Michael F. Lappert
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British chemist
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Chemistry
Michael F. Lappert's Degrees
- PhD Chemistry University of Oxford
- Bachelors Chemistry University of Oxford
Why Is Michael F. Lappert Influential?
(Suggest an Edit or Addition)According to Wikipedia, Michael Franz Lappert was a Czech-born British inorganic chemist. Mainly located at the University of Sussex, he was recognized for contributions to organometallic complexes. Early life and education Lappert was born in Czechoslovakia and came to the UK as a Kindertransport refugee. He received his PhD in 1951 at the Northern Polytechnic, London.
Michael F. Lappert's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The Chemistry of -Diketiminatometal Complexes (2002) (753)
- Transition metal-carbene complexes (1972) (401)
- Subvalent Group 4B metal alkyls and amides. Part I. The synthesis and physical properties of kinetically stable bis[bis(trimethysilyl)methyl]-germanium(II), -tin(II), and -lead(II) (1976) (254)
- Metal .sigma.-hydrocarbyls, MRn. Stoichiometry, structures, stabilities, and thermal decomposition pathways (1976) (242)
- Synthesis of bis[bis(trimethylsilyl)amido]iron(II). Structure and bonding in M[N(SiMe3)2]2 (M = manganese, iron, cobalt): two-coordinate transition-metal amides (1988) (226)
- The coordination chemistry of electron-rich alkenes (enetetramines) (1988) (201)
- Chemistry of thermally stable bis(amino)silylenes (2001) (192)
- Monomeric, volatile bivalent amides of group IVB elements, M(NR12)2 and M(NR1R2)2(MGe, Sn, or Pb; R1Me3Si, R2Me3C) (1974) (191)
- Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured SnII and PbII alkyls, M[CH(SiMe3)2]2 (1973) (178)
- Structure and reactivity of sterically hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li{N(SiMe3)2}(OEt2)]2 and tetrakis(2,2,6,6-tetramethylpiperidinatolithium) (1983) (177)
- Stable silylmethyl and neopentyl complexes of scandium(III) and yttrium(III) (1973) (177)
- Lanthanum does form stable molecular compounds in the +2 oxidation state. (2008) (176)
- The role of group 14 element carbene analogues in transition metal chemistry (1990) (173)
- A new synthesis of divalent group 4B alkyls M[CH(SiMe3)2]2(M = Ge or Sn), and the crystal and molecular and molecular strcuture of the tin compound (1976) (173)
- Self-assembly of interpenetrating coordination nets formed from interpenetrating cationic and anionic three-dimensional diamondoid cluster coordination polymers. (2004) (149)
- Subvalent Group 4B metal alkyls and amides. Part 5. The synthesis and physical properties of thermally stable amides of germanium(II), tin(II), and lead(II) (1977) (148)
- Synthesis, structures and reactions of new thermally stable silylenes. (1996) (141)
- A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)] (1987) (137)
- Synthesis and Structure of a rac‐Tris(divinyldisiloxane) diplatinum(0) Complex and its Reaction with Maleic Anhydride (1991) (134)
- Metal Amide Chemistry (2009) (123)
- Synthesis and structural characterisation of the first neutral homoleptic lanthanide metal(III) alkyls: [LnR3][Ln = La or Sm, R = CH(SiMe3)2] (1988) (119)
- Subvalent Group 4B Metal Alkyls and Amides. Part 9. Germanium and Tin Alkene Analogues, the Dimetallenes M2R4 (M: Ge or Sn, R: CH(SiMe3)2): X-Ray Structures, Molecular Orbital Calculations for M2H4, and Trends in the Series M2R′4 (M: (1987) (116)
- Bivalent germanium, tin, and lead 2,6-di-tert-butylphenoxides and the crystal and molecular structures of M(OC6H2Me-4-But2-2,6)2 (M = Ge or Sn) (1980) (115)
- Chemistry of organo-zirconium and -hafnium compounds (1986) (112)
- Principles and Applications of Organotransition Metal Chemistry (1987) (109)
- Homogeneous catalysis: VIII. Carbene-transition-metal complexes as hydrosilylation catalysts (1984) (108)
- Three- and four-co-ordinate, hydrocarbon-soluble-aryloxides of scandium, yttrium, and the lanthanoids; X-ray crystal structure of tris(2,6-di-t-butyl-4-methylphenoxo)scandium (1983) (108)
- Carbene complexes. Part 12. Electron-rich olefin-derived neutral mono- and bis-(carbene) complexes of low-oxidation-state manganese, iron, cobalt, nickel, and ruthenium (1978) (102)
- The chemistry of transition-metal carbene complexes and their role as reaction intermediates (1973) (102)
- Amino derivatives of metals and metalloids (1965) (99)
- Contributions to the chemistry of carbenemetal chemistry (2005) (96)
- Bridged hydrocarbyl or hydrocarbon binuclear transition metal complexes: classification, structures, and chemistry (1983) (96)
- Spontaneous generation of stable pnictinyl radicals from "jack-in-the-box" dipnictines: a solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization. (2001) (94)
- Molecular structures of the main group 4 metal(II) bis(trimethylsilyl)-amides M[N(SiMe3)2]2 in the crystal (X-ray) and vapour (gas-phase electron diffraction) (1983) (92)
- The coordination chemistry of bivalent group IV donors (1975) (91)
- A 1,3-diaza-2,4-distannacyclobutanediide: synthesis, structure, and bonding. (2004) (89)
- SILYLENENICKEL(0) OR SILYL(SILYLENE)PLATINUM(II) COMPLEXES BY REACTION OF SI(NCH2BUT)2C6H4-1,2 WITH NICL2(PPH3)2, NI(COD)2, OR PTCL2(PPH3)2 (1998) (88)
- Chloroboration and allied reactions of unsaturated compounds II. Haloboration and phenylboration of acetylenes; and the preparation of some alkynylboranes (1964) (88)
- Organometallic Complexes with Silicon-Transition Metal or Silicon-Carbon-Transition Metal Bonds (1973) (87)
- Lithium and sodium 2,6-di-tert-butylphenoxides and the crystal and molecular structure of [Li(OC6H2Me-4-But2-2,6)(OEt2)]2 (1980) (87)
- Synthesis, structures and oxidative addition reactions of new thermally stable silylenes; crystal structures of chelates [Si{N(CH2tBu)}2C6H4-1,2] and [(Si{N(CH2tBu)}2C6H4-1,2)(m-E)]2 (E = Se or Te). (1996) (85)
- Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2] (1991) (83)
- Metallocene halides. Part I. Synthesis, spectra, and redistribution equilibria of di-π-cyclopentadienyldihalogeno-titanium(IV),-zirconium-(IV), and -hafnium(IV) (1969) (82)
- Applied homogeneous catalysis with organometallic compounds, Vols. 1 and 2, B. Cornils, W.A. Herrmann (Eds.). VCH, London (1996) (1997) (82)
- STABLE HOMOLEPTIC METAL ALKYLS (1974) (81)
- Synthesis and Characterisation of N,N′‐Disubstituted 1,2‐phenylenebis(amido)tin(II) Compounds; X‐Ray structures of 1,2‐ and of [1,2‐ (tmeda) (1995) (81)
- Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box (2000) (81)
- Higher-nuclearity group 14 metalloid clusters: [Sn(9){Sn(NRR')}(6)]. (2006) (80)
- Crystalline (NN)C–M(NN) complexes: synthesis, structure, bonding and lability [M = Si, Ge, Sn or Pb; (NN) = 1,2-(ButCH2N)2C6H4] (2000) (79)
- Recent studies on metal and metalloid bis(trimethylsilyl)methyls and the transformation of the bis(trimethylsilyl)methyl into the azaallyl and β-diketinimato ligands (1995) (79)
- Subvalent Group 4B metal alkyls and amides. Part 8. Germanium and tin carbene analogues MR2[M = Ge or Sn, R = CH(SiMe3)2]: syntheses and structures in the gas phase (electron diffraction); molecular-orbital calculations for MH2 and GeMe2 (1986) (78)
- Bulky alkyls, amides, and aryloxides of main Group 5 elements. Part 1. Persistent phosphinyl and arsinyl radicals ·MRR′ and their chloroprecursors MRR′Cl and related compounds (1980) (78)
- Alkyl-bridged complexes of the d- and f-block elements. Part 2. Bis[bis(η-cyclopentadienyl)methylmetal(III)] complexes, and the crystal and molecular structure of the yttrium and ytterbium species (1979) (76)
- Insertion Reactions of Compounds of Metals and Metalloids Involving Unsaturated Substrates (1967) (75)
- Neutral and anionic silylmethyl complexes of the Group 3a and lanthanoid metals; the X-ray crystal and molecular structure of [Li(thf)4][Yb{CH(SiMe3)2}3Cl](thf = tetrahydrofuran) (1978) (74)
- “Dibutylmagnesium”, a convenient reagent for the synthesis of useful organic magnesium reagents MgA2 including cyclopentadienyls, aryloxides, and amides. Preparation of Zr(C5H5)Cl3. X-ray structure of [{μ-N(SiMe)3C6H4N}(SiMe3)-o(OEt2)]2 (1985) (73)
- Carbene complexes. Part VIII. Chromium(0), iron(0), rhodium(I), iridium(I), nickel(II), palladium(II), platinum(II), and gold(I) mono- and oligo-carbene species from electron-rich olefins (1974) (73)
- Subvalent Group 4B metal alkyls and amides. Part II. The chemistry and properties of bis[bis(trimethylsilyl)methyl]tin(II) and its lead analogue (1976) (71)
- γ Agostic C–H or β agostic Si–C bonds in La{CH(SiMe3)2}3? A DFT study of the role of the ligand (2003) (70)
- 103. Co-ordination compounds having carboxylic esters as ligands. Part II. Relative acceptor strengths of some Group III and IV halides (1962) (70)
- Amido-derivatives of metals and metalloids. Part X. Reactions of titanium(IV), zirconium(IV), and hafnium(IV) amides with unsaturated substrates, and some related experiments with amides of boron, silicon, germanium, and tin(IV) (1970) (69)
- Bonding studies of compounds of boron and the group IV element (1971) (68)
- CARBENE COMPLEXES. XXIV: PREPARATION AND CHARACTERIZATION OF TWO ENETETRAMINE-DERIVED CARBENERHODIUM(I) CHLORIDE COMPLEXES RHCL(LR)3 AND RHCL(COD)LR L R=DCN(ME)CU(CH)4CNME-O AND THE PREPARATION AND X-RAY STRUCTURES OF THE ENET ETRAMINE L2R AND ITS SALT L2RBF42 (1994) (68)
- The first high resolution direct NMR observation of an f-block element (1989) (67)
- A crystalline carbene–silylene adduct 1,2-C6H4[N(R)]2C-Si[N(R)]2C6H4-1,2 (R = CH2But); synthesis, structure and bonding in model compounds† (1999) (67)
- Synthesis and P-P cleavage reactions of [P(X)X']2; X-ray structures of [Co[P(X)X'](CO)3] and P4[P(X)X']2[X = N(SiMe3)2, X'= NPri2]. (2004) (66)
- Synthesis and characterisation of bis(amino)silylene–nickel(0), –palladium(II), –platinum(0), –platinum(II) and copper(I) complexes (2003) (66)
- Chemical Shift Tensors and NICS Calculations for Stable Silylenes (1998) (66)
- Alkyl-bridged complexes of the d- and f-block elements. Part 1. Di-µ-alkyl-bis(η-cyclopentadienyl)metal(III)dialkylaluminium(III) complexes and the crystal and molecular structure of the ytterbium methyl species (1979) (65)
- Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states (1987) (63)
- Homogeneous Catalysis Part II. Ziegler Systems as Catalysts for Hydrosilylation (1974) (63)
- Free Radicals in Organometallic Chemistry (1976) (63)
- Tris(2,6-di-t-butylphenoxo)yttrium: a three-coordinate hydrocarbon-soluble aryloxide of yttrium (1987) (62)
- The first stable transition metal (molybdenum or tungsten) complexes having a metal–phosphorus(III) double bond: the phosphorus analogues of metal aryl- and alkyl-imides; X-ray structure of [Mo(η-C5H5)2(PAr)](Ar = C6H2But3-2,4,6) (1987) (62)
- Chemistry, including the X-ray structure, of bis[bis(trimethylsilyl)methylgermanium(II)], R2GeGeR2[R = CH(SiMe3)2], a stable compound having a metal–metal ‘double bond,’ a dimetallene (1984) (62)
- Transformation of the bis(trimethylsilyl)methyl into a β-diketinimato ligand; the X-ray structure of [Li(L′L′)]2, SnCl(Me)2(L′L′) and SnCl(Me)2(LL), [L′L′= N(R)C(Ph)C(H)C(Ph)NR, LL = N(H)C(Ph)C(H)C(Ph)NH, R = SiMe3) (1994) (61)
- Carbene complexes: XX. Electron-rich carbeneiron(0) trigonal bipyramidal carbonyls and their germanium(II) and tin(II) analogues [Fe(CO)3(L)(L′)] (L = CN(Me)(CH2)2NMe, L′ = PEt3, 3 CO's equatorial; or L = M(OAr)2 (equatorial: M = Ge OR Sn, Ar = C6H2But2-2,6-Me-4), L′ = CO) (1986) (59)
- Comprehensive chemical kinetics. Volume 20 complex catalytic processess (1979) (59)
- Subvalent group 14 metal compounds XIV. The X-ray crystal structures of two monomeric group 14 metal bisamides, Ge[N(SiMe3)2]2 and Sn[Me2]2 (1992) (59)
- An electron-rich olefin as a source of co-ordinated carbene; synthesis of trans-PtCl2[C(NPhCH2)2]PEt3 (1971) (58)
- Regular papersCarbene complexes: XXIV2. Preparation and characterization of two enetetramine-derived carbenerhodium(I) chloride complexes RhCl(LR)3 and [RhCl(COD)LR] and the preparation and X-ray structures of the enetetramine L2R and its salt [L2R][BF4]2 (1994) (58)
- Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates (2004) (58)
- Mono-, di-, and Ttianionic beta-diketiminato ligands: a computational study and the synthesis and structure of [(YbL)(3)(THF)], L = [[N(SiMe(3))C(Ph)](2)CH]. (2003) (57)
- Amido-derivatives of metals and metalloids. Part VI. Reactions of titanium(IV), zirconium(IV), and hafnium(IV) amides with protic compounds (1968) (57)
- Reactions of LiCHR2 and related lithium alkyls with α-H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and β-diketiminates (2000) (55)
- Crystalline amidocerium(IV) oxides and a side-on bridging dioxygen complex. (2010) (55)
- Transformation of the bis(trimethylsilyl)methyl into a 1,3-diaza-allyl ligand. Synthesis and crystal structures of [] and [{UCl(μ-Cl)(L)(NR)}2][UCl2(L)(L′)]2[R = SiMe3; Ar = C6Me2-2,5; L = ; L′ = ] (1995) (55)
- Subvalent group 4B metal alkyls and amides. Part 7. Transition-metal chemistry of metal(II) bis(trimethylsilyl)amides M′(NR2)2(R = SiMe3; M′= Ge, Sn, or Pb) (1985) (54)
- Carbene complexes. XIX: Optically active electron-rich olefin-derived carbene-transition-metal complexes ― Crystal structures of [RhCl(COD)(C7H12N2)], [RhCl(COD)(C9H16N2)], [RhCl(PPh3)2(C9H18N2)] and [Co(CO)(NO)(PPh3)(C6H12N2)] (1985) (53)
- [Th(III)[.eta.5-C5H3(SiMe3)2]3], an actinide compound with a 6d1 ground state (1988) (53)
- Amido derivatives of metals and metalloids XII. Further reactions with protic compounds (1970) (53)
- Transformation of the bis(trimethylsilyl)methyl into aza-allyl and β-diketinimato ligands; the X-ray structures of [Li{N(R)C(But)CH(R)}]2 and [Zr{N(R)C(But)CHC(Ph)N(R)}Cl3](R = SiMe3) (1994) (52)
- Reactions Of Boron Trichloride With Organic Compounds (1958) (52)
- Synthesis, structures and reactions of ytterbium(II) alkyls (1994) (52)
- 481. Infrared spectra of boron compounds (1958) (52)
- Chemistry of bulky alkoxides of bivalent germanium and tin; structures of gaseous [Sn(OBut)2]2 and crystalline Ge(OCBut3)2 (1985) (52)
- Synthesis and structures of 1,3,1′,3′-tetrabenzyl-2,2′-biimidazolidinylidenes (electron-rich alkenes), their aminal intermediates and their degradation products (1998) (52)
- Bis(trimethylsilyl)phosphidometal complexes (1987) (51)
- Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2] (1995) (51)
- Silylmethyl and related complexes II. Preparation, spectra, and thermolysis of the tetraneopentyls of titanium, zirconium, and hafnium (1973) (51)
- Rhodium(I)-catalysed dismutation of electron-rich olefins: rhodium(I) carbene complexes as intermediates (1972) (51)
- Oxidation in nonclassical organolanthanide chemistry: synthesis, characterization, and X-ray crystal structures of cerium(III) and -(IV) amides. (2004) (51)
- Synthesis, characterisation and alkylation reactions of lanthanideβ-diketiminates; crystal structures of[Nd(L–L)2Cl] and[Ce(L–L)(CHR2)2][L–L = N(R)C(Ph)C(H)C(Ph)NR,R = SiMe3] (1997) (50)
- Synthesis and structures of crystalline bis(trimethylsilyl)methanido complexes of potassium, calcium and ytterbium (2002) (50)
- Nonclassical Organolanthanoid Metal Chemistry: [K([18]-crown-6)(η2-PhMe)2]X (X = [(LnCpt3)2(μ-H)], [(LnCp‘ ‘2)2(μ-η6:η6-PhMe)]) from [LnCpx3], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cpt = η5-C5H4SiMe2But; Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3) (2000) (50)
- Subvalent group 14 metal compounds XI. Oxidative addition reactions of organic halides or acid anhydrides (including CH4 − nCln, PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to some bivalent group 14 metal amides or alkyls (1987) (50)
- The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure (1986) (49)
- New reactions of β-diketiminatolanthanoid complexes: sterically induced self-deprotonation of β-diketiminato ligands (2005) (49)
- Synthesis and characterisation of two monomeric crystalline thallium(I)β-diketiminates (2005) (49)
- Reactions of Li- and Yb-coordinated N,N'-bis(trimethylsilyl)-beta-diketiminates: one- and two-electron reductions, deprotonation, and C-N bond cleavage. (2004) (49)
- The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8) (1990) (49)
- Structures of the radical P[N(SiMe3)2](NPri2), its dimer, cation and chloro derivative. (2004) (48)
- Cerium masquerading as a group 4 element: synthesis, structure and computational characterisation of [CeCl(N(SiMe3)2)3]. (2001) (48)
- Triaryl-silyl, -germyl, and -stannyl radicals .MAr3 (M = Si, Ge, or Sn and Ar = 2,4,6-Me3C6H2) and .Ge(2,6-Me2C6H3)3: Synthesis and ESR studies (1980) (48)
- Standard heats of formation and M–C bond energy terms for some homoleptic transition metal alkyls MRn (1975) (47)
- The first neutral, mononuclear 4f metal thiolates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amides (1992) (47)
- 352. Amino-derivatives of metals and metalloids. Part I. Preparation of aminostannanes, stannylamines, and stannazanes (1965) (46)
- The first examples of intermolecular weak (agostic) γ-methyl-metal interactions in organolanthanide complexes: The synthesis and X-ray structures of [{Yb(η-CP″)2}∞.] and [{Eu(η-CP″)2}∞] [CP″ C5H3(SiMe3)2-1,3] (1992) (46)
- Synthesis and electron spin resonance study of stable dialkyls and diamides of phosphorus and arsenic, R12M· and (R22N)2M· (1976) (45)
- A novel carbon dioxide complex: synthesis and crystal structure of [Nb(η-C5H4Me)2(CH2SiMe3)(η2-CO2)] (1981) (45)
- 174. Co-ordination compounds having carboxylic esters as ligands. Part I. Stoicheiometry, structure, and stereochemistry (1961) (45)
- Stabilisation of transition metals in a low coordinative environment using the bis(trimethylsilyl)methyl ligand; a monomeric CrIII alkyl, Cr[CH(SiMe3)2]3, and related complexes (1974) (43)
- Synthesis of a Stable Biphenyl‐Bis(carbene) and ‐Bis(silylene) [M{(NCH2But)2C6H3‐3,4}]2 (M = C or Si) (2005) (43)
- Carbene complexes. Part I. Electron-rich olefins as a source of carbene complexes of platinum(II) and palladium(II); and some experiments with (CF3)2CN2 (1973) (43)
- Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu) (2001) (43)
- X-ray structure of a derivative of the “simplest metallocene: Cyclopentadienyllithium”, [Li{;η-C5H4(SiMe3)};{;NMe2(CH2)2NMe2};] (i.e., LiCp′(TMEDA)) (1984) (43)
- New Reactions of a Silylene: Insertion into MN Bonds of M[N(SiMe3)2]2 (M Ge, Sn, or Pb) (1997) (43)
- Use of the bis(trimethylsilyl)cyclopentadienyl ligand for stabilising early (f0–f3) lanthanocene chlorides; X-ray structure of [(Pr{η-[C5H3(SiMe3)2]}2Cl)2] and of isoleptic scandium and ytterbium complexes (1981) (43)
- The first monomeric crystalline tin(II) alkyls; X-ray structures of the β-N-functionalised alkyls Sn(R)X [R̄= C̄(SiMe3)2C5H4N–2 and X̄= R̄, Cl̄, or N̄(SiMe3)2] (1988) (42)
- A general synthesis of transition-metal carbene complexes: Cr0, Fe0, IrI, NiII, PdII, PtII, and AuI mono- and oligo-carbene species from electron-rich olefins (1973) (42)
- Synthesis of homoleptic tris(organo-chelate)iridium(III) complexes by spontaneous ortho-metallation of electronrich olefin-derived N,N′-diarylcarbene ligands and the X-ray structures of fac-[6H3Me-p}3] and mer-6H3Me-p}2 {C6H4Me-p}Cl (a product of HCl cleavage) ☆ (1982) (42)
- Facile formation of a homoleptic Ce(IV) amide via aerobic oxidation. (2006) (42)
- Routes to optically active electron-rich olefins (L*2 and some derived carbenemetal complexes; x-ray structures of [Co(CO)(L*)(NO(PPh3)] and cis-[Rh(Cl)(COD)(L′*)][L*= (S)-Me, (1983) (41)
- Metal (Li, GeII, GeIII, SnII, and PbII) 2,6-dialkylbenzenethiolates; X-ray crystal structures of Sn(SAr)2(Ar = C6H2But3-2,4,6) and [M(SAr′)2]3(M = Sn or Pb, Ar′= C6H3Pri2-2,6) (1983) (41)
- Carbene complexes. Part 11. Steric and conformational effects upon the transition-metal reactivity of electron-rich olefins and derived species; heteroatom-donor-olefin–metal (Cr0, Mo0, W0, or RhI) and 2-imidazoline-N-donor–metal complexes, and the crystal and molecular structure of tetracarbonyl[NN (1977) (41)
- RECENT ADVANCES IN THE CHEMISTRY OF BIVALENT ORGANIC COMPOUNDS OF GERMANIUM, TIN AND LEAD (1995) (41)
- Synthesis and characterisation of unusual tetraaminoalkenes (enetetramines) (1992) (41)
- Tris[bis(trimethylsilyl)methyl]tin(III), R3Sn·: an unusually stable stannyl radical, from photolysis of R2Sn (1973) (40)
- Subvalent Group 4B metal alkyls and amides. Part 4. An electron spin resonance study of some long-lived photochemically synthesised trisubstituted silyl, germyl, and stannyl radicals (1976) (40)
- Carbene complexes. Part 18. Synthetic routes to electron-rich olefin-derived monocarbenerhodium(I) neutral and cationic complexes and their chemical and physical properties (1984) (40)
- Heteroleptic ytterbium(II) complexes supported by a bulky beta-diketiminato ligand. (2009) (40)
- Aspects of non-classical organolanthanide chemistry (2002) (39)
- Silylmethyl and related complexes. Part I. Kinetically stable alkyls of titanium(IV), zirconium(IV), and hafnium(IV) (1973) (39)
- Bonding studies of compounds of Group 3–5 elements. Part XVIII. He(I) photoelectron spectra of bivalent homoleptic alkyls and amides, especially of Group 4 elements, and of tin(II) chloride and bromide (1976) (39)
- Carbene complexes. Part 9. Electron-rich olefin-derived carbene–molybdenum(0) and amidinium molybdate(0) complexes, and the crystal and molecular structure of cis-tetracarbonylbis(1,3-dimethylimidazolidin-2-ylidene)molybdenum(0), cis-[Mo(CO)4{CN(Me)CH2CH2NMe}2] (1977) (38)
- First identification by EPR spectra of lanthanum(ii) organometallicintermediates (and E½ forLa3+ → La2+) in theC–O bond activation of dimethoxyethane (1997) (38)
- Synthesis and structures of selected benzamidinates of Li, Na, Al, Zr and Sn(II) using the C1-symmetric ligands [N(SiMe3)C(C6H4Me-4 or Ph)NPh]-. (2007) (38)
- Co-ordination chemistry of heavy-atom group IV donors, and the crystal and molecular structure of [(Me3Si)2CH]2SnCr(CO)5 (1974) (38)
- Carbene complexes: XXIII. Preparation, characterisation, and structures of the enetetramine-derived carbenerhodium(I) chloride complexes [RhCl(LR)3],trans-[RhCl(CO)(L2R′)], and [{RhCl(COD)}2{μ-L2(323)R}] [L2R or R′ = CN(R or R′)(CH2)2NR(or R′) (R CH2)Ph or Et, R′ Me) and L(323)R CN(R)(CH2)3N(CH2)2N( (1993) (38)
- The novel, chelating C, N-bidentate 2,6-bis(dimethylamino)phenylligand (R-), showing ambidentate N,N′-character inM(R)2 (M = Ge, Sn, Pb) and Sn(R)X [X =N(SiMe3)2, CH(SiMe3)2,Cl] (1997) (38)
- The role of the transition metal in the homogeneous catalytic polymerisation of strained organosilicon heterocycles (1972) (38)
- Synthesis and structures of the ytterbium(II) β-diketiminates [Yb{N(SiMe3)C(R2)C(H)C(R4)N(SiMe3)}2] (R2 = R4 = Ph, C6H4Me-4, or C6H4Ph-4; or R2 = C6H4Me-4, R4 = 1-adamantyl) (2003) (37)
- 385. Amino-derivatives of metals and metalloids. Part II. Aminostannylation of unsaturated substrates, and the infrared spectra and structures of carbamato- and dithiocarbamato-trimethylstannanes and related compounds (1965) (37)
- Heterobimetallic (Pd/PtGe/Sn) trinuclear clusters containing a planar M3(CO)3(μ2-M′)3 core: Spectroscopy, cyclic voltammetry, and ESR characterisation of electrochemical reduction products. Crystal structures of [(M{μ2-Sn(NR2)2}(CO))3] (M = Pd or Pt, R = SiMe3)☆ (1985) (37)
- Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring (1994) (36)
- Photolytic homolysis of metal–metal bonds of some binuclear transition-metal carbonyls: an electron spin resonance investigation using spin trapping (1977) (36)
- Cerium(III) dialkyl dithiocarbamates from [Ce[N(SiMe3)2]3] and tetraalkylthiuram disulfides, and [Ce(kappa2-S2CNEt2)4] from the Ce(III) precursor; Tb(III) and Nd(III) analogues. (2004) (36)
- Synthesis and structures of some sterically hindered zinc complexes containing 6-membered and rings (2008) (36)
- Thermally Stable Heterobinuclear Bivalent Group 14 Metal Complexes Ar2 M-Sn[1,8-(NR)2 C10 H6 ] (M=Ge, Sn; Ar=2,6-(Me2 N)2 C6 H3 ; R=CH2 tBu). (1999) (36)
- Unusual kinetically stable dialkyltin(IV) oxides; X-ray structures of [{SnR2(µ-O)}2] and [{SnR2(OH)}2(µ-O)][R = CH(SiMe3)2] (1990) (36)
- Crystal structure (at –40°) of tetrakis[trimethylsilylmethylcopper(I)], an alkyl bridged, square planar, tetranuclear copper(I) cluster (1973) (36)
- Carbene complexes. Part II. Thermally-induced isomerisations of trans-platinum(II) and palladium(II) complexes and the chemistry of the cis- and trans-isomers (1973) (36)
- Amido derivatives of metals and metalloids VII. Carbon-carbon insertion reactions into metalnitrogen bonds and related systems (1968) (35)
- Photochemical synthesis and electron spin resonance characterisation of stable trivalent metal alkyls (Si, Ge, Sn) and amides (Ge and Sn) of Group IV elements (1974) (35)
- A spectrophotometric rapid kinetic study of reactions catalysed by coenzyme-B12-dependent ethanolamine ammonia-lyase. (1978) (35)
- Synthesis and structures of crystalline dilithium diamides and aminolithium amides derived from N,N′-disubstituted 1,2-diaminobenzenes or 1,8-diaminonaphthalene (2001) (35)
- Silylmethyl and related complexes. Part 4. Preparation, properties, and crystal and molecular structure of tetrakis[(trimethylsilylmethyl)-copper(I)], an alkyl-bridged, square-planar, tetranuclear copper(I) cluster (1977) (34)
- Organozirconium dinitrogen complexes [Zr(η-C5H4R')2(η2-N2)R] and [{Zr(η-C5H5)2R}2N2][R=(Me3Si)2CH,R'= H OR Me] (1979) (34)
- Synthesis and theoretical studies on rare three-coordinate lead complexes. (2007) (34)
- Synthesis and structures of lithium, aluminium, gallium and lanthanide amidinates containing a γ-pendant amine functionality (2000) (34)
- Metallocene(III) tetrahydridoborates of the Group 3A elements and the X-ray structure of [Sc{η-C5H3(SiMe3)2}2(µ-H)2BH2] (1983) (34)
- Synthesis and X-ray molecular structures of the silver(I) amides [{Ag[µ-N(SiMe3)2]}4] and [{Ag[µ-NCMe2(CH2)3CMe2]}4] (1996) (34)
- Crystalline binuclear cis- and trans-chlorotin(II) amides [Sn(µ-Cl)(NR2)]2, the cis-1a ⇌trans-1b isomerisation for [NR2= NCMe2(CH2)3CMe2], and the X-ray structures of 1a and of trans-[Sn(µ-Cl){N(SiMe3)2}]2 (1991) (34)
- Reactions of the stable bis(amino)silylene Si[{N(CH2tBu)}2C6H4-1,2] with group 3 or lanthanide metal organic compounds. Crystal structures of [Ln(η5-C5H5)3Si{[N(CH2tBu)]2C6H4-1,2}]·C7H8 (Ln = Y or Yb) (2000) (34)
- Ytterbium(II) amides and crown ethers: addition versus amide substitution (2002) (33)
- Carbene complexes. Part 14. The synthesis and steric and electronic effects in electron-rich olefin-derived bis-, tris-, and tetrakis-(carbene)-ruthenium(II) and a tetrakis(carbene)osmium(II) complex; the crystal and molecular structure of trans-dichiorotetrakis(1,3-diethylimidazo-lidin-2-ylidene)ru (1978) (33)
- Synthesis, Structures, Characterization, Dynamic Behavior, and Reactions of Novel Late Transition Metal(II) 1-Azaallyls (2004) (33)
- Generation and e.s.r. spectra of some new phosphorus-centred radicals Ṗ2Ar2X, Ṗ(Ar)X, Ṗ(OAr)2, ṖAr2(:O), ṖAr[N(SiMe3)2](:NSiMe3), and [P2Ar2]˙– derived from the bulky group C6H2But3-2,4,6(= Ar) (1982) (33)
- Carbene complexes. Part 16. Synthesis and properties of NN′N″N‴-tetra-aryl-substituted electron-rich olefin-derived carbeneruthenium(II) complexes containing a spontaneously formed ortho-metallated-N-arylcarbene ligand; the crystal and molecular structures of [RuCl{CN(C6H4Me-4)CH2CH2NC6H3Me-4}(PEt3) (1979) (33)
- Monomeric bivalent group 4B metal dialkylamides M[NCMe2(CH2)3CMe2]2(M = Ge or Sn), and the structure of a gaseous disilylamide, Sn[N(SiMe3)2]2, by gas electron diffraction (1979) (33)
- Synthesis, structure and reactivity of [Yb(η-C5Me5){Si(SiMe3)3}(thf)2] (1996) (33)
- Monomeric magnesium 1-azaallyl and β-diketiminato complexes derived from the bis(trimethylsilyl)methyl ligand: The X-ray structure of the four-coordinate planar magnesium complex [Mg{N(R)C(But)C(H)R}2] and of [Mg({N(R)C(Ph)}2CH)2]† (1999) (33)
- Subvalent Group 4B metal alkyls and amides. Part III Mössbauer spectroscopy studies of bis[bis(trimethylsilyl)methyl]tin(II) and its derivatives (1976) (33)
- Synthesis and structure of crystalline [K{Sn(CH2But)3}(η-C6H5Me)3] and the first NMR spectral observation of119Sn–39K coupling (1993) (33)
- Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La5(μ5-O)(μ3-OtBu)4(μ-OtBu)4(OtBu)5 (2000) (32)
- Synthetic and structural studies on some bis(cyclopentadienyl)molybdenum and -tungsten complexes containing doubly bonded tin or phosphorus (1989) (32)
- Four-and five-co-ordinate lanthanide (II) aryloxides: X-ray structures of the bis(2,6-di-t-butyl-4-methylphenoxo)ytterbium(II) complexes [Yb(OAr)2(L)2] and [Yb(OAr)2(L′)3][ArC6H2But2-2,6-Me-4, L = tetrahydrofuran (thf) or OEt2, L′= thf] (1989) (32)
- Homolysis of metal–carbon and metal–metal bonds: spin-trapping of the resulting carbon- and metal-centred radicals (1974) (32)
- Unusual crystalline heterobimetallic trinuclear β-diketiminates [Yb{L(µ-Li(thf)}2] and [Yb{L′(µ-Li(thf)}2]·thf [L, L′ = {N(SiMe3)C(R)}2CH, R = Ph, C6H4Ph-4]Electonic supplementary information (ESI) available: NOE data for 1 and NMR data for 2. See http://www.rsc.org/suppdata/cc/b2/b203321f/ (2002) (31)
- Silylmethyl and related complexes (1973) (31)
- Synthesis and structures of beta-diketiminatotin(II) halides, an amide and of Sn(=E)[{N(R)C(Ph)}2CH](NR2) (E = S or Se, R = SiMe3). (2004) (31)
- Synthesis, structure and reductive dechlorination of the C-centred phosphorus(III) beta-diketiminate PCl(Ph)L [L = C[C(Me)NC6H3Pri2(-2),6][C(Me)NHC6H3Pri2(-2),6]]. (2003) (31)
- Subvalent group 14 metal compounds-XIII. Oxidative addition reactions of germanium and tin amides M(NR2)2 (R = SiMe3, M = Ge OR Sn) with sulphur, selenium, tellurium or MeOOCCCCOOMe; X-ray structures of [Ge(NR2)2(μ-Te)]2 and (1991) (31)
- Metal and metalloid amides : syntheses, structures, and physical and chemical properties (1980) (31)
- 433. Spectra and structure of amide complexes (1960) (31)
- Organolanthanide hydroxides; the synthesis and crystal structures of the samarocene and ytterbocene hydroxides [SmCp2″(μ-OH)2] and [YbCp2′(μ-OH)2][Cp″ = η5-C5 H3(SiMe3)2-1,3; Cp′ = η5-C5H4SiMe3] (1991) (30)
- Insertion of diphenyldiazomethane into [ZrCp2(Cl)PR2] (Cp = η-C5H5, R = Sime3); X-ray structures of [ZrCp2(PR2)X] (X = Cl OR Me) and [PR2}] (1988) (30)
- Lanthanide metal amides revisited; the use of the 2,2,6,6-tetramethylpiperidinato (TMP) ligand (2004) (30)
- The diverse reactions of the silylene Si[(NCH2But)2C6H4-1,2] with Li[Si(SiMe3)3](thf)3 and K[N(SiMe3)2] (2000) (30)
- Synthesis and characterisation of 2, 4, 6-tri-t-butylphenylphosphines; X-ray structure of [P(C6H2But3-2,4,6)S]3 (1982) (30)
- The first crystalline alkali metal salt of a benzenoid radical anion without a stabilizing substituent and of a related dimer: X-ray structures of the toluene radical anion and of the benzene radical anion dimer potassium-crown ether salts. (2001) (30)
- Stable Intramolecularly Base-Stabilized Germylene− and Stannylene−Borane Adducts: M[C6H3(NMe2)2-2,6]2BH3 (M = Ge, Sn) (1998) (30)
- The reaction pathway from Speier's to Karstedt's hydrosilylation catalyst (1995) (30)
- Unsaturated σ-hydrocarbyl transition-metal complexes. Part I. Tri-methyltin acetylides as sources of late transition-metal derivatives: metathesis, oxidative addition, and oxidative cleavage (1973) (30)
- μ-Methylene transition metal binuclear compounds: complexes with Me3 SiCH2− and related ligands (1970) (29)
- Pseudohalides of Group IIIB and IVB Elements (1966) (29)
- Bonding studies of compounds of boron and the group 4 elements. Part 9.—Photoelectron spectra and bonding studies of halogeno-, dimethylamino-, and methyl-boranes, BX3 and BX2Y (1972) (29)
- Carbene complexes. Part 10. Electron-rich olefin-based mono-, bis-, and tris-carbene-tungsten(0) complexes and some derived six and seven-co-ordinate mono- and bis-carbene-dihalogenotungsten(II) and related molybdenum(II) species (1977) (28)
- Synthesis and characterisation of lanthanide(II) aryloxides including the first structurally characterised europium(II) compound [Eu(OC6H2But2-2,6-Me-4)2(thf)3]·thf (thf = tetrahydrofuran) (1995) (28)
- Organometallic complexes of the Group 3A and lanthanoid metals containing M(µ-Cl)2Li bridging units; the X-ray structure of [Nd{η-[C5H3(SiMe3)2]}2(µ-Cl)2Li(thf)2](thf = tetrahydrofuran) (1981) (28)
- Ready oxidative addition of an alkyl or aryl halide to a tin(II) alkyl or amide; evidence for a free-radical pathway (1976) (28)
- Lithium Derivatives of Novel Monoanionic Di-N,N‘-chelating Pyridyl- and Quinolyl-1-azaallyl Ligands (1997) (28)
- Three-coordinate neutral ligand-free ytterbium(II) complexes [{YbX(µ-X)}2](X = OAr 1 or OCBut3 3) or [{Yb(NR2)(µ-X)}2](X = OCBut3 2 or OAr 4)(Ar = C6H2But2-2,6-Me-4, R = SiMe3); the X-ray structures of 1 and 2 (1994) (28)
- Comprar Metal Amide Chemistry | Michael Lappert | 9780470721841 | Wiley (2009) (28)
- Developments In Inorganic Polymer Chemistry (1962) (28)
- The molecular structure of gaseous bis(trimethylsilyl)methane, CH2(Si(CH3)3)2, as determined by electron diffraction: An unusually large SiCSi angle (1983) (28)
- Syntheses and Structures of the Crystalline, Highly Crowded 1,3-Bis(trimethylsilyl)cyclopentadienyls [MCp″3] (M = Y, Er, Yb), [PbCp″2], [{YCp″2(μ-OH)}2], [(ScCp″2)2(μ-η2:η2-C2H4)], [YbCp″2Cl(μ-Cl)K(18-crown-6)], and [{KCp″}∞] (2012) (28)
- Synthesis and crystal structure of trimeric sodium 2,2,6,6- tetramethylpiperidide (NaTMP) (1999) (28)
- Bonding studies of compounds of boron and the group IV elements : X. Photoelectron spectra of compounds Me4M (MC, Si, Ge, Sn, or Pb) and the lack of participation of M d-orbitals (1973) (28)
- Co-ordination chemistry of bivalent Group 4B heavy metal donors M[N(SiMe3)2]2(M = Ge or Pb) or Ge[CH(SiMe3)2]2; and the crystal and molecular structure of [Cr(CO)5(Ge{CH(SiMe3)2}2)] (1977) (27)
- Use of a highly hindered phosphino-alkoxide ligand in the formation of monomeric homoleptic lanthanoid metal complexes: X-ray structures of [Ln(OCBut2CH2PMe2)3](Ln = Y or Nd) (1988) (27)
- Homoleptic, three-co-ordinate group 8c noble metal(0) complexes having GeII or SnII ligands, [M{M′(NR2)2}3](M = Pd or Pt, M′= Ge or Sn, R = SiMe3), and the X-ray structure of one of them (M = Pd, M′= Sn) (1985) (27)
- Binuclear organometallic compounds VIII. Oxidative addition of Si-H or Si-Cl compounds to low valent Fe, Co, or Ni complexes stabilised by mono- or bi-dentate phosphines (1974) (27)
- Synthesis and structures of neutral and cationic β-diketiminatoaluminium methyls† (1999) (27)
- Silylmethyl and related complexes. 7. Bulky, monomeric, heavy Group III metal trialkyls and the crystal and molecular structure of tris[bis(trimethylsilyl)methyl]indium (1980) (27)
- Synthesis, chemical behaviour, and structure (crystal and solution) of a fluorouranocene(IV) tetrafluoroborate; X-ray crystal structure of [{Ucp″2(µ-BF4)(µ-F)}2][cp″=η-C5H3(SiMe3)2] (1984) (27)
- The beta-dialdiminato ligand [{N(C6H3Pri(2)-2,6)C(H)}2CPh]-: the conjugate acid and Li, Al, Ga and In derivatives. (2006) (27)
- Subvalent Group 14 metal compounds. Part 16. Synthesis, crystal structure and characterisation of some β-functionalised-alkyltin(II) complexes, SnR(X){R = C5H4N[C(SiMe3)2]-2; X = R, Cl or N(SiMe3)2} (1993) (27)
- Trimethylsilylmethylcopper, a stable copper(I) alkyl (1973) (27)
- Synthesis and structures of bis[bis(trimethylsilyl)amido]-tin(IV) cyclic chalcogenides [{Sn[N(SiMe3)2]2(µ-E)}2] and a heterobimetallic analogue [{(Me3Si)2N}2Ge(µ-Te)2Sn-{N(SiMe3)2}2](E = S, Se or Te) (1995) (27)
- Organometalloidal derivatives of the transition metals : III. σ- and π-silylallyl complexes☆ (1976) (26)
- Four-co-ordinate lanthanide metal(III) chloro(alkyl)s: synthesis and X-ray structure of [LaR3(µ-Cl)Li(pmdeta)][R = CH(SiMe3)2, pmdeta =N,N,N′,N″,N″-pentamethyldiethylenetriamine] (1988) (26)
- Scandium Its Occurrence, Chemistry, Physics, Metallurgy, Biology and Technology (1975) (26)
- Bulky metal aryloxides, arylamides, and sulphur and phosphorus analogues. Part 1. Synthetic and chemical studies of titanium and zirconium aryloxides (1986) (26)
- Alkaline-earth-metal arenesulfonates as precursors to organic derivatives of Group 2 metals (1996) (26)
- Novel Zirconium and Hafnium Complexes of Monoanionic Di-N,N‘-chelating Pyridyl- and Quinolyl-1-azaallyl Ligands and Their Activity in Olefin Polymerization Catalysis (1999) (26)
- Binuclear organometallic compounds. Part VI. Complexes containing metal–metal bonds between elements of group IVA and group IVB (1972) (25)
- The role of bivalent tin compounds in platinum co-ordination chemistry; X-ray structure of [Pt{Sn(NR′2)2}3], trans-[(Pt(µ-Cl)(PEt3){SnCl(NR′2)2})2], and (SnClR2)2[R = CH(SiMe3)2, R′= SiMe3] (1985) (25)
- Bis(trimethylsilyl)phosphido complexes (1988) (25)
- Gmelin handbook of inorganic chemistry, 8th edition (1982) (25)
- The Thermally Stable Silylene Si[(NCH2But)2C6H4‐1,2]: Reactions with ButCN, AdCN, ButNC, AdN3, and Me3SiN3 (Ad = 1‐Adamantyl) (2001) (25)
- Synthesis and characterisation of ytterbium(II) alkyls (1995) (25)
- ORGANOACTINIDE CHEMISTRY. II: THE CHEMISTRY OF SOME NOVEL CYCLOPENTADIENYLTHORIUM COMPLEXES (1995) (25)
- α-Heterodiazoalkanes and the Reactions of Diazoalkanes with Derivatives of Metals and Metalloids (1971) (25)
- Synthesis and Structures of Crystalline Lithium, Sodium, Potassium, and Magnesium Silylmethyls Derived from the Ligands [CH(SiMe3){SiMe3-n(OMe)n}]- (n = 1, 2), [CH(SiMe2OMe)2]-, and [CH(SiMe3)(SiMe2Ph)]- (2003) (24)
- Bis(trimethylsilyl)phosphido complexes. Part 3. Syntheses, structures and reactions of [bis(trimethylsilyl)phosphido]-zirconocene(IV) complexes and the X-ray structure of {AlMe2[µ-P(SiMe3)2]}2 (1991) (24)
- Silylmethyl and related complexes. Part 6. Preparation, properties, and crystal and molecular structure of tris[bis(trimethylsilyl)methyl]-chromium(III);the chemistry of related compounds of titanium(III), vanadium(III), zirconium(IV), and hafnium(IV) (1978) (24)
- The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)](Ln = La, Ce) (1996) (24)
- Monomeric, coloured germanium(II) and tin(II) di-t-butylamides, and the crystal and molecular structure of Ge(NCMe2[CH2]3CMe2)2 (1980) (24)
- Reactions of the stable bis(amino)silylene with multiply bonded compounds (1998) (24)
- Synthesis, structures and catalytic properties of chelating N,N′-bis(silylated) 1,2-benzenediamidozirconium(IV) chlorides [and a titanium(IV) analogue] and dimethylamides (2001) (24)
- Preparation and properties of some bis(cyclopentadienyl)ytterbium(II) complexes and the X-ray crystal and molecular structures of [Yb(η-C5H4SiMe3)2(thf)2] (1980) (24)
- 394. Chloroboration and allied reactions of unsaturated compounds. Part III. Aminoboration and alkoxyboration of isocyanates and isothiocyanates (1964) (24)
- Syntheses and structures of highly hindered N-functionalised alkyl–group 2 metal complexes [M{NC5H4C(SiMe3)2-2}2](M = Mg, Zn, Cd, or Hg) (1986) (24)
- Modern Coordination Chemistry–The Legacy of Joseph Chatt (2002) (24)
- The chromium–heavy group 5 donor bond: a comparison of structural changes within the series [Cr(CO)5(XPh3)](X = P, As, Sb, or Bi)via their X-ray crystal structures (1979) (24)
- Trimethylsilylcyclopentadienylthallium(I) complexes: syntheses and X-ray structures of the multidecker sandwich complexes (Tl(μ-η:η-C5H4SiMe3)]n and [Tl{μ-η:η-C5H3(SiMe3)2-1,3}]6 (a doughnut molecule) (1987) (24)
- Chemistry of o-xylidene–metal complexes. Part 1. o-Xylidene-magnesium reagents as metallocyclic precursors and synthesis of [Pt(CH2C6H4CH2-o)(cod)](cod = cyclo-octa-1,5-diene); the X-ray crystal structure of the macrometallocycle [{Mg(CH2C6H4CH2-o)(C4H8O)2}3] (1982) (24)
- Syntheses, structures and reactions of a series of beta-diketiminatoyttrium compounds. (2008) (24)
- Photoelectron spectra of electron-rich olefins and an isostructural boron compound; olefins of exceptionally low first ionisation potential (1971) (23)
- Crystalline Na-Si(NN) derivatives [Si(NN)= Si((NCH2tBu)2C6H4-1,2)]: the silylenoid [Si(NN)OMe]-, the dianion [(NN)Si-Si(NN)]2-, and the radical anion c-[Si(NN)]3-. (2005) (23)
- Wittig-type reactions of 2-lithio-2-trimethylsilyl-1,3-dithian: an improved and extended synthesis of alkylidenedithians for 1-carbon homologation (1972) (23)
- Synthesis, spectroscopic properties and crystal structures of [ML2Cl2][M = Th or U; L =η-C5H3(SiMe3)2-1,3] and [UL2X2](X = Br, I or BH4) (1995) (23)
- Carbene complexes. Part 13. The synthesis and characterisation of secondary carbene complexes of vanadium(I), chromium(0), molybdenum(0), tungsten(0), manganese(I), rhenium(I), iron(0), ruthenium(II), cobalt(I), iridium(III), and platinum(IV), and hydridorhodium(III) (1978) (23)
- The synthesis and properties of the transannularly bonded electron-rich olefin derived from 1,4,8,11-tetra-azacyclotetradecane; X-ray crystal structure of the chelating cis-dicarbenerhodium(I) salt obtained therefrom (1980) (23)
- Lipophilic lithium alkoxides or dialkylboroxides; X-ray structures of [Li(µ-OR′)]2 and Li(OBR2)(tmeda), [tmeda =(Me2NCH2)2, R = CH(SiMe3)2, R′= CBut3 or BR2] (1989) (23)
- Binuclear organometallic compounds. Part V. Insertion into M–C and H–C bonds of co-ordinatively unsaturated transition-metal fragments: synthesis of group VIA metal cyclopentadienyltricarbonyl metallates (germanium and tin) and hydrides (1971) (23)
- Homogeneous catalysis: VI. Hydrosilylation using tris(pentanedionato)rhodium(III) or tetrakis(μ-acetato)dirhodium(II) as catalyst (1979) (23)
- Subvalent Group 4B metal alkyls and amides. Part 6. Oxidative addition of an alkyl or aryl halide to bis[bis(trimethylsilyl)methyl]tin(II); hydrogen-1 nuclear magnetic resonance data on the tin(IV) adducts and a single-crystal X-ray study of tris[bis(trimethylsilyl)methyl]chlorotin(IV) (1977) (23)
- Phosphorusphosphorus single or double bond formation from PCl3−nRn (n = 1 or 2) and a bis-imidazolidine reducing agent (1986) (23)
- Synthesis, Structures, and Reactivities of Guanidinatozinc Complexes and Their Catalytic Behavior in the Tishchenko Reaction (2013) (23)
- Novel monoanionic di-N,N′-centred chelating ligands and their C1 and C2 symmetrical zirconium complexes (1996) (22)
- Carbene complexes: XXII. Preparation, properties and structures of the N,N-functionalized bis(amino)carbenemolybdenum(O) carbonyls [Mo(CO)4 {CN(CH2CH:CH2)(CH2) 2N}(CH2CH:CH2)}] and Mo(CO)3{CN[(CH2)3PPh2] (CH2)2N {(CH2)3PPh2}]n☆ (1993) (22)
- Chloroboration and allied reactions of unsaturated compounds. Part IV. Boration of di-p-tolylcarbodi-imide (1966) (22)
- Three-fragment oxidative addition of chloroform-iminium or -amidinium chlorides to RhI or PtII substrates; complexes of the secondary carbene CHNMe2 (1972) (22)
- Synthetic and Structural Studies on the Cyclic Bis(amino)stannylenes Sn[(NR)2C10H6‐1, 8] and their Reactions with SnCl2 or Si[(NCH2But)2C6H4‐1, 2] (R = SiMe3 or CH2But) (2004) (22)
- Bis(η-cyclopentadienyl)lanthanoid(III) chlorides (1982) (22)
- Synthesis, structure, and reactivity of a µ-bis(dialkylphosphido)-dilithium [Li(µ-PR2)]2[R = CH(SiMe3)2] (1984) (22)
- Telluroureas and derived transition metal complexes: the crystal and molecular structure of [Cr(CO)5{TeCN(Et)CH2CH2NEt}] (1980) (22)
- Reaction of the silylene Si[(NCH2But)2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R](M = Li, Na or K; R = SiMe3 or SiMe2Ph). (2004) (22)
- Dimeric µ-dimethyl lanthanide complexes, a new class of electron-deficient compound, and the crystal and molecular structure of [Yb(η-C5H5)2Me]2 (1976) (22)
- A DINUCLEAR TIN(II) AMIDE, A META-STANNYLAMINOCYCLOPHANE AND ITS ORTHOSTANNYLATED DERIVATIVE, A DIMERIC TRINUCLEAR TIN(II) CLUSTER (1997) (22)
- New group 14 element(IV) β-diiminates and a Sn(II) analogue (2009) (21)
- Synthesis and characterisation of the first stable, heteroleptic silylstannylenes† (1997) (21)
- Mechanistic studies of some oxidative-addition reactions: free-radical pathways in the Pt0–RX, Pt0–PhBr, and PtII–R′SO2X reactions (R = alkyl, R′= aryl, X = halide) and in the related rhodium(I) or iridium(I) systems (1980) (21)
- The first monomeric prochiral tin(II) complexes Sn[N(SiMe3)2]X [X = OC6H2But2-2,6-Me-4, 1 or NCMe2(CH2)3CME2, 2]; the X-ray structure of 1 and oxidative addition reactions of 2 (1992) (21)
- Activation parameters for rotation about an M–Ccarb bond from temperature dependent 1H n.m.r. spectra of RhI carbene complexes (1974) (21)
- Synthesis and Structures of Alkali Metal Amides Derived from the Ligands [N(SiMe2Ph)(SiMe3)]−, [N(tBu)(SiMe3)]−, [N(Ph)(2‐C5H4N)]−, and [N(2‐C5H4N)2]− (2003) (21)
- Synthesis and structures of the heavier alkali metal alkyls; the X-ray structures of [Na(µ-R)]∞ and [Rb(µ-R)(pmdeta)]2[R = CH(SiMe3)2, pmdeta =(Me2NCH2CH2)2NMe] (1993) (21)
- Silylmethyl and related complexes VIII. Bis[bis(trimethyl)silylmethyl]manganese(II): Its synthesis, properties, and crystal structures of its tetrahydrofuran and bis(dimethylphosphino)ethane adducts☆ (1990) (21)
- Bonding studies of organometallic compounds of boron and the group IV elements. Part I. Heats of hydrolysis and bond energies for some trimethylsilyl derivatives (1967) (21)
- Binuclear organometallic compounds. Part I. The amine elimination reaction for synthesis of compounds containing bonds between elements of group IV and transition metals (1970) (21)
- Novel two-coordinate germanium(II) arylamides: Ge(NHAr)2, ArN[Ge(NHAr)]2(µ-NAr) and [Ge(µ-NAr)]22, and the X-ray structures of 2 and Sn(NHAr)2(Ar = C6H2But3-2,4,6) (1990) (21)
- Homogeneous catalysis: IX. Hydrosilylation using tris(Pentanedionato)rhodium(III)-trialkylaluminium as catalyst☆ (1984) (21)
- The synthesis and X-ray structures of ytterbocene(II) complexes containing pendant pyridyl groups, [Yb(Cpx)2] (Cpx=η5-C 5H3(R)[CMe2(CH2)nC5H4N-2]-1,3; R H or SiMe3 and n = 0 or 1 (1994) (20)
- Synthesis and Structures of Mono(1-aza-allyl) Complexes of Aluminum† (1999) (20)
- Unusual alkali metal a- or -phenyl(trimethylsilyl)amides (2000) (20)
- Bulky metal aryloxides, arylamides and sulphur and phosphorus analogues—III. Aluminium compounds derived from 2,4,6-TRI-t-butylaniline; X-ray structure of [{μ-NHC6H2But2-4,6-C(Me)2CH2-2}]2 ☆ (1990) (20)
- Carbene complexes XXIV. Preparation and characterization of two enetetramine-derived carbenerhodium(I) chloride complexes RhCl(LR))3 and [RhCl(COD)LR] and the preparation and X-ray structures of the enetetramine L2R and its salt [L2R][BF4]2 (1995) (20)
- Magnetic resonance spectroscopic studies of a tetraaryl-distannene and -digermene [M2R4] (R = C6HBut-2-Me3-4,5,6 and M = Sn or Ge)† (1998) (20)
- Organometallic chemistry of the actinides (1998) (20)
- Lanthanides in organic synthesis (1995) (20)
- Metal (Li, K, SnII and HgII) complexes of the 1,3-diazaallyl [N(R)C(Ph)NC(Ph)CR2]– (R = SiMe3) (1998) (20)
- Molecular structures of bis(trimethylsilyl)methyl-lithium [(LiR)n, R = CH(SiMe3)2] in the vapour (gas-phase electron diffraction: a monomer, n= 1) and the crystal (X-ray: a polymer, n=∞) (1984) (20)
- A new class of benzoin condensation catalyst, the bi-(1,3-dialkylimidazolidin-2-ylidenes) (1982) (20)
- Bonding studies of boron and the Group 3–5 elements. Part XV. He(I) photoelectron spectra of monomeric Group 3 trihalide, trimethyl, and mixed halogenomethyl species (1975) (19)
- Bonding studies of transition metal complexes (1974) (19)
- trans/cis-isomerism and isomerisation of PdII and PtII carbene complexes; The crystal and molecular structures of cis- and trans-PtCl2 [C(NPhCH2)2]PEt3 (1972) (19)
- The synthesis and X-ray structure of a novel monocyclopentadienyluranium(IV) chloride [UCp′''Cl2(THF)(μ-Cl)2Li(THF)2][Cp′''=η-C5H2(SiMe3)3-1,2,4] (1987) (19)
- Transition-metal complexes of two valence tautomers of a bulky phenoxide, 2,6-Bu-t2-4-MeC6H2O− (ArO−); preparation and crystal and molecular structure of a phenoxytitanium(III) and a cyclohexadienonylrhodium(I) complex, [Ti(η-C5H5)2 OAr] and [Rh(ArO-η5)(PPh3)2] (1980) (19)
- Carbene complexes. Part VII. Chloromethyleneammonium chlorides. Electron-rich carbenoids, as precursors to secondary carbene metal complexes; crystal and molecular structure of trichloro(dimethylaminomethylene)bis(triethylphosphine)rhodium(III) (1974) (19)
- 633. Reactions of sulphoxides with some Group III and IV halides (1961) (19)
- Preparation and X-ray structure of [Ge{N(SiMe3)2}2(µ-O)]2, a rare 1,3-cyclodigermoxane (1992) (19)
- Synthesis and 171Yb-{1H} nuclear magnetic resonance spectra of ytterbium(II) aryloxides [Yb(OR′)2(L)n][(L)n=(OEt2)2, (thf)2, (thf)3, (pyridine)2 or Me2PCH2CH2PMe2] and [{Yb(µ-OR′)(X)}2](X = OR′ or NR2)(R′= C6H2But2-2,6-Me-4, R = SiMe3, thf = tetrahydrofuran) (1995) (19)
- Reactivity of a Super-Electron-Rich Olefin Derived from Cyclam (2009) (19)
- Homogeneous Catalysis. IV. Hydrosilylation of Cyclic or Linear Dienes- Using Low-Valent Nickel Complexes and Related Experiments (1977) (19)
- Metallocene derivatives of early transition elements. Part 1. Niobium(IV) chlorides, chloroalkyls, and dialkyls [Nb(η-C5H4X)2RR′], and the crystal and molecular structure of [Nb(η-C5H5)2(CH2Ph)2] (1981) (19)
- A new method for the preparation of bis(bistrimethylsilylmethyl)tin(II) Sn[CH(SiMe3)2]2 and lts molecular structure has been determined by gas electron diffraction. Prediction of non-planar, trans-folded ground state structures for digermene (Ge2H4) and distannene (Sn2H4) (1982) (19)
- Bonding studies of compounds of boron and the group IV elements. Part VIII. Heats of hydrolysis and bond energies for some trimethylmetalyl derivatives Me3M–X(M = Si, Ge, and Sn) (1972) (19)
- Novel lithium 3-sila- and 3-germa-β-diketiminates†‡ (1998) (18)
- 271. Fission of mixed ethers by boron trichloride (1952) (18)
- Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt (1981) (18)
- Synthesis and characterisation of 1-alkyl-2-imidazoline complexes ofnoble metals; crystal structure oftrans-[PtCl2{NC(H)N(Et)CH2CH2}(PEt3)] (1997) (18)
- Insertion into metal—carbon and hydrogen—carbon bonds; synthesis of group VIA metal cyclopentadienylcarbonyl metallates and hydrides (1969) (18)
- Neutral isonitrile adducts of alkali and alkaline earth metals (1998) (18)
- Butyl metal aryloxides, arylamides, and sulphur and phosphorus analogues—II. Synthesis and characterization of novel bulky alkoxides and aryloxides of aluminium; X-ray structure of [Al(μ-OCH2Ar)Me2]2 (Ar = C6H2Bu3t-2,4,6) (1990) (18)
- µ-Dialkyl inner transition metal(III) tetra-alkylaluminates; the crystal and molecular structure of di-µ-methyl-(dimethylaluminium)biscyclopentadienylyttrium and -ytterbium (1976) (18)
- Metallocene halides. Part II. The low frequency infrared and Raman spectra of di-π-cyclopentadienyldihalogeno-titanium(IV), -zirconium(IV), and -hafnium(IV) (1969) (18)
- Electronic structure of stable benzodiazasilylenes: photoelectron spectra and quantum-chemical investigations (1996) (18)
- A comparative study of the behaviour of N-trimethylsilyl and N-neopentyl-anilines and 1,2-diaminobenzenes towards trimethylalane; X-ray structures of nine Al–N compounds (2003) (18)
- Boron halides as reagents in inorganic syntheses. Part II. A further general method for the preparation of anhydrous bromides and iodides: halogen exchange reactions (1971) (18)
- Azomethine derivatives of early transition metals (1971) (18)
- Novel(silylimino)diarylphosphoranyl(trimethylsilyl)methyl-C,Nligands[CH(SiMe3)PPh2NSiMe3]- ([LL′]-) and[CH(SiMe3){Ph(1,2-C6H4)PNSiMe2}]-([LL″]-) and the structures of[Li(LL″)]2 and[Pb(LL′)2] (1997) (18)
- Synthesis and structures of some bimetallic (Li/Ca, Li/Zn, Li/Li) diamides derived from 1,2-bis(neopentylamino)benzene and of Li2[{N(SiMe2NPr(i)2)}2C6H4-1,2](thf)3. (2006) (18)
- Lipophilic halogenozirconocene(III) complexes: [{Zr[η-C5H3(SiMe3)2-1,3]2(µ-Cl)}2], [NBun4][Zr{η-C5H3(SiMe3)2-1,3}2Cl2] and [Zr{η-C5H3(SiMe3)2-1,3}2Cl2] (1992) (18)
- Synthesis and structures of some heterometallic [(Li, Y)2, (M3, Ce) (M = Li or Na), (Li, Zr2) and (Li, Zr)4] oligomeric diamides derived from 1,2-bis(neopentylamino)benzene. (2006) (18)
- The initiation of polymerization by organometallic compounds—II. The polymerization of acrylonitrile with titanium tetradimethylamide and related reactions (1971) (18)
- Organometallic chemistry of the actinides. Part 3 novel 1-aza-allyl- and β-diketiminatothorium chlorides; X-ray structures of [{Th(L⎴L')2(μ3-Cl)(μ-Cl)2K(OEt2)}∞] and [Th(L⎴L)2Cl2] [LL′ = N(SiMe3)C(But)C(H)SiMe3; LL = N(SiMe3)C(Ph)2CH] (1997) (18)
- Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{μ-N(Ph)R}-trans)2(μ-tmen)]∞ (R = SiMe3 1 or CH2But 2) and [Li{μ-N(Ph)CH2But}(OEt2)]2 (2001) (18)
- A new one-pot arylacetylene synthesis: 4-RC6H4CC(TMS) from 4-RC6H4CN and LiC(TMS)3(THF)2 via (TMSSiMe3, R = H, F, Br, OMe or But) (1998) (18)
- Synthesis and characterisation of N-functionalized enetetramines, and their properties (2004) (18)
- Homogeneous Catalysis : VII. The catalysis of isoprene hydrosilylation using metal atoms (1979) (18)
- Metallocene derivatives of early transition elements. Part 4. Synthesis and crystal structures of a series of zirconocene(IV) halides [Zr(η-C5H4SiMe3)2X2](X = Cl or Br) and [Zr{η-C5H3(SiMe3)2-1,3}2X2](XF, Br, or I) (1987) (18)
- Unprecedented Oxidative Chlorosilylation Addition Reactions to a Diarylgermylene and -stannylene (2002) (18)
- Synthesis and Structures of the Crystalline Heavier Alkali Metal Alkyls: X-ray Structures of [K(μ-R){O(Me)But}]∞, [(pmdeta)K(μ-R)K(μ-R)2K(μ-R)K(pmdeta)], and [Cs(μ-R)(tmeda)]∞ (R = CH(SiMe3)2) (2000) (17)
- Homogeneous Catalysis : III. Hydrosilylation of α,β-unsaturated aldehydes; regiospecific reduction of CO using Ni0 catalysts (1975) (17)
- Unsaturated σ-hydrocarbyl transition-metal complexes. Part 4. Crystal and molecular structure of trans-chlorobis(diethylphenylphosphine)-(phenylethynyl)platinum(II) and comments on the relative trans influence of various carbon ligands (1978) (17)
- 439. Infrared spectra of nitriles and their complexes with boron trichloride (1960) (17)
- Synthesis and structural characterisation of bis(trimethylsilyl)amidotin(II) triflate [{Sn(NR2)(μ-η2-∞ (R=SiMe3, −OTf=−OSO2CF3) (2000) (17)
- Wittig-type reactions of 2-lithio-2-trimethylsilyl-1,3-dithian and related reactions (1974) (17)
- Monomeric, base-free Mn(II) dialkyls; synthesis, magnetic properties and molecular structure of MnR2 [R=CH(SiMe3)2], SCF MO calculations on Mn(CH3)2 and photoelectron spectra of Mn(CH2CMe3)2 (1988) (17)
- A novel high-yield route to organic derivatives of group 2 metals; X-ray structure of [{Ba(OTf)2}4(py)14]·py (OTf = OSO2CF3) and NMR spectral characterisation of [Ba(NR2)(µ-NR2)2Na(thf)2](R = SiMe3) (1994) (17)
- Catalysis and solvent participation in organometallic oxidative additions (Pt0→PtII and SnII→SnIV) (1978) (17)
- Metal β-diketiminates revisited: ansa-CH2-bridged bis(β-diketiminate)s of lithium and aluminium having diverse structures (2004) (17)
- A 1-Aza-2-silacyclobut-3-ene and an Alkyne from [Li{Si(SiMe3 )3 }(thf)3 ] and the Isocyanide 2,6-Me2 C6 H3 NC. (1999) (17)
- The role of lithium 1,3-bis(trimethylsilyl)-1-aza-allyls in phosphorus chemistry (1997) (17)
- The synthesis and characterisation of some divinyldisiloxane—(tertiary phosphine) complexes of platinum(0) and nickel(0) (1997) (17)
- A complete series of uranocene(III) halides [{UCp″2X}n][X = F, Cl, Br, or I; Cp″=η-C5H3(SiMe3)2]; single-crystal X-ray structure determinations of the chloride and bromide (n= 2 for X–=µ-Cl– or µ-Br–) (1986) (17)
- A hexaphosphorus chain as part of a dimeric P,P′-containing ligand; 1,3-phosphozirconation of white phosphorus; X-ray structure of [Zr(η-C5H5)2{P(PR2)PP(PR2)P}](R = SiMe3) (1987) (17)
- Bonding studies of compounds of boron and the Group 3–5 elements. Part XIII. He(I) photoelectron spectra of phosphines RnPX3–n(R = Me or But; X = H, Cl, or F; n= 1–3), (Me2N)nPCl3–n(n= 1–3), and (R2N)PF2(R = Me or Et) (1975) (17)
- Organozirconium(III)–dinitrogen complexes: evidence for (η2-N2)–metal bonding in [Zr(η-C5H5)2(N2)(R)][R = Me3Si)2CH] (1978) (17)
- Bonding studies of compounds of boron and the group IV elements (1973) (17)
- Stable acyls and iminoacyls of zirconium(IV), [Zr(η-C5H5)2{C(:X)R}R′] [X = O or NTol-p; R = Me3CCH2, Me3SiCH2, or (Me3Si)2CH; R′ = Cl or alkyl] (1979) (17)
- Phosphorus(III and V)– and arsenic(III)–nitrogen metallacycles derived from the bulky arylamido ligand NHAr (Ar = C6H2But3-2,4,6); X-ray structures of ArNPN(Ar)AIMe2 and PAr(NHAr)2 (1986) (16)
- Highly hindered γ-PIII-functionalised alkoxo–lithium complexes: syntheses and structures of [Li(µ-OCBut2CH2PR2)]2(R = Me or Ph) and [Li(µ-OCBut2CH2PPh2)2Li(OCBut2)] (1986) (16)
- C–C bond-making by trapping of a nucleophilic carbene (from an electron-rich olefin) by a σ–π-acetylido(hexacarbonyl)di-iron complex; X-ray crystal and molecular structure of [(OC)3FeC(+CNMeCH2CH2NMe)(Ph)Fe(CO)3PPh2] (1978) (16)
- 295. Interaction of boron trichloride with catechol, quinol, resorcinol, and pyrogallol (1959) (16)
- Synthesis and characterisation of twelve Sn(IV) diaryls and formation of a Sn(III) triaryl. (2009) (16)
- Alkylideneamido-derivatives of metals and metalloids. Part VI. The synthesis of alkylideneamido(carbene)rhodium(I) complexes and related chemistry; the crystal and molecular structure of trans-Rh[N:C(CF3)2][C(NMeCH2)2](PPh3)2 (1974) (16)
- The first example of an intermolecular weak (agostic)γ-methyl-metal interaction: the low temperature single crystal X-ray and neutron diffraction structure of (MgR2)∞[R = CH(SiMe3)2] (1990) (16)
- Reactions of ytterbium(II) amides with various Brønsted acids, CS2 or LiNR2; crystal structures of [{Yb(NR2)(µ-OCBut3)}2] and [Yb(OCBut3)2(thf)2](R = SiMe3, thf = tetrahydrofuran) (1995) (16)
- 2,2-Dimethyl-1,1,1,1-tetracarbonyl-1-ferra-2-silacyclopentane: insertion of [Fe(CO)4] into a strained organosilicon ring (1972) (16)
- 586. Cyclic organic boron compounds. Part IV. B-amino- and B-alkoxy-borazoles and their precursors the tris(primary amino)borons and (primary amino)boron alkoxides (1959) (16)
- Carbene complexes. Part 15. The synthesis and properties of electron-rich olefin-derived mono-and oligo-carbenenitrosyl-ruthenium, -osmium, and -nickel complexes (1978) (16)
- Conversion of the silicone poly(dimethylsiloxane) by thallium(I) ethoxide into the ladder polymer [{Tl2(OSiMe2)O}2]n; X-ray structure of the product and of thallium(I) triphenylsilanolate (1988) (16)
- Light-induced anaerobic CoIII–C homolysis of aqueous vitamin B12 coenzyme or of ethylcobalamin; spin-trapping of the 5′-deoxyadenosyl or Et radical (1975) (16)
- Synthetic and structural studies on some organic compounds of zirconium (1989) (16)
- Unusual molecular structures of some sterically hindered lithium amides: electron diffraction results on gaseous [Li{N(SiMe3)2}]2 and X-ray data on crystalline monomeric Li(NHAr)(tmeda)(Ar = C6H2But3-2,4,6; tmeda = Me2NCH2CH2NMe2) (1984) (16)
- Subvalent group 14 metal compounds: XV. Germanium and tin amides M(NR2)2 as ligands in carbonylchromium(0) chemistry. The crystal structure of the compounds cis-Cr (CO)4{Sn(NR′2)2}2 M = Ge or Sn, R′ SiMe3 or NR2 = NCMe2(CH2)3C Me2☆ (1993) (16)
- [3]- and [1,3]-Sigmatropic amino-Claisen rearrangements of electron-rich alkenes [1,3,1',3'-tetraallyl-2,2'-biimidazolidinylidenes] (1989) (16)
- Synthesis and structures of a 3-sila-beta-diketiminatomagnesium bromide, ketenimide and triflate. (2005) (16)
- The preparation and properties of triphenyl borate and the phenoxyboron chlorides (1955) (16)
- Advances in Organometallic Chemistry, Vol. 28 (1988) (16)
- Coenzyme‐B12 ‐dependent enzyme reactions: A spectrophotometric rapid kinetic study of ethanolamine ammonia‐lyase (1975) (15)
- Dilithium diamides [{Li(OC4H8)}2{C20H12(NR)2}](R = SiMe3 or CH2But) derived from R-, S- or R,S-2,2′-diamino-1,1′-binaphthyl derivatives (1996) (15)
- Carbene complexes. Part 21. Synthesis and characterisation of bis(carbene)molybdenum(II) complexes and dimetal(0) complexes of the Group 6 elements containing novel bridging bis(carbene) ligands; X-ray structures of [Mo(CO)2(LEt)2(OSO2CF3)2][LEt=CN(Et)(CH2)2NEt] and [W(CO)5{C(OEt)CH2C6H4CH2C(OEt)-o} (1987) (15)
- Synthesis and structures of some silylallyl-lithium or -potassium complexes (1999) (15)
- 69. Alkyl bisdialkylaminoboronites and related compounds (1957) (15)
- Reactions of amino-derivatives of transition-metals (1965) (15)
- An electrochemical and DFT study on selected β-diketiminato metal complexes (2006) (15)
- Metal secondary amides derived from the highly hindered 2,4,6-tri-t-butylaniline; X-ray crystal structure of trans-[Li(µ-NHAr)(OEt2)]2(Ar = C6H2But3-2,4,6) (1984) (15)
- Substituted triazines and pyrimidines from 1,3,5-triazine and a lithium amidinate, alkyl- or 1-azaallyl (2001) (15)
- Oxidative cleavage of the metal-metal bond of bi- or poly-nuclear carbonyl complexes by cyclopentadienyl(trimethyl)stannane (1970) (15)
- Studies on the subunit structure of the adenosylcobalamin‐dependent enzyme ethanolamine ammonia‐lyase (1979) (15)
- Hydrocarbon-soluble, crystalline, four-co-ordinate chloro(aryl oxide)s, dialkylamido(aryl oxide)s and di[bis(trimethylsilyl)cyclopentadienyl]s of ThIV and UIV; X-ray crystal structure of diethylamidotris(2,6-di-t-butylphenoxo)uranium(IV) (1983) (15)
- Synthesis and structures of halides and pseudohalides of bis[2,6-bis(dimethylamino)phenyl]tin(IV). (2009) (15)
- Synthesis and structural characterisation of new ansa-bis(propene)s and {ansa-bis(allyl)}alkali metal and {ansa-bis(allyl)}transition metal complexes (2000) (15)
- A three-fragment oxidative addition reaction as a route to transition metal carbene complexes: imidoyl halides and rhodium(I) compounds as precursors for rhodium(III) carbenes (1972) (15)
- Organometallic compounds Synthesis, Structure, and Theory : edited by Bernard L. Shapiro, Texas A&M University Press, 1983, xxvii + 481 pages, $35.00. (1984) (15)
- Synthesis of bis(η-1,3,5-tri-t-butylbenzene) sandwich complexes of titanium, zirconium, and hafnium, and of the hafnium(0) carbonyl complex [Hf(η-But3C6H3)2(CO)] (1987) (15)
- Some reactions of the ethylenebis(phenylphosphido)dilithium reagent [{Li(THF)2}2(PhPCH2CH2PPh)]2, and its X-ray structure (1988) (14)
- Organolanthanide chemistry with bis(trimethylsilyl)methyl- and tert-butyldimethylsilyl-substituted cyclopentadienyl ligands. (1999) (14)
- The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls. (2005) (14)
- beta-Diiminato ligand (L) transformations in reactions of KL with PI3 and I2 [L = {N(C6H3Pr(i)2-2,6)C(H)}2CPh]. (2007) (14)
- Chloroboration and allied reactions of unsaturated compounds. Part VIII. Insertion of isocyanates and isothiocyanates into Al–Et and Al–Br bonds (1968) (14)
- Bonding studies of compounds of boron and the Group IV elements. Part II. Ionisation potentials of boron halides and mixed halides by electron impact and by molecular orbital calculations (1968) (14)
- Amido-derivatives of metals and metalloids. Part XIV. Reactions of titanium(III) dimethylamides with protic or unsaturated reagents, or with metal hydrides (1971) (14)
- Unsaturated σ-hydrocarbyl transition-metal complexes. Part 2. Synthesis and reactions of vinylplatinum complexes and a comparison with analogous fluorovinyl and alkynyl complexes (1977) (14)
- The molecular structure of di-t-butylamine, NH[C(CH3)3]2, as determined by gas-phase electron diffraction: an exceptionally sterically hindered amine (1986) (14)
- Novel arylimides of phosphorus(III) and arsenic(III)[the arsazene being the first stable compound containing an asIIIN double bond]; X-ray structures of E(NAr)(NHAr)(E = P or As, Ar = C6H2But3-2,4,6) (1986) (14)
- Synthesis of ylideplatinum(II) complexes via α-functionalised alkylplatinum(II) intermediates and some comparative data on palladium(II) complexes; X-ray structure of trans-[Pt(CH2PEt3)I(PEt3)2]I (1982) (14)
- Organometallic diazoalkanes. Part I. Synthesis and characterisation of simple group IVB organometallic diazomethanes, and the tin–carbon cleavage reactions of bis(trimethylstannyl)diazomethane (1970) (14)
- Binuclear organometallic compounds. Part IX. Nuclear magnetic double resonance studies of tin-119 chemical shifts in compounds with transition metal-to-tin bonds (1975) (14)
- The reactions of lithium trimethysilylmethyls with isocyanides; structures and reactions of the derived lithium 1-azaallyls, β-diketiminates and a 1-azabuta-1,3-dienyl-3-amide (2001) (14)
- Synthesis, properties, and X-ray crystal structure of trans-dichlorotetrakis-(1,3-diethylimidazolidin-2-ylidene)ruthenium(II), a neutral tetracarbenemetal complex (1976) (14)
- Reactions of strained organosilicon heterocycles with nonacarbonyldi-iron(0). Part I. Reactivity and mechanism (1976) (14)
- Novel SnII−AgI Reactions from Sn[CH(SiMe3)2]2 and AgX (X = NCS, CN, NCO, or I): SnII−AgI or SnIVX2 Complexes (1998) (14)
- Unusual group 14 metal thiolates and sulphides derived from tris(trimethylsilyl)methanethiol; X-ray structures of [Pb(NR2)(µ-SCR3)]2 and cis-[Ge(CH2Ph)(NR2)(µ-S)]2, (R = SiMe3) (1985) (14)
- Coordination of Copper(I) in Two Novel Chlorocuprate(I) Anions; Structures of Tetramethylphosphonium Catena-mu-Chloro-mu3-chloro-[mu-chloro-dicuprate(I)] and Bis(tetramethylphosphonium) Trichlorocuprate(I). (1988) (14)
- Metallocene derivatives of early transition elements. Part 3. Synthesis, characterisation, conformation, and rotational barriers [for the Zr–C(sp3) bond] of the zirconium(IV) complexes [Zr(η-C5H4R)2{CH-(SiMe3)2}Cl] and the crystal and molecular structures of the t-butyl and trimethylsilyl complexes (1981) (14)
- Carbene complexes. Part V. Imidoyl chlorides as synthetic reagents, and the preparation of rhodium(III) carbene complexes from rhodium(I) precursors (1974) (14)
- Amino-derivatives of metals and metalloids. Part IV. Aminosilylation and aminophosphination of some unsaturated substrates (1966) (14)
- Variation of bonding modes in homoleptic tin(ii) 1-azaallyls (1997) (14)
- Ligand redistribution reactions as a route to cyclopentadienyl- or 1-aza-allylzirconium(IV) trichlorides and the x-ray structures of [{Cl2(μ-Cl)}2 and [2Cl2] LL′ = N(R)C(But)CHR, R=SiMe3] (1995) (14)
- The number of functional active sites per molecule of the adenosylcobalamin-dependent enzyme, ethanolamine ammonia-lyase, as determined by a kinetic method. (2005) (14)
- Neutral η-arene complexes of rhodium(I); X-ray structure of η-toluene(η-cyclo-octene)[bis{bis(trimethylsilyl)amido}chlorostannate(II)}]rhodium(I) (1985) (14)
- Reactions of Electron-Rich Olefins with Proton-Active Compounds (1997) (13)
- Iridium(III) hydrides derived from an iridium(I) substrate by oxidative addition and cyclometallation of germanium(II) bis(trimethylsilyl)amide; X-ray structures of [{CH2Me2SiN(R)(NR2)Ge}HIr(µ-Cl)2{Ge(NR2)N(R)SiMe2CH2}IrH{Ge(NR2)2}] and [lr{GeCl(NR2)N(R)SiMe2CH2}(CO)2H{Ge(NR2)2}](R = SiMe3) (1986) (13)
- Synthesis and characterisation of stable anionic group 3a dichlorometallocene(III) complexes and the X-ray structure of [AsPh4][Nd{η-C5H3(SiMe3)2}2Cl2] (1983) (13)
- Synthesis and structure of the NbIV metallocycle [M(η-C5H4SiMe3)2{CH2C6H4CH2-o}] (M = Nb, R = Me3Si) and reductive cleavage of d° analogues (M = Ti, Zr, OR Hf; R = H or Me3Si) by Na[C10H8] (1980) (13)
- First mixed valence cerium–organic trinuclear cluster [Ce3(OBut)10NO3] as a possible molecular switch: synthesis, structure and density functional calculations (2002) (13)
- Carbene complexes : IV. Far infrared and 31P NMR spectra of palladium and platinum carbene complexes (1974) (13)
- Cyclic Boron Compounds: VI. A BN Substituted Cyclobutadiene Analog. Synthesis Structure, Stereochemistry, and Mechanism of Formation (1964) (13)
- Co-ordination chemistry of tridentate phosphinothiolates; syntheses and structures of [Li4{PhP(C6H3S-2-SiMe3-3)2}2(MeOCH2CH2OMe)2], [Sn2{PhP(C6H3S-2-SiMe3-3)2}2] and [NHEt3][Sm{PhP(C6H3S-2-R-3)2}2(py)2]·2py (R = H or SiMe3, py = C5H5N) (1996) (13)
- Hypervalent silicon via intramolecular co-ordination in a four-membered ring system: synthesis and structure of SiCl2X[2-C(SiMe3)2C5H4N](X = H or Me); X-ray structures of the former complex and of SiCl2Me(2-CPh2C5H4N) (1990) (13)
- Synthesis, structure, and reactions of the first homoleptic lithium-arsenic compound, [Li(μ-AsR2)]3 (R = CH(SiMe3)2) (1987) (13)
- Heterotrimetallic salts: synthesis, structures, and superbase reactivity of crystalline tert-butoxides [Li4Na2K2(OtBu)8(mu-L)]n. (2008) (13)
- Use of the Bulky Alkyl Ligand (Me3Si)2CH-to Stabilize Unusual Low Valent Transition Metal Alkyls and Dialkylstannylene Derivatives (1976) (13)
- Alkylideneamido-derivatives of metals and metalloids. Part IV. 1,1-Bis(trifluoromethyl)methyleneamido-complexes of Group IVB metals (1973) (13)
- Reactions of silylallyl-lithium or -potassium compounds with ButCN; synthesis and structures of [M{N(SiMe2R)C(But)(CH)3SiMe2But}] [M = Li(tmen), R = Me; or M = K, R = But], [Li{N(SiMe3)C(But)>>CCHC(SiMe3)(CH2)2C>>H2}(tmen)] and [{Li[NC(But)>>CHCHC(SiMe3)(CH2)2C>>H2]}4] (tmen = Me2NCH2CH2NMe2) (1999) (13)
- beta-Diiminato complexes of arsenic including the formally AsI compound [As3L3] [L = [N(C6H3Pri2-2,6)C(H)]2CPh]. (2009) (13)
- The Thermally Stable Silylene Si[{N(CH2But)}2C6H4-1,2]: Reactivity toward CN Double Bonds (1997) (13)
- Synthesis of α-functionalised-alkylplatinum(II) complexes by oxidative addition of geminal dihalides to platinum(0) substrates; X-ray structure of cis-[Pt(CH2I)I(PPh3)2] (1981) (13)
- Synthesis and characterization of trimethylsilylmethyl-, bis(trimethylsilyl)methyl-and silyl-substituted cyclopentadienes and their alkali metal complexes1Dedicated to Professor Ken Wade, as a mark of friendship and as a recognition of his many contributions to chemistry.1 (1998) (12)
- 73. Infrared spectra of ethylene and o-phenylene derivatives of boric acid (1960) (12)
- Carbene complexes. Part 17. Crystal structure of trans-tetracarbonylbis(1,3-dimethylimidazolidin-2-ylidene)molybdenum(0), trans-[Mo(CO)4{CN(Me)CH2CH2NMe}2], structural comparison with the cis isomer, and a kinetic study of the trans→cis isomerisation (1981) (12)
- Lanthanide metal(III) heteroleptic alkyls: synthesis of [LnR3(µ-Me)Li(pmdeta)][Ln = La or Sm, R ={CH(SiMe3)2}, pmdeta =N,N,N′,N″,N″-pentamethyldiethylenetriamine] and X-ray structure of the samarium complex (1989) (12)
- Reactions of strained organosilicon heterocycles with nonacarbonyldi-iron(0). Part 2. Preparation and reactions of silaferracyclopentanes (1978) (12)
- Synthesis and molecular structures of copper(I) 1-azaallyls (1998) (12)
- A metallotricycle: synthesis, one-electron reduction, and crystal structure of the thermally robust complex tris-o-xylidenetungsten(VI), [W(CH2C6H4CH2-o)3] (1981) (12)
- Alkylideneamido-derivatives of metals and metalloids. Part III. The chemistry of alkylideneamino(trimethyl)stannanes (1973) (12)
- The synthesis and characterisation of di- and trinuclear vinylsilicon-(tertiary phosphine) complexes of platinum(0) and nickel(0) (1997) (12)
- Bis(trimethylsilyl)phosphinodithioformates, the phosphorus analogues of dithiocarbamates; X-ray structure of [Zr(cp)2(Cl)(η2-S2CPR2)] and its thermolysis product [{Zr(cp)2(µ-S)}2](cp =η-C5H5, R = SiMe3) (1987) (12)
- Synthesis and Reactivity of Novel Niobocene Complexes Containing Allyl or 1-Azaallyl Ligands. X-ray Crystal Structure of [Li{η3-N(SiMe3)C(tBu)CH2}]3 (1998) (12)
- The Chemistry of β-Diketiminatometal Complexes (2002) (12)
- Reactions of α-lithiated phosphinimines with PhCN; thecrystal structure of[K{N(H)C(Ph)C(H)P(Ph)2NSiMe3}(tmen)]2 (tmen =Me2NCH2CH2NMe2) (1997) (12)
- The synthesis and molecular structures of the crystalline 1-aza-2-phospha(V)allyllithium compounds [Li(LL′)(OEt2)2] and [Li(LL′)]2 [LL′ = CH(SiMe3)P(Ph)2NSiMe3] and the preparation and characterisation of the new phosphinimines CH(R1)(R2)P(Ph)2 NSiMe3 [R1 = R2 = SiMe3; R1 = H, R2 = Si(Me)2NEt2]† (1999) (12)
- Synthesis and characterization of N-silylated, C1-symmetric benzamidinates of lithium, sodium, and tin(II) (2006) (12)
- Free radicals as intermediates in the oxidative addition of alkyl halides to platinum(0) (1973) (12)
- 143. The interaction of aldehydes with boron trichloride (1957) (12)
- The stable silylene Si[(NCH2tBu)2C6H4-1,2]: insertion into LiC or LiSi bonds of lithium alkyls LiR or [LiSi(SiMe3)3(THF)3] [R=Me, tBu or CH(SiMe3)2] (2002) (12)
- Binuclear organometallic compounds. Part III. Metal–metal bond dissociation energies, Raman, and infrared spectra for the series (π-C5H5)(CO)3M1M2Me3: (M1= Cr, Mo, or W; M2= Ge or Sn) (1971) (12)
- Preparation and X-ray crystal structure of [Sn{N(SiMe3)2}2(µ-O2)]2, a rare example of a bis(1,2-µ-peroxo)-bridged metal complex (1992) (12)
- Chemistry of o-xylidene–metal complexes. Part 3. Tungste o-xylidene complexes derived from tetrachloro(oxo)tungsteh(VI); X-ray crystal structures of [W(CH2C6H4CH2-o)3]·0.5C6H6 and [{W(CH2C6H4CH2-o)2O}2Mg(C4H8O)4] (1984) (11)
- Diversity of triflate coordination modes in neodymocene complexes containing bulky bis(trimethylsilyl)cyclopentadienyl ligands (2006) (11)
- Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1-aza-allyl-lanthanide complexes; X-ray structures of [Sm(LL′)2I(thf)], [Yb(LL′)2] and [RNC(But)CH(R)]2 (thf = tetrahydrofuran, LL′ = η3-N(R)C(But)CHR, RSiMe3) (1997) (11)
- Reassignment to a manganese(II) species of an ESR spectrum attributed to Mn(CO)5 (1975) (11)
- 583. Preparation, stability, and complex formation of aryloxyboron compounds (1956) (11)
- Crystalline di- or trianionic metal (Al, Sm) beta-diketiminates. (2010) (11)
- Preparation, spectra and X-ray structure of an archetypal coordination compound [BCl3(NH3)] and its thermolysis (1995) (11)
- Crystalline alkyl-lithiums from α-trimethylsilyl-substituted o-xylenes; X-ray crystal structure of [{o-C6H4(CHSiMe3)2}{Li(tmeda)}2](tmedaMe2NCH2CH2NMe2) (1982) (11)
- Spontaneous N-aryl (rather than P-aryl) orthometallation in the system [RuCl2(PPh3)3]–[CN(Ar)(CH2)2NAr]2(Ar = C6H4Me-4); X-ray crystal and molecular structure of [RuCl(PEt3)2{CN(Ar)(CH2)2N(C6H3Me-4)}], a stereochemically rigid 5-co-ordinate RuII complex, with a short (2.2 Å) Ru …. H contact (1977) (11)
- Paramagnetic carbenemetal complexes. Part 2. Synthesis and spectroscopic studies of stable electron-rich olefin-derived paramagnetic carbenecarbonyl- and carbenenitrosyl-iron(I) complexes (1981) (11)
- Binuclear organometailic compounds. Part VII. Trimethylstannyl complexes of tantalum(V), molybdenum(IV), and tungsten(IV) (1973) (11)
- Bonding studies of transition-metal complexes. Part II. Helium-I photoelectron spectra of homoleptic d0,d1, and d10 tetrakis(dialkylamides) of transition and Group 4B metals and tungsten hexakis(dimethylamide) (1975) (11)
- The microwave spectra of 1-cyanoprop-2-yne HCCCH2CN) and 1-isocyanoprop-2-yne HCCCH2NC (1988) (11)
- Bonding studies of compounds of boron and elements of groups 3–5. Part 16.—Ab initio SCFMO calculations and He(I) photoelectron spectra of halogen-bridged dimeric group 3 metal halides and methylmetal halides (1976) (11)
- 1009. Reactions of the phenylboron chlorides and bromides and the chemistry of n-butyl phenylbromoboronite (1957) (11)
- Cyclic boron compounds. Part IX. Aldiminoboranes and their cyclic dimers (1969) (11)
- Synthesis, crystal structures and reactions of sila- and germa-β-diketiminates (2003) (11)
- A convenient route to vinylsiloxane-tertiary phosphine-nickel(0) complexes; the molecular structure of [(Ni{P(C6H4Me-4)3})2{μ-(L′′L′′)2}] {(L′′L′′)2=[CH2CH(Me)Si(μ-O)]4} (2000) (11)
- Amino derivatives of metals and metalloids as ligands (1965) (11)
- Lithium enamides, β-diketiminates and 1,3-diazaallyls from the 1:1 insertion of an isonitrile into the Li–C bond of LiCH(SiMe3)2†‡ (1998) (11)
- Transition-metal complexes with (CF3)2CN– as ligand and a tautomeric hydrogen transfer from metal to ligand (1971) (11)
- Hydrocarbon‐Soluble Homoleptic Bulky Aryl Oxides of the Lanthanide Metals: [Ln(OArR)3)] (2007) (11)
- The role of C-chlorocarbenemetal complexes in carbene– and carbyne–metal complex chemistry; experiments with [Cr(CO)5{C(Cl)NMe2}] and [Cr(CO)5(CNMe2)]+ (1976) (11)
- Stannadesulfurization of a bis(dimethyldithiocarbamato)tungsten(II) complex: formation of a coordinated bis(dimethylamino)acetylene complex (1990) (11)
- Synthesis of the 2,4,5-tri-tert-butyl-1,3-diphospholide anion by phosphinidene elimination from 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene on treatment with the amide Li[NPh(SiMe3)]. (2007) (11)
- Reactions of hydridosilacyclobutanes with low-valent complexes of iron or platinum (1978) (11)
- Stannadesulfurization of a bis(diethyldithiocarbamato)tungsten(II) complex. Formation of an aminocarbynetungsten complex (1990) (10)
- Transition-metal chemistry of dichloromethylene(dimethyl)ammonium chloride; C-chlorocarbene complexes (1975) (10)
- Reactions between a sodium amide Na[N(SiMe3)R1] (R1 = SiMe3, SiMe2Ph or But) and a cyanoalkane RCN (R = Ad or Bu(t)). (2006) (10)
- Carbene complexes. Part VI. Complexes from imidoyl chloride and rhodium(I) precursors, and the crystal and molecular structure of carbonyltri-iodo-[α-(N-methyl-α-methyliminobenzylamino)benzylidene-N,C]rhodium, I3(OC)Rh–CPh(NMe)CPh:NMe (1974) (10)
- Amido-derivatives of metals and metalloids. Part XIII. Dialkylamides of low-valent titanium: their preparation and properties (1971) (10)
- Amido derivatives of metals and metalloids. Part VIII. Metathetical reactions of organostannanes; their use in amination (1969) (10)
- Unusual metal alkyls (1978) (10)
- Chemistry of o-xylenediyl–metal complexes. Part 5. Silicon and tin metallacycles derived from o-C6H4(HR)2(R = H or SiMe3) (1992) (10)
- The preparation of esters of alkyl- and aryl-boronic acids (1955) (10)
- Bonding studies of transition–metal complexes. Part III. He(I) photoelectron spectra of three-co-ordinate homoleptic bis(trimethylsilyl)amides of scandium, titanium, chromium, iron, gallium, and indium (1976) (10)
- Reactions of 1,3,5-triazine with organolithium compounds containing trimethylsilyl substituents; X-ray structures of 1,3,5-triaza- and 1,3,5,7-tetraaza-heptatrienyllithium compounds† (1999) (10)
- An e.s.r. study of the photochemistry of zirconocene(IV) alkyls and chlorides (1983) (10)
- A series of bis(η-cyclopentadienyl)uranium(III) dichloro-bridged-alkali-metal and dihalogenobis(η-cyclopentadienyl)uranate(III) complexes: single-crystal X-ray structure determination of [UCp″2(µ-Cl)2Li(pmdeta)] and [PPh4][UCp″2Cl2][Cp″=η-C5H3(SiMe3)2-1,3, pmdeta =(Me2NCH2CH2)2NMe] (1988) (10)
- Syntheses and structures of structurally diverse potassium beta-diketiminates derived from the ligand [(N(SiMe3)C(Ph))2CH]. (2002) (10)
- Syntheses and crystal structures of two ytterbocene complexes [Yb(η-Cp′′)2I(THF)] and [Yb(η-Cp′′)2(μ-Cl)2Li(THF)2] (Cp′′=C5H3(SiMe3)2-1,3) (2000) (10)
- 1‐Azaallyl Complexes of NiII, PdII, and TiIII (2000) (10)
- Two crystalline toluene-soluble 1,2-organobis(phenylphosphido)dilithium compounds. The monomeric 1,2-C6H4(PPh)2[Li(TMEDA)]2 and the dimeric [(PhPCH2CH2PPh) {Li(THF)2}2]2☆ (1987) (10)
- Metal complexes derived from the o-xylylidene ligand, o-C6H4(CH2–)2, and the X-ray crystal and molecular structure of the metallocycle [Zr(η-C5H5)2{(CH2)2C6H4-o}] (1980) (10)
- The initiation of polymerization by inorganic amides (1968) (10)
- Preparation and X-ray characterisation of the first heteroleptic hydrocarbon-soluble tin(II) pseudohalide, Sn(NCS)[N(SiMe3)2] (1992) (10)
- Synthesis and structures of dilithium (1,2-diphosphido)-benzenes (1995) (10)
- Free-radical displacement reactions at a transition-metal centre: bimolecular homolytic substitution (SH2) at square-planar PtII (1973) (10)
- Cyclic boron compounds. Part VIII. Amino- and hydrazino-boranes and their cyclic dimers (1966) (10)
- Metal-metal bonds between elements of group IVA and group IVB (1968) (10)
- Synthesis and structures of the transition metal(II) β-diketiminates [ML2] (M = Mn, Fe, Ni, Cu, Pd), [ML2′] (M = Ni, Cu) and [M(η3-C3H5)L] (M = Ni, Pd); L or L′ = [{N(SiMe3 or H)C(Ph)}2CH] (2009) (10)
- 798. Chloroboration and allied reactions of unsaturated compounds. Part I. Chloroboration and organoboration of isocyanates and isothiocyanates (1963) (10)
- Nuclear magnetic resonance studies of π-bonding in aminoboranes. Part 2.—Barrier to internal rotation about the boron-nitrogen bond (1968) (10)
- Synthesis and structures of the 1,3-diphospha-2-metallapentanes [LnM{P(Ph)C6H4PPh}][MLn= ZrCp″2(2), rac-SnR2(3), SnMe2, or BAr; Cp″=η-C5H3(SiMe3)2-1,3, R = CH(SiMe3)2, Ar = C6H2But3-2,4,6]; X-ray structures of complexes (2) and (3) (1989) (10)
- Synthesis, properties, and crystal structure of octaethylporphin bis[cis-dicarbonyldichlororhodate(I)][oepH4]2+2[RhCl2(CO)2]– and some new reactions of Co(oep) derivatives (1974) (10)
- Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5‐Pentamethylcyclopentadienyl)Ytterbium (2007) (10)
- Bulky alkyls and a hydridoalkyl of zirconium(IV): influence of steric constraints upon (i) conformation and the Zr–C rotational barrier and (ii) the Zr–C bond length. X-Ray crystal and molecular structure of [zr(η-C5H5)2{CH(SiMe3)2}Ph] (1978) (10)
- Reactions of 1,3,5-triazine with organolithium compounds yielding 1,4-dihydrotriazines or the ring-opened products, a 3-lithio-1,3,5,7-tetraazaheptatriene or -1,3,5-triazaheptatriene† (1997) (10)
- Amides of rhodium(I) and ruthenium(II), [Rh(NR2)(PPh3)2] and [RuH(NR2)(PPh3)2](R = Me3Si): novel low co-ordination number d8 and d6 metal complexes (1979) (10)
- Lower valent dialkylamides of titanium and vanadium (1969) (10)
- 373. Cyclic organic boron compounds. Part V. Infrared spectra of borazoles and boroxoles (1961) (10)
- The molecular structure of dimeric bis(trimethylsilyl)amidolithium, [LiN(Si(CH3)3)2]2, as determined by gas-phase electron diffraction (1984) (10)
- Enthalpies of combustion of five sterically hindered amines (1981) (9)
- Metal complexes derived from a bidentate ligand possessing two chiral centres, o-C6H4[CH(SiMe3)–]2; stereospecific synthesis of the meso-metallocycles [M{CH(SiMe3)C6H4CH(SiMe3)-o}(η-C5H5)2] and their reversible one-electron reduction (1980) (9)
- 730. The chemistry of certain acyloxyboron compounds and boron chelates (1958) (9)
- Boron Chemistry — 4 : edited by R.W. Parry and G. Kodama, Pergamon Press, Oxford — New York — Toronto — Sydney — Paris — Frankfurt, 1980, viii + 161 pages, £22.00, $49.50. (1981) (9)
- 62. Reaction in boron trichloride–cyclic ether systems (1957) (9)
- Synthesis, X-ray crystal structure and solution NMR spectroscopic studies of [Li{N(H)C(Me)C(H)(CN)}(py)2]2(py = NC5H5) (1996) (9)
- 785. Pseudohalides. Part II. Preparation, characterisation, and reactions of 3-co-ordinate mononuclear iso- and isothio-cyanatoboranes (1965) (9)
- Lipophilic metal (Na, TiIII ZrIV, Rh1 and PdII) complexes derived from the hybrid ligands -or and hor (R = Me2PCH2CBut2); the X-ray structures of [t[graphic ommitted]Me2)2] and trans-[R[graphic ommitted]H)2] (1993) (9)
- 1008. Infrared spectra of open-chain boron–nitrogen compounds (1960) (9)
- Paramagnetic carbenemetal complexes. Part 1. Cationic chromium(I) complexes and the chemistry of their chromium(0) precursors and of related molybdenum(0) and Tungsten(0) complexes, especially with bulky carbene ligands C(OR′)R[R CH(SiMe3)2 or CH2SiMe3] (1980) (9)
- meta- and para-Bis[zirconyl(IV)amino]cyclophanes; 1,3- or 1,4-C6H4[N(SiMe3)]2 as bridging ligands† (1999) (9)
- Crystal Structure and Excited Optical Nonlinearity of a 1D Polymeric [W2O2S6Cu4(NCMe)4]n Cluster (2004) (9)
- Dimetallostannylene-transition-metal complexes (1990) (9)
- Metal-substituted silacyclobutanes. 2. Derivatives of silicon, germanium, and tin (1978) (9)
- Metal–silacyclobutane complexes. Part 1. Derivatives of iron and manganese (1978) (9)
- Photoelectron spectra and energy level trends in MenSiCl4-nand related series. (1971) (9)
- Aspects of the Chemistry of the Cyclic Phosphonium Salt [Ph2PaP(Cl)N(SiMe3)C(tBu)=CbH(Pa–Cb)]Cl and the Related Diazadiphosphetidine [ClPaN(R)P(Cl)NbR(Pa–Nb)] [R = C(tBu)=C(H)SiMe3] (1998) (9)
- The trans-influence of the ligand trimethylsilylmethylide (Me3SiCH2–) in platinum(II) complexes and the crystal structure of a platinum(II) alkyl (1972) (9)
- Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C4tBu4: crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6). (2008) (9)
- Stereospecific synthesis of a metallo-enolate: E-[Zr{OC(SiMe3)CHAr}Cl(η-C5H5)2](structurally characterised)via carbonylation of [Zr{CH(SiMe3)Ar}Cl(η-C5H5)2](Ar = 9-anthryl) (1985) (9)
- Synthesis and characterisation of a novel macrocyclic vinylsiloxane-based tris(alkene)nickel(0) complex (1995) (9)
- Synthesis and structures of crystalline lithium 1-azaallyls and a 1,3-diazaallyl derived from Li{CH(SiMe3)(SiMe3−n(OMe)n)} (n=1 or 2) and Li{CH(SiMe2OMe)2} and RCN (R=tBu, Ph, 2,5-Me2C6H3, or Ad) (2003) (9)
- Coenzyme B12-dependent enzyme reactions. I. Emission Mössbauer spectroscopic study of ethanolamine ammonia lyase a coenzyme B12-dependent enzyme. (1974) (8)
- Ziegler-type systems as catalysts for hydrosilylation: linear dimerisation with terminal acetylenes (1972) (8)
- Electron spin resonance of t-alkyl-, silyl-, and germyl-aminyl radicals and some observations on the amides MBr{N(SiMe3)2}3(M = Ge, Sn, or Pb) (1980) (8)
- 568. Cyclic organic boron compounds. Part I. Preparation, characterisation, and stability of esters of metaboric acid (1958) (8)
- Synthesis and structure of the silylated benzene radical anion salts [K([18]crown-6){C6H4(SiMe3)2-1,4}] and [K([18]crown-6)(THF)2][C6H2(SiMe3)4-1,2,4,5] (2011) (8)
- 1-[(π-Cyclopentadienyl)dicarbonyliron]-1-methylsilacyclobutane and related iron-substituted silacyclobutanes (1973) (8)
- 23.1 – Zirconium and Hafnium: Introduction (1982) (8)
- 226. Interaction of boron trichloride with optically active alcohols and ethers (1951) (8)
- Stable paramagnetic carbenemetal complexes; syntheses and properties of low spin d7(1,3-dimethylimidazolidin-2-ylidene)iron(I) tetrafluoroborates (1977) (8)
- Effect of successive fluorination on the structure of cyclopropane (1988) (8)
- Donor-acceptor complexes of mixed boron trihalides (1971) (8)
- The He(I) and He(II) photoelectron spectra of bis(2,4,6-tri-t-butylphenyl)-diphosphene (1983) (8)
- Synthesis of the sterically hindered complexes [M(CO)5(CNBR2)][R=CH(SiMe3)2; M = Cr, Mo, or W]. Crystal structure of [Cr(CO)5(CNBR2)] (1994) (8)
- Sodium and potassium 3-sila-β-diketiminates show new coordination modes (2002) (8)
- Synthesis and structures of some new types of lithium beta-diketiminates. (2008) (8)
- Reactions of M[CH(SiMe3)2] (M = Na or K) with PhCN, and related chemistry. (2006) (8)
- Synthesis and structures of 3-sila-β-diketiminato complexes of the coinage metals (2007) (8)
- Preparation of organoboranes relative reactivities of competing sites towards organolithium and -magnesium compounds (1966) (8)
- Mössbauer spectra of some organotin compounds of type R3SnX (1971) (8)
- The role of oxygen in chemistry and biochemistry (Studies in inorganic chemistry 33) (1988) (8)
- Organometallic diazoalkanes. Part II. Heterocyclic syntheses with the co-ordinated ligand CN22–; reactions of trimethylstannyl- and trimethylsilyl-diazoalkanes (1971) (8)
- Metal halide complexes of hexamethylcyclotriphosphazatriene (1966) (8)
- An Ab Initio Molecular Orbital Calculation of the Molecular Structure and Conformational Preferences of Imidazolidine and 1,3-Dioxolane. (1988) (8)
- Subvalent Group 14 metal compounds. Part 10. Syntheses and structures of some bis(metallo)plumbylenes [Pb{Mo(R)(CO)3}2(OC4H8)][R =?-C5H5, ?-C5H3(SiMe3)2-1,3, or ?-C5Me5]; X-ray crystal structures of [Pb{Mo(?-C5Me5)(CO)3}2(OC4H8)] and [{Pb[Mo(?-C5Me5)(CO)3][Mo(?-C5Me5)(CO)2(-CO)]}2] (1987) (8)
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- Synthesis and structure of an azatrisilacyclobutane and its precursor, a novel lithium enamide having a tricyclic (LiNSiO)2 skeleton. (2002) (8)
- 1,3-Organometallic insertion reactions with trimethylsilyldiazomethane: synthesis of (trimethylsilyl)methylazo–transition metal complexes (1969) (8)
- SantaCoder: don't reach for the stars! (2023) (7)
- Divinyldisiloxane and divinylsilane complexes of rhodium(I) (1999) (7)
- Catalysis and Chemical Processes (1982) (7)
- Subvalent Amides of Silicon and the Group 14 Metals (2008) (7)
- 432. Interaction of boron trichloride and amides or oximes, and allied reactions (1960) (7)
- 176. Interaction of boron and hydrogen halides with esters of boronic acids (1956) (7)
- 1308. Thermochemistry of the complexes of boron trifluoride with dimethyl sulphoxide and ethyl acetate, and the thermal decomposition of the diphenyl sulphoxide–boron trichloride complex (1965) (7)
- Formation of co-ordinated diphenylketen from carbon monoxide and an alkylzirconocene(IV) benzhydryl complex: X-ray structure of [{Zr(η-C5H5)2(OCCPh2)}]2 (1982) (7)
- Group 6 metallocene(IV)–main group metal complexes: synthesis and structures of a Mo–B–Li compound and of [W(η-C5H5)2H{SnCl2CH(SiMe3)2}] (1995) (7)
- Amido-derivatives of metals and metalloids. Part V. Lewis acid behaviour of certain borazines and aminoboranes (1967) (7)
- New Approach to anionic transition metal alkyls; synthesis and e.s.r. characterisation of the d1 dialkylmetallate(III)'s [M(η-C5H4R1)2R22]–(M = Ti, Zr, or Hf) (1979) (7)
- The synthesis, structure, and reactions of some simple unsaturated σ-hydrocarbylplatinum(II) complexes (1973) (7)
- Reactions of trialkyltin acetylides with some low oxidation state transition metal complexes: Oxidative addition, oxidative cleavage, and alkynylation (1972) (7)
- Complexes containing the [TeCl4X]− moiety (X = Cl or an aryl group) (2009) (7)
- Coenzyme B-12-dependent reactions. Part IV. Observations on the purification of ethanolamine ammonia-lyase. (1976) (7)
- Spectroscopic and electronic properties of 1-azaallylmetal(I) (M = Cu or Au) complexes; molecular structure of [{Au[µ-N(R)C(Ph)CR2]}2] (R = SiMe3) (1999) (7)
- Pseudohalides. Part III. Infrared, ultraviolet, and proton magnetic resonance spectra of boron isocyanates and isothiocyanates (1967) (7)
- Binuclear organometallic compounds. Part II. Reactions of triorganotin hydrides with iridium(I) and rhodium(I) complexes (1970) (7)
- Homogenous Catalysis V. Hydrosilylation of Dienes with Octacarbonyldicobalt(0) (2011) (7)
- Synthesis and structures of four crystalline lithium β-diketiminates derived from [Li{CH(SiMe3)(SiMe2OMe)}]8 and PhCN or ButCN and PhCN (2004) (7)
- Synthesis and characterisation of a series of 1,2-phenylenedioxoborylcyclopentadienyl-metal complexes (Ti(IV), Zr(IV), Hf(IV), La(III), Ce(III), Yb(III), Sn(II) and Fe(II)) (2005) (7)
- Unusual, thermally stable, sublimable aminoboranes B(NHAr)X2(X = Cl, F, or NH2); X-ray crystal structure of bis(amino)(2,4,6-tri-t-butylphenylamino)borane, B(NH2)2(NHAr) (1984) (7)
- 761. The preparation and properties of di-n-butylboronous anhydride (1957) (7)
- Synthesis and crystal structures of novel 1-aza-2-silacyclobut-3-enes (2002) (7)
- 438. The preparation and properties of co-ordination compounds of boron trichloride and nitriles (1960) (7)
- Bonding studies of compounds of boron and the Group III and IV elements.: XII. Variable temperature He I photoelectron spectra of Group III halides, 2MX3 ⇌ M2X6 (M = Al or Ga, X = Cl, Br, or I) (1974) (7)
- Bonding studies of compounds of boron and the group IV elements. Part III. First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method (1970) (7)
- Chloroboration and allied reactions of unsaturated compounds. Part VI. Thiaboration, and other aspects of boron–sulphur chemistry (1967) (6)
- Boron Chemistry (1967) (6)
- Synthesis and characterisation of three dinuclear β-dialdiminatobismuth(III) dihalides (2010) (6)
- 731. The infrared spectra and structures of some acyloxy-derivatives of boron (1958) (6)
- Gmelin Handbook of Inorganic Chemistry. 8th Edition, Sc, Y, La-Lu, Rare Earth Elements. Part D 6. Ion Exchange and Solvent Extraction Reactions. Organometallic Compounds (1984) (6)
- Synthesis and structures of the dinuclear tin(II) complexes [R = Ph, X(Z) = CPh; R = SiMe3, X(Z) = PPh2] and of related compounds (2009) (6)
- Synthesis and Structures of Five Crystalline Organometallic (Li/Y, Mg/Mg) or Coordination (Mg, CrII, Y/Y) Complexes † (2011) (6)
- Edge inversion in tricoordinated main group IV anions (1991) (6)
- Amido-derivatives of metals and metalloids. Part IX. Reactions of tin(IV) and titanium(IV) amides with compounds having carbonyl and sulphinyl multiple bonds (1969) (6)
- The co-ordination chemistry of electron-rich poly(organosulphur) compounds. Part 1. Chromium(0), molybdenum(0), and tungsten(0) complexes having tetrakis(thioalkyl)olefins as two- or four-electron donors: the crystal and molecular structure of tetracarbonyl[tetrakis(methylthio)ethene-SS″]chromium (1979) (6)
- Molecular vibrations of cyclo[d.e.e.d.e.e.d.e.e.[nonakisbenzene and the topology of primitive coronoids with trigonal symmetry (1988) (6)
- Bis[(Trimethylsilyl)Methyl] Magnesium (2007) (6)
- Inorganic and Organometallic Reaction Mechanisms (1986) (6)
- Carbene and related complexes of molybdenum derived from electron-rich olefins (1977) (6)
- 762. The properties of the anhydride and esters of diphenylboronous acid (1957) (6)
- A new approach to cationic transition metal alkyls: [M(η-C5H5)2(CH2SiMe3)2]+[Y]–(M = Nb or Ta, Y = BF4 or SbF6) and their conversion into the alkylidene complexes [M(η-C5H5)2(CHSiMe3)(CH2SiMe3)] (1978) (6)
- Boron halides as reagents in inorganic syntheses. Part IV. Preparation of tris-µ-chloro-hexabromo-triangulo-trirhenium(III)(3Re–Re) and Re3I9; halogen exchange reactions with Re3Cl9 and the crystal structure of a sublimation product of tris-µ-chloro-hexabromo-triangulo-trirhenium(III)(3Re–Re) (1972) (6)
- STEREOCHEMICAL NON-RIGIDITY IN A MACROCYCLIC VINYLSILOXANE-BASED TRIS(ALKENE)NICKEL(0) COMPLEX (1995) (6)
- A dilithium o-phenylenediphosphide [Li(tmeda)]2[C6H4(PR)2-1,2] as a [C6H4(PR–)2-1,2] or [C6H4(P2–)2-1,2] synthon: the X-ray structures of C6H4[PCH2CHOCMe2OCHCH2-RR]2-1,2 and [C6H4{P(SiBut-P)-1,2}]3(µ3-SiBut)(R = SiMe3, tmeda =[Me2NCH2]2) (1992) (6)
- Nuclear magnetic resonance studies of π-bonding in aminoboranes. Part I. Ambient temperature spectra (1968) (6)
- Bonding studies of compounds of boron and the Group 3–5 elements. Part XIV. Redistribution equilibria in phenylboron dihalide and boron trihalide systems (1975) (6)
- The molecular structure of a germene GeR2 (R = CH(SiMe3)2) by gas electron diffraction; Self-consistent-field molecular orbital calculations on stannene, SnH2, and distannene, Sn2H4 (1984) (6)
- Co-ordination chemistry of electron-rich poly(organosulphur) compounds. Part 2. Comparative data on reactions of di-µ-chloro-bis[chloro(triethylphosphine)platinum(II)], and the crystal and molecular structure of cis-µ-2,2-bis(methylthio)ethene-1,1-dithiolato-SS″ : S′S‴-bis[chloro(triethylphosphine)p (1979) (6)
- John Dalton, the man and his legacy: the bicentenary of his Atomic Theory (2003) (6)
- Electron-rich olefins as heteroatom donors; the crystal and molecular structures of µ-dimethylthioethene-1,1-dithiolato-SS′S″S‴-bis[chloro(triethyphosphine)platinum(II)] and tetrarbonyl-NN′N″N‴-tetramethylbi(imidazolidin-2-ylidene)-NN″-chromium(0) (1975) (6)
- Synthesis of Bis(bis(trimethylsilyl)amido)iron(II). Structure and Bonding in M(N(SiMe3)2)2 (M: Mn, Fe, Co): Two-Coordinate Transition-Metal Amides. (1988) (6)
- Participation of neighbouring transition-metal in the nucleophilic C–Si cleavage of π-C5H5(CO)3MoCH2SiMe3: possible formation of an anionic transition-metal carbene intermediate (1970) (6)
- 813. The interaction of ethylene glycol with boron trichloride and the alkoxyboron chlorides (1957) (5)
- Advances in inorganic biochemistry : edited by Gunther L. Eichhorn and Luigi G. Marzili, Vol. 1, 1979, Elsevier/North Holland, Amsterdam, 261 pages, US $ 24.50; Dfl. 50.00. (1980) (5)
- Synthesis and Characterization of a Series of 1, 2‐Phenylenedioxoborylcyclopentadienes (2003) (5)
- A new synthesis of metal-centred (e.g., Group iv element) radicals from an organometallic halide and an electron-rich olefin (1976) (5)
- Definitive evidence that the ESR spectrum observed during photolysis of Mn2(CO)10 in THF is due to octahedral high-spin (d5) manganese(II) (1976) (5)
- Structures and relative stabilities of benzenoid and ortho-quinonoid molecules containing the divalent groups −CH2−, −NH− and −O−: an ab initio study (1988) (5)
- The molecular structure of gaseous, monomeric bis(trimethylsilyl)methyl-lithium, LiCH(Si(CH3)3)2, as determined by electron diffraction (1985) (5)
- The preparation and stability of alkyl dichloroboronites (1955) (5)
- High yield syntheses and characterisation of a new zirconocene(II) dicarbonyl (Zr[η-C5H3(SiMe3)2]2(CO)2], a convenient precursor to various zirconocene(II or IV) complexes☆ (1984) (5)
- Mass spectra of sila-cyclobutane and -cyclobutene derivatives (1976) (5)
- Interaction of boron trichloride with chloro-alcohols and with cyclic ethers (1955) (5)
- Comprehensive Coordination Chemistry, Volume 2, Ligands : xvii + 1179 pages, ISBN 0-08-035945-5 (1988) (5)
- Chloroboration and allied reactions of unsaturated compounds. Part IX. Organometallic insertion reactions of diketen; synthesis of β-keto-enolates (1969) (5)
- Cyclic Boron Compounds: VII. Cyclic Boroureas and Borocarbamates (1964) (5)
- Light-induced conversion of ethane-1,2-diol or 2-aminoethanol into acetaldehyde in the presence of 8-methoxy-5′-deoxy-5′-adenosyl-cobalamin or a simpler cobalt(III) alkyl (1978) (5)
- Monomeric di-t-butylmethyleneaminoboranes (1972) (5)
- Bonding studies of compounds of boron and the Group IV elements. Part V. Boron-11 nuclear magnetic resonance data for the boron trihalides and mixed trihalides (1971) (5)
- C-Centred chiral metal alkyls,[MR*(Cl)(η-C5H5)2],rac- andmeso-[ZrR*2(η-C5H5)2][R* = CH(SiMe3)C6H4Me-o], and their one-electron reductions; reaction ofLi[CH(SiMe3)2](Me2NCH2CH2NMe2) with[MCl2(η-C5H5)2](M = Zr or Hf) (1997) (5)
- Bonding studies of compounds of the group IV elements: Ionisation potentials of the Me3M radicals (1969) (5)
- Alkylideneamido-derivatives of metals and metalloids. Part V. Complexes of the late transition metals with (CF3)2C:N– as ligand, and a tautomeric hydrogen transfer from metal to ligand (1973) (5)
- 558. Studies with boron trichloride and organic sulphides. Part I. The preparation and properties of di-n-butyl sulphide–boron trichloride (1953) (5)
- Aspects of the chemistry of a bulky zirconocene(III) chloride (1989) (5)
- 308. Stability, solvolysis, and co-ordination reactions of esters of boronic acids and their halogen derivatives (1956) (5)
- Synthesis, characterisation, and crystal structure of a tetra(phosphino)ethene [Ph]2 (1989) (5)
- Synthesis and structures of dinuclear low-coordinate lithium and zirconium(IV) complexes derived from the diamido ligands 1,3-(CH2C6H3R12)2C6H4(R1= Me or Pri) (2002) (5)
- Bonding studies of compounds of boron and the group IV elements. Part IV. Redistribution equilibria among the boron trihalides by 11B nuclear resonance (1971) (5)
- An N-lithio-indole from the reaction of LiCH(TMS)2 and PhNC. (2003) (5)
- Photolytic homolysis of the metal–carbon (sp3 or sp2) bond of alkyl or acyl transition-metal complexes: an electron spin resonance study using spin trapping; and a note on aminyl oxides [MLn{N(Ȯ)R}][MLn= Ru(CO)4(SiMe3), Os(CO)4(SiMe3), or Fe(η-C3H5)(CO)3; R = aryl] (1981) (4)
- Intramolecular free radical functionalisation of the methyl group of 5′-deoxyadenosine (1981) (4)
- Spectroscopic Properties of Inorganic and Organometallic Compounds, Volume 21 (1989) (4)
- Synthesis and X-ray crystal structure of a Wv metallocycle [{W(CH2C6H4CH2-o)2O}2Mg(tetrahydrofuran)4] (1981) (4)
- Phosphorus-Phosphorus Single or Double Bond Formation from PCl3-nRn(n = 1 or 2) and a Bis-imidazolidine Reducing Agent. (1986) (4)
- 19. The preparation of esters of diphenylboronous acid (1957) (4)
- Boron halides as reagents in inorganic syntheses. Part I. A general method for the preparation of anhydrous bromides and oxybromides, and a comment on reactions with elemental sulphur (1967) (4)
- Preliminary communicationThe molecular structure of a germene GeR2 (r = CH(Sime3)2) by gas electron diffraction; self-consistent-field molecular orbital calculations on stannene, SnH2, and distannene, Sn2H4 (1984) (4)
- A NEW SYNTHESIS OF DIVALENT GROUP 4B ALKYLS M(CH(SIME3)2 )2 (M = GE OR SN), AND THE CRYSTAL AND MOLECULAR STRUCTURE OF THE TIN COMPOUND (1976) (4)
- Amides of the Group 3 and Lanthanide Metals (2008) (4)
- Boron halides as reagents in inorganic syntheses. Part III. Preparation and characterisation of halogen- and pseudohalogen-bridged, binuclear, cationic complexes of platinum(II) (1972) (4)
- 135. Reaction sequences in alcohol–boron trichloride–pyridine systems (1953) (4)
- Metal Vapour Synthesis in Organometallic Chemistry (1980) (4)
- Novel α,ω-bis(trialkylsilyl)-allyl and -1-azapentadienyl ligands; structures of [Li{η3-CH(CHSiMe2But)2}(tmen)], [Li{N(SiMe3)CBut(CH)3SiMe2But}(tmen)] and [K{η4-N(SiMe2But)CBut(CH)3SiMe2But}]∞ (1996) (4)
- 1095. Co-ordination compounds having carboxylic esters as ligands. Part III. The thermochemistry of the complexes of ethyl acetate with group III halides (1965) (4)
- 325. Pseudohalides. Part I. Preparation, characterisation, and reactions of iso- and isothio-cyanatoborazoles (1963) (4)
- 290. Dephenylation reactions of phenylboron acids and esters (1958) (4)
- Introduction to this Special Issue (2002) (4)
- Synthesis of some low oxidation state organotitanium compounds (1989) (4)
- IUPAC. Coordination Chemistry-20, (Calcutta/India, 1979) : edited by D. Banerjea, 275 pages, Oxford, Pergamon Press, 1980 $ 75. (1981) (4)
- Photoelectron spectra of some sterically hindered phenols and related compounds (1983) (4)
- 40th anniversary issue (2004) (4)
- A zirconocene(IV) chloro-alkyl and dialkyl containing chiral α-cabon atoms, [Zr(η-C5H5)2(R*)(X)][R*= CH(SiMe3)C6H4Me-o, X = Cl or R*]: synthesis, stereoisomerism, and d1 reduction products (1981) (4)
- Effect of substituent dtp to optical properties of heterobimetallic M/Ag/S nest-shaped clusters (M = Mo, W) (2005) (4)
- Some 2,6-bis(dimethylamino)phenyl–mercury(II) and –boron complexes (2002) (4)
- Synthesis and structures of neutral and cationic 1-azaallylaluminium methyls† (1999) (3)
- Reactions in boron trifluoride-n-butyl alochol-tri-n-butyl borate systems (1955) (3)
- Synthesis and structures of crystalline Li, Al and Sn(II) 1-azaallyls and beta-diketiminates derived from [Li{mu,eta3-N(SiMe3)C(Ad)C(H)SiMe3}]2 (Ad = 1-adamantyl). (2008) (3)
- Synthesis and Structural Characterization of the First Neutral Homoleptic Lanthanide Metal(III) Alkyls: (LnR3) (Ln = La or Sm, R = CH(SiMe3)2). (1989) (3)
- Bis(silylaminodiarylphosphoranylsilylmethyl-C,N)-tin(II) and -lead(II) complexes and their precursors; structures of H(LL′), H(LL″), Sn(LL″)2 and Pb(LL″)2; [LL′]− = [CH(SiMe3)P(Ph)2NSiMe3]−, (2006) (3)
- Lanthanide(II) Complexes of the Dihydrotriazinido Ligand [N{C(Ph)=N}2C(tBu)Ph]− (2008) (3)
- Titelbild: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. 26/2006) (2006) (3)
- 561. Phenylchloroboronites and phenylboronates (1957) (3)
- Lithium Dibenzylamide, a Simple,Selective and Highly Efficient Catalyst for Isocyanate Cyclotrimerizationto Isocyanurate (2011) (3)
- SILYLMETHYL AND RELATED COMPLEXES. 7. BULKY, MONOMERIC, HEAVY GROUP III METAL L TRIALKYLS AND THE CRYSTAL AND MOLECULAR STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)METHYL)INDIUM (1981) (3)
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- Synthesis and characterisation of [AlMen{Si(SiMe3)3}3−n(thf)] (n = 1 or 2) (2007) (3)
- Heterocyclic syntheses with the co-ordinated ligand CN22–; reactions of bistrimethylstannyldiazomethane and trimethylsilyldiazomethane (1969) (3)
- Structural studies (gas electron diffraction, vibrational spectra, He(I) photoelectron spectra (PES), and molecular orbital calculations) on gaseous methylenebis(phosphane), CH2(PH2)2, and the PES of the series CH2(PXY)2 (XY HMe, HPri, Me2, PriCl, ButCl, or Cl2 (1988) (3)
- Steric effects in substitution reactions and isomerisations in square planar carbene and dicarbene complexes of rhodium(I) (1974) (3)
- MONOMERIC, VOLATILE BIVALENT AMIDES OF GROUP IVB ELEMENTS, M(NR(1)2)2 AND M(NR(1)R(2))2 (M=GE, SN OR PB, R(1)=ME3SI, R(2)=ME3C) (1975) (3)
- A monomeric aldiminoborane and evidence for BN π-bonding (1968) (3)
- Hydrostannation of some iridium(I) complexes (1968) (3)
- Contributions to the Chemistry of Carbenemetal Chemistry. (2006) (3)
- Ionisation potentials and β-bonding in the series Cl nB(NNfe2)3-n (1965) (3)
- Synthesis and structures of the [benzamidinato]3- complexes Li3(tmeda)(L1)]2 and [Li(thf)4][Li5(L2)(OEt2)2] [L1 = N(SiMe3)C(Ph)N(SiMe3) and L2 = N(SiMe3)C(C6H4-4)NPh]. (2011) (3)
- 23.2 - Cyclopentadienyl and Other Anionic π-Ligand Complexes of Zirconium and Hafnium (1982) (3)
- Organosilyl derivatives of zirconium, molydenum, and tungsten (1967) (3)
- Journal of Organometallic Chemistry Library 4 (1978) (2)
- Metal β-Diketonates and Allied Derivatives (1979) (2)
- SUBVALENT GROUP 4B METAL ALKYLS AND AMIDES. PART 4. AN ELECTRON SPIN RESONANCE STUDY OF SOME LONG-LIVED PHOTOCHEMICALLY SYNTHESIZED TRISUBSTITUTED SILYL, GERMYL, AND STANNYL RADICALS (1977) (2)
- Advances in Boron and the Boranes (1989) (2)
- Leaving no stone unturned: Pathways in organometallic chemistry (1995) (2)
- Studies on 1,2-phenylenedioxoborylcyclopentadienes and some of their metal (Ti, Zr, Fe) complexes (2006) (2)
- Synthesis and structures of beta-dialdiminatoantimony(III) halides and beta-dialdiminium hexahalogenoantimoniates. (2009) (2)
- TRIS(BIS(TRIMETHYLSILYL)METHYL)TIN(III), R3SN, AN UNUSUALLY STABLE STANNYL RADICAL, FROM PHOTOLYSIS OF R2SN (1974) (2)
- Lipophilic Strontium and Calcium Alkyls, Amides, and Phenoxides. X-Ray Structures of the Crystalline Square-Planar ((trans-Sr(NR′2)2(μ-1,4- dioxane))∞) and Tetrahedral (CaR2(1,4-dioxane)2); R′ = SiMe3, R = CH(SiMe3)2. (2010) (2)
- Li, Al, Sn and Zr Complexes of Bidentate N,N′-Centred Ligands (2001) (2)
- Boron halides as reagents in inorganic chemistry; synthesis of anhydrous metal bromides and binuclear halogen-bridged platinum(II) cations (1967) (2)
- [R = Me, Bu-t or CH(SiMe3)(2)] (2002) (2)
- SUBVALENT GROUP 4B METAL ALKYLS AND AMIDES. PART 1. THE SYNTHESIS AND PHYSICAL PROPERTIES OF KINETICALLY STABLE BIS(BIS(TRIMETHYLSILYL)METHYL)GERMANIUM(II), -TIN(II), AND -LEAD(II) (1977) (2)
- FREE-RADICAL DISPLACEMENT REACTIONS AT A TRANSITION-METAL CENTRE, BIMOLECULAR HOMOLYTIC SUBSTITUTION (S(H)2) AT SQUARE-PLANAR PT(II) (1973) (2)
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- CARBENE COMPLEXES PART 8, CHROMIUM(0), IRON(0)-, RHODIUM(I), IRIDIUM(I), NICKEL(II), PALLADIUM(II), PLATINUM(II), AND GOLD(I) MONO- AND OLIGO-CARBENE SPECIES FROM ELECTRON-RICH OLEFINS (1974) (2)
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- BONDING STUDIES OF TRANSITION-METAL COMPLEXES PART 2, HELIUM-I PHOTOELECTRON SPECTRA OF HOMOLEPTIC D(0), D(1), AND D(10) TETRAKIS(DIALKYLAMIDES) OF TRANSITION AND GROUP 4B METALS AND TUNGSTEN HEXAKIS(DIMETHYLAMIDE) (1975) (2)
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- Crystalline metal (Li, Mg, Ca, Sr, Ba, Sn, Pb) complexes of the new chelating N,N'-dianionic [1,2-N(R)C6H4(CH2NR)](2-) ligand (R = SiMe3, CH2Bu(t)). (2011) (1)
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- The chemistry of inorganic ring systems : by Ionel Haiduc. Part 1, 622 pages, Part 2, 575 pages. Wiley-Interscience, New York/London, 1970, 250 s per part. (1971) (0)
- UNUSUAL, THERMALLY STABLE, SUBLIMABLE (ARYLAMINO)DIHALOBORANES OR -DIAMINOBORANES: X-RAY CRYSTAL STRUCTURE OF BIS(AMINO)(2,4,6-TRI-TERT-BUTYLPHENYLAMINO)BORANE (1984) (0)
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- Carbene Complexes. Part 21. Synthesis and Characterization of Bis(carbene)molybdenum(II) Complexes and Dimetal(0) Complexes of the Group 6 Elements Containing Novel Bridging Bis(carbene) Ligands; X-Ray Structures of (Mo(CO)2(LEt)2(OSO (1988) (0)
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- BINUCLEAR ORGANOMETALLIC COMPOUNDS PART 9, NUCLEAR MAGNETIC DOUBLE RESONANCE STUDIES OF TIN-119 CHEMICAL SHIFTS IN COMPOUNDS WITH TRANSITION METAL-TO-TIN-BONDS (1975) (0)
- Syntheses and structures of structurally diverse potassium ??-diketiminates derived from the ligand [{N(SiMe3)C(Ph)}2CH]???Electronic supplementary information available: details of crystallography for 1???4 and further analytical data for 1???5. See http://www.rsc.org/suppdata/cc/b2/b205296b/ (2002) (0)
- Lipophilic metal (Na, TiIII, ZrIV, RhI and PdII) complexes derived from the hybrid ligands -OR and HOR (R = Me2PCH2CBut2) ; the X-ray structures of [TiCl(OCBut2CH2PMe2)2] and trans-[Rh(CO)Cl(PMe2CH2CBut2OH)2] (1993) (0)
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- UNSATURATED Σ-HYDROCARBYL TRANSITION-METAL COMPLEXES. PART 2. SYNTHESIS S AND REACTIONS OF VINYLPLATINUM COMPLEXES AND A COMPARISON WITH ANALOGOUS FLUOROVINYL AND ALKYNYL COMPLEXES (1977) (0)
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- SILYLMETHYL AND RELATED COMPLEXES. PART 6. PREPARATION, PROPERTIES, AND CRYSTAL AND MOLECULAR STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)METHYL)CHROMIUM(III), THE CHEMISTRY OF RELATED COMPOUNDS OF TITANIUM(III), VANADIUM(III), ZIRCONIUM(IV) (1978) (0)
- CHEMISTRY OF O-XYLIDENE-METAL COMPLEXES. PART 2. PREPARATION AND PROPERTIES OF THE O-XYLIDENE-METAL(IV) COMPLEXES (M(CH2C6H4CH2-O)(η-C5H4R)2) (M = TI, ZR, HF, NB: R = H, SIME3) AND ((M′(CH2C6H4CH2-O)2(OC4H8))N) (M′ = TI, ZR, HF): X-RA (1984) (0)
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- Synthesis, Characterization, and Crystal Structure of a Tetra(phosphino)ethene Cyclic (Ph-P-CH2-CH2-P(Ph)C=)2. (1989) (0)
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- HOMOLYSIS OF METAL‐CARBON AND METAL‐METAL BONDS, SPIN‐TRAPPING OF THE RESULTING CARBON‐ AND METAL‐CENTRED RADICALS (1975) (0)
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- HOMOGENEOUS CATALYSIS. VI. HYDROSILYLATION USING TRIS(PENTANEDIONATO)RHODIUM(III) OR TETRAKIS(μ-ACETATO)DIRHODIUM(II) AS CATALYST (1979) (0)
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- CO‐ORDINATION CHEMISTRY OF HEAVY‐ATOM GROUP IV DONORS, AND THE CRYSTAL AND MOLECULAR STRUCTURE OF ((ME3SI)2CH)2SNCR(CO)5 (1975) (0)
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- CARBENE COMPLEXES PART 5, IMIDOYL CHLORIDES AS SYNTHETIC REAGENTS, AND THE PREPARATION OF RHODIUM(III) CARBENE COMPLEXES FROM RHODIUM(I) PRECURSORS (1974) (0)
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- SILYLMETHYL AND RELATED COMPLEXES PART 3, REACTION OF (TRIMETHYLSILYL)METHYL OR NEOPENTYL ALKYLATING REAGENTS WITH CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I), STERIC ACCELERATION TO DECOMPOSITION OF THE PRESUMED TRANSITION METAL ALKYL I (1974) (0)
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- CARBENE COMPLEXES. PART 10. ELECTRON-RICH OLEFIN-BASED MONO-, BIS-, AND TRIS-CARBENE-TUNGSTEN(0) COMPLEXES AND SOME DERIVED SIX- AND SEVEN-COORDINATE MONO- AND BIS-CARBENE-DIHALOGENOTUNGSTEN(II) AND RELATED MOLYBDENUM(II) SPECIES (1977) (0)
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- Subvalent Group 14 Metal Compounds. Part 11. Oxidative Addition Reactions of Organic Halides or Acid Anhydrides (Including CH4-nCln, PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to Some Bivalent Group 14 Metal Amides or Alkyls. (1988) (0)
- CARBENE COMPLEXES PART 7, CHLOROMETHYLENEAMMONIUM CHLORIDES, ELECTRON-RICH CARBENOIDS, AS PRECURSORS TO SECONDARY CARBENE METAL COMPLEXES, CRYSTAL AND MOLECULAR STRUCTURE OF TRICHLORO(DIMETHYLAMINOMETHYLENE)BIS(TRIETHYLPHOSPHINE)RHODI (1974) (0)
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- A NEW ONE-POT ARYLACETYLENE SYNTHESIS : 4-RC6H4CC(TMS) FROM 4-RC6H4CN AND LIC(TMS)3(THF)2 VIA LIN(TMS)C(C6H4R-4)C(TMS)2(THF) (TMS = SIME3, R = H, F, B R, OME OR BUT) (1998) (0)
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- By Reaction with a Diazoalkane (2007) (0)
- CARBENE COMPLEXES. II. STERIC AND CONFOR (1978) (0)
- Reactions of Amides with 1,3‐, 1,4‐, or 1,5‐Dipoles By Ring Opening (2007) (0)
- An electrochemical and DFT study on selected beta-diketiminato metal complexes. (2006) (0)
- The Molecular Structure of Di-t-butylamine, NH(C(CH3)3)2, as Determined by Gas-Phase Electron Diffraction: an Exceptionally Sterically Hindered Amine. (1986) (0)
- Structure and Bonding 43. Bonding Problems, J.B. Goodenough, P. Hemmerich, J.A. Ibers, C.K. Jørgensen, J.B. Neilands, D. Reinen, R.J.P. Williams (Eds.). Springer-Verlag, Berlin/Heidelberg/New York (1981) (1981) (0)
- A METALLOTRICYCLE: SYNTHESIS, ONE-ELECTRON REDUCTION, AND CRYSTAL STRUCTURE OF THE THERMALLY ROBUST COMPLEX TRIS-O-XYLIDENETUNGSTEN(VI), (W(CH2C6H4CH2-O)3) (1981) (0)
- Advances in Organometallic Chemistry, Volume 19 : Edited by F.G.A. Stone and R. West, Academic Press, New York, 1981, ix + 318 pages, $54.50 (1982) (0)
- The Molecular Geometries of Coordination Compounds in the Vapour Phase, M. Hargittai, I. Hargittai. Elsevier, Amsterdam (1977), U.S. $39.25, Dutch Fl.74.00 (1977) (0)
- READY OXIDATIVE ADDITION OF AN ALKYL OR ARYL HALIDE TO A TIN(II) ALKYL OR AMIDE, EVIDENCE FOR A FREE-RADICAL PATH (1976) (0)
- Gmelin Handbook of Inorganic Chemistry, 8th Edition, Rh - Rhodium, Supplement Volume B2. Coordination Compounds with O- and N-Containing Ligands. (1984) (0)
- HOMOGENEOUS CATALYSIS. VII. THE CATALYSIS OF ISOPRENE HYDROSILYLATION USING METAL ATOMS (1979) (0)
- Aspects of the Chemistry of Subvalent Organic Compounds of Germanium, Tin and Lead; Synthesis and Structures of the Bis{bis(trimethylsilyl)amido}tin(IV) Chalcogenides (1996) (0)
- Inorganic chemistry. Chapter 6. Introduction (1977) (0)
- CARBENE COMPLEXES. 14. THE SYNTHESIS, STE (1978) (0)
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