Philip Power
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American chemist
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Chemistry
Philip Power's Degrees
- PhD Chemistry Stanford University
- Masters Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is Philip Power Influential?
(Suggest an Edit or Addition)According to Wikipedia, Philip Patrick Power is a Distinguished Professor of Chemistry at the University of California, Davis. He has contributed to the synthesis, structure, and physical and chemical characterization of inorganic and organometallic compounds. His research focuses on low-coordinate main group and transition metal compounds. Much of this work hinges on the use of sterically crowded ligands to stabilize unusual geometries.
Philip Power's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Synthesis and Characterization of (2001) (1666)
- Main-group elements as transition metals (2010) (919)
- π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements (1999) (765)
- Pi-bonding and the lone pair effect in multiple bonds involving heavier main group elements: developments in the new millennium. (2010) (738)
- Slow magnetization dynamics in a series of two-coordinate iron(II) complexes (2013) (404)
- Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers (2005) (395)
- Persistent and stable radicals of the heavier main group elements and related species. (2003) (350)
- Facile activation of dihydrogen by an unsaturated heavier main group compound. (2005) (327)
- A quantum chemical study of the quintuple bond between two chromium centers in [PhCrCrPh]: trans-bent versus linear geometry. (2006) (260)
- The chemistry of boron and its speciation in plants (1997) (257)
- Synthesis and Characterization of 2,6-Trip2H3C6PbPbC6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3): A Stable Heavier Group 14 Element Analogue of an Alkyne (2000) (252)
- London dispersion forces in sterically crowded inorganic and organometallic molecules (2017) (216)
- Interaction of multiple bonded and unsaturated heavier main group compounds with hydrogen, ammonia, olefins, and related molecules. (2011) (208)
- Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue (2000) (204)
- Multiple bonding in heavier element compounds stabilized by bulky terphenyl ligands. (2007) (203)
- Synthesis and characterization of a digermanium analogue of an alkyne. (2002) (202)
- Synthesis and Characterization of the Monomeric Diaryls M{C6H3-2,6-Mes2}2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me3C6H2−) and Dimeric Aryl−Metal Chlorides [M(Cl){C6H3-2,6-Mes2}]2 (M = Ge or Sn) (1997) (200)
- Synthesis and Characterization of 2,6-Dipp2-H3C6SnSnC6H3-2,6-Dipp2 (Dipp = C6H3-2,6-Pri2): A Tin Analogue of an Alkyne (2002) (199)
- Bonding and Reactivity of Heavier Group 14 Element Alkyne Analogues (2007) (198)
- Homologous Series of Heavier Element Dipnictenes 2,6-Ar2H3C6E=EC6H3-2,6-Ar2 (E = P, As, Sb, Bi; Ar = Mes = C6H2-2,4,6-Me3; or Trip = C6H2-2,4,6-iPr3) Stabilized by m-Terphenyl Ligands (1999) (186)
- Stable two-coordinate, open-shell (d1-d9) transition metal complexes. (2012) (183)
- Reaction of hydrogen or ammonia with unsaturated germanium or tin molecules under ambient conditions: oxidative addition versus arene elimination. (2009) (177)
- Structures, bonding, and reaction chemistry of the neutral organogallium(I) compounds (GaAr)n(n = 1 or 2) (Ar = terphenyl or related ligand): an experimental investigation of Ga-Ga multiple bonding. (2003) (173)
- Germanium and tin analogues of alkynes and their reduction products. (2003) (169)
- Diarylstannylene activation of hydrogen or ammonia with arene elimination. (2008) (162)
- Silicon, germanium, tin and lead analogues of acetylenes. (2003) (148)
- Subvalent Group 4B metal alkyls and amides. Part 5. The synthesis and physical properties of thermally stable amides of germanium(II), tin(II), and lead(II) (1977) (148)
- Synthesis and Structures of Monomeric Divalent Germanium and Tin Compounds Containing a Bulky Diketiminato Ligand (2001) (145)
- Metallocalixarenes: syntheses and x-ray crystal structures of titanium(IV), iron(III), and cobalt(II) complexes of p-tert-butylcalix[4]arene (1985) (144)
- Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions (2009) (142)
- Homonuclear multiple bonding in heavier main group elements (1998) (140)
- Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si (2003) (140)
- Three-coordinate iron complexes: x-ray structural characterization of the iron amide-bridged dimers [Fe(NR2)2]2 (R = SiMe3, C6H5) and the adduct Fe[N(SiMe3)2]2(THF) and determination of the association energy of the monomer Fe{N(SiMe3)2}2 in solution (1991) (138)
- Reactions of the heavier group 14 element alkyne analogues Ar'EEAr' (Ar' = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with unsaturated molecules: probing the character of the EE multiple bonds. (2005) (136)
- Isolation and Reduction of Sterically Encumbered Arylboron Dihalides: Novel Boranediyl Insertion into C−C σ-Bonds (1996) (133)
- Boron-boron double bonding in the species [B2R4]2-: synthesis and structure of [{(Et2O)Li}2{Mes2BB(Mes)Ph}], a diborane(4) dianion analog of a substituted ethylene (1992) (132)
- Isolation of a stable, acyclic, two-coordinate silylene. (2012) (128)
- Isolation and x-ray crystal structure of the boron methylidenide ion [Mes2BCH2]- (Mes = 2,4,6-Me3C6H2): a boron-carbon double bonded alkene analog (1987) (128)
- Synthesis and characterization of the non-kekulé, singlet biradicaloid Ar'Ge(μ-NSiMe3)2GeAr' (ar' = 2,6-Dipp2C6H3, Dipp = 2,6-i-Pr2C6H3) (2004) (124)
- Isolation and structural characterization of unsolvated lithium aryls (1993) (123)
- Metal Amide Chemistry (2009) (123)
- Reduction of a Tetraaryldialane to Generate Al-Al π-Bonding (1993) (122)
- Synthesis and structure of the "dialuminyne" Na(2)[Ar'AlAlAr'] and Na(2)[(Ar''Al)3]: Al--Al bonding in Al2Na2 and Al3Na2 clusters. (2006) (121)
- Substituent effects in formally quintuple-bonded ArCrCrAr compounds (Ar = terphenyl) and related species. (2007) (120)
- Synthesis and structural characterisation of the first neutral homoleptic lanthanide metal(III) alkyls: [LnR3][Ln = La or Sm, R = CH(SiMe3)2] (1988) (119)
- Reactions of trimethylaluminum or trimethylgallium with bulky primary amines: structural characterization of the thermolysis products (1991) (117)
- Some highlights from the development and use of bulky monodentate ligands (2004) (116)
- Synthesis and characterization of the homologous M-M bonded series Ar'MMAr' (M = Zn, Cd, or Hg; Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) and related arylmetal halides and hydride species. (2007) (116)
- (η5-C5H5)(CO)2MoGeC6H3-2,6-Mes2: A Transition-Metal Germylyne Complex (1996) (113)
- Addition of H2 to distannynes under ambient conditions. (2008) (113)
- Isolation and crystal structures of the halide-free and halide-rich phenyllithium etherate complexes [(PhLi.Et2O)4] and [(PhLi.Et2O)3.LiBr] (1983) (109)
- A zinc-zinc-bonded compound and its derivatives bridged by one or two hydrogen atoms: a new type of Zn-Zn bonding. (2006) (109)
- First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul. (1986) (108)
- Triple Bonding to Germanium: Characterization of the Transition Metal Germylynes (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Mes2 (M = Mo, W; Mes = −C6H2-2,4,6-Me3) and (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Trip2 (M = Cr, Mo, W; Trip = −C6H2-2,4,6-i-Pr3) and the Related Single Bonded Metallogermylenes (η5-C5H5)(CO)3M-G̈e-C6H (2000) (105)
- The synthesis and structure of lithium derivatives of the sterically encumbered β-diketiminate ligand [{(2,6-Pri2H3C6)N(CH3)C}2CH]−, and a modified synthesis of the aminoimine precursor (2001) (104)
- One‐Electron Reductions of Organodiborane(4) Compounds: Singly Reduced Anions and Rearrangement Reactions (2006) (102)
- Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25 degrees C and 1 atmosphere. (2009) (99)
- Three-coordinate metal amides of manganese(II) and cobalt(II): synthesis and x-ray structure of the first tris(silylamide) of manganese and the x-ray crystal structures of [M2(N(SiMe3)2)4] (M = Mn, Co) (1984) (98)
- Synthesis of Sterically Encumbered Terphenyls and Characterization of Their Metal Derivatives Et2OLiC6H3-2,6-Trip2 and Me2SCuC6H3-2,6-Trip2 (Trip = 2,4,6-i-Pr3C6H2-) (1996) (96)
- Tl2[Aryl2P4]: a thallium complexed diaryltetraphosphabutadienediide and its two-electron oxidation to a diaryltetraphosphabicyclobutane, aryl2p4. (2005) (96)
- The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C6H3- 2,6-Dipp2; Dipp = C6H3-2,6-Pri2), with Toluene (2003) (95)
- Spontaneous generation of stable pnictinyl radicals from "jack-in-the-box" dipnictines: a solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization. (2001) (94)
- Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers (2010) (93)
- Isolation and x-ray crystal structures of the mononuclear cuprates [CuMe2]-, [CuPh2]-, and [Cu(Br)CH(SiMe3)2]- (1985) (92)
- Monomeric InC6H3-2,6-Trip2 (Trip = -C6H2-2,4,6-i-Pr3) and Its Manganese Complex (η5-C5H5)(CO)2MnInC6H3-2,6-Trip2: One-Coordinate Indium in the Solid State (1998) (92)
- Molecular structures of the main group 4 metal(II) bis(trimethylsilyl)-amides M[N(SiMe3)2]2 in the crystal (X-ray) and vapour (gas-phase electron diffraction) (1983) (92)
- Reduction of a Boron–Nitrogen 1,3‐Butadiene Analogue: Evidence for a Strong B ? B π‐Bond (1992) (91)
- Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character (1993) (91)
- Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN)2 }MN-2,6-Trip2 C6 H3 ] (M=Al or Ga; Dipp=2,6-iPr2 C6 H3 ; Trip=2,4,6-iPr3 C6 H2 ). (2001) (88)
- [2,6-Trip2H3C6Sn(μ-H)]2 (Trip = C6H2-2,4,6-i-Pr3): Synthesis and Structure of a Divalent Group 14 Element Hydride (2000) (87)
- Synthesis and Structure of a Unique Monomeric σ‐Bonded Aryllithium Compound Stabilized by a Weak Li—Benzene π Interaction (1996) (85)
- Complexes of Ni(i): a "rare" oxidation state of growing importance. (2017) (84)
- Isomeric forms of heavier main group hydrides: experimental and theoretical studies of the [Sn(Ar)H]2 (Ar = terphenyl) system. (2007) (83)
- Reactivity of Ar'GeGeAr' (Ar' = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) toward alkynes: isolation of a stable digermacyclobutadiene. (2004) (82)
- Element Derivatives of Sterically Encumbering Terphenyl Ligands (1999) (82)
- Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box (2000) (81)
- Synthesis and characterization of HC[C(Me)N(C(6)H(3)-2,6-i-Pr(2))](2)MX(2) (M = Al, X = Cl, I; M = Ga, In, X = Me, Cl, I): sterically encumbered beta-diketiminate group 13 metal derivatives. (2001) (80)
- Higher-nuclearity group 14 metalloid clusters: [Sn(9){Sn(NRR')}(6)]. (2006) (80)
- Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si-Pb) dichalcogenolate carbene analogues with sub-90° interligand bond angles. (2013) (79)
- Synthesis, (9)Be NMR Spectroscopy, and Structural Characterization of Sterically Encumbered Beryllium Compounds. (1997) (78)
- Dispersion force stabilized two-coordinate transition metal-amido complexes of the -N(SiMe3)Dipp (Dipp = C6H3-2,6-Pr(i)2) ligand: structural, spectroscopic, magnetic, and computational studies. (2013) (78)
- Bulky alkyls, amides, and aryloxides of main Group 5 elements. Part 1. Persistent phosphinyl and arsinyl radicals ·MRR′ and their chloroprecursors MRR′Cl and related compounds (1980) (78)
- Quasi-isomeric gallium amides and imides GaNR2 and RGaNR (R = organic group): reactions of the digallene, Ar'GaGaAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2) with unsaturated nitrogen compounds. (2006) (78)
- The isolation and x-ray structures of lithium crown ether salts of the free phenyl carbanions [CHPh2]- and [CPh3]- (1985) (77)
- Series of Two-Coordinate and Quasi-Two-Coordinate Transition-Metal Complexes: Synthesis, Structural, and Spectroscopic Studies of Sterically Demanding Borylamide Ligands -NRBR′2 (R: Ph, R′: Mes, Xyl; R = R′: Mes), Their Lithium Salts (1990) (77)
- The "diindene" ArInInAr (Ar = C(6)H(3)-2,6-Dipp(2), Dipp = C(6)H(3)-2,6-Pr(i)(2)). Dimeric versus monomeric in(I) aryls: para-substituent effects in terphenyl ligands. (2002) (77)
- Gallium-boron donor-acceptor bonds. (2001) (76)
- Isolation and x-ray crystal structures of the solvate complexes [Li(Et2O)benzyl]x and [Li(THF)2mesityl]2 (1985) (76)
- Isomeric Forms of Divalent Heavier Group 14 Element Hydrides: Characterization of Ar‘(H)GeGe(H)Ar‘ and Ar‘(H)2GeGeAr‘·PMe3 (Ar‘ = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) (2003) (76)
- Synthesis and Characterization of the Neutral “Digallene” Ar′GaGaAr′ and Its Reduction to Na2Ar′GaGaAr′ (Ar′=2,6‐Dipp2C6H3, Dipp=2,6‐iPr2C6H3) (2002) (75)
- Comparison of B–B π-bonding in singly reduced and neutral diborane (4) derivatives: isolation and structure of [{Li(Et2O)2}{MeO(mes)BB(mes)OMe}] (1996) (75)
- Synthesis and characterization of three-coordinate and related beta-diketiminate derivatives of manganese, iron, and cobalt. (2002) (74)
- Synthesis and characterization of bulky aryl derivatives of the heavier Main Group 3 elements (1993) (74)
- Isolation and first structural characterization of dimethyl sulfide solvates of phenyllithium, phenylcopper, and lower and higher order lithium phenylcuprate reagents (1990) (74)
- Synthesis and spectroscopic and x-ray structural studies of the mesitylphosphines Ph2Mes and PHMes2 (Mes = 2,4,6-Me3C6H2) and their lithium salts [Li(THF)3PHMes] and [{Li(OEt2)PMes2}2] (1987) (74)
- Synthesis and characterization of quasi-two-coordinate transition metal dithiolates M(SAr*)2 (M = Cr, Mn, Fe, Co, Ni, Zn; Ar* = C6H3-2,6(C6H2-2,4,6-Pri3)2. (2005) (73)
- Ab initio quantum chemistry calculations on the electronic structure of heavier alkyne congeners: diradical character and reactivity. (2006) (73)
- Direct spectroscopic observation of large quenching of first-order orbital angular momentum with bending in monomeric, two-coordinate Fe(II) primary amido complexes and the profound magnetic effects of the absence of Jahn- and Renner-Teller distortions in rigorously linear coordination. (2009) (72)
- Synthesis and characterization of thiolato complexes with two-coordinate iron(II) (1994) (72)
- Synthesis and Characterization of the Monomeric Terphenyl−Metal Halides Ge(Cl){C6H3-2,6-Trip2} (Trip = C6H2-2,4,6-i-Pr3) and Sn(I){C6H3-2,6-Trip2} and the Terphenyl−Metal Amide Sn{N(SiMe3)2}{C6H3-2,6-Trip2}† (1998) (72)
- Synthesis and spectroscopic and X-ray structural characterization and dynamic solution behavior of the neutral cobalt(II) alkoxides [Co{OC(C6H11)3}2]2•CH3OH•1/2C6H12•THF, [Co(OCPh3)2]2•n-C6H14, [Co(OSiPh3)2(THF)]2, and Co(OCPh3)2(THF)2 (1987) (71)
- Nature of the boron-phosphorus bond in monomeric phosphinoboranes and related compounds (1991) (70)
- Synthesis of the Square‐Planar Gallium Species K2[Ga4(C6H3‐2,6‐Trip2)2] (Trip=C6H2‐2,4,6‐iPr3): The Role of Aryl–Alkali Metal Ion Interactions in the Structure of Gallium Clusters (2000) (70)
- The use of very crowded silylamide ligands -N(SiMenPh3−n)2 (n=0, 1, or 2) to synthesize crystalline, two-coordinate derivatives of Mn(II), Fe(II), and Co(II) and the free ion [Ph3SiNSiPh3]− (1989) (69)
- Boron‐Phosphorus Compounds and Multiple Bonding (1990) (69)
- Synthesis and Structure of [MeAlN(2,6‐iPr2C6H3)]3: An Aluminum‐Nitrogen Analogue of Borazine (1988) (69)
- Structural and spectroscopic characterization of the compounds [Al(NMe2)3]2, [Ga(NMe2)3]2, [(Me2N)2Al{μ-N(H)1-Ad}]2 (1-Ad = 1-adamantanyl) and [{Me(μ-NPh2)Al}2NPh(μ-C6H4)] (1990) (68)
- The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide. (2005) (68)
- Reactions of (H2AlMes*)2 (Mes* = 2,4,6-(t-Bu)3C6H2) with H2EAr (E = N, P, or As; Ar = aryl): Characterization of the Ring Compounds (Mes*AlNPh)2 and (Mes*AlEPh)3 (E = P or As) (1996) (68)
- Reactions between primary amines and magnesium or zinc dialkyls: intermediates in metal imide formation (1996) (67)
- Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes (1995) (66)
- Structural characterization of the solvate complexes of the lithium diorganophosphides [{Li(Et2O)PPh2}.infin.], [{Li(THF)2PPh2}.infin.], and [{Li(THF)P(C6H11)2}.infin.] (1986) (65)
- Large differences in secondary metal-arene interactions in the transition-metal dimers ArMMAr (Ar = terphenyl; M = Cr, Fe, or Co): implications for Cr-Cr quintuple bonding. (2008) (65)
- Synthesis and characterization of novel quasiaromatic zinc-sulfur aggregates and related zinc-oxygen complexes (1991) (65)
- X-ray crystal structures of the diphenylphosphide and -arsenide anions: use of a crown ether to effect complete metal cation and organometalloid anion separation (1984) (64)
- Synthesis and characterization of the monomeric imides Ar'MNAr' ' (M = Ga or In; Ar' or Ar' ' = terphenyl ligands) with two-coordinate gallium and indium. (2003) (64)
- Donor-Free Alkali Metal Thiolates: Synthesis and Structure of Dimeric, Trimeric, and Tetrameric Complexes with Sterically Encumbered Terphenyl Substituents. (1996) (64)
- Room-temperature reaction of carbon monoxide with a stable diarylgermylene. (2009) (64)
- Free inorganic, organic, and organometallic ions by treatment of their lithium salts with 12-crown-4 (1988) (64)
- The Neutral Transition Metal Thiolates [M(SAr)2]2 (M Mn, Fe or Co, Ar 2,4,6‐t‐Bu3C6H2) (1991) (64)
- Synthesis and Characterization of the .sigma.-Bonded, Quasi-Linear, Metal(II) Diaryls MMes2 (M = Mg, Mn, Fe; Mes = 2,4,6-tert-Bu3C6H2-) (1995) (64)
- Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide. (2009) (63)
- Synthesis and reactivity of dimeric Ar'TlTlAr' and trimeric (Ar"T1)3 (Ar', Ar" = bulky terphenyl group) thallium(I) derivatives: Tl(I)-Tl(I) bonding in species ligated by monodentate ligands. (2005) (63)
- Convergent syntheses of [Sn7{C6H3-2,6-(C6H3-2,6-iPr2)2}21: a cluster with a rare pentagonal bipyramidal motif. (2007) (62)
- X-ray crystal structure of the boron-stabilized carbanion [Li(12-crown-4)2][CH2C6H2(3,5-Me2)(4-B{2,4,6-Me3C6H2}2)].cntdot.Et2O: evidence for boron ylide character (1986) (62)
- Synthesis, structural, and magnetic characterization of linear and bent geometry cobalt(II) and nickel(II) amido complexes: evidence of very large spin-orbit coupling effects in rigorously linear coordinated Co2+. (2012) (62)
- Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules. (2012) (61)
- Synthesis, structure, and magnetic and electrochemical properties of quasi-linear and linear iron(I), cobalt(I), and nickel(I) amido complexes. (2014) (61)
- Isolation and structural characterization of the solvated lithium salts of the main group 5 anions [EPh2]− (E = N, P, As, or Sb) and [Sb3Ph4]− (1986) (61)
- Synthesis and some reactivity studies of germanium, tin and lead analogues of alkynes (2005) (61)
- Two types of intramolecular addition of an Al-N multiple-bonded monomer LAlNAr' arising from the reaction of LAl with N3Ar' (L = HC[(CMe)(NAr)]2, Ar' = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3). (2004) (61)
- Reversible complexation of ethylene by a silylene under ambient conditions. (2014) (60)
- Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores (1980) (59)
- Subvalent group 14 metal compounds XIV. The X-ray crystal structures of two monomeric group 14 metal bisamides, Ge[N(SiMe3)2]2 and Sn[Me2]2 (1992) (59)
- Synthesis and Characterization of [Sn2{C6H3-2,6(2,4,6-i-Pr3C6H2)2}2]-•: A Singly Reduced Valence Isomer of a “Distannyne”† (1997) (59)
- Reactions of Ar'CrCrAr' with N2O or N3(1-Ad): complete cleavage of the Cr-Cr quintuple interaction. (2009) (58)
- Synthesis and characterization of the homoleptic aryloxides [M{O(2,4,6-tert-Bu3C6H2)}2]2 (M = manganese, iron), the adducts [Mn(OCPh3)2(py)2] and [Fe(OCPh3)2(THF)2], and the mixed complex [Fe{N(SiMe3)2}{.mu.-O(2,4,6-tert-Bu3C6H2)}]2: evidence for primarily ionic metal-oxygen bonding (1991) (58)
- An unsymmetric oxo/imido-bridged germanium-centered singlet diradicaloid. (2009) (57)
- Sterically encumbered terphenyl substituted primary pnictanes ArEH2 and their metallated derivatives ArE(H)Li (Ar=C6H3-2,6-Trip2; Trip=2,4,6-triisopropylphenyl; E=N, P, As, Sb) (2000) (57)
- Boron-phosphorus analogs of benzene and cyclobutadiene. Synthesis and characterization of the boraphosphabenzenes (RBPR')3 (R = Mes, Ph; R' = Ph, Mes, C6H11, tert-Bu) and the diphosphadiboretane (thexylBPMes)2 (1989) (56)
- Synthesis, characterization and real molecule DFT calculations for neutral organogallium(I) aryl dimers and monomers: weakness of gallium-gallium bonds in digallenes and digallynes. (2009) (56)
- Synthesis and Characterization of Sterically Encumbered Derivatives of Aluminum Hydrides and Halides: Assessment of Steric Properties of Bulky Terphenyl Ligands. (1996) (56)
- Reduction of Ge(Cl)C6H3mes2-2,6 togive the cyclotrigermenyl radical(GeC6H3mes2-2,6)3· andthe trigermenyl anion saltK(GeC6H3mes2-2,6)3 (1997) (55)
- The structure of a monomeric phosphinoborane: synthesis and x-ray crystal structure of (diphenylphosphino)dimesitylborane (1986) (55)
- Two-coordinate, nonlinear, crystalline d6 and d7 complexes: syntheses and structures of M{N(SiMePh2)2}2, M = Fe or Co (1987) (55)
- A stable aluminacyclopropene LAl(eta2-C2H2) and its end-on azide insertion to an aluminaazacyclobutene. (2005) (55)
- Reaction of a sterically encumbered iron(I) aryl/arene with organoazides: formation of an iron(V) bis(imide). (2008) (54)
- C-H activation of cycloalkenes by dimetallynes (M = Ge, Sn) under ambient conditions. (2011) (54)
- Subvalent group 4B metal alkyls and amides. Part 7. Transition-metal chemistry of metal(II) bis(trimethylsilyl)amides M′(NR2)2(R = SiMe3; M′= Ge, Sn, or Pb) (1985) (54)
- Synthesis, Structures, and Spectroscopy of the Metallostannylenes (η5-C5H5)(CO)3M−S̈n−C6H3-2,6-Ar2 (M = Cr, Mo, W; Ar = C6H2-2,4,6-Me3, C6H2-2,4,6-Pri3) (2002) (53)
- Synthesis and Solid-State Structure of 2,6-Trip2 C6 H3 Tl (Trip=2,4,6-iPr3 C6 H2 ): A Monomeric Arylthallium(I) Compound with a Singly Coordinated Thallium Atom. (1998) (53)
- Very large changes in bond length and bond angle in a heavy group 14 element alkyne analogue by modification of a remote ligand substituent. (2006) (53)
- Multiple Bonding Involving the Heavier Main Group 3 Elements Al, Ga, In, and Tl (1996) (53)
- Isolation and X-ray crystal structures of the organolithium etherate complexes, [Li(Et2O)2(CPh3)] and [{Li(Et2O)(2,4,6-(CHMe2)3C6H2)}2] (1988) (52)
- First examples of three-coordinate manganese(III) and cobalt(III): synthesis and characterization of the complexes M[N(SiMe3)2]3 (M = Mn or Co) (1989) (51)
- Synthesis and Characterization of a Quasi‐One‐Coordinate Lead Cation (2004) (51)
- Use of NMR Spectroscopy in the Synthesis and Characterization of Air- and Water-Stable Silicon Nanoparticles from Porous Silicon (2005) (51)
- Synthesis and characterization of the metal(I) dimers [Ar'MMAr']: comparisons with quintuple-bonded [Ar'CrCrAr']. (2008) (51)
- Room temperature synthesis of surface-functionalised boron nanoparticles. (2007) (51)
- Subvalent group 14 metal compounds XI. Oxidative addition reactions of organic halides or acid anhydrides (including CH4 − nCln, PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to some bivalent group 14 metal amides or alkyls (1987) (50)
- The Syntheses and Characterization of the Bulky Terphenyl Silanes and Chlorosilanes 2,6-Mes2C6H3SiCl3, 2,6-Trip2C6H3SiCl3, 2,6-Mes2C6H3SiHCl2, 2,6-Trip2C6H3SiHCl2, 2,6-Mes2C6H3SiH3, 2,6-Trip2C6H3SiH3 and 2,6-Mes2C6H3SiCl2SiCl3 (1998) (50)
- Cleavage of the Sn-Sn multiple bond in a distannyne by cyclooctatetraene: formation of the pi-bound inverse sandwich complex [(Ar'Sn)2(mu2-eta2:eta3-cot)]. (2010) (50)
- Terphenyl Ligand Stabilized Lead(II) Derivatives of Simple Organic Groups: Characterization of Pb(R)C6H3-2,6-Trip2 (R = Me, t-Bu, or Ph; Trip = C6H2-2,4,6-i-Pr3), {Pb(μ-Br)C6H3-2,6-Trip2}2, py·Pb(Br)C6H3-2,6-Trip2 (py = Pyridine), and the Bridged Plumbylyne Complex [{W(CO)4}2(μ-Br)(μ-PbC6H3-2,6-Trip (2000) (50)
- A germanium isocyanide complex featuring (n → π*) back-bonding and its conversion to a hydride/cyanide product via C-H bond activation under mild conditions. (2012) (50)
- Synthesis and characterization of compounds with boron-boron double bonds (1992) (50)
- Lewis base induced tuning of the Ge-Ge bond order in a "digermyne". (2007) (50)
- The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects (2015) (49)
- Synthesis, spectroscopic characterization, and determination of the solution association energy of the dimer [Co{N(SiMe3)2}2]2: magnetic studies of low-coordinate Co(II) silylamides [Co{N(SiMe3)2}2L] (L = PMe3, pyridine, and THF) and related species that reveal evidence of very large zero-field spli (2013) (49)
- Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2) (1987) (49)
- Synthesis and structural and spectroscopic characterization of the germanazene [GeN(2,6-i-Pr2C6H3)]3 and the tin and lead tetramers [SnN(BMes2)]4, [SnN(2,6-i-Pr2C6H3)]4, and [PbN(2,6-i-Pr2C6H3)]4 (1991) (48)
- Synthesis and characterization of the monomeric aluminum monoamides (tert-Bu) 2AlN(R)R' (R and R' = bulky aryl, alkyl, or silyl groups) (1993) (48)
- New Base-Free Alanes and Gallanes: Synthesis and Characterization of Monomeric Mes*2GaH (Mes* = 2,4,6-tert-Bu3C6H2), Dimeric (Trip2MH)2 (Trip = 2,4,6-i-Pr3C6H2; M = Al, Ga), and Related Sterically Crowded Arylaluminum Species (1994) (48)
- Synthesis and characterization of neutral, homo and heteronuclear clusters with unsubstituted germanium or tin atoms. (2003) (47)
- Syntheses and x-ray structures of the lithium, nickel, and cobalt complexes [Li(THF)4][Ni(NPh2)3].0.5C7H8, [{Ni(NPh2)2}2] and [{Co(NPh2)2}2]: structural characterization of three coordinate first row d7 and d8 complexes (1985) (47)
- Formation of [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne. (2002) (47)
- The X-ray crystal structures of the mononuclear silyllithium species Li(THF)3SiPh3 and Li(THF)3Si(SiMe3)3 (1993) (47)
- Stable, two-coordinate, open skell (d0-d9) transition metal complexes (1989) (46)
- π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium (2010) (46)
- Synthesis and Characterization of the New Selenolate Ligand -SeC6H3-2, 6-Mes2 (Mes = C6H2-2, 4, 6-Me3) and Its Two-Coordinate Zinc and Manganese Derivatives: Factors Affecting Bending in Two-Coordinate Metal Complexes with Aryl-Substituted Ligands (1995) (46)
- Structural characterization of the iron-bridged "double-cubane" cluster complexes [Mo2Fe7S8(SC2H5)12]3- and [M2Fe7S8(SCH2C6H5)12]4- (M = molybdenum, tungsten) containing MFe3S4 cores (1980) (46)
- Synthesis, structural characterization, and spectroscopy of the cadmium-cadmium bonded molecular species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2). (2006) (46)
- Structural studies of tin(II) and lead(II) dimethylamides: x-ray crystal structure of [Sn(NMe2)2]2 and isolation of its lead analog (1984) (46)
- Synthesis and characterization of the mononuclear compounds tert-Bu2MOAr (M = aluminum or gallium, Ar = bulky aryl group): are the short Al-O and Ga-O bonds a consequence of .pi.-interactions? (1991) (46)
- Synthesis and structural characterization of the beryllium compounds [Be(2,4,6-Me3C6H2)2(OEt2)], [Be{O(2,4,6-tert-Bu3C6H2)}2(OEt2)], and [Be{S(2,4,6-tert-Bu3C6H2)}2(THF)].cntdot.PhMe and determination of the structure of [BeCl2(OEt2)2] (1993) (46)
- Isolation and x-ray crystal structure of the cuprate complex decaethoxydichlorotetralithium bis(hexaphenyldilithiumtricuprate) ([Li2Cu3Ph6]2[Li4Cl2(Et2O)10]): the first x-ray structural characterization of an anionic organocopper-lithium cluster (1984) (46)
- Synthesis, Structure, and Spectroscopic Characterization of Unassociated Mono-, Di and Triamido Derivatives of Aluminum and Gallium (1994) (45)
- Spin-state crossover with structural changes in a cobalt(II) organometallic species: low-coordinate, first row, heteroleptic amido transition metal aryls. Synthesis and characterization of Ar'MN(H)Ar# (M = Mn, Fe, Co) (Ar' = C6H3-2,6-(C6H3-2,6-iPr2)2, Ar# = C6H3-2,6-(C6H2-2,4,6-Me3)2). (2009) (45)
- Imide Transfer Properties and Reactions of the Magnesium Imide ((THF)MgNPh)(6): A Versatile Synthetic Reagent. (1996) (45)
- Recent developments in the chemistry of low valent Group 14 hydrides. (2008) (45)
- The role of group 14 element hydrides in the activation of C-H bonds in cyclic olefins. (2012) (45)
- Reversible, photoinduced activation of P₄ by low-coordinate main group compounds. (2014) (45)
- Recycle of tin thiolate compounds relevant to ammonia-borane regeneration. (2010) (45)
- Synthesis and electron spin resonance study of stable dialkyls and diamides of phosphorus and arsenic, R12M· and (R22N)2M· (1976) (45)
- Characterization of Ge5R4 (R = CH(SiMe3)2, C6H3-2,6-Mes2): Germanium Clusters of a New Structural Type with Singlet Biradical Character (2004) (45)
- Stabilized Terphenyl-Substituted Digermene Derivatives of Simple Organic Groups and Their Halide Precursors: Preference for Symmetrically Bonded Structures (2001) (44)
- Synthesis and structural characterization of manganese(II) derivatives of the bulky, chelating bis(amido) ligands [(NMes)2SiMe2]2- and [DippNCH2CH2NDipp]2-, their neutral amine precursors, and their lithium salts (Mes = 2,4,6-Me3C6H2; Dipp = 2,6-i-Pr2C6H3) (1991) (44)
- Ligand substitution properties of the MFe3S4 double-cubane cluster complexes [Mo2Fe6S8(SR)9]3- and [M2Fe7S8(SR)12]3- (M = molybdenum, tungsten) (1982) (43)
- Terphenyl ligand stabilized lead(II) derivatives: steric effects and lead-lead bonding in diplumbenes. (2004) (43)
- Synthesis and structure of diarylboryl-substituted hydrazines and diphosphanes: role of .sigma.-oribital hybridization and .pi.-orbital overlap in N-N and P-P multiple-bond lengths (1991) (43)
- Two-coordinate first row transition metal complexes with short unsupported metal-metal bonds. (2010) (43)
- Monomeric, two-coordinate, univalent chromium(I) compounds: steric prevention of metal-metal bond formation. (2007) (43)
- Synthesis and characterization of the phosphinidene borate complexes [Li(Et2O)2PRB(Mes)2] and [Li(12-crown-4)2][RPB(Mes)2].cntdot.THF [R = Ph, C6H11 or Mes (Mes = 2,4,6-Me3C6H2)]: the first structurally characterized boron-phosphorus double bonds (1986) (42)
- Synthesis and X‐Ray Structure of (2,4,6‐Me3C6H2BPC6H11)3: A Boron‐Phosphorus Analogue of Borazine (1987) (42)
- Dimeric gallium oxide and sulfide species stabilized by a sterically encumbered beta-diketiminate ligand. (2001) (42)
- Synthesis and Characterization of [Sn8(2,6-Mes2C6H3)4] (Mes=2,4,6-Me3C6H2): A Main Group Metal Cluster with a Unique Structure (2001) (42)
- Mononuclear cobalt(II) complexes having alkoxide and amide ligands: synthesis and x-ray crystal structures of [Co(Cl)(OC-tert-Bu3)2.Li(THF)3], [Li(THF)4.5][Co{N(SiMe3)2}(OC-tert-Bu3)2], and [Li{Co(N(SiMe3)2)(OC-tert-Bu3)2}] (1986) (42)
- Synthesis and Characterization of the Very Bulky Phenols Ar*OH and Ar′OH (Ar* = C6H3‐2,6‐Trip2, Trip = C6H2‐2,4,6‐iPr3; Ar′ = C6H3‐2,6‐Dipp2, Dipp = C6H3‐2,6‐iPr2) and Their Lithium and Sodium Derivatives (LiOAr′)2 and (NaOAr*)2 (2003) (42)
- Theoretical studies of multiple bonds in gallium–gallium and germanium–germanium compounds (2000) (42)
- Synthesis and Characterization of Na2{Ge(C6H3-2,6-Trip2)}2 and K2{Sn(C6H3-2,6-Trip2)}2 (Trip = -C6H2-2,4,6-i-Pr3): A New Class of Multiply Bonded Main Group Compounds (1998) (41)
- Solid-state and high-resolution liquid 119Sn NMR spectroscopy of some monomeric, two-coordinate low-valent tin compounds: very large chemical shift anisotropies. (2000) (41)
- Simple one-step route to a transition-metal complex containing a phosphorus-phosphorus double bond. Synthesis and x-ray crystal structure of {trans-bis[bis(trimethylsilyl)methyl]diphosphene}bis[tetracarbonyliron(0)] (1983) (41)
- Reaction of M(II) Diaryls (M = Mn or Fe) with Ammonia to Afford Parent Amido Complexes (2010) (41)
- An unusual carbon-carbon bond cleavage in bulky metal alkoxides: syntheses and x-ray crystal structures of three-coordinate manganese(II) and chromium(II) complexes containing the di-tert-butylmethoxide ligand (1985) (41)
- A NEW SYNTHETIC ROUTE TO ORGANOALUMOXANES (RALO)N : SYNTHESIS OF (MES*ALO)4 (MES* = -C6H2-2,4,6-T-BU3) AND ITS REACTIONS WITH ALR3 (R = ME OR ET) (1997) (41)
- Univalent transition metal complexes of arenes stabilized by a bulky terphenyl ligand: differences in the stability of Cr(I), Mn(I) or Fe(I) complexes. (2008) (40)
- Unsymmetric dipnictenes—synthesis and characterization of MesPEC6H3-2,6-Trip2 (E = As or Sb; Mes = C6H2-2,4,6-Me3, Trip = C6H2-2,4,6-Pri3) (1998) (40)
- Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Application to Metal–Metal Bonded Compounds (2010) (40)
- Silylamines with Pyramidal Coordination at Nitrogen (1993) (40)
- Synthesis and Characterization of the Monomeric Sterically Encumbered Diaryls E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge, Sn, or Pb)† (2006) (40)
- Synthesis and Characterization of the Metalloplumbylenes (η5-C5H5)(CO)3M-P̈b-C6H3-2,6-Trip2 (M = Cr, Mo, or W; Trip = −C6H2-2,4,6-i-Pr3) (2000) (40)
- Interaction of phosphorous bis(trimethylsilyl)amide dichloride with carbonylmetalate dianions of iron and chromium: syntheses and x-ray crystal structures of new transition metal complexes involving phosphorus and arsenic in multiple bonding (1983) (39)
- The synthesis and structure of sterically encumbered terphenyl tin(II) halide derivatives: simultaneous existence of monomers and dimers in the crystalline phase (2001) (39)
- Neutral catecholate derivatives of manganese and iron: synthesis and characterization of the metal-oxygen cubane-like species M4(DBCat)4(py)6 (M = Mn, Fe), the trinuclear complex Mn3(DBCat)4(py)4, and the dimers M2(DBCat)2(py)n (M = Mn, n = 6; M = Fe, n = 4,6) (1992) (39)
- Mechanisms of reactions of open-shell, heavier group 14 derivatives with small molecules: n-π* back-bonding in isocyanide complexes, C-H activation under ambient conditions, CO coupling, and ancillary molecular interactions. (2013) (39)
- Heavier Main Group Dimetallene Reactivity: Effects of Frontier Orbital Symmetry (2013) (39)
- Characterization of the sterically encumbered terphenyl-substituted species 2,6-Trip2H3C6Sn-Sn(Me)2C6H3-2,6-Trip2, an unsymmetric, group 14 element, methylmethylene, valence isomer of an alkene, its related lithium derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the monomer Sn(t-Bu)C6H (2000) (39)
- Activation of gaseous PH3 with low coordinate diaryltetrylene compounds. (2014) (39)
- Reversible and irreversible higher-order cycloaddition reactions of polyolefins with a multiple-bonded heavier group 13 alkene analogue: contrasting the behavior of systems with π-π, π-π*, and π-n+ frontier molecular orbital symmetry. (2012) (39)
- New copper chemistry. 21. Phenylcopper(I) and diphenylcuprate(I): characterization of aggregation states by carbon-13 NMR spectroscopy (1993) (39)
- Syntheses and X-ray crystal structures of lithium and chromium(II) complexes of the tri-t-butylmethoxide ligand (1983) (38)
- A New In4 Cluster with Short InIn Bonds in Trigonal-Planar In(InTrip2)3† (1996) (38)
- Boron-pnictogen multiple bonds: donor-stabilized P=B and As=B bonds and a hindered iminoborane with a B-N triple bond. (2007) (38)
- Synthesis and characterization of the isoelectronic d10 species bis[bis(methyldiphenylsilyl)amido]cuprate(1-) and -zinc (1991) (38)
- Transition metal alkylgallyl complexes: synthesis, structure, and spectroscopic studies of (.eta.5-C5H5)(CO)2FeGa(tert-Bu)2, {(.eta.5-C5H5)(CO)2Fe}2Ga(tert-Bu), and (.eta.5-C5H5)(CO)2FeGa(tert-Bu)2.{(.eta.5-C5H5)(CO)2Fe}2 (1994) (37)
- (2,6‐Mes2H3C6)2BiH, a Stable, Molecular Hydride of a Main Group Element of the Sixth Period, and Its Conversion to the Dibismuthene (2,6‐Mes2H3C6)BiBi(2,6‐Mes2C6H3) (2000) (37)
- Isolation and Structural Characterization of the Lithium Cyanoorganocuprate Salt [Li(THF)2{Cu(CN)C6H3-2,6-Trip2}]2 (Trip = −C6H2-2,4,6-i-Pr3) (1998) (37)
- Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2OEt2: from digallene to digallacyclohexadiene to digallatabenzene. (2009) (37)
- Synthesis and x-ray structural characterization of the metal borylamide complexes Li(Et2O)2NPhBMes2, (THF)(Et2O)2LiClCo{NPhBMes2}2, and Mn{NMesBMes2}2.cntdot.3PhMe (Mes = 2,4,6-Me3C6H2): modified amide ligands with poor bridging and .pi.-donor characteristics (1987) (37)
- A donor-stabilization strategy for the preparation of compounds featuring P=B and As=B double bonds. (2006) (36)
- Different reactivity of the heavier group 14 element alkyne analogues Ar'MMAr' (M = Ge, Sn; Ar' = C6H3-2,6(C6H3-2,6-Pri2)2) with R2NO. (2005) (36)
- The synthesis, characterization and some properties of new quasi-aromatic main group ring systems (1990) (36)
- Monomeric manganese(II) alkoxides: syntheses and x-ray crystal structures of novel three- and four-coordinate manganese complexes of the tri-tert-butylmethoxide ligand (1984) (36)
- Dispersion Forces, Disproportionation, and Stable High-Valent Late Transition Metal Alkyls. (2016) (36)
- Synthesis of [Me2SCu(C6H2-2,4,6-tert-Bu3)] and [(Me2S)2Cu(.mu.-C6H2-2,4,6-Ph3)Cu(C6H2-2,4,6-Ph3)]: mononuclear and dinuclear organocopper(I) species of formula [CuR.cntdot.solvate]1 or 2 (1992) (36)
- Synthesis and x-ray structural characterization of Mg(2,4,6-R3C6H2)2(THF)2 (R = Me, iso-Pr) and the three-coordinate magnesiate species [Li(THF)0.6(Et2O)0.4][Mg(2,4,6-iso-Pr3C6H2)3] (1992) (36)
- Synthesis and Structure of the Magnesium Imide [(thf)MgNPh]6† (1994) (36)
- Synthesis and structural characterization of the cyclic species [GeN(2,6-iso-Pr2C6H3)]3: the first "germanazene" (1990) (36)
- A reversible valence equilibrium in a heavier main group compound. (2003) (35)
- Synthesis and characterization of the monomeric gallium monoamides t-Bu2GaN(R)SiPh3 (R = t-Bu, 1-adamantyl), Trip2MN(H)Dipp (M = Al, Ga; Trip = 2,4,6-i-Pr3C6H2; Dipp = 2,6-i-Pr2C6H3), and Trip2GaNPh2 (1993) (35)
- [M(NMesBMes2)2] (M = Cr, Ni) : Stable, Distorted, Two-Coordinate d4 and d8 Complexes† (1989) (35)
- In8(C6H3-2,6-Mes2)4 (Mes=C6H2-2,4,6-Me3): A Metal-Rich Main-Group Cluster with a Distorted Cubane Structure (2000) (35)
- Unusual electrocyclic rearrangements with group 14 element compounds: reversible isomerization of a π-aromatic digermyl complex with carbon-carbon and germanium-germanium multiple bond cleavage. (2011) (35)
- Synthesis and x-ray crystal structure of the first transition-metal cluster involving framework phosphorus-phosphorus double bonds (1984) (35)
- Synthesis and spectroscopic and structural characterization of the novel lithium borylamide salts trans-[Li(Et2O)NHBMes2]2, a dimer, and the ion pair [Li(Et2O)3][Mes2BNBMes2] with a linear allene-like, [R2B = N = BR2]+ moiety (1988) (35)
- Synthesis and characterization of low-coordinate divalent aryl transition-metal halide analogues of grignard reagents: precursors for reduction to metal-metal-bonded complexes. (2007) (35)
- Crystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide (1986) (35)
- Enhanced thermal stability in organodiborane(4) compounds: synthesis and structural characterization of MeO(Mes)BB(Mes)OMe, Mes2BB(Mes)OMe, Mes2BB(Mes)Ph, and Mes2BB(Mes)CH2SiMe3 (Mes = 2,4,6-Me3C6H2) (1992) (35)
- Thermally controlling the singlet–triplet energy gap of a diradical in the solid state (2016) (35)
- Synthesis, Characterization, and CO Elimination of Ferrio-Substituted Two-Coordinate Germylenes and Stannylenes (2011) (34)
- Synthesis and Characterization of New Thiolato Derivatives of Lithium, Magnesium, and Zinc: Examples of Two-Coordinate Lithium and Zinc Species Ligated by Sulfur (1994) (34)
- Metal-rich, neutral and cationic organotin clusters. (2005) (34)
- Facile, High-Yield Functionalization of Germanium and Tin by Oxidative Insertion of Tetrelenes into the E–H Bonds of Inorganic Acids (E = C, N, O, F): Arene Elimination versus Oxidative Addition and Formation of a Germanium Cation–Water Complex (2013) (34)
- Reversible complexation of isocyanides by the distannyne Ar'SnSnAr' (Ar' = C(6)H(3)-2,6(C(6)H(3)-2,6-(i)Pr(2))(2)). (2010) (33)
- Monomeric bivalent group 4B metal dialkylamides M[NCMe2(CH2)3CMe2]2(M = Ge or Sn), and the structure of a gaseous disilylamide, Sn[N(SiMe3)2]2, by gas electron diffraction (1979) (33)
- Influence of Ligand Modifications on Structural and Spectroscopic Properties in Terphenyl Based Heavier Group 14 Carbene Homologues (2015) (33)
- Nature of bonding in group 13 dimetallenes: a delicate balance between singlet diradical character and closed shell interactions. (2010) (33)
- Synthesis and structural characterization of a series of dimeric metal(II) imido complexes {M(mu-NAr(#))}2 [M = Ge, Sn, Pb; Ar(#) = C6H3-2,6-(C6H2-2,4,6-Me3)2] and the related monomeric primary amido derivatives M{N(H)Ar(#)}2 (M = Ge, Sn, Pb): spectroscopic manifestations of secondary metal-ligand i (2010) (33)
- Structural Characterization of the "Magnesylamine" [(Et2O)Mg(Cl){N(SiMe3)2}]2 and the Two-Coordinate Magnesium Amide Mg{N(SiMePh2)2}2 (1994) (33)
- Synthesis and Spectroscopic and X-ray Structural Characterization of Compounds Involving Boron-Phosphorus Multiple Bonds: Lithium Salts of Boryl Phosphides and Their Precursors (1989) (33)
- Addition of ethylene or hydrogen to a main-group metal cluster under mild conditions. (2015) (33)
- Molecular structure of bis[bis(trimethylsilyl)amino]zinc as determined by gas electron diffraction (1984) (33)
- Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex. (2010) (33)
- Synthesis and structural characterization of magnesium and cobalt derivatives of the bulky aryl ligand −C6H3-2,6-Mes2 (1996) (32)
- Nature of M–E Bonds in Metallosilylenes, -germylenes, -stannylenes, and -plumbylenes [(η5-C5H5)(Me3P)(H)2M(EPh)] (M = Fe, Ru, Os; E = Si, Ge, Sn, Pb) (2011) (32)
- Counterintuitive mechanisms of the addition of hydrogen and simple olefins to heavy group 13 alkene analogues. (2013) (32)
- Synthesis and Structure of Stable Tri-tert-butylgermyl-Substituted Stannylene and Germylene (2001) (32)
- X-ray crystal structure of a late-transition-metal dialkylamide, [(CuNEt2)4] (1984) (31)
- An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects (2020) (31)
- Detailed Structural Characterization of the Polyvalent Iminoiodinanes ArINTs (Ar = C6H5 or 2,4,6-Me3C6H2; Ts = SO2C6H4-4-Me) and the Aryldichloroiodinane 2,4,6-i-Pr3C6H2ICl2 (1995) (31)
- New terphenylphenoxides of group 13 and 14 elements (2006) (31)
- Synthesis and x-ray crystal structure of [Li2Cu2(CH2SiMe3)4(SMe2)2].infin.: the first detailed structural characterization of a lithium dialkylcuprate aggregate (1990) (31)
- Synthesis and characterization of the neutral three-coordinate thiolate complexes Al[S(2,4,6-t-Bu3C6H2)]3 and Ga[S(2,4,6-t-Bu3C6H2)]3 (1991) (31)
- Synthesis and Characterization of [Mes*AlH2]2 (Mes* = 2,4,6-(tert-Bu)3C6H2): A Base-Free Arylalane (1994) (30)
- Dispersion Force Effects on the Dissociation of “Jack-in-the-Box” Diphosphanes and Diarsanes (2015) (30)
- Activation of olefins with low-valent gallium compounds under ambient conditions. (2011) (30)
- New Copper Chemistry. 22. Synthesis and Characterization of [Cu3Ph2(PMDTA)2]+: A Cationic Organocopper(I) Species (1994) (30)
- The structure of 1,2-diaryl-1,2-bis(dimethylamino)diboron compounds and related species: boron–nitrogen analogues of buta-1,3-dienes (1992) (30)
- (THFMgNPh)6 as an imide transfer agent: synthesis of titanium and zirconium imido complexes (1996) (30)
- Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor. (2002) (30)
- Structural characterization of a higher order cuprate: x-ray crystal structure of [Li3Cu2Ph5(SMe2)4] (1989) (30)
- Synthesis and structure of the neutral three-coordinate gallium selenolate Ga[Se(2,4,6-t-Bu3C6H2)]3 and the monomeric lithium selenolate Li(THF)3Se(2,4,6-t-Bu3C6H2) (1991) (29)
- Reaction of {HC(CMeNAr)2}Li (Ar=2,6-i-Pr2C6H3) with indium monochloride to yield the InIn bonded dimer [{HC(CMeNAr)2}InCl]2 and the hydroxide [{HC(CMeNAr)2}InCl(μ-OH)]2 (2002) (29)
- Mechanistic study of stepwise methylisocyanide coupling and C-H activation mediated by a low-valent main group molecule. (2013) (29)
- Reversible Coordination of H2 by a Distannyne. (2018) (29)
- Steric Enhancement of Group 12 Metal Hydride Stability and the Reaction of an Arylzinc Hydride with Tetramethylpiperidinyl Oxide (TEMPO) (2009) (29)
- An arene-stabilized cobalt(I) aryl: reactions with CO and NO. (2008) (29)
- Syntheses and x-ray crystal structures of the compounds [ArPAs]2 and [ArPSb]2 (Ar = 2,4,6-(tert-Bu)3C6H2. P2As2- and P2Sb2-substituted analogs of bicyclo[1.1.0]butane (1990) (29)
- Synthesis of nanocrystalline gallium nitride in silica aerogels (1996) (29)
- Reversible σ-dimerizations of persistent organic radical cations. (2013) (29)
- Synthesis and Characterization of the Organoiodocuprate Complexes [Li(THF)4][2,6-Mes2H3C6Cu2I2] (Mes = C6H2-2,4,6-Me3) and (Et2O)2Li{ICuC6H3-2,6-Trip2} (Trip = C6H2-2,4,6-i-Pr3) (1999) (29)
- Primary Alanes and Alanates: Useful Synthetic Reagents in Aluminum Chemistry (2000) (28)
- Comprar Metal Amide Chemistry | Michael Lappert | 9780470721841 | Wiley (2009) (28)
- Synthesis and Characterization of Ge(II), Sn(II), and Pb(II) Monoamides with -NH2 Ligands. (2005) (28)
- Reactions of Terphenylbismuth Dihalides with KSi(SiMe3)3, K2Si2(SiMe3)4 and Na2[Fe(CO)]4: Reduction vs. Metathesis (2008) (28)
- Thorium(IV) and Uranium(IV) Halide Complexes Supported by Bulky β-Diketiminate Ligands (2013) (28)
- Ready oxidative addition of an alkyl or aryl halide to a tin(II) alkyl or amide; evidence for a free-radical pathway (1976) (28)
- Synthesis of the sterically encumbering terphenyl silyl and alkyl amines HN(R)ArMes2HN(R)ArMes2 (R = Me and SiMe3), their lithium derivatives LiN(R)ArMes2LiN(R)ArMes2, and the tertiary amine Me2NArMes2Me2NArMes2 (2006) (28)
- Bonding and Reactivity of a β-Diketiminate, Gallium(I), Carbene Analogue (2002) (28)
- Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium (2001) (28)
- Synthesis and x-ray crystal structures of the mono- and binuclear arylmanganate complexes [{Li(Et2O)2}2Mn2Ph6], [Li(THF)4]2[Mn2Ph6], and [Li(THF)4][MnMes3] (1988) (27)
- Uncommon η3-(N,C,C‘)-1-Azaallyl Bonding Mode for the Nacnac Ligand: A Bis(β-diketiminato)uranium(III) Iodide Complex (2004) (27)
- Stable plumbylene dichalcogenolate monomers with large differences in their interligand angles and the synthesis and characterization of a monothiolato Pb(II) bromide and lithium trithiolato plumbate. (2013) (27)
- Synthesis and Structure of the Novel Ga3P3 Ring Compound [(2,4,6‐Ph3C6H2)GaP(cyclo‐C6H11)]3 (1991) (27)
- Linear and nonlinear two-coordinate vanadium complexes: synthesis, characterization, and magnetic properties of V(II) amides. (2013) (27)
- Co-ordination chemistry of bivalent Group 4B heavy metal donors M[N(SiMe3)2]2(M = Ge or Pb) or Ge[CH(SiMe3)2]2; and the crystal and molecular structure of [Cr(CO)5(Ge{CH(SiMe3)2}2)] (1977) (27)
- Synthesis and Characterization of Lewis Base-Free, σ-Bonded Lithium Aryls: A Structural Model for Unsolvated Phenyllithium in the Solid State (1997) (27)
- Isolation and X-ray crystal structure of a monomeric, σ-bonded aryllithium etherate complex [Li(Et2O)2-2,4,6-Ph3C6H2] (1991) (27)
- Unusual structures of lithium terphenyl derivatives (2002) (27)
- Reaction of the Primary Alane (2,4,6-t-Bu(3)H(2)C(6)AlH(2))(2) with Nitriles, Isonitriles, and Primary Amines. (1998) (26)
- Attempted Isolation of Heavier Group 14 Element Ketone Analogues: Effect of O−H···π-Ar Hydrogen Bonding on Geometry (2001) (26)
- Reaction of bulky monosubstituted phosphorus(III) halides with disodium tetracarbonylferrate. Steric and electronic factors in the synthesis of Fe(CO)4 complexes of diphosphene and phosphinidene ligands (1987) (26)
- Reactions of low-coordinate transition-metal amides with secondary phosphanes and arsanes: synthesis, structural, and spectroscopic studies of [M{N(SiMe3)2}(.mu.-PMes2)]2 (M = manganese, iron), [Mn{N(SiMe3)2}(.mu.-AsMes2)]2 and Mes2AsAsMes2 (1991) (26)
- Reaction of bulky monosubstituted phosphorus(III) halides with disodium pentacarbonylchromate. Steric and electronic factors in the synthesis of Cr(CO)5 complexes of diphosphenes, phosphinidenes, phosphanes, diphosphanes, and cyclopolyphosphanes (1987) (26)
- Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten) (1979) (26)
- Reactions of Alkenes and Alkynes with an Acyclic Silylene and Heavier Tetrylenes under Ambient Conditions (2014) (26)
- Synthesis and Structure of the Solvent-Free Sodium Aryl (NaC6H3-2,6-Mes2)2 (1997) (26)
- SYNTHESIS AND STRUCTURE OF UNASSOCIATED MONO-, DI-, AND THITHIOLATE DERIVATIVES OF ALUMINIUM AND GALLIUM : INVESTIGATION OF AL-S AND GA-S PI -BONDING (1995) (26)
- Synthesis and characterization of the monomeric three-coordinate indium thiolate and selenolate complexes In[E(2,4,6-t-Bu3C6H2)]3 (E=S,Se) (1993) (25)
- LOW-TEMPERATURE SYNTHESIS OF ALUMINUM SULFIDE AS THE SOLVATE AL4S6(NME3)4 IN HYDROCARBON SOLUTION (1997) (25)
- Structural characterization, infrared spectroscopy, and theoretical calculations for B(C6F5)3-stabilized benzene-ammonia and benzene-water complexes. (2011) (25)
- Reversible Sn-Sn Triple Bond Dissociation in a Distannyne: Support for Charge Shift Bonding Character. (2019) (25)
- Synthesis and Structure of [Et2OZn(SC6H2tBu3)2], the First T‐Shaped Zinc Complex (1990) (25)
- Syntheses and X-ray crystal structures of two new transition-metal complexes having diphosphene ligands in novel bonding modes (1983) (25)
- A monomeric thallium(I) amide in the solid state: synthesis and structure of TlN(Me)ArMes2 (ArMes2 = C6H3-2,6-Mes2). (2005) (25)
- Second-Order Jahn–Teller (SOJT) Structural Distortions in Multiply Bonded Higher Main Group Compounds (2018) (25)
- The Instability of Ni{N(SiMe3 )2 }2 : A Fifty Year Old Transition Metal Silylamide Mystery. (2015) (25)
- Methyl-Bridged Transition Metal Complexes (M = Cr−Fe) Supported by Bulky Terphenyl Ligands (2009) (24)
- New class of .sigma.-bonded aliphatic aza-macrocyclic complexes of transition metals: synthesis and x-ray crystal structures of nitrogen-bridged [(TiN4C12H24)2] and the oxo-bridged species [(N4C12H25)TiOTi(N4C12H25)] (1983) (24)
- Synthesis and Structures of Low-Valent Alkynyl Tin and Germanium Complexes Supported by Terphenyl Ligands: Heavier Group 14 Element Enediyne Analogues† (2010) (24)
- Mössbauer study of the three-coordinate planar Fe(II) thiolate complex [Fe(SR)(3)](-) (R = C(6)H(2)-2,4,6-tBu(3)): model for the trigonal iron sites of the MoFe(7)S(9):homocitrate cofactor of nitrogenase. (2002) (24)
- Dispersion-Force-Assisted Disproportionation: A Stable Two-Coordinate Copper(II) Complex. (2016) (24)
- Synthesis and characterization of some group 1 and 2 metal derivatives of the crowding terphenyl thiolate and selenolate ligands —EC6H3-2,6-Trip2 (ES or Se; Trip 2,4,6-i-Pr3C6H2−) (1997) (24)
- Reactions of Phenyllithium with the Stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-Pri3) and the Synthesis of the Distannylstannylene Sn(SnPh2Ar*)2: Contrasting Behavior in Methyl and Phenyl Derivatives (2003) (24)
- Reactions of M{N(SiMe3)2}2 (M=Mn, Fe or Co) with pyridine and 4,4′-bipyridyl: structural and magnetic studies (2003) (24)
- Synthesis of the sterically congested diarylphosphines ArTrip2P(Ph)H(ArTrip2=C6H3-2,6(C6H2-2,4,6-Pri3)) and ArMes2P(Ph)H(ArMes2=C6H3-2,6(C6H2-2,4,6-Me3)) and the monomeric Sn(II)-diphosphide [ArMes2P(Ph)]2Sn (2007) (24)
- Compounds with M3Se3 (M = Li, Zn) Rings: Synthesis and Characterization of [Zn(CH2SiMe3)Se-2,4,6-t-Bu3C6H2]3·0.5C6H14 and [Li(THF)Se-2,4,6-t-Bu3C6H2]3·PhMe (1993) (23)
- Terphenyl substituted derivatives of manganese(II): distorted geometries and resistance to elimination. (2010) (23)
- Mononuclear lithium amides using a crown ether: X- ray crystal structure of lithium bis(trimethylsilyl)amide·12-crown-4, [lin(sime3)2·12-crown-4] (1984) (23)
- Synthesis and characterization of the monomeric phosphinogallanes But2GaPR′R″(R′, R″= bulky aryl or silyl groups) and related compounds (1993) (23)
- New Routes to Synthetically Useful, Sterically Encumbered Arylaluminum Halides and Hydride Halides. (1996) (23)
- Synthesis and characterization of unassociated aluminum monophosphides (1994) (22)
- Synthesis and characterization of new, modified terphenyl ligands: Increasing the rotational barrier for flanking rings (2006) (22)
- Characterization of Ar'Sn(micro-Br)Sn(Ar')CH2C6H4-4-Pri (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2): a stable structural analogue for a heavier group 14 element monobridged alkene isomer HM(micro-H)MH2 (M = Sn or Pb). (2004) (22)
- Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible metal-carbon insertion equilibrium, and a new route to diplumbenes. (2015) (22)
- 1,4-Dilithio-1,2,3,4-tetraphenyl-butadiene - crystal structure of the 1,2-dimethoxyethane adduct (1994) (22)
- Solid-state 119Sn NMR and Mössbauer spectroscopy of "distannynes": evidence for large structural differences in the crystalline phase. (2006) (22)
- Synthesis and characterization of the monomeric digallylphosphine and digallylarsine derivatives MesP{Ga(Trip)2}2.cntdot.Et2O and PhAs{Ga(Trip)2}2 (1993) (22)
- Multiple Bonding Between Heavier Group 13 Elements (2002) (22)
- Synthesis, structure, and reactivity of a µ-bis(dialkylphosphido)-dilithium [Li(µ-PR2)]2[R = CH(SiMe3)2] (1984) (22)
- Synthesis and Structural Characterization of {LiN(SiMe3)2MMe3}.infin. (M = Al, Ga): Amido Ligands Isoelectronic to the Alkyl Group -C(SiMe3)3 (1995) (22)
- Isolation and x-ray crystal structures of the homoleptic, .sigma.-bonded transition-metal aryl complexes [(LiEt2O)4VPh6] and [(LiEt2O)3CrPh6] (1988) (22)
- Synthesis and spectroscopic and x-ray structural characterization of the first homoleptic transition-metal boryloxides [Mn(OBTrip2)(.mu.-OBTrip2)]2 and [Fe(OBMes2)(.mu.-OBMes2)]2 (1991) (22)
- A main-group donor-acceptor adduct: 1,3,4,5-tetramethylimidazol-2-ylidene-tris(pentafluorophenyl)borane. (2005) (22)
- Experimental and Computational Study of Auxiliary Molecular Effects on the Mechanism of the Addition of Hydrazines to a Low-Valent Germanium Complex (2012) (22)
- Two-coordinate, quasi-two-coordinate, and distorted three coordinate, T-shaped chromium(II) amido complexes: unusual effects of coordination geometry on the lowering of ground state magnetic moments. (2012) (21)
- Synthesis, structural, spectroscopic, and magnetic characterization of two-coordinate cobalt(II) aryloxides with bent or linear coordination. (2014) (21)
- Synthesis and characterization of the M(II) (M = Ge, Sn, or Pb) phosphinidene dimers {M(μ-PAr')}2 (Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2). (2010) (21)
- A nickel complex containing an extremely long nickel-phosphorus bond. Syntheses and x-ray structures of [Ni(CN)2[P(CH2OH)Ph2]3](C6H6)0.5 and trans-[Ni(CN)2[P(CH2-OH)Ph2]2] (1984) (21)
- Tethered Heavy Dicarbene Analogues: Synthesis and Structure of Ditetryldiyl Ethers (Ar′E)2(μ-O) (E = Ge, Sn; Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) (2011) (21)
- A silicon-nitrogen analog of the [PPN]+ cation: synthesis and structural characterization of the [Ph3SiNSiPh3]- ion (1987) (21)
- A boron-centered radical: a potassium-crown ether stabilized boryl radical anion. (2016) (21)
- Asymmetric bonding involving a phosphinidene complex. Synthesis and X-ray crystal structure of [{Fe(CO)3P(4-Me-2,6-t-Bu2C6H2O)}2], an organometallic cyclobutadiene analogue? (1986) (21)
- Syntheses and x-ray crystal structures of two new classes of macrocyclic ligands having both phosphorus and nitrogen donor atoms (1984) (21)
- Tri- and tetra-meric copper(I) amides {Cu[N(SiMePh2)2]}3 and {Cu[N(SiMe2Ph)2]}4 (1992) (21)
- Synthesis and spectroscopic and structural characterization of the monomeric diborylphosphine and diphosphinoborane compounds PhP(BMes2)2 and MesB(PPh2)2 (Mes=2,4,6-Me3C6H2) (1988) (21)
- Unusual bonding in the secondary aminophosphine [HP{N(SiMe3)2}2]2: X-ray structures and NMR and IR studies of the main group V amino compounds HE(NR2)2 (E = P, As, R = SiMe3; E = P, R = Ph) (1988) (20)
- Multiple bonding, π-bonding contributions and aromatic character in isoelectronic boron-phosphorus, boron-arsenic, aluminum-nitrogen and zinc-sulfur compounds (1991) (20)
- Comparison of pi-Bond Strengths in M-E (M = B, Al, Ga; E = O, N, S) Compounds. Ab Initio Calculation of Rotational Barriers. (1997) (20)
- The Monomeric Alanediyl :AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2): An Organoaluminum(I) Compound with a One-Coordinate Aluminum Atom. (2020) (20)
- Reversible Complexation of Lewis Bases to Low-Coordinate Fe(II), Co(II), and Ni(II) Amides: Influence of the Metal, Donor Ligand, and Amide Substituent on Binding Constants. (2017) (19)
- A compound with severely distorted geometry at ligated carbon: synthesis and x-ray crystal structure of Bi[CH(SiMe3)2]3, a trialkylbismuth complex with high thermal stability (1983) (19)
- Synthesis and Structure of Mes*AlN(Ph)Al(Mes*)N(Ph)NPh: A Formal Aluminum−Nitrogen Analog of the Cyclopentadienide Ion (1996) (19)
- Synthesis and structural characterization of a novel cluster with a Ga-P framework (1991) (19)
- Reactivity of Organogallium−Amine Adducts and Gallium Amides toward Some Nonhydrolytic Gel Precursor Mixtures (1996) (19)
- Dynamic Behavior and Isomerization Equilibria of Distannenes Synthesized by Tin Hydride/Olefin Insertions: Characterization of the Elusive Monohydrido Bridged Isomer. (2017) (19)
- Tin(II) Hydrides as Intermediates in Rearrangements of Tin(II) Alkyl Derivatives. (2017) (18)
- Terphenyl complexes of molybdenum and tungsten with quadruple metal-metal bonds and bridging carboxylate ligands. (2014) (18)
- Synthesis and characterization of two of the three isomers of a germanium-substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond. (2010) (18)
- Reversible Complexation of Alkynes by a Germylene (2019) (18)
- Syntheses, structures, and spectroscopic studies of several new classes of compounds having boron-arsenic bonds (1993) (18)
- Syntheses and x-ray crystal structures of highly dissociated rhodium(I) phosphine complexes using very bulky phosphine ligands (1984) (18)
- Multiple Ga-Ga Bonding Character in Na2 [Ga(GaTrip2 )3 ], and a Comparison with Neutral Ga(GaTrip2 )3 (Trip=2,4,6-iPr3 C6 H2 ). (1998) (18)
- Synthesis, structural investigation and thermal properties of a novel manganese complex Mn2(DAT)2Cl4(H2O)4 (DAT=1,5-diaminotetrazole). (2010) (18)
- Catalysis and solvent participation in organometallic oxidative additions (Pt0→PtII and SnII→SnIV) (1978) (17)
- Synthesis and x-ray structures of compounds having very short phosphorus-phosphorus single bonds: how much of the shortening in P-P double bonds is due to p-p .pi.-overlap? (1989) (17)
- Using liquid and solid state NMR and photoluminescence to study the synthesis and solubility properties of amine capped silicon nanoparticles. (2007) (17)
- Synthesis and characterization of the unstable primary amido tin(ii) dimer Sn(2){N(H)Dipp}(4) (Dipp = C(6)H(3)-2,6-Pr(i)(2)) and the first sesqui-amido hemi-chloride derivative Sn(2){N(H)Dipp}(3)Cl: facile conversion of a primary amide to the imide (SnNDipp)(4). (2008) (17)
- The first X-ray crystal structural characterizations of alkali metal alkyl thiolates: X-ray crystal structures of [Li2(thf)4{SCH(SiMe3)2}2] and [Li2(thf)3.5{SC(SiMe3)3}2](thf = tetrahydrofuran) (1985) (17)
- New route to organoaluminium sulfides: synthesis of (Mes*AlS)2 (Mes* = -C6H2But3-2,4,6) and its dimethyl sulfoxide adduct [Mes*AlS(OSMe2)]2 (1998) (17)
- Synthesis of the monomeric HBTrip2 (Trip=2,4,6-i-Pr3C6H2) and the X-ray crystal structures of [HBMes2]2 (Mes=2,4,6-Me3C6H2) and HBTrip2 (1990) (17)
- A ditetrylyne as a π-electron donor: synthesis and characterization of [AgAr'GeGeAr'](+)SbF6(-) and [Ag2Ar'GeGe(F)Ar'](+)SbF6(-) (Ar' = C6H3-2,6(C6H3-2,6-Pr(i)2)2). (2010) (17)
- Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites. (2012) (17)
- Molecular Zinc Species with Ge–Zn and Sn–Zn Bonds: A Reversible Insertion of a Stannylene into a Zinc–Carbon Bond (2016) (16)
- Reactions of m-Terphenyl-Stabilized Germylene and Stannylene with Water and Methanol: Oxidative Addition versus Arene Elimination and Different Reaction Pathways for Alkyl- and Aryl-Substituted Species (2015) (16)
- Isolation and x-ray crystal structure of the lithiated phosphoranide [Li(THF)cyclenP]x and the x-ray crystal and electron diffraction structures of cyclenPH (1988) (16)
- Tantalum(V) Phosphinidene Complexes as Phospha‐Wittig Reagents (1993) (16)
- Synthesis and structure of two lithium terphenyls and a “halide rich” terphenyl lithium species (2005) (16)
- Counterintuitive Interligand Angles in the Diaryls E{C6H3-2,6-(C6H2-2,4,6-iPr3)2}2 (E = Ge, Sn, or Pb) and Related Species: The Role of London Dispersion Forces (2018) (16)
- A closed paramagnetic electron-precise cluster (1988) (15)
- Synthesis and structural characterization of (THF)3Na{(SnC6H3–2,6-Trip2)2} (Trip=C6H2-2,4,6-i-Pr3): effects of cation–anion association on Sn–Sn multiple bonding (1999) (15)
- Facile C-H Bond Metathesis Mediated by a Stannylene. (2018) (15)
- Reactions of MCl5 (M = niobium or tantalum) with excess phenyllithium: structural characterization of bisbenzyne/polyphenyl derivatives of niobium and tantalum (1988) (15)
- Metathetical Exchange between Metal-Metal Triple Bonds. (2020) (15)
- Detection of a rotation barrier around a bond between heavier Main Group 3 and 5 elements (1992) (15)
- Access to Stable Metalloradical Cations with Unsupported and Isomeric Metal-Metal Hemi-Bonds. (2015) (15)
- Stable Two-Coordinate, Open-Shell (d1-d9) Transition Metal Complexes (2012) (15)
- A Compound with a Boron–Arsenic Double Bond (1990) (15)
- Syntheses and characterization of the gallium-phosphorus cages {(Et2O)2Li}{t-BuGa}{P(t-Bu)}2{Ga(t-Bu)2} and {(t-Bu)2Ga}{t-BuGa}{P(t-Bu)}2{Ga(t-Bu)2} (1993) (15)
- Computational Analysis of n→π* Back-Bonding in Metallylene–Isocyanide Complexes R2MCNR′ (M = Si, Ge, Sn; R = tBu, Ph; R′ = Me, tBu, Ph) (2013) (15)
- Structural and spectroscopic properties of the cobalt(II) 3,5-di-tert-butylcatecholate tetramer having a distorted Co4O4 cubane core (1988) (15)
- Synthesis and Structural Characterization of [{(Et2O)Mg}6(NPh)4Br4]: A Magnesium–Imide Cage Species Derived from a Dimagnesylamine Solution (1994) (14)
- Reduction of digermenes with alkali metals: salts of formula M2[[Ge(H)Ar']2] (m = Li, Na, Or K, Ar' = terphenyl) with three different structures. (2004) (14)
- N-H and N=C bond formation via germanium(III) diradicaloid intermediates and C-S bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) with azides. (2009) (14)
- Synthesis and characterization of the lithium organoargentate salts [Li(THF)4][Ag(Triph)2]·THF and [Li(THF)4][Ag(C6H3-2,6-Mes2)2]·1/8OEt2 (Triph=–C6H2-2,4,6-Ph3; Mes=C6H2-2,4,6-Me3) (1999) (14)
- Isolation and Computational Studies of a Series of Terphenyl Substituted Diplumbynes with Ligand Dependent Lead-Lead Multiple-Bonding Character. (2019) (14)
- Synchrotron-based Nickel Mössbauer Spectroscopy. (2016) (14)
- Transition Metal Acetylide Rearrangement and Coupling Induced by Coordinative Unsaturation (2009) (14)
- Reduction of terphenyl iron(II) or cobalt(II) halides in the presence of trimethylphosphine: an unusual triple dehydrogenation of an alkyl group. (2009) (14)
- Reaction of cyclopentadienyl zirconium derivatives with sterically encumbered arylaluminum hydrides: X-ray crystal structure of (η5-C5H5)2(H)Zr(μ2-H)2Al(H)C6H2-2,4,6-But3 (1999) (14)
- Salts of the two-coordinate homoleptic manganese(I) dialkyl anion [Mn{C(SiMe3)3}2](-) with quenched orbital magnetism. (2015) (14)
- Die neutralen Übergangsmetallthiolate [{M(SAr)2}2] (M = Mn, Fe, Co; Ar = 2,4,6-tBu3C6H2) (1991) (13)
- Do nonclassical silabenzene anions exist? Synthesis and crystal structure of crown ether-stabilized lithium silacyclohexadieneides, Li(12-crown-4)2Me2SiC5H5 and Li(12-crown-4)2-tert-Bu(H)SiC5H5 (1990) (13)
- Hydroalumination of Alkenes and Alkynes by Primary Aluminum Hydrides under Mild Conditions (2014) (13)
- Two-coordinate, homoleptic manganese(II) primary terphenyl amido complexes: the effects of secondary coordination on geometry and Lewis base complexation. (2009) (13)
- A primary monomeric alane: [N,N′-bis(2,6-diisopropylphenyl)pentane-2,4-diiminato-N,N′]dihydridoaluminium (2001) (13)
- The structures of organocuprates and heteroorganocuprates and related species in solution and in the solid state (2007) (13)
- Synthesis and characterization of the titanium bisamide Ti{N(H)Ar(iPr6)}2 (Ar(iPr6) = C6H3-2,6-(C6H2-2,4,6-(i)Pr3)2 and its TiCl{N(H)Ar(iPr6)}2 precursor: Ti(II) → Ti(IV) cyclization. (2013) (13)
- Synthese und Struktur des Ga3P3‐Ringsystems [2,4,6‐Ph3C6H2)GaP(cyclo‐C6H11)]3 (1991) (13)
- Monomeric Alanes: Synthesis, Structure, and Thermolysis of MesAl(H)N(SiMe(3))(2) and a One-Pot Synthetic Route to Mes(2)AlH (Mes = -C(6)H(2)-2,4,6-t-Bu(3)). (1998) (13)
- Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum-Copper and Gallium-Copper Bonds. (2020) (13)
- MOLECULAR STRUCTURE OF BIS(BIS(TRIMETHYLSILYL)AMINO)ZINC AS DETERMINED BY GAS ELECTRON DIFFRACTION (1984) (12)
- Reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] to form the unique methyl-bridged compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2] (1996) (12)
- Dichloro and alkylchloro gallium derivatives of dichalcogenoimidodiphosphinate ligands: isolation of a spirogallium cation. (2005) (12)
- Characterization of 2,6-Trip2H3C6GaCl2, {2,6-Trip2H3C6InCl(µ-Cl)}2 and {2,6-Trip2H3C6GaCl(µ-OH)}2 (Trip = 2,4,6-triisopropylphenyl) (1999) (12)
- Synthesis and Characterization of a Novel Energetic Complex [Cd(DAT)6](NO3)2 (DAT = 1,5‐diamino‐tetrazole) with High Nitrogen Content (2010) (12)
- Effects of the alkali metal counter ions on the germanium-germanium double bond length in a heavier group 14 element ethenide salt. (2004) (12)
- Synthesis, characterization, and magnetism of divalent aryl transition-metal complexes of the simplest dialkylamide, NMe(2): rare T-shaped coordination at chromium. (2009) (12)
- Measurement of extreme hyperfine fields in two-coordinate high-spin Fe2+ complexes by Mössbauer spectroscopy: essentially free-ion magnetism in the solid state. (2014) (12)
- Intramolecular C−H Activation by Putative Terminal Two-Coordinate Manganese(III) Imido Intermediates: Hydrogen Abstraction from a Phenyl Group (2010) (12)
- Addition of alkynes to digermynes: experimental insight into the reaction pathway. (2016) (12)
- New Characterization of V{N(SiMe3)2}3: Reductions of Tris[bis(trimethylsilyl)amido]vanadium(III) and -chromium(III) To Afford the Reduced Metal(II) Anions [M{N(SiMe3)2}3]- (M = V and Cr). (2019) (12)
- Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion. (2017) (12)
- Catalytic dehydrocoupling of amines and boranes by an incipient tin(ii) hydride. (2016) (12)
- Synthesis and Characterization of Primary Aluminum Parent Amides and Phosphides (2014) (12)
- Reduction of terphenyl Co(II) halide derivatives in the presence of arenes: insertion of Co(I) into a C-F bond. (2012) (11)
- STRUCTURAL STUDIES OF TIN(II) AND LEAD(II) DIMETHYLAMIDES: X-RAY CRYSTAL STRUCTURE OF (SN(NME2)2)2 AND ISOLATION OF ITS LEAD ANALOG (1984) (11)
- Facile insertion of ethylene into a group 14 element-carbon bond: effects of the HOMO-LUMO energy gap on reactivity. (2019) (11)
- Structure and bonding energy analysis of cationic metal-ylyne complexes of molybdenum and tungsten, [(MeCN)(PMe3)4M≡EMes]+ (M = Mo, W; E = Si, Ge, Sn, Pb): a theoretical study. (2011) (11)
- Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne. (2002) (11)
- Characterization of a Plumbylplumbylene: An Isomeric Form of a “Diplumbene” (2005) (11)
- Synthesis and characterization of the monomeric molybdenum trithiolate Mo(η7-dmpt)(η1-dmpt)2 (dmpt = 2,6-dimesitylphenylthiolate) (1998) (11)
- Models for Bonding in the Alkali Metal-Gallium Clusters K2Ga4(C6H3-2,6-Trip2)2 and Na2Ga4Trip6 (Trip=C6H2-2,4,6-i-Pr3): Importance of Alkali Metal-Aryl Interactions (2002) (11)
- X‐RAY CRYSTAL STRUCTURE OF A LATE‐TRANSITION‐METAL DIALKYLAMIDE, ((CUNET2)4) (1984) (11)
- Reactions of Terphenyl-Substituted Digallene AriPr4GaGaAriPr4 (AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with Transition Metal Carbonyls and Theoretical Investigation of the Mechanism of Addition (2016) (10)
- Synthesis and characterization of low valent vanadium thiolate complexes (2008) (10)
- Ligand field influence on the electronic and magnetic properties of quasi-linear two-coordinate iron(II) complexes. (2015) (10)
- Synthesis of a Cyclic Co2Sn2 Cluster Using a Co– Synthon (2018) (9)
- Synthesis and thermolytic behavior of tin(IV) formates: in search of recyclable metal-hydride systems. (2010) (9)
- Steric and Electronic Properties of the Bulky Terphenyl Ligand ArtBu6 (ArtBu6 = C6H3-2,6-(C6H2-2,4,6-tBu3)2) and Synthesis of Its Tin Derivatives ArtBu6SnCl, ArtBu6SnSn(H)2ArtBu6, and ArtBu6SnSnArtBu6: A New Route to a Distannyne via Thermolysis of the Asymmetric Hydride ArtBu6SnSn(H)2ArtBu6 (2018) (9)
- Interaction of the bulky alane (H2AlC6H3-2,6-Mes2)2 (Mes=–C6H3-2,4,6-Me3) with H2EPh (E=N, P or As) (1998) (9)
- Two-Coordinate, Late First-Row Transition Metal Amido Derivatives of the Bulky Ligand -N(SiPr i3)Dipp (Dipp = 2,6-diisopropylphenyl): Effects of the Ligand on the Stability of Two-Coordinate Copper(II) Complexes. (2019) (9)
- Effects of Remote Ligand Substituents on the Structures, Spectroscopic, and Magnetic Properties of Two-Coordinate Transition-Metal Thiolate Complexes. (2018) (9)
- A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization (2021) (9)
- The Reactions of Aryl Tin(II) Hydrides {AriPr6Sn(μ-H)}2 (AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2) and {AriPr4Sn(μ-H)}2 (AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with Aryl Alkynes: Substituent Dependent Structural Isomers (2017) (9)
- Synthesis of the Sterically Related Nickel Gallanediyl Complexes [Ni(CO)3(GaAr′)] (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) and [Ni(CO)3(GaL)] (L = HC[C(CH3)N(C6H3-2,6-iPr2)]2): Thermal Decomposition of [Ni(CO)3(GaAr′)] to give the Cluster [Ni4(CO)7(GaAr′)3] (2010) (9)
- Main group chemistry: A heavier-element ketone at last. (2012) (9)
- Synthesis and characterization of the unusual cluster [Ni2(GaAr′)2(η1:η1-μ2-C2H4)]: Ready addition of ethylene to Ni(COD)(GaAr′)2 at 25 °C and 1 atmosphere (2011) (9)
- SYNTHESES AND X-RAY CRYSTAL STRUCTURES OF TWO NEW TRANSITION METAL COMPLEXES HAVING DIPHOSPHENE LIGANDS IN NOVEL BONDING MODES (1984) (8)
- Cleavage of Ge–Ge and Sn–Sn Triple Bonds in Heavy Group 14 Element Alkyne Analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) by Reaction with Group 6 Carbonyls (2016) (8)
- Electron spin resonance of t-alkyl-, silyl-, and germyl-aminyl radicals and some observations on the amides MBr{N(SiMe3)2}3(M = Ge, Sn, or Pb) (1980) (8)
- Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared-Absorbing Dye to a Single-Molecule Magnet. (2017) (8)
- Reversible Binding of Ethylene and Propylene by Germylenes (2019) (7)
- Beyond Steric Crowding: Dispersion Energy Donor Effects in Large Hydrocarbon Ligands. (2022) (7)
- Bulky alkyls and amides of main group 5 elements II. Rotational barriers in phosphorus compounds containing bulky groups (1978) (7)
- Unexpected Coordination Complexes of the Metal Tris-silylamides M{N(SiMe3)2}3 (M = Ti, V). (2020) (7)
- Subvalent Amides of Silicon and the Group 14 Metals (2008) (7)
- Synthesis and molecular structures of the 1,2-dihalogen derivatives of Ga(II) and In(II), [{GaI(ArMe6)}2], [{InCl(ArMe6)}2]2, [{InI(ArMe6)}2]2, and [{In4Cl2I2(ArMe6)4}], ArMe6C6H3-2,6(C6H2-2,4,6-Me3)2 (2013) (7)
- Quasi-three-coordinate iron and cobalt terphenoxide complexes {Ar(iPr8)OM(μ-O)}2 (Ar(iPr8) = C6H-2,6-(C6H2-2,4,6-(i)Pr3)2-3,5-(i)Pr2; M = Fe or Co) with M(III)2(μ-O)2 core structures and the peroxide dimer of 2-oxepinoxy relevant to benzene oxidation. (2015) (7)
- Neutron diffraction analysis of the first stable hydride derivative of a divalent group-14 metal (2005) (7)
- Insertion of a Transient Tin Nitride into Carbon-Carbon and Boron-Carbon Bonds. (2017) (7)
- Synthesis and Structure of the Bis(amido)sodate Salt Na[Na{N(SiMe3)2AlMe3}2]: An Na+ Ion Complexed Solely by Na+- - -H3C− Interactions (1996) (7)
- Analysis of the bonding between two M(μ-NAr(#)) monomers in the dimeric metal(II) imido complexes {M(μ-NAr(#))}2 [M = Si, Ge, Sn, Pb; Ar(#) = C6H3-2,6-(C6H2-2,4,6-R3)2]. The stabilizing role played by R = Me and iPr. (2014) (7)
- Preface: forum on main-group chemistry from synthesis to applications. (2011) (7)
- Synthesis and isolation of two high-nuclearity managanese(II) imido compounds: structural characterization of a compound containing a [Mn6(µ3-NPh)4]4+ core (1996) (6)
- Synthesis and solid state structures of increasingly sterically crowded 1,4-diiodo-2,3,5,6-tetraarylbenzenes: a new series of bulky benzenes and aryls (2003) (6)
- Synthesis and characterization of a quasi-one-coordinate lead cation. (2004) (6)
- Synthesis and Structural Characterization of a Dimeric Cobalt(I) Homoleptic Alkyl and an Iron(II) Alkyl Halide Complex (2014) (6)
- Characterization of a Monomeric, Homoleptic, Solvent-Free Samarium Bis(aryloxide). (2018) (6)
- Two quasi-stable lead(ii) hydrides at ambient temperature. (2019) (6)
- Synthesis and reactions of novel boron-phosphorus compounds (1990) (6)
- Synthesis and structure of a tetranuclear copper(II) 3,5-di-tert-butylcatecholate pyridine complex, [Cu(DTBC)Py]4 · 2CH3CN (1988) (6)
- Synthesis and structural characterization of [PhE(BNMe2)2]2 (E = P or As): Six‐Membered P2B4 and As2B4 Rings with Unusual Structures (1995) (6)
- Bonding and metal-atom dynamics in two unique Sn(I)-Sn(III) complexes. (2005) (6)
- ipso-and para-Functionalization of meta-terphenyl ligands with substituted methyl groups: Unusual head-to-tail coupling of terphenyl moieties (2006) (6)
- Evidence for π bonding in the boron–thiolate compounds (2,4,6-Me3C6H2)2B(SPh) and (2,4,6-Pri3C6H2)B(SPh)2 (1994) (6)
- Two-Coordinate, Nonlinear Vanadium(II) and Chromium(II) Complexes of the Silylamide Ligand-N(SiMePh2)2: Characterization and Confirmation of Orbitally Quenched Magnetic Moments in Complexes with Sub-d5 Electron Configurations. (2021) (5)
- TERPHENYL LIGANDS AND COMPLEXES (2018) (5)
- Dalton communications. Synthesis and characterization of [Li(OEt2)3][Co2(SC6H2Pri3-2,4,6)5]: a compound with a face-sharing ditetrahedral structure (1993) (5)
- Synthesis and characterization of the organocopper–copper halide complex [CuMes*{Cu2Br2(SMe2)3}] (Mes* = C6H2But3-2,4,6) (1998) (5)
- Synthesis and characterization of sterically encumbered aluminum thiolato complexes with rare Al/S/halide structural motifs (2014) (5)
- Structural and Magnetic Studies of a Quasi-Inverse Sandwich Cyclooctatetraene Complex with Two High-Spin Chromium(II) Ions Bound Anti-Facially (2012) (5)
- Reactions of Low-Coordinate Transition-Metal Amides with Secondary Phosphanes and Arsanes: Synthesis, Structural, and Spectroscopic Studies of (M(N(SiMe3)2)(μ-PMes2))2 (M: Mn, Fe), (Mn(N(SiMe3)2)(μ -AsMes2))2, and Mes2AsAsMes2. (1991) (5)
- Synthesis and spectroscopic and structural characterization of PhB[P(Mes)BMes2]2 : a boron-phosphorus analogue of the pentadienyl cation (1992) (5)
- Isolation and First Structural Characterization of Dimethyl Sulfide Solvates of Phenyllithium, Phenylcopper, and Lower and Higher Order Lithium Phenylcuprate Reagents. (1991) (4)
- Characterization of the "Absent" Vanadium Oxo V(═O){N(SiMe3)2}3, Imido V(═NSiMe3){N(SiMe3)2}3, and Imido-Siloxy V(═NSiMe3)(OSiMe3){N(SiMe3)2}2 Complexes Derived from V{N(SiMe3)2}3 and Kinetic Study of the Spontaneous Conversion of the Oxo Complex into Its Imido-Siloxy Isomer. (2020) (4)
- Amides of the Group 3 and Lanthanide Metals (2008) (4)
- NEW CLASS OF Σ-BONDED ALIPHATIC AZA-MACROCYCLIC COMPLEXES OF TRANSITION METALS: SYNTHESIS AND X-RAY CRYSTAL STRUCTURES OF NITROGEN-BRIDGED ((TIN4C12H24)2) AND THE OXO-BRIDGED SPECIES ((N4C12H25)TIOTI(N4C12H25)) (1983) (4)
- ISOLATION AND X-RAY CRYSTAL STRUCTURE OF THE CUPRATE COMPLEX DECAETHOXYDICHLOROTETRALITHIUM BIS(HEXAPHENYLDILITHIUMTRICUPRATE) ((LI2CU3PH6)2(LI4CL2(ET2O)10)): THE FIRST X-RAY STRUCTURAL CHARACTERIZATION OF AN ANIONIC ORGANOCOPPER-LITH (1984) (4)
- Designing a Solution-Stable Distannene: The Decisive Role of London Dispersion Effects in the Structure and Properties of {Sn(C6H2-2,4,6-Cy3)2}2 (Cy = Cyclohexyl). (2021) (4)
- Germanium Hydride Radical Trapped during the Photolysis/Thermolysis of Diarylgermylene. (2019) (4)
- LIGAND SUBSTITUTION PROPERTIES OF THE MFE3S4 DOUBLE-CUBANE CLUSTER COMPLEXES (MO2FE6S8(SR)9)3- AND (M2FE7S8(SR)12)3- (M = MOLYBDENUM, TUNGSTEN) (1982) (4)
- Second order Jahn-Teller interactions at unusually high molecular orbital energy separations. (2020) (4)
- Boron‐Boron Double Bonding in the Species (B2R4)2‐: Synthesis and Structure of (((Et2O)Li)2(Mes2BB(Mes)Ph)), a Diborane(4) Dianion Analogue of a Substituted Ethylene. (1992) (4)
- Reactions of crowded secondary phosphines with (.eta.3-2-XC3H4)M(1,5-COD) (X = H or Me and M = Rh or Ir) (1984) (4)
- Structural Characterization of the Solvate Complexes of the Lithium Salts of Diorganophosphides and Phosphinideneborates; A Pathway to Phosphorus-Boron Double Bonds (1987) (4)
- Synthesis of some low oxidation state organotitanium compounds (1989) (4)
- A terphenyl halide series: 2,6‐Trip2H3C6X (Trip = 2,4,6‐triisopropylphenyl; X = Cl, Br, I) (2000) (4)
- Transition Metal Functionalization of P4 Using a Diarylgermylene Anchor. (2017) (4)
- The synthesis and characterization of the vanadium diphosphene complex trans-[{V(η5-C5H5)(CO)3}2(PMes)2] (1989) (4)
- Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species (2003) (4)
- Synthesis and Structural Characterization of the First Neutral Homoleptic Lanthanide Metal(III) Alkyls: (LnR3) (Ln = La or Sm, R = CH(SiMe3)2). (1989) (3)
- Titelbild: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. 26/2006) (2006) (3)
- Synthesis and characterization of the neutral "digallene" Ar'GaGaAr' and its reduction to Na(2)Ar'GaGaAr' (Ar'=2,6-Dipp(2)C(6)H(3), Dipp=2,6-iPr(2)C(6)H(3)). (2002) (3)
- Molecular Cages and Clusters of the Heavier Group 14 Elements (E = Si, Ge, Sn or Pb) of Formula EnRm (n ≥m) (2005) (3)
- DIVALENT MANGANESE, IRON, AND COBALT BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND THEIR TETRAHYDROFURAN COMPLEXES (2018) (3)
- Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)). (2003) (3)
- High-resolution electron microscopy and microanalysis of ordered arrays of size-controlled amorphous gallium nitride nanoparticles synthesized in situ in a block copolymer matrix (2002) (3)
- Michael Lappert (1928-2014). (2014) (2)
- Synthesis and x-ray crystal structure of a unique rhodium(I) phosphine complex: a novel intermolecular ring closure to produce a bidentate phosphorus alkyl bound ligand (1983) (2)
- Di- and Trivalent Trimethylsily1-Substituted Tin Amides and Related Compounds Such as Sn(N(SiMe3)2)2. (1977) (2)
- Structural Characterization and Coordination Behavior of 1,2-Diphosphino and 1,2-Diarsino-Diborane(4) Compounds (1996) (2)
- Boron-Phosphorus Analogues of Benzene and Cyclobutadiene. Synthesis and Characterization of the Boraphosphabenzenes (RBPR′)3 (R: Mes, Ph; R′: Ph, Mes, C6H11, tBu) and the Diphosphadiboretane (ThexylBPMes)2. (1989) (2)
- Richard Hadley Holm: A Remembrance and A Tribute (2021) (2)
- A Silicon-Nitrogen Analogue of the (PPN)+ Cation: Synthesis and Structural Characterization of the (Ph3SiNSiPh3)- Ion. (1988) (2)
- Synthesis and Characterization of the Monomeric Digallylphosphane and Digallylarsane Derivatives MesP(Ga(Trip)2)2×Et2O and PhAs(Ga( Trip)2)2. (1993) (2)
- Structural studies of the monomeric, low coordinate, indium amides (t-Bu)2InN(2,6-i-Pr2C6H3)SiPh3 and In{N(SiMe3)2}3 (1993) (2)
- Amides of the Transition Metals (2008) (2)
- Reaction of LiArMe6 (ArMe6 = C 6 H 3 -2,6-(C 6 H 2 -2,4,6-Me 3 ) 2 ) with indium(I)chloride yields three m -terphenyl stabilized mixed-valent organoindium subhalides (2016) (2)
- ISOLATION OF THE OPEN FORM OF CYCLENPHOSPHORANE BY DEPROTONATION AND REACTION WITH ELECTROPHILIC REAGENTS (1995) (2)
- A donor–acceptor adduct: sterically encumbered terphenyl dichloro[2,6-bis(2,4,6-triisopropylphenyl)phenyl]dichloro(pyridine)gallium benzene hemisolvate (2001) (2)
- Synthesis of the sterically congested diarylphosphines and and the monomeric Sn(II)-diphosphide [ArMes2P(Ph)]2Sn (2007) (2)
- A New Synthetic Route to Alkyl Terminated Silicon Nanoparticles. (2002) (2)
- Book Review: Organic Chemistry—in Color, and Good: The Chemistry of Inorganic Homo‐ and Heterocycles. Vol. 1 and 2. Edited by I. Haiduc and D. B. Sowerby (1988) (2)
- VI.B.4 DOE Chemical Hydrogen Storage Center of Excellence (2005) (2)
- The [2 + 4] Diels-Alder cycloadditon product of a probable dialuminene, Ar'AlAlAr' (Ar' = C(6)H(3)- 2,6-dipp(2); dipp = C(6)H(3)-2,6-Pr(i)(2)), with toluene. (2003) (2)
- Nature of the Boron‐Phosphorus Bond in Monomeric Phosphinoboranes and Related Compounds. (1992) (2)
- Reductions of M{N(SiMe3)2}3 (M = V, Cr, Fe): Terminal and Bridging Low-Valent First-Row Transition Metal Hydrido Complexes and "Metallo-Transamination". (2021) (2)
- Low-Coordinate Iron Chalcogenolates and Their Complexes with Diethyl Ether and Ammonia. (2021) (1)
- What IS Inorganic Chemistry? (2019) (1)
- pi-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements. (1999) (1)
- Dimeric Copper and Lithium Thiolates: Comparison of Copper Thiolates with Their Lithium Congeners. (2021) (1)
- THREE-COORDINATE METAL AMIDES OF MANGANESE(II) AND COBALT(II): SYNTHESIS AND X-RAY STRUCTURE OF THE FIRST TRIS(SILYLAMIDE) OF MANGANESE AND THE X-RAY CRYSTAL STRUCTURES OF (M2(N(SIME3)2)4) (M = MN, CO) (1985) (1)
- First Examples of Three-Coordinate Manganese(III) and Cobalt(III): Synthesis and Characterization of the Complexes M(N(SiMe3)2)3 (M: Mn or Co). (1990) (1)
- Synthesis, Structure, and Spectroscopic Characterization of Unassociated Mono-, Di and Triamido Derivatives of Aluminum and Gallium. [Erratum to document cited in CA121:83423] (1994) (1)
- Cover Picture: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. Int. Ed. 26/2006) (2006) (1)
- Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of (2001) (1)
- The Unusual Structural Behavior of Heteroleptic Aryl Copper(I) Thiolato Molecules: Cis vs Trans Structures and London Dispersion Effects (2022) (1)
- Inhibition of Alkali Metal Reduction of 1-Adamantanol by London Dispersion Effects. (2022) (1)
- Hydrides, Halides, and Polymers: Some Unexpected Intermediates on the Routes to First-Row Transition Metal M{N(SiMe3)2}n (n = 2, 3) Complexes. (2021) (1)
- Unusual coordination of tetrylenes to molybdenum carbonyl fragments. (2014) (1)
- Reusing meta-terphenyl ligands: synthesis, metalation and recycling of 5-pyrrolidino-m-terphenyl (2022) (1)
- Amides of the Group 13 Metals (2008) (1)
- SYNTHESES AND X‐RAY CRYSTAL STRUCTURES OF TWO NEW CLASSES OF MACROCYCLIC LIGANDS HAVING BOTH PHOSPHORUS AND NITROGEN DONOR ATOMS (1984) (1)
- Two‐Coordinate, Nonlinear, Crystalline d6 and d7 Complexes: Syntheses and Structures of M(N(SiMePh2)2)2, M: Fe or Co. (1988) (1)
- The synthesis and characterization of metal derivatives of the new, conveniently prepared, bulky thiolato ligand HSC6H2-2,4,6-Ph3 (1992) (1)
- Synthesis and X-Ray Structures of Compounds Having Very Short Phosphorus-Phosphorus Single Bonds: How Much of the Shortening in P-P Double Bonds is Due to p-p π-Overlap? (1989) (1)
- Cleavage of the SnSn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the p-Bound Inverse Sandwich (2010) (1)
- Synthesis and Structural Characterization of the Cyclic Species (GeN(2,6-i-Pr2C6H3))3: The First “Germanazene”. (1990) (1)
- Amides of the Group 15 Metals (As, Sb, Bi) (2008) (1)
- Isolation and Structural Characterization of Unsolvated Lithium Aryls. (1994) (1)
- Preface for the Advances in Main-Group Inorganic Chemistry Forum. (2017) (1)
- Synthesis and Structure of Diarylboryl-Substituted Hydrazines and Diphosphanes: Role of σ-Orbital Hybridization and π-Orbital Overlap in N-N and P-P Multiple-Bond Lengths. (1991) (1)
- Synthesis and Spectroscopic and X-Ray Structural Characterization of Compounds Involving Boron-Phosphorus Multiple Bonds: Lithium Salts of Boryl Phosphides and Their Precursors. (1989) (1)
- A COMPOUND WITH SEVERELY DISTORTED GEOMETRY AT LIGATED CARBON: SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF BI(CH(SIME3)2)3, A TRIALKYLBISMUTH COMPLEX WITH HIGH THERMAL STABILITY (1984) (0)
- Electronic Properties of Molybdenum-Iron-Sulfur-Clusters: Approaches to the Molybdenum Site in Nitrogenase (1980) (0)
- Chlorofunctional 1,3,5,2λ5,4λ5‐Triazadiphosphinines (2007) (0)
- Synthesis and Characterization of the Bulky Thiolate Complexes (Li(OEt2)3) (Ti(S-2,4,6-iPr3C6H2)4) and (Li(THF)3(S-2,4,6-tBu3C6H2)). Comparisons of M-SR and M-OR Bonding. (1987) (0)
- Synthesis and Structure of (MeAlN(2,6-iPr2C6H3))3: An Aluminum-Nitrogen Analogue of Borazole. (1989) (0)
- Synthesis and Structure of (Et2OZn(SC6H2tBu3)2), the First T‐Shaped Zinc Complex. (1991) (0)
- Synthesis and characterization of the non-Kekulé, singlet biradicaloid Ar'Ge(micro-NSiMe(3))(2)GeAr' (Ar' = 2,6-Dipp(2)C(6)H(3), Dipp = 2,6-i-Pr(2)C(6)H(3)). (2004) (0)
- Unsymmetric Dipnictenes — Synthesis and Characterization of MesP=EC6H3-2,6-Trip2 (E: As or Sb; Mes: C6H2-2,4,6-Me3, Trip: C6H2-2,4,6-Pr3i). (1999) (0)
- BULKY ALKYLS, AMIDES, AND ARYLOXIDES OF MAIN GROUP 5 ELEMENTS. PART 1. PERSISTENT PHOSPHINYL AND ARSINYL RADICALS ·MRR′ AND THEIR CHLORO PRECURSORS MRR′CL AND RELATED COMPOUNDS (1981) (0)
- Syntheses and X-Ray Crystal Structures of the Compounds (ArPAs)2 and (ArPSb)2 (Ar: 2,4,6-(tBu)3C6H2). P2As2- and P2Sb2-Substituted Analogues of Bicyclo(1.1.0)butane. (1990) (0)
- Structural Characterization and Coordination Behavior (1996) (0)
- Book Review: Multiple Bonds and Low Coordination in Phosphorus Chemistry. Edited by M. Regitz and O. J. Scherer (1991) (0)
- Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes (2020) (0)
- Erratum: Synthesis of the monomeric HBTrip2 (Trip = 2,4,6-i-Pr3C6H2) and the X-ray crystal structures of [HBMes2]2 (Mes = 2,4,6-Me3C6H2) and HBTrip2 (Organometallics (1990) 9, (146)) (1990) (0)
- Unusual Bonding in the Secondary Aminophosphine (HP(N(SiMe3)2)2)2: X-Ray Structures and NMR and IR Studies of the Main Group V Amino Compounds HE(NR2)2 (E = P, As, R = SiMe3; E = P, R = Ph). (1988) (0)
- The Synthesis, Characterization and Some Properties of New quasi‐ Aromatic Main Group Ring Systems (1991) (0)
- Structure of 1,4,7,10,13,16‐hexaazapentacyclo[11.5.1.14,10.07,20.016,19]icosane, C14H26N6 (1984) (0)
- Hydrostannylation of Olefins by a Hydridostannylene Tungsten Complex (2022) (0)
- Isolation and Structural Characterization of the Solvated Lithium Salts of the Main Group 5 Anions (EPh2)- (E: N, P, As, or Sb) and (Sb3Ph4)-. (1987) (0)
- Tantalum(V) Phosphinidene Complexes as Phospha-Wittig Reagents (1993) (0)
- Synthesis and Spectroscopic and X-Ray Structural Characterization and Dynamic Solution Behavior of the Neutral Cobalt(II) Alkoxides (Co(OC(C6H11)3)2)2·CH3OH·1/2C6H12·THF, (Co(OCPh3)2)2·n-C6H14, (Co(OSiPh3)2(THF))2, and Co(OCPh3)2(THF) (1987) (0)
- Silylamines with Pyramidal Coordination at the Nitrogen. (1993) (0)
- Stable Derivatives of New Isomeric Forms of Heavier Group 14 Element Alkene Analogues (2006) (0)
- Mononuclear Cobalt(II) Complexes Having Alkoxide and Amide Ligands: Synthesis and X‐Ray Crystal Structures of [Co(Cl)(OC‐tBu3)2·Li(THF)3], [Li(THF)4{Co(N(SiMe3)2)(OCBu3)2}], and [Li{Co(N(SiMe3)2)(OC‐tBu3)2}]. (1986) (0)
- Beryllium and the Alkaline Earth Metal Amides (2008) (0)
- The Structures of a Monomeric Lower-Order Lithium Organocyanocuprate and a Bulky Terphenyl Grignard Reagent in the Solid State (2020) (0)
- Isolation and X-Ray Crystal Structure of the Lithiated Phosphoranide (Li(THF)cyclenP)x and the X-Ray Crystal and Electron Diffraction Structures of cyclenPH. (1988) (0)
- Synthesis and Spectroscopic and Structural Characterization of the Monomeric Diborylphosphine and Diphosphinoborane Compounds PhP(BMes2)2 and MesB(PPh2)2 (Mes: 2,4,6-Me3C6H2). (1989) (0)
- Disproportionation of Sn(II){CH(SiMe3)2}2 to ·Sn(III){CH(SiMe3)2}3 and ·Sn(I){CH(SiMe3)2}: Characterization of the Sn(I) Product (2023) (0)
- Silicon, Germanium, Tin and Lead Analogues of Acetylenes (2004) (0)
- Compounds Containing Boron‐Phosphorus Multiple Bonds (1990) (0)
- Synthesis and Structure of the Neutral Three-Coordinate Gallium Selenolate Ga(Se(2,4,6-tert-Bu3C6H2))3 (II) and the Monomeric Lithium Selenolate Li(THF)3Se(2,4,6-tert-Bu3C6H2) (V). (1992) (0)
- Structural Characterization of a Higher Order Cuprate: X-Ray Crystal Structure of (Li3Cu2Ph5(SMe2)4). (1989) (0)
- CCDC 845708: Experimental Crystal Structure Determination (2011) (0)
- CCDC 606922: Experimental Crystal Structure Determination (2006) (0)
- Subvalent Group 14 Metal Compounds. Part 11. Oxidative Addition Reactions of Organic Halides or Acid Anhydrides (Including CH4-nCln, PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to Some Bivalent Group 14 Metal Amides or Alkyls. (1988) (0)
- Structural and Spectroscopic Properties of the Cobalt(II) 3,5-Di-tert-butylcatecholate Tetramer Having a Distorted Co4O4 Cubane Core. (1988) (0)
- Crystal and Molecular Structure of Chloramine-T Trihydrate. Absence of a Sodium-Nitrogen Interaction in the Oxidant N-Chloro-N-sodiotoluene-p-sulfonamide (1987) (0)
- Synthesis and Characterization of the Monomeric Phosphinogallanes tBu2GaPR′R′′ (R′,R′′: Bulky Aryl or Silyl Groups) and Related Compounds. (1993) (0)
- (M(NArBAr2)2) (M: Cr, Ni). Stable Distorted Two-Coordinate d4 and d8 Complexes. (1989) (0)
- Insertion Reactions of NH3 and H2O with the Ferriogermylenes ArGeFeCp(CO)2 (Ar = ArMe6 (−C6H3-(C6H2-2,4,6-Me3)2) or AriPr4 (−C6H3-(C6H3-2,6-iPr2)2); Cp = η5-C5H5): Structural Isomerism and Polymorphism in a Metallogermylene (2021) (0)
- Synthesis and Spectroscopic and Structural Characterization of the Novel Lithium Borylamide Salts trans-(Li(Et2O)NHBMes2)2, a Dimer, and the Ion Pair (Li(Et2O)3) (Mes2BNBMes2) with a Linear Allene-Like, (R2B=N=BR2)-, Moiety. (1988) (0)
- ISOLATION AND CRYSTAL STRUCTURES OF THE HALIDE-FREE AND HALIDE-RICH PHENYLLITHIUM ETHERATE COMPLEXES ((PHLI.ET2O)4) AND ((PHLI.ET2O)3.LIBR) (1983) (0)
- Models for Bonding in the Alkali Metal-Gallium Clusters K 2 Ga 4 (C 6 H (2002) (0)
- STERICALLY CROWDED σ- AND π-BONDED METAL ARYL COMPLEXES (2018) (0)
- Comproportionation of a dialuminyne with alane or dialane dihalides as a clean route to dialuminenes. (2022) (0)
- Rings, Clusters and Polymers of Mayn Group and Transition Elements. Herausgegeben von H. W. Roesky. Elsevier, Amsterdam 1989. 560 S., geb. HFI 350.00—ISBN 0–444–88172–7 (1990) (0)
- Synthesis and Spectroscopic and X-Ray Structural Studies of the Mesitylphosphines PH2Mes (I) and PHMes2 (II) (Mes: 2,4,6-Me3C6H2) and Their Lithium Salts (Li(THF)3PHMes) (III) and ((Li(OEt2)PMes2)2) (1987) (0)
- The Structure of 1,2‐Diaryl‐1,2‐bis(dimethylamino)diboron Compounds and Related Species: Boron‐Nitrogen Analogues of Buta‐1,3‐dienes. (1992) (0)
- Reduction of a Digallane to Afford a Radical Anion with Ga-Ga Multiple Bonding Character. (1993) (0)
- Hydrostannylation of carbon dioxide by a hydridostannylene molybdenum complex. (2021) (0)
- Synthesis and Structural Characterization of a Novel Cluster with a GaP Framework (0)
- A NICKEL COMPLEX CONTAINING AN EXTREMELY LONG NICKEL-PHOSPHORUS BOND. SYNTHESES AND X-RAY STRUCTURES OF (NI(CN)2(P(CH2OH)PH2)3)(C6H6)0.5 AND TRANS-(NI(CN)2(P(CH2-OH)PH2)2) (1984) (0)
- Use of Very Crowded Silylamide Ligands -N(SiMenPh3-n)2(n = 0, 1, or 2) To Synthesize Crystalline, Two-Coordinate Derivatives of Mn(II), Fe(II), and Co(II) and the Free Ion (Ph3SiNSiPh3)-. (1989) (0)
- Reactions of MCl5 (M = Nb or Ta) with Excess PhLi: Structural Characterization of Bisbenzyne/Polyphenyl Derivatives of Niobium and Tantalum. (1988) (0)
- Editorial for the Mike Lappert Commemorative Issue (2015) (0)
- Synthesis of the monomeric HBtrip2 (trip 2,4,6-iso-Pr3C6H2) and the x-ray crystal structures of [HBMes2]2 (Mes = 2,4,6-Me3C6H2) and HBtrip2 [Erratum to document cited in CA112(5):35933q] (1990) (0)
- VLADIMIR YA. LEE AND AKIRA SEKIGUCHI Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds John Wiley, 2010, 448 pp. Price £115.00 / €138.00 (hardback) ISBN-13 978-0-470-72543-6 (2012) (0)
- Amides of the Actinide Metals (2008) (0)
- Structural Characterization of the Solvate Complexes of the Lithium Diorganophosphides [{Li(Et2O)PPh2}∞], [{Li(THF)2PPh2}∞], and [{Li(THF)P(C6H11)2}∞]. (1986) (0)
- Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Application to Metal—Metal Bonded Compounds (2011) (0)
- Bonding and Reactivity of Heavier Group 14 Element Alkyne Analogues. (2007) (0)
- Multiple Bonding, π‐Bonding Contributions, and Aromatic Charater in Isoelectronic Boron‐Phosphorus, Boron‐Arsenic, Aluminum‐Nitrogen, and Zinc‐Sulfur Compounds (2010) (0)
- Synthesis, structure, and reactivity of a μ-bis(dialkylphosphido)-dilithium [Li(μ-PR2)]2 (1984) (0)
- Terpene dispersion energy donor ligands in borane complexes. (2022) (0)
- Synthesis and Spectroscopic and Structural Characterization of Derivatives of the Quasi-Alkoxide Ligand (OBMes2)- (Mes: 2,4,6-Me3C6H2). (1987) (0)
- Novel Delocalized Rings Involving Heavier Main Group Elements (1992) (0)
- Stable, Two-Coordinate, Open Shell (d0-d9) Transition Metal Complexes (1989) (0)
- Structure of a Monomeric Phosphinoborane: Synthesis and X‐Ray Crystal Structure of (Diphenylphosphino)dimesitylborane. (1987) (0)
- X-RAY CRYSTAL STRUCTURES OF THE DIPHENYLPHOSPHIDE AND ARSENIDE ANIONS: USE OF A CROWN ETHER TO EFFECT COMPLETE METAL CATION AND ORGANOMETALLOID ANION SEPARATION (1984) (0)
- Isolation and X-Ray Crystal Structure of the Boron Methylidenide Ion (Mes2BCH2)- (Mes: 2,4,6-Me3C6H2): A Boron-Carbon Double Bonded Alkene Analogue. (1987) (0)
- Synthesis and Characterization of a Fe 2 ( µ -O) 2 Complex {3,5- i Pr 2 -Ar*OFe( µ -O)} 2 with a Very Short Fe···Fe Separation (2011) (0)
- Book Review: Rings, Clusters and Polymers of Main Group and Transition Elements. Edited by H. W. Roesky (1990) (0)
- Reduction of a Boron‐Nitrogen 1,3‐Butadiene Analogue. Evidence for a Strong B‐B π‐Bond. (2010) (0)
- CCDC 845707: Experimental Crystal Structure Determination (2011) (0)
- Synthesis and characterization of Sn-Sn multiple bonds using modified bulky terphenyl ligands. (2008) (0)
- London Dispersion Effects in a Distannene/Tristannane Equilibrium: Energies of their Interconversion and the Suppression of the Monomeric Stannylene Intermediate. (2023) (0)
- A Compound with a Boron-Arsen Double Bond. (1990) (0)
- SUBVALENT GROUP 4A METAL ALKYLS AND AMIDES. PART 7. TRANSITION‐METAL CHEMISTRY OF METAL(II) BIS(TRIMETHYLSILYL)AMIDES M(NR2)2 (R = SIME3: M = GERMANIUM, TIN, OR LEAD) (1985) (0)
- SYNTHESIS AND ELECTRONIC AND REDOX PROPERTIES OF “DOUBLE-CUBANE” CLUSTER COMPLEXES CONTAINING MOLYBDENUM IRON SULFIDE (MOFE3S4) AND TUNGSTEN IRON SULFIDE (WFE3S4) CORES (1980) (0)
- Synthesis and structural characterization of the neutral π-bridged, In-In bonded indium(II) amide dimer [(In{N(Dipp)SiMe_{3}})_{2} (μ_{2}-η^{1}:η^{1}C_{5}H_{5}) (μ_{2}-η^{1}:η^{2}C_{5}H_{5})] (Dipp=2,6 diisopropylphenyl) (2010) (0)
- Reactions of Terphenylbismuth Dihalides with KSi(SiMe3)3, K2Si2(SiMe3)4 and Na2[Fe(CO)]4: Reduction vs. Metathesis (Eur. J. Inorg. Chem. 16/2008) (2008) (0)
- Synthesis and Structural and Spectroscopic Characterization of the Germanazene (GeN(2,6-iPr2C6H3))3 and the Tin and Lead Tetramers (SnN( BMes2))4, (SnN(2,6-iPr2C6H3))4, and (PbN(2,6-iPr2C6H3))4. (1991) (0)
- Recent Developments in the Chemistry of Low-Valent Group 14 Hydrides (2009) (0)
- The Neutral Transition‐Metal Thiolates ((M(SAr)2)2) (M: Mn, Fe or Co, Ar: 2,4,6‐tBu3C6H2). (1991) (0)
- SUBVALENT GROUP 4A METAL ALKYLS AND AMIDES. PART 5. THE SYNTHESIS AND PHYSICAL PROPERTIES OF THERMALLY STABLE AMIDES OF GERMANIUM(II), TIN(II), AND LEAD(II) (1978) (0)
- READY OXIDATIVE ADDITION OF AN ALKYL OR ARYL HALIDE TO A TIN(II) ALKYL OR AMIDE, EVIDENCE FOR A FREE-RADICAL PATH (1976) (0)
- Amides of Zinc, Cadmium and Mercury (2008) (0)
- Do Nonclassical Silabenzene Anions Exist? Synthesis and X-Ray Crystal Structure of Crown Ether Stabilized Lithium Silacyclohexadienides, Li(12-crown-4)2Me2SiC5H5 and Li(12-crown-4)2-tBu(H)SiC5H5. (1990) (0)
- Reaction of Bulky Monosubstituted Phosphorus(III) Halides with Disodium Pentacarbonylchromate. Steric and Electronic Factors in the Synthesis of Cr(CO)5 Complexes of Diphosphenes, Phosphinidenes, Phosphanes, Diphosphanes, and Cyclopol (1988) (0)
- Syntheses, Structures, and Spectroscopic Studies of Several New Classes of Compounds Having Boron‐Arsenic Bonds. (1993) (0)
- π‐Bonding and the Lone Pair Effect in Multiple Bonds Between Heavier Main Group Elements (2000) (0)
- A donor-stabilized strategy for the preparation ofP=B and As=B double bonds (2006) (0)
- Synthesis and X-Ray Structural Characterization of the Metal Borylamide Complexes Li(Et2O)2NPhBMes2, (THF)(Et2O)2LiClCo(NPhBMes2)2, and Mn(NMesBMes2)2·3 PhMe (Mes: 2,4,6-Me3C6H2): Modified Amide Ligands with Poor Bridging and π-Donor (1987) (0)
- Structural Characterization of the Solvate Complexes of the Lithium Salts of Diorganophosphides and Phosphinideneborates. A Pathway to Phosphorus-Boron Double Bonds. (1987) (0)
- ChemInform Abstract: Synthesis and X-Ray Structure Analysis of (2,4,6-Me3C6H2BPC6H11)3, a Boron-Phosphorus-Analogue of Borazole. (1988) (0)
- THE ISOLATION AND X-RAY STRUCTURES OF LITHIUM CROWN ETHER SALTS OF THE FREE PHENYL CARBANIONS (CHPH2)- AND (CPH3)- (1985) (0)
- Editorial for the virtual issue on synthetic inorganic chemistry. (2013) (0)
- Oxidation of 1-(4'-substituted phenyl)-2-(4- methylphenyl)diazene — Benzylic substitution vs. C-azo bond breaking (2005) (0)
- Inhibition of Alkali Metal Reduction of 1‐Adamantanol by London Dispersion Effects (2022) (0)
- Reaction of Bulky Monosubstituted Phosphorus(III) Halides with Disodium Tetracarbonylferrate. Steric and Electronic Factors in the Synthesis of Fe(CO)4 Complexes of Diphosphene and Phosphinidene Ligands. (1988) (0)
- CCDC 857389: Experimental Crystal Structure Determination (2012) (0)
- Erratum: Synthesis, structure, and spectroscopic characterization of unassociated mono-, Di-, and triamido derivatives of aluminum and gallium (Organometallics (1994) 13, (2795-2798)) (1994) (0)
- Synthesis and Characterization of the Phosphinidene Borate Complexes (Li(Et2O)2PRBMes2) and (Li(12-crown-4)2)(RPBMes2)·THF, R = Ph, C6H11, or Mes (Mes = 2,4,6-Me3C6H2): The First Structurally Characterized Boron-Phosphorus Multiple Bo (1987) (0)
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