Philip Eaton
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American organic chemist
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Philip Eatonchemistry Degrees
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Chemistry
Philip Eaton's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Philip Eaton Influential?
(Suggest an Edit or Addition)According to Wikipedia, Philip E. Eaton was an American chemist. He served as Professor Emeritus of Chemistry at the University of Chicago. Eaton and his fellow researchers were the first to synthesize the "impossible" cubane molecule in 1964.
Philip Eaton's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Phosphorus pentoxide-methanesulfonic acid. Convenient alternative to polyphosphoric acid (1973) (404)
- The Cubane System (1964) (295)
- Cubanes : starting materials for the chemistry of the 1990s and the new century (1992) (243)
- ACCELERATION OF THE DIELS-ALDER REACTION BY ALUMINUM CHLORIDE (1960) (239)
- Catalysis of symmetry-restricted reactions by transition metal compounds. Valence isomerization of cubane (1970) (171)
- Magnesium amide bases and amido-Grignards. 1. Ortho magnesiation (1989) (139)
- Polynitrocubanes: Advanced High-Density, High-Energy Materials** (2000) (135)
- Photochemical reactions of simple alicyclic enones (1968) (114)
- Octanitrocubane: A New Nitrocarbon (2002) (102)
- The Tricyclo[5.3.0.02,6]decane System. The Photodimers of Cyclopentenone (1962) (91)
- Silver(I)- and palladium(II)-catalyzed isomerizations of cubane. Synthesis and characterization of cuneane (1970) (78)
- Synthesis of 1,4-dinitrocubane (1984) (73)
- On the Mechanism of the Photodimerization of Cyclopentenone (1962) (69)
- Systematic substitution on the cubane nucleus. Synthesis and properties of 1,3,5-trinitrocubane and 1,3,5,7-tetranitrocubane (1993) (65)
- Synthesis of peristylane and the acs-(Cs)-C14-tetraquinane, C14-pentaquinane, and norperistylane systems (1977) (61)
- The synthesis of pentaprismane (1986) (60)
- REGIOCHEMICAL VARIATIONS IN REACTIONS OF METHYLCUBANE WITH TERT-BUTOXYL RADICAL, CYTOCHROME P-450 ENZYMES, AND A METHANE MONOOXYGENASE SYSTEM (1996) (60)
- Synthesis of homopentaprismane and homohypostrophene and some comments on the mechanism of metal ion catalyzed rearrangements of polycyclic compounds (1976) (58)
- Cubene (1,2-dehydrocubane) (1988) (56)
- X-ray structures of cubylcubane and 2-tert-butylcubylcubane: short cage-cage bonds (1988) (56)
- BuMgNiPr2: a new base for stoichiometric, position-selective deprotonation of cyclopropane carboxamides and other weak CH acids. (2002) (54)
- Conversion of isocyanates to nitro compounds with dimethyldioxirane in wet acetone (1988) (51)
- A Computational Study of the Interactions among the Nitro Groups in Octanitrocubane (2001) (50)
- [2.2.2]Propellane system (1973) (49)
- trans-2-Cycloheptenone1 (1965) (48)
- Synthesis and Chemistry of 1,3,5,7-Tetranitrocubane Including Measurement of Its Acidity, Formation of o-Nitro Anions, and the First Preparations of Pentanitrocubane and Hexanitrocubane1 (1997) (48)
- Alkynylcubanes as Precursors of Rigid-Rod Molecules and Alkynylcyclooctatetraenes (1994) (47)
- LiCB(11)Me(12): a catalyst for pericyclic rearrangements. (2001) (47)
- The Electronic Structure of Cubane (C8H8) as Revealed by Photoelectron Spectroscopy (1978) (46)
- Systematic substitution on the cubane nucleus. Amide activation for metalation of "saturated" systems (1985) (45)
- Building with Cubane-1,4-diyl. Synthesis of Aryl-Substituted Cubanes, p-[n]Cubyls, and Cubane-Separated Bis(arenes)1 (1999) (44)
- NITRATION OF ORGANOLITHIUMS AND GRIGNARDS WITH DINITROGEN TETROXIDE : SUCCESS AT MELTING INTERFACES (1997) (42)
- trans-2-Cyclooctenone (1964) (41)
- The rearrangement of 4,5,6,7-tetrachloro-3a,4,7,7a-tetrahydro-4,7-methanoiden-8-one☆ (1961) (41)
- Bond lengths and quadratic force field for cubane (1991) (40)
- Long-distance electron transfer through rodlike molecules with cubyl spacers (1993) (40)
- Unusual Structure, Phase Transition, and Dynamics of Solid Cubane (1997) (40)
- Octahydro- and perhydro[0.0]paracyclophane (1978) (36)
- The preparation and fate of cubylcarbinyl radicals (1991) (36)
- [4.2.2]- and [3.2.2]Propellanes (1971) (35)
- Solid cubane: A brief review (1998) (34)
- Orientational disorder in solid cubane: a thermodynamic and carbon-13 NMR study. (1992) (33)
- Photodimerization of Cyclopentenone. Singlet or Triplet?1 (1966) (31)
- Barton Decarboxylation of Cubane-1,4-dicarboxylic Acid: Optimized Procedures for Cubanecarboxylic Acid and Cubane (1995) (31)
- Transmetalation and reverse transmetalation on ortho-activated aromatic compounds: a direct route to o,o'-disubstituted benzenes (1988) (31)
- Neutron-scattering investigation of molecular reorientations in solid cubane (1999) (30)
- Through-space amide activation of carbon-hydrogen bonds in triangulanes (1993) (30)
- 9-Phenyl-1(9)-homocubene, probably the most twisted olefin yet known, and the carbene 1-phenyl-9-homocubylidene, its rearrangement product (1987) (29)
- cis, syn, cis-Tricyclo[6.3.0.03,7]undecane ketones (1976) (29)
- Selective oxidation of tertiary-secondary vic-diols to α-hydroxy ketones by dioxiranes (1993) (29)
- DIMERIZATION OF CUBENE. 1-IODOADAMANTANE AS A PROBE FOR RADICAL INTERMEDIATES (1995) (29)
- Inactivation of monoamine oxidase by (aminomethyl)cubane. First evidence for an .alpha.-amino radical during enzyme catalysis (1993) (28)
- The reactions of 1,4-dihalocubanes with organolithiums. The case for 1,4-cubadiyl (1990) (28)
- Cubyl Anion Formation and an Experimental Determination of the Acidity and C−H Bond Dissociation Energy of Cubane (1997) (27)
- Reverse transmetalation: a strategy for obtaining certain otherwise difficultly accessible organometallics (1987) (26)
- Synthesis of zinc, cadmium, tin, and silicon derivatives of cubane (1987) (24)
- Amide activation for cyclopropane ortho lithiation (1987) (24)
- The geometries of pentaprismane and hexaprismane insights from molecular mechanics (1983) (24)
- Cyclopentannulation of bicyclo[3.3.0]octane-3,7-dione. A more convenient synthesis of the [5]peristylane system (1984) (23)
- Synthesis of iodocubanes by decarboxylative iodination (1989) (21)
- Picosecond radical kinetics. Bond cleavage of the cubylcarbinyl radical (1992) (21)
- Long-range steric effects in rhodium(I) cleavages of secopentaprismanes. A reversible rhodium(I)-mediated cyclobutane-diolefin conversion (1978) (20)
- Tricyclo[4.2.2.01,6]decane-tricyclo[4.2.2.01,5]decane interconversions. [4.2.2]propellane rearrangements and a nonphotochemical propellane synthesis (1980) (20)
- The nature of the cubyl cation (1992) (19)
- Oxidation of 1-methylcyclobutene by metal ions (1971) (19)
- Formation of the Radical Anion of Cubene and Determination of the Heat of Formation, Heat of Hydrogenation, and Olefin Strain Energy of Cubene (1994) (19)
- Resolution of trishomocubanone: the enantiomeric (D3)-trishomocubanes (1978) (18)
- Direct radical substitution on the cubane skeleton (1990) (18)
- Automerization of homocubylidene : proof of a reversible olefin/carbene rearrangement (1990) (18)
- Systematic substitution on the cubane nucleus: steric and electronic effects (1992) (17)
- Oxidative deiodination of cubyl iodides: A tactic for the nucleophilic introduction of substituents onto the cubane framework (1986) (17)
- Synthesis of alkynylcyclooctatetraenes and alkynylcubanes (1991) (17)
- Regiospecific oxidation of binor S and acid-catalyzed rearrangement of the product to the first example of a pentacyclo[6.6.0.05,14.07,12.09,13]tetradecane (1990) (16)
- Synthesis of Methylcubane and Cyclopropylcubane. The Cubane-1,4-diyl Route (1995) (16)
- Toward tricyclo[2.2.2.2]decane. 1. [n.2.2.2]Paddlane systems, n = 10-14 (1983) (16)
- Conjugated acetylenic ketones. 2-Cyclooctynone (1967) (15)
- Methodologies for 2-alkylidene-1,3-cyclopentanediones (1984) (15)
- Cubanourea : a cubane-propellane (1990) (14)
- Photocondensation reactions of unsaturated ketones (1964) (14)
- 4-substituted cubylcarbinylamines: a new class of mechanism-based monoamine oxidase B inactivators. (1997) (14)
- Synthesis of dodecahedrane precursors. 3. Synthesis of alkylidene-1,3-cyclopentanediones and attempts to roof peristylanes (1984) (14)
- Peristylenones and norperistylenones: highly reactive intermediates. Synthesis of dodecahedrane precursors. Part 2 (1979) (14)
- Isomerizations in the dicyclopentadiene series (1960) (13)
- Hydrogen bromide cleavage of cubane-1,4-dicarboxylic acid. Easy entry into the nortwistbrendane(ene) system (1990) (13)
- Oxyfunctionalization of non-natural targets by dioxiranes. 6. On the selective hydroxylation of cubane. (2009) (13)
- Bridgehead Functionalization of Non‐Enolizable Ketones: The First Preparatively Useful Methods (1994) (13)
- Anions Stabilized by β‐Nitro Groups: The Acidity and ortho‐Metalation of Nitrocubanes—Penta‐ and Hexanitrocubanes (1996) (12)
- Azidocubanes; 2. Acid-Induced Rearrangement: Formation of 9-Azahomocubanes1 (1990) (12)
- Regiospecific Functionalization of Binor S by A Gif Type Oxidation System (1991) (12)
- Trishomocubanone (pentacyclo[6,3,0,02,6,03,10,05,9]undecan-4-one) (1974) (12)
- The Bent Bonds of Cubane (2017) (11)
- Vibrations of the cubane molecule: inelastic neutron scattering study and theory (1999) (11)
- Photolysis of cubyl iodides: access to the cubyl cation (1989) (11)
- The mechanism of the olefin-to-carbene rearrangement for 9-phenyl-1(9)-homocubene (1990) (11)
- Azidocubanes. 1. Photolysis: formation of a homoprismyl nitrile (1987) (11)
- A new approach to substituted cyclobutanes: Direct β-deprotonation/ magnesiation of cyclobutane carboxamides (2003) (11)
- The Electronic Structure of Pentaprismane (C10H10), as Revealed by its Photoelectron Spectrum (1982) (11)
- NEUTRON SCATTERING STUDY OF THE LATTICE MODES OF SOLID CUBANE (1995) (10)
- A new approach to all—cis triquinane synthesis and a new route to the C16—hexaquinane system (1981) (10)
- On the Discovery of Direct Ortho-Magnesiation (1991) (10)
- Kinetic Acidity of Cubane. (1991) (9)
- Rhodium(I)-catalysed isomerization of cyclobutane cage compounds: synthesis of cis,syn,cis-tricyclo[5,3,0,02,6]deca-4,8-diene-3,10-dione and of exo-dicyclopentadienone (1970) (9)
- Notes- Pyrolysis of the Cage Ketone C10Cl10O (1960) (9)
- Cubane radical cation in liquid hydrocarbons: Time-resolved fluorescence detected magnetic resonance study (1991) (9)
- Direct Metalation of 1,3,5,7-Tetranitrocubane with Amides of Tin and Lead. Preparation and Chemistry of o-Nitrostannanes and o-Nitroplumbanes in the Cubyl Series(1). (1997) (8)
- Isomerization of the cubane radical cation to the bridged 1,4-bishomobenzene (bicyclo[3.3.0]octa-2,6-diene-4,8-diyl) radical cation (1990) (8)
- 1,7-Cyclobutanonorbornane system (1984) (8)
- Aza-analogues of cage compounds: Potential precursors to azacubanes and 1-azahomocubanes† (1993) (7)
- Photochemical rearrangement of cis,anti,cis-tricyclo[5,3,0,02,6]deca-4,9-diene-3,8-dione: a new approach to cubane precursors (1970) (7)
- PHOSPHORUS PENTOXIDE-METHANESULFONIC ACID, A CONVENIENT ALTERNATIVE TO POLYPHOSPHORIC ACID (1974) (7)
- Improved Syntheses of 2-Hydroxymethylenecyclopentanone (2-Formylcyclopentanone) and Spiro[4.5]dec-6-en-1,8-dione (1983) (6)
- Lewis acid-induced rearrangement of the Diels–Alder dimer of tetrachlorocyclopentadienone: structure reassignments (2002) (6)
- Cubanes: Starting Materials for the Chemistry of the 1990s and the New Century (1993) (5)
- An Improved Preparation of 9-Oxabicyclo[3.3.1]nona-2,6-diene (1990) (5)
- Structures of the [n.2.2]propellanes. I (1974) (5)
- Time-dependent mass spectra and breakdown graphs. III. The cubane cation; complete or partial instability? (1983) (5)
- Azidocarbonyl‐substituted cubanoureas (1993) (4)
- Additions and Corrections - Pentaprismane (1981) (4)
- Systematic Substitution on the Cubane Nucleus. Synthesis and Properties of 1,3,5‐Trinitrocubane and 1,3,5,7‐Tetranitrocubane. (1994) (4)
- Synthesis and Chemistry of 1,3,5,7‐Tetranitrocubane Including Measurement of Its Acidity, Formation of o‐Nitro Anions, and the First Preparations of Pentanitrocubane and Hexanitrocubane. (1998) (4)
- LiCB11Me12: A Catalyst for Pericyclic Rearrangements. (2001) (4)
- On the reaction of sodium methoxide with perbromo-D2h-bishomocubane. A structural reassignment. (2001) (4)
- Synthesis of Methylcubane and Cyclopropylcubane. The Cubane-1,4-diyl Route. (2010) (4)
- Barton Decarboxylation of Cubane-1,4-dicarboxylic Acid: Optimized Procedures for Cubanecarboxylic Acid and Cubane. (1995) (3)
- Stable Tin and Lead Derivatives of Nitrocubanes: Their Formation and Use in Multiple Functionalization (1996) (3)
- ANNULATED CYCLOPENTADIENONE KETALS. A ROUTE TO 1,2-BRIDGED NORBORNENES (1976) (3)
- Azidocarbonyl-Substituted Cubanoureas. (1994) (1)
- Azidocubanes. Part 2. Acid-Induced Rearrangement: Formation of 9- Azahomocubanes. (1991) (1)
- X-ray structures of cubylcubane and 2-tert-butylcubylcubane: short cage-cage bonds [Erratum to document cited in CA109(18):161024v] (1989) (1)
- Aza‐Analogues of Cage Compounds: Potential Precursors to Azacubanes and 1‐Azahomocubanes. (1994) (1)
- TRISHOMOCUBANONE (PENTACYCLO(6,3,0,0(2,6),0(3,10),0(5,9))UNDECAN‐4‐ONE) (1975) (1)
- Fluxionality Induced by High Pressure: [9‐D]9‐Homocubyl Triflate, a Pressure‐Sensing Molecule (1995) (1)
- Cubanourea: A Cubane-Propellane. (1991) (1)
- Synthesis Of Cubane Based High Energy Materials (1988) (1)
- Picosecond Radical Kinetics. Bond Cleavage of the Cubylcarbinyl Radical. (1992) (1)
- Energetic Materials from Cubane. (1993) (0)
- cis,syn,cis-2,3,4,8,9-Pentachloro-1,5,7,7-tetramethoxytricyclo[4.3.0.02,5]nona-3,8-diene (2002) (0)
- Systematic Substitution on the Cubane Nucleus: Steric and Electronic Effects. (1992) (0)
- Selective Oxidation of Tertiary-Secondary vic-Diols (I), (III), (V), ( VII) to α-Hydroxy Ketones (II), (IV), (VI), (VIII) by Dioxiranes. (1993) (0)
- SYSTEMATIC SUBSTITUTION ON THE CUBANE NUCLEUS. AMIDE ACTIVATION FOR METALATION OF “SATURATED” SYSTEMS (1985) (0)
- Direct Radical Substitution on the Cubane Skeleton. (1990) (0)
- IMPROVED SYNTHESES OF 2-HYDROXYMETHYLENECYCLOPENTANONE (2-FORMYLCYCLOPENTANONE) AND SPIRO(4.5)DEC-6-ENE-1,8-DIONE (1984) (0)
- Direct Metalation of 1,3,5,7-Tetranitrocubane with Amides of Tin and Lead. Preparation and Chemistry of o-Nitrostannanes and o-Nitroplumbanes in the Cubyl Series. (1998) (0)
- Photolysis of Cubyl Iodides: Access to the Cubyl Cation. (1989) (0)
- First, Second and Third Generation High Energy Materials from Cubane (1992) (0)
- 1,2,4,5,6,7,8,9-Octachlorotricyclo[5.2.1.02,6]deca-4,8-diene-3,10-diol (2002) (0)
- Bis(1-bromo-9-chlorohomocub-9-yl) ether (2002) (0)
- OX. VON 1-METHYLCYCLOBUTEN DURCH METALLIONEN (1971) (0)
- Synthesis of Zinc, Cadmium, Tin, and Silicon Derivatives of Cubane. (1987) (0)
- Synthesis of Alkynylcyclooctatetraenes and Alkynylcubanes. (1992) (0)
- X-Ray Structures of Cubylcubane (Ia) and 2-tert.-Butylcubylcubane (Ib): Short Cage-Cage Bonds (1989) (0)
- 1-Azahomocubane (2023) (0)
- 9-Phenyl-1(9)-homocubene, Probably the Most Twisted Olefin Yet Known, and the Carbene 1-Phenyl-9-homocubylidene, Its Rearrangement Product. (1987) (0)
- A NEW APPROACH TO ALL-CIS TRIQUINANE SYNTHESIS AND A NEW ROUTE TO THE C16-HEXAQUINANE SYSTEM (1982) (0)
- Magnesium Amide Bases and Amido-Grignards. Part 1. Ortho Magnesiation. (1990) (0)
- Conversion of Isocyanates to Nitro Compounds with Dimethyldioxirane in Wet Acetone. (1989) (0)
- The crystal and molecular structure of pentaprismane carboxylic acid, C11H10O2 (1982) (0)
- Synthesis of Iodocubanes by Decarboxylative Iodination. (1990) (0)
- STRUCTURES OF THE (N.2.2)PROPELLANES PART 1, 2‐HYDROXY(4.2.2)PROPELLANE P‐NITROBENZOATE (1975) (0)
- Oxidative Deiodination of Cubyl Iodides: A Tactic for the Nucleophilic Introduction of Substituents onto the Cubane Framework. (1987) (0)
- Regiospecific Oxidation of Binor S and Acid-Catalyzed Rearrangement of the Products to the First Example of a Pentacyclo(6.6.0.05,14.07,12.09, 13)tetradecane. (1991) (0)
- Cubanes: intra- and supramolecular trends (1996) (0)
- Bond Lengths and Quadratic Force Field for Cubane. (1991) (0)
- Through‐Space Amide Activation of C‐H Bonds in Triangulanes. (1994) (0)
- Amide Activation for Cyclopropane Ortho-Lithiation. (1987) (0)
- The Reactions of 1,4-Dihalocubanes with Organolithiums. The Case for 1,4-Cubadiyl. (1990) (0)
- Reverse Transmetalation: A Strategy for Obtaining Certain Otherwise Difficultly Accessible Organometallics. (1987) (0)
- Photolysis of cubyl iodides: access to the cubyl cation [Erratum to document cited in CA110(9):74904j] (1989) (0)
- RESOLUTION OF TRISHOMOCUBANONE- THE ENANTIOMERIC (D3)-TRISHOMOCUBANES (1978) (0)
- Transmetalation and Reverse Transmetalation on Ortho‐Activated Aromatic Compounds: A Direct Route to o,o′‐Disubstituted Benzenes. (1988) (0)
- Cubyl cation. [Erratum to document cited in CA112(19):177967c] (1992) (0)
- Cubene (1,2-Dehydrocubane). (1989) (0)
- An Improved Preparation of 9-Oxabicyclo(3.3.1)nona-2,6-diene. (1990) (0)
- Synthesis of Pentaprismane (VII). (1986) (0)
- CYCLOPENTANNULATION OF BICYCLO(3.3.0)OCTANE-3,7-DIONE. A MORE CONVENIENT SYNTHESIS OF THE (5)PERISTYLANE SYSTEM (1984) (0)
- On the Nature of Cubyl Cation. (1992) (0)
- Isomerization of the Cubane Radical Cation (II) to the Bridged 1,4-Bishomobenzene (Bicyclo(3.3.0)octa-2,6-diene-4,8-diyl) Radical Cation (IV). (1990) (0)
- The Preparation and Fate of Cubylcarbinyl Radicals. (1992) (0)
- Automerization of Homocubylidene: Proof of a Reversible Olefin/Carbene Rearrangement. (1990) (0)
- Azidocubanes. Part 1. Photolysis: Formation of a Homoprismyl Nitrile. (1987) (0)
- THE (2.2.2)PROPELLANE SYSTEM (1974) (0)
- HBr Cleavage of Cubane-1,4-dicarboxylic Acid. Easy Entry into the Nortwistbrendane(ene) System. (1990) (0)
- 3A.2 APPLICATIONS OF EATON’S REAGENT (2005) (0)
- Interconversion of the Tetracyclo[6.3.0.0 4,11 .0 5,9 ]undeca-2,6-diene and Tetracyclo-[7.2.0.0 4,11 .0 6,10 ]undeca-2,7-diene Ring Systems (1993) (0)
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