Pierre Deslongchamps
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Pierre Deslongchamps's Degrees
- PhD Computer Science Université de Montréal
- Masters Computer Science Université de Montréal
- Bachelors Computer Science Université de Montréal
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(Suggest an Edit or Addition)Pierre Deslongchamps's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Stereoelectronic effects in organic chemistry (1983) (672)
- Stereoelectronic control in the cleavage of tetrahedral intermediates in the hydrolysis of esters and amides (1975) (178)
- 1,7-Dioxaspiro[5.5]undecanes. An excellent system for the study of stereoelectronic effects (anomeric and exo-anomeric effects) in acetals (1981) (112)
- The transannular Diels-Alder strategy: applications to total synthesis (2001) (105)
- The Oxidation of Acetals by Ozone (1974) (95)
- Total synthesis of ouabagenin and ouabain. (2008) (68)
- Ozonolysis of Acetals. (1) Ester Synthesis, (2) THP Ether Cleavage, (3) Selective Oxidation of β-Glycoside, (4) Oxidative Removal of Benzylidene and Ethylidene Protecting Groups (1971) (68)
- Total synthesis of ryanodol (1979) (63)
- Electrophysiological effects of ryanodine derivatives on the sheep cardiac sarcoplasmic reticulum calcium-release channel. (1996) (57)
- Modifying chemotherapy response by targeted inhibition of eukaryotic initiation factor 4A (2013) (56)
- The Relative Rate of Hydrolysis of a Series of Acyclic and Six-Membered Cyclic Acetals, Ketals, Orthoesters, and Orthocarbonates (2000) (49)
- Intramolecular strategies and stereoelectronic effects. Glycosides hydrolysis revisited (1993) (49)
- A highly efficient access to spiroketals, mono-unsaturated spiroketals, and furans: Hg(II)-catalyzed cyclization of alkyne diols and triols. (2011) (48)
- Synthesis of the antiproliferative agent hippuristanol and its analogues via Suárez cyclizations and Hg(II)-catalyzed spiroketalizations. (2011) (45)
- Transannular Diels−Alder Entry into Stemodanes: First Asymmetric Total Synthesis of (+)-Maritimol (2000) (44)
- Total synthesis of (+/-)-momilactone A. (2002) (44)
- The Hydrolysis of Cyclic Orthoesters. Stereoelectronic Control in the Cleavage of Hemiorthoester Tetrahedral Intermediates (1975) (44)
- Transannular Diels-Alder reaction on macrocycles. A general strategy for the synthesis of polycyclic compounds (1992) (44)
- Bent bonds, the antiperiplanar hypothesis and the theory of resonance. A simple model to understand reactivity in organic chemistry. (2011) (44)
- Stereoselective synthesis of cis-decalins via Diels–Alder and double Michael addition of substituted Nazarov reagents (1992) (43)
- Oxidation of Benzylidene Acetals by Ozone (1975) (41)
- Structural determinants of high-affinity binding of ryanoids to the vertebrate skeletal muscle ryanodine receptor: a comparative molecular field analysis. (1994) (40)
- Efficient synthetic approach to potent antiproliferative agent hippuristanol via Hg(II)-catalyzed spiroketalization. (2010) (40)
- Total synthesis of ouabagenin and ouabain. (2009) (40)
- One-step construction of a 13α-methyl 14α-hydroxy steroid via a new anionic polycyclization method (1988) (40)
- Intramolecular Michael addition of cyclic β-ketoester on conjugated acetylenic ketone (1986) (39)
- Cyclization of Hydroxyenol Ethers into Spiroacetals. Evidence for the position of the transition state and its implication on the stereoelectronic effects in acetal formation (1992) (37)
- The Importance of Conformation of the Tetrahedral Intermediate in the Hydrolysis of Amides. Selective Cleavage of the Tetrahedral Intermediate Controlled by Orbital Orientation (1972) (37)
- The total synthesis of (+)-ryanodol. Part I. General strategy and search for a convenient diene for the construction of a key tricyclic intermediate (1990) (34)
- Structural components of ryanodine responsible for modulation of sarcoplasmic reticulum calcium channel function. (1997) (34)
- The Importance of Conformation in the Ozonolysis of Acetalsl (1972) (33)
- A convergent synthesis of the cardenolide skeleton: intramolecular aldol condensation via reduction of alpha-bromoketones. (2002) (32)
- Synthesis of triquinacene and some of its derivatives (1978) (30)
- Novel synthesis of highly functionalized 14-beta-hydroxysteroids related to batrachotoxin and ouabain. (2004) (30)
- Synthesis of cis-decalin via Diels-Alder and double Michael cycloaddition with substituted Nazarov reagent (1988) (30)
- Efficient parallel synthesis of macrocyclic peptidomimetics. (2008) (30)
- Formal total synthesis of erythromycin A. Part I. Total synthesis of a 1,7-dioxaspiro[5.5]undecane derivative of erythronolide A (1985) (30)
- Furanophane transannular Diels-Alder approach to (+)-chatancin: an asymmetric total synthesis of (+)-anhydrochatancin. (2003) (30)
- A new synthesis of twistane (1967) (30)
- Stereoelectronic control in acetal formation (1980) (29)
- A Convenient Synthesis OF 2-Carbomethoxycyclohexanone (1976) (29)
- The anomeric and reverse anomeric effect. A simple energy decomposition model for acetals and protonated acetals (1992) (29)
- The total synthesis of (+)-ryanodol. Part IV. Preparation of (+)-ryanodol from (+)-anhydroryanodol (1990) (28)
- Studies directed toward asymmetric synthesis of cardioactive steroids via anionic polycyclization. (2002) (28)
- New strategy for convergent steroid synthesis. (2003) (27)
- Pyranophane transannular diels-alder approach to (+)-chatancin: a biomimetic asymmetric total synthesis. (2003) (27)
- The total synthesis of (+)-ryanodol. Part II. Model studies for rings B and C of (+)-anhydroryanodol. Preparation of a key pentacyclic intermediate (1990) (27)
- HYDROLYSIS OF IMIDATE SALTS STEREOELECTRONIC CONTROL IN THE CLEAVAGE OF THE HEMIORTHOAMIDE TETRAHEDRAL INTERMEDIATE (1975) (26)
- Bent bonds and the antiperiplanar hypothesis as a simple model to predict Diels–Alder reactivity: retrospective or perspective? (2013) (26)
- Ceric Ammonium Nitrate Oxidation of Cyclic Ketones (1972) (25)
- Total synthesis of (+)-cassaine via transannular Diels-Alder reaction. (2008) (25)
- Differential reactivity of alpha- and beta-anomers of glycosyl acceptors in glycosylations. A remote consequence of the endo-anomeric effect? (2000) (24)
- Stereoselective synthesis of (±)epihinesol (agarospirol) (1970) (24)
- Transannular Diels-Alder studies on the asymmetric total synthesis of chatancin: the pyranophane approach. (2000) (24)
- The Mechanism of Hydrolysis of Imidate Salts. The Importance of Stereoelectronic Control and pH of the Reaction Medium on the Cleavage of Tetrahedral Intermediates (1975) (23)
- Synthesis and transannular diels-alder reaction of a 13-membered macrocyclic triene having a tetrasubstituted enol ether as a dienophile (1987) (23)
- 13C chemical shift data for 1,7-dioxaspiro[5.5]undecanes and related compounds (1981) (23)
- Thermal decomposition of ozonides. A complementary method to the Baeyer–Villiger oxidation of hindered ketones (1979) (22)
- CONFIGURATION OF DIELS–ALDER ADDUCT OF FURAN AND ACETYLENE DICARBOXYLIC ACID (1966) (22)
- A Convenient Synthesis of Triquinacene (1973) (22)
- Hydrolysis of alpha- and beta-glycosides. New experimental data and modeling of reaction pathways. (2004) (21)
- First experimental evidence for a synperiplanar stereoelectronic effect in the acid hydrolysis of acetal (1993) (21)
- 1,7-Dithia and 1-oxa-7-thiaspiro[5.5]undecanes. Excellent systems for the study of stereoelectronic effects (anomeric and exo-anomeric effects) in the monothio and the dithioacetal functions (1981) (21)
- Intramolecular Michael addition of cyclic β-ketoester on conjugated olefinic ketone, a stereoelectronically controlled process (1986) (21)
- Syntheses of α-agarofuran and isodihydroagarofuran (1968) (20)
- 1994 R.U. Lemieux Award Lecture Hydrolysis of acetals and ketals. Position of transition states along the reaction coordinates, and stereoelectronic effects (1994) (20)
- Synthetic studies toward highly functionalized 5beta-lanosterol derivatives: a versatile approach utilizing anionic cycloaddition. (2006) (19)
- Total asymmetric synthesis of the aphidicolin derivative (11R)-(-)-8-epi-11-hydroxyaphidicolin using tandem transannular Diels-Alder/aldol reactions. (2000) (19)
- New approach to aphidicolin and total asymmetric synthesis of unnatural (11R)-(-)-8-epi-11-hydroxyaphidicolin by tandem transannular Diels-Alder/aldol reactions. (2000) (19)
- Synthesis of an optically active 13β-methyl 14β-hydroxy steroid via base-catalyzed reactions (1990) (19)
- A new bis(2,2,2-trifluoroethyl)phosphonate for the synthesis of Z-unsaturated N-methoxy-N-methylamides. (2002) (19)
- Stereocontrolled synthesis of optically active 14β-hydroxy steroids and other steroid derivatives (1992) (19)
- The total synthesis of (±)hinesol and (±)epihinesol (1980) (18)
- Studies directed towards the total synthesis of aldosterone and naturally occurring analogues. A unified approach using the transannular Diels-Alder reaction (1998) (18)
- On the nature of the anomeric effect in XHn—CH2—OH systems, with X = F, O, N, C (1992) (18)
- Formal total synthesis of erythromycin A. Part III. Synthesis of Woodward's carbamate key intermediate from a 1,7-dioxaspiro[5.5]undecane derivative of erythronolide A (1985) (17)
- Synthesis of tricyclic compounds via sequential intramolecular Michael addition and alkylation of β-ketoester ynones (1987) (17)
- The total synthesis of (+)-ryanodol. Part III. Preparation of (+)-anhydroryanodol from a key pentacyclic intermediate (1990) (17)
- Study of very reactive tautomeric phenol dienones as dienes in Diels-Alder reactions. (2009) (17)
- Syntheses of 8-acetoxy-4-twistanone, twistane, 1-twistanol, 1-twistylamine, and 1-twistane carboxylic acid (1969) (17)
- Synthesis and transannular diels-alder reaction of a cis-trans-trans 13-membered macrocyclic trienone (1987) (16)
- High-Temperature Isomerization of Benzenoid Polycyclic Aromatic Hydrocarbons. Analysis through the Bent Bond and Antiperiplanar Hypothesis Orbital Model. (2018) (16)
- Synthetic approach toward the total synthesis of kempane diterpenes via transannular Diels-Alder strategy. (2006) (16)
- Experimental evidence for a synperiplanar stereoelectronic effect in the ozonolysis of a tricyclic acetal (1993) (16)
- Transannular Diels-Alder model studies on the total synthesis of chatancin. The furanophane approach. Part 2 [1]: Macrocyclization and Diels-Alder reaction (1999) (16)
- HYDROLYSIS OF CYCLIC ORTHOESTERS : EXPERIMENTAL OBSERVATIONS AND THEORETICAL RATIONALIZATION (1996) (16)
- Transannular Diels–Alder reactions on 14-membered macrocyclic trienes. Part II: formation of macrocycles and thermal conversion into tricyclic systems (1993) (15)
- The importance of conformation of the tetrahedral intermediate in the hydrolysis of esters and amides (1975) (15)
- Investigation of the constituents of RyaniaSpeciosa (1985) (15)
- Versatile strategy to access tricycles related to quassinoids and triterpenes. (2010) (15)
- Transannular Diels-Alder model studies on the total synthesis of chatancin. The furanophane approach. Part 1: Assembly of the acyclic substrates (1999) (15)
- Nazarov reagents for convergent and expedient synthesis of new steroids. (2002) (15)
- SN2 iodide displacement on unsymmetrical cyclic dioxenium salts. A stereoelectronically controlled reaction (1980) (15)
- Transannular Diels-Alder reaction of 14-membered macrocyclic trienes. Part I: Theoretical analysis and stereochemical predictions (1988) (15)
- Synthesis ofLycopodiumAlkaloids. I. A Synthetic Proof for the Structure of Lyconnotine (1964) (15)
- A convenient synthesis of triquinacene-2-carboxylic acid and a new approach towards the synthesis of dodecahedrane (1981) (14)
- Stereocontrolled Synthesis of Acyclic Tri- and Tetra-C-Substituted α-Alkoxymethyl α,β-Unsaturated Esters (1994) (14)
- A simple and direct method of cyclization for the synthesis of a 10-membered ring (1984) (14)
- Total synthesis of (+)-cassaine utilizing an anionic polycyclization strategy. (2013) (14)
- Synthesis of 11-and 12-membered rings by a direct cyclization method (1987) (14)
- Bent Bonds (τ) and the Antiperiplanar Hypothesis-The Chemistry of Cyclooctatetraene and Other C8H8 Isomers. (2018) (14)
- Transannular Diels-Alder reaction of 14-membered macrocyclic trienes. Part II: Experimental results and synthetic potential (1988) (14)
- Ryanoids and related compounds. A total synthesis of 3-epiryanodine (1993) (14)
- The products of hydrolysis of cyclic orthoesters as a function of pH and the theory of stereoelectronic control (1985) (14)
- The Relative Rate of Hydrolysis of a Series of Acyclic and Six-Membered Cyclic Acetals, Ketals, Orthoesters, and Orthocarbonates. (2000) (14)
- Stereocontrolled synthesis of the C-1 to C-7 fragment of erythronolide A. A model study using the 1,7-dioxaspiro[5.5]undecane system (1984) (13)
- Highly stereoselective double michael cyclization of 1-phenylsulfinyl and sulfonyl analogues of the nazarov reagent (1990) (13)
- Acid catalysed hydrolysis of orthoesters: mechanism of hydrolysis of 2,4,10-trioxaadamantanes substituted in position 3 (1980) (13)
- Cascade polycyclization: exploration of a convergent route to access various tricyclic and tetracyclic products related to sterols. (2003) (13)
- Experimental and Semiempirical Calculation Studies of Transannular Diels-Alder and Other Competing Pericyclic Reactions (1995) (13)
- Synthesis of the antiproliferative agent hippuristanol and its analogues from hydrocortisone via Hg(II)-catalyzed spiroketalization: structure-activity relationship. (2014) (13)
- Bent bonds (τ) and the antiperiplanar hypothesis, and the reactivity at the anomeric center in pyranosides. (2016) (12)
- Formal total synthesis of erythromycin A. Part II. Preparation of a 1,7-dioxaspiro[5.5]undecane derivative of erythronolide A seco acid methyl ester from erythromycin A (1985) (12)
- Transannular Diels-Alder approach to the synthesis of momilactone A (1999) (12)
- Total Synthesis of (+)-Occidentalol (1972) (12)
- Anionic polycyclization entry to tricycles related to quassinoids and terpenoids: a stereocontrolled total synthesis of (+)-cassaine. (2014) (12)
- Transannular Diels–Alder reactions on 14-membered macrocyclic trienes. Part I: stereoselective syntheses of the macrocyclic trienes precursors (1993) (12)
- Studies towards the total synthesis of ouabagenin (2005) (11)
- The structure of lyconnotine: A novel lycopodium alkaloid (1964) (11)
- Hydrolysis and carbonyl-oxygen exchange in tertiary amides. Estimation of the free energy changes for breakdown and conformational changes of tetrahedral intermediates (1980) (11)
- Study on the influence of unsaturations on the formation of C-11, C-12, C-13 and C-14 membered rings (1986) (11)
- Synthesis and resolution of R(−)-5-hexyn-3-ol (1985) (11)
- Stereocontrolled construction of 1,7-dimethyl A.B.C.[6.6.6] tricycles. Part I. Transannular Diels–Alder reactions of 14-membered macrocycles containing trans-dienophiles (1993) (11)
- Stereoelectronic effects on reactivity. Crystal-structure–reactivity correlations for acetals with synperiplanar lone pairs (1997) (11)
- Synthetic studies towards ryanodine (1977) (11)
- A new synthesis of 2,10,11-trioxatricyclo[4.4.4.01,6]tetradecane (1980) (11)
- Bent Bonds and the Antiperiplanar Hypothesis. A Model To Account for Sigmatropic [1, n]-Hydrogen Shifts. (2018) (11)
- Theoretical and experimental determination of the effects governing the transannular Diels-Alder reaction of trans-trans-cis systems with or without activation of the dienophile. (2001) (11)
- The valence tautomer of methyl-7-oxa-bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate and its dimer (1967) (11)
- Conformational analysis of 1-oxaspiro[5.5]undecanes. A powerful probe for the endo and the exo anomeric effects in acetals (1990) (11)
- Synthesis of a 14β-Hydroxysteroid Using the Transannular Diels-Alder Strategy (1997) (10)
- Synthesis of 2,3-Dihydrotriquinacen-2-one (1971) (10)
- Stereocontrolled synthesis of a trans-anti-trans tricycle via a transannular Diels-Alder strategy (1988) (10)
- Bent bonds and the antiperiplanar hypothesis - a simple model to rationalize [1,3]-sigmatropic alkyl shifts. (2016) (10)
- New approach toward the total synthesis of (+)-aphidicolin by tandem transannular Diels–Alder/aldol strategy (2003) (10)
- A one-step synthesis of the twistane ring system 8-acetoky-4-twistanone (1968) (10)
- Synthesis of 9- and 10-membered rings by the intramolecular Michael addition of malonate on enone and ynone (1986) (10)
- The Bent Bond / Antiperiplanar Hypothesis: Modulating the Reactivity and the Selectivity in the Glycosylation of Bicyclic Pyranoside Models. (2020) (10)
- Solid phase combinatorial synthesis of a library of macro-heterocycles and related acyclic compounds. (2000) (10)
- Transannular Diels-Alder reaction studies with an activated dienophile. An enantioselective synthesis of an A.B.C.[6.6.6] trans-syn-cis tricycle☆ (1997) (9)
- Design of an organic sequence suitable for the solid phase combinatorial synthesis of libraries of macro-heterocycles (2000) (9)
- Stereocontrolled chiral synthesis of a trans-anti-trans tricycle by a transannular Diels–Alder reaction (1992) (9)
- Comparative effects of conjugated and deconjugated isomeric enones on the transannular Diels-Alder reaction. (2003) (9)
- Applying the Bent Bond / Antiperiplanar Hypothesis to the Stereoselective Glycosylation of Bicyclic Furanosides. (2019) (9)
- Stereocontrolled construction of A.B.C.[6.6.6] tricycle via transannular Diels–Alder reaction of 14-membered macrocycle with acetylene as dienophile (1990) (8)
- The hydrolysis of cis and trans methoxy bicyclic and tricyclic orthoesters. Evidence for a chair–boat inversion prior to breakdown in some hemiorthoester tetrahedral intermediates (1985) (8)
- Transannular Diels–Alder cyclization of a substituted 13-membered macrocyclic triene. An approach to the A.B.C.[6.6.5] rings of the Veratrum alkaloids (1992) (8)
- Transannular Diels-Alder studies on the asymmetric synthesis of (+)-maritimol (1999) (8)
- 1,5-Acyclic stereoselection. The stereocontrolled synthesis of optically active vitamin E fourteen-carbon side chain alcohol (1984) (8)
- ORMOSIA ALKALOIDS: III. CHEMISTRY OF ORMOSANINE AND ORMOJANINE; DEHYDROGENATION TO 3,6,8-TRIALKYLATED QUINOLINES (1966) (8)
- Suppression of eukaryotic initiation factor 4E prevents chemotherapy-induced alopecia (2013) (8)
- Synthesis of 14-hydroxy steroids. Total synthesis of methyl 14β-hydroxy-1,7,17-trioxo-5β,8-androstene-10β-oate and related compounds (1990) (8)
- Synthetic approach to ryanodine; the use of O-spirodienone lactone in organic synthesis (1969) (8)
- The Bent Bond / Antiperiplanar Hypothesis and the Chemical Reactivity of Annulenes. (2020) (8)
- First experimental and theoretical evidence of a deactivating enone dienophile in the transannular Diels-Alder reaction. (2003) (8)
- Studies on the transannular Diels–Alder reaction of 15-membered macrocyclic trienes containing a trans-trans diene. Part I: Synthesis and isomerization of various model cyclopentadecatrienes (1995) (8)
- Hydrolysis of cyclic unsymmetrical anti imidate salts. New evidence for stereoelectronic control (1979) (8)
- Formation of 14-membered carbocycles by intramolecular Michael addition on ynones and enones (1992) (8)
- A Simple Synthesis of 2-Methoxy and 2-Ethoxytetrahydrofuran (1972) (7)
- STEREOELECTRONIC CONTROL IN HYDROLYTIC REACTIONS (1977) (7)
- Enantioselective Synthesis of a Polyfunctionalized Tetracycle Related to Pentacyclic Triterpenes by Using an Anionic Cycloaddition Reaction (2003) (7)
- THE ACID-CATALYZED OXIDOREDUCTION OF SPIROKETALS. EVIDENCE FOR STEREOELECTRONIC CONTROL IN HYDRIDE TRANSFER TO CYCLIC OXENIUM IONS (1981) (7)
- Thermal rearrangement of optically active tetradeuterated 2-methoxymethyl-methylenecyclopropane and the bent bond/antiperiplanar hypothesis. (2019) (7)
- Oxidative cleavage of conformationally rigid vinyl orthoesters. Evidence for primary and secondary stereoelectronic control in the cleavage of tetrahedral intermediates (1980) (7)
- Transannular Diels–Alder cyclization of substituted 13-membered trienes. An approach to the B.C.D.[6.6.5] rings of the 14β-hydroxysteroids (1996) (7)
- On the mechanism of the Diels-Alder reaction of enal dienophiles. Competitive reactivity and ab initio calculations using a transannular probe (1998) (7)
- Design and synthesis of macro-heterocycles structurally related to tirofiban (2000) (7)
- A Stereospecific Transannular Diels-Alder Approach to the [6.6.7] Tricyclic Skeleton Related to Aphidicolin and Scopadulan Natural Products (1995) (6)
- Synthesis of chiral trans-syn-cis and trans-anti-trans [6.6.6] tricycles by transannular Diels-Alder reaction (1999) (6)
- The bent bond / antiperiplanar hypothesis and the thermal rearrangement of cyclopropyl halides and tosylates (2020) (6)
- Study on the enolization of alkylation of cis and trans 2-tert-5-X-1,3-dioxanes (X = CO2CH3, CHO, COPh, NO2, and CN). Evidence for stereoelectronic control (1986) (6)
- Synthesis and Transannular Diels-Alder Reaction of a 13-Membered Macrocyclic Triene. A Synthetic Approach Towards the Tricyclic Part A.B.C.[6.6.5] of the Veratrum Alkaloids (1992) (6)
- Transannular diels-alder reaction of trans-trans-cis 15-membered macrocyclic trienes. Evidence for asynchronous transition state. (1992) (6)
- The thermal rearrangements of naphthalene and azulene. An analysis through the bent bond and antiperiplanar hypothesis orbital model (2021) (6)
- Total synthesis of 14β-fluorosteroids via a transannular DielsAlder reaction (2006) (6)
- Hydrolytic behavior of two β-lactams and their corresponding imidate salts. New evidence for stereoelectronic control (1980) (6)
- ORMOSIA ALKALOIDS: IV. STEREOCHEMISTRY OF ORMOJANINE; STRUCTURE AND STEREOCHEMISTRY OF PIPTANTHINE, DASYCARPINE, AND ORMOSININE (1966) (6)
- Synthesis and transannular Diels-Alder reaction of a cis-trans-trans and a trans-cis-cis 13-membered macrocyclic trienone (1989) (6)
- Synthesis of 1-Methyl-tricyclo[5.2.2.02,6]undec-2(6)-ene-8-one (1972) (5)
- The synthesis of 1-azatwistane☆ (1970) (5)
- The Transannular Diels—Alder Strategy: Applications to Total Synthesis (2001) (5)
- Alkylation of 1-Methyl-2-piperidones (1975) (5)
- Synthesis of cis-Decalin and Tricyclic Compounds via Anionic Cycloaddition with Substituted Nazarov Reagents (1990) (5)
- Transannular diels-alder reaction of trans-trans-trans 15-membered macrocyclic trienes (1992) (4)
- First transannular Diels–Alder reactions involving tetrasubstituted non-activated dienophiles (1994) (4)
- Studies on the transannular Diels–Alder reaction of 15-membered macrocyclic trienes containing a trans-trans diene. Part II: Evidence for unsymmetrical transition states in the formation of A.B.C.[6.6.7] tricyclic products (1995) (4)
- Ab initio and semiempirical corroboration of the observed stereoselectivity in the transannular Diels-Alder reaction leading to steroids (1998) (4)
- Synthesis of (Z)- and (E)-3,4-Dimethyl-hex-3-ene-1,6-diols (1989) (4)
- The structure of piptanthine a catalytic epimerization of Ormosia alkaloids (1964) (4)
- The conformation and reactivity of butadiene and the bent bond/antiperiplanar hypothesis orbital model (2021) (4)
- Novel Synthetic Strategy Towards Taxol by Macrocyclization Reaction – Conformational Requirement of Ring A (2006) (4)
- Transannular Diels-Alder/Intramolecular Aldol Tandem Reaction as a Stereocontrolled Route to (+)-Aphidicolin and its Isosteric C8-Epimer. (1996) (4)
- Formation of Cyclic Ketals from Hydroxyalkyl Enol Ethers, a stereoelectronically controlled endo‐trig‐cyclization process (1996) (4)
- Synthesis of a pentacyclic lactone related to quinovaic acid and emmolactone using an anionic polycyclization strategy (2002) (4)
- Stereocontrolled construction of A.B.C.[6.6.6] tricycle via transannular Diels–Alder reaction of 14-membered triene macrocycle (1990) (3)
- The Hydrolysis of Imidate Salts. Stereoelectronic Control in the Cleavage of the Hemiorthoamide Tetrahedral Intermediate (1975) (3)
- Bent bond / antiperiplanar hypothesis and antiaromatic, aromatic and nonaromatic molecules (2021) (3)
- Pharmacology of the Ryania Alkaloids: The Ester A, a Ryanodine Analog That Only Increases Sarcoplasmic Reticulum Calcium Permeability (1990) (3)
- Facile Synthesis of Methyl 2-Formyl-5-hydroxymethyl-3-furancarboxylate (1999) (3)
- Intramolecular Strategies and Stereoelectronic Effects: Glycosides and Orthoesters Hydrolysis Revisited (1993) (3)
- Solvolytic reactivity of bridgehead substituted tricyclo[4.4.0.03,8]decanes (twistanes) (1970) (3)
- THE CONCEPT OF STRATEGY IN ORGANIC SYNTHESIS (1985) (3)
- Transannular Diels–Alder Studies of 14-Membered cis–trans–trans Macrocyclic Trienes Having Allylic Ether or Enone Dienophile (2000) (3)
- THE IMPORTANCE OF CONFORMATION OF THE TETRAHEDRAL INTERMEDIATE IN THE HYDROLYSIS OF AMIDES, SELECTIVE CLEAVAGE OF THE TETRAHEDRAL INTERMEDIATE CONTROLLED BY ORBITAL ORIENTATION (1973) (3)
- MACROCYCLIZATION OF TERMINAL BIS-ALLYLIC CHLORIDES VIA AN INTRAMOLECULAR GEM-DIALKYLATION OF MALONONITRILE OR METHYL CYANOACETATE (1998) (3)
- Stereospecific syntheses of the α-patchoulene and α-cedrene skeletons from a common intermediate (1977) (3)
- Synthesis and equilibration of conformationally rigid cis and trans tricyclic mono and dithioacetals. An evaluation of stereoelectronic (anomeric) effects in thioacetals (1985) (3)
- TRANSANNULAR DIELS-ALDER/INTRAMOLECULAR ALDOL TANDEM REACTION AS A STEREOCONTROLLED ROUTE TO (+)-APHIDICOLIN AND ITS ISOSTERIC C8-EPIMER (1995) (3)
- Solid-phase synthesis of hydroxy-acids leading to macrolactones (2000) (3)
- Total synthesis of 3-azasteroids via the transannular Diels–Alder strategy (2001) (3)
- Functionalized hydrocarbons with condensed ring skeletons. VII. A methyltricyclo[8.4.0.02,7]tetradec-8-ene (1989) (2)
- Functionalized hydrocarbons with condensed ring skeletons. VIII. A dimethyl-substituted tricyclo[8.4.0.02,7]tetradec-8-ene (1990) (2)
- Functionalized hydrocarbons with condensed ring skeletons. X. A methyltricyclo[7.4.0.0(2,6)]tetradec-7-ene. (1990) (2)
- The Total Synthesis of (+)-Ryanodol. Part 3. Preparation of (+)-Anhydroryanodol from a Key Pentacyclic Intermediate. (1990) (2)
- On the relative rate of hydrolysis of a series of ketals and their proton affinities (2000) (2)
- Ormosia alkaloids, Part I: structure of ormojanine and ormosanine (1963) (2)
- Experimental evidence for the stereoelectronically controlled hydrolysis of orthocarbonates (1994) (2)
- Hydrolysis of Isomeric Tricyclic Orthoesters and AM1 Molecular Modelling of the Reaction Pathway Further Evidence for Stereoselectronic Control (1996) (2)
- High throughput solid phase parallel synthesis of macrocyclic peptidomimetics. (2009) (2)
- Hydrolysis of α‐ and β‐Glycosides. New Experimental Data and Modeling of Reaction Pathways. (2004) (2)
- The addition of electrophiles on ester enolates containing an oxygen in the β-position. A stereoelectronically controlled reaction (1986) (2)
- Transannular Diels—Alder Entry into Stemodanes: First Asymmetric Total Synthesis of (+)-Maritimol. (2000) (2)
- Revisiting the conformational analysis of unsaturated organic compounds using the bent bond / antiperiplanar hypothesis (2021) (2)
- Erratum: Studies towards the total synthesis of ouabagenin (2005) (2)
- Novel synthesis of a highly functionalized cyclopropane derivative (2003) (2)
- The Total Synthesis of (+)-Ryanodol. Part 1. General Strategy and Search for a Convenient Diene for the Construction of a Key Tricyclic Intermediate. (1990) (2)
- Bent Bonds and the Antiperiplanar Hypothesis as a Simple Model to Predict Diels—Alder Reactivity: Retrospective or Perspective? (2013) (2)
- Stereochemistry of Eʹ and Eʹʹ decarboxylative-dehydration reactions and the bent bond / antiperiplanar hypothesis orbital model (2021) (1)
- Synthesis and transannular Diels–Alder reaction of a 13-membered macrocyclic triene having a tetrasubstituted enol ether as dienophile (1990) (1)
- Head capsule growth and early sexual dimorphism in Culex quinquefasciatus Say (Diptera: Culicidae). (1980) (1)
- Unique trans-syn-cis [6.6.7] Tricycle Derivative from Transannular Diels–Alder Contraction of a Model 15-Membered trans-cis-cis Macrocyclic Triene (1997) (1)
- Studies on the Transannular Diels‐Alder Reaction of 15‐Membered Macrocyclic Trienes Containing a trans‐trans Diene. Part 1. Synthesis and Isomerization of Various Model Cyclopentadecatrienes. (1996) (1)
- Crystallographic Evidence of [1,5]Prototropic Shifts Occurring upon Transannular Diels‒Alder Reaction of a 14-Membered Macrocycle leading to a 5α-Steroid Skeleton (1998) (1)
- A New Allylidene Phosphorane Reagent for the Efficient Conversion of Aldehydes to γ,δ-Unsaturated Allyl-β-Ketoesters (2000) (1)
- Functionalized hydrocarbons with condensed ring skeletons. V. Substituted 1,2-dimethyltricyclo[8.4.0.02,7]tetradec-8-ene (1990) (1)
- Macrocyclic Studies of EZ and ZZ 12-membered Aza Macrocycles; Novel Molecular Rearrangement Observed (1999) (1)
- Total Synthesis of Ouabagenin (Ia) and Quabain (Ib). (2008) (1)
- Use of the transannular DielsAlder (TADA) reaction to probe biological receptors: Rational design and synthesis of tricyclic TADA adducts capable of rigidly holding pharmacophore parts (2002) (1)
- Functionalized hydrocarbons with condensed ring skeletons. IX. A trioxotricyclo[8.4.0.02,7]tetradecane (1990) (1)
- Ryanoids and Related Compounds. A Total Synthesis of 3-Epiryanodine ( VI). (1993) (1)
- Synthesis of E and Z Alkyl Tetrahydro-2-Pyrilidene and Tetrahydro-2-Furylidene Acetates (1985) (1)
- Functionalized bicyclo[4.4.0]decane from double Michael addition reaction (1989) (1)
- Functionalized hydrocarbons with condensed ring skeletons. VI. A tricyclo[8.4.0.03,8]tetradec-1-ene and its parent fourteen-membered dimethyl macrocycle (1991) (1)
- Diastereoselectivity in the transannular Diels-Alder reaction of a trans-trans-trans 14-membered macrocycle leading to steroids (1997) (1)
- The Total Synthesis of (+)-Ryanodol. Part 4. Preparation of (+)-Ryanodol from (+)-Anhydroryanodol. (1990) (1)
- The acid-catalyzed oxido-reduction of spiroketals. Evidence for stereoelectronic control in hydride transfer to cyclic oxenium ions (1981) (1)
- A New Allylidene Phosphorane Reagent for the Efficient Conversion of Aldehydes to γ,δ-Unsaturated Allyl β-Ketoesters. (2001) (1)
- Suppression of eukaryotic initiation factor 4E prevents chemotherapy-induced alopecia (2013) (1)
- Studies on the Formation of 14‐Membered Macrocycles by Intramolecular Michael Addition. (1995) (1)
- Intramolecular Michael Addition of Cyclic β‐Ketoester on Conjugated Olefinic Ketone, a Stereoelectronically Controlled Process. (1987) (1)
- Transannular Diels-Alder Cyclization of a Substituted 13-Membered Macrocyclic Triene. An Approach to the A.B.C.(6.6.5) Rings of the Veratrum Alkaloids. (1993) (1)
- A Highly Efficient Access to Spiroketals, Mono‐Unsaturated Spiroketals, and Furans: Hg(II)‐Catalyzed Cyclization of Alkyne Diols and Triols. (2011) (1)
- Total Synthesis of (+)‐Cassaine Utilizing an Anionic Polycyclization Strategy. (2014) (1)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 9. A Trioxotricyclo(8.4.0.02,7)tetradecane. (1991) (1)
- Bent Bonds, the Antiperiplanar Hypothesis and the Theory of Resonance. A Simple Model to Understand Reactivity in Organic Chemistry (2011) (1)
- First Evidence of a Chair‐Boat‐Boat Transition State in the Transannular Diels‐Alder Reaction. (1994) (0)
- Functionalized Bicyclo(4.4.0)decane from Double Michael Addition Reaction. (1989) (0)
- Spatially-defined macrocyclic compounds that are useful for drug discovery (2004) (0)
- THERMAL DECOMPOSITION OF OZONIDES. A COMPLEMENTARY METHOD TO THE BAEYER-VILLIGER OXIDATION OF HINDERED KETONES (1980) (0)
- SYNTHESIS OF 1-AZATWISTANE (1976) (0)
- One-Step Construction of a 13α-Methyl 14α-Hydroxy Steroid via a New Anionic Polycyclization Method. (1989) (0)
- SYNTH. VON 2,3-DIHYDRO-TRICHINACENON-(2) (1971) (0)
- ELECTRONIC DISTRIBUTIONS AND CHEMICAL EFFECTS. XXVIII. THEORETICAL AND EXPERIMENTAL STUDY OF TRICYCLO(4.4.0.03,8)DECANE (“TWISTANE”) (1982) (0)
- 1994 R.U. Lemieux Award Lecture. Hydrolysis of Acetals and Ketals. Position of Transition States Along the Reaction Coordinates, and Stereoelectronic Effects. (1995) (0)
- Synthesis and Transannular Diels‐Alder Reaction of a 13‐Membered Macrocyclic Triene Having a Tetrasubstituted Enol Ether as a Dienophile. (1988) (0)
- A Simple and Direct Method of Cyclization for the Synthesis of 10‐Membered Rings. (1987) (0)
- NEW EVIDENCE OF STEREOELECTRONIC CONTROL FROM THE BASIC HYDROLYSIS OF ESTERS, LACTONES, AMIDES AND LACTAMS. CARBONYL OXYGEN EXCHANGE. REVERSIBLE RING OPENING OF LACTAMS AND LACTONES (1977) (0)
- Total Synthesis of (+)-Cassaine via Transannular Diels—Alder Reaction. (2009) (0)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 14. A Dioxotricyclo(8.4.0.02,7)tetradec‐6‐ene (2010) (0)
- Synthesis of Z- and E-3,4-Dimethylhex-3-ene-1,6-diols. (1990) (0)
- Stereocontrolled Synthesis of a trans-anti-trans Tricycle via a Transannular Diels-Alder Strategy. (1989) (0)
- Transannular Diels-Alder Reaction of Trans-Trans-Trans 15-Membered Macrocyclic Trienes (I), (IV). (1993) (0)
- Stereocontrolled Construction of A.B.C.(6.6.6) Tricycle via Transannular Diels‐Alder Reaction of 14‐Membered Macrocycle with Acetylene as Dienophile. (2010) (0)
- Transannular Diels—Alder Model Studies on the Total Synthesis of Chatancin. The Furanophane Approach. Part 2. Macrocyclization and Diels—Alder Reaction. (1999) (0)
- Transannular Diels‐Alder Reaction of 14‐Membered Macrocyclic Trienes. Part 2. Experimental Results and Synthetic Potential. (1988) (0)
- Studies on the Transannular Diels‐Alder Reaction of 15‐Membered Macrocyclic Trienes Containing a trans‐trans Diene. Part 2. Evidence for Unsymmetrical Transition States in the Formation of A.B.C.(6.6.7) Tricyclic Products. (1996) (0)
- First Transannular Diels-Alder Reactions Involving Tetrasubstituted Non-Activated Dienophiles. (1995) (0)
- Pyranophane Transannular Diels—Alder Approach to (+)‐Chatancin (I): A Biomimetic Asymmetric Total Synthesis. (2004) (0)
- TOTALSYNTH. VON (+)-OCCIDENTALOL (1972) (0)
- The Acid-catalyzed Oxidoreduction of Spiroketals. Evidence for Seteroelectronic Control in Hydride Transfer to Cyclic Oxenium lons (1981) (0)
- Expedient Synthesis of a 5α-Steroid Using the Transannular Diels- Alder Strategy. (1997) (0)
- Combination Synthesis of libraries of macrocyclic compounds that are useful for drug discovery (2000) (0)
- Increasing the Efficiency of the Transannular Diels-Alder Strategy via Stille Macrocyclizations. (2001) (0)
- The Total Synthesis of (+)-Ryanodol. Part 2. Model Studies for Rings B and C of (+)-Anhydroryanodol. Preparation of a Key Pentacyclic Intermediate. (1990) (0)
- Anomeric and Reverse Anomeric Effect. A Simple Energy Decomposition Model for Acetals and Protonated Acetals (1993) (0)
- Transannular Diels—Alder Reaction Studies with an Activated Dienophile. An Enantioselective Synthesis of an A.B.C.[6.6.6.] trans-syn-cis Tricycle. (1998) (0)
- Synthesis of 14‐Hydroxy Steroids. Total Synthesis of Methyl 14β‐ Hydroxy‐1,7,17‐trioxo‐5β,8‐androstene‐10β‐oate and Related Compounds. (1991) (0)
- Synthesis of cis‐Decalin via Diels‐Alder and Double Michael Cycloaddition with Substituted Nazarov Reagent. (1989) (0)
- Synthese totale de 14 beta-fluorosteroides via la reaction de diels-alder transannulaire (2003) (0)
- Facile Synthesis of Methyl 2‐Formyl‐5‐hydroxymethyl‐3‐furancarboxylate. (1999) (0)
- MECHANISM OF HYDROLYSIS OF IMIDATE SALTS. IMPORTANCE OF STEREOELECTRONIC CONTROL AND PH OF THE REACTION MEDIUM ON THE CLEAVAGE OF TETRAHEDRAL INTERMEDIATES (1976) (0)
- Total Synthesis of (.+-.)-Momilactone A (I). (2003) (0)
- Transannular Diels—Alder Studies on the Asymmetric Synthesis of (+)-Maritimol. (1999) (0)
- Conformational Analysis of 1-Oxaspiro(5.5)undecanes. A Powerful Probe for the endo and the exo Anomeric Effects in Acetals (1990) (0)
- Synthesis of (+)-Cassaine (2009) (0)
- SYNTH. VON DELTA(2,6)-1-METHYL-TRICYCLO(5,2,2,0(2,6))UNDECENON-(8) (1972) (0)
- Stereocontrolled Synthesis of Optically Active 14β‐Hydroxy Steroids and Other Steroid Derivatives. (1993) (0)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 8. A Dimethyl‐Substituted Tricyclo(8.4.0.02,7)tetradec‐8‐ene. (1991) (0)
- Stereoselective Synthesis of cis-Decalins via Diels-Alder and Double Michael Addition of Substituted Nazarov Reagents. (1993) (0)
- Synthesis of Ouabain (2008) (0)
- Transannular Diels‐Alder Reaction on Macrocycles. A General Strategy for the Synthesis of Polycyclic Compounds (2010) (0)
- CARBON-13 CHEMICAL SHIFT DATA FOR 1,7-DIOXASPIRO(5.5)UNDECANES AND RELATED COMPOUNDS (1981) (0)
- THE TOTAL SYNTHESIS OF (.+-.)HINESOL AND (.+-.)EPIHINESOL (1981) (0)
- Synthesis and Transannular Diels-Alder Reaction of a trans-cis-cis 13-Membered Macrocyclic Trienone (IV). (1988) (0)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 6. A Tricyclo(8.4.0.03,8)tetradec‐1‐ene (I) and Its Parent Fourteen‐ Membered Dimethyl Macrocycle (1991) (0)
- Highly Stereoselective Double Michael Cyclization of 1-Phenylsulfinyl and Sulfonyl Analogues of the Nazarov Reagent. (1991) (0)
- 14‐Membered Macrocycles: Methyl trans‐(10E)‐5‐Methyl‐8‐methylene‐11,15‐dioxobicyclo[12.3.0]heptadec‐4‐ene‐14‐carboxylate, (I), and Methyl trans‐(2E,10E)‐10‐Methyl‐7‐methylene‐4,17‐dioxobicyclo[12.3.0]heptadeca‐2,10‐diene‐1‐carboxylate, (II) (1996) (0)
- Transannular Diels-Alder Reactions on 14-Membered Macrocyclic Trienes. Part 1. Stereoselective Syntheses of the Macrocyclic Trienes Precursors. (1993) (0)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 5. Substituted 1,2-Dimethyltricyclo(8.4.0.02,7)tetradec-8-ene (1990) (0)
- Theoretical and Experimental Determination of the Effects Govering the Transannular Diels—Alder Reaction of trans—trans—cis Systems with or without Activation of the Dienophile. (2001) (0)
- Transannular Diels—Alder Studies of 14-Membered cis—trans—trans Macrocyclic Trienes Having Allylic Ether or Enone Dienophile. (2010) (0)
- Selective Synthesis of trans-anti-cis (TAC) or cis-anti-trans (CAT) Tricycles from the Transannular Diels-Alder of TTT Macrocyclic Trienes. (1994) (0)
- CCDC 173471: Experimental Crystal Structure Determination (2002) (0)
- Total Asymmetric Synthesis of the Aphidicolin Derivative (11R)‐(‐)‐8‐Epi‐11‐hydroxyaphidicolin Using Tandem Transannular Diels—Alder/Aldol Reactions. (2000) (0)
- Synthesis and Transannular Diels-Alder Reaction of a cis-trans-trans and a trans-cis-cis 13-Membered Macrocyclic Trienone. (1990) (0)
- Functionalized Hydrocarbons with Condensed Ring Skeletons. Part 10. A Methyltricyclo(7.4.0.02,6)tetradec‐7‐ene (1991) (0)
- A New Bis(2,2,2‐trifluoroethyl)phosphonate for the Synthesis of Z‐Unsaturated N‐Methoxy‐N‐methylamides. (2003) (0)
- A new mechanism for the thermal and photochemical Diels-Alder cycloaddition based on the bent bond /antiperiplanar hypothesis orbital model (2022) (0)
- Synthesis of cis-Decalin and Tricyclic Compounds via Anionic Cycloaddition with Substituted Nazarov Reagents. (1991) (0)
- Expedient Synthesis of a 5α-Steroid Using the Transannular Diels-Alder Strategy (2000) (0)
- SYNTH. VON 1-AZA-TWISTAN (1970) (0)
- Studies Directed Towards the Total Synthesis of Aldosterone and Naturally Occurring Analogues. A Unified Approach Using the Transannular Diels—Alder Reaction. (1998) (0)
- CCDC 173472: Experimental Crystal Structure Determination (2002) (0)
- Synthesis of an Optically Active 13β‐Methyl 14β‐Hydroxy Steroid via Base‐Catalyzed Reactions. (1991) (0)
- SYNTHESIS OF E AND Z ALKYL TETRAHYDRO‐2‐PYRANYLIDENE AND TETRAHYDRO‐2‐FURYLIDENE ACETATES (1985) (0)
- Combinatorial production of libraries of macrocyclic compounds for discovery of pharmaceutical active ingredients (2000) (0)
- Transannular Diels‐Alder/Intramolecular Aldol Tandem Reaction as a Stereocontrolled Route to (+)‐Aphidicolin and Its Isosteric C8‐Epimer. (1996) (0)
- contain spatially defined macrocycles, the peptide bond surrogate (2004) (0)
- A Stereospecific Transannular Diels-Alder Approach to the (6.6.7) Tricyclic Skeleton Related to Aphidicolin and Scopadulan Natural Products. (1996) (0)
- transition states in the formation of A.B.C.(6.6.7) tricyclic products1 (1995) (0)
- A NEW SYNTHESIS OF 2,10,11-TRIOXATRICYCLO(4.4.4.01,6)TETRADECANE (1980) (0)
- Stereocontrolled Construction of 1,7-Dimethyl A.B.C.(6.6.6)tricycles. Part 2. Transannular Diels-Alder Reaction of 14-Membered Macrocycles Containing cis-Dienophiles. (1994) (0)
- Selective Synthesis of trans‐anti‐cis (TAC) Tricycles from the Transannular Diels‐Alder of TTT Macrocyclic Trienes. (1994) (0)
- Synthesis of 17‐Membered Ring Macrocycle: Studies Toward the Enantioselective Synthesis of Fusidic Acid. (1998) (0)
- Cyclization of Hydroxyenol Ethers into Spiroacetals. Evidence for the Position of the Transition State and Its Implication on the Stereoelectronic Effects in Acetal Formation. (1992) (0)
- Transannular Diels-Alder Cyclization of Substituted 13-Membered Trienes. An Approach to the B.C.D(6.6.5) Rings of the 14β- Hydroxysteroids. (1996) (0)
- Transannular Diels—Alder Model Studies on the Total Synthesis of Chatancin. The Furanophane Approach. Part 1. Assembly of the Acyclic Substrates. (1999) (0)
- Solid-state stereochemistry of Diels-Alder adducts between a bicyclic cyclohexadienone derivative and α-acyloxyacrylonitrile (1991) (0)
- Study on the Influence of Unsaturations on the Formation of C-11, C-12, C-13 and C- 14 Membered Rings. (1986) (0)
- Transannular Diels—Alder Studies on the Asymmetric Total Synthesis of Chatancin: The Pyranophane Approach. (2001) (0)
- Use of Malonate Connectors in Solid Phase Organic Chemistry. Application to the Synthesis of Macrocarbocycles (2000) (0)
- Synthesis of a 14β-Hydroxysteroid Using the Transannular Diels- Alder Strategy. (1997) (0)
- Acyclic 1,5-Stereoselection: Synthesis of the Optically Active Side Chain of Vitamin E. (1987) (0)
- Diastereoselectivity in the Transannular Diels—Alder Reaction of a trans-trans-trans 14-Membered Macrocycle Leading to Steroids. (1998) (0)
- Two 14-Membered Macrocycles with trans-trans and trans-cis Dienes. Trimethyl (2E,4E)-cis- and Trimethyl (2Z,4E)-trans-11,15-Dioxobicyclo[12.3.0]heptadeca-2,4-diene-7,7,14-tricarboxylate (1996) (0)
- Stereocontrolled Construction of A.B.C.(6.6.6) Tricycle via Transannular Diels‐Alder Reaction of 14‐Membered Triene Macrocycle. (1991) (0)
- we decided to concentrate on that one alone. We were attracted by the tricyclic structure (1977) (0)
- Unique trans-syn-cis [6.6.7] Tricycle Derivative from Transannular Diels—Alder Contraction of a Model 15-Membered trans-cis-cis Macrocyclic Triene. (1998) (0)
- Synthesis and Transannular Diels‐Alder Reaction of a cis‐trans‐trans 13‐Membered Macrocyclic Trienone. (1988) (0)
- Formation of 14‐Membered Carbocycles by Intramolecular Michael Reaction of Cyclic β‐Ketoesters on Enones and Ynones. (1995) (0)
- defindos macrocyclic compounds especially useful for drug discovery. (2004) (0)
- Formation of 14-Membered Carbocycles by Intramolecular Michael Addition on Ynones and Enones. (2010) (0)
- Stereocontrolled Synthesis of Acyclic Tri- and Tetra-C-Substituted . alpha.-Alkoxymethyl α,β-Unsaturated Esters. (1994) (0)
- Application of the Variable Oxygen Probe to Derivatives of 2,6-Dimethyltetrahydropyran-4-ol: Evidence for Through-Bond nO–σCC–σ*CO Interactions (2020) (0)
- Stereocontrolled Chiral Synthesis of a trans-anti-trans Tricycle by a Transannular Diels-Alder Reaction. (1993) (0)
- Transannular Diels-Alder Reactions on 14-Membered Macrocyclic Trienes. Part 2. Formation of Macrocycles and Thermal Conversion into Tricyclic Systems. (1993) (0)
- Crystallographic Evidence of [1,5]Prototropic Shifts Occurring Upon Transannular Diels—Alder Reaction of a 14-Membered Macrocycle Leading to a 5α-Steroid Skeleton. (1998) (0)
- Progress Toward the Total Synthesis of Cassaine via the Transannular Diels—Alder Strategy. (2001) (0)
- Mechanism of the Diels—Alder Reaction of Enal Dienophiles. Competitive Reactivity and ab initio Calculations Using a Transannular Probe. (1999) (0)
- Intramolecular Michael Addition of Cyclic β‐Ketoester on Conjugated Acetylenic Ketone. (1987) (0)
- A new synthesis of twistane1 (1967) (0)
- Macrocyclization of Terminal Bis-allylic Chlorides via an Intramolecular gem-Dialkylation of Malononitrile or Methyl Cyanoacetate. (1999) (0)
- Synthesis of Tricyclic Compounds via Sequential Intramolecular Michael Addition and Alkylation of β-Keto Ester Ynones. (1987) (0)
- Furanophane Transannular Diels—Alder Approach to (+)‐Chatancin: An Asymmetric Total Synthesis of (+)‐Anhydrochatancin. (2004) (0)
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What Schools Are Affiliated With Pierre Deslongchamps?
Pierre Deslongchamps is affiliated with the following schools:
