Richard H. Holm
American chemist
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Chemistry
Richard H. Holm's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Richard H. Holm Influential?
(Suggest an Edit or Addition)According to Wikipedia, Richard Hadley Holm was an American inorganic chemist. Biography A native of Boston, Massachusetts, Holm received his B.S. from the University of Massachusetts Amherst in 1955 and his Ph.D. from the Massachusetts Institute of Technology in 1959 under the direction of F. Albert Cotton. As an independent researcher, he joined the chemistry faculty at Harvard University in 1962. He was later on the faculties of the University of Wisconsin–Madison, Massachusetts Institute of Technology, and Stanford University prior to returning to Harvard in 1980. He was the Higgins Professor of Chemistry at Harvard.
Richard H. Holm's Published Works
Published Works
- Structural and Functional Aspects of Metal Sites in Biology. (1996) (1945)
- Iron-sulfur clusters: nature's modular, multipurpose structures. (1997) (1496)
- Metal-centered oxygen atom transfer reactions (1987) (741)
- Synthetic analogues of the active sites of iron-sulfur proteins. (1976) (408)
- Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases. (2004) (355)
- Modeling coordination sites in metallobiomolecules. (1980) (274)
- The biologically relevant oxygen atom transfer chemistry of molybdenum: from synthetic analogue systems to enzymes (1990) (258)
- Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes (1964) (242)
- The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters. (2004) (236)
- Spectral Investigations of Metal Complexes of β-Diketones. I. Nuclear Magnetic Resonance and Ultraviolet Spectra of Acetylacetonates1 (1958) (219)
- Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra(mercapto-m 3 -sulfido-iron) clusters, (Fe 4 S 4 (SR) 4 ) 2- . (1973) (210)
- A Solid-State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction (1996) (200)
- Centenary Lecture. Metal clusters in biology: quest for a synthetic representation of the catalytic site of nitrogenase (1981) (188)
- Low-potential nickel(III,II) complexes: new systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [NiFe]-hydrogenases (1991) (187)
- Axial ligation modes in iron(III) Porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate. (1976) (170)
- Metal Complexes of Schiff Bases and β‐Ketoamines (2007) (166)
- Theoretical Inorganic Chemistry. (1962) (164)
- Complete Electron-Transfer Series of the [M-N4] Type (1966) (163)
- Preface: biomimetic inorganic chemistry. (2004) (161)
- Structural and electronic effects on the polarographic half-wave potentials of copper (II) chelate complexes. (1975) (159)
- Trinuclear Cuboidal and Heterometallic Cubane-Type Iron–Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology (1992) (158)
- Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters. (2014) (154)
- The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions (1963) (152)
- Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters. (2003) (151)
- Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-. (1974) (151)
- Synthetic analogues of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of oxidized and reduced rubredoxin sites. (1977) (147)
- A Proton Resonance Study of Bis-(acetylacetone)-ethylenediimine and Related Schiff Bases (1961) (147)
- Magnetic circular dichroism studies. 43. Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism (1976) (146)
- Studies on Ni(II) Complexes. I. Spectra of Tricyclic Schiff Base Complexes of Ni(II) and Cu(II) (1960) (144)
- Nuclear Magnetic Resonance Studies of Keto-enol Equilibria. III. α,β-Unsaturated-β-Ketoamines (1962) (142)
- Metal Complexes Derived from cis‐1,2‐dicyano‐1,2‐ethylenedithiolate and Bis(Trifluoromethyl)‐1,2‐dithiete (2007) (140)
- Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. XI. Synthesis and Properties of Complexes Containing the Fe2S2 Core and the Structures of Bis[o-xylyl-α,α′-dithiolato-μ-sulfido-ferrate(III)] and Bis[p-tolylthiolato-μ-sulfido-ferrate(III)] Dianions (1975) (138)
- Proton magnetic resonance investigation of antiferromagnetic oxo-bridged ferric dimers and related high-spin monomeric ferric complexes (1973) (136)
- Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties (1985) (135)
- Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy. (2003) (134)
- Synthetic routes to iron sulfide (Fe2S2, Fe3S4, Fe4S4, and Fe6S9), clusters from the common precursor tetrakis(ethanethiolate)ferrate(2-) ion ([Fe(SC2H5)4]2-): structures and properties of [Fe3S4(SR)4]3- and bis(ethanethiolate)nonathioxohexaferrate(4-) ion ([Fe6S9(SC2H5)2]4-), examples of the newest (1983) (133)
- Synthetic approaches to the active sites of iron-sulfur proteins (1977) (133)
- Syntheses employing pyridyllithium reagents: new routes to 2,6-disubstituted pyridines and 6,6′-disubstituted 2,2′-bipyridyls (1973) (130)
- Synthesis, solution stereochemistry, and electron delocalization properties of bis(.beta.-iminoamino)nickel(II) complexes (1968) (130)
- Structure and properties of a synthetic analogue of bacterial iron--sulfur proteins. (1972) (129)
- Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes (2011) (124)
- Magnetic Investigations of Spin-free Cobaltous Complexes. III. On the Existence of Planar Complexes (1960) (124)
- Nonmolecular Metal Chalcogenide/Halide Solids and Their Molecular Cluster Analogues (1990) (124)
- A Basis Set of Re6Se8 Cluster Building Blocks and Demonstration of Their Linking Capability: Directed Synthesis of an Re12Se16 Dicluster (1997) (122)
- Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site. (2010) (117)
- Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-. (2001) (115)
- Molybdenum-mediated oxygen-atom transfer: an improved analog reaction system of the molybdenum oxotransferases (1993) (113)
- Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems (1989) (111)
- Magnetic Investigations of Spin-free Cobaltous Complexes. VI.1 Complexes Containing Phosphines and the Position of Phosphines in the Spectrochemical Series (1961) (108)
- Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction (2011) (107)
- Stabilization of trivalent nickel in tetragonal NiS4N2 and NiN6 environments : synthesis, structures, redox potentials, and observations related to [NiFe]-hydrogenases (1990) (106)
- Structural and Functional Aspects of Metal Sites in Biology (1997) (106)
- Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4). (1974) (103)
- Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis, structures, and oxygen atom transfer reactions and kinetics. (2001) (100)
- A Thermodynamic Scale for Oxygen Atom Transfer Reactions (1993) (100)
- Definition of reaction sequences resulting in self-assembly of [Fe4S4(SR)4]2- clusters from simple reactants (1981) (99)
- Quantitative extrusions of the iron sulfide(Fe4S4*) cores of the active sites of ferredoxins and the hydrogenase of Clostridium pasteurianum (1977) (99)
- Spectroscopic and structural characterization of ruthenium(II) carbonyl-porphine complexes (1973) (98)
- Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis (1985) (98)
- Synthetic approaches to the molybdenum site in nitrogenase. Preparation and structural properties of the molybdenum-iron-sulfur "double-cubane" cluster complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3- (1979) (97)
- Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: means of formation and spectroscopic and redox properties (1981) (94)
- Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active sites of the DMSO reductase enzyme family. (2000) (94)
- Systematic stereochemistry of metal(II) thiolates: synthesis and structures of [M2(SC2H5)6]2- (M = Mn(II), Ni(II), Zn(II), Cd(II)) (1985) (94)
- Binuclear iron system ferromagnetic in three oxidation states: synthesis, structures, and electronic aspects of molecules with a Fe2(OR)2 bridge unit containing Fe(III,III), Fe(III,II), and Fe(II,II) (1989) (90)
- Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes (1998) (89)
- Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8). (2008) (88)
- Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors. (1988) (88)
- Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes (1998) (88)
- Chemical and electrochemical reactivity of nickel(II,I) thiolate complexes: examples of ligand-based oxidation and metal-centered oxidative addition (1989) (87)
- Synthetic and Electron Spin Resonance Studies of Six-Coordinate Complexes Related by Electron-Transfer Reactions (1964) (87)
- Inorganic derivatives of iron sulfide thiolate dimers and tetramers: synthesis and properties of the halide series [Fe2S2X4]2- and [Fe4S4X4]2- (X = chlorine, bromine, iodine) (1978) (87)
- The molybdenum-iron-sulfur cluster complex [Mo2Fe6S9(SC2H5)8]3-. A synthetic approach to the molybdenum site in nitrogenase (1978) (86)
- Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re(6)S(8)](2+) and [Re(6)Se(8)](2+). (1999) (86)
- Structural Conversions of Synthetic and Protein-Bound Iron-Sulfur Clusters. (2016) (85)
- Cadmium-113 Fourier Transform Nuclear Magnetic Resonance and Raman Spectroscopic Studies of Cadmium(II)-Sulfur Complexes, Including [Cd10(SCH2CH2OH)16]4+ (1976) (84)
- Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates. (2011) (83)
- Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution (1988) (82)
- E.s.r. Studies of Four-Coördinate Complexes of Nickel, Palladium and Platinum Related by Electron Transfer Reactions (1963) (82)
- Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re(6)(&mgr;(3)-Se)(8)](2+). (1999) (82)
- Molecular Assemblies Containing Linear and Bent [FeIII-CN-CuII] Bridge Units: Synthesis, Structures, and Relevance to Cyanide-Inhibited Heme-Copper Oxidases (1994) (81)
- The Stereochemistry of Bis‐Chelate Metal(II) Complexes (2007) (80)
- Synthetic analogues of the active sites of iron-sulfur proteins. 15. Comparative polarographic potentials of the [Fe4S4(SR)4]2 -- ,3 -- and clostridium pasteurianum ferredoxin redox couples. (1977) (80)
- Subsite-specific structures and reactions in native and synthetic [4Fe-4S) cubane-type clusters (2007) (80)
- Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase (1984) (80)
- Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters [tetra-.mu.-sulfido-tetrakis(alkyl or aryl thiolato)tetraferrate](2-) (1974) (80)
- Synthesis, Structures and Oxo Transfer Reactivity of bis(Dithiolene) Tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes (1998) (79)
- Thermodynamic fitness of molybdenum(IV,VI) complexes for oxygen-atom transfer reactions, including those with enzymic substrates (1986) (78)
- Toward functional models of metalloenzyme active sites: analog reaction systems of the molybdenum oxo transferases (1986) (78)
- The Synthesis and Proton Resonance Study of the Solution Equilibria of Bis(β-ketoamino) nickel(II) Complexes (1965) (77)
- The Cuboidal Fe3S4 Cluster: Synthesis, Stability, and Geometric and Electronic Structures in a Non-Protein Environment (1996) (76)
- The Synthesis, Structures, and Solution Equilibria of Bis(pyrrole-2-aldimino)metal(II) Complexes (1966) (76)
- Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubane. (2003) (75)
- Synthesis and structural systematics of ethane-1,2-dithiolato complexes (1986) (75)
- Reduction of nitrate to nitrite by molybdenum-mediated atom transfer: a nitrate reductase analog reaction system (1989) (75)
- Stabilization of nickel(III) in a classical N2S2 coordination environment containing anionic sulfur (1987) (74)
- Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in nu(CN) Values, and Relation to the Heme-a(3)/Cu(B) Site in Cyanide-Inhibited Heme-Copper Oxidases. (1998) (74)
- Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites. (2009) (74)
- Dimensional Reduction of Re6Se8Cl2: Sheets, Chains, and Discrete Clusters Composed of Chloride‐Terminated [Re6Q8]2+ (Q S, Se) Cores (1995) (74)
- Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2- (1982) (72)
- Three-dimensional macrocyclic encapsulation reactions. III. Geometrical and electronic features of tris(diimine) complexes of trigonal-prismatic, antiprismatic, and intermediate stereochemistry (1972) (71)
- Effects of chelate ring substituents on the polarographic redox potentials of tris(.beta.-diketonato)ruthenium(II,III) complexes (1972) (71)
- Subsite-differentiated analogs of biological [4Fe-4S]2+ clusters: synthesis, solution and solid-state structures, and subsite-specific reactions (1988) (71)
- Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum. (2001) (70)
- Aspects of the oxygen atom transfer chemistry of tungsten (1989) (70)
- Characterization of dimeric dithiolene complexes (1968) (70)
- Synthetic analogues of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe 4S4(SC6H5)4] (1978) (69)
- Potential Electron Transfer Complexes of the [M-O4] Type: Synthesis and Properties of Complexes Derived from Pyrocatechol and Tetrachloropyrocatechol (1966) (68)
- Structural and Reaction Chemistry of Nickel Complexes in Relation to Carbon Monoxide Dehydrogenase: A Reaction System Simulating Acetyl-coenzyme a Synthase Activity (1991) (68)
- Polycubane Clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = But, Cy, Pri) and [Fe4S4]0 Core Aggregation upon Loss of Phosphine (1996) (68)
- Synthesis and Structural Characterization of Unsupported [FeIII-CN-CuII] Bridges Related to That in Cyanide-Inactivated Cytochrome c Oxidase (1994) (67)
- Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands. (2002) (66)
- Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes (1995) (66)
- Synthesis and properties of tetraaza[14]tetraene and tetraaza[14]hexane macrocyclic complexes (1972) (66)
- Further Examples of Complexes Related by Electron-Transfer Reactions: Complexes Derived from Bis (trifluoromethyl)-1,2-dithietene (1964) (65)
- Rearrangement of symmetrical dicubane clusters into topological analogues of the P cluster of nitrogenase: nature's choice? (2002) (65)
- Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies (1998) (64)
- Synthetic approach to the mononuclear active sites of molybdoenzymes: catalytic oxygen atom transfer reactions by oxomolybdenum(IV,VI) complexes with saturation kinetics and without molybdenum(V) dimer formation (1984) (64)
- Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster (1997) (64)
- Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = iron, cobalt, nickel) (1992) (64)
- Nickel-Mediated Formation of Thio Esters from Bound Methyl, Thiols, and Carbon Monoxide: A Possible Reaction Pathway of Acetyl-Coenzyme A Synthase Activity in Nickel-Containing Carbon Monoxide Dehydrogenases (1995) (62)
- Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation (1984) (61)
- Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants (1986) (61)
- Studies on Nickel(II) Complexes. II. On the Solution Magnetism of Bis-(N-methylsalicylaldimine)-nickel(II) and Related Complexes (1961) (61)
- Synthesis and characterization of an asymmetric bridged assembly containing the unsupported [FeIII-O-CuII] bridge: an analog of the binuclear site in oxidized cytochrome c oxidase (1993) (60)
- Structure proofs of ligated and polymeric dioxomolybdenum(VI)-tridentate complexes: MoO2(C5H3N-2,6-(CH2S)2)(C4H8SO) and [MoO2(C5H3N-2,6-(CH2O)2)]n (1983) (60)
- Inter- and intramolecular ligand exchange reactions of ruthenium(II) carbonyl porphine complexes with nitrogen bases (1972) (60)
- Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores (1980) (59)
- Speculative synthetic chemistry and the nitrogenase problem (2003) (59)
- Synthetic analogs of the active sites of iron-sulfur proteins. IX. Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes obtained by ligand substitution reactions. (1974) (59)
- Magnetic Investigations of Spin-Free Cobaltous Complexes. I. Tetrahalo Cobalt(II) Ions (1959) (58)
- Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II)) (1984) (58)
- Relative stereochemical and electronic effects of oxygen and sulfur donor atoms in planar and tetrahedral complexes of nickel(II) (1969) (58)
- Chemical Bonding in Solids (1974) (57)
- Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the oxidized active site of the sulfite oxidase enzyme family. (2001) (57)
- Studies on Nickel(II) Complexes. V.1 A Nuclear Resonance Study of Conformational Equilibria (1964) (57)
- Diastereoisomeric four-coordinate complexes. III. Paramagnetic nickel(II) complexes with three asymmetric centers (1967) (56)
- Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II rhombs. (2004) (56)
- Synthesis and stereochemistry of mono-, bi-, and tetranuclear manganese thiolates (1983) (56)
- Direct oxygen atom transfer in the mechanism of action of Rhodobacter sphaeroides dimethyl sulfoxide reductase (1995) (56)
- Subsite-differentiated analogs of native iron sulfide [4Fe-4S]2+ clusters: preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions (1990) (56)
- Fluoride-bridged dimers : binuclear copper(II) complexes and iron(III)-copper(II) assemblies (1993) (56)
- Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of [W6I14]2- (1995) (56)
- Three-dimensional macrocyclic encapsulation reactions. II. Synthesis and properties of nonoctahedral clathro chelates derived from tris(2-aldoximo-6-pyridyl)phosphine and boron trifluoride or tetrafluoroborate (1971) (55)
- Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III) (1970) (55)
- Studies of the Planar-Tetrahedral Configurational Equilibrium in Solutions of Bis(β-ketoamino)cobalt(II) Complexes (1966) (54)
- Oxygen-Bridged Iron-Copper Assemblies Pertinent to Heme-Copper Oxidases: Synthesis and Structure of an [FeIII-(OH)-CuII] Bridge and Exafs Multiple-Scattering Effects of Linear Oxo and Nonlinear Hydroxo Bridges (1995) (54)
- Letter: Ferric porphyrin thiolates. Possible relationship to cytochrome P-450 enzymes and the structure of (p-nitrobenzenethiolato)iron(III) protoporphyrin IX dimethyl ester. (1975) (53)
- Improved syntheses of tetrachlorodi-.mu.-sulfidodiferrate(2-) ([Fe2S2Cl4]2-) and hexachloro-.mu.-oxodiferrate(2-) ([Fe2OCl6]2-) and oxo/sulfido ligand substitution by use of silylsulfide reagents (1983) (52)
- New Systems of Complexes Related by Electron-Transfer Reactions (1965) (52)
- Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: relevance to molybdoenzymes (1988) (52)
- Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein. (2005) (52)
- Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes (1982) (52)
- Synthetic analogs of the active sites of iron-sulfur proteins. Structure and properties of bis(o-xylyldithiolato-m2-sulfidoferrate (3)), an analog of the 2Fe-2S proteins. (1973) (52)
- Inorganic derivatives of iron-sulfide-thiolate dimers and tetramers. Structures of tetrachloro-.mu.-disulfido-diferrate(III) and tetrakis(chloro-.mu.3-sulfido-iron) dianions (1977) (51)
- Structural and Functional Bis(dithiolene)-Molybdenum/Tungsten Active Site Analogues of the Dimethylsulfoxide Reductase Enzyme Family (2000) (51)
- Tetrathiovanadate(V) and tetrathiorhenate(VII): structures and reactions, including characterization of the VFe2S4 core unit (1985) (51)
- Electron-transfer complexes of the [M-N2S2] type. The existence of cation-stabilized free-radical complexes (1967) (50)
- Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species (1992) (49)
- Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase. (2001) (49)
- Studies on Nickel(II)Complexes. IV. Bis-(N-sec-alkylsalicylaldimine) Complexes: Conformational Equilibria in Solution (1963) (48)
- Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9] (1982) (48)
- Synthesis and Reactivity Aspects of the Bis(dithiolene) Chalcogenide Series [WIVQ(S2C2R2)2]2- (Q = O, S, Se) (1999) (48)
- Preparation, properties, and racemization kinetics of copper(II)-Schiff base-amino acid complexes related to vitamin B6 catalysis (1970) (48)
- Chemical and electrochemical interrelationships of the 1-Fe, 2-Fe, and 4-Fe analogs of the active sites of iron-sulfur proteins (1977) (48)
- Identification of the Geometrical Isomers of Some Tris-Chelate Cobalt(III) Complexes by Nuclear Resonance (1964) (47)
- Dihydrogen Evolution by Protonation Reactions of Nickel(I). (1996) (47)
- Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4]2+ core (1987) (46)
- Structural characterization of the iron-bridged "double-cubane" cluster complexes [Mo2Fe7S8(SC2H5)12]3- and [M2Fe7S8(SCH2C6H5)12]4- (M = molybdenum, tungsten) containing MFe3S4 cores (1980) (46)
- Metal Ion Incorporation Reactions of the Cluster [Fe3S4(LS3)]3-, Containing the Cuboidal [Fe3S4]0 Core (1997) (46)
- Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features. (2012) (46)
- On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase. (2005) (45)
- Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type clusters topologically related to the nitrogenase P-cluster. (2004) (45)
- A Study of Transition Metal Compounds Containing the Tricyanomethanide Ion (1964) (45)
- A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically demanding thiolate ligand. (2009) (45)
- Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study. (2008) (45)
- Antiferromagnetic exchange interactions in [Fe4S4(SR)4]2-,3- clusters (1982) (45)
- Subsite-specific functionalization of the [4Fe-4S]2+ analog of iron-sulfur protein clusters (1987) (45)
- Diastereoisomeric four-coordinate complexes. V. Pseudo-tetrahedral complexes of controlled absolute configuration. Configurational interconversion of nickel(II) complexes withour racemization (1968) (44)
- Kinetics of oxygen atom transfer in an analogue reaction system of the molybdenum oxotransferases (1993) (44)
- Three-dimensional macrocyclic encapsulation reactions. I. Synthesis of six-coordinate complexes with nonoctahedral stereochemistry (1970) (44)
- Applications of isotropic shifts to the investigation of structures and structural equilibriums of metal complexes (1969) (44)
- Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes. (2002) (44)
- Synthesis and Electron Delocalization of [Fe4S4]-S-Fe(III) Bridged Assemblies Related to the Exchange-Coupled Catalytic Site of Sulfite Reductases (1994) (44)
- Single cubane-type MFe3S4 clusters (M = Mo, W): synthesis and properties of oxidized and reduced forms and the structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2C6H2O2)] (1983) (44)
- Chemical approaches to bridged biological metal assemblies (1995) (43)
- Molybdenum-mediated imido group transfer: stoichiometric and catalytic reactions and structures (1990) (43)
- Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit. (1975) (43)
- Ligand substitution properties of the MFe3S4 double-cubane cluster complexes [Mo2Fe6S8(SR)9]3- and [M2Fe7S8(SR)12]3- (M = molybdenum, tungsten) (1982) (43)
- Intrinsic binding properties of a differentiated iron subsite in analogs of native [Fe4S4]2+ clusters (1991) (43)
- Magnetic Investigations of Spin‐Free Cobaltous Complexes. II. Tetrahedral Complexes (1960) (43)
- Heterometallic clusters: synthesis and reactions of vanadium-iron-sulfur single- and double-cubane clusters and the structure of [V2Fe6S8Cl4(C2H4S2)2]4- (1987) (43)
- Biologically related iron-sulfur clusters as reaction centers. Reduction of acetylene to ethylene in systems based on [Fe4S4(SR)4]3-. (1979) (42)
- Comparative stereochemical populations and thermodynamics of structural interconversion of planar and tetrahedral cobalt(II) and nickel(II) complexes (1968) (42)
- Stereochemistry of [Cd4(SC6H5)10]2−, a cage complex related to the cadmium―cysteinate aggregates in metallothioneins (1983) (42)
- Synthesis and stereochemical rearrangements of complexes containing the Fe-S6 core (1971) (42)
- The clusters [Co8S6(SPh)8]4-,5-: preparations, properties, and structural relationship of near-cubic Co8(.mu.4-S)6 cores to the clusters in synthetic pentlandite (1985) (42)
- Synthetic approaches to 14-, 15-, and 16-membered tetraaza macrocycles and their metal complexes (1973) (42)
- Preparation and stereochemistry of bis-chelate chromium(II), manganese(II), iron(II), and cobalt(II) complexes of the types M-O4 and M-O2S2 (1969) (42)
- Mononuclear active sites of molybdoenzymes: chemical approaches to structure and reactivity (1984) (42)
- Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase. (2007) (41)
- Synthesis and ground state electronic properties of tetraaza macrocyclic iron(II, III) complexes containing [14]-, [15]-, and [16]-membered rings (1975) (41)
- Electron distribution in the nonclassical bis(dithiolene) electron transfer series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results. (2001) (41)
- Resonance Raman spectra of spinach ferredoxin and adrenodoxin and of analog complexes (1983) (41)
- Reaction Sequence Related to That of Carbon Monoxide Dehydrogenase (acetyl Coenzyme a Synthase): Thioester Formation Mediated at Structurally Defined Nickel Centers (1990) (41)
- The Unperturbed Oxo-Sulfido Functional Group cis-Mo(VI)OS, Related to that in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization and Reactivity Aspects (1999) (41)
- Letter: Theoretical model for the 4-Fe active sites in oxidized ferredoxin and reduced "high-potential" proteins. Electronic structure of the analogue [Fe4S4(SCH3)4]2-. (1975) (41)
- Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = sulfur, selenium) (1992) (40)
- Thermodynamics and kinetics of the planar-tetrahedral interconversion of dihalobis(diarylmethylphosphine)nickel(II) complexes (1970) (40)
- Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin proteins. (1975) (40)
- Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16. (2003) (40)
- Proton magnetic resonance properties of the tetranuclear clusters [Fe4S4(SR)4]3-, analogs of the 4-Fe sites of reduced ferredoxins (1978) (40)
- Selenium substitution in [Fe4S4(SR)4]2-: synthesis and comparative properties of [Fe4X4(YC6H5)4]2- (X, Y = sulfur, selenium) and the structure of [(CH3)4N]2[Fe4Se4(SC6H5)4] (1978) (40)
- Synthesis, structure, and electronic features of (.mu.-sulfido)bis[(N,N'-ethylenebis(salicylaldiminato))iron(III)], [Fe(salen)]2S, containing the only authenticated example of the iron(III)-sulfur-iron(III) single bridge (1984) (39)
- Vanadium-mediated oxygen atom transfer reactions (1990) (39)
- Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes (1972) (39)
- Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophiles (1978) (39)
- Synthesis, structure, and properties of [Co8S6(SC6H5)8]4-, containing an octanuclear Co8S6 rhombic dodecahedron related to that of cobalt pentlandite (1982) (39)
- Identification of iron-sulfur centers in the iron-molybdenum proteins of nitrogenase. (1979) (39)
- Alternative spin states in synthetic analogs of biological iron-sulfur [4Fe-4S]+ clusters: further cases of variable ground states and the structure of (Et4N)3[Fe4S4(S-o-C6H4S-tert-Bu)4], containing a reduced cluster with a compressed tetragonal distortion (1989) (39)
- Insertion of vanadium-iron-sulfur, [VFe3S4]2+, and molybdenum-iron-sulfur, [MoFe3S4]3+, cores into a semirigid trithiolate cavitand ligand: regiospecific reactions at a vanadium site similar to that in nitrogenase (1989) (38)
- Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites of tungstoenzymes. (2000) (38)
- Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox. (2004) (38)
- Structural distortions of the [Fe4S4]2+ core of [Fe4S4(S-t-C4H9)4]2− in different crystalline environments and detection and instability of oxidized ([Fe4S4]3+) clusters (1983) (38)
- Synthetic analogs of the active sites of iron-sulfur proteins; X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2 minus;. (1975) (38)
- Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase. (2003) (38)
- Hexanuclear iron―sulfur basket clusters: topological isomers of prismanes. Synthesis, structure, and reactions (1988) (38)
- Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues. (2010) (38)
- Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site. (2009) (37)
- Octaethylisobacteriochlorin, a model of the sirohydrochlorin ring system of siroheme enzymes: preparation and spectroscopic and electrochemical properties of the free base and its zinc(II) complex (1980) (37)
- The stereochemistry of decakis(benzenethiolato)tetracadmate(2-) ion, a cage complex related to the cadmium-cysteinate aggregates in metallothioneins (1983) (37)
- Comparative electronic properties of vanadium-iron-sulfur and molybdenum-iron-sulfur clusters containing isoelectronic cubane-type [VFe3S4]2+ and [MoFe3S4]3+ cores (1987) (37)
- Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases. (2007) (37)
- Molybdenum and Tungsten Structural Analogues of the Active Sites of the Mo(IV) + [O] -> Mo(VI)O Oxygen Atom Transfer Couple of DMSO Reductases (1998) (36)
- A NUCLEAR MAGNETIC RESONANCE STUDY OF KETO-ENOL EQUILIBRIA IN SCHIFF BASES. II (1961) (36)
- The cavitand concept in the synthesis of subsite-differentiated analogs of biological [4Fe-4S/Se]2+ clusters: cluster capture reactions, ligand conformational analysis, and the structure of a trigonal [4Fe-4Se]2+ analog (1990) (36)
- Comparative stereochemical effects of sulfur and oxygen donor atoms in four- and six-coordinate metal complexes (1968) (36)
- On the molecular solid-state boundary. A cyclic iron-sulfur cluster of nuclearity eighteen: synthesis, structure, and properties (1990) (35)
- Alternative spin states in synthetic analogs of biological clusters: spin-quartet ground states and structures of tetrakis(benzenethiolato)tetrasulfidotetraferrate(3-) and tetrakis(benzenethiolato)tetraselenidotetraferrate(3-) as their tetramethylammonium salts (1988) (35)
- Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications. (1986) (35)
- Studies on Nickel(II) Complexes. III. Bis-(N-arylsalicylaldimine) Complexes (1962) (35)
- Synthetic nickel-iron NiFe3Q4 cubane-type clusters (S = 3/2) by reductive rearrangement of linear [Fe3Q4(SEt)4]3- (Q = sulfur, selenium) (1990) (35)
- Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes. (2005) (35)
- Mononuclear and Binuclear Metal(II) Complexes of Ethane-1,2-Dithiolate. Preparation, Equilibrium and Redox Properties of [Ni(S2C2H4)2]2- and [Ni2(S2C2H4)3]2-, and the Structures of Ni2(S2C2H4)3]2- and [Pd(S2C2H4)2]2- (1986) (35)
- Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III) (1971) (35)
- The high potential iron-sulfur cluster of aconitase is a binuclear iron-sulfur cluster. (1979) (34)
- Evidence for the localized iron(III)/iron(II) oxidation state configuration as an intrinsic property of [Fe2S2(SR)4]3- clusters (1981) (34)
- On the structure of the nickel/iron/sulfur center of the carbon monoxide dehydrogenase from Rhodospirillum rubrum: an x-ray absorption spectroscopy study. (1992) (34)
- Doubly bridged double cubanes containing MFe3S4 clusters (M = Mo, W). Synthesis, structure, and conversion to spin-quartet single clusters in solution (1982) (34)
- Stereochemistry and rearrangement rates of some tris(β-diketonato)- and tris(β-thioketonato)metal(III) complexes (1971) (34)
- Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+). (2002) (33)
- Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters (1985) (33)
- Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites. (2001) (33)
- Reactivity properties of single molybdenum iron sulfide (MoFe3S4) cubane-type clusters: synthesis, structure, and ligand substitution reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2- (1983) (33)
- A binuclear manganese system with three isolated oxidation states: synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII (1991) (33)
- Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: electron-transfer coupling across sulfur-containing bridges of variable length (1989) (33)
- Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophile. (2006) (32)
- [.beta.-Na2Fe18S30]8- and [Na9Fe20Se38]9-: high-nuclearity clusters by mono- or bicyclization of unidimensional polymeric fragments and the existence of isomeric monocyclic clusters (1992) (32)
- Diastereoisomeric four-coordinate complexes. IV. Zinc(II) complexes with three asymmetric centers and ligand racemization in bis[N-(alkoxycarbonylalkyl])salicylaldimino]metal(II) complexes (1968) (32)
- Structural diversity of homoleptic ethane-1,2-dithiolato complexes of the first transition series (1985) (31)
- Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe(6)S(8)(PEt(3))(6)](n)()(+) (n = 0-4) Cluster Electron Transfer Series. (1996) (31)
- Crystal and molecular structure of bis[(tetramethyl[14]hexaenatotetraaza)nickel] bis(trifluoromethanesulfonate): conversion of a metal-stabilized .pi.-radical to a diamagnetic dimer with a long metal-metal bond and eclipsed macrocyclic ligands upon crystallization (1976) (31)
- A fluorine-19 NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase (1979) (31)
- Chemistry of the Metal Carbonyls. XX. Nature of the Reaction Product from Cyclopentadienylvanadium Tetracarbonyl and Dimethyl Disulfide (1963) (31)
- Structural Interconversions of Octahedral, Planar, and Tetrahedral Nickel(II) Complexes (1965) (31)
- Electronic properties of single- and double-MoFe3S4 cubane-type clusters (1983) (31)
- A new class of (N,N'-bis(salicylideneamino)ethanato)iron(II) complexes: five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions (1988) (31)
- Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants. (2012) (31)
- Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment. (2004) (31)
- Analogue reaction systems of selenate reductase. (2006) (31)
- Comprehensive iron-selenium-thiolate cluster chemistry (1991) (31)
- Isonitrile binding to a site-differentiated synthetic analog of biological [4Fe-4S] clusters: equilibria, magnetic interactions, and the spin-isolated [3Fe-4S] cluster fragment, and the structure of a low-spin iron(II) subsite (1990) (31)
- Existence of the Planar [UNK] Tetrahedral Equilibrium in Solutions of Cobalt(II) Complexes (1965) (31)
- Isotropic Nuclear Magnetic Resonance Shifts in Tetrahedral Bispyridine and Bispicoline Complexes of Nickel(II) (1966) (30)
- Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins (1980) (30)
- Derivatives of tetrathiovanadate(V): synthesis of the linear heterometallic Fe(.mu.2-S)2V(.mu.2-S)2Fe core and the structures of tetrathiovanadate(3-) ion ([VS4]3-) and tetrachlorotetrathiodiferratevanadate(3-) ion ([VFe2S4Cl4]3-) (1983) (30)
- Heterometal cuboidal clusters MFe[sub 4]S[sub 6](PEt[sub 3])[sub 4]Cl (M = V, Mo): synthesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molybdenum cofactor of nitrogenase (1993) (30)
- Demonstration of the generality of the [Fe4S4(SR)4]2- (compressed D2d)/[Fe4S4(SR)4]3- (elongated D2d) structural change in electron-transfer reactions of ferredoxin 4-Fe site analogs. A model for unconstrained structural changes in ferredoxin proteins (1979) (30)
- Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase. (2004) (30)
- A biomimetic approach to oxidized sites in the xanthine oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes. (2008) (30)
- Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. (2010) (30)
- Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M = Mo, W). (2003) (30)
- The influence of net charge on the redox potentials of Fe4S4 cubane-type clusters in aprotic solvents (2000) (30)
- Equilibria and solute structures in the aqueous systems pyridoxal-alanine-zinc(II) and -aluminum(III) as investigated by proton resonance (1969) (30)
- Studies on Nickel(II) Complexes. VI. The Conformational Equilibria of Bis(o-hydroxynaphthaldimine) Complexes (1964) (30)
- Synthesis, structure, and properties of the cluster complex [MoFe4S4(SC2H5)3(C6H4O2)3]3-, containing a single cubane-type molybdenum-iron-sulfur (MoFe3S4) core (1981) (30)
- Trichlorotetrakis(triethylphosphine)hexathioheptairon (Fe7S6(PEt3)4Cl3): a topological link between the prismatic and cube-octahedral structures of iron-sulfur clusters (1986) (30)
- Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se) (1997) (30)
- Equivalence of metal centers in the iron-sulfur protein active site analogs (Fe4S4(SR)4)2-. (1974) (29)
- [FeIIIN4SR] coordination unit. Synthesis and ground state electronic properties of macrocyclic ferric thilates (1975) (29)
- Bridged multiclusters derived from the face-capped octahedral [Re6 III(μ3-Se)8]2+ cluster core (2001) (29)
- Synthesis of a [Fe4S4]−S−Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase (1996) (29)
- Intramolecular rearrangement reactions of tris-chelate complexes. IV. Rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonate)metal(III,IV) complexes (1973) (29)
- Synthetic and Paramagnetic Resonance Studies of Trigonal Vanadium Complexes (1965) (29)
- MOLYBDENUM-IRON SULFIDE-BRIDGED DOUBLE CUBANES (1997) (29)
- Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a topological analogue of the P-cluster of nitrogenase. (2001) (28)
- A broad-substrate analog reaction system of the molybdenum oxotransferases (1992) (28)
- Effects of secondary bonding interactions on the iron-sulfur cubane-type [Fe4S4]2+ core of ferredoxin site analogs: [Fe4S4(SC6H4-o-OH)4]2-, a distorted cubane-type cluster with one five-coordinate iron atom (1983) (28)
- Nuclear resonance studies of vanadium(III) complexes. I. Stereochemistry and electron delocalization of tris .beta.-diketonates (1967) (28)
- Improved syntheses of the dimeric complexes [Fe2X2(SC6H4Y)4]2- and [Fe2X2((SCH2)2C6H4)2]2- (X = sulfur, selenium), analogs of the 2-Fe sites of oxidized ferredoxin proteins (1980) (28)
- Aqueous solution equilibria of pyridoxamine, pyridoxal, 3-hydroxypyridine-4-aldehyde, and 3-hydroxypyridine-2-aldehyde as studied by proton resonance (1968) (27)
- Inversion and ligand-exchange kinetics of tetrahedral bis-chelate complexes of zinc(II) and cadmium(II) (1971) (27)
- A hexanuclear iron-sulfide-thiolate cluster: assembly and properties of [Fe6S9(S-tert-C4H9)2]4- containing three types of bridging sulfur atoms (1981) (27)
- Cyanide poisoning: an analog to the binuclear site of oxidized cyanide-inhibited cytochrome c oxidase (1994) (27)
- Studies on nickel(II) complexes. VII. a nuclear resonance investigation of mixed ligand complexes (1964) (27)
- Multiple-edge XAS studies of cyanide-bridged iron-copper molecular assemblies relevant to cyanide-inhibited heme-copper oxidases using four-body multiple-scattering analysis (1997) (27)
- Dithiotropolonates. II. Synthesis and properties of dithiotropolone and its metal(II) complexes (1970) (27)
- A new structural type in iron-sulfide-thiolate chemistry: preparation, properties, and structure of the hexanuclear cluster [Fe6S9(S-tert-C4H9)2]4- (1982) (27)
- Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. (2004) (26)
- The homogeneous hydrogen-evolving systems [Mo2Fe6S8(SPh)9]4-,5-/C6H5SH: reaction characteristics, kinetics, and possible mechanisms (1983) (26)
- Electronic properties of the linear antiferromagnetically coupled clusters (Fe/sub 3/S/sub 4/(SR)/sub 4/)/sup 3 -/, structural isomers of the (Fe/sub 3/S/sub 4/)/sup +/ unit in iron-sulfur proteins (1984) (26)
- Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2-. (1974) (26)
- Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten) (1979) (26)
- Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase. (2005) (26)
- Demonstration of the existence of single cubane-type molybdenum iron sulfide (MoFe3S4) clusters with S = 3/2 ground states: preparation, structure, and properties (1982) (26)
- Structural identification of iron-sulfur clusters of the respiratory chain-linked NADH dehydrogenase. (1981) (25)
- Soluble sulfides of niobium(V) and tantalum(V): synthesis, structures, and properties of the fivefold symmetric cages [M6S17]4− (1985) (25)
- Identification of the iron-sulfur center in trimethylamine dehydrogenase. (1977) (25)
- Solution stereochemistry of four-coordinate bis(chelate)metal(II) complexes. Further experimental results and a summary of stereochemical trends (1970) (25)
- Tetranuclear Cuboidal and Hexanuclear Prismatic Iron–Sulfur–Nitrosyl Clusters (1993) (25)
- Structural Analysis of Cubane-Type Iron Clusters. (2013) (25)
- Phosphine cleavage of iron(III)-bridged double cubanes: a new route to MoFe3S4 single cubanes (1987) (25)
- A binuclear mixed-valence ferromagnetic iron system with an S = 9/2 ground state and valence trapped and detrapped states (1989) (25)
- X-RAY POWDER DATA AND STRUCTURES OF SOME BIS-(ACETYLACETONO)-METAL(II) COMPOUNDS AND THEIR DIHYDRATES (1961) (25)
- Heterometal Clusters Containing the Cuboidal Fe4S3 Fragment: Synthesis, Electron Distribution, and Reactions (1994) (25)
- Crystal structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a reduced ferredoxin site analog with a nontetragonal Fe4S4 core structure in the solid state (1979) (25)
- Precursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer series. (2006) (25)
- Synthesis and stereochemistry of bis(N,N-disubstituted-dithiocarbamato)maleonitriledithioleneiron complexes (1972) (24)
- Synthesis and Metal Ion Incorporation Reactions of the Cuboidal Fe3S4 Cluster (1995) (24)
- Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron–sulfur clusters relevant to the FeMo cofactor (2018) (24)
- Stability range of heterometal cubane-type clusters MFe3S4: assembly of double-cubane clusters with the rhenium-iron-sulfur [[ReFe3S4]] core (1989) (24)
- Trinuclear metal(II)-sulfide-thiolate complexes: synthesis, structures, and properties of [M3S(1,2-(SCH2)2C6H4)3]2- (M = Fe(II), Co(II)) (1983) (24)
- Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re(6)Se(8)](2+) Core. (2002) (24)
- Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states. (2010) (24)
- Spectroscopic and electronic structure studies of symmetrized models for reduced members of the dimethylsulfoxide reductase enzyme family. (2008) (24)
- Analogues of the [Fe4S4]+ sites of reduced ferredoxins: single-step synthesis of the clusters [Fe4S4(SR)4]3− and examples of compressed tetragonal core structures (1984) (24)
- A synthetic analog of the iron/copper bridged assembly in cytochrome c oxidase (1993) (24)
- Heterometal dependence of electron distributions and redox potentials in clusters with cubane-type [MFe3S4]z cores (1993) (24)
- An X-ray spectroscopic investigation of bis(dithiolene)molybdenum(IV,V,VI) and -tungsten(IV,V,VI) complexes: Symmetrized structural representations of the active sites of molybdoenzymes in the DMSO reductase family and of tungstoenzymes in the AOR and F(M)DH families (1999) (24)
- Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer complexes and related reactions. (2009) (23)
- Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. (2007) (23)
- An initial approach to biologically related bridged assemblies: pyridinethiolate-linked iron Fe4S4-Fe complex systems (1991) (23)
- An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR). (2004) (23)
- Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states. (2009) (23)
- High-Nuclearity Sulfide-Rich Molybdenum−Iron−Sulfur Clusters: Reevaluation and Extension (2002) (23)
- Magnetic Evidence Indicative of Structures and Structural Changes in Complexes of Cobalt(II) (1960) (22)
- Iron-sulfur-thiolate basket clusters (1988) (22)
- Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for the initial step in biotin synthase catalysis. (2001) (22)
- Characterization of the Self-Condensation Equilibrium of [Fe(4)S(4)(SH)(4)](2-): Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster. (1997) (22)
- Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligation. (2000) (22)
- Toward an expanded oxygen atom transfer reactivity scale: Computational investigation of the energetics of oxo transfer reaction couples (2008) (22)
- Cyanide and methylisocyanide binding to the isolated iron-molybdenum cofactor of nitrogenase. (1989) (22)
- Entry to the solution chemistry of niobium and tantalum sulfides: Synthesis of soluble forms of the tetrathiometalates (MS sub 4 ) sup 3 minus (1990) (22)
- Synthesis of structural analogues of the oxidized sites in the xanthine oxidoreductase enzyme family. (2007) (22)
- Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family. (2003) (21)
- GENERAL SYNTHETIC ROUTES TO TETRAAZA MACROCYCLES, PREPARATION OF THE CORRIN INNER RING STRUCTURE (1973) (21)
- Introduction: bioinorganic enzymology II. (2014) (21)
- Hydrogen evolution from homogeneous reaction systems containing reduced molybdenum-iron-sulfur clusters (1980) (21)
- Tetrakis (ethane-1,2-dithiolato) divanadate (III): a binuclear complex with a quadruple bridge, a metal-metal bond, and nonoctahedral stereochemistry (1983) (21)
- Structural characterization of metallopeptides designed as scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy. (2002) (21)
- Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligation. (2007) (21)
- Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites. (2012) (21)
- Initial members of the family of molecular mid-valent high-nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-). (2005) (21)
- Bis[bis(1,2-ethanedithiolato)ferrate(III)] dianion, a .mu.2-thiolato dimer. Synthesis and properties (1975) (21)
- Synthesis and structure of a new type of molybdenum-iron-sulfur double-cubane cluster and evidence for formation of magnetically uncoupled S = 3/2 MoFe3S4 subclusters (1981) (20)
- Group 5 tetrathiometalates : simplified syntheses and structures (1992) (20)
- VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal. (2008) (20)
- [Na2Fe18S30]8-. A high-nuclearity cyclic cluster generated solely by iron-sulfur bridge bonding (1988) (20)
- A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase. (1999) (20)
- MAGNETIC OBSERVATIONS OF SOME SUBSTITUTED NICKEL(II) SALICYLALDIMINE COMPLEXES (1960) (20)
- Solution chemistry of ethane-1,2-dithiolate complexes: equilibria and electron-transfer reactions (1986) (20)
- Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters. (2011) (20)
- Synthetic transformations of tetraaza macrocyclic metal complexes. Preparation of the corrinoid and other unsaturated ring systems by oxidative dehydrogenation reactions of nickel(II), copper(II), and cobalt(II) macrocycles (1975) (20)
- Oxo sulfido ligand substitution in dimolybdate ([Mo2O7]2-): reaction sequence and characterization of the final product, [MoS3(OSiMe3)]- (1985) (20)
- Characterization of the iron-sulfur centers in succinate dehydrogenase. (1979) (19)
- Core chalcogenide atom substitution reactions of [Fe2X2(SR)4]2- and [Fe4X4(SR)4]2-,3- clusters (X = sulfur, selenium) (1981) (19)
- SYNTHETIC ANALOGS OF THE 4‐FE ACTIVE SITES OF REDUCED FERREDOXINS. ELECTRONIC PROPERTIES OF THE TETRANUCLEAR TRIANIONS (FE4S4(SR)4)3‐ AND THE STRUCTURE OF ((C2H5)3(CH3)N)3(FE4S4(SC6H5)4) (1978) (19)
- Terminal Ligand Assignments Based on Trends in Metal−Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters (1998) (19)
- THE SYNTHESIS AND STRUCTURE OF DECA(BENZENETHIOLATO)TETRAFERRATE(II) DIANION, AN INTERMEDIATE IN THE ASSEMBLY OF (FE4S4(SC6H5)4)2- FROM SIMPLE REAGENTS (1980) (19)
- Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-bridged double cubanes: oxygen-ligated topological PN clusters. (2007) (19)
- New inorganic ring system: planar Fe/sub 3/(. mu. /sub 2/-SR)/sub 3/ in (Fe/sub 3/(SR)/sub 3/X/sub 6/)/sup 3 -/ - synthesis, structures, and solution conformation and equilibrium (1986) (19)
- Introduction: Bioinorganic enzymology II. (2014) (19)
- Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Monooxo MoIV and Bisoxo MoVI Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in Sulfite Oxidase and Its Relation to the Mechanism of DMSO Reductase (2014) (19)
- Resonance Raman spectroscopic evidence for structural variation among bacterial ferredoxin, HiPIP, and Fe4S4(SCH2Ph)42. (1975) (19)
- Metallocyclopeptide complexes with MII(S.Cys)4 chromophores. (2000) (19)
- Zero-valent nickel complexes of bis(phosphino)-o-carboranes (1965) (19)
- X-ray absorption spectroscopy of a structural analogue of the oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes. (2003) (19)
- Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon and silicon reagents. (2004) (18)
- Nontemplate synthesis of an unsaturated tetraaza[14]macrocycle and its metal(II) complexes (1971) (18)
- STEREOELECTRONIC PREFERENCES IN ELECTRON TRANSFER SERIES OF NICKEL WITH TRIDENTATE LIGANDS CONTAINING HARD-SOFT DONOR SETS (1994) (18)
- Synthetic analogs of the active sites of iron-sulfur proteins. 8. Some electronic properties of (Fe4S4(SR)4)3-, analogs of reduced bacterial ferredoxins. (1974) (18)
- Ligand-based redox reactions. Analysis of the electron paramagnetic resonance spectrum of the [Ni(Me4[14]hexaenatoN4)]+ cation radical, the central member of a three-membered electron transfer series containing a tetraaza[14]annulene ligand system (1975) (18)
- Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors. (1996) (18)
- FERRIC PORPHYRIN THIOLATES, POSSIBLE RELATIONSHIP TO CYTOCHROME P-450 ENZYMES AND THE STRUCTURE OF (P-NITROBENZENETHIOLATO)IRON(III) PROTOPORPHYRIN IX DIMETHYL ESTER (1975) (18)
- Demonstration of alternative spin states in clusters containing the biologically relevant [Fe4S4]1+ core (1986) (18)
- Self-assembly of a tetradecanuclear iron nitride cluster. (2006) (18)
- SOLUBLE METAL SULFIDES - SYNTHESIS AND STRUCTURES OF [M6S17]4- (M = NB, TA) - ICOSAHEDRAL-FRAGMENT CAGES CONTAINING FOUR TYPES OF COORDINATED SULFIDE (1983) (18)
- Hexakis(triethylphosphine)hexathioxohexairon(+): extension of stabilization of the basket core topology to the [Fe6S6]+ oxidation level (1990) (18)
- Reactivity of Cubane-Type [(OC)(3)MFe(3)S(4)(SR)(3)](3-) Clusters (M = Mo, W): Interconversion with Cuboidal [Fe(3)S(4)](0) Clusters and Electron Transfer. (1997) (18)
- Bridged Binuclear Bis-Dithiolene Complexes of Iron and Cobalt (1971) (17)
- [Na9Fe20Se38]9-: a [sodium-iron-selenium] high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs (1991) (17)
- Heterometal cubane-type clusters: a rhenium-iron-sulfur (ReFe3S4) single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand (1991) (17)
- Molecular Assemblies Containing Unsupported [Fe(III)-(&mgr;(2):eta(2)-RCO(2))-Cu(II)] Bridges. (1996) (17)
- The Adsorption of Zinc(II) on Anion-exchange Resins. II. Stoichiometry, Thermodynamics, Loading Studies, Dowex-2 Adsorption and Factors Influencing the Rate of the Adsorption Process (1957) (17)
- X-ray spectroscopy of enzyme active site analogues and related molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands. (2000) (17)
- Ground-State Electronic Structures of Binuclear Iron(II) Sites: Experimental Protocol and a Consistent Description of Moessbauer, EPR, and Magnetization Measurements of the Bis(phenolate)-Bridged Complex [Fe2(salmp)2]2- (1994) (17)
- Nuclear resonance studies of vanadium(III) complexes. II. Synthesis, stereochemistry and electron delocalization properties of tris(.beta.-ketoamines) (1967) (17)
- Subsite-differentiated analogs of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol (1991) (17)
- Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Sharing Tetrahedra (1994) (16)
- Utility of the electron-transfer series concept. Deprotonated complexes of butane-2,3-dione bis(2-pyridylhydrazone) (1967) (16)
- Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase. (1982) (16)
- Core conversion reactions of iron-sulfur clusters: topological isomer of the Fe6S6-prismane core (1988) (16)
- Spin isolation of the [3Fe―4S] fragment of a [4Fe―4S] cluster: electronic properties of the [3Fe―4S]0 cluster (1989) (16)
- [29] Identification of iron-sulfur clusters in proteins (1978) (16)
- Proton Contact Shifts in Dynamical Nickel(II) Complexes and the Detection of Diastereoisomers by Nuclear Resonance (1963) (16)
- Nuclear resonance studies of vanadium(III) complexes. III. Synthesis, stereochemistry, and electron delocalization properties of tris(salicylaldehydes) and tris(salicylaldimines) (1967) (16)
- CHEMICAL AND ELECTROCHEMICAL INTERRELATIONSHIPS OF THE 1‐FE, 2‐FE, AND 4‐FE ANALOGS OF THE ACTIVE SITES OF IRON‐SULFUR PROTEINS (1978) (15)
- Fluorine-19 chemical shifts as probes of the structure and reactivity of the iron-molybdenum cofactor of nitrogenase. (1988) (15)
- Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase. (1996) (15)
- Diastereoisomeric four-coordinate complexes. VI. Paramagnetic nickel(II) complexes with four asymmetric ligand centers (1968) (15)
- The [2:2] Site-Differentiated Clusters [Fe4S4L2(RNC)6] Containing Two Low-Spin Iron(II) Sites (1994) (15)
- Letter: Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism. (1976) (15)
- A new class of binuclear and trinuclear iron-sulfur clusters derived from bis[bis(trimethylsilyl)amido]iron(II). (2008) (14)
- Carbon monoxide affinities of iron(II) octaethylporphyrin, octaethylchlorin, and octaethylisobacteriochlorin (1982) (14)
- Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate (2005) (14)
- Dithiotropolone (2-mercaptocycloheptatrienethione) and its metal complexes (1968) (14)
- Influence of extrinsic factors on electron transfer in a mixed-valence Fe(2+)/Fe(3+) complex: experimental results and theoretical considerations. (2001) (14)
- Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and W(IV)-dithiolene chelate rings. (2000) (14)
- 8.3 – Electron Transfer: Iron–Sulfur Clusters (2003) (14)
- Concerning the Existence of High-Spin Planar Cobaltous Complexes: Bis(1,2-dicyanomaleonitriledithiolato)cobalt(II) Dianion (1963) (14)
- DETERMINATION OF THE EXCHANGE-COUPLING CONSTANT OF AN FE3+-FE3+ PAIR IN A CUBANE-TYPE IRON-SULFUR CLUSTER (1997) (14)
- PMR STUDIES ON CLOSTRIDIUM PASTEURIANUM FERREDOXIN. ORIGINS OF CONTACT‐SHIFTED RESONANCES AND DENATURATION BY DIMETHYL SULFOXIDE (1973) (14)
- Analogs of the [4Fe-4S]+ sites of reduced ferredoxins: structural and spectroscopic properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in crystalline and solution phases (1983) (13)
- Variability of niobiumsulfur bond lengths: The molecular structures of sulfido-tris(N,N-diethyldithiocarbamato)niobium(V) (1985) (13)
- Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous media. (2011) (13)
- Synthesis and electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3-, analogues of the 4-Fe active sites of reduced ferredoxins. (1977) (13)
- Binding of oxysulfur anions to macrocyclic iron(II,III): [(Fe(TPP))2SO4] and Fe(Me6[14]-4,11-dieneN4)(S2O5)] (1989) (13)
- Synthesis of metal dithiolene complexes by Si-S bond cleavage of a bis(silanylsulfanyl)alkene (2006) (13)
- Complexes containing the Fe-S6 core with unusual magnetic, electrochemical, and stereochemical properties (1970) (13)
- The modular nature of all-ferrous edge-bridged double cubanes. (2010) (12)
- Magnetic and Moessbauer properties of bis (N,N-disubstituted dithiocarbamato)dithioleneiron complexes. Evidence for a singlet-triplet spin-state equilibrium (1974) (12)
- The Adsorption of Zinc(II) on Anion-exchange Resins. III. The Adsorption from Bromide, Fluoride, Cyanide, Oxalate, Acetate, Nitrate, Phosphate, Sulfate and Alkaline Media, the Perchlorate Eflect and Adsorption from Mixed Solvent Media (1957) (12)
- The magnetic circular dichroism spectra of the linear trinuclear clusters [Fe3S4(SR)4]3− in purple aconitase and in a synthetic model (1990) (12)
- Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase. (1997) (12)
- Synthesis and structures of the cuboidal iron-sulfur-nitrosyl-phosphine clusters [Fe4S3(NO)4(PR3)3]0,1+ (R = Et, Pri, C6H11) (1998) (12)
- Analogs of bridged biological active site assemblies: the Fe4S4-sulfide-heme unit (1993) (12)
- Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and oxosulfidomolybdates(VI) and -tungstates(VI). (2007) (11)
- The crystal and molecular structure of the electron transfer complex butane-2, 3-dione-bis(2′-pyridyl-hydrazonato)nickel, [Ni(BDPH)-2H] (1969) (11)
- Clusters containing the iron-rhenium-sulfur [ReFe3(.mu.3-S)4] core: an expansion of the heterometal cubane-type cluster series MFe3S4 (1990) (11)
- OCTANUCLEAR IRON-SULFUR CLUSTERS WITH SYMMETRICALLY COUPLED FE4S4 AND FE4S5 CORES (1995) (11)
- The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites (1998) (11)
- Conformational Analysis of Coordination Compounds. XIV* Proton, Carbon-'13, Cobalt-59 and Platinum-195 N.M.R. Spectra of Six-Membered Diamine Chelate Rings (1982) (11)
- Formation, spectroscopic characterization, and solution stability of an [Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate. (2012) (10)
- Diastereoisomeric four-coordinate complexes. VII. Proton resonance detection of the nonequivalence of enantiomeric nickel(II) complexes in an optically active solvent (1968) (10)
- Li3[VS4].cntdot.2DMF: a solubilized form of tetrathiovanadate(V) (1988) (10)
- [1:3] Site-differentiated and sulfide-bridged cubane clusters in chemistry and biology (1998) (10)
- Detection and identification of intermediates and products of a nonenzymic transamination reaction by proton resonance (1968) (10)
- 7 – Stereochemistry and Structural and Electronic Equilibria (1973) (10)
- Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization. (2011) (10)
- The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state. (2011) (10)
- Trinuclear oxothiomolybdates from the reductive cleavage of [Mo8O26]4- with hexamethyldisilthiane (1985) (9)
- Molybdenum-Mediated Oxygen Atom Transfer: An Improved Analogue Reaction System of the Molybdenum Oxotransferases. (1993) (9)
- Electronic Properties of Monocapped Prismane and Basket Iron-Sulphur Clusters (1991) (9)
- Structural identification of the extruded cores of the active centers of iron-sulfur proteins by fluorine-19 nuclear magnetic resonance spectroscopy. Application to milk xanthine oxidase (1978) (9)
- Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(II) complex. (2014) (9)
- Determination of antiferromagnetic exchange coupling in the tetrahedral thiolate-bridged diferrous complex [Fe2(SEt)6]2-. (2002) (9)
- Theoretical study of the influence of strain and polarization on performance of AlGaN/4H-SiC HBT (2005) (9)
- Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe(3)S(4) Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges. (1998) (9)
- Stereochemically nonrigid cobalt(III) complexes (1971) (9)
- Controlled Incorporation of Nitrides into W-Fe-S Clusters. (2019) (9)
- ELECTRONIC PROPERTIES OF THE LINEAR ANTIFERROMAGNETICALLY COUPLED CLUSTERS (FE3S4(SR)4)3-, STRUCTURAL ISOMERS OF THE IRON-SULFUR(1+) ((FE3S4)1+) UNIT IN IRON-SULFUR PROTEINS (1985) (9)
- A convenient method for the synthesis of macrocyclic tetra-amides by double condensation reaction (1984) (8)
- Electron Transfer: Iron—Sulfur Clusters (2004) (8)
- Tetrahedral and square-pyramidal sulphur-rich complexes of manganese(II) (1993) (8)
- Synthesis of New Types of Dithiolene Ligands (1995) (8)
- [Fe2S2(CO)6]2− as a cluster precursor: synthesis and structure of [MoFe3S6(CO)6]2− and oxidative decarbonylation to a persulfide-bridged MoFe3S4 double cubane (1987) (8)
- The structure of dihydrooctaaza-[14]-annulenes and their nickel(II) complexes (1972) (8)
- MÖSSBAUER PROPERTIES OF SYNTHETIC ANALOGS OF ACTIVE SITES OF THE IRON-SULFUR PROTEINS (1974) (8)
- Concerning Cation-Stabilized Anion Free Radicals (1966) (8)
- 9 – Stereochemically Nonrigid Metal Chelate Complexes (1975) (7)
- Dipole moments and structures of some bis-(trifluoroacetylacetonato) complexes (1960) (7)
- Iron octaethylisobacteriochlorin, a model system for the siroheme prosthetic group of nitrite and sulphite reductases (1979) (7)
- THE (FE(III)N4SR) COORDINATION UNIT, SYNTHESIS AND GROUND STATE ELECTRONIC PROPERTIES OF MACROCYCLIC FERRIC THIOLATES (1975) (7)
- Synthesis and structural characterization of two tungsten(VI) dioxo complexes with N,O- and N,S-coordinating ligands (2001) (7)
- 3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported by a ring or benzenoid frame. (1998) (6)
- Thermodynamic Fitness of Molybdenum(IV,VI) Complexes for Oxygen Atom Transfer Reactions, Including Those with Enzymatic Substrates. (1987) (6)
- Synthesis of tautomeric Schiff base complexes and ketimine .far. aldimine conversion rates of copper(II) complexes (1972) (6)
- Lability of ruthenium(II) carbonyl porphine complexes with nitrogen bases (1971) (6)
- Structural Insights from the Mo K-Edge X-Ray Absorption Near Edge Structure of the Iron-Molybdenum Protein of Nitrogenase and Its Iron-Molybdenum Cofactor by Comparison with Synthetic Fe (1986) (6)
- Stability and nickel binding properties of peptides designed as scaffolds for the stabilization of NiII-Fe4S4 bridged assemblies (2002) (6)
- General synthetic routes to tetraaza macrocycles. Preparation of the corrin inner ring structure (1973) (6)
- On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W) (1997) (6)
- Quantitative extrusions of the Fe4S4 cores of the active sites of ferredoxins and the hydrogenase of Clostridium pasteurianum. (1977) (5)
- STRUCTURE PROOFS OF LIGATED AND POLYMERIC DIOXOMOLYBDENUM(VI)-TRIDENTATE COMPLEXES: MOO2(C5H3N-2,6-(CH2S)2)(C4H8SO) AND (MOO2(C5H3N-2,6-(CH2O)2))N (1983) (5)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF OXIDIZED AND REDUCED RUBREDOXIN (1976) (5)
- Ground Spin State Variability in (Fe4S4(SR)4)3-. Synthetic Analogues of the Reduced Clusters in Ferredoxins and Other Iron-Sulfur Proteins: Cases of Extreme Sensitivity of Electronic State and Structure to Extrinsic Factors. (1988) (5)
- TETRAKIS(ETHANE-1,2-DITHIOLATO)DIVANADATE(III): A BINUCLEAR COMPLEX WITH A QUADRUPLE BRIDGE, A METAL-METAL BOND, AND NONOCTAHEDRAL STEREOCHEMISTRY (1984) (5)
- Dithiotropolonates. III. Ring-alkylation reactions of bis(dithiotropolonato)nickel(II) and -zinc(II) complexes (1972) (5)
- The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters (2004) (4)
- Kinetics, Mechanisms, and Catalysis of Oxygen Atom Transfer Reactions of S-Oxide and Pyridine N-Oxide Substrates with Molybdenum(IV,VI) Complexes: Relevance to Molybdoenzymes. (1988) (4)
- TRINUCLEAR OXOTHIOMOLYBDATES FROM THE REDUCTIVE CLEAVAGE OF (MO8O26)4- WITH HEXAMETHYLDISILTHIANE (1985) (4)
- Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters (Fe4S4(SR)4). Evidence for dominant contact interactions. (1974) (4)
- Protein-bound iron-sulfur clusters: application of a structural database☆ (1995) (4)
- Terminal Ligand Assignments Based on Trends in Metal—Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters. (1998) (4)
- Insertion of (VFe3S4)2+ and (MoFe3S4)3+ Cores into a Semirigid Trithiolate Cavitand Ligand: Regiospecific Reactions at a Vanadium Site Similar to That in Nitrogenase. (1989) (4)
- LIGAND SUBSTITUTION PROPERTIES OF THE MFE3S4 DOUBLE-CUBANE CLUSTER COMPLEXES (MO2FE6S8(SR)9)3- AND (M2FE7S8(SR)12)3- (M = MOLYBDENUM, TUNGSTEN) (1982) (4)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 14. SYNTHESIS, , PROPERTIES, AND STRUCTURES OF BIS(O-XYLYL-α,α′-DITHIOLATO)FERRATE(II,III) ANIONS, ANALOGS OF OXIDIZED AND REDUCED RUBREDOXIN SITES (1977) (4)
- Electronic structure of 5,7,12,14-tetramethyl-1,4,8,11-tetra-azacyclotetradeca-2,4,6,9,11,13-hexaenato–nickel(II) cation radical, the central member of a ligand-based electron-transfer series (1975) (3)
- ASSEMBLY OF BIOLOGICALLY RELEVANT IRON-SULFUR CLUSTERS (1984) (3)
- METAL ION EXCHANGE REACTIONS IN CAGE MOLECULES: THE SYSTEMS (M4-NM′N(SC6H5)10)2- (M, M′ = FE(II), CO(II), ZN(II), CD(II)) WITH ADAMANTANE-LIKE STEREOCHEMISTRY AND THE STRUCTURE OF (FE4(SC6H5)10)2- (1983) (3)
- Subsite-Specific Functionalization of the (4 Fe-4 S)2+ Analogue of Iron-Sulfur Protein Clusters. (1987) (3)
- Subsite-Differentiated Analogues of Biological (4 Fe-4 S)2+ Clusters: Synthesis, Solution and Solid-State Structures, and Subsite-Specific Reactions. (1988) (3)
- Synthesis and selected properties of a reduced single-cubane cluster containing the [MoFe3,S4]2+ (S = 2) core (1983) (3)
- Stabilization of Trivalent Nickel in Tetragonal NiS4N2 and NiN6 Environments: Synthesis, Structures, Redox Potentials, and Observations Related to (NiFe)-Hydrogenases. (1990) (3)
- SYNTHETIC TRANSFORMATIONS OF TETRAAZA MACROCYCLIC METAL COMPOLEXES. PREPARATION OF THE CORRINOID AND OTHER UNSATURATED RING SYSTEMS BY OXIDATIVE DEHYDROGENATION REACTIONS OF NICKEL(II), COPPER(II), AND COBALT(II) MACROCYCLES (1975) (3)
- Angle Dependence of the Properties of the (Fe2X)4+ Bridge Unit (X: O, S): Structures, Antiferromagnetic Coupling, and Properties in Solution. (1988) (3)
- A topological method for the enumeration of bridging modes and connectivity patterns of the clusters MmQnLl with four-coordinate metal sites and Q.mu.2,3,4 bridging atoms (1992) (3)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS. 15. COMPARATIVE POLAROGRAPHIC POTENTIALS OF THE (FE4S4(SR)4)2-,3- AND CLOSTRIDIUM PASTEURIANUM FERREDOXIN REDOX COUPLES (1977) (3)
- Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes. (1999) (2)
- A NEW STRUCTURAL TYPE IN IRON-SULFIDE-THIOLATE CHEMISTRY: PREPARATION, PROPERTIES, AND STRUCTURE OF THE HEXANUCLEAR CLUSTER (FE6S9(S-TERT-C4H9)2)4- (1982) (2)
- SYNTHESIS AND STEREOCHEMISTRY OF METAL(II) THIOLATES OF THE TYPES (M(SR)4)2-, (M2(SR)6)2-, AND (M4(SR)10)2- (M = FE(II), CO(II)) (1984) (2)
- Identification of iron--sulfur clusters in proteins. (1978) (2)
- MAGNETIC PROPERTIES OF [Fe4S4(SR)4]3- CLUSTERS (1980) (2)
- Comprehensive Tungsten‐Iodine Cluster Chemistry: Isolated Intermediates in the Solid‐State Nucleation of (W6I14)2‐. (1995) (2)
- SYNTHETIC ROUTES TO IRON SULFIDE (FE2S2, FE3S4, FE4S4, AND FE6S9), CLUSTERS FROM THE COMMON PRECURSOR TETRAKIS(ETHANETHIOLATE)FERRATE(2-) ION ((FE(SC2H5)4)2-): STRUCTURES AND PROPERTIES OF (FE3S4(SR)4)3- AND BIS(ETHANETHIOLATE)NONATHI (1983) (2)
- CHAPTER 7 – Synthetic Analogues of the Active Sites of Iron–Sulfur Proteins* (1977) (2)
- Nickel-Mediated Formation of Thioesters from Bound Methyl, Thiols, and Carbon Monoxide: A Possible Reaction Pathway of Acetyl-Coenzyme A Synthase Activity in Nickel-Containing Carbon Monoxide Dehydrogenases. (1995) (2)
- Oxomolybdenum(IV,V,VI) Complexes: Structures, Reactivities, and Criteria of Detection of Binuclear (μ-Oxo)molybdenum(V) Products in Oxygen Atom Transfer Systems. (1989) (2)
- Iron-sulphur clusters in natural and synthetic systems. (1975) (2)
- Subsite-Differentiated Analogues of Native (4Fe-4S)2+ Clusters: Preparation of Clusters with Five- and Six-Coordinate Subsites and Modulation of Redox Potentials and Charge Distributions. (1990) (2)
- Subsite-Specific Structures and Reactions in Native and Synthetic (4Fe - 4S) Cubane-Type Clusters (1991) (2)
- Synthesis of a new class of polydentate ligands: [bis(2-imidazolyl)methyl] amino-thioether-thiols (1984) (2)
- 50 Years of metals in biology: the Gordon Research Conference. (2012) (2)
- Electron transfer behaviour of dimeric complexes of cobalt with dithiolate ligands (1966) (2)
- Vanadium(III), Cobalt(II), and Nickel(II) β‐Keto Amine Complexes (2007) (2)
- Stability Range of Heterometal Cubane-Type Clusters MFe3S4: Assembly of Double-Cubane Clusters with the ReFe3S4 Core. (1989) (2)
- SYNTHETIC APPROACHES TO THE MOLYBDENUM SITE IN NITROGENASE. PREPARATION AND STRUCTURAL PROPERTIES OF THE MOLYBDENUM-IRON-SULFUR “DOUBLE-CUBANE” CLUSTER COMPLEXES (MO2FE6S8(SC2H5)9)3- AND (MO2FE6S9(SC2H5)8)3- (1979) (2)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 6, SPECTRAL AND REDOX CHARACTERISTICS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) (1974) (1)
- Controlled Incorporation of Nitrides into W‐Fe‐S Clusters (2019) (1)
- ANALOGS OF THE (FE4S4)+ SITES OF REDUCED FERREDOXINS: SINGLE-STEP SYNTHESIS OF THE CLUSTERS (FE4S4(SR)4)3- AND EXAMPLES OF COMPRESSED TETRAGONAL COR STRUCTURES (1985) (1)
- Alternative Spin States in Synthetic Analogues of Biological Clusters: Spin-Quartet Ground States and Structures of (Fe4S4(SPh)4)3- and (Fe4Se4(SPh)4)3- as Their Tetramethylammonium Salts. (1988) (1)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 2, SYNTHESIS AND STRUCTURE OF THE TETRA(MERCAPTO-MU(3)-SULFIDO-IRON) CLUSTERS, (FE4S4(SR)4)(2-) (1973) (1)
- Structural Chemistry of Vanadium-Iron-Sulfur Clusters Containing the Cubane-Type (VFe3S4)2+ Core. (1987) (1)
- IMPROVED SYNTHESES OF TETRACHLORODI‐μ‐SULFIDODIFERRATE(2‐) ((FE2S2CL4)2‐) AND HEXACHLORO‐μ‐OXODIFERRATE(2‐) ((FE2OCL6)2‐) AND OXO/SULFIDO LIGAND SUBSTITUTION BY USE OF SILYLSULFIDE REAGENTS (2002) (1)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 10, KINETICS AND MECHANISM OF THE LIGAND SUBSTITUTION REACTIONS OF ARYLTHIOLS WITH THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) (1975) (1)
- Alternative Spin States in Synthetic Analogues of Biological (4Fe-4S)+ Clusters: Further Cases of Variable Ground States and the Structure of (Et4N)3(Fe4S4(S-o-C6H4StBu)4), Containing a Reduced Cluster with a Compressed Tetragonal Dis (1989) (1)
- Model system studies of axial ligation in the oxidized reaction states of cytochrome P-450 enzymes. (1976) (1)
- Developments in the Biomimetic Chemistry of Cubane-Type and Higher Nuclearity Iron-Sulfur Clusters (2014) (1)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 11, SYNTHESIS AND PROPERTIES OF COMPLEXES CONTAINING THE FE2S2 CORE AND THE STRUCTURES OF BIS(O-XYLYL-ALPHA,ALPHA′-DITHIOLATO-MU-SULFIDO-FERRATE(III)) AND BIS(P-TOLYLTHIOLATO-MU-SULFIDO-FERRATE(III)) DIANIONS (1975) (1)
- Physical Inorganic Chemistry. By Michell J. Sienko and Robert A. Plane (1964) (1)
- Electrons in Oxygen- And Sulphur Containing Ligands (1976) (1)
- THE CLUSTERS (CO8S6(SPH)8)4-,5-: PREPARATIONS, PROPERTIES, AND STRUCTURAL RELATIONSHIP OF NEAR-CUBIC CO8(μ4-S)6 CORES TO THE CLUSTERS IN SYNTHETIC PENTLANDITE (1985) (1)
- Thiol as an Electron Donor in Molybdenum Oxo-Transferase Analogue Reaction Systems: Observations by 19F NMR Spectroscopy and Biological Implications. (1987) (1)
- Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re6S8]2+ and [Re6Se8]2+. (2000) (1)
- Group 5 Tetrathiometalates: Simplified Syntheses and Structures. (1993) (0)
- Binding of Oxysulfur Anions to Macrocyclic Iron(II,III): ((Fe(TPP))2SO4) and (Fe(Me6(14)-4,11-dieneN4)(S2O5)). (1989) (0)
- VARIABILITY OF NIOBIUM:SULFUR MULTIPLE BOND LENGTHS: THE MOLECULAR STRUCTURES OF SULFIDOTRIS(N,N-DIETHYLDITHIOCARBAMATO)NIOBIUM(V) (1985) (0)
- Preparation, Structure, and Reactions of Triphenyl Phosphite Complexes of Iron, Ruthenium, and Osmium (1978) (0)
- Recent developments in biologically related metal-sulfur clusters (1997) (0)
- Oxygen atom transfer reactions of molybdenum complexes and iron-porphyrin complexes as models for enzyme active sites (1989) (0)
- Stabilization of trivalent nickel in an anionic sulfur environment as part of an effort directed towards a functional model for nickel containing hydrogenases (1989) (0)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 9, FORMATION AND SOME ELECTRONIC AND REACTIVITY PROPERTIES OF FE4S4 GLYCYL-L-CYSTEINYLGLYCYL OLIGOPEPTIDE COMPLEXES OBTAINED BY LIGAND SUBSTITUTION REACTIONS (1974) (0)
- Onthestructure ofthenickel/iron/sulf ur center ofthecarbon monoxide dehydrogenase fromRhodospirillum rubrum: An x-ray absorption spectroscopy study (Nicarbon monoxide dehydrogenase/Rhodospiriilum rubrum/edge andextended x-rayabsorption fine structure spectroscopy/Ni active site) (1992) (0)
- A HEXANUCLEAR IRON-SULFIDE-THIOLATE CLUSTER: ASSEMBLY AND PROPERTIES OF (FE6S9(S-TERT-C4H9)2)4- CONTAINING THREE TYPES OF BRIDGING SULFUR ATOMS (1982) (0)
- Clusters Containing the (ReFe3(μ3-S)4) Core: An Expansion of the Heterometal Cubane-Type Cluster Series MFe3S4. (1990) (0)
- Entry to the Solution Chemistry of Niobium and Tantalum Sulfides: Synthesis of Soluble Forms of the Tetrathiometalates (MS4)3-. (1991) (0)
- Demonstration of Alternative Spin States in Clusters Containing the Biologically Relevant (Fe4S4)+ Core. (1986) (0)
- Model Fe(III) Porphyrin Systems: Axial Ligation in Oxidized Cytochrome P-450.S (1976) (0)
- SYNTHESIS AND ELECTRONIC PROPERTIES OF THE TETRANUCLEAR TRIANIONS (FE4S4(SR)4)3-, ANALOGS OF THE 4-FE ACTIVE SITES OF REDUCED FERRODOXINS (1977) (0)
- A New Inorganic Ring System: Planar Fe3(μ2-SR)3 in (Fe3(SR)3X6)3- - Synthesis, Structures, and Solution Conformation and Equilibrium. (1987) (0)
- Phosphine Cleavage of Iron(III)-Bridged Double Cubanes: A New Route to MoFe3S4 Single Cubanes. (1987) (0)
- OXO SULFIDO LIGAND SUBSTITUTION IN DIMOLYBDATE ((MO2O7)2-): REACTION SEQUENCE AND CHARACTERIZATION OF THE FINAL PRODUCT, (MOS3(OSIME3))- (1985) (0)
- A Solid-State Route to Molecular Clusters: Access to the Solution Chemistry of (Re6Q8)2+ (Q: S, Se) Core-Containing Clusters via Dimensional Reduction. (1996) (0)
- INORGANIC DERIVATIVES OF IRON SULFIDE THIOLATE DIMERS AND TETRAMERS- SYNTHESIS AND PROPERTIES OF THE HALIDE SERIES (FE2S2X4)2- AND (FE4S4X4)2- (X = CHLORINE, BROMINE, IODINE) (1978) (0)
- High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters: reevaluation and extension. (2002) (0)
- Stabilization of Nickel(III) in a Classical N2S2 Coordination Environment Containing Anionic Sulfur. (1988) (0)
- Oxygen atom and imido group transfer reactions of Mo and V (1989) (0)
- (Na2Fe18S30)8-: A High-Nuclearity Cyclic Cluster Generated Solely by Iron-Sulfur Bridge Bonding. (1988) (0)
- SYNTHESIS AND SELECTED PROPERTIES OF A REDUCED SINGLE-CUBANE CLUSTER CONTAINING THE (MOFE3S4)2+ (S = 2) CORE (1984) (0)
- Spin Isolation of the (3Fe-4S) Fragment of a (4Fe-4S) Cluster: Electronic Properties of the (3Fe-4S)0 Cluster. (1990) (0)
- Rhenium‐Selenium‐Chlorine Solid Phases: Cluster Excision and Core Substitution Reactions of Molecular Species. (1993) (0)
- Biologically related nickel chemistry (1991) (0)
- Formation of Bridged (4Fe-4S)2+ Double Cubanes by Site-Specific Reactions: Electron-Transfer Coupling Across Sulfur-Containing Bridges of Variable Length. (1989) (0)
- Hexanuclear Iron-Sulfur Basket Clusters: Topological Isomers of Prismanes. Synthesis, Structure, and Reactions. (1988) (0)
- Synthetic Analogues and Reaction Systems Relevant to the Molybdenum and Tungsten Oxotransferases (2004) (0)
- BIS(BIS(1,2-ETHANEDITHIOLATO)FERRATE(III)) DIANION, A MU(2)-THIOLATO DIMER, SYNTHESIS AND PROPERTIES (1975) (0)
- SOLUBLE METAL SULFIDES. SYNTHESIS AND STRUCTURES OF (M6S17)4- (M = NIOBIUM OR TANTALUM): ICOSAHEDRAL-FRAGMENT CAGES CONTAINING FOUR TYPES OF COORDINATED SULFIDE (1984) (0)
- Subsite-specific reactivity of Fe4S4 clusters bound to tridentate, trithiol ligands as models for enzyme active sites (1989) (0)
- SYNTHESIS, STRUCTURE, AND ELECTRONIC FEATURES OF (μ-SULFIDO)BIS((N,N′-ETHYLENEBIS(SALICYLALDIMINATO))IRON(III)), (FE(SALEN))2S, CONTAINING THE ONLY AUTHENTICATED EXAMPLE OF THE IRON(III)-SULFUR-IRON(III) SINGLE BRIDGE (1985) (0)
- AnSCFSolvation Model fortheHydrophobic Effect andAbsolute FreeEnergies ofAqueous Solvation (1992) (0)
- ELECTRON EXCHANGE KINETICS OF (FE4S4(SR)4)2-/(FE4S4(SR)4)3- AND (FE4SE4(SR)4)2-/(FE4SE4(SR)4)3- SYSTEMS. ESTIMATES OF THE INTRINSIC SELF-EXCHANGE RATE CONSTANT OF 4-FE SITES IN OXIDIZED AND REDUCED FERREDOXINS (1980) (0)
- SYNTHESIS OF A NEW CLASS OF POLYDENTATE LIGANDS: (BIS(2-IMIDAZOLYL)METHYL)AMINO-THIOETHER-THIOLS (1984) (0)
- A New Class of (N,N′-Bis(salicylideneamino)ethanato)iron(II) Complexes: Five-Coordinate (Fe(II)(salen)L)-. Preparation, Properties, and Mechanism of Electron-Transfer Reactions. (1988) (0)
- Initial Members of the Family of Molecular Mid‐Valent High‐Nuclearity Iron Nitrides: [Fe4N2X10]4‐ and [Fe10N8X12]5‐ (X: Cl‐, Br‐). (2005) (0)
- Electronic Properties of Molybdenum-Iron-Sulfur-Clusters: Approaches to the Molybdenum Site in Nitrogenase (1980) (0)
- Heterometallic Clusters: Synthesis and Reactions of Vanadium-Iron-Sulfur Single- and Double-Cubane Clusters and the Structure of (V2Fe6S8Cl4(C2H4S2)2)4-. (1987) (0)
- Electronic Control of the ‘Bailar Twist’ in Formally d0-d2 Molybdenum tris(dithiolene) Complexes: A Sulfur K-edge XAS and DFT Study (2009) (0)
- EQUIVALENCE OF METAL CENTERS IN THE IRON-SULFUR PROTEIN ACTIVE SITE ANALOGS (FE4S4(SR)4)(2-) (1974) (0)
- On the Molecular/Solid-State Boundary. A Cyclic Iron-Sulfur Cluster of Nuclearity Eighteen: Synthesis, Structure, and Properties. (1990) (0)
- Dimensional Reduction of Re6S8Cl2: Sheets, Chains and Discrete Clusters Composed of Chloride‐Terminated (Re6Q8)2+ (Q: S, Se) Cores. (1995) (0)
- MOLYBDENUM-IRON-SULFUR CLUSTERS (1981) (0)
- Models for metallobiomolecular active sites (1989) (0)
- STRUCTURAL DISTORTIONS OF THE (FE4S4)2+ CORE OF (FE4S4(S-TERT-C4H9)4)2- IN DIFFERENT CRYSTALLINE ENVIRONMENTS AND DETECTION AND INSTABILITY OF OXIDIZED ((FE4S4)3+) CLUSTERS (1983) (0)
- Fe7S6(PEt3)4Cl3: A Topological Link Between the Prismatic and Cuboctahedral Structures of Iron-Sulfur Clusters. (1987) (0)
- Self-Assembly of a Tetradecanuclear Iron Nitride Cluster (2006) (0)
- Effects of pentacoordination at a single iron atom of site-functionalized Fe4S4 clusters (1989) (0)
- SOLUBLE SULFIDES OF NIOBIUM(V) AND TANTALUM(V): SYNTHESIS, STRUCTURES, AND PROPERTIES OF THE FIVEFOLD SYMMETRIC CAGES (M6S17)4- (1985) (0)
- CCDC 208689: Experimental Crystal Structure Determination (2003) (0)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 7, LIGAND SUBSTITUTION REACTIONS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) AND THE STRUCTURE OF ((CH3)4N)2(FE4S4(SC6H5)4) (1974) (0)
- INOR 473-Homo- and heterometal iron-sulfur clusters of nuclearity three or higher in relation to biological clusters (2008) (0)
- Assembly of Vanadium - Iron - Sulfur Cubane Clusters from Mononuclear and Linear Trinuclear Reactants. (1986) (0)
- Li3(VS4)·2 DMF: A Solubilized Form of Tetrathiovanadate(V). (1989) (0)
- High‐Nuclearity Sulfide‐Rich Molybdenum—Iron—Sulfur Clusters: Reevaluation and Extension. (2002) (0)
- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 4, LIGAND SUBSTITUTION REACTIONS OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)(2-) (1974) (0)
- Crystal and Molecular Structure of [Ni(Me4[14]hexaenato N4)]2(CF3SO3)2: Conversion of a Metal-Stabilized π-Radical to a Diamagnetic Dimer with a Long Metal-Metal Bond and Eclipsed Macrocyclic Ligands upon Crystallization. (1977) (0)
- SYNTHESIS AND ELECTRONIC AND REDOX PROPERTIES OF “DOUBLE-CUBANE” CLUSTER COMPLEXES CONTAINING MOLYBDENUM IRON SULFIDE (MOFE3S4) AND TUNGSTEN IRON SULFIDE (WFE3S4) CORES (1980) (0)
- Solution Chemistry of Ethane-1,2-dithiolate Complexes: Equilibria and Electron-Transfer Reactions. (1986) (0)
- Tetrathiovanadate(V) and Tetrathiorhenate(VII): Structures and Reactions, Including Characterization of the VFe2S4Core Unit. (1986) (0)
- Binuclear Iron System Ferromagnetic in Three Oxidation States: Synthesis, Structures, and Electronic Aspects of Molecules with a Fe2(OR)2 Bridge Unit Containing Fe(III,III), Fe(III,II), and Fe(II,II). (1989) (0)
- Comparative Electronic Properties of Vanadium-Iron-Sulfur and Molybdenum-Iron-Sulfur Clusters Containing Isoelectronic Cubane-Type (VFe3S4)2+ and (MoFe3S4)3+ Cores. (1987) (0)
- Synthesis and Structural Systematics of Ethane-1,2-dithiolato Complexes. (1986) (0)
- ELECTRON-TRANSFER SERIES OF MOFE3S4 DOUBLE-CUBANE CLUSTERS: ELECTRONIC PROPERTIES OF COMPONENTS AND THE STRUCTURE OF ((C2H5)4N)5(MO2FE6S8(SC6H5)9) (1982) (0)
- Chemical and Electrochemical Reactivity of Nickel(II,I) Thiolate Complexes: Examples of Ligand-Based Oxidation and Metal-Centered Oxidative Addition. (1989) (0)
- PROTON MAGNETIC RESONANCE PROPERTIES OF THE TETRANUCLEAR CLUSTERS (FE4S4(SR)4)3‐, ANALOGS OF THE 4‐FE SITES OF REDUCED FERREDOXINS (1978) (0)
- Core Conversion Reactions of Iron-Sulfur Clusters: Topological Isomer of the Fe6S6-Prismance Core. (1988) (0)
- Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology (1993) (0)
- DERIVATIVES OF TETRATHIOVANADATE(V): SYNTHESIS OF THE LINEAR HETEROMETALLIC FE(μ2-S)2V(μ2-S)2FE CORE AND THE STRUCTURES OF TETRATHIOVANADATE(3-) ION ((VS4)3-) AND TETRACHLOROTETRATHIODIFERRATEVANADATE(3-) ION ((VFE2S4CL4)3-) (1984) (0)
- IMPROVED SYNTHESES OF THE DIMERIC COMPLEXES (FE2X2(SC6H4Y)4)2- AND (FE2X2((SCH2)2C6H4)2)2- (X = SULFUR, SELENIUM), ANALOGS OF THE 2-FE SITES OF OXIDIZED FERREDOXIN PROTEINS (1981) (0)
- Cleavage of Ni-( μ 2 -S)-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions (2010) (0)
- Additions and Corrections - Studies on Nickel(II) Complexes. V. A Nuclear Resonance Study of Conformational Equilibria. (1964) (0)
- SYNTHESE EMPLOYING PYRIDYLLITHIUM REAGENTS, NEW ROUTES TO 2,6-DISUBSTITUTED PYRIDINES AND 6,6′-DISUBSTITUTED 2,2′-BIPYRIDYLS (1973) (0)
- [Na2Fe18S30]8−, A high-nuclearity cyclic cluster containing no terminal ligands: Amidate supported formation, structural diversity, novel physical properties (1989) (0)
- Nuclear Resonance Studies of Structural Equilibria in Solutions of Nickel(II) Complexes (1964) (0)
- INOR 33-Synthetic efforts to structural analogs of C-cluster of carbon monoxide dehydrogenase (CODH) (2007) (0)
- (Na9Fe20Se38)9-: A High-Nuclearity Bicyclic Cluster Constructed by the Fusion of Fe2Se2 Rhombs. (1991) (0)
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