Richard F. Heck
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American chemist
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Chemistry
Why Is Richard F. Heck Influential?
(Suggest an Edit or Addition)According to Wikipedia, Richard Frederick Heck was an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactionss that couple aryl halides with alkenes. The analgesic naproxen is an example of a compound that is prepared industrially using the Heck reaction.
Richard F. Heck's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides (1972) (1698)
- Palladium‐Catalyzed Vinylation of Organic Halides (2005) (878)
- Palladium reagents in organic syntheses (1985) (869)
- Palladium-catalyzed reactions of organic halides with olefins (1979) (719)
- Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives (1968) (595)
- Palladium-catalyzed carboalkoxylation of aryl, benzyl, and vinylic halides (1974) (544)
- Palladium-catalyzed amidation of aryl, heterocyclic, and vinylic halides (1974) (489)
- The Reaction of Cobalt Hydrotetracarbonyl with Olefins (1961) (400)
- Organophosphinepalladium complexes as catalysts for vinylic hydrogen substitution reactions (1974) (311)
- Palladium-catalyzed formylation of aryl, heterocyclic, and vinylic halides (1974) (254)
- Palladium-catalyzed conjugated diene synthesis from vinylic halides and olefinic compounds (1975) (210)
- Mechanism of arylation and carbomethoxylation of olefins with organopalladium compounds (1969) (202)
- Palladium-catalyzed arylation of allylic alcohols with aryl halides (1976) (198)
- The mechanism of carbonylation of halo(bis ligand)organoplatinum(II), -palladium(II), and -nickel(II) complexes (1976) (172)
- Palladium-catalyzed vinylic substitution with highly activated aryl halides (1978) (155)
- Salt Effects and Ion Pairs in Solvolysis and Related Reactions. III.1 Common Ion Rate Depression and Exchange of Anions during Acetolysis2,3 (1956) (145)
- Palladium catalyzed reductions of halo- and nitroaromatic compounds with triethylammonium formate (1977) (144)
- Carbonylation reactions of ortho-palladation products of .alpha.-arylnitrogen derivatives (1975) (124)
- Allylation of aromatic compounds with organopalladium salts (1968) (123)
- Palladium-catalyzed annulation of aryl iodides with diphenylacetylene (1987) (122)
- Alkyne reactions with arylpalladium compounds (1989) (119)
- The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones (1968) (118)
- Dicarboalkoxylation of olefins and acetylenes (1972) (111)
- Palladium-catalyzed synthesis of 2-quinolone derivatives from 2-iodoanilines (1978) (106)
- The palladium-catalyzed arylation of enol esters, ethers, and halides. A new synthesis of 2-aryl aldehydes and ketones (1968) (104)
- Carboxyalkylation Reactions Catalyzed by Cobalt Carbonylate Ion (1963) (98)
- Acylcobalt Carbonyls and their Triphenylphosphine Complexes (1962) (97)
- Aromatic haloethylation with palladium and copper halides (1968) (97)
- The addition of alkyl- and arylpalladium chlorides to conjugated dienes (1968) (90)
- Neighboring methoxyl participation in solvolytic nucleophilic substitution (1958) (86)
- Palladium-catalyzed arylation of ethylene (1978) (85)
- The Reaction of Epoxides with Cobalt Hydrocarbonyl and Cobalt Tetracarbonyl Anion (1963) (85)
- A synthesis of diaryl ketones from arylmercuric salts (1968) (83)
- 4.3 – Vinyl Substitutions with Organopalladium Intermediates (1991) (82)
- Alkyl- and Acyl-cobalt Carbonyls Containing Olefinic Unsaturation. Allylcobalt Tricarbonyl and Related Compounds1 (1961) (81)
- Palladium-catalyzed vinylic substitution reactions with heterocyclic bromides (1978) (80)
- Palladium-catalyzed triethylammonium formate reductions. 4. Reduction of acetylenes to cis-monoenes and hydrogenolysis of tertiary allylic amines (1980) (78)
- Isoquinolinium salt syntheses from cyclopalladated benzaldimines and alkynes (1988) (76)
- New applications of palladium in organic syntheses (1978) (73)
- Palladium-catalyzed alkenylation and alkynylation of polyhaloarenes (1990) (73)
- The 2010 Nobel Prize in Chemistry: Palladium-Catalysed Cross-Coupling (2011) (73)
- Palladium-catalyzed vinylic substitution reactions with carboxylic acid derivatives (1977) (68)
- The Mechanism of the Allyl Halide Carboxylation Reaction Catalyzed by Nickel Carbonyl (1963) (64)
- Electronic and steric effects in the olefin arylation and carboalkoxylation reactions with organopalladium compounds (1971) (64)
- Palladium-catalyzed reductions of .alpha.,.beta.-unsaturated carbonyl compounds, conjugated dienes, and acetylenes with trialkylammonium formates (1978) (62)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. III. Hydrogen, Nitrosyl and Binuclear Derivatives (1963) (56)
- Addition reactions of transition metal compounds (1969) (55)
- Palladium-catalyzed cyclizations of bromodialkenyl ethers and amines (1983) (55)
- π-Allyliron Carbonyl Complexes (1964) (51)
- Alkyliridium and Alkylrhodium Dihalocarbonylbis (trialkyl- or triarylphosphines) (1964) (51)
- 2-(Phenylazo)phenyl complexes of the transition metals (1968) (50)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. I. Acylcobalt Carbonyls (1963) (49)
- Palladium-catalyzed syntheses of conjugated polyenes (1981) (48)
- Palladium-catalyzed syntheses of aryl polyenes (1984) (48)
- Rearrangement in the palladium-catalyzed cyclization of .alpha.-substituted N-acryloyl-o-bromoanilines (1979) (48)
- Cinnolinium salt synthesis from cyclopalladated azobenzene complexes and alkynes (1987) (47)
- Ligandless Heck Coupling between a Halogenated Aniline and Acrylonitrile Catalyzed by Pd/C: Development and Optimization of an Industrial-Scale Heck Process for the Production of a Pharmaceutical Intermediate (2008) (45)
- Low-pressure, palladium-catalyzed N,N'-diarylurea synthesis from nitro compounds, amines, and carbon monoxide (1975) (45)
- Palladium-catalyzed triethylammonium formate reductions. 3. Selective reduction of dinitroaromatic compounds (1980) (43)
- Alkyne reactions with cyclopalladated complexes (1986) (40)
- REACTIONS OF ALKYL- AND ACYL-COBALT CARBONYLS WITH TRIPHENYLPHOSPHINE (1960) (40)
- Palladium-catalyzed arylation of conjugated dienes (1978) (40)
- Selective palladium-catalyzed vinylic substitutions with bromoiodo aromatics (1979) (38)
- Reactions of .pi.-allylic palladium intermediates with amines (1980) (37)
- Palladium-catalyzed vinylic substitution reactions of N-vinyl amides (1978) (36)
- Cobalt and Palladium Reagents in Organic Synthesis: The Beginning (2006) (36)
- Synthesis and Reactions of Alkylcobalt and Acylcobalt Tetracarbonyls (1966) (36)
- Monoterpene Syntheses via a Palladium Catalyzed Isoprene Dimerization (1976) (35)
- Neighboring Carbon and Hydrogen. XXIX. ρ-σ Analysis of Acetolysis of Substituted Neophyl Arylsulfonates (1957) (35)
- Phosphite Complexes of Alkyl- and Acyl-Cobalt Carbonyls (1963) (33)
- Alkylation of olefins with “alkylpalladium acetates” lacking β hydrogen substituents. Observation of an intramolecular shift of an acetatopalladium group in neophylpalladium acetate (1972) (32)
- The Addition of Acylcobalt Carbonyls to Acetylenes. -(2,4)-(Alkeno-4-lactonyl)cobalt Tricarbonyl Derivatives and Their Conversion to 2,4-Pentadieno-4-lactones (1964) (31)
- Palladium-catalyzed reactions of vinylic bromides with allylic alcohol and amine derivatives (1982) (31)
- Neighboring Carbon and Hydrogen. XXVII. Ar1-5 Aryl Participation and Tetralin Formation in Solvolysis1,2 (1957) (30)
- Crystalline vinyl ether polymers (1959) (30)
- Palladium-catalyzed arylation of unsaturated acetals and ketals (1977) (29)
- Alkyl- and Acylcobalt Carbonyls Containing Olefinic Unsaturation. II. Cyclization of 5-Hexenoylcobalt Tetracarbonyl and Nonterminal Olefin Complexes (1963) (29)
- NEIGHBORING CARBON AND HYDROGEN. XXIV. SOME METHOXYL-SUBSTITUTED 2-ARYL-1-ALKYL BENZENESULFONATES (1956) (29)
- π-Allyl-π-Cyclopentadienylcobalt Halides (1963) (28)
- PALLADIUM-CATALYZED VINYLATION OF ORGANIC HALIDES (1983) (27)
- cis- and trans-Propenylbenzene and their Azeotropes with n-Decane (1953) (27)
- Substituent effects upon dissociation and migration reactions of five-coordinate platinum(II) carbonyl complexes (1978) (27)
- Palladium-catalyzed synthesis of 2,4-dienoic acid derivatives from vinylic halides (1981) (26)
- Palladium-catalyzed three carbon chain extension reactions with acrolein acetals. A convenient synthesis of conjugated dienals (1981) (25)
- Palladium-catalyzed vinylation of conjugated dienes (1979) (23)
- Cyclopentadienylcobalt derivatives of chelating aromatic ligands (1968) (23)
- Palladium-catalyzed reactions of vinyl bromides with disubstituted alkynes: a new synthesis of fulvenes (1991) (22)
- Inexpensive Ruthenium NNS‐Complexes as Efficient Ester Hydrogenation Catalysts with High C=O vs. C=C Selectivities (2018) (22)
- Insertion Reactions of Metal Complexes (1965) (20)
- The mechanism of reactions of organopalladium salts with vinylcyclopropanes (1985) (20)
- Palladium-catalyzed synthesis of allylic tertiary amines from vinylic bromides, olefins, and secondary amines (1978) (20)
- Substituted tetralin formation from o-palladated Schiff bases and two equivalents of methyl acrylate (1979) (19)
- Palladium-catalyzed cyclizations of bromo dienes (1983) (18)
- Transition Metal-Catalyzed Reactions of Organic Halides with CO, Olefins, and Acetylenes (1977) (16)
- Multiple alkyne insertions in cyclopalladated complexes. The crystal and molecular tructure of [η2-(Et5C5)(FBF3)] (1987) (15)
- Alkoxycarbonylcobalt tetracarbonyl derivatives (1964) (15)
- Palladium-catalyzed arylation and vinylation of 1,4-dienes (1982) (15)
- Role of Neighboring Groups in Replacement Reactions. XIX. Polarimetric Acetolysis Rate of trans-2-Acetoxycyclohexyl p-Toluenesulfonate (1952) (14)
- Nondissociative First-Order Reactions of Some Metal Carbonyls (1966) (14)
- .pi.-Allylic ligand transfer reactions between cobalt and palladium complexes (1968) (13)
- REARRANGEMENT IN THE PALLADIUM-CATALYZED CYCLIZATION OF α-SUBSTITUTED N-ACRYLOYL-O-BROMOANILINES (1979) (12)
- Steric and Electronic Effects in the Dissociation of Cobalt Carbonyl Derivatives. IV. Rates of Dissociation of Mono (trimethylolpropane phosphite) Derivatives and π-Allylcobalt Carbonyl Bis (trimethylolpropane phosphite) Complexes (1965) (12)
- The Reaction of Iodine with Acylcobalt Tricarbonyl Triphenylphosphine Complexes (1964) (12)
- Neighboring Carbon and Hydrogen. XXVIII. Ar2-6 Participation in Solvolysis of Some ι-Aryl-1-alkyl Bromobenzenesulfonates1,2 (1957) (10)
- First example of dissymmetrical lanthanide cryptates: synthesis and steady state photophysical properties (2002) (10)
- The Role of Neighboring Groups in Replacement Reactions. XXII. Competition between o-MeO-5 and Ar1-3 Participation in Solvolysis of o-Methoxyneophyl Tolunesulfonate1,2 (1957) (9)
- 1-Phenylcyclopenten-3-one Derivatives and Their Conversion into Bis-π-(1-methyl-3-phenylcyclopentadienyl)titanium Dichlorides (1965) (9)
- Aryl participation in the solvolysis of some gem-dimethyl-substituted 4-aryl-1-alkyl p-bromobenzenesulfonates (1972) (8)
- The Addition of Acylcobalt Carbonyls to α,β-Unsaturated Carbonyl Compounds. 1-Acyloxy-π-allylcobalt Tricarbonyl Derivatives (1965) (8)
- Crystalline polymers from alkyl propenyl ethers (1959) (7)
- CATALYTIC APPLICATIONS OF PALLADIUM IN ORGANIC SYNTHESES * (1977) (7)
- The preparation of ketene derivatives from α,β-unsaturated acid chlorides and “arylpalladium chlorides”☆ (1971) (7)
- The Addition of Acyl- and Alkylcobalt Carbonyls to Conjugated Dienes (2002) (6)
- Crystalline poly(1‐methoxybutadiene) (1959) (6)
- Addition-elimination reactions of palladium compounds with olefins (1971) (6)
- PALLADIUM‐CATALYZED VINYLIC SUBSTITUTION WITH HIGHLY ACTIVATED ARYL HALIDES (1978) (5)
- Cross coupling reactions in organic synthesis themed issue (2011) (5)
- Preparation of 1-Acyl-1,3-butadiene Derivatives from Acylmethyl--allylcobalt Tricarbonyls (2002) (5)
- Organotransition Metal Chemistry A Mechanistic Approach (2012) (4)
- Ar1-5 and Ar2-6 aryl participation in ionic and free radical processes (1956) (3)
- A PALLADIUM-CATALYZED CONJUGATED DIENE SYNTHESIS FROM VINYLIC HALIDES AND OLEFINIC COMPOUNDS (1975) (2)
- Chapter X – Dinitrogen, Dioxygen, Carbene, and Sulfur Dioxide Transition Metal Complexes (1974) (2)
- Chapter VI – Reactions of Dienes, Trienes, and Tetraenes with Transition Metal Compounds (1974) (2)
- 2‐Methyl‐3‐Phenylpropanal (2003) (2)
- Reaction of the trityl cation with dimethylketene dimethylacetal (1964) (2)
- Triphenylphosphine Derivatives of -Cyclopentenonylcobalt Tricarbonyls and their Dehydrogenation to -Cyclopentadienonecobalt Dicarbonyl Triphenylphosphine Cations (2002) (2)
- Chapter V – Addition and Elimination Reactions of Olefinic Compounds (1974) (2)
- Aldehydes from Allylic Alcohols and Phenylpalladium Acetate: 2‐Methyl‐3‐Phenylpropionaldehyde (2003) (1)
- Chapter IX – Reactions of Transition Metal Complexes with Carbon Monoxide and Organic Carbonyl Compounds (1974) (1)
- Chapter IV – Homogeneous Hydrogenation Reactions (1974) (1)
- Isoquinolinium Salt Syntheses from Cyclopalladated Benzaldimines and Alkynes. (1988) (1)
- Chemoenzymatic synthesis of carbon‐14 labelled antioxidants (1993) (1)
- PALLADIUM CATALYZED REACTIONS OF VINYLIC HALIDES WITH AMINES AND OLEFINS (1980) (1)
- PALLADIUM-TRIARYLPHOSPHINE COMPLEXES AS CATALYSTS FOR VINYLIC HALIDE REACTIONS (1982) (1)
- Chapter VII – Transition Metal Reactions with Acetylenes (1974) (1)
- Alkene and Alkyne Reactions with Cyclopalladated Organopalladium Complexes (1991) (0)
- REACTIONS OF Π‐ALLYLIC PALLADIUM INTERMEDIATES WITH AMINES (1981) (0)
- A LOW-PRESSURE, PALLADIUM-CATALYZED N,N′-DIARYLUREA SYNTHESIS FROM NITRO COMPOUNDS, AMINES, AND CARBON MONOXIDE (1975) (0)
- (1Z,3E,5E,7Z)-1,2,3,4,5,6,7,8-octaphenylocta-1,3,5,7-tetraene and 3,4-diphenylisocoumarin (1990) (0)
- Chapter I – Historical and Chemical Background (1974) (0)
- Palladium-Catalyzed Alkenylation and Alkynylation of Polyhaloarenes. (1990) (0)
- Chapter VIII – Mixed Olefin, Diene, and Acetylene Combination Reactions (1974) (0)
- 19. Dichloro(Ethene)(N,N,N′,N′‐Tetraethyl‐1,2‐Ethanediamine)Platinum(ii) and Related Complexes (2007) (0)
- Le palladium, magique des chimistes (2010) (0)
- BEEE TRANSACTIONS ON (1968) (0)
- CHM 320 – Laboratory Projects Spring (2013) (0)
- Chapter II – The Formation of Hydrogen and Carbon Bonds to Transition Metals (1974) (0)
- Metal Chemistry: The Chemistry of Platinum and Palladium . With Particular Reference to Complexes of the Elements. F. R. Hartley. Halsted (Wiley), New York, 1973. xiv, 544 pp., illus. $45. (1973) (0)
- TRANSITION METAL-CATALYZED REACTIONS OF ORGANIC HALIDES WITH CARBON MONOXIDE, OLEFINS, AND ACETYLENES (1977) (0)
- Palladium‐Catalyzed Reactions of Vinyl Bromides with Disubstituted Alkynes: A New Synthesis of Fulvenes. (2010) (0)
- Chapter III – Reactions of Transition Metal σ- and π-Bonded Derivatives (1974) (0)
- TUPAC NEW APPLICATIONS OF PALLADIUM IN ORGANIC SYNTHESES (2006) (0)
- A novel transparent electrode process (1970) (0)
- Triarylphosphine-Palladium Complexes CATALYSTS FOR THE FORMATION OF CARBON-CARBON BONDS (1980) (0)
- Palladium-Catalyzed Anellation of Aryl Iodides with Diphenylacetylene. (1987) (0)
- Multiple Alkyne Insertions in Cyclopalladated Complexes. The Crystal and Molecular Structure of Cyclic (η2‐(Et5C5)C(Et)CH2(C9H6N)Pd(FBF3)) (1987) (0)
- ACS PRF Funding Leads to Nobel Prize in Chemistry for Two 2010 Laureates (2010) (0)
- Transition Metals in Homogeneous Catalysis : ed. by G.N. Schrauzer, Marcel Dekker, Inc., New York, 1971, ix + 415 pages. (1972) (0)
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