Norio Miyaura

Norio Miyaura's AcademicInfluence.com Rankings

Norio Miyaura

Chemistry

#1448

World Rank

#2162

Historical Rank

Organic Chemistry

#170

World Rank

#217

Historical Rank

chemistry Degrees

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Chemistry

Norio Miyaura's Degrees

PhD Chemistry Hokkaido University
Masters Chemistry Hokkaido University
Bachelors Chemistry Hokkaido University

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Norio Miyaura's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds (1995) (9366)
A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides (1980) (1442)
The Palladium-Catalyzed Cross-Coupling Reaction of Phenylboronic Acid with Haloarenes in the Presence of Bases (1982) (1380)
Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters (1995) (1116)
Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst (1979) (855)
Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. (2002) (756)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones (1998) (496)
Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to Enones (1997) (391)
Palladium-catalyzed inter- and intramolecular cross-coupling reactions of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with 1-halo-1-alkenes or haloarenes. Syntheses of functionalized alkenes, arenes, and cycloalkenes via a hydroboration-coupling sequence (1989) (381)
Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes (1985) (380)
Cross-Coupling Reactions (2002) (352)
Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. (2005) (338)
Metal-Catalyzed Reactions of Organoboronic Acids and Esters (2008) (300)
Platinum(0)-catalyzed diboration of alkynes (1993) (296)
A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature. (2002) (296)
Metal-catalyzed reactions of diborons for synthesis of organoboron compounds. (2004) (279)
Rhodium-Catalyzed Addition of Organoboronic Acids to Aldehydes. (1998) (251)
Palladium-catalyzed cross-coupling reaction of organoboron compounds with organic triflates (1993) (245)
Rhodium- or Iridium-Catalyzed trans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds (2000) (238)
A borylcopper species generated from bis(pinacolato)diboron and its additions to α,β-unsaturated carbonyl compounds and terminal alkynes (2001) (232)
Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes (1996) (228)
Synthesis of arylboronates via the palladium(0)-catalyzed cross-coupling reaction of tetra(alkoxo)diborons with aryl triflates (1997) (228)
Chemistry of Group 13 element-transition metal linkage — the platinum- and palladium-catalyzed reactions of (alkoxo)diborons (2000) (227)
Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(II) complexes (2002) (226)
Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence. (2002) (222)
Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates (2002) (214)
Addition and Coupling Reactions of Bis(pinacolato)diboron Mediated by CuCl in the Presence of Potassium Acetate (2000) (204)
Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of Arylboronic Acids with Aryl Electrophiles: Synthesis of Biaryl Ketones (1998) (202)
Transition metal-catalyzed borylation of alkanes and arenes via CH activation (2003) (197)
Synthesis of pinacol arylboronates via cross-coupling reaction of bis(pinacolato)diboron with chloroarenes catalyzed by palladium(0)–tricyclohexylphosphine complexes (2001) (195)
Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent. (2003) (180)
Synthesis of Biaryls via a Nickel(0)-Catalyzed Cross-Coupling Reaction of Chloroarenes with Arylboronic Acids. (1997) (179)
Cyclic triolborates: air- and water-stable ate complexes of organoboronic acids. (2008) (172)
Palladium-Catalyzed Alkyl-Alkyl Cross-Coupling Reaction of 9-Alkyl-9-BBN Derivatives with Iodoalkanes Possessing β-Hydrogens. (1992) (161)
Synthesis of Sterically Hindered Biaryls via the Palladium-Catalyzed Cross-Coupling Reaction of Arylboronic Acids or their Esters with Haloarenes (1992) (151)
Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds: Large Accelerating Effects of Bases and Ligands (2003) (149)
Iridium‐Catalyzed Direct Borylation of Five‐Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions (2003) (135)
Synthesis of unsymmetrical biaryl ketones via palladium-catalyzed carbonylative cross-coupling reaction of arylboronic acids with iodoarenes (1993) (127)
Conjugate addition of aryl boronic acids to enones catalyzed by cationic palladium(II)-phosphane complexes. (2003) (126)
Metal‐Catalyzed Cross‐Coupling Reactions of Organoboron Compounds with Organic Halides (2008) (124)
Iridium-catalyzed hydroboration of alkenes with pinacolborane (2004) (122)
Diboration of alkenes with bis(pinacolato)diboron catalysed by a platinum(0) complex (1997) (117)
1,4-Addition of Arylboronic Acids and Arylsiloxanes to α,β-Unsaturated Carbonyl Compounds via Transmetalation to Dicationic Palladium(II) Complexes (2004) (114)
Palladium-catalyzed cross-coupling reactions of B-alkyl-9-BBN or trialkylboranes with aryl and 1-alkenyl halides (1986) (112)
Novel synthesis of isoflavones by the palladium-catalyzed cross-coupling reaction of 3-bromochromones with arylboronic acids or its esters. (1988) (110)
Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes. (2010) (106)
Palladium(0)-catalyzed thioboration of terminal alkynes with 9-(alkylthio)-9-borabicyclo[3.3.1]nonane derivatives: stereoselective synthesis of vinyl sulfides via the thioboration-cross-coupling sequence (1993) (104)
Acceleration effect of Lewis acid in allylboration of aldehydes: catalytic, regiospecific, diastereospecific, and enantioselective synthesis of homoallyl alcohols. (2002) (104)
Cross-Coupling Reaction of Alkyl- or Arylboronic Acid Esters with Organic Halides Induced by Thallium(I) Salts and Palladium-Catalyst (1989) (102)
A synthesis of allylboronates via the palladium(0)-catalyzed cross-coupling reaction of bis(pinacolato)diboron with allylic acetates (1996) (98)
Rhodium(I)-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Amides (2001) (97)
Iridium-catalyzed borylation of arenes and heteroarenes via C-H activation (2006) (97)
Me-bipam for enantioselective ruthenium(II)-catalyzed arylation of aldehydes with arylboronic acids. (2009) (91)
New convenient approach to the preparation of (Z)-allylic boronates via catalytic 1,4-hydroboration of 1,3-dienes with catecholborane (1989) (91)
Palladium-Catalyzed Benzylic C–H Borylation of Alkylbenzenes with Bis(pinacolato)diboron or Pinacolborane (2001) (86)
A synthesis of biaryls via nickel(0)-catalyzed cross-coupling reaction of chloroarenes with phenylboronic acids (1996) (84)
Direct synthesis of aryl halosilanes through iridium(I)-catalyzed aromatic C-H silylation by disilanes. (2003) (80)
Synthesis of Biaryls via Cross-Coupling Reaction of Arylboronic Acids with Aryl Chlorides Catalyzed by NiCl2/Triphenylphosphine Complexes (2000) (80)
Convenient and general synthesis of acetylenes via the reaction of iodine with lithium l-alkynyltriorganoborates (1973) (78)
Synthesis of Allenes by Palladium-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Propargylic Carbonates: Transmetallation of Organoboron Compounds with (Alkoxo)palladium Complexes Under Neutral Conditions (1994) (76)
Enantioselective 1,4-Addition of Ar3Bi, [ArBF3]K, and ArSiF3 to Enones Catalyzed by a Dicationic Palladium(II)−Chiraphos or −Dipamp Complex (2005) (76)
Platinum(0)-catalysed diboration of alka-1,3-dienes with bis(pinacolato)diboron (1996) (74)
Palladium(II)‐Catalyzed 1,4‐Addition of Arylboronic Acids to β‐Arylenones for Enantioselective Synthesis of 4‐Aryl‐4H‐chromenes (2007) (72)
An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones (2012) (71)
Platinum(0)-catalyzed diboration of allenes with bis(pinacolato)diboron (1998) (70)
Rhodium-catalyzed phenylation of N-arylsulfonyl aldimines with sodium tetraphenylborate or trimethyl(phenyl)stannane (2000) (69)
Iridium-Catalyzed Dimerization of Terminal Alkynes to (E)-Enynes, (Z)-Enynes, or 1,2,3-Butatrienes (2000) (68)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones (1991) (68)
Synthesis of 1-Alkenylboronic Esters via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with 1-Alkenyl Halides and Triflates (2000) (65)
The palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with allylic or benzylic bromides. Convenient syntheses of 1,4-alkadienes and allybenzenes from alkynes via hydroboration (1980) (65)
γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R,S)-CyPF-t-Bu) Complex: Mechanistic Studies on Transmetalation and Enantioselection (2009) (65)
An N‐Linked Bidentate Phosphoramidite Ligand (N‐Me‐BIPAM) for Rhodium‐Catalyzed Asymmetric Addition of Arylboronic Acids to N‐Sulfonylarylaldimines (2009) (65)
Palladium-catalyzed biaryl-coupling reaction of arylboronic acids in water using hydrophilic phosphine ligands (2002) (65)
Regio- and stereospecific preparation of .beta.-(alkylthio)alkenyl-1,3,2-benzodioxaboroles by nickel-catalyzed hydroboration of thioacetylenes with catecholborane (1993) (64)
Introduction to Cross-Coupling Reactions (2002) (64)
Palladium-Catalyzed Cross-Coupling Reaction of Aryl or Vinylic Triflates with Organoboron Compounds (1990) (63)
Isolation and molecular structure of unusual oxochromium(V) cations for the catalytic epoxidation of alkenes (1983) (63)
Synthesis of ketones from iodoalkenes, carbon monoxide and 9-alkyl-9-borabicyclo[3.3.1]nonane derivatives via a radical cyclization and palladium-catalysed carbonylative cross-coupling sequence (1995) (62)
A stereospecific synthesis of conjugated (E, Z)- and (Z, Z)-alikadienes by a palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with 1-alkenyl bromides (1981) (62)
Rhodium(i)-catalyzed asymmetric hydroboration of alkenes with 1,3,2-benzodioxaborole (1990) (62)
The Cross-Coupling Reaction of Arylboronic Acids with Chloropyridines and Electron-Deficient Chloroarenes Catalyzed by a Polymer-Bound Palladium Complex (2000) (61)
New stereospecific syntheses of pheromone bombykol and its three geometrical isomers (1983) (61)
Stereo- and regiospecific syntheses to provide conjugated (E,Z)- and (Z,Z)-alkadienes, and arylated (Z)-alkenes in excellent yields via the palladium-catalyzed cross-coupling reactions of (Z)-1-alkenylboronates with 1-bromoalkenes and aryl iodides (1986) (59)
Improvements of Efficiency and Regioselectivity in the Iridium(I)-Catalyzed Aromatic CH Silylation of Arenes with Fluorodisilanes (2006) (58)
A Regio- and Stereoselective Platinum(0)-Catalyzed Hydroboration of Allenes Controlled by Phosphine Ligands (1999) (53)
Synthesis of Chiral Esters of (E)-3-(Silyloxy)-2-propenylboronic Acid via the Iridium-Catalyzed Isomerization of the Double Bond. (1999) (53)
Organic synthesis using haloboration reactions 11. A formal carboboration reaction of 1-alkynes and its application to the di- and trisubstituted alkene synthesis (1988) (52)
The palladium-catalyzed cross-coupling reaction of 9-organothio-9-borabicyclo[3.3.1]nonanes with organic electrophiles: Synthesis of unsymmetrical sulfides (1996) (51)
Platinum(0)-Catalyzed Diboration of Methylenecyclopropanes with Bis(pinacolato)diboron: A Selective Route to 2,4-Bis(boryl)-1-butenes (1999) (51)
Stereoselective Synthesis of Silyl Enol Ethers via the Iridium-Catalyzed Isomerization of Allyl Silyl Ethers (1999) (51)
Regioselective aromatic C-H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes. (2005) (51)
RHODIUMKATALYSIERTE ADDITION VON ORGANOBORONSAUREN AN ALDEHYDE (1998) (51)
Convenient one-pot synthesis of vinylic sulfides from thioalkynes via a catalytic hydroboration-coupling sequence (1993) (50)
A Synthesis of (E)-(1-Organo-1-alkenyl)boronates by the Palladium-Catalyzed Cross-Coupling Reaction of (E)-1,2-Bis(boryl)-1-alkenes with Organic Halides- A Formal Carboboration of Alkynes via the Diboration-Coupling Sequence. (1996) (49)
γ-Selective Cross-coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/D-t-BPF Complex (2006) (49)
Enantioselective 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds catalyzed by rhodium(I)-chiral phosphoramidite complexes (2007) (49)
1,4-Addition of arylboronic acids to β-aryl-α,β-unsaturated ketones and esters catalyzed by a rhodium(I)–chiraphos complex for catalytic and enantioselective synthesis of selective endothelin A receptor antagonists (2006) (49)
Aryl triolborates: novel reagent for copper-catalyzed N arylation of amines, anilines, and imidazoles. (2008) (48)
Palladium-catalyzed carbonylative cross-coupling reaction of 1-halo-1-alkenes with 9-alkyl-9-BBN derivatives. A direct synthesis of α,β-unsaturated ketones (1991) (46)
Preparation of 1-Aryl- or 1-Alkenyl-2-(perfluoroalkyl)acetylenes (1990) (45)
Synthesis of biaryls via nickel-catalyzed cross-coupling reaction of arylboronic acids and aryl mesylates (1998) (45)
Palladium(II)-catalyzed 1,4-addition of arylboronic acids to β-arylenals for enantioselective syntheses of 3,3-diarylalkanals: a short synthesis of (+)-(R)-CDP 840 (2007) (44)
Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters (2011) (44)
1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes (2008) (44)
New four-carbon-atom homologation involving the free-radical chain reaction of 1,3-butadiene monoxide with organoboranes. Synthesis of 4-alkyl-2-buten-1-ols from olefins via hydroboration (1971) (42)
Vinylic C--H borylation of cyclic vinyl ethers with bis(pinacolato)diboron catalyzed by an Iridium(I)-dtbpy complex. (2008) (41)
The palladium-catalyzed “head-to-tail” cross-coupling reaction of 1-alkenylboranes with phenyl or 1-alkenyl iodides. A novel synthesis of 2-phenyl-1-alkenes or 2-alkyl-1,3-alkadienes via organoboranes (1981) (41)
Bis(Pinacolato)Diboron (2003) (41)
Palladium-catalyzed cross-coupling reaction of (1-ethoxy-1-alken-2-yl)boranes with ortho-functionalized iodoarenes. A novel and convenient synthesis of benzo-fused heteroaromatic compounds (1987) (40)
A Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds Catalyzed by 2β-CD-[Rh(OH)(cod)]2 or [RhCl(cod)]2 in a Single Aqueous Medium (2001) (40)
Asymmetric 1,4-addition of potassium aryltrifluoroborates [ArBF3]K to enones catalyzed by dicationic palladium(II) complexes (2005) (40)
STEREOSELECTIVE SYNTHESIS OF ARYLATED (E)‐ALKENES BY THE REACTION OF ALK‐1‐ENYLBORANES WITH ARYL HALIDES IN THE PRESENCE OF PALLADIUM CATALYST (1980) (40)
Palladium-catalyzed cross-coupling of (2-ethoxyvinyl)boranes with aryl and benzyl halides. A new method for conversion of organic halides into aldehydes with two more carbon atoms (1982) (39)
Iridium-catalyzed ortho-C–H Borylation of Aryl Ketones with Bis(pinacolato)diboron (2011) (39)
A stereoselective preparation of γ-alkoxyallylboronates via catalytic isomerization of pinacol [(E)-3-alkoxy-1-propenyl]boronates (1995) (39)
Palladium-catalyzed iminocarbonylative cross-coupling reaction between haloarenes, t-BuNC, and 9-alkyl-9-BBN derivatives. Synthesis of alkyl aryl ketones (1992) (38)
A stereoselective isomerization of allyl silyl ethers to (E)- or (Z)-silyl enol ethers using cationic iridium complexes (1998) (37)
Synthesis of Organoboron Compounds via the Transition Metal-Catalyzed Addi-tion and Coupling Reaction of (Alkoxo) diborons (1999) (37)
Asymmetric Cross-coupling of Potassium 2-Butenyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/Josiphos Complex (2006) (36)
Asymmetric 1,4-addition of triarylbismuths to enones catalyzed by dicationic palladium(II) complexes. (2004) (36)
Practical synthesis of pinacolborane for one-pot synthesis of unsymmetrical biaryls via aromatic C-H borylation-cross-coupling sequence (2008) (36)
1, 4-Addition of Arylsiloxanes to Enones Catalyzed by Dicationic Palladium(II) Complexes in Aqueous Media (2003) (36)
Synthesis of B-trisubstituted borazines via the rhodium-catalyzed hydroboration of alkenes with N,N′,N″-trimethyl or N,N′,N″-triethylborazine (2006) (35)
Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with vinyl triflates β-substituted by a carbonyl group: efficient synthesis of β-boryl-α,β-unsaturated carbonyl compounds and their synthetic utility (2003) (33)
Stereo- and Regiospecific Synthesis of Trisubstituted Alkenes via the Palladium-catalyzed Cross-coupling Reaction of Diisopropyl (E)-(1-Alkyl-1-alkenyl)boronates with Organic Halides (1986) (33)
A new facile synthesis of 2-substituted 1,3-butadiene derivatives via palladium-catalyzed cross-coupling reaction of 2,3-alkadienyl carbonates with organoboron compounds (1994) (32)
Synthesis of biaryls via the cross-coupling reaction of arylboronic acids (1998) (32)
Synthesis of Functionalized 1-Alkenylboronates via Hydroboration-Dealkylation of Alkynes with Diisopinocampheylborane (1993) (32)
Aromatic C-H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(I)/2,9-dimethylphenanthroline (dmphen) complex. (2013) (32)
Reaction of organoboranes with α-lithium furan (1971) (31)
Two novel reactions of monomeric formaldehyde with trialkylboranes. Remarkably rapid elimination diverted by oxygen to a free-radical chain addition (1972) (30)
Cross-coupling reactions of 1-alkenylboranes with 3,4-epoxy-1-butene catalyzed by palladium or nickel complexes (1982) (29)
Chiral Bis-phosphoramidites Based on Linked-BINOL for Rhodium-catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds (2005) (29)
Stereoselective Synthesis of Conjugated 2,4-Alkadienoates via the Palladium-Catalyzed Cross-Coupling of 1-Alkenylboronates with 3-Bromo-2-alkenoates (1989) (29)
Stereoselective synthesis of allylic boronates via palladium-catalyzed cross-coupling reaction of Knochel's (dialkoxyboryl) methylzinc reagents with 1-halo-1-alkenes (1993) (28)
Asymmetric addition of arylboronic acids to glyoxylate catalyzed by a ruthenium/Me-BIPAM complex. (2012) (28)
Stereoselective synthesis of exocyclic alkenes via hydroboration-cross-coupling sequence (1992) (28)
Me-BIPAM for the synthesis of optically active 3-aryl-3-hydroxy-2-oxindoles by ruthenium-catalyzed addition of arylboronic acids to isatins. (2012) (28)
Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated N-Acylamides Catalyzed by Dicationic Palladium(II)-(S,S)-Chiraphos Complex (2007) (28)
Synthesis and cycloaddition of 2-(dialkoxyboryl)-1,3-butadiene (1993) (28)
New stereo- and regiospecific synthesis of humulene by means of the palladium-catalyzed cyclization of haloalkenylboranes (1984) (26)
Intramolecular allylboration of γ-(ω-formylalkoxy)allylboronates for syntheses of trans- or cis-2-(ethenyl)tetrahydropyran-3-ol and 2-(ethenyl)oxepan-3-ol (2003) (26)
CHROMYL COMPLEXES IN THE DIRECT EPOXIDATION OF ALKENES (1983) (26)
Rhodium-catalyzed 1,4-addition of lithium 2-furyltriolborates to unsaturated ketones and esters for enantioselective synthesis of γ-oxo-carboxylic acids by oxidation of the furyl ring with ozone. (2011) (26)
The reaction of copper(I) methyltrialkylborates with allylic halides or 2-propynylic halides. (1977) (25)
Pd/Josiphos-Catalyzed Enantioselective α-Arylation of Silyl Ketene Acetals and Mechanistic Studies on Transmetalation and Enantioselection (2011) (25)
A Sequence of Palladium-Catalyzed Borylation of Allyl Acetates with Bis(pinacolato)diboron and Intramolecular Allylboration for the Cyclization of Oxo-2-alkenyl Acetates (1997) (25)
Stereospecific Synthesis of (2Z,4E,6E)-3,7,11-Trimethyl-2,4,6,10-dodecatetraene [trans(C10)-Allofarnesene] (1982) (25)
Iridium-catalyzed Vinylic C-H Borylation of Cyclic Vinyl Ethers by Bis(pinacolato)diboron (2008) (25)
A Stoichiometric Aromatic C—H Borylation Catalyzed by Iridium(I)/2,2′‐Bipyridine Complexes at Room Temperature. (2002) (24)
Olefination and hydroxymethylation of aldehydes using Knochel's (dialkoxyboryl)methylcopper reagents (1996) (24)
Rhodium(I)- or Palladium(II)-Catalyzed 1,4-Additions of Organoboron, -silicon and -bismuth Compounds to Electron-Deficient Alkenes (2006) (23)
Enantioselective Synthesis of Arylglycine Derivatives by Asymmetric Addition of Arylboronic Acids to Imines (2011) (23)
A stereoselective route to alkenyl sulfides through the palladium-catalyzed cross-coupling reaction of 9-alkyl-BBN with 1-bromo-1-phenylthioethene or (E)- and (Z)-2-bromo-1-phenylthio-1-alkenes (1988) (23)
Stereoselective synthesis of conjugated dienones via the palladium-catalyzed cross-coupling reaction of 1-alkenylboronates with 3-halo-2-alken-1-ones. (1987) (22)
Reactions of cuprous methyltrialkylborates obtainable from trialkylboranes with acrylonitrile, ethyl acrylate and 1-acyl-2-vinylcyclopropane. Convenient syntheses of nitriles, carboxylic esters and γ,δ-unsaturated ketones (1976) (22)
Iridium-Catalyzed C-H Borylation of Arenes and Heteroarenes: 1-Chloro-3-iodo-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene and 2-(4,4,5,5,-Tetramethyl-1,3,2-dioxaborolan-2-yl)indole (2005) (21)
Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer–Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine (2008) (21)
Double-coupling of dibromo arenes with aryltriolborates for synthesis of diaryl-substituted planar frameworks (2011) (20)
New Synthetic Reactions of Organoboron Compounds by Transition-Metal Catalysts (1993) (20)
Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compounds (2002) (20)
Celebrating 20 Years of SYNLETT - SpecialAccount On Palladium(II)-Catalyzed Additions of ArylboronicAcids to Electron-Deficient Alkenes, Aldehydes, Imines,and Nitriles (2009) (19)
Stereoselective Isomerization of Unsymmetrical Diallyl Ethers to Allyl (E)-Vinyl Ethers by a Cationic Iridium Catalyst (2000) (19)
Preparation of h-BN nano-tubes, -bamboos, and -fibers from borazine oligomer with alumina porous template (2008) (19)
Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross-Metathesis between Pinacol Allylboronate and Terminal or Internal Alkenes (2002) (19)
Synthesis of ortho-Acylbenzylboronates via Cross-Coupling Reaction of (Dialkoxyboryl)methylzinc Reagents with Haloarenes. A Stable ortho-Quinodimethane Precursor. (1993) (19)
The Palladium–Catalyzed Cross-Coupling Reaction of Enol Acetates of α-Bromo Ketones with 1-Alkenyl-, Aryl-, or Alkylboron Compounds; A Facile Synthesis of Ketones and Their Enol Acetates (1992) (18)
The Coupling Reaction of Copper(I) Methyltrialkylborates with Benzyl Bromides. A Convenient Synthesis of Alkylbenzenes from Organoboranes (1976) (18)
Stereospecific Synthesis of the Fungal Prohormone (±)-Trisporol B via the Palladium-Catalyzed Cross-Coupling Reaction of 1-Alkenylborane with 1-Haloalkene (1986) (18)
Nucleophilic Borylation of Benzyl Halides with Bis(pinacolato)diboron Catalyzed by Palladium(0) Complexes (2002) (17)
Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls (2010) (17)
For Aldol Reactions (2005) (17)
Reaction of lithium alkynyltrialkylborates with propionic acid. General and convenient syntheses of internal and terminal olefins using organoboranes (1974) (16)
The Reactions of Copper(I) 1-Alkenyltrimethylborates with Allylic Bromides or 2-Propynyl Bromide (1980) (16)
A chiral bidentate phosphoramidite (Me-BIPAM) for Rh-catalyzed asymmetric hydrogenation of α-dehydroamino esters, enamides, and dimethyl itaconate (2009) (16)
Synthesis of oxo-2-alkenylboronates and their cyclization to 3-methylene cycloalkanols via intramolecular allylboration (1994) (15)
Vinylic organoboranes. 1. A convenient synthesis of acetylenes via the reaction of lithium (1-alkynyl) organoborates with iodine (1986) (15)
Heck and Cross-Coupling Reactions: Two Core Chemistries in Metal-Catalyzed Organic Syntheses (2004) (15)
Hydroboration, Diboration, Silylboration, and Stannylboration (2001) (15)
Palladium-Catalyzed Cross-Coupling Reaction of (E)-1-Alkenyl-1,3,2-benzo-dioxaboroles with Allylic Phenoxides. A Simple Route 1,4-Alkadienes from Alkynes via Hydroboration$^\dag$ (1988) (14)
Synthesis of 10-Hydroxy-2-decenoic Acid (Royal Jelly Acid) from the Butadiene Telomer (1977) (14)
The coupling reaction of copper(I) methyltrialkylborates with aroyl chlorides. A convenient synthesis of alkyl aryl ketones from organoboranes (1977) (14)
Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones (2002) (13)
The Oxygen-Induced Reactions of Organoboranes with 3,4-Epoxy-1-butynes. A New Route to Functionalized Allenes (1973) (13)
Palladium-Catalyzed Cross-Coupling Reactions of Aryl and Vinylic Boron Compounds with Organic Halides (1988) (13)
Palladium‐catalyzed reaction of 1‐alkenylboronates with vinylic halides: (1Z,3E)‐1‐phenyl‐1,3‐octadiene (2003) (13)
The Reactions of Organoboranes and Lithium Dialkylcuprates with 1-Acyl-2-vinylcyclopropanes. A Convenient New Route to γ,δ-Unsaturated Ketone Synthesis (1975) (13)
Stereoselective syntheses of conjugated 1-phenylthio-1,3-alkadienes and 1,3,5-alkatrienes through the palladium-catalyzed cross-coupling reaction of (E)- or (Z)-1-alkenylboronates with (E)- or (Z)-2-bromo-1-phenylthio-1-alkenes. (1987) (12)
A stereoselective synthesis of 1,2-diarylethenyl ethyl ethers via the carbocupration-cross coupling sequence (1996) (11)
Synthesis of Pinacol Arylboronates via Cross‐Coupling Reaction of Bis(pinacolato)diboron with Chloroarenes Catalyzed by Palladium(0)—Tricyclohexylphosphine Complexes. (2002) (11)
Stereoselective Synthesis of (Z)-(1-Organo-1-alkenyl)boronic Esters by the Palladium-Catalyzed Cross-Coupling Reaction of (Z)-(1-Iodo-1-alkenyl)boronic Esters with Organozinc Reagents (1993) (11)
Addition Reaction of Copper(I) Methyltrialkylborates with Ethyl Propiolate. Stereospecific Synthesis of (E)-α,β-Unsaturated Acid Esters (1977) (11)
Palladium-Catalyzed Inter- and Intramolecular Cross-Coupling Reactions of B-Alkyl-9-borabicyclo(3.3.1)nonane Derivatives with 1-Halo-1-alkenes or Haloarenes. Syntheses of Functionalized Alkenes, Arenes, and Cycloalkenes via a Hydroboration-Coupling Sequence. (1989) (11)
9.05 – Boron (2007) (11)
ISOPROPENYLATION OF OLEFINS VIA THE REACTION OF IODINE WITH LITHIUM TRIALKYLISOPROPENYLBORATES OBTAINABLE FROM TRIALKYLBORANES (1974) (11)
Synthesis of Tetra-ortho-substituted Biaryls using Aryltriolborates (2011) (11)
A Convenient and General Synthesis of 2-Alkynoates or 1-Alkynyl Aryl Ketones via the Reaction of Iodine with the Ate-complexes Obtained from Lithium Ethoxycarbonyl-or Aroylacetylenide and Trialkylboranes (1977) (11)
Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates (2011) (11)
The reaction of iodine with ate-complexes obtained from organoboranes and lithium chloroacetylide. Convenient syntheses of symmetric alkynes and alkenes (1975) (11)
Metal‐Catalyzed Borylation of CH and CHalogen Bonds of Alkanes, Alkenes, and Arenes for the Synthesis of Boronic Esters (2011) (10)
Rhodium-Catalyzed Asymmetric1,4-Addition of Heteroaryl Cyclic Triolborate to α,β-UnsaturatedCarbonyl Compounds (2009) (10)
Lithium thioalkynolates and its reaction with carbonyl compounds. (1979) (10)
Synthesis of Functionalized Organotin Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Aryl or 1-Alkenyl Halides with 9-(ω-Stannylalkyl)-9-borabicyclo[3.3.1]nonanes (1991) (10)
The Reaction of Copper(I) Methyltrialkylborates with 1-(1-Pyrrolidinyl)-6-chloro-1-cyclohexene (1979) (10)
OXYGEN-INDUCED 1,4-ADDITION REACTION OF ORGANOBORANES TO CROTONALDIMINE (1974) (9)
Cross-Coupling Reaction with Lithium Methyltriolborate (2012) (9)
Asymmetric 1,4-Addition ofArylboronic Acids to α,β-Unsaturated Esters Catalyzedby Dicationic Palladium(II)-Chiraphos Complex for Short-Step Synthesisof SmithKline Beecham’s Endothelin Receptor Antagonist (2008) (9)
Synthesis of Optically Pure 2-Substituted 1,3-Propanediol Spiroacetal Derivatives of l-Menthone via Hydroboration-Coupling Sequence (1992) (9)
The synthesis of methoxycyclopropanes via the treatment of ate-complexes obtained from B-alkyl-9-borabicyclo[3,3,1]nonanes and lithium methoxyallene with acetic acid (1980) (9)
Synthesis of Sterically Hindered Biaryls (III), (V), and (VII) via the Palladium-Catalyzed Cross-Coupling Reaction of Arylboronic Acids or Their Esters with Haloarenes. (1992) (8)
Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the copper(I) mediated coupling reaction of Knochel's (dialkoxyboryl)methylzinc reagents with propargylic tosylates (1994) (8)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones. (1998) (8)
Rhodium‐Catalyzed Conjugate Addition of Aryl‐ or 1‐Alkenylboronic Acids to Enones (1998) (8)
A Synthesis of Biaryls via Nickel(0)-Catalyzed Cross-Coupling Reaction of Chloroarenes with Phenylboronic Acids. (2010) (8)
Reaction of organoboranes with methoxycarbene, and reaction of dichloromethyl methyl ether with at-complex obtained from organoboranes and methyl lithium (1969) (7)
Nickel Acetylacetonate-Induced 1,4-Additions of 1-Alkenyl(Disiamyl)Boranes to α,β-Unsaturated Ketones, Esters and Nitriles (1996) (7)
Photo-induced transformations. Part 79. On the mechanism of the formation of oxa steroids via photo- and thermally-induced rearrangement of 3-hydroxy-Δ5-steroid hypoiodites in the presence of mercury(II) oxide and iodine. An oxygen-18 labelling study. (1985) (7)
The reaction of copper(I) methyltrialkylborates with ethyl β-bromocrylates. Stereospecific syntheses of (E)- and (Z)-α,β-unsaturated acid esters from organoboranes (1977) (7)
The Cross‐Coupling Reaction of Arylboronic Acids with Chloropyridines and Electron‐Deficient Chloroarenes Catalyzed by a Polymer‐Bound Palladium Complex. (2001) (6)
Rhodium-Catalyzed Addition of Arylboronic Acids to N-Sulfonyl Aldimines (2000) (6)
Palladium(0)-Catalyzed Reaction of 9-Alkyl-9-Borabicyclo[3.3.1]Nonane with 1-Bromo-1-Phenylthioethene: 4-(3-Cyclohexenyl)-2-Phenylthio-1-Butene (2003) (6)
Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates (2002) (6)
PALLADIUM‐CATALYZED CROSS‐COUPLING OF (2‐ETHOXYVINYL)BORANES WITH ARYL AND BENZYL HALIDES. A NEW METHOD FOR CONVERSION OF ORGANIC HALIDES INTO ALDEHYDES WITH TWO MORE CARBON ATOMS (1982) (6)
Inter- and Intramolecular Additions of 1-Alkenylboronic Acids or Esters to Aldehydes and Ketones Catalyzed by Rhodium(I) Complexes in Basic, Aqueous Solutions (2002) (5)
Synthesis of Biaryls via the Cross‐Coupling Reaction of Arylboronic Acids (1999) (5)
Iridium‐Catalyzed C—H Coupling Reaction of Heteroaromatic Compounds with Bis(pinacolato)diboron: Regioselective Synthesis of Heteroarylboronates. (2002) (5)
Transition Metal-Catalyzed Borylation of Alkanes and Arenes via C—H Activation (2003) (5)
Novel Synthesis of Isoflavones by the Palladium‐Catalyzed Cross‐Coupling Reaction of 3‐Bromochromones with Arylboronic Acids or Its Esters. (1988) (4)
Metal-Catalyzed Reactions of Diborons for Synthesis of Organoboron Compounds (2004) (4)
Tandem Conjugate Addition-Aldol Cyclization to give Optically Active 1-Aryl-1H-indenes via Asymmetric Pd2+-Catalyzed 1,4-Addition of Aryl boronic Acids (2007) (4)
Asymmetric Conjugate 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Esters Catalyzed by Rhodium(I)/(S)-Binap. (2001) (4)
Stereoselective Synthesis of Silyl Enol Ethers via the Iridium‐Catalyzed Isomerization of Allyl Silyl Ethers. (1999) (4)
Addition and Coupling Reactions of Bis(pinacolato)diboron Mediated by CuCl in the Presence of Potassium Acetate. (2001) (4)
The Reaction of Cyanogen Bromide with Dilithium Ethynylbis[trialkylborates]. A Novel Synthesis of Di-, Tri-, and Tetrasubstituted Ethenes Using Organoboranes (1975) (4)
Mild Iridium‐Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential Intermediate. (2002) (4)
A Large Accelerating Effect of Tri(tert‐butyl)phosphine in the Rhodium‐Catalyzed Addition of Arylboronic Acids to Aldehydes. (2000) (4)
Metal-Catalyzed Reactions of Organoboron Compounds in Organic Syntheses (2008) (4)
Palladium‐Catalyzed Alkyl‐Alkyl Cross‐Coupling Reaction of 9‐Alkyl‐9‐ BBN Derivatives with Iodoalkanes Possessing β‐Hydrogens. (1992) (3)
Synthesis of Ketones from Iodoalkenes, Carbon Monoxide and 9-Alkyl-9- borabicyclo(3.3.1)nonane Derivatives via a Radical Cyclization and Palladium-Catalyzed Carbonylative Cross-Coupling Sequence. (1995) (3)
Synthesis of Biaryls via Cross-Coupling Reaction of Arylboronic Acids with Aryl Chlorides Catalyzed by NiCl2/Triphenylphosphine Complexes. (2001) (3)
A Palladium-Catalyzed Biaryl Coupling of Arylboronic Acids in Aqueous Media Using A Gluconamide-Substituted Triphenylphosphine (GLCAphos) Ligand (2000) (3)
A CONVENIENT SYNTHESIS OF α-BROMOKETONES FROM VINYLOXYBORANES OBTAINED BY THE REACTION OF ORGANOBORANES WITH α, β-UNSATURATED KETONES (1973) (3)
Asymmetric Conjugate Additionof Arylboronic Acids to Enones Catalyzed by Rhodium-MonodentatePhosphoramidite Complexes in the Presence of Bases (2003) (3)
For the Reduction of Carbonyl Compounds (2005) (3)
An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines. (2009) (3)
Metal‐Catalyzed Borylation of Alkanes and Arenes via C ? H Activation for Synthesis of Boronic Esters (2006) (3)
Synthesis of Arylboronates via the Palladium(0)-Catalyzed Cross- Coupling Reaction of Tetra(alkoxo)diborons with Aryl Triflates. (1997) (3)
THE PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF 1-ALKENYLBORANES WITH ALLYLIC OR BENZYLIC BROMIDES. CONVENIENT SYNTHESES OF 1,4-ALKADIENES AND ALLYLBENZENES FROM ALKYNES VIA HYDROBORATION (1980) (2)
Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo) diborons: An Efficient and Convenient Approach to cis-Bis(boryl) alkenes. (1996) (2)
Rhodium-catalyzed addition reactions of organoboronic acids (2000) (2)
A Regio- and Stereoselective Platinum(0)-Catalyzed Hydroboration of Allenes Controlled by Phosphine Ligands. (2000) (2)
Synthesis of Arylboronates via Palladium-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Aryl Halides or Triflates (1997) (2)
New Convenient Approach to the Preparation of Z-Allylic Boronates via Catalytic 1,4-Hydroboration of 1,3-Dienes with Catecholborane. (1990) (2)
Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Esters Catalyzed by Dicationic Palladium(II)—Chiraphos Complex for Short-Step Synthesis of SmithKline Beecham′s Endothelin Receptor Antagonist. (2009) (2)
Preparation of 1-Aryl- or 1-Alkenyl-2-(perfluoroalkyl)acetylenes. (1990) (2)
Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds: Large Accelerating Effects of Bases and Ligands. (2003) (2)
Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates. (2012) (2)
Chiral Bis-phosphoramidites Based on Linked-BINOL for Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds. (2006) (2)
Palladium(0)-Catalyzed Thioboration of Terminal Alkynes with 9-( Alkylthio)-9-borabicyclo(3.3.1)nonane Derivatives: Stereoselective Synthesis of Vinyl Sulfides via the Thioboration-Cross-Coupling Sequence. (1993) (2)
Celebrating 20 Years of SYNLETT — Special Account on Palladium(II)-Catalyzed Additions of Arylboronic Acids to Electron-Deficient Alkenes, Aldehydes, Imines, and Nitriles (2009) (2)
A Synthesis of (E)-(1-Organo-1-alkenyl)boronates by the Palladium- Catalyzed Cross-Coupling Reaction of (E)-1,2-Bis(boryl)-1-alkenes with Organic Halides: A Formal Carboboration of Alkynes via the Diboration- Coupling Sequence. (1997) (2)
Palladium-Catalyzed Cross-Coupling Reactions of B-Alkyl-9-BBN or Trialkylboranes with Aryl and 1-Alkenyl Halides. (1987) (2)
Regioselective cleavage of aryl decyl ethers with alkali metals. (1976) (2)
Rhodium(I)-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Amides. (2010) (2)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Heteroaryl Cyclic Triolborate to α,β‐Unsaturated Carbonyl Compounds. (2009) (2)
A Chiral Bidentate Phosphoramidite (Me-BIPAM) for Rh-Catalyzed Asymmetric Hydrogenation of α-Dehydroamino Esters, Enamides, and Dimethyl Itaconate. (2009) (2)
ortho-C—H Borylation of Benzoate Esters with Bis(pinacolato)diboron Catalyzed by Iridium—Phosphine Complexes. (2010) (2)
Cross-Coupling Reaction of Organoboron Compounds via Base-Assisted Transmetalation to Palladium(II) Complexes. (2010) (2)
For Amidation of Carboxylic Acids (2005) (1)
Enantioselective Synthesis of Arylglycine Derivatives by Asymmetric Addition of Arylboronic Acids to Imines. (2012) (1)
A Stereoselective Isomerization of Allyl Silyl Ethers to (E)- or (Z)-Silyl Enol Ethers Using Cationic Iridium Complexes. (1998) (1)
For Hydroxyalkylation of Phenols (2005) (1)
Asymmetric Conjugate Addition of Arylboronic Acids to Enones Catalyzed by Rhodium‐Monodentate Phosphoramidite Complexes in the Presence of Bases. (2003) (1)
Enantioselective 1,4‐Addition of Arylboronic Acids to α,β‐Unsaturated Carbonyl Compounds Catalyzed by Rhodium(I)‐Chiral Phosphoramidite Complexes. (2007) (1)
Palladium‐Catalyzed Carbonylative Cross‐Coupling Reaction of 1‐Halo‐1‐ alkenes with 9‐Alkyl‐9‐BBN Derivatives. A Direct Synthesis of α,. beta.‐Unsaturated Ketones. (1991) (1)
Synthesis of Biaryls via Nickel‐Catalyzed Cross‐Coupling Reaction of Arylboronic Acids and Aryl Mesylates. (1999) (1)
Stereospecific Synthesis of the Fungal Prohormone (±)-Trisporol B via the Palladium-Catalyzed Cross-Coupling Reaction of 1-Alkenylborane with 1-Haloalkene. (1986) (1)
γ‐Selective Cross‐Coupling of Potassium Allyltrifluoroborates with Aryl and 1‐Alkenyl Bromides Catalyzed by a Pd(OAc)2/D‐t‐BPF Complex. (2006) (1)
Aromatic C—H Silylation of Arenes with 1-Hydrosilatrane Catalyzed by an Iridium(I)/2,9-dimethylphenanthroline(dmphen) Complex. (2014) (1)
Aryl Triolborates: Novel Reagent for Copper‐Catalyzed N Arylation of Amines, Anilines, and Imidazoles. (2008) (1)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Heteroaryl Triolborates (2009) (1)
A New Facile Synthesis of 2‐Substituted 1,3‐Butadiene Derivatives via Palladium‐Catalyzed Cross‐Coupling Reaction of 2,3‐Alkadienyl Carbonates with Organoboron Compounds. (1994) (1)
Convenient One‐Pot Synthesis of Vinylic Sulfides from Thioalkynes via a Catalytic Hydroboration‐Coupling Sequence. (1994) (1)
Rhodium‐Catalyzed Addition Reactions of Organoboronic Acids (2000) (1)
Rhodium-Catalyzed Phenylation of N-Arylsulfonyl Aldimines with Sodium Tetraphenylborate or Trimethyl(phenyl)stannane. (2000) (1)
Regio- and Stereospecific Preparation of β-(Alkylthio)alkenyl-1,3, 2-benzodioxaboroles by Nickel-Catalyzed Hydroboration of Thioacetylenes with Catecholborane. (1993) (1)
Palladium-Catalyzed Biaryl-Coupling Reaction of Arylboronic Acids in Water Using Hydrophilic Phosphine Ligands. (2002) (1)
Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer—Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine. (2008) (1)
Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of Arylboronic Acids with Aryl Electrophiles: Synthesis of Biaryl Ketones. (1998) (1)
Palladium‐Catalyzed Benzylic C—H Borylation of Alkylbenzenes with Bis(pinacolato)diboron or Pinacolborane. (2002) (1)
Synthesis of Lithium 2‐Pyridyltriolborate and its Cross‐Coupling Reaction with Aryl Halides (2012) (1)
Metal‐Catalyzed Borylation of C—H and C—Halogen Bonds of Alkanes, Alkenes, and Arenes for the Synthesis of Boronic Esters (2012) (1)
Me‐Bipam for Enantioselective Ruthenium(II)‐Catalyzed Arylation of Aldehydes with Arylboronic Acids. (2009) (1)
Palladium‐Catalyzed Carbonylative Cross‐Coupling Reaction of Iodoalkanes with 9‐Alkyl‐9‐BBN Derivatives. A Direct and Selective Synthesis of Ketones. (1992) (1)
Rhodium-catalyzed 1,4-addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds: large accelerating effects of bases and ligands. (2003) (1)
Suzuki Coupling Reactions (2005) (1)
Synthesis of Allenes by Palladium‐Catalyzed Cross‐Coupling Reaction of Organo‐Boron Compounds with Propargylic Carbonates: Transmetalation of Organo‐Boron Compounds with (Alkoxo)palladium Complexes Under Neutral Conditions. (1994) (1)
Enantioselective 1,4‐Addition of Ar3Bi, [ArBF3]K, and ArSiF3 to Enones Catalyzed by a Dicationic Palladium(II)—Chiraphos or —Dipamp Complex. (2006) (1)
Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones. (2002) (0)
NEW STEREO- AND REGIOSELECTIVE SYNTHESIS OF HUMULENE BY MEANS OF THE PALLADIUM-CATALYZED CYCLIZATION OF HALOALKENYLBORANES (1984) (0)
Photo-induced Transformations. Part 79. Mechanism of the Formation of Oxa Steroids via Photo- and Thermally-induced Rearrangement of 3-Hydroxy-Δ5-steroid Hypoiodites in the Presence of Mercury(II) Oxide and Iodine. An 18O Labelling St (1985) (0)
A STEREOSPECIFIC SYNTHESIS OF CONJUGATED (E,Z)- AND (Z,Z)-ALKADIENES BY A PALLADIUMCATALYZED CROSS-COUPLING REACTION OF 1-ALKENYLBORANES WITH 1-ALKENYL BROMIDES (1981) (0)
The Palladium-Catalyzed Cross-Coupling Reaction of 9-Organothio-9- borabicyclo(3.3.1)nonanes with Organic Electrophiles: Synthesis of Unsymmetrical Sulfides. (1997) (0)
Aryl‐ and Hetarylboranes (2006) (0)
Synthesis of Functionalized Organotin Compounds via Palladium‐ Catalyzed Cross‐Coupling Reaction of Aryl or 1‐Alkenyl Halides with 9‐( ω‐Stannylalkyl)‐9‐borabicyclo(3.3.1)nonanes. (1992) (0)
Palladium- and Nickel-Catalyzed Cross-Coupling Reactions (2005) (0)
Use as Catalysts (2005) (0)
Palladium‐Catalyzed Cross‐Coupling Reactions of Aryl and Vinylic Boron Compounds with Organic Halides (1989) (0)
A CONVENIENT STEROSPECIFIC SYNTHESIS OF α,β-UNSATURATED CARBOXYLIC ESTERS VIA THE PALLADIUM-CATALYZED CARBONYLATION OF 1-ALKENYLBORANES (1982) (0)
A Route to Prepare BN Nanofibers from Borazine Oligomer Using Al Template (2005) (0)
A Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds Catalyzed by 2β-CD-[Rh(OH)(cod)]2 or [RhCl(cod)]2 in a Single Aqueous Medium. (2001) (0)
By Palladium-Catalyzed Coupling of 1,3,2-Dioxaborolanes (2005) (0)
Via Magnesium and Lithium Reagents (2005) (0)
Diboration of Alkenes and Alkynes (2005) (0)
REACTION OF LITHIUM ALKYNYLTRIALKYLBORATES WITH PROPIONIC ACID, GENERAL AND CONVENIENT SYNTHESES OF INTERNAL AND TERMINAL OLEFINS USING ORGANOBORANES (1974) (0)
Stereoselective Synthesis of Allylic Boronates via Palladium-Catalyzed Cross-Coupling Reaction of Knochel′s (Dialkoxyboryl)methylzinc Reagents with 1-Halo-1-alkenes. (1993) (0)
Rhodium(I)-Catalyzed Asymmetric Hydroboration of Alkenes (I) with 1,3,2-Benzodioxaborole. (1990) (0)
Synthesis of Unsymmetrical Biaryl Ketones (IV) via Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of Arylboronic Acids (I) with Iodoarenes (II). (1994) (0)
Me‐BIPAM for the Synthesis of Optically Active 3‐Aryl‐3‐hydroxy‐2‐oxindoles by Ruthenium‐Catalyzed Addition of Arylboronic Acids to Isatins. (2013) (0)
Practical Synthesis of Pinacolborane for One-Pot Synthesis of Unsymmetrical Biaryls via Aromatic C—H Borylation—Cross-Coupling Sequence. (2008) (0)
THE OXYGEN-INDUCED REACTIONS OF ORGANOBORANES WITH 3,4-EPOXY-1-BUTYNES, A NEW ROUTE TO FUNCTIONALIZED ALLENES (1973) (0)
Formation of Diol Esters (2005) (0)
Synthesis of 1‐Alkenylboronic Esters via Palladium‐Catalyzed Cross‐Coupling Reaction of Bis(pinacolato)diboron with 1‐Alkenyl Halides and Triflates. (2000) (0)
Arylation of Organic Electrophiles (2005) (0)
Direct Synthesis of Aryl Halosilanes Through Iridium(I)-Catalyzed Aromatic C—H Silylation by Disilanes. (2004) (0)
Palladium‐Catalyzed Cross‐Coupling Reaction of Organoboron Compounds with Organic Triflates. (1993) (0)
Asymmetric Addition of Arylboronic Acids to Glyoxylate Catalyzed by a Ruthenium/Me‐BIPAM Complex. (2012) (0)
Organic Synthesis Using Haloboration Reactions. Part 11. A Formal Carboration Reaction of 1‐Alkynes and Its Application to the Di‐ and Trisubstituted Alkene Synthesis. (1988) (0)
Conjugate Addition of Aryl Boronic Acids to Enones Catalyzed by Cationic Palladium(II)—Phosphane Complexes. (2003) (0)
Palladium-Catalyzed Cross-Coupling Reaction of Aryl or Vinylic Triflates with Organoboron Compounds. (1990) (0)
Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenals for Enantioselective Syntheses of 3,3-Diarylalkanals: A Short Synthesis of (+)-(R)-CDP 840. (2007) (0)
Via Other Metal Reagents (2005) (0)
Hydroboration of Alkenes and Alkynes (2005) (0)
Direct Borylation of Alkanes and Arenes (2005) (0)
Palladium-Catalyzed Cross-Coupling Reaction of (1-Ethoxy-1-alken-2-yl)boranes with ortho-Functionalized Iodoarenes. A Novel and Convenient Synthesis of Benzo-Fused Heteroaromatic Compounds. (1987) (0)
A Palladium-Catalyzed Biaryl Coupling of Arylboronic Acids in Aqueous Media Using a Gluconamide-Substituted Triphenylphosphine (GLCAphos) Ligand. (2000) (0)
Asymmetric 1,4‐Addition of Triarylbismuths to Enones Catalyzed by Dicationic Palladium(II) Complexes. (2005) (0)
Biaryls via a One-Pot Borylation-Cross-Coupling Sequence Using Pinacolborane (2008) (0)
Palladium(II)‐Catalyzed 1,4‐Addition of Arylboronic Acids to β‐Arylenones for Enantioselective Synthesis of 4‐Aryl‐4H‐chromenes. (2007) (0)
Iridium-Catalyzed Vinylic C—H Borylation of Cyclic Vinyl Ethers by Bis(pinacolato)diboron. (2008) (0)
Synthesis of ortho‐Acylbenzylboronates via Cross‐Coupling Reaction of ( Dialkoxyboryl)methylzinc Reagents with Haloarenes. A Stable ortho‐ Quinodimethane Precursor. (1994) (0)
Stereoselective Synthesis of 1,2‐Diarylethenyl Ethyl Ethers via the Carbocupration‐Cross Coupling Sequence. (1997) (0)
REACTION OF CYANOGEN BROMIDE WITH DILITHIUM ETHYNYLBIS(TRIALKYLBORATES). NOVEL SYNTHESIS OF DI-, TRI-, AND TETRASUBSTITUTED ETHENES USING ORGANOBORANES (1976) (0)
A CONVENIENT SYNTHESIS OF ALPHA-BROMOKETONES FROM VINYLOXYBORANES OBTAINED BY THE REACTION OF ORGANOBORANES WITH ALPHA,BETA-UNSATURATED KETONES (1975) (0)
Via Tin Reagents (2005) (0)
For the Substitution of Epoxides (2005) (0)
Iridium-Catalyzed ortho-C—H Borylation of Aryl Ketones with Bis(pinacolato)diboron. (2012) (0)
Rhodium‐Catalyzed Addition of Arylboronic Acids to N‐Sulfonyl Aldimines. (2001) (0)
Metal-Catalyzed C—C and Carbon—Heteroatom Bond Formation (2005) (0)
THE REACTION OF COPPER(I) METHYLTRIALKYLBORATES WITH ETHYL β-BROMOACRYLATES. STEREOSPECIFIC SYNTHESIS OF (E)- AND (Z)-α,β-UNSATURATED ACID ESTERS FROM ORGANOBORANES (1977) (0)
The Palladium-Catalyzed Cross-Coupling Reaction of Enol Acetates of . alpha.-Bromo Ketones with 1-Alkenyl-, Aryl-, or Alkylboron Compounds. A Facile Synthesis of Ketones and Their Enol Acetates. (1993) (0)
Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated N-Acylamides Catalyzed by Dicationic Palladium(II)-(S,S)-Chiraphos Complex. (2008) (0)
Stereo- and Regiospecific Synthesis of Trisubstituted Alkenes via the Palladium-Catalyzed Cross-Coupling Reaction of Diisopropyl (E)-(1-Alkyl-1-alkenyl)boronates with Organic Halides. (1987) (0)
Discussion Addendum for: Palladium‐Catalyzed Reaction of 1‐Alkenylboronates with Vinylic Halides: (1Z,3E)‐1‐Phenyl‐1,3‐Octadiene (2012) (0)
Copper-Mediated C—C Bond Formation (2005) (0)
Iridium-Catalyzed Borylation of Arenes and Heteroarenes via C—H Activation (2007) (0)
Palladium-Catalyzed Iminocarbonylative Cross-Coupling Reaction Between Haloarenes, tBuNC, and 9-Alkyl-9-BBN Derivatives. Synthesis of Alkyl Aryl Ketones. (1993) (0)
THE SYNTHESIS OF METHOXYCYCLOPROPANES VIA THE TREATMENT OF ATE-COMPLEXES OBTAINED FROM B-ALKYL-9-BORABICYCLO(3.3.1)NONANES AND LITHIUM METHOXYALLENE WITH ACETIC ACID (1980) (0)
REACTIONS OF CUPROUS METHYLTRIALKYLBORATES OBTAINABLE FROM TRIALKYLBORANES WITH ACRYLONITRILE, ETHYL ACRYLATE, AND 1-ACYL-2-VINYLCYCLOPROPANE. CONVENIENT SYNTHESES OF NITRILES, CARBOXYLIC ESTERS AND Γ,Δ-UNSATURATED KETONES (1976) (0)
Palladium‐Catalyzed Cross‐Coupling Reaction of Bis(pinacolato)diboron with 1‐Alkenyl Halides or Triflates: Convenient Synthesis of Unsymmetrical 1,3‐Dienes via the Borylation‐Coupling Sequence. (2002) (0)
Borylation of Aryl, Vinyl, and Allyl Halides (2005) (0)
Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. (2004) (0)
A Sequence of Palladium-Catalyzed Borylation of Allyl Acetates with Bis(pinacolato)diboron and Intramolecular Allylboration for the Cyclization of Oxo-2-alkenyl Acetates. (1997) (0)
Double‐Coupling of Dibromo Arenes with Aryltriolborates for Synthesis of Diaryl‐Substituted Planar Frameworks. (2012) (0)
Rhodium-Catalyzed Addition Reactions (2005) (0)
Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates. (2003) (0)
Stereo‐ and Regiospecific Syntheses to Provide Conjugated (E,Z)‐ and (Z,Z)‐Alkadienes, and Arylated (Z)‐Alkenes in Excellent Yields via the Palladium‐Catalyzed Cross‐Coupling Reactions of (Z)‐1‐Alkenylboronates with 1‐Bromoalkenes and Aryl Iodides. (1986) (0)
Mechanism of the photoinduced rearrangement of 5.ALPHA.-androstan-17.BETA.-ol hypoiodite to 13.ALPHA.- and 13.BETA.-formyloxy-16-iodo-13,16-seco-D-nor-5.ALPHA.-androstane in the presence of HgO and I2 - An 18O labeling study. (1983) (0)
Synthesis and Cycloaddition of 2‐(Dialkoxyboryl)‐1,3‐butadiene. (1993) (0)
Stereoselective Preparation of γ-Alkoxyallylboronates via Catalytic Isomerization of Pinacol ((E)-3-Alkoxy-1-propenyl)boronates. (1995) (0)
Acceleration Effect of Lewis Acid in Allylboration of Aldehydes: Catalytic Regiospecific, Diastereospecific, and Enantioselective Synthesis of Homoallyl Alcohols. (2003) (0)
A process for preparing vonhexaalkylborazin (2005) (0)
Vinylic Organoboranes. Part 1. A Convenient Synthesis of Acetylenes via the Reaction of Lithium (1-Alkynyl)organoborates with Iodine. (1987) (0)
STEREOSPECIFIC SYNTHESIS OF (2Z,4E,6E)-3,7,11-TRIMETHYL-2,4,6,10-DODECATETRAENE (TRANS(C10)-ALLOFARNESENE) (1982) (0)
1,4‐Additions of Arylboron, ‐Silicon, and ‐Bismuth Compounds to α,β‐Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium(II) Complexes (2008) (0)
By Palladium-Catalyzed Coupling of Diboranes (2005) (0)
Enantioselective Ruthenium(II)-Catalyzed Aldehyde Arylations (2009) (0)
Synthesis of Allylboronates via the Palladium(0)‐Catalyzed Cross‐ Coupling Reaction of Bis(pinacolato)diboron with Allylic Acetates. (1997) (0)
LITHIUM THIOALKYNOLATES AND ITS REACTION WITH CARBONYL COMPOUNDS (1980) (0)
Rhodium- or Iridium-Catalyzed trans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds. (2000) (0)
Palladium-Catalyzed Cross-Coupling Reactions in Organic Syntheses (2011) (0)
THE REACTIONS OF ORGANOBORANES AND LITHIUM DIALKYLCUPRATES WITH 1-ACYL-2-VINYLCYCLOPROPANES, A CONVENIENT NEW ROUTE TO GAMMA,DELTA-UNSATURATED KETONE SYNTHESIS (1975) (0)
Development of Novel Adsorbents for Selective Removal of Glycosylated LDL(New Adsorbent and Technical Development,General Presentation) (1996) (0)
Nickel Acetylacetonate-Induced 1,4-Additions of 1-Alkenyl(disiamyl) boranes to α,β-Unsaturated Ketones, Esters and Nitriles. (1996) (0)
ChemInform Abstract: Cross-Coupling Reaction of Organoboron Compounds via Base-Assisted Transmetalation to Palladium(II) Complexes. (2002) (0)
Discussion Addendum for: Palladium(0)‐Catalyzed Reaction of 9‐Alkyl‐9‐Borabicyclo[3.3.1]Nonane with 1‐Bromo‐1‐Phenylthioethene: 4‐(3‐Cyclohexenyl)‐2‐Phenylthio‐1‐Butene (2012) (0)
Nucleophilic Borylation of Benzyl Halides with Bis(pinacolato)diboron Catalyzed by Palladium(0) Complexes. (2002) (0)
(2R,3R)‐2,3‐Bis(diphenylphosphino)butane (2014) (0)
Synthesis of Organoboron Compounds via the Transition Metal‐Catalyzed Addition and Coupling Reaction of (Alkoxo)diborons (2001) (0)
C—C Bond Formation via the Boron-Mannich Reaction (2005) (0)
Iridium-Catalyzed ortho-Borylationof Benzoate Esters with Bis(pinacolato)diboron (2010) (0)
For the Rearrangement of Epoxides (2005) (0)
Asymmetric Cross-Coupling of Potassium 2-Butenyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/Josiphos Complex. (2007) (0)
Stereoselective Synthesis of Exocyclic Alkenes via Hydroboration-Cross- Coupling Sequence. (1992) (0)
Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls. (2010) (0)
Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with Vinyl Triflates β-Substituted by a Carbonyl Group: Efficient Synthesis of β-Boryl-α,β-unsaturated Carbonyl Compounds and Their Synthetic Utility. (2004) (0)
A Stereoselective Route to Alkenyl Sulfides (V), (VIII) Through the Palladium‐Catalyzed Cross‐Coupling Reaction of 9‐Alkyl‐9‐BBN (III) with 1‐Bromo‐1‐phenylthioethene (VII) or E‐ and Z‐2‐Bromo‐1‐phenylthio‐1‐alkenes (IV). (1989) (0)
Stereoselective Synthesis of Conjugated 2,4-Alkadienoates via the Palladium-Catalyzed Cross-Coupling of 1-Alkenylboronates with 3-Bromo-2-alkenoates. (1990) (0)
Iridium-Catalyzed Dimerization of Terminal Alkynes to (E)-Enynes, (Z)-Enynes, or 1,2,3-Butatrienes. (2000) (0)
Synthesis of Tetra-ortho-Substituted Biaryls Using Aryltriolborates. (2011) (0)
Asymmetric Hydrogenation of 1-Phenylethenylboronic Acid and Esters for the Synthesis of Chiral Organoboron Compounds. (2010) (0)
1,4-Addition of Arylsiloxanes to Enones Catalyzed by Dicationic Palladium(II) Complexes in Aqueous Media. (2003) (0)
Platinum(0)‐Catalyzed Diboration of Methylenecyclopropanes with Bis(pinacolato)diboron: A Selective Route to 2,4‐Bis(boryl)‐1‐butenes. (2000) (0)
Platinum(0)‐Catalyzed Diboration of Allenes with Bis(pinacolato)diboron. (1998) (0)
Asymmetric 1,4‐Addition of Potassium Aryltrifluoroborates [ArBF3]K to Enones Catalyzed by Dicationic Palladium(II) Complexes. (2005) (0)
Synthesis of Oxo-2-alkenylboronates and Their Cyclization to 3- Methylene Cycloalkanols via Intramolecular Allylboration. (1994) (0)
Synthesis of Optically Pure 2-Substituted 1,3-Propanediol Spiroacetal Derivative of l-Menthone via Hydroboration-Coupling Sequence. (1993) (0)
Inter- and Intramolecular Additions of 1-Alkenylboronic Acids or Esters to Aldehydes and Ketones Catalyzed by Rhodium(I) Complexes in Basic, Aqueous Solutions. (2003) (0)
Cross-Coupling Reaction of Alkyl- or Arylboronic Acid Esters, e.g. (I), (VI), (IX), with Organic Halides, e.g. (II), (VII), (X), Induced by Thallium(I) Salts and Palladium Catalyst. (1990) (0)
Synthesis of Functionalized 1‐Alkenylboronates via Hydroboration‐ Dealkylation of Alkynes with Diisopinocampheylborane. (1994) (0)
Palladium-Catalyzed Enantioselective Synthesis of 4-Aryl-4H-chromenes (2007) (0)
CCDC 720032: Experimental Crystal Structure Determination (2009) (0)
REGIOSELECTIVE CLEAVAGE OF ARYL DECYL ETHERS WITH ALKALI METALS (1976) (0)
Intramolecular Allylboration of γ‐(ω‐Formylalkoxy)allylboronates for Syntheses of trans‐ or cis‐2‐(Ethenyl)tetrahydropyran‐3‐ol and 2‐(Ethenyl)oxepan‐3‐ol. (2003) (0)
Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross‐Metathesis Between Pinacol Allylboronate and Terminal or Internal Alkenes. (2002) (0)
Tandem Conjugate Addition—Aldol Cyclization to Give Optically Active 1‐Aryl‐1H‐indenes via Asymmetric Pd2+‐Catalyzed 1,4‐Addition of Arylboronic Acids. (2008) (0)
Copper-Catalyzed C—O, C—S, and C—N Bond Formation (2005) (0)
Protection, Chromatographic Separations, and Analysis of Diols (2005) (0)
Platinum(0)‐Catalyzed Diboration of Alkynes. (1994) (0)
Stereoselective Isomerization of Unsymmetrical Diallyl Ethers to Allyl (E)-Vinyl Ethers by a Cationic Iridium Catalyst. (2000) (0)
Olefination and Hydroxymethylation of Aldehydes Using Knochel′s ( Dialkoxyboryl)methylcopper Reagents. (1996) (0)
Recognition of Sugar Molecules (2005) (0)
Stereoselective Synthesis of (Z)‐(1‐Organo‐1‐alkenyl)boronic Esters by the Palladium‐Catalyzed Cross‐Coupling Reaction of (Z)‐(1‐Iodo‐1‐ alkenyl)boronic Esters with Organozinc Reagents. (1994) (0)
Platinum(0)‐Catalyzed Diboration of Alka‐1,3‐dienes with Bis( pinacolato)diboron. (1997) (0)
Rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated amides. (2001) (0)
Diboration of Alkenes with Bis(pinacolato)diboron Catalyzed by a Platinum(0) Complex. (1997) (0)
For Diels–Alder Reactions (2005) (0)

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What Schools Are Affiliated With Norio Miyaura?

Norio Miyaura is affiliated with the following schools:

Hokkaido University