Michael P. Doyle
#89,267
Most Influential Person Now
American chemist
Michael P. Doyle 's AcademicInfluence.com Rankings
Michael P. Doyle chemistry Degrees
Chemistry
#1538
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#2282
Historical Rank
#564
USA Rank
Physical Chemistry
#148
World Rank
#179
Historical Rank
#50
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Chemistry
Michael P. Doyle 's Degrees
- Bachelors Chemistry University of California, Berkeley
Why Is Michael P. Doyle Influential?
(Suggest an Edit or Addition)According to Wikipedia, Michael P. Doyle is a professor of chemistry at University of Texas at San Antonio. Doyle was awarded the George C. Pimentel Award in Chemical Education by the American Chemical Society in 2002. and elected as a Fellow of the American Association for the Advancement of Science in 1995.
Michael P. Doyle 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Catalytic carbene insertion into C-H bonds. (2010) (1241)
- Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides (1998) (1182)
- Recent Advances in Asymmetric Catalytic Metal Carbene Transformations. (1998) (929)
- Catalytic methods for metal carbene transformations (1987) (730)
- Oxidation of nitrogen oxides by bound dioxygen in hemoproteins. (1981) (562)
- Kinetics and mechanism of the oxidation of human deoxyhemoglobin by nitrites. (1981) (319)
- The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts (2014) (249)
- Highly enantioselective trapping of zwitterionic intermediates by imines (2012) (209)
- New aspects of catalytic asymmetric cyclopropanation (1998) (196)
- Ligand effects on dirhodium(II) carbene reactivities. Highly effective switching between competitive carbenoid transformations (1993) (195)
- Oxidation and reduction of hemoproteins by trioxodinitrate(II). The role of nitrosyl hydride and nitrite (1988) (191)
- Perspective on dirhodium carboxamidates as catalysts. (2006) (184)
- Electronic and steric control in carbon-hydrogen insertion reactions of diazoacetoacetates catalyzed by dirhodium(II) carboxylates and carboxamides (1993) (182)
- Electrophilic metal carbenes as reaction intermediates in catalytic reactions (1986) (182)
- Dirhodium(II) caprolactamate: an exceptional catalyst for allylic oxidation. (2004) (180)
- Alkyl nitrite-metal halide deamination reactions. 6. Direct synthesis of arenediazonium tetrafluoroborate salts from aromatic amines, tert-butyl nitrite, and boron trifluoride etherate in anhydrous media (1979) (166)
- Benzylic oxidation catalyzed by dirhodium(II,III) caprolactamate. (2005) (165)
- Dirhodium(II) tetrakis(carboxamidates) with chiral ligands. Structure and selectivity in catalytic metal-carbene transformations (1993) (164)
- Basic Organic Stereochemistry (2001) (162)
- Exceptionally high trans (anti) stereoselectivity in catalytic cyclopropanation reactions (1990) (160)
- Mechanistic investigation of oxidative Mannich reaction with tert-butyl hydroperoxide. The role of transition metal salt. (2013) (156)
- Silane reductions in acidic media. II. Reductions of aryl aldehydes and ketones by trialkylsilanes in trifluoroacetic acid. Selective method for converting the carbonyl group to methylene (1973) (155)
- Alkyl Nitrite-Metal Halide Deamination Reactions. 2. Substitutive Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Direct and Remarkably Efficient Conversion of Arylamines to Aryl Halides (1977) (149)
- The oxidative mannich reaction catalyzed by dirhodium caprolactamate. (2006) (149)
- Enantioselective Intramolecular Cyclopropanations of Allylic and Homoallylic Diazoacetates and Diazoacetamides Using Chiral Dirhodium(II) Carboxamide Catalysts (1995) (148)
- Highly effective catalytic methods for ylide generation from diazo compounds. Mechanism of the rhodium- and copper-catalyzed reactions with allylic compounds (1982) (147)
- The new chemical biology of nitrite reactions with hemoglobin: R-state catalysis, oxidative denitrosylation, and nitrite reductase/anhydrase. (2009) (142)
- High enantioselectivity in the intramolecular cyclopropanation of allyl diazoacetates using a novel rhodium(II) catalyst (1991) (140)
- Asymmeric formal [3 + 3]-cycloaddition reactions of nitrones with electrophilic vinylcarbene intermediates. (2011) (134)
- Exceptional selectivity in cyclopropanation reactions catalyzed by chiral cobalt(II)-porphyrin catalysts. (2009) (132)
- Correlations between catalytic reactions of diazo compounds and stoichiometric reactions of transition-metal carbenes with alkenes. Mechanism of the cyclopropanation reaction (1984) (130)
- Simple and sustainable iron-catalyzed aerobic C-H functionalization of N,N-dialkylanilines. (2013) (127)
- Oxidation of secondary amines catalyzed by dirhodium caprolactamate. (2007) (114)
- Intramolecular regioselective insertion into unactivated prochiral carbon-hydrogen bonds with diazoacetates of primary alcohols catalyzed by chiral dirhodium(II) carboxamidates. Highly enantioselective total synthesis of natural lignan lactones (1996) (103)
- Epoxides and aziridines from diazoacetates via ylide intermediates. (2001) (103)
- Rearrangements of Ylides Generated from Reactions of Diazo Compounds with Allyl Acetals and Thioketals by Catalytic Methods. Heteroatom Acceleration of the [2,3]-Sigmatropic Rearrangement (1984) (103)
- Catalytic asymmetric syntheses of quinolizidines by dirhodium-catalyzed dearomatization of isoquinolinium/pyridinium methylides--the role of catalyst and carbene source. (2013) (102)
- Allylic oxidations catalyzed by dirhodium caprolactamate via aqueous tert-butyl hydroperoxide: the role of the tert-butylperoxy radical. (2009) (96)
- Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions (1990) (95)
- Reductive deamination of arylamines by alkyl nitrites in N,N-dimethylformamide. A direct conversion of arylamines to aromatic hydrocarbons (1977) (94)
- Highly selective catalyst-directed pathways to dihydropyrroles from vinyldiazoacetates and imines. (2003) (92)
- Dirhodium(II) tetrakis[methyl 2-oxaazetidine-4-carboxylate]: a chiral dirhodium(II) carboxamidate of exceptional reactivity and selectivity. (2000) (91)
- Asymmetric synthesis of lactones with high enantioselectivity by intramolecular carbon-hydrogen insertion reactions of alkyl diazoacetates catalyzed by chiral rhodium(II) carboxamides (1991) (90)
- Effective Uses of Dirhodium(II) Tetrakis[methyl 2-oxopyrrolidine-5(R or S)-carboxylate] for Highly Enantioselective Intermolecular Cyclopropenation Reactions (1994) (90)
- A new rhodium(II) phosphate catalyst for diazocarbonyl reactions including asymmetric synthesis (1992) (90)
- Synthesis of nitrogen-containing polycycles via rhodium(II)-induced cyclization-cycloaddition and insertion reactions of N-(diazoacetoacetyl)amides. Conformational control of reaction selectivity (1991) (90)
- Copper-Catalyzed Divergent Addition Reactions of Enoldiazoacetamides with Nitrones. (2016) (87)
- Rhodium(II) acetate and nafion-H catalyzed decomposition of N-aryldiazoamides. An efficient synthesis of 2(3H)-indolinones (1988) (85)
- Control of chemoselectivity in catalytic carbenoid reactions. Dirhodium(II) ligand effects on relative reactivities (1992) (85)
- Cycloaddition reactions of enoldiazo compounds. (2017) (84)
- Stereoselectivity of catalytic cyclopropanation reactions. Catalyst dependence in reactions of ethyl diazoacetate with alkenes (1984) (82)
- Stereocontrol in Intermolecular Dirhodium(II)-Catalyzed Carbonyl Ylide Formation and Reactions. Dioxolanes and Dihydrofurans. (1997) (82)
- Chiral catalyst controlled diastereoselection and regioselection in intramolecular carbon-hydrogen insertion reactions of diazoacetates (1996) (80)
- C-H functionalization. (2012) (80)
- Efficient aziridination of olefins catalyzed by mixed-valent dirhodium(II,III) caprolactamate. (2005) (79)
- Autocatalytic oxidation of hemoglobin induced by nitrite: activation and chemical inhibition. (1985) (79)
- Synthesis of tetrahydropyridazines by a metal-carbene-directed enantioselective vinylogous N-H insertion/Lewis acid-catalyzed diastereoselective Mannich addition. (2012) (78)
- Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates (1994) (78)
- Silane reductions in acidic media : VIII. Boron trifluoride catalyzed organosilane reductions. selectivity and mechanism (1976) (77)
- A novel three-component reaction catalyzed by dirhodium(II) acetate: decomposition of phenyldiazoacetate with arylamine and imine for highly diastereoselective synthesis of 1,2-diamines. (2003) (77)
- A new class of chiral lewis acid catalysts for highly enantioselective hetero-Diels-Alder reactions: exceptionally high turnover numbers from dirhodium(II) carboxamidates. (2001) (75)
- A New and General Synthesis of α-Silyl Carbonyl Compounds by SI-H Insertion from Transition Metal Catalyzed Reactions of Diazo Esters and Diazo Ketones (1988) (74)
- High enantioselectivity for intermolecular cyclopropenation of alkynes by diazo esters catalyzed by chiral dirhodium(II) carboxamides (1992) (74)
- Development and Evaluation of a Prep Course for Chemistry Graduate Teaching Assistants at a Research University (2012) (74)
- Construction of β-lactams by highly selective intramolecular C-H insertion from rhodium(II) carboxylate catalyzed reactions of diazoacetamides (1988) (74)
- Intramolecular catalytic asymmetric carbon-hydrogen insertion reactions. Synthetic advantages in total synthesis in comparison with alternative approaches. (2011) (73)
- Hydrolysis, nitrosyl exchange, and synthesis of alkyl nitrites (1983) (71)
- Bicyclic pyrazolidinone derivatives from diastereoselective catalytic [3 + 3]-cycloaddition reactions of enoldiazoacetates with azomethine imines. (2013) (69)
- A donor-acceptor cyclopropene as a dipole source for a silver(I) catalyzed asymmetric catalytic [3+3]-cycloaddition with nitrones. (2013) (66)
- Chiral catalysts for enantioselective intermolecular cyclopropanation reactions with methyl phenyldiazoacetate. Origin of the solvent effect in reactions catalyzed by homochiral dirhodium(II) prolinates (1996) (66)
- Enantioselective metal carbene transformations with polyethylene-bound soluble recoverable dirhodium(II) 2-pyrrolidone-5(S)-carboxylates (1992) (65)
- Chiral Catalysts for Enantioselective Carbenoid Cyclopropanation Reactions (1991) (65)
- Silane reductions in acidic media. I. Reduction of aldehydes and ketones in alcoholic acidic media. General synthesis of ethers (1972) (64)
- Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates. (2013) (63)
- Synthesis and catalytic reactions of chiral N-(diazoacetyl)oxazolidones (1985) (60)
- Enantiocontrol and regiocontrol in lactam syntheses by intramolecular carbon-hydrogen insertion reactions of diazoacetamides catalyzed by chiral rhodium(II) carboxamides (1992) (59)
- Highly Selective Enantiomer Differentiation in Intramolecular Cyclopropanation Reactions of Racemic Secondary Allylic Diazoacetates. (1996) (58)
- Rh(II)‐Catalyzed Isomerizations of Cyclopropenes Evidence for Rh(II)‐Complexed Vinylcarbene Intermediates (1990) (58)
- Enantiocontrol in the Generation and Diastereoselective Reactions of Catalytically Generated Oxonium and Iodonium Ylides. Metal-Stabilized Ylides as Reaction Intermediates (1998) (58)
- RHODIUM(II) PERFLUOROBUTYRATE CATALYZED HYDROSILYLATION OF 1-ALKYNES. TRANS ADDITION AND REARRANGEMENT TO ALLYLSILANES (1991) (57)
- Vinyldiazolactone as a vinylcarbene precursor: Highly selective C-H insertion and cyclopropanation reactions. (2006) (57)
- Rhodium(II)- and copper(II)-catalyzed reactions of enol diazoacetates with nitrones: metal carbene versus Lewis acid directed pathways. (2012) (57)
- Lewis acid promoted reactions of diazocarbonyl compounds. 3. Synthesis of oxazoles from nitriles through intermediate .beta.-imidatoalkenediazonium salts (1980) (57)
- Rhodium(II) Perfluorobutyrate Catalyzed Silane Alcoholysis. A Highly Selective Route to Silyl Ethers (1990) (57)
- Propargylic oxidations catalyzed by dirhodium caprolactamate in water: efficient access to alpha,beta-acetylenic ketones. (2008) (57)
- Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement. (2012) (57)
- Cyclopropanation of .alpha.,.beta.-unsaturated carbonyl compounds and nitriles with diazo compounds. The nature of the involvement of transition-metal promoters (1982) (56)
- Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates. (2013) (56)
- Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate. (2007) (55)
- Conformational and electronic preferences in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed carbon-hydrogen insertion reactions of N,N-disubstituted diazoacetoacetamides (1989) (55)
- Involvement of peroxide and superoxide in the oxidation of hemoglobin by nitrite. (1982) (54)
- ASYMMETRIC RHODIUM CARBENOID INSERTION INTO THE SI-H BOND (1996) (54)
- Contemporary Carbene Chemistry (2013) (53)
- Divergence of carbonyl ylide reactions as a function of diazocarbonyl compound and aldehyde substituent: dioxolanes, dioxolenes, and epoxides. (2004) (52)
- Highly stereoselective syntheses of five- and seven-membered ring heterocycles from ylides generated by catalytic reactions of styryldiazoacetates with aldehydes and imines. (2001) (52)
- Lewis Acid/Rhodium-Catalyzed Formal [3 + 3]-Cycloaddition of Enoldiazoacetates with Donor-Acceptor Cyclopropanes. (2015) (52)
- The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions (2002) (51)
- Rearrangements of oxocyclopropanecarboxylate esters to vinyl ethers. Disparate behavior of transition-metal catalysts (1983) (51)
- Addition/elimination in the rhodium(II) perfluorobutyrate catalyzed hydrosilylation of 1-alkenes. Rhodium hydride promoted isomerization and hydrogenation (1992) (51)
- Enhancement of enantiocontrol/diastereocontrol in catalytic intramolecular cyclopropanation and carbon-hydrogen insertion reactions of diazoacetates with Rh2(4S-MPPIM)4 (1995) (50)
- Multifunctionalized 3-hydroxypyrroles in a three-step, one-pot cascade process from methyl 3-TBSO-2-diazo-3-butenoate and nitrones. (2011) (50)
- Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl l-acyl-2-oxoimidazolidine-4(S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations (1996) (49)
- Formation of Macrocyclic Lactones by Enantioselective Intramolecular Cyclopropanation of Diazoacetates Catalyzed by Chiral CuI and RhII Compounds (1996) (49)
- Alkyl Nitrite-Metal Halide Deamination Reactions. 3. Arylation of Olefinic Compounds in the Deamination of Arylamines by Alkyl Nitrites and Copper(II) Halides. A Convenient and Effective Variation of the Meerwein Arylation Reaction (1977) (49)
- Divergent outcomes of carbene transfer reactions from dirhodium- and copper-based catalysts separately or in combination. (2011) (48)
- Catalytic Asymmetric [3+1]-Cycloaddition Reaction of Ylides with Electrophilic Metallo-enolcarbene Intermediates. (2017) (48)
- Highly enantioselective catalytic synthesis of functionalized chiral diazoacetoacetates. (2011) (48)
- Cationic chiral dirhodium carboxamidates are activated for Lewis acid catalysis. (2008) (48)
- Highly Enantioselective Intramolecular Cyclopropanation Reactions of N-Allylic-N-methyldiazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxamidates (1996) (46)
- Generation of Halomethyl Radicals by Halogen Atom Abstraction and Their Addition Reactions with Alkenes. (2019) (45)
- Enantiocontrolled macrocycle formation by catalytic intramolecular cyclopropanation (2000) (45)
- Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages. (2003) (45)
- A new approach to macrocyclization via alkene formation in catalytic diazo decomposition. Synthesis of patulolides A and B. (2000) (44)
- Macrocyclic lactones from dirhodium(II)-catalyzed intramolecular cyclopropanation and carbon-hydrogen insertion (1995) (44)
- Selectivity in reactions of allyl diazoacetates as a function of catalyst and ring size from gamma-lactones to macrocyclic lactones. (2000) (44)
- Dirhodium-catalyzed phenol and aniline oxidations with T-HYDRO. Substrate scope and mechanism of oxidation. (2011) (44)
- Vinyldiazo Reagents and Metal Catalysts: A Versatile Toolkit for Heterocycle and Carbocycle Construction (2018) (44)
- Facile catalytic methods for intermolecular generation of allylic oxonium ylides and their stereoselective[2,3]-sigmatropic rearrangement (1988) (43)
- Asymmetric hetero-Diels-Alder reaction catalyzed by dirhodium(II) carboxamidates. (2004) (43)
- Total synthesis of (S)-(+)-imperanene. Effective use of regio- and enantioselective intramolecular carbon-hydrogen insertion reactions catalyzed by chiral dirhodium(II) carboxamidates. (2002) (42)
- Highly selective γ-lactone syntheses by intramolecular carbenoid carbon-hydrogen insertion in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed reactions of diazo esters (1989) (42)
- Highly regioselective and stereoselective silylformylation of alkynes under mild conditions promoted by dirhodium(II) perfluorobutyrate (1994) (42)
- Highly Enantioselective Route to β-Lactams via Intramolecular C-H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates (1995) (42)
- Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds. (2017) (42)
- Preparation and Catalytic Properties of Immobilized Chiral Dirhodium(II) Carboxamidates (2002) (42)
- Effective and highly stereoselective coupling with vinyldiazomethanes to form symmetrical trienes. (2002) (42)
- Chiral Dirhodium Carboxamidates: Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams (1996) (41)
- A facile three-component one-pot synthesis of structurally constrained tetrahydrofurans that are t-RNA synthetase inhibitor analogues. (2004) (41)
- Highly Regio- and Enantioselective Formal [3 + 2]-Annulation of Indoles with Electrophilic Enol Carbene Intermediates. (2016) (40)
- Three-Component Cascade Reactions with 2,3-Diketoesters: A Novel Metal-Free Synthesis of 5-Vinyl-pyrrole and 4-Hydroxy-indole Derivatives. (2015) (40)
- Nitric Oxide Dissociation from Trioxodinitrate(II) in Aqueous Solution (1984) (40)
- Vinylogous reactivity of enol diazoacetates with donor-acceptor substituted hydrazones. Synthesis of substituted pyrazole derivatives. (2013) (40)
- Tandem sequence of phenol oxidation and intramolecular addition as a method in building heterocycles. (2012) (40)
- Highly efficient regioselective silylcarbonylation of alkynes catalyzed by dirhodium(II) perfluorobutyrate (1993) (39)
- Macrocyclic Cyclopropenes by Highly Enantioselective Intramolecular Addition of Metal Carbenes to Alkynes. (1999) (39)
- Silane reductions in acidic media. III. Reductions of aldehydes and ketones to alcohols and alcohol derivatives. General syntheses of alcohols, symmetrical ethers, carboxylate esters and acetamides (1974) (39)
- Tetrakis[(4S)‐4‐phenyloxazolidin‐2‐one]dirhodium(II) and Its Catalytic Applications for Metal Carbene Transformations (1993) (39)
- Highly enantioselective oxonium ylide formation and stevens rearrangement catalyzed by chiral Dirhodium(II) carboxamidates (1997) (38)
- Contemporary Carbene Chemistry: Moss/Contemporary Carbene Chemistry (2013) (38)
- Radical-Mediated Strategies for the Functionalization of Alkenes with Diazo Compounds. (2020) (38)
- Construction of highly functionalized diazoacetoacetates via catalytic Mukaiyama-Michael reactions. (2008) (38)
- Silane reductions in acidic media. VII. Aluminum chloride catalyzed hydrogen-halogen exchange between organosilanes and alkyl halides. An efficient hydrocarbon synthesis (1976) (38)
- Recent advances in stereoselective synthesis involving diazocarbonyl intermediates (1997) (38)
- Chiral Dirhodium(II) Catalysts for Selective Metal Carbene Reactions (2015) (38)
- Catalyst Selection for Metal Carbene Transformations (2001) (37)
- Optimization of Enantiocontrol for Carbon-Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3-Aryl-l-propyl Diazoacetates in High Optical Purity (1995) (37)
- ALKYL NITRITE‐METAL HALIDE DEAMINATION REACTIONS. 2. SUBSTITUTIVE DEAMINATION N OF ARYLAMINES BY ALKYL NITRITES AND COPPER(II) HALIDES. A DIRECT AND REMARKABLY EFFICIENT CONVERSION OF ARYLAMINES TO ARYL HALIDES (1977) (37)
- Highly enantioselective carbonyl-ene reactions of 2,3-diketoesters: efficient and atom-economical process to functionalized chiral α-hydroxy-β-ketoesters. (2014) (37)
- Diazo Esters as Dienophiles in Intramolecular (4 + 2) Cycloadditions: Computational Explorations of Mechanism. (2017) (37)
- Efficient Alternative Catalysts and Methods for the Synthesis of Cyclopropanes from Olefins and Diazo Compounds (1981) (37)
- Catalytic conversion of diazocarbonyl compounds to imines: applications to the synthesis of tetrahydropyrimidines and β-lactams. (2014) (37)
- Lewis acid catalyzed indole synthesis via intramolecular nucleophilic attack of phenyldiazoacetates to iminium ions. (2009) (37)
- Dirhodium(II) Tetrakis[alkyl 2-oxaazetidine-4(S)-carboxylates]. A New Set of Effective Chiral Catalysts for Asymmetric Intermolecular Cyclopropanation Reactions with Diazoacetates (1996) (37)
- Dirhodium(II)-Catalyzed Annulation of Enoldiazoacetamides with α-Diazoketones: An Efficient and Highly Selective Approach to Fused and Bridged Ring Systems. (2016) (37)
- Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles (2018) (36)
- Divergent stereocontrol of acid catalyzed intramolecular aldol reactions of 2,3,7-triketoesters: synthesis of highly functionalized cyclopentanones. (2012) (35)
- Enantioselective cis-β-lactam synthesis by intramolecular C-H functionalization from enoldiazoacetamides and derivative donor-acceptor cyclopropenes. (2015) (35)
- A New Enantioselective Synthesis of Milnacipran and an Analogue by Catalytic Asymmetric Cyclopropanation (2001) (35)
- Tetrahydroquinolines and benzazepines through catalytic diastereoselective formal [4 + 2]-cycloaddition reactions between donor-acceptor cyclopropenes and imines. (2013) (35)
- Divergent Rhodium-Catalyzed Cyclization Reactions of Enoldiazoacetamides with Nitrosoarenes. (2017) (35)
- Reactivity and Selectivity in Catalytic Reactions of Enoldiazoacetamides. Assessment of Metal Carbenes as Intermediates (2016) (34)
- Chiral catalyst enhancement of diastereocontrol for OH insertion reactions of styryl- and phenyldiazoacetate esters of pantolactone (2002) (34)
- Catalytic addition methods for the synthesis of functionalized diazoacetoacetates and application to the construction of highly substituted cyclobutanones. (2005) (34)
- Hindered organosilicon compounds. Synthesis and properties of di-tert-butyl-, di-tert-butylmethyl-, and tri-tert-butylsilanes (1975) (34)
- Comparative evaluation of enantiocontrol for intramolecular cyclopropanation of diazoacetates with chiral CuI, RhII and RuII catalysts (1997) (34)
- Solvent enhancement of reaction selectivity: a unique property of cationic chiral dirhodium carboxamidates. (2011) (33)
- Macrocycle Formation by Catalytic Intramolecular Cyclopropanation. A New General Methodology for the Synthesis of Macrolides (1997) (33)
- Enhancement of stereoselectivity in catalytic cyclopropanation reactions (1987) (33)
- Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor-acceptor cyclopropenes. (2015) (33)
- Addition of arylchlorocarbenes to α,β-unsaturated esters. Absolute rates, substituent effects, and variable reactivities (1988) (33)
- Cycloheptatriene syntheses through rhodium(II) acetate-catalyzed intramolecular addition reactions of N-benzyldiazoacetamides (1988) (33)
- Transition-metal-catalyzed rearrangements of oxocyclopropanes to vinyl ethers. Activation by vicinal carboalkoxy substituents (1981) (33)
- Synthesis of pyrrolizidine bases by highly diastereoselective and regioselective catalytic carbon-hydrogen insertion reactions of chiral pyrrolidinediazoacetamides (1996) (32)
- Regioselectivity in catalytic cyclopropanation reactions (1982) (32)
- Chiral Dirhodium(II) Carboxamidate-Catalyzed [2+2]-Cycloaddition of TMS-Ketene and Ethyl Glyoxylate (2005) (32)
- Diversifying Science, Technology, Engineering, and Mathematics (STEM): An Inquiry into Successful Approaches in Chemistry (2014) (32)
- "Matched/mismatched" diastereomeric dirhodium(II) carboxamidate catalyst pairs. Structure-selectivity correlations in diazo decomposition and hetero-Diels-Alder reactions. (2005) (31)
- In search of high stereocontrol for the construction of cis-disubstituted cyclopropane compounds. Total synthesis of a cyclopropane-configured urea-PETT analogue that is a HIV-1 reverse transcriptase inhibitor. (2002) (31)
- Alkyl nitrite-metal halide deamination reactions. 7. Synthetic coupling of electrophilic bromination with substitutive deamination for selective synthesis of multiply brominated aromatic compounds from arylamines (1980) (31)
- Enantioselective Syntheses of 2-Deoxyxylono-1,4-lactone and 2-Deoxyribono-1,4-lactone from 1,3-Dioxan-5-yl Diazoacetates. (1999) (31)
- Influences of catalyst configuration and catalyst loading on selectivities in reactions of diazoacetamides. Barrier to equilibrium between diastereomeric conformations. (2003) (30)
- Formation and characterization of 3-O-arenediazoascorbic acids. New stable diazo ethers (1989) (30)
- Cyclopropanation versus carbon–hydrogen insertion. The influences of substrate and catalyst on selectivity (2001) (30)
- Synthesis of Chiral Tetrasubstituted Azetidines from Donor-Acceptor Azetines via Asymmetric Copper(I)-Catalyzed Imido-Ylide [3+1]-Cycloaddition with Metallo-Enolcarbenes. (2019) (30)
- Chemoselectivity and enantiocontrol in catalytic intramolecular metal carbene reactions of diazo acetates linked to reactive functional groups by naphthalene-1,8-dimethanol (1999) (30)
- Syntheses of Tetrahydropyridazine and Tetrahydro-1,2-diazepine Scaffolds through Cycloaddition Reactions of Azoalkenes with Enol Diazoacetates. (2016) (30)
- Outer-Sphere One-Electron Reductions of Arenediazonium Salts (1987) (29)
- Correlation between catalytic cyclopropanation and ylide generation (1981) (29)
- Catalyst Choice for Highly Enantioselective [3 + 3]-Cycloaddition of Enoldiazocarbonyl Compounds (2018) (29)
- Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone. (2013) (28)
- Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes. (2012) (28)
- Synthesis of 2-deoxyxylolactone from glycerol derivatives via highly enantioselective carbon-hydrogen insertion reactions (1994) (28)
- Reaction between azide and nitronium ions. Formation and decomposition of nitryl azide (1973) (28)
- Olefin coordination with rhodium(II) perfluoroalkanoates in solution (1987) (28)
- Catalytic Intramolecular Addition of Metal Carbenes to Remote Furans (1999) (28)
- Identification of a Mr = 17,000 protein as the plastoquinone-binding protein in the cytochrome b6-f complex from spinach chloroplasts. (1989) (28)
- Unexpected catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides that form 5-arylaminofuran-2(3H)-one-4-carboxylates. (2012) (28)
- Templated Carbene Metathesis Reactions from the Modular Assembly of Enol‐diazo Compounds and Propargyl Acetates (2013) (28)
- Straightforward access to the [3.2.2]nonatriene structural framework via intramolecular cyclopropenation/Buchner reaction/Cope rearrangement cascade. (2015) (27)
- Oxidation of hemoglobin and myoglobin by alkyl nitrites inhibition by oxygen. (1981) (27)
- Enantioselectivity and cis/trans‐Selectivity in Dirhodium(II)‐Catalyzed addition of diazoacetates to olefins (1995) (27)
- SPIROLACTONES FROM DIRHODIUM(II)-CATALYZED DIAZO DECOMPOSITION WITH REGIOSELECTIVE CARBON-HYDROGEN INSERTION (1995) (27)
- Enantioselective carbon-hydrogen insertion is an effective and efficient methodology for the synthesis of (R)-(-)-baclofen. (2002) (27)
- High selectivity from configurational match/mismatch in carbon-hydrogen insertion reactions of steroidal diazoacetates catalyzed by chiral dirhodium(II) carboxamidates. (2001) (27)
- Silane reductions in acidic media. VI. Mechanism of organosilane reductions of carbonyl compounds. Transition state geometries of hydride transfer reactions (1975) (27)
- Unprecedented Intramolecular [4 + 2]-Cycloaddition between a 1,3-Diene and a Diazo Ester. (2016) (27)
- FORMATION OF MACROCYCLES BY CATALYTIC INTRAMOLECULAR AROMATIC CYCLOADDITION OF METAL CARBENES TO REMOTE ARENES (1996) (26)
- Reduction of arenediazonium salts by hydroquinone. Kinetics and mechanism for the electron-transfer step (1988) (26)
- Structural effects in alkyl nitrite oxidation of human hemoglobin. (1984) (26)
- Pericyclic reaction of a zwitterionic salt of an enedione-diazoester. A novel strategy for the synthesis of highly functionalized resorcinols. (2010) (26)
- Macrocyclic oxonium ylide formation and internal [2,3]-sigmatropic rearrangement catalyst influence on selectivity (1997) (26)
- The Selection of Catalysts for Metal Carbene Transformations (2016) (26)
- Silane reductions in acidic media. IV. Reductions of alkyl-substituted cyclohexanones by mono-, di-, and trialkylsilanes. Stereochemistry of alcohol and ether formation (1975) (25)
- Influence of olefin coordination on cyclopropanation selectivity (1984) (25)
- Exceptionally effective catalysis of cyclopropanation reactions by the hexarhodium carbonyl cluster (1981) (25)
- Synthesis of allenes by [2,3]-sigmatropic rearrangement of prop-2-yn-1-yl oxonium ylides formed in rhodium(II) carboxylate catalysed reactions of diazo compounds (1990) (25)
- Stereoselective synthesis of disubstituted 3(2H)-furanones via catalytic intramolecular C-H insertion reactions of α-diazo-β-keto esters including asymmetric induction (1994) (24)
- Optimization of enantiocontrol in cis-selective cyclopropanation reactions catalyzed by dirhodium(II) tetrakis[alkyl 2-oxaazetidine-4(S)-carboxylates] (2000) (24)
- Chiral Dirhodium(II) Catalysts and Their Applications (2005) (24)
- (1R, 5S)-(-)-6,6-DIMETHYL-3-OXABICYCLO3.1.0HEXAN-2-ONE. HIGHLY ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION CATALYZED BY DIRHODIUM(II) TETRAKISMET HYL 2-PYRROLIDONE-5(R)-CARBOXYLATE : ((3-OXABICYCLO3.1.0HEXAN-2-ONE, 6,6-DI METHYL-, (1R-CIS)-) (1996) (24)
- Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds (2008) (24)
- Olefin coordination with rhodium(II) trifluoroacetate (1984) (24)
- Catalytic Asymmetric Synthesis of Cyclopentyl β-Amino Esters by [3+2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates. (2016) (23)
- Improved enantioselection for chiral dirhodium(II) carboxamide-catalysed carbon-hydrogen insertion reactions of tertiary alkyl diazoacetates (1995) (23)
- Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise? (2012) (23)
- Polyether macrocycles from intramolecular cyclopropanation and ylide formation. Effect of catalyst and coordination. (2006) (23)
- Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene (1988) (23)
- Enantioselective intramolecular cyclopropanation of N-allylic- and N-homoallylic diazoacetamides catalyzed by chiral dirhodium(II) catalysts (1994) (23)
- Reactivities and selectivities in macrocyclic addition reactions with diazoacetates using copper(I) and rhodium(II) catalysts (2000) (23)
- An efficient methodology to substituted furans via oxidation of functionalized α-diazo-β-ketoacetates. (2011) (23)
- Academic Excellence: The Role of Research in the Physical Sciences at Undergraduate Institutions. (2000) (23)
- Reactivity Enhancement for Chiral Dirhodium(II) Tetrakis(Carboxamidates) (2001) (23)
- A new catalytic transformation of diazo esters: hydride abstraction in dirhodium(II)-catalysed reactions (1995) (23)
- A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation. (2005) (23)
- Bis(phenyl)dirhodium(III) caprolactamate: a dinuclear paddlewheel complex with no metal-metal bond. (2007) (23)
- Highly Selective Synthesis of a 2-Deoxyxylonolactam via Enantioselective Carbon-Hydrogen Insertion Reactions Using Chiral Dirhodium(II) Carboxamidates (2002) (22)
- 501 – Transition Metal Carbene Complexes: Cyclopropanation (1995) (22)
- Stereoselective synthesis of highly functionalized alpha-diazo-beta-ketoalkanoates via catalytic one-pot Mukaiyama-Aldol reactions. (2010) (22)
- Enantioselective β-lactone formation from phenyldiazoacetates via catalytic intramolecular carbon-hydrogen insertion (2001) (21)
- Activation parameters for the reaction of phenylchloro carbene with pyridine, tri-n-butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins (1989) (21)
- Catalytic role of copper triflate in Lewis acid promoted reactions of diazo compounds (1984) (21)
- New catalysts and methods for highly enantioselective metal carbene reactions (1998) (21)
- Control of selectivity in the generation and reactions of oxonium ylides. (2011) (21)
- Oxidative deamination of primary amines by copper halide nitrosyls. The formation of geminal dihalides (1976) (21)
- α-Amino Radical-Mediated Diverse Difunctionalization of Alkenes: Construction of C–C, C–N, and C–S Bonds (2020) (21)
- Versatile Donor‐Acceptor Cyclopropenes in Metal Carbene Transformations (2016) (20)
- Stereoselective Synthesis of Substituted 5-Hydroxy-1,3-dioxanes (1998) (20)
- Catalytic Desymmetric Cycloaddition of Diaziridines with Metalloenolcarbenes: the Special Role of Donor-Acceptor Cyclopropenes. (2019) (20)
- Stereoselective synthesis of bicyclic pyrrolidines by a rhodium-catalyzed cascade process. (2004) (20)
- A short stereoselective synthesis of (+)- and (−)-2-oxabicyclo[3.3.0]oct-6-en-3-one by intramolecular carbon–hydrogen insertion catalyzed by chiral dirhodium(II) carboxamidates (2003) (20)
- Molybdenum hexacarbonyl catalyzed cyclopropanation of .alpha.,.beta.-unsaturated esters and nitriles and diazocarbonyl compounds (1980) (20)
- Oxidation of deoxyhemerythrin to semi-methemerythrin by nitrite. (1984) (20)
- The New Chemical Biology of Nitrite Reactions with Hemoglobin: R-State Catalysis, Oxidative Denitrosylation, and Nitrite Reductase/Anhydrase (2009) (20)
- Enoldiazosulfones for Highly Enantioselective [3 + 3]-Cycloaddition with Nitrones Catalyzed by Copper(I) with Chiral BOX Ligands. (2018) (19)
- Unsymmetrical alkenes by carbene coupling from diazirine decomposition in the presence of diazo compounds (1987) (19)
- Constructing chiral diazoacetoacetates by enantioselective catalytic Mukaiyama aldol reactions (2006) (19)
- Diazoacetoacetate enones for the synthesis of diverse natural product-like scaffolds. (2013) (19)
- Macrocycle Formation from Catalytic Metal Carbene Transformations (2001) (19)
- Substrate-dependent divergent outcomes from catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides: azabicyclo[3.1.0]hexanes or 5-arylaminofuran-2(3H)-ones. (2012) (19)
- Catalytic asymmetric cycloaddition reactions of enoldiazo compounds. (2019) (19)
- Displacement of Dinitrogen by Oxygen: A Methodology for the Catalytic Conversion of Diazocarbonyl Compounds to Ketocarbonyl Compounds by 2,6-Dichloropyridine-N-oxide. (2018) (19)
- Observations of Rhodium‐Containing Reaction Intermediates using HPLC with ICP‐MS and ESI‐MS Detection (2006) (19)
- Asymmetric catalysis, part 108 copper catalysts with optically active ligands in the enantioselective Meerwein arylation of activated olefins (1997) (19)
- Disproportionation of trityl alkyl ethers. Synthesis of aldehydes and ketones in a cationic chain reaction involving hydride transfer (1973) (19)
- Diastereoselectivity enhancement in cyclopropanation and cyclopropenation reactions of chiral diazoacetate esters catalyzed by chiral dirhodium(II) carboxamides (1993) (18)
- Nickel(II) bromide-catalyzed oxidations of primary and secondary alcohols to carbonyl compounds by benzoyl peroxide (1979) (18)
- Oxidation of oxymyoglobin by nitric oxide through dissociation from cobalt nitrosyls (1983) (18)
- Hg(OTf)2 Catalyzed Intramolecular 1,4-Addition of Donor-Acceptor Cyclopropenes to Arenes. (2015) (18)
- SILANE REDUCTIONS IN ACIDIC MEDIA. 10. IONIC HYDROGENATION OF CYCLOALKENES. STEREOSELECTIVITY AND MECHANISM (1978) (18)
- Enantioselective catalytic intramolecular cyclopropanation of allylic α-diazopropionates optimized with dirhodium(II) tetrakis[methyl 2-oxazolidinone-4(S or R)-carboxylate] (1995) (18)
- Effective methods for the syntheses of 2‐pyrazolines and pyrazoles from diazocarbonyl compounds (1983) (18)
- Diazirines in carbenoid reactions catalyzed by rhodium(II) carboxylates (1989) (18)
- Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations (2014) (17)
- MECHANISM OF NITROSYL TRANSFER. DISSOCIATION OF NITRIC OXIDE FROM COBALT NITROSYLS (1982) (17)
- β-Lactam formation via rhodium(II) catalyzed carbon-hydrogen insertion reactions of α-diazo amides (1993) (17)
- An efficient route to highly enantioenriched tetrahydroazulenes and β-tetralones by desymmetrization reactions of δ,δ-diaryldiazoaceto-acetates. (2015) (17)
- Enantioselectivity for catalytic cyclopropanation with diazomalonates (2003) (16)
- The Academic Perspective (2004) (16)
- Regioselective oxidations of primary alcohols in 1,4-diols (1982) (16)
- Rhodium(II) acetate catalyzed hydrocarbon oxidations by molecular oxygen (1984) (16)
- Enantiocontrol in intramolecular cyclopropanation of diazoketones. Conformational control of metal carbene alignment (1997) (16)
- Silane reductions in acidic media. V. Reductions of alkyl-substituted cyclohexanones by di- and tri-tert-butylsilanes. Steric hindrance to nucleophilic attack at silicon in the trifluoroacetolysis of silyl alkyl ethers (1975) (16)
- (4,0)-Dirhodium(II) tetrakis[methyl 1-acetyl-2-oxoimidazolidine-4(S)-carboxylate]. Implications for the mechanism of ligand exchange reactions (1997) (16)
- Enantioselective cis-β-lactam synthesis by intramolecular C–H functionalization from enoldiazoacetamides and derivative donor–acceptor cyclopropenes (2015) (16)
- Diazo Chemistry II: Aliphatic, Inorganic and Organometallic Compounds By Heinrich Zollinger (Swiss Federal Institute of Technology). VCH: New York. 1995. xiii + 522 pp. $125.00. ISBN 3-527-29222-5. (1996) (15)
- Cyclic ether formation in oxidations of primary alcohols by cerium(IV). Reactions of 5-phenyl-1-pentanol, 4-phenyl-1-butanol, and 3-phenyl-1-propanol with ceric ammonium nitrate (1975) (15)
- Diverse Pathways in Catalytic Reactions of Propargyl Aryldiazoacetates: Selectivity between Three Reaction Sites. (2017) (15)
- Divergent pathways of β,γ-unsaturated α-diazocarbonyl compounds catalyzed by dirhodium and Lewis acids catalysts separately or in combination (2015) (15)
- Amplification of asymmetric induction in sequential reactions of bis-diazoacetates catalyzed by chiral dirhodium(II) carboxamidates. (2005) (15)
- Reactions of the nitrosonium ion. 11. Fluoride transfer from complex fluoride anions to carbenium ions in the nitrosative decomposition of aliphatic azides (1979) (15)
- Enantioselective carbonyl-ene reactions catalyzed by chiral cationic dirhodium(II,III) carboxamidates. (2014) (15)
- Regioselective hydroformylation of alkenes catalyzed by di(n-carboxylato)rhodium(I) complexes (1994) (15)
- Copper-Catalyzed Formal [4+2] Cycloaddition of Enoldiazoimides with Sulfur Ylides. (2018) (14)
- Recent Developments in the Synthetic Uses of Silyl-protected Enoldiazoacetates for Heterocyclic Syntheses (2014) (14)
- Silane reductions in acidic media. 9. The effect of Lewis acids on stereoselectivities in ketone reductions. The principle of complexation-induced conformational perturbation. Energy minimization in the transition states for hydride transfer (1977) (14)
- Reactions of the nitrosonium ion. IV. Nitrosative cleavage of the carbon-nitrogen double bond. Reaction of N-arylimines and ketimines with nitrosonium salts (1972) (14)
- Brønsted Acid Catalyzed Friedel-Crafts-type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds. (2020) (14)
- Formation and Reactions of Dithiodicarbenium Salts (1982) (14)
- Expedient access to substituted 3-amino-2-cyclopentenones by dirhodium-catalyzed [3+2]-annulation of silylated ketene imines and enoldiazoacetates. (2014) (14)
- Determination of a geometry and dead time correction factor for neutron activation analysis (1974) (13)
- Chiral donor–acceptor azetines as powerful reactants for synthesis of amino acid derivatives (2019) (13)
- Asymmetric [3+3] Cycloaddition for Heterocycle Synthesis (2017) (13)
- Regioselectivity in Nickel(II)-Mediated Oxidations of Diols (1983) (13)
- Reactions of the nitrosonium ion. V. Nitrosative cleavage of the carbon-nitrogen double bond. Attempted exchange of oxygen for nitrogen (1973) (13)
- Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols. (2012) (13)
- Dirhodium(II) tetrakis[N,N-dimethyl-2-pyrrolidone-5(S)-carboxamide]. Structural effects on enantioselection in metal carbene transformations (1994) (13)
- Stereoselectivity in Metal Carbene Addition to a Carbon‐Carbon Triple Bond Tied to the Reactant Diazoacetate Through a Chiral Linker (2006) (13)
- Lewis acid-promoted 1,3-dipolar addition reactions of diazocarbonyl compounds. A general synthesis of oxazoles (1978) (13)
- Rhodium acetate-catalyzed aerobic Mukaiyama epoxidation of alkenes (2013) (12)
- Catalytic Oxidative Cleavage Reactions of Arylalkenes by tert-Butyl Hydroperoxide - A Mechanistic Assessment. (2020) (12)
- Academic Excellence¿The Role of Research (2002) (12)
- Experimental Organic Chemistry (1980) (12)
- 5.2 – Transition Metal Carbene Complexes: Diazodecomposition, Ylide, and Insertion (1995) (12)
- Homologation of acetals of α,β-unsaturated carbonyl compounds with diazo esters. Synthesis of acetals of β,γ-unsaturated carbonyl compounds (1983) (12)
- Asymmetric syntheses with catalytic enantioselective metal carbene transformations (1994) (12)
- Cu(OTf)2-Catalyzed Three-Component Imino Diels-Alder Reaction Using Propenylbenzenes: Synthesis of 2,4-Diaryl Tetrahydroquinoline Derivatives (2011) (12)
- Enantiomer recognition of amides by dirhodium(II) tetrakis[methyl 2-oxopyrrolidine-5(S)-carboxylate]. (2011) (12)
- A Spectrometric Study of the Oxidation of Alcohols by Cerium(IV). (1974) (12)
- Degradation of uric acid during autocatalytic oxidation of oxyhemoglobin induced by sodium nitrite. (1991) (12)
- Measures of Merit For Offensive Information Operations Courses of Action (2000) (12)
- Catalysis of olefin isomerization by tight ion pairs (1987) (12)
- Catalytic, Asymmetric, Intramolecular Carbon–Hydrogen Insertion (2013) (11)
- Intramolecular Regioselective Insertion into Unactivated Prochiral Carbon-Hydrogen Bonds with Diazoacetates of Primary Alcohols Catalyzed by Chiral Dirhodium(II) Carboxamidates. Highly Enantioselective Total Synthesis of Natural Lignan Lactones. (1997) (11)
- Replacing mineral acids in the laboratory: Nafion-catalyzed dehydration and esterification (1993) (11)
- Alkyl nitrite-metal halide deamination reactions. 5. In situ generation of nitrosyl halides. Effective product control from nitrosyl chloride diazotization of primary aliphatic amines in N,N-dimethylformamide (1978) (10)
- Reactions of the nitrosonium ion. II. Reactions of triphenylmethyl, benzhydryl, and benzyl azides with nitrosonium compounds (1972) (10)
- Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes. (2021) (10)
- Lewis acid - promoted cyclopropanation of α,β-unsaturated carbonyl compounds by diazocarbonyl compounds. A facile synthesis of 1,2-disubstituted cyclopropylcarbonyl compounds of high isomeric purity (1979) (10)
- Asymmetric synthesis of 1H-pyrrol-3(2H)-ones from 2,3-diketoesters by combination of aldol condensation with benzilic acid rearrangement. (2016) (10)
- Substrate versus Catalyst Control of Stereoselectivity in the Cyclopropanation of a Carbon-Carbon Double Bond Linked to the Reactant Diazoacetate through a Chiral Linker (2006) (10)
- Role of Donor–Acceptor Cyclopropenes in Metal Carbene Reactions. Conversion of E-Substituted Enoldiazoacetates to Z-Substituted Metallo-Enolcarbenes (2019) (10)
- Chiral Dirhodium(II) Carboxamidates for Asymmetric Cyclopropanation and Carbon-Hydrogen Insertion Reactions (2005) (9)
- Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels-Alder reactions. (2009) (9)
- Synthesis of dirhodium(II) tetrakis[methyl 1-(3-phenylpropanoyl)-2-oxaimidazolidine-4(S)-carboxylate], Rh2(4S-MPPIM)4 (2003) (9)
- Highly Regio-, Diastereo-, and Enantioselective Rhodium-Catalyzed Intramolecular Cyclopropanation of (Z)-1,3-Dienyl Aryldiazoacetates. (2017) (9)
- Ag(I)-Catalyzed Reactions of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles. (2021) (9)
- Free-radical rearrangements in the thermal decomposition of tert-butylperoxy 3-(1-phenylcyclopropyl)propanoate, 4-(1-phenylcyclopropyl)butanoate, and 5-(1-phenylcyclopropyl)pentanoate (1973) (9)
- A survey of enoldiazo nucleophilicity in selective C-C bond forming reactions for the synthesis of natural product-like frameworks. (2014) (9)
- Nucleophilic character of an electrophilic carbene. Synthesis of cyclopropanes by thermal decomposition of 3-chloro-3-phenyldiazirine (1984) (9)
- Asymmetric Addition and Insertion Reactions of Catalytically‐Generated Metal Carbenes (2005) (9)
- Enhanced enantiocontrol in catalytic metal carbene transformations with dirhodium (II) tetrakis[methyl 2‐oxooxazolidin‐4(S)‐carboxylate], Rh2(4S‐MEOX)4 (2010) (9)
- Comparative enantiocontrol with allyl phenyldiazoacetates in asymmetric catalytic intramolecular cyclopropanation. (2003) (9)
- Identification and characterization of isomeric intermediates in a catalyst formation reaction by means of speciation analysis using HPLC-ICPMS and HPLC-ESI-MS. (2006) (9)
- Diphenylglycoluril as a novel ligand architecture for dirhodium(II) carboxamidates (2008) (9)
- Medium effects. I. Solvolysis of 5-hexenyl p-nitrobenzenesulfonate in acetic acid-nonhydroxylic solvent (20:80) mixtures (1967) (9)
- Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate (1986) (9)
- The chemistry of vicinal tricarbonyls: an expedient route to fully-substituted 3-aminopyrroles (2015) (9)
- Procatalysts for carbenoid transformations (1985) (9)
- Rhodium(ii)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans. (2018) (9)
- ALKYL NITRITE‐METAL HALIDE DEAMINATION REACTIONS. 3. ARYLATION OF OLEFINIC COMPOUNDS IN THE DEAMINATION OF ARYLAMINES BY ALKYL NITRITES AND COPPER(II) HALIDES. A CONVENIENT AND EFFECTIVE VARIATION OF THE MEERWEIN ARYLATION REACTION (1977) (8)
- Synthesis of bis(sigma-aryl)dirhodium(III) caprolactamates by oxidative arylation with arylboronic acids. (2008) (8)
- Oxidative deamination of primary amines: selective synthesis of geminal dihalides (1976) (8)
- Synthetic Carbene and Nitrene Chemistry (2005) (8)
- Catalyst-Free Rearrangement of Allenyl Aryldiazoacetates into 1,5-Dihydro-4H-pyrazol-4-ones. (2016) (8)
- Enantiocontrol in catalytic metal carbene reactions (1999) (8)
- Catalyst-Free Formation of Nitrile Oxides and Their Further Transformations to Diverse Heterocycles. (2021) (8)
- Does an axial propeller shape on a dirhodium(III,III) core affect equatorial ligand chirality? (2011) (8)
- Synthesis of 1 H-Pyrrol-3(2 H)-ones via Three-Component Reactions of 2,3-Diketo Esters, Amines, and Ketones. (2018) (8)
- Dirhodium(II) Tetraacetate Catalysed Hydroboration of Alkenes (1993) (7)
- Selective Oxidations of Alcohols by Bromine in Combination with Nickel(II) Benzoate (1981) (7)
- Diverse Reactions of Vinyl Diazo Compounds with Quinone Oxonium Ions, Quinone Imine Ketals, and Eschenmoser’s Salt (2021) (7)
- Hetero-bis(sigma-aryl)dirhodium(III) caprolactamates. Electronic communication between aryl groups through dirhodium(III). (2009) (7)
- Attempted synthesis of casbene by intramolecular cyclopropanation (2002) (7)
- Reactions of the nitrosonium ion. I. Reaction of alkyl azides with nitrosonium salts. A new method for the production of carbonium ions (1970) (7)
- The disproportionation of trityl benzyl ethers. Kinetic analysis of the trityl salt catalyzed reaction. Evidence for the involvement of ion pairs in the hydrogen transfer step (1976) (7)
- Catalyst-Directed Divergent Catalytic Approaches to Expand Structural and Functional Scaffold Diversity via Metallo-Enolcarbene Intermediates (2021) (7)
- Electronic and Steric Control in Carbon-Hydrogen Insertion Reactions of Diazoacetoacetates Catalyzed by Dirhodium(II) Carboxylates and Carboxamides. (1993) (6)
- Copper(i)-catalyzed highly enantioselective [3 + 3]-cycloaddition of γ-alkyl enoldiazoacetates with nitrones (2020) (6)
- Electron transfer between hemoglobin and arenediazonium salts. Mechanism of heme aryl-iron complex formation (1987) (6)
- Electron Transfer in the Heme Pocket of Hemoglobin (1985) (6)
- Stereoselective Synthesis of Substituted 5‐Hydroxy‐1,3‐dioxanes. (1998) (6)
- Medium effects. II. Cyclization of 6-heptenyl p-nitrobenzenesulfonate during solvolysis in 2,2,2-trifluoroethanol☆ (1968) (6)
- Dirhodium(II)-catalyzed carbonyl ylide generation. Stereoelectronic control in dioxolane formation (1998) (6)
- Steric selectivity in oxidations of diols (1980) (6)
- Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ε‐caprolactamate] of tert‐Butyldimethylsilyl‐protected trans‐Dehydroandrosterone (2014) (6)
- Control of enantioselectivity in catalytic metal carbene reactions. (2000) (6)
- Enantioselective Catalytic Cyclopropanation-Rearrangement Approach to Chiral Spiroketals. (2021) (6)
- Brønsted Acid Catalyzed Oxocarbenium-Olefin Metathesis/Rearrangements of 1H-Isochromene Acetals with Vinyl Diazo Compounds. (2021) (6)
- Steric balance within chiral dirhodium(II) carboxamidate catalysts enhances stereoselectivity (2003) (6)
- Silver‐Catalyzed Carbene Functionalization of Methane in Supercritical Carbon Dioxide (2011) (6)
- Reactions of the nitrosonium ion. VII. Syntheses of dihydroisoquinolines and oxazoles from azides in nitrile solvents (1975) (6)
- Nucleophilic Reactivity of the Carbon-Carbon Double Bond. VI. The Use of Urea as a Base in Acetolysis Reactions (1967) (6)
- Intermolecular [5 + 1]-Cycloaddition between Vinyl Diazo Compounds and tert-Butyl Nitrite to 1,2,3-Triazine 1-Oxides and Their Further Transformation to Isoxazoles. (2021) (5)
- Nitrosyl transfer to metalloproteins. Selective intermolecular transfer of the nitrosyl group from cobalt nitrosyls to hemoglobin and myoglobin (1980) (5)
- Enantiomer differentiation in intramolecular carbon—hydrogen insertion reactions of racemic secondary alkyl diazoacetates catalyzed by chiral dirhodium(ii) carboxamidates (1995) (5)
- Simple and Sustainable Iron‐Catalyzed Aerobic C—H Functionalization of N,N‐Dialkylanilines. (2013) (5)
- Electronic and Steric Control: Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazo Compounds (1992) (5)
- The nature of fluoride transfer from complex fluoride anions to carbenium ions (1975) (5)
- Chemical and electrochemical oxidation of O,O,O-trisubstituted phosphorothioates and triphenylphosphine sulfide (1983) (5)
- (1R,5S)‐(−)‐6,6‐Dimethyl‐3‐Oxabicyclo[3.1.0]Hexan‐2‐One. Highly Enantioselective Intramolecular Cyclopropanation Catalyzed by Dirhodium(II) Tetrakis[Methyl 2‐Pyrrolidone‐5(R)‐Carboxylate] (2003) (5)
- Stereoselectivity in metal carbene and Lewis acid-catalyzed reactions from diastereomeric dirhodium(II) carboxamidates: Menthyl N-acetyl-2-oxoimidazolidine-4(S)-carboxylates (2005) (5)
- Dinuclear compounds without a metal-metal bond. Dirhodium(III,III)carboxamidates (2015) (5)
- Chiral 3-Acylglutaric Acid Derivatives from Strain-Induced Nucleophilic retro-Claisen Ring-Opening Reactions. (2020) (5)
- Synthesis, Structure and Reactivity of a Novel Series of Diastereomeric Dirhodium(II) Tetracarboxamidates. Catalysts for Asymmetric Diazoacetate Transformations (1998) (4)
- Cycloheptanone via a Lewis acid-catalyzed cyclization of 6-heptenoyl chloride to .beta.-chlorocycloheptanone (1969) (4)
- Highly Enantioselective Intramolecular Cyclopropanation Reactions of N- Allylic-N-methyldiazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxamidates. (1996) (4)
- A Donor—Acceptor Cyclopropene as a Dipole Source for a Silver(I) Catalyzed Asymmetric Catalytic [3 + 3]‐Cycloaddition with Nitrones. (2014) (4)
- Preparing Chemists and Chemical Engineers for A Globally Oriented Workforce (2004) (4)
- High Enantioselectivity in the Intramolecular Cyclopropanation of Allyl Diazoacetates Using a Novel Rhodium(II) Catalyst. (1991) (4)
- Influence of the diene in the Hetero-Diels-Alder reaction catalyzed by dirhodium(II) carboxamidates (2004) (4)
- THE DISPROPORTIONATION OF TRITYL BENZYL ETHERS. KINETIC ANALYSIS OF THE TRITYL SALT CATALYZED REACTION. EVIDENCE FOR THE INVOLVEMENT OF ION PAIRS IN TH HYDROGEN TRANSFER STEP (1976) (4)
- Addition/Elimination in the Rhodium(II) Perfluorobutyrate Catalyzed Hydrosilylation of 1‐Alkenes. Rhodium Hydride Promoted Isomerization and Hydrogenation. (1992) (4)
- First attempts at differential diastereoselection in catalytic reactions of N-chirally substituted dirhodium(ii) tetrakis[methyl 2-oxoimidazolidine-4(S)-carboxylates] with diazoacetates (2001) (4)
- Asymmetric chemical transformations (1995) (4)
- High Stereocontrol in the Preparation of Silyl-Protected γ-Substituted Enoldiazoacetates (2019) (4)
- Effective Uses of Dirhodium(II) Tetrakis(methyl 2‐oxopyrrolidine‐5(R or S)‐carboxylate) for Highly Enantioselective Intermolecular Cyclopropenation Reactions. (1995) (4)
- Cu(OTf)2‐Catalyzed Three‐Component Imino Diels—Alder Reaction Using Propenylbenzenes: Synthesis of 2,4‐Diaryl Tetrahydroquinoline Derivatives. (2011) (3)
- Lewis Acid Promoted Reactions of n-(1-Phenylcyclopropyl)alkanoyl Chlorides. Ring-Size Effects in Competitive Intramolecular Acylation of Phenyl and Cyclopropyl Substituents (1979) (3)
- ALKYL NITRITE-METAL HALIDE DEAMINATION REACTIONS. PART IV. NITROSATIVE OXIDATION OF ARYLHYDRAZINES BY ALKYL NITRITES AND COPPER(II) HALIDES (1977) (3)
- Reactions of the nitrosonium ion. III. Reaction of alkyl azides with nitrosonium compounds. Effect of solvent, quenching agent, and nitrosonium compound (1972) (3)
- Enantiocontrol in Macrocycle Formation from Catalytic Metal Carbene Transformations (2001) (3)
- Reversible oxidation of 1,3-dithiolan-2-thione (1977) (3)
- Asymmetric Synthesis of Lactones with High Enantioselectivity by Intramolecular Carbon‐Hydrogen Insertion Reactions of Alkyl Diazoacetates Catalyzed by Chiral Rhodium(II) Carboxamides. (1992) (3)
- Enantioselective Metal Carbene Transformations with Polyethylene‐Bound Soluble Recoverable Dirhodium(II) 2‐Pyrrolidone‐5(S)‐carboxylates. (1993) (3)
- Nitrosative cleavage of benzalazine and related aldehyde azines. Production, decomposition and trapping of iminodiazonium ions (1974) (3)
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- Highly Enantioselective Carbonyl‐Ene Reactions of 2,3‐Diketoesters: Efficient and Atom‐Economical Process to Functionalized Chiral α‐Hydroxy‐β‐ketoesters. (2014) (3)
- Tetrahydroquinolines and Benzazepines Through Catalytic Diastereoselective Formal [4 + 2]-Cycloaddition Reactions Between Donor—Acceptor Cyclopropenes and Imines. (2013) (3)
- Application of α-Aminoalkyl Radicals as Reaction Activators (2021) (3)
- High Enantioselectivity for Intermolecular Cyclopropenation of Alkynes by Diazo Esters Catalyzed by Chiral Dirhodium(II) Carboxamides. (1992) (3)
- A Value Function Approach to Information Operations MOE's: A Preliminary Study (1997) (3)
- Construction of Highly Functionalized Diazoacetoacetates via Catalytic Mukaiyama—Michael Reactions. (2008) (3)
- Rhodium(II) Perfluorobutyrate‐Catalyzed Silane Alcoholysis. A Highly Selective Route to Silyl Ethers. (1991) (3)
- Enantioselective Tertiary Electrophile (Hetero)Benzylation: Pd-Catalyzed Substitution of Isoprene Monoxide with Arylacetates. (2021) (3)
- Intramolecular cycloaddition/rearrangement cascade from gold(iii)-catalysed reactions of propargyl aryldiazoesters with cinnamyl imines. (2018) (3)
- tert‐Butyl Hydroperoxide (2012) (3)
- LEWIS ACID PROMOTED REACTIONS OF DIAZOCARBONYL COMPOUNDS. 3. SYNTHESIS OF OXAZOLES FROM NITRILES THROUGH INTERMEDIATE β-IMIDATOALKENEDIAZONIUM SALTS (1981) (3)
- Optimization of Enantiocontrol for Carbon‐Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3‐Aryl‐1‐propyl Diazoacetates in High Optical Purity. (1996) (2)
- Enantioselective Intramolecular Cyclopropanations of Allylic and Homoallylic Diazoacetates and Diazoacetamides Using Chiral Dirhodium( II) Carboxamide Catalysts. (1995) (2)
- Highly Enantioselective Syntheses from Diazocarbonyl Compounds Catalyzed by Chiral Dirhodium(II) Carboxamides (1995) (2)
- Highly Selective Catalyst‐Dependent Competitive 1,2‐C→C, ‐O→C, and ‐N→C Migrations from β‐Methylene‐β‐silyloxy‐β‐amido‐α‐diazoacetates. (2013) (2)
- Conformational isomers of extraordinary stability: carboxamidate-bridged dimetalloorganic compounds. (2009) (2)
- Ligand Effects on Dirhodium(II) Carbene Reactivities. Highly Effective Switching Between Competitive Carbenoid Transformations. (1994) (2)
- Chiral Catalysts for Enantioselective Intermolecular Cyclopropanation Reactions with Methyl Phenyldiazoacetate. Origin of the Solvent Effect in Reactions Catalyzed by Homochiral Dirhodium(II) Prolinates. (1996) (2)
- Thermal decomposition of tert-butylperoxy 6-bromohexanoate. Lack of evidence for radical displacement on carbon and 1,5-bridged bromine radicals (1967) (2)
- Rhodium(II) Perfluorobutyrate Catalyzed Hydrosilylation of 1‐Alkynes. Trans Addition and Rearrangement to Allylsilanes. (1991) (2)
- Dirhodium(II) Tetraacetate Catalyzed Hydroboration of Alkenes. (1994) (2)
- Nitrosative oxidation of arylhydrazines by alkyl nitrites and copper(II) halides (1977) (2)
- Reactions of the nitrosonium ion. VIII. Reactions of nitrosonium tetraflouroborate and benzhydryl tetraflouroborate with benzhydryl azides. The mechanism of aldehyde and ketone formation (1975) (2)
- Copper(I)‐Catalyzed Highly Enantioselective [3+3]‐Cycloaddition of β‐Aryl/Alkyl Vinyl Diazoacetates with Nitrones (2021) (2)
- Catalysis with Dirhodium(II) Complexes (1998) (2)
- Ag I ‐Catalyzed Reaction of Enol Diazoacetates and Imino Ethers: Synthesis of Highly Functionalized Pyrroles (2021) (2)
- Tetrakis((4S)‐4‐phenyloxazolidin‐2‐one)dirhodium(II) and Its Catalytic Applications for Metal Carbene Transformations. (1993) (2)
- Catalytic Allylic Oxidation of Cyclic Enamides and 3,4-Dihydro-2H-Pyrans by TBHP. (2017) (2)
- A facile route to some useful homochiral alkyl Imidazolidin-2-one-4(S)-carboxylates (1996) (2)
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- Faculty Time. Academic Excellence: A Study of the Role of Research in the Natural Sciences at Undergraduate Institutions. Special Report. (2002) (2)
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- Total Synthesis of (S)‐(+)‐Imperanene. Effective Use of Regio‐ and Enantioselective Intramolecular Carbon—Hydrogen Insertion Reactions Catalyzed by Chiral Dirhodium(II) Carboxamidates. (2002) (1)
- Dirhodium(II) Tetraoctanoate (2006) (1)
- Highly Enantioselective Route to β‐Lactams via Intramolecular C‐H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates. (1996) (1)
- Reactions of the nitrosonium ion. 10. Decarboxylations of azodicarboxylates by nitrosonium and nitronium salts. Decarboxylative oxidation and substitution reactions (1977) (1)
- A New Enantioselective Synthesis of Milnacipran and an Analogue by Catalytic Asymmetric Cyclopropanation. (2001) (1)
- Preparation and Catalytic Properties of Immobilized Chiral Dirhodium(II) Carboxamidates. (2002) (1)
- Chemoselectivity in dirhodium(II) catalyzed reactions of diazoacetoacetates prepared from α,β-unsaturated ketones (2010) (1)
- Dirhodium(II) Tetrakis(trifluoroacetate) (2006) (1)
- Propargylic Oxidations Catalyzed by Dirhodium Caprolactamate in Water: Efficient Access to α,β‐Acetylene Ketones. (2008) (1)
- Dirhodium(II) Tetrakis(alkyl 2‐oxoazetidine‐4(S)‐carboxylates). A New Set of Effective Chiral Catalysts for Asymmetric Intermolecular Cyclopropanation Reactions with Diazoacetates. (1996) (1)
- Spirolactones from Dirhodium(II)-Catalyzed Diazo Decomposition with Regioselective Carbon-Hydrogen Insertion. (1995) (1)
- Copper‐Catalyzed Divergent Addition Reactions of Enoldiazoacetamides with Nitrones. (2016) (1)
- A Novel Three‐Component Reaction Catalyzed by Dirhodium(II) Acetate: Decomposition of Phenyldiazoacetate with Arylamine and Imine for Highly Diastereoselective Synthesis of 1,2‐Diamines. (2004) (1)
- Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes (2021) (1)
- Discussion Addendum For: Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ε‐Caprolactamate] of tert ‐Butyldimethylsilyl‐Protected trans ‐Dehydroandrosterone (2019) (1)
- Highly Regioselective and Stereoselective Silylformylation of Alkynes Under Mild Conditions Promoted by Dirhodium(II) Perfluorobutyrate. (1994) (1)
- Synthesis of 1,2,3-Triazine Derivatives by Deoxygenation of 1,2,3-Triazine 1-Oxides. (2022) (1)
- Dirhodium(II) Tetrakis[methyl 2‐oxaazetidine‐4‐carboxylate]: A Chiral Dirhodium(II) Carboxamidate of Exceptional Reactivity and Selectivity. (2000) (1)
- Dirhodium(II)‐Catalyzed Formal [3 + 2 + 1]‐Annulation of Azomethine Imines with Two Molecules of a Diazo Ketone (2013) (1)
- Challenges in the Highly Selective [3 + 1]-Cycloaddition of an Enoldiazoacetamide to Form a Donor–Acceptor Cis-Cyclobutenecarboxamide † (2021) (1)
- Zipf's Law Revealed at Predominantly Undergraduate Institutions: Million Dollar and Thirty-Publication Faculty. Academic Excellence: A Study of the Role of Research in the Natural Sciences at Undergraduate Institutions. Special Report. (2001) (1)
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- Divergent Stereocontrol of Acid Catalyzed Intramolecular Aldol Reactions of 2,3,7‐Triketoesters: Synthesis of Highly Functionalized Cyclopentanones. (2012) (1)
- Chiral Rhodium(II) Carboxamides. A New Class of Catalysts for Enantioselective Cyclopropanation Reactions. (1992) (1)
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- The Tyranny of Small Numbers. Academic Excellence: A Study of the Role of Research in the Natural Sciences at Undergraduate Institutions. Special Report. (2002) (1)
- Enhanced Enantiocontrol in Catalytic Metal Carbene Transformations with Dirhodium(II) Tetrakis(methyl 2-oxooxazolidin-4(S)-carboxylate), Rh2(4S-meox)4. (1995) (1)
- The [3 + 3]‐Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts (2014) (1)
- Control of Chemoselectivity in Catalytic Carbenoid Reactions. Dirhodium(II) Ligand Effects on Relative Reactivities. (1992) (1)
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- Oxidation of hemoglobin by arenediazonium salts. The influence of dioxygen (1984) (1)
- A New and General Synthesis of α-Silyl Carbonyl Compounds by Si-H Insertion from Transition Metal-Catalyzed Reactions of Diazo Esters and Diazo Ketones. (1989) (1)
- REARRANGEMENTS OF YLIDES GENERATED FROM REACTIONS OF DIAZO COMPOUNDS WITH ALLYL ACETALS AND THIOKETALS BY CATALYTIC METHODS. HETEROATOM ACCELERATION OF THE (2,3)-SIGMATROPIC REARRANGEMENT (1984) (1)
- Comparative Evaluation of Enantiocontrol for Intramolecular Cyclopropanation of Diazoacetates with Chiral Cu(I), Rh(II), and Ru(II) Catalysts. (1997) (1)
- HIGHLY EFFICIENT OLEFIN ISOMERIZATION CATALYZED BY METAL HYDRIDES DERIVES FROM DIRHODIUM(II) CARBOXYLATES AND CATECHOLBORANE (1994) (1)
- Internal Lewis acid catalyzed ring-expansion reactions of cyclopropylalkanoyl chlorides (1975) (1)
- Improved Enantioselection for Chiral Dirhodium(II) Carboxamide‐ Catalyzed Carbon‐Hydrogen Insertion Reactions of Tertiary Alkyl Diazoacetates. (1995) (1)
- Macrocyclic Lactones from Dirhodium(II)-Catalyzed Intramolecular Cyclopropanation and Carbon-Hydrogen Insertion. (1995) (1)
- Dirhodium(II) Tetraacetamidate (2007) (1)
- A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero‐Diels—Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates. (2010) (1)
- Highly Selective γ-Lactone Syntheses by Intramolecular Carbenoid Carbon-Hydrogen Insertion in Rhodium(II) Carboxylate and Rhodium(II) Carboxamide Catalyzed Reactions of Diazo Esters. (1990) (1)
- Asymmetric Catalysis. Part 58. Enantioselective S-H and C-H Insertions with Optically Active Rh(II) and Cu(II) Catalysts. (2010) (1)
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- Construction of β‐Lactams by Highly Selective Intramolecular C‐H Insertion from Rhodium(II) Carboxylate Catalyzed Reactions of Diazoacetamides. (1988) (1)
- Acetolysis of 4-bromobutyl-1,1-d2 p-nitrobenzenesulfonate. Evidence for 1,4-bromine participation and the existence of a 5-membered cyclic bromonium ion during acetolysis. (1968) (1)
- A new approach to organic laboratory projects (1973) (1)
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- Dirhodium(II) Tetrakis[R 2‐oxaazetidine‐4(S)‐carboxylate] (2005) (1)
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- Chiral Dirhodium(II) Carboxamidates for Catalytic Asymmetric Synthesis (2005) (1)
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- Synthesis of 2-Deoxyxylolactone from Glycerol Derivatives via Highly Enantioselective Carbon-Hydrogen Insertion Reactions. (1994) (0)
- Unusually large scalar coupling between geminal protons in a saturated pyrimidine (2016) (0)
- SILANE REDUCTIONS IN ACIDIC MEDIA PART 2, REDUCTIONS OF ARYL ALDEHYDES AND KETONES BY TRIALKYLSILANES IN TRIFLUOROACETIC ACID, A SELECTIV METHOD FOR CONVERTING THE CARBONYL GROUP TO METHYLENE (1973) (0)
- Highly Regio- and Stereoselective Dirhodium Vinylcarbene Induced Nitrone Cycloaddition with Subsequent Cascade Carbenoid Aromatic Cycloaddition/N—O Cleavage and Rearrangement. (2012) (0)
- Outer-Sphere One-Electron Reductions of Arenediazonium Salts. (1987) (0)
- Cu/Box-Catalyzed Mukaiyama-Michael Additionstowards Chiral Diazoacetoacetates (2011) (0)
- Expedient Access to Substituted 3‐Amino‐2‐cyclopentenones by Dirhodium‐Catalyzed [3 + 2]‐Annulation of Silylated Ketene Imines and Enoldiazoacetates. (2014) (0)
- Enantiocontrol in Intramolecular Cyclopropanation of Diazoketones. Conformational Control of Metal Carbene Alignment. (1997) (0)
- Constructing Chiral Diazoacetoacetates by Enantioselective Catalytic Mukaiyama Aldol Reactions. (2006) (0)
- BORON TRIFLUORIDE CATALYZED ELIMINATION OF BORATE ESTERS. A MILD PROCEDURE FOR THE PREPARATION OF ALKENES (1977) (0)
- Rhodium-Catalyzed Asymmetric C-H Insertion and Cyclopropanation (2007) (0)
- Enantioselective Syntheses of 2‐Deoxyxylono‐1,4‐lactone and 2‐Deoxyribono‐1,4‐lactone from 1,3‐Dioxan‐5‐yl Diazoacetates. (2000) (0)
- Chiral Rhodium(II) Carboxamides. Remarkably Effective Catalysts for Enantioselective Metal Carbene Transformations (1993) (0)
- Enantioselective Catalytic Intramolecular Cyclopropanation of Allylic . alpha.‐Diazopropionates Optimized with Dirhodium(II) Tetrakis(methyl 2‐ oxazolidinone‐4(S or R)‐carboxylate). (1996) (0)
- Reaction times aims for undergrads (1992) (0)
- Metal Carbene Cycloaddition Reactions (2021) (0)
- Linked PDF of Table of Contents (2022) (0)
- Inverse Electron Demand Diels-Alder-Type Heterocycle Syntheses with 1,2,3-Triazine 1-Oxides: Expanded Versatility. (2023) (0)
- REACTIONS OF THE NITROSONIUM ION. 11. FLUORIDE TRANSFER FROM COMPLEX FLUORIDE E ANIONS TO CARBENIUM IONS IN THE NITROSATIVE DECOMPOSITION OF ALIPHATIC AZIDES (1979) (0)
- Vinyldiazolactone as a Vinylcarbene Precursor: Highly Selective C—H Insertion and Cyclopropanation Reactions. (2007) (0)
- Medium effects in nucleophilic substitution reactions (1968) (0)
- Rhodium Acetate-Catalyzed Aerobic Mukaiyama Epoxidation of Alkenes. (2014) (0)
- Macrocycle Formation by Catalytic Intramolecular Cyclopropanation. A New General Methodology for the Synthesis of Macrolides. (1998) (0)
- Optimization of Enantiocontrol in cis‐Selective Cyclopropanation Reactions Catalyzed by Dirhodium(II) Tetrakis[alkyl 2‐oxaazetidine‐4(S)‐carboxylates]. (2000) (0)
- Medium effec ts in nucleophilic substitution reactions (1968) (0)
- Addition of Arylchlorocarbenes (II) to α,β‐Unsaturated Esters. Absolute Rates, Substituent Effects, and Variable Reactivities. (1989) (0)
- The Chemistry of Vicinal Tricarbonyls: An Expedient Route to Fully‐Substituted 3‐Aminopyrroles. (2015) (0)
- A Facile Route to Some Useful Homochiral Alkyl Imidazolidin-2-one-4(S)- carboxylates. (1996) (0)
- Conformation and Electronic Preferences in Rhodium(II) Carboxylate and Rhodium(II) Carboxamide-Catalyzed Carbon-Hydrogen Insertion Reactions of N,N-Disubstituted Diazoacetoacetamides. (1990) (0)
- Stereoselective Synthesis of Highly Functionalized α‐Diazo‐β‐ketoalkanoates via Catalytic One‐Pot Mukaiyama‐Aldol Reactions. (2010) (0)
- Activation Parameters for the Reaction of Phenylchlorocarbene (II) with Pyridine (IV), Tri-n-butyltin Hydride (VI), and Triethylsilane (VIII). Evidence Against the Need to Invoke Reversibly Formed Complexes in the Reaction of this Car (1989) (0)
- Failure of the principle of hard and soft acids and bases to explain the amount of cyclization of various hex-5-enyl derivatives during acetolysis (1967) (0)
- CYCLIC ETHER FORMATION IN OXIDATIONS OF PRIMARY ALCOHOLS BY CERIUM(IV), REACTIONS OF 5-PHENYL-1-PENTANOL, 4-PHENYL-1-BUTANOL, AND 3-PHENYL-1-PROPANOL WITH CERIC AMMONIUM NITRATE (1975) (0)
- Formation of Macrocyclic Lactones by Enantioselective Intramolecular Cyclopropanation of Diazoacetates Catalyzed by Chiral Cu(I) and Rh(II) Compounds. (1996) (0)
- Stereoretentive Catalytic [3 + 2]/[3 + 3]-Cycloaddition of Nonracemic Donor-Acceptor Cyclopropanes: Synthesis of Substituted Pyrrolidines and 1,2-Oxazinanes. (2023) (0)
- Facile Catalytic Methods for Intermolecular Generation of Allylic Oxonium Ylides and Their Stereoselective (2,3)‐Sigmatropic Rearrangement. (1989) (0)
- Enantioselective Carbonyl—Ene Reactions Catalyzed by Chiral Cationic Dirhodium(II,III) Carboxamidates. (2015) (0)
- Brønsted Acid Catalyzed Friedel–Crafts‐Type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds (2020) (0)
- Enantiocontrolled Macrocycle Formation by Catalytic Intramolecular Cyclopropanation. (2000) (0)
- Dirhodium(II) Tetraacetate (2006) (0)
- Boron Trifluoride-Catalyzed Elimination of Borate Esters. A Mild Procedure for the Preparation of Alkenes (1977) (0)
- Making ends meet: Catalytic cycloaddition (2006) (0)
- OXIDATIVE DEAMINATION OF PRIMARY AMINES- SELECTIVE SYNTHESIS OF GEMINAL DIHALIDES (1976) (0)
- Research as Chemical Education. (1984) (0)
- First Attempts at Differential Diastereoselection in Catalytic Reactions of N-Chirally Substituted Dirhodium(II) Tetrakis[methyl 2-oxoimidazolidine-4(S)-carboxylates] with Diazoacetates. (2010) (0)
- NITROSATIVE CLEAVAGE OF BENZALAZINE AND RELATED ALDEHYDE AZINES, PRODUCTION, DECOMPOSITION AND TRAPPING OF IMINODIAZONIUM IONS (1974) (0)
- Highly Enantioselective Oxonium Ylide Formation and Stevens Rearrangement Catalyzed by Chiral Dirhodium(II) Carboxamidates. (1997) (0)
- Catalytic Conversion of Diazocarbonyl Compounds to Imines: Applications to the Synthesis of Tetrahydropyrimidines and β‐Lactams. (2014) (0)
- Dinitrogen Extrusion from Enoldiazo Compounds under Thermal Conditions: Synthesis of Donor—Acceptor Cyclopropenes. (2015) (0)
- Lewis Acid Catalyzed Diastereoselective 1,3-Dipolar Cycloaddition Between Diazoacetoacetate Enones and Azomethine Ylides. (2014) (0)
- Cationic Dirhodium Carboxamidates for Lewis Acid Catalyzed Reactions (2008) (0)
- OPERATION AND UTILIZATION OF THE RHODE ISLAND NUCLEAR SCIENCE CENTER REACTOR FACILITY. (1972) (0)
- A New Rhodium(II) Phosphate Catalyst for Diazocarbonyl Reactions Including Asymmetric Synthesis. (1993) (0)
- Dirhodium(II)-Catalyzed Carbonyl Ylide Generation. Stereoelectronic Control in Dioxolane Formation. (1998) (0)
- SILANE REDUCTIONS IN ACIDIC MEDIA. VIII. BORON TRIFLUORIDE CATALYZED ORGANOSILANE REDUCTIONS. SELECTIVITY AND MECHANISM (1976) (0)
- Dirhodium(II) Tetrakis[methyl 2‐oxapyrrolidine‐carboxylate] (2005) (0)
- Dirhodium(II) Tetrakis[methyl 1‐(3‐phenylpropanoyl)‐2‐oxaimidazolidine‐carboxylate] (2005) (0)
- Addition Reactions Catalyzed by Rhodium(II) Carboxylates (1992) (0)
- Enantioselectivity and cis/trans‐Selectivity in Dirhodium(II)‐ Catalyzed Addition of Diazoacetates to Olefins. (1995) (0)
- INFLUENCE OF OLEFIN COORDINATION OF CYCLOPROPANATION SELECTIVITY (1985) (0)
- Enhancement of Stereoselectivity in Catalytic Cyclopropanation Reactions. (1987) (0)
- Catalytic Asymmetric Synthesis of Cyclopentyl β‐Amino Esters by [3 + 2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates. (2016) (0)
- Formation of a Dipolar Adduct in the Reaction of Arylchlorocarbenes with Diethyl Maleate. (1987) (0)
- Synthetic Advantages of Chiral Dirhodium (II) Carboxamidate Catalysts (2003) (0)
- Untitled Document (2001) (0)
- Effectively Managing through a Crisis (2009) (0)
- Rhodium(II)‐ and Copper(II)‐Catalyzed Reactions of Enol Diazoacetates with Nitrones: Metal Carbene versus Lewis Acid Directed Pathways. (2012) (0)
- REACTIONS OF THE NITROSONIUM ION. IX. NATURE OF FLUORIDE TRANSFER FROM COMPLEX FLUORIDE ANIONS TO CARBENIUM IONS (1976) (0)
- Cumulative latency-of-response recording for evaluating CAL (1988) (0)
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Other Resources About Michael P. Doyle
What Schools Are Affiliated With Michael P. Doyle ?
Michael P. Doyle is affiliated with the following schools:
- University of Regina
- University of St. Thomas
- University of Maryland, College Park
- University of California, Berkeley
- University of Texas at Austin
- Iowa State University
- University of Alberta
- Trinity University
- University of Texas at San Antonio
- University of Arizona
- Princeton University
- University of KwaZulu-Natal
