Paul Grieco
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American chemist
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Chemistry
Paul Grieco's Degrees
- Bachelors Chemistry University of California, Berkeley
Why Is Paul Grieco Influential?
(Suggest an Edit or Addition)According to Wikipedia, Paul Grieco is an organic chemist at Montana State University. His research focuses on the total synthesis of natural products and the study of solvent effects in various organic reactions. He has received several awards for his work, including the American Chemical Society Arthur C. Cope Scholar Award in 1990 and the ACS Award for Creative Work in Synthetic Organic Chemistry in 1991. Among his contributions are two name reactions: the Grieco elimination and the Grieco three-component condensation.
Paul Grieco's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Organic synthesis in water (1998) (705)
- Pyridinium p-toluenesulfonate. A mild and efficient catalyst for the tetrahydropyranylation of alcohols (1977) (649)
- Organoselenium chemistry. A facile one-step synthesis of alkyl aryl selenides from alcohols (1976) (492)
- Dramatic rate accelerations of Diels-Alder reactions in 5 M lithium perchlorate-diethyl ether: the cantharidin problem reexamined (1990) (253)
- One-pot synthesis of symmetrical and unsymmetrical bisarylethynes by a modification of the sonogashira coupling reaction. (2002) (222)
- Aza Diels-Alder reactions in aqueous solution: cyclocondensation of dienes with simple iminium salts generated under Mannich conditions (1985) (218)
- Role reversal in the cyclocondensation of cyclopentadiene with heterodienophiles derived from aryl amines and aldehydes: synthesis of novel tetrahydroquinolines (1988) (154)
- Methods for the Synthesis of a-Methylene Lactones (1975) (145)
- “Micellar” catalysis in the aqueous intermolecular diels-alder reaction: rate acceleration and enhanced selectivity (1983) (142)
- A mild two-step method for the hydrolysis of lactams and secondary amides (1983) (136)
- Cyclopentenones. Efficient synthesis of cis-jasome (1972) (110)
- AQUEOUS INTERMOLECULAR DIELS-ALDER CHEMISTRY: REACTIONS OF DIENE CARBOXYLATES WITH DIENOPHILES IN WATER AT AMBIENT TEMPERATURE (1983) (109)
- Sesquiterpene lactones: total synthesis of (+/-)-vernolepin and (+/-)-vernomenin. (1977) (104)
- Aryl selenocyanates and aryl thiocyanates: reagents for the preparation of activated esters (1978) (96)
- Convergent, enantiospecific total synthesis of the novel cyclodepsipeptide (+)-jasplakinolide (jaspamide) (1988) (93)
- [1,3]-Sigmatropic rearrangement of allyl vinyl ethers at ambient temperature in 3.0 M lithium, perchlorate-diethyl ether (1991) (88)
- Biomimetic total synthesis of pseudotabersonine : a novel oxindole-based approach to construction of Aspidosperma alkaloids (1993) (86)
- Organoselenium chemistry. .alpha.-Phenylseleno lactones. New general route to the synthesis of fused .alpha.-methylene lactones (1974) (83)
- Immonium ion based synthetic methodology: a novel method for the N-methylation of dipeptides and amino acid derivatives via retro aza Diels-Alder reactions (1987) (81)
- Water as a solvent for the Claisen rearrangement: practical implications for synthetic organic chemistry (1989) (80)
- LiAl(OC(Ph)(CF3)2)4: A Hydrocarbon-Soluble Catalyst for Carbon−Carbon Bond-Forming Reactions (1996) (77)
- Synthetic studies on quassinoids: total synthesis of (-)-chaparrinone, (-)-glaucarubolone, and (+)-glaucarubinone (1993) (70)
- Reactions of allylsilanes with simple iminium salts in water: a facile route to piperidines via an aminomethano desilylation-cyclization process (1986) (69)
- Effect of polar solvents on the rates of Claisen rearrangements: assessment of ionic character (1989) (68)
- Alkylation of the dianion of .beta.-keto phosphonates. Versatile synthesis of dimethyl (2-oxoalkyl)phosphonates (1973) (68)
- Cycloalkenone synthesis via Lewis acid-catalyzed retro Diels-Alder reactions of norbornene derivatives: synthesis of 12-oxophytodienoic acid (12-oxoPDA) (1989) (66)
- One-step conversion of protected lactols into lactones (1978) (66)
- Remote double bond migration via rhodium catalysis: a novel enone transposition (1976) (62)
- Total synthesis of (+)-costunolide (1977) (61)
- Aza Diels-Alder reactions in water: Cyclocondensation of C-acyl iminium ions with cyclopentadiene (1986) (59)
- Complete transfer of chirality in the [3,3]-sigmatropic rearrangement of allylic acetates catalyzed by palladium(II). Application to stereocontrolled syntheses of prostaglandins possessing either the C-15(S) or C-15(R) configuration (1980) (58)
- General 1,5-diene synthesis. Application to the synthesis of squalene (1974) (56)
- Macrolide antibiotics. 1. Total synthesis of the Prelog-Djerassi lactone and methynolide (1979) (56)
- A nano-scale barrel and cube: transition metal-mediated self-assembly of CpCoCb-derived ligand scaffolds. (2001) (53)
- N-Phenylselenophthalimide. A useful reagent for the facile transformation of (1) carboxylic acids into either selenol esters or amides and (2) alcohols into alkyl phenyl selenides (1981) (52)
- STEREOCONTROLLED TOTAL SYNTHESIS OF ANTIBIOTIC A-23187 (CALCIMYCIN) (1982) (51)
- Chelation controlled addition of allylstannanes to aldehydes in lithium perchlorate-diethyl ether (1992) (51)
- Total synthesis of lupeol (1971) (51)
- Lithium perchlorate catalyzed conjugate addition of o-silylated ketene acetals to hindered α,β-unsaturated carbonyl compounds at atmospheric pressure (1991) (50)
- Retro aza Diels-Alder reactions: acid catalyzed heterocycloreversion of 2-azanorbornenes in water at ambient temperature (1987) (49)
- Intramolecular variants of aminomethano desilylation: Reactions of in situ generated immonium ions with allylsilanes (1986) (47)
- Organoselenium chemistry. Epoxidation of olefins with benzeneseleninic acid and hydrogen peroxide ("benzeneperoxyseleninic acid") (1977) (47)
- Remote oxidation of unactivated carbon-hydrogen bonds in steroids via oxometalloporphinates (1990) (45)
- Functionalization of unactivated carbon-hydrogen bonds in steroids via (salen)manganese(III) complexes (1993) (44)
- Quinolizidine synthesis via intramolecular immonium ion based Diels-Alder reactions. Total synthesis of (.+-.)-lupinine, (.+-.)-epilupinine, (.+-.)-cryptopleurine, and (.+-.)-julandine (1988) (43)
- Quassinoids: total synthesis of dl-quassin (1984) (43)
- Bicyclo[2.2.1]heptanes as intermediates in the synthesis of steroids. Total synthesis of estrone (1980) (42)
- An intramolecular immonium ion variation of the Diels-Alder reaction: synthesis of (.+-.)-dihydrocannivonine (1986) (41)
- Organocopper chemistry. Reactions of lithium dialkylcopper reagents with activated vinylcyclopropanes. Instance of 1,7 addition (1973) (41)
- Synthesis of allylic halides and 1,5-dienes from allylic alcohols (1969) (41)
- Intramolecular Imino Diels−Alder Reaction of a 3-Vinyl Indole: Application to a Total Synthesis of (±)-Eburnamonine (1999) (40)
- Total synthesis of (–)-epothilone B (1998) (40)
- Aqueous intermolecular diels-alder chemistry : Reaction of (e)-2,4-pentadienyl ammonium chloride and related ammonium salts with dienophiles in water (1986) (39)
- Pseudoguaianolides. Stereospecific total synthesis of (.+-.)-ambrosin, (.+-.)-damsin, and (.+-.)-psilostachyin C (1977) (39)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. III. Formation of the bicyclo[2.2.1]heptane system (1969) (39)
- Convergent, enantiospecific total synthesis of the hypocholesterolemic agent (+)-compactin. (1986) (39)
- CARBOCYCLIC RING CONSTRUCTION VIA AN INTRAMOLECULAR DIELS-ALDER REACTION OF AN IN SITU-GENERATED, HETEROATOM-STABILIZED ALLYL CATION : TOTAL SYNTHESIS OF ()-LYCOPODINE (1998) (35)
- Alkaloid Synthesis via Intramolecular Imino Diels-Alder Chemistry: Total Synthesis of (.+-.)-Eburnamonine (1994) (34)
- Total synthesis of (.+-.)-bruceantin (1993) (34)
- Intramolecular Reactions of Diazocarbonyl Compounds (1980) (34)
- Elaboration of the C(3)-C(12) carbon fragment of calcimycin (A-23187). Formal total synthesis of calcimycin (1980) (33)
- Proteomic analysis of Sulfolobus solfataricus during Sulfolobus Turreted Icosahedral Virus infection. (2012) (33)
- Sesterterpenes. I. Stereospecific total synthesis of moenocinol (1975) (33)
- Total synthesis of the mixed peptide-polypropionate based cyclodepsipeptide (+)-geodiamolide b (1988) (32)
- Lithium catalyzed hetero Diels-Alder reactions cyclocondensation of N-protected α-amino aldehydes with 1-methoxy-3-tert-butyldimethylsilyloxybutadiene in the presence of lithium perchlorate (1993) (32)
- Bicyclo[2.2.1]heptanes in organic synthesis. Total synthesis of the 16-membered ring macrolide tylonolide hemiacetal: synthesis and coupling of the C(3)-C(9) and C(11)-C(17) fragments (1982) (32)
- Preparation and lithiation of N-(N,N-dimethylamino)pyrrole: a useful reagent for the preparation of 2-acylpyrroles (1981) (32)
- Synthetic studies on quassinoids: total synthesis of simalikalactone D and assignment of the absolute configuration of the .alpha.-methylbutyrate ester side chain. (1992) (32)
- Total synthesis of the hypocholesterolemic agent (+)-compactin (1983) (31)
- Aryl selenocyanates: useful reagents for cyanoselenenylation of aldehydes (1977) (31)
- (R)-(+)- and (S)-(-)-5-Ethyl-5-methyl-1,3-dioxolane-2,4-dione reagents for the direct preparation of .alpha.-hydroxy-.alpha.-methylbutyrate esters: assignment of the absolute configuration of the .alpha.-acetoxy-.alpha.-methylbutyrate ester side chain of quassimarin via total synthesis (1993) (30)
- Mode of action of the anticancer quassinoids--inhibition of the plasma membrane NADH oxidase. (1998) (30)
- Organoselenium chemistry. General furan synthesis (1975) (30)
- Total synthesis of .beta.-elemenone (1977) (30)
- Reactions of allylstannanes with in situ generated immonium salts in protic solvent: a facile aminomethano destannylation process (1987) (30)
- Anticancer activity of glaucarubinone analogues. (1998) (29)
- Magnesium trifluoromethanesulfonimide(triflimide) promoted substitution reactions of allylic and benzylic acetates. Magnesium triflimide as a substitute for magnesium perchlorate (1997) (29)
- Alkylation of the dianion of .beta.-keto sulfoxides. Versatile synthesis of phenyl (2-oxoalkyl) sulfoxides. General route to ketones, 1,4-diketones, and aldols (1974) (29)
- Octahydroquinoline synthesis via immonium ion based Diels-Alder chemistry: synthesis of (−)-8a-epipumiliotoxin C (1988) (29)
- Isolation of 12-hydroxycaryophyllene-4,5-oxide, a sesquiterpene from Lactarius camphoratus (1981) (28)
- Conversion of ketones into lactones with benzeneseleninic acid and hydrogen peroxide (benzeneperoxyseleninic acid): a new reagent for the Baeyer-Villiger reaction (1977) (28)
- SELECTIVE DEPROTECTION OF ALKYL T-BUTYLDIMETHYLSILYL ETHERS IN THE PRESENCE OF ARYL T-BUTYLDIMETHYLSILYL ETHERS (1999) (28)
- Bicyclo[2.2.1]heptanes in organic synthesis. Stereocontrolled approach to sterol side-chain construction: synthesis of De-AB-cholest-11-en-9-one (1979) (27)
- Global Analysis of Viral Infection in an Archaeal Model System (2012) (27)
- Retro aza Diels-Alder reactions of 2-azanorbornenes: improved methods for the unmasking of primary amines (1990) (27)
- Site-selective hydroxylation of steroids via oxometalloporphinates covalently linked to ring D: introduction of hydroxyl groups into the C(9) and C(12) position of 5.alpha.-androstanes (1991) (27)
- Total synthesis of (.+-.)-eriolanin (1978) (26)
- Sesquiterpene lactones. Total synthesis of (.+-.)-eriolanin and (.+-.)-eriolangin (1980) (26)
- Stereospecific total synthesis of dl-helenalin: a general route to helenanolides and ambrosanolides (1978) (26)
- Stereoselective Trans-trisubstituted olefin synthesis via rearrangement of allylic sulfonium ylides (1973) (26)
- Stereochemistry and total synthesis of (.+-.)-ivangulin (1977) (25)
- Letter: Total synthesis of (+/-)-vernolepin and (+/-)-vernomenin. (1976) (25)
- Construction of Carbocyclic Arrays Containing Nitrogen via Intramolecular Imino Diels−Alder Reactions in Polar Media. A Comparative Study: 5.0 M Lithium Perchlorate−Diethyl Ether versus Water (1999) (25)
- Carbocyclic Ring Construction via Intramolecular Ionic Diels−Alder Reactions of in Situ-Generated, Heteroatom-Stabilized Allyl Cations in Highly Polar Media (1996) (25)
- Total synthesis of dl-sirenin (1969) (25)
- Rotational barriers and conformational studies in 9-arylxanthyl derivatives (1970) (24)
- Trimethylsilylacetic acid dianion: application to organic synthesis (1975) (24)
- Pseudoguaianolides. 1. Stereospecific total synthesis of the ambrosanolides dl-ambrosin and dl-damsin (1982) (24)
- TOTAL SYNTHESIS OF DL-QUASSIN (1980) (24)
- Expanding the paradigm of thiol redox in the thermophilic root of life. (2014) (23)
- Facile retro Diels–Alder reaction of a pentamethyltricyclo[5.2.1.02,6]decenone derivative: synthesis of (+)-15(S)-prostaglandin A2 (1990) (23)
- Synthesis of the highly oxygenated ergostane type steroid (+)-withanolide E (1991) (23)
- Construction of the gem-dimethylcyclopropane unit employing triphenylphosphonium isopropylide (1972) (23)
- Oxabicyclo[3.2.1]octenes in organic synthesis--direct ring opening of oxabicyclo[3.2.1] systems employing silyl ketene acetals in concentrated solutions of lithium perchlorate-diethyl ether: application to the synthesis of the C(19)-C(27) fragment of rifamycin S. (2001) (22)
- Studies directed toward the total synthesis of scytophycin C: Synthesis of the C(1)C(18) fragment of scytophycin C (1998) (22)
- Practical synthesis of .alpha.-methylene-.gamma.-butyrolactone (1974) (22)
- Acid catalyzed intramolecular Diels-Alder reactions in lithium perchlorate-diethyl ether: Enhanced reaction rates and diastereoselectivity (1994) (21)
- Model studies directed toward the total synthesis of vernolepin. III. Synthesis of the alpha-methylene-delta-valerolactone ab ring model. (1975) (21)
- Brønsted acid catalysed electrophilic substitution of indole by allylic alcohols in lithium perchlorate-diethyl ether : application to the total synthesis of Yuehchukene (1993) (20)
- Novel esters of glaucarubolone as inducers of terminal differentiation of promyelocytic HL-60 cells and inhibitors of 7,12-dimethylbenz[a]anthracene-induced preneoplastic lesion formation in mouse mammary organ culture. (2001) (20)
- Lithium cobalt-bis-dicarbollide catalyzed substitution reactions of allylic acetates (1996) (20)
- .beta.-Lactam antibiotics: a formal stereocontrolled total synthesis of (.+-.)-thienamycin (1984) (20)
- Total synthesis of racemic 12-methylprostaglandins. (1977) (20)
- Synthesis of mono- and bifunctional alpha-methylene lactone systems as potential tumor inhibitors. (1977) (20)
- Synthetic applications of phenylthio[(.alpha.-diethoxymethyl)vinyl] cuprate and (.alpha.-diethoxymethyl)vinylcopper (1976) (20)
- Fluoroprostaglandins: total synthesis of (+)-13-fluoroprostaglandin F2α methyl ester (1985) (20)
- A short synthesis of dl-epi-pyroangolensolide and dl-pyroangolensolide: confirmation of the structures of pyroangolensolide and calodendrolide (1985) (20)
- Fluoroprostaglandins: synthesis of (.+-.)-10.beta.-fluoroprostaglandin F2.alpha. methyl ester (1979) (20)
- .alpha.-Methylene lactones. VIII. Blocking and deblocking of .alpha.-methylene-.gamma.-butyrolactones (1975) (19)
- Direct substitution of secondary allylic alcohols with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether - An alternative to the [1,3] sigmatropic rearrangement of allyl vinyl ethers (1992) (19)
- 2-Azonianorbornene-2-spiro-1′ -aziridinium triflate - a novel ethylene immonium ion equivalent: Application to a synthesis of physostigmine (1992) (19)
- Glaucarubolone and Simalikalactone D, Respectively, Preferentially Inhibit Auxin‐Induced and Constitutive Components of Plant Cell Enlargement and the Plasma Membrane NADH Oxidase (1999) (19)
- Oxabicyclo[3.2.1]octenes in organic synthesis: direct ring opening of oxabicyclo[3.2.1] ring systems with diisobutylaluminum hydride and a silyl ketene acetal--synthesis of the chiral C(19)-C(26) and C(27)-C(32) fragments of Scytophycin C. (2002) (19)
- A new strategy for the preparation of 11-oxygenated steroids synthesis of (±)-adrenosterone (1998) (19)
- Stereospecific synthesis of (+-)-(E)-nuciferol via the [2,3]-sigmatropic rearrangement of allytlic sulfoxides (1973) (19)
- Sodium 6-methoxy-(E,E)-3,5-hexadienoate: a useful diene in the aqueous diels-alder reaction (1985) (19)
- C19 QUASSINOIDS : TOTAL SYNTHESIS OF DL-SAMADERIN B (1994) (18)
- Prostaglandins. A total synthesis of (plus or minus)-11,15-dideoxy-PGE2 and (plus or minus)-11-deoxy-PGE2 methyl ester. (1973) (18)
- Total synthesis of the highly oxygenated quassinoid (.+-.)-klaineanone (1988) (18)
- Deoxyvernolepin. A cytotoxic vernolepin prototype. (1977) (18)
- Lithium Cobalt-Bis-Dicarbollide: A Novel Lewis Acid Catalyst for the Conjugate Addition of Silyl Ketene Acetals to Hindered .alpha.,.beta.-Unsaturated Carbonyl Compounds (1994) (18)
- Ring-fluorinated prostaglandins: total synthesis of (.+-.)-10.alpha.-fluoroprostaglandin F2.alpha. methyl ester (1979) (18)
- Synthesis of the Valeriana waalichi hydrocarbon sesquifenchene. Route to specifically functionalized 7,7-disubstituted bicyclo[2.2.1]heptane derivatives (1975) (17)
- Acid catalyzed intramolecular Diels-Alder reactions in lithium perchlorate-diethyl ether: Acid promoted migration of terminal dienes prior to [4+2] cycloaddition in conformationally restricted substrates (1994) (17)
- Aqueous intermolecular Diels-Alder chemistry: vernolepin revisited (1984) (17)
- Total synthesis of (±)-sesbanimide A and B (1992) (17)
- Synthetic studies on quassinoids: total synthesis of (.+-.)-chaparrinone (1990) (17)
- Fluoroprostaglandins: synthesis and biological evaluation of the methyl esters of (+)-12-fluoro-, (-)-ent-12-fluoro-, (+)-15-epi-fluoro-, and (-)-ent-15 epi-12-fluoroprostaglandin F2 alpha. (1980) (16)
- Organoselenium chemistry II. A method for the protection of α-methylene lactones (1974) (16)
- Quassinoids: total synthesis of dl-castelanolide (1984) (16)
- Direct conversion of carboxylic acids into amides (1979) (16)
- .alpha.-Methylene lactones. IX. Oxygenated .alpha.-methylene-.gamma.-butyrolactones (1975) (15)
- Polyandrol, a C19 quassinoid from Castela polyandra. (1995) (15)
- ?-Hydroxymethylation of ?- and ?-lactones: a new synthesis of ?-methylene-?-butyrolactones (1972) (15)
- Structure, absolute configuration, and synthesis of stramonin-B, a new cytotoxic pseudoguaianolide (1978) (15)
- Model studies in the quassimarin series: total synthesis of de-A-quassimarin (1987) (15)
- ORGANOSELENIUM CHEMISTRY, A GENERAL FURAN SYNTHESIS (1975) (15)
- A new method for exclusive α-methylenation of fused γ-butyrolactones pyrolysis of α-phenylsulfinyl lactones (1974) (15)
- Rhodium-catalyzed migration of double bonds: preparation of substituted phenols and anilines (1978) (15)
- Nb(OCH(CF3)2)6−: prototype for a new class of weakly coordinating anions based on polyfluoroalkoxide substituents (1997) (15)
- Aqueous intermolecular diels-alder chemistry: novel products derived from substituted benzoquinone-diene carboxylate adducts via tandem Michael reactions (1984) (15)
- Model studies directed toward the total synthesis of vernolepin: construction of the α-methylene-δ-lactone portion of vernolepin. (1973) (15)
- C(14)-fluorinated prostaglandins: synthesis and biological evaluation of the methyl esters of (+)-14-fluoro-, (+)-15-epi-14-fluoro-, (+)-13(E)-14-fluror-, and (+)-13(E)-15-epi-14-fluoroprostaglandin F2 alpha. (1980) (15)
- Quassinoids from the twigs and thorns of Castela polyandra. (1999) (14)
- Conversion of S-phenylsulfonylcysteine residues to mixed disulfides at pH 4.0: utility in protein thiol blocking and in protein-S-nitrosothiol detection. (2014) (14)
- Methods for the conversion of vinyl sulfides to aldehydes (1975) (14)
- Stereochemical consequence of the coupling of lithium dimethylcuprate with a cyclopentenyl allylic lactone. Total synthesis of dl-iridomyrmecin (1981) (14)
- Studies related to the absolute configuration of cyclocinamide A: Total synthesis of 4(R),11(R)-cyclocinamide A (1998) (14)
- ACID CATALYZED IONIC DIELS-ALDER REACTIONS IN CONCENTRATED SOLUTIONS OF LITHIUM PERCHLORATE IN DIETHYL ETHER (1995) (14)
- Cationic [5+2] cycloaddition reactions promoted by trimethylsilyl triflate in highly polar media (1997) (13)
- Stereospecific trisubstituted olefin synthesis via interconversion of allylic sulphoxides and sulphenates (1972) (13)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. IV. Cyclization of 5-methyl-6--(-3-pentenyl)bicyclo(3.1.0)hexan-2-one. (1971) (13)
- C-12 substituted prostaglandins: synthesis and biological evaluation of (.+-.)-12-hydroxyprostaglandin F2.alpha. methyl ester (1978) (13)
- A novel approach to iboga alkaloids: Total synthesis of (±)-ibogamine and (±)-epi-ibogamine (1996) (13)
- SYNTHESIS AND REACTIVITY OF (E)-4,6,7-OCTATRIENOIC ACID SODIUM SALT IN THE AQUEOUS DIELS–ALDER REACTION (1985) (13)
- Pseudoguaianolides. 2. Stereocontrolled total synthesis of the helenanolide dl-helenalin (1982) (13)
- Effect of the quassinoids glaucarubolone and simalikalactone D on growth of cells permanently infected with feline and human immunodeficiency viruses and on viral infections. (1997) (13)
- Studies Relating to the Structure of Bruceoside C: Total Synthesis of the Alleged Aglycon of Bruceoside C (1996) (13)
- Enhanced sensitivity employing zwitterionic and pI balancing dyes (Z-CyDyes) optimized for 2D-gel electrophoresis based on side chain modifications of CyDye fluorophores. New tools for use in proteomics and diagnostics. (2013) (13)
- Synthetic studies on quassinoids: total synthesis of (±)-glaucarubolone and (±)-holacanthone (1992) (13)
- Diels-alder reactions enhanced diastereofacial selectivity in 5.0 M LiClO4-Et2O approach to the construction of the isoindolone nucleus of cytochalasans (1993) (13)
- Synthetic studies on quassinoids: total synthesis of dl-castelanolide (1982) (13)
- A quassinoid (peninsularinone) and a steroid from Castela peninsularis (1994) (12)
- C(12)-Substituted prostaglandins. An enantiospecific total synthesis of (+)-12-fluoromethylprostaglandin F2.alpha. methyl ester (1983) (12)
- A highly efficient route to a key intermediate for the synthesis of prostaglandins (1972) (12)
- Proteomic and Systems Biology Analysis of Monocytes Exposed to Securinine, a GABAA Receptor Antagonist and Immune Adjuvant (2012) (12)
- Diastereoselection in an aqueous Diels-Alder reaction: a formal total synthesis of the Inhoffen-Lythgoe diol (1988) (12)
- Synthesis and biological properties of 12-fluoroprostacyclins (1978) (12)
- Proteomic comparison of near-isogenic barley (Hordeum vulgare L.) germplasm differing in the allelic state of a major senescence QTL identifies numerous proteins involved in plant pathogen defense. (2016) (12)
- Selective trapping of SNO-BSA and GSNO by benzenesulfinic acid sodium salt: mechanistic study of thiosulphonate formation and feasibility as a protein S-nitrosothiol detection strategy. (2013) (12)
- Isolation and structure of stephalic acid, a new clerodane diterpene from Stevia polycephala ☆ (1982) (11)
- REARRANGEMENTS OF ALLYLIC ACETATES CATALYZED BY PALLADIUM(II): AN ENANTIOSPECIFIC SYNTHESIS OF A KEY INTERMEDIATE FOR THE PREPARATION OF 12-HYDROXYPROSTAGLANDINS (1981) (11)
- Chemical transformations in the quassinoid series: Construction of the sensitive hydroxy enone functionality present in the ring A of quassimarin and related quassinoids (1987) (11)
- Synthesis of the C(19)C(32) fragment of scytophycin C via stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminum (1998) (11)
- Dianions of .beta.-ketophosphonates. Two-step synthesis of (+)-ar-turmerone (1973) (11)
- Synthesis of substituted mono- and diazidobenzenes (1967) (11)
- Semiochemicals to enhance herbivory by Diorhabda carinulata aggregations in saltcedar (Tamarix spp.) infestations (2018) (10)
- α-Carboxylation of lactones: a general route to α-methylene lactones (1973) (10)
- An improved route to a key hydroazulenone intermediate for helenanolide synthesis (1980) (10)
- A convenient route to and trisubstituted olefins from geraniol and nerol (1969) (10)
- Helenanolides: stereocontrolled total synthesis of dl-bigelovin, dl-mexicanin I, and dl-linifolin A (1983) (10)
- Application of organoselenium chemistry to the total synthesis of (±)-tuberiferine (1976) (10)
- Gerin, a eudesmane methyl ester in trichome exudates of Geraea viscida (1979) (10)
- Total synthesis of 12-fluoroprostaglandin F2α methyl ester (1976) (10)
- Intramolecular cationic [5 + 2] cycloaddition reactions promoted by trimethylsilyl triflate in 3.0 M lithium perchlorate-ethyl acetate: Application to a formal total synthesis of (±)-isocomene (1997) (10)
- Iminium ions as initiators and allylsilanes as terminators in polyolefin cyclizations: total synthesis of (±)-yohimbone via a vinylogous aminomethano desilylation process (1987) (9)
- TOTAL SYNTHESIS OF 5(R)- AND 5(S)-POLYANDRANE (1999) (9)
- 1-Trimethylsilyloxy-1-cyclopropylethylene: a useful reagent for the preparation of .beta.-cyclopropyl-.alpha.,.beta.-unsaturated ketones (1978) (9)
- Synthetic studies on quassinoids: total synthesis of (.+-.)-shinjulactone C (1990) (9)
- Synthetic Studies on Quassinoids: Total Synthesis and Biological Evaluation of (+)-Des-D-chaparrinone. (1998) (9)
- TOTAL SYNTHESIS OF THE HYPOCHOLESTEROLEMIC AGENT (+)‐COMPACTIN (1983) (9)
- [2,3]-Sigmatropic rearrangements of acetylenic and allenic sulfonium ylides. Synthesis of allenes and conjugated dienes (1974) (9)
- Biochemical consequences of resistance to a recently discovered IMP dehydrogenase inhibitor, benzamide riboside, in human myelogenous leukemia K562 cells. (1996) (9)
- Synthesis of Allylic Sulfones and Their Conversion to Dienoic and Trienoic Acids (1975) (9)
- DIANIONS OF BETA-KETOPHOSPHONATES, A TWO-STEP SYNTHESIS OF (+-)-AR-TURMERONE (2002) (8)
- An Alternate Method for Construction of the Vernolepin AB-Ring System (1975) (8)
- 9-Borabicyclo[3.3.1]nonane induced fragmentation of 2-azanorbornenes: A formal bora-aza retro ene reaction (1993) (8)
- Kinetic enolates of enedione systems related to the Wieland-Miescher ketone (1979) (8)
- Aggregatibacter actinomycetemcomitans biofilm killing by a targeted ciprofloxacin prodrug (2013) (8)
- Helenanolides: total synthesis of dl-bigelovin (1979) (8)
- Biomimetic Total Synthesis of Pseudotabersonine: A Novel Oxindole‐ Based Approach to Construction of Aspidosperma Alkaloids. (1993) (8)
- The reaction of cyclic anhydrides with sodium azide in polar aprotic media (1966) (8)
- Synthetic Studies on Quassinoids: Total Synthesis of Simalikalactone D and Assignment of the Absolute Configuration of the α- Methylbutyrate Ester Side Chain. (1992) (7)
- Synthetic Studies on Quassinoids: Transformation of (−)-Glaucarubolone into (−)-Peninsularinone. In Vivo Antitumor Evaluation of (−)-Glaucarubolone, (−)-Chaparrinone, and (−)-Peninsularinone (1998) (7)
- endo-Dicyclopentadiene Synthesis of (±)-Sesquifenchene and (±)-epi-β-Santalene (1975) (7)
- SYNTHETIC STUDIES ON QUASSINOIDS : SYNTHESIS OF ()-SHINJUDILACTONE AND ()-13-EPI-SHINJUDILACTONE (1998) (7)
- Studies on the acid-catalyzed opening of non-rigid: acylcyclopropanes: a dramatic solvent effect. A route to the bicyclo[2.2.1]heptane ring system (1974) (7)
- Drug-antibody conjugates with anti-HIV activity. (1999) (7)
- Letter: The total synthesis of (plus or minus)-diumycinol. (1975) (7)
- TOTAL SYNTHESIS OF ENDIANDRIC ACID A VIA AN INTRAMOLECULAR DIELS-ALDER STRATEGY (1997) (7)
- Baeyer-Villiger oxidation promoted by reaction of peracids with cyclic oxocarbenium ions generated in situ from internal hemiketals. (2000) (7)
- Phenylthioacetic acid dianion: latent vinyl, oxiranyl, and acyl carbanion equivalents (1975) (6)
- Dianions of β-keto-sulphoxides. A new general synthesis of vinyl ketones (1974) (6)
- Total synthesis of deoxyvernolepin (1976) (6)
- Synthetic studies on diterpenes from a termite soldier: Total synthesis of (±)-biflora-4,10(19),15-triene (1986) (6)
- Synthetic studies on highly oxygenated quassinoids: Total synthesis of (±)-14β,15β-dihydroxyklaineanone (1996) (6)
- Total synthesis of 12-methylprostaglandin A2 (1975) (6)
- Proteomic and Systems Biology Analysis of the Monocyte Response to Coxiella burnetii Infection (2013) (6)
- Non-quassinoid constituents from the twigs and thorns of Castela polyandra. (1999) (6)
- Studies Directed toward the Total Synthesis of Calcimycin (A-23187) (1979) (6)
- 12-Methylprostaglandins total synthesis of 12-methylPGF2α and 12-methylPGE2 (1975) (6)
- Synthetic studies on quassinoids: one-step transformation of .alpha.-hydroxy ketones into O-methyl-protected diosphenols (1981) (6)
- An asymmetric approach to the synthesis of 12-methylprostaglandins (1976) (5)
- Structure and total synthesis of temisin (1978) (5)
- Development of Cationic Diels-Alder Reaction in Highly Polar Media and Total Syntheses of Natural Products (2000) (5)
- C(12)-SUBSTITUTED PROSTAGLANDINS. AN ENANTIOSPECIFIC TOTAL SYNTHESIS OF (+)-12-FLUOROMETHYLPROSTAGLANDIN F2α METHYL ESTER (1984) (5)
- A GENERAL 1,5‐DIENE SYNTHESIS, APPLICATION TO THE SYNTHESIS OF SQUALENE (2002) (5)
- A new method for the conversion of enol phenyl thioethers to ketones (1998) (5)
- Functionalization of Unactivated C-H Bonds in Steroids via (Salen) manganese(III) Complexes. (1994) (5)
- Novel base-induced double epimerization of ethyl 2-endo,3-exo-3-nitro-7-oxabicyclo[2.2.1]heptane-2-carboxylate (1984) (5)
- Synthesis of the highly oxygenated quassinoid shinjulactone D (1991) (4)
- Construction of Carbocyclic Arrays Containing Nitrogen via Intramolecular Imino Diels—Alder Reactions in Polar Media. A Comparative Study: 5.0 M Lithium Perchlorate—Diethyl Ether versus Water. (2000) (4)
- Total synthesis of 12-hydroxymethylprostaglandin F2α methyl ester (1977) (4)
- α-Methylene lactones. VII. A facile route to an oxygenated α-methylene-γ-butyrolactone (1974) (4)
- Cycloalkenone Synthesis via Lewis Acid-Catalyzed Retro-Diels-Alder Reactions of Norbornene Derivatives: Synthesis of 12-Oxophytodienoic Acid. (1990) (4)
- Elaboration of the carbon skeleton of quassinoids synthesis of (1β,9β-1-hydroxypicras-12-en-16-one (1980) (4)
- Functionalized carbocyclic rings via intramolecular Diels-Alder reactions of in situ-generated, γ substituted, heteroatom-stabilized allyl cations in acidic polar media (1999) (4)
- Synthetic studies toward quassinoids: anomalous results from the metal-ammonia reduction of phenanthrenone derivatives (1985) (4)
- Reduction of substituted decalones. Stereochemical reversal in the lithium-ammonia reduction of ketones (1979) (4)
- A General Route to 3-Methyl-6-alkyl-,Δ2-cyclohexenones (1973) (4)
- Macrolide antibiotics: chemical transformations in the tylosin series (1983) (4)
- Fluoroprostaglandins: Total Synthesis of (+)-13-Fluoroprostaglandin F2α Methyl Ester. (1986) (4)
- Site‐Selective Hydroxylation of Steroids via Oxometalloporphinates Covalently Linked to Ring D: Introduction of Hydroxyl Groups into the C(9) and C(12) Position of 5α‐Androstanes. (1991) (4)
- Synthetic studies on quassinoids: construction of the BCE ring system of quassimarin and related natural products (1984) (3)
- Iminium Ion‐Based Diels–Alder Reactions: N‐Benzyl‐2‐Azanorbornene (2003) (3)
- Allylic Chlorides from Allylic Alcohols: Geranyl Chloride (2003) (3)
- Synthesis of 5-alkyl-?2-cyclopentenones and 6-alkyl-?2-cyclohexenones (1975) (3)
- CHEMICAL TRANSFORMATIONS IN THE QUASSINOID SERIES: NOVEL COPPER(II) MEDIATED RING CONTRACTION OF Δ-LACTONES TO Γ-LACTONES. A SYNTHETIC ENTRY INTO THE SAMANDERINS (1985) (3)
- Chemical transformations in the quassinoid series: novel copper(II) mediated ring contraction of .delta.-lactones to .gamma.-lactones. A synthetic entry into the samanderins (1985) (2)
- Synthetic studies on quassinoids: a novel, general method for the elaboration of the C(8),C(13)epoxymethano bridge of quassimarin (1984) (2)
- Geraniol and nerol in organic synthesis. Useful intermediates for the syntheses of C17-juvenile hormone (1972) (2)
- (+/-)-Deoxyvernolepin. A cytotoxic vernolepin prototype. (1977) (2)
- Synthesis and biological evaluation of the methyl esters of (+)-12-fluoro-13,14-dihydroprostaglandin F2alpha and (+)-15-epi-12-fluoro-13,14-dihydroprostaglandin F2alpha. (1981) (2)
- Analysis of plasma proteins using 2D gels and novel fluorescent probes: in search of blood based biomarkers for Alzheimer’s disease (2022) (2)
- SESQUITERPENE LACTONES- TOTAL SYNTHESIS OF (.+-.)-VERNOLEPIN AND (.+-.)-VERNOMENIN (1977) (2)
- Role Reversal in the Cyclocondensation of Cyclopentadiene with Heterodienophiles Derived from Arylamines and Aldehydes: Synthesis of Novel Tetrahydroquinolines. (1989) (2)
- Chemical transformations in the quassinoid series: Construction of the C(8),C(11) bridged hemiketal ring system of chaparrinone and related quassinoids (1989) (2)
- Synthesis of the Highly Oxygenated Ergostane Type Steroid (+)‐ Withanolide E. (1991) (2)
- A MODEL FOR THE ELABORATION OF THE (S)-3-HYDROXY-TRANS-1-OCTENYL SIDE CHAIN OF PROSTANOIDS (1974) (2)
- TOTAL SYNTHESIS OF (.+-.)-VERNOLEPIN AND (.+-.)-VERNOMENIN (1976) (2)
- Total synthesis of -mexicanin I and -linifolin A (1979) (2)
- TOTAL SYNTHESIS OF β-ELEMENONE (1977) (2)
- Oxabicyclo[3.2.1]octenes in Organic Synthesis—Direct Ring Opening of Oxabicyclo[3.2.1] Systems Employing Silyl Ketene Acetals in Concentrated Solution of Lithium Perchlorate—Diethyl Ether: Application to the Synthesis of the C(19)—C(27) Fragment of Rifamycin S. (2001) (2)
- Dramatic Rate Accelerations of Diels-Alder Reactions in 5 M Lithium Perchlorate-Diethyl Ether: The Cantharidin Problem Reexamined. (1990) (2)
- Remarkable stereoselectivity in the reaction of nucleophilic reagents with C(7) carbonyl derivatives of functionalized bicyclo[2.2.1]heptanes (1981) (1)
- Oxabicyclo[3.2.1]octenes in Organic Synthesis: Direct Ring Opening of Oxabicyclo[3.2.1] Ring Systems with Diisobutylaluminum Hydride and a Silyl Ketene Acetal — Synthesis of the Chiral C(19)—C(26) and C(27)—C(32) Fragments of Scytophycin C. (2002) (1)
- (R)‐(+)‐ and (S)‐(‐)‐5‐Ethyl‐5‐methyl‐1,3‐dioxolane‐2,4‐dione Reagents for the Direct Preparation of α‐Hydroxy‐α‐methylbutyrate Esters: Assignment of the Absolute Configuration of the α‐ Acetoxy‐α‐methylbutyrate Ester Side Chain of Quassimarin via Total Synthesis. (1993) (1)
- Total Synthesis of (.+‐.)‐Bruceantin (I). (1993) (1)
- Chelation Controlled Addition of Allylstannanes to Aldehydes in Lithium Perchlorate-Diethyl Ether. (1992) (1)
- A Convergent, Enantiospecific Total Synthesis of the Novel Cyclodepsipeptide (+)-Jasplakinolide (Jaspamide). (1988) (1)
- LiAl(OC(Ph)(CF3)2)4: A Hydrocarbon‐Soluble Catalyst for Carbon‐Carbon Bond‐Forming Reactions. (1997) (1)
- CHEMICAL AND BIOLOGICAL STUDIES ON NEW PROSTANOIDS (1979) (1)
- REDUCTION OF SUBSTITUTED DECALONES. STEREOCHEMICAL REVERSAL IN THE LITHIUM‐AMMONIA REDUCTION OF KETONES (1979) (1)
- Selective Deprotection of Alkyl t-Butyldimethylsilyl Ethers in the Presence of Aryl t-Butyldimethylsilyl Ethers. (1999) (1)
- SYNTHETIC STUDIES ON QUASSINOIDS: A NOVEL, GENERAL METHOD FOR THE ELABORATION OF THE C(8),C(13) EPOXYMETHANO BRIDGE OF QUASSIMARIN (1985) (1)
- OXYGENATED ALPHA-METHYLENE-GAMMA-BUTYROLACTONES (1975) (1)
- Carbocyclic Ring Construction via an Intramolecular Diels—Alder Reaction of an in situ-Generated, Heteroatom-Stabilized Allyl Cation: Total Synthesis of (.+-.)-Lycopodine. (2010) (1)
- Lithium Trifluoromethanesulfonimide in Acetone or Diethyl Ether as a Safe Alternative to Lithium Perchlorate in Diethyl Ether for Effecting Diels-Alder Reactions. Unexpected Influence of the Counterion on Exo/ Endo Selectivity. (1995) (1)
- BICYCLO(2.2.1)HEPTANES AS INTERMEDIATES IN THE SYNTHESIS OF STEROIDS. TOTAL SYNTHESIS OF ESTRONE (1980) (1)
- Synthetic Studies on Quassinoids: Total Synthesis of (.+-.)- Chaparrinone. (1991) (1)
- TOTAL SYNTHESIS OF RACEMIC 12-METHYLPROSTAGLANDINS (1977) (1)
- PROSTAGLANDINS, A TOTAL SYNTHESIS OF (+-)-11,15-DIDEOXY-PGE2 AND (+-)-11-DEOXY-PGE2 METHYL ESTER (1973) (1)
- Magnesium Trifluoromethanesulfonimide(triflimide) Promoted Substitution Reactions of Allylic and Benzylic Acetates. Magnesium Triflimide as a Substitute for Magnesium Perchlorate. (1997) (1)
- SYNTHESIS OF THE VALERIANA WAALICHI HYDROCARBON SESQUIFENCHENE, A ROUTE TO SPECIFICALLY FUNCTIONALIZED 7,7-DISUBSTITUTED BICYCLO(2,2,1)HEPTANE DERIVATIVES (1975) (1)
- Lithium Perchlorate‐Catalyzed Conjugate Addition of O‐Silylated Ketene Acetals to Hindered α,β‐Unsaturated Carbonyl Compounds at Atmospheric Pressure. (1992) (1)
- STUDIES ON THE ACID-CATALYZED OPENING OF NON-RIGID ACYLCYCLOPROPANES, A DRAMATIC SOLVENT EFFECT, A ROUTE TO THE BICYCLO(2,2,1)HEPTANE RING SYSTEM (1974) (1)
- METHODS FOR THE SYNTHESIS OF ALPHA-METHYLENE LACTONES (1975) (1)
- A STEREOSELECTIVE TRANS-TRISUBSTITUTED OLEFIN SYNTHESIS VIA REARRANGEMENT OF ALLYLIC SULFONIUM YLIDES (1973) (0)
- Chemical Transformations in the Quassinoid Series: Construction of the Sensitive Hydroxy Enone Functionality (I) Present in Ring A of Quassimarin and Related Quassinoids. (1987) (0)
- Intramolecular Cationic (5 + 2) Cycloaddition Reactions Promoted by Trimethylsilyl Triflate in 3.0 M Lithium Perchlorate-ethyl Acetate: Application to a Formal Total Synthesis of (.+-.)-Isocomene. (1997) (0)
- SYNTHETIC STUDIES TOWARDS CALCIMYCIN (1981) (0)
- (1,3) Sigmatropic Rearrangement of Allyl Vinyl Ethers at Ambient Temperature in 3.0 M Lithium Perchlorate-Diethyl Ether. (1991) (0)
- Therapeutic quassionoidpræparationer having antineoplastic, antiviral activity and herbistatisk (1995) (0)
- Model Studies in the Quassimarin Series: Total Synthesis of De-A-quassimarin (I). (1988) (0)
- Studies Directed Toward the Total Synthesis of Scytophycin C: Synthesis of the C1—C18 Fragment of Scytophycin C. (1998) (0)
- Functionalized Carbocyclic Rings via Intramolecular Diels—Alder Reactions of in situ Generated, γ Substituted, Heteroatom-Stabilized Allyl Cations in Acidic Polar Media. (2010) (0)
- Total Synthesis of 5(R)- and 5(S)-Polyandrane. (2000) (0)
- Novel transformations in the quassin series (1981) (0)
- FLUOROPROSTAGLANDINS: SYNTHESIS OF (.+-.)-10β-FLUOROPROSTAGLANDIN F2α METHYL ESTER (1979) (0)
- DIANIONS OF BETA-KETO-SULPHOXIDES, A NEW GENERAL SYNTHESIS OF VINYL KETONES (1974) (0)
- Additions and Corrections, "Synthesis of the Valeriana Waalichi Hydrocarbon Sesquifenchene. A Route to Specifically Functionalized 7, 7-Disubstituted Bicyclo(2.2.1)heptane Derivatives." (1975) (0)
- A New Method for the Conversion of Enol Phenyl Thioethers to Ketones. (1998) (0)
- (1β,9β)‐1‐Methoxypicras‐12‐en‐16‐one (1982) (0)
- STEREOSPECIFIC TOTAL SYNTHESIS OF DL-HELENALIN- A GENERAL ROUTE TO HELENANOLIDES AND AMBROSANOLIDES (1978) (0)
- A STEREOSPECIFIC SYNTHESIS OF (+-)-(E)-NUCIFEROL VIA THE (2,3)-SIGMATROPIC REARRANGEMENT OF ALLYLIC SULFOXIDES (1973) (0)
- ALPHA-METHYLENE LACTONES PART 7, A FACILE ROUTE TO AN OXYGENATED ALPHA-METHYLENE-GAMMA-BUTYROLACTONE (1975) (0)
- 50 TOTAL SYNTHESIS OF THE PRELOG-DJERASSI LACTONE AND METHYNOLIDE (1979) (0)
- ALPHA-CARBOXYLATION OF LACTONES, A GENERAL ROUTE TO ALPHA-METHYLENE LACTONES (1973) (0)
- Anomalous Products from the Thermal Diels−Alder Reaction of a (E)-2-Thiophenyl Butadiene Tethered to 3-Methallyl Cyclohexenone (1999) (0)
- Synthetic Studies on Quassinoids: Transformation of (‐)‐Glaucarubolone into (‐)‐Peninsularinone. In vivo Antitumor Evaluation of (‐)‐Glaucarubolone, (‐)‐Chaparrinone, and (‐)‐Peninsularinone. (1998) (0)
- Facile Retro Diels-Alder Reaction of a Pentamethyltricyclo(5.2.1.02,6)decenone Derivative: Synthesis of (+)-15(S)-Prostaglandin A2. (1990) (0)
- Immonium Ion Based Synthetic Methodology: A Novel Method for the N-Methylation of Dipeptides and Amino Acid Derivatives via Retro Aza Diels-Alder Reactions. (1988) (0)
- SYNTHESIS OF 5-ALKYL-DELTA(2)-CYCLOPENTENONES AND 6-ALKYL-DELTA(2)-CYCLOHEXENONES (1975) (0)
- Octahydroquinoline Synthesis via Iminium Ion Based Diels-Alder Chemistry: Synthesis of (-)-8a-Epipumiliotoxin C. (1989) (0)
- Aqueous Intermolecular Diels-Alder Chemistry. Reaction of (E)-2,4-Pentadienyl Ammonium Chloride and Related Ammonium Salts with Dienophiles in Water. (1986) (0)
- A New Strategy for the Preparation of 11-Oxygenated Steroids Synthesis of (.+-.)-Adrenosterone. (1998) (0)
- Synthetic Studies Toward Quassinoids: Anomalous Results from the Metal- Ammonia Reduction of Phenanthrenone Derivatives. (1986) (0)
- CONVERSION OF KETONES INTO LACTONES WITH BENZENESELENIC ACID AND HYDROGEN PEROXIDE. BENZENEPEROXYSELENIC ACID‐ A NEW REAGENT FOR THE BAEYER‐VILLIGER REACTION (1978) (0)
- (±)-6-epi-Eriolanin (1979) (0)
- TOTAL SYNTHESIS OF 12‐FLUOROPROSTAGLANDIN F2α METHYL ESTER (1976) (0)
- Cationic (5 + 2) Cycloaddition Reactions Promoted by Trimethylsilyl Triflate in Highly Polar Media. (1997) (0)
- Alkaloid Synthesis via Intramolecular Imino Diels‐Alder Chemistry: Total Synthesis of (.+‐.)‐Eburnamonine (XV). (1995) (0)
- MODEL STUDIES DIRECTED TOWARD THE TOTAL SYNTHESIS OF VERNOLEPIN PART 3, SYNTHESIS OF THE ALPHA-METHYLENE-DELTA-VALEROLACTONE AB RING MODEL (1975) (0)
- SYNTHETIC APPLICATIONS OF PHENYLTHIO((α-DIETHOXYMETHYL)VINYL) CUPRATE AND (α-DIETHOXYMETHYL)VINYLCOPPER (1976) (0)
- Total Synthesis of Endiandric Acid A via an Intramolecular Diels-Alder Strategy. (1997) (0)
- TOTAL SYNTHESIS OF 14-FLUOROPROSTAGLANDIN F2α AND 14-FLUOROPROSTACYCLIN (1979) (0)
- Therapeutic Quassinoid preparations with antineoplastic, antiviral and herb ista genetic effect (1995) (0)
- A PRACTICAL SYNTHESIS OF ALPHA-METHYLENE-GAMMA-BUTYROLACTONE (1974) (0)
- One‐Pot Synthesis of Symmetrical and Unsymmetrical Bisarylethynes by a Modification of the Sonogashira Coupling Reaction. (2003) (0)
- SESTERTERPENES PART 1, STEREOSPECIFIC TOTAL SYNTHESIS OF MOENOCINOL (1975) (0)
- Studies toward the total synthesis of pentalenic acid by Steven Michael Reister A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science in Chemistry (0)
- 12-METHYLPROSTAGLANDINS TOTAL SYNTHESIS OF 12-METHYLPGF(2ALPHA) AND 12-METHYLPGE2 (1975) (0)
- Water as a Solvent for the Claisen Rearrangement: Practical Implications for Synthetic Organic Chemistry. (1990) (0)
- (2,3)-SIGMATROPIC REARRANGEMENTS OF ACETYLENIC AND ALLENIC SULFONIUM YLIDES, SYNTHESIS OF ALLENES AND CONJUGATED DIENES (1974) (0)
- SYNTHESIS AND BIOLOGICAL EVALUATION OF THE METHYL ESTERS OF (+)-12-FLUORO-13,14-DIHYDROPROSTAGLANDIN F2α AND (+)-15-EPI-12-FLUORO-13,14-DIHYDROPROSTAGLANDIN F2α (1981) (0)
- 9‐Borabicyclo(3.3.1)nonane‐Induced Fragmentation of 2‐Azanorbornenes: A Formal Bora‐Aza Retro Ene Reaction. (1993) (0)
- Retro Aza Diels-Alder Reactions: Acid-Catylyzed Heterocycloreversion of 2-Azanorbornenes in Water at Ambient Temperature. (1988) (0)
- Lithium Cobalt‐bis‐dicarbollide Catalyzed Substitution Reactions of Allylic Acetates. (1997) (0)
- FLUOROPROSTAGLANDINS: SYNTHESIS AND BIOLOGICAL EVALUATION OF THE METHYL ESTERS OF (+)-12-FLUORO-, (-)-ENT-12-FLUORO-, (+)-15-EPI-FLUORO-, AN (-)-ENT-15-EPI-12-FLUOROPROSTAGLANDIN F2α (1981) (0)
- A NEW METHOD FOR EXCLUSIVE ALPHA-METHYLENATION OF FUSED GAMMA-BUTYROLACTONES VIA PYROLYSIS OF ALPHA-PHENYLSULFINYL LACTONES (1974) (0)
- TRIMETHYLSILYLACETIC ACID DIANION, APPLICATION TO ORGANIC SYNTHESIS (1975) (0)
- Quinolizidine Synthesis via Intramolecular Iminium Ion Based Diels-Alder Reactions: Total Syntheses of (.+-.)-Lupinine, (.+-.)-Epilupinine, (.+-.)-Cryptopleurine, and (.+-.)-Jolandine. (1988) (0)
- Lithium‐Catalyzed Hetero‐Diels‐Alder Reactions. Cyclocondensation of N‐ Protected α‐Amino Aldehydes with 1‐Methoxy‐3‐tert‐ butyldimethylsilyloxybutadiene in the Presence of Lithium Perchlorate. (1993) (0)
- Synthetic studies on quassimarin: construction of the pentacyclic carbon skeleton (1987) (0)
- A NOVEL APPROACH TO IBOGA ALKALOIDS : TOTAL SYNTHESIS OF ()-EPI-IBOGAMINE (1996) (0)
- Acid-Catalyzed Ionic Diels-Alder Reactions in Concentrated Solutions of Lithium Perchlorate in Diethyl Ether. (2010) (0)
- CARBON-14 FLUORINATED PROSTAGLANDINS: SYNTHESIS AND BIOLOGICAL EVALUATION OF THE METHYL ESTERS OF (+)-14-FLUORO-, (+)-15-EPI-14-FLUORO-, (+)-13(E)-14-FLUORO-, AND (+)-13(E)-15-EPI-14-FLUOROPROSTAGLANDIN F2α (1981) (0)
- Total Synthesis of a Highly Oxygenated Quassinoid, (.+‐.)‐Klaineanone. (1988) (0)
- SYNTHESIS AND REACTIVITY OF (E)-4,6,7-OCTATRIENOIC ACID SODIUM SALT IN THE AQUEOUS DIELS-ALDER REACTION (1985) (0)
- Synthesis of the C19—C32 Fragment of Scytophycin C via Stereospecific Methylation of γ,δ-Epoxy Acrylates with Trimethylaluminum. (1998) (0)
- RING-FLUORINATED PROSTAGLANDINS: TOTAL SYNTHESIS OF (.+-.)-10α-FLUOROPROSTAGLANDIN F2α METHYL ESTER (1979) (0)
- 2‐Azonianorbornene‐2‐spiro‐1′‐aziridinium Triflate. A Novel Ethylene Immonium Ion Equivalent: Application to a Synthesis of Physostigmine. (2010) (0)
- THE TOTAL SYNTHESIS OF (+-)-DIUMYCINOL (XII) (1975) (0)
- An Intramolecular Immonium Ion Variation of the Diels-Alder Reaction: Synthesis of (.+-.)-Dihydrocannivonine. (1987) (0)
- Acid Catalyzed Intramolecular Diels‐Alder Reactions in Lithium Perchlorate‐Diethyl Ether: Acid Promoted Migration of Terminal Dienes Prior to (4 + 2) Cycloaddition in Conformationally Restricted Substrates. (1995) (0)
- Broensted Acid Catalyzed Electrophilic Substitution of Indole by Allylic Alcohols in Lithium Perchlorate-Diethyl Ether: Application to the Total Synthesis of Yuehchukene. (1993) (0)
- CCR5 Antagonist and Agonist Binding Site Structures (2005) (0)
- Studies Relating to the Structure of Bruceoside C: Total Synthesis of the Alleged Aglycon of Bruceoside C. (1996) (0)
- Diels-Alder Reactions. Enhanced Diastereofacial Selectivity in 5.0 M LiClO4-Et2O Approach to the Construction of the Isoindolone Nucleus of Cytochalasans. (1994) (0)
- Aza Diels-Alder Reactions in Water: Cyclocondensation of C-Acyl lminium Ions with Cyclopentadiene. (1986) (0)
- A GENERAL ROUTE TO 3-METHYL-6-ALKYL-DELTA(2)-CYCLOHEXENONES (1973) (0)
- β-LACTAM ANTIBIOTICS: A FORMAL STEREOCONTROLLED TOTAL SYNTHESIS OF (.+-.)-THIENAMYCIN (1985) (0)
- ELABORATION OF THE CARBON SKELETON OF QUASSINOIDS. SYNTHESIS OF (1β,9β)-1-HYDROXYPICRAS-12-EN-16-ONE (1980) (0)
- SYNTHETIC STUDIES OF QUASSINOIDS: CONSTRUCTION OF THE BCE RING SYSTEM OF QUASSIMARIN AND RELATED NATURAL PRODUCTS (1985) (0)
- Reactions of Allylstannanes with in situ Generated Immonium Salts in Protic Solvent: A Facile Aminomethano Destannylation Process. (1987) (0)
- Direct Substitution of Secondary Allylic Alcohols with O‐Silylated Ketene acetals in 3.0 M Lithium Perchlorate‐Diethyl Ether. An Alternative to the (1.3)Sigmatropic Rearrangement of Allyl Vinyl Ethers. (1993) (0)
- REMARKABLE STEREOSELECTIVITY IN THE REACTION OF NUCLEOPHILIC REAGENTS WITH C(7) CARBONYL DERIVATIVES OF FUNCTIONALIZED BICYCLO(2.2.1)HEPTANES (1981) (0)
- OLEFIN-WECHSELWIRKUNG BEI DER SAEURE-KATALYSIERTEN RINGOEFFNUNG VON ACYLCYCLOPROPANEN 4. MITT. CYCLISIERUNG VON 5-METHYL-6-ENDO-(TRANS-3-PENTENYL)-BICYCLO(3,1,0)HEXAN-2-ON (1971) (0)
- COMPLETE TRANSFER OF CHIRALITY IN THE (3,3)-SIGMATROPIC REARRANGEMENT OF ALLYLIC ACETATES CATALYZED BY PALLADIUM(II). APPLICATION TO STEREOCONTROLLED SYNTHESES OF PROSTAGLANDINS POSSESSING EITHER THE C-15(S) OR C-15(R) CONFIGURATION (1981) (0)
- Retro Aza Diels-Alder Reactions of 2-Azanorbornenes: Improved Methods for the Unmasking of Primary Amines. (1990) (0)
- 1-TRIMETHYLSILYLOXY-1-CYCLOPROPYLETHYLENE- A USEFUL REAGENT FOR THE PREPARATION OF β-CYCLOPROPYL-α,β-UNSATURATED KETONES (1978) (0)
- Synthetic Studies on Quassinoids: Synthesis of (.+-.)-Shinjudilactone and (.+-.)-13-epi-Shinjudilactone. (1999) (0)
- CCR5 and CXCR4 antagonist and agonist binding sites (2006) (0)
- Discovery of plasma protein biomarkers related to Alzheimers disease, sex and APOE genotype. (2020) (0)
- ORGANOSELENIUM CHEMISTRY PART 2, A METHOD FOR THE PROTECTION OF ALPHA-METHYLENE LACTONES (1974) (0)
- CONVERSION OF VINYL SULFIDES TO ALDEHYDES (1976) (0)
- Intramolecular Variants of Aminomethano Desilylation: Reactions of in situ Generated Immonium Ions with Allylsilanes. (1987) (0)
- Lithium Cobalt-Bis-dicarbollide: A Novel Lewis Acid Catalyst for the Conjugate Addition of Silyl Ketene Acetals to Hindered α,β- Unsaturated Carbonyl Compounds. (1995) (0)
- BLOCKING AND DEBLOCKING OF ALPHA-METHYLENE-GAMMA-BUTYROLACTONES (1975) (0)
- Reactions of Allylsilanes with Simple Iminium Salts in Water: A Facile Route to Piperidines via an Aminomethano Desilylation-Cyclization Process. (1986) (0)
- RHODIUM-CATALYZED MIGRATION OF DOUBLE BONDS- PREPARATION OF SUBSTITUTED PHENOLS AND ANILINES (1978) (0)
- SYNTHESIS OF MONO- AND BIFUNCTIONAL α-METHYLENE LACTONE SYSTEMS AS POTENTIAL TUMOR INHIBITORS (1977) (0)
- A Novel Approach to Iboga Alkaloids: Total Synthesis of (.+-.)- Ibogamine and (.+-.)-epi-Ibogamine. (1997) (0)
- Carbocyclic Ring Construction via Intramolecular Ionic Diels‐Alder Reactions of in situ Generated, Heteroatom‐Stabilized Allyl Cations in Highly Polar Media. (1996) (0)
- Studies Related to the Absolute Configuration of Cyclocinamide A: Total Synthesis of 4(R),11(R)-Cyclocinamide A. (2010) (0)
- PHENYLTHIOACETIC ACID DIANION, LATENT VINYL, OXIRANYL, AND ACYL CARBANION EQUIVALENTS (1975) (0)
- Development of Cationic Diels—Alder Reaction in Highly Polar Media and Total Syntheses of Natural Products (2001) (0)
- APPLICATION OF ORGANOSELENIUM CHEMISTRY TO THE TOTAL SYNTHESIS OF (.+-.)-TUBERIFERINS (1976) (0)
- Acid‐Catalyzed Intramolecular Diels‐Alder Reactions in Lithium Perchlorate‐Diethyl Ether: Enhanced Reaction Rates and Diastereoselectivity. (1994) (0)
- BICYCLO(2.2.1)HEPTANES IN ORGANIC SYNTHESIS. STEREOCONTROLLED APPROACH TO STEROL SIDE-CHAIN CONSTRUCTION: SYNTHESIS OF DE-AB-CHOLEST-11-EN-9-ONE (1979) (0)
- C19 Quassinoids: Total Synthesis of dl-Samaderin B. (1995) (0)
- Iminium Ions as Initiators and Allylsilanes as Terminators in Polyolefin Cyclizations: Total Synthesis of (.+-.)-Yohimbone via a Vinylogous Aminomethano Disilylation Process. (1987) (0)
- Intramolecular Imino Diels—Alder Reaction of a 3-Vinyl Indole: Application to a Total Synthesis of (.+-.)-Eburnamonine. (2000) (0)
- Analysis of plasma proteins using 2D gels and novel fluorescent probes: in search of blood based biomarkers for Alzheimer’s disease (2022) (0)
- Synthetic Studies on Quassinoids: Total Synthesis of (-)-Chaparrinone ( VIII), (-)-Glaucarubolone (X), (+)-Glaucarubinone (XII). (1993) (0)
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