Peter B. Hitchcock

Peter B. Hitchcock's AcademicInfluence.com Rankings

Peter B. Hitchcock

Chemistry

#1498

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#2231

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Physical Chemistry

#138

World Rank

#168

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Chemistry

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Peter B. Hitchcock's Published Works

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Published Works

Structural chemistry of 1,2 dilauroyl-DL-phosphatidylethanolamine: molecular conformation and intermolecular packing of phospholipids. (1974) (285)
Hydrogen bonding in imidazolium salts and its implications for ambient-temperature halogenoaluminate(III) ionic liquids (1995) (263)
Preparation and characterization of C60Br6 and C60Br8 (1992) (243)
Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex (2006) (220)
Lanthanum does form stable molecular compounds in the +2 oxidation state. (2008) (176)
Hydrogen-bond acceptor abilities of tetrachlorometalate(II) complexes in ionic liquids (1993) (160)
Calcium-Catalyzed Intermolecular Hydrophosphination (2007) (149)
A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)] (1987) (137)
Synthesis and Structure of a rac‐Tris(divinyldisiloxane) diplatinum(0) Complex and its Reaction with Maleic Anhydride (1991) (134)
Mechanistic studies on the reductive cyclooligomerisation of CO by U(III) mixed sandwich complexes; the molecular structure of [(U(eta-C8H6{Si(i)Pr3-1,4}2)(eta-Cp*)]2(mu-eta1:eta1-C2O2). (2008) (125)
Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex. (2002) (124)
Synthesis and structural characterisation of the first neutral homoleptic lanthanide metal(III) alkyls: [LnR3][Ln = La or Sm, R = CH(SiMe3)2] (1988) (119)
Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation. (2004) (119)
Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex: The X-ray Crystal Structure of [(U (η-C8H6{SiiPr3-1,4}2)(η-C5Me4H)]2(μ-η2: η2-C4O4) (2006) (117)
Subvalent Group 4B Metal Alkyls and Amides. Part 9. Germanium and Tin Alkene Analogues, the Dimetallenes M2R4 (M: Ge or Sn, R: CH(SiMe3)2): X-Ray Structures, Molecular Orbital Calculations for M2H4, and Trends in the Series M2R′4 (M: (1987) (116)
A Monomeric Solvent-Free Bent Lanthanide Dialkyl and a Lanthanide Analog of a Grignard Reagent. Crystal Structures of Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3}I.cntdot.OEt2]2 (1994) (110)
Reductive Cleavage of Dinitrogen by a Vanadium Diamidoamine Complex: the Molecular Structures of [V(Me3SiN\{CH2CH2NSiMe3\}2)( m -N)]2 and K[V(Me3SiN\{CH2CH2NSiMe3)2) m -N)]2 (1999) (109)
Upon the structure of room temperature halogenoaluminate ionic liquids (1986) (109)
Heavier group 2 element catalyzed hydrophosphination of carbodiimides (2008) (108)
Three- and four-co-ordinate, hydrocarbon-soluble-aryloxides of scandium, yttrium, and the lanthanoids; X-ray crystal structure of tris(2,6-di-t-butyl-4-methylphenoxo)scandium (1983) (108)
Zinc Guanidinate Complexes and Their Application in Ring‐Opening Polymerisation Catalysis (2004) (107)
Triazenide complexes of the heavier alkaline earths: synthesis, characterization, and suitability for hydroamination catalysis. (2008) (107)
The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring (1996) (103)
Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex: relevance to catalytic amination. (2003) (103)
Suzuki–Miyaura cross-coupling of aryl and alkyl halides using palladium/imidazolium salt protocols (2004) (101)
Preparation and characterisation of C60(ferrocene)2 (1992) (97)
A Linear Homocatenated Compound Containing Six Indium Centers (2006) (93)
Metal vapor synthesis as a straightforward route to group 10 homoleptic carbene complexes (1999) (91)
A 1,3-diaza-2,4-distannacyclobutanediide: synthesis, structure, and bonding. (2004) (89)
SILYLENENICKEL(0) OR SILYL(SILYLENE)PLATINUM(II) COMPLEXES BY REACTION OF SI(NCH2BUT)2C6H4-1,2 WITH NICL2(PPH3)2, NI(COD)2, OR PTCL2(PPH3)2 (1998) (88)
A mononuclear indium(I) carbene analogue. (2004) (86)
Synthesis, structures and oxidative addition reactions of new thermally stable silylenes; crystal structures of chelates [Si{N(CH2tBu)}2C6H4-1,2] and [(Si{N(CH2tBu)}2C6H4-1,2)(m-E)]2 (E = Se or Te). (1996) (85)
Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2] (1991) (83)
International tables for crystallography volume A. (1988) (81)
Synthesis and Characterisation of N,N′‐Disubstituted 1,2‐phenylenebis(amido)tin(II) Compounds; X‐Ray structures of 1,2‐ and of [1,2‐ (tmeda) (1995) (81)
Higher-nuclearity group 14 metalloid clusters: [Sn(9){Sn(NRR')}(6)]. (2006) (80)
Crystalline (NN)C–M(NN) complexes: synthesis, structure, bonding and lability [M = Si, Ge, Sn or Pb; (NN) = 1,2-(ButCH2N)2C6H4] (2000) (79)
The first structurally characterised solvent-free ς-bonded diorganocalcium, Ca[C(SiMe3)3]2 (1997) (79)
Alkyl derivatives of europium(+2) and ytterbium(+2). Crystal structures of Eu[C(SiMe3)3]2, Yb[C(SiMe3)2(SiMe2CH=CH 2)]I·OEt2 and Yb[C(SiMe3)2(SiMe2OMe)]I·OEt2 (1996) (76)
Organic salts of L-tartaric acid: materials for second harmonic generation with a crystal structure governed by an anionic hydrogen-bonded network (1992) (76)
“Dibutylmagnesium”, a convenient reagent for the synthesis of useful organic magnesium reagents MgA2 including cyclopentadienyls, aryloxides, and amides. Preparation of Zr(C5H5)Cl3. X-ray structure of [{μ-N(SiMe)3C6H4N}(SiMe3)-o(OEt2)]2 (1985) (73)
An improved synthesis of bis(1,3-di- N - tert -butylimidazol-2-ylidene)palladium(0) and its use in C–C and C–N coupling reactions (2001) (72)
Structures of the cephalosporolides B–F, a group of C10 lactones from Cephalosporium aphidicola (1985) (70)
The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst (2002) (70)
Synthesis of C2 and Cs symmetric zinc complexes supported by bis(phosphinimino)methyl ligands and their use in ring opening polymerisation catalysis (2002) (70)
CARBENE COMPLEXES. XXIV: PREPARATION AND CHARACTERIZATION OF TWO ENETETRAMINE-DERIVED CARBENERHODIUM(I) CHLORIDE COMPLEXES RHCL(LR)3 AND RHCL(COD)LR L R=DCN(ME)CU(CH)4CNME-O AND THE PREPARATION AND X-RAY STRUCTURES OF THE ENET ETRAMINE L2R AND ITS SALT L2RBF42 (1994) (68)
A crystalline carbene–silylene adduct 1,2-C6H4[N(R)]2C-Si[N(R)]2C6H4-1,2 (R = CH2But); synthesis, structure and bonding in model compounds† (1999) (67)
Superbasicity of a bis-guanidino compound with a flexible linker: a theoretical and experimental study. (2009) (66)
Synthesis and P-P cleavage reactions of [P(X)X']2; X-ray structures of [Co[P(X)X'](CO)3] and P4[P(X)X']2[X = N(SiMe3)2, X'= NPri2]. (2004) (66)
Synthesis and characterisation of bis(amino)silylene–nickel(0), –palladium(II), –platinum(0), –platinum(II) and copper(I) complexes (2003) (66)
The molecular structures of H2Os3(CO)10, H(SC2H5)Os3(CO)10 and (OCH3)2Os3(CO)10 (1977) (65)
Structural diversity in the coordination of amidines and guanidines to monovalent metal halides. (2004) (64)
Kinetic stability of heteroleptic (beta-diketiminato) heavier alkaline-earth (Ca, Sr, Ba) amides. (2005) (64)
Tris(2,6-di-t-butylphenoxo)yttrium: a three-coordinate hydrocarbon-soluble aryloxide of yttrium (1987) (62)
The first stable transition metal (molybdenum or tungsten) complexes having a metal–phosphorus(III) double bond: the phosphorus analogues of metal aryl- and alkyl-imides; X-ray structure of [Mo(η-C5H5)2(PAr)](Ar = C6H2But3-2,4,6) (1987) (62)
Chemistry, including the X-ray structure, of bis[bis(trimethylsilyl)methylgermanium(II)], R2GeGeR2[R = CH(SiMe3)2], a stable compound having a metal–metal ‘double bond,’ a dimetallene (1984) (62)
Transformation of the bis(trimethylsilyl)methyl into a β-diketinimato ligand; the X-ray structure of [Li(L′L′)]2, SnCl(Me)2(L′L′) and SnCl(Me)2(LL), [L′L′= N(R)C(Ph)C(H)C(Ph)NR, LL = N(H)C(Ph)C(H)C(Ph)NH, R = SiMe3) (1994) (61)
Neutral carbene analogues of the heaviest Group 13 elements: consideration of electronic and steric effects on structure and stability. (2005) (61)
Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry (2003) (61)
Single crystal X-ray structure of benzene-solvated C60 (1992) (60)
Exploration of the Suitability of Bicyclic Guanidinates as Ligands in Catalytic Chemistry Mediated by Titanium (2003) (59)
Carbene complexes: XX. Electron-rich carbeneiron(0) trigonal bipyramidal carbonyls and their germanium(II) and tin(II) analogues [Fe(CO)3(L)(L′)] (L = CN(Me)(CH2)2NMe, L′ = PEt3, 3 CO's equatorial; or L = M(OAr)2 (equatorial: M = Ge OR Sn, Ar = C6H2But2-2,6-Me-4), L′ = CO) (1986) (59)
Subvalent group 14 metal compounds XIV. The X-ray crystal structures of two monomeric group 14 metal bisamides, Ge[N(SiMe3)2]2 and Sn[Me2]2 (1992) (59)
Regular papersCarbene complexes: XXIV2. Preparation and characterization of two enetetramine-derived carbenerhodium(I) chloride complexes RhCl(LR)3 and [RhCl(COD)LR] and the preparation and X-ray structures of the enetetramine L2R and its salt [L2R][BF4]2 (1994) (58)
Pyridine N-alkylation by lithium, magnesium, and zinc alkyl reagents: synthetic, structural, and mechanistic studies on the bis(imino)pyridine system. (2005) (58)
Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates (2004) (58)
Novel zirconium complexes derivedfrom C2-symmetric diamide ligands; the X-ray crystal structure of [Zr(η1-CH2Ph)(η2-CH2Ph){(C6H3)2-2,2′-(NCH2C6H4Ph-4)2-6, 6′-Me2}] (1996) (57)
Mono-, di-, and Ttianionic beta-diketiminato ligands: a computational study and the synthesis and structure of [(YbL)(3)(THF)], L = [[N(SiMe(3))C(Ph)](2)CH]. (2003) (57)
Trifluoromethyl coordination and C-F bond activation at calcium. (2007) (57)
A novel class of salts for second harmonic generation (1989) (56)
The synthesis and crystal structures of 1-phenyl-3-methyl-4-butanolypyrazol-5-one and of two pyrazolonato complexes of iron (1993) (56)
Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction. (2011) (56)
Crystalline amidocerium(IV) oxides and a side-on bridging dioxygen complex. (2010) (55)
Reactions of LiCHR2 and related lithium alkyls with α-H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and β-diketiminates (2000) (55)
Transformation of the bis(trimethylsilyl)methyl into a 1,3-diaza-allyl ligand. Synthesis and crystal structures of [] and [{UCl(μ-Cl)(L)(NR)}2][UCl2(L)(L′)]2[R = SiMe3; Ar = C6Me2-2,5; L = ; L′ = ] (1995) (55)
Multiple coordination geometries supported by methylene-linked guanidines. (2004) (54)
First structural characterisation of penta- and hexa-phosphorus analogues of ferrocene. Synthesis, crystal and molecular structure of the air-stable, sublimable iron sandwich compounds [Fe(η5-C2R2P3)2], and [Fe(η5-C3R3P2)(η5-C2R2P3)](R = But) (1987) (54)
Tetraphosphatricyclo[4.2.0.02,5]octadienes; New Phosphaalkyne Cyclotetramers Derived from λ3σ2‐Diphosphetes (1995) (53)
1-methyl-3-ethylimidazolium hexachlorouranate(IV) and 1-methyl-3-ethylimidazolium tetrachlorodioxo-uranate(VI): Synthesis, structure, and electrochemistry in a room temperature ionic liquid (1986) (53)
Carbene complexes. XIX: Optically active electron-rich olefin-derived carbene-transition-metal complexes ― Crystal structures of [RhCl(COD)(C7H12N2)], [RhCl(COD)(C9H16N2)], [RhCl(PPh3)2(C9H18N2)] and [Co(CO)(NO)(PPh3)(C6H12N2)] (1985) (53)
Transformation of the bis(trimethylsilyl)methyl into aza-allyl and β-diketinimato ligands; the X-ray structures of [Li{N(R)C(But)CH(R)}]2 and [Zr{N(R)C(But)CHC(Ph)N(R)}Cl3](R = SiMe3) (1994) (52)
Chemistry of bulky alkoxides of bivalent germanium and tin; structures of gaseous [Sn(OBut)2]2 and crystalline Ge(OCBut3)2 (1985) (52)
Synthesis, structures and reactions of ytterbium(II) alkyls (1994) (52)
Structure and biosynthesis of harzianopyridone, an antifungal metabolite of Trichoderma harzianum (1989) (52)
Synthesis and structures of 1,3,1′,3′-tetrabenzyl-2,2′-biimidazolidinylidenes (electron-rich alkenes), their aminal intermediates and their degradation products (1998) (52)
First example of cyclodimerisation of a phospha-alkyne to a 1,3-diphosphacyclobutadiene. Syntheses of complexes of the type [M(η5-C5R5){η4-(ButCP)2}] R = H or Me; M = Co, Rh, or Ir): crystal and molecular structure of η5-pentamethylcyclopentadienyl-2,4-di-t-butyl-1,3-diphosphacyclobutadienecobalt(I) (1986) (51)
Bis(trimethylsilyl)phosphidometal complexes (1987) (51)
Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2] (1995) (51)
Oxidation in nonclassical organolanthanide chemistry: synthesis, characterization, and X-ray crystal structures of cerium(III) and -(IV) amides. (2004) (51)
Crystal structure of the tetrahydrofuran adduct of tris(trimethylsilyl)-methyl-lithium, [Li(thf)4][Li{C(SiMe3)3}2], an ate derivative of lithium (1983) (50)
Synthesis, characterisation and alkylation reactions of lanthanideβ-diketiminates; crystal structures of[Nd(L–L)2Cl] and[Ce(L–L)(CHR2)2][L–L = N(R)C(Ph)C(H)C(Ph)NR,R = SiMe3] (1997) (50)
Structural and catalytic properties of bis(guanidine)copper(I) halides. (2003) (50)
Synthesis and structures of crystalline bis(trimethylsilyl)methanido complexes of potassium, calcium and ytterbium (2002) (50)
Unusual oxidative coupling of 1,2,4-triphosphacyclopentadienyl and 1,3-diphosphacyclopentadienyl anions. Synthesis and molecular structure of the novel pentaphosphorus cage compound P5C5But5 (1989) (50)
Redetermination of 2,2'-bithiophene (1994) (49)
Synthesis and characterisation of two monomeric crystalline thallium(I)β-diketiminates (2005) (49)
Crystal Structures of (Tris(trimethylsilyl)methyl)- and (Tris(dimethylphenylsilyl)methyl)potassium (1994) (49)
beta-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon-Carbon Bond Formation (2008) (49)
Phospholipid arrangements in multilayers and artificial membranes: quantitative analysis of the X-ray diffraction data from a multilayer of 1,2-dimyristoyl-DL-phosphatidylethanolamine. (1975) (49)
The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8) (1990) (49)
Reactions of Li- and Yb-coordinated N,N'-bis(trimethylsilyl)-beta-diketiminates: one- and two-electron reductions, deprotonation, and C-N bond cleavage. (2004) (49)
New reactions of β-diketiminatolanthanoid complexes: sterically induced self-deprotonation of β-diketiminato ligands (2005) (49)
Structures of the radical P[N(SiMe3)2](NPri2), its dimer, cation and chloro derivative. (2004) (48)
Tris(imidazolin-2-ylidene-1-yl)borate Complexes of the Heavier Alkaline Earths: Synthesis and Structural Studies (2009) (48)
Cerium masquerading as a group 4 element: synthesis, structure and computational characterisation of [CeCl(N(SiMe3)2)3]. (2001) (48)
Hexaphosphapentaprismane: a new gateway to organophosphorus cage compound chemistry. (2002) (48)
Stereocontrolled addition of organozinc reagents derived from 2-(bromomethyl)acrylates to chiral imines. (1992) (47)
The first neutral, mononuclear 4f metal thiolates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amides (1992) (47)
The synthesis of enantiomerically pure 4-substituted [2.2]paracyclophane derivatives by sulfoxide-metal exchange. (2005) (47)
The first examples of intermolecular weak (agostic) γ-methyl-metal interactions in organolanthanide complexes: The synthesis and X-ray structures of [{Yb(η-CP″)2}∞.] and [{Eu(η-CP″)2}∞] [CP″ C5H3(SiMe3)2-1,3] (1992) (46)
The structural characteristics of organozinc complexes incorporating N,N'-bidentate ligands. (2004) (45)
A novel carbon dioxide complex: synthesis and crystal structure of [Nb(η-C5H4Me)2(CH2SiMe3)(η2-CO2)] (1981) (45)
The Remarkable Stable Emerald Green C60 F15 [CBr(CO2 Et)2 ]3 : The First [60]Fullerene That Is also the First [18]Trannulene. (2001) (45)
U(III)-induced reductive co-coupling of NO and CO to form U(IV) cyanate and oxo derivates. (2010) (45)
Pyrazolonato complexes of lead. Crystal structures of bis(1-phenyl-3-methyl-4-acetyl pyrazolonato)lead(II) and bis(1-phenyl-3-methyl-4-butanoylpyrazolonato)lead(II) (1996) (44)
Cerium(III) and Cerium(IV) Bis(η8-pentalene) Sandwich Complexes: Synthetic, Structural, Spectroscopic, and Theoretical Studies (2007) (44)
New heptacoordinated tin complexes of 2,6-diacetylpyridine-bis(thiosemicarbazone), H2daptsc, and of 2,6-diacetylpyridine-bis(semicarbazone), H2dapsc. Crystal and molecular structures of [MeSnCl(Hdaptsc)]Cl·MeOH and [MeSnCl(H2dapsc)]Cl2·2H2O (1994) (44)
Stabilization of low-oxidation-state early transition-metal complexes bearing 1,2,4-triphosphacyclopentadienyl ligands: structure of [[Sc(P3C2tBu2)2]2]; ScII or mixed oxidation state? (2003) (44)
New Reactions of a Silylene: Insertion into MN Bonds of M[N(SiMe3)2]2 (M Ge, Sn, or Pb) (1997) (43)
Synthesis of a Stable Biphenyl‐Bis(carbene) and ‐Bis(silylene) [M{(NCH2But)2C6H3‐3,4}]2 (M = C or Si) (2005) (43)
Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu) (2001) (43)
The First Delocalized Phosphole Containing a Planar Tricoordinate Phosphorus Atom: 1-[Bis(trimethylsilyl)methyl]-3,5-bis(trimethylsilyl)-1,2,4-triphosphole. (1998) (43)
Preparation and crystal structure of a two-co-ordinate manganese compound, bis[tris(trimethyl)silylmethyl]manganese (1985) (43)
Insertion reactions into Pd[bond]O and Pd[bond]N bonds: preparation of alkoxycarbonyl, carbonato, carbamato, thiocarbamate, and thioureide complexes of palladium(II). (2003) (43)
A New Class of Linked-bis(N,N'-dialkylamidinate) Ligand: Applications in the Synthesis of Bimetallic Aluminium Complexes (2002) (42)
Structural consequences of the prohibition of hydrogen bonding in copper-guanidine systems. (2004) (42)
Facile formation of a homoleptic Ce(IV) amide via aerobic oxidation. (2006) (42)
Titanium(IV) complexes incorporating the aminodiamide ligand [(SiMe3)N CH2CH2 N(SiMe3)]2−(L) ; the X-ray crystal structures of [TiMe2(L) ] and [TiClCH(SiMe3)(L)] (1995) (42)
Reactivity of divalent germanium alkoxide complexes is in sharp contrast to the heavier tin and lead analogues. (2012) (42)
New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) (1999) (42)
Synthesis of homoleptic tris(organo-chelate)iridium(III) complexes by spontaneous ortho-metallation of electronrich olefin-derived N,N′-diarylcarbene ligands and the X-ray structures of fac-[6H3Me-p}3] and mer-6H3Me-p}2 {C6H4Me-p}Cl (a product of HCl cleavage) ☆ (1982) (42)
The crystal structure of di-t-butylsilanediol and its relevance to the liquid crystallinity of diisobutylsilanediol (1985) (41)
Routes to optically active electron-rich olefins (L*2 and some derived carbenemetal complexes; x-ray structures of [Co(CO)(L*)(NO(PPh3)] and cis-[Rh(Cl)(COD)(L′*)][L*= (S)-Me, (1983) (41)
Carbene complexes. Part 11. Steric and conformational effects upon the transition-metal reactivity of electron-rich olefins and derived species; heteroatom-donor-olefin–metal (Cr0, Mo0, W0, or RhI) and 2-imidazoline-N-donor–metal complexes, and the crystal and molecular structure of tetracarbonyl[NN (1977) (41)
Preparation and crystal structure of the tetrahydrofuran adduct of lithium bis [tris(trimethylsilyl)methyl]cuprate, [Li(THF)4] [Cu{C(SiMe3)3}2]. The first structural characterization of a Gilman reagent (1984) (41)
Metal (Li, GeII, GeIII, SnII, and PbII) 2,6-dialkylbenzenethiolates; X-ray crystal structures of Sn(SAr)2(Ar = C6H2But3-2,4,6) and [M(SAr′)2]3(M = Sn or Pb, Ar′= C6H3Pri2-2,6) (1983) (41)
Ligand and metal effects on the formation of main-group polyhedral clusters. (2003) (41)
[Me2Al(THF)2]+[{Me2Si(NDipp) 2}2Zr2Cl5]- (Dipp = 2,6-diisopropylphenyl), an unusual zirconium/aluminum ion pair containing a THF-stabilized dimethylaluminum cation (2002) (41)
Synthesis and characterisation of unusual tetraaminoalkenes (enetetramines) (1992) (41)
The Elusive Titanocene (1998) (40)
Scandium, yttrium, uranium, and thorium derivatives of the 1,4-bis(trimethylsilyl)cyclo-octatetraene dianion; the X-ray crystal structure of [Sc2(η-C8H6{1,4-(SiMe3)2})2(µ-Cl)2(µ-thf)](thf = tetrahydrofuran) (1989) (40)
Preparation and crystal structures of the crowded organotin fluorides (PhMe2Si)3CSnMe2F, (Me3Si)3CSnMe2F, and (Me3Si)3CSnPh2F (1987) (40)
Reactions of β-Diketiminate-Stabilized Calcium Amides with 9-Borabicyclo[3.3.1]nonane (9-BBN) (2007) (40)
Synthesis and characterization of arylamide-bridged binuclear palladium(II) complexes. Crystal structure of anti-[[Pd(C6F5)(t-BuNC)(.mu.-NHPh)]2] (1993) (40)
Heteroleptic ytterbium(II) complexes supported by a bulky beta-diketiminato ligand. (2009) (40)
Hydrogen-bonded layers of hydrogentartrate anions: two-dimensional building blocks for crystal engineering (1993) (39)
Aspects of non-classical organolanthanide chemistry (2002) (39)
Some derivatives of tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure (1983) (39)
Dimerization of β-diketiminato calcium complexes through dihapto-acetylide ligation (2005) (39)
Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U(III) complex. (2009) (39)
Synthesis and structures of selected benzamidinates of Li, Na, Al, Zr and Sn(II) using the C1-symmetric ligands [N(SiMe3)C(C6H4Me-4 or Ph)NPh]-. (2007) (38)
The novel, chelating C, N-bidentate 2,6-bis(dimethylamino)phenylligand (R-), showing ambidentate N,N′-character inM(R)2 (M = Ge, Sn, Pb) and Sn(R)X [X =N(SiMe3)2, CH(SiMe3)2,Cl] (1997) (38)
Reactivity of hydroxo complexes of palladium(II) towards nitriles: formation of carboxamide and imino ether derivatives of palladium(II) (1999) (38)
Anti-Bimetallic Complexes of Divalent Lanthanides with Silylated Pentalene and Cyclooctatetraenyl Bridging Ligands as Molecular Models for Lanthanide-Based Polymers (2009) (38)
First examples of η5- and η5 η1-coordination in triphosphorus analogues of ferrocene. Crystal structure of the iron sandwich complex [Fe(η5-C5H5) (η5-C2R2P3)W (CO)5] (R But) (1988) (38)
Titanium Complexes Incorporating Bicyclic Guanidinate Ligands. Structure of a Novel Titanium-Aluminium Complex (2001) (38)
Triangulo -pentahalotrimetal complexes of nickel(II) and cobalt(II) with N,N,N′,N′,N -tetramethylethane-1,2-diamine and related compounds (2001) (38)
Carbene complexes: XXIII. Preparation, characterisation, and structures of the enetetramine-derived carbenerhodium(I) chloride complexes [RhCl(LR)3],trans-[RhCl(CO)(L2R′)], and [{RhCl(COD)}2{μ-L2(323)R}] [L2R or R′ = CN(R or R′)(CH2)2NR(or R′) (R CH2)Ph or Et, R′ Me) and L(323)R CN(R)(CH2)3N(CH2)2N( (1993) (38)
Synthesis of substituted oligothiophenes and X-ray crystal structures of3′-methyl-2,2′∶5′,2″-terthiophene,3,3″-dimethyl-2,2′∶5′,2″-terthiophene and5′-(2-thienyl)-2,2′∶3′,2″-terthiophene (1997) (37)
Base-catalyzed oxygenation of tert-butylated phenols. 2. Formation of 3-aryl-2,5-di-tert-butyl-2,4-cyclopentadienones by base-catalyzed oxygenation of 4-aryl-2,6-di-tert-butylphenols: x-ray structure determination of 2,5-di-tert-butyl-3-(4-chlorophenyl)cyclopentadienone (1978) (37)
Heterobimetallic (Pd/PtGe/Sn) trinuclear clusters containing a planar M3(CO)3(μ2-M′)3 core: Spectroscopy, cyclic voltammetry, and ESR characterisation of electrochemical reduction products. Crystal structures of [(M{μ2-Sn(NR2)2}(CO))3] (M = Pd or Pt, R = SiMe3)☆ (1985) (37)
Synthesis and structures of the ytterbium(II) β-diketiminates [Yb{N(SiMe3)C(R2)C(H)C(R4)N(SiMe3)}2] (R2 = R4 = Ph, C6H4Me-4, or C6H4Ph-4; or R2 = C6H4Me-4, R4 = 1-adamantyl) (2003) (37)
Hydrogen-bonding in organosilanetriols. The crystal structures of tris(trimethylsilyl)silyl- and tris(trimethylsilyl)-methyl-silanetriols (1989) (37)
(Phosphacyclopentadienyl)indium(I) Derivatives: Synthesis and X-ray Crystal Structure of [In(η5-P3C2But2)] (1999) (37)
Synthesis of stereochemically defined phosphonamidate-containing peptides: Inhibitors for the HIV-1 proteinase (1992) (37)
Synthesis, structure and DNA binding studies of a mononuclear cobalt(III) complex with a NNO donor Schiff base derived from 4-methyl-2,6-dibenzoylphenol and ethane-1,2-diamine (2007) (36)
Thermally Stable Heterobinuclear Bivalent Group 14 Metal Complexes Ar2 M-Sn[1,8-(NR)2 C10 H6 ] (M=Ge, Sn; Ar=2,6-(Me2 N)2 C6 H3 ; R=CH2 tBu). (1999) (36)
Thermolysis of [tris(trimethylsilyl)methyl](diphenyl)fluorosilane. Isomerization of a sila-olefin intermediate (1980) (36)
The syntheses and structures of Group 1 expanded dipyrrolides: the formation of a 12-rung amidolithium circular ladder (2003) (36)
Synthesis and M-Cγ hemilability of group 2 bis(phosphinimino)methanides (2006) (36)
Unusual kinetically stable dialkyltin(IV) oxides; X-ray structures of [{SnR2(µ-O)}2] and [{SnR2(OH)}2(µ-O)][R = CH(SiMe3)2] (1990) (36)
Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring (1994) (36)
The combined use of stereoelectronic control and ring closing metathesis for the synthesis of (-)-8-epi-swainsonine (2007) (36)
Activation of P4 by U(η5-C5Me5)(η8-C8H6(SiiPr3)2-1,4)(THF); the X-ray structure of [U(η5-C5Me5)(η8-C8H6(SiiPr3)2-1,4)]2(μ-η2:η2-P4) (2011) (36)
A Novel Hexamer of ButC P: Synthesis, Structure, and Theoretical Studies (1994) (36)
Cerium(III) dialkyl dithiocarbamates from [Ce[N(SiMe3)2]3] and tetraalkylthiuram disulfides, and [Ce(kappa2-S2CNEt2)4] from the Ce(III) precursor; Tb(III) and Nd(III) analogues. (2004) (36)
Synthesis and structures of some sterically hindered zinc complexes containing 6-membered and rings (2008) (36)
Two Diorganopotassates: Crystal Structure of [K(C6H6)][K{C(SiMe3)2(SiMe2Ph)}2] (1996) (35)
The crystal and molecular structure of a versatile bidentate ligand: tetraphenyldithioimidodiphosphinate, Ph2(S)P -NH-P(S)Ph2 (1985) (35)
Dimerization of indanediyl fragments: an alkene analogue for group 13? (2005) (35)
Structural studies on a lithium organo-amidocuprate in the solid state and in solution. (2007) (35)
Synthesis and structures of crystalline dilithium diamides and aminolithium amides derived from N,N′-disubstituted 1,2-diaminobenzenes or 1,8-diaminonaphthalene (2001) (35)
The first structurally characterised σ-bonded organonickel(I) compound. Crystal structures of [Ni{C(SiMe3)2(SiMe2C5H4N-2)}(PPh3)], [Ni{C(SiMe3)(SiMe2C5H4N-2)(SiMe2O)}]2 and [Pd(μ-Cl){C(SiMe3)2(SiMe2C5H4N-2)}]2 (2000) (35)
Zirconium complexes incorporating the new tridentate diamide ligand [(Me3 Si)N{CH2CH2N(SiMe3)}2]2–(L); the crystal structures of [Zr(BH4)2L] and [ZrCl{CH(SiMe3)2}L] (1995) (35)
A Novel Organolead(II) Species the Plumbacycloalkane Derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2Ch2] (1997) (35)
Catalytic bond forming reactions promoted by amidinate, guanidinate and phosphaguanidinate compounds of magnesium. (2014) (34)
Synthesis and Crystal Structures of the Compounds [Sn{C(SiMe2Ph)3}Cl]2, [Pb{C(SiMe3)3}Cl]3, and [M{C(SiMe3)2(SiMe2OMe)}Cl]2 (M = Sn or Pb) (1997) (34)
Synthesis and theoretical studies on rare three-coordinate lead complexes. (2007) (34)
An organozinc hydride cluster: an encapsulated tetrahydrozincate? (2008) (34)
Upon the hydrogen-bonding ability of the H4 and H5 protons of the imidazolium cation (1990) (34)
Synthesis and X-ray molecular structures of the silver(I) amides [{Ag[µ-N(SiMe3)2]}4] and [{Ag[µ-NCMe2(CH2)3CMe2]}4] (1996) (34)
Reactions of the stable bis(amino)silylene Si[{N(CH2tBu)}2C6H4-1,2] with group 3 or lanthanide metal organic compounds. Crystal structures of [Ln(η5-C5H5)3Si{[N(CH2tBu)]2C6H4-1,2}]·C7H8 (Ln = Y or Yb) (2000) (34)
Synthesis and structures of lithium, aluminium, gallium and lanthanide amidinates containing a γ-pendant amine functionality (2000) (34)
A Versatile Bulky Bidentate Ligand for Both Main Group and Transition Metals. Derivatives of Lithium, Potassium, Magnesium, Chromium, Manganese, and Cobalt Containing the C(SiMe3)2(SiMe2C5H4N-2) Group (2000) (34)
The preparation and crystal structures of the compounds (Ph2MeSi)3CMCl (M = Zn, Cd, or Hg) (1993) (34)
Ytterbium(II) amides and crown ethers: addition versus amide substitution (2002) (33)
Some sterically hindered lithium alkylbromo- and alkylchloro-magnesates, -cadmates, and -manganates. Crystal and molecular structures of [Li(thf)2(-Br)2Mg{C(SiMe3)3}(thf)], [Li(thf)4][{Cd[C(SiMe3)3]}3(-Br)3(3-Br)]0.5C6H12, [{Li(thf)}3(3-Br)3(3-OSiMe3)Cd{C(SiMe3)3}], and [Li(thf)4][{Mn[C(SiMe3)3]}3(- (1988) (33)
Carbene complexes. Part 16. Synthesis and properties of NN′N″N‴-tetra-aryl-substituted electron-rich olefin-derived carbeneruthenium(II) complexes containing a spontaneously formed ortho-metallated-N-arylcarbene ligand; the crystal and molecular structures of [RuCl{CN(C6H4Me-4)CH2CH2NC6H3Me-4}(PEt3) (1979) (33)
Synthesis, Structures, Characterization, Dynamic Behavior, and Reactions of Novel Late Transition Metal(II) 1-Azaallyls (2004) (33)
Monomeric magnesium 1-azaallyl and β-diketiminato complexes derived from the bis(trimethylsilyl)methyl ligand: The X-ray structure of the four-coordinate planar magnesium complex [Mg{N(R)C(But)C(H)R}2] and of [Mg({N(R)C(Ph)}2CH)2]† (1999) (33)
Synthesis, structure and reactivity of [Yb(η-C5Me5){Si(SiMe3)3}(thf)2] (1996) (33)
Synthesis and structure of crystalline [K{Sn(CH2But)3}(η-C6H5Me)3] and the first NMR spectral observation of119Sn–39K coupling (1993) (33)
Carbene complexes. Part 14. The synthesis and steric and electronic effects in electron-rich olefin-derived bis-, tris-, and tetrakis-(carbene)-ruthenium(II) and a tetrakis(carbene)osmium(II) complex; the crystal and molecular structure of trans-dichiorotetrakis(1,3-diethylimidazo-lidin-2-ylidene)ru (1978) (33)
The first structurally authenticated divalent lanthanide stannyl derivative (1991) (33)
Aggregation behaviour of thallium(I) β-diketiminates (2006) (33)
Organometallic Compounds of the Alkali Metals with Phenylsilyl Substituents at the Carbanionic Center. Crystal Structures of LiC(SiMe3)2(SiMe2Ph)·Et2O, NaC(SiMe3)2(SiMe2Ph)·TMEDA, NaC(SiMe3)(SiMe2Ph)2·TMEDA, {LiCH(SiMe2Ph)2}2, RbC(SiMe2Ph)3, and CsC(SiMe2Ph)3(TMEDA = Tetramethylethylenediamine) (1997) (32)
Synthetic and structural studies on some bis(cyclopentadienyl)molybdenum and -tungsten complexes containing doubly bonded tin or phosphorus (1989) (32)
The structure of [Os7(CO)21]; X-ray and 13C nuclear magnetic resonance analyses (1977) (32)
Magnetochemistry of the tetrahaloferrate(III) ions. 1. Crystal structure and magnetic ordering in bis[4-chloropyridinium tetrachloroferrate(III)]-4-chloropyridinium chloride and bis[4-bromopyridinium) tetrachloroferrate(III)]-4-bromopyridinium chloride (1990) (32)
Complexes of metal(II) halides of the first transition series with N,N,N′,N′-tetramethylmethane-diamine, -ethane-1,2-diamine and -propane-1,3-diamine (2001) (32)
C60F18O the first characterised intramolecular fullerene ether (2000) (32)
The reaction of 2-formylpyridine thiosemicarbazone (HFPT) with tin tetrahalides. Crystal and molecular structure of [SnCl3(FPT)] (1993) (32)
[1 + 4]-Cycloadditions of silylenes to 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene (2002) (32)
Alkoxide and Aryloxide Derivatives of a (Triamidoamine)uranium Complex. (1997) (32)
Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La5(μ5-O)(μ3-OtBu)4(μ-OtBu)4(OtBu)5 (2000) (32)
Carbodiimide insertion reactions of homoleptic heavier alkaline earth amides and phosphides. (2010) (32)
Four-and five-co-ordinate lanthanide (II) aryloxides: X-ray structures of the bis(2,6-di-t-butyl-4-methylphenoxo)ytterbium(II) complexes [Yb(OAr)2(L)2] and [Yb(OAr)2(L′)3][ArC6H2But2-2,6-Me-4, L = tetrahydrofuran (thf) or OEt2, L′= thf] (1989) (32)
Bis(diphenylphosphido) derivatives of the heavier group 2 elements. (2007) (31)
Synthesis, structure and reductive dechlorination of the C-centred phosphorus(III) beta-diketiminate PCl(Ph)L [L = C[C(Me)NC6H3Pri2(-2),6][C(Me)NHC6H3Pri2(-2),6]]. (2003) (31)
Stabilisation of High Oxidation-State Niobium Using 'Electron-Rich' Bicyclic-Guanidinates (2005) (31)
A conformational study of phospha(III)- and phospha(V)-guanidine compounds. (2006) (31)
Synthesis and Characterization of the First Compounds Containing a Stable Phosphirenyl Cation: Crystal and Molecular Structure of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)W(CO)5]† (1994) (31)
Tri-, penta-, and hexa-phospha ruthenocenes (1995) (31)
Yttrium complexes incorporating the chelating diamides [ArN(CH2)xNAr]2- (Ar = C6H3-2,6-iPr2, x= 2, 3) and their unusual reaction with phenylsilane. (2004) (31)
Subvalent group 14 metal compounds-XIII. Oxidative addition reactions of germanium and tin amides M(NR2)2 (R = SiMe3, M = Ge OR Sn) with sulphur, selenium, tellurium or MeOOCCCCOOMe; X-ray structures of [Ge(NR2)2(μ-Te)]2 and (1991) (31)
Synthesis and structures of beta-diketiminatotin(II) halides, an amide and of Sn(=E)[{N(R)C(Ph)}2CH](NR2) (E = S or Se, R = SiMe3). (2004) (31)
A Step Too Far? Assessment of the Boroxide Ligand in Ring-Opening Polymerization (2004) (31)
Unusual crystalline heterobimetallic trinuclear β-diketiminates [Yb{L(µ-Li(thf)}2] and [Yb{L′(µ-Li(thf)}2]·thf [L, L′ = {N(SiMe3)C(R)}2CH, R = Ph, C6H4Ph-4]Electonic supplementary information (ESI) available: NOE data for 1 and NMR data for 2. See http://www.rsc.org/suppdata/cc/b2/b203321f/ (2002) (31)
Synthesis and characterization of mononuclear pyrazolyl complexes of palladium(II) and platinum(II). Crystal structures of [NBu4][M(C6F5)2(pyrazole)(pyrazolato)] (M = Pd, Pt) (1992) (31)
Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand. (2002) (31)
Formation of gold(III)-carbon .sigma.-bonds in the bromination of linear gold(I) complexes of olefinic tertiary phosphines (1971) (30)
Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties (2008) (30)
Tetraphosphatricyclo[4.2.0.02, 5]octadiene, neue Phosphaalkin‐Cyclotetramere; intermediäres Auftreten von λ3σ2‐Diphospheten (1995) (30)
Organolanthanide hydroxides; the synthesis and crystal structures of the samarocene and ytterbocene hydroxides [SmCp2″(μ-OH)2] and [YbCp2′(μ-OH)2][Cp″ = η5-C5 H3(SiMe3)2-1,3; Cp′ = η5-C5H4SiMe3] (1991) (30)
A new class of actinide''sandwich'' complexes: Synthesis and molecular structure of a thorium bis(eta(8)-pentalene) complex (1997) (30)
Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(mu-I)2]3(mu3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3). (2008) (30)
Synthesis and characterisation of iodo functionalised ytterbium(II) and ytterbium(III) alkoxides (1996) (30)
The first crystalline alkali metal salt of a benzenoid radical anion without a stabilizing substituent and of a related dimer: X-ray structures of the toluene radical anion and of the benzene radical anion dimer potassium-crown ether salts. (2001) (30)
Lanthanide metal amides revisited; the use of the 2,2,6,6-tetramethylpiperidinato (TMP) ligand (2004) (30)
The diverse reactions of the silylene Si[(NCH2But)2C6H4-1,2] with Li[Si(SiMe3)3](thf)3 and K[N(SiMe3)2] (2000) (30)
Synthesis and X-ray crystal structure of the first homoleptic main group diazadiene complex, bis(1,4-di-t-butyl-1,4-diazabuta-1,3-diene) gallium (1989) (30)
Racemic N-aryl bis(amidines) and bis(amidinates): on the trail of enantioselective organolanthanide catalysts. (2006) (30)
Non-planar co-ordination of C2-symmetric biaryl-bridged Schiff-base ligands: well expressed chiral ligand environments for zirconium† (1999) (30)
Hexa-phosphorus analogues of metallocenes: synthesis of the first paramagnetic sandwich complex containing two η51,2,4-triphosphacyclopentadienyl rings. Crystal and molecular structures of [Cr(η5-C2But2P3)2] (1988) (30)
Reactions of sterically hindered organozinc and organocadmium compounds containing functional silicon centres. Crystal structures of Zn[C(SiMe3)2(SiMe2OCOCF3)]2 and Cd[C(SiMe3)2(SiMe2OMe)]2 (1992) (30)
Synthesis and characterisation of 2, 4, 6-tri-t-butylphenylphosphines; X-ray structure of [P(C6H2But3-2,4,6)S]3 (1982) (30)
Synthesis of non-proteinogenic amino acids with three chiral centres (1991) (29)
The Synthesis and Crystal Structures of RbC(SiMe3)3 and CsC(SiMe3)3·3.5 C6H6: A One‐dimensional Ionic Solid and an Ionic Solid with a Molecular Structure (1995) (29)
Disproportionation and reduction of hydrazine at a molybdenum–thiolate centre: crystal structures of [MoH(SC6H2Pri3-2,4,6)3(NH3)(PMePh2)] and [MoH(SC6H2Pri3-2,4,6)3(NH2NHPh)(PMePh2)] (1997) (29)
Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule. (2007) (29)
Some unusual organo-zinc and -mercury compounds. The crystal structures of the compounds [(HOMe2Si)(Me3Si)2C]2Zn, [(MeOMe2Si)(Me3Si)2C]2Zn, and [(MeOMe2Si)(Me3Si)2C]2Hg (1991) (29)
Intramolecular hydrogen bonding in complexes containing bicyclic guanidine ligands (2006) (29)
The first structurally authenticated zerovalent heteroarene complexof a lanthanide; synthesis and X-ray structure ofbis(2,4,6-tri-tert-butyl- phosphorin)holmium(O) (1997) (29)
Group 1 and 13 complexes of aryl-substituted bis(phosphinimino)methyls (2004) (29)
Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µ-hydroxy)-bis{tris(dimethylphenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2] and µ4-oxohexa(µ-hydroxy)tetrakis{tris(trimethylsilyl)methylindium}, [O{(Me3Si)3Cln}4(OH)6] (1986) (29)
Synthesis of α-amino esters by dynamic kinetic resolution of α-haloacyl imidazolidinones (2001) (29)
Metalation of Tris(trimethylsilyl)‐ and Tris(dimethylphenylsilyl)methane with Methylsodium: The First Dialkylsodate (1994) (28)
Synthesis, crystal and molecular structure of the “slipped” sandwich complex [Ni(η5-P3C2R2)(η3-P2C3R3)] (R = But) (1989) (28)
Design and synthesis of multi-component 18 pi annulenic fluorofullerene ensembles suitable for donor-acceptor applications. (2004) (28)
Synthesis and Structure of the Arsaalkyne Tetramer (AsCtBu)4 and its Fe(CO)4 Derivative (1993) (28)
Vanadyl complexes in ambient-temperature ionic liquids. The first x-ray crystal structure of a tetrachlorooxovanadate(IV) salt (1993) (28)
Three-coordinate neutral ligand-free ytterbium(II) complexes [{YbX(µ-X)}2](X = OAr 1 or OCBut3 3) or [{Yb(NR2)(µ-X)}2](X = OCBut3 2 or OAr 4)(Ar = C6H2But2-2,6-Me-4, R = SiMe3); the X-ray structures of 1 and 2 (1994) (28)
Preparation of New Lithium Organotrihydroaluminates: Crystal Structure of {(C4H8O)2Li(.mu.-H)2AlH[C(SiMe2Ph)3]}2 (1994) (28)
[{Yb6[η-C5Me4(SiMe2But)]6I8}{Li(thf)4}2]: the spontaneous self-assembly of a hexanuclear ytterbium(II) octaiododianion (1996) (28)
Phosphine-catalysed cycloaddition of buta-2,3-dienoates andbut-2-ynoates to [60]fullerene (1997) (28)
A Dichromium(II) Bis(η8-pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical Studies (2008) (28)
Synthesis and characterisation of lanthanide(II) aryloxides including the first structurally characterised europium(II) compound [Eu(OC6H2But2-2,6-Me-4)2(thf)3]·thf (thf = tetrahydrofuran) (1995) (28)
Synthesis and coordination chemistry of neutral phospha(III)guanidines. Formation of 1-aza-3-phospha-4-metallacyclobut-1-ene rings at group 6 metals (2003) (28)
Syntheses and Structures of the Crystalline, Highly Crowded 1,3-Bis(trimethylsilyl)cyclopentadienyls [MCp″3] (M = Y, Er, Yb), [PbCp″2], [{YCp″2(μ-OH)}2], [(ScCp″2)2(μ-η2:η2-C2H4)], [YbCp″2Cl(μ-Cl)K(18-crown-6)], and [{KCp″}∞] (2012) (28)
Synthesis, Characterization and Crystal Structure of a Nickel(II) Schiff Base Complex Derived from Acetylacetone and Ethylenediamine (2002) (27)
Solution- and solid-state characterisation of a configurationally-stable beta-diketiminato-supported calcium primary amide. (2004) (27)
A Non-Metallocene Hydride of Titanium(III) (1999) (27)
Synthesis and structures of neutral and cationic β-diketiminatoaluminium methyls† (1999) (27)
Homoleptic, three-co-ordinate group 8c noble metal(0) complexes having GeII or SnII ligands, [M{M′(NR2)2}3](M = Pd or Pt, M′= Ge or Sn, R = SiMe3), and the X-ray structure of one of them (M = Pd, M′= Sn) (1985) (27)
Activation of carbon dioxide by divalent tin alkoxides complexes. (2011) (27)
The beta-dialdiminato ligand [{N(C6H3Pri(2)-2,6)C(H)}2CPh]-: the conjugate acid and Li, Al, Ga and In derivatives. (2006) (27)
Catalytic hydroacetylenation of carbodiimides with homoleptic alkaline earth hexamethyldisilazides. (2014) (27)
Use of a highly hindered phosphino-alkoxide ligand in the formation of monomeric homoleptic lanthanoid metal complexes: X-ray structures of [Ln(OCBut2CH2PMe2)3](Ln = Y or Nd) (1988) (27)
Synthesis and structures of bis[bis(trimethylsilyl)amido]-tin(IV) cyclic chalcogenides [{Sn[N(SiMe3)2]2(µ-E)}2] and a heterobimetallic analogue [{(Me3Si)2N}2Ge(µ-Te)2Sn-{N(SiMe3)2}2](E = S, Se or Te) (1995) (27)
Antifungal activity and biotransformation of diisophorone by Botrytis cinerea. (2005) (27)
DACH-Bridged (DACH = trans-1,2-Diaminocyclohexane) Bis(iminophosphonamide) Derivatives of Groups 3 and 13 and Their Use in the Enantiomorphic Polymerization of Methyl Methacrylate (2007) (27)
Synthesis of a homoleptic Sm(II) bis(phosphinimino)methanide (2003) (27)
Synthesis, chemical behaviour, and structure (crystal and solution) of a fluorouranocene(IV) tetrafluoroborate; X-ray crystal structure of [{Ucp″2(µ-BF4)(µ-F)}2][cp″=η-C5H3(SiMe3)2] (1984) (27)
Oxidative Addition to a Monomeric Stannylene To Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of CH2Me2Si(Me3Si)2CSnC(SiMe3)2SiMe2CH2, CH2Me2Si(Me3Si)2CSnMe(OCOCF3)C(SiMe3)2SiMe2CH2, and (CF3COO)2MeSnC(SiMe3)2SiMe2CH2C (2000) (27)
A Bimetallic Bis-pentalene Sandwich Complex: Synthesis and Structure of Mo2[C8H4(1,4-SiPri3)2]2 (1998) (26)
A structural, theoretical and coordinative evaluation of the bicyclic guanidinate derived from 1,4,6-triazabicyclo[3.3.0]oct-4-ene. (2008) (26)
Synthesis of aluminium complexes bearing a piperazine-based ligand system (2010) (26)
Synthesis of tripodal amido complexes of the early actinides ; molecular structure of {N[CH2CH2N(SiMe3)]3UCl}2 (1994) (26)
Early-late, mixed-metal compounds supported by amidophosphine ligands. (2004) (26)
Novel triphospholyl and diphosphastibolyl lead(II) complexes (1999) (26)
Preparation of the isocyanide complexes trans-[ReCl(CNR)(dppe)2](R = Me or But) and their reactions with acid to give carbyne complexes. X-Ray crystal structure of trans-[ReCl(CNHMe)(dppe)2][BF4] (1981) (26)
Synthesis of Terminal and Bridging Acetonyl Complexes of Palladium(II). Crystal Structures of [{(AsPh3)(C6F5)Pd}2{μ-CH2C(O)CH3}2], [(AsPh3)(C6F5)Pd{CH2C(O)CH3}(t-BuNC)], and [(o-C6H4CH2NMe2)Pd{O,O‘-CH(CO2Et)2}] (2001) (26)
Catalytic 2,3,4-hexatriene formation by terminal alkyne coupling at calcium. (2009) (26)
Synthesis of β-diketiminato calcium silylamides and their reactions with triethylaluminium (2010) (26)
Attachment of the New Bulky Ligand (Me3Si)2(Me2NMe2Si)C to Li Hg Al Ga and Sn. Crystal Structures of [Li\{C(SiMe3)2(SiMe2NMe2)\}(THF)2] [Hg\{C(SiMe3)2(SiMe2NMe2)\}2] [Al\{C(SiMe3)2(SiMe2NMe2)\}X2] (X=Cl Ph) and [Ga\{c(SiMe3)2(SiMe2NMe2)\}Cl2] (1999) (26)
Novel Zirconium and Hafnium Complexes of Monoanionic Di-N,N‘-chelating Pyridyl- and Quinolyl-1-azaallyl Ligands and Their Activity in Olefin Polymerization Catalysis (1999) (26)
Remarkable Transformation of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-Tri-tert-butyl-1,3-diphosphacyclopentadienide Anion (2000) (26)
Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion. (2006) (26)
Complexes of organoaluminium compounds. Part 10. Crystal and molecular structures of the cage compounds bis-µ-methylamido-hexa-µ3-methylimido-bis(dimethylaluminium)-hexakis(methylaluminium) and bis-µ-methylamido-hexa-µ3-methylimido-bis(dimethylgallium)-hexakis-(methylgallium) (1979) (26)
The synthesis and directed ortho-lithiation of 4-tert-butylsulfinyl[2.2]paracyclophane. (2005) (25)
ORGANOACTINIDE CHEMISTRY. II: THE CHEMISTRY OF SOME NOVEL CYCLOPENTADIENYLTHORIUM COMPLEXES (1995) (25)
Crystal and molecular structure of chromocene (η5-C5H5)2Cr (1996) (25)
Lithium and aluminium complexes supported by chelating phosphaguanidinates. (2005) (25)
Lanthanocene Chemistry with [CpR]-, [Cpt]-, [Cptt]-, and [CpR‘2SiMe2]2- Ligands: Synthesis and Characterization of Bis(cyclopentadienyl)lanthanide(III) Halides and Bis(cyclopentadienyl)lanthanide(II) Complexes and Crystal Structures of [{NdCpR2(μ-Cl)}2], [{TmCptt2(μ-I)}2], and [Yb(CpR‘2SiMe2)(THF)2] (2000) (25)
The role of bivalent tin compounds in platinum co-ordination chemistry; X-ray structure of [Pt{Sn(NR′2)2}3], trans-[(Pt(µ-Cl)(PEt3){SnCl(NR′2)2})2], and (SnClR2)2[R = CH(SiMe3)2, R′= SiMe3] (1985) (25)
Synthesis of 5/7-, 5/8- and 5/9-bicyclic lactam templates as constraints for external beta-turns. (2005) (25)
The Thermally Stable Silylene Si[(NCH2But)2C6H4‐1,2]: Reactions with ButCN, AdCN, ButNC, AdN3, and Me3SiN3 (Ad = 1‐Adamantyl) (2001) (25)
Synthesis and characterisation of ytterbium(II) alkyls (1995) (25)
Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion. (2005) (25)
IRIDIUM COMPLEXES OF ORTHOMETALATED TRIARYL PHOSPHITES : SYNTHESIS, STRUCTURE, REACTIVITY, AND USE AS IMINE HYDROGENATION CATALYSTS (1996) (25)
Isolation and characterisation ofCs-symmetryC60Me5O2OH, the first methylatedfullerenol; a bis-epoxide with two oxygens in a pentagonal ring (2000) (25)
The antifungal activity and biotransformation of diisophorone by the fungus Aspergillus niger (2004) (25)
BIOTRANSFORMATION OF THE FUNGISTATIC SESQUITERPENOID GINSENOL BY BOTRYTIS CINEREA (1999) (25)
Displacement of a cyclopentadienyl ligand by a crown ether from a lanthanocene(II) [LnCp′′2]; crystal structures of the first cationic lanthanoid(II) complexes, [SmCp′′([18]-crown-6)][SmCp′′3]·0.5C6H6 and [YbCp′′([18]-crown-6)][Cp′′]·3C6H6 [Cp′′ = η5-C5H3(SiMe3)2-1,3] (1998) (25)
Synthesis, structures and catalytic properties of chelating N,N′-bis(silylated) 1,2-benzenediamidozirconium(IV) chlorides [and a titanium(IV) analogue] and dimethylamides (2001) (24)
Lithiation of Diphenyl(triorganosilyl)methanes (2002) (24)
Nucleophilic attack at pyridine nitrogen and its use to access a novel mono-anionic ligand for iron-based ethylene polymerisation catalysts. (2002) (24)
First Examples of Complexes Containing η1‐Bonded Phosphaalkynes—Synthesis and Crystal and Molecular Structure of trans‐[Mo(AdCP)2(Et2PCH2CH2PEt2)2] (Ad = adamantyl) (1987) (24)
Crystal engineering : hydrogen-bonded salts of hydroxybenzoic acids for second harmonic generation (1993) (24)
Carbon dioxide activation by "non-nucleophilic" lead alkoxides. (2009) (24)
The crystal structure of bis{tris(trimethylsilyl)methyl}magnesium: an example of two-co-ordinate magnesium in the solid state (1989) (24)
Crystal structure of [Li(tmen)2][Li{C(SiMe3)3}2]. A multinuclear magnetic resonance study of tris(trimethylsilyl)methyllithium–tetrahydrofuran(1/2) and –N,N,N′,N′-tetramethylethylenediamine (1/1)(tmen) (1993) (24)
Compounds of Germanium, Tin, and Lead Containing the Ligand C(SiMe3)2(SiMe2C5H4N-2) (2001) (24)
Crystal growth and hydration effects in morpholinium 4-hydroxybenzoate (M4HB) (2001) (24)
The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)](Ln = La, Ce) (1996) (24)
Syntheses, structures and reactions of a series of beta-diketiminatoyttrium compounds. (2008) (24)
Synthesis and Structures of Crystalline Lithium, Sodium, Potassium, and Magnesium Silylmethyls Derived from the Ligands [CH(SiMe3){SiMe3-n(OMe)n}]- (n = 1, 2), [CH(SiMe2OMe)2]-, and [CH(SiMe3)(SiMe2Ph)]- (2003) (24)
Exploring the auxiliary co-ordination sphere of tripodal amino(triamido) actinide complexes (1995) (24)
Insights into the making of a stable silylene. (2006) (23)
C60F36: there is a third isomer and it has C1 symmetry. (2002) (23)
Copper(II) adducts with N,N,N′,N′-tetramethylethane-1,2-diamine and attempts to prepare trinuclear derivatives (2001) (23)
Synthesis of Tris(tetramethylcyclopentadienyl) Derivatives of the Actinide Metals: Molecular Structure of [UCl(.eta.-C5Me4H)3] (1994) (23)
Single crystal X-ray structure of tetrahedral C60F36: the most aromatic and distorted fullerene. (2002) (23)
Novel transition metal phospha-alkyne complexes. X-Ray crystal and molecular structure of a side-bonded ButCP complex of zerovalent platinum, Pt(PPh3)2(ButCP) (1981) (23)
Crystalline Na-Si(NN) derivatives [Si(NN)= Si((NCH2tBu)2C6H4-1,2)]: the silylenoid [Si(NN)OMe]-, the dianion [(NN)Si-Si(NN)]2-, and the radical anion c-[Si(NN)]3-. (2005) (23)
The first mononuclear η8-coordinated pentalenecomplex: synthesis and molecular structure of[Ta{η8-C8H4(SiMe3)2-1,4}Cl3] (1997) (23)
Cycloaddition reactions of the titanium imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe 3)2}(py)] with ButCP and MeCN (2000) (23)
Synthesis and structural characterisation of the 3,5-di-tert-butyl-1,2,4-triphospholyl complexes of monovalent gallium and thallium, [M(η5-P3C2Bu2t)], M=Ga, Tl (2002) (23)
A new bonding mode for the bicyclic guanidinate, [hpp]−, in the tetrametallic yttrium oxide cluster, Y4(hpp)8Cl2(μ4-O) (2004) (23)
The synthesis and properties of the transannularly bonded electron-rich olefin derived from 1,4,8,11-tetra-azacyclotetradecane; X-ray crystal structure of the chelating cis-dicarbenerhodium(I) salt obtained therefrom (1980) (23)
Lipophilic lithium alkoxides or dialkylboroxides; X-ray structures of [Li(µ-OR′)]2 and Li(OBR2)(tmeda), [tmeda =(Me2NCH2)2, R = CH(SiMe3)2, R′= CBut3 or BR2] (1989) (23)
SYNTHESIS AND STRUCTURES OF TIN(II) AND LEAD(II) 1-AZA-ALLYLS; THE N(SIME3)C(PH)C(SIME3)2- LIGAND (1998) (23)
Preparation, crystal structure, and reactivity of bis {tris(trimethylsilyl) methyl} magnesium (1994) (23)
First structural characterisation of 1,2,4-selenadiphosphole and 1,2,4-telluradiphosphole ring systems. Crystal and molecular structures of the η1-complexes [M(CO)5(P2SeC2But2)] (M=Cr, W) and [W(CO)5(P2TeC2But2)] (1999) (23)
Preparation and ligating properties of the first example of a 1,2,4-triphosphole, P3C2But2R [R = CH(SiMe3)2]: crystal and molecular structures of P3C2But2CH(SiMe3)2, trans-[PtCl2(PEt3){P3But2CH(SiMe3)2}]and[Fe2(CO)6{µ-P3C2But2CH(sime3)2}] (1995) (23)
Synthesis and X-ray crystal structure of polymeric and dimeric copper(I) cyanide complexes incorporating a bicyclic guanidine ligand (2001) (22)
1,4-Bis(trimethylsilyl)but-2-ene-1,4-diyl Complexes of Lithium, Magnesium, Aluminum, and Gallium (1995) (22)
Reaction of the silylene Si[(NCH2But)2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R](M = Li, Na or K; R = SiMe3 or SiMe2Ph). (2004) (22)
A DINUCLEAR TIN(II) AMIDE, A META-STANNYLAMINOCYCLOPHANE AND ITS ORTHOSTANNYLATED DERIVATIVE, A DIMERIC TRINUCLEAR TIN(II) CLUSTER (1997) (22)
Preparation of new vanadium(II) iodides and crystal structure of hexakis(acetonitrile)vanadium(II)(tetraiodide) (1994) (22)
Synthesis and crystal structures of new complexes of di- and tribenzyltin N-ethyl and N-benzyl-2-amino cyclopent-1-ene-1-carbodithioates (2002) (22)
Synthetic and Structural Studies on the Cyclic Bis(amino)stannylenes Sn[(NR)2C10H6‐1, 8] and their Reactions with SnCl2 or Si[(NCH2But)2C6H4‐1, 2] (R = SiMe3 or CH2But) (2004) (22)
Pyrazolonato complexes of uranium. Crystal structures of bis-oxobis(1-phenyl-3-methyl-4-acetylpyrazol-5-onato)aquouranium(VI) and Bis-oxobis(1-phenyl-3-methyl-4-benzoylpyrazol-5-onato(propanol)uranium(VI) (1990) (22)
Structural diversity in organolithium -sodium and -potassium cycanocuprates (2000) (22)
Oxidative addition reactions of alkyl halides with the group 13 carbene analogue [In{N(Dipp)C(Me)}2CH] (Dipp=2,6-iPr2C6H3). (2007) (22)
The First Distibabutadiene: Synthesis and Structure of trans‐1,4‐Bis(trimethylsiloxy)‐1,4‐bis(2,4,6‐tri‐tert‐butylphenyl)‐2,3‐distibabutadiene (1995) (22)
Synthesis, structure, and reactivity of a µ-bis(dialkylphosphido)-dilithium [Li(µ-PR2)]2[R = CH(SiMe3)2] (1984) (22)
An ether-free, internally coordinated dialkylcalcium(II) complex (2009) (22)
Three-coordinate bis(phosphinimino)methanide derivatives of 'open shell' [M(II)] (M = Mn, Fe, Co) transition metals (2004) (22)
Carbene complexes: XXII. Preparation, properties and structures of the N,N-functionalized bis(amino)carbenemolybdenum(O) carbonyls [Mo(CO)4 {CN(CH2CH:CH2)(CH2) 2N}(CH2CH:CH2)}] and Mo(CO)3{CN[(CH2)3PPh2] (CH2)2N {(CH2)3PPh2}]n☆ (1993) (22)
Preparation and crystal structure of [itris(trimethylsilyl)methyl]diphenylborane (1984) (22)
The crystal structure of 4-methyl-2,6-dibenzoylphenol and its conversion into a mononuclear cobalt(III) complex by treatment with cobalt(II) chloride and propane-1,3-diamine (2002) (22)
Novel monoanionic di-N,N′-centred chelating ligands and their C1 and C2 symmetrical zirconium complexes (1996) (22)
Studies of the 24-electron nido-5-vertex clusters [M(η4-P2C2But2)] (M = Ge, Pb, Sn): Synthesis and characterization of [M(η4-P2C2But2)] (M = Ge, Pb), [Sn(η4-P2C2But2){W(CO)5}n] (n = 1, 2), and [I2GeP2C2But2] and the Mössbauer spectrum of [Sn(η4-P2C2But2)] (2003) (21)
A MIXED-VALENCE URANIUM(III/IV) BIMETALLIC ; STRUCTURE, MAGNETISM AND REACTIVITY (1996) (21)
A novel monomeric alkyl-lithium compound. Crystal structure of [Li{C(SiMe2Ph)3}(tetrahydrofuran)] (1983) (21)
Crystal structures of organometallic compounds of lithium and magnesium containing the bulky ligands C(SiMe3)2(SiMe2X) X=Me, Ph, NMe2, or C5H4N-2 (2001) (21)
Syntheses and 31P NMR studies of ruthenium(II), rhodium(I), and rhodium(III) complexes containing η5-P2C3tBu3 and η5- and η1-P3C2tBu2 ligated ring systems. Crystal structures of [Rh(η5-P2C3tBu3)(η4-COD)] (COD = 1,5-cyclooctadiene) and the novel hydrido-η1-triphosphacyclopentadienyl complex [RhH(η1-P (1993) (21)
Novel two-coordinate germanium(II) arylamides: Ge(NHAr)2, ArN[Ge(NHAr)]2(µ-NAr) and [Ge(µ-NAr)]22, and the X-ray structures of 2 and Sn(NHAr)2(Ar = C6H2But3-2,4,6) (1990) (21)
Mono and diterpenes from seeds of Xylopia sericea (2001) (21)
Synthesis and structures of the heavier alkali metal alkyls; the X-ray structures of [Na(µ-R)]∞ and [Rb(µ-R)(pmdeta)]2[R = CH(SiMe3)2, pmdeta =(Me2NCH2CH2)2NMe] (1993) (21)
New group 14 element(IV) β-diiminates and a Sn(II) analogue (2009) (21)
Synthesis, structure and reactivity of the hexaphospha-titanocene, bis-(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)titanium(II) (1999) (21)
Insertion reactions of beta-diketiminate-stabilised calcium amides with 1,3-dialkylcarbodiimides. (2008) (21)
Parallel Metallocenes of Germanium Tin and Lead (2000) (21)
The first monomeric prochiral tin(II) complexes Sn[N(SiMe3)2]X [X = OC6H2But2-2,6-Me-4, 1 or NCMe2(CH2)3CME2, 2]; the X-ray structure of 1 and oxidative addition reactions of 2 (1992) (21)
Platinum–phosphorus bond lengths and nuclear magnetic resonance coupling constants in complexes of tri(n-alkyl)- and tricyclohexylphosphines. Crystal and molecular structure of trans-di-iodobis(trimethylphosphine)platinum(II) (1977) (21)
Synthesis and Structures of Alkali Metal Amides Derived from the Ligands [N(SiMe2Ph)(SiMe3)]−, [N(tBu)(SiMe3)]−, [N(Ph)(2‐C5H4N)]−, and [N(2‐C5H4N)2]− (2003) (21)
Penta- and hexaphospha ferrocenes as ligands: crystal and molecular structures of [Fe(η5-P3C2tBu2)2W(CO)5], [Fe(η5-P3C2tBu2)(η5-P2C3tBu3)W(CO)5] and the novel triruthenium carbonyl cluster complex [Fe(η5-P3C2tBu2)2Ru3(CO)10] containing two interlinked η5-P3C2tBu2 ring systems (1992) (21)
The nature of the co-ordinate link. Part 11. Synthesis and phosphorus-31 nuclear magnetic resonance spectroscopy of platinum and palladium complexes containing side-bonded (E)-diphenyldiphosphene. X-Ray crystal and molecular structures of [Pd{(E)-PhPPPh}(Ph2PCH2CH2PPh2)] and [Pd{[(E)-PhPPPh][W(CO)5] (1984) (21)
Stereochemistry of catabolism of the DNA base thymine and of the anti-cancer drug 5-fluorouracil (1985) (21)
Tuning low-coordinate metal environments: high spin d5–d7 complexes supported by bis(phosphinimino)methyl ligation (2003) (21)
Synthesis and characterisation of the first stable, heteroleptic silylstannylenes† (1997) (21)
Dimesitylzinc: A strictly 2-coordinate, homoleptic diarylzinc compound (2003) (21)
L-PROLINE 2,5-DIHYDROXYBENZOIC ACID (1/1): A ZWITTERION CO-CRYSTAL (1995) (21)
Silylmethyl and related complexes VIII. Bis[bis(trimethyl)silylmethyl]manganese(II): Its synthesis, properties, and crystal structures of its tetrahydrofuran and bis(dimethylphosphino)ethane adducts☆ (1990) (21)
An isolable radical anion and dianion of a cyclotetrasilane: synthesis and structure of [Si(1,2-(NEt)2C6H4)](4)(-)(.-) and [Si(1,2-(NEt)2C6H4)](4)(2-). (2004) (21)
The synthesis and X-ray structures of ytterbocene(II) complexes containing pendant pyridyl groups, [Yb(Cpx)2] (Cpx=η5-C 5H3(R)[CMe2(CH2)nC5H4N-2]-1,3; R H or SiMe3 and n = 0 or 1 (1994) (20)
Rhodium(I) and iridium(I) complexes of Ph2P(S)CH2P(S)Ph2, bis(diphenylphosphino)methane disulfide (1991) (20)
Adducts of bis(O,O-alkylene dithiophosphates) of nickel(II) with 2,9-dimethyl-1,10-phenanthroline. X-ray crystal and molecular structure of(2,9 -dimethyl-1,10-phenanthroline)bis(4,4,5,5-tetramethyl 1,3,2-dioxaphospholane-2-thione-2-thiolato)nickel(II) (1989) (20)
Carbene complexes XXIV. Preparation and characterization of two enetetramine-derived carbenerhodium(I) chloride complexes RhCl(LR))3 and [RhCl(COD)LR] and the preparation and X-ray structures of the enetetramine L2R and its salt [L2R][BF4]2 (1995) (20)
Organometallic chemistry of the actinides (1998) (20)
The molecular structure of [dimethyl(phenyl)silyl]tris(trimethylsilyl)methane (1981) (20)
The use of trimethylsilyl iodide as a synthon in coordination chemistry (2002) (20)
Novel double alkoxides of titanium(IV) and iron(II)/(III): synthetic, structural and spectroscopic studies (2002) (20)
Remarkable carbene-induced transformation of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene, P3C3But3, to the 1,2,4-triphosphole, P3C2But2CBut(carbene). Crystal and molecular structure of the planar triphosphole complex [Mo(CO)3(η5-P3C2But2CBut(carbene))] [carbene = C(N(Me)C(Me)=C(Me)N(Me))] (2000) (20)
Salviarin, a new diterpenoid from Salvia splendens (1978) (20)
A Lewis-basic, dionio-substituted phosphane. (2007) (20)
Synthesis and crystal structures of new complexes of di- and tribenzyltin 2-amino-1-cyclopentene-1-carbodithioates (2006) (20)
Synthesis, crystal and molecular structure of [Sn(eta 4-P2C2But2)]: the first non transition metal 1,3-diphosphacyclobutadienyl compound. (2002) (20)
Galactose-conjugates of the oseltamivir pharmacophore--new tools for the characterization of influenza virus neuraminidases. (2009) (20)
Hydrogen bonding in organosilicon hydroxides: crystal structures of dicyclohexylsilanediol and bis(hydroxydimethylsilyl)bis(trimethylsilyl)methane (1986) (20)
Unusual alkali metal a- or -phenyl(trimethylsilyl)amides (2000) (20)
C2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends. (2005) (20)
Reactions of a highly crowded cyclic stannylene with iodoalkanes, enones, and dienes. Inhibition of nucleophilic substitution at tin(IV) centers (2002) (20)
Metal (Li, K, SnII and HgII) complexes of the 1,3-diazaallyl [N(R)C(Ph)NC(Ph)CR2]– (R = SiMe3) (1998) (20)
Crystal and molecular structure of chloro(triphenyl phosphite)gold(I) (1977) (20)
Synthesis and Reactivity of Binuclear Bis(μ-aryloxo) Complexes of Palladium and Platinum. Crystal Structure of [NBu4][Pt(C6F5)2(OC6H4NO2-p)(CO)] (1996) (20)
A cis-influence of π-bonding ligands in two rhodium() complexes (1969) (20)
Preparation and some reactions of the compounds HgVsi2, CdVsi2, and Hg(Vsi)Br [Vsi = (Me3Si)2 = CHMe2Si)C]. Crystal structure of CdVsi2 (1987) (20)
Bulky metal aryloxides, arylamides and sulphur and phosphorus analogues—III. Aluminium compounds derived from 2,4,6-TRI-t-butylaniline; X-ray structure of [{μ-NHC6H2But2-4,6-C(Me)2CH2-2}]2 ☆ (1990) (20)
The crystal structure of [(pmdeta)Li(µ-Cl)Li(pmdeta)][Li{C(SiMe3)3}2][pmdeta = Me2N(CH2)2NMe(CH2)2NMe2]. A novel linear chlorine-centred cation (1986) (19)
Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl2(PEt3)(PPhCPhCPh)], cis-[Ptl(PPh3)(CPhCPhPPhMe)] and [(Et3P)2Pt(CPhCPhPPh)W(CO)5] (1991) (19)
The preparation and crystal structures of [(Me3Si)3C]PhSi(OH)2 and [(Me3Si)3C]PhSi(OMe)OH (1985) (19)
Complexes of organoaluminium compounds. Part 13. Preparation and nuclear magnetic resonance spectra of the arylamido-compounds AlMe2(NHR′)(R′= Ph, C6H4Me-o, C6H4Me-p, C6H3Me2-2,6) and the imido-compounds AlMe(NR′). Crystal and molecular structures of [{AlMe2(NHC6H4Me-o)}2] and [{AlMe(NPh)}6] (1985) (19)
Attachment to manganese or cobalt of a bulky tri(organosilyl)methyl ligand containing an NMe2 or an OMe donor group (2002) (19)
The influence of a 15-hydroxy group on the rearrangement reactions of steviol and its 16,17-epoxide (1990) (19)
Syntheses and Structures of Diruthenium Triple-Decker Complexes with Bridging 1,2,4-Triphospholyl and 1-Arsa-3,4-Diphospholyl Anions (1995) (19)
Synthesis and Molecular Structures of Uranium and Thorium Diamidoamine Complexes (2003) (19)
Transition-metal complexes of two valence tautomers of a bulky phenoxide, 2,6-Bu-t2-4-MeC6H2O− (ArO−); preparation and crystal and molecular structure of a phenoxytitanium(III) and a cyclohexadienonylrhodium(I) complex, [Ti(η-C5H5)2 OAr] and [Rh(ArO-η5)(PPh3)2] (1980) (19)
New cage isomers derived from hexaphospha-pentaprismane, P6C4tBu4 (2003) (19)
Stereoselective synthesis of polyfunctionalised hydroxylated cyclopentanes from dihydroxylated 2-cyclopentenone derivatives (2001) (19)
Routes to titanium tetrazole complexes (2004) (19)
Preparation and crystal structures of aluminium hydride adducts with tetrahydrofuran [AlH3·OC4H8]2 and AlH3·2OC4H8 (1993) (19)
A study of the molecular and electronic structures of the indium(I) phospholyls [In(η5-P2C3But3)] and [In(η5-P3C2But2)] by X-ray diffraction, photoelectron spectroscopy and density functional theory (2000) (19)
Novel transition metal phospha-alkyne complexes: tBuCP acting as a 6 electron donor ligand. Synthesis, crystal and molecular structure of [Co2(CO)6(μ-tBuCP)W(CO)5] (1982) (19)
Metallocene derivatives of early transition elements. Part 1. Niobium(IV) chlorides, chloroalkyls, and dialkyls [Nb(η-C5H4X)2RR′], and the crystal and molecular structure of [Nb(η-C5H5)2(CH2Ph)2] (1981) (19)
Crowded organometallic compounds of the alkali metals with diphenylphosphino substituents in the organic group (2000) (19)
Synthesis and 171Yb-{1H} nuclear magnetic resonance spectra of ytterbium(II) aryloxides [Yb(OR′)2(L)n][(L)n=(OEt2)2, (thf)2, (thf)3, (pyridine)2 or Me2PCH2CH2PMe2] and [{Yb(µ-OR′)(X)}2](X = OR′ or NR2)(R′= C6H2But2-2,6-Me-4, R = SiMe3, thf = tetrahydrofuran) (1995) (19)
Isolation and spectroscopic characterisation of C60F17CF2CF3 and isomers of C60F17CF3; insertion of :CF2 into fluorofullerene C–F bonds (2000) (19)
Preparation and X-ray structure of [Ge{N(SiMe3)2}2(µ-O)]2, a rare 1,3-cyclodigermoxane (1992) (19)
New FeII starting materials: preparation, characterisation and structural features of iron halide complexes with alcohol ligands (2004) (18)
Synthesis and reactivity of [Pd2L2R2(µ-OH)2]-type complexes (L = PEt3 or PPh3; R = Me, PhCH2 or Ph). Crystal structure of [Pd2(PPh3)2Ph2(µ-OH)(µ-NHC6H4OMe-p)] (1997) (18)
Neutral isonitrile adducts of alkali and alkaline earth metals (1998) (18)
Synthetic, structural and theoretical studies on new aromatic 1,2,4-azadiphosphole ring systems: crystal and molecular structure of P2C2But2NPh (1999) (18)
Novel(silylimino)diarylphosphoranyl(trimethylsilyl)methyl-C,Nligands[CH(SiMe3)PPh2NSiMe3]- ([LL′]-) and[CH(SiMe3){Ph(1,2-C6H4)PNSiMe2}]-([LL″]-) and the structures of[Li(LL″)]2 and[Pb(LL′)2] (1997) (18)
Synthesis and structures of some heterometallic [(Li, Y)2, (M3, Ce) (M = Li or Na), (Li, Zr2) and (Li, Zr)4] oligomeric diamides derived from 1,2-bis(neopentylamino)benzene. (2006) (18)
Novel lithium 3-sila- and 3-germa-β-diketiminates†‡ (1998) (18)
Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{μ-N(Ph)R}-trans)2(μ-tmen)]∞ (R = SiMe3 1 or CH2But 2) and [Li{μ-N(Ph)CH2But}(OEt2)]2 (2001) (18)
Synthesis and characterisation of 1-alkyl-2-imidazoline complexes ofnoble metals; crystal structure oftrans-[PtCl2{NC(H)N(Et)CH2CH2}(PEt3)] (1997) (18)
Crystal polymorphism in pendimethalin herbicide is driven by electronic delocalization and changes in intramolecular hydrogen bonding. A crystallographic, spectroscopic and computational study (1998) (18)
Synthesis and structures of some bimetallic (Li/Ca, Li/Zn, Li/Li) diamides derived from 1,2-bis(neopentylamino)benzene and of Li2[{N(SiMe2NPr(i)2)}2C6H4-1,2](thf)3. (2006) (18)
New dithiolate-bridged rhodium complexes (1993) (18)
Reactivity of [HC{(C(Me)N(Dipp))}2Ca{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with C–H acids: Synthesis of heteroleptic calcium η5-organometallics (2006) (18)
Lipophilic halogenozirconocene(III) complexes: [{Zr[η-C5H3(SiMe3)2-1,3]2(µ-Cl)}2], [NBun4][Zr{η-C5H3(SiMe3)2-1,3}2Cl2] and [Zr{η-C5H3(SiMe3)2-1,3}2Cl2] (1992) (18)
A comparative study of the behaviour of N-trimethylsilyl and N-neopentyl-anilines and 1,2-diaminobenzenes towards trimethylalane; X-ray structures of nine Al–N compounds (2003) (18)
Organometallic chemistry of the actinides. Part 3 novel 1-aza-allyl- and β-diketiminatothorium chlorides; X-ray structures of [{Th(L⎴L')2(μ3-Cl)(μ-Cl)2K(OEt2)}∞] and [Th(L⎴L)2Cl2] [LL′ = N(SiMe3)C(But)C(H)SiMe3; LL = N(SiMe3)C(Ph)2CH] (1997) (18)
Cycloaddition reactions of a 1,2,4-triphosphacyclopenta-1,3-diene. Synthesis, crystal, and molecular structure of the novel hexaphosphorus cage compound P6C4But4H2 containing five directly bonded phosphorus atoms (1989) (18)
The first structurally authenticated divalent lanthanide siloxide derivative, [Yb(OSiMe2 tBu) (η2-dme) (μ-OSiMe2 tBu)]2 (1996) (18)
An η2 transition state for the insertion of M(PR3)2 fragments (M = Pd or Pt) into the phosphorus–carbon bonds of pentacarbonyl(phosphirane)tungsten complexes (1993) (18)
Unprecedented Oxidative Chlorosilylation Addition Reactions to a Diarylgermylene and -stannylene (2002) (18)
Solid- and solution-state structures of indium 'alkene analogues'. (2007) (18)
The reaction of (Me3Si)3CBr with Mg in tetrahydrofuran (THF) or diethyl ether. Crystal structure of (Me3Si)3CMg(μ-Br)3Mg(THF)3 (1994) (18)
Butyl metal aryloxides, arylamides, and sulphur and phosphorus analogues—II. Synthesis and characterization of novel bulky alkoxides and aryloxides of aluminium; X-ray structure of [Al(μ-OCH2Ar)Me2]2 (Ar = C6H2Bu3t-2,4,6) (1990) (18)
Novel Chelated Diorganolithate Ion [CH2SiMe2C(SiMe3)2LiC(SiMe3)2SiMe2CH2]-and Highly Crowded Chelated Organomercury Compound [CH2SiMe2C(SiMe3)2HgC(SiMe3)2SiMe2CH2] (1996) (18)
Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines. (2008) (18)
The crystal structure of tris (phenyldimethylsilyl) methane (1984) (17)
A novel high-yield route to organic derivatives of group 2 metals; X-ray structure of [{Ba(OTf)2}4(py)14]·py (OTf = OSO2CF3) and NMR spectral characterisation of [Ba(NR2)(µ-NR2)2Na(thf)2](R = SiMe3) (1994) (17)
Syntheses and 31P NMR studies of some cycloocta-1,5-dienerhodium(I) complexes containing coordinated 1,3-DI-t-butyl- 2,4-dihalogenocyclodiphosphazanes, [PXNtBu]2 (X = Cl, F) and related ligands. Crystal and molecular structure of bis(chloro)(cycloocta-1,5-diene)1,3-di-t-butyl-2,4-difluorocyclodiphos (1983) (17)
The first monoorganolead(II) derivative, [PbR(-Cl)}2] where R = C(SiMe2Ph)3 (1995) (17)
Complexes of organoaluminium compounds. Part IX. Crystal and molecular structure of hepta-µ3-methylimido-heptakis(methylaluminium) a cage compound in the series of oligomers [R1XYR2]n (1976) (17)
Metal β-diketiminates revisited: ansa-CH2-bridged bis(β-diketiminate)s of lithium and aluminium having diverse structures (2004) (17)
Synthesis and structural characterisation of bis(trimethylsilyl)amidotin(II) triflate [{Sn(NR2)(μ-η2-∞ (R=SiMe3, −OTf=−OSO2CF3) (2000) (17)
The role of lithium 1,3-bis(trimethylsilyl)-1-aza-allyls in phosphorus chemistry (1997) (17)
Synthesis and molecular structure of tris(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)molybdenum(0) (1994) (17)
Variable coordination behaviour of pyrazole-containing N,P and N,P(O) ligands towards palladium(II). (2007) (17)
Synthesis and Structures of the Crystalline Heavier Alkali Metal Alkyls: X-ray Structures of [K(μ-R){O(Me)But}]∞, [(pmdeta)K(μ-R)K(μ-R)2K(μ-R)K(pmdeta)], and [Cs(μ-R)(tmeda)]∞ (R = CH(SiMe3)2) (2000) (17)
Yttrium iodide and bis(trimethylsilyl)methyl complexes of the chelating diamide [ArN(CH2)3NAr]2- (Ar = 2,6-iPr2C6H3) (2002) (17)
Structural and electronic comparison of 15- to 17-electron dichloro-complexes of molybdenum and rhenium: electrochemical behaviour and crystal structures of trans-[ReCl2(dppe)2]A (A = Cl or BF4; dppe = Ph2PCH2CH2PPh2), trans-[ReCl2(dppe)2] and [NBun4]2[trans-MoCl2(dppe)2][BF4]3 (1993) (17)
The synthesis and characterisation of some divinyldisiloxane—(tertiary phosphine) complexes of platinum(0) and nickel(0) (1997) (17)
Use of 1,3‐diphosphacyclobutadiene complexes in the synthesis of mixed metal aggregates containing cobalt, rhodium, and platinum: Structure of a hexarhodium complex (1991) (17)
A 1-Aza-2-silacyclobut-3-ene and an Alkyne from [Li{Si(SiMe3 )3 }(thf)3 ] and the Isocyanide 2,6-Me2 C6 H3 NC. (1999) (17)
Crystal and molecular structure of bis[1,3-bis(diphenylphosphino)propane]platinum(0): a reevaluation (1990) (17)
Synthesis and structures of compounds of Groups 11 and 12 containing the ligand C(SiMe3)2(SiMe2C5H4N-2) (2002) (17)
An Unusual Alkyltrihydroaluminate. Crystal Structures of [AlH2{C(SiMe3)2(SiMe2OMe)}(μ-H)Li(THF)], [AlCl2{C(SiMe2OMe)(SiMe3)2(THF)], and [Li{C(SiMe2OMe)(SiMe3)2}(THF)2] (THF = Tetrahydrofuran) (1998) (17)
Phosphaalkyne-bridged clusters: Synthesis, characterization, and nonlinear optical properties of Fe4Se2(mu-Se2PCBut)(CO)(11) (1997) (17)
The stable silylene Si[(NCH2But)2C6H4-1,2]: Reactions with Group 14 element halides (2006) (17)
Generation and interconversions of the di- and tri-nuclear platinum complexes [Pt2H2(dppe)2], [Pt2H3(dppe)2]+, and [Pt3H3(dppe)3]+. Crystal and molecular structure of [Pt3H3(dppe)3]+[BEt4]–, (dppe = Ph2PCH2CH2PPh2) (1988) (17)
Planar-chiral imidazole-based phosphine ligands derived from [2.2]paracyclophane. (2010) (16)
First example of a 1,2,4-triphosphabuta-1,3-diene complex: synthesis and crystal and molecular structure of [Co(η5-C2R2P3)(η4-C2R2HP3)](R = But) (1988) (16)
An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus–carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane (1989) (16)
Synthesis and crystal structures of organometallic compounds containing the ligands C(SiMe3)2(SiMe2H) and C(SiMe2Ph)2(SiMe2H) (2004) (16)
Preparation of isocyanide and mixed dinitrogen–isocyanide complexes of rhenium(I) from reactions of trans-[ReCl(N2)(PMe2Ph)4], mer-[Re(S2PPh2)(N2)(PMe2Ph)3], or mer-[Re(S2CNEt2)(N2)(PMe2Ph)3] with methyl isocyanide; crystal structure of mer-[Re(S2PPh2)(N2)(CNMe)(PMe2Ph)3] (1987) (16)
Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition (1999) (16)
The first example of an intermolecular weak (agostic)γ-methyl-metal interaction: the low temperature single crystal X-ray and neutron diffraction structure of (MgR2)∞[R = CH(SiMe3)2] (1990) (16)
First syntheses, structural and theoretical studies ofη5-1,2,4-triphosphole metal tricarbonyl complexes of Cr, Moand W (1997) (16)
Double-Sandwich Pentalene Complexes M2(pent†)2 (M = Rh, Pd; pent† = 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding (2012) (16)
Synthesis and characterisation of twelve Sn(IV) diaryls and formation of a Sn(III) triaryl. (2009) (16)
Unusual molecular structures of some sterically hindered lithium amides: electron diffraction results on gaseous [Li{N(SiMe3)2}]2 and X-ray data on crystalline monomeric Li(NHAr)(tmeda)(Ar = C6H2But3-2,4,6; tmeda = Me2NCH2CH2NMe2) (1984) (16)
Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)}2]2– [N{N″}2]2–. Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N″}2)}2(µ-H)2] (1999) (16)
Synthesis and reactivity of alkyl-palladium N-heterocyclic carbene complexes. (2007) (16)
Stepwise reduction of a phosphaalkyne PC bond to a phosphaalkene and a phosphine at the FeH(dppe)2 centre. Crystal and molecular structure of the η1-co-ordinated phosphaalkyne complex trans-[FeH(η1-PCBut)(dppe)2][BPh4] (1998) (16)
Mononuclear tantalum (V) pentalene complexes: synthesis of [Ta{η8-C8H4(1,4-SiiPr3)2}X3] (X = CH3, Cl, I) and the X-ray crystal structures of [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)3], [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)2Cl], [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)Cl2] and [Ta{η8-C8H4(1,4-SiiPr3)2}I3] (2004) (16)
Reactions of ytterbium(II) amides with various Brønsted acids, CS2 or LiNR2; crystal structures of [{Yb(NR2)(µ-OCBut3)}2] and [Yb(OCBut3)2(thf)2](R = SiMe3, thf = tetrahydrofuran) (1995) (16)
Phosphorus(III and V)– and arsenic(III)–nitrogen metallacycles derived from the bulky arylamido ligand NHAr (Ar = C6H2But3-2,4,6); X-ray structures of ArNPN(Ar)AIMe2 and PAr(NHAr)2 (1986) (16)
Reaction of trimethylgallium with tricarbonyl-η5-cyclopentadienyl-hydridotungsten and with dicarbonyl-η5-cyclopentadienylhydrido(triphenylphosphine)tungsten. Crystal and molecular structure of µ3-gallio-tris(tricarbonyl-η5-cyclopentadienyltungsten) (1975) (16)
Hydrogen-bonding interaction between a hydroxy group and the π-electrons of an aryl group. Crystal structure of [tris(dimethylphenylsilyl)methyl]methylsilanol (1991) (16)
Synthesis and structures of a 3-sila-beta-diketiminatomagnesium bromide, ketenimide and triflate. (2005) (16)
Poly(guanidyl)silanes as a new class of chelating, N-based ligand. (2004) (16)
Novel η2-ring edge coordination in the triphosphaferrocene complex [Fe(η5-C5H5)(η5-P3C2tBu2)Rh(η5-C5Me5)CO] (1999) (16)
Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds; a Spectroscopic and Crystallographic Study (2006) (16)
cis- and trans-Influences in platinum(II) complexes. X-Ray crystal-structure analysis of cis-dichloro(triethylphosphine)(trifluorophosphine)platinum(II) (1978) (16)
Synthetic and structural studies on some organic compounds of zirconium (1989) (16)
Extension of ring switching strategy to the glutamate antagonist 2-(pyrimidin-2,4-dione-5-ylmethyl)-(2S)-glycine and related compounds with two chiral centres (2000) (16)
Synthesis and structural characterization of an unusual η3-ligated 1,3-diphosphacyclobutadiene molybdenum complex via cyclodimerization of a phosphaalkyne. Crystal structure of [Mo(η5-C9 H7)(CO)2P-η3-(tBu)CPC(tBu)PFBF3] (1994) (16)
Subvalent group 14 metal compounds: XV. Germanium and tin amides M(NR2)2 as ligands in carbonylchromium(0) chemistry. The crystal structure of the compounds cis-Cr (CO)4{Sn(NR′2)2}2 M = Ge or Sn, R′ SiMe3 or NR2 = NCMe2(CH2)3C Me2☆ (1993) (16)
Preparation and single crystal structure determination of the solvated intercalate C60·I2·toluene (1993) (16)
The effect of P-cyclohexyl groups on the coordination chemistry of phosphaguanidinates. (2006) (16)
New mono- and bis(pentafluorophenyl)palladium(II) complexes with iminophosphine ligands. Crystal structure of [Pd(C6F5)(SC6H5)(o-Ph2PC6H4–CHNiPr)] (2001) (16)
Preparation and crystal structures of the crowded triorganotin isothiocyanate (PhMe2Si)3CSnMe2NCS and nitrate (PhMe2Si)3CSnMe2ONO2 (1993) (16)
Some [tris(trimethyl)- and [tris(dimethylphenyl)-silyl]methyl derivatives of phosphorus. The crystal structure of [tris(dimethylphenylsilyl)methylphosphonous dichloride (1989) (15)
Metal secondary amides derived from the highly hindered 2,4,6-tri-t-butylaniline; X-ray crystal structure of trans-[Li(µ-NHAr)(OEt2)]2(Ar = C6H2But3-2,4,6) (1984) (15)
SYNTHESIS AND CHARACTERIZATION OF SN(ETA 5-C5ME5)CL AND SNETA 5-C5ME4(SIME2BUT)CL (1997) (15)
C 2 -symmetric Schiff-base complexes of zirconium; structural analogues of the ansa-metallocenes (1996) (15)
C1 C70F38 contains four planar aromatic hexagons; the parallel between fluorination of [60]- and [70]fullerenes. (2005) (15)
{Tris[(dimethylamino)dimethylsilyl]methyl}magnesium Iodide. A Grignard Reagent without a Carbon−Magnesium Bond? (1997) (15)
Synthesis and structural characterisation of the first example of a 3, 3′-diphospha-1,1′-biphospholyl ring system; crystal and molecular structure of P4C6But6 (1993) (15)
Synthesis, crystal and molecular structure of the first metal complex [Pt(PPh3)2{η2-AsC(C6H2But3)}] derived from an arsaalkyne (1994) (15)
Synthesis and structural characterisation of new ansa-bis(propene)s and {ansa-bis(allyl)}alkali metal and {ansa-bis(allyl)}transition metal complexes (2000) (15)
Hydrazido(2-) (or isodiazene) complexes of tungsten (1979) (15)
Synthesis and structural characterisation of lanthanide and actinide phosphaorganometallic complexes derived from the 3,5-di-tert-butyl-1,2,4-triphospholyl ring anion, P3C2But−2: Crystal and molecular structures of [M(η5-P3C2But2)2(η2-P3C2But2)] (M = Sc, Y, Tm, and U) (2008) (15)
Samarium(III) Pentalene Sandwich Compounds [Sm(η8-C8H4{SiiPr3-1,4}2)(Cp*)] and [Sm(η8-C8H4{SiiPr3-1,4}2)(η5-C8H5{SiiPr3-1,4}2)] and a Mixed-Valence Hexasamarium Cluster Derived from Sm(II)-Based Solvent Activation (2008) (15)
Stereochemistry of Epoxidation of Some Caryophyllenols. (1997) (15)
Synthesis, structure and electrochemistry of a paramagnetic (1,4-diazabutadiene)thorium complex (1995) (15)
Use of the monomeric η2-phospha-alkyne complex [Pt(PPh3)2(ButCP)] in heterometallic cluster synthesis. Crystal and molecular structure of the novel pentametallic complex [Pd2Pt3(PPh3)5(ButCP)3] (1985) (15)
Synthesis and structures of halides and pseudohalides of bis[2,6-bis(dimethylamino)phenyl]tin(IV). (2009) (15)
Crystal and molecular structures of cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II), cis-RuCl2(PF3)2(PPh3)3, and dichloro(2,7-dimethylocta-2,6-diene-1,8-diyl)(trifluorophosphine)ruthenium(IV), RuCl2(PF3)(C10H16) (1975) (15)
Carbene complexes. Part 21. Synthesis and characterisation of bis(carbene)molybdenum(II) complexes and dimetal(0) complexes of the Group 6 elements containing novel bridging bis(carbene) ligands; X-ray structures of [Mo(CO)2(LEt)2(OSO2CF3)2][LEt=CN(Et)(CH2)2NEt] and [W(CO)5{C(OEt)CH2C6H4CH2C(OEt)-o} (1987) (15)
The use of temporary tethers in the meta photocycloaddition reaction (2004) (15)
Synthesis, crystal and molecular structures of the novel, structurally different, cage compounds P6C4But4SiI2 and P6C4But4GeI2, resulting from intra-molecular coupling of two 1,2,4-triphospholyl rings (2000) (15)
First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph) (1988) (15)
Dilithium diamides [{Li(OC4H8)}2{C20H12(NR)2}](R = SiMe3 or CH2But) derived from R-, S- or R,S-2,2′-diamino-1,1′-binaphthyl derivatives (1996) (15)
Magnetochemistry of the tetrahaloferrate(III) ions. 6. Crystal structure and magnetic ordering in [(pyH)3Cl][FeCl4]2 (1992) (15)
Synthesis and structures of some silylallyl-lithium or -potassium complexes (1999) (15)
Molecular and electronic structures of bis[1,4-bis(trimethylsilyl)cyclooctatetraene] sandwich complexes of titanium and zirconium (1994) (15)
Substituted triazines and pyrimidines from 1,3,5-triazine and a lithium amidinate, alkyl- or 1-azaallyl (2001) (15)
Mixed biphosphine complexes of palladium(0) ; the structure of {bis(diphenylphosphino)ethane}-{bis(dicyclohexylphosphino)ethane} palladium(0) (1993) (15)
Hydrocarbon-soluble, crystalline, four-co-ordinate chloro(aryl oxide)s, dialkylamido(aryl oxide)s and di[bis(trimethylsilyl)cyclopentadienyl]s of ThIV and UIV; X-ray crystal structure of diethylamidotris(2,6-di-t-butylphenoxo)uranium(IV) (1983) (15)
A stable disilacyclopropane: [1 + 2] cycloaddition of the silylene Si[(NCH2But)2C6H4-1,2] with a silene (2004) (15)
Manganese and Cesium Derivatives of the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of Li(THF)2.75(Et2O)0.25(μ-Cl)- MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3 (2000) (15)
Synthesis, properties, and X-ray crystal structure of trans-dichlorotetrakis-(1,3-diethylimidazolidin-2-ylidene)ruthenium(II), a neutral tetracarbenemetal complex (1976) (14)
Synthesis, spectroscopic properties and molecular structure of the paramagnetic complex [(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)]vanadium(II) (1995) (14)
Synthesis, structural studies and fluxional behaviour of η1-ligated 1,2,4-triphosphacyclopentadienyl complexes of palladium(II) and platinum(II). Crystal and molecular structures of trans-[PtCl(P3C2Bu2t)(PEt3)2] and trans-[Pt(P3C2Bu2t)2 (PEt3)2] (1989) (14)
Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph2)] (1986) (14)
beta-Diiminato ligand (L) transformations in reactions of KL with PI3 and I2 [L = {N(C6H3Pr(i)2-2,6)C(H)}2CPh]. (2007) (14)
MOLECULAR AND CRYSTAL STRUCTURE OF THE ADDUCTS OF C60F18 WITH AROMATIC HYDROCARBONS (2002) (14)
Variation of bonding modes in homoleptic tin(ii) 1-azaallyls (1997) (14)
The synthesis of triangulo-trimetal complexes containing both iron(II) and vanadium(II) (2001) (14)
Neutral η-arene complexes of rhodium(I); X-ray structure of η-toluene(η-cyclo-octene)[bis{bis(trimethylsilyl)amido}chlorostannate(II)}]rhodium(I) (1985) (14)
Unusual group 14 metal thiolates and sulphides derived from tris(trimethylsilyl)methanethiol; X-ray structures of [Pb(NR2)(µ-SCR3)]2 and cis-[Ge(CH2Ph)(NR2)(µ-S)]2, (R = SiMe3) (1985) (14)
The first thermochromic vanadium(IV) alkoxide system (2005) (14)
Novel arylimides of phosphorus(III) and arsenic(III)[the arsazene being the first stable compound containing an asIIIN double bond]; X-ray structures of E(NAr)(NHAr)(E = P or As, Ar = C6H2But3-2,4,6) (1986) (14)
The First Example of the Two‐Electron Reduction of a Phosphaalkyne – Synthesis and Structural Characterisation of the Diuranium(IV) Pentalene Complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] (2013) (14)
Boroxide complexes of the group 4 metals : A noninnocent ligand in olefin polymerization (2005) (14)
The crystal structure of the alkyltrihydroborate[(thf)Li(µ-H)3BC(SiMe2Ph)3], (thf = tetrahydrofuran) (1984) (14)
The effect of diamine chain length on the formation of CoIII Schiff base complexes: The unexpected formation of a neutral complex containing a tetradentate ligand (2008) (14)
Synthesis, structure and DNA binding studies of mononuclear copper(II) complexes with mixed donor macroacyclic ligands, 2,6-bis({N-[2&3-(phenylselenato)alkyl]}benzimidoyl)-4-methylphenol (2009) (14)
Insertion reactions of SO2 into Pd-OR bonds: preparation of alkyl sulfito complexes of palladium(II). (2004) (14)
Bimetallic zirconium heterocycles supported by boron-oxygen ligands. (2002) (14)
Reactions of tBuC≡P with cyclooctatetraene-supported titanium imido complexes (2006) (14)
Carbon–Silicon Bond Activation by [Pd(ItBu)2] – the Molecular Structures of [Pd(Me3Si)(ItBu)(μ-I)]2 and [Pd(CH2ItBu)I2] (2009) (14)
Regio- and site-selective cycloadditions (1988) (14)
Novel SnII−AgI Reactions from Sn[CH(SiMe3)2]2 and AgX (X = NCS, CN, NCO, or I): SnII−AgI or SnIVX2 Complexes (1998) (14)
[1 + 4]-Cycloaddition of a stable silylene to 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene (1999) (14)
Electronic structure of [M(η-P3C2But2)(CO)3] (M = Mn or Re): a study by photoelectron spectroscopy and density functional calculations (2001) (14)
Preparation and crystal structure of the argentate complex [Li(tetrahydrofuran)4][Ag{C(SiMe3)3}2] (1984) (14)
The reactions of lithium trimethysilylmethyls with isocyanides; structures and reactions of the derived lithium 1-azaallyls, β-diketiminates and a 1-azabuta-1,3-dienyl-3-amide (2001) (14)
Non-oxo vanadium(IV) alkoxide chemistry: solid state structures, aggregation equilibria and thermochromic behaviour in solution. (2011) (14)
The hydroxylation of the sesquiterpenoid valerianol by Mucor plumbeus (1999) (14)
Iodo(methoxydimethylsilyl)bis(trimethylsilyl)methane: A reagent for the preparation of novel organometallic compounds. Crystal structures of Mg{C(SiMe3)2(SiMe2OMe)}2 and MgI2(OEt2)2 (1996) (14)
The preparation and molecular structure of the highly sterically hindered tris(trimethylsilyl)methylboron compound (Me3Si)3CB(Ph)[O(CH2)4C(SiMe3)3] (1982) (14)
Ligand redistribution reactions as a route to cyclopentadienyl- or 1-aza-allylzirconium(IV) trichlorides and the x-ray structures of [{Cl2(μ-Cl)}2 and [2Cl2] LL′ = N(R)C(But)CHR, R=SiMe3] (1995) (14)
Reactivity of [NBu4]2[{(C6X5)2M(μ-OH)}2] (X=F or Cl; M=Pd or Pt) towards heterocyclic thiones: crystal structure of [NBu4]2[{(C6F5)2Pd(μ-ν2-LL′)}2] (LL′=methylimidazole-2-thiolate) (1998) (14)
The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls. (2005) (14)
Organolanthanide chemistry with bis(trimethylsilyl)methyl- and tert-butyldimethylsilyl-substituted cyclopentadienyl ligands. (1999) (14)
Some reactions of the ethylenebis(phenylphosphido)dilithium reagent [{Li(THF)2}2(PhPCH2CH2PPh)]2, and its X-ray structure (1988) (14)
Aphidicolane metabolites of Cephalosporium aphidicola (1992) (14)
Ring expansions in the reactions of transition metal-carbon .sigma.-bonded chelate complexes (1971) (14)
The chemistry of trichloro[tris(trimethylsilyl)methyl] and trichloro[tris(dimethylphenylsilyl)methyl] complexes of gallium, indium, and thallium. Crystal and molecular structures of [Li(thf)2(µ-Cl)2GaCl-{C(SiMe2Ph)3}]·thf, [Li(thf)3(µ-Cl)InCl2{C(SiMe3)3}], and [{(Me3Si)3C}In(µ-Cl)2{µ-Fe(CO)4}ln{C(Si (1987) (14)
Novel Trimerization of Phosphaalkynes in the Coordination Sphere of Ruthenium Complexes (1994) (14)
Reactions of a stable silylene with halocarbons. (2005) (13)
Novel intramolecular hydrogen-atom transfer in an η4-ligated cycloocta-1,5-diene η-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [Ru(η4-C8H12){η-P3C2But2[CH(SiMe3)2]}] and [Ru(η5-C8H11){η-P3C2But2H[CH(SiMe3)2]}] (1996) (13)
Biotransformation of ent-16β,19-dihydroxykaurane by Cephalosporium aphidicola (1995) (13)
Synthesis and crystal structure of a novel tetraiminediphenolate iron(II) macrocyclic complex: A six-coordinate iron–protein model (2002) (13)
Co-ordination chemistry of tridentate phosphinothiolates; syntheses and structures of [Li4{PhP(C6H3S-2-SiMe3-3)2}2(MeOCH2CH2OMe)2], [Sn2{PhP(C6H3S-2-SiMe3-3)2}2] and [NHEt3][Sm{PhP(C6H3S-2-R-3)2}2(py)2]·2py (R = H or SiMe3, py = C5H5N) (1996) (13)
Novel zirconium borohydride complexes: syntheses and molecular structures of [Zr(.eta.-C8H6(SiMe3)2)(.eta.3-BH4)(.eta.2-BH4)] and [(.eta.-C8H6(SiMe3)2)Zr(.mu.-.eta.6:.eta.4-C8H6(SiMe3)2)(.mu.-H)Zr(.eta.3-BH4)] (1995) (13)
Oxepinobenzofurans—The True Nature of Sterically Hindered “Benzoxetes” (1978) (13)
Syntheses of complexes containing the novel 1,2,3-azadiphosphole and 1,2,5-azadiphosphole ring systems: crystal and molecular structure of [Ir(η5-C5Me5)(η4-(ButCPNButPCBut)] (2000) (13)
Tris(trimethylsilyl)methyl and tris(dimethylphenylsilyl)methyl derivatives of boron. Crystal structures of dihydroxy[tris(trimethylsilyl)methyl]borane and of the lithium–boron complex [(MeOH)2Li(µ-OMe)2B(OMe)2] (1989) (13)
Synthesis of chromium(0) and molybdenum(0) bis (η6-arene) derivatives and their monoelectronic oxidation to [M(η6-arene)2]+ cations (2006) (13)
Tantalum chloride species incorporating anionic and cationic guanidine components (2003) (13)
First structural evidence for complexes containing arsadiphospholyl anions. Crystal structure of the iron(II) complex [Fe(η5-C5H5) (η5-C2tBu2AsP2)W(CO)5] (1994) (13)
The bio-transformation of ent-19-hydroxykaur-16-en-15-one by Cephalosporium aphidicola. (1994) (13)
Insertion reactions of the [RhCl(PPh3)2] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPhCPh)(PPh3)2], [RhCl(PPhCPhCPhCO)(PPh3)2] and the novel dimeric complex [{RhCl(PPhCPhCPhCO)(PPh3)}2] (1992) (13)
cis-Bis(2,2′-bipyridine)bis(pyridine)ruthenium(II) salts: a spectroscopic and structural study (1988) (13)
Facile insertion and halogen migration reactions of the hexaphosphapentaprismane cage P6C4tBu4 with zerovalent and divalent platinum complexes. (2008) (13)
Syntheses of the novel cage compounds P3Se3C3But3 and P3Se4C3But3 and an unusual insertion reaction of [PtCl2(PMe3)] into the Se–Se bond of the latter to give the six-coordinate Pt(IV) complex [PtCl2(PMe3)P3Se4C3But3] (2000) (13)
Iridium(III) hydrides derived from an iridium(I) substrate by oxidative addition and cyclometallation of germanium(II) bis(trimethylsilyl)amide; X-ray structures of [{CH2Me2SiN(R)(NR2)Ge}HIr(µ-Cl)2{Ge(NR2)N(R)SiMe2CH2}IrH{Ge(NR2)2}] and [lr{GeCl(NR2)N(R)SiMe2CH2}(CO)2H{Ge(NR2)2}](R = SiMe3) (1986) (13)
Synthesis and structural characterisation of the first hexaphosphastrontocene [Sr(η5-P3C2But2)2] and its pyrazine adduct (2000) (13)
Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl2(PPhCPhcph)(PEt3)] and cis-[PtI(PPhMeCPhCPh)(PPh3)] (1988) (13)
Five-co-ordinate cobalt(III): crystal and molecular structure of corrole(triphenylphosphine)cobalt(III) (1976) (13)
Facial selectivity in the hydroboration of androst-4-enes (1995) (13)
Reactions of silylallyl-lithium or -potassium compounds with ButCN; synthesis and structures of [M{N(SiMe2R)C(But)(CH)3SiMe2But}] [M = Li(tmen), R = Me; or M = K, R = But], [Li{N(SiMe3)C(But)>>CCHC(SiMe3)(CH2)2C>>H2}(tmen)] and [{Li[NC(But)>>CHCHC(SiMe3)(CH2)2C>>H2]}4] (tmen = Me2NCH2CH2NMe2) (1999) (13)
First mixed valence cerium–organic trinuclear cluster [Ce3(OBut)10NO3] as a possible molecular switch: synthesis, structure and density functional calculations (2002) (13)
1,2,4-Triphospholyl gold(I) and copper(I) complexes: synthesis, crystal and molecular structures of [Cu(PMe3)2(μ-P3C2tBu2)(μ-I)Cu(PMe3)2], [Cu(PMe3)2(μ-P3C2tBu2)2Cu(PMe3)2] and [Au(η1-P3C2tBu2)2][Au(PEt3)2] (2003) (13)
Paramagnetic aluminium–1,4-di-t-butyl-1,4-diazabutadiene (dbdab) complexes derived from metal vapours and/or metal hydrides: crystal structures of [Al(dbdab)2] and [Al(dbdab){N(But)CH2}2] (1990) (13)
beta-Diiminato complexes of arsenic including the formally AsI compound [As3L3] [L = [N(C6H3Pri2-2,6)C(H)]2CPh]. (2009) (13)
First η1-ligated 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene complexes and the remarkable trihydration reaction of trans-[PtCl2(PMe3)(P3C3But3)] to cis-[PtCl(PMe3)(P3O3C3H5But3)], containing the novel CH(But)PH(O)C(But)PH(O)CH(But)P(O) ring system (1999) (13)
The structural characterization of buckminsterfullerene compounds (1993) (13)
One- and two-step [2 + 2] cycloaddition reactions of group 4 imides with the phosphaalkyne ButCP. Crystal and molecular structures of [Zr(η5-C5H5)2(PCButNC6H3Me2-2,6)] and [TiCl2(P2C2But2NBut)(py)] (py) = pyridine) (1999) (13)
Hydrogen-bonding in organosilanediols. The crystal structure of bis(pentamethylcyclopentadienyl)silanediol (1990) (13)
Attachment of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2si(Me3Si)2C to K Zn Sn and Yb. Crystal structures of LnMC(SiMe3)2Sime2CH2CH2Me2Si(Me3Si)2CMLn (MLn = K(C6H6)2 K(THF)2 SnCl3 or SnMe2Cl) and CH2SiMe2C(SiMe3)2ZnC(SiMe3)2SiMe2CH2 (THF = t (1999) (13)
Synthesis, crystal structure and reactions of the dimeric organolithium compound [{[(MeO)Me2Si]3CLi}2] (1992) (13)
Reactions of [Fe2(CO)6(μ-CO)(μ-dppm)], with PhCCH and the phospha-alkyne, tBuCP. Crystal and molecular structures of the four diiron complexes [Fe2(CO) 4(μ-CO)(μ-dppm)2], [Fe2,(CO)5,(μ-dppm)(μ-η2-CHC(CO)Ph], [Fe2,(CO)4,(μ-CO)(μ-dppm)(μ-η2-tBuCP)], and [Fe2(CO)5 (μ-dppm)(μ-gh2-PC(CO)tBu)]☆ (1993) (13)
The cycloaddition reaction of 1,3-diphospha-2,4,5-tri-t-butylcyclopentadiene and 1,2,4-triphospha-3,5-di-t-butylcyclopentadiene: crystal and molecular structure of the ethanol adduct of P5C5But5H2 (1990) (13)
The synthesis of monomeric terminal lead aryloxides: dependence on reagents and conditions. (2007) (13)
Chemistry and ligating properties of the 1,2,4-thiadiphosphole P2SC2But2 (2002) (13)
The structure of buckminsterfullerene compounds (1994) (13)
Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules (2017) (13)
Synthesis, structure, and reactions of the first homoleptic lithium-arsenic compound, [Li(μ-AsR2)]3 (R = CH(SiMe3)2) (1987) (13)
1:1 Adducts of triphenyltin chloride with oxovanadium(IV) tetradentate Schiff-base complexes (1999) (13)
-influence and electronegativity. Crystal and molecular structure of -di-iodobis(trimethylphosphine) platinum(II) (1977) (13)
Complexes of organoaluminium compounds. Part 12. Preparation, nuclear magnetic resonance spectra, and the crystal and molecular structure of bis(µ-isopropylamido-dimethylaluminium) (1981) (13)
Transition-metal imido-boroxide complexes: a structural and spectroscopic investigation of the influence of boron (2002) (13)
Erste Beispiele für Komplexe mit η1‐gebundenen Phosphaalkinen – Synthese sowie Kristall‐ und Molekülstruktur von trans‐[Mo(AdCP)2(Et2PCH2CH2PEt2)2] (Ad Adamantyl) (1987) (13)
Synthesis of (2S,4S)- and (2S,4R)-5-fluoroleucine and (2S,4S)-[5,5-2H2]-5-fluoroleucine. (2004) (12)
Differences in the η1-ligating properties of 2,4,6-tritertiarybutyl-phosphabenzene, PC5H2Bu3t and 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P3C3Bu3t (2010) (12)
Preparation and crystal structure of dimethyltris(trimethylsilyl)methylsilanatolithium tetrahydrofuranate (1986) (12)
Synthesis and molecular structures of copper(I) 1-azaallyls (1998) (12)
Metal Complexes of Guanidine-Substituted Alkyl Ligands: An Unsolvated Monomeric Two-Coordinate Organolithium (2007) (12)
Lanthanide metal(III) heteroleptic alkyls: synthesis of [LnR3(µ-Me)Li(pmdeta)][Ln = La or Sm, R ={CH(SiMe3)2}, pmdeta =N,N,N′,N″,N″-pentamethyldiethylenetriamine] and X-ray structure of the samarium complex (1989) (12)
The preparation and crystal structures of the sterically hindered lithium alkylchloroacadmate [Li(thf)4][Li(thf)2(µ-Cl)4{CdC(SiMe3)3}2].thf (thf = tetrahydrofuran), the alkylcadmium halides [{Cd[C(SiMe3)3]Cl}4] and [{Cd[C(SiMe2Ph)3]Br}2], and the hydrate [{Cd[C(SiMe2Ph)3]Br(H2O)}]2.(thf) (1988) (12)
Insertion reactions of [Pt(PPh3)2] fragments into the four-membered ring complex [W(CO)5PPhC(OEt)CPhCHPh]. Crystal and molecular structures of [Pt(dppe)PPh(W(CO)5)C(OEt)CPhCHPh] and [Pt(PPh3)2((W(CO)5)PhPC(OEt)CPhCHPh)(η2-PC))] (1991) (12)
New compounds containing thetriangulo-trichlorotrivanadium(II) moiety (1997) (12)
Reinvestigation of the alkylation of pyroglutamate ester urethanes (1998) (12)
The Hexaphosphapentaprismane P6C4tBu4: A “Jaws‐Like” Cage Molecule That Bites! (2001) (12)
Studies towards a total synthesis of kainic acid (2003) (12)
Reaction of tris[(diphenylphosphino)dimethylsilyl]methane with molybdenum hexacarbonyl and deprotonation to give a salt with a planar carbanion. Crystal structures of (Ph2PMe2Si)3CH and [Li(tmen)2][C(SiMe2PPh2)3], tmen = N,N,N′,N′-tetramethylethane-1,2-diamine (1999) (12)
Synthesis and characterization of trimethylsilylmethyl-, bis(trimethylsilyl)methyl-and silyl-substituted cyclopentadienes and their alkali metal complexes1Dedicated to Professor Ken Wade, as a mark of friendship and as a recognition of his many contributions to chemistry.1 (1998) (12)
Preparation and X-ray crystal structure of [Sn{N(SiMe3)2}2(µ-O2)]2, a rare example of a bis(1,2-µ-peroxo)-bridged metal complex (1992) (12)
The lithiation of arylamines and the preparation of cyclopentadienyltitanium(IV) arylaminate complexes (2003) (12)
Tris(triorganosilyl)methyl derivatives of potassium and lithium bearing dimethylamino or methoxy substituents at silicon. Crystal structures of KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3 and [LiC(SiMe3)(SiMe2OMe)2]2 (1999) (12)
Novel synthesis of a phosphinidene oxide-κP(RPO, R = ButCH2–) complex of rhenium(I) from a phosphaalkyne precursor. Crystal and molecular structure of [ReCl(Ph2PCH2CH2PPh2)2{P(O)CH2But}] (1992) (12)
Palladium catalyzed arylation reactions of meta photocycloadducts. (2004) (12)
Tri- and tetra-metallic complexes containing phospha-alkyne ligands. First examples of μ3(η2-⊊) bonded phospha-alkynes; crystal and molecular structure of [Fe2Pt(Ph2PCH2CH2PPh2)(CO)6(Me3CCP)] (1988) (12)
Synthesis of the first example of a metal complex containing a co-ordinated µ3-(η2-⊥) phospha-alkyne ligand. Addition of an Fe2(CO)6 unit to the η2-phospha-alkyne complex [Pt(dppe)(ButCP)]: crystal and molecular structure of [Fe2Pt(dppe)(CO)6(ButCP)](dppe = Ph2PCH2CH2PPh2) (1984) (12)
Syntheses of some bulky alkylalanes and alkyltrihydroaluminates: crystal structures of [Li(THF)2AlH3C(SiMe3)2(SiMe2NMe2)]2, Li(THF)2Al2H5{C(SiMe3)3}2, (Me3Si)3CAlH2·THF and the pyrazolato derivative [LiAlH(C3H3N2)2C(SiMe3)3]2 (THF=tetrahydrofuran) (2000) (12)
Self-organisation in P-substituted guanidines leading to solution-state isomerisation. (2004) (12)
The synthesis and characterisation of di- and trinuclear vinylsilicon-(tertiary phosphine) complexes of platinum(0) and nickel(0) (1997) (12)
Metabolic products of Fusarium acuminatum: acuminatopyrone and chlamydosporol (1991) (12)
Syntheses and Theoretical and Mechanistic Aspects of 1-Thia-24- and 1-Thia-34-disphosphole Formed from CS2 and tBuCP and Crystal and Molecular Structure of the First 1-Thia-34-disphosphole Complex: cis-[\{PtCl2(PEt3)\}2(P2SC2tBu2)] (2000) (12)
Synthesis and crystal structure of tetraiminediphenolate diiron(II) macrocyclic complex (2004) (12)
Novel tris(trimethylsilyl)methylboron compounds. Crystal structures of the diborane {(Me3Si)3C}HB (μ-H)2BH{C(SiMe3)3} and the bis(aminoboryl)amine {(Me3Si)3C(NH2)B}2NH (1990) (12)
η3- and η5-ligating modes of 1,3-diphosphacyclopentadienyl rings in structurally related molybdenum complexes. Crystal and molecular structure of [Mo(η5-C5Me5)(η3-P2C3But3)(CO)2] and [Mo(η3-C9H7)(η5-P2C3But3)(CO)2](C9H7= indenyl) (1990) (12)
The stable silylene Si[(NCH2tBu)2C6H4-1,2]: insertion into LiC or LiSi bonds of lithium alkyls LiR or [LiSi(SiMe3)3(THF)3] [R=Me, tBu or CH(SiMe3)2] (2002) (12)
Synthesis and characterization of N-silylated, C1-symmetric benzamidinates of lithium, sodium, and tin(II) (2006) (12)
STEREOCHEMISTRY OF A REARRANGEMENT OF B AND C RINGS IN CLOVANE SKELETON (1998) (12)
Model studies for the synthesis of the antibiotic lactonamycin and the discovery of new reactions and mechanisms for the construction of substituted heterocycles (2010) (12)
The structure of thiobiscephalosporolide A, A dimeric pentaketide macrolide from Cephalosporium aphidicola (1985) (12)
Hydrazido(2–)-complexes of tungsten-(V) and -(VI) and a bis(diazenido)-complex of tungsten(IV). X-Ray crystal structure of cis-[WCl3(NNH2)(PMe2Ph)2] (1982) (12)
Reactions of α-lithiated phosphinimines with PhCN; thecrystal structure of[K{N(H)C(Ph)C(H)P(Ph)2NSiMe3}(tmen)]2 (tmen =Me2NCH2CH2NMe2) (1997) (12)
Six-coordinate vanadyl tetradentate Schiff base complexes with methanol, methoxide, water or fluoride as the sixth ligand (2000) (12)
The synthesis and molecular structures of the crystalline 1-aza-2-phospha(V)allyllithium compounds [Li(LL′)(OEt2)2] and [Li(LL′)]2 [LL′ = CH(SiMe3)P(Ph)2NSiMe3] and the preparation and characterisation of the new phosphinimines CH(R1)(R2)P(Ph)2 NSiMe3 [R1 = R2 = SiMe3; R1 = H, R2 = Si(Me)2NEt2]† (1999) (12)
Trigonal Prismatic Structure of Tris(butadiene)molybdenum and Related Complexes Revisited: Diolefin or Metallacyclopentene Coordination? (2002) (12)
Crystal and molecular structure of 1,8-bis(trimethylsilyl)octatetrayne (1975) (12)
A novel cyclisation strategy for the synthesis of lactonamycin: A new route to highly functionalised heterocyclic rings (2006) (12)
The fullerenes: Precursors for 21st century materials (1994) (12)
Isatin chloride: a phantom. Reactions of 2-(2,2-dichloro-2,3-dihydro-3-oxoindol-1-yl)-3H-indol-3-one (1996) (12)
Synthesis and crystal structures of some cobalt halide derivatives containing alkyl or silanolato groups (2005) (11)
Stannadesulfurization of a bis(dimethyldithiocarbamato)tungsten(II) complex: formation of a coordinated bis(dimethylamino)acetylene complex (1990) (11)
Iron(iii) and titanium(iv) oxoalkoxide chemistry: synthetic, structural, magnetochemical and spectroscopic studies of [Ti3(3-OPri)2(-OPri)3(OPri)6][FeCl4] and [Fe5(5-O)(-OPri)8Cl5]Electronic supplementary information (ESI) available: crystallographic data in Tables 5 and 6, and ORTEP-3 representatio (2004) (11)
Synthesis of the η1-phosphaalkyne complex trans-[FeH(PCBut)(dppe)2][BF4] and its conversion into a η1-fluorophosphaalkene complex. Crystal structure of trans-[FeH(PFCHBut)(dpee)2][FeCl2F2] (1991) (11)
The crystal structure of t-Bu2Si(OH)F. A cyclic hydrogen-bonded tetramer (1985) (11)
The crystal structure of [tris(trimethylsilyl)methyl]silanetriol. A novel and remarkably stable hydrogen-bonded cage structure (1985) (11)
Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1-aza-allyl-lanthanide complexes; X-ray structures of [Sm(LL′)2I(thf)], [Yb(LL′)2] and [RNC(But)CH(R)]2 (thf = tetrahydrofuran, LL′ = η3-N(R)C(But)CHR, RSiMe3) (1997) (11)
Synthesis of the 2,4,5-tri-tert-butyl-1,3-diphospholide anion by phosphinidene elimination from 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene on treatment with the amide Li[NPh(SiMe3)]. (2007) (11)
[2+2] Cyclo-addition reactions of bis-pentamethylcyclopentadienyl zirconium metal complexes containing terminal chalcogenide ligands with the phospha-alkyne PCtBu. Syntheses, crystal and molecular structures of the four complexes [Zr(η5-(C5Me5)2(SC(tBu)P))], [Zr(η5-(C5Me5)2(SeC(tBu)P))], [Zr(η5-(C5M (2003) (11)
An Alkyllithium Compound with a Free Planar Carbanion. The Crystal Structure of [Li(THF)4][C(SiMe2C6H4Me-o)3] (1997) (11)
Differences in coordination chemistry of alkyne and phosphaalkyne metal carbonyl complexes. Syntheses, crystal and molecular structures of [Mo2(CO)4(η5-C5H5)2(ButCP)Fe(CO)4] and [Mo2(CO)4(η5-C5H5)2(ButCP)W(CO)5] (1987) (11)
Stereochemistry of the metabolism of the DNA base thymine and the drug 5-fluorouracil (1983) (11)
Synthesis and characterization of platinum(0) alkene complexes; X-ray crystal structure determinations on [Pt(trans-PhCHCHCHO)(PPh3)2] and [Pt(trans-PhCHCHCOMe)(PPh3)2] (1997) (11)
Syntheses and structures of lithium cyanocuprates containing the C(SiMe3)3, C(SiMe3)2(SiMe2NMe2) and C(SiMe3)(SiMe2OMe)2 groups (2002) (11)
Structural and bonding aspects of molybdenum tricarbonyl complexes of 2,4,6-tritertiarybutyl-1,3,5-triphosphabenzene, P 3 C 3 Bu t 3 and some λ 3 ,λ 3 ,λ 5 - and λ 3 ,λ 5 ,λ 5 -alkylated derivatives (2010) (11)
The hydroxylation of globulol and 7-epiglobulol by Cephalosporium aphidicola (1994) (11)
Cyclonerotriol [6-(3-hydroxy-2,3-dimethylcyclopentyl)-2-methylhept-2-ene-1,6-diol], a new sesquiterpenoid metabolite of Fusarium culmorum (1975) (11)
An electron-deficient indium hydride. Crystal structure and n.m.r. spectrum of (Me3Si)3Cln(H)(µ-H)Li(thf)2(µ-H)ln(µ-H)(H)C(SiMe3)3(thf = tetrahydrofuran) (1986) (11)
Structure--activity relationships in the fungistatic activity against Botrytis cinerea of clovanes modified on ring C. (2004) (11)
A convenient route to vinylsiloxane-tertiary phosphine-nickel(0) complexes; the molecular structure of [(Ni{P(C6H4Me-4)3})2{μ-(L′′L′′)2}] {(L′′L′′)2=[CH2CH(Me)Si(μ-O)]4} (2000) (11)
Anomalous reactions of the diamine Me2NCH2NMe2 with nickel(II) and cobalt(II) (2002) (11)
Phospha(III)guanidinate complexes of titanium(IV) and zirconium(IV) amides (2010) (11)
Coordination of neutral, methylene bridged bis-guanidyls at palladium. (2010) (11)
Spontaneous N-aryl (rather than P-aryl) orthometallation in the system [RuCl2(PPh3)3]–[CN(Ar)(CH2)2NAr]2(Ar = C6H4Me-4); X-ray crystal and molecular structure of [RuCl(PEt3)2{CN(Ar)(CH2)2N(C6H3Me-4)}], a stereochemically rigid 5-co-ordinate RuII complex, with a short (2.2 Å) Ru …. H contact (1977) (11)
Poly{guanidinium} salts: application in the preparation of a coordinatively saturated aluminium cation. (2007) (11)
Intermediates in nickel(0)–phosphine complex catalyzed dehydrogenative silylation of olefins (2006) (11)
Diversity of triflate coordination modes in neodymocene complexes containing bulky bis(trimethylsilyl)cyclopentadienyl ligands (2006) (11)
Examining the stability of phospha(III)guanidines: Formation of a formamidinium:phosphinate ion-pair and an N-protonated phospha(III)guanidinium chloride (2012) (11)
Palladium-mediated fragmentation of meta photocycloadducts using carbon based electrophiles. Part 1 (2006) (11)
Two new diterpenoids from Teucrium fruticans (1978) (11)
Lithium enamides, β-diketiminates and 1,3-diazaallyls from the 1:1 insertion of an isonitrile into the Li–C bond of LiCH(SiMe3)2†‡ (1998) (11)
Beta-lactams as versatile synthons for homochiral ibotenate analogues with potential for activity at glutamate receptors. (2003) (11)
Crystalline di- or trianionic metal (Al, Sm) beta-diketiminates. (2010) (11)
Preparation, spectra and X-ray structure of an archetypal coordination compound [BCl3(NH3)] and its thermolysis (1995) (11)
A synthesis of (+)-Prelog-Djerassi Lactonic acid (1998) (11)
Synthesis, crystal structures and reactions of sila- and germa-β-diketiminates (2003) (11)
Novel mono-and bis-metallated complexes of dialkyldiaziridines; X-ray diffraction structures of three platinum complexes (1993) (11)
Tetrakis(hydroxydimethylsilyl)methane and its dehydration with rearrangement. Crystal structure of 2,2,4,4,6,6-hexamethyl-5-(hydroxydimethylsilyl)-1,3-dioxa-2,4,6-trisilacyclohexane (1984) (11)
Controlling diastereoselectivity in the reactions of enantiomerically pure alpha-bromoacyl-imidazolidinones with nitrogen nucleophiles: substitution reactions with retention or inversion of configuration. (2005) (11)
Use of coordinated phosphaalkyne ligands in transition metal cluster interlinkage. Synthesis of dimolybdenum-triruthenium and dimolybdenum-triosmium complexes [Mo2M3(η5-C5H5)2(CO)15(tBuCP)], (M = Ru, Os) and crystal and molecular structure of di-η5-cyclopentadienyltetracarbonyl-μ-(3,3-dimethyl-1-pho (1984) (11)
Preparation and X-ray characterisation of the first heteroleptic hydrocarbon-soluble tin(II) pseudohalide, Sn(NCS)[N(SiMe3)2] (1992) (10)
A dimeric copper coumarin complex: synthesis and crystal structure of [{Cu(4-methyl-7-(salicylideneamino)coumarin)2}2] (2008) (10)
Synthesis and structures of the 1,3-diphospha-2-metallapentanes [LnM{P(Ph)C6H4PPh}][MLn= ZrCp″2(2), rac-SnR2(3), SnMe2, or BAr; Cp″=η-C5H3(SiMe3)2-1,3, R = CH(SiMe3)2, Ar = C6H2But3-2,4,6]; X-ray structures of complexes (2) and (3) (1989) (10)
Synthesis, Characterization, and Molecular Structure of Bis{(tert-butyldimethylsilyl)- tetramethylcyclopentadienyl}lead (1996) (10)
The synthesis and properties of a new linear NPN proligand (2003) (10)
The crystal structure of the compound meso,meso′ ethylenebis[octaethylporphyrinatonickel(II)] (1983) (10)
The absolute configuration of the optically-active silylplatinum complex (+)-trans-[PtCl{SiMe(1-C10H7)Ph}(PMe2Ph)2], (1973) (10)
Synthesis and structures of dilithium (1,2-diphosphido)-benzenes (1995) (10)
Synthesis and Structural Characterisation of Group 10 Homo‐ and Hetero‐Dimetallic Sulfur‐Bridged Complexes of the [Ni(ema)(μ‐S,S′)M(diphos)](M = Ni, Pd, Pt) Type (2005) (10)
Ambiphilic ligands from the 1,4-benzenebis(amidine) framework (2004) (10)
Quantitative structure-antifungal activity relationships of some benzohydrazides against Botrytis cinerea. (2007) (10)
Reactions of the alkyltrihydroaluminate [Li(thf)2{AlH3[C(SiMe3)3]}]2. Crystal structures of [Li(tmen)2][AlH3{C(SiMe3)3}], [AlBr2{C(SiMe3)3}]·thf, [AlI2{C(SiMe3)3}]·thf, [Li(thf)2(µ-NHPh)2{AlH[C(SiMe3)3]}] and [Li(thf)4][Al(NHPh)3{C(SiMe3)3}] (1998) (10)
Yttrate Metathesis: Ligand Design for the Controlled Synthesis of f-Block Heterobimetallic Compounds. (2001) (10)
Syntheses and crystal structures of two ytterbocene complexes [Yb(η-Cp′′)2I(THF)] and [Yb(η-Cp′′)2(μ-Cl)2Li(THF)2] (Cp′′=C5H3(SiMe3)2-1,3) (2000) (10)
Reactions of 1,3,5-triazine with organolithium compounds containing trimethylsilyl substituents; X-ray structures of 1,3,5-triaza- and 1,3,5,7-tetraaza-heptatrienyllithium compounds† (1999) (10)
Bond lengths in platinum(II) and platinum(IV) complexes. Crystal and molecular structure of -tetrachlorobis(triethylphosphine) platinum(IV) (1977) (10)
Synthesis and structural study of [{Pd(CH2C9H6N)}2(µ-O2CR)(µ-X)] complexes (R = Me or CF3; X = hydroxide, amide or thiolate) (1994) (10)
Hydrogen bonding in organosilanediols. The crystal structure of di-o-tolylsilanediol (1986) (10)
1‐Azaallyl Complexes of NiII, PdII, and TiIII (2000) (10)
Low-co-ordination arsenic and antimony compounds: synthesis and characterisation of 2-arsa- and 2-stiba-1,3-dionatolithium(I) complexes, [Li{OC(R)EC(R)O}L](E = As or Sb; R = But, C6H2Pri3-2,4,6 or C6H2But3-2,4,6; L = Et2O or MeOCH2CH2OMe) (1996) (10)
Novel anionic cages from ‘alkylmanganese chloride’ and ‘alkylcobalt chloride’ solutions. Crystal and molecular structure of [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)](thf = tetrahydrofuran) (1985) (10)
Preparation and X-ray crystal structure of a carbamylsilane (1991) (10)
1,2-N,N-Dimethylaminomethylferrocenyl as a ligand towards titanium and vanadium (1996) (10)
Remarkable ‘edge’ ligation of a triphosphacyclopentenylring system. Synthesis, crystal and molecular structure of[Ni(η5-P3C2But2){η2-P3C2But2CH(SiMe3)2Me}] (1997) (10)
Synthesis and structures of the transition metal(II) β-diketiminates [ML2] (M = Mn, Fe, Ni, Cu, Pd), [ML2′] (M = Ni, Cu) and [M(η3-C3H5)L] (M = Ni, Pd); L or L′ = [{N(SiMe3 or H)C(Ph)}2CH] (2009) (10)
Stannadesulfurization of a bis(diethyldithiocarbamato)tungsten(II) complex. Formation of an aminocarbynetungsten complex (1990) (10)
Novel C–H activation in a bis-tetrairidium carbonyl complex of the sandwich compound [Fe(η5-C5H5)(η5-P3C2But2)]: crystal and molecular structures of [Ir4(CO)11{Fe(η5-C5H5)(η5-P3C2But2)}] and [HIr4(CO)10-{µ-Fe(η5-C5H5)(η5-P3CH2(CMe2)CBut)}Ir4(CO)11] (1996) (10)
Unusual stereoselectivity in the alkylation of pyroglutamate ester urethanes (2001) (10)
Syntheses and structures of structurally diverse potassium beta-diketiminates derived from the ligand [(N(SiMe3)C(Ph))2CH]. (2002) (10)
Two crystalline toluene-soluble 1,2-organobis(phenylphosphido)dilithium compounds. The monomeric 1,2-C6H4(PPh)2[Li(TMEDA)]2 and the dimeric [(PhPCH2CH2PPh) {Li(THF)2}2]2☆ (1987) (10)
Synthesis and Structural Characterization of [Ir4(mu-CO)(CO)7{mu4-eta3-Ph2PC(H)C(Ph)PCBu t}(mu-PPh2)]: Alkyne-Phosphaalkyne Coupling and Formation of a Novel 2-phosphabutadienylphosphine Ligand (1998) (10)
The thermally stable silylene Si[(NCH2But)2C6H4-1,2]: reaction with pyridine and quinoline (2004) (10)
Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes. (2009) (10)
Carbene complexes. Part VI. Complexes from imidoyl chloride and rhodium(I) precursors, and the crystal and molecular structure of carbonyltri-iodo-[α-(N-methyl-α-methyliminobenzylamino)benzylidene-N,C]rhodium, I3(OC)Rh–CPh(NMe)CPh:NMe (1974) (10)
Synthesis and Characterization of a Phosphaalkyne-Bridged Pentairon Carbonyl Cluster. Crystal and Molecular Structure of [{Fe3Se2(CO)8}(.mu.-PCBut){Fe2Se(CO)6}] (1995) (10)
Reactions between a sodium amide Na[N(SiMe3)R1] (R1 = SiMe3, SiMe2Ph or But) and a cyanoalkane RCN (R = Ad or Bu(t)). (2006) (10)
Inorganic Chemistry Concepts, Vol. 6. Inorganic Stereochemistry (1982) (9)
A hexaco-ordinate platinum complex containing four Pt–Sn bonds, one of them to SnII (1982) (9)
The microbiological hydroxylation of 3,16-Disubstituted androstanes by cephalosporium aphidicola (1998) (9)
Lipophilic metal (Na, TiIII ZrIV, Rh1 and PdII) complexes derived from the hybrid ligands -or and hor (R = Me2PCH2CBut2); the X-ray structures of [t[graphic ommitted]Me2)2] and trans-[R[graphic ommitted]H)2] (1993) (9)
Reactions of a Highly Crowded Triorganotin Iodide with Silver Salts. Migration of a Methyl Group from Silicon to Tin within a Cation (2002) (9)
meta- and para-Bis[zirconyl(IV)amino]cyclophanes; 1,3- or 1,4-C6H4[N(SiMe3)]2 as bridging ligands† (1999) (9)
Neutral and Anionic Antimony(III) Species Supported by a Bicyclic Guanidinate (2012) (9)
4α-hydroxydihydroilludin M—A new sesquiterpenoid metabolite of Clitocybe illudens (1982) (9)
An Alkylzinc Bromide and a Lithium Alkyldibromozincate Containing Tris(organosilyl)methyl Groups (2004) (9)
Aspects of the Chemistry of the Cyclic Phosphonium Salt [Ph2PaP(Cl)N(SiMe3)C(tBu)=CbH(Pa–Cb)]Cl and the Related Diazadiphosphetidine [ClPaN(R)P(Cl)NbR(Pa–Nb)] [R = C(tBu)=C(H)SiMe3] (1998) (9)
Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C4tBu4: crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6). (2008) (9)
Electrophilic aromatic substitution by the fluorofullerene C60F18. (2004) (9)
Heterobimetallic complexes containing both iron(II) and cobalt(II) (2003) (9)
Synthesis, X-ray crystal structure and solution NMR spectroscopic studies of [Li{N(H)C(Me)C(H)(CN)}(py)2]2(py = NC5H5) (1996) (9)
The microbiological hydroxylation of the sesquiterpenoid patchoulol by Mucor plumbeus (1999) (9)
Synthesis of substituted dibenzophospholes. Part 5. Synthesis of intermediates for 4-and 6-aryl substituents (1987) (9)
Dimetallostannylene-transition-metal complexes (1990) (9)
The molecular structure of 2,2′,5,5′-tetraphenyl-1,1′-diphosphaferrocene (1997) (9)
Carbon monoxide–phosphaalkyne coupling and C–Hactivation of an N–Me group in the4e-η2-phosphaalkyne complex[WF(C6H4CH2NMeCH2CH2NMe2)(CO)(η2-PCBut)].Crystal and molecular structure of[WF{CH2N(CH2Ph)CH2CH2NMe2}(CO){η4-PCBut(CO)CButP}] (1997) (9)
Synthesis, crystal, and molecular structure of the novel infinite chain mixed metal carbene complex [Pd(µ-Cl)2Pt{C(PPh2)2}]n derived from co-ordinated bis(diphenylphosphino)methane (dppm) (1986) (9)
The biotransformation of the diterpenoid, sclareol, by Cephalosporium aphidicola (1994) (9)
Stereoselective synthesis of β-substituted aspartic acids via tetrahydro-1,3-oxazin-6-ones (1999) (9)
Non-primary valence interactions in low valent transition metal complexes and some possible implications for the structure of coordinatively unsaturated species (1975) (9)
Crystallographic evidence for intermolecular hydrogen bonding between aryl groups and OH groups in silanols (1992) (9)
Synthetic, structural and theoretical studies on the new 2,3-dihydro-1,2,4-thia-, selena- and tellura-diphospholes, P2EC2But2(H)Me, (E=S, Se, Te) and their [M(CO)5] complexes (M=Cr, Mo, W) (2002) (9)
Synthesis of (2S,3S)-3'-fluoroisoleucine. (2004) (9)
Synthesis and characterisation of a novel macrocyclic vinylsiloxane-based tris(alkene)nickel(0) complex (1995) (9)
A strategy for the propagation of hydrogen-bonding in bicyclic guanidinium salts (2008) (9)
Synthesis and structures of crystalline lithium 1-azaallyls and a 1,3-diazaallyl derived from Li{CH(SiMe3)(SiMe3−n(OMe)n)} (n=1 or 2) and Li{CH(SiMe2OMe)2} and RCN (R=tBu, Ph, 2,5-Me2C6H3, or Ad) (2003) (9)
The geometry of SiOCN and SiNCO linkages. The crystal structures of (Me3Si)2(Ph2MeSi)CSiMe2OCN and (PhMe2Si)3CSiMe2NCO (1995) (9)
Organotin compounds containing a bulky (Me3Si)3C or related ligand. Crystal structures of {(Me3Si)3CMe(O2NO)Sn}2O, (PhMe2Si)3CSnMeCl2 and (PhMe2Si)3CSnCl3 (1998) (8)
Subvalent Group 14 metal compounds. Part 10. Syntheses and structures of some bis(metallo)plumbylenes [Pb{Mo(R)(CO)3}2(OC4H8)][R =?-C5H5, ?-C5H3(SiMe3)2-1,3, or ?-C5Me5]; X-ray crystal structures of [Pb{Mo(?-C5Me5)(CO)3}2(OC4H8)] and [{Pb[Mo(?-C5Me5)(CO)3][Mo(?-C5Me5)(CO)2(-CO)]}2] (1987) (8)
Bilayer arrangements of phospholipids: a structural analysis of 1,2-dilauroyl-(±)-phosphatidylethanolamine: acetic acid and its implications for membrane models (1974) (8)
Bicyclic Guanidinates in Mono- and Di-Valent Metal Complexes, Including Group 1/2 and Group 1/12 Heterometallic Systems (2013) (8)
An unusual bicyclic tetrasiloxane (1981) (8)
On the electronic structure of tis(β-diketonato)ruthenium(III) complexes: A linear correlation of electrochemical reduction potentials in solution with vertical first ionisation energies in the gas phase (1986) (8)
Synthesis and structure of the silylated benzene radical anion salts [K([18]crown-6){C6H4(SiMe3)2-1,4}] and [K([18]crown-6)(THF)2][C6H2(SiMe3)4-1,2,4,5] (2011) (8)
Upon the electronic structure of the µ-oxo-bis[pentachlororuthenate(IV)] anion and the non-existence of caesium µ-oxo-bis[pentabromoruthenate(IV)] (1986) (8)
Rhodium(I) complexes of 4-t-butylcyclohexyldiaziridine and adamantyldiaziridine: Synthesis, structure and catalytic activity (1993) (8)
1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3But3: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour (2005) (8)
The first hetero-binuclear alkoxide of iron and vanadium: structural and spectroscopic features (2003) (8)
4-Methyl-7-(salicylideneamino)coumarin (2006) (8)
Effect of N-aryl substituents on the reactivity of electron-rich olefins as precursors of transition-metal–carbene complexes. The crystal and molecular structure of NN′N″N‴-tetraphenylbis(1,3-imidazolidin-2-ylidene), and its π-electron distribution (1979) (8)
Fluorophosphine complexes of rhodium(I) and iridium(I): towards the design of systems with extended metal–metal interactions. The crystal structure of [{IrCl(PF3)2}2] (1985) (8)
Synthesis and structures of some new types of lithium beta-diketiminates. (2008) (8)
Lithium trialkoxo[tris(trimethylsilyl)methyl]aluminates, analogues of intermediates in reductions of carbonyl compounds. Crystal structures of [Li(thf)2][AlR(OEt)3] and {Li[AlR(OPri)2(OH)]}2, R = C(SiMe3)3 and thf = tetrahydrofuran (1997) (8)
Neutral and zwitterionic group 4 metal alkyls with ancillary boroxide ligands. (2004) (8)
The biotransformation of methyl ent-15-oxokaur-16-en-19-oate by Rhizopus stolonifer and Mucor plumbeus (1995) (8)
Use of phospha-alkynes in metal aggregate synthesis. Crystal and molecular structure of the remarkable hexa-rhodium complex [Rh2Cl2{Rh(η5-C5H5)(P2C2But2)}4] (1987) (8)
Reactions of M[CH(SiMe3)2] (M = Na or K) with PhCN, and related chemistry. (2006) (8)
Preparation and crystal structure of the novel internally solvated dimeric organolithium compound [{LiC(SiMe2OMe)3}2] (1986) (8)
Nucleophilic activity of a linked bis{guanidine} leading to formation of a dicationic C4N4-heterocycle. (2007) (8)
A functionalised diphosphine as a (PN)-binucleating ligand: X-ray structure of the `double A-frame' complex [RhCl(BTPE)]2][RhCl4(BTPE)]2·χCHCl3 (BTPE = (C7H4NS)2PCH2CH2P(C7H4NS)2) (1988) (8)
Synthesis of the sterically hindered complexes [M(CO)5(CNBR2)][R=CH(SiMe3)2; M = Cr, Mo, or W]. Crystal structure of [Cr(CO)5(CNBR2)] (1994) (8)
Mercurycyclopentadienyl Derivatives Are Not Always Fluxional (1998) (8)
Crystallographic characterisation of the lattice structure C60·[Fe4(CO)4(η5-C5H5)4] as the 1/3 benzene solvate (1993) (8)
Synthesis, crystal and molecular structures of pyridine adducts of the zinc and cadmium bis-1,2,4-triphospholyl complexes [M(η1-P3C2tBu2)2(NC5H5)n] (M=Zn, n=2; M=Cd, n=3) (2001) (8)
A new aliphatic N,C,N’-pincer ligand with pendant guanidine groups (2014) (8)
Synthesis and structure of an azatrisilacyclobutane and its precursor, a novel lithium enamide having a tricyclic (LiNSiO)2 skeleton. (2002) (8)
Synthesis and reactivity of bis(η-1,4-di-tert-butylbuta-1,3-diene)cobalt; the X-ray crystal structure of the anionic butadiene sandwich complex [K(18-crown-6)(thf)2][Co(η-C4H4But2)2] (1993) (8)
Towards a flexible strategy for the synthesis of enantiomerically pure [2.2]paracyclophane derivatives: The chemistry of 4-tolylsulfinyl[2.2] paracyclophane (2010) (8)
Formation of a medium ring imino ether by a diazo insertion reaction (1996) (8)
Synthesis and structures of 3-sila-β-diketiminato complexes of the coinage metals (2007) (8)
[4 + 2] Cycloaddition reactions involving 1,3-diphosphacyclopentadiene and 1,2,4-triphosphacyclopentadiene: Crystal and molecular structures of the exo-compounds P5C5tBu5H2 and P4C6tBu6H2 (1997) (8)
The structure of tri(cyclohexyl)tin chloride between 108 and 298 K: a compound in which molecular dimensions vary with temperature. (2003) (8)
Deactivation pathways of ethylene polymerization catalysts derived from titanium and zirconium 1,3-bis(furyl)-1,1,3,3-tetramethyldisilazide complexes. (2007) (8)
Sodium and potassium 3-sila-β-diketiminates show new coordination modes (2002) (8)
Coupling of Two Phosphaalkynes via a Carbonyl Group in the Addition Across a Rh=Rh Double Bond (1991) (8)
Group 3 complexes incorporating (furyl)-substituted disilazide ligands (2010) (8)
Sodium and potassium derivatives of diphenyl(trimethylsilyl)methane (2002) (8)
Carbonyl complexes of molybdenum and tungsten with functionalized diphosphines: X-ray crystal structure of [{W(CO)3}2{μ-P(C6H4SMe-2)2CH2CH2P(C6H4SMe-2)2}] (1991) (8)
Organoiron compounds derived from the indium 'carbene analogues', [In(N(Ar)C(Me))2CH] (Ar = dipp = 2,6-iPr2C6H3; = Mes = 2,4,6-Me3C6H2). (2008) (8)
A bulky tris(trisilyl)methyl ligand incorporating a donor sulfur atom: some (Me3Si)2(PhSMe2Si)CSnMe2X compounds (1996) (8)
Mono- and bi-nuclear complexes of rhodium with functionalised diphosphine ligands (1992) (8)
Formation of a tetrazole from (PhMe2Si)3CSiMe2I. Crystal structure of (PhMe2Si)3CSiMe3 (1988) (8)
Metal-vapour synthesis of phospha-organometallic compounds: reaction of nickel atoms with the phospha-alkyne tBuCP. Structural characterisation of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)], a derivative of the novel, aromatic phosphirenyl cation (2004) (8)
An Electrochemical Study of the Ruthenium(III) and ‐(IV) Hexachlorometallates in a Basic Room Temperature Chloroaluminate Molten Salt (1991) (8)
THE COMPETITION BETWEEN CROSS-COUPLING AND THE EXCHANGE REACTION IN THE PHOTOREDUCTION OF AROMATIC KETONES (1995) (7)
Synthesis and structures of four crystalline lithium β-diketiminates derived from [Li{CH(SiMe3)(SiMe2OMe)}]8 and PhCN or ButCN and PhCN (2004) (7)
Aluminum triiodide induced complexation and structural rearrangement of the hexaphospha–pentaprismane cage, P6C4tBu4 (2009) (7)
Conformational control by halogen substitution and by crystallisation: a study of the molecular structures of CH(SiMe2H)3 and CH(SiMe2Br)3 by gas-phase electron diffraction, and ab initio molecular orbital calculations (2000) (7)
Synthesis and crystal structures of novel 1-aza-2-silacyclobut-3-enes (2002) (7)
Crystal and molecular structure of hepta-µ3-methylimido-heptakis-(methylaluminium). A new aluminium–nitrogen cage (1973) (7)
Syntheses and structural characterisation of [Ir4(CO)11(η1-L)] and [Ir4(CO)10(η1-L)2]{L =[Fe(η5-P3C2But2)(η5-P2C3But3)] and [Fe(η5-C5H5)(η5-P3C2But2)]} and [Ir4(CO)11{µ-η1 : η1-[Fe(η5-C5H5)(η5-P3C2But2)]}Ir4(CO)11] and its facile conversion to [Ir4H(CO)10{Fe(η5-C5H5)[η5-P3C(CMe2CH2)CBut]}Ir4(CO)11], (1996) (7)
Isolation and characterisation of symmetrical C60Me6, C60Me5Cl and C60Me5O2OH, together with unsymmetrical C60Me5O3H, C60Me5OOH, C60Me4PhO2OH, and C60Me12; fragmentation of methylfullerenols to C58 (2002) (7)
Complexes containing the [TeCl4X]− moiety (X = Cl or an aryl group) (2009) (7)
Synthesis and structural characterisation of trans-Cp2Mo2O2(μ-O)(μ-Te) and cis-Cp2Mo2O2(μ-O)(μ-S) (1997) (7)
1:1 Imidazolium 7,7',8,8'-Tetracyano-p-quinodimethanide ([TCNQ].bul.-) Salts: Substituent Control of Solid-State Architecture (1994) (7)
The structure of fullerene compounds (1997) (7)
The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex (1995) (7)
Synthesis of titanium(IV) ferrocenylaminate complexes (2003) (7)
Pentahalophenyl palladium and platinum trinuclear complexes with tetrathiomolybdate and tetrathiotungstate (1995) (7)
The novel linear-polymeric organolithium compound {(Me2NMe2Si)3CLi}∞ (1996) (7)
[(C3tBu3)V(CO)4] : partial insertion of vanadium into the cyclopropenyl ring (1994) (7)
Condensation reactions of monomeric hydroxo palladium complexes with active methyl and methylene compounds. (2004) (7)
Formation of co-ordinated diphenylketen from carbon monoxide and an alkylzirconocene(IV) benzhydryl complex: X-ray structure of [{Zr(η-C5H5)2(OCCPh2)}]2 (1982) (7)
Diazoalkane complexes of tungsten. Crystal structures of [WBr(N–NCHCH2CH2CH2OH)(dppe)2][PF6]·0.5EtOH (1) and [WBr(N–NCMe2)(dppe)2]Br·0.5MeOH (2) (1980) (7)
Synthesis and characterisation of a series of 1,2-phenylenedioxoborylcyclopentadienyl-metal complexes (Ti(IV), Zr(IV), Hf(IV), La(III), Ce(III), Yb(III), Sn(II) and Fe(II)) (2005) (7)
Group 6 metallocene(IV)–main group metal complexes: synthesis and structures of a Mo–B–Li compound and of [W(η-C5H5)2H{SnCl2CH(SiMe3)2}] (1995) (7)
Imino sulfinamidines: synthesis and coordination chemistry of a novel class of chiral bidentate ligands. (2006) (7)
Structure of thiobiscephalosporolide-A, a macrolide from Cephalosporium aphidicola (1981) (7)
Synthesis of the dicarbonyl ruthenium(0) triphosphole complex [Ru(CO)2{η5-P3C2But2CH(SiMe3)2}] and its conversion into a tricarbonyl complex containing the novel 4-electron donor triphosphorus-ring system {CButPP(H)CH(SiMe3)2CButP(O)H} (1999) (7)
Structural studies of complexes of vanadium(III) and titanium(IV) with N , N -dimethylaminomethylferrocenyl (1999) (7)
Divinyldisiloxane and divinylsilane complexes of rhodium(I) (1999) (7)
Novel β-iminoenolato (or β-carbonyliminato) complexes starting from di-μ-hydroxo palladium or platinum complexes with dimethyl acetylenedicarboxylate and primary amines: Crystal structure of (1996) (7)
Synthesis and reactivity of trimethylphosphite complexes of cobalt, rhodium and iridium. Crystal and molecular structure of [IrH(P(OMe)3)4(P(OMe)2OSnMe2Cl2)][SnCl3Me2] (1983) (7)
Unusual, thermally stable, sublimable aminoboranes B(NHAr)X2(X = Cl, F, or NH2); X-ray crystal structure of bis(amino)(2,4,6-tri-t-butylphenylamino)borane, B(NH2)2(NHAr) (1984) (7)
The structure of teuflin, a diterpenoid from Teucrium flavum; X-ray crystallographic and spectroscopic determination (1979) (7)
Structural differences in η5-C5H5 and η5-P3C2But2 tetrametallic complexes. Synthesis of [PtM2Cl(P3C2but2)(CO)8(PEt3)2] and [Pt2M2(P3C2But2)2(CO)6(PEt3)2], (M=Cr, Mo, W). Crystal and molecular structure of [Pt2W2(P3C2But2)2(CO)6(PEt3)2] (1990) (7)
Thiolateisocyanide complexes of molybdenum(II) and tungsten(II): crystal structures of cis-[Mo(SC6H2Pri3-2,4,6)2(CNMe)4], cis-[Mo(SC6H2Pri3-2,4,6)2(CNBut)4] and cis-[W(SC6H2Pri3-2,4,6)2(CNMe)4], and anodically induced isomerisation studies (1997) (7)
Synthesis and molecular structure of the novel bimetallic complex [{CoCl2Ph2P(O)CH2CH2P(O)Ph2}2], containing a 14-membered ring (1991) (7)
The inhibition of the fungus Botrytis cinerea by an eremophilane phytoalexin analogue (2004) (7)
Spectroscopic and electronic properties of 1-azaallylmetal(I) (M = Cu or Au) complexes; molecular structure of [{Au[µ-N(R)C(Ph)CR2]}2] (R = SiMe3) (1999) (7)
Teuflidin, a norclerodane diterpenoid from Teucrium flavum (1978) (7)
Me2NCH2XCH2NMe2 (X=O or NMe) and cyclotriazane complexes of nickel(II) (2003) (7)
Exploring the chelating potential of 1,3-bis(furyl)-1,1,3,3-tetramethyldisilazides (2007) (7)
Complexes of organoaluminium compounds. Part 11. Nitric oxide complexes of trimethyl-aluminium and -gallium and the crystal and molecular structure of [Me3Al(ONNMeO)AlMe2] (1980) (7)
Synthesis, structure and electrochemistry of the first fulvalene derivative of an actinide (1995) (7)
Tin and Mercury Compounds Supported by a Bulky Organometallic Ligand Incorporating a Pendant Guanidine Functionality (2014) (7)
Synthesis of a η2-2,3-diphosphabutadiene complex of zerovalent platinum from the corresponding η2-phosphaalkyne complex (2003) (7)
Synthesis and Structures of Five Crystalline Organometallic (Li/Y, Mg/Mg) or Coordination (Mg, CrII, Y/Y) Complexes † (2011) (6)
Co-ordination chemistry of electron-rich poly(organosulphur) compounds. Part 2. Comparative data on reactions of di-µ-chloro-bis[chloro(triethylphosphine)platinum(II)], and the crystal and molecular structure of cis-µ-2,2-bis(methylthio)ethene-1,1-dithiolato-SS″ : S′S‴-bis[chloro(triethylphosphine)p (1979) (6)
The dimerization of the chromene, precocene II (1984) (6)
Vanadium(II)-diamine complexes: synthesis, UV-Visible, infrared, thermogravimetry, magnetochemistry and INDO/S characterisation (2003) (6)
Organometallic compounds of Group 13 elements containing the ligand C(SiMe3)2(SiMe2C5H4N-2) (2005) (6)
Lithiation of ferrocenylamines and vanadium dinitrogen chemistry (2002) (6)
Preparation and structures of some new pyrrolidinido- and piperidinidoalanes and -aluminates (1996) (6)
Main group complexes incorporating 1,3-bis(furyl)-1,1,3,3-tetramethyldisilazide ligands (2007) (6)
Complexes of lithium tetrahydroaluminate with N,N,N′,N′-tetramethylethane-1,2-diamine (tmen). Crystal structures of [{Li(tmen)(AlH4)}2] and [Li(tmen)2][AlH4] and the use of the 6Li-{1H} nuclear Overhauser effect to study LiAlH4 and LiBH4 in donor solvents (1998) (6)
The Stereochemistry of Epoxidation of Steroidal 4,6-Dienes (1999) (6)
A dilithium o-phenylenediphosphide [Li(tmeda)]2[C6H4(PR)2-1,2] as a [C6H4(PR–)2-1,2] or [C6H4(P2–)2-1,2] synthon: the X-ray structures of C6H4[PCH2CHOCMe2OCHCH2-RR]2-1,2 and [C6H4{P(SiBut-P)-1,2}]3(µ3-SiBut)(R = SiMe3, tmeda =[Me2NCH2]2) (1992) (6)
Notizen/Notes Synthese und Struktur von 2-Phosphonioallen-Komplexen (1991) (6)
Preparation and X-ray crystal structure of an unusual bicyclic trisilane-tris(disoloxane) (1988) (6)
Synthesis of stable fused 2,1,4-oxathiazolidines by a novel and efficient photochemical reaction (1983) (6)
Synthesis of 1,3-thiazetidines and 2,1,4-oxathiazolidines by high yielding novel photochemical rearrangements (1992) (6)
Stereoselective synthesis of non-proteinogenic amino acids (1997) (6)
Novel alkyne and phosphaalkyne coupling on an Ir4 cluster: synthesis and molecular structure of [Ir4(µ-CO)(CO)7{µ4-η3-Ph2 PC(H)C(Ph)PCBut}(µ-PPh2)] (1994) (6)
ent-Norambreinolide from Sideritis nutans (1985) (6)
Amidophosphine ligands as constructs for early–late heterobimetallic complexes; the formation of an anisotropic metallocage (2001) (6)
Palladium-mediated fragmentation reactions of meta photocycloadducts to afford arylated or oxidatively cyclised products (2006) (6)
Synthesis and characterisation of platinum(0) complexes of propenoates: X-ray diffraction study of [Pt(CH2 CHCO2CH2Ph)(PPh3)2] (1997) (6)
New aspects of the Hunsdiecker–Barton halodecarboxylation—syntheses of phospha-shikimic acid and derivatives (2010) (6)
The Oxidation of Some Steroidal Dienes by Potassium Permanganate:Copper Sulfate (1999) (6)
Synthesis of titanium(IV) (cyclopentadienylalkyl)aminate complexes (2003) (6)
Electron-rich olefins as heteroatom donors; the crystal and molecular structures of µ-dimethylthioethene-1,1-dithiolato-SS′S″S‴-bis[chloro(triethyphosphine)platinum(II)] and tetrarbonyl-NN′N″N‴-tetramethylbi(imidazolidin-2-ylidene)-NN″-chromium(0) (1975) (6)
Steric Factors in the Preparation of Nitrostilbenes (2004) (6)
Lithiation and alkylation reactions of the tri-phosphaferrocenes, [Fe(η5-P3C2tBu2)(η5-C5R5)], (R = H and Me): Crystal and molecular structures of the LiFe(η4-P2C2tBu2PnBu)(η5-C5Me5)2 dimer, [Fe(η4-P2C2tBu2PnBuMe)(η5-C5Me5)] and cis-[PtCl2(PMe3)Fe(η4-P2C2tBu2PnBuMe)(η5-C5H5)] (2008) (6)
syn-bromination of trans-triphenylsilylstyrene and its anti-debromosilylation (1976) (6)
The crystal structure of (Me3Si)3CSi(OH)2(OCOCF3). Novel hydrogen bonding (1992) (6)
Syntheses and molecular structures of [Sn{η-C5Me4(SiMe2But)}2] and [Fe{η-C5Me4(SiMe2But)}2] (1996) (6)
Facile formation of a bridging cyclooctatrieneyne ligand; synthesis and molecular structure of [{η-C8H6(SiMe3)2}Zr{CH(SiMe3)2}{µ-η8 : η2-C8H4(SiMe3)2}Zr{CH(SiMe3)2}] (1994) (6)
Synthesis and structures of the dinuclear tin(II) complexes [R = Ph, X(Z) = CPh; R = SiMe3, X(Z) = PPh2] and of related compounds (2009) (6)
New dianionic ligands η5-C–5H4Si(Me)2C–(H)SiMe3 and η5-C–5H4SiMe2{NC(But)C(H)SiMe3}–; syntheses, structures and reactivity of their lithium and zirconium derivatives† (1998) (6)
The molecular and crystal structures of gibberellin A4 and gibberellin A13 methyl esters (1979) (6)
Remarkable carbonylation of a co-ordinated phospha-alkyne ButCP to afford the novel phosphinidene ligand ButC(CO)P, crystal and molecular structure of [Re2(CO)8Pt(dppe){ButC(CO)P}](dppe = 1,2-bisdiphenylphosphinoethane) (1987) (6)
First examples of η1-ligated halogenophosphaalkenes. Crystal structures of trans-[RhCl(PPh3)2{η1-PXC(SiMe3)2}] (X = F or Cl) (1989) (6)
Synthesis and characterisation of three dinuclear β-dialdiminatobismuth(III) dihalides (2010) (6)
Preparation of bis(η6-2-R-benzo[b]thiophene)-chromium and -molybdenum (R = H, Me, SiMe3) sandwich complexes via metal vapour synthesis. Crystal structure of [Cr(η6-2-Me C8H5S)2] (1995) (6)
A monoclinic crystal form of tris(triphenylphosphine)platinum(0) (1989) (6)
The Structure of a Novel Copper(I) Cyanide Complex with Dimethylsulphoxide, (CuCN)2.2DMSO (1986) (6)
Reactions of substituted hydrazines with vanadium(III) compounds: crystal structures of [NH2Me2]2[(VCl3)2(µ-NNMe2)3], [V(OC6H3Pri2-2,6)3(NH2NMe2)2] and [V(OC6H3Pri2-2,6)3(NH2NMePh)2] (1996) (6)
Synthesis and crystal structure of the crowded disiloxane [{(Me3Si)3C}Cl2Si]2O (1990) (6)
Tri-µ-bromo-bis[tribromoruthenate(III)] salts: a synthetic, structural, spectroscopic, and electrochemical study (1990) (6)
A novel molecular species incorporating a cyclic organolithate anion and a disiloxane-solvated lithium cation (1998) (6)
Isolation, characterization, and chemical reactions of fullerenes (1993) (6)
Planar Chirality and Helical Polymers: Ferrocenyl-Substituted Amidinium―Carboxylate Salts (2011) (5)
Crystal Structure of [SiH2Mes2] (Mes = 2,4,6-trimethylphenyl) (2005) (5)
Crystal structure and variable-temperature hydrogen-1 nuclear magnetic resonance spectrum of (dimethylnitratosilyl)[methyldiphenylsilyl]bis(trimethylsilyl)methane, C(SiMe3)2(SiMePh2)(SiMe2 ONO2) (1984) (5)
The crystal structure and absolute configuration of the complex (+)‐trans‐{PtCl[SiMe‐(1‐C10H7)Ph](PMe2Ph)2} (1976) (5)
Novel photochemical rearrangements of dihydro-1,3-thiazines (1998) (5)
Steric effects in the tetracyanoethylene catalysed methanolysis of some cyclohexane epoxides (2005) (5)
A crowded lithium diaryloxo{tris(trimethylsilyl)methyl}aluminate and a bis(triarylsiloxo){tris(trimethylsilyl)methyl}alane (2002) (5)
A diplatinum complex containing one bridging and two chelating dppm ligands. The X-ray structure analysis of [Pt2 (dppm)3] [PF6]2 (dppm = Ph2CH2PPh2) (1984) (5)
The First Structurally Characterized Diorganoaluminate (2003) (5)
Syntheses, Structures and Photoelectron Spectra of Phospha-Alkenes and Phospha-Alkynes and Their Transition Metal Complexes (1983) (5)
New pathways in the reaction between the 1,2,4-triphosphole P3C2But2CH(SiMe3)2 and selenium: Crystal and molecular structures of three new cage compounds, P3Se4C2But2CH(SiMe3)2, P3Se3C2But2 H2CH(SiMe3)2 and P5Se2C4But4(CHSiMe3But) (2007) (5)
Syntheses and characterization of novel sterically demanding amido ligand derivatives and their alkali metal ion complexes, crystal structures of [SiH2Mes2], [NH(SiHMes2)2] and [Na{N(SiHMes2)2}(OEt2)] (2006) (5)
Remarkable organophosphorus cage compounds from the reaction of cobaltocene and the triphosphole (P3C2Bu2CH)-C-t(SiMe3)(2): crystal and molecular structures of [Co(eta(C5H5)-C-5)(eta(H4CHCHP6C4Bu4t)-H-4)] and (P6C4Bu4CH)-C-t(SiMe3) (2001) (5)
Surprising reactions of a 2H-azaphosphirene complex with a silylene. (2005) (5)
Synthesis and Characterization of a Series of 1, 2‐Phenylenedioxoborylcyclopentadienes (2003) (5)
Group 9 metal 1,1′-bis(phosphino)ferrocene complexes: synthesis, structures, solution conformation and unusual reactivity (1996) (5)
An alternative to the use of delta-lactam urethanes in the "ring switch" approach to higher homologues of AMPA-type glutamate antagonists. (2003) (5)
A total synthesis of galbonolide B. (2007) (5)
2,2'‐Bithiophene‐5‐carbaldehyde (1994) (5)
Synthesis, characterisation, and crystal structure of a tetra(phosphino)ethene [Ph]2 (1989) (5)
Triangulo-μ3-sulfido-trinickel(II) cone-shaped clusters and anion traps: structural characterization (2004) (5)
Novel phosphaalkyne/benzoyldiazenido ligand coupling forming the first η2-phosphidocarbene complex. Synthesis and molecular structure of [ReCl2{η4-N(NCOPh)PCButPCBut}(PPh3)] (1991) (5)
Tris(triphenylphosphine)(trifluorophosphine)rhodium(I) hydride benzene solvate (1977) (5)
CLEAVAGE OF AN SI-ME BOND BY INTRAMOLECULAR ALKOXIDE-ION ATTACK. CRYSTAL STRUCTURE OF 6,6-BIS(TRIMETHYLSILYL)NORBORNAN-ENDO-2-OL (1991) (5)
The synthesis and crystal structure of μ-di-η6-phenyl(trimethylsilyl)methane-bis(tricarbonyl)chromium (1988) (5)
The metabolism of the sesquiterpenoid 12-nor-8α-presilphiperfolan-9β-ol by the fungus Botrytis cinerea (2004) (5)
Preparation and reactions of nitrosyl complexes of molybdenum and tungsten; X-ray structure of trans-[Mo(OH)(NO)(Ph2PCH2CH2PPh2)2]·2C4H8O (1982) (5)
The stereochemistry of the Grignard reaction of steroidal 4,5-epoxy-3-ketones (2005) (5)
Double stereodifferentiation in aldol reactions on protected pyroglutamate esters (2001) (5)
Synthesis of reactive γ-lactams related to penicillins and cephalosporins (1996) (5)
Synthesis and structures of dinuclear low-coordinate lithium and zirconium(IV) complexes derived from the diamido ligands 1,3-(CH2C6H3R12)2C6H4(R1= Me or Pri) (2002) (5)
Syntheses and crystal structures of some lithium di- and tri-(thiolato)[tris(trimethylsilyl)methyl]aluminates (2000) (5)
The formation of an ent-6α,7α-epoxykaurene of possible biosynthetic significance by Gibberella fujikuroi (1982) (5)
Novel rearrangements of sesquiterpenoid panasinsane derivatives under acidic conditions. (2001) (5)
1H-Benzimidazolium hydrogen l-tartrate dihydrate (1994) (5)
Reaction of the dinitrogen complex [Re(η2-S2PPh2)(N2)(PMe2Ph)3] with methylisocyanide. Preparation and X-ray structure of the mixed dinitrogenisocyanide complex mer-[Re(η1-S2PPh2)(N2(CNMe)(PMe2Ph)3] (1983) (5)
The first 2,3-dihydro-1H-[1,2,4] triphosphole (2002) (5)
Investigation of a route to ibotenic acid analogues via a reduced pyroglutamate template. (2006) (5)
SYNTHESIS, NMR SPECTROSCOPIC STUDIES, AND X-RAY STRUCTURES OF PLATINUM(II) COORDINATION COMPLEXES OF THE ORGANOPHOSPHORUS CAGE COMPOUNDS P4C4Bu4 t AND P5C5Bu5 t (1996) (5)
Reaction of the stable silylene Si[(NCH2But)2C6H4-1,2] with lithium amides. (2005) (5)
Oxotitanium(IV) and dichlorotitanium(IV) complexes with tetradentate Schiff bases (2000) (5)
Redox Processes Involved in the Synthesis and Reactivity of Oxazolinylthiophenolato Complexes of Iron(II)/(III) (2010) (4)
Synthesis of Substituted Oligothiophenes and X‐Ray Crystal Structures of 3′‐Methyl‐2,2′:5′,2′′‐terthiophene, 3,3′′‐Dimethyl‐2,2′:5′,2′′‐ terthiophene, and 5′‐(2‐Thienyl)‐2,2′:3′,2′′‐terthiophene. (1997) (4)
Novel α,ω-bis(trialkylsilyl)-allyl and -1-azapentadienyl ligands; structures of [Li{η3-CH(CHSiMe2But)2}(tmen)], [Li{N(SiMe3)CBut(CH)3SiMe2But}(tmen)] and [K{η4-N(SiMe2But)CBut(CH)3SiMe2But}]∞ (1996) (4)
The Influence of para Substituents on the Rotation of Aromatic Nitro Groups (2004) (4)
Novel ring opening and halogen transfer from platinum(II) to phosphorus in the reaction of [PtCl2(CNR)2](R = But,p-MeOC6H4) with the phosphirene ring PPhCPhCPh. Crystal and molecular structure of the dimeric chlorophosphane complex [PtCl(PClPhCPhCPh)(CNBut)]2 (1993) (4)
Opening “Jaws”: Functionalisation of the hexaphosphapentaprismane cage, P6C4tBu4, affording X2P6C4tBu4 (X = Me, I), crystal and molecular structures of X2P6C4tBu4 (X = Me, I) and [cis-PtCl2Me2P6C4tBu4] (2009) (4)
The First Examples of Planar Chiral Organic Benzimidazole Derivatives (2006) (4)
The Stereochemistry of the 1,2-Addition of Grignard Reagents to Some Steroidal Unsaturated Ketones † (2003) (4)
Structural studies of group 1 metal 4-azapentalenyl complexes. (2005) (4)
The stereochemistry and hydrolysis of gibberellin 16,17-epoxides. X-Ray molecular structures of ent-17-acetoxy-1α,10α-epoxy-2β,3α,13,16β-tetrahydroxy-20-norgibberella-7,19-dioic acid 19,2-lactone 7-methyl ester and of ent-17-chloro-1α,10α-epoxy-2β,3α,13,16β-tetrahydroxy-20-norgibberella-7,19-dioic a (1989) (4)
Studies in terpenoid biosynthesis. Part 39. The stereochemistry of the relationship between substrate and oxidant in the hydroxylation of aphidicolin at C-18 by Cephalosporium aphidicola (1992) (4)
The conformation of fujenal, a seco-ring Bent-kaurenoid diterpene (1985) (4)
Crystal Structure of the 1,3-Disilacyclobutane Derivative (Me3Si)2CSiMe2C(SiMe3)2SiMe2 (1998) (4)
1,2,3-Triphenylphosphirene derivatives of the iridium carbonyl clusters [HIr4(CO)9L(μ-PPh2)] (L = CO, PPh3) resulting from substitution, insertion and hydrometallation processes (2000) (4)
Preparation and Characterization of C60Br6 and C60Br8. (1993) (4)
trans‐Di‐μ‐chloro‐bis[chloro(tributylphosphine)palladium] (1995) (4)
Bimetallic complexes of molybdenum and tungsten with functionalized diphosphines: X-ray crystal structure of [{W(CO)3}(μ-mtppe)] (1989) (4)
Studies on the Synthesis of the Zaragozic Acids: Discovery of a Novel Cascade Sequence (1999) (4)
Some 2,6-bis(dimethylamino)phenyl–mercury(II) and –boron complexes (2002) (4)
Mixed-sandwich complexes of zirconium(III) and hafnium(III): Potential analogues of [U(η-C8H6{SiiPr3-1,4}2)(η-Cp∗)] for cyclooligomerisation of CO (2010) (4)
X-Ray diffraction and phosphorus-31 NMR studies of the dynamically disordered 3:2 phenol–triphenylphosphine oxide complex (2000) (4)
Novel photochemistry of the cephalosporin nucleus (1985) (4)
Desilylation and cyclometallation reactions of diphenyl{tris(trimethylsilyl)methyl}phosphine with platinum(II) compounds. Crystal structure of trans-[PtClPPh2C(SiMe3)2SiMe2CH2{PPh2CH(SiMe3)2}] (1990) (4)
Synthesis of fused 1,3-thiazetidines by a novel and efficient photochemical rearrangement (1983) (4)
Triphospholes as2e and4e donors: Synthesis and structural characterization of the 1,2,4-triphosphole complexes ?1-trans-[PtCl2(PEt3)(P3C2But2CH(SiMe3)2] and ?1-?1-trans-[PtCl2(PEt3)2}2(?-P3C2But2CH(SiMe3)2] (1998) (4)
Synthesis of µ-carbene and µ-carbyne complexes of rhodium and cobalt from substituted diazirines. Crystal structures of [Rh2(η5-C5Me5)2(CO)2{µ-C(C6H4F-4)(OMe)}] and [Rh2(η5-C5Me5)2(µ-CO)(µ-C6H4Me-4)][BPh4] (1991) (4)
Steroidal allylic and homoallylic rearrangements during halogenation with triphenylphosphine and carbon tetrachloride (1988) (4)
The synthesis and single-crystal X-ray structure of the first mononuclear iridium carbonyl hydride with two orthometallated phosphite ligands, cis-[IrHCO{P(O-o-tBuC6H3) (O-o-tBuC6H4)2}2] (1999) (4)
Novel and efficient photochemical rearrangement of 1,3-thiazine derivatives (1981) (4)
Synthesis of µ-carbene complexes of rhodium from substituted diazirines (1987) (4)
Reactivity of an N-mesityl bis(phosphinimino)methane with group 10 metals (2007) (4)
New titanium(IV) and vanadium(IV) haloalkoxides: synthetic route and structural characterisation (2003) (4)
Coupling of two phospha-alkyne units via a carbonyl group, in the addition across the RhRh double bond of [Rh2(CO)2(η5-C5Me5)2], crystal and molecular structure of the complex [Rh2(CO)(η5-C5Me5)2{PCRC(O)CRP}](R = adamantyl) (1987) (4)
The structure of albidin—an X-ray crystallographic study (1986) (4)
Sulphurisation reactions of P5C5tBu5 and P5C5tBu5H2: crystal and molecular structure of the ethanol adduct of P5C5tBu5H2S3 (1992) (4)
Into the second dimension with ferrocenebis-amidinium salts (2012) (4)
First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(PriNH)2CH2But}2] (2000) (4)
Crystal and molecular structure of 10,10-dimethyl-3,4-dioxatricyclo-[5.2.1.0]decane-2-spiro-2′-adamantane and a comparison of C–O and O–O bond lengths in small rings as a function of ring size (1979) (4)
Resolution of 2-methyoxy-2-(2'-thiazinyl)glycinates (1991) (4)
The metabolism of the diterpenoid hydrocarbon, ent-trachylobane, by Gibberella fujikuroi and the X-ray structure determination of the methyl ester of trachylobagibberellin A40 (1982) (4)
NOVEL METHOXYL AND HYDROXYL DIRECTED PINACOL REARRANGEMENTS OF AN ISOCARYOLANE SESQUITERPENOID UNDER MITSUNOBU CONDITIONS (1999) (4)
Synthesis and structures of crystalline Li, Al and Sn(II) 1-azaallyls and beta-diketiminates derived from [Li{mu,eta3-N(SiMe3)C(Ad)C(H)SiMe3}]2 (Ad = 1-adamantyl). (2008) (3)
Stereochemistry of hydroboronation and osmylation of 3α,5-cycloandrost-6-en-17-one (1988) (3)
Synthesis and X-Ray Crystal and Molecular Structure of1,6-Bis(3-thienyl)hexane (1997) (3)
The Transannular Effect of One Androstane Epoxide on the Stereochemistry of a Second Epoxidation (1999) (3)
Absolute configuration of (+)‐ethambutol hydrobromide (1992) (3)
N,N,N′,N′-tetramethylethane-1,2-diamine complexes of vanadium chlorides (2003) (3)
Syntheses and Structures of (η4-2-Phosphabutadiene)tricarbonyliron Complexes (1997) (3)
Adduct formation between diphenyltin dichloride and 2-phenyl-1,3-dithiane trans-1-trans-3-dioxide: preparation, spectroscopy, crystal and molecular structure of Ph2SnCl2.CH2(CH2)2SOCH(Ph)SO (1997) (3)
A 13C NMR Method for Determining the Stereochemistry of the A/B Ring Junction in B-Norsteroids (1999) (3)
Neighbouring group participation on the bromination of methyl gibberellate: X-ray molecular structure of methyl 3,13-di-O-acetylgibberellate 16β,17-dibromide and ent-3α,13-diacetoxy-17-bromo-10β,16β-dihydroxy-20-norgibberell-1-ene-7,19-dioic acid 19,10-lactone 7-methyl ester (1988) (3)
Synthesis and structures of neutral and cationic 1-azaallylaluminium methyls† (1999) (3)
Yttrate Metathesis: Ligand Design for the Controlled Synthesis of f-Block Heterobimetallic Compounds We thank the Royal Society for the provision of a University Research Fellowship (M.S.H.) and Dr. A. G. Avent for assistance with NMR spectra. (2001) (3)
Orthorhombic crystal form of trans‐carbonylchlorobis(triphenylphosphine)rhodium(I) dichloromethane solvate (1991) (3)
Synthesis, structure and reactivity of ionogenic Sn(η-CpR)Cl derivatives (1996) (3)
Synthesis and Characterization of Monomeric Aryloxo Palladium Complexes of the Type [Pd(N–N)(OAr)(C6F5)].Crystal Structure of [Pd(tmeda)(C6F5)(OC6H4NO2‐p)] (2005) (3)
The stereochemistry of a rearrangement and fragmentation reaction of ring D of 13-hydroxygibberellins (1988) (3)
Lanthanide(II) Complexes of the Dihydrotriazinido Ligand [N{C(Ph)=N}2C(tBu)Ph]− (2008) (3)
A sodium boroxide containing an unusual Na4O4 ladder core (2010) (3)
Regiospecificity in the Hydroborationof 6-Hydroxyandrost-4-enes. (1997) (3)
Rac-cis-1,2-bis(phenylsulfinyl)ethenebis(triphenylphosphine)-platinum(0), a novel Pt(0)-olefin complex: preparation, properties and molecular structure (1997) (3)
The effect of a 4-Formyl and Hydroxymethyl Substituent on Steroid Biotransformations by Mucor Plumbeus † (2003) (3)
Neighbouring group participation in the reduction of the diterpenoid fujenal (1987) (3)
The hydroxylation at C-17 in the biosynthesis of the diterpenoid aphidicolin (1997) (3)
Photochemical transformations of cephalosporins (1992) (3)
Synthesis and Structural Characterization of the First Neutral Homoleptic Lanthanide Metal(III) Alkyls: (LnR3) (Ln = La or Sm, R = CH(SiMe3)2). (1989) (3)
Reductive cyclotetramerization of CO to squarate by a U(III) complex: the X-ray crystal structure of [(U (eta-C8H6{SiiPr3-1,4}2)(eta-C5Me4H)]2(mu-eta2: eta2-C4O4). (2006) (3)
The biotransformation of the Diterpenoid, Rosenonolactone by Mucor Plumbeus (2003) (3)
Ligand–ligand interactions and the structures of simple binary carbonyls (1976) (3)
Structure of an iridium complex of 1,1'-bisdiphenylphosphinoferrocene (1993) (3)
The crystal structure of tetrakis(hydroxydimethylsilyl)methane. A remarkable three-dimensional hydrogen-bonded network (1988) (3)
The Preparation and Microbiological Hydroxylation of 10β,11-Oxido-4α,5α,7β-eremophilane (1999) (3)
Synthesis and characterisation of [AlMen{Si(SiMe3)3}3−n(thf)] (n = 1 or 2) (2007) (3)
Synthesis and structures of the [benzamidinato]3- complexes Li3(tmeda)(L1)]2 and [Li(thf)4][Li5(L2)(OEt2)2] [L1 = N(SiMe3)C(Ph)N(SiMe3) and L2 = N(SiMe3)C(C6H4-4)NPh]. (2011) (3)
Bis(silylaminodiarylphosphoranylsilylmethyl-C,N)-tin(II) and -lead(II) complexes and their precursors; structures of H(LL′), H(LL″), Sn(LL″)2 and Pb(LL″)2; [LL′]− = [CH(SiMe3)P(Ph)2NSiMe3]−, (2006) (3)
1α-Hydroxyalliacolide, a sesquiterpenoid metabolite of Marasmius alliaceus. X-Ray molecular structure of 1α-hydroxyalliacolide (1985) (3)
Facial Selectivity in the Hydroboration of Androst-4-enes. (1995) (3)
1,3 Silicon to silicon migration of the methoxy group in solvolysis of (bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane. Crystal structures of (ethoxydimethylsilyl)(methoxydiphenylsilyl)bis(trimethylsilyl)-methane and (methoxydimethylsilyl)(methoxydiphenylsilyl)bis(trimethylsilyl (1987) (3)
The formation of unsaturated diterpenoid alcohols from 1,4-glycols with N,N-dimethylformamide dimethyl acetal (1990) (3)
Synthesis and structural determination of the stable dinuclear carbonyl-phosphite rhodium(0) complex: (CO)2(P(O-o-tBuPh)3)Rh-Rh(P(O-o-tBuPh)3)(CO)3 (1999) (3)
The Hydroboration of Steroidal Vinyl Halides † (2002) (3)
Novel Organophosphorus Cage Compound Produced by an Unexpected Oxidative Coupling of 1,2,4-Triphosphole: Crystal and Molecular Structures of Two Isomers of Formula P6C4Bu t4 CHSiMe3 (2002) (3)
The stereochemistry of some reactions at C-16 in gibberellins; an X-ray crystallographic study of the methyl esters of gibberellin A2 and gibberellin A9 hydrochloride (1987) (3)
A Structural and Theoretical Study of the Thiophosphinite and Dithiophosphinate Anions (2008) (3)
Isatin Chloride: A Phantom. Reactions of 2‐(2,2‐Dichloro‐2,3‐dihydro‐3‐ oxoindol‐1‐yl)‐3H‐indol‐3‐one. (1997) (3)
Titelbild: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. 26/2006) (2006) (3)
A linear potassium metalated vanadium(IV) polymeric alkoxide: Structural and spectroscopic studies (2006) (3)
Structure of Menthyl Methylphenylphosphinate, an Important Intermediate in Chiral Phosphine Syntheses (1991) (3)
Ureato(1-) complexes of palladium(II) and platinum(II) crystal structure of [NBu4][(C6F5)2Pt{PhNC(O)NPri2}] (2003) (3)
Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu(t)3)(2)], (M = Ni, Pd, Pt). (2009) (3)
Ligating similarities between the novel five-electron-donor η4-P3C2But2(R)H ring system, (R=CH(SiMe3)2) and the η5-cyclopentadienyl ring. Syntheses, crystal and molecular structures of [Co2(CO)5(μ-P3C2But2CH(SiMe3)2)] and [Co(CO)2(η4-P3C2But2H(CH(SiMe3)2] (2000) (3)
Rearrangements of the C/D ring system of the tetracyclic diterpenoid, aphidicolin (1992) (3)
Preparation of Androstanes Related to Aphidicolin (2007) (3)
Synthesis of (2S,3R)-[3',3',3'-2H3]-valine and (2S,3S)-4-fluorovaline. (2004) (3)
First example of the cycloaddition of a terminal phosphinidene across the RhRh bond of [Rh2(η5-C5Me5)2{η-(CO)2}. Crystal structure of [Rh2(η5- C5Me5)2(CO)2{MePW(CO)5}] (1993) (3)
Syntheses and NMR spectroscopic characterisation of transition metal complexes containing the azadiphosphetine ring system RP(NR′)PCR′ (R Et3C, R′tBu)☆ (1993) (2)
The reaction of some substituted 2α,3α-epoxy-5α-hydroxyandrostanes with hydrogen bromide in acetic acid (1991) (2)
The Westphalen Rearrangement of a Tricyclic Steroid † (2003) (2)
Structure of an iridium bis(phosphine) diene complex, a catalyst for homogeneous hydrogenation (1990) (2)
The Stereochemistry of Epoxidation of 5β-methyl-19-norsteroidal 9,10-alkenes (2005) (2)
The bromination of some B-norandrost-5-enes. X-Ray molecular structure of 17β-acetoxy-4β,6α-dibromo-5β-methyl-7,19-dinorandrost-9(10)-ene (1990) (2)
A rearrangement in the nitration of 3β, 17β-diacetoxy-7-norandrost-5-ene (1994) (2)
Interactions between the Aldehyde and Anhydride Groups in the Diterpenoid Fujenal † (2002) (2)
The conformation of some site-specific inhibitors of the ring contraction step in gibberellin plant hormone biosynthesis (1988) (2)
1-Methyl-3-ethylimidazolium Hexachlorouranate(IV) and 1-Methyl-3-ethylimidazolium Tetrachlorodioxouranate(VI): Synthesis, Structure, and Electrochemistry in a Room Temperature Ionic Liquid. (1986) (2)
[3+2] Cycloaddition reactions of the phospha-alkyne, ButCP, with a transition metal trisulphide containing terminal thio ligands: syntheses, crystal and molecular structures of [W(η5-(C5Me5)(S)(S2PCtBu)]2 and [W(η5-(C5Me5)(S)(S2C2Ph2)]2 (1998) (2)
[R = Me, Bu-t or CH(SiMe3)(2)] (2002) (2)
Stereochemistry of epoxidation of some A-norandrost-5-enes (1988) (2)
Boat Forms of Ring A in B-Norsteroids (1999) (2)
Crystal structure of the crowded silanol (Me3Si)3CSiPh2OH (1994) (2)
Geometry of the SiOCN Linkage. Crystal Structure of (Me3Si)2(PhMe2Si)CSiMe2OCN (1995) (2)
Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2](-). (2015) (2)
The structure of perfluorocyclopentadienedicobalt heptacarbonyl (1966) (2)
Li, Al, Sn and Zr Complexes of Bidentate N,N′-Centred Ligands (2001) (2)
A correction to the molecular structure of [dimethyl(phenyl)silyl]tris(trimethylsilyl)methane (1982) (2)
The conformation of some N,N-disubstituted arylamines (2004) (2)
Phosphaalkyne tetramerisation: first structural characterisation of a tetraphosphabishomoprismane. Synthesis and molecular structure of [W2(CO)10(P4C4But4)] (1995) (2)
Ring a Aromatic Steroids in the Pregnane Series (2006) (2)
The Preparation and Crystal structure of 16-Acetylandrosta-4,16-Dien-3-One+ (2003) (2)
Structure of N-methyl benzaldehyde nitrone (1991) (2)
Extended metal–metal interactions in fluorophosphine complexes of iridium(I) (1984) (2)
Partial synthesis of some diterpenoids with potential antitumour activity (1991) (2)
Tin(IV) to platinum(II) ligand transfer reactions of sulfinyl-containing Lewis bases (1997) (2)
The Rotation of the Nitro and Formyl Groups Relative to the Aromatic Ring in Some ortho-nitroarylaldehydes (2008) (2)
The cyclisation of humulene 6,7- and 9,10-epoxides catalysed by tetracyanoethylene (2004) (2)
CYCLONEROTRIOL(6-(3-HYDROXY-2,3-DIMETHYLCYCLOPENTYL)-2-METHYLHEPT-2-ENE-1,6-DIOL), A NEW SESQUITERPENOID METABOLITE OF FUSARIUM CULMORUM (1975) (2)
Adventitious Isolation and Crystal Structure of Potassium 2,4-Dinitrophenolate (1998) (2)
Varied reactions of [M(L)]3 with HgCl2, FeBr2, CeCl3, AgOTf; ligand transfer, nucleophilic attack with recombination and/or fragmentation [M = Li or Na; L = N(SiMe3){C(H)N}3SiMe3]. (2009) (2)
Corrigendum to 'palladium-mediated fragmentation of meta photocycloadducts -using carbon based electrophiles. Part 1' [Tetrahedron 62 (14) (2006) 3423-3434] (2010) (2)
Reactivity of [M(η4-P2C2tBu2)] (M = Ge, Sn), with tert-Butylphosphaethyne P≡CtBu: Synthesis, Structural Characterisation and Computational Studies of the Novel Zwitterionic Organophosphorus Cage Compounds [MP4C4tBu4] (M = Ge, Sn) (2008) (2)
The conformation of some ortho substituted stilbenes (2005) (2)
Lipophilic Strontium and Calcium Alkyls, Amides, and Phenoxides. X-Ray Structures of the Crystalline Square-Planar ((trans-Sr(NR′2)2(μ-1,4- dioxane))∞) and Tetrahedral (CaR2(1,4-dioxane)2); R′ = SiMe3, R = CH(SiMe3)2. (2010) (2)
An unusual hydroboration of 3-hydroxy-3-methyl-Δ4-steroids (2004) (2)
The stereochemistry of reduction of the 1- and 16-carbonyl group in the normal and 8,13-isogibberellins (1984) (2)
Synthesis and structures of beta-dialdiminatoantimony(III) halides and beta-dialdiminium hexahalogenoantimoniates. (2009) (2)
1,3-Bis(diphenylphosphino)propane-2κ2P,P′-{μ-2-[bis(2-mercaptoethyl)amino]ethanesulfinato(3–)-1κ4N,S,S′,S′′:2κ2S,S′}chloro-2κCl-dinitroso-1κ2N-iron(II)nickel(II) acetonitrile hemisolvate (2005) (2)
Aldol reactions promoted by diethylzinc; the X-ray crystal structure and stereochemistry of dypnopinacol. (1991) (2)
The Conformation of Some Disubstituted Anilides (2004) (2)
Formation of 3(4→18)-abeo-aphidicolenes via cyclopropyl intermediates. X-Ray molecular structure of 3(4→18)-abeo-17-noraphidicol-2,18(4)-dien-16-one (1986) (2)
Neighbouring-group participation in the chromium trioxide oxidation of steroidal 4,5-epoxides. X-Ray molecular structure of 4β,6β,17β-triacetoxy-3β,5α-dihydroxyandrostane (1991) (2)
Preparation and Characterization of C60(Ferrocene)2. (2010) (2)
An unusual bis(dicyano-nickel) complex possessing both bridging- and chelate-ligation by 1,3-bis(diphenylphosphino)propane (2005) (2)
Stereochemistry of some reactions of ring D of the diterpenoid aphidicolin (1992) (2)
Novel Hydrogen Transfer Reactions to the Ligated 1,2,4-Triphosphole in [Ru(η4-C8H12){η-P3C2But 2CH(SiMe3)2}] (1997) (1)
The Conformation of Some ortho-bromoarylaldehydes (2008) (1)
Isolation and Spectroscopic Characterization of C60F17CF2CF3 and Isomers of C60F17CF3; Insertion of :CF2 into Fluorofullerene C—F Bonds. (2001) (1)
Synthesis and Decomposition of Dichloroiodoarenes. An Improved Low Temperature X‐Ray Structure of Dichloroiodobenzene and the Structure of 1‐Chloro‐2,3,5,6‐tetrakis(chloromethyl)‐4‐methylbenzene. (1996) (1)
Low oxidation state complexes of group 3 elements. The first isolated examples of scandium in formal oxidation states of (I) and (II). (1997) (1)
An anomalous oxidation of 11α-hydroxyestratrienes with pyridinium dichromate (1985) (1)
Transannular participation of some C-19 esters in reactions at C-20 of gibberellin A13 (1982) (1)
First evidence for two different mu-eta¹-eta¹- and mu-eta¹-eta²- co-ordination modes of the P3C2Bu t2 ring of [Fe(eta5-P3C2Bu t2)(eta5-C5H5)] to a same cluster fragment: synthesis and characterisation of [Ir4(CO)10{[Fe(eta5-P3C2Bu t2)(eta5-C5H5)}] and x-ray molecular structure of the mu-eta¹-eta²- i (2000) (1)
Synthesis and characterisation of six Fe(II or III), Co(II) or Zr(IV) complexes containing the ligand [CH(SiMe2R)P(Ph)2NSiMe3]− (R = Me, NEt2) and of [Co{N(SiMe3)C(Ph)C(H)P(Ph)2NSiMe3}2] (2008) (1)
Comparison of the reactivities of the compounds (Me3Si)2C(SiMe2OMe)(SiMe2Cl) and (MeOMe2Si)3C(SiMe2Cl). Crystal structure of (MeOMe2Si)3CSiPh2H (1991) (1)
Acid-catalysed cleavage of some 3-substituted 5α,6α-epoxy-7-norandrostan-17-ones (1991) (1)
Base catalysed syntheses of the novel tetrahydropyridine-2-thione, piperidine-2-thione and 6-aza-2-oxa-3-oxo-5-thioxobicyclo[2.2.2]octane ring systems (1998) (1)
Cover Picture: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. Int. Ed. 26/2006) (2006) (1)
DIAZOALKANE COMPLEXES OF TUNGSTEN. CRYSTAL STRUCTURES OF (WBR(N-N:CHCH2CH2CH2OH)(DPPE)2)(PF6).0.5ETOH(1) AND (WBR(N-N:CME2)(DPPE)2)BR.0.5MEOH(2) (1980) (1)
Preparation and crystal structure of [tris(trimethylsilyl)methyl]diphenylborane (1984) (1)
1,3-Dinitropyrrolo[1,2-b]isoquinoline-5,10-dione (1992) (1)
Stereochemistry of 4,5:10,11 bis-(tetramethylene)-4,10-cyclotridecadiene-2,6,8,12-tetrayn-1-one (1971) (1)
The Remarkably Stable Emerald Green C60F15[CBr(CO2Et)2]3: The First [60]Fullerene That Is also the First [18]Trannulene. (2001) (1)
The Biotransformation of 5β-Methylestr-9-Enes by Cephalosporium Aphidicola † (2003) (1)
Neighbouring Group Participation in the Tetracyanoethylene Catalysed Methanolysis of some Steroidal Hydroxy-epoxides (1998) (1)
The Effect of a Tertiary Amine in the Catalytic Osmylation of Alkenes. (1995) (1)
Novel Rings and Cages Derived from Phospha-Alkynes (1994) (1)
Steroids Related to the Diterpenoid Tumour Inhibitor Aphidicolin (1998) (1)
A contribution to 1-azapentadienylmetal chemistry: Si, Sn(II), Fe(II) and Co(II) complexes (2009) (1)
β-Diiminatolanthanoid(III) halides revisited (2009) (1)
Synthesis and structures of lithium salts of two cluster iodoarsenate(III)s and a periodohexaantimonate(III) (2010) (1)
catena-Poly[[(1,4-dioxane-O1)iodolithium]-μ-(1,4-dioxane-O1:O4)] (1997) (1)
Synthesis of an external β-turn based on the GLDV motif of cell adhesion proteins (2003) (1)
Protonation of the lithio derivatives of the 1,2,4-tri-phosphaferrocenes, [LiFe(η4-P2C2tBu2PBu)(η5-C5R5)] (R = H, Me): Crystal and molecular structure of [Fe(η4-P3C2tBu2BuH)(η5-C5Me5)] (2008) (1)
THE COORDINATION CHEMISTRY OF ELECTRON-RIC (1979) (1)
Synthesis of alpha-amino esters by dynamic kinetic resolution of alpha-haloacyl imidazolidinones (2001) (1)
CRYSTAL STRUCTURE AND VARIABLE TEMPERATURE HYDROGEN-1 NUCLEAR MAGNETIC RESONANCE SPECTRUM OF (DIMETHYLNITRATOSILYL)(METHYLDIPHENYLSILYL)BIS(TRIMETHYLSILYL)METHANE, C(SIME3)2(SIMEPH2)(SIME2ONO2) (1984) (1)
The Conformation of the Side Chain of 21-Alkylpregnanes † (2003) (1)
Novel Metal Complexes Containing 1-Azaallyl and β-Diketiminato Ligands (2001) (1)
Preparation and structure of an unusually stable cationic µ-carbyne complex of rhodium (1989) (1)
Synthesis and deprotonation of (phenylselenolatodimethylsilyl)bis(trimethylsilyl) methane: The crystal structure of (Me3Si)2(Me2SiBr)CH (2012) (1)
3-Nitrodibenzofuran and 3-iododibenzofuran (1995) (1)
Crystalline metal (Li, Mg, Ca, Sr, Ba, Sn, Pb) complexes of the new chelating N,N'-dianionic [1,2-N(R)C6H4(CH2NR)](2-) ligand (R = SiMe3, CH2Bu(t)). (2011) (1)
Structure of 4-Methoxyphenyl Methyl Sulfone and a Redetermination of the Structure of Methyl Phenyl Sulfone (1992) (1)
The Stereochemistry of Epoxidation of Some Steroidal Alkenes with Potassium Permanganate‐Copper Sulfate. (1995) (1)
Neighbouring Group Participation in the Methanolysis of a Vicinal Diepoxide (1999) (1)
The Hydroxylation of Some Longifolanes by Mucor Plumbeus (2003) (1)
An iridium complex of tris(4‐methoxyphenyl)phosphine (1994) (1)
The isolation and biosynthesis of the chromone 6-hydroxymethyleugenin in Cephalosporium aphidicola (1987) (1)
The Hydrolysis of 3,10-epoxypatchenol under Mild Aqueous Conditions (2005) (1)
Synthesis and structures of the 2-(dimethylsila)pyrimidine derivatives (Ar = Ph, C6H4But-4; X = H, SiMe3, Li(hmpa)2, K(thf)3; n = 1, 2) (2008) (1)
Phosphine‐Catalyzed Cycloaddition of Buta‐2,3‐dienoates and But‐2‐ ynoates to (60)Fullerene. (1997) (1)
The First Neutral, Mononuclear 4f Metal Thiolates and New Methods for Corresponding Aryl Oxides and Bis(trimethylsilyl)amides. (1992) (1)
An iridium complex of tris(2,4,6‐trimethoxyphenyl)phosphine (1994) (1)
STERICALLY HINDERED ′BENZOXETES′ - THE FIRST ISOLATED OXEPINS (1978) (1)
Structure of a novel iridium‐containing hydrogenation catalyst (1989) (1)
Tris(trimethylsilyl)methyl and Tris(dimethylphenylsilyl)methyl Derivatives of Boron. Crystal Structures of Dihydroxy(tris(trimethylsilyl)methyl)borane and of the Lithium-Boron Complex ((MeOH)2Li(μ-OMe)2B(OMe)2). (1989) (1)
The Fullerenes - Precursors for 21st Century Materials. (1994) (1)
Synthesis, crystal structure and nuclear magnetic resonance spectral study of the (+)-(R,R,R*,S*)- and (–)-(S,S,R*,S*)-enantiomers of the chiral diphosphine [C6H4(PPhCH2CHO)2CMe2]-1,2 (1995) (1)
Synthesis of cyclopropa[d]thiazolines by a novel and efficient photochemical rearrangement of 1,3-thiazines (1992) (1)
The Formation and Structure of Some Androstane 4- and 6-Ketones (1999) (1)
The reactions between the aldehyde-anhydride fujenal and ammonia, hydrazine and hydroxylamine (2004) (1)
Synthesis of Silver (I) Complexes of Iminoalkyl Functionalised N-Heterocyclic Carbenes (2010) (1)
Modern X-Ray Analysis on Single Crystals, : by P. Luger. W. de Gruyter, Berlin and New York, l980, xiv + 312 pages, DM 96. (1980) (1)
Structure of methyltris(2,4,6‐trimethoxyphenyl)phosphonium iodide ethanol solvate (1993) (1)
Isolation and Characterization of Symmetrical C60Me6, C60Me5Cl and C60Me5O2OH, Together with Unsymmetrical C60Me5O3H, C60Me5OOH, C60Me4PhO2OH, and C60Me12; Fragmentation of Methylfullerenols to C58. (2002) (1)
Different modes of hydrogen migration in reactions of diphosphaallene, ArPCPAr (Ar = 2,4,6-But3C6H2) with [W(CO)5(THF)] and [Fe3(CO)12]. Crystal and molecular structure of [Fe2(CO)6(ArPCHPCH2(CMe2)C6H2But2)] (1988) (1)
Base-catalysed epoxidation and reduction of 3-formyl-A-norandrost-3(5)-en-17-one (1981) (1)
THE NATURE OF THE COORDINATE LINK. PART 11. SYNTHESIS AND PHOSPHORUS-31 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF PLATINUM AND PALLADIUM COMPLEXES CONTAINING SIDE-BONDED (E)-DIPHENYLDIPHOSPHENE. X-RAY CRYSTAL AND MOLECULAR STRUCTURES OF (PD((E)-PHP:PPH)(PH2PCH2CH2PPH2)) AND (PD(((E)-PHP:PPH)(W(CO)5 (1985) (1)
An X-ray crystallographic study of the conformation of arylmethanesulfonamides (2004) (1)
cis-Bis(2,2′-bipyridine)bis(pyridine)ruthenium(II) Salts: A Spectroscopic and Structural Study. (1988) (1)
The Oxidation of 3-Hydroxy-3-Methyl-Δ4-Steroids by Chromium Trioxide † (2003) (1)
Subvalent Group 14 Metal Compounds. Part 10. Syntheses and Structures of Some Bis(metallo)plumbylenes (Pb(Mo(R)(CO)3)2(OC4H8)) (R: η-C5H5, η-C5H3(SiMe3)2-1,3, or η-C5Me5); X-Ray Crystal Structures of (Pb(Mo(η-C5Me5)(CO)3)2(OC4H8)) and (1988) (0)
CCDC 172116: Experimental Crystal Structure Determination (2002) (0)
The First Delocalized Phosphole Containing a Planar Tricoordinate Phosphorus Atom: 1‐[Bis(trimethylsilyl)methyl] ‐3,5‐bis(trimethylsilyl)‐1,2,4‐triphosphole. (1998) (0)
Unusual Stereoselectivity in the Alkylation of Pyroglutamate Ester Urethanes. (2002) (0)
THE CRYSTAL STRUCTURE OF THE COMPOUND MESO,MESO′-ETHYLENEBIS(OCTAETHYLPORPHYRINATONICKEL(II)) (1983) (0)
The Stereochemistry of Reactions of 5 β-Androst-3-enes (1998) (0)
PREPARATION AND REACTIONS OF NITROSYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN: X-RAY STRUCTURE OF TRANS-BIS(1,2-BIS(DIPHENYLPHOSPHINO)ETHANE)HYDROXY(NITROSYL)MOLYBDENUM-TETRAHYDROFURAN (1:2) (1982) (0)
Subvalent Group 14 Metal Compounds. Part 13. Oxidative Addition Reactions of Germanium and Tin Amides M(NR2)2 (R: SiMe3, M: Ge or Sn) with Sulfur, Selenium, Tellurium or MeOOCCCCOOMe; X‐Ray Structures of (Ge(NR2)2(μ‐Te))2 and Cyclic Sn(NR2)2CC(OMe)OSn(NR2) 2CC(OMe)O. (1991) (0)
SYNTHETIC, STRUCTURAL AND SPECTROSCOPIC STUDIESOF HETERONUCLEAR (OXO)ALKOXIDESAS PRECURSORSFOR MIXED-METAL OXIDES (2005) (0)
A Synthesis of (+)-Prelog-Djerassi Lactonic Acid. (1999) (0)
UNUSUAL, THERMALLY STABLE, SUBLIMABLE (ARYLAMINO)DIHALOBORANES OR -DIAMINOBORANES: X-RAY CRYSTAL STRUCTURE OF BIS(AMINO)(2,4,6-TRI-TERT-BUTYLPHENYLAMINO)BORANE (1984) (0)
THE SYNTHESIS AND PROPERTIES OF THE TRANSANNULARLY BONDED ELECTRON‐RICH OLEFIN DERIVED FROM 1,4,8,11‐TETRAAZACYCLOTETRADECANE; X‐RAY CRYSTAL STRUCTURE OF THE CHELATING CIS‐DICARBENERHODIUM(I) SALT OBTAINED THEREFROM (1981) (0)
Desilylation and Cyclometallation Reactions of Diphenyl(tris(trimethylsilyl)methyl)phosphine with Platinum(II) Compounds. Crystal Structure of Cyclic trans-(PtClPPh2C(SiMe3)2SiMe2CH2(PPh2CH(SiMe3)2)). (1990) (0)
NOVEL INTRAMOLECULAR HYDROGEN-ATOM TRANSFER IN AN ETA 4-LIGATED CYCLOOCTA-1,5-DIENE ETA -1,2,4-TRIPHOSPHOLE RUTHENIUM(O) COMPLEX. SYNTHESIS, CRYSTAL A ND MOLECULAR STRUCTURES OF RU(ETA 4-C8H12)ETA -P3C2BUT2CH(SIME3)2 AND RU(ET A 5-C8H11)ETA -P3C2BUT2HCH(SIME3)2 (1996) (0)
The Formation and Structure of Some Androstane 4‐ and 6‐Ketones. (1999) (0)
X-ray structure determination—A practical guide : by G.H. Stout and L.H. Jensen, Wiley-Interscience, Chichester, 1989, xv + 453 pages, £35.50. ISBN 0-471-60711-8 (1990) (0)
Carbene Complexes. Part 21. Synthesis and Characterization of Bis(carbene)molybdenum(II) Complexes and Dimetal(0) Complexes of the Group 6 Elements Containing Novel Bridging Bis(carbene) Ligands; X-Ray Structures of (Mo(CO)2(LEt)2(OSO (1988) (0)
Preparation and X-Ray Structure of mer-|Re(η1-S2 PPh2)(N2)(CNME)(PMe2Ph)3|, a Mixed Dinitrogen-Isocyanide Complex Stabilized by a Sulphur Ligand (1984) (0)
Base-Catalyzed Syntheses of the Novel Tetrahydropyridine-2-thione, Piperidine-2-thione and 6-Aza-2-oxa-3-oxo-5-thioxobicyclo[2.2.2]octane Ring Systems. (2010) (0)
Structure of tris(2,4,6‐trimethoxyphenyl)phosphine oxide hydrate (1993) (0)
Preparation of Isocyanide and Mixed Dinitrogen-Isocyanide Complexes of Rhenium(I) from Reactions of trans-(ReCl(N2)(PMe2Ph)4), mer-(Re(S2PPh2)(N2)(PMe2Ph)3), or mer-(Re(S2CNEt2)(N2)(PMe2Ph)3) with Methyl Isocyanide; Crystal Structure (1987) (0)
The Stereochemistry of the 1,2‐Addition of Grignard Reagents to Some Steroidal Unsaturated Ketones. (2004) (0)
Syntheses and structures of structurally diverse potassium ??-diketiminates derived from the ligand [{N(SiMe3)C(Ph)}2CH]???Electronic supplementary information available: details of crystallography for 1???4 and further analytical data for 1???5. See http://www.rsc.org/suppdata/cc/b2/b205296b/ (2002) (0)
HYDRAZIDO(2-)(OR ISODIAZENE) COMPLEXES OF TUNGSTEN (1979) (0)
REACTION OF TRIMETHYLGALLIUM WITH TRICARBONYL‐ETA(5)‐CYCLOPENTADIENYLHYDRIDOTUNGSTEN AND WITH DICARBONYL‐ETA(5)‐CYCLOPENTADIENYLHYDRIDO(TRIPHENYLPHOSPHINE)TUNGSTEN, CRYSTAL AND MOLECULAR STRUCTURE OF MU(3)‐GALLIOTRIS(TRICARBONYL‐ETA(5)‐CYCLOPENTADIENYLTUNGSTEN) (1975) (0)
Platinum and palladium complexes of 2-aminofluorene; structure of trans-(2-aminofluorene)(triethylphosphine)-platinum(II) dichloride (1993) (0)
Synthesis of chromium(0) and molybdenum(0) bis (eta(6)-arene) derivatives and their monoelectronic oxidation to [M(eta(6)-arene)(2)](+) cations. (2006) (0)
Tri-μ-bromo-bis(tribromoruthenate(III)) Salts: A Synthetic, Structural, Spectroscopic, and Electrochemical Study. (1990) (0)
Biotransformation of the Fungistatic Sesquiterpenoid Ginsenol by Botrytis cinerea. (1999) (0)
The Preparation and Crystal Structure of 16-Acetylandrosta-4,16-dien-3-one. (2003) (0)
New reactions of beta-diketiminatolanthanoid complexes: sterically induced self-deprotonation of beta-diketiminato ligands. (2005) (0)
Structure and Biosynthesis of Harzianopyridone, an Antifungal Metabolite of Trichoderma harzianum. (1990) (0)
CCDC 609883: Experimental Crystal Structure Determination (2006) (0)
Lipophilic metal (Na, TiIII, ZrIV, RhI and PdII) complexes derived from the hybrid ligands -OR and HOR (R = Me2PCH2CBut2) ; the X-ray structures of [TiCl(OCBut2CH2PMe2)2] and trans-[Rh(CO)Cl(PMe2CH2CBut2OH)2] (1993) (0)
A Rearrangement in the Nitration of 3β,17β-Diacetoxy-7- norandrost-5-ene. (2010) (0)
Novel Compounds Derived from the 1,2,4‐Triphosphacyclopentadienyl Anion P3C2tBu‐ 2. (1997) (0)
Synthesis and Structural Characterization of the First Example of a 3, 3′-Diphospha-1,1′-biphospholyl Ring System. Crystal and Molecular Structure of P4C6tBu6. (1993) (0)
CARBENE COMPLEXES. 16. SYNTHESI (1980) (0)
Suzuki—Miyaura Cross‐Coupling of Aryl and Alkyl Halides Using Palladium/Imidazolium Salt Protocols. (2004) (0)
First Example of a 1,2,4-Triphosphabuta-1,3-diene Complex: Synthesis and Crystal and Molecular Structure of (Co(η5-C2R2P3)(η4-C2R2HP3)) (R = But). (1988) (0)
Synthetic, Structural and Theoretical Studies on New Aromatic 1,2,4-Azadiphosphole Ring Systems: Crystal and Molecular Structure of P2C2tBu2NPh. (2000) (0)
Bicyclic Guanidinate Compounds of Magnesium and Their Activity as Pre‐Catalysts in the Tishchenko Reaction. (2011) (0)
Formation of a Medium Ring Imino Ether by a Diazo Insertion Reaction. (1997) (0)
Some Sterically Hindered Lithium Alkylbromo- and Alkylchloro-magnesates, -cadmates, and -manganates. Crystal and Molecular Structures of (Li(thf)2(μ-Br)2Mg(C(SiMe3)3)(thf)), (Li(thf)4) ((Cd(C(SiMe3)3))3(μ-Br)3(μ3-Br))·0.5 C6H12, ((Li( (1988) (0)
Neighboring Group Participation in the Methanolysis of a Vicinal Diepoxide. (1999) (0)
PREPARATION OF THE ISOCYANIDE COMPLEXES TRANS-(RECL(CNR)(DPPE)2) (R = ME OR CME3) AND THEIR REACTIONS WITH ACID TO GIVE CARBYNE COMPLEXES. X-RAY CRYSTAL STRUCTURE OF TRANS-(RECL(CNHME)(DPPE)2)(BF4) (1981) (0)
NOVEL C-H ACTIVATION IN A BIS-TETRAIRIDIUM CARBONYL COMPLEX OF THE SANDWICH COMPOUND FE(ETA 5-C5H5)(ETA 5-P3C2BUT2) : CRYSTAL AND MOLECULAR STRUCTURES OF IR4(CO)11FE(ETA 5-C5H5)(ETA 5-P3C2BUT2) AND HIR4(CO)10-MU -FE(ETA 5-C5H 5) (ETA 5-P3CH2(CME2)CBUT)IR4(CO)11 (1996) (0)
Synthesis of the η1‐Phosphaalkyne Complex trans‐(FeH(P CtBu)(dppe)2)(BF4) and Its Conversion into a η1‐ Fluorophosphaalkene Complex. Crystal Structure of trans‐(FeH(PF=CHtBu)( dppe)2)(FeCl2F2). (1991) (0)
Steroidal Allylic and Homoallylic Rearrangements During Halogenation with Triphenylphosphine and Carbon Tetrachloride. (1988) (0)
Preparation and Some Reactions of the Compounds HgVsi2, CdVsi2, and Hg(Vsi)Br (Vsi = (Me3Si)2((CH2=CH)Me2Si)C). Crystal Structure of CdVsi2. (1987) (0)
Ring A Aromatic Steroids in the Pregnane Series. (2006) (0)
Complexes of Organoaluminium Compounds. Part 13. Preparation and NMR Spectra of the Arylamido-compounds AlMe2(NHR′) (R′ : Ph, C6H4Me-o, C6H4Me-p, C6H3Me2-2,6) and the Imido-compounds AlMe(NR′). (1986) (0)
The Inhibition of the Fungus Botrytis cinerea by an Eremophilane Phytoalexin Analogue. (2005) (0)
Cycloaddition Reactions of a 1,2,4-Triphosphacyclopenta-1,3-diene. Synthesis, Crystal, and Molecular Structure of the Novel Hexaphosphorus Cage Compound P6C4But3H2 Containing Five Directly Bonded Phosphorus Atoms. (1990) (0)
Synthesis and Structure of a rac‐Tris(divinyldisiloxane)diplatinum(0) Complex with Its Reaction with Maleic Anhydride. (1991) (0)
Stannadesulfurization of a bis(diethyldithiocarbamato)tungsten(II) complex. Formation of an aminocarbynetungsten complex [Erratum to document cited in CA113(17):152677r] (1991) (0)
Stereochemistry of Some Reactions of Ring D of the Diterpenoid Aphidicolin. (1992) (0)
Controlling Diastereoselectivity in the Reactions of Enantiomerically Pure α-Bromoacyl-imidazolidinones with Nitrogen Nucleophiles: Substitution Reactions with Retentions or Inversion of Configuration. (2005) (0)
Preparation and Crystal Structures of the Crowded Organotin Fluorides (PhMe2Si)3CSnMe2F, (Me3Si)3CSnMe2F, and (Me3Si)3CSnPh2F. (1987) (0)
A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu)}2C6H4‐1,2] (2008) (0)
CCDC 271691: Experimental Crystal Structure Determination (2006) (0)
Regiospecificity in the Hydroboration of 6‐Hydroxyandrost‐4‐enes. (1997) (0)
Some (Tris(trimethyl)silyl)methyl and (Tris(dimethylphenyl)silyl)methyl Derivatives of Phosphorus. The Crystal Structure of (Tris(dimethylphenyl)silyl)methylphosphonous Dichloride. (1989) (0)
THE PREPARATION AND MICROBIOLOGICAL HYDROXYLATION OF 10BETA , 11-OXIDO-4ALPHA , 5ALPHA , 7BETA -EREMOPHILANE (1999) (0)
The First Monomeric Prochiral Tin(II) Complexes Sn(N(SiMe3)2)X (X = OC6H2But2-2,6-Me-4, 1 or cyclicNCMe2(CH2)3CMe2, 2). The X-Ray Structure of 1 and Oxidative Addition Reaction of 2. (1992) (0)
Reactions of Zero- and Divalent Platinum Metal Complexes with Phosphirene Ring Systems. Crystal Structures of Cyclic cis-(PtCl2(PEt3)(PPhCPh=CPh)), cis-(PtI(PPh3)(CPh=CPhPPhMe)) and ((Et3P)2Pt(CPh=CPhPPh)W(CO)5). (1991) (0)
The First Structurally Authenticated Divalent Lanthanoid Stannyl Derivative. (1992) (0)
Novel cages derived from 1,2,4-triphosphacyclopentadiene (2001) (0)
An Unusual Hydroboration of 3-Hydroxy-3-methyl-Δ4-steroids. (2006) (0)
Researches on non-classical organolanthanide chemistry (2003) (0)
The Oxidation of 3‐Hydroxy‐3‐methyl‐Δ4‐steroids by Chromium Trioxide (2004) (0)
CRYSTAL AND MOLECULAR STRUCTURES OF CIS-DICHLOROBIS(TRIFLUOROPHOSPHINE)-BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II), CIS-RUCL2(PF3)2(PPH3)2, AND DICHLORO(2,7-DIMETHYLOCTA-2,6-DIENE-1,8-DILYL)(TRIFLUOROPHOSPHINE)RUTHENIUM (IV) RUCL2(PF3)(C10H (1975) (0)
Partial Synthesis of Some Diterpenoids with Potential Antitumor Activity. (1992) (0)
Synthesis, structure, and reactivity of a μ-bis(dialkylphosphido)-dilithium [Li(μ-PR2)]2 (1984) (0)
New Cages Derived from 1,2,4-Triphosphol (2002) (0)
Rearrangements of the C/D Ring System of the Tetracyclic Diterpenoid, Aphidicolin. (1992) (0)
CARBENE COMPLEXES. 14. THE SYNTHESIS, STE (1978) (0)
Photochemical Transformations of Cephalosporins. (1992) (0)
Aspects of the Chemistry of Subvalent Organic Compounds of Germanium, Tin and Lead; Synthesis and Structures of the Bis{bis(trimethylsilyl)amido}tin(IV) Chalcogenides (1996) (0)
Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring. (1994) (0)
The Transannular Effect of One Androstane Epoxide on the Stereochemistry of a Second Epoxidation. (2000) (0)
SYNTHESIS AND STRUCTURES OF BISBIS(TRIMETHYLSILYL)AMIDO-TIN(IV) CYCLIC CHALCOGENIDES SNN(SIME3)22(MU -E)2 AND A HETEROBIMETALLIC ANALOGUE ME3SI)2N2GE( MU -TE)2SN-N(SIME3)22 (E = S, SE OR TE) (1995) (0)
The Hexaphosphapentaprismane P(6)C(4)tBu(4): A "Jaws-Like" Cage Molecule That Bites! We thank the EPSRC (M.D.F., J.F.N.), the AEC of Syria, Damascus (M.M.A.K.), The Royal Society (J.F.N., L.N.), and FKFP-0029/2000 (L.N.) for financial support. (2001) (0)
1,3‐Bis(diphenylphosphino)propane‐2κ2P,P′‐dicarbonyl‐1κ2C‐chloro‐2κCl‐{μ‐2,2′,2′′‐nitrilotriethanethiolato(3–)‐1κ4N,S,S′,S′′:2κ2S,S′}iron(II)nickel(II) acetonitrile solvate (2005) (0)
Reactivity of [M(η4-P2C2tBu2)] (M = Ge, Sn), with tert-Butylphosphaethyne P≡CtBu: Synthesis, Structural Characterisation and Computational Studies of the Novel Zwitterionic Organophosphorus Cage Compounds [MP4C4tBu4] (M = Ge, Sn) (Eur. J. Inorg. Chem. 11/2008) (2008) (0)
Uranium halide complexes in ionic liquids (2005) (0)
The Stereochemistry of Epoxidation of Steroidal 4,6-Dienes. (1999) (0)
Synthesis and characterisation of two monomeric crystalline thallium(I) beta-diketiminates. (2005) (0)
Studies in Terpenoid Biosynthesis. Part 39. The Stereochemistry of the Relationship Between Substrate and Oxidant in the Hydroxylation of Aphidicolin at C-18 by Cephalosporium aphidicola. (2010) (0)
A Total Synthesis of Galbonolide B (I). (2008) (0)
Studies on the base-catalysed addition of amines to alkynes and allenes: A novel cascade sequence for the construction of spirocyclic aminals (2006) (0)
Li, Al, Sn and Zr Complexes of Bidentate N,N′‐Centered Ligands. (2002) (0)
Stereoselective Synthesis of β‐Substituted Aspartic Acids via Tetrahydro‐1,3‐oxazin‐6‐ones. (1999) (0)
BASE-CATALYZED EPOXIDATION AND REDUCTION OF 3-FORMYL-A-NORANDROST-3(5)-EN-17-ONE (1982) (0)
PLATINUM-PHOSPHORUS BOND LENGTHS AND NUCLEAR MAGNETIC RESONANCE COUPLING CONSTANTS IN COMPLEXES OF TRI(N-ALKYL)- AND TRICYCLOHEXYLPHOSPHINES. CRYSTAL AND MOLECULAR STRUCTURE OF TRANS-DIIODOBIS(TRIMETHYLPHOSPHINE)PLATINUM(II) (1978) (0)
Homogeneous Hydrogenation of Imines Catalyzed by Iridium Complexes (2017) (0)
Synthesis of the first example of a metal complex containing a Co-ordinated u3(η2-⊥) phospha-alkyne ligand. Addition of an Fe2(CO)6 unit to the η2-phospha-alkyne complex [Pt(ButCP)] (dppe=Ph2PCH2CH2PPh2) (dppe)(ButCP)]: crystal and molecular structure of [Fe2Pt(dppe)(CO)6 (1984) (0)
Preparation, Spectra and X-Ray Structure of an Archetypal Coordination Compound (BCl3(NH3)) and Its Thermolysis. (1995) (0)
Synthesis and characterization of a phosphaalkyne-bridged pentairon carbonyl cluster. Crystal and molecular structure of [{Fe 3 Se 2 (CO) 8 }(.mu.-PCBut){Fe 2 Se(CO) 6 }] (1995) (0)
Synthesis and Characterization of Unusual Tetraaminoalkenes ( Enetetramines). (1992) (0)
Structure of an iridium(I) complex of tris(2,6‐dimethoxyphenyl)phosphine, [Ir(C8H12)(C5H5N)(P{2,6‐(CH3O)2C6H3}3)][PF6] (1993) (0)
Base‐Catalyzed Oxygenation of tert‐Butylated Phenols. Part 2. Formation of 3‐Aryl‐2,5‐di‐tert‐butyl‐2,4‐cyclopentadienones by Base‐Catalyzed Oxygenation of 4‐Aryl‐2,6‐di‐tert‐butylphenols: X‐Ray Structure Determination of 2,5‐Di‐tert‐butyl‐3‐(4‐chlorophenyl)cyclopentadienone. (1978) (0)
Stereochemistry of Epoxidation of Some A-Norandrost-5-enes. (1988) (0)
CCDC 111670: Experimental Crystal Structure Determination (1999) (0)
Use of Phospha-Alkynes RCP in Organometallic Chemistry (1993) (0)
Synthesis of Non‐Proteinogenic Amino Acids with Three Chiral Centres. (1992) (0)
CRYSTAL AND MOLECULAR STRUCTURE OF 10,10-DIMETHYL-3,4-DIOXATRICYCLO(5.2.1.01,5)DECANE-2-SPIRO-2′-ADAMANTANE AND A COMPARISON OF CARBON-OXYGEN AND OXYGEN-OXYGEN BOND LENGTHS IN SMALL RINGS AS A FUNCTION OF RING SIZE (1979) (0)
The Cycloaddition Reaction of 1,3-Diphospha-2,4,5-tri-t- butylcyclopentadiene and 1,2,4-Triphospha-3,5-di-t- butylcyclopentadiene: Crystal and Molecular Structure of the Ethanol Adduct of P5C5But5H2. (1991) (0)
Formation of 3(4→18)-abeo-Aphidicolenes via Cyclopropyl Intermediates. (1986) (0)
Sulfurization Reactions of P5C5tBu5 and P5C5tBu5H2: Crystal and Molecular Structure of the Ethanol Adduct of P5C5tBu5H2S3. (1992) (0)
Neighbouring Group Participation in the Reduction of the Diterpenoid Fujenal. (1987) (0)
Cleavage of an Si-Me Bond by Intramolecular Alkoxide Ion Attack. Crystal Structure of 6,6-Bis(trimethylsilyl)norbornan-endo-2-ol. (1991) (0)
Synthesis of a eta 2-2,3-diphosphabutadiene complex of zerovalent platinum from the corresponding eta 2-phosphaalkyne complex. (2003) (0)
SYNTHESIS OF STABLE FUSED 2,1,4‐OXATHIAZOLIDINES BY A NOVEL AND EFFICIENT PHOTOCHEMICAL REACTION (1983) (0)
Structure of the precursor of an iridium-containing hydrogenation catalyst (1989) (0)
The Chemistry of Trichloro(tris(trimethylsilyl)methyl) and Trichloro(tris(dimethylphenylsilyl)methyl) Complexes of Gallium, Indium, and Thallium. Crystal and Molecular Structures of (Li(thf)2(μ-Cl)2GaCl(C(SiMe2Ph)3))·thf, (Li(thf)3(μ- (1987) (0)
Upon the Hydrogen-Bonding Ability of the H4 and H5 Protons of the Imidazolium Cation. (1990) (0)
REACTION OF THE DINITROGEN COMPLEX (RE(η2-S2PPH2)(N2)(PME2PH)3) WITH METHYL ISOCYANIDE. PREPARATION AND X-RAY STRUCTURE OF THE MIXED DINITROGEN-ISOCYANIDE COMPLEX MER-(RE(η1-S2PPH2)(N2)(CNME)(PME2PH)3) (1983) (0)
The Oxidation of Some Steroidal Dienes by Potassium Permanganate/Copper Sulfate. (1999) (0)
The Oxidation of Some Steroidal Dienes by Potassium Permanganate: Copper Sulfate (1999) (0)
C60F18O, the First Characterized Intramolecular Fullerene Ether. (2000) (0)
Regio- and Site-Selective Cycloadditions. Part 1. The Reaction of Aryl Azides and of Ethyl Diazoacetate with the Bis(trimethylsilyl)polyynes, Me3Si(CC)nSiMe3 (n = 2 or 3). (1988) (0)
Synthesis and structures of dinuclear low-coordinate lithium and zirconium ( IV ) complexes derived from the diamido ligands (2002) (0)
Unusual Oxidative Coupling of 1,2,4-Triphosphacyclopentadienyl and 1,3-Diphosphacyclopentadienyl Anions. Synthesis and Molecular Structure of the Novel Pentaphosphorus Cage Compound P5C5But5 (III). (1990) (0)
NOVEL ALPHA ,OMEGA -BIS(TRIALKYLSILYL)-ALLYL AND 1-AZAPENTADIENYL LIGANDS ; STRUCTURES OF LIETA 3-CH(CHSIME2BUT)2(TMEN), LIN(SIME3)CBUT(CH)3SIME2BUT ( TMEN) AND KETA 4-N(SIME2BUT)CBUT(CH)3SIME2BUT (1996) (0)
COMPLEXES OF ORGANOALUMINUM COMPOUNDS. PART 12. PREPARATION, NUCLEAR MAGNETIC C RESONANCE SPECTRA, AND THE CRYSTAL AND MOLECULAR STRUCTURE OF BIS(μ-ISOPROPYLAMIDODIMETHYLALUMINUM) (1981) (0)
FLUOROPHOSPHINE COMPLEXES OF RHODIUM(I) AND IRIDIUM(I): TOWARDS THE DESIGN OF SYSTEMS WITH EXTENDED METAL-METAL INTERACTIONS. THE CRYSTAL STRUCTURE OF DI-μ-CHLOROBIS(BIS(TRIFLUOROPHOSPHINE)IRIDIUM(I)) (1985) (0)
Interactions Between the Aldehyde and Anhydride Groups in the Diterpenoid Fujenal. (2003) (0)
THE CRYSTAL AND MOLECULAR STRUCTURE OF A VERSATILE BIDENTATE LIGAND: TETRAPHENYLDITHIOIMIDODIPHOSPHINATE, PH2(S)PNHP(S)PH2 (1985) (0)
EFFECT OF N-ARYL SUBSTITUENTS ON THE REACTIVITY OF ELECTRON-RICH OLEFINS AS PRECURSORS OF TRANSITION METAL CARBENE COMPLEXES. THE CRYSTAL AND MOLECULAR STRUCTURE OF NN′N′′N′′′-TETRAPHENYLBIS(1,3-IMIDAZOLIDIN-2-YLIDENE) AND ITS Π-ELECT (1979) (0)
CCDC 607082: Experimental Crystal Structure Determination (2007) (0)
Stereochemistry of Hydroboronation and Osmylation of 3α,5-Cycloandrost-6-en-17-one. (1988) (0)
Conformation of Fujenal, a Seco-ring B ent-Kaurenoid Diterpene. (1986) (0)
Unusual Silylene Reactions with M(II) Compounds (M = Ge, Sn or Pb) (2008) (0)
1,3 Silicon to Silicon Migration of the Methoxy Group in Solvolysis of (Bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane. Crystal Structures of (Ethoxydimethylsilyl)(methoxydiphenylsilyl)bis(trimethylsilyl)methane a (1988) (0)
Synthesis, Characterization, and Crystal Structure of a Tetra(phosphino)ethene Cyclic (Ph-P-CH2-CH2-P(Ph)C=)2. (1989) (0)
CARBENE COMPLEXES. II. STERIC AND CONFOR (1978) (0)
1α-Hydroxyalliacolide, a Sesquiterpenoid Metabolite of Marasmius alliaceus. (1986) (0)
The Stereochemistry of a Rearrangement and Fragmentation Reaction of Ring D of 13-Hydroxygibberellins. (1988) (0)
Synthesis and Structure of the Arsaalkyne Tetramer (AsCtBu)4 and Its Fe(CO)4 Derivative. (1993) (0)
Novel Two-Coordinate Germanium(II) Arylamides: Ge(NHAr)2, ArN(Ge(NHAr)) 2(μ-NAr), and (Ge(μ-NAr))2 (IV), and the X-Ray Structure of (IV) and Sn(NHAr)2 (Ar = C6H2But3-2,4,6). (1991) (0)
The Stereochemistry of Some Reactions at C-16 in Gibberellins: An X-Ray Crystallographic Study of the Methyl Esters of Gibberellin A2 and Gibberellin A9 Hydrochloride. (1987) (0)
SYNTHESES AND MOLECULAR STRUCTURES OF SNETA -C5ME4(SIME2BUT)2 AND FEETA -C5ME4(SIME2BUT)2 (1996) (0)
Synthesis of Substituted Dibenzophospholes. Part 5. Synthesis of Intermediates for 4- and 6-Aryl Substituents. (1987) (0)
Neighboring Group Participation in the Bromination of Methyl Gibberellate: X-Ray Molecular Structure of Methyl 3,13-Di-O-acetylgibberellate 16β,17-Dibromide and ent-3α,13-Diacetoxy-17-bromo-10β,16β-dihydroxy-20-norgibberell-# 1-ene-7, (1988) (0)
Preparation and X‐Ray Characterization of the First Heteroleptic Hydrocarbon‐Soluble Tin(II) Pseudohalide, Sn(NCS)(N(SiMe3)2). (1992) (0)
A 13C NMR Method for Determining the Stereochemistry of the A/B Ring Junction in B-Norsteroids. (1999) (0)
Novel Photochemical Rearrangements of Dihydro-1,3-thiazines. (1998) (0)
Structure and Bonding, Vol. 44: Metal Complexes : edited by M.J. Clarke et., Springer-Verlag, Berlin, 202 pages, DM 98 (1981) (0)
First structural characterisation of a transition metal complex containing a bridging PCR(CO) ligand (R = But). Synthesis, crystal, and molecular structure of [Fe2(CO)5(µ-dppm){µ-η2-PCBut(CO)}](dppm = Ph2PCH2PPh2) (1989) (0)
Adducts of Bis(O,O-alkylene dithiophosphates) of Nickel(II) with 2,9-Dimethyl-1,10-phenanthroline. X-Ray Crystal and Molecular Structure of (2,9-Dimethyl-1,10-phenanthroline)bis(4,4,5,5-tetramethyl-1,3,2-dioxaphospholane-2-thione-2-th (1990) (0)
On the Electronic Structure of Tris(β-diketonato)ruthenium(III) Complexes: A Linear Correlation of Electrochemical Reduction Potentials in Solution with Vertical First Ionisation Energies in the Gas Phase. (1986) (0)
Comparison of the Reactivities of the Compounds (Me3Si)2C(SiMe2OMe)( SiMe2Cl) and (MeOMe2Si)3C(SiMe2Cl). Crystal Structure of (MeOMe2Si) 3CSiPh2H. (1991) (0)
REACTIONS OF THE ALKYLTRIHYDROALUMINATE LI(THF)2AIH3C(SIME3)32. CRYSTAL STRUCTURES OF LI(TMEN)2AIH3C (SIME3)3, AIBR2-C(SIME3)3.THF, AII2C(SIME3)3.THF, LI(THF)2(MU -NHPH)2-AIHC(SIME3)3 AND LI(THF)4AL(NHPH)3C(SIME3)3 (1998) (0)
Structure determination by X-ray crystallography : By M.F.C. Ladd and R.A. Palmer, 2nd edit., Plenum Press, New York and London; xviii + 502 pages, US$39.50, ISBN 0-306-41878-9. (1985) (0)
Synthesis and Structure of 2-Phosphonioallene Complexes. (1991) (0)
The Formation of Unsaturated Diterpenoid Alcohols from 1,4-Glycols with N,N-Dimethylformamide Dimethyl Acetal (II). (1990) (0)
First Examples of Complexes Containing η1-Bonded Phosphaalkynes Synthesis and Crystal and Molecular Structure of trans-(Mo(Ad-CP)2(Et2P-(CH2)2-PEt2)2) (Ad: Adamantyl). (1987) (0)
Preparation and X‐Ray Structure of (Ge(N(SiMe3)2)2(μ‐O))2, a Rare 1, 3‐Cyclodigermoxane (1993) (0)
METALLOCENE DERIVATIVES OF EARLY TRANSITION ELEMENTS. PART 1. NIOBIUM(IV) CHLORIDES, CHLOROALKYLS, AND DIALKYLS (NB(η-C5H4X)2RR′), AND THE CRYSTAL AND MOLECULAR STRUCTURE OF (NB(η-C5H5)2(CH2PH)2) (1981) (0)
Synthesis and Properties of Chlorotris (1,3-Dibenzylimidazolidin-2-ylidene) Rhodium (I) and of Some Related Compounds (1989) (0)
CCDC 819595: Experimental Crystal Structure Determination (2011) (0)
The Westphalen Rearrangement of a Tricyclic Steroid. (2003) (0)
threo‐1,2‐Dibromo‐1‐triphenylsilyl‐2‐phenylethane (1978) (0)
Erratum to “Ligating similarities between the novel five-electron-donor η4-P3C2But2(R)H ring system, (RCH(SiMe3)2) and the η5-cyclopentadienyl ring. Syntheses, crystal and molecular structures of [Co2(Co)5(μ-P3C2But2CH(SiMe3)2] and [Co(Co)2(η4-P3C2But2H(CH(SiMe3)2]”: [Journal of Organometallic Chemi (2002) (0)
Neighboring-Group Participation in the Chromium Trioxide Oxidation of Steroidal 4,5-Epoxides. X-Ray Molecular Structure of 4β,6β, 17β-Triacetoxy-3β,5α-dihydroxyandrostane. (1991) (0)
The stereochemistry of the Grignard reaction of some boat ring ketones in the diterpenoids (2004) (0)
Synthesis and X-Ray Crystal and Molecular Structure of 1,6-Bis(3- thienyl)hexane. (1997) (0)
COMPLEXES OF ORGANOALUMINUM COMPOUNDS. PART IX. CRYSTAL AND MOLECULAR STRUCTURE OF HEPTA-μ3-METHYLIMIDO-HEPTAKIS(METHYLALUMINUM) A CAGE COMPOUND IN THE SERIES OF OLIGOMERS (R1XYR2)N (1976) (0)
Aggregation behaviour of thallium(I) beta-diketiminates. (2006) (0)
Preparation of Androstanes Related to Aphidicolin. (2008) (0)
SYNTHESIS, PROPERTIES, AND X-RAY CRYSTAL STRUCTURE OF TRANS-DICHLOROTETRAKIS(1,3-DIETHYLIMIDAZOLIDIN-2-YLIDENE)RUTHENIUM(II), A NEUTRAL TETRACARBENEMETAL COMPLEX (1976) (0)
Bromination of Some B‐Norandrost‐5‐enes. X‐Ray Molecular Structure of 17β‐Acetoxy‐4β,6α‐dibromo‐5β‐methyl‐7,19‐ dinorandrost‐9(10)‐ene (1991) (0)
Synthesis and Crystal Structure of the Crowded Disiloxane (((Me3Si)3C) Cl2Si)2O. (1991) (0)
The Structure of Albidin - an X-Ray Crystallographic Study. (1986) (0)
CARBENE COMPLEXES PART 6, COMPLEXES FROM IMIDOYL CHLORIDE AND RHODIUM(I) PRECURSORS, AND THE CRYSTAL AND MOLECULAR STRUCTURE OF CARBONYLTRI-IODO-(ALPHA-(N-METHYL-ALPHA-METHYLIMINOBENZYLAMINO)BENZYLIDENE-N,C)RHODIUM (1974) (0)
Synthesis, Crystal Structure and Reactions of the Dimeric Organolithium Compound ((((MeO)Me2Si)3CLi)2). (1992) (0)
Migration of the Methoxy Group in an Organosilicon Cation. Reactions of (Bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane with Silver Borofluoride and Silver Chloride. Crystal Structure of (Chlorodiphenylsilyl)(meth (1987) (0)
THE FIRST MONONUCLEAR ETA 8-COORDINATED PENTALENE COMPLEX : SYNTHESIS AND MOLECULAR STRUCTURE OF TAETA 8-C8H4(SIME3)2-1,4CL3 (1997) (0)
FIVE-COORDINATE COBALT(III)- CRYSTAL AND MOLECULAR STRUCTURE OF CORROLE(TRIPHENYLPHOSPHINE)COBALT(III) (1977) (0)
C1 C70F38 Contains Four Planar Aromatic Hexagons: The Parallel Between Fluorination of [60]‐ and [70]Fullerenes. (2005) (0)
Novel Hexamer of tBuCP: Synthesis, Structure, and Theoretical Studies (1995) (0)
SYNTHESES AND STRUCTURAL CHARACTERISATION OF IR4(CO)11(ETA 1-L) AND IR4(CO)10(ETA 1-L)2 L = FE(ETA 5-P3C2BUT2)(ETA 5-P2C3BUT3) AND FE(ETA 5-C5H5)(ETA 5-P3C2BUT2) AND IR4(CO)11MU -ETA 1:ETA 1-FE(ETA 5-C5H5)(ETA 5-P3C2BUT2)IR4( CO)11 AND ITS FACILE CONVERSION TO IR4H(CO)10FE(ETA 5-C5H5)ETA 5-P3C(CME2C (1996) (0)
Unusual Kinetically Stable Dialkyltin(IV) Oxides. X‐Ray Structures of ( (SnR2(μ‐O))2) and ((SnR2(OH))2(μ‐O)) (R = CH(SiMe3)2). (1991) (0)
Preparation and Crystal Structures of the Crowded Triorganotin Isothiocyanate (PhMe2Si)3CSnMe2NCS and Nitrate (PhMe2Si)3CSnMe2ONO2. (2010) (0)
Interaction of Metal Bis(Phosphane) Fragments with Phosphirene and Phosphirane Complexes (1987) (0)
The Influence of a 15‐Hydroxy Group on the Rearrangement Reactions of Steviol and Its 16,17‐Epoxide. (1991) (0)
β-diketiminates of some main group elements : New structural motifs (2006) (0)
Preparation and X-Ray Crystal Structure of an Unusual Bicyclic Trisilane-tris(disiloxane). (1988) (0)
COMPLEXES OF ORGANOALUMINUM COMPOUNDS. PART 11. NITRIC OXIDE COMPLEXES OF TRIMETHYLALUMINUM AND -GALLIUM AND THE CRYSTAL AND MOLECULAR STRUCTURE OF ((N-METHYL-N-(NITROSO-O′)HYDROXYLAMIDO-O)DIMETHYLALUMINUM-O′)TRIMETHYLALUMINUM (1981) (0)
Boat Forms of Ring A in B-Norsteroids. (2010) (0)
Synthetic, Structural and Spectroscopic Studies of Heteronuclear (Oxo)alkoxides as Precursors for Mixed Metal Oxides (2007) (0)
Theory and practice of direct methods in crstallography : M.F.C. Ladd R.J. Palmer (Editors), Plenum Press, New York and London, 1980, xiv + 411 pages, $35.00. (1980) (0)
Erratum to “Synthesis of the dicarbonyl ruthenium(0) triphosphole complex [Ru(Co)2{η5-P3C2But2CH(SiMe3)2}] and its conversion into a triphosphorus-ring system {CButPP(H)CH(SiMe3)2CButP(O)H}”: [Journal of Organometallic Chemistry 584 (1999) 58–62 (2002) (0)
Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium beta-diketiminates. (2004) (0)
THE CHEMISTRY OF 1-AZA-ALLYL- AND BETA -DIKETIMINATO-METAL COMPLEXES: A REVIEW (1996) (0)
Phosphorus Compounds. Part 91. Tetraphosphatricyclo(4.2.0.02,5) octadienes. New Phosphaalkyne Cyclotetramers Derived from λ3. sigma.2-Diphosphetes. (1995) (0)
CCDC 609100: Experimental Crystal Structure Determination (2006) (0)
A η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular strunctures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPH)-W(CO)5], dppe=1,2-bis (1989) (0)
Coupling of Two Phosphaalkynes via a Carbonyl Group in the Addition Across a Rh=Rh Double Bond. (1991) (0)
Insertion Reactions of the Stable Silylene Si[(NCH2tBu)2C6H4‐1,2] (2008) (0)
Alkylpalladium N‐Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties. (2009) (0)
Butyl Metal Aryloxides, Arylamides, and Sulfur and Phosphorus Analogues. Part 2. Synthesis and Characterization of Novel Bulky Alkoxides and Aryloxides of Aluminum; X-Ray Structure of (Al(μ-OCH2Ar)Me2)2 (Ar = C6H2tBu3-2,4,6). (1990) (0)
STRUCTURES OF THE CEPHALOSPOROLIDES B-F, A GROUP OF C10 LACTONES FROM CEPHALOSPORIUM APHIDICOLA (1985) (0)
Structure of a Chiral Iridium Bis(phosphine)-Diene Complex (I), a Catalyst for Homogeneous Hydrogenation. (1991) (0)
Hydrolysis of 3,10-Epoxypatchenol under Mild Aqueous Conditions. (2005) (0)
The Hydroboration of Steroidal Vinyl Halides. (2003) (0)
Formation of a Tetrazole from (PhMe2Si)3CSiMe2I. Crystal Structure of Cyclic (PhMe2Si)3CSiMe2N-N=C(Me)-N=N. (1988) (0)
Preparation and X‐Ray Crystal Structure of a Carbamoylsilane. (1991) (0)
Double Stereodifferentiation in Aldol Reactions on Protected Pyroglutamate Esters. (2001) (0)
Synthesis of Galbonolide B (2008) (0)
Complexes of Organoaluminium Compounds. Part l0. Crystal and Molecular Structures of the Cage Compounds Bis-μ-methylamido-hexa-μ3 -methylimido-bis(dimethylaluminium)-hexakis(methylaluminium) and Bis-μ-methylamido-hexa-μ3-methylimido-b (1979) (0)
Hexyltris(2,4,6-trimethoxyphenyl)-phosphonium iodide (1995) (0)
Novel Tris(trimethylsilyl)methylboron Compounds. Crystal Structures of the Diborane ((Me3Si)3C)HB (μ-H)2BH(C(SiMe3)3) and the Bis(aminoboryl)amine ((Me3Si)3C(NH2)B)2NH. (1990) (0)
Synthesis of Cyclopropa(d)thiazolines by a Novel and Efficient Photochemical Rearrangement of 1,3‐Thiazines. (1993) (0)
Synthesis of α‐Amino Esters by Dynamic Kinetic Resolution of α‐Haloacyl Imidazolidinones. (2001) (0)
Absolute Configuration of (+)-Ethambutol Hydrobromide. (1992) (0)
Sodium and potassium 3-sila-beta-diketiminates show new coordination modes. (2002) (0)
Synthesis, Structure, and Reactions of the First Homoleptic Lithium- Arsenic Compound, (Li(μ-AsR2))3 (R: CH(SiMe3)2). (1987) (0)
The Reaction of Some Substituted 2α,3α‐Epoxy‐5α‐ hydroxyandrostanes with Hydrogen Bromide in Acetic Acid. (1991) (0)
Metabolic Products of Fusarium acuminatum: Acuminatopyrone and Chlamydosporol. (1991) (0)
The synthesis and X-ray structures of ytterbocene(II) complexes containing pendant pyridyl groups, [Yb(CP (2010) (0)
Synthesis, Crystal and Molecular Structures of the Novel, Structurally Different, Cage Compounds P6C4tBu4SiI2 and P6C4tBu4GeI2, Resulting from intra‐Molecular Coupling of Two 1,2,4‐Triphospholyl Rings. (2000) (0)
THE ABSOLUTE CONFIGURATION OF THE OPTICALLY-ACTIVE SILYL-PLATINUM COMPLEX (+)-TRANS-(PTCL SI(CH3)(1-C10H7)C6H5 (P(CH3)2C6H5)2) (1973) (0)
Studies on the Base‐Catalyzed Addition of Amines to Alkynes and Allenes: A Novel Cascade Sequence for the Construction of Spirocyclic Aminals. (2006) (0)
The crystal structure of the organosilicon p-toluenesulfonate (Me3Si)3CSiPh(H)(OSO2C6H4Me-p) (1993) (0)
RAPID HOMOGENEOUS HYDROGENATION OF IMINES CATALYSED BY IRIDIUM COMPLEXES OF CHELATING BIPHOSPHINES (1996) (0)
Substituted Triazines and Pyrimidines from 1,3,5‐Triazine and a Lithium Amidinate, Alkyl‐ or 1‐Azaallyl. (2001) (0)
Structure of a Novel Iridium-Containing Hydrogenation Catalyst. (1989) (0)
The Chlorination of Some Androst-4-en-3-ones by Sulfuryl Chloride. (1991) (0)
Some Reactions of the Ethylenebis(phenylphosphido)dilithium Reagent ((Li(THF)2)2(PhPCH2CH2PPh))2, and Its X-Ray Structure. (1988) (0)
Stannadesulfurization of a Bis(dimethyldithiocarbamato)tungsten(II) Complex: Formation of a Coordinated Me2NCCNMe2 Complex. (1990) (0)
The Stereochemistry and Hydrolysis of Gibberellin 16,17-Epoxides. X-Ray Molecular Structures of ent-17-Acetoxy-1α,10α-epoxy-2β,3α,13,16β-tetrahydro# xy-20-norgibberella-7,19-dioic Acid 19,2-Lactone 7-Methyl Ester (IV) and of ent-17-Ch (1989) (0)
The Thermally Stable Silylene Si[(NCH2But) 2C6H4‐1,2]: Reaction with Pyridine and Quinoline (2004) (0)
Biotransformation of ent-16β,19-Dihydroxykaurane by Cephalosporium aphidicola. (1996) (0)
The Aromaticity of Highly Fluorinated Derivatives of [70]Fullerene (2006) (0)
HYDRAZIDO(2-) COMPLEXES OF TUNGSTEN(V) AND -(VI) AND A BIS(DIAZENIDO) COMPLEX OF TUNGSTEN(IV). X-RAY CRYSTAL STRUCTURE OF CIS-TRICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)HYDRAZIDOTUNGSTEN(V) (1982) (0)
Synthesis of 1,3-Thiazetidines and 2,1,4-Oxathiazolidines by High Yielding Novel Photochemical Rearrangements. (1992) (0)
The Cyclization of Humulene 6,7‐ and 9,10‐Epoxides Catalyzed by Tetracyanoethylene (2006) (0)

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