Richard F. Heck
#4,734
Most Influential Person
American chemist
Why Is Richard F. Heck Influential?
(Suggest an Edit or Addition)According to Wikipedia, Richard Frederick Heck was an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactionss that couple aryl halides with alkenes. The analgesic naproxen is an example of a compound that is prepared industrially using the Heck reaction.
Richard F. Heck's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides (1972) (1687)
- Palladium‐Catalyzed Vinylation of Organic Halides (2005) (874)
- Palladium reagents in organic syntheses (1985) (868)
- Palladium-catalyzed reactions of organic halides with olefins (1979) (716)
- Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives (1968) (593)
- Palladium-catalyzed carboalkoxylation of aryl, benzyl, and vinylic halides (1974) (542)
- Palladium-catalyzed amidation of aryl, heterocyclic, and vinylic halides (1974) (481)
- The Reaction of Cobalt Hydrotetracarbonyl with Olefins (1961) (398)
- Organophosphinepalladium complexes as catalysts for vinylic hydrogen substitution reactions (1974) (310)
- Palladium-catalyzed formylation of aryl, heterocyclic, and vinylic halides (1974) (250)
- Palladium-catalyzed conjugated diene synthesis from vinylic halides and olefinic compounds (1975) (210)
- Mechanism of arylation and carbomethoxylation of olefins with organopalladium compounds (1969) (202)
- Palladium-catalyzed arylation of allylic alcohols with aryl halides (1976) (198)
- The mechanism of carbonylation of halo(bis ligand)organoplatinum(II), -palladium(II), and -nickel(II) complexes (1976) (170)
- Palladium-catalyzed vinylic substitution with highly activated aryl halides (1978) (155)
- Palladium catalyzed reductions of halo- and nitroaromatic compounds with triethylammonium formate (1977) (144)
- Salt Effects and Ion Pairs in Solvolysis and Related Reactions. III.1 Common Ion Rate Depression and Exchange of Anions during Acetolysis2,3 (1956) (141)
- Carbonylation reactions of ortho-palladation products of .alpha.-arylnitrogen derivatives (1975) (124)
- Allylation of aromatic compounds with organopalladium salts (1968) (123)
- Palladium-catalyzed annulation of aryl iodides with diphenylacetylene (1987) (122)
- Alkyne reactions with arylpalladium compounds (1989) (117)
- The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones (1968) (117)
- Dicarboalkoxylation of olefins and acetylenes (1972) (110)
- Palladium-catalyzed synthesis of 2-quinolone derivatives from 2-iodoanilines (1978) (106)
- The palladium-catalyzed arylation of enol esters, ethers, and halides. A new synthesis of 2-aryl aldehydes and ketones (1968) (103)
- Aromatic haloethylation with palladium and copper halides (1968) (97)
- Acylcobalt Carbonyls and their Triphenylphosphine Complexes (1962) (97)
- Carboxyalkylation Reactions Catalyzed by Cobalt Carbonylate Ion (1963) (95)
- The addition of alkyl- and arylpalladium chlorides to conjugated dienes (1968) (90)
- Neighboring methoxyl participation in solvolytic nucleophilic substitution (1958) (86)
- The Reaction of Epoxides with Cobalt Hydrocarbonyl and Cobalt Tetracarbonyl Anion (1963) (85)
- Palladium-catalyzed arylation of ethylene (1978) (85)
- A synthesis of diaryl ketones from arylmercuric salts (1968) (83)
- 4.3 – Vinyl Substitutions with Organopalladium Intermediates (1991) (82)
- Alkyl- and Acyl-cobalt Carbonyls Containing Olefinic Unsaturation. Allylcobalt Tricarbonyl and Related Compounds1 (1961) (81)
- Palladium-catalyzed vinylic substitution reactions with heterocyclic bromides (1978) (80)
- Palladium-catalyzed triethylammonium formate reductions. 4. Reduction of acetylenes to cis-monoenes and hydrogenolysis of tertiary allylic amines (1980) (77)
- Isoquinolinium salt syntheses from cyclopalladated benzaldimines and alkynes (1988) (75)
- Palladium-catalyzed alkenylation and alkynylation of polyhaloarenes (1990) (73)
- New applications of palladium in organic syntheses (1978) (72)
- The 2010 Nobel Prize in Chemistry: Palladium-Catalysed Cross-Coupling (2011) (71)
- Palladium-catalyzed vinylic substitution reactions with carboxylic acid derivatives (1977) (68)
- Electronic and steric effects in the olefin arylation and carboalkoxylation reactions with organopalladium compounds (1971) (64)
- The Mechanism of the Allyl Halide Carboxylation Reaction Catalyzed by Nickel Carbonyl (1963) (64)
- Palladium-catalyzed reductions of .alpha.,.beta.-unsaturated carbonyl compounds, conjugated dienes, and acetylenes with trialkylammonium formates (1978) (62)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. III. Hydrogen, Nitrosyl and Binuclear Derivatives (1963) (56)
- Palladium-catalyzed cyclizations of bromodialkenyl ethers and amines (1983) (55)
- Addition reactions of transition metal compounds (1969) (55)
- π-Allyliron Carbonyl Complexes (1964) (51)
- Alkyliridium and Alkylrhodium Dihalocarbonylbis (trialkyl- or triarylphosphines) (1964) (51)
- 2-(Phenylazo)phenyl complexes of the transition metals (1968) (50)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. I. Acylcobalt Carbonyls (1963) (49)
- Rearrangement in the palladium-catalyzed cyclization of .alpha.-substituted N-acryloyl-o-bromoanilines (1979) (48)
- Palladium-catalyzed syntheses of conjugated polyenes (1981) (48)
- Palladium-catalyzed syntheses of aryl polyenes (1984) (48)
- Cinnolinium salt synthesis from cyclopalladated azobenzene complexes and alkynes (1987) (47)
- Low-pressure, palladium-catalyzed N,N'-diarylurea synthesis from nitro compounds, amines, and carbon monoxide (1975) (45)
- Ligandless Heck Coupling between a Halogenated Aniline and Acrylonitrile Catalyzed by Pd/C: Development and Optimization of an Industrial-Scale Heck Process for the Production of a Pharmaceutical Intermediate (2008) (44)
- Palladium-catalyzed triethylammonium formate reductions. 3. Selective reduction of dinitroaromatic compounds (1980) (42)
- REACTIONS OF ALKYL- AND ACYL-COBALT CARBONYLS WITH TRIPHENYLPHOSPHINE (1960) (40)
- Alkyne reactions with cyclopalladated complexes (1986) (40)
- Palladium-catalyzed arylation of conjugated dienes (1978) (40)
- Selective palladium-catalyzed vinylic substitutions with bromoiodo aromatics (1979) (38)
- Synthesis and Reactions of Alkylcobalt and Acylcobalt Tetracarbonyls (1966) (36)
- Reactions of .pi.-allylic palladium intermediates with amines (1980) (36)
- Palladium-catalyzed vinylic substitution reactions of N-vinyl amides (1978) (36)
- Cobalt and Palladium Reagents in Organic Synthesis: The Beginning (2006) (35)
- Neighboring Carbon and Hydrogen. XXIX. ρ-σ Analysis of Acetolysis of Substituted Neophyl Arylsulfonates (1957) (35)
- Monoterpene Syntheses via a Palladium Catalyzed Isoprene Dimerization (1976) (35)
- Phosphite Complexes of Alkyl- and Acyl-Cobalt Carbonyls (1963) (33)
- Alkylation of olefins with “alkylpalladium acetates” lacking β hydrogen substituents. Observation of an intramolecular shift of an acetatopalladium group in neophylpalladium acetate (1972) (32)
- Palladium-catalyzed reactions of vinylic bromides with allylic alcohol and amine derivatives (1982) (31)
- The Addition of Acylcobalt Carbonyls to Acetylenes. -(2,4)-(Alkeno-4-lactonyl)cobalt Tricarbonyl Derivatives and Their Conversion to 2,4-Pentadieno-4-lactones (1964) (31)
- Neighboring Carbon and Hydrogen. XXVII. Ar1-5 Aryl Participation and Tetralin Formation in Solvolysis1,2 (1957) (30)
- Crystalline vinyl ether polymers (1959) (30)
- NEIGHBORING CARBON AND HYDROGEN. XXIV. SOME METHOXYL-SUBSTITUTED 2-ARYL-1-ALKYL BENZENESULFONATES (1956) (29)
- Palladium-catalyzed arylation of unsaturated acetals and ketals (1977) (29)
- Alkyl- and Acylcobalt Carbonyls Containing Olefinic Unsaturation. II. Cyclization of 5-Hexenoylcobalt Tetracarbonyl and Nonterminal Olefin Complexes (1963) (29)
- π-Allyl-π-Cyclopentadienylcobalt Halides (1963) (28)
- cis- and trans-Propenylbenzene and their Azeotropes with n-Decane (1953) (27)
- Substituent effects upon dissociation and migration reactions of five-coordinate platinum(II) carbonyl complexes (1978) (27)
- Palladium-catalyzed synthesis of 2,4-dienoic acid derivatives from vinylic halides (1981) (26)
- PALLADIUM-CATALYZED VINYLATION OF ORGANIC HALIDES (1983) (26)
- Palladium-catalyzed three carbon chain extension reactions with acrolein acetals. A convenient synthesis of conjugated dienals (1981) (25)
- Palladium-catalyzed vinylation of conjugated dienes (1979) (23)
- Palladium-catalyzed reactions of vinyl bromides with disubstituted alkynes: a new synthesis of fulvenes (1991) (22)
- Inexpensive Ruthenium NNS‐Complexes as Efficient Ester Hydrogenation Catalysts with High C=O vs. C=C Selectivities (2018) (22)
- Cyclopentadienylcobalt derivatives of chelating aromatic ligands (1968) (22)
- The mechanism of reactions of organopalladium salts with vinylcyclopropanes (1985) (20)
- Insertion Reactions of Metal Complexes (1965) (20)
- Palladium-catalyzed synthesis of allylic tertiary amines from vinylic bromides, olefins, and secondary amines (1978) (20)
- Substituted tetralin formation from o-palladated Schiff bases and two equivalents of methyl acrylate (1979) (19)
- Palladium-catalyzed cyclizations of bromo dienes (1983) (17)
- Transition Metal-Catalyzed Reactions of Organic Halides with CO, Olefins, and Acetylenes (1977) (16)
- Multiple alkyne insertions in cyclopalladated complexes. The crystal and molecular tructure of [η2-(Et5C5)(FBF3)] (1987) (15)
- Palladium-catalyzed arylation and vinylation of 1,4-dienes (1982) (15)
- Alkoxycarbonylcobalt tetracarbonyl derivatives (1964) (15)
- Nondissociative First-Order Reactions of Some Metal Carbonyls (1966) (14)
- Role of Neighboring Groups in Replacement Reactions. XIX. Polarimetric Acetolysis Rate of trans-2-Acetoxycyclohexyl p-Toluenesulfonate (1952) (14)
- .pi.-Allylic ligand transfer reactions between cobalt and palladium complexes (1968) (13)
- REARRANGEMENT IN THE PALLADIUM-CATALYZED CYCLIZATION OF α-SUBSTITUTED N-ACRYLOYL-O-BROMOANILINES (1979) (12)
- The Reaction of Iodine with Acylcobalt Tricarbonyl Triphenylphosphine Complexes (1964) (12)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. IV. Rates of Dissociation of Mono (trimethylolpropane phosphite) Derivatives and π-Allylcobalt Carbonyl Bis (trimethylolpropane phosphite) Complexes (1965) (12)
- First example of dissymmetrical lanthanide cryptates: synthesis and steady state photophysical properties (2002) (10)
- Neighboring Carbon and Hydrogen. XXVIII. Ar2-6 Participation in Solvolysis of Some ι-Aryl-1-alkyl Bromobenzenesulfonates1,2 (1957) (10)
- The Role of Neighboring Groups in Replacement Reactions. XXII. Competition between o-MeO-5 and Ar1-3 Participation in Solvolysis of o-Methoxyneophyl Tolunesulfonate1,2 (1957) (9)
- 1-Phenylcyclopenten-3-one Derivatives and Their Conversion into Bis-π-(1-methyl-3-phenylcyclopentadienyl)titanium Dichlorides (1965) (9)
- The Addition of Acylcobalt Carbonyls to α,β-Unsaturated Carbonyl Compounds. 1-Acyloxy-π-allylcobalt Tricarbonyl Derivatives (1965) (8)
- Aryl participation in the solvolysis of some gem-dimethyl-substituted 4-aryl-1-alkyl p-bromobenzenesulfonates (1972) (8)
- CATALYTIC APPLICATIONS OF PALLADIUM IN ORGANIC SYNTHESES * (1977) (7)
- The preparation of ketene derivatives from α,β-unsaturated acid chlorides and “arylpalladium chlorides”☆ (1971) (7)
- Crystalline polymers from alkyl propenyl ethers (1959) (7)
- Crystalline poly(1‐methoxybutadiene) (1959) (6)
- The Addition of Acyl- and Alkylcobalt Carbonyls to Conjugated Dienes (2002) (6)
- Addition-elimination reactions of palladium compounds with olefins (1971) (6)
- Preparation of 1-Acyl-1,3-butadiene Derivatives from Acylmethyl--allylcobalt Tricarbonyls (2002) (5)
- Cross coupling reactions in organic synthesis themed issue (2011) (5)
- PALLADIUM‐CATALYZED VINYLIC SUBSTITUTION WITH HIGHLY ACTIVATED ARYL HALIDES (1978) (5)
- Organotransition Metal Chemistry A Mechanistic Approach (2012) (4)
- Ar1-5 and Ar2-6 aryl participation in ionic and free radical processes (1956) (3)
- Triphenylphosphine Derivatives of -Cyclopentenonylcobalt Tricarbonyls and their Dehydrogenation to -Cyclopentadienonecobalt Dicarbonyl Triphenylphosphine Cations (2002) (2)
- 2‐Methyl‐3‐Phenylpropanal (2003) (2)
- A PALLADIUM-CATALYZED CONJUGATED DIENE SYNTHESIS FROM VINYLIC HALIDES AND OLEFINIC COMPOUNDS (1975) (2)
- Chapter X – Dinitrogen, Dioxygen, Carbene, and Sulfur Dioxide Transition Metal Complexes (1974) (2)
- Chapter V – Addition and Elimination Reactions of Olefinic Compounds (1974) (2)
- Reaction of the trityl cation with dimethylketene dimethylacetal (1964) (2)
- Chapter VI – Reactions of Dienes, Trienes, and Tetraenes with Transition Metal Compounds (1974) (2)
- Chapter IV – Homogeneous Hydrogenation Reactions (1974) (1)
- Chapter IX – Reactions of Transition Metal Complexes with Carbon Monoxide and Organic Carbonyl Compounds (1974) (1)
- Chapter VII – Transition Metal Reactions with Acetylenes (1974) (1)
- Isoquinolinium Salt Syntheses from Cyclopalladated Benzaldimines and Alkynes. (1988) (1)
- PALLADIUM-TRIARYLPHOSPHINE COMPLEXES AS CATALYSTS FOR VINYLIC HALIDE REACTIONS (1982) (1)
- Aldehydes from Allylic Alcohols and Phenylpalladium Acetate: 2‐Methyl‐3‐Phenylpropionaldehyde (2003) (1)
- PALLADIUM CATALYZED REACTIONS OF VINYLIC HALIDES WITH AMINES AND OLEFINS (1980) (1)
- Chemoenzymatic synthesis of carbon‐14 labelled antioxidants (1993) (1)
- ACS PRF Funding Leads to Nobel Prize in Chemistry for Two 2010 Laureates (2010) (0)
- Metal Chemistry: The Chemistry of Platinum and Palladium . With Particular Reference to Complexes of the Elements. F. R. Hartley. Halsted (Wiley), New York, 1973. xiv, 544 pp., illus. $45. (1973) (0)
- Palladium-Catalyzed Anellation of Aryl Iodides with Diphenylacetylene. (1987) (0)
- Chapter II – The Formation of Hydrogen and Carbon Bonds to Transition Metals (1974) (0)
- Palladium-Catalyzed Alkenylation and Alkynylation of Polyhaloarenes. (1990) (0)
- TUPAC NEW APPLICATIONS OF PALLADIUM IN ORGANIC SYNTHESES (2006) (0)
- Triarylphosphine-Palladium Complexes CATALYSTS FOR THE FORMATION OF CARBON-CARBON BONDS (1980) (0)
- Chapter I – Historical and Chemical Background (1974) (0)
- Alkene and Alkyne Reactions with Cyclopalladated Organopalladium Complexes (1991) (0)
- A LOW-PRESSURE, PALLADIUM-CATALYZED N,N′-DIARYLUREA SYNTHESIS FROM NITRO COMPOUNDS, AMINES, AND CARBON MONOXIDE (1975) (0)
- BEEE TRANSACTIONS ON (1968) (0)
- Chapter VIII – Mixed Olefin, Diene, and Acetylene Combination Reactions (1974) (0)
- 19. Dichloro(Ethene)(N,N,N′,N′‐Tetraethyl‐1,2‐Ethanediamine)Platinum(ii) and Related Complexes (2007) (0)
- Chapter III – Reactions of Transition Metal σ- and π-Bonded Derivatives (1974) (0)
- Palladium‐Catalyzed Reactions of Vinyl Bromides with Disubstituted Alkynes: A New Synthesis of Fulvenes. (2010) (0)
- Le palladium, magique des chimistes (2010) (0)
- Multiple Alkyne Insertions in Cyclopalladated Complexes. The Crystal and Molecular Structure of Cyclic (η2‐(Et5C5)C(Et)CH2(C9H6N)Pd(FBF3)) (1987) (0)
- TRANSITION METAL-CATALYZED REACTIONS OF ORGANIC HALIDES WITH CARBON MONOXIDE, OLEFINS, AND ACETYLENES (1977) (0)
- A novel transparent electrode process (1970) (0)
- (1Z,3E,5E,7Z)-1,2,3,4,5,6,7,8-octaphenylocta-1,3,5,7-tetraene and 3,4-diphenylisocoumarin (1990) (0)
- REACTIONS OF Π‐ALLYLIC PALLADIUM INTERMEDIATES WITH AMINES (1981) (0)
- Transition Metals in Homogeneous Catalysis : ed. by G.N. Schrauzer, Marcel Dekker, Inc., New York, 1971, ix + 415 pages. (1972) (0)
- CHM 320 – Laboratory Projects Spring (2013) (0)
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