Pierre Vogel

Pierre Vogel's AcademicInfluence.com Rankings

Pierre Vogel

Biology

#6762

World Rank

#9551

Historical Rank

Biochemistry

#889

World Rank

#997

Historical Rank

biology Degrees

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Biology

Pierre Vogel's Degrees

Bachelors Biochemistry University of Zurich
Masters Biochemistry University of Zurich
PhD Biochemistry ETH Zurich

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Pierre Vogel's Published Works

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Published Works

Organosulfur compounds: electrophilic reagents in transition-metal-catalyzed carbon-carbon bond-forming reactions. (2005) (233)
Chemoselective C-H bond activation: ligand and solvent free iron-catalyzed oxidative C-C cross-coupling of tertiary amines with terminal alkynes. Reaction scope and mechanism. (2009) (166)
Challenges in the Discovery of Indoleamine 2,3-Dioxygenase 1 (IDO1) Inhibitors. (2015) (162)
Assignment of the Absolute Configuration of Natural Lentiginosine by Synthesis and Enzymic Assays of Optically Pure (+) and (-)-Enantiomers (1995) (156)
Rational design of indoleamine 2,3-dioxygenase inhibitors. (2010) (144)
Rational design of 4-aryl-1,2,3-triazoles for indoleamine 2,3-dioxygenase 1 inhibition. (2012) (141)
Palladium-catalyzed Stille cross-couplings of sulfonyl chlorides and organostannanes. (2003) (132)
Evidence for protonated cyclopropane intermediates from studies of stable solutions of carbonium ions (1973) (119)
Palladium-catalyzed Suzuki-Miyaura cross-couplings of sulfonyl chlorides and boronic acids. (2004) (118)
Derivatives of 7-oxabicyclo[2.2.1]heptane in nature and as useful synthetic intermediates (1999) (113)
Iron-catalyzed desulfinylative C-C cross-coupling reactions of sulfonyl chlorides with grignard reagents. (2008) (109)
Glycosidase inhibitors as potential HIV entry inhibitors? (2004) (108)
Palladium-catalyzed desulfitative Mizoroki-Heck couplings of sulfonyl chlorides with mono- and disubstituted olefins: rhodium-catalyzed desulfitative heck-type reactions under phosphine- and base-free conditions. (2005) (97)
The Preparation of Optically Pure 7-Oxabicyclo[2.2.1]Hept-2-Ene Derivatives - the Cd Spectrum of (+)-(1r)-7-Oxabicyclo[2.2.1]Hept-5-En-2-One (1983) (87)
New organic chemistry of sulfur dioxide. (2007) (80)
Functionalized pyrrolidines inhibit alpha-mannosidase activity and growth of human glioblastoma and melanoma cells. (2005) (78)
Optically Pure 7-Oxabicyclo[2.2.1]Hept-5-En-2-Yl Derivatives (Naked Sugars) as New Chirons (1990) (77)
The first synthesis of substituted azepanes mimicking monosaccharides: a new class of potent glycosidase inhibitors. (2004) (76)
Naked Sugars as Synthetic Intermediates - Total Synthesis of L-Daunosamine (1986) (73)
Total, Asymmetric-Synthesis of (+)-Castanospermine, (+)-6-Deoxycastanospermine, and (+)-6-Deoxy-6-Fluorocastanospermine (1991) (69)
Total Syntheses of (−)-Conduritol B ((−)-1L-Cyclohex-5-ene-1,3/2,4-tetrol) and of (+)-Conduritol F((+)-1D-Cyclohex-5-ene-1,2,4/3-tetrol). Determination of the Absolute Configuration of (+)-Leucanthemito† (1990) (68)
Enantiomerically Pure 7-Oxabicyclo[2.2.1]Hept-5-En-2-Yl Derivatives as Synthetic Intermediates .3. Total Synthesis of D-Ribose and L-Ribose Derivatives (1988) (68)
Optical resolution of 7-oxabicyclo[2.2.1]hept-21-ene derivatives. Diastereoselectivity in the formation of cyanohydrine-brucine complexes (1984) (66)
Synthesis and glycosidase inhibitory activity of 7-deoxycasuarine (2003) (64)
New concise total synthesis of (+)-lentiginosine and some structural analogues. (2005) (64)
Copper(I)‐ and Copper(II)‐catalyzed Diels‐Alder Additions of α‐Substituted Acrylonitrile to Furan. The Synthesis of 7‐Oxa‐bicyclo[2.2.1]hept‐5‐en‐2‐one (1982) (63)
Iron/copper-catalyzed C–C cross-coupling of aryl iodides with terminal alkynes (2008) (63)
New Chiral Auxiliaries and New Optically Pure Ketene Equivalents Derived from Tartaric-Acids - Improved Synthesis of (-)-7-Oxabicyclo[2.2.1]Hept-5-En-2-One (1990) (62)
Regioselectivity of electrophilic additions to 7-oxabicyclo[2.2.1]heptenes controlled by remote substituents. Arenesulfonyl substituted 7-oxabicyclo[2.2.1]heptenes as stereo- and regioselective chiral dienophiles (1986) (62)
Iron‐Catalyzed Mizoroki–Heck Cross‐Coupling Reaction with Styrenes (2008) (62)
(1S,2S,7R,8aS)- and (1S,2S,7S,8aS)-trihydroxyoctahydroindolizine: Two new glycosidase inhibitors by nitrone cycloaddition strategy (1996) (59)
Detailed analysis and follow-up studies of a high-throughput screening for indoleamine 2,3-dioxygenase 1 (IDO1) inhibitors. (2014) (58)
Synthesis of (−)‐Conduritol C (1L‐Cyclohex‐5‐ene‐1,2,3/4‐tetrol) (1989) (58)
Total Asymmetric Syntheses of 1,5-Dideoxy-1,5-Iminooctitols and 1,2,6,7,8-Pentahydroxyindolizidines (1994) (57)
One-Pot Synthesis of Cyclic Nitrones and Their Conversion to Pyrrolizidines: 7a-epi-Crotanecine Inhibits α-Mannosidases (2006) (55)
Palladium-catalyzed desulfitative Sonogashira-Hagihara cross-couplings of arenesulfonyl chlorides and terminal alkynes (2004) (54)
Synthesis and Biological Properties of Monothiosaccharides (2001) (52)
Syntheses of (+)- and (-)-Methyl 8-Epinonactate and (+)- and (-)-Methyl Nonactate (1987) (51)
Recent Synthetic Approaches Toward Non-anomeric Spiroketals in Natural Products (2008) (51)
Face Selectivity of the Diels‐Alder Additions of Exocyclic Dienes Grafted onto 7‐Oxabicyclo[2.2.1]heptanes (1982) (51)
An Efficient Synthesis of 2,3,5,6-Tetramethylidene-7-oxanorbornane† (1980) (51)
Structural Insights into the Specificity of Xyn10B from Paenibacillus barcinonensis and Its Improved Stability by Forced Protein Evolution* (2009) (51)
The π-Anisotropy of the Double Bond of a syn-11-Oxasesquinorbornene Derivative.. Stereoselectivity of the Diels–Alder additions of (2-norborneno)[c]furan. Crystal structure of 11-oxa-endo-tetracyclo[6.2.1.13,6.02,7]-dodec-2(7)-ene-9,10-exo-dicarboxylic anhydride†‡ (1981) (50)
Synthesis of (±)-4-Demethoxydaunomycinone by Double Diels-Alder Additions to 2, 3, 5, 6-Tetramethylidene-7-oxanorbornane† (1980) (49)
New Synthetic Seven‐Membered 1‐Azasugars Displaying Potent Inhibition Towards Glycosidases and Glucosylceramide Transferase (2008) (46)
New method for measuring equilibrium deuterium isotope effects. Isomerization of 3-deuterio-2,3-dimethylbutyl-2-ium ion (1971) (45)
Total Synthesis of L-Allose, L-Talose, and Derivatives (1989) (45)
Total, Asymmetric-Synthesis of Deoxypolyoxin-C (1990) (45)
Synthesis of novel pyrrolidine 3,4-diol derivatives as inhibitors of alpha-L-fucosidases. (2009) (44)
Acid-catalyzed rearrangements of 5-6-exo-epoxy-7-oxabicyclo[2.2.1]hept-2-yl derivatives. Migratory aptitudes of acyl vs. alkyl groups in Wagner-Meerwein transpositions (1987) (44)
Enantiomerically pure 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives (naked sugars) as synthetic intermediates. 18. Synthesis of .alpha.-(1.fwdarw.2)-, .alpha.-(1.fwdarw.3)-, .alpha.-(1.fwdarw.4)-, and .alpha.-(1.fwdarw.5)-C-linked disaccharides through 2,3,4,6-tetra-O-acetylglucopyranosyl radical ad (1992) (44)
Derivatives of (2R, 3R, 4S)-2-aminomethylpyrrolidine-3,4-diol are selective α-mannosidase inhibitors (2001) (42)
Synthesis, Biological Evaluation and Docking Studies of Casuarine Analogues: Effects of Structural Modifications at Ring B on Inhibitory Activity Towards Glucoamylase (2010) (42)
Inhibition Mechanisms of Indoleamine 2,3-Dioxygenase 1 (IDO1). (2019) (42)
Amino(hydroxymethyl)cyclopentanetriols, an Emerging Class of Potent Glycosidase Inhibitors—Part I: Synthesis and Evaluation of β‐D‐Pyranoside Analogues in the manno, gluco, galacto, and GlcNAc Series (2001) (41)
Synthesis and conformational analysis of (alpha-D-galactosyl)phenylmethane and alpha-,beta-difluoromethane analogues: interactions with the plant lectin viscumin. (2009) (41)
Sulfur dioxide mediated one-pot, three- and four-component syntheses of polyfunctional sulfonamides and sulfonic esters: study of the stereoselectivity of the ene reaction of sulfur dioxide. (2004) (40)
Non-planarity of pi-systems in 5,6-bis(methylene)-7-oxanorborn-2-ene (1981) (40)
Design and synthesis of acetamido tri- and tetra-hydroxyazepanes: potent and selective beta-N-acetylhexosaminidase inhibitors. (2009) (40)
Spirocyclopropyl pyrrolidines as a new series of α-l-fucosidase inhibitors (2006) (40)
Syntheses and Glycosidase Inhibitory Activities of 2‐(Aminomethyl)‐5‐(hydroxymethyl)pyrrolidine‐3,4‐diol Derivatives (2004) (39)
The 7,8-epoxy-2,3,5,6-tetrakis(methylene) bicyclo[2.2.2]octane; synthesis and diels-alder reactivity (1980) (38)
Synthesis and Diels‐Alder Reactivity of 2,3,5,6‐Tetramethylidenenorbornane (1981) (38)
Regioselective Additions of Electrophiles to Olefins Remotely Perturbed - the Carbonyl Group as a Homoconjugated Electron Donating Substituent (1982) (37)
Iron and Molybdenum Carbonyls of 5,6-Dimethylene-7-Oxabicyclo[2.2.1]Hept-2-Ene - Crystal and Molecular-Structure of (C8H8O)Fe2(Co)7 (1978) (37)
Site of Protonation and Conformational Effects on Gas-Phase Basicity in Beta-Amino Alcohols - the Nature of Internal H-Bonding in Beta-Hydroxy Ammonium-Ions (1983) (36)
New leads for selective inhibitors of alpha-L-fucosidases. Synthesis and glycosidase inhibitory activities of [(2R,3S,4R)-3,4-dihydroxypyrrolidin-2-yl]furan derivatives. (2001) (36)
Iron and ruthenium carbonyls of 2,3,5,6-tetrakis(methylene)bicyclo[2.2.2]octane. Crystal and molecular structure of (C12H14)Fe(CO)3 (1979) (36)
Synthesis and Diels‐Alder Reactivity of 5,6,7,8‐Tetramethylidene‐2‐bicyclo[2.2.2]octanol and ‐octanone. Selective Oxidations of the Corresponding Bis(irontricarbonyl) Complexes (1983) (36)
An Efficient Combinatorial Method for the Discovery of Glycosidase Inhibitors (2002) (35)
α- and β-Homogalactonojirimycins (α- and β-Homogalactostatins): synthesis and further biological evaluation (2001) (34)
A short and convenient synthesis of 1-deoxymannojirimycin and N-oxy analogues from D-fructose. (2009) (34)
Stereoselective synthesis of (2S,3S,4R,5S)-5-methylpyrrolidine-3,4-diol derivatives that are highly selective alpha-L-fucosidase inhibitors. (2005) (34)
Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids. (2005) (33)
Search for alpha-glucosidase inhibitors: new N-substituted valienamine and conduramine F-1 derivatives. (2006) (33)
Stereoselective syntheses of 1,4-dideoxy-1,4-imino-octitols and novel tetrahydroxyindolizidines. (2003) (32)
Synthesis of seven- and eight-membered carbasugar analogs via ring-closing metathesis and their inhibitory activities toward glycosidases (2002) (32)
Synthesis of C‐Linked Imino Disaccharides (= Aza‐C‐disaccharides) with a Pyrrolidine‐3,4‐diol Moiety Attached at C(3) of Galactose via a Hydroxymethylene Linker and of a 7‐(1,2,3‐Trihydroxypropyl)‐octahydroxyindolizine‐1,2,6,8‐tetrol (1998) (32)
Tandem Staudinger-azaWittig mediated ring expansion: rapid access to new isofagomine-tetrahydroxyazepane hybrids. (2007) (32)
Hetero-Diels-Alder addition of sulfur dioxide to 1,3-dienes. Suprafaciality, regioselectivity, and stereoselectivity (1992) (31)
Total Synthesis of Cyclophellitol Starting from Furan (1992) (31)
A critical role of autophagy in antileukemia/lymphoma effects of APO866, an inhibitor of NAD biosynthesis (2014) (31)
C-Glycosides and C-disaccharide precursors through carbonylative Stille coupling reactions (1997) (31)
The spirocyclopropyl moiety as a methyl surrogate in the structure of l-fucosidase and l-rhamnosidase inhibitors. (2009) (31)
Synthesis of amino- and diaminoconduritols and their applications (2006) (31)
Development of a new carbon-carbon bond forming reaction. new organic chemistry of sulfur dioxide. Asymmetric four-component synthesis of polyfunctional sulfones. (2001) (31)
Synthesis and glycosidase inhibitory activities of 2-(aminoalkyl)pyrrolidine-3,4-diol derivatives. (2003) (30)
The C-disaccharide alpha-C(1-->3)-mannopyranoside of N-acetylgalactosamine is an inhibitor of glycohydrolases and of human alpha-1,3-fucosyltransferase VI. Its epimer alpha-(1-->3)-mannopyranoside of N-acetyltalosamine is not. (2000) (30)
Nucleophilic opening of epoxyazepanes: expanding the family of polyhydroxyazepane-based glycosidase inhibitors. (2006) (30)
Palladium-catalyzed desulfinylative Negishi C–C bond forming cross-couplings of sulfonyl and organozinc chlorides (2006) (30)
Synthesis and alpha-Mannosidase Inhibitory Evaluation of (2R,3R,4S)- and (2S,3R,4S)-2-(Aminomethyl)pyrrolidine-3,4-diol Derivatives (2003) (29)
Experimental and Abinitio Molecular-Orbital Studies on Collisions of Ch4+. and Ch5+ with Molecular-Oxygen - on the Formation of Methane (Ch4(2+)) and Methonium (Ch5(2+)) Dications and Stable Chn-Species (N = 0-3) (1985) (29)
New 1-amino-1-deoxy- and 2-amino-2-deoxy-polyhydroxyazepanes: synthesis and inhibition of glycosidases (2005) (29)
Preparation and Diels‐Alder Reactivity of 2,3,5,6,7,8‐Hexamethylidenebicyclo [2.2.2]octane (‘[2.2.2]Hericene’). Force‐field calculations of exocyclic dienes as a moiety of bicyclic skeletons (1983) (29)
C(1 -> 4)-linked disaccharides through carbonylative Stille cross-coupling (2005) (29)
The carbonyl group as homoconjugated electron donating substituent. Ab initio STO 3G MO calculations (1984) (29)
Interaction between Non-Conjugated Chromophores .14. Regioselectivity of the Diels-Alder Additions of 2-Substituted 5,6-Dimethylidenenorbornanes and Dimethylidenebicyclo[2.2.2]Octanes (1982) (29)
Peptide-Based Materials (2012) (28)
Ligandless Iron-Catalyzed Desulfinylative C-C Allylation Reactions using Grignard Reagents and Alk-2-enesulfonyl Chlorides (2009) (28)
Bicyclo[3.1.0]hex-3-en-2-y1 cation (1971) (28)
Synthesis of enantiomerically pure 1,2-diamine derivatives of 7-azabicyclo[2.2.1]heptane. New leads as glycosidase inhibitors and rigid scaffolds for the preparation of peptide analogues. (2003) (28)
Highly stereoselective total syntheses of 2,5-anhydro-3-deoxy- and -4-deoxy-D-hexonic acids and of the related deoxyadenosines-C (1990) (28)
1,2,3-Triazoles as inhibitors of indoleamine 2,3-dioxygenase 2 (IDO2). (2016) (28)
Polyhydroxypyrrolidine Glycosidase Inhibitors Related to (+)-Lentiginosine (2000) (28)
Synthesis of rare carbohydrates and analogues starting from enantiomerically pure 7-oxabicyclo[2.2.1]heptyl derivatives ("naked sugars") (2000) (28)
Reductive oxa ring opening of 7-oxabicyclo[2.2.1]heptan-2-ones. Synthesis of C-alpha-galactosides of carbapentopyranoses (1995) (28)
Peptide-Based Materials (2012) (28)
Total asymmetric synthesis of (-)-conduramine B-1 and of its enantiomer. N-Benzyl derivatives of conduramine B-1 are beta-glucosidase inhibitors. (2005) (28)
Synthesis of α-D-(1→3) and α-D-(1→4)-C-linked galactosides of D-mannose derivatives. Conformation of α-C-galactosides.☆ (1994) (27)
Desulfinylation of prop-2-enesulfinic acid: experimental results and mechanistic theoretical analysis. (2009) (27)
A doubly-convergent and regioselective synthesis of (±)-daunomycinone (1984) (27)
Total synthesis of the gastroprotective substance AI-77-B and of analogues (1993) (27)
Stereoselective control in the base-catalyzed H-d exchange reaction of 5,6,7,8-tetrakis(methylene)-2-bicyclo[2.2.2]octanone irontricarbonyl complexes (1983) (26)
Iron, molybdenum and tungsten carbonyls of 5,6,7,8-tetrakis(methylene)bicyclo[2.2.2]oct-2-ene. Crystal and molecular structure of (C12H12)Fe(CO)3 (1979) (26)
Selective Hydrogen-Chloride Elimination from Primary Chlorides Induced by the Fluoride Anion - Anchimeric Participation of the Chloromethyl Group in the Heterolytic Opening of an Epoxide Stereospecific Syntheses of 5,6-Bis(Methylidene)-Syn-2-Norbornen-7-Ol and 5,6-Bis(Methylidene)-Endo-3-Chloro-Exo- (1979) (26)
The electron-releasing homoconjugated carbonyl group. Application to the total syntheses of 3-deoxy-, 4-deoxy-hexose, lividosamine and derivatives (1989) (26)
The Demjanov and Tiffeneau-Demjanov one-carbon ring enlargements of 2-aminomethyl-7-oxabicyclo[2.2.1]heptane derivatives. The stereo- and regioselective additions of 8-oxabicyclo[3.2.1]oct-6-en-2-one to soft electrophiles. (1993) (26)
The Non‐planarity of the Bicyclo[2.2.1]hept‐2‐ene Double bond. Crystal Structures of Bicyclo[2.2.2]oct‐2‐ene, Bicyclo[2.2.1]hept‐2‐ene, and Bicyclo[2.1.1]hex‐2‐ene Systems (1984) (26)
Aza-C-disaccharides: Synthesis of 6-deoxygalactonojirimycin beta-C(1->3) linked with D-altrofuranosides and D-galactose (1997) (26)
Enantiomerically pure 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives (naked sugars) as synthetic intermediates. XII. Highly stereoselective total syntheses of octoses and derivatives (1991) (26)
New Dienophiles - 1-Acetylvinyl Arenecarboxylates - Reactivity toward Cyclopentadiene and Exocyclic Dienes (1981) (26)
A new, non-iterative asymmetric synthesis of long-chain 1,3-polyols. (2000) (26)
Interaction between Non‐Conjugated Chromophores: 5,6‐Dimethylidene‐exo‐2‐norborneol, 5,6‐Dimethylidene‐exo, exo‐2,3‐norbornanediol and 5,6‐Dimethylidene‐2‐norbornanone (1977) (26)
A NEW STEREOSELECTIVE AND CONVERGENT APPROACH TO THE SYNTHESIS OF LONG-CHAIN POLYPROPIONATE FRAGMENTS (1994) (25)
A Highly Stereoselective Total Synthesis of (+/-)Castanospermine (1989) (25)
Synthesis of Undeculofuranoside Derivatives of the Herbicidins and of Analogs (1995) (25)
Synthesis and glycosidase inhibitory activities of 5-(1', 4'-dideoxy-1', 4'-imino-d-erythrosyl)-2-methyl-3-furoic acid (=5-[(3s, 4r)-3,4-dihydroxypyrrolidin-2-yl]-2-methylfuran-3-carboxylic acid) derivatives: New leads as selective α-l-fucosidase and β-galactosidase inhibitors (2003) (25)
Carbon-13 n.m.r. spectra of 2,3-dimethylenebicyclo[2.2.1]heptanes and 2,3-dimethylene-7-oxabicyclo[2.2.1]heptanes (1977) (25)
Synthesis of Rare Carbohydrates and Biomolecules from Furan (1990) (25)
The use of levoglucosenone and isolevoglucosenone as templates for the construction of C-linked disaccharides. (2006) (25)
Synthesis and glycosidase inhibitory activity of new penta-substituted C8-glycomimetics (2005) (24)
Total Synthesis of Allonojirimycin (5-Amino-5-Deoxy-D-Allopyranose) (1989) (24)
Novel 2-[(benzylamino)methyl]pyrrolidine-3,4-diol derivatives as alpha-mannosidase inhibitors and with antitumor activities against hematological and solid malignancies. (2010) (24)
The Conformational Behavior of Novel Glycosidase Inhibitors with Substituted Azepan Structures: An NMR and Modeling Study (2004) (24)
Total syntheses of 1,5-dideoxy-1,5-imino-D-erythro-L-allo-octitol and (1S,2R,6R,7R,8S,8aS)-pentahydroxyindolizidine (1992) (23)
Synthesis of a C(29)-C(51) subunit of spongistatin 1 (Altohyrtin A) starting from (R)-3-benzyloxy-2-methylpropan-1-ol. (2000) (23)
Palladium-catalyzed conversion of beta,gamma-unsaturated silyl sulfinates into (E)-alkenes: asymmetric synthesis of polypropionate fragments. (2004) (23)
Total synthesis of the C37C45 F-ring fragment of spongistatins (1998) (23)
Sulfur dioxide mediated one-pot, four-component synthesis of polyfunctional sulfones and sulfonamides, including medium-ring cyclic derivatives (2005) (23)
Organocatalysis: Fundamentals and Comparisons to Metal and Enzyme Catalysis (2016) (23)
The carbonyl group as homoconjugated electron-releasing substituent. Regioselective electrophilic additions at bicyclo[2.2.1]hept-5-en-2-one, bicyclo[2.2.2]oct-5-en-2-one, and derivatives (1989) (23)
Double bond pyramidalization in bicyclic alkanes. Ab initio mo calculations on bicyclo[2.2.1] hept-2-ene, bicyclo[2.2.1] hex-2-ene and bicyclo[3.2.1] oct-6-ene derivatives (1985) (23)
The Synthesis of (+/-)-11-Deoxydaunomycinone Via Regioselective Tandem Diels-Alder Reactions (1985) (23)
The synthesis of disaccharides, oligosaccharides and analogues containing thiosugars (2002) (23)
2,3,5,6-Tetrakis(methylene)-1,4-cyclohexanediyl (1,2,4,5-tetramethylenebenzene), a disjoint non-Kekule singlet hydrocarbon biradical (1993) (23)
O-17 Nuclear Magnetic-Resonance - the Effects of Remote Unsaturation on O-17-Chemical Shifts in Polycyclic Ethers (1980) (22)
Total asymmetric syntheses of d-lividosamine and 2-acetamido-2,3-dideoxy-d-arabino-hexose derivatives. ☆ (1992) (22)
Intramolecular Diels-Alder Reactions of 3h-Pyrroles Resulting from the Thermal Rearrangements of 2h-Pyrroles (1987) (22)
Amides in one pot from carboxylic acids and amines via sulfinylamides. (2014) (22)
Total syntheses of (+)- and (−)-1-deoxynojirimycin (1,5-dideoxy-1,5-imino-d- and l-glucitol) and of (+)- and (−)-1-deoxyidonojirimycin (1,5-dideoxy-1,5-imino-d- and l-iditol) via furoisoxazoline-3-aldehydes (1998) (22)
Chemo- and stereoselective coordination of 5,6-dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene by d8- and d6-metal carbonyls. Diels-Alder reactivity of dienes perturbed by remote olefin complexation (1984) (22)
Mechanism of the diphenyldisulfone-catalyzed isomerization of alkenes. Origin of the chemoselectivity: experimental and quantum chemistry studies. (2006) (22)
The Effects of Homoconjugated Cyclopropane and Oxirane Rings on the Diels-Alder Reactivity of 2,3-bis (methylidene)norbornane†‡§ (1979) (22)
Acid-catalyzed rearrangement of 3-aza-8-oxatricyclo[3.2.1.02,4]octan-6-one acetals. Highly stereoselective total synthesis of 3-amino-3-deoxy-D-altrose and derivatives (1989) (22)
Chemistry of protoadamantane. VI. Bridged and classical polymethyl 2-adamantyl cations (1974) (22)
A new, doubly convergent synthesis of anthracyclinones. Diels-alder additions to 2,3,5,6-tetrakis(methylene)-7-oxanorbornane. (1979) (22)
BCl3-mediated ene reaction of sulfur dioxide and unfunctionalized alkenes. (2010) (21)
Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters (2009) (21)
Thermoneutral Dyotropic Transfer of Hydrogen in a Hydrocarbon (1981) (21)
Hyperconjugative Interactions in Bicyclo[2.2.1)Heptane Derivatives - Effects on Diels-Alder Reactivity of S-Cis-Butadiene Group of 2,3-Dimethylidene-Norbornanes (1976) (21)
Carbohydrates in Sustainable Development I (2010) (21)
Expeditious asymmetric synthesis of a stereoheptad corresponding to the C(19)-C(27)-ansa chain of rifamycins: formal total synthesis of Rifamycin S. (2005) (21)
Equilibrium deuterium isotope effects in systems undergoing rapid rearrangements. Dimethyl-tert-butylcarbonium ion and cyclopentyl cation (1971) (20)
A Kinetically Stable Singlet-State of 1,2,4,5-Tetramethylenebenzene (1992) (20)
Inductive and Polarizability Effects of an Exocyclic Diene‐Iron Tricarbonyl Group. The acetolyses of exo‐ and endo‐irontricarbonyl complexes of 5,6‐dimethylidene‐2‐exo‐norbornyl and 2,3‐dimethylidene‐7‐anti‐norbornyl parabromobenzenesulfonates (1981) (20)
Diels‐Alder Regioselectivity Controlled by Remote Substituents. The Cycloadditions of 1‐(Dimethoxymethyl)‐2,3‐dimethylidene‐ and ‐2,3,5,6‐tetramethylidene‐7‐oxabicyclo[2.2.1]heptanes (1986) (20)
Synthesis of [(2S,3S,4R)-3,4-dihydroxypyrrolidin-2-yl]-5-methylfuran-4-carboxylic acid derivatives: new leads as selective beta-galactosidase inhibitors. (2002) (20)
A C-linked disaccharide analogue of Thomsen-Friedenreich epitope induces a strong immune response in mice. (2012) (20)
Polyhydroxyazepanes mimicking monosaccharides: Synthesis of an α-D-galacto-like iminoheptitol (2004) (20)
Total synthesis of 2-(β-D-ribofuranosyl)thiazole-4-carboxamide (tiazofurin) and of precursors of ribo-C-nucleosides (1989) (20)
Monosaccharide and Disaccharide Mimics: New Molecular Tools for Biology and Medicine (2001) (20)
Nature of the 2-bicyclo[2.1.1]hexyl cation (1973) (20)
Synthesis of d- and l-2,3-trans-3,4-cis-4,5-trans-3,4-dihydroxy-5-hydroxymethylproline and tripeptides containing them. (2004) (20)
Synthesis of long-chain polyketide fragments by reaction of 1,3-dioxy-1,3-dienes with allylsilanes: umpolung with sulfur dioxide. (2004) (20)
First asymmetric synthesis of the cyclohexanone subunit of baconipyrones A and B. Revision of its structure. (2004) (20)
Tandem oxyallylations and retro-ene eliminations. One pot stereoselective synthesis of polypropionate fragments with three contiguous stereogenic centers and one (E)-alkene unit (1997) (20)
π-Facial diastereoselection in [4+2]-cycloadditions of 3,4- epoxy-2-methyleneoxolanes with oxadienes: A short synthesis of spiroketals. (1994) (20)
Substituent Effect on the Competition between Hetero-Diels-Alder and Cheletropic Additions of Sulfur Dioxide to 1-Substituted Buta-1,3-dienes (2002) (19)
Stereoselective synthesis of novel tetrahydroxypyrrolizidines (2004) (19)
Face Selectivity of the Diels‐Alder Additions of 2‐Substituted 5,6‐bis((E)‐chloromethylidene)bicyclo[2.2.2]octanes (1982) (19)
Substituent effects on the regioselectivity of the baeyer-villiger oxidation of 7-oxabicyclo[2.2.1]heptan-2-ones (1992) (19)
A New Approach to the Synthesis of Long-Chain Polypropionates Based on the Diels-Alder Monoadditions of 2,2′-Ethylidenebis[3,5-dimethylfuran]† (1996) (19)
Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors. (1983) (19)
2,3,5,6‐Tetramethylidene‐Bicyclo[2.2.1]Heptane (Preliminary Communication) (1975) (19)
One-pot synthesis of 1-aryl-3-methyl-1,3-dienes using methallyl(trimethyl)silane and aldehydes and their low temperature (Z)->(E) isomerization induced by sulfur dioxide (2005) (19)
One-Pot, Three-Component Synthesis of Open-Chain, Polyfunctional Sulfones (2004) (19)
Facile migration of acyl groups in Wagner-Meerwein transpositions. Acid-catalyzed rearrangements of 5,6-exo-epoxy-7-oxa-2-bicyclo[2.2.1]heptanone and derivatives. (1987) (19)
Allyl, methallyl, prenyl, and methylprenyl ethers as protected alcohols: their selective cleavage with diphenyldisulfone under neutral conditions. (2004) (18)
Optical activity in remotely perturbed exocyclic s‐cis‐butadienes. Preparation and circular dichroism of enantiomerically pure 5,6‐dimethylidene‐2‐norbornyl derivatives (1980) (18)
Synthesis of β-D-(1→3)-C-linked 1,5,6-trideoxy-1,5-iminogalactoside of D-altrose derivatives (1996) (18)
Use of sultines in the asymmetric synthesis of polypropionate antibiotics (2008) (18)
Short and convergent synthesis of (1 -> 3)-C-linked imino disaccharides (aza-C-disaccharides) (1999) (18)
Total synthesis and determination of the absolute configuration of (-)-dolabriferol. (2010) (18)
The norbornene mystery revealed. (2011) (18)
Stereospecific functionalisations of iron carbonyl complexes of 5,6,7,8-tetrakis(methylene)bicyclo[2.2.2]oct-2-ene. Crystal and molecular structure of (C12H12)Fe2(CO)6 (1981) (18)
New carbon-carbon bond formation through oxyallylation of enoxysilanes with sulfur dioxide adduct of 1-methoxybutadiene. Stereoselective synthesis of (Z)-4-methoxy-6-oxoalk-2-enyl methyl sulfones (1997) (18)
A Short and Flexible Route to Aza‐β‐(1→6)‐C‐disaccharides: Selective α‐Glycosidase Inhibitors (1999) (18)
Sulfur dioxide promotes its hetero-Diels-Alder and cheletropic additions to 1,2-dimethylidenecyclohexane (1998) (18)
Synthesis of the C(1)-C(11) polyene fragment of apoptolidin with a new sulfur dioxide-based organic chemistry. (2005) (18)
Highly Stereoselective Total Syntheses of 2,5‐Anhydro‐4‐deoxy‐D‐ribo‐hexonic Acid and of (1S)‐1‐C‐(6‐amino‐7H‐purin‐8‐yl)‐1,4‐anhydro‐3‐deoxy‐D‐erythro‐pentitol (= cordycepin C) (1989) (18)
The bora-ene reaction of sulfur dioxide and prop-2-ene-1-boronic esters. New route to sulfoxides (2006) (18)
The simultaneous double Diels-Alder addition of 1,1-bis(3,5-dimethylfur-2-yl)ethane; toward a new, asymmetric synthesis of long-chain polypropionate fragments and analogues (1996) (18)
Resolution of 7-oxabicyclo[2.2.1]hept-5-en-2-one via cyclic aminals (1999) (17)
Abinitio Mo calculations on the rearrangements of 7-Oxa-2-Bicyclo[2.2.1]Heptyl cations - the facile migration of acyl group in Wagner-Meerwein rearrangements (1988) (17)
The Acetolysis of Exo-5,6-Dimethylidene-2-Norbornyl and Endo-5,6-Dimethylidene-2-Norbornyl Para-Bromobenzenesulfonates and of Their Optically-Active and Deuterium-Labeled Derivatives (1980) (17)
Polysulfones: catalysts for alkene isomerization. (2004) (17)
Interaction between Exocyclic s-cis-Butadiene and Homoconjugated Functions. Preparation and Diels-Alder Reactivity of Remotely Substituted 2,3-Dimethylidenebicyclo[2.2.2]octanes† (1982) (17)
Migratory insertion reactions of norbornene, norbornadiene and 7-oxanorbornene derivatives into the palladium–carbon bond of heterodinuclear Fe–Pd–Acyl complexes. Substrate influence on the Pd coordination sphere and crystal structure of [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)Pd{C9H9NO3C(O)Me}] (1999) (16)
The anti-lymphoma activity of APO866, an inhibitor of nicotinamide adenine dinucleotide biosynthesis, is potentialized when used in combination with anti-CD20 antibody (2014) (16)
Total, asymmetric synthesis of hexoses and azasugars branched at C(5).☆ (1991) (16)
Amide formation in one pot from carboxylic acids and amines via carboxyl and sulfinyl mixed anhydrides. (2013) (16)
Synthesis of enantiomerically pure 7-oxabicyclo[2.2.1]hept-2-enes precursors in the preparation of taxol analogues (1996) (16)
From 2,2'-methylenedifuran to all stereomeric pentadecane-1,3,5,7,9,11,13,15-octols. (2001) (16)
2,5-Bis[[(Z)-(2-Nitrophenyl)Sulfenyl]Methylene]-3,6-Dimethylene-7-Oxabic Yclo[2.2.1]Heptane - a Versatile Reagent for Tandem Regioselective Diels-Alder Reactions (1984) (16)
EQUILIBRIUM DEUTERIUM ISOTOPE EFFECTS IN SYSTEMS UNDERGOING RAPID REARRANGEMENTS. METHYL INTERCHANGE IN DIMETHYLISOPROPYLCARBONIUM ION. (1971) (16)
Synthesis and l-fucosidase inhibitory potency of a cyclic sugar imine and its pyrrolidine analogue (2008) (16)
Scope and limitations of the double [4+3]-cycloadditions of 2-oxyallyl cations to 2,2'-methylenedifuran and derivatives. (2003) (16)
Total asymmetric synthesis of polypropionate fragments and doubly branched heptono-1,4-lactones (1993) (15)
Total synthesis of branched-chain higher-carbon sugars. First synthesis of caldose, calditol and 4-deoxycalditol stereoisomers (1990) (15)
Recent Progress in the Synthesis of Zaragozic Acids and Analogs (2001) (15)
Through-Bond Interactions of Beta-Carbonyl and Beta-Imine Lone Pairs with Cationic 2p Orbital - Quantum Calculations on Bicyclo[2.2.2]Oct-1-Yl Cation and Derivatives (1990) (15)
Radical additions to silyl ketene acetals. Introduction of C-moieties to 7-oxabicyclo[2.2.1]hept-5-en-2-endo-ol (1991) (15)
Asymmetric Synthesis of Complicated Bicyclic and Tricyclic Polypropanoates via the Double Diels-Alder Addition of 2,2'-Ethylidenebis[3,5-dimethylfuran] (2001) (15)
Preparation and Diels-Alder Reactivity of Tricarbonyliron Complexes of [2.2.2]Hericene (1983) (15)
Stereoselective Amino-Hydroxylation of the Double-Bond in 7-Oxabicyclo[2.2.1]Hept-5-En-2-Yl Derivatives - Remote Substituent Participation in Acid-Catalyzed Decompositions of Aziridines and Triazolines (1988) (15)
Charge-transfer bands of bicyclic β,γ-unsaturated ketones. Circular dichroism of (+)-(1R)-5,6-dimethylidene-2-bicyclo[2.2.2]octanone and (+)-(1R)-2-bicyclo[2.2.2]oct-5-enone (1981) (15)
Regioselectivity of 1,3-Dipolar Cycloadditions Controlled by Remote Substitution and Lewis Acid Catalysts (1986) (15)
Synthesis of α-(1→3)- and α-(1→4)-linked c-disaccharides using (+)-7-oxabicyclo[2.2.1]hept-5-en-2-one (“naked sugar”). (1991) (15)
Synthesis of N-Substituted (3S,4S)- and (3R,4R)-Pyrrolidine-3,4-diols: Search for New Glycosidase Inhibitors (2004) (15)
Enantioselective synthesis of (-)-conduramine C1 and aminobromocyclitol derivatives (1994) (15)
New efficient route to an advanced precursor of the AB spiroketal of spongistatins. (2007) (15)
Efficient resolution of N-Boc-7-azabicyclo[2.2.1]hept-5-en-2-one: formal syntheses of natural epibatidine and its enantiomer (2003) (15)
Face selectivity of the Diels-Alder additions of sulfur-substituted dienes and tetraenes grafted onto 7-oxabicyclo[2.2.1]heptanes (1985) (14)
Total asymmetric synthesis of doubly branched carba-hexopyranoses and amino derivatives starting from the Diels-Alder adducts of maleic anhydride to furfuryl esters (1999) (14)
Noniterative approach to the total asymmetric synthesis of 15-carbon polyketides and analogs with high stereodiversity (2005) (14)
'Naked sugars of the second generation': Asymmetric synthesis of long-chain polypropionates and analogues starting with acetone (1996) (14)
Macrocycles by Intramolecular Diels‐Alder Reaction—Regioselective Synthesis of Anthracycline Precursors (1984) (14)
Conduramine F-1 epoxides: synthesis and their glycosidase inhibitory activities (2007) (14)
Enantiomerically pure Diels-Alder adducts of maleic anhydride to furfural acetals through thermodynamic control. Single crystal and molecular structure of (1S,4R,4′S,5′S)-1-(4′,5′-dimethyldioxolan-2′-yl)-5,6-dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene (1996) (14)
(1S,2S,3R,6R)‐6‐Aminocyclohex‐4‐ene‐1,2,3‐triol (= (−)‐Conduramine B‐1) Is a Selective Inhibitor of α‐Mannosidases. Its Inhibitory Activity Is Enhanced by N‐Benzylation (2005) (14)
2,3-Dimethylidenenorbornanes and "2,3,5,6-Tetramethylidenenorbornanes (1977) (14)
Short, stereoselective syntheses of C(1 -> 3)-linked disaccharides (1998) (14)
Interactions between Oxygen Lone-Pair Orbitals and Double-Bond Pi-Orbitals in Beta,Gamma-Unsaturated, Bicyclic Ketones - a Pe-Spectroscopic Investigation (1987) (14)
Control of the Diels‐Alder‐Addition Regioselectivity by Remote Olefins. Syntheses and Cycloadditions of 2,3,5‐Trimethylidenebicyclo[2.2.1]heptane and 2,3,5,6,7‐Pentamethylidenebicyclo[2.2.2]octane (1986) (14)
Secondary 2-Norbornyl Cation Intermediates Substituted at C(5) and C(7) by Electron-Withdrawing Groups - Addition of Fluorosulfuric Acid to Unsaturated Norbornane Derivatives (1979) (14)
Structure of Tricarbonyl(diene)iron Complexes in Solution. Variable‐Temperature Circular Dichroism of trans‐μ‐(2,3,5,6‐Tetramethylidenebicyclo[2.2.2]octane)bis(tricarbonyliron) Complexes (1986) (14)
Asymmetric Synthesis of the Polyol Subunit of the Polyene Macrolide Antibiotic RK‐397 (2006) (14)
Specific, uncompetitive inhibition of beta-galactosidases by a 5,6-isopropylidenedioxyfuro[2,3-d]isoxazole-3-methanol derivative. (1999) (14)
Face Selectivity in the Diels-Alder Additions and Chelotropic Addition of Sulfur-Dioxide to 2-(D)Methylidene-3-Methylidenebicyclo[2.2.1]Heptane (1985) (14)
Dihydroxypyrrolidines C-linked to galactose. Total synthesis of a specific inhibitor of α-mannosidases (1997) (14)
1H-NMR Spectra of Cyclohexa-1,4-dienes and Cyclohexenes Annellated to Bicyclo[2.2.1]hept-2-enes. The Inter-Ring Homoallylic H,H Coupling Constants as Stereochemical Probes† (1985) (13)
Synthesis of an α-C-galactoside of a carbasugar: A new class of disaccharide mimics (1995) (13)
Homocheletropic Addition of Sulfur-Dioxide to 1,4-Dienes - Competition between Cheletropic and Homocheletropic Additions of Polyenes (1994) (13)
Synthesis and solution conformational analysis of 2,3-anhydro-3-C-[(1R)-2,6-anhydro-1-deoxy-1-fluoro-D-glycero-D-gulo-heptitol-1-C-yl]-beta-D-gulo-furanose: first example of a monofluoromethylene-linked C-disaccharide. (2001) (13)
The hetero-Diels-Alder addition of sulfur dioxide to 1-fluorobuta-1,3-dienes: the sofa conformations preferred by 6-fluorosultines (6-fluoro-3,6-dihydro-1,2-oxathiin-2-oxides) enjoy enthalpic and conformational Anomeric effects. (2002) (13)
Total Synthesis of Undeculofuranosiduronic Acid-Derivatives Related to Herbicidins (1993) (13)
Expeditious syntheses of methyl 8-epi-nonactate and methyl nonactate (1986) (13)
Stereoselective Double Functionalization of Iron-Carbonyl Complexes of 5,6,7,8-Tetramethylidenebicyclo[2.2.2]Oct-2-Ene - Crystal-Structure and Absolute-Configuration of (-)-Trans-Mu-[(2s,5r,7s)-C,5,6,C-Eta-C,7,8,C-Eta-(6,7,8-Trimethylidene-5 -((Z)-2-Oxopropylidene)-2-Bicyclo[2.2.2]Octyl Acetate)]-Bi (1985) (13)
Total, Asymmetric Synthesis of Methyl 3-Deoxy-3-(1′,2′,6′-trideoxy-2′,6′-imino-d-galactitol-1-yl)-α-d-manno-pyranoside (A C-Linked Imino Disaccharide): Conformational Analysis and Glycosidase Inhibition (1999) (13)
Ab initio and experimental studies on the hetero-Diels-Alder and cheletropic additions of sulfur dioxide to (E)-1-methoxybutadiene: A mechanism involving three molecules of SO2 (2002) (13)
Radical Cation States of 2,3,5,6,7,8-Hexamethylidenebicyclo [2.2.2]octane† (1980) (13)
C‐Linked Disaccharide Analogue of the Thomsen–Friedenreich (T)‐Epitope α‐O‐Conjugated to L‐Serine (2005) (13)
Synthesis of (Z)-3-Deoxy-3-(1,2,3,6-Tetradeoxy-3,6-Imino-L-Arabino-Hexitol-1-C-Ylidene)-D-Xylo-Hexose Derivatives. First Examples Of Homo-(1→3)-C-Linked Iminodisaccharides. (2000) (13)
Synthesis of Polypropionate Fragments Containing Tertiary‐Alcohol Moieties. Cross‐aldolisations with lithium enolates of 7‐oxabicyclo[2.2.1]heptan‐2‐one derivatives (1995) (13)
One-Pot, Asymmetric and Diastereoselective Four-Component Synthesis of Polyfunctional (Z)-Alkenyl Methyl Sulfones with Three Stereogenic Centers (2002) (13)
One-pot, four-component synthesis of polyfunctional sulfones (2004) (13)
Substituent effects on the regioselectivity of one-carbon ring expansions of 7-oxabicyclo[2.2.1]heptan-2-one derivatives with diazomethane (1991) (12)
2,3-Bis(Methylene)Bicyclo[2.1.1]Hexane and 3,4-Bis(Methylene)Tricyclo[3.1.0.02,6]Hexane - Interaction between a Pi-System and a Cyclobutane or Bicyclobutane Moiety (1985) (12)
5a-Carba-β-D-, 5a-Carba-β-L- and 5-Thio-β-L-xylopyranosides as New Orally Active Venous Antithrombotic Agents (1998) (12)
Total asymmetric synthesis of long-chain, branched carbohydrates and of an aza-C-disaccharide (1996) (12)
Circular Dichroism of Tricarbonyl(diene)iron Complexes. The Octant Rule Applied to Ketones Perturbed by Remote Fe(CO)3 Groups. Crystal Structure of (±)-Tricarbonyl[(1RS,4RS,5RS,6SR)-C5,6,C-η-(5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octanone)]iron (1986) (12)
Stereoselective syntheses of polyhydroxylated azepane derivatives from sugar-based epoxyamides. Part 1: synthesis from D-mannose (2010) (12)
Synthesis and Diels-Alder Reactivity of 7-Isopropylidene-2,3,5,6-Tetramethylenebicyclo-[2.2.1]Heptane (7,7-Dimethyl[2.2.1]Hericene) (1982) (12)
Iron carbonyl complexes of 2,3,5,6-tetrakis(methylene)-7-oxabicyclo[2.2.1]heptane. Crystal and molecular structure of (C10H10O)Fe(CO)3 and (C9H10CO)Fe2(CO)6 (1980) (12)
Fluorous Chemistry (2012) (12)
Interaction between Non-Conjugated Chromophores .17. Effects of Remote Substitution on the Photooxidation of Exocyclic S-Cis-Butadienes Grafted onto Bicyclo[2.2.1]Heptanes - Thermal and Rhodium Catalyzed Rearrangements of 3,6-Dihydro-1,2-Dioxines (1982) (12)
Fluorous Chemistry (2012) (12)
Total asymmetric syntheses of 3- and 4-deoxy-hexoses and derivatives☆ (1992) (12)
Synthesis of a New C(1→2)‐Linked Iminodisaccharide Starting from Levoglucosenone (2002) (12)
Reduction of 5,6‐Dimethylidene‐exo‐2,3‐epoxynorbornane with Metal Hydrides. Efficient syntheses of 6‐methyl‐5‐methylidene‐anti‐3‐ nortricyclanol and of 2,3‐dimethylidene‐anti‐7‐norbornanol (1978) (12)
Synthesis of C-linked analogues of β-d-galactopyranosyl-(1→3)-d-galactopyranosides and of β-d-galactopyranosyl-(1→3)-d-galactal (2004) (12)
Synthesis and Diels‐Alder Reactivity of 1‐(Dimethoxy)methyl‐2,3,5,6‐tetramethylidene‐7‐oxabicyclo[2.2.1]heptane. Preliminary communication (1985) (12)
Anti-cancer activity of 5-O-alkyl 1,4-imino-1,4-dideoxyribitols. (2011) (12)
Convergent syntheses of C(1→3)-linked disaccharides starting from isolevoglucosenone (2000) (12)
Total stereoselective syntheses of β-C-manno-pyranosides and of β-C(1→3)-linked disaccharides (1999) (12)
Regioselective electrophilic additions of bicyclo[2.2.n]alk-2-enes controlled by remote epoxide functions (1987) (12)
Organic chemistry: Theory, reactivity, mechanisms in modern synthesis (2018) (12)
Regioselective rearrangement of 7-azabicyclo[2.2.1]hept-2-aminyl radicals: first synthesis of 2,8-diazabicyclo[3.2.1]oct-2-enes and their conversion into 5-(2-aminoethyl)-2,3,4-trihydroxypyrrolidines, new inhibitors of α-mannosidases (2003) (12)
Stereoselective acetylation of iron carbonyl complexes of 5,6,7,8-tetrakis(methylene)bicyclo[2.2.2]oct-2-ene. Diene—heterotriene tricarbonyliron coordination equilibrium in solution and crystal structure of (C12H11COCH3)Fe2(CO)6 (1981) (12)
Asymmetric Synthesis and DNA Intercalation of (-)-6-[[(Aminoalkyl)oxy]methyl]-4-demethoxy-6,7- dideoxydaunomycinones(1)(,). (1996) (12)
Cycloadditionen an Derivate des Oxaquadricyclans (Bis-homo-furans) (1967) (12)
Face Selectivity of the Diels‐Alder Reaction of 5,6‐Bis((D)methylidene)‐2‐bicyclo[2.2.2]octene (1983) (11)
Stereoselective Synthesis of 8-Oxabicyclo[3.2.1]octane-2,3,4,6,7-pentols and Total Asymmetric Synthesis of 2,6-Anhydrohepturonic Acid Derivatives and of beta-C-manno-Pyranosides Suitable for the Construction of (1 ¿ 3)-C,C-Linked Trisaccharides (2001) (11)
Synthesis of branched seven-membered 1-N-iminosugars and their evaluation as glycosidase inhibitors. (2012) (11)
Hetero-Diels-Alder and cheletropic additions of sulfur dioxide to 1,2-dimethylidenecycloalkanes. Determination of thermochemical and kinetics parameters for reactions in solution and comparison with estimates from quantum calculations (2002) (11)
Title : A critical role of autophagy in antileukemia / lymphoma effects of APO 866 , an inhibitor of NAD biosynthesis (11)
Carbaxylosides of 4-ethyl-2-oxo-2H-benzopyran-7-yl as non-hydrolyzable, orally active venous antithrombotic agents. (1998) (11)
Cycloadditions to Derivatives of Oxaquadricyclanes (Bishomofuran) (1967) (11)
HYPERCONJUGATIVE INTERACTIONS IN BICYCLO(2.2.1)HEPTANE DERIVATIVES. EFFECTS ON THE DIELS-ALDER REACTIVITY OF THE S-CIS-BUTADIENE GROUP O 2,3-DIMETHYLIDENENORBORNANES (1976) (11)
Unambiguous Proof for Alcoxycarbonyl-group Migration in Wagner-Meerwein Rearrangements (1980) (11)
Synthesis of (+)-3,7,8-trideoxy-3,7-imino-D-threo-L-galacto-octitol and its inhibition of beta-glucosidases (1996) (11)
Asymmetric Syntheses of New Polyhydroxylated Quinolizidines: Cross‐Aldol Reactions of 7‐Oxabicyclo[2.2.1]heptan‐2‐one and 3a,4a,7a,7b‐Tetrahydro[1,3]dioxolo[4,5]furo[2,3‐d]isoxazole‐3‐carbaldehyde Derivatives (2000) (11)
Stereoselective Synthesis of 2,4,6-Trimethylcyclohex-4-ene-1,3-diol Derivatives and of polypropionate fragments with four contiguous stereogenic centers† (1995) (11)
Iron and ruthenium carbonyls of 6,7-dimethylene-exo-3-oxatricyclo[3.2.1.02.4]octane. Protic acid additions to an epoxide ring homoconjugated to a η4-(diene)Fe(CO)3 function. Crystal structures of (C9H10O)Fe(CO)3 and (C10H14O2)Fe(CO)3 (1979) (11)
Regioselectivity of 7-Oxabicyclo[2.2.1]Hepta-2,5-Diene-Phenol Rearrangement as a Function of the Acid Promoter - Stereoselective Synthesis of 1,2,3,4-Tetrahydro-2-Hydroxynaphthalen-2-Yl Methyl Ketones (1990) (11)
Synthesis of (+)‐1,3:2,5‐dianhydroviburnitol ((+)‐(1R,2R,3S,5R,6S)‐4,7‐dioxatricyclo[3.2.1.03,6]octan‐2‐ol) (1988) (11)
2,3,5,6,7,8-Hexakis(Methylene)Bicyclo[2.2.2]Octane (1980) (11)
Enantioselective synthesis of (R)-(−)-2-acetyl-2,5,12-trihydro-1,2,3,4-tetrahydro-6,11-naphthacenequinone via diastereoselective diels-alder cycloaddition (1993) (11)
Synthesis of (E,Z)-1-alkoxy-3-acyloxy-2-methylpenta-1,3-dienes via Danishefsky-type dienes or O-acylation of enones. (2009) (11)
[10,11-Methylene and 11-methyl-prostaglandins]. (1973) (10)
Synthesis of aza-C-disaccharides (dideoxyimino-alditols C-linked to monosaccharides) and analogues (2005) (10)
Electrophilic additions controlled by remote substituents. Total synthesis of daunosamine. (1986) (10)
Synthesis of α-C(1→3)-mannopyranoside of N-acetylgalactosamine, a new β-galactosidase inhibitor (1999) (10)
Experimental and Theoretical-Studies on the Homoconjugation in Bicyclic Carbenium and Oxonium Ions in the Gas-Phase (1986) (10)
Stereoselective synthesis of new conduramines and aminocyclitol derivatives (1998) (10)
Efficient synthesis of 2,6,7,8-tetrahydroxyindolizidines (castanospermine analogues) via the dipolar cycloadditions of N-benzyl-C-(tetrofuranos-4-yl)nitrones to methyl acrylate (2007) (10)
Ironcarbonyl Complexes of 5,6-Dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene Derivatives. Synthesis of Substituted Tricarbonyl(ortho-quinodimethane)iron Complexes and 2-Indanones (1987) (10)
Stereoselective synthesis of alpha-C-galactopyranosides of conduritols and aminoconduritols (1996) (10)
The Photochemistry of 5,6‐Dimethylidene‐2‐norborananone. Synthesis and Diels‐Alder Reactivity of 2,3‐Dimethylidenebicyclo‐[2.1.1]hexane (1980) (10)
Non‐iterative Asymmetric Synthesis of C15 Polyketide Spiroketals (2004) (10)
Convergent synthesis of (1→2)- and (1→4)-C-linked imino disaccharides† (1999) (10)
Stereoselective oxidation of ruthenium and iron carbonyl complexes of 5,6,7,8-tetrakis(methylene)bicyclo[2.2.2]oct-2-ene (1980) (10)
Synthesis of a 5-Hydroxypiperidine-2,3,4,6-tetramethanol, a New 2,6-Dideoxy-2,6-iminoheptitol Derivative. (1999) (10)
(2,9 : 6,12-η-2,3,5,6-Tetrakis(methylene)-bicyclo[2.2.2]octane)zirconocene, an Isolable Bis(olefin)zirconium(II) Compound† (1982) (10)
Highly Stereoselective Synthesis of (+/-)-Aminobromocyclitol Derivatives from Furan (1991) (10)
The stereoselective methylations and hydroxymethylations of 2,8-dioxabicyclo[3.2.1]octan-3-one derivatives. Synthesis of branched-chain sugars (1989) (10)
Competition between hetero-Diels-Alder and cheletropic additions of sulfur dioxide to 2-substituted buta-1,3-dienes. Synthesis of 2-(1-naphthyl)and 2-(2-naphthyl)buta-1,3-diene (2002) (10)
Synthesis and Applications of Silyl 2-Methylprop-2-ene-1-sulfinates in Preparative Silylation and GC-Derivatization Reactions of Polyols and Carbohydrates. (2016) (10)
The catalyzed desulfinylative allylation of carbonyl compounds with alk-2-enesulfonyl chlorides and silyl alk-2-enesulfinates. (2010) (9)
New nonhydrolyzable mimetics of sialyl Lewis x and their binding affinity to P-selectin (2004) (9)
Anomeric effects in pyranosides and related acetals (2009) (9)
Remote substituent control of the regioselectivity of the aryl- and vinylpalladation of 7-oxabicyclo[2.2.1]heptenes (1996) (9)
Synthesis of 1,1-bis(3,5-dimethyl-2-furyl)ethene; the chemo- and site-selectivity of its cycloadditions (1993) (9)
Synthesis of 1,1 '-methylenedi[(1R,1 ' R,3R,3 ' R,5R,5 ' R)-8-oxabicyclo[3.2.1]oct-6-en-3-ol] and derivatives: precursors of long-chain polyketides (2000) (9)
Asymmetric total synthesis of azasugars branched at C-5 (1991) (9)
An Expeditious, Non‐Iterative, and Asymmetric Synthesis of 3,5,7,9,11,13,15‐Heptahydroxypentadecanals (2003) (9)
Application of new optically pure ketene equivalents derived from tartaric acids to the total, asymmetric syntheses of (+)-6-deoxycastanospermine and (+)-6-deoxy-6-fluorocastanospermine (1990) (9)
Total asymmetric syntheses of β-hydroxy-δ-lactones via Umpolung with sulfur dioxide. (2011) (9)
Fluoride Anion as Base in Organic-Synthesis - Methylenation of 1,2-Cycloalcanediols by Dichloromethane - New Method for Preparation of 2,3-Dimethylidene-Norbornanes (1977) (9)
Total synthesis of a protected form of 2,6-anhydro-5-azido-3,5-dideoxy-2-C-hydroxymethyl-l-allo-heptose; a potential precursor of analogs of C-glycosides of neuraminic acid (2000) (9)
Spongistatins: Biological activity and synthetic studies (2008) (8)
Synthesis of New Pyrrolidine Derivatives as Inhibitors of a-Mannosidase and of the Growth of Human Glioblastoma Cells (2006) (8)
Synthesis of a C-disaccharide analog of the Thomsen-Friedenreich (T) epitope (2001) (8)
Syntheses and tandem Diels‐Alder reactivities of 7,7‐diphenyl‐[2.2.1]hericene (= 7‐(diphenylmethylidene)‐2,3,5,6‐ tetramethylidenebicyclo[2.2.1]heptane) and 7‐oxa[2.2.1]hericene ( = 2,3,5,6‐tetramethylidenebicyclo[2.2.1]heptan‐7‐one) (1988) (8)
The regioselectivity of the addition of benzeneselenyl chloride to 7-azanorborn-5-ene-2-yl derivatives is controlled by the 2-substituent: new entry into 3-and 4-hydroxy-5-substituted prolines (2010) (8)
The Homoconjugated Electron‐Releasing Carbonyl Group of 1‐Methylbicyclo[2.2.1]hept‐5‐en‐2‐one. Regioselective syntheses of 5‐chloro‐ and 6‐chloro‐1‐methylbicyclo[2.2.1]hept‐5‐en‐2‐one (1993) (8)
The hetero-Diels-Alder addition of sulfur dioxide: the pseudo-chair conformation of a 4,5-dialkylsultine. (2003) (8)
Stereoselective Synthesis of (1R)-1-C-(6-Amino-7H-purin-8-yl)-1,4-anhydro-2,3-dideoxy-3-fluoro-D-erythro-pentitol1 (1992) (8)
Regioselective addition of protic acids to tricarbonyliron complexes of 2,3,5,6-tetrakis(methylene)-7-oxabicyclo[2.2.1]heptane. Crystal structure of (C10H10O)Fe2(CO)6 (1981) (8)
Aryl and arylmethyl C-glycosides through desulfitative Stille and carbonylative Stille cross-coupling of tinglycals and sulfonyl chlorides (2004) (8)
Remote control of Diels-Alder additions. Enantioselective synthesis of (2R)-1,2,3,4-tetrahydro-2-hydroxy-5,8-dimethoxynaphthalen-2-yl methyl ketone (Wong's anthracycline intermediate) from furfural (1997) (8)
Sulfur dioxide-mediated syntheses of polyfunctional alkenes and (E,Z)- and (E,E)-2,4-dien-1-ones. (2005) (8)
Interaction between oxygen lone-pair orbitals of ether and α,β-unsaturated ketone functions in 3,5,6-trimethylidene-7-oxabicyclo[2.2.1]heptan-2-one and 3,6-dimethylidene-7-oxabicyclo[2.2.1]heptane-2,5-dione : a PE-spectroscopic investigation (1990) (8)
Synthesis of a (2R,6R)-2-(hydroxymethyl)-6-propa-1,2-dienyl-2H-pyran-3(6H)-one derivative, a new enone for the convergent construction of C-glycosides of D-disaccharides (2001) (8)
Total Asymmetric-Synthesis of 5-Deoxy-5-Thio-L-Allose (1994) (8)
Stereoselective Double Friedel‐Crafts Acylation of trans‐μ‐(2,3,6,7‐Tetramethylidenebicyclo[3.2.1]octane)bis(tricarbonyliron). Crystal Structure of trans‐μ‐{(1RS,2RS,3SR,5RS,6SR,7SR)‐C,2,3,C‐η:C,6,7,C‐η‐[(Z,Z)‐1,1′‐(3,7‐Dimethylidenebicyclo[3.2.1]octane‐2,6‐diylidene)di(2‐propanone)]}bis(tricarbonyl (1986) (8)
Highly stereoselective, total synthesis of β-c-hexopyranosyl derivatives (1993) (8)
Monoolefin and diene cycloaddition induced by transition-metal carbonyls. Cyclodimerization of 5,6-dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene catalyzed by dodecacarbonyltriosmium (1984) (8)
Total, asymmetric synthesis of ethyl d-ido-4-heptulosuronate derivatives starting from diethyl 4-oxopimelate (1999) (8)
Nature of the 5-norbornen-2-yl Cation Intermediate in the acetolysis of 2-deuterio-endo-5-norbornen-2-yl brosylate (1975) (7)
Construction of Polypropionate Fragments in Natural Product Synthesis (2013) (7)
Syntheses of β‐C(1→3)‐Glucopyranosides of 2‐ and 4‐Deoxy‐D‐hexoses (2003) (7)
Synthesis of (1 -> 3)-C and homo(1 -> 3)-C-linked iminodisaccharides starting from levoglucosenone and isolevoglucosenone (2002) (7)
SYNTHESIS AND DIELS-ALDER REACTIVITY OF 7-ISOPROPYLIDENE-2,3,5,6-TETRAKIS(METHYLENE)BICYCLO(2.2.1)HEPTANE (7,7-DIMETHYL(2.2.1)HERICENE) (1983) (7)
Synthesis and Diels-Alder reactivity of 2,3,6,7-tetrakis(methylene)bicyclo[3.2.1]octane (1986) (7)
Face Selectivity of the Diels-Alder Reaction of Hexadienone Moieties Grafted onto the Bicyclo[2.2.2]octene Skeleton and Perturbed by a Remote Tricarbonylbutadieneiron Group (1985) (7)
Acid‐Promoted Rearrangements of N‐Substituted 8‐Oxa‐3‐azatricyclo[3.2.1.02′4] octane‐6,7‐dicarboxylates: Remote Substituent Effects on the Regioselectivity of the N‐Acylaziridine/Dihydrooxazone Rearrangement (1990) (7)
An expeditious asymmetric synthesis of polyfunctional 1,7-dioxaspiro[5.5]undecanes (2004) (7)
(2,9: 6,12-π-2,3,5,6-Tetrakis(methylen)-bicyclo[2.2.2]octan)zirconocen, eine isolierbare Bis(olefin)zirconium(II)-Verbindung† (1982) (7)
Site- and regioselectivity of the hetero-diels-alder and cheletropic additions of sulfur dioxide to a 2,3,6,7-tetramethylidenebicyclo[3.2.1]octane derivative. (1993) (7)
Tandem Diels-Alder Reactivity Controlled by Remote Substituents. Regioselective synthesis of linearly annellated six-membered ring systems from (1RS,5SR,6RS,7SR)-6,7-bis(chloromethyl)-8,9-dimethylidene-2-oxabicyclo[3.2.2]nonan-3-one. Crystal structure of (1RS,5RS,6SR,11RS)-6,7-bis(chloromethyl)-3-ox (1988) (7)
The Reactions of γ-Butyrolactone and γ-Butyrolactonol Derivatives, and of Tetrahydrofuran with Mixtures of Alcohols and Thionyl Chloride (1991) (7)
Concise synthesis of complicated polypropionates through one-pot dissymmetrical two-directional chain elongation. (2011) (7)
The Reaction of Water with Iron- and Rutheniuncarbonyl Complexes of Polyolefins: 1,2- and 1,4-hydrogenation of 1,3-dienes. hydrogenolysis of allylic ethereal bonds and deoxygenation of 7-oxabicyclo[2.2.1]hept-2-enes (1988) (7)
Long-distance effect on one-bond C-C scalar couplings upon introduction of a double bond in bicyclic systems (1997) (7)
Alkaloid Synthesis (2012) (7)
Dynamic Representation of Quantum Chemical Results Using Computer-Graphics - Molecular-Rearrangements, Art or Science (1983) (7)
Highly Stereoselective Aminohydroxylations of exo-2-Cyano-7-oxabicyclo[2.2.1]hept-5-en-2-yl Acetate (1991) (7)
Four component synthesis of (Z)-4-alkoxy-1,3-dimethylalk-2-enyl methyl sulfones: on the intermediacy of sultines (3,6-dihydro-1,2-oxathiin-2-oxides) arising from suprafacial hetero-Diels-Alder additions of sulfur dioxide (2001) (7)
Alkaloid Synthesis (2012) (7)
De Novo Synthesis of Monosaccharides (2001) (7)
Chemo- and stereoselective functionalization of 7-oxabicyclo[2.2.1]hept-5-en-2-one with dichloroketene (1986) (7)
A New Total Synthesis ofD-threo-L-talo-Octose (1991) (7)
Long-Range Substituent Effects - the Regioselective Electrophilic Additions of Exo-3,6-Epoxytetrahydrophthalide and Its Derivatives (1986) (7)
The hetero-Diels–Alder addition of sulfur dioxide: structure of the first crystalline sultine. Quantum calculations on the conformations of 6-fluoro-3,6-dihydro-1,2-oxathiine 2-oxides (2001) (7)
Stereoselectivity of the Diels-Alder additions of exocyclic dienes grafted onto bicyclo[2.2.n]alkanes (1980) (7)
Stereoselective Control in the Base-Catalyzed H/D Exchange of 5,6-Dimethylidene-2-Bicyclo[2.2.N]Alkanone Tricarbonyliron Complexes - Revision of the Structures of Tricarbonyliron Complexes of 5,6-Dimethylidenebicyclo[2.2.2]Oct-2-Ene and 5,6-Dimethylidenebicyclo[2.2.1]Hept-2-Ene (1984) (7)
Syntheses of Exo-3,8-Dioxatricylo[3.2.1.0(2,4)]Octane and 4,7-Dioxatricyclo[3.2.1.0(3,6)]Octane and the Relative Basicities of Their Ethereal Moieties (1993) (7)
Transition metal promoted isomerization of 3-oxaquadricyclanes: preparation of a new oxepine derivative. (1974) (7)
Synthesis of a C-Iminoribofuranoside Analog of the Nicotinamide Phosphoribosyltransferase (NAMPT) Inhibitor FK866 (2012) (6)
Stereoselective Syntheses of Branched-Chain Carbohydrates Bearing Furan and Pyrrole Moieties (1995) (6)
NEW DIENOPHILES: 1‐ACETYLVINYL ARENECARBOXYLATES. REACTIVITY TOWARD CYCLOPENTADIENE AND EXOCYCLIC DIENES (1981) (6)
Asymmetric Total Synthesis of (11R, 12S, 13S, 9Z, 15Z)‐9, 12, 13‐Trihydroxyoctadeca‐9, 15‐dienoic Acid, a self‐defensive agent against rice‐blast disease (1994) (6)
Synthesis of a polyhydroxyquinolizidine bearing a polyhydroxylated carbon side-chain (1999) (6)
Azole-Based Indoleamine 2,3-Dioxygenase 1 (IDO1) Inhibitors. (2021) (6)
Determining the Role of the Aromatic Ring of N-Arylmethyl ent-conduramine F-1 in their Interactions with α-Glucosidases by Saturation Transfer Difference NMR Spectroscopy Experiments (2012) (6)
Photoreductive cleavage of phenyl-selenium bonds of phenylselenoalkanes (1994) (6)
Short diastereoselective synthesis of the C1-C13 (AB spiroacetal) and C17-C28 fragments (CD spiroacetal) of spongistatin 1 and 2 through double chain-elongation reactions. (2010) (6)
Hydroxylated Indolizidines and their Synthesis (1993) (6)
Total asymmetric synthesis of 3-amino-3-deoxy-L-talose and derivatives (1994) (6)
Homochiral matching in the Diels-Alder cyclodimerization of 2-vinyl-7-oxabicyclo[2.2.1]hept-2-ene derivatives (1994) (6)
Stabilizing Effect by Geminal Dioxy Substitution and Anomeric Effect in 3,6-Dihydro-6-Methoxy-1,2-Oxathiin 2-Oxides (1993) (6)
Synthesis of 4-hydroxy-2,6-bis(hydroxymethyl)tetrahydropyran-2-carbaldehyde derivatives (1998) (6)
Interactions between Homoconjugated Diene and Epoxide Functions - Effect on Diels-Alder Regioselectivity (1983) (6)
Unimolecular and Supramolecular Electronics II: Chemistry and Physics Meet at Metal-Molecule Interfaces (2012) (6)
Conformational analysis of 2,3,5,6-tetrakis(methylene)bicyclo[2.2.2]octanes by circular dichroism. (1984) (6)
Unimolecular and Supramolecular Electronics II: Chemistry and Physics Meet at Metal-Molecule Interfaces (2012) (6)
Crystal and Molecular Structure of 2,3,5,6,7,8‐Hexamethylidenebicyclo [2.2.2]octane (‘[2.2.2]hericene’) (1983) (6)
Short synthesis of the C16-C28 polyketide fragment of apoptolidin A aglycone. (2007) (6)
REACTION OF 5,6‐DIMETHYLENE‐7‐OXABICYCLO(2.2.1)HEPT‐2‐ENE WITH IRON CARBONYLS (1977) (6)
Polysulfones: solid organic catalysts for the chemoselective cleavage of methyl-substituted allyl ethers under neutral conditions. (2004) (6)
Structure of (Alkene)Tetracarbonyliron Complexes - Variable-Temperature Circular-Dichroism of (5-Substituted 7-Oxabicyclo[2.2.1]Hept-2-Ene)Tetracarbonyliron Complexes (1986) (6)
Synthetic Studies toward the CD Spiroketal of Spongistatins (2010) (6)
π-Facial diastereoselectivity in the electrophilic and electrophilic–nucleophilic additions to dimethyl (1R,2R,3S,4S)-bicyclo[2.2.2]oct-5-ene-2,3-dicarboxylate (1993) (6)
Regioselective Synthesis of 5-Endo,6-Endo-Dihydroxy-7-Oxabicyclo[2.2.1]Heptan-2-One with Differential Protection of the Diol Group (1995) (6)
Palladium-catalyzed desulfitative mizoroki-heck coupling reactions of sulfonyl chlorides with olefins in a nitrile-functionalized ionic liquid (2006) (5)
Highly Stereoselective Synthesis of Perhydro-8a-(hydroxymethyl)phenanthrene-1,2,4,5,7,8-hexol and Derivatives. (1997) (5)
Synthesis of Higher-Carbon Sugars Via Cross-Aldolization of 7-Oxanorbornan-2-One and Carbohydrate Aldehyde Derivatives (1989) (5)
Synthesis of optically active 5-alkoxy-6-methylcyclohex-2-en-1-ones and 4-alkoxy-5-methylcyclopent-1-enyl benzoate. (2009) (5)
The Homoallyl-Cyclopropylcarbinyl Cation Rearrangement in the Solvolyses of exo- and endo-5-Norbornen-2-yl p-Bromobenzenesulfonates. Application of 2H-NMR. Spectroscopy† (1980) (5)
Unexpected selectivity between pinacolic rearrangement and intramolecular displacement in the acid-promoted epoxide ring opening of 6-exo-cyano-3,8-dioxabicyclo[3.2.1.02,4]oct-6-endo-yl esters (1994) (5)
Polypropionate fragments with four contiguous chiral centres from acetone (1994) (5)
SYNTHESIS OF (-)-6-(3'-AMINOPROPYLOXY) METHYL-4-DEMETHOXY-6,7-DIDEOXY-DAUNOMYCINONE, A NEW DNA INTERCALATOR RELATED TO ANTHRACYCLINES (1995) (5)
Diels-alder stereo- and regioselectivity controlled by remote substituents and solvent. Cycloadditions of 1-(dimethoxymethyl)-2,3-bis(methylene)-7-oxabicyclo[2.2.1]Heptane (1984) (5)
The optical resolution of bicyclo[2.2.1]Hept-5-Ene-2-cyanohydrins using brucine : a crystallographic and molecular-mechanics study (1993) (5)
Synthesis of Optically Pure Tricarbonyliron Complexes of 5,6‐Dimethylidenebicyclo[2.2.2.]oct‐2‐yl derivatives. Crystal structure and absolute configuration of (+)‐tricarbonyl(1S,2S,4R,5R,6S)‐C,5,6,C,‐η‐(5,6‐dimethylidenebicyclo[2.2.2]oct‐2‐yl p‐bromobenzoate)iron (1988) (5)
En route toward squalestatins and analogues from furfuryl alcohol and maleic anhydride (1999) (5)
2,5-BIS((Z)-2-NITROBENZENESULFENYLMETHYLENE)-3,6-BIS(METHYLENE)-7-OXABICYCLO(2.2.1)HEPTANE. A VERSATILE REAGENT FOR TANDEM REGIOSELECTIVE DIELS-ALDER REACTIONS (1984) (5)
Total, Asymmetric Synthesis of Glycosidase Inhibitors such as the Aza Sugars, Castanospermine and Analogs, from Furan (1993) (5)
Efficient Asymmetric Synthesis of Long-Chain Polyketides Containing up to Ten Contiguous Stereogenic Centres by Double Chain Elongation (2011) (5)
Synthesis of polyfunctional, linearly condensed six-membered ring systems by regioselective tandem Diels-Alder additions. Synthesis and reactivity of 6,7-bis(chloromethyl)-8,9-bis(methylene)-2-oxabicyclo[3.2.1]nonan-3-one (1987) (5)
The Diels‐Alder Reactivity of 2,2′‐Ethylidenebis[3,5‐dimethylfuran] and Exploratory Chemistry of the Mono‐adducts (1996) (5)
THE ACETOLYSIS OF EXO‐ AND ENDO‐5,6‐DIMETHYLIDENE‐2‐NORBORNYL P‐BROMOBENZENESULFONATES AND OF THEIR OPTICALLY ACTIVE AND DEUTERIUM‐LABELED DERIVATIVES (1980) (5)
Total Asymmetric Synthesis of a New 9,12‐Anhydroerythronolide Aglycone (2002) (5)
Combinatorial Diels—Alder Approach to the Synthesis of Antitumor Anthracyclines and Analogues (1998) (5)
Equilibrium and kinetic deuterium isotope effects on the hetero-Diels-Alder addition of sulfur dioxide. (2003) (5)
Induction of cell killing and autophagy by amphiphilic pyrrolidine derivatives on human pancreatic cancer cells. (2018) (5)
Asymmetric induction in the rearrangement of monocyclic endoperoxides into γ-hydroxy-αβ-unsaturated aldehydes (1980) (5)
Chemo-,Regio-, and Stereoselective Hydroalumination of 7,8-Epoxy-2,3,5,6-tetramethylenebicyclo|2.2.2|octane (1982) (5)
Combinatorial synthesis of linearly condensed polycyclic compounds, including anthracyclinones, through tandem Diels-Alder additions (2007) (4)
Face Selectivity of the Diels-Alder Additions and Cheletropic Additions of Sulfur-Dioxide to 2-Vinyl-7-Oxabicyclo[2.2.1]Hept-2-Ene Derivatives (1994) (4)
A Total, Asymmetric-Synthesis of 2-Deoxy-L-Fucose from Furan (2006) (4)
Polynuclear Iron and Rhodium Complexes of 7-Oxa[2.2.1]Hericene (2,3,5,6-Tetramethylidenebicyclo[2.2.1]Heptan-7-One) (1989) (4)
Regio- and stereoselective thioamination of 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives (1993) (4)
Derivatives of 7‐Oxabicyclo[2.2.1]heptane in Nature and as Useful Synthetic Intermediates (2000) (4)
Competition between cheletropic and homocheletropic additions of sulfur dioxide to 2,3,5,6-tetrakis(methylene)bicyclo[2.2.n]alkanes. Crystal and molecular structures of two 3-thiabicyclo[3.1.0]hexane 3,3-dioxide derivatives. (1995) (4)
Remote substituent effect on the electrophilic additions of 1,3-dienes. Synthesis of (2R)-5-(acetoxymethyl)-2-acetyl-1,2,3,4-tetrahydro-10-methoxynaphthacene-2,12-diyl diacetate (1995) (4)
TOTAL ASYMMETRIC SYNTHESIS OF SECO-ACIDS OF 9,12-ANHYDROERYTHRONOLIDE AGLYCONS (1998) (4)
Diels-alder additions of 1,3-dienes to propargylic alcohols catalyzed by the Wilkinson's catalyst (1990) (4)
Synthesis of 2-(1-aminocyclopropyl)pyrrolidine-3,4-diol derivatives applying titanium-mediated reaction conditions (2012) (4)
Synthesis and Tandem Diels-Alder Reactivity of 1,3-Dimethoxy-5,6,7,8-Tetramethylidenebicyclo[2.2.2]Oct-2-Ene (1988) (4)
Stereoselective Nucleophilic Additions to a Bicyclic Ketone Controlled by a Remote Tricarbonyl(diene)iron Moiety (1985) (4)
Synthesis of new oxathiazinane dioxides and their in vitro cancer cell growth inhibitory activity. (2010) (4)
Regioselective base-induced ethereal bridge openings of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic derivatives; Synthesis of squalestatin core analogues (1999) (4)
Synthesis of 2,2', 2 , 2'''-(1,2-ethanediylidene)tetrafuran and Diels-Alder reaction with dimethyl acetylenedicarboxylate (2002) (4)
Synthesis and Circular Dichroism of Optically Pure (±)‐(1S,2S,5S)‐5‐Methoxy‐3,4,6,7‐tetramethylidenebicyclo[3.2.1]oct‐2‐yl Derivatives. Baker's Yeast Reduction of 4‐Methoxy‐5,6,7,8‐tetramethylidenebicyclo[2.2.2]octan‐2‐one (1990) (4)
SYNTHESIS OF THE C-DISACCHARIDE α-C(1→3)-L-FUCOPYRANOSIDE OF N-ACETYLGALACTOSAMINE[1] (2001) (4)
Novel Method for the Preparation of O,O-Dialkyl Phosphorochloridothionates1 (1960) (4)
The conformational analysis and the rearrangements of (norborn-2-eno)[d](3,6-dihydro-1,2-dioxine) (1979) (4)
Remote Tricarbonyl(diene)iron Substituent Effect on Ester Heterolysis. The Solvolyses of 5,6,7,8‐Tetramethylidenebicyclo[2.2.2]oct‐2‐yl Methanesulfonate and of its Tricarbonyliron Mono‐ and Dinuclear Complexes (1987) (4)
Pyrrolidine derivatives as new inhibitors of α-mannosidases and growth inhibitors of human cancer cells (2006) (4)
Circular Dichroism of Planar, Exocyclic S‐cis‐Butadienes Remotely Perturbed (1988) (4)
Imino-C-disaccharides and analogues: synthesis and biological activity (2009) (4)
Total Asymmetric Synthesis of Glycomimetics and Polypropionates of Biological Interest (2008) (4)
Total asymmetric synthesis of 6-deoxy-5-C-methyl-d-ribo-hexose: structure in aqueous solution (1991) (4)
The Circular-Dichroism of 5,6-Dimethylidene-2-Bicyclo[2.2.N]Alkyl Esters - Chiral Exciton Coupling Between Benzoate and Exocyclic S-Cis-Butadiene Chromophores (1984) (4)
Synthesis Of Pyrrolidine 3,4-Diol Derivatives With Anticancer Activity On Pancreatic Tumor Cells (2014) (3)
1.13 – Synthesis of Monosaccharides and Analogs (2007) (3)
The Electron‐Releasing Carbonyl Group. Part 2. Spectroscopic Detection and Synthetic Applications (1997) (3)
Quantum calculations on the acid catalyzed rearrangements of norborn-5-en-2-one, 7-oxanorborn-5-en-2-one and 7-azanorborn-5-en-2-one (2008) (3)
Tandem Cheletropic Additions of Sulfur-Dioxide to [2.2.2]Hericene - the Barrelene Effect (1988) (3)
Conformational Analysis of Endoperoxides Grafted onto Bicyclo[2.2.n]alkanes as a Test of the Rigidity of the Bicyclic Skeleton. Photo‐oxidation of [2.2.2] Hericene and 2,3,5,6‐Tetramethylidenebicyclo[2.2.n]alkanes (1986) (3)
Copper(II) Acetate (2005) (3)
Conformational analysis of α-methoxyketones. A photoelectron spectroscopic investigation of 3-methoxybicyclo[2.2.1]heptan-2-ones. (1992) (3)
Stereoselective Synthesis of (2S,3S,4R,5S)‐5‐Methylpyrrolidine‐3,4‐diol Derivatives that Are Highly Selective α‐L‐Fucosidase Inhibitors. (2006) (3)
Synthesis of New Aza‐C‐disaccharides Linking 4‐Deoxy‐4‐amino‐β‐L‐erythro‐furanose to C‐2 of D‐Glucose and D‐Allose (2006) (3)
Deracemization of 5-(4-hydroxyphenyl)-5-phenylhydantoin (HPPH): practical synthesis of (−)-(S)-HPPH (2004) (3)
Synthesis of d- and l-erythro 1,5-dithiopent-1-enopyranoside sulfonium salts and their evaluation as glycosidase inhibitors (2009) (3)
Synthesis of (1RS,2RS,5SR)-3,4,6,7-Tetramethylidene-8-oxobicyclo[3.2.1]-oct-2-yl Acetate and the Chemo- and Stereoselective Coordination of its Butadiene Functions with Rhodium and Iron Moieties (1990) (3)
Sulfur Dioxide: A Powerful Tool for the Stereoselective Construction of C ? C Bonds (2013) (3)
Exceptionally high barriers to 1,2-hydride shifts in the 1-adamantyl cation (1971) (3)
Assignment of the Absolute Configuration of Natural Lentiginosine by Synthesis and Enzymatic Assays of Optically Pure (+) and (‐)‐ Enantiomers. (1996) (3)
Spirocyclopropyl pyrrolidines as a new series of alpha-L-fucosidase inhibitors. (2006) (3)
Umpolung with Sulfur Dioxide: Carbon-Carbon Cross-Coupling of Electron-Rich 1,3-Dienes and Alkenes; Application to the Enantioselective Synthesis of Long-Chain Polyketide Fragments (2009) (3)
Structures of four N‐benzoylaziridine and aziridinium p‐toluenesulfonate derivatives grafted onto 7‐oxabicyclo[2.2.1]heptane skeletons (1993) (3)
Cyclodimerization of 1-(Dimethoxyniethyl)-5,6-dimethylidene-7-oxa-bicyclo[2.2.1]hept-2-ene Induced by Nonacarbonyldiiron. Crystal Structure of (1RS, 2SR, 3RS, 4RS, 4aRS, 9aSR)- Tricarbonyl[C, 2,3, C-η-(1,4-epoxy-1,5-bis(dimethoxymethyl)-2,3-dimethylidene-1,2,3,4,4a,9,9a,10-octahydroanthracene)]iron† (1989) (2)
THE PREPARATION OF OPTICALLY PURE 7-OXABICYCLO(2.2.1)HEPT-2-ENE DERIVATIVES. THE CD SPECTRUM OF (+)-(1R)-7-OXABICYCLO)2.2.1)HEPT-5-EN-2-ONE (1983) (2)
Palladium-Catalyzed Desulfitative Mizoroki—Heck Coupling Reactions of Sulfonyl Chlorides with Olefins in a Nitrile-Functionalized Ionic Liquid. (2007) (2)
(2,3-Bis(methylen)bicycIo[2.2.2]octan)zirconocen: Synthese, Struktur und elektrochemische Reduktion/(2,3-Bis(methylene)bicyclo[2.2.2]octane)zirconocene: Synthesis, Structure, and Electrochemical Reduction (1985) (2)
Dynamic modeling of chemical reactions: the Diels-Alder cycloaddition (1987) (2)
Synthesis of 1,2,3,4‐Tetrahydro‐1,2‐dimethylidenenaphthalene: A Reactive s‐cis‐Butadiene Undergoing Highly Chemo‐ and Regioselective Cyclodimerization (2002) (2)
Synthesis and Circular-Dichroism of 5-Halogenobicyclo[2.2.1]Hept-5-En-2-Ones and 6-Halogenobicyclo[2.2.1]Hept-5-En-2-Ones - Tests for the Dekkers Quantitative Chirality Rule (1988) (2)
Stereochemistry and Reactivity of Pi-Systems (1982) (2)
Synthesis of [(2S,3S,4R)-3,4-Dihydroxypyrrolidin-2-yl]-5-methylfuran-4-carboxylic Acid Derivatives: New Leads as Selective β-Galactosidase Inhibitors. (2002) (2)
Synthesis of enantiomerically enriched 2-substituted pyrrolidine analogues of norhygrine: application of the hetero-diels-alder addition of sulfur dioxide (2007) (2)
Synthesis and glycosidase inhibitory activity of 1-amino-3,6-anhydro-1-deoxy-D-sorbitol derivatives. (2010) (2)
Palladium-Catalyzed Desulfitative Mizoroki—Heck Couplings of Sulfonyl Chlorides with Mono- and Disubstituted Olefins: Rhodium-Catalyzed Desulfitative Heck-Type Reactions under Phosphine- and Base-Free Conditions. (2006) (2)
Acetolyses of π-irontricarbonyl complexes of 2,3-dimethylidene-7anti-norbornyl and 5,6-dihethylidene-2exo-morbornyl esters. (1981) (2)
Synthesis of C‐Linked Analogues of β‐D‐Galactopyranosyl‐(1→3)‐D‐galactopyranosides and of β‐D‐Galactopyranosyl‐(1→3)‐D‐galactal. (2005) (2)
The electron-releasing carbonyl group .1. Discovery and theoretical studies (1997) (2)
Syntheses of Stable α-Silyloxyepoxides and α-Chloroalkyl Silyl Ethers Derivatives of 3,10-Dioxa-5-azatricyclo[5.2.1.02,6]dec-4-enes (1994) (2)
Asymmetric synthesis of polycyclic polyketides via the double Diels-Alder addition of 2,2 '-ethylidenebis[3,5-dimethylfuran] (2000) (2)
Regioselectivity of the diels-alder cycloadditions of 2-substituted 5,6-bis(methylene)-norbornanes. (1978) (2)
Sugar Mimetics: Why and How (2000) (2)
An Efficient Combinatorial Method for the Discovery of Glycosidase Inhibitors. (2002) (2)
Total Synthesis of Polypropionate Natural Products: Application of New Sulfur Dioxide Chemistry (2005) (2)
Stereoselective Syntheses of Protected Aminohydroxycyclopentanecarbaldehyde Derivatives from 7-Oxabicyclo(2.2. 1)hept-5-en-2-yl Systems. (1991) (2)
Identification of new FK866 analogues with potent anticancer activity against pancreatic cancer. (2022) (2)
Synthesis and Glycosidase Inhibitory Activities of Pyrrolidines and Piperidines with N-(Polyhydroxyalkyl) Side Chains (2007) (2)
Double Addition of Fluorosulfuric Acid to Norbornadiene and Quadricyclane (1975) (2)
The homoallyl-cyclopropylcarbinyl cation rearrangement in the acetolysis of exo- and endo-5,6-bis(methylene)-2-norbornyl p-bromobenzenesulfonates. Application of deuterium NMR spectroscopy (1978) (2)
Oxetane Formation by 1,3-Migration of Benzyloxy Group in 7-Oxabicyclo[2.2.1]hept-2-yl Cations: Synthesis of 4,7-Dioxatricyclo[3.2.1.03,6]octane and 2-Oxabicyclo[2.2.2]octane Encrusted in the 1,4:5,8-Diepoxy-perhydrophenanthrene Ring System (2000) (2)
Aryl and Arylmethyl C-Glycosides Through Desulfitative Stille and Carbonylative Stille Cross-Coupling of Tinglycals and Sulfonyl Chlorides. (2004) (2)
New Chiral Auxiliaries and New Optically Pure Ketene Equivalents Derived from Tartaric Acids. Improved Synthesis of (‐)‐7‐Oxabicyclo(2. 2.1)hept‐5‐en‐2‐one. (1991) (2)
Carbonyliron‐Assisted Cycloaddition of a 1,3‐Diene to a CC Double Bond: Synthesis of an Anthracyclinone Precursor (1982) (2)
One-Pot Synthesis of 1-Aryl-3-methyl-1,3-dienes Using Methallyl(trimethyl)silane and Aldehydes and Their Low Temperature (Z)(E) Isomerization Induced by Sulfur Dioxide. (2005) (1)
Stereoselective Synthesis of 5a‐Ethyl‐1,2,3,3a,4,5,5a,6,9a,9b‐decahydro‐ 1,3,4‐trihydroxy‐3a‐(hydroxymethyl)‐7H‐benz[e]inden‐7‐one Derivatives (1999) (1)
Stereoselective Syntheses of Protected Amino-hydroxy-cyclopentane-carbaldehyde Derivatives from 7-Oxabicyclo[2.2.1]hept-5-en-2-yl Systems (1990) (1)
Sustainable Development: The Roles of Carbon and Bio-Carbon: An Introduction to Molecular Sciences (1)
Synthesis of C-Linked Imino Disaccharides (= Aza-C-disaccharides) with a Pyrrolidine-3,4-diol Moiety Attached at C(3) of Galactose via a Hydroxymethylene Linker and of a 7-(1,2,3-Trihydroxypropyl)octahydroxyindolizine-1,2,6,8-tetrol. (1998) (1)
Total Synthesis and Determination of the Absolute Configuration of (-)-Dolabriferol (2011) (1)
Derivatives of (2R,3R,4S)‐2‐Aminomethylpyrrolidine‐3,4‐diol are Selective α‐Mannosidase Inhibitors. (2001) (1)
Structure-based optimization of type III indoleamine 2,3-dioxygenase 1 (IDO1) inhibitors (2022) (1)
Synthesis of Monosaccharides and Analogues. Part 1. Applications of Chemoenzymatic Methods and Organocatalysis (2008) (1)
C(1→4)‐Linked Disaccharides Through Carbonylative Stille Cross‐Coupling. (2005) (1)
C-Disaccharides and analogs: The search for anticancer agents (2007) (1)
Short and Convergent Synthesis of (1→3)‐C‐Linked Imino Disaccharides (Aza‐C‐disaccharides). (1999) (1)
Asymmetric Induction in the Rearrangement of Monocyclic Endoperoxides into Gamma-Hydroxy-Alpha-Beta-Unsaturated Aldehydes (1980) (1)
Total Asymmetric Synthesis of Monosaccharides and Analogues (2007) (1)
The Syntheses of 3- and 4-Deoxy-hexoses (1994) (1)
A mine for functional molecules and materials (2010) (1)
Carbohydrates in sustainable development, Part 1. Renewable resources for chemistry and biotechnology. Preface. (2010) (1)
Synthesis of Polypropionate Fragments Containing Tertiary‐Alcohol Moieties. Cross‐Aldolizations with Lithium Enolates of 7‐Oxabicyclo(2. 2.1)heptan‐2‐one Derivatives. (1995) (1)
Aza‐C‐disaccharides: Synthesis of 6‐Deoxygalactonojirimycin β‐C(1→3) Linked with D‐Altrofuranosides and D‐Galactose. (1998) (1)
Organic Chemistry and Synthesis Rely More and More upon Catalysts (2022) (1)
Short, Stereoselective Syntheses of C(1→3)‐Linked Disaccharides. (1998) (1)
NONPLANARITY OF Π SYSTEMS IN 5,6-BIS(METHYLENE)-7-OXANORBORN-2-ENE (1981) (1)
The Diels-Alder chemoselectivity of 3,4,6,7-tetramethylidenebicyclo[3.2.1]octane-2-exo,8-syn-diyl derivatives (1992) (1)
A Kinetically Stable Singlet State of 1,2,4,5-Tetramethylenebenzene. (1992) (1)
The Circular-Dichroism of 2,3-Dimethylidene-5-Norbornyl Derivatives (1983) (1)
REGIOSELECTIVE ADDITIONS OF ELECTROPHILES TO OLEFINS REMOTELY PERTURBED. THE CARBONYL GROUP AS A HOMOCONJUGATED ELECTRON DONATING SUBSTITUENT (1982) (1)
Optically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“Naked Sugars”) as New Chirons (1990) (1)
Stereoselective Synthesis of New 8‐Oxabicyclo[3.2.1]oct‐6‐en‐2‐one and 8‐Oxabicyclo[3.2.1]octa‐3,6‐dien‐2‐one Derivatives. The Electron‐Releasing and Electron‐Withdrawing Effects of Homoconjugated Ketones. (2001) (1)
Synthesis of 7-Oxabicyclo[2.2.1]heptane and Derivatives (2014) (1)
Topics in Current Chemistry (2013) (1)
The Electron‐Releasing Carbonyl Group. Part 1. Discovery and Theoretical Studies (1997) (1)
Vapor-Phase Uv Spectra of 2,3,5,6,7,8-Hexakis(Methylene)Bicyclo [2.2.2] Octane ([2.2.2] Hericene) and Related S-Cis-Butadiene Derivatives (1983) (1)
Polypropionate Fragments with Four Contiguous Chiral Centers from Acetone. (1994) (1)
5a‐Carba‐β‐D‐, 5a‐Carba‐β‐L‐ and 5‐Thio‐β‐L‐xylopyranosides as New Orally Active Venous Antithrombotic Agents. (1999) (1)
C-linked disaccharide analogue of the Thomsen-Friedenreich (T)-epitope alpha-O-conjugated to L-serine. (2005) (1)
Renewable resources for chemistry and biotechnology (2010) (1)
Synthesis of a (2R,6R)‐2‐(Hydroxymethyl)‐6‐propa‐1,2‐dienyl‐2H‐pyran‐3(6H)‐one Derivative, a New Enone for the Convergent Construction of C‐Glycosides of C‐Disaccharides. (2001) (1)
Asymmetric synthesis of 1-aminopentadecane-3,5,7,9,11,13,15-heptols and of 1,15-diaminopentadecane-3,5,7,9,11,13-hexols and derivatives (2002) (1)
OPTICAL RESOLUTION OF 7-OXABICYCLO(2.2.1)HEPT-2-ENE DERIVATIVES. DIASTEREOSELECTIVITY IN THE FORMATION OF CYANOHYDRIN-BRUCINE COMPLEXES (1984) (1)
Reaction of dodecacarbonyltriruthenium with 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives: synthesis of (µ3-η2-benzyne)-nonacarbonyldihydridotriruthenium and derivatives (1991) (1)
Combinatorial Diels-Aider Approach to the Synthesis of Anti-tumor Anthracyclines and Analogues (1998) (1)
COPPER(I)‐ AND COPPER(II)‐CATALYZED DIELS‐ALDER ADDITIONS OF α‐SUBSTITUTED ACRYLONITRILE TO FURAN. THE SYNTHESIS OF 7‐OXABICYCLO(2.2.1)HEPT‐5‐EN‐2‐ONE (1983) (1)
New Leads for Selective Inhibitors of α‐L‐Fucosidases. Synthesis and Glycosidase Inhibitory Activities of [(2R,3S,4R)‐3,4‐Dihydroxypyrrolidin‐2‐yl]furan Derivatives. (2002) (1)
Synthesis of Polyfunctional, Linearly Condensed 6-Membered Ring-Systems by Regioselective Tandem Diels-Alder Additions (1987) (1)
Disaccharide mimics as drugs against cancer and epitopes for anti-cancer vaccine candidates (2016) (1)
Reductive Oxa Ring Opening of 7‐Oxabicyclo(2.2.1)heptan‐2‐ones. Synthesis of C‐α‐Galactosides of Carbapentopyranoses. (1996) (1)
Exocyclic Dienes and the Synthesis of Anthracyclins (1982) (1)
Iron and molybdenum carbonyls of 5,6,7,8-tetramethylenebicyclo[2.2.2]-oct-2-ene (1977) (1)
Syntheses and Tandem Diels‐Alder Reactivities of 7,7‐Diphenyl(2.2.1)hericene (= 7‐(Diphenylmethylidene)‐2,3,5,6‐tetramethylidenebicyclo(2.2.1)heptane) and 7‐Oxa(2.2.1)hericene (= 2,3,5,6‐Tetramethylidenebicyclo(2.2.1)heptan‐7‐one). (1988) (1)
C-linked disaccharides analogues of the T epitope: Toward an artificial anti-cancer vaccine (2004) (1)
Interaction Between Non-Conjugated Chromophores. Part 24. Conformational Analysis of Endoperoxides Grafted Onto Bicyclo[2.2.n]aIkanes as a Test of the Rigidity of the Bicyclic Skeleton. (1986) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 20. FACE SELECTIVITY IN THE DIELS‐ALDER REACTION OF 5,6‐BIS((D)METHYLIDENE)‐2‐BICYCLO(2.2.2)OCTENE (1984) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 10. 7,8-EPOXY-2,3,5,6-TETRAKIS(METHYLENE)BICYCLO(2.2.2)OCTANE; SYNTHESIS AND DIELS-ALDER REACTIVITY (1980) (0)
Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 20. Total Asymmetric Syntheses of D‐Lividosamine and 2‐Acetamido‐2,3‐dideoxy‐D‐arabino‐ Hexose Derivatives. (1993) (0)
Enantioselective Synthesis of (R)-(-)-2-Acetyl-2,5,12-trihydroxy-1,2,3, 4-tetrahydro-6,11-naphthacenequino ne via Diastereoselective Diels- Alder Cycloaddition. (1993) (0)
Synthesis and Circular Dichroism of Optically Pure (+)‐(1S,2S,5S)‐5‐Methoxy‐3,4,6,7‐tetramethylidenebicyclo(3.2.1)oct‐2‐yl Derivatives. Baker′s Yeast Reduction of 4‐Methoxy‐5,6,7,8‐tetramethylidenebicyclo(2.2.2)octan‐2‐one. (1990) (0)
Stereoselective Synthesis of 8‐Oxabicyclo[3.2.1]octane‐2,3,4,6,7‐pentols and Total Asymmetric Synthesis of 2,6‐Anhydrohepturonic Acid Derivatives and of β‐C‐manno‐Pyranosides Suitable for the Construction of (1→3)‐C,C‐Linked Trisaccharides. (2001) (0)
STEREOSELECTIVE CONTROL IN THE BASE-CATALYZED HYDROGEN/DEUTERIUM EXCHANGE OF 5,6-DIMETHYLIDENE-2-BICYCLO(2.2.N)ALKANONE TRICARBONYLIRON COMPLEXES. REVISION OF THE STRUCTURES OF TRICARBONYLIRON COMPLEXES O 5,6-DIMETHYLIDENEBICYCLO(2.2. (1984) (0)
Synthesis of 4-Hydroxy-2,6-bis(hydroxymethyl)tetrahydropyran-2-carbaldehyde Derivatives. (2010) (0)
Cyclodimerization of 1‐(Dimethoxymethyl)‐5,6‐dimethylidene‐7‐oxabicyclo(2.2.1)hept‐2‐ene Induced by Nonacarbonyldiiron. Crystal Structure of (1RS,2SR,3RS,4RS,4aRS,9aSR)‐Tricarbonyl(C,2,3,C‐η‐(1,4‐epoxy‐1,5‐bis(dimeth# oxymethyl)‐2,3‐dimethylidene‐1,2,3,4,4a,9,9a,10‐octahydroanthracene))iron. (1989) (0)
Remote Substituent Effect on the Electrophilic Additions of 1,3‐Dienes. Synthesis of (2R)‐5‐(Acetoxymethyl)‐2‐acetyl‐1,2,3,4‐tetrahydro‐10‐ methoxynaphthacene‐2,12‐diyl Diacetate. (1995) (0)
Depletion of the intracellular coenzyme NAD plus in activated T-cells ameliorates experimental autoimmune encephalomyelitis (2009) (0)
Aliphatic and Alicyclic Ketones (excluding Cyclobutanones and Cyclopropanones) (2005) (0)
Synthesis of Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐2‐enes Precursors in the Preparation of Taxol Analogues. (1997) (0)
Remote Control of Diels—Alder Additions. Enantioselective Synthesis of (2R)‐1,2,3,4‐Tetrahydro‐2‐hydroxy‐5,8‐dimethoxynaphthalen‐2‐yl Methyl Ketone (Wong′s Anthracycline Intermediate) from Furfural. (1998) (0)
2,3,5,6,7,8-HEXAKIS(METHYLENE)BICYCLO(2.2.2)OCTANE (1981) (0)
MONOOLEFIN AND DIENE CYCLOADDITION INDUCED BY TRANSITION-METAL CARBONYLS. CYCLODIMERIZATION OF 5,6-DIMETHYLIDENE-7-OXABICYCLO(2.2.1)HEPT-2-ENE CATALYZED BY DODECACARBONYLTRIOSMIUM (1984) (0)
One-Pot, Asymmetric and Diastereoselective Four-Component Synthesis of Polyfunctional (Z)-Alkenyl Methyl Sulfones with Three Stereogenic Centers. (2010) (0)
Asymmetric Total Synthesis of (11R,12S,13S,9Z,15Z)-9,12,13- Trihydroxyoctadeca-9,15-dienoic Acid (IX), a Self-Defensive Agent Against Rice-Blast Disease. (1995) (0)
Synthesis of β‐D‐(1 → 3)‐C‐Linked 1,5,6‐Trideoxy‐1,5‐ iminogalactoside of D‐Altrose Derivatives. (1996) (0)
A NEW, DOUBLY CONVERGENT SYNTHESIS OF ANTHRACYCLINONES. DIELS-ALDER ADDITIONS TO 2,3,5,6-TETRAKIS(METHYLENE)-7-OXANORBORNANE (1980) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 19. CRYSTAL AND MOLECULAR STRUCTURE OF 2,3,5,6,7,8-HEXAMETHYLIDENEBICYCLO(2.2.2)OCTANE (′(2.2.2)HERICENE′) (1983) (0)
BCl3‐Mediated Ene Reaction of Sulfur Dioxide and Unfunctionalized Alkenes. (2010) (0)
2,3,5,6-TETRAMETHYLIDENE-BICYCLO(2.2.1)HEPTAN (1975) (0)
PREPARATION AND DIELS-ALDER REACTIVITY OF TRICARBONYLIRON COMPLEXES OF (2.2.2)HERICENE (1984) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 18. PREPARATION AND DIELS-ALDER REACTIVITY OF 2,3,5,6,7,8-HEXAMETHYLIDENEBICYCLO(2.2.2)OCTANE (′(2.2.2)HERICENE′). FORCE-FIELD CALCULATIONS OF EXOCYCLIC DIENES AS A MOIETY OF BICYCL (1983) (0)
STEREOSELECTIVE DOUBLE FUNCTIONALIZATION OF IRON-CARBONYL COMPLEXES OF 5,6,7,8-TETRAMETHYLIDENEBICYCLO(2.2.2)OCT-2-ENE. CRYSTAL STRUCTURE AND ABSOLUTE CONFIGURATION OF (-)-TRANS-μ-((2S,5R,7S)-C,5,6,C-η:C,7,8,C-η-(6,7,8-TRIMETHYLIDENE- (1985) (0)
THE SYNTHESIS OF (.+-.)-11-DEOXYDAUNOMYCINONE VIA REGIOSELECTIVE TANDEM DIELS-ALDER REACTIONS (1985) (0)
CHEMO-, REGIO- AND STEREOSELECTIVE HYDROALUMINATION OF 7,8-EPOXY-2,3,5,6-TETRAMETHYLENEBICYCLO(2.2.2)OCTANE (1983) (0)
2,3,5,6‐Tetrakis(methylene)‐1,4‐cyclohexanediyl (1,2,4,5‐ Tetramethylenebenzene), a Disjoint Non‐Kekule Singlet Hydrocarbon Biradical. (1993) (0)
Synthesis of the C(1)—C(11) Polyene Fragment (I) of Apoptolidin with a New Sulfur Dioxide‐Based Organic Chemistry. (2006) (0)
Stereoselective Aminohydroxylation of the Double Bond in 7-Oxabicyclo-(2.2.1)hept-5-en-2-yl Derivatives. Remote Substituent Participation in Acid-Catalyzed Decompositions of Aziridines and Triazolines. (1989) (0)
Disaccharides through Carbonylative Stille Cross Coupling (2008) (0)
OXYGEN-17 NUCLEAR MAGNETIC RESONANCE. THE EFFECTS OF REMOTE UNSATURATION ON OXYGEN-17 CHEMICAL SHIFTS IN POLYCYCLIC ETHERS (1981) (0)
Development of a New Carbon—Carbon Bond Forming Reaction. New Organic Chemistry of Sulfur Dioxide. Asymmetric Four-Component Synthesis of Polyfunctional Sulfones. (2010) (0)
Iron‐Catalyzed Mizoroki—Heck Cross‐Coupling Reaction with Styrenes. (2009) (0)
INTERACTIONS BETWEEN NONCONJUGATED CHROMOPHORES. 13. INTERACTION BETWEEN EXOCYCLIC S-CIS-BUTADIENE AND HOMOCONJUGATED FUNCTIONS. PREPARATION AND DIELS-ALDER REACTIVITY OF REMOTELY SUBSTITUTED 2,3-DIMETHYLIDENEBICYCLO(2.2.2)OCTANES (1982) (0)
Total Syntheses of (+)‐ and (‐)‐1‐Deoxynojirimycin (1,5‐Dideoxy‐1,5‐imino‐D‐ and L‐glucitol) and of (+)‐ and (‐)‐1‐Deoxyidonojirimycin (1,5‐Dideoxy‐1,5‐imino‐D‐ and L‐iditol) via Furoisoxazoline‐3‐aldehydes. (1999) (0)
(1S,2S,7R,8aS)‐ (X) and (1S,2S,7S,8aS)‐Trihydroxyoctahydroindolizine ( XII): Two New Glycosidase Inhibitors by Nitrone Cycloaddition Strategy. (1996) (0)
The solvolyses of exo- and endo-5-norbornen-2-yl p-bromobenzenesulfonates. A re-investigation using deuterium nmr spectroscopy. (1978) (0)
Synthesis of Higher-Carbon Sugars via Cross-Aldolization of 7-Oxanorbornan-2-one and Carbohydrate Aldehyde Derivatives. (1990) (0)
ANTHRACYCLINONES. PART II. SYNTHESIS OF (.+-.)-4-DEMETHOXYDAUNOMYCINONE BY DOUBLE DIELS-ALDER ADDITIONS TO 2,3,5,6-TETRAMETHYLIDENE-7-OXANORBORNANE (1980) (0)
Expeditious Syntheses of Methyl 8‐epi‐Nonactate and Methyl Nonactate. (1987) (0)
Radical Additions to Silyl Ketene Acetals. Introduction of C‐Moieties to 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐endo‐ol. (1992) (0)
Negishi Cross-Coupling of Sulfonyl Chlorides (2006) (0)
Regioselective Rearrangement of 7‐Azabicyclo[2.2.1]hept‐2‐aminyl Radicals: First Synthesis of 2,8‐Diazabicyclo[3.2.1]oct‐2‐enes and Their Conversion into 5‐(2‐Aminoethyl)‐2,3,4‐trihydroxypyrrolidines, New Inhibitors of α‐Mannosidases. (2003) (0)
Ab initio and experimental studies on the hetero-Diels-Alder and cheletropic additions of sulfur dioxide to (E)-1-methoxybutadiene: a mechanism involving three molecules of SO(2). (2002) (0)
New organic chemistry of sulfur dioxide: new reactions, newreagents, total asymmetric synthesis of polypropionateantibiotics (2020) (0)
Sulfur Dioxide Mediated One-Pot, Four-Component Synthesis of Polyfunctional Sulfones and Sulfonamides, Including Medium-Ring Cyclic Derivatives. (2006) (0)
A Novel Approach to the Synthesis of N‐Substituted 1‐C‐Aminomethyl Glycofuranosides. (2006) (0)
Stereoselective Synthesis of New Conduramines and Aminocyclitol Derivatives. (1999) (0)
Stereoselective Synthesis of 5a-Ethyl-1,2,3,3a,4,5,5a,6,9a,9b-decahydro-1,3,4-trihydroxy-3a- (hydroxymethyl)-7H-benz[e]inden-7-one Derivatives. (2010) (0)
Glycochemistry today. (2011) (0)
Highly Stereoselective, Total Synthesis of β-C-Hexopyranosyl Derivatives. (1993) (0)
3‐Acetoxy‐2‐trimethylsilylmethyl‐1‐propene (2007) (0)
Optical resolution of bicyclic cyanohydrins. The structure of the hydrogen-bonded brucine–cyanohydrin complex derived from (+)-norbornenone (1987) (0)
Substituent Effect on the Regioselectivity of One-Carbon Ring Expansions of 7-Oxabicyclo(2.2.1)heptan-2-one Derivatives with Diazomethane. (1992) (0)
Interaction between Non-Conjugated Chromophores .22. Synthesis and Diels-Alder Reactivity of 1-(Dimethoxy)Methyl-2,3,5,6-Tetramethylidene-7-Oxabicyclo[2.2.1]Heptane (1985) (0)
Ligandless Iron‐Catalyzed Desulfinylative C—C Allylation Reactions Using Grignard Reagents and Alk‐2‐enesulfonyl Chlorides. (2010) (0)
Organosulfur Compounds: Electrophilic Reagents in Transition‐Metal‐Catalyzed Carbon—Carbon Bond‐Forming Reactions (2006) (0)
Pyrimidalization of the Carbon-Atom of the Nitrogen-Carbon Double-Bond of 2-Azabicyclo[2.2.1]Hept-2-Enes - Radiocrystallographic Study and Calculations of Quantum-Mechanics (1986) (0)
Hetero-Diels—Alder and Cheletropic Additions of Sulfur Dioxide to Conjugated Dienes. Experimental Facts and Theoretical Analysis (2007) (0)
Synthesis of (Z)‐3‐Deoxy‐3‐ (1,2,3,6‐tetradeoxy‐3,6‐imino‐L‐arabino‐hexitol‐1‐C‐ylidene) ‐D‐xylo‐hexose Derivatives. First Examples of Homo‐(1→3)‐C‐linked Iminodisaccharides. (2000) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 25. Total Asymmetric Synthesis of 3-Amino-3-deoxy-L-talose (XI) and Derivatives. (1994) (0)
Stereoselective Double Friedel‐Crafts Acylation of trans‐μ‐(2,3,6,7‐Tetramethylidene‐ bicyclo[3.2.1]Octane)bis(tricarbonyliron). (1986) (0)
New Carbon‐Carbon Bond Formation Through Oxyallylation of Enoxysilanes with Sulfur Dioxide Adduct of 1‐Methoxybutadiene. Stereoselective Synthesis of (Z)‐4‐Methoxy‐6‐oxoalk‐2‐enyl Methyl Sulfones. (1997) (0)
Asymmetric Synthesis of the Polyol Subunit of the Polyene Macrolide Antibiotic RK‐397. (2006) (0)
THE NON-PLANARITY OF THE BICYCLO(2.2.1)HEPT-2-ENE DOUBLE BOND. CRYSTAL STRUCTURES OF BICYCLO(2.2.2)OCT-2-ENE, BICYCLO(2.2.1)HEPT-2-ENE, AND BICYCLO(2.1.1)HEX-2-ENE SYSTEMS (1984) (0)
Radical Cation States of 2,3,5,6-Tetramethylenenorbornane, 2,3,5,6-Tetramethylenebicyclo[2.2.2]Octane and of Related Compounds (2010) (0)
CCDC 796122: Experimental Crystal Structure Determination (2011) (0)
Palladium-Catalyzed Suzuki—Miyaura Cross-Couplings of Sulfonyl Chlorides and Boronic Acids. (2004) (0)
Asymmetric Syntheses of New Polyhydroxylated Quinolizidines: Cross-Aldol Reactions of 7-Oxabicyclo[2.2.1]heptan-2-one and 3a,4a,7a,7b-Tetrahydro[1,3]dioxolo[4,5]furo [2,3-d]isoxazole-3-carbaldehyde Derivatives. (2010) (0)
Remote Substituent Control of the Regioselectivity of the Aryl‐ and Vinylpalladation of 7‐Oxabicyclo(2.2.1)heptenes. (1996) (0)
BICYCLO(3,1,0)HEXEN-(3)-YL-(2)-KATION (1971) (0)
The Diels-Alder Reactivity of 2,2′-Ethylidenebis(3,5-dimethylfuran) and Exploratory Chemistry of the Monoadducts. (1996) (0)
Polynuclear Iron and Rhodium Complexes of 7‐Oxa(2.2.1)hericene (2,3,5,6‐Tetramethylidenebicyclo(2.2.1)heptan‐7‐one). (1989) (0)
PYROLYSE VON 2,3-DIMETHYLIDEN-7-OXABICYCLO(2,2,1)HEPTAN (1974) (0)
Derivatives of (2R,3R,4S)-2-aminomethylpyrrolidine-3,4-diol are selective alpha-mannosidase inhibitors. (2001) (0)
Total Synthesis of Cyclophellitol (I) Starting from Furan. (1993) (0)
Syntheses of (+)- and (-)-Methyl 8-Epinonactate and (+)- and (-)-Methyl Nonactate. (1987) (0)
Synthesis of α‐(1→3)‐ and α‐(1→4)‐Linked C‐ Disaccharides Using (+)‐7‐Oxabicyclo(2.2.1)hept‐2‐en‐2‐one (“Naked Sugar”). (2010) (0)
“Naked Sugars of the Second Generation”: Asymmetric Synthesis of Long- Chain Polypropionates and Analogues Starting with Acetone (1996) (0)
SYNTHESIS AND DIELS-ALDER REACTIVITY OF 2,3,5,6-TETRAMETHYLIDENENORBORNANE (1982) (0)
Carbaxylosides of 4-Ethyl-2-oxo-2H-benzopyran-7-yl as Nonhydrolyzable, Orally Active Venous Antithrombotic Agents. (1998) (0)
CONFORMATIONAL ANALYSIS OF 2,3,5,6-TETRAKIS(METHYLENE)BICYCLO(2.2.2)OCTANES BY CIRCULAR DICHROISM (1984) (0)
Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 17. Total, Asymmetric Synthesis of Hexoses and Azasugars Branched at C(5). (1992) (0)
Specific, Uncompetitive Inhibition of β‐Galactosidases by a 5,6‐Isopropylidenedioxyfuro[2,3‐d]isoxazole‐3‐methanol Derivative. (2010) (0)
A Short and Flexible Route to Aza‐β‐(1→6)‐C‐disaccharides: Selective α‐Glycosidase Inhibitors. (2010) (0)
2,3-Bis(methylene)bicyclo[2.1.1]hexane and 3,4-Bis(methylene)tricyclo-[3.1.0.02,6]hexane. (1986) (0)
ORGN 454-New organic chemistry of sulfur dioxide: Asymmetric total synthesis of polypropionate antibiotics (2009) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 9. THE EFFECTS OF HOMOCONJUGATED CYCLOPROPANE AND OXIRANE RINGS ON THE DIELS-ALDER REACTIVITY OF 2,3-BIS(METHYLIDENE)NORBORNANE (1980) (0)
Synthesis of New Pyrrolidine Derivatives as Inhibitors of α‐Mannosidase and of the Growth of Human Glioblastoma Cells. (2007) (0)
Synthesis of 1,1‐Bis(3,5‐dimethyl‐2‐furyl)ethene. The Chemo‐ and Site‐ Selectivity of Its Cycloadditions. (1993) (0)
Synthesis of tri-and tetramines containing two 2,3-dihydroxypyrrolidine moieties and their inhibitory activity toward alpha-mannosidases (2002) (0)
Enantiomerically pure 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives (naked sugars) as synthetic intermediates. XII. Highly stereoselective total syntheses of octoses and derivatives. [Erratum to document cited in CA114(25):247589y] (1992) (0)
Tandem Staudinger—azaWittig Mediated Ring Expansion: Rapid Access to New Isofagomine-Tetrahydroxyazepane Hybrids. (2007) (0)
Synthesis of Rare Carbohydrates and Analogues Starting from Enantiomerically Pure 7-Oxabicyclo[2.2.1]heptyl Derivatives (“Naked Sugars”) (2000) (0)
Total Asymmetric Synthesis of a New 9,12‐Anhydroerythronolide Aglycone. (2002) (0)
alpha- and beta-homogalactonojirimycins (alpha- and beta-homogalactostatins): synthesis and further biological evaluation. (2001) (0)
HYDROGEN CHLORIDE ELIMINATION FROM PRIMAR (1979) (0)
Trifluoromethanesulfonyl chloride, first update (2006) (0)
Iron/copper-catalyzed CC cross-coupling of aryl iodides with terminal alkynes (2009) (0)
Synthesis of monosaccharides and analogues -Part two: chain elongation of aldehydes (2007) (0)
A New Asymmetric Carbon—Carbon Bond Forming Reaction: Four‐Component Stereoselective Synthesis of (Z)‐4,6‐Dihydroxy‐3‐methylalk‐2‐enyl Methyl Sulfones. (2000) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 20. SYNTHESIS AND DIELS-ALDER REACTIVITY OF 5,6,7,8-TETRAMETHYLIDENE-2-BICYCLO(2.2.2)OCTANOL AND -OCTANONE. SELECTIVE OXIDATIONS OF THE CORRESPONDING BIS(IRONTRICARBONYL) COMPLEXES (1984) (0)
Iron-Catalyzed Desulfinylative C—C Cross-Coupling Reactions of Sulfonyl Chlorides with Grignard Reagents. (2008) (0)
EFFICIENT SYNTHESIS OF 2,3,5,6-TETRAMETHYLIDENE-7-OXANORBORNANE (1980) (0)
Cycloaddition of a 1,3‐Diene to a C ? C Double Bond Assisted by Iron Carbonyls. Synthesis of an Antitumoral Anthracyclinone Precursor (1982) (0)
Synthesis of 2,3,5,6-Tetramethylene (2,2,2)Bicyclo-7-Octene - Uv Spectrum and Reactivity with Strong Dienophile (1976) (0)
Homochiral Matching in the Diels-Alder Cyclodimerization of 2-Vinyl-7- oxabicyclo(2.2.1)hept-2-ene Derivatives. (1994) (0)
(2,9:6,12-η-2,3,5,6-TETRAKIS(METHYLENE)BICYCLO(2.2.2)OCTANE)ZIRCONOCENE, AN ISOLABLE BIS(OLEFIN)ZIRCONIUM(II) COMPOUND (1983) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. 14. REGIOSELECTIVITY OF THE DIELS-ALDER ADDITIONS OF 2-SUBSTITUTED 5,6-DIMETHYLIDENENORBORNANES AND -BICYCLO(2.2.2)OCTANES (1982) (0)
Interaction Between Oxygen Lone-Pair Orbitals of Ether and α,β-Unsaturated Ketone Functions in 3,5,6-Trimethylidene-7-oxabicyclo(2.2.1)heptan-2-one and 3,6-Dimethylidene-7-oxabicyclo(2.2.1)heptane-2,5-dione: A PE-Spectroscopic Investi (1990) (0)
THE HOMOALLYL-CYCLOPROPYLCARBINYL CATION REARRANGEMENT IN THE SOLVOLYSES OF EXO- AND ENDO-5-NORBORNEN-2-YL P-BROMOBENZENESULFONATES. APPLICATION OF DEUTERIUM NMR SPECTROSCOPY (1980) (0)
Conformational Analysis of α‐Methoxyketones. A Photoelectron Spectroscopic Investigation of 3‐Methoxybicyclo(2.2.1)heptan‐2‐ones (1992) (0)
Stereoselective Synthesis of C‐Disaccharides, Aza‐C‐Disaccharides and C‐Glycosides of Carbapyranoses Using the “Naked Sugars” (2005) (0)
A Highly Stereoselective Total Synthesis of (.+-.)-Castanospermine (II). (1989) (0)
New Organic Chemistry of Sulfur Dioxide (2008) (0)
Interactions between Homoconjugated Diene and Epoxide Functions. Effect on Diels-Alder Regioselectivity. The Circular Dichroism of 2,3-Dimethylidene-5-norbornyl Derivatives. (1983) (0)
CHARGE-TRANSFER BANDS OF BICYCLIC β,Γ-UNSATURATED KETONES. CIRCULAR DICHROISMS OF (+)-(1R)-5,6-DIMETHYLIDENE-2-BICYCLO(2.2.2)OCTANONE AN (+)-(1R)-2-BICYCLO(2.2.2)OCT-5-ENONE (1982) (0)
Synthesis of a C29—C51 Subunit of Spongistatin 1 (Altohyrtin A) Starting from (R)‐3‐Benzyloxy‐2‐methylpropan‐1‐ol. (2000) (0)
Synthesis of a Polyhydroxyquinolizidine Bearing a Polyhydroxylated Carbon Side‐Chain. (1999) (0)
Ligandless Iron‐Catalyzed Desulfinylative C–C Allylation Reactions using Grignard Reagents and Alk‐2‐enesulfonyl Chlorides (Eur. J. Org. Chem. 36/2009) (2009) (0)
Synthesis, Crystal-Structure and Reactivity of (Mu-3-Eta-2-7-Oxabicyclo[2.2.1]Hept-5-Yn-2-One)-Nonacarbonyldihydridotri Ruthenium and (Mu-3-Eta-2-7-Oxabicyclo[2.2.1]Hept-5-Yn-2-One)-Hexacarbonyldihydridotri S(Triphenylphosphine)Triruthenium (1992) (0)
Total Synthesis of Castanospermine and Other Potential Glycosidase Inhibitors (1989) (0)
The Demjanov and Tiffeneau-Demjanov One-Carbon Ring Enlargements of 2- Aminomethyl-7-oxabicyclo(2.2.1)heptane Derivatives. The Stereo- and Regioselective Additions of 8-Oxabicyclo(3.2.1)oct-6-en-2-one to Soft Electrophiles. (1993) (0)
The Homoconjugated Electron-Releasing Carbonyl Group of 1- Methylbicyclo(2.2.1)hept-5-en-2-one. Regioselective Syntheses of 5- Chloro- and 6-Chloro-1-methylbicyclo(2.2.1)hept-5-en-2-one (1993) (0)
l.m.n.)Hericenes and Related Exocyclic Polyenes (1990) (0)
THE CHEMISTRY OF PROTOADAMANTANE PART 6, BRIDGED AND CLASSICAL POLYMETHYL 2‐ADAMANTYL CATIONS (1974) (0)
Synthesis of Enantiomerically Enriched 2-Substituted Pyrrolidine Analogues of Norhygrine. Application of the Hetero-Diels—Alder Addition of Sulfur Dioxide. (2007) (0)
Unexpected Selectivity Between Pinacolic Rearrangement and Intramolecular Displacement in the Acid‐Promoted Epoxide Ring Opening of 6‐exo‐Cyano‐3,8‐dioxatricyclo(3.2.1.02,4)oct‐6‐endo‐yl Esters. (1994) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives as Synthetic Intermediates. Part 3. Total Synthesis of D- and L-Ribose Derivatives. (1988) (0)
The Reactions of γ‐Butyrolactone and γ‐Butyrolactonol Derivatives, and of Tetrahydrofuran with Mixtures of Alcohols and Thionyl Chloride. (1992) (0)
Palladium‐Catalyzed Desulfinylative Negishi C—C Bond Forming Cross‐Coupling of Sulfonyl and Organozinc Chlorides. (2006) (0)
Synthesis of (+)-3,7,8-Trideoxy-3,7-imino-D-threo-L-galacto-octitol and Its Inhibition of β-Glucosidases. (1996) (0)
Long‐Range Substituent Effects. The Regioselective Electrophilic Additions of exo‐3,6‐Epoxytetrahydrophthalide and Its Derivatives. (1987) (0)
Remote Tricarbonyl(diene)iron Substituent Effect on Ester Heterolysis. The Solvolyses of 5,6,7,8-Tetramethylidenebicyclo(2.2.2)oct-2-yl Methanesulfonate and of its Tricarbonyliron Mono- and Dinuclear Complexes. (1987) (0)
The Bora-ene Reaction of Sulfur Dioxide and Prop-2-ene-1-boronic Esters. New Route to Sulfoxides. (2006) (0)
The Diels‐Alder Chemoselectivity of 3,4,6,7‐Tetramethylidenebicyclo(3. 2.1)octane‐2‐exo,8‐syn‐diyl Derivatives. (1992) (0)
Polysulfones: Solid Organic Catalysts for the Chemoselective Cleavage of Methyl‐Substituted Allyl Ethers under Neutral Conditions. (2005) (0)
Convergent Synthesis of (1→2)‐ and (1→4)‐C‐Linked Imino Disaccharides. (2000) (0)
Asymmetric Total Synthesis of Azasugars Branched at C-5. (1992) (0)
Stabilizing Effect by Geminal Dioxy Substitution and Anomeric Effect in 3,6-Dihydro-6-methoxy-1,2-oxathiin 2-Oxides. (1993) (0)
Total Synthesis of Branched-Chain Higher-Carbon Sugars. First Synthesis of Caldose, Calditol, and 4-Deoxycalditol Stereoisomers. (1990) (0)
The endergonic ene-reaction of alkenes andSO, can now be used to prepare alpha, beta unsaturated sulfones and sulfonamides (2020) (0)
ORGN 229-Phosphineless iron-catalyzed carbon-carbon bond cross-coupling reactions (2009) (0)
Long‐Distance Effect on One‐Bond C‐C Scalar Couplings Upon Introduction of a Double Bond in Bicyclic Systems. (1997) (0)
Polyhydroxyazepanes Mimicking Monosaccharides: Synthesis of an α-D-Galacto-Like Iminoheptitol. (2005) (0)
Stereoselective Syntheses of Branched-Chain Carbohydrates Bearing Furan and Pyrrole Moieties. (1996) (0)
Palladium-Catalyzed Conversion of β,γ-Unsaturated Silyl Sulfinates into (E)-Alkenes: Asymmetric Synthesis of Polypropionate Fragments. (2004) (0)
Synthesis of a New C(1→2)‐Linked Iminodisaccharide Starting from Levoglucosenone. (2002) (0)
Synthesis and Circular Dichroism of 5- and 6-Halobicyclo(2.2.1)hept-5-en-2-ones: Tests for Dekker′s Quantitative Chirality Rule. (1988) (0)
DIELS-ALDER STEREO- AND REGIOSELECTIVITY CONTROLLED BY REMOTE SUBSTITUENTS AND SOLVENT. CYCLOADDITIONS OF 1-(DIMETHOXYMETHYL)-2,3-BIS(METHYLENE)-7-OXABICYCLO(2.2.1)HEPTANE (1985) (0)
THE CARBONYL GROUP AS A HOMOCONJUGATED ELECTRON-DONATING SUBSTITUENT. AB INITIO STO 3G MO CALCULATIONS (1984) (0)
CHEMO- AND STEREOSELECTIVE COORDINATION OF 5,6-DIMETHYLIDENE-7-OXABICYCLO(2.2.1)HEPT-2-ENE BY D8- AND D6-METAL CARBONYLS. DIELS-ALDER REACTIVITY OF DIENES PERTURBED BY REMOTE OLEFIN COMPLEXATION (1984) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 17. EFFECTS OF REMOTE SUBSTITUTION ON THE PHOTOOXIDATION OF EXOCYCLIC S-CIS-BUTADIENES GRAFTED ONTO BICYCLO(2.2.1)HEPTANES. THERMAL AND RHODIUM-CATALYZED REARRANGEMENTS OF 3,6-DIHYD (1982) (0)
Circular Dichroism of 5,6‐Dimethylidene‐2‐bicyclo[ 5,6‐Dimethylidene‐2‐bicyclo| 5,6‐Dimethylidene‐2‐bicyclo|2.2.n|aIkyl | 5,6‐Dimethylidene‐2‐bicyclo|2.2.n|aIkyl ]alkyl Esters. Chiral Exciton Coupling Between Benzoate and Exocyclic s‐cis‐Butadiene Chromophores. (1984) (0)
Synthesis of Seven‐ and Eight‐Membered Carbasugar Analogues via Ring‐Closing Metathesis and Their Inhibitory Activities Toward Glycosidases. (2003) (0)
Total Synthesis of the C37—C45 F-Ring Fragment of Spongistatins. (1998) (0)
Notes: The Chemistry of the Aliphatic Esters of Phosphorodithioic Acids. IV. O,O,S-Trialkyl Phosphorodithioates by the Reaction of O,O-Dialkyl Hydrogen Phosphorodithioates with Their Salts (1959) (0)
INTERACTION BETWEEN NON-CONJUGATED CHROMOPHORES- 5,6-DIMETHYLIDENE-EXO-2-NORBORNEOL, 5,6-DIMETHYLIDENE-EXO, EXO-2,3-NORBORNANEDIOL AND 5,6-DIMETHYLIDENE-2-NORBORNANONE (1977) (0)
Chemoselective C—H Bond Activation: Ligand and Solvent-Free Iron-Catalyzed Oxidative C—C Cross-Coupling of Tertiary Amines with Terminal Alkynes. Reaction Scope and Mechanism. (2009) (0)
Total Asymmetric Synthesis (2008) (0)
The Carbonyl Group as Homoconjugated Electron-Releasing Substituent. Regioselective Electrophilic Additions at Bicyclo(2.2.1)hept-5-en-2-one, Bicyclo(2.2.2)oct-5-en-2-one, and Derivatives. (1989) (0)
CRYSTAL STRUCTURE AND ABSOLUTE CONFIGURATION OF (+)-(1S,2R)-5,6-DIMETHYLIDENE-2-EXO-NORBORNYL-EXO-IRONTRICARBONYL P-BROMOBENZOATE (1982) (0)
A Novel Approach to the Synthesis of N-Substituted 1-C-Aminomethyl Glycofuranosides (2006) (0)
The Hetero-Diels-Alder Addition of Sulfur Dioxide: Structure of the First Crystalline Sultine. Quantum Calculations on the Conformations of 6-Fluoro-3,6-dihydro-1,2-oxathiine 2-Oxides. (2001) (0)
Synthesis of Rare Carbohydrates from 7-Oxanorbornenes (Naked Sugars) (1988) (0)
SYNTHESES OF 2,3,5,6-TETRAMETHYLENEBICYCLO(2.2.2)OCTANE AND 2,3,5,6-TETRAMETHYLENEBICYCLO(2.2.2)OCT-7-ENE. ULTRAVIOLET SPECTRA AND REACTIVITY WITH A STRONG DIENOPHILE (1977) (0)
THE Π-ANISOTROPY OF THE DOUBLE BOND OF A SYN-11-OXASESQUINORBORNENE DERIVATIVE. STEREOSELECTIVITY OF THE DIELS-ALDER ADDITIONS OF (2-NORBORNENO)(C)FURAN. CRYSTAL STRUCTURE OF 11-OXA-ENDO-TETRACYCLO(6.2.1.13,6.02,7)DODEC-2(7)-ENE-9,10- (1982) (0)
Naked Sugars as Synthetic Intermediates - Stereospecific Synthesis of L-Daunosamine (1985) (0)
NATUR DES BICYCLO(2,1,1)HEXYL-KATIONS (1973) (0)
Dihydroxypyrrolidines C‐Linked to Galactose. Total Synthesis of a Specific Inhibitor of α‐Mannosidases. (1997) (0)
Face Selectivity in the Diels‐Alder Additions and Chelotropic Addition of Sulfur Dioxide to 2‐(D)Methylidene‐3‐methylidenebicyclo[2.2.1]heptane. (1985) (0)
Synthesis and Diels-Alder Reactivity of 2,3,6,7-Tetrakis(methylene)bicyclo(3.2.1)octane. (1987) (0)
New Concise Total Synthesis of (+)‐Lentiginosine (I) and Some Structural Analogues. (2005) (0)
Acid‐Catalyzed Rearrangements of 5,6‐exo‐Epoxy‐7‐oxabicyclo(2.2.1)hept‐2‐yl Derivatives. Migratory Aptitudes of Acyl vs. Alkyl Groups in Wagner‐Meerwein Transpositions. (1988) (0)
Synthetic Studies toward the CD Spiroketal of Spongistatins Sylvain Favre (2010) (0)
Polyhydroxypyrrolidine Glycosidase Inhibitors Related to (+)-Lentiginosine. (2000) (0)
“Naked Sugars” as Synthetic Intermediates. Part 26. Synthesis of . alpha.-D-(1 3) and α-D-(1 4)-C-Linked Galactosides of D-Mannose Derivatives. Conformation of α-C- Galactosides. (1995) (0)
Highly Stereoselective Synthesis of (.+‐.)‐Aminobromocyclitol Derivatives (V), (XIV) from Furan. (1992) (0)
Solvolyses of Exo-5-Norbornen-2-Yl and Endo-5-Norbornen-2-Yl Para-Bromobenzenesulfonates - Reinvestigation Using Deuterium Nmr-Spectroscopy (1978) (0)
SITE OF PROTONATION AND CONFORMATIONAL EFFECTS ON GAS‐PHASE BASICITY IN β‐AMINO ALCOHOLS. THE NATURE OF INTERNAL HYDROGEN BONDING IN β‐HYDROXY AMMONIUM IONS (1983) (0)
Ironcarbonyl Complexes of 5,6-Dimethylidene-7-oxabicyclo(2.2.1)hept-2-ene Derivatives. Synthesis of Substituted Tricarbonyl(ortho-quinodimethane)iron Complexes and 2-Indanones. (1988) (0)
Variable temperature circular dichroism of tricarbonyl(1,3-diene)iron complexes (1984) (0)
Interaction Between Non-Conjugated Chromophores. Part.25. Diels-Alder Regioselectivity Controlled by Remote Substituents. (1986) (0)
Cycloaddition of a 1,3-diene to a carbon-carbon double bond assisted by iron carbonyls. Synthesis of an anthracyclinone precursor (1982) (0)
Naked Sugar as Synthetic Intermediates. Part 23. Total Synthesis of the Gastroprotective Substance AI‐77‐B and of Analogues. (1993) (0)
1H-NMR Spectra of Cyclohexa-1,4-dienes and Cyclohexenes Annellated to Bicyclo[2.2.1]hept-2-enes. (1986) (0)
Regioselectivity of Electrophilic Additions to 7-Oxabicyclo(2.2.1)heptenes Controlled by Remote Substituents. Arenesulfonyl Substituted 7-Oxabicyclo(2.2.1)heptenes as Stereo- and Regioselective Chiral Dienophiles. (1987) (0)
Tandem Cheletropic Additions of Sulfur Dioxide to (2.2.2)Hericene. The “Barrelene Effect”. (1988) (0)
REGIOSELECTIVITY OF THE DIELS-ALDER CYCLOADDITIONS OF 2-SUBSTITUTED 5,6-BIS(METHYLENE)-NORBORNANES (1979) (0)
Total Synthesis of Allonojirimycin (5-Amino-5-deoxy-D-allopyranose). (1990) (0)
Facile Migration of Acyl Groups in Wagner-Meerwein Transpositions. Acid-Catalyzed Rearrangements of 5,6-exo-Epoxy-7-oxa-2-bicyclo(2.2.1)heptanone and Derivatives. (1987) (0)
Stereoselective Nucleophilic Additions to a Bicyclic Ketone Controlled by a Remote Tricarbonyl(diene)iron Moiety. (1986) (0)
Stereoselective Synthesis of 2,4,6‐Trimethylcyclohex‐4‐ene‐1,3‐diol Derivatives and of Polypropionate Fragments with Four Contiguous Stereogenic Centers. (1995) (0)
Sulfur dioxide: A nice recoverable inorganic tool for the construction of bioactive compounds (2017) (0)
Interactions Between Non-Conjugated Chromophores. Part 28. Regioselective Electrophilic Additions of Bicyclo(2.2.n)alk-2-enes Controlled by Remote Epoxide Functions. (1988) (0)
Convergent Syntheses of C(1→3)‐Linked Disaccharides Starting from Isolevoglucosenone. (2000) (0)
STEREOSELECTIVITY OF THE DIELS-ALDER ADDITIONS OF EXOCYCLIC DIENES GRAFTED ONTO BICYCLO(2.2.N)ALKANES (1980) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART II. OPTICAL ACTIVITY IN REMOTELY PERTURBED EXOCYCLIC S-CIS-BUTADIENES. PREPARATION AND CIRCULAR DICHROISM AND ENANTIOMERICALLY PURE 5,6-DIMETHYLIDENE-2-NORBORNYL DERIVATIVES (1980) (0)
Highly Stereoselective Aminohydroxylations of exo‐2‐Cyano‐7‐oxabicyclo( 2.2.1)hept‐5‐en‐2‐yl Acetate. (1992) (0)
Syntheses of Stable α‐Silyloxy Epoxides and α‐Chloroalkyl Silyl Ether Derivatives of 3,10‐Dioxa‐5‐azatricyclo(5.2.1.02,6)dec‐4‐ enes. (1994) (0)
Tandem Diels‐Alder Reactivity Controlled by Remote Substituents. Regioselective Synthesis of Linearly Anellated Six‐Membered Ring Systems from (1RS,5SR,6RS,7SR)‐6,7‐Bis(chloromethyl)‐8,9‐dimethylidene‐2‐oxabicyclo(3.2.2)nonan‐3‐one. Crystal Structure of (1RS,5RS,6SR,11RS)‐6,7‐Bis(chloromethyl)‐3‐oxo (1988) (0)
Circular Dichroism of Tricarbonyl(diene)iron Complexes. The Octant Rule Applied to Ketones Perturbed by Remote Fe(CO)3 Groups. (1986) (0)
Synthesis of (‐)‐6‐(3′‐Aminopropyloxy)methyl‐4‐demethoxy‐6,7‐dideoxy‐ daunomycinone, a New DNA Intercalator Related to Anthracyclines. (1995) (0)
Site- and Regioselectivity of the Hetero-Diels-Alder and Cheletropic Additions of Sulfur Dioxide to a 2,3,6,7-Tetramethylidenebicyclo(3.2.1) octane Derivative. (1994) (0)
10,11-METHYLEN- UND 11-METHYL-PROSTAGLANDIN (1973) (0)
Ironcarbonyl Complexes of Exocyclic Polyenes. The Tricarbonyl(1,3-Diene)Iron Moiety as Remote Substituent (1989) (0)
Cycloadditions of enones (2010) (0)
Face Selectivity of the Diels - Alder Additions of Sulfur-Substituted Dienes and Tetraenes Grafted onto 7-Oxabicyclo[2.2.1]heptanes. (1986) (0)
Synthesis and Solution Conformational Analysis of 2,3-Anhydro-3-C- [(1R)-2,6-anhydro-1-deoxy-1-fluoro-D-glycero-D-gulo-heptitol-1-C-yl] -β-D-gulo-furanose: First Example of a Monofluoromethylene-Linked C-Disaccharide. (2001) (0)
Interaction Between Non-Conjugated Chromophores. Part 15. Face Selectivity of the Diels-Alder Additions of 2-Substituted 5,6-Bis(E)-chloromethylidene)bicyclo- [2.2.2]octanes. (1982) (0)
Tandem Oxyallylations and Retro-ene Eliminations. One Pot Stereoselective Synthesis of Polypropionate Fragments with Three Contiguous Stereogenic Centers and One (E)-Alkene Unit. (1997) (0)
REDUCTION OF 5,6-DIMETHYLIDENE-EXO-2,3-EPOXYNORBORNANE WITH METAL HYDRIDES. EFFICIENT SYNTHESES OF 6-METHYL-5-METHYLIDENE-ANTI-3-NORTRICYCLANOL AND OF 2,3-DIMETHYLIDENE-ANTI-7-NORBORNANOL (1978) (0)
Total, Asymmetric Synthesis of Ethyl D‐ido‐4‐Heptulosuronate Derivatives Starting from Diethyl 4‐Oxopimelate. (1999) (0)
Drugs and high-value-added materials from agricultural leftovers (2020) (0)
IRON AND MOLYBDENUM CARBONYLS OF 5,6-DIMETHYLENE-7-OXABICYCLO(2.2.1)HEPT-2-ENE. CRYSTAL AND MOLECULAR STRUCTURE OF (C8H8O)FE2(CO)7 (1978) (0)
Synthesis of Carbohydrates and Derivatives from 7-Oxanorbornenes (Naked Sugars) (1990) (0)
The Electron-Donating Carbonyl Group Total Synthesis of Rare Sugars (1989) (0)
Structure of Tricarbonyl(diene)iron Complexes in Solution. Variable-Temperature Circular Dichroism of trans-μ-(2,3,5,6-Tetramethylidenebicyclo[2.2.2]octane)bis(tricarbonyliron) Complexes. (1986) (0)
Research Topics: Asymmetric Synthesis of Natural Products and Analogues of Biological Interest (1997) (0)
INDUCTIVE AND POLARIZABILITY EFFECTS OF AN EXOCYCLIC DIENE-IRON TRICARBONYL GROUP. THE ACETOLYSES OF EXO- AND ENDO-IRONTRICARBONYL COMPLEXES OF 5,6-DIMETHYLIDENE-2-EXO-NORBORNYL AND 2,3-DIMETHYLIDENE-7-ANTI-NORBORNYL PARABROMOBENZENES (1982) (0)
Sulfur Dioxide Mediated Syntheses of Polyfunctional Alkenes and (E,Z)‐ and (E,E)‐2,4‐Dien‐1‐ones. (2005) (0)
Asymmetric Syntheses of Herbicidine Undecoses and of C-Galactosides of Cyclitols Starting with Furan (1995) (0)
RADICAL CATION STATES OF 2,3,5,6,7,8-HEXAMETHYLIDENEBICYCLO(2.2.2)OCTANE (1980) (0)
Torturing the 7-Oxabicyclo[2.2.1]heptane Skeleton with an Oxetane Ring: 4,7-Dioxatricyclo[3.2.1.03,6]octane at 190K (1996) (0)
Interaction Between Non-Conjugated Chromophores. Part 27. Synthesis and Formation of Ironcarbonyl Complexes of 3′,3′-Dimethyl-2,3,5,6-tetramethylidenespiro(bicyclo(2.2.1)heptane-7,2′-oxirane). Single-Crystal and Molecular Structure of (1987) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 8. Total Synthesis of 2-(β-D-Ribofuranosyl)thiazole-4-carboxamide (Tiazofurin) and of Precursors of ribo-C-Nucleosid (1990) (0)
Derivatives of dihydroxypyrrolidine as anti- cancer compounds (2009) (0)
One-Pot, Four-Component Synthesis of Polyfunctional Sulfones. (2002) (0)
Palladium‐Catalyzed Desulfinylative C—C Allylation of Grignard Reagents and Enolates Using Allylsulfonyl Chlorides and Esters. (2009) (0)
Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 15. A New Total Synthesis of D‐threo‐L‐talo‐Octose. (1991) (0)
“Naked Sugars” as Synthetic Intermediates. Total Synthesis of L-Daunosamine. (1987) (0)
Syntheses of exo-3,8-Dioxatricyclo(3.2.1.02,4)octane and 4,7- Dioxatricyclo(3.2.1.03,6)octane and the Relative Basicities of Their Ethereal Moieties. (1993) (0)
The Simultaneous Double Diels‐Alder Addition of 1,1‐Bis(3,5‐ dimethylfur‐2‐yl)ethane; Toward a New, Asymmetric Synthesis of Long‐ Chain Polypropionate Fragments and Analogues. (1996) (0)
Synthesis of N-Substituted (3S,4S)- and (3R,4R)-Pyrrolidine-3,4-diols: Search for New Glycosidase Inhibitors. (2005) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 7. Acid-Catalyzed Rearrangement of 3-Aza-8-oxatricyclo(3.2.1.02,4)octan-6-one Acetals. Highly Stereoselective Total (1989) (0)
Preparation and Synthetic Applications of 8-Oxabicyclo[3.2.1]oct-6-en-3-one Derivatives (2008) (0)
Interactions Between Oxygen Lone‐Pair Orbitals and Double‐Bond π‐Orbitals in β,γ‐Unsaturated, Bicyclic Ketones: A PE‐Spectroscopic Investigation (1987) (0)
Synthesis of Undeculofuranoside Derivatives of the Herbicidins and of Analogues. (1996) (0)
Face Selectivity in the Diels-Alder Additions and Chelotropic Reaction of Sulfur-Dioxide of 2-Deuteriomethylene-3-Methylenebicyclo[2.2.1]Heptane (1985) (0)
FACE SELECTIVITY OF THE DIELS‐ALDER REACTION OF HEXADIENONE MOIETIES GRAFTED ONTO THE BICYCLO(2.2.2)OCTENE SKELETON AND PERTURBED BY A REMOTE TRICARBONYLBUTADIENEIRON GROUP (1985) (0)
Computational Chemistry Column: Should a chemist be able to do his own programming? (1992) (0)
CCDC 117983: Experimental Crystal Structure Determination (1999) (0)
π-Facial Diastereoselectivity in the Electrophilic and Electrophilic-Nucleophilic Additions to Dimethyl (1R,2R,3S,4S)-Bicyclo( 2.2.2)oct-5-ene-2,3-dicarboxylate. (1993) (0)
Total Asymmetric Syntheses of Conduritol-C and Conduritol-D, and of a Cyanoglucoside (1986) (0)
One-Pot, Three-Component Synthesis of Open-Chain, Polyfunctional Sulfones. (2002) (0)
The Electron-Releasing Homoconjugated Carbonyl Group. Application to the Total Synthesis of 3-Deoxy-, 4-Deoxyhexose, Lividosamine, and Derivatives. (1990) (0)
Expeditious Asymmetric Synthesis of Polypropionates Relying on Sulfur Dioxide-Induced C–C Bond Forming Reactions (2021) (0)
Polyhydroxylated Perhydro-1H-benz[e]indenyl Derivatives with Two Angular 3a,5a-Carbaldehyde Moieties (1999) (0)
STEREOSELECTIVE OXIDATION OF RUTHENIUM AND IRON CARBONYL COMPLEXES OF 5,6,7,8-TETRAKIS(METHYLENE)BICYCLO(2.2.2)OCT-2-ENE (1980) (0)
Total Asymmetric Synthesis of Doubly Branched Carba‐hexopyranoses and Amino Derivatives Starting from the Diels—Alder Adducts of Maleic Anhydride to Furfuryl Esters. (1999) (0)
Regio‐ and Stereoselective Thioamination of 7‐Oxabicyclo(2.2.1)hept‐5‐ en‐2‐yl Derivatives. (1994) (0)
Highly Stereoselective Synthesis of Perhydro‐8a‐(hydroxymethyl) phenanthrene‐1,2,4,5,7,8‐hexol and Derivatives. (1997) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 5. Highly Stereoselective Total Syntheses of 2,5-Anhydro-4-deoxy-D-ribo-hexonic Acid and of (1S)-1-C-(6-Amino-7H-pur (1989) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 24. Total Asymmetric Syntheses of 1,5-Dideoxy-1,5-iminooctitols and 1,2,6,7,8- Pentahydroxyindolizidines. (1994) (0)
Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 4. Total Synthesis of L‐Allose, L‐Talose, and Derivatives. (1989) (0)
Anticancer Activities of Novel Nicotinamide Phosphoribosyltransferase Inhibitors in Hematological Malignancies (2023) (0)
Synthesis of Amino‐ and Diaminoconduritols and Their Applications (2006) (0)
One-pot three- and four-component synthesis of polyfunctional sulfones, sulfonic esters, and sulfonamides (2003) (0)
Hetero‐Diels‐Alder Addition of Sulfur Dioxide to 1,3‐Dienes. Suprafaciality, Regioselectivity, and Stereoselectivity. (1993) (0)
Asymmetric Synthesis and DNA Intercalation of (‐)‐6‐(((Aminoalkyl)oxy) methyl)‐4‐demethoxy‐6,7‐dideoxydaunomycinones. (1997) (0)
Synthesis of alpha-C(1-->3)-mannopyranoside of N-acetylgalactosamine, a new beta-galactosidase inhibitor. (1999) (0)
Enantiomerically Pure 7-Oxabicyclo[2.2.1]Hept-5-En-2-Yl Derivatives (Naked Sugars) as Synthetic Intermediates .22. Stereoselective Synthesis of (1r)-1-C-(6-Amino-7h-Purin-8-Yl)-1,4-Anhydro-2,3-Dideoxy-3-Fluoro-D-Eryt Hro-Pentitol (1993) (0)
Stereoselective Synthesis of α-C-Galactopyranosides of Conduritols and Aminoconduritols. (2010) (0)
Total, Asymmetric Synthesis of Deoxypolyoxin C. (1991) (0)
“Naked Sugars” as Synthetic Intermediates. Part 25. Enantioselective Synthesis of (-)-Conduramine C1 (VI) and Aminobromocyclitol Derivatives. (1994) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 19. Total Asymmetric Syntheses of 3- and 4-Deoxy-Hexoses and Derivatives. (1993) (0)
Total Synthesis of Aminodeoxyhexoses Via the Amino-Hydroxylation of 7-Oxanorbornene Derivatives (1988) (0)
Regioselectivity of 7-Oxabicyclo(2.2.1)hepta-2,5-diene - Phenol Rearrangement as a Function of the Acid Promoter. Stereoselective Synthesis of 1,2,3,4-Tetrahydro-2-hydroxynaphthalen-2-yl Methyl Ketones. (1990) (0)
CONTROL OF THE DIELS-ALDER ADDITION REGIOSELECTIVITY BY REMOTE SUBSTITUENTS. SYNTHESIS OF ANTHRACYCLINE PRECURSORS (1983) (0)
Synthesis of 5-Alkoxycyclohex-2-enones by Ring-Closing Metathesis (2009) (0)
Dynamic Modeling of Diels-Alder Reaction Using Computer-Graphics (1987) (0)
UNAMBIGUOUS PROOF FOR ALKOXYCARBONYL-GROUP MIGRATION IN WAGNER-MEERWEIN REARRANGEMENTS (1981) (0)
A New Approach to the Synthesis of Long-Chain Polypropionates Based on the Diels-Alder Monoadditions of 2,2′-Ethylidenebis(3,5-dimethylfuran). (1996) (0)
TRANSITION METAL PROMOTED ISOMERIZATION OF 3-OXAQUADRICYCLANES, PREPARATION OF A NEW OXEPINE DERIVATIVE (1974) (0)
The Reaction of Water with Iron- and Rutheniumcarbonyl Complexes of Polyolefins: 1,2- and 1,4-Hydrogenation of 1,3-Dienes. Hydrogenolysis of Allylic Ethereal Bonds and Deoxygenation of 7-Oxabicyclo(2.2.1)hept-2-enes. (1988) (0)
Total Asymmetric Synthesis of 5-Deoxy-5-thio-L-allose. (1994) (0)
Asymmetric Synthesis of 1-Aminopentadecane-3,5,7,9,11,13,15-heptols and of 1,15-Diaminopentadecane-3,5,7,9,11,13-hexols and Derivatives Asymmetric Synthesis of Aminopentadecanealcohols and Derivatives (2002) (0)
ACETOLYSIS OF Π-IRONTRICARBONYL COMPLEXES OF 2,3-DIMETHYLIDENE-7-ANTI-NORBORNYL AND 5,6-DIMETHYLIDENE-2-EXO-NORBORNYL ESTERS (1981) (0)
Synthesis of an α-C-Galactoside of a Carbasugar: A New Class of Disaccharide Mimics. (1995) (0)
Chemo‐ and Stereoselective Functionalization of 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐one with Dichloroketene. (1987) (0)
Interaction Between Non-Conjugated Chromophores. Part 29. Circular Dichroism of Planar, Exocyclic s-cis-Butadienes Remotely Perturbed (1988) (0)
Synthesis of α‐C(1→3)‐Mannopyranoside of N‐Acetylgalactosamine, a New β‐Galactosidase Inhibitor. (1999) (0)
The Use of Levoglucosenone and Isolevoglucosenone as Templates for the Construction of C-Linked Disaccharides (2006) (0)
RADICAL CATION STATES OF 2,3,5,6‐TETRAMETHYLENENORBORNANE, 2,3,5,6‐TETRAMETHYLENEBICYCLO(2.2.2)OCTANE AND OF RELATED COMPOUNDS (1979) (0)
Noniterative Approach to the Total Asymmetric Synthesis of 15-Carbon Polyketides and Analogues with High Stereodiversity (2005) (0)
Remote Substituent Effects on the Cheletropic and Homocheletropic Additions of Sulfur-Dioxide to Exocyclic Polyenes Grafted onto Bicyclo[2.2.2]Octane Skeletons (1995) (0)
C‐Glycosides and C‐Disaccharide Precursors Through Carbonylative Stille Coupling Reactions. (1997) (0)
MACROCYCLES BY INTRAMOLECULAR DIELS‐ALDER REACTION ‐ REGIOSELECTIVE SYNTHESIS OF ANTHRACYCLINE PRECURSORS (1984) (0)
Experimental and ab Initio MO Studies on Collisions of CH4+·and CH5+with Molecular Oxygen: On the Formation of Methane (CH42+) and Methonium (CH52+) Dications and Stable CHn-Species (n: 0-3) (1985) (0)
INTERACTIONS BETWEEN NONCONJUGATED CHROMOPHORES. PART 12. THE PHOTOCHEMISTRY OF 5,6-DIMETHYLIDENE-2-NORBORNANONE. SYNTHESIS AND DIELS-ALDER REACTIVITY OF 2,3-DIMETHYLIDENEBICYCLO(2.1.1)HEXANE (1980) (0)
Enantomerically Pure 7-Oxabicyclo(2.2.1.)hept-5-en-2-yl Derivatives (“ Naked Sugars”) as Synthetic Intermediates. Part 21. Total, Asymmetric Synthesis of (1R)-1C-(6′-Amino-7′H-purin-8′-yl)-1,4-anhydro-3-azido-2, 3-dideoxy-D-erythro-pentitol. (2010) (0)
Synthesis of Optically Pure Tricarbonyliron Complexes of 5,6‐Dimethylidenebicyclo(2.2.2)oct‐2‐yl Derivatives. Crystal Structure and Absolute Configuration of (+)‐Tricarbonyl((1S,2S,4R,5R,6S)‐C,5,6,C‐η‐(5,6‐dimethylidenebicyclo(2.2.2)# oct‐2‐yl p‐Bromobenzoate))iron. (1988) (0)
Total Asymmetric Syntheses of β‐Hydroxy‐δ‐lactones via Umpolung with Sulfur Dioxide. (2011) (0)
A Total Asymmetric Synthesis of 2‐Deoxy‐L‐fucose (‐)‐(I) from Furan. (1992) (0)
One-pot synthesis of cyclic nitrones and their conversion to pyrrolizidines: 7a-epi-crotanecine inhibits alpha-mannosidases. (2006) (0)
Interaction Between Non‐Conjugated Chromophores. Part 26. Control of the Diels‐ Alder‐Addition Regioselectivity by Remote Olefins. (1986) (0)
Application of New Optically Pure Ketene Equivalents Derived from Tartaric Acids to the Total, Asymmetric Syntheses of (+)‐6‐ Deoxycastanospermine and (+)‐6‐Deoxy‐6‐fluorocastanospermine. (1991) (0)
Highly Stereoselective Total Syntheses of Octoses and Derivatives. (1991) (0)
Acid-Promoted Rearrangements of N-Substituted 8-Oxa-3-azatricyclo(3.2.1.02,4)octane-6,7-dicarboxylates: Remote Substituent Effects on the Regioselectivity of the N-Acylaziridine/Dihydrooxazole Rearrangement. (1990) (0)
Regioselective Synthesis of 5‐endo,6‐endo‐Dihydroxy‐7‐oxabicyclo(2.2.1) heptan‐2‐one with Differential Protection of the Diol Group. (1995) (0)
Synthesis of Polyfunctional, Linearly Condensed Six-Membered Ring Systems by Regioselective Tandem Diels-Alder Additions. Synthesis and Reactivity of 6,7-Bis(chloromethyl)-8,9-bis(methylene)-2-oxabicyclo-(3.2.1)nonan-3-one. (1987) (0)
Its Improved Stability by Forced Paenibacillus barcinonensis Xyn 10 B from Structural Insights into the Specificity of Enzyme Catalysis and Regulation : (2010) (0)
Intramolecular Diels-Alder Reactions of 3H-Pyrroles Resulting from the Thermal Rearrangements of 2H-Pyrroles. (1988) (0)
Structural studies of the p-anisotropy in norbornenes (1982) (0)
SECONDARY 2-NORBORNYL CATION INTERMEDIATES SUBSTITUTED AT C(5) AND C(7) BY ELECTRON-WITHDRAWING GROUPS. ADDITION OF FLUOROSULFURIC ACID TO UNSATURATED NORBORNANE DERIVATIVES (1979) (0)
INTERACTION BETWEEN NONCONJUGATED CHROMOPHORES. PART 16. FACE SELECTIVITY OF THE DIELS-ALDER ADDITIONS OF EXOCYCLIC DIENES GRAFTED ONTO 7-OXABICYCLO(2.2.1)HEPTANES (1982) (0)
Enantiomerically Pure 7‐Oxabicyclo(2.2.1)hept‐5‐en‐2‐yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 6. Synthesis of (‐)‐Conduritol C (1L‐Cyclohex‐5‐ene‐1,2,3/4‐tetrol). (1989) (0)
Control of Diels-Alder Addition, Stereo- and Regioselectivity by Remote Substituents and Tricarbonyl(diene)iron Moieties. (1987) (0)
Enantiomerically Pure 7-Oxabicyclo(2.2.1)hept-5-en-2-yl Derivatives (“Naked Sugars”) as Synthetic Intermediates. Part 11. Total Syntheses of (-)-Conduritol B (V) ((-)-1L-Cyclohex-5-ene-1,3/2,4-tetrol) and of (+)-Conduritol F (IV) ((+) (1990) (0)
Synthesis of (+)-1,3:2,5-Dianhydroviburnitol ((+)-(1R,2R,3S,5R,6S)-4,7-Dioxatricyclo(3.2.1.03,6)octan-2-ol). (1988) (0)
Phosphineless iron-catalyzed carbon-carbon bond cross-coupling reactions (2009) (0)
Synthesis of Monosaccharides and Analogues. Part 3. Monosaccharides from Simple Achiral Unsaturated Compounds (2009) (0)
Tandem Cheletropic Additions of So2 to [2.2.2]Hericene - the Barrelene Effect (1988) (0)
Stereoselective Methylations and Hydroxymethylations of 2,8‐Dioxabicyclo(3.2.1)octan‐3‐one Derivatives. Synthesis of Branched‐Chain Sugars. (1990) (0)
IRON, MOLYBDENUM AND TUNGSTEN CARBONYLS OF 5,6,7,8-TETRAKIS(METHYLENE)BICYCLO(2.2.2)OCT-2-ENE. CRYSTAL AND MOLECULAR STRUCTURE OF (C12H12)FE(CO)3 (1980) (0)
IRON AND MOLYBDENUM CARBONYLS OF 5,6,7,8-TETRAMETHYLENEBICYCLO(2.2.2)OCT-2-ENE (1977) (0)
The Syntheses of 3‐ and 4‐Deoxy‐hexoses (1995) (0)
π‐Facial Diastereoselection in (4 + 2) Cycloadditions of 3,4‐Epoxy‐ 2‐methyleneoxolanes with Oxadienes: A Short Synthesis of Spiroketals. (1994) (0)
Substituent Effects on the Regioselectivity of the Baeyer-Villiger Oxidation of 7-Oxabicyclo(2.2.1)heptan-2-ones. (1993) (0)
A New Stereoselective and Convergent Approach to the Synthesis of Long‐ Chain Polypropionate Fragments. (1995) (0)
Photoreductive Cleavage of Phenyl-Selenium Bonds of Phenylselenoalkanes. (2010) (0)

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What Schools Are Affiliated With Pierre Vogel?

Pierre Vogel is affiliated with the following schools:

University of Lausanne
University of Oviedo
ETH Zurich
École Polytechnique Fédérale de Lausanne
University of Seville
University of Basel
University of Florence
University of Geneva
University of Zurich