Robert H. Crabtree
#31,573
Most Influential Person Now
Inorganic chemist
Robert H. Crabtree's AcademicInfluence.com Rankings
Robert H. Crabtreechemistry Degrees
Chemistry
#333
World Rank
#643
Historical Rank
Inorganic Chemistry
#16
World Rank
#16
Historical Rank
Download Badge
Chemistry
Why Is Robert H. Crabtree Influential?
(Suggest an Edit or Addition)According to Wikipedia, Robert Howard Crabtree is a British-American chemist. He is serving as Conkey P. Whitehead Professor Emeritus of Chemistry at Yale University in the United States. He is a naturalized citizen of the United States. Crabtree is particularly known for his work on "Crabtree's catalyst" for hydrogenations, and his textbook on organometallic chemistry.
Robert H. Crabtree's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The organometallic chemistry of the transition metals (1992) (1436)
- Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis. (2010) (1195)
- Definition of the hydrogen bond (IUPAC Recommendations 2011) (2011) (1126)
- Recent homogeneous catalytic applications of chelate and pincer N-heterocyclic carbenes (2004) (926)
- Molecular Catalysts for Water Oxidation. (2015) (754)
- The organometallic chemistry of alkanes (1985) (735)
- Defining the hydrogen bond: An account (IUPAC Technical Report) (2011) (710)
- Aspects of Methane Chemistry (1995) (575)
- A functional model for O-O bond formation by the O2-evolving complex in photosystem II. (1999) (571)
- Iridium compounds in catalysis (1979) (540)
- Redox-active ligands in catalysis. (2013) (526)
- Comprehensive organometallic chemistry III (2007) (494)
- Resolving heterogeneity problems and impurity artifacts in operationally homogeneous transition metal catalysts. (2012) (489)
- Highly active and robust Cp* iridium complexes for catalytic water oxidation. (2009) (486)
- A new intermolecular interaction: unconventional hydrogen bonds with element-hydride bonds as proton acceptor. (1996) (462)
- Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect (2001) (456)
- Half-sandwich iridium complexes for homogeneous water-oxidation catalysis. (2010) (452)
- Abnormal, mesoionic and remote N-heterocyclic carbene complexes (2013) (421)
- Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics (2003) (397)
- The Organometallic Chemistry of the Transition Metals: Crabtree/The Organometallic Chemistry (2005) (390)
- Transition Metal Complexation of σ Bonds (1993) (388)
- Study of the N−H···H−B Dihydrogen Bond Including the Crystal Structure of BH3NH3 by Neutron Diffraction (1999) (388)
- Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst (2006) (368)
- Organometallic alkane CH activation (2004) (362)
- Functional Models for the Oxygen-Evolving Complex of Photosystem II. (2008) (348)
- Secondary coordination sphere interactions facilitate the insertion step in an iridium(III) CO2 reduction catalyst. (2011) (339)
- Homogeneous Transition Metal Catalysis of Acceptorless Dehydrogenative Alcohol Oxidation: Applications in Hydrogen Storage and to Heterocycle Synthesis. (2017) (315)
- Unconventional Hydrogen Bonds: Intermolecular B-H.cntdot..cntdot..cntdot.H-N Interactions (1995) (312)
- NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis (2005) (312)
- Light-driven water oxidation for solar fuels. (2012) (311)
- A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalyst (2001) (302)
- Hydrogen storage in liquid organic heterocycles (2008) (295)
- Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β-Alkylation of Alcohols, and N-Alkylation of Amines (2009) (293)
- Dibenzo[a,e]cyclooctatetraene in a proposed test for heterogeneity in catalysts formed from soluble platinum-group metal complexes (1983) (293)
- Palladium Complexes with Tridentate Pincer Bis-Carbene Ligands as Efficient Catalysts for C−C Coupling (2002) (271)
- Distinguishing homogeneous from heterogeneous catalysis in electrode-driven water oxidation with molecular iridium complexes. (2011) (265)
- Characterization of the O(2)-evolving reaction catalyzed by [(terpy)(H2O)Mn(III)(O)2Mn(IV)(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2"-terpyridine). (2001) (262)
- Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex. (2001) (258)
- Rh-catalyzed oxidative coupling between primary and secondary benzamides and alkynes: synthesis of polycyclic amides. (2010) (256)
- Iridium-catalyzed hydrogenation of N-heterocyclic compounds under mild conditions by an outer-sphere pathway. (2011) (245)
- Cationic iridium diolefin complexes as alkene hydrogenation catalysts and the isolation of some related hydrido complexes (1977) (243)
- Hydrogen Bonding in Anion Recognition: A Family of Versatile, Nonpreorganized Neutral and Acyclic Receptors. (1999) (241)
- Recent Advances in C–F Bond Activation (1997) (239)
- Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2). (2002) (235)
- A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst (2011) (234)
- Dihydrogen complexes: some structural and chemical studies (1990) (234)
- Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure. (2015) (233)
- Chelated Iridium(III) Bis-carbene Complexes as Air-Stable Catalysts for Transfer Hydrogenation (2002) (231)
- A molecular catalyst for water oxidation that binds to metal oxide surfaces (2015) (227)
- Abnormal C5-Bound N-Heterocyclic Carbenes: Extremely Strong Electron Donor Ligands and Their Iridium(I) and Iridium(III) Complexes (2004) (222)
- Directing effects in homogeneous hydrogenation with [Ir(cod)(PCy3)(py)]PF6 (1986) (222)
- Metal–Ligand Multiple Bonds (2005) (218)
- Manganese Oxyl Radical Intermediates and O−O Bond Formation in Photosynthetic Oxygen Evolution and a Proposed Role for the Calcium Cofactor in Photosystem II (1999) (215)
- Tridentate Carbene CCC and CNC Pincer Palladium(II) Complexes: Structure, Fluxionality, and Catalytic Activity (2001) (211)
- Mechanism of C−H Activation by Diiron Methane Monooxygenases: Quantum Chemical Studies (1997) (201)
- Synergistic effect between anatase and rutile TiO2 nanoparticles in dye-sensitized solar cells. (2009) (200)
- Introduction to selective functionalization of C-H bonds. (2010) (199)
- An NMR method for distinguishing classical from nonclassical structures in transition metal polyhydrides (1988) (197)
- Palladium-catalyzed decarboxylative coupling of aromatic acids with aryl halides or unactivated arenes using microwave heating. (2008) (196)
- Comparison of primary oxidants for water-oxidation catalysis. (2013) (194)
- New ruthenium(II) CNC-pincer bis(carbene) complexes: Synthesis and catalytic activity (2003) (192)
- Pd(II) catalyzed acetoxylation of arenes with iodosyl acetate (1996) (191)
- A New Type of Hydrogen Bond (1998) (189)
- Computed ligand electronic parameters from quantum chemistry and their relation to Tolman parameters, Lever parameters, and Hammett constants. (2001) (185)
- Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors (2011) (184)
- Intramolecular alkyne hydroalkoxylation and hydroamination catalyzed by iridium hydrides. (2005) (184)
- Interactions between CH and NH bonds and d8 square planar metal complexes: hydrogen bonded or agostic? (1997) (183)
- A READILY AVAILABLE NON-PREORGANIZED NEUTRAL ACYCLIC HALIDE RECEPTOR WITH AN UNUSUAL NONPLANAR BINDING CONFORMATION (1997) (180)
- Multifunctional ligands in transition metal catalysis (2011) (179)
- Introduction: CH Activation. (2017) (178)
- Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications. (2007) (176)
- Iridium complexes in alkane dehydrogenation (1979) (172)
- Efficient selective and atom economic catalytic conversion of glycerol to lactic acid (2014) (172)
- Selective catalytic dehydrogenation of alkanes to alkenes (1987) (169)
- Key factors in pincer ligand design. (2018) (168)
- Precursor transformation during molecular oxidation catalysis with organometallic iridium complexes. (2013) (168)
- Influence of the ligand field on slow magnetization relaxation versus spin crossover in mononuclear cobalt complexes. (2013) (165)
- Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes (2011) (160)
- ALKANE DEHYDROGENATION BY IRIDIUM COMPLEXES (2002) (158)
- Disubstituted imidazolium-2-carboxylates as efficient precursors to N-heterocyclic carbene complexes of Rh, Ru, Ir, and Pd. (2005) (154)
- Factors Affecting the Strength of N-H.cntdot..cntdot..cntdot.H-Ir Hydrogen Bonds (1995) (153)
- Reactivity differences in the syntheses of chelating N-heterocyclic carbene complexes of rhodium are ascribed to ligand anisotropy (2004) (153)
- HIGH-VALENT OXOMANGANESE CLUSTERS : STRUCTURAL AND MECHANISTIC WORK RELEVANT TO THE OXYGEN-EVOLVING CENTER IN PHOTOSYSTEM II (1995) (152)
- Applications to Organic Synthesis (2005) (147)
- Dihydrido Olefin and Solvento Complexes of Iridium and the Mechanisms of Olefin Hydrogenation and Alkane Dehydrogenation (1982) (147)
- Transfer Hydrogenation of Imines and Alkenes and Direct Reductive Amination of Aldehydes Catalyzed by Triazole-Derived Iridium(I) Carbene Complexes (2007) (147)
- Unusual activity and selectivity in alkyne hydrosilylation with an iridium catalyst stabilized by an O-donor ligand (1990) (146)
- An Unusual Type of H.cntdot..cntdot..cntdot.H Interaction: Ir-H.cntdot..cntdot..cntdot.H-O and Ir-H.cntdot..cntdot..cntdot.H-N Hydrogen Bonding and Its Involvement in .sigma.-Bond Metathesis (1994) (144)
- Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines. (2002) (144)
- Homogeneous catalysis of silane alcoholysis via nucleophilic attack by the alcohol on an Ir(.eta.2-HSiR3) intermediate catalyzed by [IrH2S2(PPh3)2]SbF6 (S = solvent) (1989) (143)
- Acetylacetonate anchors for robust functionalization of TiO2 nanoparticles with Mn(II)-terpyridine complexes. (2008) (141)
- Oxygen evolution catalysis by a dimanganese complex and its relation to photosynthetic water oxidation. (2008) (140)
- Particle formation during oxidation catalysis with Cp* iridium complexes. (2012) (135)
- Transition-metal polyhydride complexes (1985) (134)
- Computational structure-activity relationships in H2 storage: how placement of N atoms affects release temperatures in organic liquid storage materials. (2007) (133)
- Reduction of Systematic Uncertainty in DFT Redox Potentials of Transition-Metal Complexes (2012) (133)
- Hydrogen Transfer Reduction of Aldehydes with Alkali-Metal Carbonates and Iridium NHC Complexes (2004) (131)
- An Organometallic Future in Green and Energy Chemistry (2011) (131)
- "Recent Developments in the Organometallic Chemistry of N -Heterocyclic Carbenes" (2007) (130)
- An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2. (2005) (127)
- Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study (2008) (126)
- Some molecular hydrogen complexes of iridium (1986) (125)
- Coordination chemistry of halocarbons (1990) (124)
- An Unconventional Intermolecular Three‐Center N–H …︁ H2Re Hydrogen Bond in Crystalline [ReH5(PPh3)3]·indole·C6H6 (1995) (123)
- Outer sphere hydrogenation catalysis (2013) (120)
- Some diolefin complexes of iridium(I) and a trans-influence series for the complexes [IrCl(cod)L] (1977) (119)
- Aldehyde Decarbonylation Catalysis under Mild Conditions (1999) (119)
- Anchoring groups for photocatalytic water oxidation on metal oxide surfaces. (2017) (116)
- An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst (2011) (114)
- Iridium-based complexes for water oxidation. (2015) (114)
- Control of slippage and conformation in indenyl complexes (1985) (113)
- Dihydridoiridium diolefin complexes as intermediates in homogeneous hydrogenation (1979) (111)
- Methanol dehydrogenation by iridium N-heterocyclic carbene complexes. (2015) (111)
- Mechanism for photosynthetic O2 evolution. (1986) (110)
- Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand (2017) (109)
- Binding modes of carboxylate- and acetylacetonate-linked chromophores to homodisperse polyoxotitanate nanoclusters. (2012) (109)
- Bis-carbene complexes from oxidative addition of imidazolium C–H bonds to palladium(0) (2002) (108)
- H-H, C-H, and Related Sigma-Bonded Groups as Ligands (1988) (108)
- Ultrafast photodriven intramolecular electron transfer from an iridium-based water-oxidation catalyst to perylene diimide derivatives (2012) (106)
- Occurrence and origin of a pronounced directing effect of a hydroxyl group in hydrogenation with [Ir(cod)P(C6H11)3(py)]PF6 (1983) (105)
- Catalysed low temperature H2 release from nitrogen heterocycles (2006) (104)
- Interplay of Linker, N-Substituent, and Counterion Effects in the Formation and Geometrical Distortion of N-Heterocyclic Biscarbene Complexes of Rhodium(I) (2006) (103)
- Di‐μ‐Chloro‐Bis(η4‐1,5‐Cyclooctadiene)‐Dirhodium(I) (2007) (103)
- Inter- vs. intramolecular C-H activation: a C-H-Ir bridge in [IrH2(8-methylquinoline)L2]BF4 and a C-H+M→C-M-H reaction trajectory (1985) (102)
- Dehydrogenative silation, isomerization and the control of syn- vs. anti-addition in the hydrosilation of alkynes (1993) (102)
- Dimer-of-dimers model for the oxygen-evolving complex of photosystem II. Synthesis and properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6. (2004) (100)
- Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides (2009) (99)
- C-H oxidation by platinum group metal oxo or peroxo species. (2011) (98)
- O2 Evolution and Permanganate Formation from High-Valent Manganese Complexes (1997) (98)
- A Possible Mechanism (2016) (97)
- Hydroxamate anchors for water-stable attachment to TiO2 nanoparticles (2009) (97)
- Hydroxamate anchors for improved photoconversion in dye-sensitized solar cells. (2013) (96)
- Mechanism of H-H Activation by Nickel-Iron Hydrogenase (1998) (96)
- An Experimental−Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation (2010) (96)
- Introduction and History (2011) (95)
- Electrochemical activation of Cp* iridium complexes for electrode-driven water-oxidation catalysis. (2014) (94)
- Axially Chiral Bidentate N-Heterocyclic Carbene Ligands Derived from BINAM: Rhodium and Iridium Complexes in Asymmetric Ketone Hydrosilylation (2005) (94)
- Inter- vs. intramolecular carbon-hydrogen activation: a carbon-hydrogen-iridium bridge in [IrH2(mq)L2]BF4 and a CH + M .fwdarw. CMH reaction trajectory (1985) (94)
- Green alcohol couplings without transition metal catalysts: base-mediated β-alkylation of alcohols in aerobic conditions (2010) (94)
- Water-stable, hydroxamate anchors for functionalization of TiO2 surfaces with ultrafast interfacial electron transfer (2010) (93)
- Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry. (2010) (93)
- Definition of the Hydrogen Bond (2010) (89)
- Dihydrogen Complexation. (2016) (89)
- A mechanism from quantum chemical studies for methane formation in methanogenesis. (2002) (88)
- A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium (2008) (87)
- Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups (2013) (87)
- Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways. (2010) (85)
- Preferential C-binding versus N-binding in imidazole depends on the metal fragment involved. (2002) (82)
- Homogeneous water oxidation by a di-μ-oxo dimanganese complex in the presence of Ce4+ (2007) (82)
- Transfer hydrogenation reduction of ketones, aldehydes and imines using chelated iridium(III) N-heterocyclic bis-carbene complexes (2004) (82)
- Sodium periodate as a primary oxidant for water-oxidation catalysts. (2012) (82)
- Speciation of the catalytic oxygen evolution system: [MnIII/IV2(mu-O)2(terpy)2(H2O)2](NO3)3 + HSO5-. (2007) (82)
- SELECTIVE STOICHIOMETRIC AND CATALYTIC CARBON-HYDROGEN BOND CLEAVAGE REACTIONS IN HYDROCARBONS BY IRIDIUM COMPLEXES (1984) (81)
- A rational basis for the axial ligand effect in C-H oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH-, O2-) from a DFT study. (2008) (77)
- Proton-coupled electron transfer in [(bpy)2Mn(O)2Mn(bpy)2]3+ (1989) (77)
- Classical (M = osmium) and nonclassical (M = iron, ruthenium) polyhydride structures for the complexes MH4(PR3)3 (1986) (76)
- Inverse design and synthesis of acac-coumarin anchors for robust TiO2 sensitization. (2011) (76)
- Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study (2012) (76)
- General synthesis of di-mu-oxo dimanganese complexes as functional models for the oxygen evolving complex of photosystem II. (2005) (76)
- A structural analysis of the semibridging carbonyl (1986) (75)
- A tridentate Ni pincer for aqueous electrocatalytic hydrogen production (2012) (74)
- Organometallic Ni pincer complexes for the electrocatalytic production of hydrogen. (2012) (74)
- Hydrogen-Transfer Catalysis with Cp*IrIII Complexes: The Influence of the Ancillary Ligands (2014) (74)
- C-C bond cleavage in hydrocarbons by iridium complexes (1986) (73)
- Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn sub 3 O sub 4 sup 4+ and Mn sub 2 O sub 2 sup 3+ complexes (1990) (72)
- Nitrogen Fixation by Nitrogenases: A Quantum Chemical Study (1998) (72)
- An N-heterocyclic carbene/iridium hydride complex from the oxidative addition of a ferrocenyl-bisimidazolium salt: implications for synthesis. (2005) (71)
- Alcohol cross-coupling reactions catalyzed by Ru and Ir terpyridine complexes. (2008) (71)
- Modeling the Solvent Sphere: Mechanism of the Shilov Reaction (1996) (71)
- Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity. (2008) (70)
- Ultrafast Photooxidation of Mn(II)−Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles (2007) (70)
- Nitrogen-Containing Liquid Organic Hydrogen Carriers: Progress and Prospects (2017) (69)
- A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis. (2017) (67)
- Deposition of an oxomanganese water oxidation catalyst on TiO2 nanoparticles: computational modeling, assembly and characterization (2009) (66)
- Outer Sphere Anion Participation Can Modify the Mechanism for Conformer Interconversion in Pd Pincer Complexes (2003) (66)
- Bioinspired High-Potential Porphyrin Photoanodes (2012) (65)
- High turnover remote catalytic oxygenation of alkyl groups: how steric exclusion of unbound substrate contributes to high molecular recognition selectivity. (2008) (65)
- A Three-Center Hydrogen Bond in 2,6-Diphenylpyridinium Tetrachloroaurate (1995) (65)
- Facile reversible metalation in an agostic complex and hydrogenolysis of a metal aryl complex via a dihydrogen complex (1992) (64)
- Comparison of amorphous iridium water-oxidation electrocatalysts prepared from soluble precursors. (2012) (64)
- Complexation of an amide to iridium via an iminol tautomer and evidence Ir–H ⋯ H–O hydrogen bond (1994) (63)
- Selective stoichiometric and catalytic C−H bond cleavage reactions in hydrocarbons by iridium complexes (1984) (62)
- Distinct mechanisms of bridging-oxo exchange in di-mu-O dimanganese complexes with and without water-binding sites: implications for water binding in the O(2)-evolving complex of photosystem II. (2007) (62)
- Metalation-resistant ligands: some properties of dibenzocyclooctatetraene complexes of molybdenum, rhodium and iridium (1983) (62)
- Defining the hydrogen bond: an account (2011) (61)
- Catalyst Activation by Loss of Cyclopentadienyl Ligands in Hydrogen Transfer Catalysis with Cp*IrIII Complexes (2014) (61)
- Selective partial reduction of quinolines: Hydrosilylation vs. transfer hydrogenation (2008) (61)
- Deprotonated thioamides as thiolate S-donor ligands with a high tendency to avoid M-S-M bridge formation: crystal and molecular structure of bis(2-hydroxy-5-methylacetophenone N,N-dimethylthiosemicarbazonato)dinickel (1993) (61)
- Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor (2016) (60)
- Homogeneous tungsten, rhenium, and iridium catalysts in alkane dehydrogenation driven by reflux of substrate or of cosolvent or by inert-gas flow (1993) (60)
- Interfacial electron transfer into functionalized crystalline polyoxotitanate nanoclusters. (2012) (59)
- Rapid screening and combinatorial methods in homogeneous organometallic catalysis (2001) (59)
- Water oxidation catalyzed by the tetranuclear Mn complex [Mn(IV)4O5(terpy)4(H2O)2](ClO4)6. (2012) (59)
- The preparation and some catalytic properties of a number of rhodium(I) diolefin complexes (1977) (59)
- Characterization of an amorphous iridium water-oxidation catalyst electrodeposited from organometallic precursors. (2013) (58)
- Energy production and storage : inorganic chemical strategies for a warming world (2010) (58)
- Mineralization of Chlorofluorocarbons and Aromatization of Saturated Fluorocarbons by a Convenient Thermal Process (1996) (58)
- NEW TYPES OF HYDROGEN BONDS (1998) (57)
- Towards a functional model of hydrogenase: electrocatalytic reduction of protons to dihydrogen by a nickel macrocyclic complex (1992) (56)
- Combinatorial and rapid screening approaches to homogeneous catalyst discovery and optimization (1999) (56)
- High-frequency EPR study of a new mononuclear manganese(III) complex:. [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-terpyridine). (2001) (56)
- Double geminal C-H activation and reversible alpha-elimination in 2-aminopyridine iridium(III) complexes: the role of hydrides and solvent in flattening the free energy surface. (2004) (56)
- Thermal and photochemical catalytic dehydrogenation of alkanes with [IrH2(CF3CO2)(PR3)2](R = C6H4F-p and cyclohexyl) (1985) (56)
- Selective conversion of glycerol to lactic acid with iron pincer precatalysts. (2015) (56)
- Efficiency of Interfacial Electron Transfer from Zn-Porphyrin Dyes into TiO2 Correlated to the Linker Single Molecule Conductance (2013) (55)
- REACTIVE DYES AS A METHOD FOR RAPID SCREENING OF HOMOGENEOUS CATALYSTS (1998) (55)
- Solvento complexes of tungsten, rhenium, osmium, and iridium and the X-ray crystal structure of [IrH2(Me2CO)2(PPh3)2]BF4 (1984) (55)
- Hypervalency, secondary bonding and hydrogen bonding: siblings under the skin. (2017) (55)
- Redox-active cyclopentadienyl Ni complexes with quinoid N-heterocyclic carbene ligands for the electrocatalytic hydrogen release from chemical fuels (2013) (55)
- Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox properties. (2002) (54)
- Photoelectrochemical hole injection revealed in polyoxotitanate nanocrystals functionalized with organic adsorbates. (2014) (54)
- Reversible visible-light photooxidation of an oxomanganese water-oxidation catalyst covalently anchored to TiO2 nanoparticles. (2010) (53)
- A Quantum Chemical Study of the Mechanism of Tyrosinase (1999) (53)
- Counter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2 (2002) (53)
- Electronic and Steric Effects in the Insertion of Alkynes into an Iridium(III) Hydride (2005) (52)
- Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles (2013) (52)
- Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-ray Scattering and EXAFS Spectroscopy. (2016) (52)
- Geometrically Distorted and Redox-Active Organometallic Iridium Complexes Containing Biphenyl-2,2'-diyl (1995) (52)
- Electrocatalytic Nitrogen Fixation for Distributed Fertilizer Production (2016) (51)
- The rebound mechanism in catalytic C-H oxidation by MnO(tpp)Cl from DFT studies: electronic nature of the active species. (2008) (51)
- Facile homogeneous hydrogenations of hindered olefins with [Ir(cod)py(PCy3)]PF6 (1981) (50)
- Unexpected oxidative C-C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes. (2004) (50)
- Bending of the reduced porphyrin of factor F430 can accommodate a trigonal-bipyramidal geometry at nickel: a conformational analysis of this nickel-containing tetrapyrrole, in relation to archaebacterial methanogenesis (1990) (50)
- Modes of activation of organometallic iridium complexes for catalytic water and C-H oxidation. (2014) (50)
- An Efficient Synthesis of [Ir(cod)Cl]2 and Its Reaction with PMe2Ph to Give FAC-[IrH(PMe2C6H4)(PMe2Ph)3] (1982) (50)
- Cp* Iridium Precatalysts for Selective C- H Oxidation with Sodium Periodate As the Terminal Oxidant (2013) (50)
- Solution equilibrium between classical and nonclassical polyhydride tautomers [ReH4(CO)L3]+ and [ReH2(.eta.2-H2)(CO)L3]+ (L = PMe2Ph). Equilibrium isotope effects and an intermediate trihydrogen complex in intramolecular site exchange of dihydrogen and hydride ligands (1990) (50)
- Silane alcoholysis by a nickel(II) complex in a N, O, S ligand environment (1992) (49)
- Oxidative functionalization of benzylic C–H bonds by DDQ (2012) (49)
- [(H2O)(terpy)Mn(mu-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2':6,2''-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltammetry. (2010) (48)
- Substitution of a hydroxamic acid anchor into the MK-2 dye for enhanced photovoltaic performance and water stability in a DSSC. (2014) (48)
- Mechanism of methane monooxygenase – a structural and quantum chemical perspective (1998) (48)
- A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(III) and dirhodium(II) complexes. (2007) (48)
- Probing the mechanism of water oxidation in photosystem II (1991) (48)
- Selective Ion Pairing in [Ir(bipy)H2(PRPh2)2]A (A = PF6, BF4, CF3SO3, BPh4, R = Me, Ph): Experimental Identification and Theoretical Understanding (2001) (47)
- Iridium catalyzed reversible dehydrogenation – Hydrogenation of quinoline derivatives under mild conditions (2015) (47)
- Functional Modeling of Ni,Fe Hydrogenases: A Nickel Complex in an N,O,S Environment. (1991) (47)
- Carbenes. Pincers, chelates, and abnormal binding modes (2003) (47)
- Heterolytic dihydrogen activation in an iridium complex with a pendant basic group (1999) (47)
- Thiocyanate linkage isomerism in a ruthenium polypyridyl complex. (2011) (47)
- A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides (2010) (46)
- Prehistory of the Southwestern Area (1986) (46)
- Reversible α-elimination in the conversion of N–CH3 to N–CHIr by double C–H activation (2001) (45)
- Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis† (2010) (45)
- DDQ as an electrocatalyst for amine dehydrogenation, a model system for virtual hydrogen storage (2011) (45)
- Hydrogen transfer in the presence of amino acid radicals (1997) (45)
- Proton-coupled electron transfer in high-valent oxomanganese dimers: role of the ancillary ligands (1991) (45)
- Modeling the oxygen-evolving center of photosystem II: synthesis and characterization of a tetranuclear manganese carboxylate complex (1988) (44)
- Making mercury-photosensitized dehydrodimerization into an organic synthetic method. Vapor-pressure selectivity and the behavior of functionalized substrates (1989) (44)
- Dihydrogen complexes in catalysis : isotope exchange reactions (1991) (43)
- Anion-exchange-triggered 1,3-shift of an NH proton to iridium in protic n-heterocyclic carbenes: hydrogen-bonding and ion-pairing effects. (2010) (43)
- Thermal and photochemical carbon-hydrogen bond reactions of alkenes in (tris(pyrazolyl)borato)iridium(I) complexes (1989) (42)
- New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygen-evolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn(IV). (2005) (42)
- Aminoferrocene Derivatives in Chloride Recognition and Electrochemical Sensing. (1999) (41)
- Dihydrogen binding in hydrogenase and nitrogenase (1986) (41)
- A high-valent oxomanganese dimer containing bridging and terminal inorganic phosphate ligands (1991) (41)
- PHOTOINDUCED CATALYTIC DEFLUORINATION OF PERFLUOROALKANES TO GIVE PERFLUOROALKENES (1996) (40)
- Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution. (2013) (40)
- Ion pairing effects in intramolecular heterolytic H2 activation in an Ir(III) complex: a combined theoretical/experimental study (2003) (40)
- Tuning redox potentials of bis(imino)pyridine cobalt complexes: an experimental and theoretical study involving solvent and ligand effects. (2012) (40)
- New routes to carbene complexes for thermally and oxidatively robust homogeneous catalysts (2002) (40)
- Selective catalytic oxidation of sugar alcohols to lactic acid (2015) (40)
- Stabilization of iridium(I), -(III), and -(V) in an oxygen-donor ligand environment and the selective dehydrogenative silylation and hydrosilylation of ethylene with {C(Ph2P:O)3}Ir(ol)2 (1991) (40)
- AN M-H...H-C HYDROGEN BONDING INTERACTION (1996) (39)
- Stable Iridium(IV) Complexes of an Oxidation-Resistant Pyridine-Alkoxide Ligand: Highly Divergent Redox Properties Depending on the Isomeric Form Adopted. (2015) (38)
- Arene and cyclohexadienyl complexes as intermediates in the selective catalytic dehydrogenation of cyclohexenes to arenes (1985) (37)
- Binding and activation of halocarbons by iron(II) and ruthenium(II) (1990) (37)
- A carbene-rich but carbonyl-poor [Ir6 (IMe)8 (CO)2 H14 ](2+) polyhydride cluster as a deactivation product from catalytic glycerol dehydrogenation. (2014) (37)
- Iridium complexes of some halocarbons and the crystal and molecular structure of cis,trans-[IrH2(o-C6H4I2)(PPh3)2]BF4 (1982) (37)
- Aliphatic versus aromatic carbon-hydrogen activation and the x-ray crystal structure of [IrH(H2O)(7,8-benzoquinolinato)(PPh3)2]SbF6 (1989) (36)
- C-H oxidation by hydroxo manganese(v) porphyrins: a DFT study. (2009) (36)
- A New Oxidation State for Pd? (2002) (36)
- The basic strengths of some dinitrogen complexes of molybdenum(0), tungsten(0), rhenium(I), and osmium(II) (1973) (35)
- Cycloiridation of α,β-unsaturated ketones, esters, and acetophenone (2005) (34)
- Recent advances in hydrogen bonding studies involving metal hydrides (1998) (34)
- Catalytic head-to-head alkyne dimerization to give Z-enynes. (1992) (34)
- Intramolecular Oxygen Transfer from Nitro Groups to C⋮C Bonds Mediated by Iridium Hydrides (2005) (34)
- Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst. (1991) (34)
- The origin of the directing effect in hydrogen addition to square-planar d8 complexes (1988) (34)
- Control of Olefin Hydroarylation Catalysis via a Sterically and Electronically Flexible Platinum(II) Catalyst Scaffold (2013) (34)
- Coordination chemistry of methyl iodide (1987) (33)
- Bidodecahedral coordination geometry in a dimolybdenum tetrahydride containing three fluoride bridges: crystal and molecular structure of .mu.-trifluoro-bis[tris(methyldiphenylphosphine)dihydromolybdenum] tetrafluoroborate ([((PMePh2)3H2Mo)2(.mu.-F)3]BF4) (1983) (33)
- Synthesis and electrochemistry of a series of cyclopentadienyl Ni N-heterocyclic carbene compounds (2013) (32)
- Electronic effects on the orientation of hydrogen addition to an iridium(I) complex (1983) (32)
- EFFECTS OF A NONLIGATING PENDANT HYDROGEN-BONDING GROUP IN A METAL COMPLEX: STABILIZATION OF AN HF COMPLEX (1999) (32)
- Manganese catalysts with molecular recognition functionality for selective alkene epoxidation. (2009) (31)
- Chelation of a carbon-fluorine bond to iridium in an 8-fluoroquinoline complex (1987) (31)
- Redox Activity of Oxo-Bridged Iridium Dimers in an N,O-Donor Environment: Characterization of Remarkably Stable Ir(IV,V) Complexes. (2017) (31)
- Water-Nucleophilic Attack Mechanism for the CuII(pyalk)2 Water-Oxidation Catalyst (2018) (31)
- An η1-Aldehyde Complex and the Role of Hydrogen Bonding in Its Conversion to an η1-Imine Complex (1996) (31)
- Alkane functionalization on a preparative scale by mercury-photosensitized cross-dehydrodimerization (1989) (31)
- Some Molecular Hydrogen Complexes of Iridium. (1986) (31)
- Interplay of Weak Interactions: An Iridium(III) System with an Agostic tert-Butyl but a Nonagostic Isopropyl Group (2002) (31)
- Some chelating C-donor ligands in hydrogen transfer and related catalysis (2006) (30)
- Stoichiometric C−C Coupling Reactions in the Coordination Sphere of an Iridium(III) Alkyl (2004) (30)
- Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of CO and CN functionalities including esters, amides and heteroarenes (2014) (30)
- Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction. (2017) (30)
- Synthesis and structural studies of some new rhenium phosphine heptahydride complexes. Evidence for classical structures in solution (1990) (29)
- Mercury-photosensitized sulfination, hydrosulfination, and carbonylation of hydrocarbons: alkane and alkene conversion to sulfonic acids, ketones, and aldehydes (1991) (29)
- Chemistry: Clipping the carbon–carbon bond (2000) (29)
- Redox reactions via outer sphere charge transfer complexation: the interaction of ferrocenes with σ- and π-type acceptors (2004) (29)
- Fuel selection for a regenerative organic fuel cell/flow battery: thermodynamic considerations (2012) (29)
- Domain structure for an amorphous iridium-oxide water-oxidation catalyst characterized by X-ray pair distribution function analysis. (2014) (29)
- The Stability of Organometallic Ligands in Oxidation Catalysis (2014) (28)
- Oxidative versus reductive additions: A 13C NMR study of H2, HX (X = Cl, Br, OR I), and Cl2 additions to some iridium(I) complexes (1980) (28)
- Ring slip in associative reactions of some indenyl- and phenylcyclopentadienyliridium complexes (1989) (28)
- High Oxidation State Iridium Mono-μ-oxo Dimers Related to Water Oxidation Catalysis. (2016) (28)
- Redox-active organometallic Ir complexes containing biphenyl-2,2′-diyl (1993) (28)
- Creating Ligands with Multiple Personalities (2010) (27)
- A Structural Analysis of the Semibridging Carbonyl. (1986) (27)
- Haptotropic rearrangements and carbon-hydrogen bond activation in indan, indenyl, and naphthalene complexes of iridium (1984) (27)
- Optimization of Photoanodes for Photocatalytic Water Oxidation by Combining a Heterogenized Iridium Water-Oxidation Catalyst with a High-Potential Porphyrin Photosensitizer. (2017) (27)
- Selective alkane C–C bond cleavage via prior dehydrogenation by a transition metal complex (1984) (27)
- A multifrequency high-field EPR (9–285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes (2006) (27)
- An unusual example of multiple proton-coupled electron transfers in a high-valent oxomanganese dimer, [(phen)2MnIII(O)2MnIV(phen)2](ClO4)3 (phen = 1,10-phenanthroline) (1992) (27)
- Strongly Coupled Phenazine-Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage. (2019) (27)
- C–H and H–H bond activation; dissociative vs. nondissociative binding to iridium (1985) (27)
- An η2-vinyl pathway may explain net trans hydrosilylation via transition metal catalysis even in cyclic cases (2003) (27)
- Kinetics by high-pressure nuclear magnetic resonance: Reversible hydrogen binding in (η2-H2)Cr(CO)3[P(C6H 11)3]2 (1990) (26)
- SEVEN-COORDINATE IRIDIUM(V) POLYHYDRIDES WITH CHELATING BIS(SILYL) LIGANDS (1995) (26)
- Effects of aqueous buffers on electrocatalytic water oxidation with an iridium oxide material electrodeposited in thin layers from an organometallic precursor. (2013) (26)
- Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide. (2015) (26)
- Atom economic synthesis of amides via transition metal catalyzed rearrangement of oxaziridines (2007) (26)
- Improved Syntheses and Structure of [MnIIIMnIV(O)2(phen)4](ClO4)3.cntdot.2CH3COOH.cntdot.2H2O (1994) (26)
- Fluxionality in [ReH5(PPh3)2(pyridine)] (1996) (25)
- Wilkinson's iridium acetate trimer as a water-oxidation catalyst. (2011) (25)
- Direct Interfacial Electron Transfer from High-Potential Porphyrins into Semiconductor Surfaces: A Comparison of Linkers and Anchoring Groups (2018) (24)
- A convenient general synthesis of trans-[IrCl(CO)(PR3)2] (1986) (24)
- Planar tricoordinate oxygens in a mixed aqua(tetrahydrofuran)iridium complex: x-ray crystal and molecular structure of [IrH2(THF)(H2O)(PPh3)2]SbF6.cntdot.THF (1990) (24)
- Towards multielectron photocatalysis: a porphyrin array for lateral hole transfer and capture on a metal oxide surface. (2015) (24)
- Trinuclear iridium cluster containing a tricoordinate bridging hydrogen ligand: structural and chemical studies (1982) (24)
- New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis. (2016) (24)
- Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective. (2009) (24)
- Comprar Chirality in Transition Metal Chemistry: Molecules, Supramolecular Assemblies and Materials | Hani Amouri | 9780470060544 | Wiley (2008) (24)
- New reaction of saturated fluorocarbons: partial reduction by ammonia with mercury photosensitization. (1995) (23)
- [IrH2(H2)2L2]+{L = P(C6H11)3}: A non-classical polyhydride complex (1985) (23)
- A rare eta2-butadienyl complex from an alkyne double insertion with double vinylidene rearrangement. (2003) (23)
- Nonradical tetrabutylammonium monopersulfate oxidation of hydrocarbons catalyzed by [Mn3O4bipy4(H2O)2](ClO4)4 (1996) (23)
- Understanding reactivity trends by structural and theoretical studies of distortions in ground-state reagents (1991) (23)
- SPECTROSCOPIC DETECTION OF A HYDROGEN FLUORIDE COMPLEX OF IRIDIUM (1996) (23)
- Metal ions at work. (1994) (23)
- High-Potential Porphyrins Supported on SnO2 and TiO2 Surfaces for Photoelectrochemical Applications (2016) (23)
- Transfer Hydrogenation with Glycerol as H-Donor: Catalyst Activation, Deactivation and Homogeneity (2019) (23)
- Hydrogen bonding ligand functionality and catalytic selectivity in homogeneous hydrosilylation of enones with rhodium complexes (2004) (23)
- Bioinorganic Chemistry of Manganese Related to Photosynthetic Oxygen Evolution (2007) (23)
- Site Preference Energetics, Fluxionality, and Intramolecular M−H···H−N Hydrogen Bonding in a Dodecahedral Transition Metal Polyhydride† (1997) (22)
- Copper (I): A possible olfactory binding site (1978) (22)
- The preparation, properties and some catalytic reactions of mer-hydrido(tetrahydroborato)tris(methyldiphenylphosphine)ruthenium(II) and some related complexes (1978) (22)
- A THEORETICAL STUDY OF MERCURY PHOTOSENSITIZED REACTIONS (1995) (22)
- The first polyhydrides stabilized only by N-donor ligands, hexahydro[hydrotris(pyrazolyl)borato]rhenium and heptahydro[dipyrazolylmethane]rhenium (1989) (22)
- Arene—ruthenium complexes containing nitrogen donor ligands (1977) (22)
- A tri-coordinate hydrogen ligand in a trinuclear iridium cluster (1978) (22)
- Unusual Stability of a Bacteriochlorin Electrocatalyst under Reductive Conditions. A Case Study on CO2 Conversion to CO (2018) (22)
- Hydrogen atoms as convenient synthetic reagents: mercury-photosensitized dimerization of functionalized organic compounds in the presence of molecular hydrogen (1991) (21)
- Silatrane Anchors for Metal Oxide Surfaces: Optimization for Potential Photocatalytic and Electrocatalytic Applications. (2018) (21)
- Molecular titanium-hydroxamate complexes as models for TiO2 surface binding. (2016) (21)
- Where Smokers Rule (1997) (21)
- Activation of molecular hydrogen by cationic iridium diene complexes (1976) (21)
- Catalysis of aldehyde imination by hydrogen bonding with a simple organic disulfonamide receptor (1999) (21)
- Additions and Corrections: Aspects of Methane Chemistry (1995) (21)
- Iridium(I), -(III), and -(V) complexes of an O-donor ligand in alkyne hydrosilylation (1990) (21)
- Controlling the rectification properties of molecular junctions through molecule-electrode coupling. (2016) (21)
- Physical properties of a manganese tetramer with all-oxygen coordination (1991) (21)
- T1's and proton NMR integration in metal hydride complexes (1985) (20)
- A FUNCTIONAL MODELING STUDY OF THE CO OXIDATION SITE OF NICKEL CO DEHYDROGENASE (1995) (20)
- A methylene-bis-triazolium ligand precursor in an unusual rearrangement of norbornadiene to nortricyclyl. (2003) (20)
- How hydrogen bonding affects ligand binding and fluxionality in transition metal complexes: a DFT study on interligand hydrogen bonds involving HF and H2O (2001) (20)
- Catalytic Photodefluorination of Perfluoroalkanes to Perfluoroalkenes with a Ferrocene Photosensitizer (1998) (20)
- Amination of Methane and Ethane by Mercury Photosensitization in the Presence of Ammonia (1993) (20)
- Hr2(μ-H)3H2(PPh3)4]+PF6−, A novel iridium complex containing a metal metal triple bond (1976) (20)
- Kinetic analysis of the O2-forming reaction between [Mn(III)(dpa)2]− (dpa=dipicolinate) and potassium peroxomonosulfate (2000) (20)
- Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand. (2017) (20)
- A Stable Coordination Complex of Rh(IV) in an N,O-Donor Environment. (2015) (20)
- INTERMOLECULAR N-H...H-RE INTERACTIONS INVOLVING RHENIUM POLYHYDRIDES (1997) (19)
- Intramolecular N–H ⋯ X–Ir (X = H, F) hydrogen bonding in metal complexes (1994) (19)
- Synthesis of monodentate bis(N-heterocyclic carbene) complexes of iridium: Mixed complexes of abnormal NHCs, normal NHCs, and triazole NHCs (2008) (19)
- Breaking an electronically preferred symmetry by steric effects in a series of [Ir(biph)X(QR3)2] compounds (X=Cl or I, Q=P or As) (1998) (19)
- CLUSTER EXPANSION OF A HIGH-VALENT OXOMANGANESE DIMER IN AQUEOUS SOLUTION (1994) (19)
- Colloidal palladium, easily formed in organic solvents, is a highly active and stable catalyst for selective hydrogenations and dehydrohalogenations (1993) (19)
- Tris(dimethylphenylphosphine)(dinitrogen)(dithiocarbamato)rhenium complexes and their reactions with hydrogen halides (1975) (19)
- Why nickel(II) binds CO best in trigonal bipyramidal and square pyramidal geometries and possible consequences for CO dehydrogenase (1994) (19)
- Linker rectifiers for covalent attachment of transition-metal catalysts to metal-oxide surfaces. (2014) (18)
- High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study. (2005) (18)
- Amine charge transfer complexes of perfluoroalkanes and an application to poly(tetrafluoroethylene) surface functionalization (1998) (18)
- A µ-dinitrogen complex with a long N–N bond. X-Ray crystal structure of [(PMe2Ph)4CIReN2MoCl4(OMe)] (1973) (18)
- Testing the T1 method : a comparison of T1 (min) and structural data (1990) (18)
- Direct conversion of perfluoroalkanes and perfluoroarenes to perfluoro Grignard reagents (1998) (18)
- Tungsten(VI) hexahydride complexes supported by chelating triphosphine ligands: Protonation to give [eta][sup 2]-dihydrogen complexes and catalytic dehydrogenation of cyclooctane to cyclooctene (1993) (18)
- A ferrocene-perfluoroarene molecular complex (1998) (17)
- The isolation of intermediates in hydrogen halide additions to some iridium complexes (1979) (17)
- Stretched H2 complexes: structural control in ReH7{P(C6H4-p-X)3}2 (X = CH3, H, F, CF3, OMe) complexes by electronic ligand effects (1992) (17)
- Mild, reversible reaction of iridium(III) amido complexes with carbon dioxide. (2012) (17)
- Carbon-carbon bond formation reactions of the iodomethane complex [Cp(dppe)Ru(ICH3)]PF6 (1988) (17)
- Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer. (2016) (17)
- Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions (2005) (17)
- Dipyrimidylamine and tripyrimidylamine as chelating N-donor ligands (2000) (17)
- Characterization of an activated iridium water splitting catalyst using infrared photodissociation of H2 tagged ions. (2012) (17)
- Halocarbon binding in [Ir(cod)(.eta.2-o-BrC6H4PPh2)]SbF6 (1984) (17)
- Oxidation of hydrocarbons catalyzed by manganese carboxylate complexes (1989) (17)
- C?H Activation approaches for the application of molecular recognition to organometallic chemistry and homogeneous catalysisBased on the presentation given at Dalton Discussion No. 6, 9?11th September 2003, University of York, UK. (2003) (17)
- Dehydrogenation of alkanes to arenes by iridium complexes (1987) (17)
- Synthesis and spectroscopic characterization of ruthenium(II) .eta.2-dihydrogen complexes of the type [RuH(.eta.2-H2)(L)(triphos)]+ (L = CO, P(OCH2)3CEt, PMe2Ph; triphos = PPh(CH2CH2PPh2)2) (1992) (16)
- Origin of Solvent Acceleration in Organolithium Metal−Halogen Exchange Reactions (1997) (16)
- Functional Modeling of CO Dehydrogenase: Catalytic Reduction of Methylviologen by CO/H2O with an N, O, S-Ligated Nickel Catalyst† (1993) (16)
- A study of high-valent manganese in aqueous phosphoric acid: disproportionation of the bis(.mu.-oxo)dimanganese(III,IV) bipyridine complex [MnIIIMnIV(.mu.-O)2(bpy)4]3+ (1993) (16)
- Symmetrical hydrogen bonds in iridium(III) alkoxides with relevance to outer sphere hydrogen transfer. (2012) (16)
- Neighboring group participation of halo and aryl groups in the stoichiometric and catalytic reactions of olefins with transition-metal hydrides and a new route to arene complexes (1984) (16)
- Steric Crowding in a Rhenium Polyhydride Induced by a Chelating Disilyl Ligand: Synthesis, Characterization, and Reactivity of ReH5(disil)(PPh3)2 (disil = 1,2-Bis(dimethylsilyl)benzene and 1,2-Bis(dimethylsilyl)ethane) (1994) (16)
- Homogeneous hydroformylation with cationic rhodium diolefin complexes (1979) (16)
- Arene ruthenium complexes of the thermally resistant ligand tri-2-pyridylamine (1995) (16)
- Two-Point Cooperative Binding of Ketones by a Metal and by a Neighboring Pendant NH Group (2000) (16)
- d0 and d2 Polyhydrides as unconventional proton acceptors in lntermolecular hydrogen bonding (1995) (16)
- Differing selectivities in mechanochemical versus conventional solution oxidation using Oxone (2013) (16)
- Electrochemical properties of [MnIII(terpy)(N3)3] (terpy=2,2′:6′,2″-terpyridine) in CH3CN: Electrogeneration of dimanganese(II) di-μ-azido and dimanganese(IV) di-μ-oxo complexes (2001) (15)
- Unifying the mechanisms for alkane dehydrogenation and alkene H/D exchange with [IrH2(O2CCF3)(PAr3)2]: the key role of CF3CO2 in the “sticky” alkane route (2001) (15)
- Gel-assisted crystallization of [Ir4(IMe)7(CO)H10](2+) and [Ir4(IMe)8H9](3+) clusters derived from catalytic glycerol dehydrogenation. (2015) (15)
- The mechanism of the Ni-Fe hydrogenases: a quantum chemical perspective (2001) (15)
- Characterization of siloxane adsorbates covalently attached to TiO2 (2008) (15)
- An Unusual Coordination Mode for Amides: Lone-Pair Binding via Nitrogen (1995) (15)
- Iridium-catalyzed benzylic C–H activation and functionalization of alkyl arenes (2009) (15)
- A New Charge Transfer Complex Involving ReH(5)(PPh(3))(3). (1997) (15)
- A. E. Shilov's influence on early work in organometallic CH activation and functionalization (2015) (14)
- Ruthenium in an oxygen donor environment: properties and reactions of .eta.3-(RPO(C6H4O)2)2-, .eta.3-(CpCo(PO(OEt)2)3)1- and .eta.3-HC(POPh2)3 complexes of ruthenium (1991) (14)
- Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands. (2012) (14)
- Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand. (2016) (14)
- Intermolecular Re–H···H–N and Re–H···base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method (1999) (14)
- Effects of dihydrogen bonding on fluxionality in ReH5(PPh3)2L (1997) (14)
- Unusual stereochemical rigidity in seven-coordination. Synthesis and structural characterization of ReH2(EPh3)(CO)(PMe2Ph)3 (E = Si, Sn) (1990) (14)
- Fluoroalkane aromatization over hot sodium oxalate (1999) (14)
- Synthesis and spectroscopic characterization of [ReH5(triphos)] and [ReH6(triphos)]+[triphos = PPh(CH2CH2PPh2)2] (1991) (14)
- Competitive .alpha.- and .beta.-elimination in an iridium alkyl (1988) (13)
- [(C5H4MeEt)Ir(PPh3)2]+: an agostic C.C bond or a close metal-ligand contact? (2004) (13)
- Towards thermally robust homogeneous catalysts: Re, Ir and W complexes of the highly thermally stable ligand, tri-2-pyridylamine (1996) (13)
- Surface-Attached Molecular Catalysts on Visible-Light-Absorbing Semiconductors: Opportunities and Challenges for a Stable Hybrid Water-Splitting Photoanode (2020) (13)
- Substrate binding and activation via pendant hydrogen-bonding groups as an approach to biomimetic homogeneous catalysis (2000) (13)
- 1H NMR T1(min) data and structure in a series of rhenium polyhydride complexes and the contribution of M‐H dipole–dipole relaxation (1991) (13)
- Aqueous speciation and electrochemical properties of a water-soluble manganese phthalocyanine complex. (2012) (13)
- Re–H⋯H–N interactions in the second-coordination sphere of crystalline [Re(PPh3)2(imidazole)] (1996) (13)
- Operando Structure–Activity–Stability Relationship of Iridium Oxides during the Oxygen Evolution Reaction (2022) (13)
- The antisymbiotic effect in some iridium(III) hydrides with N-, O-, and S-donor ligands (1983) (13)
- Preparation and X-ray Structure of a Trinuclear Dinitrogen-bridged Complex, trans-[MoCl4{(N2)ReCl(PMe2Ph)4}2] (1975) (12)
- Borate anion (B11H14-): a nido cage with no hydrogen...hydrogen interaction (1993) (12)
- A heterogeneous water oxidation catalyst from dicobalt octacarbonyl and 1,2-bis(diphenylphosphino)ethane (2014) (12)
- Hydrogenation of Quinaldine and Benzylic Aldehydes both Separately and Combined in a Tandem Hydrogenation–Reductive Alkylation of Quinaldine by Aldehydes with Iridium Benzoquinoline Catalysts (2013) (12)
- A novel route to alkanes, alcohols, and ethers by dehydrodimerization (1987) (12)
- π-Arene complexes as unexpected deactivation products in alkane activation and alkene hydrogenation reactions (1981) (12)
- Carbon-13 NMR spectra of some new iridium(I) complexes: evidence for reductive character in hydrogen addition and the cis and trans influences of nitriles (1982) (12)
- Ni complexes of redox-active pincers with pendant H-bonding sites as precursors for hydrogen production electrocatalysis (2014) (12)
- Functionalization of Nitrogen and Oxugen Containing Heterocycles by Mercury Photosensitized Dehydrodimerizations (1989) (12)
- Oxidative addition: an alternative view (1980) (12)
- Synthesis and characterization of some rhenium complexes with the new mixed phosphorus–nitrogen donor ligand NPh(CH2CH2PPh2)2 (1992) (12)
- High‐Valent Oxomanganese Clusters: Structural and Mechanistic Work Relevant to the Oxygen‐Evolving Center in Photosystem II (1996) (12)
- [ReH2(CO)2(PMe2Ph)3]+ a dihydride complex with classical and nonclassical tautomeric forms in equilibrium (1992) (12)
- On a convenient synthesis of WOCl4 and the question of the existence of Cp2WOCl2 (1985) (12)
- Oxidation of exogenous substrates by the O2-evolving center of photosystem II and related catalytic air oxidation of secondary alcohols via a tetranuclear manganese(IV) complex. (1989) (11)
- Metal-free amidation of ether sp3 C–H bonds with sulfonamides using PhI(OAc)2 (2014) (11)
- Infrared detection of M–H ⋯ OPPh3 hydrogen bonds (1995) (11)
- Photoelectrochemical oxidation of a turn-on fluorescent probe mediated by a surface MnII catalyst covalently attached to TiO2 nanoparticles (2014) (11)
- Rhenium phosphine heptahydride complexes: proton NMR evidence for classical structures in solution (1989) (11)
- High selectivity in the homogeneous hydrogenation of 1-alkynes to 1-alkenes by rhodium(I) carboxylato-complexes (1975) (11)
- Separating the rhenium-hydride and proton-proton dipole-dipole contributions to the 1H NMR spin-lattice relaxation rate of the hydride ligand in mer,trans-ReH(CO)3(PPh3)2 by deuteration (1991) (11)
- Perfluoroalkane photodefluorination via mercury photosensitization: experimental and theoretical aspects (1998) (11)
- C-H bond activation: A radical non-metal solution. (2009) (11)
- Current Ideas and Future Prospects in Metal-Catalyzed Methane Conversion (1994) (11)
- Bis-π-cyclopentadienyl–molybdenum and –tungsten complexes containing sulphur, phosphorus, nitrogen or hydrogen ligands (1971) (11)
- Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts (2017) (10)
- A review of: “Catalytic Aspects of Metal Phosphine Complexes: Vol. 196, ACS Advances in Chemistry Series. Eds. E.C. Alyea and D.W. Meek. American Chemical Society, Washington, D.C., 421 pp., $69.95.” (1982) (10)
- Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution (2000) (10)
- Amination of Methane, Higher Alkanes, and Alkenes by Mercury Photosensitization in the Presence of Ammonia. (1994) (10)
- Intermolecular ReH·HX hydrogen bonding (X N, C) involving ReH5(PPh3)3 (1998) (10)
- Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts (2012) (10)
- Functionalization s. β-elimination in alkane activation: a key role for 16-electron ML5 intermediates (2001) (10)
- Improved synthesis of some molybdenum and tungsten tetrahydrides (1982) (10)
- Preparation of Halogenated Fluorescent Diaminophenazine Building Blocks. (2015) (10)
- The synthesis of glycols by mercury-photosensitized alcohol dehydrodimerization (1993) (10)
- Secondary bonding in a six-coordinate Mn(II) complex as a model of associative substitution (2006) (9)
- Dinitrogen- and carbonyl-complexes as bases towards trimethylaluminium (1972) (9)
- Synthesis and characterization of rhenium complexes with 4-ethyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane (P(OCH2)3(CEt) (1991) (9)
- No Protection Required (2007) (9)
- Speeding catalyst discovery and optimization (1999) (9)
- A Dinuclear Iridium(V,V) Oxo-Bridged Complex Characterized Using a Bulk Electrolysis Technique for Crystallizing Highly Oxidizing Compounds. (2018) (9)
- Archaeological Investigations in the Chief Joseph Reservoir (1952) (9)
- Unusual fluxional and T1 properties for [ReH4(CO)(PMe2Ph)3]+: a polyhydride with classical and nonclassical tautomers (1990) (9)
- Iridium and Ruthenium Complexes with Chelating N‐Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β‐Alkylation of Alcohols, and N‐Alkylation of Amines. (2009) (9)
- NHC Ligands versus Cyclopentadienyls and Phosphines as Spectator Ligands in Organometallic Catalysis. (2006) (9)
- Study of an S = 1 Ni(II) pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic 1H NMR. (2013) (9)
- Surface-Induced Deprotection of THP-Protected Hydroxamic Acids on Titanium Dioxide (2016) (8)
- A cis-IrL(CO) group responds to increasing steric bulk of L by M-L stretching, not M-C-O tilting or bending. (2002) (8)
- Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation (2010) (8)
- Dehydrodimerization of ketones, carboxylic acids, amides, esters, alcohols, and amines, via mercury-photosensitization (1989) (8)
- Hydrodimerization of unsaturated alcohols, esters, nitriles, ketones, amines, silanes, epoxides and fluorocarbons by mercury-photosensitization (1989) (8)
- A cyclometallated iridium(III) dimethylphenylphosphine complex (1980) (8)
- Nine-coordinate hexahydride complexes of molybdenum and tungsten (1984) (8)
- Synthesis and solution structure of heterobimetallic rhenium-iridium polyhydride complexes (1993) (8)
- Alkane activation with mercury vapor (1988) (8)
- A Convenient General Synthesis of trans‐[IrCl(CO)(PR3)2]. (2002) (8)
- Assembly of High-Valent Oxomanganese Clusters in Aqueous Solution. Redox Equilibrium of Water-Stable Mn3O4+ 4 and Mn2O3+ 2 Complexes. (1991) (8)
- Oxidation by Chemical Methods (1991) (8)
- Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films (2017) (8)
- Halocarbon chelation in [Ir(cod)(η2-o-HalC6H4PPh2)]SbF6 (Hal Br, Cl): structural and chemical studies (1988) (8)
- Oxidative Addition and Reductive Elimination (2005) (7)
- N,N,O Pincer Ligand with a Deprotonatable Site That Promotes Redox‐Leveling, High Mn Oxidation States, and a Mn 2 O 2 Dimer Competent for Catalytic Oxygen Evolution (2019) (7)
- Synthesis and reactivity of ReH7(AsPh3)2 (1995) (7)
- Mercury-photosensitized reactions (1995) (7)
- In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond. (2009) (7)
- Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes (2017) (7)
- Pentahydridobis(Tricyclohexylphosphine)‐Iridium(V) and Trihydridotris(Triphenylphos‐phine)Iridium(III) (2007) (7)
- Formation of organometallic exciplexes of the type [Hg(η2-arene)] in mercury photosensitized reactions of aromatic compounds (1995) (7)
- Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes (2000) (7)
- Rhodium and Iridium in Organometallic Catalysis (2006) (7)
- Cp* versus Bis-carbonyl Iridium Precursors as CH Oxidation Precatalysts (2017) (7)
- Alkane functionalisation on a preparative scale by mercury photosensitisation (1987) (7)
- Comparison of Primary Oxidants for Water-Oxidation Catalysis (2013) (7)
- A modified MM2 force field for high-valent di-μ-oxo manganese dimers (1994) (6)
- Identification and Determination of Millimolar C6-C8 Alkenes in the Corresponding Alkanes (1986) (6)
- The isolation of intermediates in the oxidative addition of the hydrogen halides to some iridium(I) species (1978) (6)
- One-step synthesis of the degradation-resistant diamine ligands H2NCR2CR2NH2 (R = Me, Et) (1993) (6)
- Formation of a high valent di-μ-oxo manganese dimer in aqueous solution (1993) (6)
- Chemistry: A catalytic knight's move (2006) (6)
- Cationic Rhodium and Iridium Complexes in Catalysis (1983) (6)
- How students cope with a procedureless lab exercise (1979) (6)
- Modeling the Oxygen-Evolving Complex in Photosystem II (2000) (6)
- The isotopic trans effect (1986) (6)
- The neutron diffraction structure of [Ir4(IMe)8H10]2+ polyhydride cluster: Testing the computational hydride positional assignments ☆ (2017) (6)
- [η4‐1,5‐Cyclooctadiene)(Pyridine)‐(Tricyclohexylphosphine)Iridium(I)Hexafluorophosphate (2007) (6)
- Electrocatalytic, Homogeneous Ammonia Oxidation in Water to Nitrate and Nitrite with a Copper Complex. (2022) (6)
- T1, exchange and anomalous broadening in metal dihydrogen complexes (1997) (6)
- Dihydrido-diolefin complexes as intermediates in the catalytic hydrogenation of cycloocata-1,5-diene by the complexes [Ir(cod)L2]PF6 (1978) (6)
- Metal Ion Imbalance in the Body (2017) (6)
- 4,3 additions to α,β-unsaturated ketones via η2 CC binding to a ruthenium complex. (1988) (6)
- On the damage done to the structure of the Thermoplasma acidophilum proteasome by electron radiation (2018) (6)
- MERCURY PHOTOSENSITIZED DIMERIZATION OF AMINES (1993) (6)
- Electronic and Spin-State Effects on Dinitrogen Splitting to Nitrides in a Rhenium Pincer System. (2021) (6)
- Alternate Strategies for Solar Fuels from Carbon Dioxide (2020) (6)
- Carbenes in Synthesis and Homogeneous Catalysis (2007) (6)
- Accessing Molecular Dimeric Ir Water Oxidation Catalysts from Coordination Precursors. (2021) (6)
- Redox Catalysis for Dehydrogenation of Liquid Hydrogen Carrier Fuels for Energy Storage and Conversion (2011) (6)
- Tungsten and molybdenum phosphine hexahydrides: The first examples of nine coordination among mononuclear molybdenum complexes (1982) (5)
- Organometallic color chemistry: studies on [FcCHCHC5H4NCH2C6H4(tBu)]X (X=BPh4−, ClO4−) (2000) (5)
- Platinum: Inorganic & Coordination Chemistry (2006) (5)
- Comprar Handbook of Green Chemistry - Green Catalysis | Paul T. Anastas | 9783527315772 | Wiley (2009) (5)
- The Problem of Northwest Coastal-Interior Relationships as Seen from Seattle (1956) (5)
- Tritylpotassium a new dehydrohalogenation reagent (1983) (5)
- NINE‐COORDINATE HEXAHYDRIDE COMPLEXES OF MOLYBDENUM AND TUNGSTEN (1984) (5)
- Surprisingly big linker-dependence of activity and selectivity in CO2 reduction by an iridium(i) pincer complex. (2020) (5)
- Iridium Compounds in Homogeneous Hydrogenation (1979) (5)
- Co(II), a catalyst for selective conversion of phenyl rings to carboxylic acid groups (2014) (5)
- Switched-On Nickel (2001) (5)
- Homogenous Water Oxidation by a Di-μ-Oxo Dimanganese Complex in the Presence of Ce. (2007) (5)
- Complexes of π‐Bound Ligands (2005) (4)
- Consequences of the formation of an organometallic exciplex [Hg({eta}{sup 2}-arene)] in mercury-photosensitized reactions of arenes: C-C, C-O, and C-N bond cleavage (1996) (4)
- Synthesis and computational studies of Mg complexes supported by 2,2':6,2''-terpyridine ligands. (2012) (4)
- Chemistry. A new oxidation state for Pd? (2002) (4)
- C—H Oxidation by Platinum Group Metal Oxo or Peroxo Species (2011) (4)
- Recent Advances in C‐F Bond Activation (1997) (4)
- Inferring Protonation States of Hydroxamate Adsorbates on TiO2 Surfaces (2017) (4)
- Recent advances in mercury photosensitized reactions (1992) (4)
- Technetium & Rhenium: Inorganic & Coordination Chemistry (2011) (4)
- Structure–function relationships in single molecule rectification by N-phenylbenzamide derivatives (2016) (4)
- Applications of Organometallic Chemistry (2005) (4)
- Chelate and Pincer Carbene Complexes (2006) (4)
- Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic-Inorganic Ligand. (2016) (4)
- River Basin Surveys Papers, No. 24: The Sheep Island Site and the Mid-Columbia Valley (1961) (4)
- General Properties of Organometallic Complexes (2005) (4)
- Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure (2015) (4)
- Functional Manganese Model Chemistry Relevant to the Oxygen-Evolving Complex of Photosystem II: Oxidation of a Mn(III,IV) Complex Coupled to Deprotonation of a Terminal Water Ligand (2008) (4)
- Imination Catalysis via Two-point Binding of Substrate Aldehyde via a Metal and a Pendant Hydrogen-Bonding Group (2002) (3)
- THE EFFECT OF NET IONIC CHARGE ON THE CATALYTIC BEHAVIOR OF METAL HYDRIDES * (1983) (3)
- The Development of Mercury Photosensitized Reactions for Functionalizing Unactivated C - H Bonds in Organic Compounds (1991) (3)
- Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides. (2009) (3)
- Hydrogen Bonding & Dihydrogen Bonding (2011) (3)
- Classical (M: Os) and Nonclassical (M: Fe, Ru) Polyhydride Structures for the Complexes MH4(PR3)3. (1986) (3)
- Some Structure-Activity Relationships in Homogeneous Transition Metal Catalysts (1985) (3)
- Alkane Carbon–Hydrogen Bond Activation (2006) (3)
- One-Step Trimethylstannylation of Benzyl and Alkyl Halides. (2016) (3)
- Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes. [Erratum to document cited in CA113(18):161042g] (1992) (3)
- Synthesis and characterization of some new complexes of the Vaska-type trans-[IrX(CO)L2] (XCl or I; L=phosphite, phosphinite or phosphonite) and the direction of dihydrogen addition to these species (1992) (3)
- Determination of mu-oxo exchange rates in di-mu-oxo dimanganese complexes by electrospray ionization mass spectrometry. (2006) (3)
- Homogeneous Tungsten, Rhenium, and Iridium Catalysts in Alkane Dehydrogenation Driven by Reflux of Substrate or of Cosolvent or by Inert-Gas Flow. (1993) (3)
- Atom Economic Synthesis of Amides via Transition Metal Catalyzed Rearrangement of Oxaziridines. (2008) (3)
- C-H Transformation at Unfunctionalized Alkanes (2008) (3)
- Insertion and Elimination (2005) (3)
- Dihydrogen Complexes & Related Sigma Complexes (2006) (3)
- Homogeneous Catalysis of Silane Alcoholysis via Nucleophilic Attack by the Alcohol on an Ir(η2-HSiR3) Intermediate Catalyzed by (IrH2S2(PPh3)2)SbF6 (S: Solvent). (1989) (3)
- Photocatalysis in C-H Activation (1993) (3)
- Platinum Drugs for Treating Cancer (2017) (3)
- Hydride Complexes of the Transition Metals (2011) (2)
- Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution (2021) (2)
- Synthesis of PEG–iridium conjugates and their use as hydrogenation catalysts in a water/substrate two-phase medium (2001) (2)
- Anticancer Agents Beyond Cisplatin (2017) (2)
- Hydrides, hydrogen bonding and dihydrogen activation (2002) (2)
- Compounds of groups 13 to 15 (2007) (2)
- Dihydridobis(Solvent)Bis(Triphenylphosphine)Iridium(III) Tetrafluoroborates (2007) (2)
- Distortional Effects of Noncovalent Interactions in the Crystal Lattice of a Cp*Ir(III) Acylhydroxamic Acid Complex: A Joint Experimental–Computational Study (2014) (2)
- Tris[1,3-Bis(Diphenylphosphino)Propane]-Heptahydridotriiridium(2 +) Bis(Tetrafluoroborate) and Bis[1, 3-Bis-(Diphenylphosphino)Propane]-Pentahydridodiiridium(1+) Tetrafluoroborate (2007) (2)
- A Chumash Pottery Jar (1977) (2)
- SOLVATOCHROMISM AND OUTER SPHERE INTERACTIONS IN REH5(PPH3)2(L) (1997) (2)
- Molecular Recognition in Homogeneous Transition Metal Catalysis: A Biomimetic Strategy for High Selectivity (2008) (2)
- Fast 1H NMR relaxation in some ruthenium hydrides (1999) (2)
- Nitrous oxide mediated mercury photosensitized functionalization reactions of methane and other substrates with strong C-H bonds (1989) (2)
- Pincer and chelate N-heterocyclic carbene complexes of Rh, Ir, and Pd: Synthetic routes, dynamics, catalysis, abnormal binding, and counterion effects (2004) (2)
- Iridium Catalyzed Reversible Dehydrogenation — Hydrogenation of Quinoline Derivatives under Mild Conditions. (2015) (2)
- Dihydridobis(Solvent)Bis(Triphenyl‐Phosphine)Iridium(III) Tetrafluoroborates (2007) (2)
- Crystal and molecular structure of [ReH(CH3CN)3(PMe2Ph)3][BF4]2 (1987) (2)
- Compounds of groups 3 to 4 and the f elements (2007) (2)
- Progress in Inorganic Chemistry. Volume 43 Edited by Kenneth D. Karlin (Johns Hopkins University). Wiley: New York. 1995. vi + 621 pp. $125.00. ISBN 0-471-12336-6. (1996) (2)
- The lattice parameters, densities and atomic volumes of the platinum metals (1979) (2)
- Iridium N‐Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts (2009) (2)
- Diazo coupling for surface attachment of small molecules to TiO2 nanoparticles. (2020) (2)
- Abnormal C 5-Bound N-Heterocyclic Carbenes : Extremely Strong Electron Donor Ligands and Their Iridium ( I ) and Iridium ( III ) Complexes (2)
- Optimization of Surface Loading of the Silatrane Anchoring Group on TiO2. (2022) (2)
- Distorted Copper(II) Complex with Unusually Short CF···Cu Distances. (2021) (1)
- A Pd Complex of a Tridentate Pincer CNC Bis-carbene Ligand as a Robust Homogeneous Heck Catalyst. (2001) (1)
- Nucleophilic and Electrophilic Addition and Abstraction (2005) (1)
- Sigma Bonds as Ligand Donor Groups in Transition Metal Complexes (2015) (1)
- (1,5‐Cyclooctadiene)(tricyclohexylphosphine)(pyridine)iridium(I) Hexafluorophosphate (2009) (1)
- Thermal fixation of sulfur dioxide (1999) (1)
- Facile solvolysis of a surprisingly twisted tertiary amide (2016) (1)
- Coordination & Organometallic Chemistry: Principles (2006) (1)
- Protein denaturation: A physical chemistry project lab (1981) (1)
- C—H Activation Approaches for the Application of Molecular Recognition to Organometallic Chemistry and Homogeneous Catalysis (2004) (1)
- Physical Methods in Organometallic Chemistry (2005) (1)
- How far have we come? (2013) (1)
- Compounds of group 10 (2007) (1)
- Archaeology of the Northeast Mohave Desert (1978) (1)
- Rh‐Catalyzed Oxidative Coupling Between Primary and Secondary Benzamides and Alkynes: Synthesis of Polycyclic Amides. (2011) (1)
- Anodic Deposition of a Robust Iridium Water-Oxidation Catalyst from Organometallic Precursors (2011) (1)
- Green Alcohol Couplings Without Transition Metal Catalysts: Base-Mediated β-Alkylation of Alcohols in Aerobic Conditions. (2011) (1)
- Alcohol Cross‐Coupling Reactions Catalyzed by Ru and Ir Terpyridine Complexes. (2009) (1)
- Organometallic Chemistry of Alkane Activation (2006) (1)
- AROMATIC STACKING BETWEEN FERROCENE AND PERFLUOROPHENANTHRENE TO GIVE A 2 + 2 SUPRAMOLECULAR ASSEMBLY IN THE SOLID STATE (1997) (1)
- Metal Alkyls, Aryls, and Hydrides and Related σ‐Bonded Ligands (2005) (1)
- Kinetics by High-Pressure Nuclear Magnetic Resonance: Reversible Hydrogen Binding in (η2-H2)Cr(CO)3(P(C6H11)3)2. (1991) (1)
- Prebiotic chemistry. Where smokers rule. (1997) (1)
- Carbon–Carbon & Carbon–Heteroatom Activation (2006) (1)
- Hydrogen Bonds to Metals and Metal Hydrides (2013) (1)
- Metal Complexes for Treating Arthritis and Diabetes (2017) (1)
- Iridium(III) Complexes with the Weakly Bonded Anions [Bf4]‐ and [Oso2Cf3]‐ (2007) (1)
- Hydrogen Atoms as Convenient Synthetic Reagents: Mercury- Photosensitized Dimerization of Functionalized Organic Compounds in the Presence of H2. (1991) (1)
- New dairy-based food ingredients (1992) (1)
- Mechanism for photosynthetic 02 evolution ( water oxidation / photosystem I 1 / manganese ) (1)
- New Reaction of Saturated Fluorocarbons: Partial Reduction by NH3 with Hg Photosensitization. (1996) (1)
- Ring Slip in Associative Reactions of Some Indenyl and Phenylcyclopentadienyl Iridium Complexes. (1989) (1)
- ‘Pincer’-carbene complexes (2007) (1)
- Modeling the Oxygen-Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex. (1988) (1)
- Direct Conversion of Perfluoroalkanes and Perfluoroarenes to Perfluoro Grignard Reagents. (1998) (1)
- Alkane Functionalization by Mercury Photosensitization (1989) (0)
- B11H‐ 14: A Nido Cage with No H×××H Interaction (1993) (0)
- Chemistry. No protection required. (2007) (0)
- Progress in Inorganic Chemistry. Volume 50 Edited by Kenneth D. Karlin (Johns Hopkins University). Wiley: New York. 2001. viii + 632 pp. $150.00. ISBN 0-471-43510-4. (2002) (0)
- The chemistry of high-valent oxomanganese clusters in aqueous solution: A (IV,IV) dimer containing bridging and terminal phosphate ligands (1991) (0)
- NiII pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic 1 H NMR † (2013) (0)
- Book reviewActivation of saturated hydrocarbons by transition metal complexes : A.E. Shilov, published by D. Reidel Co., Dordrecht, The Netherlands, 1984, 203 pp., US $39, ISBN 90-277-1628-5 (1985) (0)
- Using the fluctuation-induced tunneling conduction (FITC) model for describing and understanding bulk charge transport in nanostructured materials (2013) (0)
- Substituent effects on 61 Ni NMR chemical shifts † (2009) (0)
- Compounds of groups 5 to 7 (2007) (0)
- Bis(1,1,1,5,5,5-Hexafluro-2,4-Pentane-Dionato)Palladium and its Complexes with 2,2′-Bipyridine and Bis[2-(Diphenylphosphino)-Ethyl]Phenylphosphine (2007) (0)
- Unusual Activity and Selectivity in Alkyne Hydrosilylation with an Iridium Catalyst Stabilized by an O‐Donor Ligand. (1991) (0)
- Controlling the recti fi cation properties of molecular junctions through molecule – electrode coupling Q 1 † (2016) (0)
- ight-driven water oxidation for solar fuels (2012) (0)
- An inexpensive method for refluxing solutions in the presence of a gas (1980) (0)
- One-Step Synthesis of the Degradation-Resistant Ligands H2NCR2CR2NH2 ( R: Me, Et). (1993) (0)
- Hydrogen Storage by Molecular Polyhydrides. (1983) (0)
- A New Intermolecular Interaction: Unconventional Hydrogen Bonds with Element‐Hydride Bonds as Proton Acceptor (1996) (0)
- Moving to Sustainable Metals: Multifunctional Ligands in Catalytic, Outer Sphere C-H, N-H and O-H Activation (2015) (0)
- Great Yale-Princeton titration contest (1978) (0)
- Appendix B: Major Reaction Types and Hints on Problem Solving (2014) (0)
- Some crystal growth strategies for diffraction structure studies of iridium complexes (2018) (0)
- Electrochemical and Photoelectrochemical Conversion of Carbondioxide to Alcohols (2011) (0)
- Malcolm L. H. Green. 16 April 1936 — 24 July 2020 (2021) (0)
- Rhodium-based production of aromatics: Ongoing work in the laboratory of our rhodium bicentenary competition winner (2003) (0)
- 1969 / 1970 Report On the Archaeological Survey of the Lower Colorado River (1970) (0)
- O-Allylhydroxyamine: A Bifunctional Olefin for Construction of Axially and Centrally Chiral Amino Alcohols via Asymmetric Carboamidation. (2023) (0)
- BODIPY and dipyrrin as unexpected robust anchoring groups on TiO2 nanoparticles. (2022) (0)
- Organometallic Catalysts and Catalysis (2011) (0)
- 4,3-Additions to α,β-Unsaturated Ketones via η2 C=C Binding to a Ruthenium Complex. (1989) (0)
- Contents list. (2017) (0)
- Metal Complexes for Killing Parasites, Bacteria and Viruses (2017) (0)
- The Archaeology Of The Northeast Mojave Desert (2015) (0)
- Photocatalytic water splitting using titania nanoparticles functionalized with high-valent oxomanganese complexes (2006) (0)
- Co(II), a Catalyst for Selective Conversion of Phenyl Rings to Carboxylic Acid Groups. (2015) (0)
- Rhodium and Iridium in Organometallic Catalysis WORK IN THE LABORATORY OF OUR RHODIUM BICENTENARY COMPETITION WINNER (2006) (0)
- Electrochemical Ammonia Oxidation with Molecular Catalysts (2023) (0)
- N,N,O Pincer Ligand with a Deprotonatable Site That Promotes RedoxLeveling, High Mn Oxidation States, and a Mn<sub>2</sub>O<sub>2</sub> Dimer Competent for Catalytic Oxygen Evolution (2019) (0)
- Alkane Functionalization on a Preparative Scale by Mercury Photosensitization. (1987) (0)
- Molecular Q 1 Q 2 design of light-harvesting photosensitizers : effect of varied linker conjugation on interfacial electron transfer † (2016) (0)
- Two Burial Sites in Central Washington (2013) (0)
- Study of oxomanganese dimers as models for the oxygen evolving center in photosystem II (1993) (0)
- Directing Effects in Homogeneous Hydrogenation with (Ir(cod)(PCy3)(py))PF6. (1987) (0)
- Mercury-Photosensitized C—H Bond Functionalization (1992) (0)
- SOME DIOLEFIN COMPLEXES OF IRIDIUM(I) AND A TRANS-INFLUENCE SERIES FOR THE COMPLEXES (IRCL(COD)L) (1977) (0)
- The Origin of the Directing Effect in H2 Addition to Square-Planar d8 Complexes. (1988) (0)
- Alkane Functionalization on a Preparative Scale by Mercury-Photosensitized Cross-Dehydrodimerization. (1989) (0)
- CCDC 743784: Experimental Crystal Structure Determination (2010) (0)
- The Synthesis of Glycols by Mercury-Photosensitized Alcohol Dehydrodimerization. (1993) (0)
- Crystal structure of 2,2'-dipyridylbis(triphenylphosphine)dihydroiridium( III) triflate dichloromethane solvate, [Ir(bру)(РhзР)2Н2]+[СFзSOз]∞·CH2Cl2 (1998) (0)
- A MU-DINITROGEN COMPLEX WITH A LONG N-N BOND, X-RAY CRYSTAL STRUCTURE OF ((P(CH3)2C6H5)4CLREN2MOCL4(O-CH3)) (1974) (0)
- Transition metal compounds in organic synthesis (2007) (0)
- Second Interim Report On the Archaeological Survey; Colorado River 1968; the 1969 / 70 Report On the Archaeological Survey of the Lower Colorado River (1970) (0)
- TRITYLPOTASSIUM. A NEW DEHYDROHALOGENATION REAGENT (1983) (0)
- Fluoroalkane Aromatization over Hot Sodium Oxalate. (2000) (0)
- Physical Chemistry of TiO2 functionalized with oxo-manganese (2005) (0)
- Biomimetic CO2 reduction based on Mg complexes (2011) (0)
- Transition‐Metal Complexation of σ Bonds (1993) (0)
- CCDC 973858: Experimental Crystal Structure Determination (2016) (0)
- Iridium(III) complexes in selective C-H oxidation (2014) (0)
- Metal-Free Amidation of Ether sp3 C—H Bonds with Sulfonamides Using PhI(OAc)2. (2015) (0)
- Synthetic Applications of Mercury Photosensitization (1993) (0)
- Making Mercury-Photosensitized Dehydrodimerization into an Organic Synthetic Method: Vapor Pressure Selectivity and the Behavior of Functionalized Substrates. (1989) (0)
- CARBON‐13 NMR SPECTRA OF SOME NEW IRIDIUM(I) COMPLEXES: EVIDENCE FOR REDUCTIVE CHARACTER IN HYDROGEN ADDITION AND THE CIS AND TRANS INFLUENCES OF NITRILES (1983) (0)
- Chapter 2. Iridium (2008) (0)
- A Cultural Resources Overview of The Colorado Desert Planning Units (2015) (0)
- Chapter 3: Cultural / Historical Review (1979) (0)
- Chemistry. Switched-on nickel. (2001) (0)
- Alkane Activation with Mercury Vapor. (1988) (0)
- Molybdenum and Tungsten Phosphine Polyhydrides (2007) (0)
- Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds (2019) (0)
- SOLVENTO COMPLEXES OF TUNGSTEN, RHENIUM, OSMIUM, AND IRIDIUM AND THE X-RAY CRYSTAL STRUCTURE OF (IRH2(ME2CO)2(PPH3)2)BF4 (1984) (0)
- Sigma-Bond Metathesis as an Unusual Asymmetric Induction Step in Rhodium-Catalyzed Enantiodivergent Synthesis of C-N Axially Chiral Biaryls. (2023) (0)
- Synthesis and Structural Studies of Some New Rhenium Phosphine Heptahydride Complexes. Evidence for Classical Structures in Solution. (1990) (0)
- Crystal and Molecular Structure of (ReH(CH3CN)3(PMe2Ph)3) (BF4)2 (1987) (0)
- Functional materials, environmental and biological applications (2007) (0)
- Synthesis and Spectroscopic Characterization of (ReH5(triphos)) and (ReH6(triphos))+ (triphos: PPh(CH2CH2PPh2)2). (1991) (0)
- Unusual Stereochemical Rigidity in Seven-Coordination. Synthesis and Structural Characterization of ReH2(EPh3)(CO)(PMe2Ph)3 (E: Si, Sn). (1991) (0)
- Main group compounds in organic synthesis (2007) (0)
- Selective Catalytic Dehydrogenation of Alkanes to Alkenes. (1988) (0)
- TRI-μ-HYDRIDO-DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)DIIRIDIUM HEXAFLUOROPHOSPHATE, A NOVEL IRIDIUM COMPLEX CONTAINING A METAL-METAL TRIPLE BOND (1976) (0)
- Oxidation Catalysis by Transition Metal Complexes (2006) (0)
- Mercury-Photosensitized Sulfination, Hydrosulfination, and Carbonylation of Hydrocarbons: Alkane and Alkene Conversion to Sulfonic Acids, Ketones, and Aldehydes. (1992) (0)
- Dehydrodimerization of Ketones, Carboxylic Acids, Amides, Esters, Alcohols, and Amines via Mercury Photosensitization. (1990) (0)
- PREPARATION AND X-RAY STRUCTURE OF A TRINUCLEAR DINITROGEN-BRIDGED COMPLEX, TRANS-(MOCL4((N2)RECL(PME2PH)4)2) (1975) (0)
- USING TERAHERTZ SPECTROSCOPY TO STUDY SYSTEMS WITH SOLAR ENERGY APPLICATIONS (2013) (0)
- Compounds of groups 1 to 2 and 11 to 12 (2007) (0)
- Catalytic activity of polynuclear manganese complexes for oxygen evolution from water using a one-electron oxidant (1993) (0)
- ARENE-RUTHENIUM COMPLEXES CONTAINING NITROGEN DONOR LIGANDS (1978) (0)
- Alkane photoreactions with mercury vapor) (1990) (0)
- Oil and fat products for the Australian baking industry (1989) (0)
- Les ligands à base d'éléments du groupe principal en catalyse et en chimie de coordination: Main-group ligands in catalysis and coordination chemistry (2004) (0)
- Proton-Coupled Electron Transfer in ((bpy)2Mn(O)2Mn(bpy)2)3+. (1990) (0)
- Dehydrogenative Silation, Isomerization and the Control of syn‐ vs. anti‐Addition in the Hydrosilation of Alkynes. (1993) (0)
- C-C Bond Cleavage in Hydrocarbons by Iridium Complexes. (1987) (0)
- Green chemistry based on TiO2 functionalized with oxo-manganese catalysts (2006) (0)
- Archaeological Impact State On East Mesa Areas 1 and 2, Imperial Valley, California (1974) (0)
- Chelation of a C-F Bond to Iridium in an 8-Fluoroquinoline Complex. (1987) (0)
- Directivity in Catalysis (1987) (0)
- ON A CONVENIENT SYNTHESIS OF TUNGSTEN OXIDE CHLORIDE (WOCL4) AND THE QUESTION OF THE EXISTENCE OF CP2WOCL2 (1985) (0)
- Competitive α- and β-Elimination in an Iridium Alkyl. (1988) (0)
- OCCURRENCE AND ORIGIN OF A PRONOUNCED DIRECTING EFFECT OF A HYDROXYL GROUP IN HYDROGENATION WITH (IR(COD)P(C6H11)3(PY))PF6 (1983) (0)
- Supporting information : Ultrafast Interfacial Electron Transfer drives Mn ( II ) photooxidation on TiO 2 Nanoparticles (2006) (0)
- Clusters and the Metal–Metal Bond (2005) (0)
- Conformational studies on factor F-430 and studies on related model compounds (1989) (0)
- High Oxidation State Complexes of Rhodium and Iridium (2019) (0)
- Hydrides and Hydrogen Bonding (2001) (0)
- Chapter 2 - Activation of Substrates with Non-Polar Single Bonds (2003) (0)
- Homogeneous Catalysts and Catalysis (2002) (0)
- Review of A Cultural History of Chemistry. Peter J. T. Morris and Alan Rocke, eds., Bloomsbury Academic: London, 2022 (2023) (0)
- DIHYDRIDOOLEFIN AND SOLVENTO COMPLEXES OF IRIDIUM AND THE MECHANISMS OF OLEFIN HYDROGENATION AND ALKANE DEHYDROGENATION (1983) (0)
- Functional Modeling of Ni,Fe Hydrogenases: A Nickel Complex in a N,O,S Environment. (1991) (0)
- Paramagnetic, High‐Oxidation‐State, and High‐Coordination‐Number Complexes (2005) (0)
- Useful Texts on Allied Topics (2005) (0)
- Physical Chemistry of TiO$_2$ functionalized with oxo-manganese catalysts (2006) (0)
- An NMR Method for Distinguishing Classical from Nonclassical Structures in Transition‐Metal Polyhydrides. (1988) (0)
- Colloidal Palladium, Easily Formed in Organic Solvents, is a Highly Active and Stable Catalyst for Selective Hydrogenations and Dehydrohalogenations. (1993) (0)
- Peter M. Maitlis. 15 January 1933—18 May 2022 (2023) (0)
- Modeling the oxygen evolving complex of photosystem II. Redox chemistry and ligand binding of biologically relevant manganese tetramers (1989) (0)
- Oxidation of Hydrocarbons Catalyzed by Manganese Carboxylate Complexes. (1990) (0)
- Solutions to Problems (2005) (0)
- Structure – function Q 1 Q 2 relationships in single molecule rectification by N-phenylbenzamide derivatives † (2016) (0)
- The First Polyhydrides Stabilized Only by N-Donor Ligands, ((HB(pz)3)ReH6) and ((CH2(pz)2)ReH7). (1989) (0)
- The role of terahertz spectroscopy in relation to the goal of catalytic water photooxidation (2009) (0)
- Functionalization of Nitrogen- and Oxygen-Containing Heterocycles by Mercury-Photosensitized Dehydrodimerizations. (1989) (0)
- Archaeology Investigation at Batuquitos Lagoons, San Diego County, California (1963) (0)
- Major Reaction Types (2005) (0)
- C–H activation (2021) (0)
- Some Recent Advances in Alkane Functionalization: Metal Phosphine Catalysts and Mercury Photosensitization (1990) (0)
- Reacting alkanes selectively (1991) (0)
- FACILE HOMOGENEOUS HYDROGENATIONS OF HINDERED OLEFINS WITH CYCLOOCTADIENYLPYRIDINYL(TRICYCLOHEXYLPHOSPHINYL)IRIDIUM HEXAFLUOROPHOSPHATE (1981) (0)
- Hydrogen Transfer Reduction of Aldehydes with Alkali‐Metal Carbonates and Iridium NHC Complexes (2004) (0)
- Thermal and Photochemical C-H Bond Reactions of Alkenes in (Tris(pyrazolyl)borato)iridium(I) Complexes. (1989) (0)
- Catalysis of Aldehyde Imination by Hydrogen Bonding with a Simple Organic Disulfonamide Receptor. (2000) (0)
- The Isotopic trans Effect. (1987) (0)
- Imination Catalysis via Two-Point Binding of Substrate Aldehyde via a Metal and a Pendant Hydrogen-Bonding Group. (2002) (0)
- Hydrodimerization of Unsaturated Alcohols, Esters, Nitriles, Ketones, Amines, Silanes, Epoxides, and Fluorocarbons by Mercury-Photosensitization. (1990) (0)
- New directions in organometallic chemistry (1997) (0)
- A Novel Route to Alkanes, Alcohols, and Ethers by Dehydrodimerization. (1988) (0)
- The Development of Mercury Photosensitized Reactions for Functionalizing Unactivated C‐H Bonds in Organic Compounds (1992) (0)
- Fifty years of coordination chemistry reviews (2017) (0)
- Chapter 8: Site Evaluation and Recommendations (1979) (0)
This paper list is powered by the following services:
Other Resources About Robert H. Crabtree
What Schools Are Affiliated With Robert H. Crabtree?
Robert H. Crabtree is affiliated with the following schools:
