Robin Perutz
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British chemist
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Chemistry
Robin Perutz's Degrees
- Bachelors Chemistry University of Oxford
Why Is Robin Perutz Influential?
(Suggest an Edit or Addition)According to Wikipedia, Robin Perutz FRS is a professor of Inorganic Chemistry at the University of York, where he was formerly head of department between 2000 and 2004.He is also the son of the Nobel Prize winner Max Perutz.
Robin Perutz's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The σ‐CAM Mechanism: σ Complexes as the Basis of σ‐Bond Metathesis at Late‐Transition‐Metal Centers (2007) (417)
- Advances in molecular photocatalytic and electrocatalytic CO2 reduction (2012) (387)
- C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales. (2011) (364)
- Transition Metal Alkane Complexes (1996) (315)
- Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters. (2005) (208)
- Photochemistry of the Group 6 hexacarbonyls in low-temperature matrices. III. Interaction of the pentacarbonyls with noble gases and other matrices (1975) (194)
- Selectivity of C-H Activation and Competition between C-H and C-F Bond Activation at Fluorocarbons. (2017) (193)
- Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics. (2002) (154)
- Ir-catalyzed borylation of C-H bonds in N-containing heterocycles: regioselectivity in the synthesis of heteroaryl boronate esters. (2006) (154)
- Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations. (2009) (132)
- A comparison of C-F and C-H bond activation by zerovalent ni and pt: a density functional study. (2004) (126)
- Improving the Photocatalytic Reduction of CO2 to CO through Immobilisation of a Molecular Re Catalyst on TiO2 (2015) (123)
- Hydrofluoroarylation of Alkynes with Ni Catalysts. C–H Activation via Ligand-to-Ligand Hydrogen Transfer, an Alternative to Oxidative Addition (2012) (122)
- Mechanism of homogeneous hydrosilation of alkenes by (.eta.5-cyclopentadienyl)rhodium (1992) (117)
- Metal fluorides form strong hydrogen bonds and halogen bonds: measuring interaction enthalpies and entropies in solution. (2008) (116)
- Rapid Intermolecular Carbon−Fluorine Bond Activation of Pentafluoropyridine at Nickel(0): Comparative Reactivity of Fluorinated Arene and Fluorinated Pyridine Derivatives (1997) (111)
- Contrasting Reactivity of Fluoropyridines at Palladium and Platinum: C-F Oxidative Addition at Palladium, P-C and C-F Activation at Platinum (2004) (110)
- Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions. (2001) (98)
- Photochemistry of the Group VI hexacarbonyls in low-temperature matrices. II. Infrared spectra and structures of carbon-13 monoxide-enriched hexacarbonyls and pentacarbonyls of chromium, molybdenum, and tungsten (1975) (96)
- Photochemistry of Transition Metal Hydrides. (2016) (90)
- Influence of quaternary structure of the globin on thermal spin equilibria in different methemoglobin derivatives. (1978) (88)
- Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy. (2006) (84)
- Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition. (2008) (84)
- Photochemistry and photophysics of a Pd(II) metalloporphyrin: Re(I) tricarbonyl bipyridine molecular dyad and its activity toward the photoreduction of CO2 to CO. (2011) (83)
- .eta.2-Coordination and carbon-fluorine activation of hexafluorobenzene by cyclopentadienylrhodium and -iridium complexes (1993) (81)
- Sequential C-F activation and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR investigation. (2007) (80)
- Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. IV. Tetracarbonylmolybdenum and tricarbonylmolybdenum (1975) (79)
- Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane. (2004) (76)
- A solvent-resistant halogen bond (2014) (76)
- Photolysis and spectroscopy with polarized light: key to the photochemistry of pentacarbonylchromium and related species (1978) (72)
- Selective activation of the ortho C?F bond in pentafluoropyridine by zerovalent nickel: Reaction via a metallophosphorane intermediate stabilized by neighboring group assistance from the pyridyl nitrogen (2010) (72)
- Selectivity in the activation of fluorinated aromatic hydrocarbons by rhodium complexes [(C5H5)Rh(PMe3)] and [(C5Me5)Rh(PMe3)] (1994) (67)
- Manganese alkane complexes: an IR and NMR spectroscopic investigation. (2011) (67)
- Pulsed matrix isolation. A comparative study (1973) (67)
- Inertness of the Aryl−F Bond toward Oxidative Addition to Osmium and Rhodium Complexes: Thermodynamic or Kinetic Origin? (1998) (66)
- CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine. (2012) (63)
- Bond energy M-C/H-C correlations: dual theoretical and experimental approach to the sensitivity of M-C bond strength to substituents. (2003) (62)
- Transient and matrix photochemistry of Fe(dmpe)2H2 (dmpe = Me2PCH2CH2Me2): dynamics of C-H and H-H activation (1993) (60)
- Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C–F bond activation (2001) (60)
- Energetics of halogen bonding of group 10 metal fluoride complexes. (2011) (54)
- Hydrogen Bonding in Transition Metal Complexes: Synthesis, Dynamics, and Reactivity of Platinum Hydride Bifluoride Complexes (2000) (53)
- Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory. (2006) (53)
- FACILE INSERTION OF CO2 INTO THE RU-H BONDS OF RU(DMPE)2H2 (DMPE = ME2PCH2CH2PME2) : IDENTIFICATION OF THREE RUTHENIUM FORMATE COMPLEXES (1996) (51)
- Comparison of rhenium–porphyrin dyads for CO2 photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy (2015) (51)
- Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. V. Two routes to square pyramidal matrix isolated chromium pentacarbonyl (1975) (48)
- Exchange Processes in Complexes with Two Ruthenium (η2-Silane) Linkages: Role of the Secondary Interactions between Silicon and Hydrogen Atoms (2002) (48)
- Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies (1993) (47)
- Matrix photochemistry of metal carbonyls (1977) (47)
- C-F Bond activation at Ni(0) and simple reactions of square planar Ni(II) fluoride complexes. (2005) (47)
- PHOTOCHEMICAL ISOMERIZATION OF METAL ETHENE TO METAL VINYL HYDRIDE COMPLEXES : A MATRIX-ISOLATION AND SOLUTION NMR STUDY (1990) (47)
- Photochemical reactions involving matrix-isolated atoms (1985) (46)
- Facile intermolecular aromatic C–F bond activation reaction of [Ru(dmpe)2H2](dmpe = Me2PCH2CH2PMe2) (1996) (46)
- Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes. (2010) (45)
- Reactivity of a Nickel Fluoride Complex: Preparation of New Tetrafluoropyridyl Derivatives† (1999) (45)
- 1.26 – Transition Metal-mediated C–F Bond Activation (2007) (45)
- Sequential arene coordination and C–F insertion in the reactions of (η5-pentamethylcyclopentadienyl)rhodium complexes with hexafluorobenzene (1991) (45)
- Chemistry of nickel tetrafluoropyridyl derivatives: their versatile behaviour with Brønsted acids and the Lewis acid BF3 (2000) (44)
- Proton-controlled photoisomerization: rhenium(I) tricarbonyl bipyridine linked to amine or azacrown ether groups by a styryl pyridine bridging ligand (2000) (42)
- Photochemical substitution of ethene and hydrogen/deuterium exchange in (.eta.5-cyclopentadienyl)bis(ethene)rhodium (1989) (39)
- Photochemical oxidative addition reactions of (.eta.5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: formation and isolation of rhodium(III) and rhodium(V) hydrides (1988) (39)
- Electron spin resonance and photoelectron studies of neutral bis(.eta.-arene)metal compounds (metal = Ti, V, Nb, Ta, Mo, and W) (1983) (38)
- Sequential displacement of coordinated ethene by hexafluorobenzene: crystal structures of .eta.2- and .eta.4-hexafluorobenzene complexes of iridium (1992) (38)
- Remote site photosubstitution in metalloporphyrin-rhenium tricarbonylbipyridine assemblies: photo-reactions of molecules with very short lived excited states. (2008) (38)
- A Catalytic Foothold for Fluorocarbon Reactions (2008) (38)
- Synthesis, molecular structure and NMR spectroscopy of atransition-metal bifluoride complex: formation via C–Factivation or reaction with Et3N·3HF (1997) (37)
- Intermediates in the time-resolved and matrix photochemistry of (.eta.5-cyclopentadienyl)rhodium complexes. Roles of alkane activation and rhodium-rhodium bond formation (1989) (37)
- Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study (2010) (36)
- Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies (1997) (36)
- Matrix isolation and transient photochemistry of ruthenium complex Ru(dmpe)2H2: characterization and reactivity of Ru(dmpe)2 (dmpe = Me2PCH2CH2PMe2) (1992) (36)
- Activation of B-H, Si-H, and C-F bonds with Tp'Rh(PMe3) complexes: kinetics, mechanism, and selectivity. (2015) (36)
- Matrix photooxidation of the metal carbonyls (M(CO)6 (M=Cr, W) by the isoelectronic molecules carbon dioxide and nitrous oxide (1985) (35)
- Direct measurement of the stability of the supramolecular synthon C6H6.C6F6 (2003) (35)
- Photochemical pump and NMR probe: chemically created NMR coherence on a microsecond time scale. (2014) (35)
- Comparisons of Photoinduced Oxidative Addition of B−H, B−B, and Si−H Bonds at Rhodium(η5-cyclopentadienyl)phosphine Centers (2006) (35)
- Computational Studies Explain the Importance of Two Different Substituents on the Chelating Bis(amido) Ligand for Transfer Hydrogenation by Bifunctional Cp*Rh(III) Catalysts (2014) (35)
- Photochemistry of small molecules in low-temperature matrixes (1985) (34)
- Intermediates in chromium carbonyl photochemistry (1972) (33)
- cis–trans Isomerisation of CpRe(CO)2(H)(ArF)(ArF= C6FnH5−n; n= 0–5) is the rate determining step in C–H activation of fluoroarenes: a DFT study (2003) (33)
- The reaction of M(CO)3(Ph2PCH2CH2PPh2)(M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products. (2004) (32)
- Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications. (2009) (32)
- Photochemical reactions of M(.eta.-C5H5)2Ln (M = W, Mo, Cr, V) in low-temperature matrixes. Detection of tungstenocene and molybdenocene (1982) (31)
- η-Arene complexes of scandium(0) and scandium(II) (1991) (31)
- Laser Flash Photolysis and Matrix Isolation Studies of Ru[R2PCH2CH2PR2]2H2 (R = C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents (1995) (31)
- Decamethylrhenocene, (.eta.5-C5Me5)2Re (1988) (31)
- Activation and η2-co-ordination of arenes: crystal and molecular structure of an (η2-hexafluorobenzene)rhodium complex (1989) (31)
- A theoretical study of [M(PH3)4] (M = Ru or Fe), models for the highly reactive d8 intermediates [M(dmpe)2] (dmpe = Me2PCH2CH2PMe2). Zero activation energies for addition of CO and oxidative addition of H2‡ (1998) (30)
- Photochemical reactions of [Re(η5-C5R5)(CO)3] (R = H or Me) with partially fluorinated benzenes: C–H and C–F activation (1999) (30)
- A new combination of donor and acceptor: bis(η6-benzene)chromium and hexafluorobenzene form a charge-transfer stacked crystal (1999) (29)
- The reaction of the unsaturated rhenium fragment {Re(η5-C5Me5)(CO)2} with 1,4-difluorobenzene. Thermal intramolecular conversion of a rhenium (difluorophenyl)(hydride) to Re(η2-C6H4F2) and a [1,4]-metallotropic shift (2001) (29)
- Structure and dynamics of the η2-hexafluorobenzenecomplexes[Re(η5-C5H4R)(CO)2(η2-C6F6)](R = H or Me) and[Rh(η5-C5Me5)(PMe3)(η2-C6F6)] (1997) (28)
- Metal Hydrides Form Halogen Bonds: Measurement of Energetics of Binding (2013) (28)
- Matrix photochemistry of (.eta.5-cyclopentadienyl)bis(ethene)rhodium and (.eta.5-cyclopentadienyl)(ethene)carbonylrhodium: a test-bed for intermediates in C-H activation (1988) (28)
- Reactivity, Structures, and NMR Spectroscopy of Half-Sandwich Pentamethylcyclopentadienyl Rhodium Amido Complexes Relevant to Transfer Hydrogenation (2009) (27)
- Synthesis, characterisation and reactivity of ruthenium bis-bifluoride, ruthenium hydride bifluoride and ruthenium hydride fluoride complexes (2001) (27)
- Picosecond Forward Electron Transfer and Nanosecond Back Electron Transfer in an Azacrown-Substituted [(bpy)Re(CO)3(L)]+ Complex: Direct Observation by Time-Resolved UV−Visible Absorption Spectroscopy (2002) (27)
- Synthesis and reactions of the rhenium fulvene complexes [Re(η6-C5Me4CH2)(CO)2(C6F4R)] (R = F or CF3): products derived from initial C–F activation (1998) (27)
- Ultrafast Time-Resolved UV−Visible and Infrared Absorption Spectroscopy of Binuclear Rhenium(I) Polypyridyl Complexes in Solution (1998) (26)
- Thermal and photochemical reactions of rhodium(trialkylsilyl)hydride complexes: NMR and bonding of poly(silyl)(hydride) complexes (1991) (26)
- Synthesis, crystal structures and some reactions of zero-valent tris[bis-1,2-(dimethylphosphino)ethane]derivatives of chromium, molybdenum, tungsten, vanadium, niobium and tantalum (1984) (26)
- EPR spectra of KrMn(CO)5 and KrFe(CO)5+ in a krypton matrix (1984) (25)
- Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule. (2002) (25)
- Aspects of Organo-Transition-Metal Photochemistry and their Biological Implications (1976) (25)
- Diene and dienyl complexes of transition elements. 8. Addition and substitution reactions of pentadienyltricarbonylmanganese with phosphines, phosphites and carbon monoxide (1984) (25)
- Intermolecular C–F and intramolecular C–H activation reaction of [Re(η5-C5Me5)(CO)3] with hexafluorobenzene: crystal and molecular structure of [Re(η6-C5Me4CH2)(CO)2(C6F5)] (1992) (25)
- Electronic structure of molybdenocene and tungstenocene: detection of paramagnetism by magnetic circular dichroism in argon matrices (1983) (25)
- Competition between intramolecular and intermolecular carbon-hydrogen bond activation in iridium ethene complexes (1993) (25)
- Vibrational spectra of terminal metal hydrides: solution and matrix-isolation studies of [(.eta.-C5H5)2MHn]x+ (M = Re, Mo, W, Nb, Ta; n = 1-3; x = 0, 1) (1986) (24)
- AN APPROACH TO DIRECT EVALUATION OF PI BONDING IN METAL CARBONYLS (1973) (24)
- A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane). (2009) (23)
- Matrix Photochemistry of Ru(CO)2(PMe3)2H2 and Ru(CO)3(PMe3)2: Formation of Ru(CO)2(PMe3)2.cntdot. .cntdot. .cntdot.S (S = Ar, CH4, Xe) (1995) (23)
- Metallocenes as reaction intermediates (1989) (22)
- ULTRAFAST REDUCTIVE ELIMINATION OF HYDROGEN FROM A METAL CARBONYL DIHYDRIDE COMPLEX; A STUDY BY TIME-RESOLVED IR AND VISIBLE SPECTROSCOPY (1997) (22)
- Light-Controlled Ion Switching: Direct Observation of the Complete Nanosecond Release and Microsecond Recapture Cycle of an Azacrown-Substituted [(bpy)Re(CO)3L]+ Complex (2004) (21)
- Photochemical oxidative addition of B-H bonds at ruthenium and rhodium. (2004) (21)
- Visible-light photoisomerization and photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)4Cl2] in organic solvent and water. (2009) (21)
- C−H Bond Cleavage in Thiophenes by [P(CH2CH2PPh2)3Ru]. UV Flash Kinetic Spectroscopy Discloses the Ruthenium−Thiophene Adduct Which Precedes C−H Insertion (1997) (21)
- NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation. (2002) (20)
- Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2]– and the crystal structure of [K(18-crown-6)(µ-H)Mo(η-C5H5)2] (1984) (20)
- Selective photochemistry at stereogenic metal and ligand centers of cis-[Ru(diphosphine)2(H)2]: preparative, NMR, solid state, and laser flash studies. (2012) (20)
- Dipyridylketone binding and subsequent C-C bond insertion reactions at cyclopentadienylrhodium. (2003) (19)
- Liquid injection field desorption/ionization of transition metal fluoride complexes (2010) (19)
- Tilden Lecture. Organometallic intermediates: ultimate reagents (1993) (19)
- Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η5-C5H5)Mn(CO)2(ethane) and (η5-C5H5)Mn(CO)2(isopentane) (2014) (18)
- Photochemistry of Metal Carbonyls (2013) (18)
- Photoisomerisation of benzenetriosmium cluster complexes: a model for arene activation on flat metal surfaces (1988) (18)
- Highly fluorinated naphthalenes and bifurcated C–H⋯F–C hydrogen bonding (2014) (18)
- Inter‐ and Intramolecular Photochemical CH Activation in Matrices and in Solution with (η6‐Arene)(carbonyl)osmium Complexes (1989) (17)
- Photochemical studies of rhenium .eta.-cyclopentadienyl complexes in matrixes and in solution: detection of rhenocene and mechanisms of hydrogen transfer (1983) (17)
- Metal dihydride complexes: Photochemical mechanisms for reductive elimination (1998) (17)
- A Ruthenium Dihydrogen Germylene Complex and the Catalytic Synthesis of Digermoxane (2015) (17)
- The Contrasting Character of Early and Late Transition Metal Fluorides as Hydrogen Bond Acceptors. (2015) (17)
- Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies. (2006) (17)
- Infrared spectroscopic evidence for photochemical generation of the metallocenes [(η-C5H5)2M](M = Mo or W) in low-temperature matrices (1979) (17)
- Control of η2-arene coordination and C–H bond activation by cyclopentadienyl complexes of rhodium (1991) (16)
- Polarized photochemistry and photo-orientation of pentacarbonylchromium in low-temperature matrices (1975) (16)
- Photochemical activation of ethene C–H bonds of (η5-C5H5)lr(C2H4)2 in low-temperature matrices and in solution (1986) (16)
- Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization. (2008) (15)
- Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction (2013) (15)
- Substituent Effects on Reductive Elimination from Disubstituted Aryl Hydride Complexes: Mechanistic and Thermodynamic Considerations (1995) (15)
- An ultrafast time-resolved UV/visible absorption study of the UV photochemistry of [(η5-C5H5)Fe(CO)2]2 (1996) (15)
- Photochemical intermolecular C–H and C–F insertion of rhodium into pentafluoroanisole to generate a metallacycle; conversion to a cyclic carbene complex (1996) (15)
- Synthesis and photochemistry of free base and zinc tetraaryl porphyrins mono-substituted with tungsten pentacarbonyl via a pyridine linker (2002) (14)
- Two photochemical pathways in competition: matrix isolation, time-resolved and NMR studies of cis-[Ru(PMe3)4(H)2] (2000) (14)
- Matrix isolation and transient absorption studies of [bis[bis(pentafluoroethyl)phosphino]ethane]tetracarbonylchromium: intermolecular alkane complexes and intramolecular F-coordination (1992) (14)
- Low-Temperature-Matrix and Room-Temperature-Solution Photochemistry of Ru(CO)3(dmpe) (dmpe = Me2PCH2CH2PMe2)† (1997) (14)
- Picosecond Photolysis of a Metal Dihydride: Rapid Reductive Elimination of Dihydrogen from Ru(dmpe)2H2 (dmpe = (CH3)2PCH2CH2P(CH3)2) (1994) (14)
- ELECTRON PARAMAGNETIC RESONANCE SPECTRA AND MOLECULAR STRUCTURE OF VANADIUM HEXACARBONYL (1982) (14)
- Electronic Fine‐Tuning of Oxygen Atom Transfer Reactivity of cis‐Dioxomolybdenum(VI) Complexes with Thiosemicarbazone Ligands (2015) (13)
- Structure and Dynamic Exchange in Rhodium η2-Naphthalene and Rhodium η2-Phenanthrene Complexes: Quantitative NOESY and EXSY Studies (2000) (13)
- A metal-based lumophore tailored to sense biologically relevant oxometalates. (2005) (13)
- Photochemical reactions of (eta 5-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: dynamics of isomer interconversion via Rh(eta 2-silane) species. (2004) (12)
- Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism (2021) (11)
- Vibrational frequency shifts for isotopes of hexacarbonylchromium. [Carbon 13, oxygen 18] (1976) (11)
- Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin–rhenium carbonyl complex† (1999) (11)
- Replacement of [RuH2(PMe3)4] by [RuH2(PEt3)4] switches reaction products: synthesis of fluoride-bridged diruthenium complexes (2003) (11)
- Selective signalling of molybdate by a siderophore derivative (2001) (11)
- Photochemistry of Os(dmpe)2H2: Matrix, Transient Solution, and NMR Studies of 16-Electron Os(dmpe)2(dmpe = Me2PCH2CH2PMe2) (1998) (10)
- Resonance Raman spectroscopy of matrix-isolated bis(.eta.6-arene)vanadium complexes (1991) (10)
- Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2. (2009) (10)
- Chapter 6. Matrix isolation (1985) (10)
- Matrix photolysis of trimethylazidosilane: silicon–hydrogen bond formation (1978) (10)
- The synthesis and spectroscopic identification of [(η5-C5H5)Re(N2)3] and [(η5-C5H5)Re(CO)(N2)2] in supercritical xenon at room temperature and in N2 matrices at 20 K (1989) (10)
- The Role of Fluorine Substituents in the Regioselectivity of Intramolecular C–H Bond Functionalization of Benzylamines at Palladium(II) (2015) (10)
- Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes (1998) (10)
- Low temperature in situ UV irradiation of [(eta 5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(III) silyl hydride complexes. (2007) (9)
- Photo-aquation of cis-[RuCl2(mPTA)4](CF3SO3)4 in water (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane). (2011) (9)
- Light-Induced Activation of a Molybdenum Oxotransferase Model within a Ru(II)-Mo(VI) Dyad. (2016) (9)
- Photochemistry of Os(η6-arene) complexes in low-temperature matrices: an infrared spectroscopic study of CH bond activation (1995) (9)
- Photochemical generation of 16-electron [Rh(η5)-C5H5)-(PMe3)] and [Ir(η5-C5H5)(PMe3)] in low-temperature matrices: evidence for methane activation (1994) (9)
- Photochemical displacement of co-ordinated ethene from [Rh(η5-C5H5)(PPh3)(C2H4)] (1998) (9)
- Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors (2019) (9)
- Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I). (2004) (8)
- Solution and matrix photochemistry of (η-cyclopentadienyl)bis(ethane)rhodium (1985) (8)
- Infra‐red microspectroscopy as a complementary technique to electron‐probe microanalysis for the investigation of natural corrosion on potash glasses (1993) (8)
- Photochemistry of Ru(etp)(CO)H2 (etp = PhP(CH2CH2PPh2)2): Fast Oxidative Addition and Coordination Following Exclusive Dihydrogen Loss (2004) (8)
- Photochemistry of M(η5-C5H5)2(H)CO and M(η5-C5H5)2H3 (M = Nb, Ta) in low-temperature matrices (1985) (8)
- Transient photochemistry of (η5-cyclopentadienyl)bis(ethene)rhodium (1987) (8)
- Synthesis and Photoisomerization of Divinyltetramethyldisiloxane and Divinyltetramethyldisilazane Complexes of (η5-C5R5)Rh (R = H, Me). Crystal and Molecular Structure of (η5-C5Me5)Rh[η4-(CH2CH)Me2SiOSiMe2(CHCH2)] (1996) (8)
- Design and synthesis of water soluble (metallo)porphyrins with pendant arms: studies of binding to xanthine oxidase (2010) (8)
- Coherent evolution of parahydrogen induced polarisation using laser pump, NMR probe spectroscopy: Theoretical framework and experimental observation. (2017) (7)
- Competing Pathways in the Photochemistry of Ru(H)2(CO)(PPh3)3 (2018) (7)
- Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide (2002) (7)
- Transient spectroscopy and kinetics of monomeric molybdenocene Mo(η-C5H5)2 in solution (1984) (7)
- Mechanistic insight into organic and industrial transformations: general discussion. (2019) (7)
- Spectroscopic and structural investigations reveal the signaling mechanism of a luminescent molybdate sensor. (2011) (6)
- Laser-Induced Fluorescence of Rhenocene in Low-Temperature Matrixes: Selective Excitation and Emission (1995) (6)
- Photochemical C-H bond activation; NMR, matrix and laser kinetic studies (1990) (6)
- Development of an Ultrafast Laser Apparatus for Time-Resolved UV-Visible and Infrared Spectroscopy (1996) (6)
- Rhenocene: Magnetic circular dichroism and laser-induced fluorescence in nitrogen matrices (1984) (5)
- Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands. (2020) (5)
- Low-Temperature Matrix Photochemistry of (η4 -Diene)tetracarbonylchromium Complexes (1985) (5)
- LASER-INDUCED FLUORESCENCE OF REACTIVE METALLOCENES (ETA-5-C5H5)2RE, (ETA-5-C5H5)2W, (ETA-5-C5H5)2MO AND (ETA-5-C5ME5)2RE (1990) (5)
- Photochemistry of [(η-C5H5)2ReH] and [(η-C5H5)(η2-C5H6)Re(CO)2] in low temperature matrices: hydrogen loss and hydrogen migration (1981) (5)
- Synthesis and Characterization of a Siderophore‐based Luminescent Sensor for Molybdate (2003) (5)
- Optical determination of magnetization behavior: a study of unstable metallocenes by magnetic circular dichroism (1988) (4)
- Photolysis of trimethylazidosilane in inert matrices: rearrangement to a dimethylsilyl imine (1978) (4)
- Photochemical Oxidative Addition of Germane and Diphenylgermane to Ruthenium Dihydride Complexes (2019) (4)
- Laser Flash Photolysis and Matrix Isolation Studies of Ru(R2PCH2CH2PR2) 2H2 (R: C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents (1996) (4)
- C-H activation by organometallics: the role of matrix isolation studies (1990) (4)
- Time-Resolved InfraredSpectroscopy of BinuclearRhenium (I) PolypyridylComplexes in Solution (1999) (4)
- The sigma-CAM Mechanism: sigma complexes as the basis of sigma-bond metathesis at late-transition-metal centers. (2007) (4)
- Photochemical generation and reactions of rhodium (η5-cyclopentadienyl) (ethene) (dinitrogen) in liquid xenon (1986) (4)
- Laser-Induced Fluorescence of Molybdenocene and Tungstenocene in Low-Temperature Matrixes (1995) (3)
- Oxidative addition of ether O-methyl bonds at a Pt(0) centre. (2014) (3)
- The variability of nitro group--protein interaction in the 2,4-dinitrophenyl-binding antibodies M315, M460 and X25 investigated by resonance Raman spectroscopy. (1981) (3)
- Ultrafast Photodissociation ofHydrogen From Ru(PPh3)3(CO)(H)2:A Time-Resolved Infrared Study (1999) (3)
- Pulsed laser photolysis of Os(pp3)H2[pp3= P(CH2CH2PPh2)3]: kinetic selectivity for reaction with methane (1994) (3)
- PHOTOCHEMICAL REACTIONS OF M(η-C5H5)2LN (M = W, MO, CR, V) IN LOW-TEMPERATURE MATRIXES. DETECTION OF TUNGSTENOCENE AND MOLYBDENOCENE (1982) (3)
- Intermediates in the Time-Resolved and Matrix Photochemistry of (η2-Cyclopentadienyl)rhodium Complexes: Roles of Alkane Activation and Rhodium-Rhodium Bond Formation. (1990) (3)
- TIME-RESOLVED RESONANCE RAMAN SPECTROSCOPY OF EXCITED-STATE PORPHYRINS (1999) (3)
- Laser spectroscopy of open-shell sandwich complexes (1991) (3)
- Computational and theoretical approaches for mechanistic understanding: general discussion. (2019) (2)
- Oxidative Addition Rates by Phosphine Substituents (1995) (2)
- Vibrational Spectra of Terminal Metal Hydrides: Solution and Matrix‐Isolation Studies of [(η‐C5H5)2MHn]x+ (M: Re, Mo, W, Nb, Ta; n:1‐3; x:0,1). (2002) (2)
- Charge-transfer interactions between sulfur dioxide and group 8 half-sandwich complexes (1994) (2)
- Organometallic Intermediates: Ultimate Reagents (1994) (2)
- NLS : conceptual design report (2015) (1)
- PHOTOCHEMISTRY OF THE GROUP 6 HEXACARBONYLS IN LOW-TEMPERATURE MATRICES PART 3, INTERACTION OF THE PENTACARBONYLS WITH NOBLE GASES AND OTHER MATRICES (1975) (1)
- Photochemical Isomerization of Metal Ethene to Metal Vinyl Hydride Complexes: A Matrix-Isolation and Solution NMR Study. (1991) (1)
- Laser-Induced Fluorescence of Decamethylrhenocene in Low-Temperature Matrices (1996) (1)
- ELECTRONIC STRUCTURE OF MOLYBDENOCENE AND TUNGSTENOCENE: DETECTION OF PARAMAGNETISM BY MAGNETIC CIRCULAR DICHROISM IN ARGON MATRIXES (1984) (1)
- Nickel‐Assisted Carbon—Fluorine Bond Activation of 2,4,6‐Trifluoropyrimidine: Synthesis of New Pyrimidine and Pyrimidinone Derivatives. (2000) (1)
- The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers (2007) (1)
- Detection of s-alkane complexes of manganese by NMR and IR spectroscopy in solution: (2015) (1)
- Organometallic chemistry and catalysisElectronic supplementary information (ESI) available: List of Posters. See http://www.rsc.org/suppdata/dt/b3/b311889d/ (2003) (1)
- Towards measuring reactivity on micro-to-millisecond timescales with laser pump, NMR probe spectroscopy. (2019) (1)
- Photoprocesses in transition metal complexes, biosystems and other molecules. Experiment and Theory (1994) (1)
- Selective Ir‐Catalyzed Borylation of Polycyclic Aromatic Hydrocarbons: Structures of Naphthalene‐2,6‐bis(boronate), Pyrene‐2,7‐bis(boronate) and Perylene‐2,5,8,11‐tetra(boronate) Esters. (2005) (1)
- Matrix Photochemistry of (η5-Cyclopentadienyl)bis(ethene)rhodium and (η5-Cyclopentadienyl)(ethene)carbonylrhodium: A Test-Bed for Intermediates in C-H Activation. (1988) (1)
- The molecular structure of (η5-cyclopentadienyl)-bis(ethene)rhodium determined by gas-phase electron diffraction (1993) (1)
- Platinum(0)-mediated C-O bond activation of ethers via an SN2 mechanism. (2016) (1)
- Decamethylrhenocene, (η5-C5Me5)2Re (1988) (1)
- Gas Phase Methods (2007) (0)
- Transition Metal Alkane Complexes(dagger). (1996) (0)
- Inter- and Intramolecular Photochemical C-H Activation with (η6-Arene)(carbonyl)osmium Complexes in Matrices and in Solution. (1990) (0)
- Optical Determination of Magnetization Behavior: A Study of Unstable Metallocenes by Magnetic Circular Dichroism. (1989) (0)
- Physical methods for mechanistic understanding: general discussion. (2019) (0)
- Laser Flash Photolysis and Matrix Isolation Studies of Oxidative Addition Rates by Phosphine Substituents (2001) (0)
- Routes to Fluorinated Organic Derivatives by Nickel Mediated C—F Activation of Heteroaromatics (2004) (0)
- Jones, David Edward Hugh (1938–2017), chemist, science journalist, and inventor (2021) (0)
- Catalytic C—F Activation of Polyfluorinated Pyridines by Nickel‐Mediated Cross‐Coupling Reactions. (2002) (0)
- MATRIX PHOTOOXIDATION OF THE METAL CARBONYLS M(CO)6 (M = CR, W) BY THE ISOELECTRONIC MOLECULES CARBON DIOXIDE AND NITROUS OXIDE (1985) (0)
- Understanding unusual element-element bond formation and activation: general discussion. (2019) (0)
- MATRIX PHOTOCHEMISTRY OF TRANSITION METAL COMPLEXES: PRINCIPLES, APPLICATIONS AND LINKS TO OTHER METHODS (1996) (0)
- Solid-State 19F NMR Chemical Shift in Square-Planar Nickel–Fluoride Complexes Linked by Halogen Bonds (2023) (0)
- Matrix Isolation and Transient Photochemistry of Ru( dm~e)~H~: Characterization and Reactivity of Ru( dmpe),! (dmpe = Me2PCH2CH2PMe2) (1992) (0)
- Methods of Bond Formation and Characterization (2007) (0)
- PHOTOCHEMISTRY OF THE GROUP 6 HEXACARBONYLS IN LOW-TEMPERATURE MATRICES PART 5, TWO ROUTES TO SQUARE PYRAMIDAL MATRIX ISOLATED CHROMIUM PENTACARBONYL (1975) (0)
- Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization (2022) (0)
- Smithson Tennant Celebration: Tennant's Science Then and Now (2012) (0)
- Photochemistry of transition metal carbonyls. (2022) (0)
- Competition between Intramolecular and Intermolecular C-H Activation in Iridium Ethene Complexes (2015) (0)
- Solvent dependence of competitive hydrogen-versushalogen-bonded self-assembly processes in multi-component crystal formation (2015) (0)
- PHOTOCHEMISTRY OF THE GROUP 6 HEXACARBONYLS IN LOWTEMPERATURE MATRICES PART 4, TETRACARBONYLMOLYBDENUM AND TRICARBONYLMOLYBDENUM (1975) (0)
- STRUCTURE AND DYNAMICS OF THE ETA 2-HEXAFLUOROBENZENE COMPLEXES RE(ETA 5-C5H4R)(CO)2(ETA 2-C6F6) (R = H OR ME) AND RH(ETA 5-C5ME5)(PME3)(ETA 2-C6F6) (1997) (0)
- Solution and solid-state studies of hydrogen and halogen bonding with N-heterocyclic carbene supported nickel(II) fluoride complexes. (2023) (0)
- CF 3 SO 3 ) 4 in water ( mPTA = N-methyl-1 , 3 , 5-triaza-7-phosphaadamantane ) † (2011) (0)
- Hydrogen bonding and wavelength dependence in time-resolved infrared spectroscopy of selective ion-sensors (2007) (0)
- Hydrogen bonds and halogen bonds: solid state, solution phase and theory (2017) (0)
- Photosensitation and photocatalysis using inorganic and organic compounds K. Kalyanasundarum and M. Grätzel (eds.), Kluwer Academic Publishers, Dordrecht, 1993, xvi + 465 pages (including full combined subject index). UK £136 ISBN 0-7923-2261-4Charge transfer photochemistry of coordination compounds (1994) (0)
- A solvent-resistant halogen bond † EDGE ARTICLE (2014) (0)
- PHOTOLYSIS AND SPECTROSCOPY WITH POLARIZED LIGHT- KEY TO THE PHOTOCHEMISTRY OF PENTACARBONYLCHROMIUM AND RELATED SPECIES (1978) (0)
- IC MATR $ X PHOTOCHEMISTRY OF METAL CARBONYLS (2006) (0)
- Interview with Robin Perutz. (2014) (0)
- Transient infrared and emission spectroscopy of selective ion-sensors (2006) (0)
- Edited By William B.Tolman. Activation of small molecules, organometallic and bioinorganic perspectives Wiley–VCH, 2006, 364pp; ISBN‐13 978‐3‐527‐313312‐5 (2008) (0)
- Liquified and Supercritical Noble Gases (2007) (0)
- Synthesis of Pyridyl and Pyridazyl Boropinacolates by Ir-Catalyzed C-H activation (2006) (0)
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