Matthias Driess
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German chemist
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Matthias Driesschemistry Degrees
Chemistry
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Inorganic Chemistry
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Chemistry
Matthias Driess's Degrees
- PhD Chemistry University of Münster
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(Suggest an Edit or Addition)Matthias Driess's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. (2011) (885)
- Unification of catalytic water oxidation and oxygen reduction reactions: amorphous beat crystalline cobalt iron oxides. (2014) (466)
- Zinc Oxide Nanoparticles with Defects (2005) (453)
- Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules (2011) (304)
- A new type of N-heterocyclic silylene with ambivalent reactivity. (2006) (267)
- Uncovering the Nature of Active Species of Nickel Phosphide Catalysts in High-Performance Electrochemical Overall Water Splitting (2017) (265)
- Boosting Visible-Light-Driven Photocatalytic Hydrogen Evolution with an Integrated Nickel Phosphide-Carbon Nitride System. (2017) (233)
- Active mixed-valent MnO(x) water oxidation catalysts through partial oxidation (corrosion) of nanostructured MnO particles. (2013) (233)
- High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity (2015) (225)
- New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules. (2013) (217)
- Cobalt-manganese-based spinels as multifunctional materials that unify catalytic water oxidation and oxygen reduction reactions. (2015) (207)
- On the role of oxygen defects in the catalytic performance of zinc oxide. (2006) (204)
- Main Group Element Analogues of Carbenes, Olefins, and Small Rings (1996) (200)
- An isolable NHC-supported silanone. (2009) (197)
- Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes (2014) (177)
- A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom. (2013) (176)
- From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. (2013) (175)
- A cyclic germadicarbene ("germylone") from germyliumylidene. (2013) (162)
- Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. (2012) (162)
- Electro- and Photochemical Water Oxidation on Ligand-free Co3O4 Nanoparticles with Tunable Sizes (2013) (154)
- Steering S-H and N-H bond activation by a stable n-heterocyclic silylene: different addition of H(2)S, NH(3), and organoamines on a silicon(II) ligand versus its Si(II)-->Ni(CO)(3) complex. (2010) (150)
- Heterogeneous water oxidation: surface activity versus amorphization activation in cobalt phosphate catalysts. (2015) (146)
- From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character. (2007) (141)
- A structurally versatile nickel phosphite acting as a robust bifunctional electrocatalyst for overall water splitting (2018) (137)
- From a Molecular 2Fe-2Se Precursor to a Highly Efficient Iron Diselenide Electrocatalyst for Overall Water Splitting. (2017) (136)
- Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes. (2012) (134)
- Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity (2014) (126)
- A Molecular Approach to Manganese Nitride Acting as a High Performance Electrocatalyst in the Oxygen Evolution Reaction. (2018) (122)
- The Pitfalls of Using Potentiodynamic Polarization Curves for Tafel Analysis in Electrocatalytic Water Splitting (2021) (120)
- Nickel as a co-catalyst for photocatalytic hydrogen evolution on graphitic-carbon nitride (sg-CN): what is the nature of the active species? (2016) (119)
- N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field (2014) (119)
- Helical cobalt borophosphates to master durable overall water-splitting (2019) (118)
- In Situ Formation of Nanostructured Core–Shell Cu3N–CuO to Promote Alkaline Water Electrolysis (2019) (118)
- Electron-rich N-heterocyclic silylene (NHSi)-iron complexes: synthesis, structures, and catalytic ability of an isolable hydridosilylene-iron complex. (2013) (117)
- Chemical vapor synthesis of size-selected zinc oxide nanoparticles. (2005) (117)
- Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds. (2007) (116)
- A heterofulvene-like germylene with a betain reactivity. (2006) (115)
- Strategies and Perspectives to Catch the Missing Pieces in Energy‐Efficient Hydrogen Evolution Reaction in Alkaline Media (2021) (115)
- An isolable silanoic ester by oxygenation of a stable silylene. (2007) (114)
- N-heterocyclic carbene (NHC)-stabilized silanechalcogenones: NHC-->Si(R2)=E (E=O, S, Se, Te). (2010) (113)
- From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature. (2010) (112)
- A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. (2008) (110)
- Uncovering the prominent role of metal ions in octahedral versus tetrahedral sites of cobalt–zinc oxide catalysts for efficient oxidation of water (2016) (109)
- Low-valent silicon cations with two-coordinate silicon and aromatic character. (2006) (107)
- Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks. (2013) (104)
- A Cobalt‐Based Amorphous Bifunctional Electrocatalysts for Water‐Splitting Evolved from a Single‐Source Lazulite Cobalt Phosphate (2019) (104)
- New Synthetic Routes to More Active Cu/ZnO Catalysts Used for Methanol Synthesis (2004) (103)
- Lessons from isolable nickel(I) precursor complexes for small molecule activation. (2012) (103)
- A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes. (2016) (102)
- Nanostructured manganese oxides as highly active water oxidation catalysts: a boost from manganese precursor chemistry. (2014) (97)
- Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. (2014) (96)
- Methanol synthesis over ZnO: A structure-sensitive reaction? (2003) (93)
- Structure–Property–Function Relationships in Nanoscale Oxide Sensors: A Case Study Based on Zinc Oxide (2007) (91)
- Hauptgruppenelementanaloga von Carbenen, Olefinen und kleinen Ringen (1996) (91)
- Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium. (2012) (89)
- N-heterocyclic silylenes as powerful steering ligands in catalysis (2017) (89)
- Uncovering structure-activity relationships in manganese-oxide-based heterogeneous catalysts for efficient water oxidation. (2015) (87)
- Activation of ammonia by a Si=O double bond and formation of a unique pair of sila-hemiaminal and silanoic amide tautomers. (2010) (86)
- Structurally Ordered Intermetallic Cobalt Stannide Nanocrystals for High-Performance Electrocatalytic Overall Water-Splitting. (2018) (84)
- Facile Access to an Active γ‐NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor (2020) (82)
- A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH). (2013) (82)
- Bis-N-heterocyclic carbene (NHC) stabilized η6-arene iron(0) complexes: synthesis, structure, reactivity, and catalytic activity. (2013) (81)
- Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. (2010) (81)
- Boosting Electrocatalytic Hydrogen Evolution Activity with a NiPt3@NiS Hetero-Nanostructure Evolved from a Molecular Nickel-Platinum Precursor. (2019) (80)
- An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene. (2011) (80)
- Boosting electrochemical water oxidation through replacement of Oh Co sites in cobalt oxide spinel with manganese. (2017) (80)
- First preparation of nanocrystalline zinc silicate by chemical vapor synthesis using an organometallic single-source precursor. (2004) (79)
- Self‐Supported Electrocatalysts for Practical Water Electrolysis (2021) (79)
- An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination. (2010) (79)
- Aromatic ylide-stabilized carbocyclic silylene. (2011) (78)
- A neutral, monomeric germanium(I) radical. (2011) (77)
- An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. (2010) (76)
- Ein cyclisches Silylon (“Siladicarben”) mit einem elektronenreichen Silicium(0)‐Atom (2013) (76)
- Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes (2014) (76)
- Diketiminate silicon(II) and related NHSi ligands generated in the coordination sphere of nickel(0). (2009) (75)
- Low-valent group 14 element hydride chemistry: towards catalysis. (2018) (75)
- Formamidines – Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions (2010) (73)
- Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene. (2008) (72)
- Lithium related deep and shallow acceptors in Li-doped ZnO nanocrystals (2010) (72)
- Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins. (2017) (72)
- The elusive silyliumylidene [ClSi:]+ and silathionium [ClSi=S]+ cations stabilized by bis(iminophosphorane) chelate ligand. (2012) (71)
- Using nickel manganese oxide catalysts for efficient water oxidation. (2015) (70)
- A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = beta-diketiminate). (2007) (69)
- β-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing for H2 and N2 Activation (2009) (68)
- Stereoselective Transfer Semi-Hydrogenation of Alkynes to E-Olefins with N-Heterocyclic Silylene-Manganese Catalysts. (2018) (68)
- From NHC-->germylenes to stable NHC-->germanone complexes. (2009) (68)
- Reactivity of N-Heterocyclic Germylene Toward Ammonia and Water (2011) (65)
- Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel. (2015) (65)
- A facile corrosion approach to the synthesis of highly active CoOx water oxidation catalysts (2017) (64)
- Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit. (2010) (63)
- Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene. (2011) (63)
- Amorphous outperforms crystalline nanomaterials: surface modifications of molecularly derived CoP electro(pre)catalysts for efficient water-splitting (2019) (62)
- From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene. (2016) (61)
- Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide. (2018) (61)
- Hydrosilylation of alkynes by Ni(CO)3-stabilized silicon(II) hydride. (2012) (61)
- Molecular clusters of the main group elements (2004) (60)
- Diphosphanyl‐ and Diarsanyl‐Substituted Carbene Homologues: Germanediyls, Stannanediyls, and Plumbanediyls with Remarkable Electronic Structures (1995) (58)
- Cobalt-Catalyzed Regioselective Borylation of Arenes: N-Heterocyclic Silylene as an Electron Donor in the Metal-Mediated Activation of C-H Bonds. (2017) (58)
- From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting (2018) (57)
- Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. (2014) (56)
- Li-doped MgO From Different Preparative Routes for the Oxidative Coupling of Methane (2011) (56)
- A New Area in Main-Group Chemistry: Zerovalent Monoatomic Silicon Compounds and Their Analogues. (2017) (56)
- The striking stabilization of Ni0(eta6-arene) complexes by an ylide-like silylene ligand. (2009) (56)
- Hydride binding to the active site of [FeFe]-hydrogenase. (2014) (56)
- A Systematic Study on Zinc Oxide Materials Containing Group I Metals (Li, Na, K)-Synthesis from Organometallic Precursors, Characterization, and Properties (2009) (54)
- Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex (2015) (54)
- Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols. (2016) (53)
- Versatile reactivity of a zwitterionic isolable silylene toward ketones: silicon-mediated, regio- and stereoselective C-H activation. (2009) (53)
- Silicon analogues of carboxylic acids: synthesis of isolable silanoic acids by donor-acceptor stabilization. (2010) (53)
- A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules. (2014) (53)
- Crystalline Copper Selenide as a Reliable Non‐Noble Electro(pre)catalyst for Overall Water Splitting (2020) (53)
- Synthesis of a "half"-parent phosphasilene R2Si=PH and its metalation to the corresponding P-zinciophosphasilene [R2Si=PM]. (2006) (53)
- Reaktive π-Komplexe der elektronenreichen Übergangsmetalle, IV. Cyclisierungsreaktionen von t-Butylphosphaacetylen an π-Areneisen-Komplexen (1987) (52)
- High Efficiency in Catalytic Hydrosilylation of Ketones with Zinc‐Based Precatalysts Featuring Hard and Soft Tridentate O,S,O‐Ligands (2010) (52)
- Enabling Iron‐Based Highly Effective Electrochemical Water‐Splitting and Selective Oxygenation of Organic Substrates through In Situ Surface Modification of Intermetallic Iron Stannide Precatalyst (2020) (52)
- Isolable Silylene‐based Catalysts Boost the Catalytic Efficiencies and Selectivity (2018) (51)
- 1,2,3‐Triphospha‐4‐silabicyclo[l.1.0]butanes from Activated, Stable Phosphasilenes and White Phosphorus (1991) (51)
- Synthesis, Characterization, and Complexation of an Unusual P2Si2 Bicyclobutane with Butterfly‐Structure: 2,2,4,4‐Tetramesityl‐1,3‐diphospha‐2,4‐disilabicyclo[1.1.0]butane (1989) (51)
- Molecular, Shell‐Like Dilithium (Silyl)phosphanediide and Dilithium (Silyl)arsanediide Aggregates with an [Li6O]4+ Core (1996) (51)
- Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex. (2017) (51)
- Chemische Tricks zur Zähmung von Silanonen und ihren schweren Homologen mit EO‐Bindungen (E=Si–Pb): von schwer fassbaren Spezies zu isolierbaren Bausteinen (2013) (51)
- An elusive hydridoaluminum(I) complex for facile C-H and C-O bond activation of ethers and access to its isolable hydridogallium(I) analogue: syntheses, structures, and theoretical studies. (2014) (51)
- O-O bond activation in heterobimetallic peroxides: synthesis of the peroxide [LNi(mu,eta2:eta2-O2)K] and its conversion into a bis(mu-hydroxo) nickel zinc complex. (2009) (50)
- A low-temperature molecular approach to highly conductive tin-rich indium tin oxide thin films with durable electro-optical performance. (2009) (50)
- Low-temperature approach to high surface ZnO nanopowders and a non-aqueous synthesis of ZnO colloids using the single-source precursor [MeZnOSiMe3]4 and related zinc siloxides (2003) (50)
- Synthesis and Unusual Reactivity of Compounds Containing Silicon−Phosphorus and Silicon−Arsenic Double Bonds: New Silylidenephosphanes and -arsanes of the Type R2SiE(SiR3) (E = P, As) (1996) (49)
- Silicon–Phosphorus and Silicon–Arsenic Multiple Bonds (1996) (49)
- A Molecular Precursor Approach to Tunable Porous Tin-Rich Indium Tin Oxide with Durable High Electrical Conductivity for Bioelectronic Devices (2011) (49)
- Some aspects of the chemistry of silylidene-phosphanes and -arsanes (1995) (47)
- Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes (2009) (47)
- Facile and efficient reduction of ketones in the presence of zinc catalysts modified by phenol ligands. (2010) (47)
- An unsymmetric substituted digermylene with a Ge(I)-Ge(I) bond and synthesis of a germylene-stannylene with a Ge(I)-Sn(I) bond. (2009) (47)
- Synthesis and unexpected reactivity of germyliumylidene hydride [:GeH]+ stabilized by a bis(N-heterocyclic carbene)borate ligand. (2014) (47)
- A series of isolable silanoic thio-, seleno-, and telluroesters (LSi(=X)OR) with donor-supported Si=X double bonds (L = beta-diketiminate; X = S, Se, Te). (2008) (46)
- Dioxygenase-like reactivity of an isolable superoxo-nickel(II) complex. (2010) (46)
- Unusual [3+1] Cycloaddition of a Stable Silylene with a 2,3-Diazabuta-1,3-diene versus [4+1] Cycloaddition toward a Buta-1,3-diene (2010) (45)
- N-Heterocyclic Germylidenide and Stannylidenide Anions: Group 14 Metal(II) Cyclopentadienide Analogues (2010) (45)
- Nano-Sized Inorganic Energy-Materials by the Low-Temperature Molecular Precursor Approach. (2018) (45)
- A neutral tetraphosphacyclobutadiene ligand in cobalt(I) complexes. (2015) (44)
- Low‐Valent Molybdenum‐Based Dual Pre‐Catalysts for Highly Efficient Catalytic Epoxidation of Alkenes and Deoxygenation of Sulfoxides (2011) (44)
- Synthesis and Solid State Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium Bis(trimethylsilyl)amide (1997) (44)
- Molecular encoding at the nanoscale: from complex cubes to bimetallic oxides. (2005) (44)
- First structural characterization of silicon–arsenic and silicon–phosphorus multiple bonds in silylated silylidene-arsanes and -phosphanes; X-ray structure of a tellura-arsasilirane derivative (1995) (44)
- An Arsanylidensilane (“Arsasilene”) and its Derivatization with Tellurium and Benzophenone† (1992) (42)
- A molecular approach to self-supported cobalt-substituted ZnO materials as remarkably stable electrocatalysts for water oxidation. (2014) (42)
- Main group chemistry: Breaking the limits with silylenes. (2012) (42)
- Alkaline electrochemical water oxidation with multi-shelled cobalt manganese oxide hollow spheres. (2017) (42)
- Facile access to silicon-functionalized bis-silylene titanium(II) complexes. (2012) (42)
- Striking reactivity of ylide-like germylene toward terminal alkynes: [4+2] cycloaddition versus C-H bond activation. (2008) (42)
- Isolable Metallo-Germylene and Metallo-Stannylene σ-Complexes with Iron (2009) (42)
- Dichotome Reaktivität eines stabilen Silylens gegenüber terminalen Alkinen: C‐H‐Insertion oder autokatalytische Bildung von Silacycloprop‐3‐en (2008) (42)
- Coordination of a SiO subunit to metals: complexes of donor-stabilized silanone featuring a terminal SiO→M coordination (M = Zn, Al) (2010) (41)
- Aktive gemischtvalente MnOx‐Katalysatoren für die Wasseroxidation durch partielle Oxidation (“Korrosion”) nanostrukturierter MnO‐Partikel (2013) (41)
- Synthesis and Structure of Siloxy‐Substituted ZnO Aggregates Having (ZnO)n (n = 2, 4) and Zn3O4 Cores (2000) (41)
- Isolable Silylene Ligands Can Boost Efficiencies and Selectivities in Metal-Mediated Catalysis. (2019) (40)
- Darstellung, Struktur und Komplexierung von 2,2′,5,5′‐Tetrahydro‐1,1′‐bi(1H‐1,2,5‐phosphadiborol)‐Derivaten (1991) (40)
- Recent Advances in Silylene Chemistry: Small Molecule Activation En-Route Towards Metal-Free Catalysis (2013) (40)
- Facile Access to Mono- and Dinuclear Heteroleptic N-Heterocyclic Silylene Copper Complexes (2014) (40)
- Is direct seawater splitting economically meaningful? (2021) (40)
- Significant role of Mn(III) sites in e(g)(1) configuration in manganese oxide catalysts for efficient artificial water oxidation. (2015) (39)
- Visible light driven non-sacrificial water oxidation and dye degradation with silver phosphates: multi-faceted morphology matters (2014) (39)
- N-Heterocyclic Silylene (NHSi) Rhodium and Iridium Complexes: Synthesis, Structure, Reactivity, and Catalytic Ability (2013) (39)
- High Electromagnetic Field Enhancement of TiO2 Nanotube Electrodes. (2018) (38)
- Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers. (2010) (38)
- Synthesis of Stannyl-Substituted Zn4O4 Cubanes as Single-Source Precursors for Amorphous Tin-Doped ZnO and Zn2SnO4 Nanocrystals and Their Potential for Thin Film Field Effect Transistor Applications (2011) (38)
- From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond. (2008) (38)
- Ein Side-on-Superoxonickel-Komplex [LNi(O2)] mit quadratisch- planarem, vierfach koordinierten Nickel(II)-Zentrum und seine Umwandlung in [LNi(μ-OH)2NiL]† (2008) (38)
- 1,2,3-Triphospha-4-silabicyclo[1.1.0]butane aus aktivierten, stabilen Phosphasilenen und weißem Phosphor† (1991) (38)
- Forcieren der σ-Donorstärke in Iridium-Pinzettenkomplexen: Bis(silylen)- und Bis(germylen)-Liganden sind stärkere Donoren als Bis[phosphor(III)]-Liganden† (2012) (38)
- Ein Heterofulven‐analoges Germylen mit Betain‐Reaktivität (2006) (38)
- Taming the germyliumylidene [CIGe:]+ and germathionium [CIGe=S]+ ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene. (2012) (37)
- Synthesis and Striking Reactivity of an Isolable Tetrasilyl-Substituted Trisilaallene (2011) (37)
- Synthesis, structure, and reactivity of a pyridine-stabilized germanone. (2011) (37)
- Evolving Highly Active Oxidic Iron(III) Phase from Corrosion of Intermetallic Iron Silicide to Master Efficient Electrocatalytic Water Oxidation and Selective Oxygenation of 5‐Hydroxymethylfurfural (2021) (36)
- Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX- (E = As, P, and N; X = S and O) Anions. (2017) (36)
- Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride. (2014) (36)
- Hydrophobic Nanoreactor Soft‐Templating: A Supramolecular Approach to Yolk@Shell Materials (2015) (35)
- A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity. (2016) (35)
- Über den Einfluss von Sauerstoffdefektstellen auf die katalytische Aktivität von Zinkoxid (2006) (35)
- An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water. (2017) (35)
- Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs. (2018) (34)
- Striking reactivity of a stable, zwitterionic silylene towards substituted diazomethanes, azides, and isocyanides. (2009) (34)
- Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn). (2011) (34)
- Molecular Clusters of the Main Group Elements: Driess: Molecular Clusters O-BK (2005) (34)
- R2SiPSiR2F: 1,3‐Sigmatropic Migration of Fluorine in a 2‐Phospha‐1,3‐disilaallyl Derivative Capable of Conjugation and Its Conversion to Phosphadisilacyclopropanes (1997) (34)
- From a stable silanone complex to isolable, donor-supported silicoxonium halides [LSi(dmap)=O-SiMe3](+)X-. (2011) (34)
- From Silylone to an Isolable Monomeric Silicon Disulfide Complex. (2015) (33)
- Consecutive fragmentations of the cubane-like zinc cluster [CH3Zn(O-i-C3H7)]4 upon electron ionization. (2005) (33)
- Sn6(PR)6], [Sn3(Pr)2, and [Cu24(PR)12] (R = Triorganoisilyl): New Tin and Copper Phosphanediyl Clusters†‡ (1997) (33)
- Boosting Water Oxidation through In Situ Electroconversion of Manganese Gallide: An Intermetallic Precursor Approach (2019) (33)
- Novel Alkali Metal Phosphanide Aggregates (1995) (32)
- Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands. (2015) (32)
- Facile Access to NaOC≡As and Its Use as an Arsenic Source To Form Germylidenylarsinidene Complexes. (2017) (32)
- Detecting structural transformation of cobalt phosphonate to active bifunctional catalysts for electrochemical water-splitting (2020) (32)
- Organometallics meet colloid chemistry: a case study in three phases based on molecular carbonyl precursors containing zinc and manganese. (2007) (32)
- A cyclopentadienide analogue containing divalent germanium and a heavy cyclobutadiene-like dianion with an unusual Ge4 core. (2008) (32)
- An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity. (2018) (31)
- From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes (2014) (31)
- Bridging the materials gap in catalysis: entrapment of molecular catalysts in functional supports and beyond. (2009) (31)
- Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium (2012) (31)
- Synthese eines “halben” Phosphasilen‐Stammsystems R2SiPH und seine Metallierung zum P‐Zinkio‐phosphasilen [R2SiPM] (2006) (30)
- As[P(NMe(2))(3)](2)(+) as simultaneous As(I) and P(I) source: synthesis and density function calculations of planar tetracoordinate arsonium and phosphonium ions. (2002) (30)
- Formation of N-heterocyclic, donor-stabilized borenium ions. (2011) (30)
- Addition of [(eta(5)-C(5)Me(5))IrH(4)] to a zwitterionic silylene: stepwise formation of iridium(V)-silyl and iridium(III)-silylene complexes. (2010) (30)
- Combination of Highly Efficient Electrocatalytic Water Oxidation with Selective Oxygenation of Organic Substrates using Manganese Borophosphates (2021) (29)
- An Isolable Silicon Dicarbonate Complex from Carbon Dioxide Activation with a Silylone. (2017) (29)
- Metallfreie Aktivierung von EH3 (E=P, As) durch ein Ylid-artiges Silylen und Bildung eines donorstabilisierten Arsasilens mit einer HSiAsH-Untereinheit† (2010) (29)
- Ein Arsanylidensilan („Arsasilen”︁) und seine Derivatisierung mit Tellur und Benzophenon (1992) (29)
- Where silylene-silicon centres matter in the activation of small molecules. (2020) (29)
- A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. (2013) (28)
- Biomimetic [2Fe-2S] clusters with extensively delocalized mixed-valence iron centers. (2015) (28)
- E(SiMe3 )4+ Ions (E=P, As): Persilylated Phosphonium and Arsonium Ions. (2001) (27)
- Facile synthesis and structural variation of novel heterobimetallic alkali metal?zinc-alkoxide and -siloxide clustersElectronic supplementary information (ESI) available: the ESI spectra of the reaction mixtures tBuOLi + ZnMe2, Me3SiOK + ZnMe2 and tBuOK + ZnMe2. See http://www.rsc.org/suppdata/dt/b3 (2003) (27)
- From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se). (2015) (27)
- Lithium Arsanylalanates as Arsenide Sources: A Simple Route to the Zintl Anion As and the Synthesis of a Tetraarsatetrasilacubane (1996) (27)
- Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2 Group and Related PR2 Derivatives (2008) (27)
- Synthesis of (fluorosilyl) phosphido iron and nickel complexes and ferriosilyl-substituted (fluorosilyl) phosphanes and evidence for the formation of a metallo phosphasilene of the type [M]PSiR2 (1997) (27)
- Cover Picture: New Vistas in N‐Heterocyclic Silylene (NHSi) Transition‐Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules (Chem. Eur. J. 1/2013) (2013) (26)
- Understanding the formation of bulk- and surface-active layered (oxy)hydroxides for water oxidation starting from a cobalt selenite precursor (2020) (26)
- Novel Molecular Clusters Having Aluminum–Phosphorus, Aluminum–Arsenic, and Gallium–Arsenic Skeletons, and Synthesis of an Al4As6Li4 Rhombododecahedron (1998) (26)
- Diphosphanyl‐ und Diarsanyl‐substituierte Carben‐Homologe: German‐, Stannan‐, und Plumbandiyle mit bemerkenswerten elektronischen Strukturen (1995) (26)
- One-pot synthesis of lithium alkylzinc alkoxo heterocubanes with a LiZn3O4 core as suitable organometallic precursors for Li-containing ZnO nanocrystals. (2009) (26)
- Modular chemistry with aluminum phosphanides: cluster formation of (AlP)n (n=3,6,7), Al4P3, and Al4Li4P6 frameworks. (2000) (26)
- Synthesis and rearrangement of stable NHC-->silylene adducts and their unique reactivity towards cyclohexylisocyanide. (2010) (26)
- Multidentate, Cyclic Phosphorus Ligands with a SiliconPhosphorus Backbone: Template Synthesis of a 1,4,7‐Triphospha‐2,3,5,6,8,9‐hexasilacyclononane and a 1,3,5,7,9,11‐Hexaphospha‐2,4,6,8,10,12‐hexasilacyclododecane (1997) (26)
- Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds. (2012) (25)
- P(SiiPr3)3: the First Trisilylphosphane Derivative with an almost Planar Three‐Coordinated Phosphorus Atom (2000) (25)
- Convenient access to homo- and heterobimetallic alkoxo hydridozinc clusters of formula [(HZnOtBu)4-n(LiOtBu)n] (n = 0, 1, 2, 3) (2006) (25)
- Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4 Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane (2015) (25)
- A comparison of silylidene-amines, -phosphanes and -arsanes: syntheses and quantum chemical calculations (1994) (24)
- The pH of Aqueous NaOH/KOH Solutions: A Critical and Non-trivial Parameter for Electrocatalysis (2021) (24)
- Syntheses and Molecular Structures of Metallasiloxanes Containing Zn3O4 and Zn6Si6O10 Cores (2003) (23)
- Molekulare, schalenartig aufgebaute Dilithium(silyl)phosphandiid‐ und Dilithium(silyl)arsandiid‐Aggregate mit einem [Li6O]4+‐Kern (1996) (23)
- (H2Si)2E2 and (Mes(tBu)Si)2E2 (E = As, P): Incommensurable Systems of Different Stability with Unusually Long EE Bonds†‡ (1992) (23)
- Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules. (2019) (23)
- The Pivotal Role of s‐, p‐, and f‐Block Metals in Water Electrolysis: Status Quo and Perspectives (2022) (23)
- Redox Non-Innocent Monoatomic Silicon(0) Complex ('Silylone'): Its One-Electron-Reduction Induces an Intramolecular One-Electron-Oxidation of Silicon(0) to Silicon(I). (2020) (23)
- Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution. (2009) (23)
- Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters. (2008) (22)
- A Low‐Temperature Molecular Precursor Approach to Copper‐Based Nano‐Sized Digenite Mineral for Efficient Electrocatalytic Oxygen Evolution Reaction (2020) (22)
- Reply to Comment on “Methylmagnesium Alkoxide Clusters with Mg4O4 Cubane- and Mg7O8 Biscubane-Like Cores: Organometallic Precursors for Low-Temperature Formation of MgO Nanoparticles with Variable Surface Defects” (2010) (22)
- Side-on coordination of a P-P bond in heterobinuclear tetraphosphorus complexes with a [Si(mu,eta(2:2)-P(4))Ni] core and nickel(I) centers. (2009) (22)
- The reaction of disilenes with P4 and As4 (1992) (22)
- Morphology-Dependent Activities of Silver Phosphates: Visible-Light Water Oxidation and Dye Degradation. (2016) (21)
- Molecular clusters of dimetalated primary phosphanes and arsanes (2000) (21)
- Novel Arsaalkenes from an Arsasilene Derivative and Isocyanides (1993) (21)
- A Persistent 1,2-Dihydrophosphasilene Adduct. (2015) (21)
- Formation of a bowl-shaped, pentacyclic phosphonium cage by methylation of a nucleophilic phosphinidene. (2005) (21)
- Molecular Heterobimetallic Approach to Li-Containing MgO Nanoparticles with Variable Li-Concentrations Using Lithium-Methylmagnesium Alkoxide Clusters (2010) (21)
- Bemerkenswerte Stabilisierung von Ni0(η6‐Aren)‐Komplexen durch einen Ylid‐artigen Silylenliganden (2009) (21)
- Monooxygenase-like reactivity of an unprecedented heterobimetallic {FeO2Ni} moiety. (2010) (21)
- The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition-Metal Complexes. (2017) (20)
- Heavier congeners of CO and CO2 as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te) (2016) (20)
- Neuartige Alkalimetallphosphanid‐Aggregate (1995) (20)
- Homocoupling of CO and isocyanide mediated by a C,C'-bis(silylenyl)-substituted ortho-carborane. (2019) (20)
- Raman and photoluminescence spectroscopic detection of surface-bound Li(+)O2(-) defect sites in Li-doped ZnO nanocrystals derived from molecular precursors. (2011) (20)
- Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application. (2017) (19)
- The dimeric tris(lithioarsino)germane tBuGe[As(SiiPr3)Li]3 : a self-assembled, solvent-free lithium-main group element aggregate with a Ge2As6Li6 rhombododecahedral frame-work (1993) (19)
- A One-Pot Approach to Mesoporous Metal Oxide Ultrathin Film Electrodes Bearing One Metal Nanoparticle per Pore with Enhanced Electrocatalytic Properties (2013) (19)
- Selective Oxidation of n-Butane over Vanadium Phosphate Based Catalysts: Reaction Network and Kinetic Analysis (2018) (19)
- Improving the Catalytic Activity in the Rhodium‐Mediated Hydroformylation of Styrene by a Bis(N‐heterocyclic silylene) Ligand (2017) (19)
- From an N-Heterocyclic Silacyclopropene to Donor-Supported Silacyclopropenylium Cations (2009) (18)
- Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand. (2017) (18)
- Geometrically Compelled Disilene with λ4-Coordinate SiII Atoms. (2018) (18)
- An S-Oxygenated [NiFe] Complex Modelling Sulfenate Intermediates of an O2 -Tolerant Hydrogenase. (2017) (18)
- Activation of C-H bonds mediated by Mo[triple bond]Mo moieties in heterobimetallic Zn/O/Mo clusters. (2010) (18)
- From Molecular Gallium and Indium Siloxide Precursors to Amorphous Semiconducting Transparent Oxide Layers for Applications in Thin-Film Field-Effect Transistors (2012) (18)
- Alkaline-Earth-Metal-Induced Liberation of Rare Allotropes of Elemental Silicon and Germanium from N-Heterocyclic Metallylenes. (2015) (18)
- A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2 M'] Complexes in Oxidation Reactions. (2017) (18)
- A novel type of oligofunctional macroheterocycle by reaction of silylidene-phosphanes and -arsanes with 1,6-diisocyanohexane (1993) (18)
- Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor. (2012) (17)
- (H2Si)2E2 und (Mes(tBu)Si)2E2 (E = As, P): inkommensurable Systeme unterschiedlicher Stabilität mit ungewöhnlich langen E-E-Bindungen†‡ (1992) (17)
- Elucidating the effect of the nucleophilicity of the silyl group in the reduction of CO2 to CO mediated by silyl-copper(I) complexes. (2014) (17)
- Structurally Ordered Intermetallic Cobalt Stannide Nanocrystals for High‐Performance Electrocatalytic Overall Water‐Splitting (2018) (17)
- Unifying Concepts in Catalysis (2010) (17)
- A Facile Synthesis of Diphosphasilacyclopropanes and 1,3-Diphospha-2,4-disilabicyclo[1.1.0]butanes and an ab Initio Study of Diphosphadisilabicyclo[1.1.0]butanes and Their Respective 1,3-Diene Isomers (1997) (17)
- Hydrosilylierung von Alkinen mit einem Ni(CO)3‐stabilisierten Silicium(II)‐Hydrid (2012) (17)
- A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent (2020) (17)
- Synthesis of the first fluoro(phosphanyl)- and diphosphanyl-stannanes and surprising formation of [P(SnMe3)4]+ SiF5-. (2003) (17)
- Coordination of N-Heterocyclic Carbene to H2SiX2 (X = Cl, OTf) and H3SiOTf (OTf = OSO2CF3): Synthesis of Donor-stabilized Parent Silylium Salts with Four- and Five-coordinate Silicon Atoms (2013) (17)
- Intermolecular Hydrogen–Fluorine Interaction in Dimolybdenum Triply Bonded Complexes Modified by Fluorinated Formamidine Ligands for the Construction of 2D‐ and 3D‐Networks (2011) (17)
- Unprecedented alkylzinc-magnesium alkoxide clusters as suitable organometallic precursors for magnesium-containing ZnO nanoparticles. (2011) (17)
- NEUARTIGE ARSAALKENE AUS EINEM ARSASILENDERIVAT UND ISOCYANIDEN (1993) (16)
- Facile Molecular Approach to Transparent Thin-Film Field-Effect Transistors with High-Performance Using New Homo- and Heteroleptic Indium(III)–Tin(II) Single-Source Precursors (2012) (16)
- Synthese, Charakterisierung und Komplexierung eines ungewöhnliche P2Si2‐Bicyclobutans mit Schmetterlingsstruktur: 2,2,4,4‐Tetramesityl‐1,3‐diphospha‐2,4‐disilabicyclo[1.1.0]butan (2006) (16)
- Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex. (2017) (16)
- From molecules to metastable solids: solid-state and chemical vapour syntheses (CVS) of nanocrystalline ZnO and Zn (2003) (16)
- Isomerization of an N-Heterocyclic Germylene to an Azagermabenzen-1-ylidene and Its Coupling to a Unique Bis(germylene)§ (2010) (16)
- Active Mixed‐Valent MnOx Water Oxidation Catalysts Through Partial Oxidation (Corrosion) of Nanostructured MnO Particles. (2014) (16)
- Facile Formation of Nanostructured Manganese Oxide Films as High-Performance Catalysts for the Oxygen Evolution Reaction. (2018) (16)
- Brückenschlag in der Katalyse: Immobilisierung von molekularen Katalysatoren in funktionellen Materialien† (2009) (16)
- Nucleophilic versus Electrophilic Reactivity of Bioinspired Superoxido Nickel(II) Complexes. (2018) (16)
- The Catalytic Activity of Zinc Oxides from Single Source Precursors with Additives for the C–H Acitivation of Lower Alkanes (2009) (16)
- van't‐Hoff‐Le‐Bel‐Fremdling: Bildung eines Phosphoniumkations mit einem planar‐tetrakoordinierten Phosphoratom (1999) (16)
- Taming Silicon Congeners of CO and CO2 : Synthesis of Monomeric SiII and SiIV Chalcogenide Complexes. (2017) (16)
- In Situ Formed “Sn 1– X In X @In 1– Y Sn Y O (2021) (15)
- Synthesis and tunable reactivity of N-heterocyclic germylene. (2012) (15)
- R2SiP‐SiR2F: 1,3‐sigmatrope Fluorwanderung in einem konjugationsfähigen 2‐Phospha‐1,3‐disilaallyl‐Derivat und seine Umwandlung in Phosphadisilacyclopropane (1997) (15)
- Unprecedented silicon(II)→calcium complexes with N-heterocyclic silylenes. (2015) (15)
- Synthese und Struktur von 2,5‐Dihydro‐1H‐1,2,5‐phosphadiborol‐Derivaten (1987) (15)
- Synthese und Struktur von neuen Germanium-Phosphor-Heterocyclen mit einem Ge2P2-Ringgerüst (1992) (15)
- Stammverbindungen der schweren Methylene: chemische Tricks zur Erzeugung isolierbarer Komplexe von nicht fassbaren Spezies H2E: (E=Ge und Sn) (2011) (15)
- Atomic layer deposition on porous powders with in situ gravimetric monitoring in a modular fixed bed reactor setup. (2017) (15)
- Entrapment of Heteropolyacids in Metallic Silver Matrices: Unique Heterogenized Acid Catalysts (2011) (15)
- [Sn6(PR)6], [Sn3(PR)2Cl2] und [Cu24(PR)12] R = Triorganosilyl): neue Zinn- und Kupfer-Phosphandiyl-Cluster†‡ (1997) (15)
- Active and Stable Nickel‐Based Electrocatalysts Based on the ZnO:Ni System for Water Oxidation in Alkaline Media (2017) (15)
- Improved chemical water oxidation with Zn in the tetrahedral site of spinel-type ZnCo2O4 nanostructure (2020) (15)
- Free Radicals of N‑Donor-Stabilized Silicon(II) Compounds Probed by Muon Spin Spectroscopy (2015) (14)
- Orthotelluric Acid as Substitute for Crystal‐Water: Syntheses and Crystal Structure of the Co‐crystallate [Te(OH)6 · 2 Adenine · 4 H2O] and the Disodium Ditellurate(VI) Aggregate {[Te2O2(OH)6(ONa)2]2[NaOH · 12.5 H2O]} (2001) (14)
- Lithiierte Cluster von primären Silylphosphanen und Silylarsanen: sphärische Körper mit und ohne Li2O‐Füllung (1999) (14)
- Multiple-Shell Clusters of Alkali Metal-Rich Phosphanides and Arsanides (1999) (14)
- Perspective on intermetallics towards efficient electrocatalytic water-splitting (2021) (14)
- Evidenz für eine Struktur‐Reaktivität‐Beziehung bei sperrig substituierten Lithium(fluorsilyl)phosphaniden (1994) (14)
- Triphosphatrisilacyclohexanes as Tridentate Coronands in Cr and Mo Complexes: Activation of SiH in an Early Stage versus Phosphane Coordination† (1992) (14)
- Synthesis, Structure, and Thermolysis of an Unusual Azaphosphasiliridine (1992) (14)
- Das dimere Tris(lithioarsino)german tBuGe[As(SiIPr3)Li]3: ein selbstorganisiertes, solvensfreies Lithium‐Hauptgruppenelement‐Aggregat mit einem Ge2As6Li6‐Rhomben‐dodekaeder‐Gerüst (1993) (14)
- Investigating the Trimethylaluminium/Water ALD Process on Mesoporous Silica by In Situ Gravimetric Monitoring (2018) (14)
- From elusive thio- and selenosilanoic acids to copper(I) complexes with intermolecular Si=E → Cu-O-Si coordination modes (E = S, Se). (2013) (14)
- Novel hypervalent complexes of main-group metals by intramolecular ligand-->metal electron transfer. (2004) (14)
- Facile Rearrangement of a Bis(N-heterocyclic carbene)borate Chelate Ligand and Access to [:GeX]+Complexes (X = H, Cl): Rearrangement of a Bis(NHC)borate Chelate Ligand (2015) (14)
- A novel type of pentacoordinate silicon complexes and unusual ligand coupling by intramolecular electron transfer. (2005) (14)
- Enhancing of catalytic properties of vanadia via surface doping with phosphorus using atomic layer deposition (2016) (13)
- A Single-Source Precursor Approach to Self-Supported Nickel-Manganese-Based Catalysts with Improved Stability for Effective Low-Temperature Dry Reforming of Methane. (2016) (13)
- Asterance-like compounds from 2,2,4,4-tetramesityl-1,3-diphospha-2,4-disilabicyclo-[1.1.0]butane (1991) (13)
- Bis(silylene)‐Stabilized Monovalent Nitrogen Complexes (2020) (13)
- Molekulare Codierung auf der Nanoskala: von komplexen Cubanen zu Bimetalloxiden (2005) (13)
- E(SiMe3)4+ (E=P, As): persilylierte Phosphonium‐ und Arsoniumionen (2001) (13)
- Through‐Bond Interactions in Silicon–Phosphorus and Silicon–Arsenic Compounds: A Facile Synthesis of Dodecamethyl‐2,3,5,6,7,8‐hexasila‐1λ3,4λ3‐diphosphabicyclo[2.2.2]octane, Its Arsenic Analogue, and Related Compounds (1997) (13)
- Lithiumarsanylalanate als Arsenidquellen: ein einfacher Zugang zum Zintl‐Anion As73− und Synthese eines Tetraarsatetrasilacubans (1996) (12)
- Synthesen, Strukturen und Eigenschaften von 2,5‐Dihydro‐1H‐1,2,5‐phosphadiborolen (1992) (12)
- Facile Low-Temperature Approach to Tin-Containing ZnO Nanocrystals with Tunable Tin Concentrations Using Heterobimetallic Sn/Zn Single-Source Precursors (2013) (12)
- Dual Catalytic Activity of Palladium Doped with a Rhodium Complex in a One‐pot, Four Step Process (2015) (12)
- Synthesis and Structure of a 2,5-Dihydro-1H-1,2,5-phosphadiborole Derivative† (1987) (12)
- Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand (2021) (12)
- A zwitterionic silylene as reactive intermediate and its unusual dimerization to an N-heterobicyclic disilane. (2009) (12)
- Promoting Photocatalytic Hydrogen Evolution Activity of Graphitic Carbon Nitride with Hole‐Transfer Agents (2020) (12)
- Synthese, Struktur und Thermolyse eines ungewöhnlichen Azaphosphasiliridins (1992) (12)
- Tuning the Rh–FeOx Interface in Ethanol Synthesis through Formation Phase Studies at High Pressures of Synthesis Gas (2021) (12)
- MOLEKULARE AGGREGATE VON DONORSOLVENSFREIEN LITHIUMSILYLPHOSPHANIDEN MIT DEM TRIPHENYLSILYL- UND TRIISOPROPYLSILYL-SUBSTITUENTEN AM PHOSPHOR (1996) (12)
- (2,4,6‐iPr3C6H2)(tBu)Si(AsH2)2: Das erste Diarsanylsilan und seine Umwandlung in ein 1,3‐Diarsa‐2‐sila‐4‐germacyclobutan und ein 1,3‐Diarsa‐2‐sila‐4‐germabicyclo[1.1.O]butan‐Derivat (1994) (11)
- Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes. (2009) (11)
- Stannites – A New Promising Class of Durable Electrocatalysts for Efficient Water Oxidation (2020) (11)
- P−H Activation By Zirconium Amido Complexes: From New Phosphanidozirconium Complexes to the First Zr2P6 Cluster with the [RP−P−PR]3− Ligand [R = Me2(iPrMe2C)Si] (2002) (11)
- Yolk@Shell Nanoarchitectures with Bimetallic Nanocores-Synthesis and Electrocatalytic Applications. (2016) (11)
- Nanoskalige anorganische Energiematerialien aus molekularen Vorstufen bei tiefer Temperatur (2018) (11)
- Beyond CO2 Reduction: Vistas on Electrochemical Reduction of Heavy Nonmetal Oxides with Very Strong E-O Bonds (E = Si, P, S). (2020) (11)
- Cyaarside (CAs- ) and 1,3-Diarsaallendiide (AsCAs2- ) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs- ). (2019) (11)
- Cyclohexylbis(hydroxymethyl)phosphane : A hydrophilic phosphane capable of forming novel hydrogen-bonding networks (2006) (11)
- Heterotermetallic indium lithium halostannates: low-temperature single-source precursors for tin-rich indium tin oxides and their application for thin-film transistors. (2012) (11)
- Chelate Silylene-Silyl Ligand Can Boost Rhodium-Catalyzed C-H Bond Functionalization Reactions. (2018) (11)
- Transition Metal Complexes of a “Half-Parent” Phosphasilene Adduct Representing Silylene→Phosphinidene→Metal Complexes (2015) (10)
- Versatile Tautomerization of EH2-Substituted Silylenes (E = N, P, As) in the Coordination Sphere of Nickel. (2019) (10)
- Ungewöhnliche Reaktivität der Silicium‐Phosphor‐Doppelbindung in einem Silyliden(fluorsilyl)phosphan: intramolekulare C,H‐Inserierung und seine Umwandlung in ein neues Silyliden(silyl)phosphan (1999) (10)
- As[P(NMe2)3]2+ als simultane AsI‐ und PI‐Quelle: Synthese und Dichtefunktionalrechnungen planar‐tetrakoordinierter Arsonium‐ und Phosphoniumionen (2002) (10)
- INTRIGUING TETRASODIUM DICATION CLUSTER NA42+ STABILIZED BETWEEN TWO SILYL(FLUOROSILYL)PHOSPHANIDE SHELLS (1998) (10)
- Tetraphosphanylsilane - A Mild PH2-Transfer Reagent and Building Block for the Synthesis of a Rhombododecahedral Li6P6Si2-Cluster Framework (2001) (10)
- Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation (2020) (10)
- Eine neue Synthese von Tetrachlordiphosphan sowie Untersuchungen zur 1,2-Addition an Cycloalkene (1993) (10)
- Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan‐Lewis‐Paaren (2018) (10)
- A Systems Approach to a One‐Pot Electrochemical Wittig Olefination Avoiding the Use of Chemical Reductant or Sacrificial Electrode (2020) (10)
- Germanium(IV) chloride at 193 K. (2002) (9)
- Synthesen und Strukturen von neuen 1,3,5-Triphospha-2,4,6-trisilacyclohexanen und Untersuchung ihrer Ligandeneigenschaften gegenüber [M(CO)3]-Komplexfragmenten (M = Cr, Mo)† (1996) (9)
- Synthesis and Crystal Structure Analysis of Tetraphosphanylsilane and Identification of Tetraphosphanylgermane. (1998) (9)
- An amplified Ylidic "half-parent" iminosilane LSi═NH. (2014) (9)
- Facile Access to Homo‐ and Heteroleptic, Triply Bonded Dimolybdenum Hexaalkoxides with Unsaturated Alkoxide Ligands (2011) (9)
- High Catalytic Synergism between the Components of the Rhenium Complex@Silver Hybrid Material in Alkene Epoxidations (2014) (9)
- In‐Liquid Plasma Modified Nickel Foam: NiOOH/NiFeOOH Active Site Multiplication for Electrocatalytic Alcohol, Aldehyde, and Water Oxidation (2022) (9)
- New Types of Ge2 and Ge4 Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand. (2021) (9)
- Mehrzähnige cyclische Phosphorliganden mit einem Silicium‐Phosphor‐Rückgrat: Templatsynthese eines 1,4,7‐Triphospha‐2,3,5,6,8,9‐hexasilacyclononans und eines 1,3,5,7,9,11‐Hexaphospha‐2,4,6,8,10,12‐hexasilacyclododecans (1997) (9)
- Coordination of a Si[double bond, length as m-dash]O subunit to metals: complexes of donor-stabilized silanone featuring a terminal Si[double bond, length as m-dash]O→M coordination (M = Zn, Al). (2010) (9)
- A heterobimetallic approach to stabilize the elusive disulfur radical trianion ("subsulfide") S2(·3-). (2013) (9)
- Intermetallic Fe6Ge5 formation and decay of a core-shell structure during the oxygen evolution reaction. (2021) (9)
- [R–PLi2(F–R)]2[R = SiPri2(C6H2Pri3-2,4,6)] the first structural characterization of a dilithium phosphandiide in the form of a fluorosilane complex (1996) (9)
- Nanostructured Intermetallic Nickel Silicide (Pre)Catalyst for Anodic Oxygen Evolution Reaction and Selective Dehydrogenation of Primary Amines (2022) (9)
- Silicon-Mediated Coupling of Carbon Monoxide, Ammonia and Primary Amines to Form Acetamides. (2019) (8)
- Synthesis and oxidation of phosphine cations. (2017) (8)
- New frontiers and challenges in silicon chemistry: ISOS XVII in Berlin. (2014) (8)
- An Isolable Bis(Silanone–Borane) Adduct (2020) (8)
- Ein beständiges 1,2-Dihydrophosphasilen-Addukt (2015) (8)
- From zinco(ii) arsaketenes to silylene-stabilised zinco arsinidene complexes. (2018) (8)
- (tBuSi)2(PC6H11)3: ein propellanartiges Cyclosilaphosphan mit bemerkenswerter Struktur (1994) (8)
- Mehrfachbindungen zwischen schweren Hauptgruppenelementen?. Von der klassischen π-Bindung zu strukturchemischem Neuland (1993) (8)
- (tBuSi)2(PC6H11)3: A Propellane‐Like Cyclosilaphosphane with Remarkable Structure (1994) (8)
- From a Molecular Single‐Source Precursor to a Selective High‐Performance RhMnOx Catalyst for the Conversion of Syngas to Ethanol (2019) (8)
- Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu-Ni complexes by ligand effects. (2016) (8)
- A soft molecular 2Fe–2As precursor approach to the synthesis of nanostructured FeAs for efficient electrocatalytic water oxidation† (2020) (8)
- Perstannylierte Ammonium- und Phosphoniumionen: metallorganische Onium- und gleichzeitig basenstabilisierte Stannyliumionen (2000) (8)
- Nanocrystalline ZnO from siloxy-substituted single-source precursors (2001) (8)
- Synthesis of siloxy- and alkoxy-substituted ZnO-aggregates for CVS of ZnO (2001) (8)
- Isolable cyclic radical cations of heavy main-group elements. (2020) (7)
- Supported ZnO catalysts for the conversion of alkanes: About the metamorphosis of a heterogeneous catalyst (2012) (7)
- From Dinuclear Zirconium(+3)-Phosphido Complexes {[Cp2ZrP(H)R]2} to the First Neutral Zirconocene–Phosphinidene Dimers [(Cp2ZrPR)2] by P–H Dehydrogenation (2005) (7)
- Facile Synthesis and Ambident Coordination of Cyclohexylbis(2-pyridyl)phosphane: Novel Dinuclear Complexes of Cu+1, Ag+1, and Co+2 Ions (2001) (7)
- Hohe elektromagnetische Feldverstärkung in nanotubularen TiO2‐Elektroden (2018) (7)
- Synthese, Struktur und Reaktionen von 1,2,3,6‐Tetrahydro‐1,2,3,6‐diphosphadiborin‐Derivaten (1989) (7)
- Synthese und Struktur eines 1,5-Diphospha-2,3,4,6,7,8hexasilabicyclo[3.2.1]octans mit einem neuen Cyclosilaphosphangerüst (1998) (7)
- Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes. (2004) (7)
- From Neutral Zn4O4 Clusters to a Cationic ZnO Dimer in Solution (2007) (6)
- Is2Si(Li)P(Li)SiR3 (Is = 2,4,6-iPr3C6H2): die ersten Lithiumsilanidyl-lithiumphosphanide und ihre Umwandlung in Disilaphosphirane und neuartige Mercuriophosphane (1996) (6)
- Novel Boron‐Phosphorus Cages with C4B4P4 and C2B4P4 Frameworks (1988) (6)
- A Facile Route to a New Class of Silicon- And Germaniumphosphorus Compounds: P2Si2-and Ge2P2- Bicyclo[1.1.0]Butanes-Synthesis and Inversion (1992) (6)
- Photocatalytic and photosensitized water splitting: A plea for well-defined and commonly accepted protocol (2018) (6)
- Diisobutyl(phosphanyl)alan: ein einfaches PH2-Transferreagens zur Synthese von polyphosphanylierten Verbindungen des Siliciums und Germaniums (2000) (6)
- Ein Tetraborylphosphonium‐Ion mit spiroheterocyclischem Aufbau (1989) (6)
- Isolable Silicon‐Based Polycations with Lewis Superacidity (2020) (6)
- Synthese und Kristallstrukturanalyse von Tetraphosphanylsilan und Nachweis von Tetraphosphanylgerman (1998) (6)
- P=Si and As=Si-bonds as building blocks for unusual phosphorus- and arsenic-silicon-heterocycles (1993) (6)
- Chemical Tricks to Stabilize Silanones and Their Heavier Homologues with E=O Bonds (E: Si—Pb): From Elusive Species to Isolable Building Blocks. (2013) (6)
- New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity Towards Activation of Small Molecules (2013) (6)
- From Metal–Organic Precursors to Functional Ceramics and Related Nanoscale Materials (2007) (6)
- An isolable β-diketiminato chlorosilylene. (2018) (5)
- Isolierbare Silicium‐basierte Polykationen mit Lewis‐Superacidität (2020) (5)
- Synthesis and molecular structure of fluoro(triphosphanyl)silane and attempts to synthesize a silylidyne–phosphane (2003) (5)
- Manganese sulfide enables the formation of a highly active β-MnOOH electrocatalyst for effective alkaline water oxidation (2022) (5)
- Triphosphatrisilacyclohexane als dreizähnige Coronanden in Cr‐ und Mo‐Komplexen: frühes Stadium der Si‐H‐Aktivierung versus Phosphankoordination (1992) (5)
- An Intermetallic CaFe6Ge6 Approach to Unprecedented Ca−Fe−O Electrocatalyst for Efficient Alkaline Oxygen Evolution Reaction (2022) (5)
- 29Si CP/MAS NMR of phosphorus-bearing organosilicon compounds. (1997) (5)
- An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline (2022) (4)
- Mechanistic studies of atomic layer deposition on oxidation catalysts - AlOx and POx deposition. (2020) (4)
- Striking transformations of the hydroborylene ligand in a HB:→NiII complex with isocyanides and CO (2018) (4)
- Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:](+)N3- with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)]. (2014) (4)
- Isolable Dibenzo[a,e]disilapentalene with a Dichotomic Reactivity toward CO2. (2020) (4)
- Metal nitrene-like reactivity of a SiN bond towards CO2 (2018) (4)
- Oxygen Evolution Activity of Amorphous Cobalt Oxyhydroxides: Interconnecting Precatalyst Reconstruction, Long‐Range Order, Buffer‐Binding, Morphology, Mass Transport, and Operation Temperature (2022) (4)
- Optimized immobilization of ZnO:Co electrocatalysts realizes 5% efficiency in photo-assisted splitting of water (2016) (4)
- Cluster Growing Through Ionic Aggregation: Synthesis and Structural Principles of Main Group Metal–Nitrogen, Phosphorus and Arsenic Rich Clusters (2005) (4)
- Taming a silyldiium cation and its reactivity towards sodium phosphaethynolate. (2018) (4)
- Molecular Clusters of Dimetalated Primary Phosphines and Arsines (2000) (4)
- Immobilization of an Iridium Pincer Complex in a Microporous Polymer for Application in Room‐Temperature Gas Phase Catalysis (2020) (4)
- Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N-Heterocyclic Silylene)Amido Iron Complexes as Catalysts. (2021) (4)
- Zwitterionic and Donor‐Stabilized N‐Heterocyclic Silylenes (NHSis) for Metal‐Free Activation of Small Molecules (2011) (4)
- A Tetraborylphosphonium Ion with a Spiroheterocyclic Structure (1989) (4)
- Biomimetische [2Fe‐2S]‐Cluster mit stark delokalisierten gemischtvalenten Eisenzentren (2015) (4)
- Steigerung der Wasseroxidation durch In‐situ‐Elektrokonversion eines Mangangallids: Ein intermetallischer Vorläuferansatz (2019) (3)
- Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein (2009) (3)
- THE FIRST ORTHOTELLURIC ACID POLYSILYLESTERS : SYNTHESIS AND CRYSTAL STRUCTURE OF (ME3SIO)8TE2O2 AND (ME4SI2O2)3TE (1999) (3)
- How To Tame Planar and Main Group Metal-Substituted Onium Ions of Phosphorus and Arsenic (2002) (3)
- Zur Kenntnis der Reaktionen von Mes2GeX2 (XF, Cl) mit [LiPH2(dme)]: Synthese von 1,1,4,4‐Tetramesityl‐2,3,5,1,4‐triphosphadigermolan (1993) (3)
- The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”) (2022) (3)
- Periodic Tales. A Cultural History of the Elements, from Arsenic to Zinc. By Hugh Aldersey-Williams. (2012) (3)
- Synthesis, Reactivity, and Electronic Structure of a Bioinspired Heterobimetallic [Ni(μ-S2)Fe] Complex with Disulfur Monoradical character (2014) (3)
- From molecular aggregates to novel organosilicon and phosphorus/arsenic compounds (1999) (3)
- Neuartige Bor-Phosphor-Kfige mit C4B4P4-und C2B4P4-Gersten (1988) (3)
- Use of Cellulose for the Production of Photocatalytic Films for Hydrogen Evolution Along the Lines of Paper Production (2021) (3)
- The study of the structure of the six-membered unsaturated N-heterocyclic silylene LSi: and related compounds by the methods of optical (Raman, IR, UV–vis) spectroscopy (2018) (3)
- Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid (2021) (3)
- Synthesen, Struktur und Eigenschaften von 1,2,5-Phosphadiborolanen† (1994) (3)
- In Situ Detection of Iron in Oxidation States ≥ IV in Cobalt‐Iron Oxyhydroxide Reconstructed during Oxygen Evolution Reaction (2023) (2)
- Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N bond towards CO2. (2018) (2)
- Toolbox for atomic layer deposition process development on high surface area powders. (2021) (2)
- Phosphorus and Arsenic Atom Transfer to Isocyanides to Form π-Backbonding Cyanophosphide and Cyanoarsenide Titanium Complexes. (2021) (2)
- Facile Rearrangement of a Bis(N‐heterocyclic carbene)borate Chelate Ligand and Access to [:GeX]+ Complexes (X = H, Cl) (2015) (2)
- Synthesis and Coordination Ability of a Donor‐Stabilised Bis‐Phosphinidene (2020) (2)
- Synthesis of High Surface Area—Group 13—Metal Oxides via Atomic Layer Deposition on Mesoporous Silica (2022) (2)
- Evolution of Carbonate-Intercalated γ-NiOOH from a Molecularly Derived Nickel Sulfide (Pre)Catalyst for Efficient Water and Selective Organic Oxidation. (2023) (2)
- N‐Heterocyclic Silylene Complexes in Catalysis: New Frontiers in an Emerging Field (2014) (2)
- Silylenes as Ligands in Catalysis (2019) (2)
- Unexpected White Phosphorus (P4) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene (2022) (2)
- From As-Zincoarsasilene (LZn-As=SiL') to Arsaethynolato (As≡C-O) and Arsaketenylido (O=C=As) Zinc Complexes. (2019) (2)
- A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand (2021) (2)
- Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O2, N2O and CO2. (2021) (1)
- A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene) (2021) (1)
- Novel, large area scalable polycrystalline Zn1-xCoxO films RF sputtered from a single mixed target for electrochemical water oxidation (2020) (1)
- Titelbild: A High‐Valent Heterobimetallic [CuIII(μ‐O)2NiIII]2+ Core with Nucleophilic Oxo Groups (Angew. Chem. 21/2013) (2013) (1)
- Activation of nickel foam through in-liquid plasma-induced phosphorus incorporation for efficient quasi-industrial water oxidation and selective oxygenation of organics (2023) (1)
- Back Cover: Silylene-Nickel Promoted Cleavage of B−O Bonds: From Catechol Borane to the Hydroborylene Ligand (Angew. Chem. Int. Ed. 26/2017) (2017) (1)
- In Situ Formed “Sn1–XInX@In1–YSnYOZ” Core@Shell Nanoparticles as Electrocatalysts for CO2 Reduction to Formate (2021) (1)
- Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst† (2021) (1)
- σ-Metathesis reaction and EH activation (E=P, As) of diphosphanyl- and diarsanylsilanes in the presence of the metal complex fragments [(dppe)M] (M=Ni, Pd, Pt; dppe=1,2-(Ph2P)2C2H4) (2002) (1)
- Synthesis and Structure of Siloxy-Substituted ZnO Aggregates Having ( ZnO ) n ( n 5 2 , 4 ) and Zn 3 O 4 Cores (2000) (1)
- Well-Defined, Silica-Supported Homobimetallic Nickel Hydride Hydrogenation Catalyst. (2021) (1)
- Bridging the Materials Gap in Catalysis: Entrapment of Molecular Catalysts in Functional Supports and Beyond (2009) (1)
- Nucleophilic versus Electrophilic Reactivity of Bioinspired Superoxido Nickel(II) Complexes (2018) (1)
- Unraveling Property‐Performance Relationships by Surface Tailoring of Oxidation Catalysts via ALD (2021) (1)
- Reviving Oxygen Evolution Electrocatalysis of Bulk La–Ni Intermetallics via Gaseous Hydrogen Engineering (2022) (1)
- E(SiMe(3))(4)(+) Ions (E=P, As): Persilylated Phosphonium and Arsonium Ions This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, and the Ministerium für Schule, Wissenschaft und Forschung des Landes Nordrhein-Westfalen. (2001) (1)
- Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms. (2021) (1)
- Elemental chalcogens acting as metal-free electrocatalysts for effective alkaline and acidic hydrogen evolution reaction (2022) (1)
- Chelating N-Heterocyclic Silylenes as Steering Ligands in Catalysis (2013) (1)
- Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions. (2023) (1)
- Reductive cleavage of P 4 by iron ( I ) centres : synthesis and structural characterisation of Fe 2 ( P 2 ) 2 complexes with two bridging P 2 2 ligands † (2015) (1)
- Silicon‐Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides (2019) (1)
- Ein S‐oxygenierter [NiFe]‐Komplex als Modell für Sulfenat‐ intermediate einer O2‐toleranten Hydrogenase (2017) (1)
- Quantification and Tuning of Surface Oxygen Vacancies for the Hydrogenation of CO 2 on Indium Oxide Catalysts (2022) (1)
- Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds (1996) (1)
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- Siliciumtetrakis(trifluormethansulfonat): Ein einfaches, neutrales Silan als weiche und harte Lewis‐Supersäure (2021) (0)
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- Multiple Bonding with Four-Coordinate Silicon ? Insights into the Nature of the Si d O and Si d S Double Bonds in Stable Silanoic Esters and Related Thioesters : A Combined NMR Spectroscopic and Computational Study (2010) (0)
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- Unusual Reactivity of the Silicon—Phosphorus Double Bond in a Silylidene(fluorosilyl)phosphane: Intramolecular C, H Insertion and Its Conversion in a New Silylidene(silyl)phosphane. (1999) (0)
- Rücktitelbild: Silylene-Nickel Promoted Cleavage of B−O Bonds: From Catechol Borane to the Hydroborylene Ligand (Angew. Chem. 26/2017) (2017) (0)
- Dual Catalytic Activity of Palladium Doped with a Rhodium Complex in a One-Pot, Four Step Process. (2015) (0)
- CCDC 260937: Experimental Crystal Structure Determination (2006) (0)
- An Arsanylidensilane (“Arsasilene”) and Its Derivatization with Tellurium and Benzophenone. (1992) (0)
- Gelernt ist gelernt: Feindbilder als “geistiges” Erbe der SED-ldeologen (1992) (0)
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