Robert J. P. Corriu

Robert J. P. Corriu's AcademicInfluence.com Rankings

Robert J. P. Corriu

Chemistry

#2240

World Rank

#3118

Historical Rank

Inorganic Chemistry

#91

World Rank

#101

Historical Rank

chemistry Degrees

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Chemistry

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Robert J. P. Corriu's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Reactivity of penta- and hexacoordinate silicon compounds and their role as reaction intermediates (1993) (753)
Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls (1972) (434)
RECENT DEVELOPMENTS OF MOLECULAR CHEMISTRY FOR SOL-GEL PROCESSES (1996) (405)
New mixed organic-inorganic polymers: hydrolysis and polycondensation of bis(trimethoxysilyl)organometallic precursors (1992) (201)
From molecular chemistry to hybrid nanomaterials. Design and functionalization. (2011) (170)
Activation of silicon-hydrogen, silicon-oxygen, silicon-nitrogen bonds in heterogeneous phase (1983) (146)
Mixed oxides SiO2–ZrO2 and SiO2–TiO2 by a non-hydrolytic sol–gel route (1996) (129)
Auto-organisation of hybrid organic–inorganic materials prepared by sol–gel chemistry (2002) (128)
Mesoporous materials with an acidic framework and basic pores. A successful cohabitation. (2006) (127)
Nucleophilic displacement at silicon sterochemistry and mechanistic implications (1980) (125)
A Solution Chemistry Study of Nonhydrolytic Sol−Gel Routes to Titania (1997) (124)
The siliconium ion question (1974) (124)
Silicon carbonitride from polymeric precursors: thermal cross-linking and pyrolysis of oligosilazane model compounds (1992) (118)
Thermal redistribution reactions in crosslinked polysiloxanes (1992) (116)
Preparation of anatase, brookite and rutile at low temperature by non-hydrolytic sol–gel methods (1996) (112)
Hypervalent Species of Silicon: Structure and Reactivity (1990) (107)
Group 14 metalloles. 2. Ionic species and coordination compounds (1990) (106)
Preparation of alumina gels by a non-hydrolytic sol-gel processing method (1994) (105)
Preparation of Silicon Carbonitrides from an Organosilicon Polymer: I, Thermal Decomposition of the Cross-linked Polysilazane (1993) (104)
Non-hydrolytic sol–gel routes to silica (1998) (104)
New poly[(silylene)diacetylenes] and poly[(germylene)diacetylenes]: synthesis and conductive properties (1992) (101)
Formation and Reactivity of Silicon–Sulfur and Silicon–Selenium Double Bonds. The First X‐Ray Structure of a Silanethione (1989) (95)
In situ formation of gold nanoparticles within thiol functionalized HMS-C16 and SBA-15 type materials via an organometallic two-step approach (2003) (91)
Preparation of monolithic gels from silicon halides by a non-hydrolytic sol-gel process (1992) (90)
Ordered mesoporous hybrid materials containing cobalt(II) Schiff base complex (2002) (89)
Molecular chemistry and nanosciences: on the way to interactive materials (2005) (81)
Mesoporous hybrid materials containing functional organic groups inside both the framework and the channel pores (2002) (77)
Ordered SBA-15 mesoporous silica containing phosphonicacid groups prepared by a direct synthetic approach (2001) (74)
Nanostructured organic-inorganic hybrid materials : Kinetic control of the texture (2001) (73)
Asymmetric synthesis at silicon (1975) (72)
Preparation of monolithic binary oxide gels by a nonhydrolytic sol-gel process (1992) (71)
Reactions de l'ortho-bis(dimethylsilyl)benzene avec les nitriles catalysees par des complexes du rhodium (1982) (70)
A tailored organometallic-inorganic hybrid mesostructured material: a route to a well-defined, active, and reusable heterogeneous iridium-NHC catalyst for H/D exchange. (2008) (69)
Nucleophilic Displacement at Silicon: Recent Developments and Mechanistic Implications (1982) (69)
Tailored Ru-NHC heterogeneous catalysts for alkene metathesis. (2009) (69)
Molecular Chemistry of Sol-Gel Derived Nanomaterials (2009) (69)
Materials chemistry communications. Preparation of monolithic metal oxide gels by a non-hydrolytic sol–gel process (1992) (68)
Reactivity of dianionic hexacoordinated silicon complexes toward nucleophiles: a new route to organosilanes from silica (1988) (68)
In situ formation of gold nanoparticles within functionalised ordered mesoporous silica via an organometallic ‘chimie douce’ approach (2001) (66)
Hybrid Silica Gels Containing 1,3-Butadiyne Bridging Units. Thermal and Chemical Reactivity of the Organic Fragment (1996) (65)
Direct synthesis of functionalized mesoporous silica by non-ionic assembly routes. Quantitative chemical transformations within the materials leading to strongly chelated transition metal ions (2004) (64)
Organosilicon polymers: pyrolysis chemistry of poly[(dimethylsilylene)diacetylene] (1992) (64)
Preparation and structure of silicon oxycarbide glasses derived from polysiloxane precursors (1997) (64)
Organosilicon gels containing silicon-silicon bonds, precursors to novel silicon oxycarbide compositions (1992) (63)
Organosilicon polymers: synthesis of poly[(silanylene)diethynylene]s with conducting properties (1990) (63)
Mechanism of pyrolysis of polycarbosilanes: poly(silylethylene) and poly(dimethylsilylethylene) (1993) (62)
Pyrolysis of polyvinylsilazane precursors to silicon carbonitride (1991) (61)
The nature of the interaction of nucleophiles such as HMPT, DMSO, DMF and Ph3PO with triorganohalo-silanes, -germanes, and -stannanes and organophosphorus compounds. Mechanism of nucleophile induced racemization and substitution at metal (1980) (61)
Synthesis of magnetic silica-based nanocomposites containing Fe3O4 nanoparticles (2004) (60)
Asymmetric synthesis at silicon: II. Alcoholysis of prochiral organosilicon compounds catalysed by rhodium complexes (1976) (59)
Reversible Covalent Chemistry of CO2: An Opportunity for Nano-Structured Hybrid Organic–Inorganic Materials (2008) (59)
Synthesis of New RuO2@SiO2 Composite Nanomaterials and their Application as Catalytic Filters for Selective Gas Detection (2007) (58)
Trialkoxysilyl Mono-, Bi-, and Terthiophenes as Molecular Precursors of Hybrid Organic-Inorganic Materials (1994) (58)
Selective synthetic routes to electroconductive organosilicon polymers containing thiophene units (1991) (58)
Thermogravimetric analysis/mass spectrometry investigation of the thermal conversion of organosilicon precursors into ceramics under argon and ammonia. 2. Poly(silazanes) (1992) (58)
CO2 as a supramolecular assembly agent: a route for lamellar materials with a high content of amine groups. (2005) (57)
Silica xerogels containing a functional group at silicon (1989) (56)
Pentacoordinated silicon hydrides: very high affinity of the silicon-hydrogen bond for the equatorial position (1986) (56)
Stereochemical proof of the existence of nucleophilic activation at a silicon atom in nucleophilic substitution reactions. Substitution of the SiCl-bond with retention of configuration (1978) (56)
Syntheses a partir de carbanions allyliques silicies (1975) (56)
Influence of the nature of the organic precursor on the textural and chemical properties of silsesquioxane materials (1998) (56)
A new trend in metal-alkoxide chemistry: the elaboration of monophasic organic-inorganic hybrid materials (1998) (55)
Some recent developments of polysilsesquioxanes chemistry for material science (1998) (55)
Control of coordination chemistry in both the framework and the pore channels of mesoporous hybrid materials (2003) (54)
Control of the Anisotropic Organization of Nanostructured Silica-Based Hybrid Materials (2002) (53)
29Si NMR of pentacoordinate silicon derivatives (1983) (53)
Poly(vinylsilane): a precursor to silicon carbide. 1. Preparation and characterization (1991) (52)
Silicon oxycarbide glasses with low O/Si ratio from organosilicon precursors (1994) (52)
Synthesis and Luminescence Properties of Monophasic Organic−Inorganic Hybrid Materials Incorporating Europium(III) (2001) (52)
Photoresponsive ordered hybrid materials containing a bridged azobenzene group (2005) (51)
Auto-organization in sol-gel type polycondensation: a door to the nanosciences. (2003) (51)
Aminosilanes in organic synthesis. Preparation of new expanded porphyrin ligands and bimetallic transition-metal complexes. Crystal structure of a tetrapyrrole macrocycle dirhodium complex (1993) (51)
Thermal reactivity of hydrogenosilsesquioxane gels (1991) (50)
New Inorganic–Organic Hybrid Materials for HPLC Separation Obtained by Direct Synthesis in the Presence of a Surfactant (2002) (50)
Study of the insertion products of manganese in the silicon-hydrogen bond. Nature of the bond and proton exchange in the HMn-SiH system (1982) (50)
Polyvinylsilazane: A Novel Precursor to Siliconcarbonitride (1992) (49)
Supramolecular self-organization in non-crystalline hybrid organic–inorganic nanomaterials induced by van der Waals interactions (2006) (49)
Soft route for monodisperse gold nanoparticles confined within SH-functionalized walls of mesoporous silica (2009) (48)
Hydrophilic conditions: a new way for self-assembly of hybrid silica containing long alkylene chains (2005) (47)
Preparation of diphenylsilylene polymers containing main-chain acetylene and (hetero)aromatic groups: χ(2) Non-linear optical and other properties (1993) (47)
Facile reduction of acid chlorides into aldehydes using hypervalent silicon hydrides (1988) (47)
Intramolecular Base Stabilization of SiN and SiP Compounds and Related Transition‐Metal Silanediyl Complexes (1991) (47)
Study of the accessibility of phosphorus centres incorporated within ordered mesoporous organic–inorganic hybrid materials (2000) (47)
Modified electrodes from organic-inorganic hybrid gels containing ferrocene units covalently bonded inside a silica network (1994) (47)
Addition of Grignard reagents to vinylsilanes (1970) (46)
Enhancement of SiH bond reactivity in pentacoordinated structures (1986) (46)
Organic-inorganic hybrid materials : hydrolysis and polycondensation of 1,1'-bis-silylated ferrocene derivatives (1993) (45)
Nonhydrolytic Sol−Gel Process: Aluminum Titanate Gels (1997) (45)
Non-hydrolytic sol-gel process : zirconium titanate gels (1997) (45)
Pentacoordinated silicon anions: reactivity toward strong nucleophiles. (1988) (45)
Bifunctional ordered mesoporous materials: direct synthesis and study of the distribution of two distinct functional groups in the pore channels (2008) (44)
Intramolecular Base Stabilization of Silicenium Ions: A New Route to Siliconium Ions (1993) (44)
Thermal reactions occurring during pyrolysis of crosslinked polysiloxane gels, precursors to silicon oxycarbide glasses (1992) (43)
Intramolecular coordination at phosphorus: donor-acceptor interaction in three- and four-coordinated phosphorus compounds (1995) (43)
Structure of a (4 + 4)-Coordinate Silicon Compound, a Precursor of Hypercoordinate Silyl Mono- and Dications (1994) (42)
An original synthesis of highly ordered organosilica with a high content of thiol groups. (2006) (42)
Synthesis of poly(alkynylsilanes) having various aromatic groups in the backbone (1990) (42)
Activations des reactifs de Grignard par les complexes du titane. Application du systeme “Cp2TiCl2—i-PrMgBr” comme agent reducteur (1974) (42)
Sol-gel route to silicon suboxides. Preparation and characterization of silicon sesquioxide (1991) (42)
Selective catalytic route to bifunctional silanes. Catalysis by rhodium and ruthenium complexes of the alcoholysis of diarylsilanes and the hydrosilylation of carbonyl compounds (1973) (42)
Direct synthesis of bifunctional mesoporous organosilicas containing chelating groups in the framework and reactive functional groups in the channel pores (2007) (42)
Lewis Base-Stabilized Transition Metal Complexes of Divalent Silicon Species (1995) (42)
The Control of Nanostructured Solids: A Challenge for Molecular Chemistry (2001) (42)
Poly(carbosilane) precursors of silicon carbide: the effect of cross-linking on ceramic residue (1991) (41)
Design of porous silica from hybrid organic–inorganic precursors (1998) (41)
Possibility of heptacoordination at silicon: synthesis and X-ray crystal structures of tris[8-(dimethylamino)naphthyl]silane and tris[2-((dimethylamino)methyl)phenyl]fluorosilane (1994) (41)
Hybrid Materials Containing Metal(II) Schiff Base Complex Covalently Linked to the Silica Matrix by Two Si−C Bonds: Reaction with Dioxygen (2003) (41)
Reactivity of hypervalent species of silicon: cleavage of the allyl-silicon bond (1987) (41)
Silylamines in organic synthesis. Reactivity of N,N-bis(silyl) enamines toward electrophiles. A route to substituted 2-aza-1,3-butadienes and pyridines (1990) (40)
A simple route to organic–inorganic hybrid materials containing Eu3+ complexes (2001) (40)
The mechanism of nucleophilic substitution at silicon. Action of organometallic reagents on chiral bifunctional silanes (1974) (40)
Synthesis of Stable Organo(bis‐silanetriols): X‐Ray Powder Structure of 1,4‐Bis(trihydroxysilyl)benzene (2000) (40)
Modified electrodes from organic-inorganic hybrid gels formed by hydrolysis-polycondensation of some trimethoxysilylferrocenes (1996) (40)
Structure of silica-based organic–inorganic hybrid xerogel (2000) (39)
Hybrid organic-inorganic xerogel access to meso- and microporous silica by thermal and chemical treatment (1999) (39)
Asymmetric hydrosilylation of ketones catalysed by a chiral rhodium complex (1974) (39)
Chemical and photochemical approaches to amino(aryl)silylenes (1994) (39)
On the behaviour of an optically active cobalt—silicon bond. Evidence for the formation of analogues of silyl-grignard reagents (1977) (38)
Hexacoordinated silicon species: a possible model for reaction intermediates. 1. X-ray determination of the geometry in the solid state (1989) (38)
Pentacoordinate silicon compounds: Stereochemical non-rigidity of chelates formed by intramolecular ring-closure. Crystal structure of 8-dimethylamino-1-trifluorosilylnaphthalene (1994) (38)
Synthesis and structures of hypervalent species of silicon and germanium: toward heptacoordination? (1988) (38)
Extension de la reaction de Michael en presence de CsF/Si(OR)4 (1983) (38)
Hydrolysis/Polycondensation in the Solid State: Access to Crystalline Silica-Based Hybrid Materials. (2001) (38)
The Structures of Tris(8‐dimethylaminol‐naphthyl)phosphane and Tris[2‐(dimethylaminomethyl)phenyl]phosphane: Crystallographic Evidence of Seven‐Coordinate Phosphorus (1993) (38)
Oligomers with Silicon, Germanium and Transit ion Metal Groups: synthesis and Characterization of Metal-Containing Poly[(silylene)diacetylenes] and Poly[(germylene)diacetylenes] (1994) (38)
The one-pot conversion of carboxylic acids to aldehydes via activated silyl carboxylates (1987) (38)
Hybrid Xerogels from Dendrimers and Arborols (1998) (38)
Evidence for an Organization of Nanostructured Silica-Based Hybrid Materials Prepared by Sol−Gel Polymerization (2000) (37)
Mesoporous hybrid materials containing two transition metal ions, one in the framework, the other in the channel poresElectronic supplementary information (ESI) available: SAXA pattern of XCu. See http://www.rsc.org/suppdata/cc/b3/b303492p/ (2003) (37)
PENTACOORDINATE HYDRIDOSILICATES : SYNTHESIS AND SOME ASPECTS OF THEIR REACTIVITY (1991) (37)
Some aspects of the reactivity of hypervalent species of silicon in organic synthesis (1988) (37)
First organic–inorganic hybrid materials with controlled porosity incorporating cyclam units (1999) (37)
Nanoporous materials: a good opportunity for nanosciences (2004) (36)
Base Stabilization of Functionalized Silylene Transition Metal Complexes (1995) (36)
Preparation of oligomers containing tetraphenylsilole, acetylene and aromatic groups in the main chain, and incorporation of iron carbonyl (1993) (36)
Reactivity of Anionic Pentacoordinated Silicon Complexes towards Nucleophiles (1986) (36)
Thermogravimetric Mass Spectrometric investigation of the thermal conversion of organosilican precursors into ceramics under argon and ammonia. 1. Poly(carbosilane) (1992) (36)
Use of the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand for the Study of Nucleophilic Substitution at Hexacoordinate Silicon Centers. Evidence Suggestive of a Heptacoordinate Silicon Transition State (1995) (35)
Organic–inorganic hybrid materials. Preparation and properties of dibenzo-18-crown-6 ether-bridged polysilsesquioxanes (2000) (35)
Electropolymerization of silythiophene monomers: FT-IR and Raman spectroscopy characterization of polythiophene films (1994) (35)
Preparation and characterization of new organic-inorganic hybrid materials incorporating phosphorus centres (1998) (34)
Solid state hydrolysis/polycondensation of alkoxysilane: access to crystal-like silicon-based hybrid materials. (2003) (34)
Adjusting the Porosity of a Silica‐Based Hybrid Material (2000) (34)
Nonhydrolytic Sol-Gel process: Aluminium and zirconium titanate gels (1997) (33)
Stereochemistry of the insertion of manganese into silicon-hydrogen and germanium-hydrogen bonds. Complexes containing a two-electron, three-center manganese...hydrogen...silicon (or germanium) interaction (1984) (33)
Synthesis of large-pore ordered mesoporous silicas containing aminopropyl groups (2005) (33)
Photochemical reaction of 16-e metal species generated from Fe(CO)5, Cr(CO)6, or RCpMn(CO)3 (R = H, Me), with primary and secondary arylsilanes in the presence of internal or external electron donors: formation of functionally stabilized hydrosilanediyl-transition metal complexes (1993) (33)
Organosilicon chemistry and nanoscience (2003) (33)
Hypervalent silicon hydrides: evidence for their intermediacy in the exchange reactions of di- and tri-hydrogenosilanes catalysed by hydrides (NaH, KH and LiAlH4) (1989) (32)
Preparation of ordered SBA-15 mesoporous silica containing chelating groups. Study of the complexation of EuIII inside the pore channels of the materials (2004) (32)
From simple molecules to highly functionalised lamellar materials (2008) (32)
Synthesis and Dynamic Behavior of the Heptafluorotrisilacyclohexane Anion: A New Fluxional Silicate with Rapid Intramolecular Exchange of Fluoride Ligand (1996) (32)
Coordination Chemistry in the Solid: Study of the Incorporation of Cu(II) into Cyclam-Containing Hybrid Materials. (2001) (32)
New Stable Titanocene and Zirconocene Catalyst Precursors for Polysilane Synthesis via Dehydrocoupling of Hydrosilanes (1995) (31)
Pentacoordinate silicon compounds: pseudorotation at silicon (1984) (31)
Study of Silyl Cations Bearing an Aryldiamine Pincer Ligand (1996) (31)
Influence of functional organic groups on the structure of CTAB templated organosilica thin films (2004) (31)
Mechanism of nucleophilic substitution at silicon: kinetic evidence on the slow formation of a pentacoordinate silicon intermediate (1975) (31)
Pentacoordinated silicon anions: synthesis and reactivity (1990) (31)
A facile synthesis of new tetrapyrrole macrocyclic derivatives. Formation of bimetallic transition metal complexes (1991) (30)
Sol–gel process: influence of the temperature on the textural properties of organosilsesquioxane materials (2000) (30)
N,N-bis(silyl)enamines as protected primary vinylamines. Nucleophilic activation of the siliconnitrogen bond. (1982) (30)
Synthesis, chemical behaviour and crystal structure of cobalt-stabilized carbenes, (Ph3Ge)(CO)3CoC(OEt)R (1979) (30)
An efficient synthesis of substituted (Z)-allylamines and 7-membered nitrogen heterocycles from (Z)-3-(tributylstannyl)allylamine (1993) (30)
Oligomers with silicon and transition metal groups: Thermolysis of poly[1,1′-bis(diorganosilylethynyl) ferrocenes] and poly[{(diorganosilylene) diacetylene}dicobalthexacarbonyls] to give iron silicide- and cobalt silicide-based ceramics (1996) (29)
Synthesis and properties of manganese hydrides having a functional silicon (1979) (29)
Preparation and NMR studies of hexacoordinated fluorosilicates: nondissociative fluorine site exchange within the octahedral complexes in solution (1992) (29)
Pentacoordinate dihydridosilicates: synthesis, structure, and aspects of their reactivity (1991) (29)
Self-assembly of layered organosilicas based on weak intermolecular interactions. (2010) (29)
Ferrocenyl compounds containing two hypervalent silicon species. Electrochemical studies (1990) (29)
Uses of SiN bonds in organic synthesis. A direct synthesis of functional protected propargylic primary amines. (1984) (28)
Generation of porosity in a hybrid organic-inorganic xerogel by chemical treatment (1999) (28)
Direct synthesis of ordered mesoporous silica containing iodopropyl groups. A useful function for chemical modifications (2007) (28)
Silylamines in organic synthesis: preparation and some reactions of N,C-dilithiosilylamines (1987) (28)
Electrochemical reduction of triorganohalo-silanes and -germanes☆ (1980) (28)
A New Way to SiC Ceramic Precursors by Catalytic Preparation of Preparation Polymers (1990) (28)
One-step route to silicon carbide precursors by a tunable catalytic polycondensation (1994) (28)
Heterogeneous catalysis in the presence of salts and without solvent (1978) (28)
Role of pentacoordinate intermediates in the hydrolysis reaction of organic silicates (1991) (28)
A New Method for the Reduction of Esters (1981) (28)
Preparation and optical properties of hybrid sol–gel systems containg doubly anchored oligoarylenevinylenes (1996) (27)
Pentacoordinated silicon compounds. Intramolecular ring closure, site preferences of substituents and the stability of the resulting chelates (1990) (27)
On the nucleophilic activation of silyl enol ethers and esters; a survey and mechanistic interpretation (1988) (27)
Preparation of oxynitride silicon glass I. Nitridation of hydrogenosilsesquioxane xerogels (1990) (27)
Hypervalent Silicon Compounds (2004) (27)
Silicon phosphorus analogies. Fluoride activation of nucleophilic displacement at the tetrahedral phosphorus: an example of nucleophilic assistance to nucleophilic substitution. 3 (1984) (27)
Evidence for a template effect in control of organic-inorganic hybrid solid formation by intermolecular interactions (1994) (27)
Nonhydrolytic sol-gel routes to layered metal(IV) and silicon phosphonates (1998) (27)
Hydrogenosilanes: Pentacoordination and pseudorotation (1986) (27)
Reactivity of hypervalent species of silicon: reduction of CO2 to formaldehyde with formation of silanone (1988) (27)
Chemistry of hybrid organic-inorganic. Access to silica materials through chemical selectivity (1997) (26)
Nucleophilic substitution at silicon: Evidence for electronic factors as driving force of the stereochemistry (1978) (26)
Nucleophilic substitution at silicon: influence of the nature of the leaving group on the stereochemistry (1978) (26)
UNSATURATED POLYMERS CONTAINING BORON AND THIOPHENE UNITS IN THE BACKBONE (1998) (25)
Synthesis and characterization of new stable α, ω-organo(bis-silanetriols) (2002) (25)
Direct synthesis of ordered and highly functionalized organosilicas containing carboxylic acid groups (2007) (25)
Synthesis, Structure, and Fluxional Behavior of a Dihydrosilane Bearing an Aryldiamine Pincer Ligand (1995) (25)
Studies of the hydrolysis of ethyl and tert-butyl phosphonates covalently bonded to silica xerogels (2002) (24)
Indium and indium-oxide nanoparticle or nanorod formation within functionalised ordered mesoporous silica (2003) (24)
Influence of kinetic parameters on the textural and chemical properties of silsesquioxane materials obtained by sol-gel process (1999) (24)
Improved Procedure for the Selective Reduction of Carbonyl Compounds and Carboxylic Acid Esters by Potassium Salt-Induced Hydrosilylation (2002) (24)
A general route to five-coordinate hydridosilicates (1989) (24)
Synthesis of bifunctionalized-pore mesoporous organosilica. Study of the accessibility and the distribution of functions in the pore channels (2006) (24)
Reactivity of dianionic hexacoordinate germanium complexes toward organometallic reagents. A new route to organogermanes (1991) (24)
The use of SiC bond in synthesis: preparation of functionalised vinylsilanes from the allyltrimethylsilyl anion and some aspects of their reactivity (1981) (24)
A Compound Containing Hexacoordinated Silicon—a Model for Nucleophilic Attack on Anionic, Pentacoordinated Silicon Species? (1989) (24)
Reactivity of Hypervalent Species: Reactions of Anionic Penta-Coordinated Silicon Complexes towards Nucleophiles (1988) (24)
Reactivity of Fe(CO)4(H)MPh3 (M = Si, Ge) and mechanism of substitution by two-electron-donor ligands: implications for the mechanism of hydrosilylation of olefins catalyzed by iron pentacarbonyl (1989) (24)
Stereochemistry at Silicon (2007) (23)
Coordination chemistry of Group 14 metalloles. 2. Functional 2,5-diphenylsilacyclopentadienes and their use as .eta.4-ligands (1986) (23)
ORGANIC-INORGANIC HYBRID SILICA. INFLUENCE OF THE NATURE OF THE ORGANIC PRECURSOR ON THE TEXTURE AND STRUCTURE OF THE SOLID (1997) (23)
Preparation of Transition Metal Oxides By A Nonhydrolytic Sol-Gel Process (1994) (23)
Influence of the nature of the catalyst on the textural properties of organosilsesquioxane materials (2000) (23)
Arigid pentacoordinate silicon structure generalization of pseudorotation (1986) (23)
Chemical behaviour of a bifunctional organosilane: α-naphthylphenylfluorosilane (1977) (23)
The Thermal Conversion of Poly[(silylene)‐diacetylene] Metal Oxide Composites: A New Approach to β‐SiCMC Ceramics (1992) (23)
Pentavalent hydridosilicates: some aspects of the reactivity of potassium tetraethoxyhydridosilicate (1989) (23)
Organic–inorganic hybrid silica: chemical reactivity as a tool for studying the solid arrangement as a function of molecular structure (1995) (23)
N → P intramolecular stabilization of phosphenium ions and preparation of hypercoordinated phosphanes with unusual properties (1997) (23)
Auto-organization of Nanostructured Organic−Inorganic Hybrid Xerogels Prepared by Sol−Gel Processing: The Case of a “Twisted” Allenic Precursor (2004) (22)
Sol–gel process—influence of ageingon the textural properties of organosilsesquioxane materials (2001) (22)
New preparation of N,N-bis(trimethylsilyl)enamines via iron carbonyl photocatalysed isomerisation of unsaturated amines (1983) (22)
Alkali metal hydrides: new metallating reagents at silicon (1980) (22)
Hexacoordination at silicon: the case of silatranes (1990) (22)
Coordination chemistry in the solid: evidence for coordination modes within hybrid materials different from those in solution. (2002) (22)
1,4-addition reactions to methacrylamide : a one pot synthesis of 3,4-dihydro 2(1H)-pyridinones and 3,5-disubstituted glutarimides (1985) (22)
Analogies between silicon and phosphorus stereochemistry—I: Influence of the leaving group on the stereochemistry of nucleophilic displacement at phosphorus (1979) (21)
Preparation et reactivite de composes chiraux et non chiraux derives de (η5-cyclopentadienyl) dicarbonylfer. stereochimie de la coupure de la liaison fer—silicium (1977) (21)
A Boron-Bridged Tetrathiaporphyrinogen. (1998) (21)
Hypervalent silicon hydrides: evidence of their intermediacy in the reaction of optically active 1-NpPhMeSiH(D) with hydrides (1989) (21)
Chemical and stereochemical behaviour of bifunctional enantiomeric silicon compounds (1978) (21)
One-step template-directed synthesis of multifunctionalised nanoporous silica: on the way to interactive nanomaterials. (2005) (21)
Five-co-ordinated silicon compounds: geometry of formation by intramolecular co-ordination. Crystal structure of 2-(dimethylaminomethyl)phenyl-1-naphthylsilane (1989) (21)
EFFICIENT SYNTHESES OF NEW PHOSPHONATE TERMINATED TRIALCOXYSILANE DERIVED OLIGOARYLENEVINYLENE FLUOROPHORES (1999) (21)
Hexacoordinate silicon species: a possible model for reaction intermediates. II: Nondissociative permutational isomerization in solution (1989) (21)
Functionalisation of the framework of mesoporous organosilicas by rare-earth complexes (2006) (21)
Silyliron carbonyl complexes in organic synthesis: selective conversion of nitriles into N,N-bis(silyl) enamines (1985) (21)
Introduction of optically active triorganogermyl ligands into transition metal complexes. Synthesis of carbene complexes, crystal structure and absolute configuration of cis - S (-)(methylphenyl-1-naphthylgermyl)-(methylethoxycarbene) tetracarbonylmanganese (1982) (20)
Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts (1991) (20)
Synthesis of Monophasic Hybrid Organic−Inorganic Solids Containing [η6-(Organosilyl)arene]chromium Tricarbonyl Moieties (1997) (20)
A re-examination of the electrochemical reduction of halosilanes and halogermanes (1980) (20)
Organogermanium polymers: Pyrolysis chemistry of poly[(germylene)diacetylenes] (1994) (20)
Silicon-phosphorus analogies. Nucleophilic catalysis in the alcoholysis of chlorophosphorus derivatives (1989) (20)
A new and mild access to N-functionalized formamido and thioformamido compounds using hypervalent silicon hydrides (1990) (20)
The chemical behaviour of cobalt-stabilized carbenes having a trisubstituted silyl or germyl ligand. Stereospecific formation of benzoylsilanes from the reaction of organosilyl-cobalt tetracarbonyl derivatives with phenyllithium (1981) (20)
Optically active silylanions. Evidence for the formation of analogues of silyl Grignard reagents (1976) (20)
Long‐Range Order in Non‐porous Hybrid Organic–Inorganic Silicon‐Based Materials by Sol–Gel Processing (2002) (19)
Synthesis and cation-exchange properties of a bis-zwitterionic lamellar hybrid material (2008) (19)
Pentacoordinate silicon and germanium derivatives: molecular structure (1981) (19)
Poly[(silylene)diacetylene]/fine metal oxide powder dispersions : Use as precursors to silicon-based composite ceramics (2000) (19)
Selective lanthanides sequestration based on a self-assembled organosilica. (2010) (19)
Synthesis and Structural Characterization of Functional Bicyclic Intramolecularly Coordinated Aminoarylsilanes in a Series of Dibenzyl(1,5)azasilocines (1997) (19)
Pentacoordinate silicon derivatives: relative apicophilicity of functional groups attached to a silicon atom (1982) (19)
More information about the existence of siliconium ions (1996) (19)
Silicon-phosphorus analogies (1980) (18)
Reactions de michael sur des amides α,β insatures activees par le systeme CsF/Si(OCH3)4 (1986) (18)
Evidences for intramolecular N →P coordination in (8-dimethylamino-1-naphthyl) diphenylphosphane and derivatives (1996) (18)
Cobalt carbonyl complexes of functional ethynylsilanes. Reactivity at the silicon atom (1989) (18)
Synthesis and characterization of functionalized phosphenium ions, stabilized by two intramolecular dative P ← N bonds (1997) (18)
Unexpected reactivity of bifunctional hexagonal hexacoordinated silicon species (1990) (18)
Silylamines in organic synthesis: A new access to functional pyrroles via organocuprates addition on methyl-bis(trimethylsilyl)aminomethylpropiolate (1987) (18)
Functional allylsilanes: reactivity of pyrrolidinoallylsilanes towards electrophiles (1983) (17)
Five-coordinate potassium dihydridosilicates: synthesis and some aspects of their reactivity (1989) (17)
Organosilicon polymers: pyrolysis of poly[(silanylene)diethynylene]s (1990) (17)
Transition-metal complexes corresponding to the insertion into a Group 4A element-carbon bond. 3. Reactivity of complexes with unsaturated carbon-carbon bonds. Crystal structure of (.eta.5-cyclopentadienyl)(triphenylgermyl)(.eta.3-hexenyl)nitrosylmolybdenum (1984) (17)
[Ru(0)]@SiO2 and [RuO2]@SiO2 Hybrid Nanomaterials: From Their Synthesis to Their Application as Catalytic Filters for Gas Sensors (2009) (17)
Hybrid materials and silica: drastic control of surfaces and porosity of xerogels via ageing temperature, and influence of drying step on polycondensation at silicon (2002) (17)
Re-examination of the electrochemical reduction of halogeno-silanes and -germanes (1979) (17)
Reaction of Grignard Reagents with Dianionic Hexacoordinated Silicon Complexes: Organosilicon Compounds from Silica Gel (1986) (17)
Reactivity of Penta‐ and Hexacoordinate Silicon Compounds and Their Role as Reaction Intermediates (1993) (17)
Mixed Si/C/M/O ceramics from 2,5-disilahexane/metal carbonyl (MFe and Co) (1998) (17)
From preceramic polymers with interpenetrating networks to SiC/MC nanocomposites (2000) (17)
Pentacoordinate silicon compounds. reactions of silatranes with nucleophiles (1990) (17)
Nonhydrolytic Sol-Gel Process: Aluminum Titanate Gels. (1997) (17)
Polymer-based materials for amplification in the telecommunication window : Influence of erbium complex concentration on relevant parameters for the elaboration of waveguide amplifiers around 1550 nm (2007) (17)
FAB mass spectra of alkali organobis-(benzene-1,2-diolato) silicates (1988) (17)
Syntheses a partir de carbanions allyliques silicies: II. Methode selective de metallation (1977) (17)
Synthèse et comportement d'un nouvel organogermane optiquement actif, l'isopropylphényl-1-naphtylgermane (1970) (17)
Bridged Polysilsesquioxanes. Molecular‐Engineering Nanostructured Hybrid Organic‐Inorganic Materials (2005) (17)
Self-organization of a tetrasubstituted tetrathiafulvalene (TTF) in a silica based hybrid organic-inorganic material. (2004) (17)
A new trialkoxysilylation reaction, the cross-coupling of (tri-isopropyloxysilyl)methyl grignard reagent with organic halides (1993) (17)
Aminosilanes in organic synthesis. addition of organocopper reagents on γ-bis(trimethylsilyl)amino-α-acetylenic amides, esters and ketones. stereochemistry and some synthetic uses. (1993) (17)
Functionalised mesoporous silica: a good opportunity for controlled peptide oligomerisation (2011) (16)
New route to hybrid materials: Rhodium complex and fluoride ion catalysed hydrolysis of hydrogenosilanes (1994) (16)
Synthesis and characterization of alkylene-bridged silsesquicarbodiimide hybrid xerogels (2003) (16)
A General Nonhydrolytic Sol‐Gel Route to Oxides (1994) (16)
Hybrid organic–inorganic materials. Preparation and properties of dibenzo-18-crown-6 ether-bridged polysilsesquioxanes (1999) (16)
Siliconnitrogen bond formation by nucleophilic activation of siliconhydrogen bonds (1991) (16)
Unexpected coordination chemistry of bisphenanthroline complexes within hybrid materials: a mild way to Eu(2+) containing materials with bright yellow luminescence. (2007) (16)
Reactivity of halogermylenes with various transition-metal complexes. The first germylenes with germanium-transition metal bonds (1983) (16)
Valorization of by-products of the sugar industry: New nanostructured hybrid materials containing sugar derived structures (2010) (16)
Comprar Molecular Chemistry of Sol-Gel Derived Nanomaterials | Robert Corriu | 9780470721179 | Wiley (2009) (16)
Preparation of a diethynyl hypervalent silicon monomer by coordination-selective cleavage: structure and polymerization to give novel polycarbosilanes containing main-chain hexacoordinate silicon (1995) (16)
Sol–gel process: temperature effect on textural properties of a monophasic hybrid material (1999) (15)
A simple synthesis of primary E-allylic amines from 1-tributylstannyl-3-bis(trimethylsilyl)amino prop-1-ene (1991) (15)
(Z)-1-METHOXY-4-(DIPHENYLPHOSPHINO)BUT-1-ENE-3-YNE : A VERSATILE SYNTHON FOR UNSYMMETRICALLY SUBSTITUTED (DIPHENYLPHOSPHINO) DIACETYLENE DERIVATIVES (1997) (15)
Organosilyl iron carbonyl complexes: synthesis and reactivity towards alkynes and nitriles (1980) (15)
Coordination chemistry of group 14 metalloles. 3. Synthesis and reactivity of 1,1-dimethyl- and 1,1,3,4-tetramethylsilole and 1,1,3,4-tetramethylgermole complexes (1987) (15)
SYNTHESIS AND REACTIVITY OF BIS(TRIETHOXYSILYL)METHANE, TRIS(TRIETHOXYSILYL)METHANE AND SOME DERIVATIVES (1998) (15)
Organic-inorganic hybrid materials incorporating phosphorus centres. Evidence for some factors controlling the accessibility of phosphorus centres (1999) (15)
Chemical and Stereochemical Properties of Compounds with Silicon or Germanium-Transition Metal Bonds (1981) (15)
Mechanism of nucleophilic substitution at silicon: evidence against complexation control (SNiSi) for coupling reactions between organosilanes and organolithiums taking place with retention (1978) (14)
Reactions of nucleophilic reagents with dianionic hexacoordinated germanium complexes: a new convenient route to functional organogermanes from germanium dioxide (1988) (14)
Cyclometalation of phosphorus ligands by UV irradiation of complexes having transition metalsilicon bonds (1981) (14)
Auto-Organisation in Silica-Based Organic-Inorganic Gels Obtained by Sol-Gel Process (2003) (14)
Synthesis and crystal structure of chiral chlorotris(carbonylmetallato)tin(IV) complexes (1982) (14)
A new method for the determination of water in organic solvents, and some comments on an electrochemical method of synthesizing SiSi bonds (1981) (14)
Auto-organization of nanostructured organic–inorganic hybrid xerogels prepared from planar precursors by sol–gel processing (2004) (14)
The Silicon-Heteroatom Bond (1991) (1991) (14)
Thermal isomerization of alternating silphenylene‐siloxane copolymer (1994) (14)
Preparation And Structure Of Phosphonium Ions With Intramolecular P ← N Coordination; Novel Diphosphonium Salts And Ionomer Containing Backbone Hypervalent Phosphorus (2000) (14)
Contributions to the chemistry of silicon-sulphur compounds: XLII. Bis(1-methyldibenzosilole)sulphide: its synthesis, crystal structure, and reaction with chromium hexacarbonyl☆ (1986) (14)
Electrical conductivity of FeCl3-doped poly(alkynylsilane)s (1991) (13)
Generic way for functionalised well-ordered cubic mesoporous silica via direct synthesis approach (2010) (13)
FAB mass spectra of alkali bis (benzene-1,2 diolato)phenyl silicates and tris (benzene-1,2 diolato) silicates and germanates: influence of the matrix (1989) (13)
Hydrophobic induced supramolecular self-organization of tetrahedral units based on van der Waals interactions (2006) (13)
Poly[(silylene)diacetylene]–metal oxide composites: A new approach to SiC–metal nitride ceramics (1993) (13)
Alkali metal hydrides: New metallating reagents for germanium and tin (1980) (13)
Siloxane bond formation by heterofunctional condensation of alkoxysilane and halogenosilane. Application to the preparation of copoly(tetramethyl-p-silphenylenesiloxane-dimethylsiloxane) (1994) (13)
Ethynylhydrosilane)cobalt carbonyl complexes. Reactivity of the silicon-hydrogen bond (1990) (13)
Intramolecular nucleophilic catalysis. Stereoselective hydrosilylation of diketones and α-hydroxyketones. (1994) (13)
The mechanism of nucleophilic substitution at silicon: solvent influence on the rates of organometallicorganosilane coupling reactions (1974) (13)
COMPARATIVE STUDY OF THE REACTIVITY OF DIFFERENT HEXACOORDINATE SILICON SPECIES TOWARDS NUCLEOPHILIC REAGENTS (1992) (12)
CRYSTALLOGRAPHIC EVIDENCE OF HEXACOORDINATION AT PHOSPHORUS VIA INTRAMOLECULAR COORDINATION OF DONOR GROUPS ON PHOSPHANE AND PHOSPHANE SULPHIDE (1996) (12)
Preparation of an optically active and other organosilicon derivatives of π-cyclopentadienyliron dicarbonyl (1973) (12)
Long-range ordered lamellar silicon based hybrid materials (2003) (12)
CsF-promoted Michael addition in heterogeneous catalysis (1981) (12)
DISILYLATED IRON CARBONYL COMPLEX AS REAGENT FOR THE CONVERSION OF NITRILES INTO ALDEHYDE-ENAMINES (1981) (12)
X-Ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen (2003) (12)
Unexpected behaviour of a hexacoordinate silicon compound (1993) (12)
Synthesis of new lamellar materials by self-assembly and coordination chemistry in the solids (2008) (12)
Self-organization of porphyrin units induced by magnetic field during sol-gel polymerization. (2007) (12)
Dynamic Stereochemistry at Silicon (2004) (12)
Use of SbF5 intercalated in graphite as fluorinating reagent in organo-silicon and -germanium chemistry (1980) (12)
Solution Chemistry for the Elaboration of Solids (1997) (12)
Monophasic pre-mullite gels prepared by a nonhydrolytic process (1994) (11)
Possibilities of 1,1-dimethylsilole as a ligand in transition-metal chemistry (1983) (11)
Organolithium route to poly(arylsilane)s (1991) (11)
Introduction of Organic Moieties into Transition-Metal Oxide Matrices via Phosphonate Groups (1998) (11)
Synthesis of optically active silicon–iron compounds. Stereochemistry of silicon–iron bond breaking (1975) (11)
HEXACOORDINATE PHOSPHONIUM SALTS InCORPORATING TWO (8-DIMETHYLAMINO)-1-NAPHTHYL LIGANDS. STRUCTURE AND REACTIVITY (1997) (11)
Grignard reagents as powders : preparation and reactivity (1989) (11)
Synthesis and X-ray structure of an sp2 silicon stabilized by two intramolecular coordinations (1994) (11)
Silylamines in Organic Synthesis. Facile Synthetic Routes to Unsaturated Protected Primary Amines. (1992) (11)
Direct syntheses of functionalized mesostructured silica by using an inexpensive silica source. (2004) (11)
Pentaco-ordinate silicon derivatives: 1H n.m.r. evidence (1980) (11)
Where organosilicon chemistry is going (2003) (11)
NUCLEOPHILIC SUBSTITUTIONS AT SILICON AND PHOSPHORUS. A COMPARISON OF CONTROLLING FACTORS (1986) (11)
Influence of angle strain on the stereochemistry of the nucleophilic displacements at silicon: Stereochemical behaviour of optically active systems containing both an intracyclic silicon atom and an intracyclic leaving group. (1980) (11)
Structure of organic–inorganic hybrid solids: influence of the hydrophilicity and hydrophobicity of precursors (2003) (11)
Synthe´se et comportement d'α silyl ce´tones cycliques (1970) (11)
Five-coordinate silicon: synthesis, dynamic behaviour and structure of a cyclic anionic trifluorosilicate forming part of a transition metal complex; crystal structure of 18-crown-6-potassium [μ4-(1,4-diphenylbutadienylene)-tricarbonyliron]trifluorosilicate (1988) (10)
Cleavage of silicon- and germanium-transition metal bonds. Dependences of the stereochemistry on the nature of the ligands and the geometry of complexes (1982) (10)
Influence of the solvent and of the counteranion on the structure of silyl cations stabilized by a terdentate aryldiamine ligand (1997) (10)
Sol-Gel Chemistry of Hydrogenosiliconates: The Role of Hypervalent Silicon Species (1990) (10)
Reactivity of hypervalent silicon derivatives. One step synthesis of mono- and di-hydrogenosilanes (1989) (10)
Reactions of coordinated organosilanes: cobalt carbonyl complexes of ethynylhydrogenosilanes (1989) (10)
Unexpected Reactivity of Functionalized Lewis Base Stabilized Silanediyl Transition Metal Complexes toward Organolithium Nucleophiles (1995) (10)
Organisation and reactivity of silicon-based hybrid materials with various cross-linking levels (2002) (10)
Synthesis of poly(ferrocenyldialkoxysilane) polymers and their introduction into oxide matrices (2001) (10)
29 Si NMR and XPS Investigation of the Structure of Silicon Oxycarbide Glasses Derived from Polysiloxane Precursors (1994) (10)
Electrochemical reduction of transition metal-substituted silicon, germanium and tin derivatives: II. Iron derivatives. Synthesis of distannanes containing Cpc(CO)2Fe groups (1984) (10)
Transition metal complexes corresponding to the insertion into a group IVB element-carbon bond: II. Preparation of manganese complexes. Mechanism of the deinsertion reaction (1984) (10)
Structure and Reactivity of Hypercoordinate Silicon Species (1999) (10)
Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis (2001) (9)
A novel bidentate silicon containing ligand: cyclopentadienyldimethylsilane (1990) (9)
Organosilicon nitrogen compounds (2010) (9)
Unexpected Basicity of a Hexacoordinate Silicon Compound, {2,6‐Bis[ (dimethylamino)methyl]phenyl}bis(1,2‐benzenediolato)silicate (1996) (9)
New mesostructured organosilica with chiral sugar derived structures: nice host for gold nanoparticles stabilisation. (2011) (9)
Preparation of oxynitride silicon glasses II. Bulk oxynitride glasses obtained by hot pressing (1990) (9)
Chimie douce: wide perspectives for molecular chemistry. A challenge for chemists: control of the organisation of matter (2001) (9)
The reaction between organosilyl derivatives of (η5-C5H5)Fe(CO)2 and triphenyl phosphite. New evidence for ortho-metalated phosphite ligands (1977) (9)
Nucleophilic substitutions at silicon (1981) (9)
(Trialkoxysilyl)tetrathiafulvalenes: Precursors of Organized Organic‐Inorganic Hybrid Materials by Sol‐Gel Chemistry (2005) (9)
Coordination chemistry of siloles: synthesis, reactions, and stereochemistry of silicon-substituted (.eta.4-2,5-diphenylsilacyclopentadiene)transition-metal complexes. Crystal structure of dicarbonyl[phenyl((.eta.4-exo-1-methyl-2,5-diphenylsilacyclopentadien-1-yl)oxy)carbene]iron (1989) (9)
Stereospecific route to asymmetric vinylgermanes: hydrogermylation of phenylacetylene catalysed by rhodium and platinum complexes (1971) (9)
Optically Active Triorganosilyl Esters of Phosphorus. Synthesis and Structure. (1986) (8)
The stereochemistry at silicon of an iron to cyclopentadienyl ligand silyl group migration in (η5-C5H5)Fe(CO)2SiR3 (1989) (8)
Hydridosilicates: a new class of pentacoordinated silicon derivatives with unusual properties (1992) (8)
Chapter 1. Hypervalent silicon compounds (2010) (8)
Nonhydrolytic Sol-Gel Process: Aluminium and Zirconium Titanate Gels (1997) (8)
Intramolecular coordination at silicon. The small effect of equatorial ligands on the stability of pentacoordinated organosilanes (1991) (8)
Silicon-phosphorus analogies rate controlling factors in SN2(P) reactions influence of the nucleophile for a given stereochemistry (1983) (8)
Hybrid Organic—Inorganic Silica Materials: Chemical Evidence for Organization in the Solid (1995) (8)
Pt(0)-Based Catalyst Supported on Silica Containing Di(ethylene oxide) Units for Hydrosilylation of Unsaturated Carbon−Carbon Bonds (2007) (8)
Investigations of the nucleophilic displacement at the tetrahedral phosphorus - kinetic effects of the nucleophile for a given stereochemistry (1986) (8)
Catalytically assisted carbon–carbon coupling reaction: a French–Japanese ‘cuisine’ (2002) (8)
Polysilsesquioxane materials containing a dienic unit: unexpected reactivity of the organic unit (2000) (8)
Analogies between silicon and phosphorus stereochemistry—II (1979) (8)
Studies of organic–inorganic solids possessing sensitive oligoarylene–vinylene chromophore-terminated phosphonates (2002) (8)
Auto-organization modulation of tetrasubstituted tetrathiafulvalenes (TTF) in silica based hybrid materials (2006) (8)
Selective Synthesis and Some Electroconductive Properties of Organosilicon Polymers Containing Aromatic Units (1992) (8)
Catalytic trimerization of isocyanates by neutral pentacoordinated silicon hydrides (1991) (8)
Coupling reactions between Grignard reagents and silicon–hydrogen bonds, catalysed by a nickel(II) complex (1970) (8)
TOF-SIMS characterization of the surface of monophase hybrid organic inorganic materials (1998) (8)
Stereochemistry of nucleophilic cleavage of silicon (or germanium)-transition metal bonds. The case of octahedral complexes: an exception to the leaving group rule (1982) (7)
New silica-based hybrid organic–inorganic solids containing oligoarylene-vinylene fluorophore-terminated phosphonates (2001) (7)
Coordination chemistry of siloles: vinyl-, allyl- and alkynyl-siloles; synthesis and structure of η4,η2-1-allyl-and 1-vinyl-2,5-diphenylsilacyclopentadiene complexes (1987) (7)
Use of triorganogermyl-lithium compounds in transition metal chemistry. Application to the synthesis of optically active anions containing a transition metal–germanium bond (1978) (7)
Appendix to ‘Transition‐metal silyl derivatives’ (2010) (7)
Intramolecular nitrogen ligand stabilization of phenyl-imidazolidine derived silicon species (1998) (7)
Exocyclic Substitution of Five-Membered Ring Chlorophosphates: A Reexamination of the rule For Nucleophilic Substitution at Phosphorus (1983) (7)
Nucleophilic substitution at a silicon atom: evidence for an equatorial attack mechanism (1975) (7)
Preparation and characterization of organic- inorganic hybrid materials incorporating diphosphino moieties. Study of the accessibility of the phosphorus atoms included into the material (2000) (7)
Exceptional affinity of nanostructured organic-inorganic hybrid materials towards dioxygen: confinement effect of copper complexes. (2007) (7)
Chapter 9. Transition-metal silyl derivatives (2010) (7)
Auto-organisation of hybrid organic-inorganic materials prepared by sol-gel process. (2002) (7)
Nucleophilic substitution at silicon: influence of the attacking allyllithium and aryloxide anion on the stereochemistry and a simple mechanistic proposal (1982) (7)
A SILICON-COBALT CLUSTER WITH AN UNUSUALLY SHORT CROSS-RING SILICON-SILICON DISTANCE (1997) (7)
EPR investigations of mesoporous silica doped with metal transitions ions (2006) (6)
The van der Waals induced supramolecular organization of hydrophobic tetrahedral units in the course of hydrolytic polycondensation (2006) (6)
Homogeneous catalytic activation of Grignard reagents by nickel complexes. A new stereospecific method for reduction of alkoxy-, chloro-, and fluoro-silanes (1973) (6)
1,4-addition reactions to α,β unsaturated tertiary amides (1982) (6)
LiAlH4 attack at a silicon center : Evidence for ion-pair dissociation as controlling factor of the stereochemistry (1978) (6)
Uses of SiN bonds in synthesis: Easy routes to functional protected primary amines from propargylic silylamines (1984) (6)
Solvent effects on the stereochemistry of coupling reactions of Grignard reagents with organosilanes (1971) (6)
The palladium-catalysed cross-coupling polymerization of diethynylmethyl (n-octyl)silane with dihaloarenes (1993) (6)
Methylphenyltriiphenylgermylsilanes fonctionnels optiquement actifs (1983) (6)
New sodium organobis(silantriolates) (1998) (6)
Preparation and reactivity of the optically active silicon–manganese compound (–)-[(π-methylcyclopentadienyl) Mn(CO)2(H)SiMePh(α-naphthyl)] (1976) (6)
First direct synthesis of highly ordered bifunctionalized mesoporous silica thin films. (2006) (6)
Formation of benzoylsilanes from the reaction of organosilylcobalt tetracarbonyl derivatives with phenyl-lithium (1977) (6)
Synthesis of New Silicon−Cobalt Clusters (1998) (6)
Self-organization of a rigid α,ω-bis-silanediol determined by X-ray crystal structure (2001) (6)
Influence de la tension de cycle sur la vitesse de substitution nucleophile d'organosilanes (1975) (6)
Coordination chemistry of group 14 metalloles (1987) (6)
Methylidyne tricobalt nonacarbonyl clusters; optically active silicon and germanium derivatives, and substitutions at silicon (1981) (6)
Selective reduction of carbonyl compounds by heterogeneous catalysis on salt surfaces (1981) (6)
Aldol Condensations Promoted by a Tetraalkoxysilane in the Presence of Fluoride Ions (1983) (5)
UNEXPECTED REACTIVITY OF HYPERVALENT ANIONIC SPECIES AS ELECTRON ACCEPTORS (1989) (5)
Nonrelaxable Anisotropic Organization of Organic–Inorganic Hybrid Materials Induced by an Electric Field (2002) (5)
Synthesis, characterization, and polycondensation of new stable α,ω-organo(bis-silanediols) (2003) (5)
THERMAL DECOMPOSITION OF HYDROSILSESQUIOXANE GELS UNDER ARGON (1992) (5)
Nanostructured Hybrid Organic–Inorganic Solids from Molecules to Materials (2009) (5)
Organosilicate Oligomers and Nanostructured Materials (2000) (5)
Recent Developments of Molecular Chemistry for Sol‐Gel Processes (1996) (5)
Erbium-doped polymer-based materials and waveguides for amplification at 1,55 μm (2006) (5)
Ceramics and Nanostructures from Molecular Precursors (2000) (5)
Electrochemical reduction of transition metal-substituted silicon, germanium and tin derivatives. I. Cobalt or cobalt and iron complexes (1984) (5)
Chemical transformations of functional polycarbosilanes (1993) (5)
Nucleophilic substitution at silicon: evidence for a parallel with addition reactions to α,β ethylenic ketones (1977) (5)
Sodium, calcium, aluminium, zinc and europium salts of p-phenylenebis(silanetriolate). Access to a new class of organosilicates (1999) (5)
Hydride transfer reactions between penta- and tetra-coordinate silicon derivatives (1992) (5)
Mechanism of nucleophilic substitution at silicon: Kinetic evidence on the slow formation of a five coordinate silicon intermediate in the case of inversion (1975) (5)
Preparation of oxynitride silicon glasses. Nitridation of functional silica xerogels (1992) (5)
Acidity in aqueous mixed solvent systems—III : Influence of the organic solvent molecular structure on the acidity of aquo-organic mixtures (acidity function, water structure, hydrophilic and hydrophobic effects) (1975) (5)
Sol–gel chemistry: evidence of redistributionat silicon atom induced by NaOH as catalystduring ageing (2001) (5)
Mechanism of nucleophilic substitution at silicon: kinetic evidence on the slow formation of a five-co-ordinate silicon intermediate (1973) (4)
New Mixed Organic‐Inorganic Polymers: Hydrolysis and Polycondensation of Bis(trimethoxysilyl)organometallic Precursors. (1993) (4)
Substitution electrophile aromatique (1969) (4)
Coordination chemistry of Group 14 metalloles. 5. Use of dicarbonyl(.eta.5-cyclopentadienyl)(1-methyl-2,5-diphenylsilacyclopentadien-1-yl)iron as a four-electron ligand: chemical properties and dynamic stereochemistry of the complexes (1989) (4)
Reactivity of Dianionic Hexacoordinate Germanium Complexes Toward Organometallic Reagents. A New Route to Organogermanes. (1991) (4)
Introduction to Material Chemistry (2009) (4)
Comparison of two soft chemistry routes for the synthesis of mesoporous carbon/β-SiC nanocomposites (2013) (4)
Chemical and stereochemical behaviour of enantiomeric bifunctional silicon compounds (1976) (4)
Effect of surface chemistry on the thermodynamics and conductivity of water in silica nanopores (2007) (4)
Synthesis of diastereoisomeric transition-metal complexes with five different and independent ligands. Resolution through an optically active germanium (1982) (4)
A Study Using X‐ray Absorption and Emission Spectroscopy of Dioxygen‐Binding Xerogels Incorporating Cyclam Units Complexed with Copper Salts (2005) (4)
Modifying Silica Xerogels by Fluoride-Ion-Catalyzed Chemical Treatment (2001) (3)
A Catalytic Preparation of a New Preceramic Polymer: Transformation into SiC (1992) (3)
Analogies between nucleophilic substitutions at silicon and phosphorus: kinetic and stereochemical studies of five- and six-membered ring oxasilacycloalkanes (1979) (3)
Six-coordinate phosphorus compounds. Crystal structures and dynamic NMR studies of phosphoranes containing chelating ligands (1996) (3)
Cleavage of Silicon‐ and Germanium‐Cobalt Bonds: Change of Stereochemistry with Different Ligands (1981) (3)
Ceramics from Molecular Precursors Transition Metal Activation of Silicon-Carbide Precursors (1995) (3)
Formation of a long range ordered polysilsesquioxane O1.5Si-Ph-SiO1.5 by thermal polycondensation of 1,4-bis(trihydroxysilyl)benzene (2002) (3)
Analogies between the dynamic stereochemistry at silicon and phosphorus. Kinetic study of solvent-induced epimerisation of menthyl chloro(phenyl)phosphonate (1978) (3)
Incorporation of cobalt carbonyl into poly(carbosilane)s containing main chain acetylene and aromatic groups (1993) (3)
Synthesis by neutral surfactant assembly of ordered mesoporous organic-inorganic hybrid materials incorporating phosphorus centres (1999) (3)
Use of an optically active germanium species for the resolution of diastereoisomeric transition metal complexes with five different and independent ligands (1987) (3)
Reactivity of Anionic Pentacoordinated Silicon Complexes Towards Nucleophiles. (1986) (3)
Study of Silyl Cations Bearing an Aryldiamine Pincer Ligand. (1997) (3)
Fluoride activation of nucleophilic displacement at tetrahedral phosphorus (1981) (3)
Pentacoordinate Hydridosilicates: Synthesis and Some Aspects of Their Reactivity. (1991) (3)
Coordination chemistry of siloles: a new aspect of the stereochemical behaviour of (η4-exo- and -endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron complexes (1987) (2)
Appendix to ‘Organosilicon derivatives of phosphorus, arsenic, antimony and bismuth’ (2010) (2)
Group 14 Metalloles. Part 2. Ionic Species and Coordination Compounds (1990) (2)
A New and Mild Access to N-Functionalized Formamido and Thioformamido Compounds Using Hypervalent Silicon Hydrides. (1991) (2)
Coordination chemistry of siloles: reaction of η4-complexed endo-1-chloro-2,5-diphenylsilacyclopentadiene with lithium reagents. Synthesis of new carbenes, and the crystal structure of dicarbonylphenyl(η4-exo-1-methyl-1-oxy-2,5-diphenylsilacyclopentadiene) carbene iron (1987) (2)
Organic–inorganic hybrid materials containing metal phosphine complexes: Evidence for preferential cis configuration of Pd(II) and Pt(II) complexes within the materials (2002) (2)
Synthesis of Carbide Compounds Derived from Colloidal Oxide and Carbohydrate (2010) (2)
A novel route to optically active organosilicon compounds (1971) (2)
NUCLEOPHILIC DISPLACEMENT AT SILICON STEREOCHEMISTRY AND MECHANISTIC IMPLICATIONS (1981) (2)
CHEMICAL AND STEREOCHEMICAL BEHAVIOR OF BIFUNCTIONAL ENANTIOMERIC SILICON COMPOUNDS. I. STUDY OF α-NAPHTHYLFERROCENYLFLUOROSILANE AND -CHLOROFLUOROSILANE (1978) (2)
Chemistry of Hybrid Organic-Inorganic. Access to Silica Materials through Chemical Selectivity (1997) (2)
An Efficient Synthesis of Substituted Z‐Allylamines and 7‐Membered Nitrogen Heterocycles from Z‐3‐(Tributylstannyl)allylamine. (1993) (2)
Some Uses of Silicon-Nitrogen Bonds in Organic Synthesis (1985) (2)
Five-Coordinated Silicon Compounds: Geometry of Formation by Intramolecular Coordination. Crystal Structure of 2-(Dimethylaminomethyl)phenyl-1-naphthylsilane. (1989) (2)
Monophasic Organic—Inorganic Hybrid Materials (1998) (2)
Photochemical Reaction of 16‐e Metal Species Generated from Fe(CO)5, Cr(CO)6, or RCpMn(CO)3 (R: H, Me), with Primary and Secondary Arylsilanes in the Presence of Internal or External Electron Donors: Formation of Functionally Stabilized Hydrosilanediyl‐Transition Metal Complexes. (1993) (2)
A Boron‐Bridged Tetrathiaporphyrinogen. (1998) (2)
Analogies between the dynamic stereochemistry at silicon and phosphorus. Kinetic evidence of nucleophilic solvent participation in the hydrolysis of menthylchloro(phenyl)phosphonate (1978) (2)
Coordination chemistry of silones: Synthesis and reactivity of new silicon-disubstituted (η4-silole) complexes (1987) (2)
Reactivity of Fe(CO)4(H)MPh3 (M: Si, Ge) and Mechanism of Substitution by Two-Electron-Donor Ligands: Implications for the Mechanism of Hydrosilylation of Olefins Catalyzed by Fe(CO)5. (1989) (2)
Resolution of an asymmetric cyclosilane: stereospecific substitution reactions (1967) (2)
A Simple Synthesis of Primary E‐Allylic Amines from 1‐Tributylstannyl‐ 3‐bis(trimethylsilyl)aminoprop‐1‐ene. (1992) (1)
More Information About the Existence of Siliconium Ions. (1996) (1)
Racemization mechanism of asymmetric chlorogermanes (1968) (1)
Organosilicon chemistry II: From molecules to materials. Edited by N. Auner, J. Weis, VCH, Weinheim 1996, xxiii, 852 pp. hardcover, DM 188.00, ISBN 3‐527‐29254‐3 (1996) (1)
Aminosilanes in Organic Synthesis. Preparation of New Expanded Porphyrin Ligands and Bimetallic Transition-Metal Complexes. Crystal Structure of a Tetrapyrrole Macrocycle Dirhodium Complex. (1993) (1)
Co-ordination at a silicon atom: effects on optical rotatory dispersion of α-silyl-ketones (1969) (1)
Facile Reduction of Acid Chlorides (II) and (IV) into Aldehydes (III) and (V) Using Hypervalent Silicon Hydrides (I). (1988) (1)
Oligomers with Silicon, Germanium, and Transition Metal Groups: Synthesis and Characterization of Metal‐Containing Poly((silylene) diacetylenes) and Poly((germylene)diacetylenes). (1995) (1)
Aminosilanes in Organic Synthesis. Addition of Organocopper Reagents on γ‐Bis(trimethylsilyl)amino‐α‐acetylenic Amides, Esters and Ketones. Stereochemistry and Some Synthetic Uses. (1993) (1)
THE REACTION BETWEEN ORGANOSILYL DERIVATIVES OF DICARBONYL(η5-CYCLOPENTADIENYL)IRON AND TRIPHENYL PHOSPHITE. NEW EVIDENCE FOR ORTHO-METALATED PHOSPHITE LIGANDS (1977) (1)
Appendix to ‘Siloxane polymers and copolymers’ (2010) (1)
Aromatic substitution: selectivity and the rate-determining step (1967) (1)
Potassium Trialkyl- and Triarylstannates: Preparation by the Deprotonation of Stannanes with Potassium Hydride (2007) (1)
NUCLEOPHILIC ASSISTANCE IN THE FORMATION OF PYROPHOSPHONATE: EFFECTIVE SIDE-REACTION OF HALOGENOPHOSPHORUS COMPOUNDS WITH WATER IN APROTIC SOLVENTS (1980) (1)
Intramolecular Coordination at Silicon. The Small Effect of Equatorial Ligands Upon the Stability of Pentacoordinated Organosilanes. (1991) (1)
Introduction of an Optically Active Ligand into Transition Metal Complexes with Five Independent Ligands (1981) (1)
From Molecular Chemistry to Hybrid Nanomaterials. Design and Functionalization (2011) (1)
ELECTROCHEMICAL REDUCTION OF TRIORGANOHALOSILANES AND -GERMANES (1980) (1)
Direct synthesis of mesoporous hybrid organic-inorganic silica powders and thin films for potential non linear optic applications (2008) (1)
Appendix to ‘Hypervalent silicon compounds’ (2010) (1)
Stereochemical Behavior of Silicon Five-Membered Rings: A Comparison of the Nucleophilic Displacements of Intracyclic Si-o and Si-S Bonds (2010) (1)
Kinetic evidence for a six-co-ordinate silicon intermediate in the racemisation of chlorosilanes (1971) (1)
Reactivity of Penta‐ and Hexacoordinated Silicon Species (2008) (1)
Thermal conversion of organosilicon cobalt precursors to mixed Si/Co/C/O ceramics (1998) (1)
Stereochemistry of coupling reactions of Grignard reagents with an asymmetric bicyclosilane (1968) (1)
Molecular Chemistry and Nanosciences (2009) (0)
Silica gel with polyazacycloalkaneinheiten (1999) (0)
ACIDITY IN AQUEOUS MIXED SOLVENT SYSTEMS PART 3, INFLUENCE OF THE ORGANIC SOLVENT MOLECULAR STRUCTURE ON THE ACIDITY OF AQUO-ORGANIC MIXTURES (ACIDITY FUNCTION, WATER STRUCTURE, HYDROPHILIC AND HYDROPHOBIC EFFECTS) (1975) (0)
INTRODUCTION OF OPTICALLY ACTIVE TRIORGANYLGERMYL LIGANDS IN TRANSITION-METAL COMPLEXES CONTAINING FIVE INDEPENDENT LIGANDS (1981) (0)
A New Trialkoxysilylation Reaction, the Cross‐Coupling of a (Tri‐ isopropyloxysilyl)methyl Grignard Reagent with Organic Halides. (1993) (0)
A Novel Bidentate Silicon Containing Ligand: Cyclopentadienyldimethylsilane. (1990) (0)
NUCLEOPHILIC ASSISTANCE IN THE FORMATION OF PYROPHOSPHONATE: EFFECTIVE SIDE REACTION OF HALOPHOSPHORUS COMPOUNDS WITH WATER IN APROTIC SOLVENTS (1981) (0)
SELECTIVE ALCOHOLYSIS OF ORGANOSILANES CATALYZED BY A RHODIUM COMPLEX (1976) (0)
Bivalent behaviour of triphenylsilyllithium in reactions with functional organogermanes (1975) (0)
Reactivity of Hypervalent Species: Reactions of Anionic Penta-Coordinated Silicon Complexes Towards Nucleophiles. (1988) (0)
USE OF SILAOXA- AND SILATHIACYCLOALKANE DERIVATIVES IN ORGANOSILICON SYNTHESIS. PREPARATION OF FUNCTIONAL DERIVATIVES ON THE SILICON ATOM AND ON A CARBO CHAIN (1976) (0)
Reaction of Grignard Reagents with Dianionic Hexacoordinated Silicon Complexes: Organosilicon Compounds from Silica Gel. (1986) (0)
Unexpected Reactivity of Hypervalent Anionic Species as Electron Acceptors. (1989) (0)
Catalytic Trimerization of Isocyanates by Neutral Pentacoordinated Silicon Hydrides. (1992) (0)
Synthesis and Solvolysis of [(ω-(Dimethylphenoxysilyl)alkyl]-diphenylphosphines, Phosphine Oxides and Phosphine Sulfides (1987) (0)
Possibility of Heptacoordination at Silicon: Synthesis and X-Ray Crystal Structures of Tris(8-(dimethylamino)naphthyl)silane and Tris(2- ((dimethylamino)methyl)phenyl)fluorosilane. (1994) (0)
USES OF SILICON-NITROGEN BONDS IN ORGANIC SYNTHESIS. A DIRECT SYNTHESIS OF FUNCTIONAL PROTECTED PROPARGYLIC PRIMARY AMINES (1984) (0)
NUCLEOPHILIC SUBSTITUTION AT A SILICON ATOM, EVIDENCE FOR AN EQUATORIAL ATTACK MECHANISM (1975) (0)
Michael Reactions with α,β-Unsaturated Amides Activated by the CsF/Si(OCH3)4 System. (1986) (0)
Grignard Reagents as Powders: Preparation and Reactivity. (1989) (0)
STEREOCHEMICAL PROOF OF THE EXISTENCE OF NUCLEOPHILIC ACTIVATION AT A SILICON ATOM IN NUCLEOPHILIC SUBSTITUTION REACTIONS. SUBSTITUTION OF THE SILICON-CHLORINE BOND WITH RETENTION OF CONFIGURATION (1978) (0)
Coordination Chemistry of Siloles: Synthesis, Reactions, and Stereochemistry of Silicon-Substituted (η4-2,5-Diphenylsilacyclopentadiene)transition-metal Complexes. Crystal Structure of Dicarbonyl(phenyl((η4-exo-1-methyl-2,5-diphenylsi (1989) (0)
HYDROSILYLATION OF ALCOHOLS IN A MOLTEN SALT (1978) (0)
Contributions to the Chemistry of Silicon-Sulphur Compounds. Part 42. Bis(1-methyldibenzosilole)sulphide: Its Synthesis, Crystal Structure, and Reaction with Chromium hexacarbonyl. (1987) (0)
SYNTHESEN MIT SILYLIERTEN ALKYL-CARBANIONEN 1. MITT. CARBANIONEN AUS MONOALKYLSILANEN (1975) (0)
HETEROGENEOUS PHASE SILYLATION OF ALCOHOLS, ALDEHYDES, AND KETONES CATALYZED BY SALTS (1978) (0)
PREPARATION AND REACTIVITY OF CHIRAL AND NONCHIRAL DERIVATIVES OF DICARBONYL(η5-CYCLOPENTADIENYL)IRON. STEREOCHEMISTRY OF THE CLEAVAGE OF THE IRON-SILICON BOND (1977) (0)
Incorporation of Siloxane And Cyclophosphazene Units Into Metal Oxides by a Nonhydrolytic Sol-Gel Route (1998) (0)
Organisation and connectivity in Silicon-based hybrid materials by sol-gel process. (2002) (0)
CLEAVING OF SILICON- AND GERMANIUM-COBALT BONDS: STEREOCHEMICAL CHANGE IN VARIOUS LIGANDS (1981) (0)
Pentacoordinated Silicon Anions: Synthesis and Reactivity. (1990) (0)
ALKALI METAL HYDRIDES: NEW METALATING REAGENTS AT SILICON (1980) (0)
NEW PREPARATION OF N,N-BIS(TRIMETHYLSILYL)ENAMINES VIA IRON CARBONYL PHOTOCATALYZED ISOMERIZATION OF UNSATURATED AMINES (1984) (0)
ORGANOSILANE REACTIONS CATALYZED BY RHODIUM COMPLEXES, SYNTHESIS OF POLYFUNCTIONAL ORGANOSILANES (1977) (0)
Halogenation of Pentavalent Silanes via Formation of a Hexavalent Species as Intermediates. (1990) (0)
A Mild Approach to N-Acylformamidines and C-Acylamidines by the Facile Reduction of Cyrbodiimides with Pentacoordinated Silicon Hydrides. (1992) (0)
Silylamines in Organic Synthesis: A New Access to Functional Pyrroles via Organocuprates Addition on Methyl Bis(trimethylsilyl)aminomethylpropiolate. (1987) (0)
THE SYNTHESIS OF R(+) or S(-) α-NAPHTHYLPHENYLMETHYLSILANE (1988) (0)
Unexpected Reactivity of Bifunctional Hexacoordinated Silicon Species. (2010) (0)
SYNTHESIS, CHEMICAL BEHAVIOR AND CRYSTAL STRUCTURE OF COBALT-STABILIZED CARBENES, (PH3GE)(CO)3COC(OET)R (1980) (0)
Aminosilanes in organic synthesis. Hydrostannation of N,N-bis(trimethylsilyl)propargylamine. Facile and selective routes to (E)-allylic amines (1993) (0)
USE OF ANTIMONY(V) FLUORIDE INTERCALATED IN GRAPHITE AS FLUORINATING REAGENT IN ORGANOSILICON AND -GERMANIUM CHEMISTRY (1980) (0)
Coordination Chemistry of Group 14 Metalloles. Part 3. Synthesis and Reactivity of 1,1-Dimethyl- and 1,1,3,4-Tetramethylsilole and 1,1,3,4-Tetramethylgermole Complexes. (1987) (0)
(Ethynylhydrosilane)cobalt Carbonyl Complexes. Reactivity of the Silicon-Hydrogen Bond. (1990) (0)
Analogous Behavior Between Silicates and Phosphates in Methanolysis Reaction. (1989) (0)
Appendix to ‘Organosilicon nitrogen compounds’ (2010) (0)
Catalyzed Methanolysis of Five Membered Ring Phosphoenolates (1987) (0)
The Chemistry of Organosilanes: Recent Investigations and Perspectives (1986) (0)
ADDITION VON GRIGNARD-REAGENZIEN AN VINYLSILANE (1971) (0)
SYNTHESIS OF OPTICALLY ACTIVE SILICON-IRON COMPOUNDS. STEREOCHEMISTRY OF SILICON-IRON BOND BREAKING (1975) (0)
EFFECT OF THE CYCLE TENSION ON THE NUCLEOPHILIC SUBSTITUTION RATE OF ORGANOSILANES (1976) (0)
A process for preparing polyazacycloalkane-containing cogels and their use (1999) (0)
SILICON PHOSPHORUS ANALOGIES. FLUORIDE ACTIVATION OF NUCLEOPHILIC DISPLACEMENT AT THE TETRAHEDRAL PHOSPHORUS: AN EXAMPLE OF NUCLEOPHILIC ASSISTANCE T NUCLEOPHILIC SUBSTITUTION. 3 (1984) (0)
A New Trend in Metal‐Alkoxide Chemistry: The Elaboration of Monophasic Organic—Inorganic Hybrid Materials (1998) (0)
First Organic—Inorganic Hybrid Materials with Controlled Porosity Incorporating Cyclam Units. (2010) (0)
Synthesis of New Lamellar Materials by Self‐Assembly and Coordination Chemistry in the Solids (2009) (0)
Tailored Organometallic Polymers (1993) (0)
Mesoporous Silica-Supported Ru-NHC Catalysts for Alkene Metathesis (2010) (0)
THE MECHANISM OF NUCLEOPHILIC SUBSTITUTION AT SILICON, ACTION OF ORGANOMETALLIC REAGENTS ON CHIRAL BIFUNCTIONAL SILANES (1974) (0)
ASYMMETRIC SYNTHESIS AT SILICON PART 1, HYDROSILYLATION OF CARBONYL COMPOUNDS CATALYSED BY A CHIRAL PHOSPHINE-RHODIUM COMPLEX, STEREOCHEMISTRY AND MECHANISM (1975) (0)
ASYMMETRIC SYNTHESIS AT SILICON. II. ALCOHOLYSIS OF PROCHIRAL ORGANOSILICON COMPOUNDS CATALYZED BY RHODIUM COMPLEXES (1977) (0)
Hydrolysis/Polycondensation in the Solid State: Access to Crystalline Silica-Based Hybrid Materials The authors are grateful to Dr. C. Dumas from the LBS laboratory at the Université de Montpellier I for the two-dimensional X-ray analysis. (2001) (0)
Intramolecular Base-Stabilization of Unsaturated Si=N- and Si=P- Silicon Compounds and Related Silanediyl-Transition-Metal Complexes. (1991) (0)
NUCLEOPHILIC SUBSTITUTION AT SILICON- INFLUENCE OF THE NATURE OF THE LEAVING GROUP ON THE STEREOCHEMISTRY (1978) (0)
USE OF THE SILICON-CARBON BOND IN SYNTHESIS: PREPARATION OF FUNCTIONALIZED VINYLSILANES FROM THE ALLYLTRIMETHYLSILYL ANION AND SOME ASPECTS OF THEIR REACTIVITY (1981) (0)
Silylamines in Organic Synthesis: Preparation and Some Reactions of N,C-Dilithiosilylamines. (1988) (0)
N,N-BIS(SILYL)ENAMINES AS PROTECTED PRIMARY VINYLAMINES. NUCLEOPHILIC ACTIVATION OF THE SILICON-NITROGEN BOND (1982) (0)
THE CHEMICAL BEHAVIOR OF COBALT-STABILIZED CARBENES HAVING A TRISUBSTITUTED SILYL OR GERMYL LIGAND. STEREOSPECIFIC FORMATION OF BENZOYLSILANES FROM THE REACTION OF ORGANOSILYL-COBALT TETRACARBONYL DERIVATIVES WITH PHENYLLITHIUM (1981) (0)
Coordination Chemistry of Group 14 Metalloles. Part 5. Use of Dicarbonyl(η5-cyclopentadienyl)(1-methyl-2,5-diphenylsilacyclopentadien-1-y# l)iron as a Four-Electron Ligand: Chemical Properties and Dynamic Stereochemistry of the Comple (1990) (0)
PREPARATION OF MONO- AND DIFUNCTIONAL 2,5-DIPHENYL-1-SILACYCLOPENTADIENES (1985) (0)
EXTENSION OF THE MICHAEL REACTION IN THE PRESENCE OF CESIUM FLUORIDE/ALKOXYSILANE (SI(OR)4) (1983) (0)
Chemistry Leading to Interactive Nanomaterials (2009) (0)
Analogies between nucleophilic substitutions at silicon and phosphorus: kinetic and stereochemical studies of five- and six-membered ring oxa- and thiasilacycloalkanes (1984) (0)
STEREOCHEMICAL BEHAVIOR OF SILICON FIVE-MEMBERED RINGS: A COMPARISON OF THE NUCLEOPHILIC DISPLACEMENTS OF INTRACYCLIC SILICON-OXYGEN AND SILICON-SULFUR BONDS (1981) (0)
Pentavalent Hydridosilicates: Some Aspects of the Reactivity of Potassium Tetraethoxyhydridosilicate. (1989) (0)
Silylamines in Organic Synthesis. Reactivity of N,N-Bis(silyl) Enamines Toward Electrophiles. A Route to Substituted 2-Aza-1,3-butadienes and Pyridines. (1990) (0)
Introduction of Optically Active Triorganogermyl Ligands into Transition Metal Complexes. Crystal Structure and Absolute Configuration of cis-S-(-)(Methylphenyl-1-naphtylgermyl)-(methylethoxycarbene)te-tracarbonylmanganese. (1982) (0)
Appendix to ‘Chemistry of compounds with silicon–sulphur, silicon–selenium and silicon–tellurium bonds’ (2010) (0)
1,4-ADDITION REACTION TO METHACRYLAMIDE: A ONE POT SYNTHESIS OF 3,4-DIHYDRO-2(1H)-PYRIDINONES AND 3,5-DISUBSTITUTED GLUTARIMIDES (1985) (0)
A Facile Synthesis of New Tetrapyrrole Macrocyclic Derivatives. Formation of Bimetallic Transition Metal Complexes. (1991) (0)
Reactivity of Hypervalent Species of Silicon: Reduction of CO2 to Formaldehyde with Formation of Silanone. (1988) (0)
USE OF TRIMETHYLSILYL CHLOROSULFONATE AS A SELECTIVE AGENT FOR SILICON-ARYL BOND CLEAVAGE (1978) (0)
Investigations of the Nucleophilic Displacement at the Tetrahedral Phosphorus. Kinetic Effects of the Nucleophile for a Given Stereochemistry. (1987) (0)
SYNTHESIS OF FUNCTIONAL CYCLODISILANES. STUDY OF THE PREPARATION OF OPTICALLY ACTIVE DISILANES (1978) (0)
The Design, Activation and Selective Transformation of Organometallic Compounds into Common and Exotic Materials (1988) (0)
Cobalt Carbonyl Complexes of Functional Ethynylsilanes. Reactivity at the Silicon Atom. (1990) (0)
SYNTHESIS USING ALLYLIC SILYL CARBANIONS. II. SELECTIVE METHOD OF METALATION (1977) (0)
New silica gel incorporating polyazacycloalkanes patterns, process for the preparation and use (1998) (0)
SYNTHESIS OF OPTICALLY ACTIVE α-FERROCENYLSILANES, REACTION STEREOCHEMISTRY (1976) (0)
Triorganosilylpotassium Compounds: Novel Access and Some Aspects of Their Reactivity. (1986) (0)
Silicon‐Phosphorus Analogies. Nucleophilic Catalysts in the Alcoholysis of Chlorophosphorus Derivatives. (1989) (0)
(2‐Dimethylaminomethylphenyl)phenylsilane (2001) (0)
CHEMICAL AND STEREOCHEMICAL BEHAVIOR OF ENANTIOMERIC BIFUNCTIONAL SILICON COMPOUNDS (1977) (0)
From Nano‐Object to Nanomaterial (2009) (0)
CHEMICAL BEHAVIOR OF A BIFUNCTIONAL ORGANOSILANE- α-NAPHTHYLPHENYLFLUOROSILANE (1977) (0)
Cooperative processes in polar-ordered polymers (1993) (0)
SILICON-PHOSPHORUS ANALOGIES. RATE-CONTROLLING FACTORS IN SN2(P) REACTIONS. INFLUENCE OF THE NUCLEOPHILE FOR A GIVEN STEREOCHEMISTRY (1984) (0)
A Hexa-Coordinated Silicon Compound - A Model for the Nucleophilic Attack on Anionic, Penta-Coordinated Silicon Species? (1989) (0)
HETEROGENEOUS CATALYSIS IN THE PRESENCE OF SALTS AND WITHOUT SOLVENT. II. HYDROSILYLATION OF SATURATED AND α,β-ETHYLENEALDEHYDES AND -KETONES (1979) (0)
Pentacoordinate dihydridosilicates: synthesis, structure, and aspects of their reactivity. [Erratum to document cited in CA115(21):232329k] (1992) (0)
HETEROGENEOUS CATALYSIS BY SALTS AND WITHOUT SOLVENT. III. SYNTHESIS OF α,β-UNSATURATED CARBONYL COMPOUNDS FROM SILYL ENOL ETHERS (1980) (0)
The Mechanism of Nucleophilic Activation at Silicon (1987) (0)
Organosilicon Chemistry and Nanosciences (2005) (0)
Structure of a (4 + 4)-Coordinate Silicon Compound, a Precursor of Hypercoordinate Silyl Mono- and Dications. (1994) (0)
THE MECHANISM OF NUCLEOPHILIC SUBSTITUTION AT SILICON, SOLVENT INFLUENCE ON THE RATES OF ORGANOMETALLIC-ORGANOSILANE COUPLING REACTIONS (1974) (0)
Thermal Conversion of Poly((silylene)diacetylene) Metal Oxide Composites: A Novel Route to β‐SiC‐MC‐Ceramics. (1992) (0)
ASYMMETRIC SYNTHESIS AT SILICON. HYDROSILYLATION OF CHIRAL KETONES CATALYSED BY RHODIUM COMPLEXES (1977) (0)
O,O‐Disubstituted Pentacoordinated Functional Cyclic Organosilanes. (1991) (0)
ChemInform Abstract: Catalytically Assisted Carbon-Carbon Coupling Reaction: A French-Japanese “Cuisine”. (2002) (0)
OPTICALLY ACTIVE SILYL ANIONS. EVIDENCE FOR THE FORMATION OF ANALOGS OF SILYL GRIGNARD REAGENTS (1976) (0)
A method for manufacturing co-gels with polyazacycoalkanenheder and use thereof (1999) (0)
Dilithium Derivative of 1,5‐Bis(dimethylamino)naphthalene Precursor of Compounds with Two Pentacoordinated Silicon Atoms. (1992) (0)
Unexpected Behavior of a Hexacoordinate Silicon Compound. (1993) (0)
Transition metal complexes corresponding to the insertion into a group IVB element-carbon bond. I: Introduction of group IVB element anions in cyclopentadienyl transition metal complexes; nucleophilicity (1984) (0)
USES OF SILICON-NITROGEN BONDS IN SYNTHESIS: EASY ROUTES TO FUNCTIONAL PROTECTED PRIMARY AMINES FROM PROPARGYLIC SILYLAMINES (1985) (0)
The One-Pot Conversion of Carboxylic Acids to Aldehydes via Activated Silyl Carboxylates. (1988) (0)
MECHANISM OF NUCLEOPHILIC SUBSTITUTION AT SILICON, KINETIC EVIDENCE ON THE SLOW FORMATION OF A FIVE COORDINATE SILICON INTERMEDIATE IN THE CASE OF INVERSION (1975) (0)
Reactivity of Hypervalent Species of Silicon: Cleavage of the Allyl- Silicon Bond. (1988) (0)
Aminosilylation of Heterocumulenes and the Intramolecular Decomposition of Their Silylfunctionalized Adducts. (1992) (0)
INFLUENCE OF ANGLE STRAIN ON THE STEREOCHEMISTRY OF THE NUCLEOPHILIC DISPLACEMENTS AT SILICON: STEREOCHEMICAL BEHAVIOR OF OPTICALLY ACTIVE SYSTEMS CONTAINING BOTH AN INTRACYCLIC SILICON ATOM AND AN INTRACYCLIC LEAVING GROUP (1981) (0)
Silicon-Nitrogen Bond Formation by Nucleophilic Activation of Silicon- Hydrogen Bonds. (1991) (0)
Reactions of Nucleophilic Reagents with Dianionic Hexacoordinated Germanium Complexes: A New Convenient Route to Functional Organogermanes from Germanium Dioxide. (1988) (0)
Chemical and Photochemical Approaches to Amino(aryl)silylenes. (1994) (0)
OPTICALLY ACTIVE FUNCTIONAL METHYLPHENYLTRIPHENYLGERMYLSILANES. II. CLEAVAGE REACTIONS OF THE SILICON-GERMANIUM BOND (1983) (0)
Polyfunctional Carbosilanes and Organosilicon Compounds. Synthesis via Grignard Reactions. (1993) (0)
Synthesis of poly(ferrocenyldialkoxysilane) polymers and formation of gels by non-hydrolytic gelation methods (1998) (0)
New hybrid nanomaterials, their preparation and their use as filters for gas sensors (2006) (0)
La chimie des organosilanes: récentes acquisitions et perspectives (1986) (0)
Reactions of Coordinated Organosilanes: Cobalt Carbonyl Complexes of Ethynylhydrogenosilanes. (1990) (0)
Reactivity of Hypervalent Silicon Derivatives. One-Step Synthesis of Mono- and Dihydrogenosilanes. (1989) (0)
Preparation and Structure of Silicon Oxycarbide Glasses Derived from Polysiloxane Precursors (1997) (0)
Five-Coordinate Potassium Dihydridosilicates: Synthesis and Some Aspects of Their Reactivity. (1989) (0)
Hexacoordination at Silicon: The Case of Silatranes. (1990) (0)
A General Route to Five-Coordinate Hydridosilicates. (1989) (0)
Pentacoordinate Silicon Compounds. Reactions of Silatranes with Nucleophiles. (1990) (0)
Structure of dioxygen binding xerogels incorporating cyclams complexed with CuCl2 salts (2005) (0)
Prospects and Stakes (2009) (0)
Hydride Transfer Reactions Between Penta- and Tetracoordinate Silicon Derivatives. (1993) (0)
Supramolecular Self‐Organization in Non‐Crystalline Hybrid Organic—Inorganic Nanomaterials Induced by van der Waals Interactions (2006) (0)
Formation and Reactivity of Compounds with Si-S and Si-Se Double Bonds. First X-Ray Structure Analysis of a Silanethione. (1989) (0)
Reactivity of Dianionic Hexacoordinated Silicon Complexes Toward Nucleophiles: A New Route to Organosilanes from Silica. (1988) (0)
RHODIUM COMPLEX-CATALYZED REACTIONS OF O-BIS(DIMETHYLSILYL)BENZENE WITH NITRILES (1982) (0)
CHEMICAL AND STEREOCHEMICAL BEHAVIOR OF ASYMMETRIC FLUOROALKOXYSILANES. PART 3. REACTIONS WITH SATURATED ORGANOLITHIUM COMPOUNDS (1979) (0)
PREPARATION AND REACTIVITY OF THE OPTICALLY ACTIVE SILICON-MANGANESE COMPOUND (-)-DICARBONYLHYDRIDO(η5-METHYLCYCLOPENTADIENYL)(1-NAPHTHYLPHENYLMETHYLSILY# L)MANGANESE (1977) (0)

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