Max Malacria
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French university professor and chemist
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Chemistry
Max Malacria's Degrees
- PhD Chemistry University of Strasbourg
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(Suggest an Edit or Addition)Max Malacria's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The behavior of 1,n-enynes in the presence of transition metals. (2002) (632)
- Transition metal catalyzed cycloisomerizations of 1,n-allenynes and -allenenes. (2011) (462)
- Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated- or Transition Metal-Catalyzed Cascade Reactions. (1996) (310)
- Synthesis and reactions of N-heterocyclic carbene boranes. (2011) (305)
- Molecular complexity from polyunsaturated substrates: the gold catalysis approach. (2014) (301)
- Recent progress in cobalt-mediated [2 + 2 + 2] cycloaddition reactions. (2006) (210)
- Golden carousel in catalysis: the cationic gold/propargylic ester cycle. (2008) (210)
- N-heterocyclic carbene boryl radicals: a new class of boron-centered radical. (2009) (202)
- Gold‐Catalyzed Cross‐Couplings: New Opportunities for CC Bond Formation (2010) (192)
- Recent advances in the use of phosphorus-centered radicals in organic chemistry. (2005) (191)
- Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor. (2008) (181)
- Generation and trapping of cyclopentenylidene gold species: four pathways to polycyclic compounds. (2009) (178)
- Chirality in Polyoxometalate Chemistry (2008) (175)
- Visible-light-induced photoreductive generation of radicals from epoxides and aziridines. (2011) (174)
- PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. (2004) (174)
- EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals. (2010) (168)
- Efficient preparation of functionalized hybrid organic/inorganic Wells-Dawson-type polyoxotungstates. (2005) (158)
- The effect of a hydroxy protecting group on the PtCl2-catalyzed cyclization of dienynes--a novel, efficient, and selective synthesis of carbocycles. (2002) (144)
- Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase CK2. (2008) (140)
- Lanthanide complexes of the monovacant Dawson polyoxotungstate [alpha1-P2W17O61]10- as selective and recoverable Lewis acid catalysts. (2006) (139)
- Of the ortho effect in palladium/norbornene-catalyzed reactions: a theoretical investigation. (2011) (139)
- Tandem gold(I)-catalyzed cyclization/electrophilic cyclopropanation of vinyl allenes. (2007) (127)
- Non‐Innocent Ligands: New Opportunities in Iron Catalysis (2012) (126)
- Cobalt-catalyzed cyclotrimerization of alkynes: the answer to the puzzle of parallel reaction pathways. (2007) (126)
- Generation and reactions of an unsubstituted N-heterocyclic carbene boryl anion. (2010) (122)
- Air-stable {(C5H5)Co} catalysts for [2+2+2] cycloadditions. (2009) (117)
- Au(I)-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene. (2006) (115)
- Intramolecular Reactions of Temporarily Silicon-Tethered Molecules (1997) (112)
- The role of bent acyclic allene gold complexes in axis-to-center chirality transfers. (2008) (105)
- Platinum dichloride-catalyzed cycloisomerization of ene-ynamides. (2004) (105)
- Gold- and platinum-catalyzed cycloisomerization of enynyl esters versus allenenyl esters: an experimental and theoretical study. (2009) (104)
- Gold(I)- and gold(III)-catalyzed cycloisomerization of allenynes: a remarkable halide effect. (2006) (104)
- Radical cyclization of N-acylcyanamides: total synthesis of luotonin A. (2007) (100)
- N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization (2010) (100)
- Oxidation of alkyl trifluoroborates: an opportunity for tin-free radical chemistry. (2010) (97)
- Substitution reactions at tetracoordinate boron: synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds. (2010) (96)
- From PtCl(2)- and acid-catalyzed to uncatalyzed cycloisomerization of 2-propargyl anilines: access to functionalized indoles. (2007) (94)
- Chiral recognition of hybrid metal oxide by peptides. (2009) (93)
- Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates. (2003) (92)
- Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes. (2010) (88)
- Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates. (2010) (86)
- Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes. (2011) (85)
- Tracking gold acetylides in gold(I)-catalyzed cycloisomerization reactions of enynes (2011) (84)
- Expeditious synthesis of phenanthridines from benzylamines via dual palladium catalysis. (2010) (82)
- Cobalt-mediated cyclic and linear 2:1 cooligomerization of alkynes with alkenes: a DFT study. (2006) (82)
- Silver and Brønsted acid catalyzed nazarov-type cyclizations to generate benzofulvenes. (2009) (80)
- Gold‐ vs. Platinum‐Catalyzed Polycyclizations by O‐Acyl Migration. Solvent‐Free Reactions (2008) (79)
- Gold-catalyzed 1,3-acyloxy migration/5-exo-dig cyclization/1,5-acyl migration of diynyl esters. (2011) (79)
- Alkyne versus allene activation in platinum- and gold-catalyzed cycloisomerization of hydroxylated 1,5-allenynes. (2008) (78)
- Regioselective activation of oxo ligands in functionalized dawson polyoxotungstates. (2008) (77)
- Palladium-catalyzed reaction of aryl iodides with ortho-bromoanilines and norbornene/norbornadiene: unexpected formation of dibenzoazepine derivatives. (2011) (75)
- PtCl 2-catalyzed cycloisomerizations of allenynes. (2004) (73)
- Exception to the ortho effect in palladium/norbornene catalysis. (2011) (72)
- Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions. (2010) (72)
- A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates. (2007) (69)
- Ionic and organometallic reductions with N-heterocyclic carbene boranes. (2009) (68)
- Radical synthesis of guanidines from N-acyl cyanamides. (2010) (68)
- Enantioselective Ir(I)-catalyzed carbocyclization of 1,6-enynes by the chiral counterion strategy. (2011) (67)
- Synthesis of aminopyridines and aminopyridones by cobalt-catalyzed [2+2+2] cycloadditions involving yne-ynamides: scope, limitations, and mechanistic insights. (2012) (65)
- New Cobalt-Catalyzed Cycloisomerization of epsilon-Acetylenic beta-Keto Esters. Application to a Powerful Cyclization Reactions Cascade. (1996) (65)
- Gold(I)-catalyzed cyclization of β-allenylhydrazones: an efficient synthesis of multisubstituted N-aminopyrroles. (2010) (64)
- Increased Lewis acidity in hafnium-substituted polyoxotungstates. (2007) (64)
- Generation of phosphorus-centered radicals via homolytic substitution at sulfur. (2007) (64)
- PtCl2-Catalyzed transannular cycloisomerization of 1,5-enynes: a new efficient regio- and stereocontrolled access to tricyclic derivatives. (2004) (63)
- Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical. (2010) (62)
- Regioselective cobalt-catalyzed formation of bicyclic 3- and 4-aminopyridines. (2011) (62)
- Synthesis of tricyclic fused 3-aminopyridines through intramolecular Co(I)-catalyzed [2+2+2] cycloaddition between ynamides, nitriles, and alkynes. (2009) (60)
- Radical migration of substituents of aryl groups on quinazolinones derived from N-acyl cyanamides. (2010) (59)
- Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox. (2009) (59)
- Radical cyclization cascade involving ynamides: an original access to nitrogen-containing heterocycles. (2003) (58)
- The Cyanamide Moiety, Synthesis and Reactivity (2012) (57)
- Production and reactions of organic-soluble lanthanide complexes of the monolacunary Dawson [alpha1-P2W17O61]10- polyoxotungstate. (2006) (57)
- BIOMIMETIC DIASTEREOSELECTIVE TOTAL SYNTHESIS OF EPI-ILLUDOL VIA A TRANSANNULAR RADICAL CYCLIZATIONS STRATEGY (1997) (56)
- Tandem Radical Reactions (2006) (56)
- Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes. (2011) (55)
- Synthesis of functionalized resorcinols by rhodium-catalyzed [5+1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO. (2010) (55)
- Radical cyclization of (bromomethyl)dimethylsilyl propargyl ethers. Regio-, chemo-, and stereoselectivity (1992) (54)
- Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes. (2010) (53)
- Rh-catalyzed [5+1] and [4+1] cycloaddition reactions of 1,4-enyne esters with CO: a shortcut to functionalized resorcinols and cyclopentenones. (2012) (53)
- A Water-Compatible NHC-Borane: Photopolymerizations in Water and Rate Constants for Elementary Radical Reactions. (2012) (53)
- Tandem PtCl2 catalyzed–thermal [3,3] rearrangements of enyne acetates (2004) (52)
- Sensing the chirality of Dawson lanthanide polyoxometalates [alpha1-LnP2W17O61]7- by multinuclear NMR spectroscopy. (2008) (52)
- Insertion of amides into a polyoxometalate. (2009) (51)
- Highly enantioselective rhodium-catalyzed [2+2+2] cycloaddition of diynes to sulfonimines. (2013) (51)
- Unprecedented aromatic homolytic substitutions and cyclization of amide-iminyl radicals: experimental and theoretical study. (2008) (51)
- N-Heterocyclic carbene-borane radicals as efficient initiating species of photopolymerization reactions under air (2011) (51)
- Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides. (2004) (50)
- Cobalt(I)-mediated preparation of polyborylated cyclohexadienes: scope, limitations, and mechanistic insight. (2007) (50)
- Diastereoselective synthesis of dibenzoazepines through chelation on palladium(IV) intermediates. (2014) (50)
- Totally chemo- and regioselective cobalt(I)-mediated formal intermolecular cyclotrimerization of alkynes. (2004) (50)
- Preparation of NHC borane complexes by Lewis base exchange with amine- and phosphine-boranes. (2010) (49)
- PtCl2- and PtCl4-catalyzed cycloisomerization of polyunsaturated precursors (2006) (47)
- Formation of cyclic sulfinates and sulfinamides through homolytic substitution at the sulfur atom. (2006) (46)
- Radical cascade cyclizations and platinum(II)-catalyzed cycloisomerizations of ynamides (2006) (46)
- Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst. (2012) (46)
- TIN-FREE RADICAL CHEMISTRY: INTRAMOLECULAR ADDITION OF ALKYL RADICALS TO ALDEHYDES AND KETONES (1999) (46)
- Cycloadditions, Cycloisomerizations and Related Reactions of Alkynes Bearing Group 13 or 14 Heteroelements (2005) (45)
- Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of pyridones and pyrazinones with alkynes: an experimental study. (2007) (45)
- Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes. (2005) (44)
- First examples of cobalt-mediated formal Alder ene reaction of allenynes (1996) (44)
- From Acyclic Precursors to Linear Triquinanes through a Diastereoselective One-Pot Process. A New Illustration of the Synthetic Power of Radical Cascades. (1998) (43)
- Alkynylboronates and ‐boramides in CoI‐ and RhI‐Catalyzed [2+2+2] Cycloadditions: Construction of Oligoaryls through Selective Suzuki Couplings (2011) (43)
- Synthesis, characterization, and structure of [GaCl3(NHC)] complexes (2007) (43)
- Synthesis of triangular tripalladium cations as noble-metal analogues of the cyclopropenyl cation. (2014) (42)
- Diastereoselective cobalt-mediated [2 + 2 + 2] cycloadditions of substituted linear enediynes phosphine oxides: scope and limitations. (2003) (41)
- Lanthanide polyoxocationic complexes: experimental and theoretical stability studies and Lewis acid catalysis. (2011) (41)
- A Straightforward Procedure for the [2+2+2] Cycloaddition of Enediynes (2009) (41)
- Cotrimerizations of Acetylenic Compounds (2007) (41)
- Silver-catalyzed cycloisomerization of 1,n-allenynamides. (2011) (40)
- The Chemistry of C2‐Symmetric Bis(sulfoxides): A New Approach in Asymmetric Synthesis (2002) (40)
- Transannular radical cascade as an approach to the diastereoselective synthesis of linear triquinane. (2002) (40)
- 5-Endo-Trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes. (1999) (39)
- Asymmetric Intramolecular Radical Vinylation Using Enantiopure Sulfoxides as Temporary Chiral Auxiliaries (1999) (39)
- Electrophilic activation of allenenes and allenynes: analogies and differences between Brønsted and Lewis acid activation. (2014) (39)
- Cobalt-mediated cycloisomerization of δ-substituted ε-acetylenic β-ketoesters construction of angular triquinane by a sequence ene/Pauson-Khand reactions (1999) (39)
- Assessing Ligand and Counterion Effects in the Noble Metal Catalyzed Cycloisomerization Reactions of 1,6-Allenynes: a Combined Experimental and Theoretical Approach (2016) (38)
- Synthesis of marmycin A and investigation into its cellular activity. (2015) (36)
- Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. (2002) (36)
- Intramolecular homolytic substitution of sulfinates and sulfinamides. (2009) (36)
- Titanium‐Mediated Domino Radical Cyclization/β Elimination of Phosphine Oxides (2004) (35)
- Radical Pd(III)/Pd(I) reductive elimination in palladium sequences. (2013) (33)
- Highly diastereoselective conjugate addition to alkylidene bis(sulfoxides): asymmetric synthesis of (+)-erythro-roccellic acid. (2003) (33)
- Self-buffering hybrid gold-polyoxometalate catalysts for the catalytic cyclization of acid-sensitive substrates. (2012) (33)
- 5-endo-trig Radical Cyclizations: A New Means to the Stereoselective Synthesis of Cyclopentanes and Diquinanes (1996) (33)
- Synthesis of variously substituted allenediynes and their cobalt (I)-mediated [2+2+2] cycloaddition reactions (1998) (32)
- Cobalt(I)-mediated [2 + 2 + 2] cyclization of allenediynes toward a diastereoselective approach to 11-aryl steroid skeletons. (2004) (32)
- Study of a Radical Cyclizations Cascade Leading to Bicyclo[3.1.1]heptanes. (1999) (30)
- Cobalt(I)-mediated cycloisomerization of enynes: mechanistic insights. (2001) (30)
- Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles (2011) (29)
- (Pentamethylcyclopentadienyl)Iridium Dichloride Dimer {[IrCp*Cl2]2}: A Novel Efficient Catalyst for the Cycloisomerizations of Homopropargylic Diols and N‐Tethered Enynes (2011) (29)
- The Role of Water in Platinum‐Catalyzed Cycloisomerization of 1,6‐Enynes: A Combined Experimental and Theoretical Gas Phase Study (2009) (29)
- New efficient construction of the ABC core of the taxoids via a sequence of consecutive cobalt(I)-mediated [2 + 2 + 2] and [4 + 2] cyclizations. (2002) (29)
- From an Acyclic, Polyunsaturated Precursor to the Polycyclic Taxane Ring System: The [4+2]/[2+2+2] and [2+2+2]/[4+2] Cyclization Strategies (2006) (28)
- Iodine(III)-mediated preparations of nitrogen-containing sulfur derivatives: dramatic influence of the sulfur oxidation state. (2004) (28)
- Convergent preparation of enantiomerically pure polyalkylated cyclopropane derivatives. (2008) (28)
- Cobalt-mediated linear 2:1 co-oligomerization of alkynes with enol ethers to give 1-alkoxy-1,3,5-trienes: a missing mode of reactivity. (2010) (27)
- Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system. (2013) (27)
- New and efficient procedure for the preparation of unsymmetrical silaketals. (2003) (27)
- Activation of allenes by gold complexes: a theoretical standpoint. (2011) (27)
- An Improved Protocol for the Synthesis of [(η4-C4R4)Co(η5-C5H5)] Complexes (2012) (27)
- Synthesis of Carbolines via Palladium/Carboxylic Acid Joint Catalysis. (2018) (27)
- Semi-Reduction of Internal Alkynes with Prototypical Subnanometric Metal Surfaces: Bridging Homogeneous and Heterogeneous Catalysis with Trinuclear All-Metal Aromatics (2017) (27)
- Intramolecular homolytic substitution at the sulfur atom: an alternative way to generate phosphorus- and sulfur-centered radicals (2008) (26)
- FROM VINYLALLENES TO KETONES OF THE DIHYDROJASMONE TYPE (1976) (26)
- A stereoselective route toward polyhydoxylated piperidines. A total synthesis of (+/-)-deoxymannojirimycin. (2005) (26)
- N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes. (2011) (26)
- Fixation of the two Tabun isomers in acetylcholinesterase: a QM/MM study. (2009) (26)
- Good to excellent diastereoselectivities in asymmetric radical cyclizations of optically pure β-alkoxy vinyl sulfoxides (1994) (26)
- Silicon-hydrogen bond activation and hydrosilylation of alkenes mediated by CpCo complexes: a theoretical study. (2009) (26)
- Lewis-acidic polyoxometalates as reusable catalysts for the synthesis of glucuronic acid esters under microwave irradiation. (2010) (26)
- A molecular approach to self-assembly of trimethylsilylacetylene derivatives on gold. (2003) (26)
- Radical Cyclization/β-Elimination Tandem Reactions: Enantiopure Sulfoxides as Temporary Chiral Auxiliaries. (1998) (26)
- Studies on diastereoselectivity of the cobalt(I) catalyzed cycloisomerization of substituted ε-acetylenic β-ketoester (1994) (24)
- Catalytic version of enediyne cobalt-mediated cycloaddition and selective access to unusual bicyclic trienes. (2013) (24)
- A new radical synthesis of allenes (1999) (24)
- Intramolecular [2+2+2] Cyclization of Triynes and Enediynes Catalyzed by CoI2‐Mn‐Phosphine Ligand (2001) (24)
- Cobalt-mediated cyclotrimerization and cycloisomerization reactions. Synthetic applications (1999) (24)
- Cobalt(I)-Mediated Intramolecular [2+2+2] Cocyclizations of (Methylenecyclopropyl)diynes as an Easy Access to Cyclopropanated Oligocycles (2005) (24)
- Use of ionic liquids in the platinum- and gold-catalyzed cycloisomerization of enyne systems (2009) (24)
- Novel reactivity of enynes in presence of cobalt (I) complexes (1996) (24)
- Ring Expansions Within the Gold‐Catalyzed Cycloisomerization of O‐Tethered 1,6‐Enynes. Application to the Synthesis of Natural‐Product‐like Macrocycles (2013) (24)
- Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides. (2007) (24)
- A New Rare Example of Cyclopropanation in Free-Radical Chemistry (1994) (23)
- Acyclic diastereofacial selection in radical addition (1991) (23)
- Cyclisation radicalaire des ethers propargyligues de (bromomethyl) dimethylsilyle (1986) (23)
- Stereospecific cobalt-mediated enediyne cyclization involving a tetrasubstituted double bond: one-step construction of the hydrophenanthrene nucleus incorporating two adjacent quaternary centers (1984) (22)
- New elements in the gold(I)-catalyzed cycloisomerization of enynyl ester derivatives embedding a cyclohexane template (2011) (22)
- Catalytic synthesis of sulfoximines using copper(II) salts (2002) (22)
- Palladium(0)-catalyzed rearrangement of silicon substituted vinyloxiranes. Enantiocontrolled preparation of α-tertiodutyldimethylsilyl-β,γ-unsaturated aldehydes. (1992) (22)
- Catalytic Semireduction of Internal Alkynes with All‐Metal Aromatic Complexes (2015) (22)
- Rearrangements of N-acyl isothioureas. Alternate access to acylguanidines from cyanamides. (2012) (22)
- Allenes as new partners in intramolecular cobalt-mediated [2+2+2] cycloaddition reactions (1994) (21)
- Highly stereoselective induction in the cobalt-mediated [2+2+2] cycloaddition of chiral phosphine oxides substituted linear enediynes (1999) (21)
- Alternative Routes to Tricyclic Cyclohexenes with Trinuclear Palladium Complexes (2018) (21)
- Palladium/norbornene catalytic system: chelation as a tool to control regioselectivity of Pd(IV) reductive elimination. (2013) (21)
- Unprecedented Radical Cyclizations Cascade Leading to Bicyclo[3.1.1]Heptanes. Toward a New Generation of Radical Cascades (1997) (21)
- Stereoselective access to the basic skeleton of tetracyclic diterpenes via a sequence of consecutive [3 + 2], [2 + 2 + 2], and [4 + +2] cycloaddition reactions (1993) (21)
- Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides (2005) (21)
- Silver mediated acetylenic oxy cope rearrangement (1986) (21)
- Asymmetric induction in the palladium catalyzed [3+2] cycloaddition reaction of trimethylenemethane with homochiral vinylsulfoxides (1989) (20)
- Stereoselective additions of silicon centered radical to α-chiral olefins: A Felkin-Anh stereoelectronic control. (1992) (20)
- Synthesis of natural quinazolinones and some of their analogues through radical cascade reactions involving N-acylcyanamides (2013) (20)
- Radical cyclization of bromomethyldimethylsilyl propargyl ethers; synthesis of a carbocyclic core of steroid skeleton by a tandem radical cyclization (1994) (20)
- Radical cyclization of bromomethyldimethylsilyl propargyl ethers—VIII. Bimolecular stereoselective hydrogen abstraction by trisubstituted vinyl radicals. A new example of rare (1,4) hydrogen transfer. (1992) (20)
- Carbonyl-inserted organo-hybrids of a Dawson-type phosphovanadotungstate: scope and chemoselective oxidation catalysis. (2011) (20)
- New elements in the reactivity of α-cyclopropyl vinyl radicals (2002) (20)
- A NEW CYCLIZATION REACTIONS CASCADE:ENE TYPE, 2+2+2, 4+2. STEREOSELECTIVE FORMATION OF SIX CARBON-CARBON BONDS AND FOUR RINGS IN A ONE-POT SEQUENCE (1995) (20)
- Unusual reactivity of acetate versus carbonate in palladium-catalyzed nucleophilic substitutions: A strong silicon effect (1996) (20)
- Chemo- and stereoselective palladium-catalyzed allylic alkylations controlled by silicon. (2003) (19)
- Improvement of the diastereoselectivity of the cobalt-mediated [2+2+2] cycloaddition of substituted linear enediynes (1999) (19)
- Water dissociation on alpha1-hafnium and ytterbium substituted Dawson polyoxotungstates: a density functional theory study. (2008) (19)
- A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics. (2015) (19)
- Intramolecular anion effect in polyoxometalate-based organocatalysts: reactivity enhancement and chirality transfer by a metal oxide-organic cation interaction. (2014) (19)
- Homolytic reduction of onium salts. (2012) (19)
- Diastereoselective approach to 11-aryl steroid skeletons through a cobalt(I)-mediated [2+2+2] cyclization of allenediynes (2006) (19)
- Stereocontrolled synthesis of α-trialkylsilyl-β, γ-unsaturated aldehydes via palladium (0) catalysis. Synthetic usefulness (1996) (19)
- Boosting catalyst activity in cis-selective semi-reduction of internal alkynes by tailoring the assembly of all-metal aromatic tri-palladium complexes. (2016) (18)
- First Example of a Total Axial to Centered Chirality Transfer in the [2 + 2 + 2] Cycloadditions of Allenediynes (2000) (18)
- A new practical one-pot access to sulfonimidates. (2002) (18)
- Diastereoselective synthesis of enantiopure acyclic beta,beta'-disubstituted vinylsulfoxides. (2008) (17)
- Formal base-free homolytic aromatic substitutions via photoredox catalysis (2015) (17)
- Synthesis of Nitrogen-Containing Heterocycles via Ring-Closing Ene-Ene and Ene-Yne Metathesis Reactions: An Easy Access to 1- and 2-Benzazepine Scaffolds and Five- and Six-Membered Lactams (2012) (17)
- Silylated pyrrolidones via diastereoselective Pd-catalysed intramolecular allylic alkylations (2001) (16)
- Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of alpha,omega-diynes. (2008) (16)
- Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo[n.3.0]derivatives (1997) (16)
- Radical β-Elimination of a Sulfinyl Group to Afford Allenes (2002) (16)
- Gold Compounds Anchored to a Metalated Arene Scaffold: Synthesis, X-ray Molecular Structures, and Cycloisomerization of Enyne (2013) (15)
- CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF3 and BH3 (2010) (15)
- Stereoselective addition of nucleophiles on α-trialkylsilyl-β,γ-unsaturated aldehydes (1995) (15)
- Radical cyclization of (bromomethyl) dimethylsilyl propargyl ethers regioselective intramolecular cyclization of vinyl radicals (1990) (15)
- Co(I)- versus Ru(II)-Catalyzed [2+2+2] cycloadditions involving alkynyl halides (2011) (15)
- Improved method for the iodine(III)-mediated preparation of aryl sulfonimidates. (2006) (15)
- Gold-Catalyzed Polymerization Based on Carbene Polycyclopropanation (2014) (15)
- N-Silyl-Tethered Radical Cyclizations: A New Synthesis of γ-Amino Alcohols (2003) (15)
- Silicon effect favoring the formation of a cyclopentene via palladium-catalyzed 5-endo-trig cyclisation (1998) (14)
- Stereoselective lithiation of α,β-epoxy-γ,δ-vinylsilanes and transformation into α-silylated ketones (2003) (14)
- Design of a radical translocation step through 1, n (n = 5, 6, 7) hydrogen transfers for incorporation into new radical cascades (1997) (14)
- Efficient Preparation of a Highly Strained Eleven‐Membered Ring (2000) (14)
- Stereocontrolled rearrangement of silylated vinyloxiranes into α-trialkylsilyl-β,γ-unsaturated aldehydes (1997) (13)
- Oxidation of alpha-alkoxy allenes into alpha'-alkoxy enones. (2010) (13)
- Reactivity of beta-lactamido N-sulfonyl radicals. (2004) (13)
- Reversal of the Diastereoselectivity in a Sequence of Cycloaddition Reactions: [2+2+2], Ene Type, [4+2]. A Totally Stereoselective Access to the Basic Skeleton of the Kaurane Family. (1996) (13)
- Photoepoxidation of vinylallenes (1979) (13)
- Enantiopure alkylidene-1,1-bis-p-tolylsulfoxides as new partners in diastereoselective radical cyclizations (2003) (13)
- The [4+2], [2+2] strategy for the construction of the AB taxane ring system (1998) (12)
- Reactivity of the lithium anion of the (S,S)-bis-p-tolylsulfinyl methane. A versatile synthesis of enantiopure alkylidene 1,1-bis-p-tolylsulfoxides (2002) (12)
- Variations on radical cascades of vinyl radicals generated from bromomethyldimethylsilyl propargyl ethers (1996) (12)
- Total chirality transfer in palladium(O)-catalyzed rearrangement of silicon substituted vinyloxiranes (1995) (12)
- Polycyclic Compounds via Radical Cascade Reactions (2008) (12)
- Synthesis of a linear benzo[3]phenylene–[60]fullerene dyad (2005) (12)
- Regio- and stereoselective palladium(0)-catalyzed alkylation of vinyloxiranes with non-stabilized lithium ester enolates nucleophiles. A direct access to highly functionalized allylic alcohols (1998) (12)
- New Cobalt Catalyzed Cycloisomerization of β-Ketoester ε-Acetylenic (1994) (12)
- INTRAMOLECULAR ADDITION OF VINYL RADICALS TO ALDEHYDES (1998) (12)
- A stereoselective synthesis of silylated epoxycyclopentanols bearing four contiguous stereogenic centers (2004) (12)
- Compared Behaviors of trans- and cis-α,β-Epoxy-γ,δ-vinyl-silanes Towards Nucleophiles and Bases: High Regioselective Ring Opening and Deprotonation (2002) (11)
- Synthetic approach to aphidicolan and stemodan basic skeletons using a “Tandem Principle” [2+2+2] and [4+2] cycloaddition reactions (1994) (11)
- Vinylallenes IX. - preparation de quelques tetraenes-1,2,4,6 (1979) (11)
- Visible‐Light, Photoredox‐Mediated Oxidative Tandem Nitroso‐Diels–Alder Reaction of Arylhydroxylamines with Conjugated Dienes (2017) (11)
- Chemoselectivity of the intramolecular radical addition between triple and double bond. (1991) (11)
- A stereoselective access to the basic skeleton of phyllocladane type diterpenes: [3+2], [2+2+2], and [4+2] cycloaddition (1989) (11)
- Pd Catalysis in Cyanide-Free Synthesis of Nitriles from Haloarenes via Isoxazolines. (2016) (11)
- Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids (2019) (11)
- One-Pot Diastereoselective Preparation of α,β-Unsaturated-γ-Silylated-δ-Lactones: Application towards Natural Compounds (2001) (10)
- Silylated Vinyloxiranes – Recent Advances and Synthetic Applications (2006) (10)
- Diastereoselective Preparation of Silylated Pyrrolidones through Palladium-Catalysed Cyclisations (2003) (10)
- Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions. (2007) (10)
- Visible-Light-Promoted Polycyclizations of Dienynes. (2019) (10)
- Metalated-Arene-Phosphino Ligands: A Novel Approach to Open-Sided Gold Compounds (2010) (10)
- N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. (2013) (9)
- Study of the Diastereoselectivity of Cobalt-Mediated [2+2+2] Cycloadditions of Substituted Linear Enediyne Esters (2001) (9)
- Radical Cyclization of Bromomethyldimethylsilyl Propargyl Ethers. Diastereoselective Synthesis of Functionalized Cyclopentanone Precursors via a (1,5) Hydrogen-Atom Transfer. (1994) (9)
- Palladium-catalyzed intramolecular cyclization of vinyloxirane regioselective formation of cyclobutanol derivative (1995) (9)
- Gold-catalyzed cycloisomerization of [3]-cumulenols (2015) (9)
- COUNTER-ION EFFECT IN THE PALLADIUM (0) CATALYZED DOUBLE ALLYLATION OF A 1,5-DINUCLEOPHILE. A NOVEL EIGHT-MEMBERED RING SYNTHESIS (1995) (9)
- New developments in radical chemistry. Applications to total synthesis and asymmetric processes (2000) (9)
- Cobalt-mediated [2+2+2] cycloaddition versus C-H and N-H activation of 2-pyridones and pyrazinones with alkynes: a theoretical study. (2007) (9)
- Titanocene-mediated homolytic opening of epoxysilanes (2006) (9)
- Complexes of Borane and N‐Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor. (2008) (9)
- Radical Cyclization of (Bromomethyl)dimethylsilyl Propargyl Ethers; VI. Serial Radical Cyclizations Leading to a Stereoselective Synthesis of Functionalized Diquinane Framework from an Acyclic Substrate1 (1990) (9)
- The silicon effect on the regioselectivity of the Tsuji-Trost reaction. Experimental and theoretical approaches (2003) (9)
- Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study. (2011) (9)
- An Unusual Anion–π Interaction in an ;rido Organometallic Assembly: Synthesis, First Crystal Structure, and Computational Study (2009) (8)
- Towards the Synthesis of 3‐Silapiperidines (2009) (8)
- Highly stereoselective generation of α-pyrones displaying four contiguous stereogenic centers (2002) (8)
- A Short and Efficient Preparation of 2-Trimethylsilylmethyl-2-propen-1-ol (1989) (8)
- Bis-sulfoxides as ligands for platinum complexes (2010) (8)
- Recent Advances in the Use of Phosphorus‐Centered Radicals in Organic Chemistry (2006) (8)
- Transition Metal‐Assisted Transformations of Diversely Functionalized Dienynes (2003) (7)
- Selective transformations of differently functionalized 4-ethynyl-octa-1,7-dienes and 5-ethynyl-nona-1,8-dienes via intramolecular Pauson–Khand reaction: preparation of new and useful building blocks for the synthesis of angularly fused triquinanes (2002) (7)
- Complex Polycyclic Molecules from Acyclic Precursors via Transition Metal Catalyzed Cascade Reactions (2007) (7)
- A New Enantioselective Synthesis of Highly Functionalized Cyclopentanols (1998) (7)
- Radical Cascade Reactions (2012) (7)
- Bi-directional alkyne tandem isomerization via Pd(0)/carboxylic acid joint catalysis: expedient access to 1,3-dienes. (2018) (7)
- Cumulenes and allenes (2008) (6)
- Reactivity of the TMM Entity in the Cyclopentene Series − Observation of a Reversed Regioselectivity in Palladium‐Catalyzed [3+2] Cycloadditions (2001) (6)
- A Synthetic Study towards the Marmycins and Analogues (2016) (6)
- Gold‐Catalyzed Cross‐Couplings: New Opportunities for C—C Bond Formation (2010) (6)
- First Tandem Radical Cyclization/Intramolecular Diels-Alder Reaction (1994) (6)
- Thermal Intramolecular Alder-Ene Cycloisomerization of 1,6-Allenynes (2008) (6)
- Reaction of Lithio Derivatives of Allenes with Butadiene Monoxide (1979) (6)
- Regioselective Double Organic Functionalization of Polyoxotungstates through Electrophilic Addition of Aromatic Isocyanates to [P2W17O61(SnR)]7–† (2013) (6)
- SN2′ Reactions between Lithiated Carbon Nucleophiles and Silylated Vinyloxiranes – Effects of Salts and Solvents on the Stereocontrol (2006) (6)
- From PtCl2- and Acid-Catalyzed to Uncatalyzed Cycloisomerization of 2-Propargyl Anilines: Access to Functionalized Indoles. (2007) (5)
- Conjugate additions to alkylidene bis(sulfoxides). (2011) (5)
- The Cyanamide Moiety: Synthesis and Reactivity (2012) (5)
- Cyclopentadienyl Ligands as Perfect Anion Receptors: Teamwork between π-Anion Interaction and C−H···Anion Hydrogen Bonds (2009) (5)
- C–C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Catalyzed by Group 8–11 Metals (2007) (5)
- Radical Cyclization of Bromomethyldimethylsilyl Propargyl Ethers; a General Method for the Stereoselective Synthesis of Variously Substituted Trimethylenemethane (TMM) Precursors (1994) (5)
- Orthogonal Syntheses of 3.2.0 Bicycles from Enallenes Promoted by Visible Light (2020) (5)
- Synthesis of a new versatile dienophile and its use in a highly diastereoselective Diels-Alder reaction (1999) (5)
- Copper-Catalyzed N-Arylation of Sulfonimidamides. (2011) (5)
- Synthesis of Variously Substituted Spirobenzocyclobutenes (1998) (5)
- Substituent Effects in NHC–Boranes: Reactivity Switch in the Nucleophilic Fluorination of NHC–Boranes (2013) (4)
- Effect of propargylic substitution on the 5-endo-trig cyclization of bromomethyldimethylsilyl propargyl ethers (2008) (4)
- Radical Cyclization of (Bromomethyl)dimethylsilyl Propargyl Ethers; III. Stereoselective Hydrogen Abstraction of Trisubstituted Vinyl Radicals. Application to a Terpenoid Building Block Synthesis1 (1991) (4)
- Gold(I)‐ and Gold(III)‐Catalyzed Cycloisomerization of Allenynes: A Remarkable Halide Effect. (2007) (4)
- Copper-Catalyzed N-Arylationof Sulfonimidamides (2011) (4)
- A Silicon‐Position Dependent 6‐endo‐trig Cyclization During Tsuji—Trost Alkylation. (2013) (4)
- Advanced Green Chemistry: Part 1: Greener Organic Reactions and Processes (2018) (4)
- NHC-Catalyzed Chemo- and RegioselectiveHydrosilylation of Carbonyl Derivatives (2012) (4)
- Platinum(II) Chloride Catalyzed Cycloisomerizations of 1,5-Enynes (2007) (4)
- Transition Metal Mediated [2+2+2] Cycloadditions (2010) (3)
- Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated‐ or Transition Metal‐Catalyzed Cascade Reactions (1996) (3)
- C‐I Selective Sonogashira and Heck Coupling Reactions Catalyzed by Aromatic Triangular Tri‐palladium (2022) (3)
- New Elements on the Behaviour of a Bissulfinylmethyl Radical (2013) (3)
- Photoelectric properties of aromatic triangular tri-palladium complexes and their catalytic applications in the Suzuki-Miyaura coupling reaction. (2021) (3)
- Gold(I)‐Catalyzed Cyclization of β‐Allenylhydrazones: An Efficient Synthesis of Multisubstituted N‐Aminopyrroles. (2011) (3)
- Novel synthesis of chiral allenyl sulfoxides and their potential use in asymmetric reactions (1992) (3)
- Addition of bis-sulfinyl anions to ketones : Stereoselective synthesis of allylic alcohols through evans-mislow rearrangement based domino reactions (2007) (3)
- Cover Picture: Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle (Angew. Chem. Int. Ed. 4/2008) (2008) (3)
- Cobalt-Mediated [2+2+2] Cycloaddition of Alkynyl Boronates to Indole and Pyrrole Double Bonds (2008) (3)
- Enantioselective Synthesis of Deoxymannojirimycin Based on Sharpless Asymmetric Epoxidation of a Highly Functionalized Allylic Alcohol (2011) (3)
- Selective ring opening of silylated vinyloxiranes and reactivity of azido-alcohols (2007) (3)
- Carbon—Heteroatom Bond Formation (2001) (3)
- New Advances in Radical Cascades Based on the Use of Vinyl Radicals (2000) (3)
- Synthesis and Reactions of N-Heterocyclic Carbene Boranes (2012) (3)
- The Behavior of 1,n‐Enynes in the Presence of Transition Metals (2002) (3)
- Synthesis of Orthogonally ProtectedAngular Nitrogen Polyheterocycles via CpCo-Catalyzed Pyridine Formation (2010) (3)
- Main‐Group Elements in Radical Chemistry (2012) (3)
- One-Pot Diastereoselective Preparation of α,β-Unsaturated-γ-silylated-δ-lactones: Application Towards Natural Compounds. (2001) (2)
- Is Aromaticity a Driving Force in Catalytic Cycles? A Case from the Cycloisomerization of Enynes Catalyzed by All-Metal Aromatic Pd3+ Clusters and Carboxylic Acids. (2021) (2)
- Two-fold tandem acyl-group shift/cyclization via gold catalysis (2014) (2)
- 5‐endo‐trig Radical Cyclizations: A New Means to the Stereoselective Synthesis of Cyclopentanes and Diquinanes. (1996) (2)
- New Advances in Bis(Sulfoxides) Chemistry (2013) (2)
- Intramolecular Reactions of Temporarily Silicon‐Tethered Molecules (1998) (2)
- AuI‐Catalyzed Cycloisomerization of 1,5‐Enynes Bearing a Propargylic Acetate: Formation of Unexpected Bicyclo[3.1.0]hexene. (2006) (2)
- Radikalcyclisierungs/β‐Eliminierungs‐Dominoreaktionen: enantiomerenreine Sulfoxide als temporäre chirale Auxiliare (1998) (2)
- Diastereoselective thiol conjugate addition on δ-alkylated-γ-silylated-α,β-unsaturated-δ-lactones (2002) (2)
- New Cobalt-Catalyzed Cycloisomerization of .epsilon.-Acetylenic β- Keto Esters. Application to a Powerful Cyclization Reactions Cascade. (1996) (2)
- Radical Cyclization Cascade Involving Ynamides: An Original Access to Nitrogen‐Containing Heterocycles. (2004) (2)
- Alkynylboronates and -boramides in CoI- and RhI-Catalyzed [2 + 2 + 2] Cycloadditions: Construction of Oligoaryls Through Selective Suzuki Couplings. (2011) (2)
- Alkyne versus Allene Activation in Platinum- and Gold-Catalyzed Cycloisomerization of Hydroxylated 1,5-Allenynes. (2008) (2)
- Probing the Amino-End Reactivity of Sulfonimidamides. (2009) (2)
- Probing the Amino-End Reactivityof Sulfonimidamides (2008) (2)
- S N -opening of allylic epoxides by vinylic-type organometallic derivatives (1985) (2)
- LIGAND EFFECTS IN PALLADIUM(0)-CATALYZED REARRANGEMENT OF A SILICON SUBSTITUTED VINYLOXIRANE (1995) (2)
- Stereoselective Access to the Basic Skeleton of Tetracyclic Diterpenes via a Sequence of Consecutive [3+2], [2+2+2], and [4+2] Cycloaddition Reactions. Studies on the Stereoselectivity of the Intramolecular Diels-Alder Reaction (1990) (2)
- Advanced Green Chemistry (2020) (2)
- Inside Cover: Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion (Angew. Chem. Int. Ed. 48/2010) (2010) (2)
- NHC-Catalyzed Chemo- and Regioselective Hydrosilylation of Carbonyl Derivatives. (2012) (2)
- Stereoselective transition metal-catalyzed and radical polycyclizations. (2002) (2)
- Diastereoselective bicyclization of enynols via gold catalysis (2019) (2)
- Innentitelbild: The Role of Bent Acyclic Allene Gold Complexes in Axis‐to‐Center Chirality Transfers (Angew. Chem. 39/2008) (2008) (2)
- Intramolecular homolytic substitution of seleninates: a computational study (2012) (2)
- Compared Behaviors of trans- and cis-α,β-Epoxy-γ,δ-vinyl-silanes Towards Nucleophiles and Bases: High Regioselective Ring Opening and Deprotonation. (2002) (1)
- A Radical Versatile Synthesis of 2-Iodomethylene Cycloalkanols (2000) (1)
- Molecular Complexity from Polyunsaturated Substrates: The Gold Catalysis Approach (2014) (1)
- Chapter 6 Towards the syntheses of natural protoilludanes and linear triquinanes from cycloundecadienynes (2004) (1)
- Catalytic Cycloaddition Reactions (2014) (1)
- Cobalt(III) Complexes (2001) (1)
- The Tsuji–Trost Reaction and Related Carbon–Carbon Bond Formation Reactions: Palladium‐Catalyzed Substitution Reactions of Alkenyl Epoxides (2003) (1)
- From Cobalt(III) Complexes (2001) (1)
- PtCl2‐ and PtCl4‐Catalyzed Cycloisomerization of Polyunsaturated Precursors. (2007) (1)
- Highly diastereoselective michael additions onto dienyl bis-sulfoxides (2005) (1)
- Tandem PtCl2 Catalyzed—Thermal [3,3] Rearrangements of Enyne Acetates. (2005) (1)
- Addition of Bis-sulfinyl Anions to Ketones: Stereoselective Synthesis of Allylic Alcohols Through Evans—Mislow Rearrangement Based Domino Reactions. (2007) (1)
- Gold‐Catalyzed 1,3‐Acyloxy Migration/5‐exo‐dig Cyclization/1,5‐Acyl Migration of Diynyl Esters. (2011) (1)
- Synthesis of Nitrogen-Containing Heterocycles via Ring-Closing Ene—Ene and Ene—Yne Metathesis Reactions: An Easy Access to 1- and 2-Benzazepine Scaffolds and Five- and Six-Membered Lactams. (2013) (1)
- A Stereoselective Route Toward Polyhydroxylated Piperidines. A Total Synthesis of (.+-.)-Deoxymannojirimycin. (2006) (1)
- Reactivity of Silylated Vinyloxiranes and Silyl Butene Diols with Palladium(0) (2004) (1)
- A Straightforward Procedure for the [2 + 2 + 2] Cycloaddition of Enediynes. (2009) (1)
- Synthesis of fused arylboronic esters via cobalt(0)-mediated cycloaddition of alkynylboronates with alpha,omega-diynes. (2004) (1)
- Synthesis of Variously Substituted Allenediynes and Their Cobalt(I)-Mediated [2 + 2 + 2] Cycloaddition Reactions. (1998) (1)
- Innentitelbild: Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion (Angew. Chem. 48/2010) (2010) (1)
- An Unusual Anion–π Interaction in an ;rido Organometallic Assembly: Synthesis, First Crystal Structure, and Computational Study (Eur. J. Inorg. Chem. 25/2009) (2009) (1)
- Titanocene‐Mediated Intramolecular Radical Vinylations. (2005) (1)
- [m+n+2]‐Carbocyclization Reactions (2011) (1)
- Cover Picture: A Molecular Approach to Self‐Assembly of Trimethylsilylacetylene Derivatives on Gold (Chem. Eur. J. 11/2003) (2003) (1)
- Radical Cascade Cyclizations and Platinum(II)‐Catalyzed Cycloisomerizations of Ynamides. (2006) (1)
- Radical cyclisation of bromomethyldimethylsilyl propynyl ethers; serial radical cyclisations leading to a hydrindene framework from an acyclic substrate, stereoselectively (1994) (1)
- trans‐1,3‐Dithiolane 1,3‐dioxide (2004) (1)
- Homolytic Reduction of Onium Salts (2012) (1)
- Photoredox Catalysis, an Opportunity for Sustainable Radical Chemistry (2020) (1)
- Control of Diastereoselectivity (2011) (1)
- Cyclopentadienylcobalt-Mediated Intermolecular Cycloaddition of α,ω-Diynes to (Cyclo)alkenes: Synthesis of Linearly Fused Oligocycles and Extension to Enantiomerically Pure (6aR,10aR)-Dihydroanthracyclinones (2010) (1)
- Chlorotris(triphenylphosphine)cobalt(I) (2001) (1)
- Synthesis of Butenolides (2001) (1)
- Reactivity of β‐Lactamido N‐Sulfonyl Radicals. (2004) (1)
- Titelbild: Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle (Angew. Chem. 4/2008) (2008) (1)
- Synthesis of Aminopyridines and Aminopyridones by Cobalt-Catalyzed [2 + 2 + 2] Cycloadditions Involving Yne-Ynamides: Scope, Limitations, and Mechanistic Insights. (2012) (1)
- Structure of dimethyl (±)‐1,2,3,4,4aα,4b,9,10‐octahydro‐6,7‐bis(trimethylsilyl)‐2β,10aβ‐ethanophenanthrene‐12,12‐dicarboxylate (1990) (1)
- Platinum Dichloride Catalyzed Cycloisomerization of Ene-ynamides. (2004) (1)
- Titanium-mediated domino radical cyclization/beta elimination of phosphine oxides. (2004) (1)
- Visible-Light Promoted Intramolecular para-Cycloadditions on Simple Aromatics. (2023) (1)
- Organometallic Complexes of Cobalt (2003) (1)
- Suzuki—Miyaura Coupling of NHC—Boranes: A New Addition to the C—C Coupling Toolbox. (2010) (1)
- Catalytic Synthesis of Sulfoximines Using Copper(II) Salts. (2010) (1)
- Enolate conjugate addition to alkylidene bis-sulfoxides : Sphaeric acid synthesis and absolute configuration determination (2006) (1)
- Stereocontrolled Synthesis of α-Trialkylsilyl-β,γ- unsaturated Aldehydes via Palladium(0) Catalysis. Synthetic Usefulness. (1996) (1)
- Towards the Synthesis of 3-Silapiperidines. (2009) (1)
- Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion. (2011) (1)
- Visible‐Light‐Promoted Polycyclizations of Dienynes (2019) (1)
- Gold-Catalyzed Cycloisomerization (2009) (1)
- GOLD-CATALYZED REACTIONS OF PROPARGYLIC ESTERS (2014) (1)
- Synthesis of 4:5‐Benzo‐1‐cobalta‐2‐silacyclopentenes and Their Reactions with Alkynes and Alkenes: An Expedient Route to Silicon‐Containing Polycyclic Frameworks. (2007) (1)
- Asymmetric Intramolecular Radical Vinylation Using Enantiopure Sulfoxides as Temporary Chiral Auxiliaries. (2010) (1)
- Synthesis via β-Hydroxyallylphosphonate Derivatives Prepared from Ketenes or Ketene Equivalents (2008) (0)
- Regioselective Intramolecular Cyclization of Vinyl Radicals. (1991) (0)
- Elimination from β-Sulfinylallyl Alcohol Derivatives (2008) (0)
- Back Cover: Visible‐Light, Photoredox‐Mediated Oxidative Tandem Nitroso‐Diels–Alder Reaction of Arylhydroxylamines with Conjugated Dienes (Eur. J. Org. Chem. 15/2017) (2017) (0)
- Radical Cyclization of Bromomethyldimethylsilyl Propargyl Ethers. Diasteroselective Synthesis of Functionalized Cyclopentane Precursors via a (1,5) Hydrogen‐Atom Transfer. (1995) (0)
- Cobalt–Allyl Complexes (2001) (0)
- Rh‐Catalyzed [5 + 1] and [4 + 1] Cycloaddition Reactions of 1,4‐Enyne Esters with CO: A Shortcut to Functionalized Resorcinols and Cyclopentenones. (2012) (0)
- Baylis–Hillman-Type Reaction of Alkenylphosphorus Compounds with Aldehydes (2008) (0)
- Via Elimination of Alkali Metal Cyclopentadienide (2001) (0)
- Radical cyclization of homopropargylic bromomethyldimethylsilyl ethers. Evidence for a hetero-trans-cycloheptene intermediate (2001) (0)
- Silver Mediated Acetylenic Oxy Cope Rearrangement. (1986) (0)
- Allylcobalt Complexes by Ligand Exchange (2001) (0)
- Cobalt-Mediated Cyclotrimerization and Cycloisomerization Reactions: Synthetic Applications (2000) (0)
- REACTIVITY OF 1,2,5-TRIENES TOWARDS PERACIDS. II. SYNTHESIS OF BICYCLO(3.1.0)HEXAN-2-ONES. INFLUENCE OF THE NATURE OF THE SOLVENT ON THEIR FORMATION (1976) (0)
- Cocyclization of Dienynes with Alkynes (2011) (0)
- Intramolecular Cyclotrimerization of Chiral Triynes (2011) (0)
- Six-Membered Rings by [2 + 2 + 2] Cycloaddition (2009) (0)
- Synthesis of 1,3‐Dienes by Metal‐Mediated C—C Bond‐Forming Reactions of Alkynes, Diynes, and Enynes (2012) (0)
- Iron‐Catalyzed Reductive Radical Cyclization of Organic Halides in the Presence of NaBH4: Evidence of an Active Hydrido Iron(I) Catalyst. (2012) (0)
- A Stereoselective Synthesis of Silylated Epoxycyclopentanols Bearing four Contiguous Stereogenic Centers. (2005) (0)
- Ruthenium(II)-Mediated [2 + 2 + 2] Carbocyclizations (2011) (0)
- Carbocyclization of Acetylene and Aryl-Substituted Monoynes Bearing Phosphoryl Moieties (2011) (0)
- N-silyl-tethered radical cyclizations: a new synthesis of gamma-amino alcohols. (2003) (0)
- Chemo‐ and Stereoselective Palladium‐Catalyzed Allylic Alkylations Controlled by Silicon. (2003) (0)
- Cyclotrimerization of Internal Alkynes (2011) (0)
- Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes or Diynes (2011) (0)
- Palladium-Catalyzed Cycloisomerization To Give Vinylcyclopentenes (2009) (0)
- Cocyclization of 1,7-Diynes and Internal Alkynes (2011) (0)
- Cocyclization of Alkenyl Isocyanates and Terminal Alkynes (2011) (0)
- Bis(alkene)(cyclopentadienyl)cobalt(I) Complexes by Ligand Exchange (2001) (0)
- Using Acid Chlorides (2008) (0)
- Codimerization Reaction between 1,3-Dienes and Alkynes (2009) (0)
- Silver‐Catalyzed Cycloisomerization of 1,n‐Allenynamides. (2011) (0)
- A New Radical Synthesis of Allenes. (1999) (0)
- Stereochemistry in the Opening of Allyl Epoxides by Alkynyl Borates. (1986) (0)
- Tris(acetylacetonato)cobalt(III) as a Precatalyst (2001) (0)
- Cocarbocyclization of 1,6-Diynes with -Alkenes (2011) (0)
- Elimination from Vinyl Sulfoxides and Vinyl Sulfones (2008) (0)
- Syntheses Catalyzed by Cobalt(II) Complexes (2001) (0)
- Oxidation with 3-Chloroperoxybenzoic Acid (2008) (0)
- 1,3-Dienes Having Endocyclic and Exocyclic Double Bonds (2009) (0)
- Carbocyclization of 1,7-Diynes with Nitriles (2011) (0)
- Cocyclizations between η-Allyliridium Complexes and Alkynes (2011) (0)
- Elimination from Phenyl Vinyl Selenoxides (2008) (0)
- STEREOCONTROLLED SYNTHESIS OF ALPHA -TRIALKYLSILYL-BETA -GAMMA -UNSATURATED ALDEHYDES VIA PALLADIUM (0) CATALYSIS, SYNTHETIC USEFULNESS (1996) (0)
- Intramolecular Homolytic Substitution at the Sulfur Atom: An Alternative Way to Generate Phosphorus‐ and Sulfur‐Centered Radicals. (2009) (0)
- Inside Back Cover: A Simple Synthesis of Triangular All‐Metal Aromatics Allowing Access to Isolobal All‐Metal Heteroaromatics (Chem. Eur. J. 35/2015) (2015) (0)
- Diels–Alder Reaction with 2-Cobaloxime-Substituted 1,3-Dienes (2001) (0)
- Carbocyclization of 1,6-Enynes and Alkynes (2011) (0)
- Synthesis via Alkenyltitanocene Derivatives (2008) (0)
- Bimolecular Cocyclization of Diynes and Acetylene (2011) (0)
- Cyclization of Diynes (2009) (0)
- Cobalt(I)-Mediated [2 + 2 + 2] Carbocyclizations (2011) (0)
- (μ-Alkyne)hexacarbonyldicobalt(0) Complexes by Ligand Exchange (2001) (0)
- Cobalt-Mediated [2 + 2 + 2] Cycloaddition of Alkynyl Boronates to Indole and Pyrrole Double Bonds. (2008) (0)
- Silicon Effect Favoring the Formation of a Cyclopentene via Palladium-Catalyzed 5-endo-trig Cyclization. (1999) (0)
- Cobalt-Mediated Cycloisomerization of δ-Substituted ε-Acetylenic β-Ketoesters. Construction of Angular Triquinane by a Sequence Ene/Pauson—Khand Reactions. (1999) (0)
- Elimination from 1,1-Disubstituted Cyclopropane Derivatives (2008) (0)
- Synthetic Approach to Aphidicolan and Stemodan Basic Skeletons Using a “Tandem Principle” (2 + 2 + 2) and (4 + 2) Cycloaddition Reactions. (1994) (0)
- VINYLALLENES. VI. SYNTHESIS OF KETONES OF THE JASMONE SERIES (1978) (0)
- Ruthenium-Catalyzed Dimerization of Propargyl Alcohols (2009) (0)
- Dehydrosilylation of Silyl Enol Ethers (2008) (0)
- Method for preparing marmycin A and analogs thereof, and also uses thereof as antibiotics, anticancer, and antimalarials agents (2016) (0)
- OXY-COPE REARRANGEMENT ASSISTED BY MERCURIC TRIFLUOROACETATE IN STOICHIOMETRIC AND CATALYTIC QUANTITIES (1985) (0)
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- SN-OPENING OF ALLYLIC EPOXIDES BY VINYLIC-TYPE ORGANOMETALLIC DERIVATIVES (1985) (0)
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- ChemInform Abstract: New Elements in the Reactivity of α-Cyclopropyl Vinyl Radicals. (2002) (0)
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- Tin-Free Radical Chemistry: Intramolecular Addition of Alkyl Radicals to Aldehydes and Ketones. (1999) (0)
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- Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) (2001) (0)
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- Cocyclization of Enynes with Buta-1,3-dienes (2011) (0)
- Synthesis via Alkenylidenemagnesium Intermediates (2008) (0)
- Rearrangement of 1-(Alk-1-ynyl)cyclopropanols (2001) (0)
- Cobalt-Mediated Linear 2:1 Cooligomerization of Alkynes with Enol Ethers to Give 1-Alkoxy-1,3,5-trienes: A Missing Mode of Reactivity. (2010) (0)
- Formal Base‐Free Homolytic Aromatic Substitutions via Photoredox Catalysis. (2015) (0)
- From Nonactivated Substrates (2008) (0)
- Cobalt-Mediated Syntheses of Alkaloids and Steroids (2009) (0)
- Carbocyclization of Tertiary Propargylic Alcohols, Bispropargylic Alcohols, and Dialkynylphosphine Oxides with 1,6-Diyne Esters (2011) (0)
- Cobalt–Dienyl Complexes (2001) (0)
- Study of the Diastereoselectivity of Cobalt-Mediated [2 + 2 + 2] Cycloadditions of Substituted Linear Enediyne Esters. (2002) (0)
- Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo(n.3.0)derivatives. (1997) (0)
- REACTIVITY OF 1,2,5-TRIENES TOWARDS PERACIDS. I. SYNTHESIS OF 1,2,5-TRIENES (1976) (0)
- Ruthenium-Catalyzed Cycloaddition (2009) (0)
- Nickel-Catalyzed Cycloaddition (2009) (0)
- Allylcobalt Complexes by Hydridocobaltation of 1,3-Dienes (2001) (0)
- Hydrocyanation of Dienes (2001) (0)
- Inside Cover: Ring Expansions Within the Gold‐Catalyzed Cycloisomerization of O‐Tethered 1,6‐Enynes. Application to the Synthesis of Natural‐Product‐like Macrocycles (ChemCatChem 5/2013) (2013) (0)
- Cobalt(II)-Mediated Aerobic Oxygenation of Alkenes (2001) (0)
- Cobalt(II) Complexes as Precatalysts (2001) (0)
- Cocyclization of Enedienes with Alkynes (2011) (0)
- Nickel-Catalyzed Aldehyde–Alkyne Coupling (2009) (0)
- Pd-Catalyzed Sequential Reactions Involving C–H Bond Activation: A Green and Sustainable Tool for Natural and Industrial Product Synthesis (2020) (0)
- Intramolecular Cyclotrimerization of Allenediynes (2011) (0)
- Synthesis of Phenanthridines via Palladium/NorborneneCatalysis (2011) (0)
- OXY‐COPE REARRANGEMENT OF 5‐HEXEN‐1‐YN‐3‐OL AIDED BY SILVER TRIFLATE (1984) (0)
- Diastereoselective Preparation of Silylated Pyrrolidones Through Palladium‐Catalyzed Cyclizations. (2003) (0)
- Coupling of Alkynes (2009) (0)
- Cover Picture: Iodine(III)‐Mediated Preparations of Nitrogen‐Containing Sulfur Derivatives: Dramatic Influence of the Sulfur Oxidation State (Chem. Eur. J. 4/2004) (2004) (0)
- Alkynylboronates and -boramides in CoI- and RhI-Catalyzed [2+2+2] Cycloadditions: Construction of Oligoaryls through Selective Suzuki Couplings (Eur. J. Org. Chem. 18/2011) (2011) (0)
- Nickel-Catalyzed Cyclization of Diynes (2009) (0)
- Oxidative Addition of Nickel(0) with Allylic Electrophiles (2001) (0)
- Intramolecular Addition of Vinyl Radicals to Aldehydes. (1998) (0)
- Metalation of Ferrocene Complexes (2001) (0)
- Asymmetric Elimination Using Sharpless Oxidation (2008) (0)
- Six-Membered Rings by Cycloisomerization of 1,5-Enynes (2009) (0)
- Elimination from Vinyl- and Allylmetal Intermediates (2008) (0)
- Ruthenium(II)-Mediated [3 + 2 + 2]-Carbocyclization Reactions (2011) (0)
- Reactivity of NBS towards N-allyl glycinyl derivatives (2003) (0)
- Conjugated Vinylic Cycloalkenes (2009) (0)
- Cocyclizations between Alk-6-enylidenecyclopropanes and Activated Alkynes (2011) (0)
- Platinum- and Gold-Catalyzed Cycloisomerization To Give Vinylcycloalkenes (2009) (0)
- Cocyclization of Chromium Fischer Carbene Complexes with Terminal Alkynes (2011) (0)
- Unprecedented Aromatic Homolytic Substitutions and Cyclization of Amide—Iminyl Radicals: Experimental and Theoretical Study. (2008) (0)
- REACTION OF 1,5-HEXADIEN-3-OLS WITH MERCURY TRIFLUOROACETATE. OXY-COPE REARRANGEMENT AT AMBIENT TEMPERATURE (1983) (0)
- A New Enantioselective Synthesis of Highly Functionalized Cyclopentanols. (1999) (0)
- Homo-Diels–Alder Reactions (2001) (0)
- Palladium(0)-Catalyzed Rearrangement of Silicon Substituted Vinyloxiranes. Enantiocontrolled Preparation of α- Tertiobutyldimethylsilyl β,γ-Unsaturated Aldehydes. (1992) (0)
- Allylcobalt Complexes by Addition of Alkyl- and Acylcobalt Complexes to Conjugated Dienes and Various Unsaturated Compounds (2001) (0)
- Cyclization of Allenynes (2009) (0)
- Cocyclization between 1,6-Diynes and Activated Alkenes (2011) (0)
- Cobalt-Mediated Ene–Yne Cyclizations (2001) (0)
- Double Alkenation Using Titanium-Substituted Ylides (2008) (0)
- Unusual Reactivity of Acetate versus Carbonate in Palladium‐Catalyzed Nucleophilic Substitutions: A Strong Silicon Effect. (1997) (0)
- Vinylzirconium and Vinyltitanium Intermediates from Propargyl Ethers and Propargyl Bromides (2008) (0)
- Titanium-Promoted Cyclization of Diynes (2009) (0)
- Dehalogenation of 2,3-Dihalopropenes and Deoxyhalogenation of β-Haloallyl Alcohol Derivatives (2008) (0)
- Transfer of Cyclopentadienyliron (2001) (0)
- Cocyclization between Norbornadiene and Activated Alkenes (2011) (0)
- 1,4-Dialkylation of Dienes (2001) (0)
- Using Tributyltin Hydride (2008) (0)
- 5‐Endo‐trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes. (1999) (0)
- C—C Bond Formation by Addition (2001) (0)
- Studies Towards the Stereoselective Synthesis of Polyquinane Frameworks from Acyclic Precursors via Radical Cyclizations (1999) (0)
- Chemistry and Durable Development. Towards Ecocompatible Organic Chemistry (2010) (0)
- Bis(alkene)(η-cyclopentadienyl)cobalt(I) Complexes by Reduction of Cobalt(II) Complexes (2001) (0)
- Increased Lewis Acidity in Hafnium‐Substituted Polyoxotungstates. (2007) (0)
- Modification of Substituents on Ferrocene Complexes (2001) (0)
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