Russel L. N. Grimes

Russel L. N. Grimes's AcademicInfluence.com Rankings

Russel L. N. Grimes

Chemistry

#2969

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#3946

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Inorganic Chemistry

#136

World Rank

#148

Historical Rank

chemistry Degrees

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Chemistry

Russel L. N. Grimes's Degrees

PhD Chemistry Stanford University
Masters Chemistry Stanford University
Bachelors Chemistry University of California, Berkeley

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Russel L. N. Grimes's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Boron Clusters Come of Age. (2004) (178)
Carboranes in the chemist's toolbox. (2015) (155)
Metallacarboranes in the new millennium (2000) (129)
Two-dimensional boron-11−boron-11 nuclear magnetic resonance spectroscopy as a probe of polyhedral structure: application to boron hydrides, carboranes, metallaboranes, and metallacarboranes (1984) (118)
Boron-Carbon Ring Ligands in Organometallic Synthesis (1992) (112)
TWO‐DIMENSIONAL BORON‐11‐BORON‐11 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY AS A PROBE OF POLYHEDRAL STRUCTURE: APPLICATION TO BORON HYDRIDES, CARBORANES, METALLABORANES, AND METALLACARBORANES (1984) (87)
Metal Interactions with Boron Clusters (1982) (84)
Triple-decked sandwich compounds. Planar C2B3H54- cyclocarborane ligands analogous to C5H5- (1973) (74)
Structure and stereochemistry in metalloboron cage compounds (1978) (70)
Small cobalt and nickel metallocarboranes from 2,3-dicarbahexaborane(8) and 1,6-dicarbahexaborane(6). Sandwich complexes of the cyclic C2B3H72- and C2B3H54- ligands (1974) (57)
Atom connectivities in polyhedral boranes elucidated via two-dimensional J-correlated boron-11-boron-11 FT NMR: a general method (1982) (56)
Crystal structure of a tetracobalt tetraboron cluster, (.eta.5-C5H5)4Co4B4H4. Structural patterns in eight-vertex polyhedra (1979) (54)
Metal sandwich complexes of cyclic planar and pyramidal ligands contaning boron (1979) (51)
(Pentamethylcyclopentadienyl)cobaltaboranes derived from the octahydropentaborate (B5H8-) and tetradecahydrononaborate (B9H14-) ions: studies in synthesis and structure (1982) (50)
Carboranes containing gallium and indium cage heteroatoms. Synthesis, molecular structure, and reactions (1972) (46)
Studies of 2-(.eta.5-C5H5)CoB4H8, a cobaltaborane analog of pentaborane(9) (1978) (43)
Nickel-Boron 'Hybrid' Clusters. Synthesis of Polyhedral Nickelaboranes and Nickelacarboranes from Small Borane and Carborane Anions. Crystal Structure of (n5-C5H5)4Ni4B4H4. (1979) (43)
Carbon-Rich Carboranes and their Metal Derivatives (1984) (42)
Iron-hydrogen and iron-cobalt metallocarboranes. Synthesis and chemistry of [(CH3)2C2B4H4]2FeIIH2 and a novel tetracarbon carborane system, (CH3)4C4B8H8 (1976) (42)
Metal–Carborane Multidecker Sandwich Complexes as Building Blocks for New Materials (1996) (41)
Role of metals in borane clusters (2002) (41)
POLYHEDRAL COBALTABORANES. VERSATILE REPLACEMENT OF BORANE(1) GROUPS BY (η5-CYCLOPENTADIENYL)COBALT UNITS IN BORON HYDRIDE FRAMEWORKS. BORANE-METAL CLUSTER HYBRID MOLECULES (1977) (41)
Electronic properties of mononuclear, dinuclear, and polynuclear cobaltacarboranes: electrochemical and spectroelectrochemical studies. (2004) (40)
Tetracarbon metallocarboranes. 2. Thermal rearrangement of 14-vertex cage systems. Crystal structures of three tetracarbon diferracarborane isomers, (.eta.5-C5H5)2Fe2(CH3)4C4B8H8 (1977) (40)
Synthesis and Reactivity: An Overview (2011) (39)
Iron(II) and -(III) metallocarboranes derived from nido-dicarbahexaborane(8) and closo dicarbaheptaborane(7) (1973) (39)
Tetracarbon metallocarboranes. 1. Iron, nickel, and molybdenum complexes derived from tetramethyltetracarbadodecaborane(12). Crystal structure of (.eta.5-C5H5)Fe(CH3)4C4B7H8 (1977) (39)
New ferraboranes. Structural analogs of hexaborane(10) and ferrocene. A complex of cyclic B5H10-, a counterpart of C5H5- (1977) (37)
Organotransition-metal metallacarboranes. 31. Metallacarborane staircase oligomers. Stepwise assembly via tetradecker stacking reactions (1993) (37)
Preparation of a stable small ferraborane, B4H8Fe(CO)3 (1974) (35)
Preparation of stable closo- and nideo-cobaltaboranes from sodium(+) octahydropentaborate(-). Complexes of the formal octahydrotetraborate(2-) and hexahydrotetraborate(4-) ligands (1973) (35)
Structures of metalloboron clusters. X-ray studies of octahedral (.eta.5-C5H5)3Co3B3H5 and capped octahedral (.eta.5-C5H5)3Co3B4H4, a boron analog of tricobalt carbon clusters (1977) (35)
Antitumor activity of mono- and dimetallic transition metal carborane complexes of Ta, Fe, Co, Mo, or W. (2000) (35)
Carboranes, Anti‐Crowns, and Big Wheels (1993) (34)
Two-dimensional correlated nuclear magnetic resonance of spin-coupled boron-11-proton systems (1980) (34)
Metallacarborane-based nanostructures: a carbon-wired planar octagon. (2003) (33)
Arene―metal―carborane triple-Decker sandwiches. Designed synthesis of homo- and heterobimetallic complexes of cobalt, iron, ruthenium, and osmium (1989) (33)
Direct insertion of transition metals into polyhedral carboranes. Structurally novel mono-, di-, and trimetallic small cage systems (1974) (33)
SMALL METALLOBORON CAGE COMPOUNDS AS ANALOGUES OF METAL CLUSTERS. UNIFYING CONCEPTS OF BONDING * (1974) (33)
Bridge insertion reactions of the 2,3-C2B4H7− ion with aluminum, gallium, and transition metal reagents (1975) (33)
Synthesis, structure, and reactions of 1,2-dicarbapentaborane(7) (1972) (33)
Linked and mercury-bridged nido-carboranes. High-yield synthesis of .mu.,.mu.'-[(CH3)2C2B4H5]2Hg, conversion to 5,5'-[(CH3)2C2B4H5]2, cleavage, and oxidative addition of benzene. Synthesis of .mu.,.mu.'-(B5H8)2Hg (1979) (32)
Metallacarboranes and metal-boron clusters in organometallic synthesis (1982) (32)
nido-Carborane building-block reagents. 1. Polycyclic arene RR′C2B4H6 derivatives: Synthesis via indenyl and fluorenyl alkynes and metal-promoted oxidative fusion (1988) (32)
Cluster forming and cage fusion in metallacarborane chemistry (1995) (31)
Tin- and lead-bridged carboranes. Further studies on silicon- and germanium-bridged C2B4H8 derivatives (1973) (31)
Carborane formation in alkyne-borane gas-phase systems. V. Conversion of two-carbon to four-carbon carboranes via alkyne insertion. Nuclear magnetic resonance studies of tetracarba-nido-hexaboranes (1972) (30)
Organotransition-Metal Metallacarboranes. 43. Directed Synthesis of Carborane-End-Capped Multidecker Sandwiches (1995) (30)
Crystal and molecular structure of (C2H5)3NH+[Co(1,2-C2B9H11)2] (1982) (29)
Icosahedral Carboranes: 1,2-C2B10H12 (2011) (28)
New chemistry of the iron dihydrogen metallocarborane [2,3-(CH3)2C2B4H4]2FeH2. Reaction with carbon monoxide and cage insertion of germanium, tin, and cobalt (1977) (28)
9 – Transition Metal Metallacarbaboranes (1995) (28)
Erratum: Organotransition-metal metallacarboranes. 10. π-Complexation of nido-(PhCH2)2C2B4H6 at the C2B3 and C6 rings. Synthesis and crystal structures of nido-2,3-[(CO)3Cr(η6-C6H 5)CH2]2-2,3-C ... (1987) (28)
Synthesis and chemistry of .mu.-silyl and .mu.-germyl carboranes (1972) (27)
Metal-promoted fusion of B6H9-. Directed synthesis and structural characterization of dodecaborane(16), B12H16 (1985) (27)
Small carborane metallocene analogs. Iron .pi.-complexes containing the formal nido-C2B4H62- and cyclo-C2B3H72- ligands (1971) (27)
Crystal and molecular structure of 2-methyl-1,7-bis(.eta.5-cyclopentadienyl)-1,7,2,4-dicobaltadicarbaheptaborane(7), a triple-decked sandwich compound (1975) (26)
Organotransition-Metal Metallacarboranes. 38. C2B3 and C2B4 Carborane Ligands as Cyclopentadienyl Analogs: Early Transition Metal Complexes (1995) (26)
Tetracarbon metallocarboranes. 3. Crystal structure of a closo 14-vertex cage, 1,14,2,5,9,12-(.eta.5-C5H5)2Fe2(CH3)4C4B8H8, a bicapped hexagonal antiprism (1978) (26)
Organotransition-Metal Metallacarboranes. 36. A Remarkably Stable Transition-Metal-Benzyne Complex: Synthesis and Structure of Cp(PMe3)(.eta.2-C6H4)Ta(Et2C2B4H4) (1995) (26)
Small metallocarboranes of tin and lead (1977) (26)
Organotransition-metal metallacarboranes. 21. Transition-metal sandwich complexes of heterocyclic ligands. Carborane-stabilized .eta.5-pyrrolyl and .eta.5-phospholyl double-decker and triple-decker compounds: synthesis, structure, and electrochemistry (1991) (25)
Formation of open-cage and closed-cage carboranes from tetraborane(10) and acetylene (1967) (25)
Carboranes from Diborane and Acetylene in an Electric Discharge (1966) (25)
Insertion Reactions of Tantalum(V) Carborane Alkyl and Aryl Complexes with Nitriles and Isonitriles. Thermal and Photochemical Isomerization of η2-Iminoacyl Isomers1 (1997) (25)
Cobalt-boron clusters (1976) (25)
Polynuclear Metallacarborane−Hydrocarbon Assemblies: Metallacarborane Dendrimers1 (2003) (25)
Tetracarbon metallocarboranes. 5. A new synthetic route: synthesis of Co2C4B6 and CoC4B7 nido cage systems by fusion of dicarbon cobaltacarboranes in ethanolic potassium hydroxide. Crystal structure of (.eta.5-C5H5)2Co2C4B6H10 (1978) (24)
Synthesis of four-, five-, and six-boron metallocarboranes from polyhedral dicarbaheptaborane (C2B5H7) (1973) (24)
Organotransition-metal metallacarboranes. 19. Indenyliron(II) and -iron(III) complexes and related species. .eta.6 .fwdarw. .eta.5 Haptotropic rearrangement, electrochemistry, and polyhedral expansion of (arene)Fe(Et2C2B4H4) clusters (1991) (24)
Triple-decker sandwich complexes of cobalt, rhodium, and ruthenium bridged by C2B3 or C3B2 rings : synthesis, structure, and electrochemistry (1990) (24)
Oxidative fusion of carborane ligands in iron and cobalt complexes: a systematic study (1982) (24)
Four-carbon carboranes. Synthesis of tetra-C-methyltetracarbadodecaborane(12) and its metallocarborane derivatives (1974) (24)
Novel Iron-Carborane Mu- and Pi-Complexes Derived from Nido-C2B4H8. A Paramagnetic Small Carborane Sandwich Compound (1972) (24)
Structural Consequences of Electron Hyperdeficiency (1976) (24)
Crystal and molecular structure of 5-(.eta.5-cyclopentadienyl)-5-cobalta-nido-decaborane(14), a cobaltaborane analog of decaborane(14) (1977) (24)
Crystal and molecular structure of dicarbacyclopentaboranyliron tricarbonyl (1973) (24)
Organotransition-metal metallacarboranes. 25. Redox chemistry and electronic studies of mono- and dinuclear iron(II)-iron(III) sandwich complexes (1992) (23)
Alkene and Alkyne Insertion Reactions with Tantalum Metallacarborane Complexes: the Et2C2B4H42-Carborane Ligand as a Spectator and Participant1 (1998) (23)
5.5 – Metallacarboranes and Metallaboranes (1982) (23)
Polyhedral ferraboranes derived from the B5H8- ion. Analogs of ferrocene, hexaborane(10), and nido-B11H15 (1979) (23)
Crystal structure of a novel triple-decked sandwich metallocarborane, .mu.(2,3)-1,3-C3H4-1,7,2,3-(.eta.5-C5H5)2Co2C2B3H3, a complex containing a bicyclic planar carborane ligand related to pentalene. Partial incorporation of a cyclopentadienyl ring into a polyhedral borane cage (1978) (23)
Substituent NMR effects in triple-decked sandwich metallocarboranes (1976) (23)
Seven-vertex phosphinohalometallacarboranes of iron, cobalt, and nickel: Syntheses, structures, and reactions (1985) (23)
Synthesis and Serendipity in Boron Chemistry: A 50 Year Perspective (2013) (23)
A STUDY OF POLYHEDRAL CAGE FLUXIONALITY IN CARBORANES. SOLUTION AND SOLID-STATE STRUCTURES OF R4C4B8H8 ISOMERS (1984) (22)
Titanium and Zirconium Et2C2B4H4−Metal−Phosphine Complexes: Synthesis, Characterization, and Ethylene Polymerization Activity1 (2000) (22)
Reactions of the 2,4-C2B5H7 carborane system (1970) (22)
Alkynyl-Linked Poly(cobaltacarboranes). Directed Synthesis, Structures, and Electrochemistry of Linear Complexes and Benzene-Centered Pinwheels1 (2003) (22)
Cytotoxicity of tantalum(V) and niobium(V) small carborane complexes and mode of action in P388 lymphocytic leukemia cells (2000) (21)
Tetrametallic nickel-boron clusters, (.eta.5-C5H5)4Ni4B4H4 and (.eta.5-C5H5)4Ni4B5H5. Synthesis of metalloboron cluster systems by transition metal aggregation on a small borane framework (1978) (21)
Crystal and molecular structure of a tetracarbon carborane, (CH3)4C4B8H8, a new type of nido cage system (1977) (21)
New Carborane cage system, 1,2-C2B3H7 (1970) (21)
Fulvalene- and polyarene-transition metal-carborane complexes as building blocks for multilevel arrays. Stepwise synthesis and structural characterization of polymetallic linked sandwiches (1989) (21)
Crystal and molecular structure of an iron dihydrogen metallocarborane, [2,3-(CH3)2C2B4H4]2FeH2. Steric aspects of the oxidative fusion process (1979) (20)
Cobalt-hydrogen metallocarboranes. Synthesis of closo-[(CH3)2C2B4H4]2CoH and nido,closo-[(CH3)2C2B3H5]CoH[(CH3)2C2B4H4] and their conversion to new cobalt-cobalt bonded metallocarboranes (1976) (20)
Small carborane ligands as spectators and as players (1999) (20)
Organotransition-metal metallacarboranes. 29. Synthesis of selectively C- and B-substituted double- and triple-decker sandwiches. (.eta.5-C5Me5)CoIII(.eta.5-R2C2B3R'3H2) cobaltocenium analogs (1992) (20)
Improved Synthetic Routes to Small Carboranes. Bench-Scale Preparation of Nido-2,3-C2B4H8 Derivatives from B5H9 and from B3H8(-) Salts. (1979) (20)
Molecular and electronic structure of a mixed-spin diiron "wedged" metallacarborane, (Me2C2B4H4)2[FeII(low-spin)][FeII(high-spin)]L2 [L2 = (THF)2 or (MeO)2C2H4], an oxidative fusion intermediate (1982) (20)
Crystal structure of a closo six-vertex metalloboron cluster, 1,2-(.eta.5-C5H5)2Co2B4H6, with hydrogen atoms bridging Co2B triangular faces (1979) (20)
Small Carborane Ligands as Tailorable Cp Surrogates. Halogenation, Alkylation, and Arylation at Metal and Cage Positions on CpX2M(Et2C2B4H4) Complexes (M = Ta, Nb)1 (2000) (20)
Nido-Carborane building-block reagents. 2. Bulky-substituent (alkyl)2C2B4H6 derivatives and (C6H5)2C2B4H6: synthesis and properties (1988) (20)
Thermal isomerization studies of small metallocarboranes. Cage rearrangement equilibriums and reversible cobalt atom migrations (1975) (19)
Nuclear magnetic resonance relaxation in complex spin systems. Proton and boron-11 spin-lattice relaxation studies of carboranes and metallocarboranes (1977) (19)
Tetradecker metallacarborane sandwiches : synthesis via double-decker stacking and structural characterization of Co-Co-Co, Co-Ni-Co, and Co-Ru-Co complexes (1992) (19)
Boron Clusters with Transition Metal-Hydrogen Bonds (1982) (19)
A hydridotantalum(V)-carborane analogue of Schwartz's reagent: synthesis and reactivity (1998) (19)
Reactions of boranes and carboranes with silanes, organosilanes, and related compounds (1971) (18)
Organotransition-metal metallacarboranes. 4. Stable .eta.8-C8H8 and .eta.7-C7H7 complexes of titanium, vanadium, and chromium: synthesis and crystal structures of (.eta.8-C8H8)M(Et2C2B4H4) (M = Ti, V) and (.eta.7-C7H7)Cr(Et2C2B4H4) (1984) (18)
Organotransition-Metal Metallacarboranes. 59.1 Synthesis and Linkage of Boron-Functionalized Ferracarborane Clusters (2002) (18)
Nickel-boron "hybrid" clusters. Synthesis of polyhedral nickelaboranes and nickelacarboranes from small borane and carborane anions. Crystal structure of (.eta.5-C5H5)4Ni4B4H4 (1979) (18)
Organotransition-metal metallacarboranes. 17. Electronic control of metallacarborane stacking reactions. Directed synthesis of Cp*Co(C2B3)M(C2B3)CoCp* tetradecker sandwiches (1991) (18)
Metal-promoted fusion and linkage of B5H8-, 1-XB5H7- (X = D, CH3), B10H13-, and (.eta.5-C5H5)CoB4H7-. Facile routes to B10H14 and (.eta.5-C5H5)2Co2B8H10 isomers (1985) (18)
"Recapitation" of nido-Metallacarboranes as a Synthetic Tool: Preparation of Apically Substituted CoC(2)B(4) Clusters via Boron Insertion(1). (1996) (18)
Nido-carborane building-block reagents. 4. Regiospecific substitution at boron in 2,3-R2C2B4H6 cages. Evidence for intramolecular C-H---Hbridge interactions in 2,3-R2C2B4H5-4-R' derivatives (1988) (18)
Designed synthesis of multi-functional carboranes and organotransition metalcarborane complexes (1987) (18)
Polyhedral cobaltaboranes. Versatile replacement of borane(1) groups by (.eta.5-cyclopentadienyl)cobalt units in boron hydride frameworks. Borane-metal cluster hybrid molecules (1977) (17)
Tricarba-'closo'-octaborane(7), a Polyhedral Carborane Containing a Bare Carbon Atom. (1971) (17)
Metal-induced oxidative fusion of boranes. Synthesis of dodecaborane(16), the first neutral dodecaborane (1984) (17)
Structural investigation of a B-ferrocenyl-substituted tetracarbon carborane, 4[(.eta.5-C5H5)Fe(.eta.5-C5H4)]-2,3,7,8-(CH3)4C4B8H7 (1980) (17)
Mercury-bridged cobaltacarborane complexes containing boron-mercury-boron three-center bonds. Synthesis and structure of .mu..mu.'-[(.eta.5-C5R5)Co(CH3)2C2B3H4]2Hg and .mu.-[(.eta.5-C5R5)Co(CH3)2C2B3H4]HgCl (R = hydrogen, methyl) and related compounds (1981) (17)
Tetracarbon metallocarboranes. 4. Structure of the nido system (.eta.5-C5H5)Co(CH3)4C4B7H6OC2H5. The problem of the structural diversity of electronically analogous cage systems (1978) (17)
Carborane formation in alkyne-borane gas phase systems. III. Flash reactions of small boranes (1969) (17)
Organotransition-metal metallacarboranes. 26. Carborane ligands in organometallic chemistry: a new class of Fischer carbene complexes (1992) (17)
New Metallacarborane Chemistry: Molybdenum and Tungsten Carbonyl Multidecker Sandwiches. Cluster Dimers Linked via Metal-Metal Bonds(1). (1998) (17)
Transition-metal-promoted oxidative fusion with carborane and borane anions. Synthesis of C4Bn (n = 8-11) carborane systems in the presence of B5H8- and B3H8- ions (1980) (17)
Recent studies of metalloboron cage compounds derived from the small carboranes (1974) (17)
Intramolecular boron-boron linkage between polyhedral cages in a commo-metallacarborane. Synthesis and structure of a fluxional metal-boron cluster, [.eta.5-C5(CH3)5]2Co3(CH3)4C4B8H7 (1981) (16)
Putting Small Metallacarboranes to Work: A Review (2002) (16)
A New Isomer of C2B3H5, C,3-Dimethyl-1,2-dicarbaclovopentaborane(5) (1966) (16)
Sources of line width in boron-11 nuclear magnetic resonance spectra. Scalar relaxation and boron-boron coupling in tetraborane(10) and pentaborane(9) (1978) (16)
Small carborane-transition metal complex, (.pi.-2-CH3C3B3H5)Mn(CO)3 (1969) (16)
Crystal and molecular structures of two thermally interconvertible metallocarborane isomers, 1,8,5,6- and 1,7,5,6-(.eta.5-C5H5)2Co2C2B5H7. Reversible metal-metal bond formation in a polyhedral surface (1976) (16)
Carborane formation in alkyne-borane gas-phase systems. IV. Mechanism study of the tetraborane(10)-acetylene reaction (1971) (16)
Organotransition-metal metallacarboranes. 34. Synthesis and structure of a hexadecker sandwich (1994) (16)
Organotransition-metal metallacarboranes. 33. Electrochemistry of polymetallacarborane staircase oligomers (1993) (16)
Organotransition-Metal Metallacarboranes. 37. Paramagnetic Iron-Cobalt and Dicobalt Triple-Decker Sandwich Complexes (1995) (16)
A NEW TYPE OF BORON HYDRIDE, B(10)H(16). (1961) (16)
Organotransition-Metal Metallacarboranes. 44. Construction of Pentadecker and Hexadecker Sandwiches from Triple-Decker Building Blocks (1995) (15)
Cobaltaborane analogs of decaborane (B10H14). Crystal and molecular structures of 6-[.eta.5-C5(CH3)5]CoB9H13, 6,9-[.eta.5-C5(CH3)5]2]2Co2B8H12, 5,7-[.eta.5-C5(CH3)5]5]2Co2B8H12, and 6-Cl-5,7-[.eta.5-C5(CH3)5]2Co2B8H11 (1982) (15)
Tetracarbon metallacarboranes. 9. New types of nido cage geometry. Crystal and molecular structures of [(C6H5)2PCH2]2Ni(CH3)4C4D8H8 (isomer 1) and (.eta.5-C5H5)Co(CH3)4C4B7H7 (isomer 2) (1980) (15)
Carboranes in medicine (2011) (15)
Organotransition metal metallacarboranes. 3. The .eta.8 coordination of planar C8H82- to vanadium. Structural characterization of (.eta.8-C8H8)V(Et2C2B4H4) (1983) (15)
Tetracarbon metallocarboranes. 8. Structure of a 12-vertex arachno carborane, .sigma.-(.eta.5-C5H5)Co(.eta.5-C5H4)+-Me4C4B8H8-, an analog of B12H126- and C2B10H124-. Mechanisms of carborane fluxional behavior and metallocarborane formation from the Me4C4B8H82- ion (1979) (15)
Organotransition-Metal Metallacarboranes. 40. Regiospecific Halogenation of Transition-Metal Small Carborane Complexes (1995) (15)
Organotransition metal metallocarboranes. 14. Pyrrolyl-transition metal-carboranyl double-decker and triple-decker sandwich complexes (1989) (15)
Tetracarbon metallacarboranes. 7. Cobalt systems derived from (CH3)4C4B8H8. Synthesis and interconversion of 11-, 12-, and 13-vertex nido cages (1979) (14)
Boranometallacarboranes. 1. Synthesis and characterization of borane-cobalt-carborane sandwich complexes (1982) (14)
Crystal and molecular structure of [.eta.5-C5(CH3)5]3Co3B4H4, an electron-hyperdeficient cluster with severe intramolecular ligand-ligand crowding (1982) (14)
Organotransition-metal metallacarboranes. 24. (C5Me5)Co(Et2C2B3H4-R) metallacarborane sandwich complexes as versatile synthons. Introduction of electron-withdrawing substituents (1992) (14)
Carbon-rich Metallacarboranes. 14. Synthesis and Structure of Mixed-ligand Cobalt and Iron Complexes Derived from (C2H5)4C4B8H 8 2- and (C2H5)2C2B4H 5 - (1985) (14)
Apically Linked Small Metallacarborane Clusters. Directed Synthesis and Structural Characterization of 7,7'-[CpCo(2,3-Et(2)C(2)B(4)H(3)](2) and [CpCo(2,3-Et(2)C(2)B(4)H(3)-7)](2)X Complexes (X = MeCH, HC=CH, C&tbd1;C)(,)(1). (1997) (14)
Carbon-rich metallacarboranes. 13. Synthesis and structure of bis(carboranyl)cobalt complexes derived from (C2H5)4C4B8H 8 2- (1985) (14)
Synthesis and structure of a cobaltocenium cobaltacarborane zwitterion. Cobaltocenium and tetrahydrofuran derivatives of nido,closo-[2,3-(CH3)2C2B3H5]CoH[2,3-(CH3)2C2B4H4] (1978) (14)
ORGANOTRANSITION-METAL METALLACARBORANES. XIL: SYNTHESIS AND STRUCTURE OF B-B- AND CP*-CP*-LINKED COBALTACARBORANE CLUSTERS (1995) (14)
Organotransition-metal Metallacarboranes 2 (1985) (14)
Infrared Spectroelectrochemistry of Boron-Hydrogen Stretches: A Tool for Diagnosis of Delocalization in Mixed-Valent Metallacarborane Complexes (1994) (14)
Small cobaltacarborane clusters in synthesis. Peralkylation, perhalogenation, and macrocycle construction (2003) (14)
Delocalization in bimetallic triple-decker complexes : electrochemistry, ESR spectroscopy, and spectroelectrochemistry of (p-MeC6H4CHMe2)2Ru2(Et2C2B3H3) and CpCo(Et2C2B3H3)Ru(p-MeC6H4CHME2) and derived ions (1992) (14)
TETRADECKER LM(C3B2)CO(C2B3)COCP SANDWICH COMPLEXES LM = CP*CO, CP*RH, OR (CYMEN)RU. DESIGNED SYNTHESIS AND ELECTRONIC PROPERTIES (1990) (13)
Organotransition-Metal Metallacarboranes. 39. Arene-Capped Ruthenium-Carborane Tetradecker Sandwich Complexes (1995) (13)
Carbon-rich metallacarboranes. 15. Novel metal-promoted cluster fusion reactions (1993) (13)
Borane-commo-carboranes. 2. Crystal and molecular structures of [2,3-(C2H5)2C2B4H4]-5-Co[B9H12-1-O(CH2)4], [2,3-(CH3)2C2B3H5]-5-CO[B9H12-1-O(CH2)4], and [1,2-(C2H5)2C2B7H7]-6-Co[B9H12-2-O(CH2)4] (1982) (13)
Organotransition-metal metallacarboranes. 9. nido-2,3-Dibenzyl-2,3-dicarbahexaborane(8) [(PhCH2)2C2B4H6], a versatile multifunctional nido-carborane: iron-polyarene sandwich compounds and chromium tricarbonyl .pi.-complexes (1987) (13)
Organotransition-metal metallacarboranes. 6. Synthesis of (CH2)n-bridged (.eta.6-arene)ferracarboranes: ferrocenophane analogs. Structure of [cyclic] [.eta.6-C6H5(CH2)3]Fe(C2B4H5) (1985) (13)
2 – Structures and Bonding (1970) (13)
Organo transition-metal metallocarboranes. 11. Chromium tricarbonyl .eta.6-complexes of nido-2,3-(PhCH2)2C2B4H6: metal complexation and oxidative fusion (1987) (13)
Carbon-rich metallacarboranes. 12. Synthesis and structures of chromium(III) complexes with nonconforming cage geometries (1983) (12)
A Delocalized Analogue of the Bicobaltocene Cation Derived from Reduction of a d6d6 (Fulvalenediyl)bis(cobaltacarborane) Complex: Electrochemistry, ESR, Optical Spectroscopy, and IR Spectroscopy of the Carborane Group (1999) (12)
Electron-rich carboranes. Studies of a stereochemically novel system, (CH3)4C4B7H9, an 11-vertex arachno cluster (1981) (12)
Organotransition-metal metallacarboranes. 7. Complexes of polycyclic arenes: preparation and structures of (.eta.6-arene)ferracarborane sandwiches of naphthalene and phenanthrene (1985) (12)
ORGANOTRANSITION-METAL METALLACARBORANES. XXXV: ELECTROCHEMISTRY, ESR, ANDCORRELATED NMR SPECTORSCOPY OF PARAMAGNETIC MONO- AND DINUCLEAR CP*COC2B4 C LUSTERS (1994) (12)
Cp-Functionalized Building Blocks for Polymetallacarborane Assemblies. Multinuclear Cobaltacarborane Complexes on Fulvalene and 1,3,5-Tris(cyclopentadienyl)benzene Scaffolds1 (2003) (12)
Solvent-induced boron-11 NMR shifts in metallaboranes and metallacarboranes (1985) (12)
Electrochemical properties of (.eta.6-arene)MII(.eta.5-Et2C2B4H4) complexes: formation of persistent d5 (M = iron, ruthenium) and d7 (M = iron) redox products (1991) (12)
Bridge deprotonation of nido-2,3-RR′C2B4H6 carboranes and B5H9: A kinetic study (1987) (12)
Tetracarbon Metallacarboranes 10 On the Thermodynamically Favored Geometry of Large Nido Cages. Structure of the Thermal Rearrangement Product (Isomer III) of (n5-C5H5)CO(CH3)4C4B7H7. (1981) (11)
Dihydrodiborolyl-transition metal-carboranyl triple-decker sandwich complexes (1989) (11)
1-[(η5-C5R5)Co]B4H8(R = H or Me) sandwich complexes containing a square cyclic B4H82– ligand analogous to C4H42–: structural and spectroscopic studies (1984) (11)
Tetracarbon metallacarboranes. 6. Stereochemical relationships between Co2C4B6 cage isomers formed by oxidative fusion. Crystal structure of (.eta.5-C5H5)2Co2(CH3)4C4B6H6, isomer V (1979) (11)
Small carboranes as building blocks in designed organometallic synthesis (1991) (11)
Organotransition-metal metallacarboranes. 8. Mono-, di-, and triiron polyarene sandwich complexes of Et2C2B4H42- containing fluorene, 9,10-dihydroanthracene or [2.2]paracyclophane ligands (1987) (11)
Benzene‐Centered Tri‐ and Tetrametallacarborane Sandwich Complexes (2000) (11)
Wired Multidecker Sandwich Assemblies. Stepwise Construction of a Hexanuclear Benzene-Centered Tris(alkynyl triple-decker) Complex1 (2002) (11)
Reactions of 1,6-dicarba-closo-hexaborane(6) (1971) (11)
DEUTERIUM TRACER STUDIES OF TRICARBAHEXABORANE (7) FORMATION. SYNTHESIS OF THE 2,4-(CH3)2C3B3H4(-)ION AND 2,4-(CH3)2-mu-D-C3B3H4. (1969) (11)
Organotransition-metal metallacarboranes. 1. Iron complexes derived from C8H82-. Structure of (.eta.6-C8H10)Fe[2,3-(CH3)2C2B4H4] (1983) (10)
Organotransition-metal metallacarboranes. 2. Synthesis and structures of (.eta.6-arene)Fe[(C2H5)2C2B4H4] complexes (1983) (10)
Cobaltocenium metallacarboranide mixed-sandwich salts, Cp2Co+(Et2C2B4H4)2M- (M = CoIII, ironIII) and Cp2Co+(Et2C2B3H4-X)CoIII(Et2C2B4H4)- (X = H, Me) (1993) (10)
Alkynyl Substitution and Linkage in Cobaltacarborane Sandwich Complexes (2001) (10)
Organotransition-Metal Metallacarboranes. 46. Multidecker Sandwiches of the Cobalt Group Metals(,)(1). (1996) (10)
Synthesis and Rearrangement of mu, mu'-SiH2(C2B4H7)2, a Bis-Carboranyl Silane Linked by a Silicon Atom Common to Two Three-Center B-Si-B Bonds. (1972) (10)
Organotransition-metal metallacarboranes. 23. (C5Me5)Co(Et2C2B3H4-R) metallacarborane sandwich complexes as versatile synthons. Introduction of organomethyl functional groups at boron (1992) (10)
ORGANOTRANSITION-METAL METALLACARBORANES 45. SYNTHESIS AND STRUCTURE OF HYDRIDORUTHENACARBORANE DOUBLE-DECKER AND TRIPLE-DECKER SANDWICH COMPLEXES (1997) (10)
Synthesis and properties of linear, branched, and cyclic metallacarborane oligomers (2003) (9)
Carborane-stabilized M(III) complexes of mononuclear and dinuclear arene complexes (M = iron, ruthenium) (1989) (9)
Unusual organic chemistry on a metallacarborane substrate: formation of a boron-vinyl ester from acetyl chloride (1991) (9)
Organotransition-metal metallacarboranes. 15. Regiospecific B-alkylation of (arene)M(Et2C2B3H5) (M = iron, ruthenium) and (C5Me5)Co(Et2C2B3H5) sandwich complexes (1990) (9)
Chapter 1 – Introduction and History (2016) (9)
Organotransition-metal metallacarboranes. 5. Studies on (.eta.6-arene)(carborane)iron complexes of benzene and biphenyl. Crystal structures of (.eta.6-C6H5C6H5)Fe(Et2C2B4H4) and 1,2-[(.eta.6-C6H6)Fe(Et2C2B4H3)]2CH(CH3)CH2, a hydrocarbon-linked bis(ferracarborane) (1985) (9)
Organotransition-metal metallacarboranes. 18. .eta.6,.eta.5-Benzyltetramethylcyclopentadienide(1-) as a bridging ligand in multilevel iron-cobalt sandwich complexes (1991) (9)
DECABORANE (16): ITS REARRANGEMENT TO DECABORANE (14) AND CLEAVAGE. (1962) (9)
Nido-Carborane building-block reagents. 3. Cyclic and open-chain oligomers incorporating -CB/sub 4/H/sub 6/C - units. Crown carboranes (1988) (9)
Metal-Carborane Multidecker Sandwiches as Building Blocks for Metallopolymers and Nanostructured Materials (2000) (9)
A Novel Heterooctametallic Metallacarborane Tetramer (1999) (9)
nido↔closo Interconversion of Six-Vertex Metallacarboranes: Access to CoC2 B3 and CoC2 B4 Clusters with Nonadjacent Carbon Atoms. (2001) (8)
Organotransition-metal metallacarboranes. 32. Electrochemical and electron spin resonance studies of tetradecker sandwich complexes (1993) (8)
Proton-proton spin coupling in metallocarboranes. Triple-resonance nuclear magnetic resonance spectroscopy as a structural probe for boron compounds (1977) (8)
Small metallacarboranes with metal-metal bonds. Crystal and molecular structures of 2,3-(CH3)2-1,2,4,5-(.eta.5-C5H5)2Co2C2B3H3 and 2,3-(CH3)2-1,2,4,5-(.eta.5-C5H5)2CoFe(H)C2B3H3 (1980) (8)
Organotransition-metal metallacarboranes. 22. Small-carborane-stabilized iron-indole and iron-thiophene .pi.-complexes (1991) (8)
Organotransition-Metal Metallacarboranes. 42. Synthesis and Cluster Fusion of Iron-Centered Tetradecker Sandwiches (1995) (8)
A mixed-metal trimetallic metallocarborane, [{(CO)3Fe}2(η5-C5H5) CoMe2C2B4H4] (1975) (8)
Metallacarboranes of the transition and lanthanide elements (2011) (8)
Radical Substitution at Boron in Small Cobaltacarboranes. Conversion of η5-C5Me5 to η4-C5Me5R Complexes1 (2002) (8)
Organotransition-metal metallacarboranes. 20. Fluoride-catalyzed carbon-silicon bond cleavage in Cp*Co(Me3Si)2C2B4H4. Synthesis of parent Cp*CoC2B4H6 and conversion to C-substituted Cp*CoRR'C2B4H4 derivatives (1991) (7)
Reactions of Metallocarboranes (1977) (7)
Electronic Interactions in (? 6 -Arene) Ferracarboranes 1 (2002) (7)
Organotransition-metal metallacarboranes. XXVIII : Controlled substitution at cage carbon atoms in CoC2B4 clusters. Linkage of bis(cobaltacarborane) sandwich complexes via carbon-bound bridging groups (1992) (7)
Organotransition-metal metallacarboranes. XVI, Directed synthesis of arene-linked metal sandwich complexes via controlled substitution on boron (1990) (7)
Studies of methyl derivatives of 1,2-dicarbaclovopentaborane(5) (1967) (7)
Chapter 16 – Carboranes in Medicine (2016) (6)
DIRECT INSERTION OF TRANSITION METALS INTO POLYHEDRAL CARBORANES, STRUCTURALLY NOVEL MONO‐, DI‐, AND TRIMETALLIC SMALL CAGE SYSTEMS (1974) (6)
Synthesis of R2R′2C4B8H8 tetracarbon carboranes from (η6-cyclooctatriene)iron(dicarbahexaborane) complexes via mixed-ligand thermal fusion (1990) (6)
A Mechanism Study of B10H10-2 Formation (1964) (6)
The Mechanism of B10H10-2 Formation from B10H12(ligand)2 Species (1967) (6)
Small carboranes: Four- to six-vertex clusters (2011) (5)
METAL-PROMOTED FUSION AND LINKAGE OF B5H8-, 1-XB5H7- (X = D, CH3), B10H13-, AND (η5-C5H5)COB4H7-. FACILE ROUTES TO B10H14 AND (η5-C5H5)2CO2B8H10 ISOMERS (1985) (5)
ARENE- AND CYCLOALKENE-TRANSITION METAL-CARBORANE SANDWICH COMPLEXES (1986) (4)
Synthesis and X-ray Crystal Structures of Two 14-vertex Di-iron Tetracarbon Metallocarbaboranes (1976) (4)
Tetracarbon metallacarboranes. 11. 11-Vertex nido cages: structures of two isomers of (.eta.5-C5H5)Co(CH3)4C4B6H6 (1981) (4)
Chapter 4 – Small Carboranes: Four- to Six-Vertex Clusters (2016) (4)
Chapter 2 – Structure and Bonding (2016) (4)
Additions and Corrections - Electron-Rich Carboranes. Studies of a Stereochemically Novel System, (CH3)4C4B7H9, an 11-Vertex Arachno Cluster (1982) (3)
Calcified pseudocyst of the spleen: case report. (1955) (3)
2,3‐diethyl‐2,3‐dicarba‐nido‐hexaborane(8) (2007) (3)
Eleven-vertex carboranes (2011) (3)
8 – Carborane Polymers (1970) (3)
CRYSTAL AND MOLECULAR STRUCTURE OF (C2H5)3NH+(CO(1,2-C2B9H11)2) (1982) (3)
Pentamethylcyclopentadienyl Cobaltaboranes Derived from the B5H8(-) and B9H14(-) Ions: Studies in Synthesis and Structure. (1981) (2)
Carboranes, Anti‐Crowns, Big Wheels, and Supersandwiches (2003) (2)
Transition Metal-Promoted Reactions of Main Group Species and Main Group-Promoted Reactions of Transition Metal Species (1992) (2)
Carboranes in Catalysis (2011) (2)
Thomas Jefferson, Alice in Wonderland, Polyhedral Boranes, and the Lipscomb Legacy (2002) (2)
Carborane Polymers and Dendrimers (2011) (2)
TETRACARBON METALLOCARBORANES. 2. THERMAL REARRANGEMENT OF 14-VERTEX CAGE SYSTEMS. CRYSTAL STRUCTURES OF THREE TETRACARBON DIFERRACARBORANE ISOMERS, (η5-C5H5)2FE2(CH3)4C4B8H8 (1977) (2)
SMALL METALLACARBORANES WITH METAL-METAL BONDS. CRYSTAL AND MOLECULAR STRUCTURES OF 2,3-(CH3)2-1,2,4,5-(η5-C5H5)2CO2C2B3H3 AND 2,3-(CH3)2-1,2,4,5-(η5-C5H5)2COFE(H)C2B3H3 (1980) (2)
STRUCTURAL CONSEQUENCES OF ELECTRON HYPERDEFICIENCY. SYNTHESIS AND CRYSTAL STRUCTURE OF AN IRON-COBALT METALLOCARBORANE HAVING TWO CLOSED POLYHEDRA FUSED ALONG AN EDGE (1976) (2)
Metal-induced oxidative fusion of boranes: synthesis of B12H16, the first neutral dodecaborane (1984) (2)
Chapter 14 – Carborane Polymers and Dendrimers (2016) (2)
Open 12-Vertex and Supra-Icosahedral Carboranes (2011) (2)
Chapter 15 – Carboranes in Catalysis (2016) (2)
The 1976 nobel prize for chemistry. (1976) (2)
3.01 – Boron-containing Rings Ligated to Metals (2007) (2)
Trimethylsilyl‐Substituted Derivatives of 2,3‐Dicarba‐nido‐Hexaborane(8) and Lithium, Sodium, and Dilithium Salts of the Carborane Dianion 2,3‐Bis(Trimethylsilyl)‐2,3‐Dicarba‐nido‐Hexaborate(2–) (2007) (2)
Tetracarbon Metallacarboranes. Part 11. 11-Vertex Nido Cages: Structures of Two Isomers of (η5-C5H5)Co(CH3)4C4B6H6. (1982) (2)
Inorganic structural chemistry by U. Müller (1993) (2)
2,2', 3,3'‐tetraethyl‐1,1‐dihydro‐[1,1' ‐commo‐bis(2,3‐dicrba‐1‐ferra‐closo‐heptaborane)] (12), [2,3‐(c2h5)2c2b4h4]2feh2 and 2,3,7,8‐tetraethyl‐2,3,7,8‐tetracarbadodecaborane(12), (c2)4c4b8h8 (2007) (2)
Chapter 13 – Metallacarboranes of the Transition and Lanthanide Elements (2016) (2)
Preparation of Stable Closo- and Nido-Cobaltaboranes from Na(+)B5H8(-). Complexes of the Formal B4H8(2-) and B4H8(2) and B4H6(4-) Ligands. (1973) (1)
SMALL COBALT AND NICKEL METALLOCARBORANES FROM 2,3-C2B4H8 AND 1,6-C2B4H6. SANDWICH COMPLEXES OF THE CYCLIC C2B3H7(2-) AND C2B3H5(4-) LIGANDS (1974) (1)
Synthetic Strategies in Boron Cage Chemistry (1989) (1)
Synthesis and structure of large boron cages and multi‐decker metal carborane sandwich complexes (2008) (1)
Electron-Rich Carboranes. Studies of a Stereochemically Novel System, (CH3)4C4B7H9, and 11-Vertex Arachno Cluster. (1981) (1)
Chapter 8 – Icosahedral Carboranes: Closo-CB11 Clusters (2016) (1)
Chapter 3 – Synthesis and Reactivity: An Overview (2016) (1)
A POLYHEDRAL GALLACARBORANE. (1969) (1)
Organotransition-Metal Metallacarboranes. Part 9. nido-2,3-Dibenzyl-2,3-dicarbahexaborane(8) ((PhCH2)2C2B4H6), a Versatile Multifunctional nido-Carborane: Iron-Polyarene Sandwich Compounds and Chromium Tricarbonyl π-Complexes. (1987) (1)
Chapter 17 – Carboranes in Other Applications (2016) (1)
Icosahedral carboranes: 1,7-C2B10H12 and 1,12-C2B10H12 (2011) (1)
Intramolecular B-B Linkage Between Polyhedral Cages in a Commo-Metallacarborane. Synthesis and Structure of a Fluxional Metal-Boron Cluster, (n(5)-C5(CH3)5)2Co3(CH3)4C4B8H7. (1980) (1)
COBALTABORANE ANALOGS OF DECABORANE (B10H14). CRYSTAL AND MOLECULAR STRUCTURES OF 6-(η5-C5(CH3)5)COB9H13, 6,9-(η5-C5(CH3)5)2)2CO2B8H12 5,7-(η5-C5(CH3)5)5)2CO2B8H12, AND 6-CL-5,7-(η5-C5(CH3)5)2CO2B8H11 (1982) (1)
Chapter 10 – Icosahedral Carboranes: 1,7-C2B10H12 and 1,12-C2B10H12 (2016) (1)
Boron-functionalized MC2B4 and MC2B3M' clusters and their applications (2000) (1)
Improved synthetic routes to small carboranes. Bench-scale preparation of nido-2,3-C2B4H8 derivatives from B5H9 and from B3H8- salts (1979) (1)
Icosahedral carboranes: Closo-CB11 clusters (2011) (1)
η8 Coordination of planar C8H8 2- to vanadium. Structural characterization of (η8-C8H8)V[(C2H 5)2C2B4H4] (1983) (1)
TETRACARBON METALLOCARBORANES. 5. A NEW SYNTHETIC ROUTE- SYNTHESIS OF CO2C4B6 AND COC4B7 NIDO CAGE SYSTEMS BY FUSION OF DICARBON COBALTACARBORANES IN ETHANOLIC POTASSIUM HYDROXIDE. CRYSTAL STRUCTURE OF (η5-C5H5)2CO2C4B6H10 (1978) (1)
Chapter 7 – Eleven-Vertex Carboranes (2016) (1)
Metal-Carborane Multidecker Sandwich Complexes as Building Blocks for New Materials (1996) (1)
CRYSTAL AND MOLECULAR STRUCTURE OF (η5-C5(CH3)5)3CO3B4H4, AN ELECTRON-HYPERDEFICIENT CLUSTER WITH SEVERE INTRAMOLECULAR LIGAND-LIGAND CROWDING (1982) (1)
Designed Synthesis and Assembly of Molecular Building-Blocks for New Materials (1999) (0)
Electronically Active Cyclocarborane-Metal-Arene Assemblies (1992) (0)
Dihydrodiborolyl-Transition Metal-Carboranyl Triple-Decker Sandwich Complexes. (1989) (0)
MERCURY-BRIDGED COBALTACARBORANE COMPLEXES CONTAINING BORON-MERCURY-BORON THREE-CENTER BONDS. SYNTHESIS AND STRUCTURE OF μμ′-((η5-C5R5)CO(CH3)2C2B3H4)2HG AND μ-((η5-C5R5)CO(CH3)2C2B3H4)HGCL (R = HYDROGEN, METHYL) AND RELATED COMPOUNDS (1981) (0)
SYNTHESIS OF FOUR-, FIVE-, AND SIX-BORON, METALLOCARBORANES FROM POLYHEDRAL C2B5H7 (1973) (0)
CARBON-RICH METALLACARBORANES. 13. SYNTHESIS AND STRUCTURE OF BIS(CARBORANYL)COBALT COMPLEXES DERIVED FROM (C2H5)4C4B8H82- (1985) (0)
3 – The Small Nido-Carboranes: CB5H9, C2B4H8, C3B3H7, C4B2H6, and C2B3H7 (1970) (0)
Tetradecker LM(C3B2)Co(C2B3)CoCp Sandwich Complexes (LM: Cp*Co, Cp*Rh, or (cymene)Ru). Designed Synthesis and Electronic Properties. (1991) (0)
Designed Synthesis of Multi-Functional Carboranes and Organo-Transition Metal - Carborane Complexes (1987) (0)
7 – The 1,7-C2B10H12 and 1,12-C2B10H12 (m- and p-Carborane) Systems (1970) (0)
Crystal Structure of a Novel Triple-Decked Sandwich Metallocarborane, μ(2,3)-l,3-C3H4-l,7,2,3-(η5-C5H5)2Co2C2B3H3, a Complex Containing a Bicyclic Planar Carborane Ligand Related to Pentalene. Partial Incorporation of a Cyclopentadien (1978) (0)
Synthesis and Characterization 4 M of ( Borane ) Cobalt ( Carborane ) Sandwich Complexes (0)
Two-Dimensional Correlated Nuclear Magnetic Resonance of Spin-Coupled 11B-1H Systems. (1979) (0)
Benzene-Centered Tri- and Tetrametallacarborane Sandwich Complexes Organotransition-Metal Metallacarboranes, part 56. This work was supported in part by the National Science Foundation (grant CHE 9980708 to R.N.G.) and the Deutsche Forschungsgemeinschaft (SFB 247, to W.S. for M.B.). Part 55: T. Dodg (2000) (0)
Organotransition-Metal Metallacarboranes. Part 13. Fulvalene- and Polyarene-Transition Metal-Carborane Complexes as Building Blocks for Multilevel Arrays. Stepwise Synthesis and Structural Characterization of Polymetallic Linked Sandw (1989) (0)
1‐(η5‐CYCLOPENTADIENYL)‐ AND 1‐(η5‐PENTAMETHYLCYCLOPENTADIENYL)COBALTA‐NIDO‐PENTABORANE SANDWICH COMPLEXES CONTAINING A SQUARE CYCLIC B4H82‐ LIGAND ANALOGOUS TO C4H42‐: STRUCTURAL AND SPECTROSCOPIC STUDIES (1985) (0)
Organotransition-Metal Metallacarboranes. Part 8. Mono-, Di-, and Triiron Polyarene Sandwich Complexes of Et2C2B4H2- 4 Containing Fluorene, 9,10-Dihydroanthracene, or (2.2)Paracyclophane Ligands. (1987) (0)
BRIDGE INSERTION REACTIONS OF THE 2,3-C2B4H7-ION WITH ALUMINIUM, GALLIUM AND TRANSITION METAL REAGENTS (1975) (0)
nido-Carborane Building-Block Reagents. Part 2. Bulky-Substituent (alkyl)2C2B4H6 Derivatives and (C6H5)2C2B4H6: Synthesis and Properties. (1989) (0)
Chapter 12 – Heteroatom Carboranes of the Main Group Elements (2016) (0)
SYNTHESIS AND STRUCTURE OF A COBALTOCENIUM COBALTACARBORANE ZWITTERION. COBALTOCENIUM AND TETRAHYDROFURAN DERIVATIVES OF NIDO,CLOSO-(2,3-(CH3)2C2B3H5)COH(2,3-(CH3)2C2B4H4) (1978) (0)
Solvent-Induced11B NMR Shifts in Metallaboranes and Metallacarboranes (1986) (0)
Organotransition-Metal Metallacarboranes. Part 15. Regiospecific B-Alkylation of (Arene)M(Et2C2B3H5) (M: Fe, Ru) and (C5Me5)Co(Et2C2B3H5) Sandwich Complexes. (1990) (0)
METAL SANDWICH COMPLEXES OF CYCLIC PLANAR AND PYRAMIDAL LIGANDS CONTAINING BORON (1979) (0)
9 – Degradation of the Icosahedral Cage. Heteroatom Carboranes and Transition Metal π-Complexes (1970) (0)
Introduction and History (2011) (0)
Synthesis of R2R′2C4B8H8 Tetracarbon Carboranes from (η6‐Cyclooctatriene)iron(dicarbahexaborane) Complexes via Mixed‐Ligand Thermal Fusion. (1990) (0)
5 – The Intermediate Closo-Carboranes: C2B6H8, C2B7H9, C2B8H10, and C2B9H11 (1970) (0)
Mercury-Bridged Cobaltacarborane Complexes Containing B-Hg-B Three-Center Bonds. Synthesis and Structure of mu, mu'-((n5-C5R5)Co(CH3)2C2B3H4)Hg, mu-(n(5)-C5R5)Co(CH3)2C2B3H4)HgCl, (R=H, CH3) and Related Compounds. (1980) (0)
Synthesis and Structure of Large Boron Cages and Multi-Decker Metal-Carborane Sandwich Complexes (1987) (0)
Seven-Vertex Phosphinohalometallacarboranes of Iron, Cobalt, and Nickel: Syntheses, Structures, and Reactions. (1986) (0)
TETRACARBON METALLACARBORANES. 10. THERMODYNAMICALLY FAVORED GEOMETRY OF LARGE NIDO CAGES. STRUCTURE OF THE THERMAL REARRANGEMENT PRODUCT (ISOMER III) OF (η5-C5H5)CO(CH3)4C4B7H7 (1981) (0)
Organotransition-Metal Metallacarboranes. Part 12. Arene-Metal-Carborane Triple-Decker Sandwiches. Designed Synthesis of Homo- and Heterobimetallic Complexes of Cobalt, Iron, Ruthenium, and Osmium. (1989) (0)
Organo-Transition-Metal Metallacarboranes. Part 26. Carborane Ligands in Organometallic Chemistry: A New Class of Fischer Carbene Complexes. (1993) (0)
CRYSTAL STRUCTURE OF A CLOSO SIX-VERTEX METALLOBORON CLUSTER, 1,2-(η5-C5H5)2CO2B4H6, WITH HYDROGEN ATOMS BRIDGING CO2B TRIANGULAR FACES (1979) (0)
“New Chemistry of Cp*Co(Et2C2B3H5) (2000) (0)
Polyhedral Cobaltaboranes. Versatile Replacement of BH Groups by Co(C5H5) Units in Boron Hydride Frameworks. Borane-Metal Cluster Hybrid Molecules. (1977) (0)
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Metal Ion-Promoted Syntheses of Boranes and Carboranes. (1986) (0)
STRUCTURAL INVESTIGATION OF A B-FERROCENYL-SUBSTITUTED TETRACARBON CARBORANE, 4((η5-C5H5)FE(η5-C5H4))-2,3,7,8-(CH3)4C4B8H7 (1980) (0)
Metallacarborane-Based Precursors for Electroactive Materials. (1995) (0)
Cyclocarborane‐Stabilized Multidecker/Multicluster Sandwich Compounds and Linked Molecular Systems (1991) (0)
Intermediate Carboranes: Seven- to Nine-Vertex Clusters (2011) (0)
TETRAMETALLIC NICKEL-BORON CLUSTERS, (η5-C5H5)4NI4B4H4 AND (η5-C5H5)4NI4B5H5. SYNTHESIS OF METALLOBORON CLUSTER SYSTEMS BY TRANSITION METAL AGGREGATION ON A SMALL BORANE FRAMEWORK (1978) (0)
Metal‐Carborane Sandwiches and Macromolecular Assemblies (2010) (0)
MOLECULAR AND ELECTRONIC STRUCTURE OF A MIXED-SPIN DIIRON “WEDGED” METALLACARBORANE, (ME2C2B4H4)2(FEII(LOW-SPIN))(FEII(HIGH-SPIN))L2 (L2 = (THF)2 OR (MEO)2C2H4), AN OXIDATIVE FUSION INTERMEDIATE (1983) (0)
Triple-Decker Sandwich Complexes of Cobalt, Rhodium, and Ruthenium Bridged by C2B3 or C3B2 Rings: Synthesis, Structure, and Electrochemistry. (1991) (0)
Index of Contributers (1992) (0)
Synthesis of 4-, 5-, and 6-Boron Metallocarboranes from the Polyhedral C2B5H7 System (1972) (0)
TETRACARBON METALLACARBORANES. 9. NEW TYPES OF NIDO CAGE GEOMETRY. CRYSTAL AND MOLECULAR STRUCTURES OF ((C6H5)2PCH2)2NI(CH3)4C4D8H8 (ISOMER 1) AND (η5-C5H5)CO(CH3)4C4B7H7 (ISOMER 2) (1980) (0)
Boron Clusters with Transition Meta1-Hydrogen Bonds (106 Literaturzitate). (1983) (0)
CARBORANE FORMATION FROM ALKYNES AND BORANES. II. SLOW REACTIONS OF B4H10 AND B5H11 WITH ACETYLENE, METHYLACETYLENE AND DIMETHYLACETYLENE. (1967) (0)
Heteroatom carboranes of the main group elements (2011) (0)
Novel Iron-Carborane , .-and 7-Complexes Derived From Nido-CaB 4 H 8 . A Paramagnetic Small Carborane Sandwich Compound (0)
Thermal Isomerization Studies of Small Metallocarboranes. Cage Rearrangement Equilibria and Reversible Cobalt Atom Migrations. (1974) (0)
Organometallacarborane Clusters in Synthesis: Recent Advances and New Directions (1995) (0)
Metal—Carborane Multidecker Sandwiches as Building Blocks for Metallopolymers and Nanostructured Materials (2001) (0)
Carboranes in Other Applications (2011) (0)
Cobalt-boron clusters. Technical report (1976) (0)
Carborane Formation in Alkyne-Borane Gas Phase Systems. V. Conversion of Two-Carbon to Four-Carbon Carboranes via Alkyne Insertion. NMR Studies of Tetracarba-nido-hexaboranes. (1971) (0)
Chapter 6 – Ten-Vertex Carboranes (2016) (0)
Paramagnetic Metallacarborane Complexes. Synthesis, Electrochemistry, ESR, and P‐NMR Studies (1995) (0)
nido-Carborane Building-Block Reagents. Part 4. Regiospecific Substitution at Boron in 2,3-R2C2B4H6 Cages. Evidence for Intramolecular C-H---Hbridge Interactions in 2,3-R2C2B4H5-4-R′ Derivatives. (1989) (0)
FOUR-CARBON CARBORANES, SYNTHESIS OF TETRA-C-METHYLTETRACARBADODECABORANE(12) AND ITS METALLOCARBORANE DERIVATIVES (1975) (0)
Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4 and (ETA to the 5th power-C5H5)4Ni4B5H5, by transition metal aggregation on a small Borane framework (1978) (0)
Tetracarbon metallocarborances. 6: Stereochemical relationships between Co2C4B6 cage isomers formed by oxidative fusion. Crystal structure of (n5-C5h5)2Co2(CH3)4C4B6H6 isomer 5 (1979) (0)
Recent Advances in Metallacarborane Sandwich Chemistry: Controlled Linking, Stacking, and Cool Fusion (1998) (0)
nido-Carborane Building-Block Reagents. Part 1. Polycyclic Arene RR′C2B4H6 Derivatives: Synthesis via Indenyl and Fluorenyl Alkynes and Metal-Promoted Oxidative Fusion. (1989) (0)
Structure and Bonding (2011) (0)
Erratum: Organotransition-metal Metallacarboranes 10 (1987) (0)
Organotransition-Metal Metallacarboranes. Part 11. Chromium Tricarbonyl η6-Complexes of nido-2,3-(PhCH2)2C2B4H6: Metal Complexation and Oxidative Fusion. (1988) (0)
Tetracarbon metallocarboranes. 1. Iron, nickel and molybdenum complexes derived from (CH3)4C4B8H8. Crystal structure of (n5-C5H5)Fe(CH3)4C4B7H8 (1977) (0)
Tetrametallic nickel-boron clusters, (eta to the 5th power-C/sub 5/H/sub 5/)4Ni/sub 4/B/sub 4/H/sub 4/ and (eta to the 5th power-C/sub 5/H/sub 5/)4Ni/sub 4/B/sub 5/H/sub 5/, by transition metal aggregation on a small borane framework. Technical report (1978) (0)
MIXED-METAL TRIMETALLIC METALLOCARBORANE, (((CO)3FE)2(η5-C5H5)COME2C2B4H4) (1976) (0)
nido-Carborane Building-Block Reagents. Part 3. Cyclic and Open-Chain Oligomers. Incorporating Cyclic-CB4H6C- Units. “Crown” Carboranes. (1989) (0)
Organotransition-Metal Metallacarboranes. Part 16. Directed Synthesis of Arene-Linked Metal Sandwich Complexes via Controlled Substitution on Boron. (1990) (0)
Organotransition-Metal Metallacarboranes. Part 10. π-Complexation of nido-(PhCH2)2C2B4H6 at the C2B3 and C6 Rings. Synthesis and Crystal Structures of nido-2,3-((CO)3Cr(η6-C6H5)CH2)2-2,3-C2B4H6 and (PhCH2)4C4B8H8, a Nonfluxional C4B8 (1987) (0)
Molecular Clusters of the Main Group Elements (2005) (0)
STUDIES OF IRON(II) AND -(III) METALLOCARBORANES DERIVED FROM NIDO-C2B4H8 AND CLOSO C2B5H7 (1973) (0)
Carbon‐Rich Metallacarboranes. Part 12. Synthesis and Structures of Chromium(III) Complexes with "Nonconforming" Cage Geometries. (1983) (0)
Chapter 5 – Intermediate Carboranes: Seven- to Nine-Vertex Clusters (2016) (0)
Boranametallacarboranes. 2. Crystal and Molecular Structures of (2, 3- (C2H5)2C2B4H4)-5-Co(B9H12-1-O(CH2)4), (2,3-(CH3)2C2B3H5)-5-Co(B9H12-1-O(CH2)4), and (1,2-(C2H5)2C2B7H7)-6-Co(B9H12-2-O(CH2)4) (1981) (0)
KLEINER CARBORAN-UEBERGANGSMETALL-KOMPLEX, (PI-2-CH3C3B3H5)MN(CO)3 (1970) (0)
4 – The Small Closo-Carboranes: C2B3H5, C2B4H6, C2B5H7, and CB5H7 (1970) (0)
STUDIES OF 2-(η5-C5H5)COB4H8, A COBALTABORANE ANALOG OF PENTABORANE(9) (1978) (0)
nido<-->closo Interconversion of Six-Vertex Metallacarboranes: Access to CoC(2)B(3) and CoC(2)B(4) Clusters with Nonadjacent Carbon Atoms Organotransition-Metal Metallacarboranes, part 57. This work was supported in part by the National Science Foundation (grant CHE 9980708) and the Alexander von Hu (2001) (0)
Chapter 11 – Open 12-Vertex and Supra-Icosahedral Carboranes (2016) (0)
Ten-Vertex Carboranes (2011) (0)
Boranametallacarboranes. 1. Synthesis and Characterization of (Borane) Cobalt (Carborane) Sandwich Complexes (1981) (0)
Organo‐Transition‐Metal Metallacarboranes. Part 17. Electronic Control of Metallacarborane Stacking Reactions. Directed Synthesis of Cp*Co( C2B3)M(C2B3)CoCp* Tetradecker Sandwiches. (1991) (0)
Four-Carbon Carboranes. Synthesis of (CH3)4C4B8H8 and Its Metallocarborane Derivatives. (1974) (0)
Cytotoxicity of Tantalum(V) and Niobium(V) Small Carborane Complexes and Mode of Action in P388 Lymphocytic Leukemia Cells. (2000) (0)
TETRACARBON METALLOCARBORANES. 4. STRUCTURE OF THE NIDO SYSTEM (η5-C5H5)CO(CH3)4C4B7H6OC2H5. THE PROBLEM OF THE STRUCTURAL DIVERSITY OF ELECTRONICALLY ANALOGOUS CAGE SYSTEMS (1978) (0)
William Nunn Lipscomb Jr (1919–2011) (2011) (0)
CARBON-RICH METALLACARBORANES. 14. SYNTHESIS AND STRUCTURE OF MIXED-LIGAND COBALT AND IRON COMPLEXES DERIVED FROM (C2H5)4C4B8H82- AND (C2H5)2C2B4H5- (1985) (0)

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What Schools Are Affiliated With Russel L. N. Grimes?

Russel L. N. Grimes is affiliated with the following schools:

University of Vermont
University of Virginia
University of Barcelona