Robert Emerson Ireland

Robert Emerson Ireland's AcademicInfluence.com Rankings

Chemistry

#4866

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#5960

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Organic Chemistry

#807

World Rank

#907

Historical Rank

chemistry Degrees

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Chemistry

Robert Emerson Ireland's Degrees

PhD Chemistry Stanford University
Bachelors Chemistry University of California, Berkeley

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Robert Emerson Ireland's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation (1976) (650)
An improved procedure for the preparation of the Dess-Martin periodinane (1993) (430)
Claisen rearrangement of allyl esters (1972) (277)
Application of the Swern oxidation to the manipulation of highly reactive carbonyl compounds (1985) (203)
Stereochemical control in the ester enolate Claisen rearrangement. 1. Stereoselectivity in silyl ketene acetal formation (1991) (192)
The total synthesis of ionophore antibiotics. A convergent synthesis of lasalocid A (X537A) (1983) (134)
N,N,N',N'-Tetramethylphosphorodiamidate group. Useful function for the protection or reductive deoxygenation of alcohols and ketones (1972) (112)
The n-Butylthiomethylene Blocking Group1 (1962) (90)
Stereochemical control in the ester enolate Claisen rearrangement. 2. Chairlike vs boatlike transition-state selection (1991) (85)
Enolate Claisen rearrangement of esters from furanoid and pyranoid glycals (1980) (82)
The synthesis of chiral subunits for macrolide synthesis: the Prelog-Djerassi lactone and derivatives (1981) (77)
3-Acyltetramic acid antibiotics. 2. Synthesis of (+)-streptolic acid (1988) (76)
The convergent synthesis of polyether ionophore antibiotics: an approach to the synthesis of the monensin tetrahydropyran-bis(tetrahydrofuran) via the ester enolate Claisen rearrangement and reductive decarboxylation (1985) (75)
3-Acyltetramic acid antibiotics. 1. Synthesis of tirandamycic acid (1981) (68)
Approach to the total synthesis of chlorothricolide: synthesis of (.+-.)-19,20-dihydro-24-O-methylchlorothricolide methyl ester ethyl carbonate (1986) (67)
An approach to the total synthesis of aplysiatoxin (1988) (67)
Convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin bis(tetrahydrofuran) via the Claisen rearrangement of an ester enolate with a .beta.-leaving group (1985) (64)
Total synthesis of lasalocid A (X537A) (1980) (62)
A Total Synthesis of FK-506(1). (1996) (59)
Reactions of pentahapto-cyclohexadienyliron tricarbonyl cations with enamines (1974) (54)
The stereoselective generation of ester enolates (1975) (49)
AN EFFICIENT METHOD FOR THE PREPARATION OF FURANOID AND PYRANOID GLYCALS (1978) (48)
Synthesis of the 9,10-acetonide of 9-dihydro-FK-506 (1992) (45)
A chiral primary alcohol equivalent: silyl-assisted asymmetric induction in the ester enolate Claisen rearrangement (1984) (45)
Experiments directed toward the total synthesis of terpenes. VII. The synthesis of (+or-)-8-beta-carbomethoxy-13-oxopodocarpanone, a degradation product of phyllocladene. (1966) (42)
Total synthesis of (.+-.)-aphidicolin and (.+-.)-.beta.-chamigrene (1984) (42)
Experiments Directed toward the Total Synthesis of Terpenes. IV. The Synthesis of (±)-Sandaracopimaradiene and (±)-Pimaradiene1,2 (1963) (40)
Efficient, stereoselective total synthesis of (.+-.)-aphidicolin (1981) (40)
Allylic Rearrangements. XLI. The Reaction of Thionyl Chloride with Steroid Allylic Alcohols1 (1958) (39)
Macrocyclic lactone formation through sulfide contraction. Synthesis of (.+-.)-diplodialide A (1980) (39)
Convergent synthesis of polyether ionophore antibiotics: Synthesis of the spiroketal and tricyclic glycal segments of monensin (1993) (38)
Carboalumination of 1-alkynes and in situ transmetalation to higher order cyanocuprates. Stereospecific synthesis of tri- and disubstituted olefins by conjugate addition to enones (1990) (38)
An approach to the total synthesis of chlorothricolide: the synthesis of the top half (1979) (37)
Diels‐Alder Approach to Highly Functionalized Tertiary α‐Hydroxy Ketones: A Novel Route to the Hexahydrobenzofuran Portion of the Avermectins and Milbemycins (1986) (37)
Experiments Directed toward the Total Synthesis of Terpenes. III. The Use of trans-Δ6-Octalone-1 in the Preparation of Dicyclic Intermediates (1962) (36)
Total synthesis of polyether antibiotics. Synthesis of the enantiomer of lasalocid A (X-537A) (1983) (36)
A NEW SYNTHETIC METHOD FOR THE PREPARATION OF a-SUBSTITUTED -KETOESTERS (1959) (36)
A new method for the synthesis of structurally specific olefins from enolate anions (1969) (35)
The convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin spiroketal (1985) (33)
Experiments Directed toward the Total Synthesis of Terpenes. II. The Synthesis of dl-6-Keto-5,5, 9-trimethyl-2-methylene-trans-decalyl-lα-acetic Acid and Derivatives1 (1962) (32)
The generation of C-glycosides through the enolate Claisen rearrangement (1979) (30)
Macrolide total synthesis. The synthesis of spiro ketal intermediates and their cleavage into open-chain derivatives (1983) (30)
Experiments Directed toward the Total Synthesis of Terpenes. V. The Synthesis of the (±)-9-Isopimaradienes1,2 (1963) (29)
The convergent synthesis of polyether ionophore antibiotics: the synthesis of the A ring carbamonensin spiro ether (1988) (29)
A convergent scheme for the synthesis of spiroketals and the synthesis of (±)-chalcogran (1980) (28)
Use of a masked aldol unit in the synthesis of the right side of FK-506 (1990) (27)
A chiral total synthesis of (-)- and (+)-nonactic acids from carbohydrate precursors and the definition of the transition for the enolate claisen rearrangement in heterocyclic systems (1980) (27)
Studies directed towards the total synthesis of FK-506 preparation of a C(1) to C(15) segment (1989) (26)
Experiments directed toward the total synthesis of terpenes. X. A stereoselective scheme for diterpenoid resin acid synthesis. (1966) (26)
Convenient method for the titration of amide base solutions (1991) (26)
Ester enolate Claisen rearrangement. Construction of the prostanoid skeleton (1976) (26)
Total synthesis of an unsymmetrical pentacyclic triterpene. DL-germanicol (1970) (25)
Stereochemistry of the Claisen rearrangement of derivatives of 5-tert-butyl-1-(hydroxymethyl)-1-cyclohexene: preferred axial attachment of the side chain (1983) (25)
Convergent synthesis of polyether ionophore antibiotics: protective manipulation and synthesis of monensin A (1993) (24)
Experiments directed toward the total synthesis of terpenes. IX. The total synthesis of (+or-)-hibaene and the oxygenation of some tetracyclic diterpenes. (1966) (24)
Experiments directed toward the total synthesis of terpenes. XVII. Development of methods for the synthesis of pentacyclic triterpenes based on a mechanistic interpretation of the stereochemical outcome of the Friedel-Crafts cyclialkylation reaction (1972) (24)
Total synthesis of FK-506. Part 1: Construction of the C16–C34 fragment☆ (1997) (24)
Experiments Directed toward the Total Synthesis of Terpenes. VIII. The Total Synthesis of (±)-Kaurene and (±)-Atisirene1 (1966) (23)
A chiral synthesis of the left-side aldehyde for lasalocid A synthesis (1980) (22)
Experiments directed toward the total synthesis of terpenes. XI. The total synthesis of (.+-.)-rimuene and (.+-.)-13-epi-rimuene (1967) (22)
The synthesis of dl-sandaracopimaradiene, dl-pimaradiene and some observations on the structure of rimuene☆ (1960) (22)
Total synthesis of terpenes. XIX. Synthesis of 8-methoxy-4a.beta., 10b.beta., 12a.alpha.-trimethyl-3,4,4a,4b.alpha.,5,6,10b,11,12,12a-decahydrochrysen-1(2H)-one, a key intermediate in the total synthesis of (+-)-shionone (1975) (21)
A Total Synthesis of Estrone and 14-Isoestrone (1957) (20)
Total synthesis of terpenes, XVIII. Convergent, stereoselective total synthesis of the unsymmetrical pentacyclic triterpene alnusenone (1973) (19)
Experiments directed toward the total synthesis of terpenes. XIII. Construction of the lactone ring of rosenonolactone (1969) (19)
Macrolide total synthesis. The synthesis of seco-acid derivatives for the synthesis of methymycin and 10-deoxymethymycin (1983) (18)
Approach to the total synthesis of chlorothricolide: synthesis of "7-epi-bottom half" and its union with "top half" systems (1981) (18)
Allylic Rearrangements. XLV.1 The Reaction of Thionyl Chloride with 4β-Hydroxycholesteryl Benzoate (1959) (18)
Total synthesis of FK-506. Part 2: Completion of the synthesis☆ (1997) (18)
3-Acyltetramic acid antibiotics. 3. An approach to the synthesis of Bu-2313 (1987) (18)
Experiments Directed toward the Total Synthesis of Terpenes. VI. The Stereochemistry of Isopimaric Acid1,2 (1963) (18)
New and efficient synthesis of 6-deoxy-L-gulose (1980) (17)
Studies on the total synthesis of steroidal antibiotics. 2. Two convergent schemes for the synthesis of tetracyclic intermediates. (1977) (16)
A stereoselective method For the generation of aldol-type systems (1977) (16)
A highly convergent synthesis of mexiprestil: 16(R) 16-methoxy 16-methyl PGE1 methyl ester (1988) (16)
Total synthesis of terpenes. XV. Synthesis of 3,10-dimethoxy-6a.beta.,12b.beta.-dimethyl-5,6,6a,6b.alpha.,7,8,12b,13-octahydropicene, a potential intermediate in triterpene synthesis (1969) (15)
Total synthesis of dl-shionone, a tetracyclic triterpene (1974) (15)
Total synthesis of DL-alnusenone (1970) (15)
Studies on the total synthesis of steroidal antibiotics. I. An efficient, stereoselective method for the formation of trans-syn-trans-perhydrophenanthrene derivatives. (1972) (15)
Experiments Directed toward the Total Synthesis of Terpenes. I. The Synthesis of 1β,9-Dimethyl-6,6-ethylenedioxy-cis-decalone-2 (1962) (14)
Experiments directed toward the total synthesis of terpenes. XXI. Alternate total synthesis of dl-alnusenone via polyene cyclization (1975) (14)
Stereospecific synthesis and acid-catalyzed cyclization of 4,6-dimethyl-trans-5,9-decadienal (1970) (14)
The construction of the C/D ring system present in the diterpenoid alkaloids atisine and garryfoline (1963) (14)
Total synthesis of terpenes. XXII. Polyene cyclization approach to tetradecahydropicene derivatives for pentacyclic triterpene synthesis (1975) (13)
Total synthesis of terpenes. XIV. Interpretation of the transmogrification of 4.beta., 7a.alpha.-dimethyl-1.alpha.-hydroxy-4.alpha.-phenyl-4,5,6,7-tetrahydro-2-indanone by base (1970) (13)
Experiments directed toward the total synthesis of terpenes. 24. On the .pi. route to aphidicolin: synthesis of 18,19-bisnoraphidicolan-3-one (1979) (12)
The preparation of trophocytes from disaggregated fat body of the cockroach (Periplaneta americana). (1994) (12)
Methodology for the enantioselective synthesis of aldols and other 1,3-dioxygenated systems (1990) (12)
Hormonal activation of phosphorylase in cockroach fat body trophocytes: A correlation with trans-membrane calcium flux. (1999) (12)
Stereochemistry of the Diels-Alder reaction of vinylcyclohexene or 1-[.alpha.-(tert-butyldimethylsilyloxy)vinyl]-.DELTA.1-cyclohexene and 2-methylcyclopentenone (1979) (11)
Convenient, stereoselective synthesis of 9,10-dimethyl-trans-1-decalones through the protolysis of fused methoxycyclopropanes (1970) (11)
The total synthesis of (±)-friedelin, an unsymmetrical, pentacyclic triterpene (1976) (11)
The stereospecific total synthesis of d1-8β-carbomethoxy-13-oxopodocarpane, a degradation product of phyllocladene (1960) (10)
Experiments directed toward the total synthesis of terpenes. XII. Stereoselective synthesis of (+-)-deoxypodocarpic acid and (+-)-13-methoxydeoxypodocarpic acid (1968) (10)
CONVERGENT SYNTHESIS OF POLYETHER IONOPHORE ANTIBIOTICS: THE SYNTHESIS OF THE MONENSIN SPIROKETAL (1985) (10)
Total synthesis of terpenes. XX. Total synthesis of (+-)-shionone, a tetracyclic triterpene (1975) (10)
THE n-BUTYLTHIOMETHYLENE GROUPING: A SUPERIOR BLOCKING GROUP FOR THE ALKYLATION OF KETONES (1959) (9)
An Improved Procedure for the Preparation of the Dess‐Martin Periodinane. (1993) (9)
Demethylation of Methyl Aryl Ethers: 4‐Ethoxy‐3‐Hydroxybenzaldehyde (2003) (9)
Allylic Rearrangements. XLII. The Preparation and Some Reactions of 3β-Chlorocholest-4-ene and 3α-Chlorocholest-4-ene1 (1959) (9)
A method for the stereoselective introduction of angular methyl groups (1968) (9)
An Approach to the Total Synthesis of Steroids (1963) (8)
The total synthesis of (±)-hibaene☆ (1965) (8)
The facile reduction of methoxyethoxymethyl esters with lithium triethylborohydride (1980) (8)
The utility of the coupling reaction between propargyl grignard reagent and allylic halides for the synthesis of acetylenes (1970) (7)
Claisen rearrangement of N-allylketene O, N-acetals (1974) (7)
Stereochemical Control in the Ester Enolate Claisen Rearrangement. Part 1. Stereoselectivity in Silyl Ketene Acetal Formation. (1991) (7)
Acid-catalyzed cyclization of 4-(2,6,6-trimethylcyclohexenyl)-2-methylbutanal. X-ray structure analysis of the major product (1971) (6)
Experiments directed toward the total synthesis of terpenes. 23. Synthesis of 4a-methyl-4,4a,7,8-tetrahydro-9H-benzocycloheptene-2(3H),5(6H)-dione (B-homo Wieland-Miescher ketone): a versatile intermediate for terpene synthesis (1979) (6)
Studies on the total synthesis of steroidal antibiotics. 3. Generation and correlation of Tetracyclic derivatives from the degradation of fusidic acid and total synthesis. (1977) (6)
Time-course of PTSD symptoms in the Australian Defence Force: a retrospective cohort study (2015) (6)
Total synthesis of terpenes. XVI. Structure and stereochemistry of two decahydropicene derivatives (1969) (5)
Synthesis of chiral subunits for macrolide synthesis: an efficient method for converting spiroketals into open-chain derivatives (1982) (5)
A Total Synthesis of FK-506. (1997) (5)
The Synthesis and Single Crystal X-Ray Structure Determination of 9a-Cyano-19-Nortestosterone (1972) (4)
Experiments directed toward the total synthesis of terpenes. 8. The total synthesis of (+or-)-kaurene and,(+or-)-atisirene. (1966) (3)
Homogeneous Catalytic Hydrogenation: Dihydrocarvone (2003) (3)
Convenient Method for the Titration of Amide Base Solutions. (1991) (2)
THE CLAISEN REARRANGEMENT OF N-ALLYLKETENE O,N-ACETALS (1974) (2)
STUDIES ON THE TOTAL SYNTHESIS OF STEROIDAL ANTIBIOTICS. 2. TWO CONVERGENT SCHEMES FOR THE SYNTHESIS OF TETRACYCLIC INTERMEDIATES (1977) (2)
STEREOSELECTIVE GENERATION OF ESTER ENOLATES (1976) (2)
Reaction product of 3,3-dichloro-2-methylpropenal and piperidine (1973) (2)
The synthesis of the dl-9-iso-pimaradienes and the revision of the structures of isopimaric acid and rimuene (1961) (2)
A novel approach to a key intermediate in the total synthesis of α-onocerin (1961) (1)
TOTAL SYNTHESIS OF (.+-.)-APHIDICOLIN AND (.+-.)-β-CHAMIGRENE (1984) (1)
The distribution and aggregation of Chinook salmon stocks on the Oregon Shelf as indicated by the commercial catch and genetics (2011) (1)
An Approach to the Total Synthesis of Aplysiatoxin. (1988) (1)
Stereoselective Synthesis of Trisubstituted Olefins: Ethyl 4‐Methyl‐(E)‐4,8‐Nonadienoate (2003) (1)
Entering the Auto Age: The Early Automobile in North Carolina, 1900-1930 (1990) (1)
Total Synthesis of FK-506. Part 1. Construction of the C16-C34 Fragment (I). (1998) (0)
BEQUEME, STEREOSELEKTIVE SYNTH. VON 9,10-DIMETHYL-TRANS-DECALONEN-(1) DURCH PROTOLYSE VON ANKONDENSIERTEN METHOXY-CYCLOPROPANEN (1970) (0)
a Key Intermediate in the Total Synthesis of (f)-Shiononel (1975) (0)
3-Acyltetramic Acid Antibiotics. Part 3. An Approach to the Synthesis of Bu-2313. (1987) (0)
Methodology for the Enantioselective Synthesis of Aldols and Other 1,3-Dioxygenated Systems. (1990) (0)
Convergent Synthesis of Polyether Ionophore Antibiotics: Synthesis of the Spiroketal and Tricyclic Glycal Segments of Monensin. (1993) (0)
The Impedance of Solid Metal Electrodes I. Lead and Tin. (1956) (0)
STUDIES ON THE TOTAL SYNTHESIS OF STEROIDAL ANTIBIOTICS. 3. GENERATION AND CORRELATION OF TETRACYCLIC DERIVATIVES FROM THE DEGRADATION OF FUSIDIC ACID AND TOTAL SYNTHESIS (1977) (0)
A CONVERGENT SCHEME FOR THE SYNTHESIS OF SPIROKETALS AND THE SYNTHESIS OF (+)-CHALCOGRAN (1980) (0)
LEGALITY VERSUS MORALITY U.S. CORPORATIONS USING TAX HAVENS (2017) (0)
CONVERGENT SYNTHESIS OF POLYETHER IONOPHORE ANTIBIOTICS: AN APPROACH TO THE SYNTHESIS OF THE MONENSIN TETRAHYDROPYRAN-BIS(TETRAHYDROFURAN) VIA THE ESTER ENOLATE CLAISEN REARRANGEMENT AND REDUCTIVE DECARBOXYLATION (1985) (0)
EXPERIMENTS DIRECTED TOWARD THE TOTAL SYNTHESIS OF TERPENES PART 22, A POLYENE CYCLIZATION APPROACH TO TETRADECAHYDROPICENE DERIVATIVES FOR PENTACYCLIC TRITERPENE SYNTHESIS (1975) (0)
EXPERIMENTS DIRECTED TOWARD THE TOTAL SYNTHESIS OF TERPENES PART 18, THE CONVERGENT, STEREOSELECTIVE TOTAL SYNTHESIS OF THE UNSYMMETRICAL PENTACYCLIC TRITERPENE ALNUSENONE (1974) (0)
N,N‐Dimethyl‐5β‐Cholest‐3‐ene‐5‐Acetamide (2003) (0)
The concept of providence in the thought of William Ellery Channing, Ralph Waldo Emerson, Theodore Parker, and Orestes A. Brownson : a study in mid-nineteenth century American intellectual history (1972) (0)
Diels-Alder Approach to Highly Functionalized Tertiary α-Hydroxy Ketones: A Novel Route to the Hexahydrobenzofuran Portion of the Avermectins and Milbemycins. (1986) (0)
Synthetic Methodology in the Context of Natural Product Total Synthesis (1989) (0)
39.95/$59.95 hbkMichael Lwy, The War of Gods: Religion and Politics in Latin America, Verso, Oxford and Cambridge, MA (1996), p. 163.39.95/$59.95 hbkMichael Lwy, The War of Gods: Religion and Politics in Latin America 11.95/517.95 pbk, Verso, London (1996), p. 163. (1998) (0)
Renate Buser : Objects in Mirror May Be Closer Than They Appear (1999) (0)
Carboalumination of 1-Alkynes and in situ Transmetalation to Higher Order Cyanocuprates. Stereospecific Synthesis of Tri- and Disubstituted Olefins by Conjugate Addition to Enones. (1990) (0)
Total Synthesis of FK-506. Part 2. Completion of the Synthesis. (1998) (0)
A REVIEW OF RECENT ADVANCES IN THE CHEMISTRY OF THE DITERPENOID ALKALOID ATISINE. (1963) (0)
Approach to the Total Synthesis of Chlorothricolide: Synthesis of (±)-19,20-Dihy- dro-24-O-methylchlorothricolide, Methyl Ester, Ethyl Carbonate. (1986) (0)
THE REACTION PRODUCT OF 3,3-DICHLORO-2-METHYL-PROPENAL AND PIPERIDINE (1973) (0)
t‐Butyl Cyanoacetate (2003) (0)
3-Acyltetramic Acid Antibiotics. Part 2. Synthesis of (+)-Streptolic Acid. (1988) (0)
EXPERIMENTS DIRECTED TOWARD THE TOTAL SYNTHESIS OF TERPENES PART 20, TOTAL SYNTHESIS OF (+-)-SHIONONE, A TETRACYCLIC TRITERPENE (1975) (0)
EXPERIMENTS DIRECTED TOWARD THE TOTAL SYNTHESIS OF TERPENES PART 19, SYNTHESIS OF 8-METHOXY-4A BETA,10B BETA,12A ALPHA-TRIMETHYL-3,4,4A,4B ALPHA,5,6,10B,11,12A-DECAHYDROCHRYSEN-1(2H)-ONE, A KEY INTERMEDIATE IN THE TOTAL SYNTHESIS OF ( (1975) (0)
THE TOTAL SYNTHESIS OF (.+-.)-FRIEDELIN, AN UNSYMMETRICAL PENTACYCLIC TRITERPENE (1976) (0)
The total synthesis of dl-rimuene (1964) (0)
The metaphysical realism of E.L. Mascall and Anglican doctrine (2010) (0)
5β‐Cholest‐3‐ene‐5‐Acetaldehyde (2003) (0)
A Highly Convergent Synthesis of Mexiprostil: 16(R) 16-Methoxy 16-Methyl PGE1 Methyl Ester (I). (1989) (0)
Occurrence, radioactivity, and diversity of Winnipeg River benthic organisms in the vicinity of Whiteshell Nuclear Research Establishment (1973) (0)
Reductive Cleavage of Vinyl Phosphorodiamidates: 17β‐tert‐Butoxy‐Gα‐androst‐2‐ene (2003) (0)
Ethyl 5β‐Cholest‐3‐ene‐5‐Acetate (2003) (0)
The Convergent Synthesis of Polyether Ionophore Antibiotics: The Synthesis of the A Ring Carbamonensin Spiro Ether. (1988) (0)
SYNTHESIS OF CHIRAL SUBUNITS FOR MACROLIDE SYNTHESIS: AN EFFICIENT METHOD FOR CONVERTING SPIROKETALS INTO OPEN‐CHAIN DERIVATIVES (1983) (0)
Convergent Synthesis of Polyether Ionophore Antibiotics: Protective Manipulation and Synthesis of Monensin A. (1993) (0)
TOTAL SYNTHESIS OF (+) AND (-) NONACTIC ACIDS FROM CARBOHYDRATES (1981) (0)
PHEROMONE SYNTHESES - MODEL REACTIONS FOR THE SYNTHESIS OF POLYETHER ANTIBIOTICS (1981) (0)
Stereochemical Control in the Ester Enolate Claisen Rearrangement. Part 2. Chairlike vs Boatlike Transition-State Selection. (1991) (0)
CONVERGENT SYNTHESIS OF POLYETHER IONOPHORE ANTIBIOTICS: THE SYNTHESIS OF THE MONENSIN BIS(TETRAHYDROFURAN) VIA THE CLAISEN REARRANGEMENT OF AN ESTER ENOLATE WITH A β-LEAVING GROUP (1985) (0)
Seven Sure Steps to Solid, Successful, Gifted Education. (1983) (0)

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What Schools Are Affiliated With Robert Emerson Ireland?

Robert Emerson Ireland is affiliated with the following schools:

California Institute of Technology
University of Michigan
University of Virginia