (19)
- Development of a screen to identify selective small molecules active against patient-derived metastatic and chemoresistant breast cancer cells (2013) (19)
- Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines. (2019) (19)
- Polymer-immobilized, hybrid multi-catalyst architecture for enhanced electrochemical oxidation of glycerol. (2017) (18)
- Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding. (2020) (18)
- A General Catalyst for the Asymmetric Strecker Reaction. (2000) (17)
- Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines (2021) (17)
- Connecting and Analyzing Enantioselective Bifunctional Hydrogen Bond Donor Catalysis using Data Science Tools. (2020) (17)
- Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings. (2021) (16)
- Non-Covalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis. (2019) (15)
- Linear Regression Model Development for Analysis of Asymmetric Copper-Bisoxazoline Catalysis. (2021) (15)
- Interrogation of 2,2'-Bipyrimidines as Low-Potential Two-Electron Electrolytes. (2021) (15)
- Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates. (2017) (15)
- Synthesis of amine functionalized oxazolines with applications in asymmetric catalysis (2009) (15)
- Pd(Quinox)-Catalyzed Allylic Relay Suzuki Reactions of Secondary Homostyrenyl Tosylates via Alkene-Assisted Oxidative Addition. (2014) (14)
- Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters (2016) (14)
- Site-selective acylation of natural products with BINOL-derived phosphoric acids. (2019) (14)
- Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling. (2020) (14)
- Palladium-Catalyzed 1,3-Difunctionalization Using Terminal Alkenes with Alkenyl Nonaflates and Aryl Boronic Acids. (2016) (14)
- Simultaneously Enhancing the Redox Potential and Stability of Multi-Redox Organic Catholytes by Incorporating Cyclopropenium Substituents. (2021) (13)
- Linear Free Energy Relationships (LFERs) in Asymmetric Catalysis (2013) (13)
- Intermolecular reductive coupling of hindered N -aryl imines towards the modular synthesis of chiral N -heterocyclic carbenes (2005) (13)
- Transition State Force Field for the Asymmetric Redox Relay Heck Reaction. (2020) (13)
- Cobalt-electrocatalytic HAT for functionalization of unsaturated C–C bonds (2022) (13)
- Palladium-Catalyzed Enantioselective Alkenylation of Enelactams using a Relay Heck Strategy. (2019) (12)
- The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives. (2013) (12)
- Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest. (2019) (12)
- Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02223b (2018) (12)
- Organic Chemistry: A Call to Action for Diversity and Inclusion. (2020) (12)
- Mechanism and Selectivity in the Pd-Catalyzed Difunctionalization of Isoprene. (2016) (11)
- A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A. (2018) (11)
- The small molecule C-6 is selectively cytotoxic against breast cancer cells and its biological action is characterized by mitochondrial defects and endoplasmic reticulum stress (2014) (11)
- Bioinspired design of a hybrid bifunctional enzymatic/organic electrocatalyst for site selective alcohol oxidation. (2018) (11)
- Mechanistic Guidance Leads to Enhanced Site-Selectivity in C–H Oxidation Reactions Catalyzed by Ruthenium bis(Bipyridine) Complexes (2021) (10)
- Transition-Metal-Catalyzed Laboratory-Scale Carbon—Carbon Bond-Forming Reactions of Ethylene (2014) (10)
- Advancing Discovery in Chemistry with Artificial Intelligence: From Reaction Outcomes to New Materials and Catalysts. (2021) (10)
- Experimental Protocols for Studying Organic Non-aqueous Redox Flow Batteries (2021) (9)
- Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir)† †Electronic supplementary information (ESI) available: Experimental details, computational details an (2018) (9)
- Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine Derivatives in Aqueous Acid. (2020) (9)
- Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of 2-Indole Triflates. (2018) (9)
- Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions† (2020) (8)
- Organic Chemistry: A Call to Action for Diversity and Inclusion. (2020) (8)
- Analyzing mechanisms in Co(i) redox catalysis using a pattern recognition platform† (2020) (7)
- Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β‐Unsaturated Systems. (2015) (7)
- Enantioselective Synthesis of γ-Functionalized Cyclopentenones and δ-Functionalized Cycloheptenones Utilizing a Redox-Relay Heck Strategy. (2019) (7)
- Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides† (2021) (7)
- Development of High Energy Density Diaminocyclopropenium-Phenothiazine Hybrid Catholytes for Non-Aqueous Redox Flow Batteries. (2021) (6)
- Molecular Oxygen Binding and Activation: Oxidation Catalysis (2006) (6)
- Molecular-level insight in supported olefin metathesis catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis (2020) (6)
- Palladium‐Catalyzed Allylic Cross‐Coupling Reactions of Primary and Secondary Homoallylic Electrophiles. (2013) (6)
- Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck Reaction. (2021) (5)
- Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck Alkenylation of O-Alkyl Enol Ethers. (2019) (5)
- Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02380a (2019) (5)
- Addition of primary amines to conjugated allenyl aldehydes and ketones (1993) (4)
- Noncovalent Stabilization of Radical Intermediates in the Enantioselective Hydroamination of Alkenes with Sulfonamides. (2022) (4)
- Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions. (2022) (4)
- Design and Application of a Screening Set for Monophosphine Ligands in Cross-Coupling (2022) (4)
- Catalytic enantioselective oxidations using molecular oxygen. (2002) (4)
- Metal‐mediated and ‐catalyzed Oxidations Using N‐Heterocyclic Carbene Ligands (2006) (4)
- Enantioselective Redox‐Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols Using Boronic Acids. (2013) (3)
- Predicting relative efficiency of amide bond formation using multivariate linear regression (2022) (3)
- Development and Molecular Understanding of a Pd-catalyzed Cyanation of Aryl Boronic Acids Enabled by High-Throughput Experimentation and Data Analysis (2021) (3)
- Cobalt-Electrocatalytic Hydrogen Atom Transfer for Functionalization of Unsaturated C–C Bonds (2021) (3)
- Elucidating the Significance of β-Hydride Elimination and the Dynamic Role of Acid/Base Chemistry in a Palladium-Catalyzed Aerobic Oxidation of Alcohols (2009) (3)
- Atroposelective Negishi Coupling Optimization Guided by Multivariate Linear Regression Analysis: Asymmetric Synthesis of KRAS G12C Covalent Inhibitor GDC-6036. (2022) (3)
- Linking Mechanistic Analysis of Catalytic Reactivity Cliffs to Ligand Classification (2021) (3)
- A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors for Alcohols with Remote γ-Stereocenters. (2021) (3)
- PdII‐Catalyzed Oxidative 1,1‐Diarylation of Terminal Olefins. (2010) (3)
- Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative Conditions. (2010) (3)
- Design and Application of a Screening Set for Monophosphine Lig-ands in Metal Catalysis (2021) (3)
- Comparing Halogen Atom Abstraction Kinetics for Mn(I), Fe(I), Co(I), and Ni(I) Complexes by Combining Electroanalytical and Statistical Modeling (2022) (2)
- Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction". (2019) (2)
- Correction to "Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives". (2021) (2)
- Multiple family therapy with severely disturbed psychiatric patients. (1985) (2)
- Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques. (2022) (2)
- Palladium‐Catalyzed Oxidative Intermolecular Difunctionalization of Terminal Alkenes with Organostannanes and Molecular Oxygen. (2009) (2)
- Leveraging Regio- and Stereoselective C(sp3)-H Functionalization of Silyl Ethers to Train a Logistic Regression Classification Model for Predicting Site-Selectivity Bias. (2022) (2)
- Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines". (2018) (2)
- Catalytic asymmetric C–H insertion reactions of vinyl carbocations (2022) (2)
- Palladium‐Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols (2002) (1)
- Statistical Analysis of Catalytic Performance in Ethylene/Methyl Acrylate Copolymerization Using Palladium/Phosphine-Sulfonate Catalysts (2022) (1)
- zed enantioselective alkenylation of alkenylbenzene derivatives † (2019) (1)
- Palladium(II)‐Catalyzed Enantioselective Aerobic Dialkoxylation of 2‐Propenyl Phenols: A Pronounced Effect of Copper Additives on Enantioselectivity. (2007) (1)
- Small Molecule Properties Define Partitioning into Biomolecular Condensates (2022) (1)
- Scope of Enantioselective Palladium(II)‐Catalyzed Aerobic Alcohol Oxidations with (‐)‐Sparteine. (2003) (1)
- Chapter 12:Oxidation Reactions with NHC–Metal Complexes (2010) (1)
- Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes". (2018) (1)
- Enantioselective C2-alkylation of indoles via a redox-relay Heck reaction of 2-indole triflates (2019) (1)
- Pd(II)-Catalyzed Enantioselective, Aerobic Dialkoxylation of Olefins (2007) (1)
- Synthesis and Preliminary Biological Study of Bisindolylmethanes Accessed by an Acid-Catalyzed Hydroarylation of Vinyl Indoles. (2012) (1)
- Palladium‐Catalyzed Hydroalkylation of Styrenes with Organozinc Reagents to Form Carbon—Carbon sp3—sp3 Bonds under Oxidative Conditions. (2010) (1)
- Workflow for Biocatalytic Reaction Performance Prediction and Analysis (2021) (1)
- Organic Chemistry: A Call to Action for Diversity and Inclusion. (2020) (1)
- Impact of Phosphine Featurization Methods in Process Development (2022) (1)
- Operationally Simple and Highly (E)‐Styrenyl‐Selective Heck Reactions of Electronically Nonbiased Olefins. (2011) (0)
- Development of statistical modeling tools for the analysis of conformationally flexible chiral catalysts (2020) (0)
- A Drug Screen in Zebrafish Identifies a New Therapeutic Agent Active in Acute Lymphoblastic Leukemia (2010) (0)
- Enantioselective Difunctionalization of Alkenes Catalyzedby Palladium(II) (2010) (0)
- uorination of homoallylic alcohols enabled by the tuning of non-covalent interactions † (2018) (0)
- A Serious Look at Serious Music Publishing (1988) (0)
- Mechanistic Questions about the Reaction of Molecular Oxygen with Palladium in Oxidase Catalysis (2007) (0)
- Cobalt-Catalyzed Cyclotrimerization of Alkynes in Aqueous Solution. (2010) (0)
- Abstract B05: Targeting nonapoptotic cell death in chemoresistant patient-derived breast cancer cells (2013) (0)
- N-Ammonium Ylide Mediators for Selective Electrochemical C–H Oxidation (2021) (0)
- Ligand‐Modulated Palladium‐Catalyzed Aerobic Alcohol Oxidations (2006) (0)
- Synthesis and Preliminary Biological Study of Bisindolylmethanes Accessed by an Acid-Catalyzed Hydroarylation of Vinylindoles. (2012) (0)
- Development of High Energy Density Diaminocyclopropenium‐Phenothiazine Hybrid Catholytes for Non‐Aqueous Redox Flow Batteries (2021) (0)
- Data science enables the development of a new class of chiral phosphoric acid catalysts (2023) (0)
- Theoretical and Experimental Investigation of Functionalized Cyanopyridines Yield an Anolyte with an Extremely Low Reduction Potential for Nonaqueous Redox Flow Batteries (2022) (0)
- Palladium‐Catalyzed Aerobic Oxidative Kinetic Resolution of Alcohols with an Achiral Exogenous Base. (2004) (0)
- Oxidation Reactions with NHC‐Metal Complexes (2011) (0)
- The Complete Oxidation of Glycerol to CO2: A Hybrid Enzymatic and Organic Electrocatalytic Cascade (2015) (0)
- Coupling Pd‐Catalyzed Alcohol Oxidation to Olefin Functionalization: Hydrohalogenation/Hydroalkoxylation of Styrenes. (2008) (0)
- Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes. (2015) (0)
- to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C – H functionalization † (2015) (0)
- An Explosophore-Based Approach Towards the Prediction of Energetic Material Sensitivity Properties (2021) (0)
- anti‐Markovnikov Hydroalkylation of Allylic Amine Derivatives via a Palladium‐Catalyzed Reductive Cross‐Coupling Reaction. (2012) (0)
- The Strategic Generation and Interception of Palladium‐Hydrides for Use in Alkene Functionalization Reactions (2014) (0)
- The small molecule C-6 is selectively cytotoxic against breast cancer cells and its biological action is characterized by mitochondrial defects and endoplasmic reticulum stress (2014) (0)
- Catalytic Iron‐Mediated Carbon‐Oxygen and Carbon‐Carbon Bond Formation in (4 + 1) Assembly of Alkylidenebutenolides. (1993) (0)
- (S)‐4‐(tert‐Butyl)‐2‐[4‐(trifluoromethyl)pyridin‐2‐yl]‐4,5‐dihydrooxazole (2016) (0)
- Managing Python Package Installations with Anaconda Technology (0)
- Modular Catalysts for the Enantioselective Allylation of Aldehydes (2005) (0)
- Palladium/Quinox-Catalyzed Wacker-Type Oxidationof Terminal Olefins (2009) (0)
- A Physical Organic Approach towards Statistical Modeling of Tetrazole and Azide Decomposition. (2023) (0)
- Synthesis of Amine Functionalized Oxazolines with Applications in Asymmetric Catalysis. (2009) (0)
- A Physical Organic Chemistry Approach to Developing Cyclopropenium-Based Energy Storage Materials for Redox Flow Batteries. (2023) (0)
- Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques. (2023) (0)
- Combined Computational and Experimental Approach to Determine and Understand the Solubility of Phenothiazines as Redoxmers (2021) (0)
- Relationships Guides Asymmetric Propargylation Three-Dimensional Correlation of Steric and Electronic Free Energy (2014) (0)
- Pd-Catalyzed Anti-Markovnikov Hydroalkylation of AllylicAmines (2011) (0)
- Using machine learning techniques to simplify mobile interfaces (2012) (0)
- Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates". (2019) (0)
- Organometallic NLO Polymers. Accordian Main-Chain NLO Polymers of Ferrocene (1991) (0)
- Palladium‐Catalyzed Reductive Coupling of Styrenes and Organostannanes under Aerobic Conditions. (2008) (0)
- Palladium-Catalyzed Hydroarylation of Styrenes under Aerobic Conditions (2008) (0)
- Enantioselective Addition of Hydrogen Cyanide to Imines Catalyzed by a Chiral (Salen)Al(III) Complex. (1998) (0)
- Recent Advances in Homogeneous Transition Metal Catalyzed Aerobic Alcohol Oxidations. (2006) (0)
- Design of Hydrogen Bond Catalysts Based on a Modular Oxazoline Template: Application to an Enantioselective Hetero Diels—Alder Reaction. (2006) (0)
- Studies toward a combinatorial synthesis of agrobactin and analogs (2003) (0)
- Enantioselective Addition of Allyl Bromides to Ketones (2007) (0)
- A Palladium-Catalyzed Enantioselective Hydroamination Route to Pyrrolidines (2012) (0)
- Benzotriazoles as Low-Potential Anolytes for Non-aqueous Redox Flow Batteries (2022) (0)
- A Well‐Defined Complex for Palladium‐Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations. (2003) (0)
- against leukemia Zebrafish screen identifies novel compound with selective toxicity (2012) (0)
- Disparate Catalytic Sca ff olds for Atroposelective Cyclodehydration (2019) (0)
- Palladium-Catalyzed Oxidative Hydro-arylation of 1,3-Dieneswith Boronic Esters (2010) (0)
- Structural and Data Science-Driven Analysis to Assess Substrate Specificity of Diketopiperazine Reverse Prenyltransferase NotF: Cascade Biocatalytic Synthesis of (–)-Eurotiumin A (2021) (0)
- Title Enantiodivergent Fluorination of Allylic Alcohols : Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion Permalink (2016) (0)
- Design and Synthesis of Modular Oxazoline Ligands for the Enantioselective Chromium‐Catalyzed Addition of Allyl Bromide to Ketones. (2007) (0)
- Palladium Sparteine Dichloride (2012) (0)
- Palladium‐Catalyzed 1,4‐Difunctionalization of Butadiene to Form Skipped Polyenes. (2013) (0)
- Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. (2022) (0)
- SI - MATLAB Script for model development (2016) (0)
- Parameteriza ) on of Phosphine Ligands Reveals Mechanis ) c Pathways and Predicts Reac ) on Outcomes (0)
- Data Science-Driven Analysis of Substrate-Permissive Diketopiperazine Reverse Prenyltransferase NotF: Applications in Protein Engineering and Cascade Biocatalytic Synthesis of (-)-Eurotiumin A. (2022) (0)
- A Palladium-Catalyzed Three-Component-Coupling Strategy for the Differential Vicinal Diarylation of Terminal 1,3-Dienes. (2015) (0)
- Data-Driven Multi-Objective Optimization Tactics for Catalytic Asymmetric Reactions Using Bisphosphine Ligands. (2022) (0)
- Csp3-Csp3 BondFormation via Palladium-Catalyzed Hydroalkylation of Styrenes (2010) (0)
- Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives † (2019) (0)
- Development of a screen to identify selective small molecules active against patient-derived metastatic and chemoresistant breast cancer cells (2013) (0)
- A Selective and General Palladium Catalyst for the OxidativeHeck Reaction (2011) (0)
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