Philip L. Fuchs

Philip L. Fuchs's AcademicInfluence.com Rankings

Philip L. Fuchs

Chemistry

#3355

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#4370

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Organic Chemistry

#527

World Rank

#609

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chemistry Degrees

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Chemistry

Philip L. Fuchs's Degrees

Bachelors Chemistry Stanford University

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Philip L. Fuchs's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′) (1972) (949)
Evolving organic synthesis fostered by the pluripotent phenylsulfone moiety. (2009) (249)
Design and synthesis of [111In]DTPA-folate for use as a tumor-targeted radiopharmaceutical. (1997) (201)
Improved aldehyde synthesis from 1,3-dithianes (1971) (158)
Alkynylation of C−H Bonds via Reaction with Acetylenic Triflones1 (1996) (157)
Chlorosulfenylation-dehydrochlorination reactions. New and improved methodology for the synthesis of unsaturated aryl sulfides and aryl sulfones (1978) (148)
Multiply convergent syntheses via conjugate-addition reactions to cycloalkenyl sulfones (1986) (140)
Synthesis and evaluation of taxol-folic acid conjugates as targeted antineoplastics. (2002) (100)
Conversion of cyclic vinyl sulfones to transposed vinyl phosphonates. (2007) (99)
Interphylal Product Splicing: The First Total Syntheses of Cephalostatin 1, the North Hemisphere of Ritterazine G, and the Highly Active Hybrid Analogue, Ritterostatin GN1N1 (1998) (86)
Chemistry of trisdecacyclic pyrazine antineoplastics: the cephalostatins and ritterazines. (2009) (85)
A triply convergent total synthesis of l(-)-prostaglandin E2 (1981) (85)
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2009) (82)
Inversion of acyclic olefins by the phosphorus betaine method. Scope and limitations (1973) (81)
Stereospecific Alkenylation of C−H Bonds via Reaction with β-Heteroatom-Functionalized Trisubstituted Vinyl Triflones1 (1997) (81)
Amelioration of the conjugate addition chemistry of .alpha.-alkoxycopper reagents: application to the stereospecific synthesis of C-Glycosides (1987) (78)
Chemospecific chromium[VI] catalyzed oxidation of C-H bonds at -40 °C (2002) (77)
Alkenylation of C−H Bonds via Reaction with Vinyl and Dienyl Triflones. Stereospecific Synthesis of Trisubstituted Vinyl Triflones via Organocopper Addition to Acetylenic Triflones1 (1996) (70)
Phosphorus betaines derived from cycloheptene and cyclooctene oxides. Inversion of cyclooctene (1973) (62)
The first synthesis of the aglycone of the potent anti-tumor steroidal saponin OSW-1 ☆ (1998) (62)
Chiral and stereochemical control via intramolecular Diels-Alder reaction of Z dienes (1982) (61)
Studies culminating in the total synthesis of (dl)-morphine (1988) (60)
.alpha.-Arylation of carbonyl groups. Utilization of the p-toluenesulfonylazo olefin functional group as an enolonium synthon (1975) (60)
A concise total synthesis of DL-histrionicotoxin. (2006) (58)
Rapid and unequivocal determination of syn-anti stereochemistry for toluenesulfonylhydrazones and other imine derivatives via carbon-13 nuclear magnetic resonance spectroscopy. A synthetic adjunct (1977) (55)
Carboethoxycyclopropyltriphenylphosphonium fluoroborate. Reagent for the facile cycloalkenylation of carbonyl groups (1974) (52)
Homoconjugate addition of organocopper reagents to cyclopropanes and its application to the synthesis of prostanoids. (1972) (52)
EFFICIENT SYNTHESES OF PYROFOLIC ACID AND PTEROYL AZIDE, REAGENTS FOR THE PRODUCTION OF CARBOXYL-DIFFERENTIATED DERIVATIVES OF FOLIC ACID (1997) (49)
APPLICATION OF THE GRUBBS RING-CLOSING METATHESIS FOR THE CONSTRUCTION OF A MACROCYCLIC ANSA-BRIDGE. SYNTHESIS OF THE TRICYCLIC CORE OF ROSEOPHILIN (1997) (48)
Synthesis of the North 1 Unit of the Cephalostatin Family from Hecogenin Acetate1 (1999) (45)
Synthesis of the South Unit of Cephalostatin. 7. Total Syntheses of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K1 (1999) (44)
Conversion of amides and lactams to thioamides and thiolactams using hexamethyldisilathiane (1994) (43)
An Efficient Protocol for the Synthesis of Unsymmetrical Pyrazines. Total Synthesis of Dihydrocephalostatin 11 (1996) (42)
Biomimetic Total Syntheses of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K (1995) (42)
Stereo- and Regiospecific Syntheses of α- and β-Substituted Vinyl and Dienyl Triflones via the Stille Reaction1 (1996) (42)
Mechanistic aspects of the CH alkynylation reaction of acetylenic triflones. Determination of phenyl versus cyclohexyl migratory aptitude for a vinylidine carbene (1996) (42)
Synthesis via vinyl sulfones. 22. A chemodirected, triply-convergent total synthesis of d-(+)-carbacyclin (1987) (41)
Enantiospecific syntheses of .gamma.-substituted enones: organometallic SN2' conjugate-addition reactions of epoxy vinyl sulfones (1981) (39)
Laboratory automation. 1: syntheses via vinyl sulfones. 14. Robotic orchestration of organic reactions: yield optimization via an automated system with operator-specified reaction sequences (1984) (38)
Synthesis of a model for the BCE ring system of bruceantin. A caveat on the cyclohexene .fwdarw. trans diaxial diol conversion (1980) (37)
Scope and Limitations of Functionalized Acetylenic Triflones in the Direct Alkynylation of C-H Bonds. (1997) (37)
Synthesis via vinyl sulfones. 21. Total synthesis of dl-morphine (1987) (36)
Chemospecific alkynylation of organic iodides (1998) (34)
Syntheses of highly substituted enantiopure C6 and C7 enones(1). (2002) (33)
Synthesis of termini-differentiated 6-carbon stereotetrads: an alkylative oxidation strategy for preparation of the c21-c26 segment of apoptolidin(1). (2002) (32)
Synthesis via vinyl sulfones. 18. Rapid access to a series of highly functionalized .alpha.,.beta.-unsaturated cyclopentenones. A caveat on aminospirocyclization (1987) (32)
Redox refunctionalization of steroid spiroketals. Structure correction of ritterazine M. (2002) (32)
Increase in intricacy—a tool for evaluating organic syntheses (2001) (31)
Fluoride-mediated elimination of allyl sulfones: application to the synthesis of a 2,4-dimethyl-A-ring vitamin D3 analogue. (2012) (31)
.alpha.-Arylation of .alpha.,.beta.-unsaturated ketones. Utilization of the .alpha.-epoxytosylhydrazone functional group as a .DELTA.2-enonium synthon (1976) (31)
New oxidative tools for the functionalization of the cephalostatin north 1 hemisphere. (2003) (31)
Olefin inversion by the phosphorus betaine method (1971) (30)
Bruceantin support studies. 10. Use of an axial .alpha.-face control element in intramolecular conjugate additions: synthesis of an ABCD tetracyclic bruceantin precursor (1986) (30)
Syntheses via vinyl sulfones. 28. Seven-ring annulation. A linch-pin approach to a tetracyclic precursor of the lathrane diterpenes (1988) (30)
An efficient and convenient synthesis of enantiopure 4-(t-butyldimethylsilyloxy)-cyclohex-2-en-1-one: a formal synthesis of (±)-mesembranol (2001) (29)
Synthesis of vinyl sulfones. 23. Addition of organometallic reagents to cyclooctenyl phenyl sulfones (1987) (29)
3,3,3-Trichloropropyl-1-triphenylphosphorane: A Reagent for the Synthesis of (Z)-1,3-Enynes, (Z,Z)-1-Chloro-1,3-dienes, and 1,3-Diynes† (2004) (29)
Reagents for silicon-mediated organic synthesis (2011) (29)
A versatile and expedient synthesis of .alpha.,.beta.-unsaturated ketones. Utilization of the .beta.-epoxy sulfone functional group as the enone progenitor (1978) (28)
The first total synthesis of (corrected) ritterazine M. (2002) (28)
Efficient Protocol for Ring Opening of Spiroketals Using Trifluoroacetyl Trifluoromethanesulfonate (TFAT)1 (2003) (28)
Synthesis via vinyl sulfones. 13. Stereoselective, chemodirected formal SN2' addition of organometallic reagents to .beta.'-amino cyclopentenyl sulfone derivatives (1985) (28)
Synthesis via Vinyl Sulfones. 57. Facile Synthesis of Allyl, .gamma.-Iodoallyl, and Cyclopropyl Triflones via Radical-Mediated Atom-Transfer Addition of Iodomethyl Triflone to Olefins and Acetylenes (1995) (27)
Dyotropic rearrangement facilitated proximal functionalization and oxidative removal of angular methyl groups: efficient syntheses of 23'-deoxy cephalostatin 1 analogues. (2002) (27)
Regiospecific silver[I] promoted, palladium[O]-catalyzed intramolecular addition of aryl iodides to vinyl sulfones. (1993) (27)
Scope and limitations in the Jacobsen epoxidation of dienyl sulfones (1997) (25)
A general approach to the synthesis of enantiopure 19-nor-vitamin D3 and its C-2 phosphate analogs prepared from cyclohexadienyl sulfone. (2012) (25)
Use of allylic triflones for allylation of C-H bonds (1998) (25)
A Highly Selective Synthesis of a Chiral Gamma-amino Trisubstituted Z-Vinyl Ester.1 (1986) (25)
An efficient synthesis of the C-23 deoxy, 17 alpha-hydroxy South 1 hemisphere and its cephalostatin 1 analog. (2003) (24)
Synthesis of a 17-Deoxy, C-14,15-Dihydro Derivative of the North Spiroketal Moiety of the Cephalostatins. Conversion to a (+)-Trisdecacyclic C2 Symmetrical Pyrazine (1994) (24)
Ramberg-Bäcklund syntheses and chemodirected annulations of exocyclic allylsilanes (1989) (24)
A biomimetically inspired, efficient synthesis of the South 7 hemisphere of cephalostatin 7. (2005) (24)
Synthesis of 15-deoxy-16.beta.-ethoxybruceantin and synthetic efforts toward bruceantin (1994) (24)
Cytochalasin support studies. 5. Conjugate addition of .beta.-oxo ester dianions to vinyl sulfones: a new procedure for seven-ring annulation. Synthesis of a chiral cytochalasin C intermediate via an intramolecular Diels-Alder reaction of a chiral Z diene (1982) (23)
Cytochalasin support studies. 10. Nucleophilic and electrophilic mercaptanylations via 2-(trimethylsilyl)ethanethiol-derived reagents (1988) (23)
Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. (2007) (23)
Fluoride ion mediated intramolecular sulfenylation of .alpha.-silyl sulfones: Ramberg-Baecklund annulation to exocyclic fused olefins (1990) (23)
An Efficient C−H Oxidation Protocol for α-Hydroxylation of Cyclic Steroidal Ethers (2004) (23)
The use of tetramethylguanidinium azide in non-halogenated solvents avoids potential explosion hazards (1994) (22)
Synthesis and pharmacological evaluation of nonacyclic and trisdecacyclic pyrazines related to cephalostatin (1992) (22)
Tetramethylguanidinium azide as a new reagent for the stereoselective synthesis of glycosyl azides (1993) (21)
Synthesis of .beta.,.gamma.-unsaturated esters. Direct generation of ester dienolates from .beta.-keto ester tosylhydrazone trianions (1977) (21)
Reduction of azides to primary amines in substrates bearing labile ester functionality. Synthesis of a PEG-solubilized, "Y"-shaped iminodiacetic acid reagent for preparation of folate-tethered drugs. (1999) (21)
Synthesis of C14,15-dihydro-C22,25-epi north unit of cephalostatin 1 via "red-ox" modifications of hecogenin acetate. (2009) (21)
Enantioconvergent syntheses of two classes of chiral cyclopentenyl sulfone synthons (1981) (21)
A Facile Synthesis of Unsymmetrical Thiolsulfonates via Sulfonylation of Mercaptans1 (1988) (20)
Efficient generation and use of 3-carboalkoxycyclopentadienone as a Diels-Alder dienophile (1987) (20)
An Efficient Method for Conversion of Carboxylic Acid Derivatives to Allylsilanes1 (1987) (20)
Conversion of δ-(sulfonyl)amino-α-epoxy ketones to bicyclic ketopyrroles via intramolecular conjugate-addition to azoene intermediates. Synthesis of the bicyclic ketopyrrole core of the 1-azafulvene roseophllin (1996) (20)
γ-Allyl Phosphinoyl Phenyl Sulfone (GAPPS): A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3-Dienes† (2003) (20)
Synthesis and evaluation of a fluorescent ritterazine-cephalostatin hybrid. (2011) (20)
Trans-1-butadienyltriphenylphosphonium bromide: A reagent for the 1,3-cyclohexadienylation of carbonyl groups. (1974) (19)
Free Radical Self-Immolative 1,2-Elimination and Reductive Desulfonylation of Aryl Sulfones Promoted by Intramolecular Reactions with Ortho-Attached Carbon-Centered Radicals(1). (1997) (19)
Six-membered-ring annulation via a conjugate addition-alkylation sequence using functionalized aryllithium reagents and vinyl sulfones (1981) (19)
Cytochalasin support studies. 2. Chiral and stereochemical control via an intramolecular Diels-Alder reaction of a (Z)-diene (1980) (19)
Pharmacophore definition and three-dimensional quantitative structure-activity relationship study on structurally diverse prostacyclin receptor agonists. (2002) (19)
Functionality propagation by alkylative oxidation of cross-conjugated cycloheptadienyl sulfones. (2003) (18)
Amine-directed addition of cuprate reagents to cyclopentenyl sulfones (1986) (18)
Synthesis of gamma-hydroxy enones via persulfate oxidation of dienyl ethers.☆ (1981) (18)
Alkynylatlon of aldehydic CH bonds via reaction with acetylenic triflones (1997) (18)
Cytochalasin support studies. The C14-C19 subunit of cytochalasin C. Intramolecular 2 + 2 photochemical cycloaddition of vinyl sulfones (1982) (17)
On the chemistry of lithium diallyl cuprate (1986) (17)
Morphine support studies. 2. Formation of the neopinone/codeinone ring system via intramolecular 1,6-addition of an amino moiety to a dienyl ketone (1986) (17)
Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I : regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol (1995) (17)
Regiospecific quassinoidal A-ring synthesis via an olefin oxidation strategy (1988) (17)
Synthesis of phorbol C-ring analogs : a biomimetic model study on the phorbol to 12-hydroxydaphnetoxin conversion (1992) (17)
Comparison of vinyl organolithium and organopalladium reagents for intramolecular conjugate addition to vinyl sulfones. (1993) (17)
.alpha.'-Functionalization of .beta.,.gamma.-unsaturated cyclohexenones. Utilization of silyl enol ethers produced from the lithium/ammonia reduction of silyl aryl ethers (1977) (16)
Intramolecular oxygen versus carbon alkylation of naphthoate esters: A caveat on the mechanistic aspects of neocarzinostatin chemistry (1993) (16)
Efficient 4 + 1 Syntheses of Highly Functionalized Cyclopentenes (1987) (15)
Asymmetric epoxy cyclohexenyl sulfones: readily accessible progenitors of stereo defined six-carbon arrays. (1999) (15)
Synthesis of allyl phosphine oxides/boranes via Horner reaction of bis(diphenylphosphine)ethane monoxide reagent with an aldehyde (2003) (15)
A new protocol for in situ dioxirane reactions: stoichiometric in oxone and catalytic in fluorinated acetophenones. (2003) (15)
Synthesis of enantiopure termini-differentiated heptane stereotriads. Application to side chain-functionalized tetrahydrofurans of IKD-8344. (2000) (15)
Methanesulfenyl triflate promoted iminosulfenylation of an allylic trichloroacetimidate. An efficient and stereospecific total synthesis of (+) mannostatin A (1994) (15)
Regiospecific 4,6-Functionalization of Pyranosides via Dimethylboron Bromide-Mediated Cleavage of Phthalide Orthoesters (1995) (14)
Intramolecular 1,4-addition of .alpha.-heteroatom-substituted radicals to .beta.,.beta.-disubstituted enones. Applications to tandem cyclizations (1991) (14)
Tandem intramolecular conjugate addition/intramolecular alkylation reactions of substituted vinyl sulfones (1984) (14)
KH/18-Crown-6: A Powerful Base for the Protection of Hindered Alcohols with t-Butyldimethylsilylchloride (1986) (14)
Synthesis of the South hexacyclic sterold unit of cephalostatin 7 (1995) (14)
Jacobsen protocols for large-scale epoxidation of cyclic dienyl sulfones: application to the (+)-pretazettine core. (2012) (14)
Ritterostatin GN1N, a Cephalostatin–Ritterazine Bis‐steroidal Pyrazine Hybrid, Selectively Targets GRP78 (2017) (14)
Conjugate addition of moderately soft anions to a vinyl sulfone (1983) (13)
Application of the Reich iodoso syn-elimination for the preparation of an intermediate appropriate for the synthesis of both hexacyclic steroidal units of cephalostatin 7 (1994) (13)
Synthesis of the C1-C20 and C15-C27 segments of aplyronine A. (2011) (13)
A mild and convenient synthesis of functionalized methyl triflones and vinyl triflones (1994) (13)
Intramolecular acylation of an α-sulfonyl anion generated via halogen-metal exchange of an α-halosulfone bearing an unsymmetrical anhydride (1991) (13)
Cytochalasin support studies. Macrocycle synthesis via enolate-assisted, intraannular 1,4-fragmentation reactions (1979) (13)
Bruceantin support studies. 3. The Robinson transposition reaction. Conjugate-addition/intramolecular Wittig reactions of enolates with [3-(phenylthio)-1,3-butadienyl]triphenylphosphonium chloride (1983) (13)
Conjugate-addition reactions of highly-functionalized aryl lithium reagents to γ-silyloxy-α,β-unsaturated sulfones: consequences of the structure of the sulfone moiety. (1980) (13)
Addition of .gamma.-Methoxy Allylsulfonyl Anions to Cyclopentenyl Phenyl Sulfones. A Facile Synthesis of .beta.-Cyclopentenyl-Substituted Dienones and Trienones (1995) (12)
Cephalostatin Synthesis. Part 11. Interphylal Product Splicing: The First Total Syntheses of Cephalostatin 1, the North Hemisphere of Ritterazine G, and the Highly Active Hybrid Analogue, Ritterostatin GN1N. (1998) (12)
Scope and Limitations in the Use of α-Silyl and α-Stannyl Sulfones as Latent α-Sulfonyl Anions (1991) (12)
SN2' Additions of cuprates to sulfone and ester-polarized cyclopentenylic systems (1989) (12)
Bis-alkylation of dimetallated phenylsulfonylmethyl triflone. A n+1 annulation strategy for synthesis of cyclic vinyl sulfones. (1992) (12)
New Synthetic Methods Exploiting Vinyl Sulfones Discovered During the Synthesis of a Natural Product (1994) (12)
An Improved Procedure for the Synthesis of 4-Oxopimelate-Derived Materials.1 (1983) (12)
A Highly Efficient Synthesis of .beta.-Substituted Six- and Seven-Membered-Ring Enones via Carbon Alkylation of .gamma.-Methoxy Allylsulfonyl Anions (1994) (12)
Synthesis of beta-substituted cyclopentenones via carbon alkylation of metalated gamma-methoxycyclopentenyl phenylsulfonyl anion (1995) (12)
Syntheses Via Vinyl Sulfones. 58. A Triply Convergent Total Synthesis of a Symchiral Pyrrolidine-Fused Prostacyclin Analog (1995) (12)
.gamma.-Substitution of allyl ylides in the Wittig reaction (1973) (12)
Synthesis of a family of epoxyvinyltriflate stereotetrads from 4-hydroxycyclohex-2-en-1-one (1999) (12)
Synthesis via vinyl sulfones. 37. Cytochalasin support studies. 11. .alpha.-Silyl sulfones as latent .alpha.-sulfonyl anions. Fluoride-promoted intramolecular 1,2-additions to aldehydes as the basis of a new cyclopentenylation strategy (1990) (12)
Oxidation and reduction reactions of highly functionalized allyl stannanes. Bicyclic and tricyclic .alpha.-stannylmethyl enones prepared via the Robinson annulation reaction of .beta.'-stannylethyl vinyl ketone (1993) (11)
Economical and environmentally friendly syntheses of 2-(phenylsulfonyl)-1,3-cyclohexadiene and 2-(phenylsulfonyl)-1,3-cycloheptadiene. (2002) (11)
Chromium [II]-mediated reductive cleavage of a tertiary halide bearing three β-alkoxy groups. Synthesis of the north hexacyclic steroid unit of the cephalostatin family (1995) (11)
Noteworthy observations accompanying synthesis of the apoptolidin disaccharide. (2011) (11)
Asymmetric synthesis of all eight seven-carbon dipropionate stereotetrads. (2007) (11)
Designer discodermolide segments via ozonolysis of vinyl phosphonates. (2009) (11)
Spiroketal equilibration : interconversion of 1,6-dioxaspiro[4.4]nonanes and 1,6-dioxaspiro[4.5]decanes. Implications for the synthesis of cephalostatin 7 (1994) (11)
CONCURRENT RING OPENING AND HALOGENATION OF SPIROKETALS (1999) (11)
Polyphosphoric acid trimethylsilyl ester promoted intramolecular acylation of an olefin by a carboxylic acid: convenient construction of C-18-functionalized delta14-hecogenin acetate. (2003) (11)
Synthesis of 6-carbon termini-differentiated stereotriads via symchiral 2-trifloxy-1,3-cyclohexadiene monoepoxide☆ (1999) (10)
Studies related to the Robinson transposition reaction (1985) (10)
Double lawton SN2'addition to epoxyvinyl sulfones: selective construction of the stereotetrads of aplyronine A. (2006) (10)
Controlled endocyclic and exocyclic γ-metalations of β-substituted cyclohexenyl sulfones. Regiospecific syntheses of γ-oxygenated cyclohexenyl sulfones. (1991) (10)
Sulfones as Radical Progenitors: An Unprecedented Example of Homolytic Sulfone Cleavage Facilitated by o-Stannyl Substitution of Aryl Sulfones(1). (1997) (10)
Bruceantin support studies. 12. Synthesis of a pentacyclic ABCDE bruceantin intermediate (1987) (10)
Use of .beta.-silylethyl vinyl ketone as a .beta.-hydroxyethyl vinyl ketone synthon in the Robinson annulation reaction (1992) (10)
Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part II: Spiroketal synthesis and stereochemical assignment by nmr spectroscopy (1995) (10)
Synthesis and Facile One-pot Aldol/Elimination/Diels-Alder Reaction of ß-Keto-Z-Dienylamides as Cytochalasin C Intermediates1 (1986) (9)
Intramolecular Conjugate Addition of Allylic Trichloroacetimidates to Cycloalkenyl Sulfones.1 A Regiospecific and Stereoselective Synthesis of Amino Alcohol Derivatives. (1994) (9)
Silver Fluoroborate Promoted Sulfur Alkylation of β-Silyl Ethyl Sulfides. Selective Synthesis of β-Thioglycosides (1994) (9)
Quantitative analysis of F‐actin redistribution in astrocytoma cells treated with candidate pharmaceuticals (2014) (9)
Lactol-directed osmylation. Stereodivergent synthesis of four C-19,20 apoptolidin diols from a single allylic hemiacetal. (2007) (9)
A convergent total synthesis of the potent cephalostatin/ritterazine hybrid -25-epi ritterostatin GN1N. (2013) (9)
Essential Reagents for Organic Synthesis (2016) (9)
S(N)2' addition/1,2-elimination of dimethylsulfonium methylide with epoxy vinyl sulfones: synthesis of exocyclic cross-conjugated dienyl sulfones. (2011) (9)
Conversion of vinyl sulfones to regiospecifically functionalized trisubstituted olefins (1995) (9)
Intramolecular photocyclization of aryl vinyl sulfones (1993) (9)
Triply-convergent synthesis of two sets of homochiral cyclopent[a]indene carbacyclin analogs (1991) (8)
A Self-Immolative Strategy for 1,2-Elimination of Homallyl Sulfones to 1,3-Dienes (1987) (8)
An Intramolecular Diels-alder Reaction of a Z-Diene. Generation Of The Chiral Isoindolone Nucleus Of Cytochalasin C.1 (1986) (8)
Carbon-13 NMR based organic spectral problems (1979) (8)
Conjugate-addition reactions of organometallic reagents to γ-oxygenated-α,β-unsaturated sulfones: Control of stereochemistry at the β-position (1978) (8)
Intramolecular methylation of an allyl sulfone via lithium alkoxyaluminate; application to the enantioselective synthesis of the CD ring of vitamin D3. (2012) (7)
Relative reactivity of anti- and syn-oximino carbonates and carbamates of 2-pyridylacetic acid esters. (2001) (7)
AMELIORATION OF THE LEAVING GROUP ABILITY OF THE ARYL SULFONE MOIETY VIA INTRAMOLECULAR OXYGEN SILYLATION (1994) (7)
Bruceantin support studies. 10. Use of an axial .beta.-face thiomethyl control element in intramolecular conjugate additions. Synthesis of a tricyclic bruceantin precursor (1987) (7)
Synthesis of tertiary alcohols via the use of the allyldimethylsilyl moiety as a latent hydroxyl group in the Kumada-Fleming-Tamao reaction. (1991) (7)
Annulation Reactions of Ortho-Chloromethyl Aryl Cuprates (1990) (7)
Reagent-directed allylic quadraselection. Chemoselective anti- and syn-Lawton S(N)2' methylation of seven-membered epoxyvinylsulfones. (2009) (7)
Bruceantin support studies. 10. Studies related to the Robinson transposition reactions (1985) (6)
SN2′ Addition of Organometallic Reagents to β′-Amino Cyclohexenyl Sulfone Derivatives (1989) (6)
Use of phosphazene base and phase-transfer conditions for regiospecific alkylative isomerization of vinyl sulfones capable of undergoing β-elimination reactions (1996) (6)
The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems. (1990) (6)
PHOSPHAZENE BASE P2-ET MEDIATED ISOMERIZATION OF VINYL SULFONES TO ALLYL SULFONES (1996) (6)
In situ nitrosonium ion generation — α-Oximinylation of enol ethers from steroidal spiroketals: Introduction of C23 (R)-OH in cephalostatin intermediates (2006) (6)
Second-generation synthesis of syn- and anti-cycloheptadienylsulfone polyketide stereodiads. (2008) (6)
Total synthesis of a homochiral arene-fused prostacyclin analog☆ (1991) (6)
Tripyl-convergent total synthesis of a homochiral benzoindane-fused prostacyclin analog (1991) (6)
Use of 1-Penten-3-One-4- Phosphonate as a Kinetic Ethyl Vinyl Ketone Equivalent in the Robinson Annulation Reaction1 (1986) (5)
Biochemical and pharmacological activity of arene-fused prostacyclin analogues on human platelets. (1994) (5)
Triply-convergent syntheses of two homochiral arene-fused prostacyclin analogs related to U68,215☆ (1991) (5)
Cesium fluoride mediated intramolecular conjugate-addition reactions of alpha sulfonyl ester to enones and alpha-chloroenones (1984) (5)
Antitumor agent 25-epi Ritterostatin GN1N induces endoplasmic reticulum stress and autophagy mediated cell death in melanoma cells (2017) (5)
Synthesis of Fluorinated Dienylic Stannanes Via the Wadsworth-Emmons Reaction (1989) (5)
Synthesis and Alkylation of Vinylsulfinic Acids via Fluoride Cleavage of β-Trimethylsilylethyl Vinyl Sulfones (1988) (5)
Citric acid mediated catalytic osmylation/oxidative cleavage of electron deficient olefins: a vinyl sulfone study (2015) (5)
Synthetic utilization of the imine moiety. 6. Intramolecular carbon alkylation of oxime anions. Stereospecific generation and rearrangement of nitrosocyclopropanes and nitrosocyclobutanes (1978) (4)
Studies on the synthesis of apoptolidin: synthesis of a C1-C27 fragment of apoptolidin D. (2011) (4)
Mass spectra of ?-substituted a-trimethylsilyl phenylsulfones (1991) (4)
Rapid Access to a Series of Highly Functionalized α,β-Unsaturated Cyclopentenones. A Caveat on Aminospirocyclization. (1987) (4)
Synthesis of a Chiral Bicyclo[4.1.0] Allylic Nitrile Via Reductive Cyclization of a Dienyl Nitrile (1985) (4)
Efficient Syntheses of Pyrofolic Acid and Pteroyl Azide, Reagents for the Production of Carboxyl‐Differentiated Derivatives of Folic Acid. (1998) (4)
Evidence for a double intramolecular trimethylsilyl rearrangement (1992) (4)
Cycloaromatization Reactions of Methyl 4-Carbomethoxy-5-Methoxy-Penta-2,4-Dienoate (1987) (3)
Torsional effects in the baeyer-villiger oxidation (1984) (3)
CYTOCHALASIN SUPPORT STUDIES. THE C14‐C19 SUBUNIT OF CYTOCHALASIN C. INTRAMOLECULAR 2 + 2 PHOTOCHEMICAL CYCLOADDITION OF VINYL SULFONES (1983) (3)
CARBONYL REGENERATION FROM P-TOLUENESULFONYLHYDRAZONES (TOSYLHYDRAZONES) (1976) (3)
Synthesis and pharmacological evaluation of vinyl sulfone based anticancer agents (1994) (3)
PULSAR: a personalized microcomputer-based system for keyword search and retrieval of literature information (1981) (3)
Synthesis and oxidation reactions of cycloheptatrienyl sulfones (2000) (3)
An efficient C-H oxidation protocol for alpha-hydroxylation of cyclic steroidal ethers. (2004) (3)
A bicyclo[2.1.0]pentane phenonium ion (1968) (3)
A simple, automated device for the precise addition of liquids (1989) (3)
Triply-convergent synthesis of a homochiral 3,3-dimethyl, 15-cyclohexyl prostacyclin analog (1991) (2)
Synthesis of enantiopure five-carbon, stereodiads applicable for the preparation of the mycolactones (2004) (2)
Synthesis of a 17-Deoxy, C-14,15-Dihydro Derivative of the North Spiroketal Moiety of the Cephalostatins. Conversion to a (+)- Trisdecacyclic C2 Symmetrical Pyrazine. (1994) (2)
Catalytic oxidation reagents (2013) (2)
Amelioration of the Conjugate Addition Chemistry of α-Alkoxycopper Reagents: Application to the Stereospecific Synthesis of C-Glycosides. (1987) (2)
Chemospecific chromium[VI] catalyzed oxidation of C-H bonds at -40 degrees C1. (2002) (2)
Triflone Chemistry. Part 7. Syntheses via Vinyl Sulfones. Part 68. Alkenylation of C-H Bonds via Reaction with Vinyl and Dienyl Triflones. Stereospecific Synthesis of Trisubstituted Vinyl Triflones via Organocopper Addition to Acetylenic Triflones. (1997) (2)
Bruceantin support studies. 5. Rapid access to a highly functionalized tricyclic bruceantin intermediate (1983) (2)
Synthesis via Vinyl Sulfones. Part 63. Conversion of δ‐(Sulfonyl) amino‐α‐epoxy Ketones to Bicyclic Ketopyrroles via Intramolecular Conjugate‐Addition to Azoene Intermediates. Synthesis of the Bicyclic Ketopyrrole Core of the 1‐Azafulvene Roseophilin. (1996) (2)
Increase in Intricacy — A Tool for Evaluating Organic Syntheses (2001) (2)
Conversion of Amides and Lactams to Thioamides and Thiolactams Using Hexamethyldisilathiane. (1994) (1)
Gamma-allyl phosphinoyl phenyl sulfone (GAPPS): a conjunctive reagent for the synthesis of EE, EZ, and ET 1,3-dienes. (2003) (1)
A robotic interface for the HP 1090M high performance liquid chromatograph (1989) (1)
Oxidation and Reduction Reactions of Highly Functionalized Allyl Stannanes. Bicyclic and Tricyclic α‐Stannylmethyl Enones Prepared via the Robinson Annulation Reaction of β′‐Stannylethyl Vinyl Ketone. (1993) (1)
Mechanism-specified 5-exo termini differentiation of a C32-desmethyl C28–C34 aplyronine A analog segment (2015) (1)
Synthesis of dl-Histrionicotoxin (2007) (1)
Mass spectra of substituted o-trimethylsilylphenyl sulfones (1990) (1)
Cephalostatin Synthesis. Part 17. Concurrent Ring Opening and Halogenation of Spiroketals. (1999) (1)
α-ARYLATION OF CARBONYL GROUPS. UTILIZATION OF THE P-TOLUENESULFONYLAZO OLEFIN FUNCTIONAL GROUP AS AN ENOLONIUM SYNTHON (1976) (1)
SN2′ Additions of Cuprates to Sulfone and Ester-Polarized Cyclopentenylic Systems. (1989) (1)
Syntheses via Vinyl Sulfones. Part 69. Triflone Chemistry. Part 8. Stereospecific Alkenylation of C-H Bonds via Reaction with β- Heteroatom-Functionalized Trisubstituted Vinyl Triflones. (1997) (1)
Tetramethylguanidinium Azide as a New Reagent for the Stereoselective Synthesis of Glycosyl Azides. (1993) (1)
Intramolecular Conjugate Addition of Allylic Trichloroacetimidates to Cycloalkenyl Sulfones. A Regiospecific and Stereoselective Synthesis of Amino Alcohol Derivatives. (1994) (1)
HYDROGEN TRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE‐ A REAGENT FOR CONVERSION OF THIODIENES TO THIOALLYLPHOSPHONIUM TETRAFLUOROBORATES (1977) (1)
The Use of Tetramethylguanidinium Azide in Non-Halogenated Solvents Avoids Potential Explosion Hazards. (1994) (1)
Cytochalasin Support Studies. Part 10. Nucleophilic and Electrophilic Mercaptanylations via 2‐(Trimethylsilyl)ethanethiol‐Derived Reagents. (1988) (1)
3,3,3-trichloropropyl-1-triphenylphosphorane: a reagent for the synthesis of (Z)-1,3-enynes, (Z,Z)-1-chloro-1,3-dienes, and 1,3-diynes. (2005) (1)
BRUCEANTIN SUPPORT STUDIES. PART 2. SYNTHESIS OF GAMMA-HYDROXY ENONES VIA PERSULFATE OXIDATION OF DIENYL ETHERS (1982) (1)
α-ARYLATION OF α,β-UNSATURATED KETONES. UTILIZATION OF THE α-EPOXYTOSYLHYDRAZONE FUNCTIONAL GROUP AS A Δ2-ENONIUM SYNTHON (1976) (1)
Evidence for competitive intramolecular trimethylsilyl rearrangement to oxygen and sulfur in beta-trimethylsilylethylthiolesters. (1988) (1)
Efficient protocol for ring opening of spiroketals using trifluoroacetyl trifluoromethanesulfonate (TFAT). (2004) (1)
Develop Reactions Automatically (1990) (1)
Syntheses via Vinyl Sulfones. Part 46. Intramolecular Photocyclization of Aryl Vinyl Sulfones. (2010) (1)
Desulfurization of α-Sulfenylated Allyl Nitriles Using an Amine-Deactivated Palladium [0] Catalyst (1986) (1)
SN2′ Addition/1,2‐Elimination of Dimethylsulfonium Methylide with Epoxy Vinyl Sulfones: Synthesis of Exocyclic Cross‐Conjugated Dienyl Sulfones. (2011) (1)
ALKYNYLATION OF ALDEHYDIC C-H BONDS VIA REACTION WITH ACELYLENIC TRIFLONES (1997) (0)
Cephalostatin Synthesis. Part 13. Synthesis of the North 1 Unit of the Cephalostatin Family from Hecogenin Acetate. (1999) (0)
Syntheses via Vinyl Sulfones. Part 52. A Highly Efficient Synthesis of β‐Substituted Six‐ and Seven‐Membered‐Ring Enones via Carbon Alkylation of γ‐Methoxy Allylsulfonyl Anions. (1994) (0)
Syntheses via Vinyl Sulfones. Part 65. Use of Phosphazene Base and Phase‐Transfer Conditions for Regiospecific Alkylative Isomerization of Vinyl Sulfones Capable of Undergoing β‐Elimination Reactions. (1996) (0)
Syntheses via Vinyl Sulfones. Part 15. Amine-Directed Addition of Cuprate Reagents to Cyclopentenyl Sulfones. (1986) (0)
Synthesis via Vinyl Sulfones. Part 74. Scope and Limitations in the Jacobsen Epoxidation of Dienyl Sulfones. (1997) (0)
Synthesis via Vinyl Sulfones. Part 33. Triply‐Convergent Synthesis of Two Sets of Homochiral Cyclopent(a)indene Carbacyclin Analogs. (1992) (0)
Synthesis via Vinyl Sulfones. Part 40. Annulation Reactions of ortho-Chloromethylarylcuprates. (1990) (0)
Cytolasin Report Studies. Part 8. Synthesis and Facile One-Pot Aldol/ Elimination/Diels-Alder Reaction of β-Keto-Z-dienylamides as Cytochalasin C Intermediates. (1987) (0)
Desulfurization of α-Sulfenylated Allyl Nitriles Using an Amine-Deactivated Palladium(0) Catalyst. (1986) (0)
BRUCEANTIN SUPPORT STUDIES. 6. CESIUM FLUORIDE-MEDIATED INTRAMOLECULAR CONJUGATE-ADDITION REACTIONS OF ALPHA-SULFONYL ESTER TO ENONES AND ALPHA-CHLOROENONES (1984) (0)
Use of β-Silylethyl Vinyl Ketone as a β-Hydroxyethyl Vinyl Ketone Synthon in the Robinson Annulation Reactions. (1993) (0)
A Facile Synthesis of Unsymmetrical Thiolsulfonates via Sulfonylation of Mercaptans. (1988) (0)
Cephalostatin Support Studies. Part 23. Chemospecific Chromium[VI] Catalyzed Oxidation of C—H Bonds at -40 °C. (2003) (0)
Syntheses via Vinyl Sulfones. Part 66. Palladium(0)‐Mediated Aminospirocyclization of Tertiary Allylic Sulfones. Stereospecific Construction of the Azabicyclic Ring System of Cephalotaxine. (1996) (0)
An Efficient and Convenient Synthesis of Enantiopure 4-(t-Butyldimethylsilyloxy)-cyclohex-2-en-1-one: A Formal Synthesis of (.+-.)-Mesembranol. (2010) (0)
Synthesis via Vinyl Sulfones. Part 20. A Self-Immolative Strategy for 1,2-Elimination of Homoallyl Sulfones to 1,3-Dienes. (1987) (0)
Bruceantin Support Studies. Part 14. Regiospecific Quassinoidal A‐Ring Synthesis via an Olefin Oxidation Strategy. (1988) (0)
Synthesis via Vinyl Sulfones. Part 73. Free Radical Self-Immolative 1,2-Elimination and Reductive Desulfonylation of Aryl Sulfones Promoted by Intramolecular Reactions with ortho-Attached Carbon-Centered Radicals. (1998) (0)
Synthesis via Vinyl Sulfones. Part 23. Addition of Organometallic Reagents to Cyclooctenyl Phenyl Sulfones. (1988) (0)
Intramolecular 1,4‐Addition of α‐Heteroatom‐Substituted Radicals to β,β‐Disubstituted Enones. Applications to Tandem Cyclizations. (1992) (0)
Methanesulfenyl Triflate Promoted Iminosulfenylation of an Allylic Trichloroacetimidate. An Efficient and Stereospecific Total Synthesis of (+) Mannostatin A. (1994) (0)
Vinyl Sulfones. Part 81. Chiral Carbon Catalogue. Part 4. Asymmetric Epoxy Cyclohexenyl Sulfones: Readily Accessible Progenitors of Stereodefined Six-Carbon Arrays. (1999) (0)
KH/18-Crown-6: A Powerful Base for the Protection of Hindered Alcohols with tert- Butyldimethylsilylchloride. (1986) (0)
Synthesis of 15-Deoxy-16β-Ethoxybruceantin and Synthetic Efforts Toward Bruceantin. (1994) (0)
Synthesis via Vinyl Sulfones. Part 37. α‐Silyl Sulfones as Latent α‐Sulfonyl Anions. Fluoride‐Promoted Intramolecular 1,2‐Additions to Aldehydes as the Basis of a New Cyclopentenylation Strategy. (1990) (0)
PHOSPHORBETAINE AUS CYCLOHEPTEN- UND CYCLOOCTENOXIDEN, INVERSION VON CYCLOOCTENEN (1973) (0)
Syntheses via Vinyl Sulfones. Part 64. Phosphazene Base P2Et Mediated Isomerization of Vinyl Sulfones to Allyl Sulfones. (1996) (0)
SYNTHESIS OF β,Γ-UNSATURATED ESTERS. DIRECT GENERATION OF ESTER DIENOLATES FROM β-KETO ESTER TOSYLHYDRAZONE TRIANIONS (1977) (0)
2,2-Dimethoxy-5,5-dimethyl-delta3-1,3,4-oxadiazoline (First Update) (2012) (0)
Seven-Ring Annulation: A Linch-Pin Approach to a Tetracyclic Precursor of the Lathrane Diterpenes. (1989) (0)
Cephalostatin Synthesis. Part 10. An Efficient Protocol for the Synthesis of Unsymmetrical Pyrazines. Total Synthesis of Dihydrocephalostatin 1 (1997) (0)
Morphine Support Studies. Part 2. Formation of the Neopinone/Codeinone Ring System via Intramolecular 1,6-Addition of an Amino Moiety to a Dienyl Ketone. (1987) (0)
Diastereoselective Strategy for Stereotetrads Synthesis (2006) (0)
Syntheses via Vinyl Sulfones. Part 36. Ramberg-Baecklund Syntheses and Chemodirected Annulations of Exocyclic Allylsilanes. (1989) (0)
2‐Phenylsulfonyl‐1,3‐Cycloheptadiene (2005) (0)
Synthesis via Vinyl Sulfones. Part 79. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4‐Hydroxycyclohex‐2‐en‐1‐one. (1999) (0)
Syntheses via Vinyl Sulfones. Part 44. Bisalkylation of Dimetalated Phenylsulfonylmethyl Triflone. A (n + 1)Annulation Strategy for Synthesis of Cyclic Vinyl Sulfones. (1992) (0)
Efficient Generation and Use of 3-Carbalkoxycyclopentadienone as a Diels-Alder Dienophile. Part 13. (1988) (0)
Synthesis via Vinyl Sulfones. Part 76. Triflone Chemistry. Part 11. Use of Allylic Triflones for Allylation of C—H Bonds. (1998) (0)
Cephalostatin Synthesis. Part 9. Biomimetic Total Syntheses of (+)- Cephalostatin 7 (Ia), (+)-Cephalostatin 12 (Ib), and (+)-Ritterazine K (Ic). (1996) (0)
Syntheses via Vinyl Sulfones. Part 57. Facile Synthesis of Allyl, . gamma.-Iodoallyl, and Cyclopropyl Triflones via Radical-Mediated Atom- Transfer Addition of Iodomethyl Triflone to Olefins and Acetylenes. (1995) (0)
Syntheses via Vinyl Sulfones. Part 60. Conversion of Vinyl Sulfones to Regiospecifically Functionalized Trisubstituted Olefins. (1995) (0)
GAMMA-SUBSTITUTION OF ALLYL YLIDES IN THE WITTIG REACTION (1974) (0)
Chemistry of Trisdecacyclic Pyrazine Antineoplastics: The Cephalostatins and Ritterazines (2009) (0)
SYNTHESIS VIA VINYL SULFONES. 2. CONJUGATE‐ADDITION REACTIONS OF ORGANOMETALLIC REAGENTS TO Γ‐OXYGENATED‐α,β‐UNSATURATED SULFONES: CONTROL OF STEREOCHEMISTRY AT THE β‐POSITION (1979) (0)
ENANTIOSPECIFIC SYNTHESES OF Γ-SUBSTITUTED ENONES: ORGANOMETALLIC SN2′ CONJUGATE-ADDITION REACTIONS OF EPOXY VINYL SULFONES (1981) (0)
Syntheses via Vinyl Sulfones. Part 22. A Chemodirected, Triply Convergent Total Synthesis of d-(+)-Carbacyclin (1987) (0)
A General Approach to the Synthesis of Enantiopure 19-nor-Vitamin D3 and Its C-2 Phosphate Analogues Prepared from Cyclohexadienyl Sulfone. (2012) (0)
Synthesis via Vinyl Sulfones. Part 31. Total Synthesis of a Homochiral Arene‐Fused Prostacyclin Analog. (1992) (0)
Synthesis via Vinyl Sulfones. Part 38. Total Synthesis of the Cephalotaxus Alkaloids dl-Cephalotaxine, dl-11-Hydroxycephalotaxine, and dl-Drupacine. (1991) (0)
Bruceantin Support Studies. Part 11. Use of 1-Penten-3-one-4-phosphonate as a Kinetic Ethyl Vinyl Ketone Equivalent in the Robinson Annulation Reaction. (1988) (0)
Correction to Studies on the Synthesis of Apoptolidin: Synthesis of a C1–C27 Fragment of Apoptolidin D (2011) (0)
Synthesis via Vinyl Sulfones. Part 29. Studies Culminating in the Total Synthesis of (dl)-Morphine (I). (1989) (0)
Synthesis via Vinyl Sulfones. Part 45. Intramolecular Oxygen Versus Carbon Alkylation of Naphthoate Esters. A Caveat on the Mechanistic Aspects of Neocarzinostatin Chemistry. (2010) (0)
Syntheses via Vinyl Sulfones. Part 16. On the Chemistry of Lithium Diallyl Cuprate. (1986) (0)
Syntheses via Vinyl Sulfones. Part 62. Triflone Chemistry. Part 4. Stereo- and Regiospecific Syntheses of α- and β-Substituted Vinyl and Dienyl Triflones via the Stille Reaction. (1996) (0)
Syntheses via Vinyl Sulfones. Part 56. Addition of γ-Methoxy Allylsulfonyl Anions to Cyclopentenyl Phenyl Sulfones. A Facile Synthesis of β-Cyclopentenyl-Substituted Dienones and Trienones. (1995) (0)
Fluoride Ion Mediated Intramolecular Sulfenylation of α-Silyl Sulfones: Ramberg-Baecklund Anellation to Exocyclic Fused Olefins. (1991) (0)
Regiospecific 4,6-Functionalization of Pyranosides via Dimethylboron Bromide-Mediated Cleavage of Phthalide Ortho Esters. (1995) (0)
Silver Fluoroborate Promoted Sulfur Alkylation of β‐Silyl Ethyl Sulfides. Selective Synthesis of β‐Thioglycosides. (1995) (0)
Derives d'acide folique (1998) (0)
CYTOCHALASIN SUPPORT STUDIES. 5. CONJUGATE ADDITION OF β-OXO ESTER DIANIONS TO VINYL SULFONES: A NEW PROCEDURE FOR SEVEN-RING ANNULATION. SYNTHESIS OF A CHIRAL CYTOCHALASIN C INTERMEDIATE VIA AN INTRAMOLECULAR DIELS-ALDER REACTION OF (1983) (0)
Cephalostatin Chemistry. Part 7. Synthesis of a C14′,15′ Dihydro Derivative of the South Hexacyclic Steroid Unit of Cephalostatin 1. Part 1. Regiospecific Rh(II)-Mediated Intermolecular Oxygen Alkylation of a Primary Neopentyl Alcohol. (1996) (0)
Bruceantin Support Studies. Part 12. Synthesis of a Pentacyclic ABCDE Bruceantin Intermediate. (1987) (0)
Synthesis and Oxidation Reactions of Cycloheptatrienyl Sulfones. (2000) (0)
Cytolasin Report Studies. Part 6. A Highly Selective Synthesis of a Chiral γ-Amino Trisubstituted Z-Vinyl Ester. (1987) (0)
Syntheses of Highly Substituted Enantiopure C6- and C7-Enones. (2003) (0)
Fluoride‐Mediated Elimination of Allyl Sulfones: Application to the Synthesis of a 2,4‐Dimethyl‐A‐Ring Vitamin D3 Analogue (V). (2012) (0)
Cytolasin Report Studies. Part 7. An Intramolecular Diels-Alder Reaction of a Z-Diene. Generation of the Chiral Isoindolonone Nucleus of Cytochalsasin C. (1987) (0)
Synthesis of β‐Substituted Cyclopentenones via Carbon Alkylation of Metalated γ‐Methoxycyclopentenyl Phenylsulfonyl Anion. (1995) (0)
Synthesis via Vinyl Sulfones. Part 88. γ‐Allyl Phosphinoyl Phenyl Sulfone (GAPPS): A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3‐Dienes. (2004) (0)
Syntheses via Vinyl Sulfones. Part 26. Synthesis and Alkylation of Vinylsulfinic Acids via Fluoride Cleavage of β‐Trimethylsilylethyl Vinyl Sulfones. (1988) (0)
Reagents for direct functionalization of C-H bonds (2007) (0)
Syntheses via Vinyl Sulfones. Part 75. Triflone Chemistry. Part 10. Scope and Limitations of Functionalized Acetylenic Triflones in the Direct Alkynylation of C-H Bonds. (1997) (0)
SYNTHESIS OF A CHIRAL BICYCLO(4.1.0)ALLYLIC NITRILE VIA REDUCTIVE CYCLIZATION OF A DIENYL NITRILE (1985) (0)
Improved and Environmentally Friendly Large-Scale Preparation of Cyclohexadienyl-, Cycloheptadienyl Sulfone and Enantiopure Epoxy Cycloheptyl Sulfones (2004) (0)
Synthesis via Vinyl Sulfones. Part 78. Synthesis of 6‐Carbon Termini‐Differentiated Stereotriads via Symchiral 2‐Trifloxy‐1,3‐cyclohexadiene Monoepoxide. (1999) (0)
Syntheses via Vinyl Sulfones. Part 43. Controlled Endocyclic and Exocyclic γ‐Metalations of β‐Substituted Cyclohexenyl Sulfones. Regiospecific Syntheses of γ‐Oxygenated Cyclohexenyl Sulfones. (1992) (0)
Improved and Environmentally Friendly Large-Scale Preparation of Cyclohexadienyl-, Cycloheptadienyl Sulfone and Enantiopure Epoxy Cycloheptyl Sulfones. (2004) (0)
BRUCEANTIN SUPPORT STUDIES. 4. AN IMPROVED PROCEDURE FOR THE SYNTHESIS OF 4-OXOPIMELATE-DERIVED MATERIALS (1983) (0)
Use of an Axial β-Face Thiomethyl Control Element in Intramolecular Conjugate Additions. Synthesis of a Tricyclic Bruceantin Precursor (I). (1987) (0)
Synthesis via Vinyl Sulfones. Part 40. Scope and Limitations in the Use of α-Silyl and α-Stannyl Sulfones as Latent α- Sulfonyl Anions. (1992) (0)
Functionality Propagation by Alkylative Oxidation of Cross‐Conjugated Cycloheptadienyl Sulfones. (2003) (0)
Synthesis via Vinyl Sulfones. Part 96. Chiral Carbon Collection. Part 18. Designer Discodermolide Segments via Ozonolysis of Vinyl Phosphonates. (2009) (0)
Cephalostatin Chemistry. Part 4. Application of the Reich Iodoso syn‐ Elimination for the Preparation of an Intermediate Appropriate for the Synthesis of Both Hexacyclic Steroidal Units of Cephalostatin 7. (1995) (0)
CONJUGATE-ADDITION REACTIONS OF HIGHLY-FUNCTIONALIZED ARYL LITHIUM REAGENTS TO Γ-SILYLOXY-α,β-UNSATURATED SULFONES: CONSEQUENCES OF THE STRUCTURE OF THE SULFONE MOIETY (1980) (0)
Syntheses via Vinyl Sulfones. Part 58. A Triply Convergent Total Synthesis of a Symchiral Pyrrolidine-Fused Prostacyclin Analogue (IX). (1995) (0)
Syntheses via Vinyl Sulfones. Part 35. SN2′ Addition of Organometallic Reagents to β′-Amino Cyclohexenyl Sulfone Derivatives. (1989) (0)
Synthesis via Vinyl Sulfones. Part 77. Triflone Chemistry. Part 12. Chemospecific Alkynylation of Organic Iodides. (1999) (0)
Bruceantin Support Studies. Part 10. Use of an Axial α-Face Control Element in Intramolecular Conjugate Additions: Synthesis of an ABCD Tetracyclic Bruceantin Precursor. (1986) (0)
Cycloaromatization Reactions of Methyl 4‐Carboxymethyl‐5‐methoxypenta‐ 2,4‐dienoate. (1988) (0)
Synthesis via Vinyl Sulfones. Part 30. Triply‐Convergent Total Synthesis of a Homochiral Benzoindane‐Fused Prostacyclin Analog. (1992) (0)
Synthesis via Vinyl Sulfones. Part 53. A Mild and Convenient Synthesis of Functionalized Methyl Triflones and Vinyl Triflones. (1995) (0)
Syntheses via Vinyl Sulfones. Part 13. Stereoselective, Chemodirected Formal SN2′ Addition of Organometallic Reagents to β′‐Amino Cyclopentenyl Sulfone Derivatives. (1986) (0)
Synthesis of Fluorinated Dienylic Stannanes via the Wadsworth-Emmons Reaction. (1990) (0)
TRANS-1-BUTADIENYLTRIPHENYLPHOSPHONIUM BROMIDE, A REAGENT FOR THE 1,3-CYCLOHEXADIENYLATION OF CARBONYL GROUPS (1975) (0)
Cephalostatin Chemistry. Part 8. Synthesis of a C14′,15′ Dihydro Derivative of the South Hexacyclic Steroid Unit of Cephalostatin 1. Part 2. Spiroketal Synthesis and Stereochemical Assignment by NMR Spectroscopy. (2010) (0)
Syntheses via Vinyl Sulfones. Part 70. Triflone Chemistry. Part 9. Alkynylation of Aldehydic C-H Bonds via Reaction with Acetylenic Triflones. (2010) (0)
Syntheses via Vinyl Sulfones. Part 47. Regiospecific Silver(I)- Promoted, Palladium(0)-Catalyzed Intramolecular Addition of Aryl Iodides to Vinyl Sulfones. (1993) (0)
Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety (2009) (0)
BRUCEANTIN SUPPORT STUDIES. 7. TORSIONAL EFFECTS IN THE BAEYER-VILLIGER OXIDATION (1984) (0)
Efficient (4+1) Syntheses of Highly Functionalized Cyclopentenes. (1987) (0)
Cephalostatin Synthesis. Part 15. Synthesis of the South Unit of Cephalostatin. Part 7. Total Syntheses of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K. (1999) (0)
Synthesis and Pharmacological Evaluation of Vinyl Sulfone Based Anticancer Agents. (1995) (0)
An Efficient Method for Conversion of Carboxylic Acid Derivatives to Allylsilanes. (1988) (0)
Syntheses via Vinyl Sulfones. Part 48. Comparison of Vinyl Organolithium and Organopalladium Reagents for Intramolecular Conjugate Addition to Vinyl Sulfones. (1993) (0)
Synthesis of Tertiary Alcohols via the Use of the Allyldimethylsilyl Moiety as a Latent Hydroxyl Group in the Kumada‐Fleming‐Tamao Reaction. (1992) (0)
Citric Acid Mediated Catalytic Osmylation/Oxidative Cleavage of Electron Deficient Olefins: A Vinyl Sulfone Study. (2015) (0)
Synthesis via Vinyl Sulfones. Part 21. Total Synthesis of d,l-Morphine. (1987) (0)
Cephalostatin Support Studies. Part 12. The First Synthesis of the Aglycone of the Potent Antitumor Steroidal Saponin OSW-1. (2010) (0)

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What Schools Are Affiliated With Philip L. Fuchs?

Philip L. Fuchs is affiliated with the following schools:

University of East Anglia
Purdue University