Robert Owen Hutchins
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American chemist
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Robert Owen Hutchinschemistry Degrees
Chemistry
#2539
World Rank
#3462
Historical Rank
#751
USA Rank
Organic Chemistry
#534
World Rank
#617
Historical Rank
#106
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Chemistry
Robert Owen Hutchins's Degrees
- Masters Chemical Engineering Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is Robert Owen Hutchins Influential?
(Suggest an Edit or Addition)According to Wikipedia, Robert Owen Hutchins was an American organic chemist and educator. Born in Danville, Illinois, Hutchins earned a B.S. degree from the University of California at Berkeley in 1961, an M.A. degree in phytochemistry from California State University, Long Beach in 1962, and a Ph.D. degree in organic chemistry from Purdue University under Joseph Wolinsky in 1967. He then completed a two-year post-doctoral research position with Ernest L. Eliel at Notre Dame University,
Robert Owen Hutchins's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Selective deoxygenation of ketones and aldehydes including hindered systems with sodium cyanoborohydride (1973) (168)
- Conformational analysis. XVIII. 1,3-Dithianes. Conformational preferences of alkyl substituents and the chair-boat energy difference (1969) (110)
- Nucleophilic borohydride: selective reductive displacement of halides, sulfonate esters, tertiary amines, and N,N-disulfonimides with borohydride reagents in polar aprotic solvents (1978) (104)
- CYANOBOROHYDRIDE. UTILITY AND APPLICATIONS IN ORGANIC SYNTHESIS. A REVIEW (1979) (95)
- Repulsion of syn-axial electron pairs. The rabbit-ear effect (1968) (90)
- Stereoselective reductions of substituted cyclohexyl and cyclopentyl carbon-nitrogen .pi. systems with hydride reagents (1983) (83)
- Selective reductive displacement of alkyl halides and sulfonate esters with cyanoborohydride reagents in hexamethylphosphoramide (1977) (73)
- Regio- and stereoselective cleavage of epoxides with cyanoborohydride and boron trifluoride etherate (1981) (69)
- Reduction of C N to CHNH by Metal Hydrides (1991) (67)
- Synthetic utility and mechanism of the reductive deoxygenation of .alpha.,.beta.-unsaturated p-tosylhydrazones with sodium cyanoborohydride (1975) (66)
- Regio- and stereoselective reductive replacement of allylic oxygen, sulfur, and selenium functional groups by hydride via catalytic activation by palladium(0) complexes (1982) (64)
- Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes (1980) (64)
- Sodium borohydride in acetic acid. A convenient system for the reductive deoxygenation of carbonyl tosylhydrazones (1978) (60)
- Reduction of aromatic nitro compounds with sodium borohydride in dimethyl sulfoxide or sulfolane. Synthesis of azo or azoxy derivatives (1971) (47)
- Doubly connected phosphorus cations. Diaminophosphenium ions from 2-R-2-phospha-1,3-diazacyclohexanes (1972) (46)
- Reductions of conjugated carbonyl compounds with cyanoborohydride in acidic media (1975) (41)
- Selective reduction of aliphatic ketones and aldehydes to hydrocarbons with sodium cyanoborohydride and p-toluenesulfonyl hydrazide in dimethylformamide-sulfolane (1971) (40)
- Aqueous polar aprotic solvents. Efficient sources of nucleophilic oxygen (1983) (38)
- A CONVENIENT AND STEREOSELECTIVE DITHIOL SYNTHESIS (1975) (38)
- Tetrabutylammonium cyanoborohydride. New, exceptionally selective reducing reagent (1973) (37)
- The selective reduction of .alpha.,.beta.-unsaturated esters, nitriles and nitro compounds with sodium cyanoborohydride (1976) (36)
- Endocyclic vs. exocyclic attack in nucleophilic displacement reactions on five- and six-membered cyclic onium salts (1976) (35)
- μ-Bis(cyanotrihydroborato)-tetrakis(triphenylphosphine) dicopper(I). A new, selective, pH dependent reducing agent (1980) (34)
- Aminoborohydrides as reducing agents. 1. Sodium (dimethylamino)- and (tert-butylamino)borohydrides as selective reducing agents (1984) (34)
- Reduction of C X to CH 2 by Wolff–Kishner and Other Hydrazone Methods (1991) (30)
- Asymmetric reduction of phosphinyl imines with hydride reagents. Enantioselective synthesis of chiral primary amines (1987) (30)
- Cyanoborohydride supported on an anion exchange resin as a selective reducing agent (1979) (29)
- Tetraalkylammonium trihydridocyanoborates. Versatile, selective reagents for reductive aminations in nonpolar media (1981) (27)
- ASYMMETRIC REDUCTIONS OF CARBON-NITROGEN DOUBLE BONDS. A REVIEW (1994) (26)
- Sodium borohydride in dimethyl sulfoxide or sulfolane. Convenient systems for selective reductions of primary, secondary and certain tertiary halides and tosylates (1969) (25)
- Selective demethylation of quaternary salts with lithium propylmercaptide in hexamethylphosphoramide (1973) (25)
- Structural and conformational studies of 2-phenyl-1,3,2-diaza- and -dioxaboracycloalkanes (1972) (20)
- The conformational preference of the diphenylphosphinoyl group in cyclohexane (1986) (20)
- Selective dehydration of secondary alcohols with methyltriphenoxyphosphonium iodide in hexamethylphosphoramide (1972) (20)
- Stereoselective Hydride Reductions of Cyclic N-Diphenylphosphinyl Imines. Highly Diastereoselective Syntheses of Protected Primary Amines (1995) (19)
- Reductive deamination of primary amines. Sodium borohydride reduction of N,N-disulfonimides in hexamethylphosphoramide (1975) (19)
- Orange benzene. Neutral dichromate oxidations in organic solvents (1977) (19)
- Conformational analysis of phosphorus heterocycles. Proton and phosphorus-31 nuclear magnetic resonance study of N,N'-dimethyl-(2R)-2-phospha-1,3-diazacyclohexanes (1972) (19)
- Selective reductions of conjugated acetylenes with magnesium in methanol and methanol-D (1989) (18)
- Floral Initiation of Xanthium in Response to Application of an Extract from a Day-Neutral Plant (1962) (18)
- Reductions of Alkyl and Aryl Halides with Magnesium and Methanol (1989) (18)
- Preparation of N-diprotected allylic amines with palladium(0)-catalyzed coupling reactions (1994) (18)
- Sodium cyanoborohydride in hexamethylphosphoramide. An exceptionally selective reagent system for the reduction of alkyl iodides, bromides, and tosylates (1971) (18)
- AMINE BORANES AS SELECTIVE REDUCING AND HYDROBORATING AGENTS. A REVIEW (1984) (17)
- UTILITY AND APPLICATIONS OF BORANE DIMETHYLSULFIDE IN ORGANIC SYNTHESIS. A REVIEW (1981) (17)
- Convenient synthesis of labile optically active secondary alkyl bromides from chiral alcohols (1976) (16)
- Photoinduced rearrangement and related reactions of ethyl N-phenylcarbamate (1976) (15)
- Nonchair conformations in phosphorus-containing cyclohexanes. Crystal and molecular structures of cis- and trans-2-phenyl-2-oxo-5-tert-butyl-1,3,2-dithiaphosphorinanes and cis-2-phenyl-5-tert-butyl-1,3,2-dithiaphosphorinane (1979) (14)
- Zeolite molecular sieves as dehydrating agents during the preparation of coordination compounds (1975) (14)
- Aromatic denitration with borohydride. Nucleophilic displacement of nitrite by hydride (1973) (14)
- Isomerization of carvone tribromides. Hydrohalide-catalyzed elimination and readdition (1970) (13)
- Highly stereoselective synthesis of cyclic primary amines via hydride reductions. (1984) (12)
- Conformational analysis of 2-phospha-1,3-dithiacyclohexanes. Further evidence for the general axial preference of phosphorus substituents in saturated six-membered rings (1972) (12)
- Reduction of tertiary halides to hydrocarbons with sodium borohydride in sulfolane (1971) (11)
- Neighboring group assistance in azabicyclic derivatives. Tremendous rate accelerations in 2-aza-6-halobicyclo[2.2.2]- and 6-aza-4-halobicyclo[3.2.1]octanes (1975) (11)
- Synthesis of a novel series of 3‐substituted [1]benzothieno[3,2‐d]pyrimidine derivatives (1985) (10)
- Conformational control. An important factor in the stereoselective reduction of ketones by bulky hydride reagents (1977) (10)
- Chemical Control of Flowering, Concentration of a Floral-Inducing Entity from Plant Extracts (1963) (10)
- A superior and general synthesis of enantioenriched 2-oxathianyl ketones (1993) (9)
- A reinvestigation of the chemistry of pinol (1971) (9)
- Synthesis and biological activity of 5-hydroxy analogs of a-ecdysone (1971) (9)
- Highly diastereoselective reductions of N-diphenylphosphinyl imines. Synthesis of axial primary cyclic amines. (1988) (9)
- Favorskii rearrangement of cis- and trans-carvone tribromides. I. Primary amines (1968) (9)
- Phosphorus-containing cyclohexanes. Nuclear magnetic resonance studies and conformational analysis of 1,3,2-dithiaphosphorinanes (1981) (9)
- An improved synthesis of 2-oxathianyl ketones (1990) (8)
- Stereoselective synthesis of meso-N,N'-dicarbethoxy-2,4-diaminopentane and meso-2,4-diaminopentane (1972) (7)
- An Efficient Approach to Spirosesquiterrenes. Synthesis of (±)β-Vetivone. (1984) (6)
- REDUCTIONS OF HETEROCYCLIC SYSTEMS; I. THE SELECTIVE REDUCTION OF 4-SUBSTITUTED PYRIDINIUM SALTS WITH CYANOBOROHYDRIDE (1979) (6)
- Phosphorus-containing cyclohexanes. Stereochemical analysis of cis- and trans-2-phenyl-2-oxo-5-tert-butyl-1,3,2-dithiaphosphorinanes (1977) (5)
- Favorskii rearrangement and Grob fragmentation of carvone tribromides (1972) (5)
- An efficient, general synthesis of spiroalkenes and related derivatives (1977) (5)
- Stereochemical aspects of phosphorus‐containing cyclohexanes (2007) (5)
- Oxidaton of benzylamines with nitrosobenzene (1973) (4)
- STEREOSELECTIVE HYDRIDE REDUCTIONS OF CYCLIC ALPHA , BETA -UNSATURATED N-DIPHENYLPHOSPHINYL IMINES TO PROTECTED ALLYLIC AMINES (1998) (4)
- Isolation and tentative identification of a new constituent of bourbon vanilla bean extract (1981) (3)
- Reductions of Alkyl and Aryl Halides with Magnesium and Methanol. (1990) (3)
- Synthesis and characterization of diethylmethylene diphosphonato metal complexes (1973) (3)
- Diethyl tert‐Butylmalonate (2003) (2)
- Reduction of Alkyl Halides and Tosylates with Sodium Cyanoborohydride in Hexamethylphosphoric Triamide (HMPA): A. 1‐Iododecane to n‐Decane B. 1‐Dodecyl Tosylate to n‐Dodecane (2003) (2)
- An Efficient and Mild Method for the Dehydrogenation of Spiroenones to Spirodienones via Organoselenium Reagents (1980) (2)
- NUCLEOPHILIC BOROHYDRIDE- SELECTIVE REDUCTIVE DISPLACEMENT OF HALIDES, SULFONATE ESTERS, TERTIARY AMINES, AND N,N-DISULFONIMIDES WITH BOROHYDRIDE REAGENTS IN POLAR APROTIC SOLVENTS (1978) (2)
- (Diethyl methylene diphosphonato) (diethyl hydrogen methylene diphosphonato)-vanadium (III) (1972) (2)
- STEREOSELECTIVE REDUCTIONS OF SUBSTITUTED CYCLOHEXYL AND CYCLOPENTYL CARBON-NITROGEN Π SYSTEMS WITH HYDRIDE REAGENTS (1984) (2)
- THE SELECTIVE REDUCTION OF α,β-UNSATURATED ESTERS, NITRILES AND NITRO COMPOUNDS WITH SODIUM CYANOBOROHYDRIDE (1977) (2)
- Reduction of triple‐bonded groups (2010) (2)
- 1-TERT-BUTYL-1,3-PROPANEDIOL (1970) (2)
- 2‐tert‐Butyl‐1,3‐diaminopropane (2003) (1)
- Stereoselective Hydride Reductions of Cyclic N‐Diphenylphosphinyl Imines. Highly Diastereoselective Syntheses of Protected Primary Amines. (1996) (1)
- AROMATIC DENITRATION WITH BOROHYDRIDE, NUCLEOPHILIC DISPLACEMENT OF NITRITE BY HYDRIDE (1973) (1)
- The effects of conditions of moulding on the surface resistivity in the range of 106 to 1010 ohms/square of a carbon-fibre/poly(ether sulphone) short-fibre composite (1993) (1)
- Conjugate Reduction of α,β‐Unsaturated p‐Toluenesulfonylhydrazones to Alkenes with Catecholborane: 5β‐Cholest‐3‐Ene (2003) (1)
- Acid-catalyzed rearrangements of endo,endo-6,7-dihydroxy- and endo,endo-6,7-diacetoxycineole (1969) (1)
- THE SYNTHETIC UTILITY AND MECHANISM OF THE REDUCTIVE DEOXYGENATION OF ALPHA,BETA-UNSATURATED P-TOSYLHYDRAZONES WITH SODIUM CYANOBOROHYDRIDE (1975) (1)
- Correction. sodium Borohydride in Acetic Acid. A Convenient System for the Deoxygenation of Carbonyl Tosylhydrazones. (1978) (1)
- Lithium Butyl(diisobutyl)aluminum Hydride (2001) (0)
- μ-BIS(CYANOTRIHYDROBORATO)TETRAKIS(TRIPHENYLPHOSPHINE)DICOPPER(I). A NEW, SELECTIVE, PH DEPENDENT REDUCING AGENT (1980) (0)
- SELEKTIVE DEHYDRATISIERUNG SEK. ALKOHOLE DURCH METHYLTRIPHENOXYPHOSPHONIUMJODID IN HEXAMETHYLPHOSPHORAMID (1973) (0)
- KONFORMATIONSANALYSE VON PHOSPHORHETEROCYCLEN (1)H- UND (31)P-NMR-UNTERSUCHUNG VON 2-CHLOR-, -METHOXY-, -METHYL-, -AETHYL- UND -PHENYLSUBSTITUIERTEN N,N′-DIMETHYL- UND N,N′,5,5-TETRAMETHYL-2-PHOSPHA-1,3-DIAZACYCLOHEXANEN (1973) (0)
- Diastereo- and Enantioselective Hydride Reductions of Ketone Phosphinyl Imines to Phosphinyl Amines: Synthesis of Protected Amines and Amino Acids (1996) (0)
- Selective Reductions of Conjugated Acetylenes with Magnesium in Methanol and Methanol‐d. (1989) (0)
- TETRABUTYLAMMONIUM CYANOBOROHYDRIDE, A NEW, EXCEPTIONALLY SELECTIVE REDUCING REAGENT (1973) (0)
- 3,5-PYRIDINEDICARBOXYLIC ACID (Dinicotinic acid) (1971) (0)
- VANADIN(III)-KOMPLEXE VON 0,0′-DIMETHYL-DIHYDROGEN-METHYLENDIPHOSPHONAT (1972) (0)
- Bis(triphenylphosphine)copper(I) Cyanoborohydride (2001) (0)
- Stereoselective Hydride Reductions of Cyclic α,β‐Unsaturated N‐Diphenylphosphinyl Imines to Protected Allylic Amines. (1999) (0)
- SYNTHESIS OF A NOVEL SERIES OF 3-SUBSTITUTED (1)BENZOTHIENO(3,2-D)PYRIMIDINE DERIVATIVES (1985) (0)
- SELEKTIVE DEMETHYLIERUNG QUATERNAERER SALZE MIT LITHIUM‐N‐PROPYLMERCAPTID IN HEXAMETHYLPHOSPHORAMID (1973) (0)
- Lithium Aluminum Hydride–Diphosphorus Tetraiodide (2001) (0)
- Preparation of N‐Diprotected Allylic Amines via Palladium(0)‐Catalyzed Coupling Reactions (1995) (0)
- 1-TERT.-BUTYL-1,3-PROPANDIOL (1971) (0)
- Asymmetric Reduction of Phosphinylimines with Hydride Reagents. Enantioselective Synthesis of Chiral Primary Amines. (1987) (0)
- cis‐4‐tert‐Butylcyclohexanol (2003) (0)
- A Superior and General Synthesis of Enantio‐Enriched 2‐Oxathianyl Ketones. (1993) (0)
- Asymmetric Reductions of Carbon‐Nitrogen Double Bonds. A Review (1994) (0)
- UTILITY AND APPLICATIONS OF BORANE DIMETHYL SULFIDE IN ORGANIC SYNTHESIS. A REVIEW (1981) (0)
- Characterization of Organic Materials. Part I. The Photo-Fries Rearrangement and Related Reactions of a Representative Model for Aromatic Polyurethanes, Ethyl N-Phenylcarbamate. (1976) (0)
- Additions and Corrections - Regio- and Stereoselective Cleavage of Epoxides with Cyanoborohydride and Boron Trifluoride Etherate. (1982) (0)
- Conformational Analysis of S-C-P Anomeric Interactions. Part 3. The Conformational Preference of the Diphenylphosphinoyl Group in Cyclohexane. (1986) (0)
- I. CARVONE TRIBROMIDE ISOMERS: STRUCTURES AND REACTIONS WITH BASES. II.THE CHEMISTRY OF PINOL (1967) (0)
- HIGHLY STEREOSELECTIVE SYNTHESIS OF CYCLIC PRIMARY AMINES VIA HYDRIDE REDUCTIONS (1984) (0)
- ORANGE BENZENE. NEUTRAL DICHROMATE OXIDATION IN ORGANIC SOLVENTS (1978) (0)
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