Miguel A. Esteruelas

Miguel A. Esteruelas's AcademicInfluence.com Rankings

Chemistry

#4335

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#5408

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Organic Chemistry

#705

World Rank

#802

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chemistry Degrees

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Chemistry

Miguel A. Esteruelas's Degrees

PhD Chemistry University of Barcelona
Masters Chemistry University of Barcelona
Bachelors Chemistry University of Barcelona

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Miguel A. Esteruelas's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Transition metal liquid crystals: advanced materials within the reach of the coordination chemist (1992) (371)
Dihydrogen Complexes as Homogeneous Reduction Catalysts. (1998) (147)
Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyridyl Chromium(III) Complexes (2003) (142)
Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and osmium(II) complexes containing triisopropylphosphine as ligand (1986) (126)
Direct Access to POP-Type Osmium(II) and Osmium(IV) Complexes: Osmium a Promising Alternative to Ruthenium for the Synthesis of Imines from Alcohols and Amines (2011) (115)
Insertion reactions of the 16-electron complexes MHCl(CO)[P(CHMe2)3]2 (M = Ru, Os) with alkynes. The x-ray crystal structure of [(E)-PhCH:CHOs(Cl)(CO)[P(CHMe2)3]2 (1986) (113)
Osmium Catalyst for the Borrowing Hydrogen Methodology: α-Alkylation of Arylacetonitriles and Methyl Ketones (2013) (110)
Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands (1992) (108)
Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(Pr3)2 (Pr3 = P-i-Pr3, PMe-t-Bu2) (1991) (103)
Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR3)2 [PR3 = PMe-tert-Bu2 and P-i-Pr3] (1989) (91)
Osmium–carbon double bonds: Formation and reactions (2007) (85)
N-Heterocyclic Carbene−Osmium Complexes for Olefin Metathesis Reactions (2005) (83)
Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ-Bond Activation Reactions. (2016) (79)
Preparation, X-ray Structure, and Reactivity of an Osmium-Hydroxo Complex Stabilized by an N-Heterocyclic Carbene Ligand: A Base-Free Catalytic Precursor for Hydrogen Transfer from 2-Propanol to Aldehydes (2008) (74)
Dehalogenation and Hydrogenation of Aromatic Compounds Catalyzed by Nanoparticles Generated from Rhodium Bis(imino)pyridine Complexes (2010) (74)
Influence of the Anion of the Salt Used on the Coordination Mode of an N-Heterocyclic Carbene Ligand to Osmium (2007) (72)
Osmium-catalyzed 7-endo heterocyclization of aromatic alkynols into benzoxepines. (2010) (70)
Aromatic diosmatricyclic nitrogen-containing compounds. (2008) (70)
Reactions of a Hexahydride-Osmium Complex with Aldehydes: Double C−Hα Activation−Decarbonylation and Single C−Hα Activation−Hydroxylation Tandem Processes and Catalytic Tishchenko Reactions (2004) (68)
Ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenenes. (2011) (67)
POP-pincer silyl complexes of group 9: rhodium versus iridium. (2013) (66)
CCC–Pincer–NHC Osmium Complexes: New Types of Blue-Green Emissive Neutral Compounds for Organic Light-Emitting Devices (OLEDs) (2014) (66)
A deceptively simple case of selective hydrogenation of phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complex (1992) (65)
Preparation and characterization of an isometallabenzene with the structure of a 1,2,4-cyclohexatriene. (2004) (62)
Abnormal and normal N-heterocyclic carbene osmium polyhydride complexes obtained by direct metalation of imidazolium salts (2008) (62)
Stabilization of NH tautomers of quinolines by osmium and ruthenium. (2006) (60)
Homogeneous Catalysis by Osmium Complexes. A Review (1995) (57)
Osmium NHC complexes from alcohol-functionalized imidazoles and imidazolium salts (2011) (57)
Exclusive formation of cis-PhCH:CH(SiEt3) by addition of triethylsilane to phenylacetylene catalyzed by ruthenium complex [(Me2CH)3P]2RuHCl(CO) (1993) (57)
Reactions of a Hexahydride−Osmium Complex with Aromatic Ketones: C−H Activation versus C−F Activation§ (2001) (56)
Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes. (2012) (56)
POP-pincer ruthenium complexes: d(6) counterparts of osmium d(4) species. (2014) (55)
η2‐Tetrahydroborato)ruthenium(II)‐ und ‐osmium(II)‐Komplexe mit fluktuierender Struktur (1987) (55)
Reactivity of OsH4(CO)(PiPr3)2 toward terminal alkynes: synthesis and reactions of the alkynyl-dihydrogen complexes OsH(C2R)(.eta.2-H2)(CO)(PiPr3)2 (R = Ph, SiMe3) (1993) (55)
POP-pincer osmium-polyhydrides: head-to-head (Z)-dimerization of terminal alkynes. (2013) (54)
Addition of carbon nucleophiles to the allenylidene ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4: synthesis of new organic ligands by formal C−C coupling between mutually inert fragments (1997) (54)
C(sp2)−H Activation of RCHE−py (E = CH, N) and RCHCHC(O)R‘ Substrates Promoted by a Highly Unsaturated Osmium−Monohydride Complex (2005) (54)
POP–Rhodium-Promoted C–H and B–H Bond Activation and C–B Bond Formation (2015) (54)
Selective hydration of nitriles to amides promoted by an Os-NHC catalyst: Formation and X-ray characterization of κ2-amidate intermediates (2012) (53)
Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: formation of osmacyclopentapyrrole derivatives. (2006) (52)
Five-Coordinate Complex [RuHCl(CO)(PPri3)2] as a Precursor for the Preparation of New Cyclopentadienylruthenium Compounds Containing Unsaturated η1-Carbon Ligands† (1996) (52)
Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate (2010) (52)
Coordination of H2 and O2 to [OsHCl(CO)(PiPr3)2]: A Catalytically Active M(η2‐H2) Complex (1988) (52)
Reduction and C(sp2)-H bond activation of ketones promoted by a cyclopentadienyl-osmium-dihydride-dihydrogen complex (2005) (51)
Ammonia-Borane dehydrogenation promoted by an osmium dihydride complex: Kinetics and mechanism (2015) (50)
Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands (2008) (50)
An Osmium-Carbene Complex with Fischer−Schrock Ambivalent Behavior (2003) (49)
MHCl(CO)(PiPr3)2 (M = Ru, Os) complexes as catalyst precursors for the reduction of unsaturated substrates (1988) (49)
Understanding the formation of N-H tautomers from alpha-substituted pyridines: tautomerization of 2-ethylpyridine promoted by osmium. (2007) (48)
Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes (1993) (48)
Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst. (2016) (48)
Conclusive evidence on the mechanism of the rhodium-mediated decyanative borylation. (2015) (48)
Xantphos-type complexes of group 9: rhodium versus iridium. (2013) (47)
Tris(pyrazol-1-yl)methane-rhodium(I) and -iridium(I) complexes; cyrstal structure of [Rh(COD)(tpzm)][RhCl2(COD)]·3CHCl3 (1988) (46)
Synthesis, molecular structure, and reactivity of octahedral alkylhydridoosmium(II) complexes [OsH(R)(CO)2(PR'3)2] (1992) (46)
Reactions of the Dihydrogen Complex OsCl2(.eta.2-H2)(CO)(PiPr3)2 with Terminal Alkynes: Synthesis of Carbene, Vinylcarbene, and .mu.-Bis-carbene Osmium (II) Derivatives (1995) (46)
Hydrosilylation of phenylacetylene via an Os(SiEt3)(.eta.2-H2) intermediate catalyzed by OsHCl(CO)(PPr-iso3)2 (1991) (45)
Alkyne-coupling reactions catalyzed by OsHCl(CO)(PiPr3)2 in the presence of diethylamine (2001) (45)
Hydride-alkenylcarbyne to alkenylcarbene transformation in bisphosphine-osmium complexes. (2005) (44)
Osmium and Ruthenium Complexes Containing an N-Heterocyclic Carbene Ligand Derived from Benzo[h]quinoline (2007) (44)
C−H Bond Activation of Terminal Allenes: Formation of Hydride-Alkenylcarbyne-Osmium and Disubstituted Vinylidene-Ruthenium Derivatives∥ (2010) (44)
C-H bond activation reactions in ketones and aldehydes promoted by POP-pincer osmium and ruthenium complexes (2015) (44)
Reactions of a Dihydrogen Complex with Terminal Alkynes: Formation of Osmium−Carbyne and −Carbene Derivatives with the Hydridotris(pyrazolyl)borate Ligand† (2008) (43)
Catalytic transfer hydrogenation by cationic rhodium(I) complexes (1981) (43)
Activation of C(sp2)−H and Reduction of CE (E = CH, N) Bonds with an Osmium-Hexahydride Complex: Influence of E on the Behavior of RCHE-py Substrates (2004) (43)
An Acyl-NHC osmium cooperative system: Coordination of small molecules and heterolytic B-H and O-H bond activation (2015) (42)
Bis-alkynyl- and hydrido-alkynyl-osmium(II) and ruthenium(II) complexes containing triisopropylphosphine as ligand (1989) (42)
From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates. (2011) (42)
C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-vinylpyridine-acetylene couplings. (2006) (41)
REACTIONS OF NEW OSMIUM-DIHYDRIDE COMPLEXES WITH TERMINAL ALKYNES : METALLACYCLOPROPENE VERSUS METAL-CARBYNE. INFLUENCE OF THE ALKYNE SUBSTITUENT (1999) (40)
Cleavage of both C(sp3)-C(sp2) bonds of alkylidenecyclopropanes: formation of ethylene-osmium-vinylidene complexes. (2010) (40)
Osmium(III) complexes with POP pincer ligands: preparation from commercially available OsCl(3)·3H(2)O and their X-ray structures. (2010) (40)
Multiple C-H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings (2010) (38)
Synthesis and characterization of hydride−alkynyl, allenylidene, carbyne, and functionalized-alkynyl complexes containing the [Os(η5-C5H5)(PiPr3)2]+ fragment: The complex [Os(η5-C5H5)(CCCPh2)(PiPr3)2]PF6, a new type of allenylidene derivative from the reactivity point of view (2000) (38)
Influence of the group 14 element on the deprotonation of OsH(η5-C5H5)(C≡CPh) (EPh3) (PiPr3) (E = Si, Ge): Two different organometallic chemistries (2001) (38)
Reactions of elongated dihydrogen-osmium complexes containing orthometalated ketones with alkynes: Hydride-vinylidene-π-alkyne versus hydride-osmacyclopropene (2003) (38)
Dehalogenation of Hexachlorocyclohexanes and Simultaneous Chlorination of Triethylsilane Catalyzed by Rhodium and Ruthenium Complexes (2004) (37)
Hydrogenation of benzylideneacetone catalyzed by OsHCl(CO)(PR{sub 3}){sub 2} (PR{sub 3} = P-i-Pr{sub 3}, PMe-t-Bu{sub 2}): New roles of dihydrogen complexes in homogeneous catalytic hydrogenation (1992) (37)
1,2,3-DIHETEROCYCLIZATION REACTIONS ON THE ALLENYLIDENE LIGAND OF A RUTHENIUM COMPLEX (1998) (37)
NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand (2009) (37)
Indirect cooperative effects leading to synergism in bimetallic homogeneous catalysts containing azolates as bridging ligands (1991) (37)
Coordination and Rupture of Methyl C(sp3)−H Bonds in Osmium−Polyhydride Complexes with δ Agostic Interaction (2007) (37)
Synthesis and Reactivity of the Unusual Five-Coordinate Hydrido−Hydroxo Complex OsH(OH)(CO)(PiPr3)2 (1997) (36)
(NHC)Palladium Complexes from Hydroxy‐Functionalized Imidazolium Salts as Catalyst for the Microwave‐Accelerated Fluorine‐Free Hiyama Reaction (2011) (35)
Osmium–carbon multiple bonds: Reduction and C–C coupling reactions (2011) (35)
Osmium hydride acetylacetonate complexes and their application in acceptorless dehydrogenative coupling of alcohols and amines and for the dehydrogenation of cyclic amines (2017) (35)
OsHCl(CO)(PiPr3)2 as catalyst for ring-opening metathesis polymerization (ROMP) and tandem ROMP-hydrogenation of norbornene and 2,5-norbornadiene (2004) (35)
Displacement of Phenyl and Styryl Ligands by Benzophenone Imine and 2-Vinylpyridine on Ruthenium and Osmium (2006) (35)
REGIOSELECTIVE ADDITION OF PRPH2 TO THE CALPHA ATOM OF THE DIPHENYLALLENYLIDENE LIGAND OF RU(ETA 5-C5H5)(C=C=CPH2)(CO)(PPFI3)BF4 (1998) (34)
New Titanium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Aminoalkyl Substituent: Preparation, Behavior of the Amino Group, and Catalytic Hydroamination of Alkynes (2005) (34)
The chemical and catalytic reactions of hydrido-chloro-carbonylbis (triisopropylphosphine)osmium(II) and its major derivatives (2001) (34)
The reduction of α,β-unsaturated ketones and cyclohexadienes catalyzed by mhcl(CO)(PiPr3)2 (M = Ru, Os) complexes (1989) (33)
Sequential and selective hydrogenation of the Cα−Cβ and M−Cα double bonds of an allenylidene ligand coordinated to osmium: New reaction patterns between an allenylidene complex and alcohols (2007) (33)
Alcohol activation by [Ir(COD)(tris(pyrazol-1-yl)methane)]+ and [Ir(COD) (tris(pyrazol-1-yl)ethanel+ cations: formation of alkoxycarbonyl derivatives [(tpzm)IrH(CO2R′)(CO)]+ and [(tpze)IrH(CO2R′)]+ (R′ = Me, Et, i-Pr) (1989) (33)
Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal-Mediated Hydration of Functionalized Allenes. (2016) (33)
Thermal properties of polynorbornene (cis- and trans-) and hydrogenated polynorbornene (2007) (33)
The Dihydride−Osmium(IV) Complex [OsH2(κ2-O2CCH3)(H2O)(PiPr3)2]BF4 as a Precursor for Carbon−Carbon Coupling Reactions (2000) (33)
Hydride−Hydroxyosmacyclopropene versus Hydride−Hydroxycarbyne and Cyclic Hydroxycarbene: Influence of the Substituents at the C(OH) Carbon Atom of the Carbon Donor Ligand (2000) (33)
Stoichiometric and Catalytic Deuteration of Pyridine and Methylpyridines by H/D Exchange with Benzene-d6 Promoted by an Unsaturated Osmium Tetrahydride Species (2009) (32)
A Four-Electron pi-Alkyne Complex as Precursor for Allenylidene Derivatives: Preparation, Structure, and Reactivity of [Os(eta^5-C~5H~5)(C=C=CPh~2)L(P^iPr~3)]PF~6 (L = CO, PHPh~2) (2004) (32)
C−H Bond Activation Reactions in π-Allene−Osmium−Triisopropylphosphine Complexes with Cyclopentadienyl or Hydridotris(pyrazolyl)borate Ligands: Formation of Isopropenyldiisopropylphosphine versus Hydride−Alkenylcarbyne Derivatives (2010) (32)
Addition of Secondary and Primary Amines to the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4: Synthesis of Azoniabutadienyl, Aminoallenyl, and Azabutadienyl Derivatives of Ruthenium(II) (1999) (32)
Synthesis and mesomorphism of stilbazole complexes of rhodium(I) and iridium(I) (1991) (32)
Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketones (1991) (32)
Reactions of Os(η5-C5H5)Cl(PiPr3)2 with NHCPh2 and PPh3: The Unit Os(η5-C5H5)(PiPr3) as Support for the Study of the Competitive Alkane−Arene Intramolecular C−H Activation (2000) (31)
CARBON-CARBON COUPLING AND CARBON-HYDROGEN ACTIVATION REACTIONS IN BIS(TRIISOPROPYLPHOSPHINE)OSMIUM COMPLEXES (1996) (31)
Cβ-H activation of aldehydes promoted by an osmium complex (2004) (31)
Oxidative Addition of Group 14 Element Hydrido Compounds to OsH(2)(eta(2)-CH(2)=CHEt)(CO)(P(i)Pr(3))(2): Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV). (1996) (31)
Dehalogenation of Polychloroarenes with HSiEt3 Catalyzed by an Homogeneous Rhodium−Triphenylphosphine System (1999) (31)
Synthesis and Characterization of OsX{NHC(Ph)C6H4}H2(PiPr3)2 (X = H, Cl, Br, I): Nature of the H2 Unit and Its Behavior in Solution (1998) (31)
Osmium(II)–Bis(dihydrogen) Complexes Containing Caryl,CNHC–Chelate Ligands: Preparation, Bonding Situation, and Acidity (2015) (31)
Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines. (2015) (31)
Borinium cations as sigma-B-H ligands in osmium complexes. (2010) (31)
Quantum Mechanical Exchange Coupling in Trihydridoosmium Complexes Containing Azole Ligands (1996) (30)
Reactions of the Square-Planar Compounds Ir(C2Ph)L2(PCy3) (L2 = 2 CO, TFB) with HSiR3 (R = Et, Ph) and Hx+1SiPh3-x (x = 1, 2): Stoichiometric and Catalytic Formation of Si−C Bonds (1996) (30)
Liquid-crystal behavior in ionic complexes of silver(I): Molecular structure-mesogenic activity relationship (1990) (30)
Reactions of OsHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of (Vinylcarbene)osmium(II) Complexes (1994) (30)
SYNTHESIS OF HYDRIDO-VINYLIDENE AND HYDRIDO-CARBYNE OSMIUM COMPLEXES CONTAINING PYRAZOLE : NEW EXAMPLES OF N-H...Y (Y = N, F, CL) HYDROGEN BONDS (1999) (30)
Preparation, X-ray Structure, and Reactivity of an Olefin-Carbene-Osmium Complex: α-Alkenylphosphine to α-Allylphosphine Transformation via an Osmaphosphabicyclopentane Intermediate (2004) (30)
Reactions of Osmium Hydride Complexes with Terminal Alkynes: Synthesis and Catalytic Activity of OsH(.eta.2-O2CCH3)(C:CHPh)(PiPr3)2 (1994) (30)
Reactions of a Dihydride−Osmium(IV) Complex with Aldehydes: Influence of the Substituent at the Carbonyl Group (2008) (30)
Hydride Exchange Processes in the Coordination Sphere of Transition Metal Complexes: The OsH3(BH4)(PR3)2 System (1996) (30)
Carbon−Carbon Coupling of Two Alkenyl Fragments on a Saturated Compound (1997) (30)
Preparation and Structure of Alkylidene−Osmium and Hydride−Alkylidyne−Osmium Complexes Containing an N-Heterocyclic Carbene Ligand (2007) (30)
Mechanism of the hydrogenation of phenylacetylene catalyzed by [Ir(COD)(.eta.2iso-Pr2PCH2CH2OMe)]BF4 (1993) (30)
Synthesis, Spectroscopic Characterization, and Reactivity of the Unusual Five-Coordinate Hydrido−Vinylidene Complex OsHCl(CCHPh)(PiPr3)2: Precursor for Dioxygen Activation (1997) (29)
Dehydrogenation of Formic Acid Promoted by a Trihydride-Hydroxo-Osmium(IV) Complex: Kinetics and Mechanism (2018) (29)
N-h and N-C bond activation of pyrimidinic nucleobases and nucleosides promoted by an osmium polyhydride. (2012) (29)
Elongated σ-Borane versus σ-Borane in Pincer–POP–Osmium Complexes (2017) (29)
Reactivity of MH([eta][sup 2]-H[sub 2]BH[sub 2])(CO)(PiPr[sub 3])[sub 2] (M = Os, Ru) toward electrophiles: Synthesis of new hydridocarbonylosmium(II) and -ruthenium(II) complexes containing triisopropylphosphine as ligand (1992) (29)
Iridium and rhodium complexes with tetrafluorobenzobarrelene diolefins (1999) (29)
Osmium-allenylidene complexes containing an N-heterocyclic carbene ligand (2008) (29)
Preparation of Tris-Heteroleptic Iridium(III) Complexes Containing a Cyclometalated Aryl-N-Heterocyclic Carbene Ligand. (2018) (29)
Chelated Assisted Metal-Mediated N–H Bond Activation of β-Lactams: Preparation of Irida-, Rhoda-, Osma-, and Ruthenatrinems (2014) (29)
One-pot synthesis for osmium(II) azavinylidene-carbyne and azavinylidene-alkenylcarbyne complexes starting from an osmium(II) hydride-azavinylidene compound (2001) (29)
Reactivity of the Imine−Vinylidene Complexes OsCl2(CCHPh)(NHCR2)(PiPr3)2 [CR2 = CMe2, C(CH2)4CH2]† (2001) (29)
Osmium-Promoted Dehydrogenation of Amine–Boranes and B–H Bond Activation of the Resulting Amino–Boranes (2014) (29)
Preparation and X-ray Structures of Alkyl−Titanium(IV) Complexes Stabilized by Indenyl Ligands with a Pendant Ether or Amine Substituent and Their Use in the Catalytic Hydroamination of Alkynes (2007) (29)
Synthesis and reactions of dihydrido(triethylsilyl)(1,5-cyclooctadiene)-iridium(III) complexes: catalysts for dehydrogenative silylation of alkenes (1986) (29)
Osmium Catalysts for Acceptorless and Base-Free Dehydrogenation of Alcohols and Amines: Unusual Coordination Modes of a BPI Anion (2018) (29)
Reactions of RuHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of Ruthenium(II) Hydroxyvinyl and Vinylcarbene Complexes (1994) (29)
New Half-Sandwich Alkyl, Aryl, Aryloxide, and Propargyloxide Titanium(IV) Complexes Containing a Cyclopentadienyl Ligand with a Pendant Ether Substituent: Behavior and Influence in the Hydroamination of Alkynes of the Ether Group (2006) (28)
Cationic Dihydride Boryl and Dihydride Silyl Osmium(IV) NHC Complexes: A Marked Diagonal Relationship (2013) (28)
α-Substituted Alkenyl and α-Disubstituted Alkylidene Complexes with the OsCl(CO)(PiPr3)2 Skeleton (2007) (28)
Arene-iridium(i) complexes. Crystal structures of [Ir(TFB)(arene)]BF4 (TFB = tetrafluorobenzobarrelene; arene = 1,4-Me2C6H4 or C6Me6) (1983) (28)
Preparation, Hydrogen Bonds, and Catalytic Activity in Metal-Promoted Addition of Arylboronic Acids to Enones of a Rhodium Complex Containing an NHC Ligand with an Alcohol Function (2012) (28)
Reactions of Ir(acac)(cyclooctene)(PCy3) with H2, HC⋮CR, HSiR3, and HSnPh3: The Acetylacetonato Ligand as a Stabilizer for Iridium(I), Iridium(III), and Iridium(V) Derivatives (1996) (28)
Square-Planar Alkylidyne-Osmium and Five-Coordinate Alkylidene-Osmium Complexes: Controlling the Transformation from Hydride-Alkylidyne to Alkylidene. (2016) (27)
Preparation of Half-Sandwich Osmium Complexes by Deprotonation of Aromatic and Pro-aromatic Acids with a Hexahydride Brønsted Base (2011) (27)
Five-Coordinate Complexes MHCl(CO)(PiPr3)2 (M = Os, Ru) as Precursors for the Preparation of New Hydrido− and Alkenyl−Metallothiol and Monothio−β-Diketonato Derivatives (1997) (27)
Meyer's Complex OsH2Cl2(PiPr3)2 as a Precursor for the Preparation of New Cyclopentadienylosmium Compounds (1997) (27)
THE OS(CO)(PIPR3)2 UNIT AS A SUPPORT FOR THE TRANSFORMATION OF TWO ALKYNE MOLECULES INTO NEW ORGANOMETALLIC LIGANDS (1997) (27)
Synthesis and reactions of new hydridosilyliridium(III) complexes containing the diolefin tetrafluorobenzobarrelene (1993) (27)
Preparation of [C,N,O]-Pincer Osmium Complexes by Alkylidene Metathesis with a Methyl Group of 2,6-Diacetylpyridine (2007) (27)
The Five-Coordinate Hydrido−Dihydrogen Complex [OsH(η2-H2)(CO)(PiPr3)2]BF4 Acting as a Template for the Carbon−Carbon Coupling between Methyl Propiolate and 1,1-Diphenyl-2-propyn-1-ol (1998) (27)
Dynamic Behavior in Solution of the Trans‐Hydridodihydrogen Complex [OsHCl(n2‐H2)(CO)(PiPr3)2]: Ab Initio and NMR Studies (1996) (27)
Preparation, properties, and reactivity of dihydridosilyl(.eta.4-cycloocta-1,5-diene)iridium(III) complexes. X-ray crystal structures of the dihydrido silyl complex IrH2(SiEt3)(.eta.4-C8H12)(AsPh3) and the cyclooctenyl derivative Ir(1-.sigma.,4,5-.eta.2-C8H13)(CO)2(AsPh3) (1987) (27)
Selective C–Cl Bond Oxidative Addition of Chloroarenes to a POP–Rhodium Complex (2017) (27)
Nematic phases in ionic melts: Mesogenic ionic complexes of silver(I) (1989) (27)
The allenylidene complex [Ru(η5-C5H5)(C=C=CPh2)(CO)(PiPr3)]BF4 as a precursor of novel pyrido[1,2-a]pyrimidinyl and 1,3-thiazinyl complexes (2000) (26)
Two- and Four-Electron Alkyne Ligands in Osmium−Cyclopentadienyl Chemistry: Consequences of the π⊥→M Interaction (2002) (26)
Preparation of Half-Sandwich Alkyl−Titanium(IV) Complexes Stabilized by a Cyclopentadienyl Ligand with a Pendant Phosphine Tether and Their Use in the Catalytic Hydroamination of Aliphatic and Aromatic Alkynes (2006) (26)
Hydroosmiation of allenes and reductive elimination of olefin in unsaturated osmium(IV) polyhydrides: Hydride versus chloride (2013) (26)
NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism (2008) (26)
Addition of CH3CO2H and HBF4 to alkynyl complexes of ruthenium(II) and osmium(II) (1994) (26)
New Cyclopentadienylosmium Compounds Containing Unsaturated Carbon Donor Coligands: Synthesis, Structure, and Reactivity of Os(η5-C5H5)Cl(CCCPh2)(PiPr3) (1998) (26)
Hydrosilylation of alkenes by iridium complexes (1986) (26)
Formation of osmium- and ruthenium-cyclobutylidene complexes by ring expansion of alkylidenecyclopropanes. (2009) (25)
[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]x and Its Activity as an Ionic Hydrogenation and Etherification Catalyst (2008) (25)
Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmium. (2018) (25)
Osmium(II) Complexes Containing a Dianionic CCCC-Donor Tetradentate Ligand (2016) (25)
Olefin-alkylidene equilibrium of 2-vinylpyridine in osmium- and ruthenium-hydrido-tris(pyrazolyl)borate and osmium-cyclopentadienyl complexes (2009) (25)
Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes (2015) (25)
Reactions of an Osmium-Elongated Dihydrogen Complex with Terminal Alkynes: Formation of Novel Bifunctional Compounds with Amphoteric Nature (2002) (25)
REACTION OF OSHCL(CO)(PIPR3)2 WITH CYCLOHEXYLACETYLENE : FORMATION OF A HYDRIDO-VINYLIDENE COMPLEX VIA A 1,3-HYDROGEN SHIFT (1995) (25)
Hydrosilylation of phenylacetylene catalyzed by [Ir(COD)(η2-iPr2PCH2CH2OMe)][BF4] (1995) (25)
Synthesis and catalytic activity of heterodinuclear Ru-Ir and Ru-Rh complexes. Crystal structure of [H(CO)(PPh3)2Ru(μ-Cl)(μ-pz)Ir(TFB)] (pz = pyrazolate, TFB = tetrafluorobenzobarrelene) (1990) (25)
Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex (2003) (25)
Reactions of an osmium-hexahydride complex with cytosine, deoxycytidine, and cytidine: the importance of the minor tautomers. (2012) (25)
Synthesis of mononuclear complexes of Ru and Os and heterobimetallic M–M′(M = Ru or Os; M′= Rh, Ir, or Au) compounds with pyrazolate or imidazolate type ligands. X-Ray crystal structure of [(Ph3P)2(OC)HRu(µ-bim)Rh(cod)](bim = dianion of 2,2′-bi-imidazole, cod = cyclo-octa-1,5-diene) (1990) (25)
2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes. (2015) (25)
Reactions of osmium-pinacolboryl complexes: Preparation of the first vinylideneboronate esters (2012) (24)
mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides. (2017) (24)
Formation of Azabutadienyl Fragments by Addition of the Isopropenyl Substituent of a Phosphine to Benzonitriles, Promoted by an Osmium Center (2005) (24)
Azole assisted C-H bond activation promoted by an osmium-polyhydride: Discerning between N and NH (2015) (24)
Rectangular and hexagonal columnar mesophases in dinuclear rhodium (II) (alkyloxy)benzoate complexes (1992) (23)
PREPARATION AND SPECTROSCOPIC AND THEORETICAL CHARACTERIZATION OF THE TETRAHYDROBORATE COMPLEX OSH3(ETA 2-H2BH2)(P-I-PR3)2 (1994) (23)
C−N and C−C Coupling Reactions: Preparation of New N-Heterocyclic Ruthenium Derivatives (2003) (23)
Osmium-Acyl Decarbonylation Promoted by Tp-Mediated Allenylidene Abstraction: A New Role of the Tp Ligand (2014) (23)
Preparation via a NHC Dimer Complex, Photophysical Properties, and Device Performance of Heteroleptic Bis(tridentate) Iridium(III) Emitters (2019) (23)
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative (2008) (23)
Syntheses, spectroscopic characterizations, and X-ray structures of new Os({eta}{sup 2}-H{sub 2}) compounds containing azole ligands (1994) (23)
Synthesis of Butadiene-Osmium(0) and -Ruthenium(0) complexes by reductive Carbon-Carbon coupling of two alkenyl fragments (1995) (23)
Reactions of an Osmium Bis(dihydrogen) Complex under Ethylene: Phosphine Addition to a C–C Double Bond and C–H Bond Activation of Fluoroarenes (2011) (22)
A Capped Octahedral MHC6 Compound of a Platinum Group Metal. (2016) (22)
C−C Coupling of the Alkynyl and Alkenyl Fragments of Os(C2CO2CH3){CHCHC(O)OCH3}(CO)(PiPr3)2 by Action of HCl: The Vinylidene [Os{CHCHC(O)OCH3}(CCHCO2CH3)(CO)(PiPr3)2]BF4 as Intermediate (1999) (22)
Dehydrative cyclization of alkynals: vinylidene complexes with the Cβ incorporated into unsaturated five- or six-membered rings. (2011) (22)
Synthesis and Spectroscopic and Theoretical Characterization of the Elongated Dihydrogen Complex OsCl(2)(eta(2)-H(2))(NH=CPh(2))(P(i)Pr(3))(2). (1998) (22)
Synthesis, X-ray structure, and protonation of [Os(C2Ph){NH:C(Ph)C6H4}(CO)(PPr-i3)2] (1995) (22)
Oxidative Addition of HSnR3 (R = Ph, Bu) to the Square-Planar Iridium(I) Compounds Ir(XR)(TFB)(PCy3) (XR = OMe, OEt, OCHMe2, OPh, SPr) and Ir(C2Ph)L2(PCy3) (L2 = TFB, 2CO) (1995) (22)
Hydrogenation of benzylideneacetone catalyzed by chlorodihydridobis(diisopropylphosphine)iridium: kinetic evidence for the participation of an iridium-.eta.2-dihydrogen complex in the activation of molecular hydrogen (1992) (22)
C−C Bond Activation of the NHC Ligand of an Osmium−Amido Complex (2010) (22)
Reactions of the cis-dicarbonyl compound Ir(η1-OC(O)CH3)(CO)2(PCy3) with HSnPh3, HSiR3 (R = Ph, Et), and Hx+1SiPh3-x (x = 1, 2) (1994) (22)
Synthesis and Spectroscopic Characterization of New Hydrido and Dihydrogen Complexes of Osmium and Ruthenium Stabilized by the Tris(pyrazolyl)borate Ligand (1997) (22)
Preparation of Phosphorescent Osmium(IV) Complexes with N,N′,C- and C,N,C′-Pincer Ligands (2017) (22)
Synthesis and reactivity of alkoxy(.eta.4-cycloocta-1,5-diene)iridium(I) and -rhodium(I) M(OR)(cod)(PCy3) compounds. X-ray crystal structure of the alkynyl Ir(C.tplbond.CPh)(cod)(PCy3) complex (1989) (21)
Selective protonation of the styryl ligand of RuMe{(E)-CH:CHPh}(CO)2(PiPr3)2 and migratory CO insertion in the methyl group of [RuMe(CO)2(PiPr3)2]BF4 (1995) (21)
Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene) (1988) (21)
Iridium(I), Iridium(III), and Iridium(V) Complexes Containing the (2-Methoxyethyl)cyclopentadienyl Ligand† (2006) (21)
Synthesis, X-ray structure, and polymerisation activity of a bis(oxazolinyl)pyridine chromium(III) complex (2002) (21)
Hydroboration and hydrogenation of an Osmium–Carbon triple bond: Osmium chemistry of a bis-σ-borane (2015) (21)
Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity (2016) (21)
Rhodium(I) complexes containing 4-pyridylmethylene-4′-alkoxyanilines as ligands: Formation of rhodium containing liquid crystals by coordination of non-mesogenic organic ligands (1990) (21)
Cycloaddition between a Transition-Metal Phenylallenylidene Complex and Allyl Alcohol† (1998) (21)
Anti-Markovnikov 1,3-CH Addition of Allenes to Allenes: A Straightforward Method To Prepare Osmium–Dienylcarbene Complexes (2012) (21)
Supported Metal Complexes (1994) (21)
SEVEN-COORDINATE DIHYDRIDO COMPLEX OSH2(KAPPA 2-O2CCH3)KAPPA 1-OC(O)CH3(PIPR3)2 AS PRECURSOR OF NEW ORGANOMETALLIC COMPOUNDS CONTAINING UNSATURATED ET A 1-CARBON LIGANDS (1998) (21)
Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance. (2015) (21)
Aromatization of a Dihydro-3-ruthenaindolizine Complex (2009) (21)
Preparation and characterization of osmium-stannyl polyhydrides: d4-d2 oxidative addition of neutral molecules in a late transition metal (2003) (20)
Influence of the Cis Ligand on the H−H Separation and the Rotation Barrier of the Dihydrogen in Osmium-Elongated Dihydrogen Complexes Containing an Ortho-Metalated Ketone† (2004) (20)
B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond. (2013) (20)
Hydride Alkenylcarbyne Osmium Complexes versus Cyclopentadienyl Type Half-Sandwich Ruthenium Derivatives (2011) (20)
Preparation, Structure, Bonding, and Preliminary Reactivity of a Six-Coordinate d4 Osmium–Boryl Complex (2012) (20)
Oxidative Addition of HX (X = H, SiR3, GeR3, SnR3, Cl) Molecules to the Complex Os(η5-C5H5)Cl(PiPr3)2 (1999) (20)
Preparation, Spectroscopic Characterization, X-ray Structure, and Theoretical Investigation of Hydride−, Dihydrogen−, and Acetone−OsTp Complexes: A Hydridotris(pyrazolyl)borate−Cyclopentadienyl Comparison (2007) (20)
Reactions of [RuH(η3C3H5)(CO)(PiPr3)2] and [Ru(η2C2Ph2)(CO)(PiPr3)2] with terminal alkynes: synthesis and characterization of new five- and six-coordinate bis(alkynyl) and alkynyl(vinyl) derivatives of ruthenium(II) (1995) (20)
β-Borylalkenyl Z–E Isomerization in Rhodium-Mediated Diboration of Nonfunctionalized Internal Alkynes (2018) (20)
Preparation and Characterization of a Monocyclopentadienyl Osmium−Allenylcarbene Complex (2007) (20)
Synthesis of Novel Organometallic Compounds Containing η1-Carbon Polycyclic Ligands: Condensation of Propargyl Alcohol with the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4 (2000) (20)
Rhodium complexes containing 1-(4-pyridylmethylene)-4-alkoxyanilines as ligands: crystal structure of an unusual square-planar cluster of 64 electrons, Rh4(OOCCH3)4(CO)4(NC5H4CH:NC6H4OC14H29)4 (1991) (20)
Regioselective addition of dienes to the Cβ-Cγ, double bond of the allenylidene ligand of [Ru(η5- 5H5)(=C=C=CPh2) (CO) (PiPr3)]BF4 (2002) (20)
An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides. (2016) (20)
Addition of Ethyl Diazoacetate to the Allenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4: Synthesis of Ruthenium Organometallic Compounds Containing New Cyclic Unsaturated η1-Carbon Ligands (1998) (20)
Rhodium(I) complexes with the 2,2′-bipyrimidine ligand (1987) (19)
Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene (2010) (19)
Analysis of the Aromaticity of Osmabicycles Analogous to the Benzimidazolium Cation (2011) (19)
Synthesis, molecular structure and reactivity of the octahedral iridium(III) compound [IrH(.eta.1,.eta.3-C8H12)(dppm)] [dppm = bis(diphenylphosphino)methane] (1992) (19)
Dihydrido and Trihydrido Diolefin Complexes Stabilized by the Os(PiPr3)2 Unit: New Examples of Quantum Mechanical Exchange Coupling in Trihydrido Osmium Compounds (1997) (19)
Substitution and oxidative addition reactions of the monoolefin complex Rh(acac)(cyclooctene)(PCy3) including the X-ray structure analyses of Rh(acac)(PCy3)2 and [Rh(acac){(E)-CH=CHCy}(PCy3)2]BF4 (1996) (19)
Thermally Activated Site Exchange and Quantum Exchange Coupling Processes in Unsymmetrical Trihydride Osmium Compounds. (1999) (19)
Preparation of Phosphorescent Iridium(III) Complexes with a Dianionic C,C,C,C-Tetradentate Ligand. (2018) (19)
Osmium-catalyzed allylic alkylation (2008) (18)
Reactions of an osmium(IV) complex with allenedienes: Coordination and intramolecular cycloadditions (2012) (18)
Alkenylation of 2-Methylpyridine via Pyridylidene–Osmium Complexes (2012) (18)
Ruthenium-Catalyzed Oxidative Amidation of Alkynes to Amides. (2019) (18)
ALLENYLIDENE LIGAND OF RU(ETA 5-C5H5)(C=C=CPH2)(CO)(PPRI3)BF4 AS ENTRY TO NOVEL UNSATURATED ETA 1-CARBON LIGANDS CONTAINING AZETIDINE AND HEXAHYDROQUI NOLINE SKELETONS (1999) (18)
Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex. (2019) (18)
Selective Synthesis and Photophysical Properties of Phosphorescent Heteroleptic Iridium(III) Complexes with Two Different Bidentate Groups and Two Different Monodentate Ligands (2017) (18)
Perfluoro-tagged rhodium and ruthenium nanoparticles immobilized on silica gel as highly active catalysts for hydrogenation of arenes under mild conditions (2013) (18)
Synthesis, Molecular Structure and Catalytic Activity of Six-Coordinate Chloro(hydrido)- and Dihydridoruthenium(II) and -osmium(II) Complexes with the Chiral Ligands PiPr2NH(Me)Ph, (S,S)-Chiraphos and (S,S,)-Diop (2004) (18)
Synthesis and reactivity of osmium complexes containing a cyclopentadienyl ligand with a pendant phosphine donor group (2004) (17)
Unprecedented Addition of Tetrahydroborate to an Osmium–Carbon Triple Bond (2014) (17)
Pyrazolato-iridium(III) complexes (1994) (17)
η1 -Arene Complexes as Intermediates in the Preparation of Molecular Phosphorescent Iridium(III) Complexes. (2017) (17)
Dihydrobiphenylenes through ruthenium-catalyzed [2+2+2] cycloadditions of ortho-alkenylarylacetylenes with alkynes. (2014) (17)
Barreleneiridium(I) complexes. Crystal structures of [Ir(Me3TFB)(η6-C6H4Me2)]ClO4 and [Ir(TFB)(η5-PhNPh2)]BF4·CH2Cl2 (TFB = tetrafluorobenzobarrelene) (1984) (17)
Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes. (2017) (17)
Iridium(I) complexes with tetrafluorobenzobarrelene (1984) (17)
Formation of Cationic Half-Sandwich Osmium−Vinylidene Complexes from [Os(η5-C5H5)(PiPr3)2]+ and Terminal Alkynes (2001) (17)
Osmium-Mediated Direct C–H Bond Activation at the 8-Position of Quinolines (2016) (17)
Preparation of IrH(diene)L2 compounds via methoxyiridium complexes: Catalysts for hydrogen transfer reactions (1986) (17)
SYNTHESIS OF RH(ACAC)H(GEET3)(PCY3) AND RH(ACAC)H(SNPH3)(PCY3) AND THEIR REACTIONS WITH ALKYNES (1996) (17)
Base-Free and Acceptorless Dehydrogenation of Alcohols Catalyzed by an Iridium Complex Stabilized by a N,N,N-Osmaligand (2018) (16)
Kinetic studies on the selective hydrogenation of phenylacetylene catalyzed by [Rh(NBD)(PPh3)2]BF4 (NBD=2,5-norbornadiene) (1998) (16)
Osmium−Alkenylcarbyne and −Alkenylcarbene Complexes with an Steroid Skeleton: Formation of a Testosterone Organometallic Derivative Containing the 7H-Amino Adenine Tautomer (2009) (16)
Synthesis, characterization, and theoretical study of stable hydride-azavinylidene osmium(IV) complexes (2000) (16)
Generation of functionally substituted cyclopentadienyl ligands in osmium(IV) chemistry (2001) (16)
Hydrogen-transfer catalytic synergism in binuclear complexes containing 2,2'-biimidazolate as a bridging ligand (1992) (16)
The Mechanisms of Homogeneous Hydrogenation (1994) (16)
Dehalogenation of polychloroarenes with sodium formate in propan-2-ol catalyzed by RhCl(PPh3)3 (2001) (16)
Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed by [Rh(NBD)(PPh3)2]BF4 in dichloromethane: a kinetic and spectroscopic investigation (2000) (16)
Synthesis, Structure, and Bonding of the Unusual μ-σ,σ-Allenylidene Complex [Rh2(μ-OOCCH3)(μ-σ,σ-CCCPh2)(CO)2(PCy3)2]BF4 (1996) (16)
Formation of an Asymmetric Acyclic Osmium−Dienylcarbene Complex (2008) (15)
Influence of the Bite Angle of Dianionic C,N,C-Pincer Ligands on the Chemical and Photophysical Properties of Iridium(III) and Osmium(IV) Hydride Complexes (2019) (15)
Osmium-Catalyzed Oxidation of Primary Alcohols with Molecular Oxygen (2011) (15)
Mono- and dinuclear osmium N,N'-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry. (2013) (15)
Cationic iridium(I) complexes with 1,5-cyclooctadiene and nitrogen ligands (1983) (15)
Iridium liquid crystal complexes by co-ordination of non-mesogenic orgainic ligands (1989) (15)
IrCl2H(PiPr3)2 as catalyst precursor for the reduction of unsaturated substrates (1993) (15)
SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM-OSMIUM COMPLEXES CONTAINING MU-BISALKENYL, MU -ALKENYLVINYLIDENE, AND MU -ALKENYLCARBENE BRIDGE LIGANDS (1999) (15)
Hydride−Carbyne to Carbene Transformation in a Cyclopentadienyl−Osmium Complex: An Alternative to the Single Hydride−Cα Migration (2002) (15)
New Cyclopentadienylosmium Derivatives Prepared from the Five-Coordinate Complex [OsHCl(CO)(PPri3)2] (1996) (15)
Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives (2018) (15)
A Novel Method To Prepare Hydride−Phosphinito Complexes (2000) (15)
Simultaneous Dehalogenation of Polychloroarenes and Chlorination of HSiEt3 Catalyzed by Complexes of the Groups 8 and 9 (2000) (15)
Formation of dinuclear iridium complexes by NHC-supported C–H bond activation (2017) (14)
Synthesis and crystal structure of [Ir(acac-C3)(COD)(phen)] (1983) (14)
Surface‐bound organometallic rhodium precursors for 1‐hexene hydrogenation (1990) (14)
Preparation and characterization of novel Os-diolefin dimers: new entry to Os-cyclooctadiene complexes. (2006) (14)
Insertion of Diphenylacetylene into Rh–Hydride and Rh–Boryl Bonds: Influence of the Boryl on the Behavior of the β-Borylalkenyl Ligand (2019) (14)
Reaction of a cationic osmium(IV) dihydride with ethylene: Formation and structure of the novel tetraethylene dimer complex [{(PiPr3)(η2-C2H 4)2Os}2(μ-OH)2(μ-O 2CCH3)]BF4 (2000) (14)
Osmium-Promoted σ-Bond Activation Reactions on Nucleosides (2020) (14)
Rhodium-Mediated Dehydrogenative Borylation–Hydroborylation of Bis(alkyl)alkynes: Intermediates and Mechanism (2019) (14)
Dioxygen activation by an osmium-dihydride: preparation and characterization of a d4 square-planar complex. (2003) (13)
Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps. (2020) (13)
Dicationic Alkylidene−, Olefin−, and Alkoxyalkenylcarbene−Osmium Complexes Stabilized by a NHC Ligand (2010) (13)
Preparation and characterization of 4-azoniaheptatrienyl, 4-azaheptatrienyl, ruthenapyrrolinone, and pyrrolinyl complexes of ruthenium (2003) (13)
Synthesis and structure of Ru{Ph6Sn3(.mu.-OMe)2}(.eta.2-H2)(CO)(PiPr3) containing a tridentate tin donor ligand and coordinated dihydrogen (1995) (13)
The π-(Hydroxyalkenyl)germane Complexes Rh(acac){η2-(E)-Et3GeCHCHC(OH)R2}(PCy3) (R = Me, Ph) as Intermediates in the Hydrogermylation of Alkynols Catalyzed by Rh(acac)(cyclooctene)(PCy3) (1999) (13)
Nazarov type cyclization on an osmium-dienylcarbene complex. (2009) (13)
REACTIVITY OF OSH2CL2(PIPR3)2 TOWARD DIOLEFINS : NEW REACTIONS INVOLVING C-H AND C-C ACTIVATION AND C-C AND C-P BOND FORMATION PROCESSES (1997) (13)
H···H Interaction in Four-Membered P−H···H−M (M = Osmium, Ruthenium) Rings (1998) (13)
Suzuki–Miyaura Cross-Coupling Reactions for Increasing the Efficiency of Tris-Heteroleptic Iridium(III) Emitters (2019) (13)
Boryl-Dihydrideborate Osmium Complexes: Preparation, Structure, and Dynamic Behavior in Solution (2015) (13)
Ring Expansion versus exo−endo Isomerization in (2-Pyridyl)methylenecyclobutane Coordinated to Hydrido(trispyrazolyl)borate- and Cyclopentadienyl-Osmium Complexes (2010) (13)
Formation of osmium-allylphosphinomethanide complexes by coupling of an isopropenyldiisopropylphosphine and monosubstituted allenes (2012) (12)
Azavinylidene and azavinylidene-bridged compounds of iridium and rhodium (1994) (12)
Recent Advances in Synthesis of Molecular Heteroleptic Osmium and Iridium Phosphorescent Emitters (2021) (12)
Dehydrogenative Addition of Aldehydes to a Mixed NHC-Osmium-Phosphine Hydroxide Complex: Formation of Carboxylate Derivatives (2016) (12)
Synthesis and characterization of IrH2{Si(OTf)Ph2}(TFB)(PR3) (PR3 = PiPr3, PCy3): First base-stabilized silylene complexes of iridium (1996) (12)
Redox-Assisted Osmium-Promoted C–C Bond Activation of Alkylnitriles (2018) (12)
A Useful Access to the Chemistry of the Indenyl-Osmium-Triisopropylphosphine Moiety (2005) (12)
Synthesis and X-ray Structure of the Unusual Cysteine-Complex OsH2{OC(=O)CH[NHC(=O)CH3]CH2S}(PiPr3)2 (1995) (12)
REDUCTIVE ELIMINATION OF PH2C=C=CHPR3BF4 FROM THE RHODIUM(III)-ALLENYL DERIVATIVES RH(ACAC)CH=C=CPH2(PR3)2BF4 (PR3 = PCY3, PIPR3) (1997) (12)
Osmium models of intermediates involved in catalytic reactions of alkylidenecyclopropanes (2013) (12)
Conceptual Extension of the Degradation–Transformation of N-Heterocyclic Carbenes: Unusual Rearrangements on Osmium (2018) (12)
Selective formation of cis-PhCHCH (SiEt3) by reaction of PhCCH with the stoichiometric amount of HSiEt3, in the presence of ruthenium catalysts (1995) (12)
Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers. (2019) (12)
Monocationic trihydride and dicationic dihydride-dihydrogen and bis(dihydrogen) osmium complexes containing cyclic and acyclic triamine ligands: influence of the N-Os-N angles on the hydrogen-hydrogen interactions. (2009) (11)
Selectivity of allenylidene versus butadienyl protonation in an osmium-bisphosphine system (2009) (11)
Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity. (2019) (11)
C(sp3)–Cl Bond Activation Promoted by a POP-Pincer Rhodium(I) Complex (2019) (11)
Selective meta-C–H Bond Activation of Substituted 1,3-Chlorobenzenes Promoted by an Osmium Pyridyl Complex (2014) (11)
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences (2020) (11)
One-pot dehydrogenative addition of isopropyl to alkynes promoted by osmium: Formation of γ-(η3-allyl)-α-alkenylphosphine derivatives starting from a dihydride−dihydrogen−triisopropylphosphine complex (2007) (11)
Synthesis and reactivity of new benzophenone imine derivatives containing the Ru(CO)(PiPr3)2 unit (1996) (11)
Trapping of a 12-Valence-Electron Osmium Intermediate (2009) (11)
N–H and C–H Bond Activations of an Isoindoline Promoted by Iridium- and Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols (2020) (11)
Dehydrogenation of a coordinated alkylphosphine as a method to prepare cyclopentadienyl-α-alkenylphosphine-osmium complexes (2004) (11)
Synthesis and reactivity of[OsH{C6H4(CHCHH)}(CO)(PPri3)2] and the formatocompounds[Os{(E )-CHCHPh}(η2-O2CH)(CO)(PPri3)2] and[OsH(η2-O2CH)(CO)(PPri3)2]* (1997) (11)
Phosphorescent Iridium(III) Complexes with a Dianionic C,C',N,N'-Tetradentate Ligand. (2020) (10)
Reactions of [IrH2(Me2CO)(Hpz)(PPh3)2]BF4 with alkynes: synthesis of new hydride-vinyl iridium(III) complexes (1994) (10)
Pyridyl-Directed C–H and C–Br Bond Activations Promoted by Dimer Iridium-Olefin Complexes (2018) (10)
Synthesis and characterization of new hydridoiridium complexes containing carboxylate ligands (1994) (10)
Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ-Bond Activation Reactions (2016) (10)
Synthesis, reactivity and catalytic activity of [RuH(η1-OCMe2)(CO)2(PPri3)2]BF4 (1995) (10)
Kinetic Analysis and Sequencing of Si-H and C-H Bond Activation Reactions: Direct Silylation of Arenes Catalyzed by an Iridium-Polyhydride. (2020) (10)
Behavior of OsH2Cl2(PiPr3)2 in Acetonitrile: The Importance of the Small Details (2009) (10)
Synthesis, characterization, and reactivity of rhodium carboxylate dimers [Rh(.mu.-OOCCR3)(CO)(PCy3)]2 (R = H, F). X-ray crystal structure of [Rh2(.mu.-OOCCH3)(.mu.-.eta.1:.eta.2-C2Ph)(CO)2(PCy3)2] (1993) (10)
Addition of H2SiPh2 to Ir(acac)(.eta.2-CH3O2C-C.tplbond.C-CO2CH3)(PR3): Synthesis and Characterization of [cyclic] Ir(acac){C[CH(OCH3)OSiPh2]:CHCO2CH3}(PR3) (R = CHMe2, cyclohexyl) (1995) (10)
Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism (2020) (10)
Synthesis and Characterization of Mixed-Phosphine Osmium Polyhydrides: Hydrogen Delocalization in [OsH5P3]+ Systems (2001) (10)
CH activation of methyl vinyl ketone in Ir(acac){η2-CH2CHC(O)CH3}(PCy3) (1998) (9)
Preparation of half-sandwich osmium-allyl complexes by consecutive c-c bond formation and c-h bond activation reactions (2006) (9)
Synthesis and Characterization of the Allenylidene Compounds [Ir(diene)(CCCPh2)(PR3)]BF4 (diene = 1,5-Cyclooctadiene, PR3 = PCy3; diene = Tetrafluorobenzobarrelene, PR3 = PCy3, PiPr3): The First Mixed-Ligand Complexes of the Type [Ir(diene)L(PR3)]+ Containing an Unsaturated η1-Carbon Ligand (1997) (9)
Preparation and full characterization of a tetrahydride-bis(stannyl)-osmium(VI) derivative (2004) (9)
Synthesis of [M(η2-C2Ph2)(CO)(PiPr3)2] (MOs or Ru) and X-ray crystal structure of the osmium derivative (1994) (9)
Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl. (2020) (9)
Dihydroboration of Alkyl Nitriles Catalyzed by an Osmium-Polyhydride: Scope, Kinetics, and Mechanism (2020) (9)
Synthesis of the first metal dihydrogen M(.eta.2-H2) complexes containing sulfur-donor ligands (1993) (8)
Preparation of Capped Octahedral OsHC6 Complexes by Sequential Carbon-Directed C–H Bond Activation Reactions (2016) (8)
C ? H Activation Coupling Reactions (2017) (8)
Tuning the Nature and Formation of Bis(dihydrogen)–Osmium Species (2018) (8)
The cyclopentadienyl-osmium moiety as template for the formation of a dihydronaphthylphosphine by coupling between phenylacetylene and an α-alkenylphosphine (2005) (8)
Insertion of Unsaturated C-C Bonds into the O-H Bond of an Iridium(III)-Hydroxo Complex: Formation of Phosphorescent Emitters with an Asymmetrical β-Diketonate Ligand. (2020) (8)
Formation and Stereochemistry of Octahedral Cationic Hydride‐Azavinylidene Osmium(IV) Complexes (2001) (8)
Lewis Base-Assisted Hydride-Carbyne to Olefin Transformation versus Carbene Formation (2002) (8)
Preparation, X-ray structures, and NMR spectra of elongated dihydrogen complexes with four- and five-coordinate tin centers (2006) (8)
Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex (2021) (8)
Osmium-centered oxetylidene: Formation and cleavage (2012) (8)
Synthesis and Characterization of OsH2Cl[κN,κO-(ONCR2)](PiPr3)2 (CR2 = C(CH2)4CH2, R = CH3): Influence of the L2 Ligand on the Nature of the H2 Unit in OsH2ClL2(PiPr3)2 (L2 = ONCR2, NHC(Ph)C6H4) Complexes (1999) (7)
Hydration of Aliphatic Nitriles Catalyzed by an Osmium Polyhydride: Evidence for an Alternative Mechanism (2021) (7)
Reactions of OsH2(η2−CH2=CHEt)(CO)(PiPr3)2 with unsaturated organic molecules (1997) (7)
Influence of the Solvent in the Synthesis of Osmium Complexes Containing Cyclopentadienyl Ligands with a Pendant Donor Group (2004) (7)
Ruthenium Hydroxycarbenes as Key Intermediates in Cycloisomerization and Decarbonylative Cyclization of Terminal Alkynals (2014) (7)
Sigma-bond activation reactions induced by unsaturated Os(IV)-hydride complexes (2020) (7)
A General Rhodium Catalyst for the Deuteration of Boranes and Hydrides of the Group 14 Elements. (2020) (6)
Osmium Complexes With POP Pincer Ligands (2018) (6)
Synthesis, Reactivity, Molecular Structure, and Catalytic Activity of the Novel Dichlorodihydridoosmium(IV) Complexes OsH2Cl2(PR3)2 (PR3: P- iPr3, PMe-tBu2). (1991) (5)
Reactions of IrXL2(PR3)(X = Cl, OTf; L2= TFB, 2CO) with HSnR3(R = Ph, nBu) (1997) (5)
Sequential protonation and methylation of a hydride-osmium complex containing a cyclopentadienyl ligand with a pendant amine group. (2005) (5)
Synthesis and catalytic activity of some cationic rhodium(I) complexes with substituted quinolines (1982) (5)
Synthesis and characterization of (PPr3i)2(CO)HRu(µ-H)- (µ-OMe)Ir(cod): an unusual example of a heterometallic complex containing a mixed hydrido–alkoxide bridge (1999) (5)
Pseudo-Tris(heteroleptic) Red Phosphorescent Iridium(III) Complexes Bearing a Dianionic C,N,C′,N′-Tetradentate Ligand (2021) (5)
Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid (2021) (5)
Unusual Activation of 1,1-Diphenyl-2-propyn-1-ol Mediated by the Os(η5-C5H5) Unit (1998) (5)
Electronic Communication in Binuclear Osmium- and Iridium-Polyhydrides (2021) (5)
Synthesis and reactions of phenylacetylide iridium(I) and rhodium(I) complexes (1990) (5)
Homogeneous Transfer Hydrogenation Catalysed by Metal Complexes (1994) (4)
Synthesis and structure of the unusual 30-electron homobinuclear vinylidene-bridged rhodium complexes [Rh2(.mu.-OOCCH3)(.mu.-C:CHR)(CO)2(PCy3)2]BF4 (1993) (4)
Preparation and Degradation of Rhodium and Iridium Diolefin Catalysts for the Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols (2021) (4)
The synthesis and structure determination of a novel η6-arenerhodium(III) complex, [(Me2SiC6H5)4Rh2H2], and the synthesis of [(Me2SiC6H5)4Ir2H2] (1987) (4)
Bromination and CC Cross-Coupling Reactions for the CH Functionalization of Iridium(III) Emitters (2021) (4)
Reactions of POP-pincer rhodium(I)-aryl complexes with small molecules: coordination flexibility of the ether diphosphine (2020) (4)
Reductive elimination of the alkenyl fragment and a phosphine ligand from [Rh(acac)?(E)-CH=CHR?(PCy3)2]BF4 (R=Cy, Ph, H): preparation of [(E)-RHC=CHPCy3]BF4 from alkynes (1999) (4)
Deacylative Alkylation vs. Photoredox Catalysis in the Synthesis of 3,3'-Bioxindoles (2020) (4)
Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles (2021) (3)
Assembly of a Dihydrideborate and Two Aryl Nitriles to Form a C,N,N′-Pincer Ligand Coordinated to Osmium (2021) (3)
Nematic phases in ionic melts: mesogenic ionic complexes of silver(I) [Erratum to document cited in CA111(16):144535m] (1991) (3)
Ruthenium- and Osmium- Hydride Compounds Containing Triisopropylphosphine as Precursors for Carbon-Carbon and Carbon-Heteroatom Coupling Reactions (2001) (3)
Exclusive formation of cis-PhCH=CH(SiEt3) by addition of HSiEt3 to PhC≡CH catalyzed by RuHCl(CO)(PiPr3)2 (1993) (3)
Kinetic and spectroscopic study of the hydrogen-transfer reaction from 2-propanol to cyclohexanone catalyzed by [IrH2(pz)(Hpz)(PPh3)2] (Hpzpyrazole) (1994) (3)
Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures (2022) (3)
Synthesis, X-ray Structure, and Catalytic Activity of the Unusual Complex [Ir(TFB)(PiPr3)2]BF4(TFB = Tetrafluorobenzobarrelene) (1997) (3)
Metathesis between E−C(sp n ) and H−C(sp3) σ‐Bonds (E=Si, Ge; n=2, 3) on an Osmium‐Polyhydride (2022) (2)
Azolium Control of the Osmium-Promoted Aromatic C–H Bond Activation in 1,3-Disubstituted Substrates (2021) (2)
Ruthenium‐ and Osmium—Hydride Compounds Containing Triisopropylphosphine as Precursors for Carbon—Carbon and Carbon—Heteroatom Coupling Reactions. (2002) (2)
C—C Coupling and C—H Bond Activation Reactions of Cyclopentadienyl—Osmium Compounds: The Rich and Varied Chemistry of Os(η5‐C5H5)Cl (PiPr3)2 and Its Major Derivatives (2005) (2)
Preparation, X-Ray Structure, and Reactivity of an Osmium-Hydroxo Complex Stabilized by an N-Heterocyclic Carbene Ligand: A Base-Free Catalytic Precursor for Hydrogen Transfer from 2-Propanol to Aldehydes. (2008) (2)
Dehalogenation of Polychloroarenes with Sodium Formate in Propan-2-ol Catalyzed by RhCl(PPh3)3. (2001) (2)
Dihydride versus Elongated Dihydrogen in [H2Os(κ2-O2CCH3)L(PiPr3)2]+Complexes: Influence of the L Ligand (2002) (2)
Alkenyl-Assisted C3–C Bond Activation of Acetylacetonate Coordinated to Iridium (2017) (2)
Catalytic Cyclization of o‐Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3‐Benzazepines. (2016) (2)
Acetylides for the Preparation of Phosphorescent Iridium(III) Complexes: Iridaoxazoles and Their Transformation into Hydroxycarbenes and N,C(sp3),C(sp2),O-Tetradentate Ligands (2022) (2)
Hydrogenation in Aqueous Systems (1994) (2)
C–Cl Oxidative Addition and C–C Reductive Elimination Reactions in the Context of the Rhodium-Promoted Direct Arylation (2022) (2)
Stabilization of a chelate tautomer of phenylacetylide (2003) (2)
Reactions of an Osmium–Hexahydride Complex with 2-Butyne and 3-Hexyne and Their Performance in the Migratory Hydroboration of Aliphatic Internal Alkynes (2022) (2)
Silyl-Osmium(IV)-Trihydride Complexes Stabilized by a Pincer Ether-Diphosphine: Formation and Reactions with Alkynes (2022) (1)
Ruthenium‐Catalyzed [2 + 2] Intramolecular Cycloaddition of Allenenes. (2011) (1)
Homogeneous catalysis with polyhydride complexes. (2022) (1)
Ligand Design and Preparation, Photophysical Properties, and Device Performance of an Encapsulated-Type Pseudo-Tris(heteroleptic) Iridium(III) Emitter. (2023) (1)
Hydrogen Activation in Biological Systems (1994) (1)
Coordination of H2 and O2 to (OsHCl(CO)(PiPr3)2): A Catalytically Active M(η2-H2) Complex. (1989) (1)
Homogeneous Hydrogenation in Organic Synthesis (1994) (0)
Acceptorless dehydrogenation reactions catalysed by a bimetallic complex (2017) (0)
CCDC 1527881: Experimental Crystal Structure Determination (2017) (0)
Osmium-Catalyzed Synthesis of 3-Benzoxepines (2010) (0)
Dihydrogen Complexes as Homogeneous Reduction Catalysts (1998) (0)
Encapsulated-Type Iridium(III) Phosphorescent Emitters with a Hexadentate Ligand of Three Different Bidentate Units (2023) (0)
Os-catalyzed cyclization of o-(alkynyl)phenethylamines by osmacyclopropenation: an easy entry to dopaminergic 3-benzazepines (2015) (0)
Reactivity of a POP-Rhodium(I) boryl complex (2017) (0)
POP-Osmium polyhydrides in chemical hydrogen storage (2018) (0)
CCDC 1527882: Experimental Crystal Structure Determination (2017) (0)
(η2-Tetrahydroborato)ruthenium(II) and -osmium(II) Complexes with Fluxional Structure. (1987) (0)
Synthesis and Reactivity of Alkoxy(η4-cycloocta-1,5-diene)iridium(I) and -rhodium(I) M(OR)(cod)(PCy3) Compounds. X-Ray Crystal Structure of the Alkynyl Ir(CCPh)(cod)(PCy3) Complex. (1989) (0)
Osmium polyhydrides containing boron ligands (2017) (0)
CCDC 1527884: Experimental Crystal Structure Determination (2017) (0)
Boron functionalization of hydridotris(pyrazolyl)borate ligand on osmium complexes (2014) (0)
Dihydrobiphenylenes Through Ruthenium-Catalyzed [2 + 2 + 2] Cycloadditions of ortho-Alkenylarylacetylenes with Alkynes. (2014) (0)
POP-Rhodium Complexes: Insertion, Isomerization and C-H Bond Activation Reactions (2018) (0)
(NHC)Palladium Complexes from Hydroxy-Functionalized Imidazolium Salts as Catalyst for the Microwave-Accelerated Fluorine-Free Hiyama Reaction. (2012) (0)
The Chemical and Catalytic Reactions of Hydrido-chloro-carbonylbis(triisopropylphosphine)osmium(II) and Its Major Derivatives (2001) (0)
POPRhodium-Promoted CH and BH Bond Activation and CB Bond Formation (2015) (0)
Nematic Phases in Ionic Melts: Mesogenic Ionic Complexes of Silver(I). (1990) (0)
Hydrosilylation of Phenylacetylene via an Os(SiEt3)(η2‐H2) Intermediate Catalyzed by OsHCl(CO)(PiPr3)2. (1991) (0)
Kinetic and Mechanistic Investigation of the Sequential Hydrogenation of Phenylacetylene Catalyzed by OsHCl(CO)(PR3)2 (PR3: PMe-tBu2 and P-iPr3). (1990) (0)
Reactivity of OsH2(η2-CH2=CHEt)(CO)(PiPr3)2 with catecholborane: Formation of σ-borane and boryl-dihydridoborate derivatives and catalytic dehydrogenation of amine-boranes (2014) (0)
CCDC 1527883: Experimental Crystal Structure Determination (2017) (0)
Making Easier the β-Lactam Fragmentation via Metal-Assistance : Mechanistic Insight (2015) (0)
Phosphorescent Ir(III) complexes with two different pincer ligands (2017) (0)
Reactions of C-halogen bond activation mediated by a rhodium POP complex (2018) (0)
SYNTHESIS AND REACTIVITY OF OSHC6H4(CH=CHH)(CO)(PPR3I)2 AND THE FORMATO COMPOUNDS OS(E)-CH=CHPH(ETA 2-2-O2CH)-(CO)(PPR3I)2 AND OSH(ETA 2-O2CH)(CO)(PP R3I)2 (1997) (0)
Rhodium-Promoted C–H Bond Activation of Quinoline, Methylquinolines, and Related Mono-Substituted Quinolines (2022) (0)
A stepwise strategy to form tris(bidentate)-Osmium(II) complexes enclosing three different bidentate ligands (2014) (0)
IrCl2H(PiPr3)2 as Catalyst Precursor for the Reduction of Unsaturated Substrates. (1993) (0)
CCDC 785699: Experimental Crystal Structure Determination (2010) (0)
Preparation and Characterisation of (6)-Azaosmahelicenes: The First d 4 - Heterometallahelicenes (2012) (0)
Novel coordination modes of a BPI anion in osmium complexes (2017) (0)
CCDC 1527885: Experimental Crystal Structure Determination (2017) (0)
Reactions of an osmium polyhydride with nitriles (2018) (0)
Sequential and selective hydrogenation of the C(alpha)-C(beta) and M-C(alpha) double bonds of an allenylidene ligand coordinated to osmium: new reaction patterns between an allenylidene complex and alcohols. (2007) (0)
Hydroboration and Hydrogenation of an Osmium ‐ Carbon triple Bond : A Bis ‐ σ ‐ Borane in the Osmium Chemistry (2015) (0)
[H(EtOH)2] [{OsCl(η4‐COD)}2(μ‐H)(μ‐Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]x and Its Activity as an Ionic Hydrogenation and Etherification Catalyst. (2008) (0)
Diastereoselective Ruthenium-Catalyzed [2+2] Cycloadditionsof Allenenes (2011) (0)
CCDC 658745: Experimental Crystal Structure Determination (2007) (0)
Recent developments in the chemistry of osmium complexes with POP-ligands (2017) (0)
Blue-green phosphorescent heteroleptic iridium(III) complexes with Nheterocyclic carbene ligands (2017) (0)
Osmathiazole Ring: Extrapolation of an Aromatic Purely Organic System to Organometallic Chemistry (2023) (0)
Preparation of Half‐Sandwich Alkyl—Titanium(IV) Complexes Stabilized by a Cyclopentadienyl Ligand with a Pendant Phosphine Tether and Their Use in the Catalytic Hydroamination of Aliphatic and Aromatic Alkynes. (2006) (0)

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What Schools Are Affiliated With Miguel A. Esteruelas?

Miguel A. Esteruelas is affiliated with the following schools:

University of California, Berkeley
Stanford University
University of Barcelona