Maurice Brookhart
American chemist
Maurice Brookhart's AcademicInfluence.com Rankings

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Chemistry
Maurice Brookhart's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Maurice Brookhart Influential?
(Suggest an Edit or Addition)According to Wikipedia, Maurice S. Brookhart is an American chemist, and professor of chemistry at the University of Houston since 2015. Brookhart received his bachelor's degree from Johns Hopkins University in 1964. He received his PhD in 1968 from the University of California, Los Angeles, in physical organic chemistry where his thesis advisor was Saul Winstein. After an NSF postdoctoral fellowship at the University of California, Los Angeles in 1968 and a NATO postdoctoral fellowship at Southampton University, England. In 1969, he joined the faculty of the University of North Carolina, where he stayed until 2015, when he joined the University of Houston as a professor of chemistry.
Maurice Brookhart's Published Works
Published Works
- Late-metal catalysts for ethylene homo- and copolymerization. (2000) (2225)
- New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins (1995) (1859)
- Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene (1998) (1109)
- Carbon-hydrogen-transition metal bonds (1983) (937)
- Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts (1996) (907)
- Dehydrogenation and related reactions catalyzed by iridium pincer complexes. (2011) (793)
- Agostic interactions in transition metal compounds (2007) (786)
- Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate (1998) (617)
- Living Polymerization of α-Olefins Using NiII−α-Diimine Catalysts. Synthesis of New Block Polymers Based on α-Olefins (1996) (609)
- [(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes (1992) (578)
- Synthesis of branched polyethylene using (α-diimine)nickel(II) catalysts : influence of temperature, ethylene pressure, and ligand structure on polymer properties (2000) (552)
- Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins (1998) (545)
- Living alkene polymerization : New methods for the precision synthesis of polyolefins (2007) (479)
- Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis (2006) (396)
- Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations1 (2000) (379)
- Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts (1999) (311)
- Iridium bis(phosphinite) p-XPCP pincer complexes: highly active catalysts for the transfer dehydrogenation of alkanes. (2004) (304)
- Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts (1997) (292)
- Cyclopropanes from reactions of transition metal carbene complexes with olefins (1987) (253)
- Selective electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complexes. (2012) (253)
- Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination (1999) (237)
- Mechanistic studies of nickel(II) alkyl agostic cations and alkyl ethylene complexes: investigations of chain propagation and isomerization in (alpha-diimine)Ni(II)-catalyzed ethylene polymerization. (2003) (215)
- Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry. (2012) (215)
- Characterization of a Rhodium(I) σ-Methane Complex in Solution (2009) (210)
- Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts. (2018) (208)
- An efficient iridium catalyst for reduction of carbon dioxide to methane with trialkylsilanes. (2012) (201)
- Rapid selective electrocatalytic reduction of carbon dioxide to formate by an iridium pincer catalyst immobilized on carbon nanotube electrodes. (2014) (195)
- Low-Temperature Spectroscopic Observation of Chain Growth and Migratory Insertion Barriers in (α-Diimine)Ni(II) Olefin Polymerization Catalysts (1999) (194)
- Palladium(II) catalysts for living alternating copolymerization of olefins and carbon monoxide (1992) (192)
- Mechanistic Studies of the Palladium(II)-Catalyzed Copolymerization of Ethylene with Carbon Monoxide (1996) (187)
- Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes. (2011) (180)
- Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane. (2012) (178)
- Living and Block Copolymerization of Ethylene and α-Olefins Using Palladium(II)−α-Diimine Catalysts (2003) (172)
- Synthesis and Properties of Iridium Bis(phosphinite) Pincer Complexes (p-XPCP)IrH2, (p-XPCP)Ir(CO), (p-XPCP)Ir(H)(aryl), and {(p-XPCP)Ir}2{μ-N2} and Their Relevance in Alkane Transfer Dehydrogenation (2004) (164)
- Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands (1994) (158)
- Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes. (2011) (154)
- Synthesis of Highly Branched Polyethylene Using “Sandwich” (8-p-Tolyl naphthyl α-diimine)nickel(II) Catalysts (2013) (148)
- Addition of Olefins to Aromatic Ketones Catalyzed by Rh(I) Olefin Complexes (1999) (144)
- Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines. (2012) (141)
- A Highly Active Anilinotropone-Based Neutral Nickel(II) Catalyst for Ethylene Polymerization (2001) (138)
- Ligand exchanges and selective catalytic hydrogenation in molecular single crystals (2010) (137)
- Mechanistic and Synthetic Studies of the Addition of Alkyl Aldehydes to Vinylsilanes Catalyzed by Co(I) Complexes (1998) (136)
- Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts (2015) (131)
- Co(I)-Catalyzed Inter- and Intramolecular Hydroacylation of Olefins with Aromatic Aldehydes (1997) (126)
- Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes (1995) (125)
- Palladium(II) beta-agostic alkyl cations and alkyl ethylene complexes: investigation of polymer chain isomerization mechanisms. (2001) (121)
- Mechanistic studies of the transfer dehydrogenation of cyclooctane catalyzed by iridium bis(phosphinite) p-XPCP pincer complexes. (2004) (120)
- Mechanistic Studies of Palladium(II)-Catalyzed Hydrosilation and Dehydrogenative Silation Reactions (1997) (118)
- Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) Complex. (2010) (118)
- Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst (2013) (117)
- Living Polymerization of Ethylene Using Pd(II) α-Diimine Catalysts (2001) (112)
- A mechanistic investigation of the polymerization of ethylene catalyzed by neutral Ni(II) complexes derived from bulky anilinotropone ligands. (2004) (112)
- Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathway (1993) (110)
- Highly Active Supported Nickel Diimine Catalysts for Polymerization of Ethylene (2002) (106)
- Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes. (2007) (106)
- Lewis Acid-Catalyzed Synthesis of Aziridines (1996) (103)
- Reactions of vinyl acetate and vinyl trifluoroacetate with cationic diimine Pd(II) and Ni(II) alkyl complexes: identification of problems connected with copolymerizations of these monomers with ethylene. (2005) (103)
- Rational design and synthesis of highly active pincer-iridium catalysts for alkane dehydrogenation (2009) (101)
- Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para-Substituted Styrenes† (1997) (100)
- Synthesis of p-xylene from ethylene. (2012) (100)
- Iridium-catalyzed reduction of alkyl halides by triethylsilane. (2007) (100)
- A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines (1993) (100)
- Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. (2002) (99)
- Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations. (2012) (99)
- Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex. (2009) (98)
- Synthesis, spectral characterization and alkylidene-transfer reactions of electrophilic iron carbene complexes Cp(CO)(L)Fe:CHR+ (L = CO, PPh3; R = Me, Et, CHMe2) (1983) (98)
- Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes (2009) (97)
- A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. (2003) (96)
- Synthesis and Ethylene Polymerization Activity of a Series of 2-Anilinotropone-Based Neutral Nickel(II) Catalysts (2003) (95)
- Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane. (2008) (93)
- 13C NMR Analysis of α-Olefin Enchainment in Poly(α-olefins) Produced with Nickel and Palladium α-Diimine Catalysts (2007) (92)
- A highly active anilinoperinaphthenone-based neutral nickel(II) catalyst for ethylene polymerization (2003) (92)
- Ethylene Polymerization and Ethylene/Methyl 10-Undecenoate Copolymerization Using Nickel(II) and Palladium(II) Complexes Derived from a Bulky P,O Chelating Ligand (2002) (91)
- Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n‐butyl acrylate)‐graft‐polyethylene through the combination of Pd‐mediated living olefin polymerization and atom transfer radical polymerization (2002) (90)
- Synthesis of a Stereoblock Polyketone through Ancillary Ligand Exchange (1996) (89)
- Structural and spectroscopic characterization of an unprecedented cationic transition-metal eta1-silane complex. (2008) (88)
- Activation of sp3 C-H bonds with cobalt(I): catalytic synthesis of enamines. (2007) (85)
- Mechanistic Studies of Pd(II)-Catalyzed Copolymerization of Ethylene and Vinylalkoxysilanes: Evidence for a β-Silyl Elimination Chain Transfer Mechanism. (2016) (81)
- Measurement of the Barrier to β-Hydride Elimination in a β-Agostic Palladium−Ethyl Complex: A Model for the Energetics of Chain-Walking in (α-Diimine)PdR+ Olefin Polymerization Catalysts (2001) (80)
- Addition Polymerization of Cyclopentene with Nickel and Palladium Catalysts (1998) (79)
- Polymerization and oligomerization of ethylene by cationic nickel(II) and palladium(II) complexes containing bidentate phenacyldiarylphosphine ligands (2003) (77)
- Efficient Slurry-Phase Homopolymerization of Ethylene to Branched Polyethylenes Using α-Diimine Nickel(II) Catalysts Covalently Linked to Silica Supports (2006) (75)
- Selective reduction of carboxylic acids to aldehydes catalyzed by B(C6F5)3. (2013) (75)
- Mechanistic Studies of Catalytic Olefin Dimerization Reactions Using Electrophilic η3-Allyl−Palladium(II) Complexes (1996) (75)
- Efficient reduction of esters to aldehydes through iridium-catalyzed hydrosilylation. (2012) (74)
- Hydrogen/Deuterium Exchange Reactions and Transfer Hydrogenations Catalyzed by [C5Me5Rh(olefin)2] Complexes: Conversion of Alkoxysilanes to Silyl Enolates† (1999) (73)
- Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work (2015) (73)
- Nickel-Catalyzed Copolymerization of Ethylene and Vinyltrialkoxysilanes: Catalytic Production of Cross-Linkable Polyethylene and Elucidation of the Chain-Growth Mechanism. (2017) (72)
- Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction (1990) (70)
- Ruthenium(II) complexes with 2,6-pyridyl-diimine ligands: synthesis, characterization and catalytic activity in epoxidation reactions (1999) (70)
- Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst (1985) (70)
- Synthesis of Branched Ultrahigh-Molecular-Weight Polyethylene Using Highly Active Neutral, Single-Component Ni(II) Catalysts (2015) (69)
- Electronic effects on the {Beta}-alkyl migratory insertion reaction of para-substituted styrene methyl palladium complexes (1996) (67)
- Ni(II)-Catalyzed Polymerization of trans-2-Butene (2001) (64)
- Polymerization of Ethylene with Cationic Palladium and Nickel Catalysts Containing Bulky Nonenolizable Imine−Phosphine Ligands (2002) (64)
- O-H Chemical Shift, Conformation, and Electron Delocalization in Protonated Carbonyl Compounds (1967) (64)
- Proton-catalyzed hydrogenation of a d(8) Ir(I) complex yields a trans Ir(III) dihydride. (2010) (62)
- Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their Relationship to the Alternating Copolymerization of Ethylene and Carbon Monoxide (2000) (62)
- Phosphinidine-Palladium Complexes for the Polymerization and Oligomerization of Ethylene (2002) (62)
- Cobalt(III)-Catalyzed Living Polymerization of Ethylene: Routes to End-Capped Polyethylene with a Narrow Molar Mass Distribution (1995) (61)
- Structural characterization and fluxional behavior of cyclohexenylmanganese tricarbonyl. Intramolecular carbon-hydrogen bond activation via a 2-electron, 3-center manganese...hydrogen...carbon interaction (1982) (61)
- Isolation of stable secondary cationic iron carbene complexes dicarbonyl(.eta.5-cyclopentadienyl)phenylcarbeneiron hexafluorophosphate and carbonyl(.eta.5-cyclopentadienyl)triphenylphosphine(phenylcarbene)iron hexafluorophosphate (1977) (59)
- Mechanistic studies of platinum(II)-catalyzed ethylene dimerization: determination of barriers to migratory insertion in diimine Pt(II) hydrido ethylene and ethyl ethylene intermediates. (2007) (59)
- 13C and 2D NMR Analysis of Propylene Polymers Made with α-Diimine Late Metal Catalysts† (2001) (58)
- Design and Study of Rh(III) Catalysts for the Selective Tail-to-Tail Dimerization of Methyl Acrylate (1994) (58)
- Kinetics and Mechanism of Iridium-Catalyzed Dehydrogenation of Primary Amines to Nitriles (2008) (58)
- Decarbonylation of Aryl Ketones Mediated by Bulky Cyclopentadienylrhodium Bis(ethylene) Complexes (2004) (58)
- Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis (2009) (56)
- Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I) Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base Coordination. (2006) (56)
- Applications of PC(sp3)P Iridium Complexes in Transfer Dehydrogenation of Alkanes (2014) (55)
- Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFeSC)- and (RFeSC)-(C5H5)(CO)(Ph2R*P)Fe=CHCH3+ (R*=(S)-2-methylbutyl). Role of metal vs. ligand chirality in the optical induction (1983) (55)
- Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. (2002) (54)
- Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+ (1980) (53)
- Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex We thank the National Institutes of Health (NIH) for financial support and O. Daugulis for samples of dimesitylphosphane and 2,4,6-tri-tert-butylphenylphosphane. V.P.W.B. acknowledges a Feodor Lynen fellowship of the Alexander-von-Humbo (2001) (53)
- Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis (2010) (53)
- Gamma-agostic species as key intermediates in the vinyl addition polymerization of norbornene with cationic (allyl)Pd catalysts: synthesis and mechanistic insights. (2009) (52)
- Dihydrogen complexes of iridium and rhodium. (2012) (52)
- Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle. (2014) (51)
- Catalytic silane alcoholysis based on the C5H5(CO)(PPh3)Fe+ moiety. NMR spectroscopic identification of key intermediates (1998) (51)
- Reduction of Alkyl Halides by Triethylsilane Based on a Cationic Iridium Bis(phosphinite) Pincer Catalyst: Scope, Selectivity and Mechanism (2009) (51)
- Bond Angle Effects on the Migratory Insertion of Ethylene and Carbon Monoxide into Palladium(II)−Methyl Bonds in Complexes Bearing Bidentate Phosphine Ligands (2001) (51)
- Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+. A mechanistic analysis of the carbene transfer reaction (1991) (50)
- Rational Design of Highly Active “Hybrid” Phosphine–Phosphinite Pincer Iridium Catalysts for Alkane Metathesis (2013) (49)
- SPECTROSCOPIC CHARACTERIZATION AND DYNAMIC PROPERTIES OF CATIONIC ETA 2-SILANE AND ETA 2-H2 COMPLEXES OF GENERAL STRUCTURE CP(CO)(L)FE(HSIR3)+ AND CP( CO)(L)FE(H2)+ (L=PET3, PPH3) (1995) (48)
- Catalytic tail-to-tail dimerization of methyl acrylate using rhodium(III) catalysts (1991) (47)
- Low-temperature protonation of cyclooctatetraeneiron tricarbonyl and methylcyclooctatetraeneiron tricarbonyl. Generation and observation of cyclooctatrienyliron tricarbonyl cations (1972) (47)
- Structural characterization of an intermediate in arene C-H bond activation and measurement of the barrier to C-H oxidative addition: a platinum(II) eta(2)-benzene adduct. (2001) (47)
- Controlled, Copper-Catalyzed Functionalization of Polyolefins (2005) (46)
- Copolymerization of Ethylene and Acrylates by Nickel Catalysts (2003) (46)
- Metallocene-catalyzed C7-linkage in the hydrooligomerization of norbornene by sigma-bond metathesis: insight into the microstructure of polynorbornene. (2004) (46)
- Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(III) complex. (2011) (45)
- Mechanistic Studies of Palladium(II)-α-Diimine-Catalyzed Polymerizations of cis- and trans-2-Butenes (2004) (45)
- A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis (2019) (45)
- H/D exchange reactions between C6D6 and C5Me5Co(CH2=CHR)2 (R = H, SiMe3): Evidence for oxidative addition of Csp2−H bonds to the [C5Me5(L)Co] moiety (1997) (44)
- Synthesis of Branched Polyethylene with “Half-Sandwich” Pyridine-Imine Nickel Complexes (2016) (44)
- Five-coordinate trispyrazolylborate dihydridosilyl platinum(IV) complexes. (2001) (44)
- Stability and dynamic processes in 16VE iridium(III) ethyl hydride and rhodium(I) σ-ethane complexes: experimental and computational studies. (2013) (43)
- New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation. (2020) (43)
- .beta.-Migratory insertion reactions of (.eta.5-C5R'5)Rh(L)(C2H4)R+BF4- (R' = hydrogen, methyl; R = hydrogen, ethyl; L = P(OMe)3, PMe3). Comparison of the energetics of hydride versus alkyl migration (1992) (43)
- Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2+ (1980) (41)
- Rhodium(I)-catalyzed homologation of aromatic aldehydes with trimethylsilyldiazomethane. (2001) (41)
- Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. (2008) (40)
- PREPARATION AND REACTIVITY OF THE (CYCLOHEXADIENE)MANGANESE TRICARBONYL ANION. POTENTIALLY USEFUL METHODS OF ARENE AND CARBON-HYDROGEN BOND ACTIVATION (1981) (39)
- Silicon−Hydrogen Bond Activation and Formation of Silane Complexes Using a Cationic Rhodium(III) Complex (2004) (39)
- Synthesis and reactivity of cyclohexenylmanganese tricarbonyl, a complex containing a two-electron, three-center Mn.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.C interaction (1983) (38)
- Structure and Reactivity of a Cobalt(I) Phthalaldehyde Complex with Both σ- and π-Bonded Aldehyde Groups. (1999) (38)
- Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthetic and mechanistic studies of the reactions of 1,3,5-cyclooctatriene and its derivatives with benzylideneacetoneiron tricarbonyl (1977) (38)
- Comparison of migratory aptitudes of hydride and alkyl groups in .beta.-migratory insertion reactions of Cp*(P(OMe)3)Rh(C2H4)R+ (R = H, CH2CH3) (1988) (38)
- Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions (1980) (37)
- Hexakis(trimethylphosphine)molybdenum chemistry: dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives (1985) (37)
- The mechanism of polymerization of butadiene by "ligand-free" nickel(II) complexes. (2007) (37)
- Acid-assisted reductive elimination as a route to platinum(II) products from platinum(IV) tris(pyrazolyl)borate reagents (2000) (36)
- Ethylene Oligomerization Catalyzed by a Unique Phosphine−Oxazoline Palladium(II) Complex. Propagation and Chain Transfer Mechanisms (2007) (36)
- Reactions of H2 and R3SiH with Electrophilic Cobalt(III) Alkyl Complexes: Spectroscopic Characterization, Dynamics, and Chemistry of [Cp*Co(L)(H)(η2-H2)][B(ArF)4] and [Cp*Co(L)(H)(η2-HSiR3)][B(ArF)4] (2007) (36)
- Redistribution of Trialkyl Silanes Catalyzed by Iridium Silyl Complexes (2012) (35)
- The Dynamics of the β-Agostic Isopropyl Complex (ArNC(R)−C(R)NAr)Pd(CH(CH2-μ-H)(CH3))+BAr4‘- (Ar = 2,6-C6H3(i-Pr)2): Evidence for In-Place Rotation versus Dissociation of the Agostic Methyl Group (1998) (34)
- The reaction of benzylideneacetoneiron tricarbonyl with dienes; measurement of relative reactivities using competition experiments (1979) (34)
- Mechanism of rhodium(III)-catalyzed methyl acrylate dimerization (1992) (33)
- Manganese-mediated reductions of arenes to cyclohexa-1,3-dienes via manganese-hydrogen-carbon bond bridged cyclohexenylmanganese tricarbonyl complexes (1984) (33)
- cis4-Cyclononatetraeneiron tricarbonyl. Its synthesis, thermal rearrangement, and low-temperature protonation (1973) (32)
- Cationic Four- and Five-Coordinate Nickel(II) Complexes: Insights into the Nickel(II)-Catalyzed Copolymerization of Ethylene and Carbon Monoxide (2001) (32)
- Reactions of Cationic Palladium(II) Methyl and Vinyl Complexes with Alkynes (1998) (31)
- Ligand and substituent effects on the dynamics and structure of agostic ethylenecobalt complexes of the type C5R5(L)Co(CH2CHR'-.mu.-H)+ BF4- [L = P(OMe)3, PMe3; R = H, Me; R' = H, Me] (1989) (31)
- Bridge flipping and rearrangement of norbornadienyl and 7-methylnorbornadienyl cations (1967) (31)
- Ground- and Transition-State Free Energy Relationships in σ and π Routes to the Nonclassical 7-Norbornenyl Cation1 (1966) (30)
- Four- and five-coordinate CO insertion mechanisms in d(8)-nickel(II) complexes. (2001) (30)
- Degenerate and nondegenerate isomerizations of 7-norbornadienyl cations (1972) (30)
- The quest for stable σ-methane complexes: computational and experimental studies (2011) (30)
- Piperidinate Complexes of Nickel and Copper Mesoporphyrin IX (1964) (30)
- Alkene Isomerization by “Sandwich” Diimine-Palladium Catalysts (2017) (29)
- The stereospecificity of proton addition to cycloheptatrieneiron tricarbonyl (1977) (28)
- Cobalt-Catalyzed Dimerization of a-Olefins to Give Linear a-Olefin Products (2005) (28)
- Spectroscopic characterization of electrophilic d4 methylene and benzylidene complexes of the type Cp(CO)2(L)M(:CHR)+ (L = PPh3, PEt3; M = Mo, W; R = H, Ph). Experimental determination of barriers to rotation about the tungsten-methylene multiple bond (1982) (28)
- Iron and ruthenium cyclopropylcarbene complexes C5H5(CO)2M:CH(c-C3H5)+ CF3SO3-. Cyclopropylcarbene transfer reactions (1987) (28)
- SPECTROSCOPIC STUDIES OF THE STRUCTURES OF PROTONATED DIENEIRON TRICARBONYL COMPLEXES (1976) (28)
- Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthesis and thermal rearrangement of tricyclo[4.4.0.02,5]deca-7,9-diene and tricyclo[4.3.0.07,9]nona-2,4-diene (1974) (28)
- Protonation of diene complexes of rhodium, iridium, ruthenium, and osmium: a fine balance between terminal and agostic hydrides (1992) (28)
- Mechanism of hydrogenolysis of an iridium-methyl bond: evidence for a methane complex intermediate. (2013) (27)
- Synthesis and Reactivity of Cationic (Allyl)(arene)nickel(II) and (Allyl)(arene)palladium(II) Complexes (2009) (27)
- Oxygen atom transfer to a half-sandwich iridium complex: clean oxidation yielding a molecular product. (2014) (27)
- Glassy State and Secondary Structures of Chiral Macromolecules: Polyisocyanates and Polyketones (2001) (27)
- Temperature- and solvent-dependent binding of dihydrogen in iridium pincer complexes. (2006) (27)
- Dynamics of agostic complexes of the type C5R5(C2H4)M(CH2CH2-.mu.-H)+. Energy differences between and ancillary ligand control of agostic and terminal hydride structures (1990) (26)
- Ethylene Polymerization Using Tetramethyl(2-methylthioethyl)cyclopentadienyl Complexes of Cobalt (2003) (26)
- Synthesis and Reactivity of Low-Valent Amido, Imido, Azavinylidene, and Nitrido Complexes of Tungsten (1994) (26)
- Structure of the Nonclassical 7-Norbornenyl Cation1 (1966) (25)
- OBSERVATION OF AN INVERSE KINETIC ISOTOPE EFFECT IN A CO(III)-CATALYZED POLYMERIZATION OF ETHYLENE (1997) (25)
- Mononuclear cis-carbonyloxotungsten(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate (1991) (25)
- Probing the oxidation chemistry of half-sandwich iridium complexes with oxygen atom transfer reagents. (2013) (24)
- Fluxionality in (cycloheptatriene)iron tricarbonyl complexes (1982) (24)
- Argonne Intense Pulsed Neutron Source Used to Solve the Molecular Structure of a Novel Organometallic Complex (1983) (24)
- Transition Metal Carbene Complexes. (1984) (24)
- Platinum(II) and Platinum(IV) Acyl and Formyl Complexes (2002) (24)
- Nitrene Transfer to Trimethylphosphine from Cationic Tungsten Tosylnitrene Complexes [Tp'(CO)2W(NTs)][X] (1994) (23)
- Role of coordination geometry in dictating the barrier to hydride migration in d6 square-pyramidal iridium and rhodium pincer complexes. (2011) (23)
- Vinyl addition polymerization of norbornene with cationic (allyl)Ni catalysts: Mechanistic insights and characterization of first insertion products (2009) (23)
- Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition (2004) (23)
- .pi. to .sigma. Rearrangements upon metal protonation of polyolefin-transition metal complexes (1974) (23)
- Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor (2015) (22)
- Exploring Oxidation of Half-Sandwich Rhodium Complexes: Oxygen Atom Insertion into the Rhodium–Carbon Bond of κ2-Coordinated 2-Phenylpyridine (2014) (22)
- Catalytic alkane transfer-dehydrogenation by PSCOP iridium pincer complexes (2016) (22)
- Synthesis, Structure, and Reactivity of [C5Me5CoLL‘] Complexes with L = Pyridine and L‘ = Olefin or L−L‘ = Bipyridine (2000) (22)
- Synthesis of Piperylene and Toluene via Transfer Dehydrogenation of Pentane and Pentene (2013) (22)
- Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M:CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to aryl rotation and benzylidene transfer reactions (1989) (22)
- Syntheses of Platinum(IV) Aryl Dihydride Complexes via Arene C−H Bond Activation (2001) (21)
- Polymerization of 1,3‐dienes and styrene catalyzed by cationic allyl Ni(II) complexes (2010) (21)
- Synthesis and reactions of the tautomeric complexes .eta.-2,3,4,5-cyclooctatrienoneiron tricarbonyl and bicyclo[4.2.0]octa-2,4-dien-7-oneiron tricarbonyl. Generation of bicyclo[4.2.0]octa-2,4-dien-7-one (1976) (21)
- The mechanism of hydrogen migration in cyclohexadienylmanganese tricarbonyl (1980) (21)
- Preparation of alkyl-substituted derivatives of cyclohexenylmanganese tricarbonyl via reduction of methylated arene complexes. Characterization of and substituent site preference determination for interconverting cyclohexenyl isomers containing a two-electron, three-center Mn.cntdot..cntdot..cntdot. (1983) (21)
- Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes. (2011) (21)
- Direct observation of the cyclooctatrienyliron tricarbonyl cation and its electrocyclic ring closure to the bicyclo[5.1.0]octadienyliron tricarbonyl cation (1970) (20)
- Palladium(II)-catalyzed copolymerization of styrenes with carbon monoxide: mechanism of chain propagation and chain transfer. (2009) (20)
- Oligomerization of ethylene to branched alkenes using neutral phosphinosulfonamide nickel(II) complexes (2000) (20)
- The Homoaromatic 1-Hydroxyhomotrophylium Cation (1967) (19)
- Gamma-agostic interactions stabilize the propagating species in the vinyl addition polymerization of norbornene. (2009) (19)
- Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions (2001) (19)
- Transfer of ethylidene from .eta.5-C5H5(CO)2Fe:CHMe+ to para-substituted styrenes. Loss of stereochemistry about the C.alpha.-C.beta. double bond of cis-.beta.-deuterio-p-methoxystyrene (1984) (19)
- Synthesis, structure, and electronic properties of monomeric and dimeric trispyrazolylborate platinum(II) hydride complexes. (2001) (19)
- Synthesis and reactivity of bidentate phosphine iron complex [(C2F5)2PCH2CH2P(C2F5)2]Fe(CO)3 (1992) (19)
- FLUXIONAL BEHAVIOR AND SUBSTITUENT SITE PREFERENCES IN CATIONIC MONOSUBSTITUTED TROPYLIUMIRON TRICARBONYL COMPLEXES (1979) (18)
- Synthesis, spectral characterization, and carbene-transfer reactions of CpFe(CO)2=CH(c-C3H5)+ CF3SO3-. Stabilization of cyclopropylmethylidene by an organometallic fragment (1985) (18)
- Detailed mechanism of thermal hydrogen migration in cyclohexadieneiron tricarbonyl (1981) (18)
- Degenerate five-carbon scrambling in the 7-norbornadienyl cation. (1967) (18)
- Tp‘PtH3: A Stable Platinum(IV) Trihydride (2000) (18)
- INSERTION REACTIONS OF ELECTROPHILIC IRON CARBENE COMPLEXES WITH ORGANOSILANES : A SYNTHETIC AND MECHANISTIC STUDY (1995) (17)
- Cobalt-catalyzed hydrosilation/hydrogen-transfer cascade reaction: a new route to silyl enol ethers. (2013) (17)
- Palladium-catalysed alkene chain-running isomerization. (2017) (17)
- Crystal and molecular structure of (.eta.5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato)iron(II) dicarbonyl: a strong electrostatic iron-triflate interaction (1983) (17)
- Tungsten nitrene complexes Tp'W(CO)2(NR)+ (R = Ph, tert-Bu) generated from amido complexes Tp'W(CO)2(NHR) (1990) (17)
- The insertion of sulfur dioxide into palladium–methyl bonds: the synthesis and X-ray crystal structure of an unusual [(dppp)PdOS(Me)O]2[BAr′4]2 dimer (2000) (17)
- Preparation and characterization of conjugated polymers made by postpolymerization reactions of alternating polyketones. (2011) (17)
- Intramolecular hydride migration from formyl to carbonyl and nitrene ligands (1992) (16)
- Single and Multiple Insertion of Carbon−Carbon Triple Bonds into the Palladium−Aryl Bond of Cationic and Neutral Arylpalladium Complexes with a 2,2‘-Bipyridine Ligand (2000) (16)
- Synthesis, structure and computational studies of a cationic T-shaped Pd-complex (2013) (16)
- Synthesis, spectroscopic characterization, dynamics, and phosphine trapping of Cp(CO)Fe[.eta.3-CH(R)C6H5] complexes (R = H, OCH3) (1989) (16)
- Diastereoselective reactions of chiral-at-iron carbene complexes C5H5(CO)(PR3)Fe:CHR+. Synclinal isomers are more reactive than anticlinal isomers (1988) (16)
- Late‐Metal Catalysts for Ethylene Homo‐ and Copolymerization (2000) (16)
- Isomerization of 1,3,5-cyclooctatrieneiron tricarbonyl to bicyclo[4.2.0]octa-2,4,-dieneiron tricarbonyl (1973) (16)
- Reactions of the (.eta.3-allyl)iron tricarbonyl anion with carbon electrophiles (1989) (16)
- Synthesis and reactivity of methyl-substituted butenylmanganese tricarbonyl complexes containing a two-electron, three-center Mn.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.C interaction (1985) (15)
- Investigation of the stereochemistry of iron-carbon.alpha. bond cleavage when phenylcyclopropane is generated by .gamma.-ionization of stereospecifically deuterated C5H5(CO)2FeCHDCHDCH(OCH3)C6H5 complexes. A transition-state model for transfer of the carbene ligand from C5H5(CO)2Fe:CHR+ to alkenes (1991) (15)
- Detection and measurement of the rate of 1,3-iron shift in cycloheptatrieneiron tricarbonyl (1978) (15)
- Generation of trans-π-pentadienyliron tricarbonyl cations from protonation of (trans,trans-2,4-hexadienal)iron tricarbonyl (1972) (14)
- Anionic manganese tricarbonyl complexes of C7 and C8 cyclic dienes and polyenes: synthesis and reactions with electrophiles (1988) (14)
- Generation of [C5(CH3)5Ru(NO)(CH3)(H2O)]+ [BAr'4]- (Ar' = 3,5-C6H3(CF3)2) and its reaction with methyl acrylate to produce chelate complexes of the type C5(CH3)5Ru(NO)(CH(R)CH2COOCH3)+ (R = H, CH3) (1994) (14)
- Simple low-valent amido, imido, and nitrido complexes of tungsten (1992) (14)
- Matrix isolation and transient absorption studies of [bis[bis(pentafluoroethyl)phosphino]ethane]tetracarbonylchromium: intermolecular alkane complexes and intramolecular F-coordination (1992) (14)
- Hydride reduction of (diene)iron tricarbonyl complexes as a route to substituted (allyl)iron tricarbonyl anions. Detection of a formyl intermediate in the hydride reduction of (1,3-butadiene)iron tricarbonyl by Et3BH- (1993) (13)
- Polymerization of Ethylene Catalyzed by Phosphine-Iminophosphorane Palladium Complexes (2017) (13)
- A Cationic Terminal Methylene Complex of Ir(I) Supported by a Pincer Ligand (2013) (13)
- Classical 7-norbornenyl cation. Competition between aryl and alkenyl functions in stabilizing 7-aryl-7-norbornenyl cations (1970) (13)
- Synthesis of 1,2-diheteroatom-substituted alkenes via rhodium-catalyzed intramolecular hydrogen transfer. (2003) (13)
- Formation of Cp(CO)(PR3)FeCH(OCH3)C6H5 complexes via PR3 substitution reactions, hydride addition to Cp(CO)(PR3)Fe:C(OCH3)C6H5+, and methoxide addition to Cp(CO)(PR3)Fe:CHC6H5+. Kinetic and thermodynamic diastereoselectivities. Relative reactivities of synclinal and anticlinal iron carbene isomers (1989) (13)
- Where Are the Chain Ends in Semicrystalline Polyethylene (2017) (12)
- Ethylene Polymerization with Ni(II) Diimine Complexes Generated from 8-Halo-1-naphthylamines: The Role of Equilibrating Syn/Anti Diastereomers in Determining Polymer Properties (2019) (12)
- Reaction of lithium dimethylcuprate with C6H6Mn(CO)3+. Observation of methyl group migration from manganese to the arene ring in C6H6(CO)2MnMe (1982) (12)
- Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn/anti Isomerization (2020) (11)
- Carbon-Carbon Bond-Forming Reactions of Eta(3)-Allyl Iron Tricarbonyl Anions with Carbon Electrophiles (1994) (11)
- Epimerization of bicyclo[6.1.0.]nonatriene (1975) (11)
- Structural characterization of [κ2-(t-Bu)2PCH2C(O)C6H5]PdMe(η2-C2H4)+BAr'4-: A model for the catalyst resting state for ethylene polymerization (2003) (11)
- Isomerization of bicyclo[5.1.0]-2,4-octadieneiron tricarbonyl to bicyclo[4.2.0]-2,4-octadieneiron tricarbonyl☆ (1974) (11)
- Two-electron, three-centre carbon–hydrogen–cobalt bonds in the compounds [Co(η-C5Me4R)(η-C2H4)(η-C2H4-µ-H)] BF4, R = Me and Et (1983) (11)
- A general route to C6H6(CO)2Mn-R complexes via C6H6(CO)2Mn−Na+: alkyl group migrations from manganese to the coordinated arene ring (1986) (10)
- Palladium(II)- and Nickel(II)-Catalyzed Olefin Polymerization (1996) (10)
- Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors. (2011) (10)
- Oligomerization of Ethylene Using a Diphosphine Palladium Catalyst (2017) (10)
- General route to anionic (.eta.4-diene)manganese tricarbonyl complexes. Reactions with electrophiles (1987) (10)
- Resolution of the chiral-at-iron acetyl complexes C5H5(CO)(PR3)FeC(O)CH3 (R = CH3, CH2CH3). Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+ (R = CH3, CH2CH3) (1989) (9)
- When phenylcyclopropanes are generated by .gamma.-ionization of erythro- and threo-d2-C5H5(CO)2FeCHDCHDCH(OCH3)C6H5, cleavage of the Fe-C.alpha. bond occurs with inversion of configuration of C.alpha. (1989) (9)
- Measurement of barriers to aryl rotation in Cp(CO)2FeCHC6H5+ and Cp(CO)2FeCH(p-CH3C6H4)+ (1980) (9)
- Reactions of [Cp(CO)2Fe=CHAr]+ (Ar = p-C6H4OMe) with O=N-Ar′ (Ar′ = C6H5, p-C6H4NMe2) and PhN=NPh (1990) (9)
- Novel furan dimer (1973) (9)
- Enantioselective benzylidene transfer reactions using the chiral-at-iron benzylidene complexes (SFeSc)- and (RFeSc)-Cp(CO)(Ph2R★P_Fe=CH6H5+ (R★ = (S-2-methylbutyl) and SFe- and (RFe)-Cp(CO)PEt3Fe=CHC6H5+ (1989) (8)
- CHEMISTRY OF DIENE AND ENONE IRON TRICARBONYL COMPLEXES * (1977) (8)
- Living Transition Metal-Catalyzed Alkene Polymerization: Polyolefin Synthesis and New Polymer Architectures (2010) (8)
- Oligomerization and polymerization of 5-ethylidene-2-norbornene by cationic palladium and nickel catalysts (2020) (8)
- Iridium‐Catalyzed Reduction of Secondary Amides to Secondary Amines and Imines by Diethylsilane. (2013) (8)
- (η5-C5H5)(Ph2PCH2CH2PPH2)RuCH2+ AsF6−. Spectral Characterization and measurement of the barrier to methylene rotation (1986) (8)
- Half-sandwich Rh(Cp*) and Ir(Cp*) complexes with oxygen atom transfer reagents as ligands (2015) (8)
- 7-Phenyl- and 7-methoxynorbornadienyl cations (1967) (8)
- Low temperature protonation of methylcyclooctatetraeneiron tricarbonyl (1971) (7)
- Low temperature spectroscopic observation of oxygen-protonated troponeiron tricarbonyl complexes (1977) (7)
- CRYSTAL AND MOLECULAR STRUCTURE OF (η5-PENTAMETHYLCYCLOPENTADIENYL)(TRIFLUOROMETHANESULFONATO)IRON(II) DICARBONYL: A STRONG ELECTROSTATIC IRON-TRIFLATE INTERACTION (1984) (7)
- Preparation of bicyclo[4.2.0]octa-2,4-dien-7-one via trapping with benzylideneacetoneiron tricarbonyl (1976) (7)
- Synthesis of 1,1'-bicobaltocene salts of tetracyano-p-quinodimethanide and the structure of 1,1'-bicobaltocene[CoIIICoIII] tris(tetracyano-p-quinodimethanide) (1982) (7)
- Co(I)‐Catalyzed Inter‐ and Intramolecular Hydroacylation of Olefins with Aromatic Aldehydes. (1997) (7)
- Synthesis, Characterization, and Reactivity Studies of (Cyclohexenyl)nickel(II) Complexes† (2010) (7)
- 2,4,6-Triphenylpyridinium: A Bulky, Highly Electron-Withdrawing Substituent Which Enhances Properties of Nickel(II) Ethylene Polymerization Catalysts. (2020) (7)
- Observation of a π- to σ-rearrangement upon proton addition to bicyclo[6,1,0]nonatrienetricarbonylmolybdenum (1973) (6)
- The thermal rearrangement and ring inversion of the 1-methoxyhomotropylium cation (1972) (6)
- Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers. (2020) (5)
- Synthesis, structure, and reactivity of iridium(III) complexes containing a 4,6-dimethyl-1,3-benzenediphenylimine pincer ligand. (2013) (5)
- Direct observation of substituted quadricyclyl cations and their rearrangements (1971) (5)
- Transfer Dehydrogenations of Alkanes and Related Reactions Using Iridium Pincer Complexes (2015) (5)
- Phenonium and Benzylic Cations from 3-Phenyl-2-butanols in FSO3H-SbF51 (1966) (5)
- Evidence for symmetrical bridging in methylated 7-norbornenyl cations (1970) (5)
- The Behavior of the 3-Phenyl-2-butanols in SO2-FSO3H-SbF51 (1966) (5)
- Low temperature protonation of cyclo-octa-1,5-diene-(duroquinone)nickel(0) (1974) (4)
- Synthesis, Structure and Reactivity of Highly Electrophilic Carbene Complexes of the Type C5H5 (CO)(L)Fe=CHR (1989) (4)
- The Structure and Magnetic and Electrical Conductivity Properties of the Charge Transfer Compound 1,1′-Dimethylferrocenium Bis-(Tetracyanoquinodimethane), [(CH3C5H4)2Fe][TCNQ]2 (1979) (4)
- Synthesis and Reactivity of a Surfactant Ferrocene. Environmental Effects on Oxidation of Ferrocene in Organized Media (1979) (4)
- Synthesis, characterization, and reactivity of (π-allyl)palladium(II) wrap-around complexes with 1,3-dienes (2011) (4)
- Synthesis of End-Functionalized Poly(norbornenes) and Poly(ethylidene norbornenes) Using a Pd(II) Catalyst in Combination with Chain Transfer Agents (2021) (4)
- Direct observation of methyl-substituted 7-norbornadienyl and bicyclo[3.2.0]heptadienyl cations (1968) (4)
- Kinetics of formation of the 4,4′-bis-dimethylaminodiphenyl carbonium ion (BDC+) and its reaction with sulfhydryl residues☆ (1974) (3)
- Enantioselective Cyclopropane Syntheses Using the Chiral Carbene Complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe=CHCH+ 3. A Mechanistic Analysis of the Carbene Transfer Reaction. (1991) (3)
- A PIVOTAL APPLICATION OF FIELD DESORPTION MASS SPECTROMETRY TO DISTINGUISH BETWEEN MOLECULAR AND IONIC ORGANOMETALLIC COMPLEXES (1981) (3)
- CIS(4)-CYCLONONATETRAENEIRON TRICARBONYL, ITS SYNTHESIS, THERMAL REARRANGEMENT, AND LOW-TEMPERATURE PROTONATION (1973) (3)
- Virtual Issue on Research in the Center for Enabling New Technologies Through Catalysis (CENTC) (2014) (3)
- New routes to ester and acid functionalized polyethylene (1997) (3)
- Reduction of Alkyl Halides by Triethylsilane Based on a Cationic Iridium Bis(phosphinite) Pincer Catalyst: Scope, Selectivity and Mechanism. (2009) (2)
- The 7-methoxynorbornadienyl cation: evidence for a symmetrically bridged structure (1971) (2)
- Co(III) catalyzed polymerizations of ethylene, oligomerizations of 1-hexene, and copolymerization of ethylene and 1-hexene (1991) (2)
- Transition metal catalyzed alternating copolymerizations of olefins and co (1995) (1)
- 2,4,6‐Triphenylpyridinium: A Bulky, Highly Electron‐Withdrawing Substituent That Enhances Properties of Nickel(II) Ethylene Polymerization Catalysts (2021) (1)
- Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex. (2002) (1)
- Regioselectivity in the transfer-dehydrogenation of alkanes by two pincer-iridium-based catalysts (2009) (1)
- Sequential Nitrene Transfers to an Organometallic Half-Sandwich Iridium Complex (2015) (1)
- Synthesis of 2-Anilinotropones via Palladium-Catalyzed Amination of 2-Triflatotropone. (2000) (1)
- Supporting Information for Reactions of Phosphinites with Alumina and Silica : A New Method for Anchoring Organic and Organometallic Complexes on Oxide Surfaces (2010) (1)
- Lewis Acid Catalyzed Synthesis of Aziridines. (1997) (1)
- Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies. (2016) (1)
- A tale of two ligands. Subtle differences in sterics exert major differences in the energetics of alkane dehydrogenation catalyzed by pincer complexes (tBuPCP)Ir vs. (tBuPOCOP)Ir (2008) (1)
- Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes (2011) (1)
- Ligand and substituent effects on the dynamics and structure of agostic complexes of the type C5R5(L)Co(CH2CHR'-μ-H)+BF4− (L=P(OMe)3, PMe3; R=H, Me; R'=H, Me) (1989) (1)
- Olefin polymerizations using cationic Ni(II) and Pd(II) diimme complexes (2001) (1)
- Polymerization of Terminal Acetylenes by a Bulky Monophosphine-Palladium Catalyst (2023) (0)
- A process for the production of alpha-olefins (1998) (0)
- Synthesis and Properties of a Stable, Cationic, Rhodium Lewis-Acid Catalyst for Hydrosilation, Mukaiyama Aldol and Cyclopropanation Reactions. (2001) (0)
- Dedication to the Special Volume for Dietmar Seyferth (2010) (0)
- Reactions of the (η3-Allyl)iron Tricarbonyl Anion with Carbon Electrophiles. (1989) (0)
- PREPARATION OF BICYCLO(4.2.0)OCTA-2,4-DIEN-7-ONE BY TRAPPING WITH BENZYLIDENEACETONEIRON TRICARBONYL (1976) (0)
- Rh(III) Catalysts for Tail-to-Tail Dimerization of Methyl Acrylate (1993) (0)
- SELECTIVE TRAPPING OF DIENES BY BENZYLIDENEACETONEIRON TRICARBONYL, SYNTHESIS AND THERMAL REARRANGEMENT OF TRICYCLO(4.4.0.0(2,5))DECA-7,9-DIENE AND TRICYCLO(4.3.0.0(7,9))NONA-2,4-DIENE (1974) (0)
- Transfer Dehydrogenation with Alumina-Supported Ir PincerComplexes (2009) (0)
- Where are the Chain Ends in Semi-Crystalline Polyethylene? (2001) (0)
- Cyclopropanes from Reactions of Transition-Metal - Carbene Complexes with Olefins (1987) (0)
- Carbon Electrophiles with Dienes and Polyenes Promoted by Transition Metals (1991) (0)
- Catalyseurs de polymerisations de l'olefine (2000) (0)
- Addition of Olefins to Aromatic Ketones Catalyzed by Rh(I) Olefin Complexes. (1999) (0)
- CATALYST COMPOSITION AND OLEFIN POLYMERIZATION USING SAME FIELD OF THE INVENTION (2017) (0)
- A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis (2019) (0)
- ENANTIOSELECTIVE CYCLOPROPANE SYNTHESIS USING THE CHIRAL CARBENE COMPLEXES (SFESC)- AND (RFESC)-(C5H5)(CO)(PH2R*P)FE:CHCH3+ (R* = (S)-2-METHYLBUTYL). ROLE OF METAL VS. LIGAND CHIRALITY IN THE OPTICAL INDUCTION (1984) (0)
- Enantioselective Benzylidene Transfer Reactions Using the Chiral-ate-Iron Benzylidene Complexes (SFeSC)- and (RFeSC)-Cp(CO)(Ph2R*P)Fe=CHC6H5+ (R* = (S)-2-Methylbutyl) and (SFe)-and (RFe)-Cp(CO)(PEt3)Fe=CHC6H5+. (1990) (0)
- Synthesis, Spectroscopic Characterization, Dynamics, and Phosphine Trapping of Cp(CO)Fe(η3-CH(R)C6H5) Complexes (R: H, OCH3). (1989) (0)
- Comparison of Migratory Aptitudes of Hydride and Alkyl Groups in β-Migratory Insertion Reactions of Cp*(P(OMe)3)Rh(C2H4)R+ (R: H, CH2CH3) (1989) (0)
- Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex † 2579 – 2586 (2016) (0)
- Catalyseurs sur support à base d'iridium (2008) (0)
- Cobalt-catalyzed dimerization of alpha-olefins to give linear alpha-olefin products. (2005) (0)
- Diastereoselective Reactions of Chiral-at-Iron Carbene Complexes C5H5(CO)(PR3)Fe=CHR+. Synclinal Isomers Are More Reactive Than Anticlinal Isomers. (1988) (0)
- Control of the glass transition in stereoregular polyketones by terpolymerization (1998) (0)
- Synthesis of 1,2‐Diheteroatom‐Substituted Alkenes via Rhodium‐Catalyzed Intramolecular Hydrogen Transfer. (2003) (0)
- A Copper(I) Catalyst for Carbene and Nitrene Transfer to Form Cyclopropanes, Cyclopropenes, and Aziridines. (1993) (0)
- Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex † ChemicalScience EDGE ARTICLE (2016) (0)
- Efficient Reduction of Esters to Aldehydes Through Iridium‐Catalyzed Hydrosilylation. (2013) (0)
- The Synthesis of 1,1'-Bicobaltocene Salts of Tetracyano-P-Quinodimethanide and the Sturcture of 1,1'-Bicobaltocene (Co (III) Co (III)) (TCNQ)3, (1981) (0)
- The Chemistry of Transition Metal Carbene Complexes. (1983) (0)
- Reactions of (Cp(CO)2Fe=CHAr)+ (Ar: p-C6H4OMe) with O=N-Ar′ (Ar′: C6H5, p-C6H4NMe2) and PhN=NPh. (1990) (0)
- Polymerisation d'ethylene (1998) (0)
- Synthesis and Spectral Characterization of a Series of Iron and Ruthenium Benzylidene Complexes, Cp(CO)(L)M=CH(C6H4R)+ (M: Fe, Ru; L: CO, PPh3; R: p-H, p-F, p-CH3, p-OCH3). Barriers to Aryl Rotation and Benzylidene Transfer Reactions. (1989) (0)
- Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes: Solution-phase and solid-supported iridium-based pincer catalysts (2009) (0)
- Additions and Corrections - A Classical 7-Norbornenyl Cation. Competition between Aryl and Alkenyl Functions in Stabilizing 7-Aryl-7-norborenyl Cations (1970) (0)
- Alpha-olefins and olefin polymers and methods for their preparation (1997) (0)
- η1 σ‐Alkyl Complexes by Nucleophilic Attack on Metal‐Chelating Diene Complexes (2007) (0)
- Materials-chirality: exploration of polyketone secondary structure by correlation between solid state optical activities and thermal properties (1998) (0)
- Tungsten nitrene complexes Tp prime W(CO) sub 2 (NR) sup + (R = Ph, Bu sup t ) generated from amido complexes Tp prime W(CO) sub 2 (NHR) (1990) (0)
- Resolution of the Chiral-at-Iron Acetyl Complexes C5H5(CO)(PR3)FeC(O)CH3 (R: CH3, CH2CH3). Enantioselective Cyclopropane Synthesis Using the Chiral Carbene Complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe=CHCH+ 3 (R: CH3, CH2CH3). (1989) (0)
- Final Report: Mechanistic Studies of Transitional Metal Catalyzed Alternating Copolymerization of Carbon Monoxide with Olefins, July 1, 1994 - May 31, 1998 (1998) (0)
- t-Boc protected poly(p-hydroxystyrene-alt-carbon monoxide): a new class of deep-UV resists (1995) (0)
- Dehydrogenation and related reactions of alkanes catalyzed by pincerâ-iridium complexes (2011) (0)
- ISOMERIZATION OF 1,3,5-CYCLOOCTATRIENEIRON TRICARBONYL TO BICYCLO(4,2,0)OCTA-2,4-DIENEIRON TRICARBONYL (1973) (0)
- Chemitrends (2010) (0)
- Rhodium-catalyzed Olefindimierisierung. (1991) (0)
- SYNTHESIS OF 1,1′-BICOBALTOCENE SALTS OF TETRACYANO-P-QUINODIMETHANIDE AND THE STRUCTURE OF 1,1′-BICOBALTOCENE(COIIICOIII) TRIS(TETRACYANO-P-QUINODIMETHANIDE) (1982) (0)
- Dynamics of Agostic Complexes of the Type C5R5(C2H4)M(CH2CH2-μ-H)+. Energy Differences Between and Ancillary Ligand Control of Agostic and Terminal Hydride Structures. (1990) (0)
- ISOMERIZATION OF BICYCLO(5,1,0)-2,4-OCTADIENEIRON-TRICARBONYL TO BICYCLO(4,2,0)-2,4-OCTADIENEIRON-TRICARBONYL (1974) (0)
- Formation of Cp(CO)(PR3)FeCH(OCH3)C6H5 Complexes via PR3 Substitution Reactions, Hydride Addition to Cp(CO)(PR3)Fe=C(OCH3)C6H+ 5, and Methoxide Addition to Cp(CO)(PR3)Fe=CHC6H+ 5. Kinetic and Thermodynamic Diastereoselectivities. Rela (1989) (0)
- Investigation of the Stereochemistry of Fe-Cα Bond Cleavage When Phenylcyclopropane is Generated by γ-Ionization of Stereospecifically Deuterated C5H5(CO)2FeCHDCHDCH(OCH3)C6H5 Complexes. A Transition-State Model for Transfer of the Carbene Ligand from C5H5( CO)2Fe=CHR+ to Alkenes. (2010) (0)
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