Natalia Shustova
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Natalia Shustovachemistry Degrees
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Inorganic Chemistry
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Organic Chemistry
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Chemistry
Natalia Shustova's Degrees
- PhD Chemistry University of California, Berkeley
- Masters Chemistry Moscow State University
- Bachelors Chemistry Moscow State University
Why Is Natalia Shustova Influential?
(Suggest an Edit or Addition)According to Wikipedia, Natalia B. Shustova is a Peter and Bonnie McCausland Professor of Chemistry at the University of South Carolina. She focuses on developing materials for sustainable energy conversion, metal-organic frameworks , covalent organic frameworks , and graphitic supramolecular structures.
Natalia Shustova's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Turn-on fluorescence in tetraphenylethylene-based metal-organic frameworks: an alternative to aggregation-induced emission. (2011) (537)
- Selective turn-on ammonia sensing enabled by high-temperature fluorescence in metal-organic frameworks with open metal sites. (2013) (364)
- Phenyl ring dynamics in a tetraphenylethylene-bridged metal-organic framework: implications for the mechanism of aggregation-induced emission. (2012) (319)
- Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements. (2018) (253)
- Photophysics Modulation in Photoswitchable Metal-Organic Frameworks. (2020) (161)
- Energy transfer on demand: photoswitch-directed behavior of metal-porphyrin frameworks. (2014) (152)
- Conformational locking by design: relating strain energy with luminescence and stability in rigid metal-organic frameworks. (2012) (147)
- Electronic Properties of Bimetallic Metal-Organic Frameworks (MOFs): Tailoring the Density of Electronic States through MOF Modularity. (2017) (130)
- Electrochemical, spectroscopic, and DFT study of C60(CF3)n frontier orbitals (n = 2-18): the link between double bonds in pentagons and reduction potentials. (2007) (113)
- Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage. (2004) (108)
- Trifluoromethyl derivatives of insoluble small-HOMO-LUMO-gap hollow higher fullerenes. NMR and DFT structure elucidation of C2-(C74-D3h)(CF3)12, Cs-(C76-Td(2))(CF3)12, C2-(C78-D3h(5))(CF3)12, Cs-(C80-C2v(5))(CF3)12, and C2-(C82-C2(5))(CF3)12. (2006) (93)
- Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective (2018) (81)
- Flipping the Switch: Fast Photoisomerization in a Confined Environment. (2018) (78)
- Active Sites in Copper-Based Metal–Organic Frameworks: Understanding Substrate Dynamics, Redox Processes, and Valence-Band Structure (2015) (74)
- Synthesis and X-ray or NMR/DFT structure elucidation of twenty-one new trifluoromethyl derivatives of soluble cage isomers of C76, C78, C84, and C90. (2008) (73)
- Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal-Organic Frameworks. (2017) (72)
- Mimic of the green fluorescent protein β-barrel: photophysics and dynamics of confined chromophores defined by a rigid porous scaffold. (2015) (69)
- Radical trifluoromethylation of Sc3N@C80. (2007) (63)
- Synthesis, spectroscopic and electrochemical characterization, and DFT study of seventeen C70(CF3)n derivatives (n=2, 4, 6, 8, 10, 12). (2008) (60)
- Metal-Organic Frameworks as a Versatile Tool To Study and Model Energy Transfer Processes. (2015) (60)
- Preparation and Structural Characterization of Two Kinetically Stable Chlorofullerenes, C60Cl28 and C60Cl30 (2005) (55)
- Poly(perfluoroalkylation) of metallic nitride fullerenes reveals addition-pattern guidelines: synthesis and characterization of a family of Sc3N@C80(CF3)n (n = 2-16) and their radical anions. (2011) (55)
- Connecting Wires: Photoinduced Electronic Structure Modulation in Metal-Organic Frameworks. (2019) (54)
- Heterometallic Metal–Organic Frameworks (MOFs): The Advent of Improving the Energy Landscape (2019) (49)
- C1-(C84-C2(11))(CF3)12: trifluoromethylation yields structural proof of a minor C84 cage and reveals a principle of higher fullerene reactivity. (2008) (49)
- Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12. (2007) (49)
- Metal–organic framework photophysics: Optoelectronic devices, photoswitches, sensors, and photocatalysts (2016) (47)
- A Bio-inspired Approach for Chromophore Communication: Ligand-to-Ligand and Host-to-Guest Energy Transfer in Hybrid Crystalline Scaffolds. (2015) (46)
- Fulleretic Materials: Buckyball- and Buckybowl-Based Crystalline Frameworks (2017) (46)
- Soluble chlorofullerenes C(60)Cl(2,4,6,8,10). Synthesis, purification, compositional analysis, stability, and experimental/theoretical structure elucidation, including the X-ray structure of C(1)-C(60)Cl(10). (2010) (44)
- Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal-Organic Frameworks with "Structural Memory". (2019) (41)
- Perfluoroalkylfullerenes (2015) (41)
- Thermally stable perfluoroalkylfullerenes with the skew-pentagonal-pyramid pattern: C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6. (2006) (41)
- Redox-tuning endohedral fullerene spin states: from the dication to the trianion radical of Sc(3)N@C(80)(CF(3))(2) in five reversible single-electron steps. (2010) (39)
- Sc3N@(C80-Ih7)(CF3)14 and Sc3N@(C80-Ih(7))(CF3)16. Endohedral metallofullerene derivatives with exohedral addends on four and eight triple-hexagon junctions. Does the Sc3N cluster control the addition pattern or vice versa? (2009) (39)
- Preparation and crystallographic characterization of C60Cl24. (2005) (39)
- Synthesis and structural characterization of highly chlorinated C70, C70Cl28. (2005) (39)
- Actinide-based MOFs: a middle ground in solution and solid-state structural motifs. (2018) (37)
- Redox-Active Corannulene Buckybowls in a Crystalline Hybrid Scaffold. (2016) (37)
- Fulleretic Well‐Defined Scaffolds: Donor–Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics (2016) (32)
- Photophysics, Dynamics, and Energy Transfer in Rigid Mimics of GFP-based Systems. (2016) (30)
- Synthesis and structures of C60 fullerene chlorides (2005) (27)
- Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials. (2018) (26)
- Substituent effects in a series of 1,7-C60(RF)2 compounds (RF = CF3, C2F5, n-C3F7, i-C3F7, n-C4F9, s-C4F9, n-C8F17): electron affinities, reduction potentials and E(LUMO) values are not always correlated (2012) (26)
- Host–Guest Interactions in a Metal–Organic Framework Isoreticular Series for Molecular Photocatalytic CO2 Reduction (2021) (23)
- Nitrogen directs multiple radical additions to the 9,9'-bi-1-aza(C60-I(h))[5,6]fullerene: X-ray structure of 6,9,12,15,18-C59N(CF3)5. (2011) (23)
- Hierarchical Corannulene‐Based Materials: Energy Transfer and Solid‐State Photophysics (2017) (23)
- Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties. (2021) (22)
- X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 °C (2007) (22)
- Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal-Organic Frameworks. (2019) (21)
- Confinement-guided photophysics in MOFs, COFs, and cages. (2021) (20)
- Let the light be a guide: Chromophore communication in metal-organic frameworks (2020) (20)
- In search of fullerene-based superacids: synthesis, X-ray structure, and DFT study of C60(C2F5)(5)H. (2011) (17)
- Dynamically Controlled Electronic Behavior of Stimuli‐Responsive Materials: Exploring Dimensionality and Connectivity (2021) (17)
- Confinement-Driven Photophysics in Cages, Covalent−Organic Frameworks, Metal–Organic Frameworks, and DNA (2020) (17)
- Inkjet-Printed Photoluminescent Patterns of Aggregation-Induced-Emission Chromophores on Surface-Anchored Metal-Organic Frameworks. (2018) (17)
- Chemical tailoring of fullerene acceptors: synthesis, structures and electrochemical properties of perfluoroisopropylfullerenes. (2011) (15)
- High-temperature and photochemical syntheses of C60 and C70 fullerene derivatives with linear perfluoroalkyl chains (2010) (15)
- "Boarding-Up": Radiation Damage and Radionuclide Leaching Kinetics in Linker-Capped Metal-Organic Frameworks. (2020) (14)
- Crystal structure of C60Cl6 prepared by a reaction of C60 with POCl3 (2006) (13)
- A Dual Threat: Redox-Activity and Electronic Structures of Well-Defined Donor-Acceptor Fulleretic Covalent-Organic Materials. (2020) (13)
- Photophysics of GFP-related chromophores imposed by a scaffold design. (2016) (13)
- Regioselective sequential additions of nucleophiles and electrophiles to perfluoroalkylfullerenes: which cage C atoms are the most reactive and why? (2013) (12)
- A metal-organic framework as a flask: photophysics of confined chromophores with a benzylidene imidazolinone core. (2017) (12)
- Unraveling the electron spin resonance pattern of nonsymmetric radicals with 30 fluorine atoms: electron spin resonance and vis-near-infrared spectroelectrochemistry of the anion radicals and dianions of C60(CF3)(2n) (2n = 2-10) derivatives and density functional theory-assisted assignment. (2010) (11)
- ESR-Vis/NIR spectroelectrochemical study of C70(CF3)2-(*) and C70(C2F5)2-(*) radical anions. (2008) (11)
- Stimuli-Modulated Metal Oxidation States in Photochromic MOFs. (2022) (11)
- Anion-exchanged and quaternary ammonium functionalized MIL-101-Cr metal-organic framework (MOF) for ReO4-/TcO4- sequestration from groundwater. (2020) (10)
- A Multivariate Toolbox for Donor–Acceptor Alignment: MOFs and COFs (2020) (10)
- Sequestration of Radionuclides in Metal–Organic Frameworks from Density Functional Theory Calculations (2019) (9)
- Direct Identification of Mixed-Metal Centers in Metal-Organic Frameworks: Cu3(BTC)2 Transmetallated with Rh2+ Ions. (2020) (9)
- Saturnene revealed: X-ray crystal structure of D(5d)-C(60)F(20) formed in reactions of C(60) with A(x)MF(y) fluorinating agents (A=alkali metal; M=3d metal). (2010) (7)
- Electronic structures and magnetism of Zr-, Th-, and U-based metal-organic frameworks (MOFs) by density functional theory (2020) (7)
- 1,6,11,18,24,27,52,55-Octakis(trifluoromethyl)-1,6,11,18,24,27,52,55-octahydro(C60-Ih)[5,6]fullerene (2006) (7)
- Supramolecular Assembly of Metal‐Organic Tubes Constructed from the Ditopic Heteroscorpionate Ligand (4‐NH2C6H4)CHpz2 (pz = Pyrazol‐1‐yl) and Silver(I) (2016) (6)
- Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks† (2021) (6)
- Stack the Bowls: Tailoring the Electronic Structure of Corannulene‐Integrated Crystalline Materials (2018) (5)
- An elusive fulvene 1,7,11,24-C60(CF3)4 and its unusual reactivity. (2014) (5)
- A MOF Multifunctional Cargo Vehicle for Reactive Gas Delivery and Catalysis. (2021) (5)
- Inside Cover: Redox‐Tuning Endohedral Fullerene Spin States: From the Dication to the Trianion Radical of Sc3N@C80(CF3)2 in Five Reversible Single‐Electron Steps (Chem. Eur. J. 16/2010) (2010) (5)
- Chlorination of C60 and C70 fullerenes using SbCl5 and VCl4 chlorides (2004) (5)
- Synthesis and Structure of the Highly Chlorinated [60]Fullerene C60Cl30 with a Drum‐Shaped Carbon Cage. (2005) (5)
- Electron affinity and suppression effect in analysis of chlorofullerenes by MALDI mass spectrometry (2005) (4)
- 1,6,11,18,24,27,33,51,54,60-Decakis(trifluoromethyl)-1,6,11,18,24,27,33,51,54,60-decahydro(C60-Ih)[5,6]fullerene (2007) (4)
- 1,6,11,16,18,24,27,36‐Octakis(trifluoromethyl)‐1,6,11,16,18,24,27,36‐octahydro(C60–Ih)[5,6]fullerene deuterochloroform solvate (2007) (4)
- Perfluoroalkylation of Fullerenes (2013) (4)
- Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks (2019) (4)
- C 1 -(C 84 -C 2 (11))(CF 3 ) 12 : Trifluoromethylation Yields Structural Proof of a Minor C 84 Cage and Reveals a Principle of Higher Fullerene (2008) (3)
- 1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene (2007) (3)
- Soluble Chlorofullerenes C60Cl2,4,6,8,10. Synthesis, Purification, Compositional Analysis, Stability, and Experimental/Theoretical Structure Elucidation, Including the X-Ray Structure of C1-C60Cl10. (2010) (3)
- Confinement-Driven Photophysics in Cages, COFs, MOFs, and DNA. (2020) (3)
- Redox-Tuning Endohedral Fullerene Spin States: From the Dication to the Trianion Radical of Sc3N@C80(CF3)2 in Five Reversible Single-Electron Steps. (2010) (3)
- Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties (2021) (2)
- Graphitic supramolecular architectures based on corannulene, fullerene, and beyond. (2021) (2)
- “Broken-hearted” carbon bowl via electron shuttle reaction: energetics and electron coupling (2021) (2)
- Negative Ions of Trifluoromethyl Fullerene Derivatives: First Thermodynamic Data (2005) (2)
- Preparation and structural characterization of two kinetically stable chlorofullerenes, c(60)cl(28) and c(60)cl(30). (2005) (2)
- Heterometallic multinuclear nodes directing MOF electronic behavior† (2020) (2)
- 1,7,16,30,36,47‐Hexakis(perfluoroisopropyl)‐1,7,16,30,36,47‐hexahydro(C60–Ih)[5,6]fullerene (2007) (2)
- 1,4,7,11,18,21,24,31,35,39,51,58,61,64‐Tetradecakis(trifluoromethyl)‐1,4,7,11,18,21,24,31,35,39,51,58,61,64‐tetradecahydro(C70–D5h)[5,6]fullerene p‐xylene trisolvate (2007) (2)
- Photoresponsive frameworks: energy transfer in the spotlight. (2021) (1)
- Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal-Organic Frameworks. (2022) (1)
- Metal-Photoswitch Friendship: From Photochromic Complexes to Functional Materials. (2022) (1)
- Luminescence of alkali rare earth borates A3Ln(BO3)2 (A = Na, K; Ln = Eu, Tb) (2023) (1)
- Cover Picture: Redox‐Active Corannulene Buckybowls in a Crystalline Hybrid Scaffold (Angew. Chem. Int. Ed. 6/2016) (2016) (1)
- X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 degrees C. (2007) (1)
- Fluorination of the cubic and hexagonal C60 modifications by crystalline manganese trifluoride (2002) (1)
- High‐Yield Synthesis of a Single Asymmetric Isomer of C70(CF3)10 by High‐Temperature Radical Trifluoromethylation (2012) (1)
- C1‐(C84—C2(11)) (CF3)12: Trifluoromethylation Yields Structural Proof of a Minor C84 Cage and Reveals a Principle of Higher Fullerene Reactivity. (2008) (1)
- Preparation and Structural Characterization of Two Kinetically Stable Chlorofullerenes, C60Cl28 and C60Cl30. (2005) (1)
- Growth of Crystalline Bimetallic Metal-Organic Framework Films via Transmetallation. (2020) (1)
- A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials (2020) (1)
- Frontispiece: Host–Guest Interactions in a Metal–Organic Framework Isoreticular Series for Molecular Photocatalytic CO 2 Reduction (2021) (1)
- 1,4,10,19,25,41,55,60,67,69‐Decakis(trifluoromethyl)‐1,4,10,19,25,41,55,60,67,69‐decahydro(C70‐D5h)[5,6]fullerene (2007) (1)
- Leaching model of radionuclides in metal-organic framework particles (2022) (1)
- Molecular and Crystal Structure of the C60F18 Adducts with Bromine and Carbon Disulfide (2008) (1)
- Keeping COFs in the loop (2022) (1)
- Structure of 7,9,12,15,18,20,39,24,45,57-C60(CF3)10(1,2:3,4-O)2. The first regiospecific diepoxidation of a fullerene derivative. (2013) (1)
- Preparation and crystallographic characterization of C~6~0Cl~2~4 (2005) (1)
- Frontispiece: Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties (0)
- Fine-Tuning Redox Properties of Perfluoroalkylated Fullerenes: Playing with Perfluoroalkyl Groups and Addition Motifs (2011) (0)
- The First X-ray Crystal Structures of Trifluoromethylated Endometallofullerenes - Invited (2009) (0)
- New Developments in Fluorination of C70 (2006) (0)
- Stable Fullerene Derivatives Can and Do Have Substituents on Triple-Hexagon Junctions (2009) (0)
- f-block MOFs: A Pathway to Heterometallic Transuranics. (2022) (0)
- Trifluoromethylation of Metallic Nitride Fullerene Sc3N@C80: further Exploration of Multiple Radical Additions (2008) (0)
- Nitrogen Directs Multiple Radical Additions to the 9,9′-Bi-1-aza(C60Ih)[5,6]fullerene: X-Ray Structure of 6,9,12,15,18-C59N(CF3)5. (2011) (0)
- Recent Advances in Fluorination of Fullerenes (2010) (0)
- Traffic Lights for Catalysis: Stimuli-Responsive Molecular and Extended Catalytic Systems. (2023) (0)
- Applications and developments part 2: general discussion. (2021) (0)
- New Challenges in Development of Soft-Ionization Mass Spectrometric Techniques for Fullerene Derivatives (2007) (0)
- Editorial for the Special Issue: Dimensionality of Emerging Materials and Energy (2022) (0)
- ESR-Vis/NIR Spectroelectrochemical Studyof C 70 A 3 ) 2 C and C 70 A 2 F 5 ) 2 C Radical Anions (2008) (0)
- Playing “Jenga” with MOFs: De-interpenetration for pore opening (2022) (0)
- Titelbild: Nitrogen Directs Multiple Radical Additions to the 9,9′‐Bi‐1‐aza(C60‐Ih)[5,6]fullerene: X‐ray Structure of 6,9,12,15,18‐C59N(CF3)5 (Angew. Chem. 24/2011) (2011) (0)
- Merging molecular catalysts and metal-organic frameworks for photocatalytic fuel production. (2022) (0)
- ESR-Vis-NIR Spectroelectrochemical Study of C60(CF3)n and C70(CF3)n Anions (2008) (0)
- Synthesis and Structures of C60 Fullerene Chlorides. (2006) (0)
- Natalia Shustova answers questions about 15 years of research on covalent organic frameworks (2020) (0)
- Polyfluoroalkylated aza[60]Fullerenes: Role of Nitrogen Atom in Addition Pattern Formation. The First X-ray Crystal Structure of Trifluoromethylated C59N. (2008) (0)
- Direct Identification of Mixed-Metal Centers in Metal−Organic Frameworks: Cu3(BTC)2 Transmetalated with Rh (2020) (0)
- CCDC 773326: Experimental Crystal Structure Determination (2011) (0)
- Vis-NIR and ESR Spectroelectrochemical Study of Sc3N@C80(CF3)2 (2010) (0)
- Dynamic HPLC Study of C60 Chlorination Leads to the Elusive Chlorofullerenes C60Cl2 and C60Cl4 (2009) (0)
- Structure of halofullerenes using experimental and theoretical approaches (2005) (0)
- (Invited) Photophysics and Electronic Structure of Metal-Organic Frameworks (2018) (0)
- Confinement-Driven Photophysics in Hydrazone-based Hierarchical Materials. (2022) (0)
- Frontispiz: Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties (0)
- Synthesis and Characterization of Heptafluoropropylated Fullerene Derivatives (2009) (0)
- Cover Picture: Nitrogen Directs Multiple Radical Additions to the 9,9′-Bi-1-aza(C60-Ih)[5,6]fullerene: X-ray Structure of 6,9,12,15,18-C59N(CF3)5 (Angew. Chem. Int. Ed. 24/2011) (2011) (0)
- Mechanistic Investigations of Gas-Phase Catalytic Hydrogenation in Metal–Organic Frameworks: Cooperative Activity of the Metal and Linker Sites in CuxRh3–x(BTC)2 (2022) (0)
- Fluorine-containing fullerenes and endometallofullerenes: Synthesis, structure, and spectroscopic characterization (2010) (0)
- Polyperfluoroalkylation of Higher Fullerenes with Hollow Cages and with Rare Earth Metal(s) Inside (2009) (0)
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