Morris S. Kharasch
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Most Influential Person Across History
American chemist
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Chemistry
Morris S. Kharasch's Degrees
- PhD Chemistry University of Chicago
- Bachelors Chemistry University of Chicago
Why Is Morris S. Kharasch Influential?
(Suggest an Edit or Addition)According to Wikipedia, Morris Selig Kharasch was a pioneering organic chemist best known for his work with free radical additions and polymerizations. He defined the peroxide effect, explaining how an anti-Markovnikov orientation could be achieved via free radical addition. Kharasch was born in the Russian Empire in 1895 and immigrated to the United States at the age of 13. In 1919, he completed his Ph.D. in chemistry at the University of Chicago and spent most of his professional career there.
Morris S. Kharasch's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Coördination Compounds of Palladous Chloride1 (1938) (356)
- ADDITION OF CARBON TETRACHLORIDE AND CHLOROFORM TO OLEFINS. (1945) (270)
- Factors Determining the Course and Mechanisms of Grignard Reactions. IV. The Effect of Metallic Halides on the Reaction of Aryl Grignard Reagents and Organic Halides1 (1941) (227)
- Reactions of hindered phenols. II. Base-catalyzed oxidations of hindered phenols (1957) (197)
- Factors Determining the Course and Mechanisms of Grignard Reactions. II. The Effect of Metallic Compounds on the Reaction between Isophorone and Methylmagnesium Bromide (1941) (195)
- Grignard Reactions of Nonmetallic Substances (1954) (193)
- THE REACTIONS OF t-BUTYL PERBENZOATE AND OLEFINS—A STEREOSPECIFIC REACTION1 (1958) (174)
- Heats of combustion of organic compounds (1929) (139)
- Reactions of Atoms and Free Radicals in Solution. X. The Addition of Polyhalomethanes to Olefins (1947) (138)
- THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. III. DIRECT INTRODUCTION OF GOLD INTO THE AROMATIC NUCLEUS (PRELIMINARY COMMUNICATION) (1931) (135)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXV. THE REACTIONS OF OLEFINS WITH MERCAPTANS IN THE PRESENCE OF OXYGEN1 (1951) (123)
- Chlorinations with Sulfuryl Chloride. I. The Peroxide-Catalyzed Chlorination of Hydrocarbons (1939) (100)
- Reactions of Atoms and Free Radicals in Solution. XII. The Addition of Bromo Esters to Olefins (1948) (97)
- Metal Salt-Induced Homolytic Reactions. I. A New Method of Introducing Peroxy Groups into Organic Molecules1,2 (1959) (92)
- Organophosphorus Chemistry. Addition Reactions of Diethyl Phosphonate and the Oxidation of Triethyl Phosphite1 (1960) (87)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. I. The Addition of Hydrogen Bromide to Allyl Bromide (1933) (86)
- ADDITION OF DERIVATIVES OF CHLORINATED ACETIC ACIDS TO OLEFINS (1945) (85)
- Reactions of Hindered Phenols. I. Reactions of 4,4'-Dihydroxy-3,5,3',5'-tetra-tert-butyl Diphenylmethane* (1957) (82)
- Factors Influencing the Course and Mechanism of Grignard Reactions. XV. The Reaction of β,β-Dimethylphenethyl Chloride with Phenylmagnesium Bromide in the Presence of Cobaltous Chloride (1944) (79)
- Reactions of atoms and free radicals in solution; the addition of aldehydes to olefins. (1949) (75)
- THE CHEMISTRY OF HYDROPEROXIDES. VI. THE THERMAL DECOMPOSITION OF α-CUMYL HYDROPEROXIDE (1951) (72)
- Structure of Peroxides Derived from Cyclohexanone and Hydrogen Peroxide1 (1958) (70)
- THE CHEMISTRY OF HYDROPEROXIDES I. THE ACID-CATALYZED DECOMPOSITION OF α,α-DIMETHYLBENZYL (α-CUMYL) HYDROPEROXIDE1 (1950) (66)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XVIII. THE ADDITION AND SUBSTITUTION OF BISULFITE (1938) (63)
- The Electronic Conception of Valence and Heats of Combustion of Organic Compounds (62)
- The Addition of N-Haloamides to Olefins (1939) (61)
- Reactions of diazoacetates and diazoketones. I. Reaction of ethyl diazoacetate with cyclohexanone and with acetone (1953) (58)
- Reactions of Atoms and Free Radicals in Solution. XI. The Addition of Bromotrichloromethane to Olefins (1947) (58)
- Photochemical para Rearrangement of Phenyl Ethers (1952) (58)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XV. THE ADDITION OF HYDROGEN BROMIDE TO 1- AND 2-BROMO- AND CHLOROPROPENES (1937) (56)
- THE CHEMISTRY OF HYDROPEROXIDES. XII. THE GENERATION AND PROPERTIES OF FREE RO2. RADICALS (1953) (55)
- Factors Influencing the Course and Mechanisms of Grignard Reactions. XI. The Effect of Metallic Halides on the Reaction of Grignard Reagents with Vinyl Halides and Substituted Vinyl Halides (1943) (52)
- Communications - A Modification of Free Radical Reactions (1958) (50)
- Chlorinations with Sulfuryl Chloride. III. (a) The Peroxide-Catalyzed Chlorination of Aliphatic Acids and Acid Chlorides. (b) The Photochemical Sulfonation of Aliphatic Acids (1940) (47)
- THE CHEMISTRY OF HYDROPEROXIDES. III. THE FREE-RADICAL DECOMPOSITION OF HYDROPEROXIDES (1950) (46)
- THE DECOMPOSITION OF UNSYMMETRICAL MERCURIORGANIC COMPOUNDS: A METHOD OF ESTABLISHING THE RELATIVE DEGREE OF ELECTRONEGATIVITY OF ORGANIC RADICALS (1926) (46)
- THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. I. AUROUS CHLORIDE CARBONYL AND A METHOD OF LINKING CARBON TO CARBON (1930) (45)
- Reactions of Atoms and Free Radicals in Solution. IV. Decomposition of Acetyl Peroxide in Aliphatic Acids—A New Synthesis of Succinic Acid and its Substitution Derivatives (1943) (44)
- Carboxylation.1 I. The Photochemical and Peroxide-catalyzed Reactions of Oxalyl Chloride with Paraffin Hydrocarbons2 (1942) (42)
- THE CHEMISTRY OF HYDROPEROXIDES. V. THE THERMAL DECOMPOSITION OF tert-ALKYL PEROXIDES (1951) (42)
- The Chemistry of Organic Gold Compounds. V. Auration of Aromatic Nitriles (1934) (39)
- Chlorinations with Sulfuryl Chloride. II. The Peroxide-Catalyzed Reaction of Sulfuryl Chloride with Ethylenic Compounds (1939) (36)
- ADDITION OF CARBON TETRABROMIDE AND BROMOFORM TO OLEFINS (1946) (35)
- A New Active Principle in Ergot and its Effects on Uterine Motility (1935) (34)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXI. THE RELATIVE REACTIVITY OF OLEFINS TOWARDS A FREE TRICHLOROMETHYL RADICAL (1949) (34)
- THE CHEMISTRY OF HYDROPEROXIDES. XI. HYDROPEROXIDES AS OXIDIZING AND REDUCING AGENTS (1952) (34)
- THE CHEMISTRY OF HYDROPEROXIDES. VIII. THE ACID-CATALYZED DECOMPOSITION OF CERTAIN HYDROPEROXIDES (1951) (34)
- THE CONVERSION OF QUATERNARY PYRROLIDINIUM SALTS TO OPEN-CHAIN DIAMINES (1944) (33)
- The Kinetics of Nitration of Aromatic Nitro Compounds in Sulfuric Acid1 (1946) (32)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXVII. THE DECOMPOSITION OF DIACETYL PEROXIDE IN ALCOHOLS (1951) (32)
- Coördination Compounds of Platinous Halides with Unsaturated (Ethylene) Substances (1936) (32)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXVI. COMPARISON OF THE REACTIONS OF LEAD TETRAACETATE AND ACETYL PEROXIDE WITH ACETIC ACID AND ISOPROPYL ETHER1 (1951) (32)
- The Condensation of Butyraldehyde and Aniline (1940) (31)
- Oxidative reactions of nitriles—I : Autoxidation (1958) (31)
- ALKYLATION REACTIONS OF TETRAETHYLLEAD. A NEW SYNTHESIS OF ETHYLDICHLOROARSINE AND RELATED COMPOUNDS1 (1949) (31)
- Reactions of atoms and free radicals in solution; the comparative reactivities of double bonds in cyclic olefins toward free radicals. (1949) (30)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. VIII. THE REACTION OF DIACETYL PEROXIDE WITH ALKYLBENZENES. A NEW SYNTHESIS OF HEXESTEROL DIMETHYL ETHER (1945) (30)
- FACTORS INFLUENCING THE COURSE AND MECHANISM OF GRIGNARD REACTIONS. XVII. INTERCHANGE OF RADICALS IN THE REACTION OF GRIGNARD REAGENTS AND ORGANIC HALIDES IN THE PRESENCE OF METALLIC HALIDES (1945) (29)
- Reactions of atoms and free radicals in solution; the additions of bromodichloromethane and dibromodichloromethane to olefins; the preparation of 2-alkenals. (1948) (29)
- Reactions of Atoms and free Radicals in Solution. XXXIII. Photochemical and Peroxide-Induced Addition of Cyclohexanone to 1-Octene (1953) (29)
- FACTORS DETERMINING THE COURSE AND MECHANISM OF GRIGNARD REACTIONS. XVIII. THE EFFECT OF METALLIC HALIDES ON THE REACTIONS OF GRIGNARD REAGENTS WITH 1-PHENYL-3-CHLOROPROPANE, CINNAMYL CHLORIDE, AND PHENYLETHYNYL BROMIDE (1945) (29)
- THE MECHANISM OF ACTION OF INHIBITORS IN FREE RADICAL INITIATED POLYMERIZATIONS AT LOW TEMPERATURES1 (1954) (28)
- Sulfonation Reactions with Sulfuryl Chloride. II. The Photochemical Sulfonation of Aliphatic Acids with Sulfuryl Chloride (1940) (28)
- Communications - Radical Substitution Reactions (1958) (27)
- THE REACTION OF TRIETHYL PHOSPHITE WITH -TRICHLOROMETHYL CARBONYL COMPOUNDS (1955) (27)
- Reactions of Atoms and Free Radicals in Solution. XXIII. The Peroxide-Induced Addition of Sulfuryl Chloride to 1-Alkenes (1951) (26)
- Synthesis of Polyenes. III. A New Synthesis of Diethylstilbestrol (1943) (25)
- Reactions of Atoms and Free Radicals in Solution. I. A Study of the Substitution of Hydrogen on an Asymmetric Carbon Atom—The Chlorination of Primary Active Amyl Chloride (1940) (25)
- The peroxide effect in the addition of reagents to unsaturated compounds; the addition of mercaptans to methyl acrylate. (1948) (24)
- Factors Determining the Course and Mechanisms of Grignard Reactions. X. The Oxidation of Grignard Reagents—Effect of Metallic Catalysts (1943) (23)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. VI. DECOMPOSITION OF DIACETYL AND OTHER PEROXIDES IN ALIPHATIC ACIDS AND SUBSTITUTED ALIPHATIC ESTERS (1945) (23)
- Some Chemical Factors Influencing Growth and Pigmentation of Certain Microörganisms (1936) (23)
- FACTORS INFLUENCING THE COURSE AND MECHANISM OF GRIGNARD REACTIONS. XX. THE CLEAVAGE OF ETHERS BY GRIGNARD REAGENTS IN THE PRESENCE OF COBALTOUS HALIDES (1952) (22)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXVIII. THE ADDITION OF N-CHLOROSULFONYL-PHTHALIMIDE TO OLEFINS (1952) (22)
- Reactions of atoms and free radicals in solution; the reactions of diacetyl peroxide with aliphatic ketones; a new synthesis of 1,4-diketones. (1948) (22)
- GRIGNARD REAGENTS—THEIR REDUCING ACTION AND RATES OF ADDITION* (1936) (22)
- The Peroxide Effect in the Rearrangement of α-Bromoacetoacetic Ester (1937) (22)
- A study of a new and potent ergot derivative, ergotocin (1935) (21)
- New Metal Salt-Induced Homolytic Reactions. II. Modification of Free Radical Reactions by Copper Salts1 (1959) (21)
- Reactions of Atoms and Free Radicals in Solution. II. The Non-Isomerization of Free Alkyl Radicals in Solution (1941) (21)
- The Chemistry of Hydroperoxides. X. The Addition of Free Alkoxy Radicals to Conjugated Systems (1951) (21)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XIII. THE ADDITION OF HYDROGEN BROMIDE TO BUTADIENE (1936) (20)
- THE CHEMISTRY OF HYDROPEROXIDES. II. THE PREPARATION AND PROPERTIES OF α,α-DIMETHYLBENZYL (α-CUMYL) PEROXIDE1 (1950) (20)
- Oxidative reactions of nitriles—II : Reactions with tert.-butyl hydroperoxide (1958) (19)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. XXIII. The Reaction of Styrene with Bisulfite (1939) (19)
- THE REACTION OF SODIUM IN LIQUID AMMONIA WITH ESTERS1 (1940) (18)
- THE CHEMISTRY OF HYDROPEROXIDES. IV. OXIDATION OF TERTIARY AROMATIC ALCOHOLS WITH HYDROGEN PEROXIDE OR HYDROPEROXIDES (1950) (18)
- Sulfonation Reactions with Sulfuryl Chloride (1939) (18)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XV. CORRECTION (1934) (18)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXIX. THE RELATIVE REACTIVITIES OF OLEFINS TOWARD THE FREE TRICHLOROMETHYL RADICAL (1953) (18)
- Reactions of Atoms and free Radicals in Solution. XXXIV. Photochemical Dissociation of Disulfides into Mercaptyl Radicals (1953) (18)
- Synthesis of Polyenes. IV (1944) (17)
- Carboxylation. II. The Reaction of Oxalyl Chloride with Unsaturated Hydrocarbons (1942) (17)
- Factors influencing the course and mechanism of grignard reactions; the preparation of substituted bibenzyls from grignard reagents, alkyl halides, and alkylbenzenes in the presence and absence of cobaltous chloride. (1948) (17)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXII. THE ADDITION OF POLYHALOMETHANES TO ALKYNES (1950) (17)
- DETECTION OF FREE RADICALS IN SOLUTION. III. FORMATION OF LONG-CHAIN α,ν-DICARBOXYLIC ACIDS (1954) (17)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. X. The Addition of Hydrogen Bromide to Methylacetylene (Allylene) (1935) (16)
- EFFECT OF ORGANIC PEROXIDES IN CHLORINATION REACTIONS (1941) (16)
- Factors Determining the Course and Mechanisms of Grignard Reactions. XIII. The Effect of Metallic Halides on the Reaction of Sterically Hindered Acid Halides with Methylmagnesium Iodide (1944) (16)
- The Chemistry of Hydroperoxides. IX. Relative Migratory Aptitudes of Groups in free Radical Rearrangements (1951) (16)
- THE PHOTOCHEMICAL REACTIONS OF OXALYL CHLORIDE AND PHOSGENE WITH CYCLOHEXANE (1940) (16)
- The Reduction of Dipole Moment by Steric Hindrance in Di-t-butylhydroquinone and its Dimethyl Ether (1942) (15)
- The New Ergot Alkaloid (1935) (15)
- Reactions of atoms and free radicals in solution; decomposition of diacetyl peroxide in allyl bromide. (1949) (15)
- Factors Determining the Course and Mechanisms of Grignard Reactions. I. Preliminary Study: The Effects of Metallic Compounds on Some Grignard-Carbonyl Interactions (1941) (15)
- Reactions of Atoms and Free Radicals in Solution. XL. Reaction of Grignard Reagents with 1-Bromooctane in the Presence of Cobaltous Bromide (1959) (14)
- Factors Influencing the Course and Mechanism of Grignard Reactions. XXIV. Reactions of 1,3-Disubstituted Compounds, 1,2-Hydrogen Atom Shift1 (1961) (14)
- THE ADDITION OF PHOSPHORUS TRICHLORIDE TO OLEFINS (1945) (14)
- Reactions of Atoms and Free Radicals in Solution. V. The Non-coplanar Free 1-Apocamphyl Radical (1943) (14)
- Carboxylation. III. The Peroxide-catalyzed Reaction of Oxalyl Chloride with the Side-chains of Aralkyl Hydrocarbons. A Preliminary Study of the Relative Reactivity of Free Radicals (1942) (14)
- CIS—TRANS ISOMERIZATION BY BROMINE ATOMS (1937) (13)
- Factors Determining the Course and Mechanisms of Grignard Reactions. VIII. The Effect of Metallic Halides on the Reaction of Grignard Reagents with Aromatic Acyl Halides (1943) (13)
- THE BEHAVIOR OF MERCURIC SALTS OF ORGANIC ACIDS TOWARD HEAT1 (1923) (13)
- THE PREPARATION AND DECOMPOSITION OF UNSYMMETRICAL MERCURI-ORGANIC COMPOUNDS. A METHOD OF ESTABLISHING THE RELATIVE DEGREE OF NEGATIVITY OF ORGANIC RADICALS1 (1925) (13)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Substances. XXII. The Addition of Hydrogen Bromide to Trimethylethylene, Styrene, Crotonic Acid, and Ethyl Crotonate (1939) (13)
- AN INDIRECT METHOD OF PREPARATION OF ORGANIC MERCURIC DERIVATIVES AND A METHOD OF LINKING CARBON TO CARBON. Preliminary Report.1 (1921) (12)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. III. The Addition of Hydrogen Bromide to Propylene (1933) (12)
- THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. II. THE PREPARATION AND PROPERTIES OF GOLD-CARBON COMPOUNDS OF THE TYPE R2AuX AND RAuX2 (1931) (12)
- THE CHEMISTRY OF HYDROPEROXIDES. VII. THE IONIC AND FREE RADICAL DECOMPOSITION OF α-PHENYLETHYL HYDROPEROXIDE (1951) (12)
- METAL CATALYSTS IN BIOLOGIC OXIDATIONS I. THE SIMPLE SYSTEM: THIOGLYCOLIC ACID, BUFFER, METAL, DITHIOL (1936) (12)
- Syntheses of Polyenes. I. Hexatriene and its Polymers (1939) (12)
- MERCURI-ORGANIC DERIVATIVES: II. NITROBENZENE MERCURY COMPOUNDS; AN INDIRECT METHOD OF MERCURIZING ORGANIC COMPOUNDS. (1921) (11)
- Factors Determining the Course and Mechanism of Grignard Reactions. VII. Analysis of Gases Formed During the Reaction of Phenylmagnesium Bromide with Organic Halides in the Presence of Cobaltous Halides (1943) (11)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXXVI. FORMATION OF OPTICALLY ACTIVE ESTERS IN THE DECOMPOSITION OF OPTICALLY ACTIVE DIACYL PEROXIDES IN SOLUTION (1954) (11)
- Reactions of Hindered Phenols. III.1 Reaction of Nitrous Acid with Hindered Phenols (1962) (11)
- REACTIONS OF ATOMS AND FREE RADICALS. VII. DIACETYL PEROXIDE AS AN AGENT FOR LINKING α-CARBON TO α-CARBON ATOMS IN ORGANIC ESTERS (1945) (11)
- THE ADDITION OF THIOCYANIC ACID TO OLEFINIC DOUBLE BONDS (1937) (10)
- Factors Determining the Course and Mechanisms of Grignard Reactions. IX. The Effect of Metallic Halides on the Reaction of Organolithium Compounds with Organic Halides (1943) (10)
- The Addition of Hydrogen Halides to cis- and trans-2-Pentene (1939) (10)
- Factors Influencing the Course and Mechanisms of Grignard Reactions. XXIII. The Reactions of Propylene Oxide and Related Compounds with Grignard Reagents1 (1961) (10)
- CONDENSATION OF EPICHLOROHYDRIN WITH ETHYLENE GLYCOL: SOME NEW POLYFUNCTIONAL DERIVATIVES (1943) (10)
- THE BROMINATION OF CYCLOHEXANE, METHYLCYCLOHEXANE, AND ISOBUTANE (1941) (10)
- THE ADDITION OF HYDROGEN CHLORIDE TO BUTADIENE (1937) (10)
- THE NEW ACTIVE PRINCIPLE(S) OF ERGOT. (1935) (9)
- Bromination of Octene-1 with N-Bromosuccinimide* (1957) (9)
- Factors Influencing the Course and Mechanism of Grignard Reactions. XXII. The Reaction of Grignard Reagents with Alkyl Halides and Ketones in the Presence of Manganous Salts (1956) (9)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. IV. The Addition of Halogen Acids to Vinyl Chloride (1934) (9)
- Reactions of atoms and free radicals in solution; the reaction of allyl bromide with bromotrichloromethane. (1949) (9)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. XX. The Addition of Hydrogen Bromide to 2-Butyne and 2-Bromo-2-butene (1939) (9)
- Reactions of Atoms and Free Radicals in Solution. XXXVIII. The Reactions oftrans-1,2- and 1,3-Dibromocyclohexanes With Grignard Reagents in the Presence of Cobaltous Bromide (1956) (9)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. II. The Addition of Hydrogen Bromide to Vinyl Bromide (1933) (9)
- Addition of Carbon Tetrachloride and Chloroform to Olefins (1945) (9)
- The Synthesis of Symmetrically Substituted Ethane Derivatives (1961) (9)
- THE NEW ERGOT ALKALOID. (1935) (8)
- The formation of free alkoxy (RO.) radicals in solution. (1951) (8)
- THE RELATIVE REACTIVITIES OF ALDEHYDES AND KETONES (1945) (8)
- Factors Determining the Course and Mechanisms of Grignard Reactions. XII. The Effect of Cobaltous Chloride on the Reaction of Methylmagnesium Bromide with Alicyclic Chlorides (1944) (8)
- THE HYDROLYTIC INSTABILITY OF THE CARBON-TO-CARBON BOND (1936) (8)
- THE PEROXIDE EFFECT IN THE CANNIZZARO REACTION (1935) (8)
- Factors influencing polysulfone formation; a new method of induction with control of polymer length. (1948) (8)
- Factors Determining the Course and Mechanism of Grignard Reactions. VI. A New Synthesis of Hexestrol Dimethyl Ether (3,4-Dianisylhexane) (1943) (8)
- THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. IV. GOLD IMIDE COMPOUNDS (1931) (8)
- THE DECOMPOSITION OF UNSYMMETRICAL ORGANOMERCURIC COMPOUNDS: A METHOD OF ESTABLISHING THE RELATIVE DEGREE OF ELECTRONEGATIVITY OF ORGANIC RADICALS. III* (1938) (8)
- The Presence of Indole in “Practical” α-Methylnaphthalene (1940) (8)
- Factors Influencing the Course and Mechanism of Grignard Reactions. XVI. An Isomer of Isophorone—Δ3,4-3,5,5-Trimethylcyclohexenone (1945) (8)
- Factors Determining the Course and Mechanism of Grignard Reactions. V. The Effect of Metallic Halides on the Reaction of Grignard Reagents with Benzalacetophenone and with Benzophenone (1942) (7)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXX. DIMERIZATION OF FREE RADICALS PRODUCED FROM OLEFINS (1953) (7)
- The electron in organic chemistry. II. Bonds of the ethylene type and factors influencing directed addition thereat (1931) (7)
- THE CATALYTIC CONDENSATION OF GRIGNARD REAGENTS WITH HYDROCARBONS (1938) (7)
- FACTORS AFFECTING THE ADDITION OF BROMINE TO PHENANTHRENE (1938) (7)
- Reations of atoms and free radicals in solution. XXXII. Reaction of free benzoyl radicals with pyridine in the presence of benzaldehyde (1953) (7)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. XI. The Solvent Effect in the Addition of Hydrogen Bromide to Isobutylene (1936) (7)
- REARRANGEMENTS IN THE TERPENE SERIES. I. ISOMERIZATION AND ESTERIFICATION OF α-PINENE (1944) (7)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. V. The Addition of Hydrogen Bromide to Butene-1 (1934) (7)
- Reactions of atoms and free radicals in solution; decomposition of diacetyl peroxide in vic-glycols. (1949) (7)
- The Oxygen Effect in the Reaction of Cyclopropane with Bromine and with Hydrogen Bromide (1939) (6)
- SPECTROSCOPIC SIMILARITY BETWEEN ERGOT (LYSERGIC ACID) AND THE YOHIMBINE ALKALOIDS. (1936) (6)
- THE DECOMPOSITION OF UNSYMMETRICAL ORGANOMERCURIC COMPOUNDS: A METHOD OF ESTABLISHING THE RELATIVE ELECTRONEGATIVITIES OF ORGANIC RADICALS. IV* (1938) (6)
- Reactions of Atoms and Free Radicals in Solution. XXXIX. The Reaction of Diacetyl Peroxide with sec-Butyl Nitrite and 3-Amyl Nitrite (1957) (6)
- THE PEROXIDE EFFECT IN THE ADDITION OF HYDROGEN BROMIDE TO ETHYLENE COMPOUNDS. XIV. THE ADDITION OF HYDROGEN BROMIDE TO THE HIGHER ALKENES (1937) (6)
- THE PEROXIDE EFFECT IN THE HALOGENATION OF AROMATIC SIDE CHAINS (1937) (6)
- ERGOTOCIN: THE ACTIVE PRINCIPLE OF ERGOT RESPONSIBLE FOR THE ORAL EFFECTIVENESS OF SOME ERGOT PREPARATIONS ON HUMAN UTERI (1935) (6)
- THE REACTIONS OF EPOXY COMPOUNDS WITH REAGENTS. I. THE INTERACTION OF PHENYLEPOXYETHANE (STYRENE OXIDE) AND ARYLMAGNESIUM HALIDES (1938) (6)
- Inhibition of Polymerization - Laboratory and Plant Control of Popcorn Polymer Growth (1947) (6)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS. XXI. “NORMAL” AND “ABNORMAL” ADDITIONS OF HYDROGEN BROMIDE (1939) (5)
- Reactions of Atoms and Free Radicals in Solution. XXIV. The Reactions of Acetyl Peroxide with Chloro- and Dichloroalkanes1 (1951) (5)
- Communications - Radiolysis of 1-Hexene (1958) (5)
- THE PEROXIDE EFFECT IN THE ADDITION OF REAGENTS TO UNSATURATED COMPOUNDS: XIX. THE ADDITION OF HYDROGEN BROMIDE TO TRICHLOROETHYLENE (1938) (5)
- Synthesis of Polyenes. II. Reactions of β-Methylallyl Chloride with Sodamide in Liquid Ammonia (1940) (5)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. VI. The Addition of Hydrogen Bromide to Isobutylene (1934) (5)
- A STUDY OF THE NITRO-ANILINES (1922) (5)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXXV. MIGRATION OF A METHYL GROUP IN THE REARRANGEMENT OF THE FREE DI-TERT-BUTYLCARBINYL RADICAL. THE REACTION OF DI-TERT-BUTYLCARBINYL CHLORIDE WITH A GRIGNARD REAGENT IN THE PRESENCE OF COBALTOUS BROMIDE (1954) (5)
- MERCURI-ORGANIC DERIVATIVES. THE MERCURIZATION OF AROMATIC AMINES AND ITS RELATION TO THE THEORY OF SUBSTITUTION. (1921) (5)
- STUDIES PERTAINING TO THE MECHANISM OF THE HETEROGENEOUS CANNIZZARO REACTION1 (1949) (5)
- Hydrogen Exchange of Phenols and Phenol Ethers with Deutero-alcohol1 (1948) (5)
- A new synthesis of sulfonyl chlorides. (1948) (5)
- FACTORS INFLUENCING THE COURSE AND MECHANISM OF GRIGNARD REACTIONS. XXI. THE REACTION OF HALOALKYL PHENYL ETHERS WITH GRIGNARD REAGENTS IN THE PRESENCE OF COBALTOUS HALIDES (1953) (5)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXXVII. THE CLEAVAGE OF QUATERNARY AMMONIUM SALTS WITH GRIGNARD REAGENTS (1955) (5)
- THE ROLE OF MERCAPTANS IN POLYMERIZATION OF DIENES AND THE COPOLYMERIZATION OF STYRENE AND DIENES (1955) (5)
- CATALYTIC EFFECTS IN THE BROMINATION OF TOLUENE (1938) (5)
- Reactions of atoms and free radicals in solution. XXXI. Reations of free benzoyl radicals with azo compounds (1953) (5)
- Exchange reactions in deuteroalcohol (1937) (5)
- VAPOR PHASE BROMINATION OF ALKYL HALIDES (1955) (4)
- FACTORS AFFECTING THE STABILITY OF MERCURIALS AND THE MERCURATION OF SUBSTITUTED PHENYLAMMONIUM SALTS (1924) (4)
- The electron in organic chemistry. I. The electronic conception of the nature of the carbon-to-carbon bond from the standpoint of the theory of partial polarity (1928) (4)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. VIII. The Addition of Hydrogen Iodide to Ethylene Compounds (1934) (4)
- Communications - A New Method of Introducing Peroxy Groups into Organic Molecules (1958) (4)
- ADDITION OF HYDROGEN BROMIDE TO 4,4-DIMETHYLPENTENE-1 (1934) (4)
- The Peroxide Effect in the Addition of Halogen Acids to Olefins. XXVI. The Addition of Halogen Acids to Trichloromethylethylene (1941) (4)
- Ergotocin (1935) (4)
- The Oxygen Effect in the Reaction of Bromine with Neopentane, t-Butylbenzene and Trimethylacetic Acid (1941) (4)
- Factors Determining the Course and Mechanism of Grignard Reactions. XIV. Replacement of Halogen Atoms of Aromatic Halides with Hydrogen Atoms by the Action of Grignard Reagents and Cobaltous Chloride (1944) (4)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. XXIV. The Addition of Hydrogen Iodide to Propene, 1-Bromopropene, Allyl Chloride, and Allyl Bromide (1940) (3)
- VAPOR PHASE PHOTOCHEMICAL BROMINATION OF 2,3-DIMETH-YLBUTANE AND 2,2,4,4-TETRAMETHYLPENTANE (1955) (3)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XIV. ADDITION OF POLYHALOMETHANES TO BUTADIENE SULFONE (1948) (3)
- ERGOTOCIN. (1935) (3)
- PROVITAMIN D ACTIVITY AND STRUCTURE—ADDITION OF GRIGNARD REAGENTS TO 7-KETOCHO-LESTERYL ACETATE* (1936) (3)
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. IX. THE THERMAL DECOMPOSITION OF α- AND β-DINAPHTHOYL PEROXIDES IN CARBON TETRACHLORIDE (1945) (3)
- Factors Influencing Polysulfone Formation (1940) (3)
- The electron in organic chemistry. IV. Monohydroxy compounds (1936) (3)
- Factors Governing the Instability of a Carbon to Nitrogen Bond. I. The Instability of the Carbon to Nitrogen Bond in Substituted Methyl Amines1 (1934) (2)
- THE PEROXIDE EFFECT IN THE ADDITION OF HALOGEN ACIDS TO OLEFINS. XXVII. THE ADDITION OF HALOGEN ACIDS TO ALLYLAMINES AND TRIALKYLALLYLAMMONIUM SALTS (1945) (2)
- METAL CATALYSTS IN BIOLOGIC OXIDATIONS II. TISSUE INHIBITORS (1936) (2)
- Stabilization of cyanogen chloride (1949) (2)
- The Preparation and Properties of 2-Chloro-2'-fluorodiethyl Sulfide1 (1955) (2)
- 3-NITRO-4-HYDROXY-5-IODO-BENZOIC ACID AND THE MERCURY DERIVATIVE OF PARA-HYDROXY-META-NITROPHENYL CARBINOL. (1921) (2)
- THE HYDROLYSIS OF CARBON TETRAIODIDE (1937) (2)
- Photobromination of Pentane (1952) (2)
- THE DETECTION OF FREE RADICALS IN SOLUTION. II. THE REACTION OF ALKYL AND ARYL HALIDES WITH MAGNESIUM IN THE PRESENCE OF ISOPRENE1 (1954) (2)
- Carboxylation. IV. Direct Introduction of the Chloroformyl (—COCI) Group into Alicyclic and Aliphatic Acid Chlorides (1942) (2)
- THE EFFECT OF METALLIC HALIDES ON THE REACTION OF ORGANOLITHIUM COMPOUNDS WITH ALKYL AND ARYL HALIDES (1941) (2)
- AROMATIC MERCURI-ORGANIC DERIVATIVES. THE HOFMANN REARRANGEMENT AND THE NATURE OF VALENCES OF MERCURY IN MERCURI-ORGANIC DERIVATIVES. (1921) (1)
- PREPARATION OF 5,5'-MERCURI-BIS-3-NITRO-4-HYDROXY-PHENYL-ARSONIC ACID.1 (1921) (1)
- Reactions of Atoms and Free Radicals in Solution. III. The Introduction of a Mercaptan Group into Cyclohexane (1941) (1)
- THE BROMINATION OF ALIPHATIC ACIDS AND THEIR ACYL DERIVATIVES (1941) (1)
- THE DETECTION OF FREE RADICALS IN SOLUTION. I. THE REACTION OF PHENOXYETHYL BROMIDE WITH ISOPROPYL-MAGNESIUM BROMIDE (OR WITH MAGNESIUM) IN THE PRESENCE OF ISOPRENE AND COBALTOUS HALIDES (1954) (1)
- AROMATIC MERCURI-ORGANIC DERIVATIVES. (1920) (1)
- Photochemical para Rearrangement of Phenyl Ethers (1952) (1)
- THE DETECTION OF FREE RADICALS IN SOLUTION. IV. THE REACTION OF ALKYL HALIDES WITH SODIUM IN THE PRESENCE OF ISOPRENE (1955) (1)
- Kharasch ] Heats of Combustion of Organic Compounds (1)
- The electron in organic chemistry. III. The thermal and hydrolytic stability and instability of the carbon-to-carbon bond (1934) (1)
- The Theory of Partial Polarity of the Ethylene Bond and the Existence of Electro-Isomerism. (1)
- Additions and Corrections - Vapor Phase Bromination of 2,3-Dimethylbutane and 2,2,4,4-Tetramethylpentane (1955) (0)
- THE REACTION OF ESTERS WITH SODIUM IN LIQUID AMMONIA (1939) (0)
- A Treatise on Physical Chemistry (Taylor, Hugh S., ed.) (1926) (0)
- Correction- Bromination of Octene-1 with N-Bromosuccinimide (1959) (0)
- FORMATION OF QUINONE BY THE ACTION OF BROMINE OXIDE ON BENZENE (1947) (0)
- Additions and Corrections. The Addition of Hydrogen Halides to cis- and trans-2-Pentene. (1939) (0)
- Additions and Corrections - Reactions of Atoms and Free Radicals in Solution. XXXII. (1953) (0)
- The reactive paraffins—An addition (1941) (0)
- Spectroscopic Similarity Between Ergot (Lysergic Acid) and the Yohimbine Alkaloids (1936) (0)
- Polar and non-polar valences as applied to organic chemistry (1925) (0)
- Additions and Corrections. The Peroxide Effect in the Addition of Reagents to the Unsaturated Compounds. XX. The Addition of Hydrogen Bromide to 2-Butyne and 2-Bromo-2-butene. (1939) (0)
- The Peroxide Effect in the Addition of Reagents to Unsaturated Compounds. XXV. The Effect of Metals on the Addition of Hydrogen Bromide to Allyl Bromide (1940) (0)
- NITROSO-TRIPHENYLAMINE AND COLORS OF THE SECOND ORDER. (1918) (0)
- The Formation of Free Alkoxy (RO ⋅) Radicals in Solution (1951) (0)
- Additions and Corrections - Reactions of Atoms and Free Radicals in Solution. XII. The Addition of Bromo Esters to Olefins (1948) (0)
- Additions and Corrections - The Catalytic Condensation of Grignard Reagents with Hydrocarbons (1938) (0)
- THE PREPARATION AND OXIDATION OF tert-DIPHENYLDEHYDROABIETINOL (1951) (0)
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