Scott E. Denmark
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American chemist
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Scott E. Denmarkchemistry Degrees
Chemistry
#332
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#642
Historical Rank
#161
USA Rank
Organic Chemistry
#54
World Rank
#80
Historical Rank
#24
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Chemistry
Scott E. Denmark's Degrees
- Bachelors Chemistry University of California, Berkeley
- PhD Chemistry University of California, Berkeley
Why Is Scott E. Denmark Influential?
(Suggest an Edit or Addition)According to Wikipedia, Scott Eric Denmark is an American chemist who is the Reynold C. Fuson Professor of Chemistry at the University of Illinois at Urbana-Champaign . Denmark received an S.B. degree from MIT in 1975 and the D.Sc.Tech. degree from ETH Zurich in 1980, under the supervision of Professor Albert Eschenmoser. He joined the faculty at UIUC the same year and became an associate professor in 1986, full professor in 1987, and was named the Fuson Professor of Chemistry in 1991. He served as the president and editor-in-chief of the Organic Reactions book series between 2008 and 2018. In 2017, Denmark was elected to the American Academy of Arts and Sciences. In 2018, he was elected to the National Academy of Sciences.
Scott E. Denmark's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Lewis base catalysis in organic synthesis. (2008) (944)
- Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones. (2003) (838)
- Tandem [4+2]/[3+2] Cycloadditions of Nitroalkenes. (1996) (510)
- Catalytic asymmetric synthesis. (2000) (473)
- Catalytic, asymmetric halofunctionalization of alkenes--a critical perspective. (2012) (385)
- Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods. (2008) (379)
- Catalytic, enantioselective, vinylogous aldol reactions. (2005) (338)
- Design and implementation of new, silicon-based, cross-coupling reactions: importance of silicon-oxygen bonds. (2002) (311)
- Asymmetric catalysis of aldol reactions with chiral lewis bases. (2000) (226)
- Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning (2019) (221)
- Lewis base catalysis of bromo- and iodolactonization, and cycloetherification (2010) (197)
- Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link (2016) (195)
- Silicon-based cross-coupling reactions in the total synthesis of natural products. (2010) (184)
- Asymmetric Allylation of Aldehydes with Chiral Lewis Bases (1994) (175)
- Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes. (1997) (174)
- Catalytic, enantioselective aldol additions to ketones. (2002) (169)
- Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis. (2012) (163)
- A comparison of (chloromethyl)- and (iodomethyl)zinc cyclopropanation reagents (1991) (156)
- On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis. (2006) (155)
- Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes. (2005) (151)
- Enantioselective Ring Opening of Epoxides with Silicon Tetrachloride in the Presence of a Chiral Lewis Base. (1998) (150)
- (E)-3-(Trimethylsilyl)-2-propen-1-ol. An Improved Preparation (1983) (148)
- Catalytic, enantioselective addition of substituted allylic trichlorosilanes using a rationally-designed 2,2'-bispyrrolidine-based bisphosphoramide. (2001) (147)
- Catalytic Epoxidation of Alkenes with Oxone (1995) (146)
- Lewis base activation of Lewis acids: catalytic enantioselective allylation and propargylation of aldehydes. (2001) (145)
- On the absolute configurational stability of bromonium and chloronium ions. (2010) (143)
- Highly stereospecific, cross-coupling reactions of alkenylsilacyclobutanes (1999) (140)
- Synthetic Analogs of the Active Sites of Iron-Sulfur Proteins. XI. Synthesis and Properties of Complexes Containing the Fe2S2 Core and the Structures of Bis[o-xylyl-α,α′-dithiolato-μ-sulfido-ferrate(III)] and Bis[p-tolylthiolato-μ-sulfido-ferrate(III)] Dianions (1975) (138)
- Asymmetric Addition of Organolithium Reagents to Imines (1994) (136)
- Catalytic asymmetric thiofunctionalization of unactivated alkenes. (2011) (136)
- Silicon-directed Nazarov cyclization (1982) (131)
- Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions. (2010) (123)
- Catalytic, stereospecific syn-dichlorination of alkenes (2015) (122)
- Organosilicon Reagents: Synthesis and Application to Palladium-Catalyzed Cross-Coupling Reactions (2003) (121)
- Preparation of Chiral Bisoxazolines: Observations on the Effect of Substituents (1995) (120)
- Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides. (2009) (120)
- The first catalytic, asymmetric alpha-additions of isocyanides. Lewis-base-catalyzed, enantioselective Passerini-type reactions. (2003) (116)
- Chemistry of Trichlorosilyl Enolates. 1. New Reagents for Catalytic, Asymmetric Aldol Additions (1996) (114)
- Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals (1991) (114)
- Lewis base activation of lewis acids. Addition of silyl ketene acetals to aldehydes. (2002) (114)
- Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions. (2006) (112)
- Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities. (2015) (112)
- Lewis base activation of Lewis acids. Vinylogous aldol reactions. (2003) (110)
- Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates. (2015) (107)
- Ligand-mediated addition of organometallic reagents to azomethine functions (1996) (106)
- Highly stereoselective hydrocarbation of terminal alkynes via Pt-catalyzed hydrosilylation/Pd-catalyzed cross-coupling reactions. (2001) (105)
- On the stereochemistry of allylmetal-aldehyde condensations. Preliminary communication (1983) (104)
- Chemistry of Enoxysilacyclobutanes - Highly Selective Uncatalyzed Aldol Additions (1994) (103)
- Sequential cross-coupling of 1,4-bissilylbutadienes: synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes. (2005) (102)
- Total synthesis of papulacandin D. (2007) (101)
- Fluoride-free cross-coupling of organosilanols. (2001) (99)
- Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction. (2017) (99)
- Lewis base catalyzed, enantioselective aldol addition of methyl trichlorosilyl ketene acetal to ketones. (2005) (98)
- Total synthesis of RK-397. (2005) (98)
- Organocerium additions to SAMP-hydrazones: general synthesis of chiral amines (1987) (97)
- Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes. (2009) (95)
- Synthesis and reactivity of enantiomerically enriched thiiranium ions. (2009) (94)
- Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes (2014) (93)
- Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction. (2004) (93)
- Lewis Base Catalyzed, Enantioselective, Intramolecular Sulfenoamination of Olefins (2014) (92)
- Lewis base catalysis of the Mukaiyama directed aldol reaction: 40 years of inspiration and advances. (2013) (91)
- Catalytic, enantioselective alpha-additions of isocyanides: Lewis base catalyzed Passerini-type reactions. (2005) (90)
- Silicon‐Directed Nazarov Reactions II. Preparation and Cyclization of β‐Silyl‐substituted Divinyl Ketones (1983) (90)
- Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides. (2006) (90)
- A systematic investigation of quaternary ammonium ions as asymmetric phase-transfer catalysts. Application of quantitative structure activity/selectivity relationships. (2011) (90)
- Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone. (2002) (89)
- Lewis base activation of Lewis acids: development of a Lewis base catalyzed selenolactonization. (2007) (87)
- The First Catalytic, Diastereoselective, and Enantioselective Crossed-Aldol Reactions of Aldehydes We are grateful to the National Science Foundation for generous financial support (NSF CHE 9803124). (2001) (86)
- The Chemistry of Trichlorosilyl Enolates. 2. Highly-Selective Asymmetric Aldol Additions of Ketone Enolates (1997) (85)
- Catalytic, Enantioselective Cyclopropanation of Allylic Alcohols. Substrate Generality. (1997) (83)
- Catalytic Epoxidation of Alkenes with Oxone. 2. Fluoro Ketones. (1997) (83)
- Enantioselective Total Syntheses of (+)-Castanospermine, (+)-6-Epicastanospermine, (+)-Australine, and (+)-3-Epiaustraline (1999) (83)
- A systematic investigation of quaternary ammonium ions as asymmetric phase-transfer catalysts. Synthesis of catalyst libraries and evaluation of catalyst activity. (2011) (82)
- Understanding the correlation of structure and selectivity in the chiral-phosphoramide-catalyzed enantioselective allylation reactions: solution and solid-state structural studies of bisphosphoramide.SnCl(4) complexes. (2003) (81)
- Stereochemistry of Allylmetal-Aldehyde Condensations. 2. Allylstannanes (1984) (81)
- Lewis base activation of Lewis acids: catalytic, enantioselective vinylogous aldol addition reactions. (2007) (80)
- Mild and General Cross-Coupling of (α-Alkoxyvinyl)silanols and -silyl Hydrides (2000) (80)
- Cross-coupling reactions of organosilicon compounds: new concepts and recent advances. (2002) (80)
- Lewis base catalyzed addition of trimethylsilyl cyanide to aldehydes. (2006) (79)
- The interplay of invention, discovery, development, and application in organic synthetic methodology: a case study. (2009) (78)
- Chiral Phosphoramide-Catalyzed Aldol Additions of Ketone Enolates. Preparative Aspects (1999) (75)
- Synthesis of (+)-casuarine. (2000) (75)
- Cross-coupling of aromatic bromides with allylic silanolate salts. (2008) (75)
- Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols. (2008) (75)
- The Chemistry of Trichlorosilyl Enolates. Aldol Addition Reactions of Methyl Ketones (2000) (74)
- Stereochemical and spectroscopic studies on the reaction of allylstannanes with aldehydes (1989) (73)
- Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations. (2018) (73)
- Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl Grignard reagents. (2013) (73)
- The Development of Chiral, Nonracemic Dioxiranes for the Catalytic, Enantioselective Epoxidation of Alkenes (1999) (73)
- Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides. (2006) (73)
- Synthesis of 3,4,5-trisubstituted isoxazoles via sequential [3 + 2] cycloaddition/silicon-based cross-coupling reactions. (2005) (72)
- Cross-coupling reactions of arylsilanols with substituted aryl halides. (2003) (72)
- Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes. (2018) (72)
- Silyl ketene imines: highly versatile nucleophiles for catalytic, asymmetric synthesis. (2012) (72)
- Enantioselective Cyclopropanation of Allylic Alcohols. The Effect of Zinc Iodide. (1997) (72)
- Synthesis of unsymmetrical biaryls from arylsilacyclobutanes (1999) (71)
- Palladium-catalyzed silylation of aryl bromides leading to functionalized aryldimethylsilanols. (2003) (71)
- On the Mechanism of Catalytic, Enantioselective Allylation of Aldehydes with Chlorosilanes and Chiral Lewis Bases (2000) (71)
- Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes. (2007) (70)
- Silicon‐Directed Nazarov Cyclizations. Part V. Substituent and heteroatom effects on the reaction (1988) (70)
- Synthesis of Phosphoramides for the Lewis Base-Catalyzed Allylation and Aldol Addition Reactions. (1999) (70)
- SnCl4(4-tert-BuC6H4CHO)2. X-ray crystal structure, solution NMR, and implications for reactions at complexed carbonyls (1987) (69)
- Asymmetric construction of quaternary centers by enantioselective allylation: application to the synthesis of the serotonin antagonist LY426965. (2002) (69)
- Cross-coupling reactions of alkenylsilanolates. Investigation of the mechanism and identification of key intermediates through kinetic analysis. (2004) (68)
- Stereospecific palladium-catalyzed cross-coupling of (E)- and (Z)-alkenylsilanolates with aryl chlorides. (2006) (67)
- Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. (2013) (67)
- On the lewis acid induced addition of allylstannanes to aldehydes: A spectroscopic investigation (1988) (67)
- Catalytic enantioselective allylation with chiral Lewis bases. (2003) (66)
- Intramolecular hydrosilylation and silicon-assisted cross-coupling: an efficient route to trisubstituted homoallylic alcohols. (2001) (66)
- Intramolecular silicon-assisted cross-coupling: total synthesis of (+)-brasilenyne. (2002) (65)
- The vinylogous anomeric effect in 3-alkyl-2-chlorocyclohexanone oximes and oxime ethers (1990) (65)
- Asymmetric electrophilic amination of chiral phosphorus-stabilized anions (1992) (65)
- Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes (2014) (65)
- On the mechanism of the selenolactonization reaction with selenenyl halides. (2006) (64)
- Sequential ring-closing metathesis and silicon-assisted cross-coupling reactions: stereocontrolled synthesis of highly substituted unsaturated alcohols. (2001) (63)
- Fluoride-promoted cross-coupling reactions of alkenylsilanols. Elucidation of the mechanism through spectroscopic and kinetic analysis. (2004) (63)
- Quantitative Structure-Selectivity Relationships in Enantioselective Catalysis: Past, Present, and Future. (2019) (63)
- Total Synthesis of (+)-Papulacandin D. (2010) (62)
- Intramolecular silicon-assisted cross-coupling reactions: general synthesis of medium-sized rings containing a 1,3-cis-cis diene unit. (2002) (62)
- Spectroscopic studies on the structure and conformation of Lewis acid-aldehyde complexes (1993) (62)
- ASYMMETRIC CONSTRUCTION OF A QUATERNARY CARBON CENTER BY TANDEM 4 + 2/3 + 2 CYCLOADDITION OF A NITROALKENE. THE TOTAL SYNTHESIS OF (-)-MESEMBRINE (1997) (61)
- Lithium/ammonia cleavage of the nitrogen-nitrogen bond in N-(methoxycarbonyl)- and N-acetylhydrazines (1990) (61)
- Tandem double-intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. Studies toward a total synthesis of daphnilactone B: piperidine ring construction. (2006) (61)
- Lewis base catalyzed enantioselective aldol addition of acetaldehyde-derived silyl enol ether to aldehydes. (2005) (59)
- Silicon-directed Nazarov cyclizations. 8. Stereoelectronic control of torquoselectivity (1990) (59)
- Solution and Solid-State Studies of a Chiral Zinc-Sulfonamide Complex Relevant to Enantioselective Cyclopropanations. (1998) (59)
- Vinylation of aryl bromides using an inexpensive vinylpolysiloxane. (2006) (58)
- Solution and solid-state structure of a phosphorus-stabilized carbanion (1990) (58)
- Inter-and Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins. 2-Nitrostyrenes (1992) (57)
- Solution- and solid-state structural studies of (halomethyl)zinc reagents (1992) (56)
- Palladium- (and nickel-) catalyzed vinylation of aryl halides. (2009) (56)
- Carbanion-Accelerated Claisen Rearrangements (1982) (56)
- Palladium-Catalyzed Cross-Coupling Reactions of Substituted Aryl(dimethyl)silanols (2004) (55)
- Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis. (2016) (55)
- Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates. (2008) (55)
- Lewis base activation of Lewis acids. Vinylogous aldol addition reactions of conjugated N,O-silyl ketene acetals to aldehydes. (2006) (55)
- Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Mechanistic Aspects: A Remarkable Case of Negative Catalysis (2014) (55)
- α-chloro ketoximes as precursors of nitrosoalkenes: preparation, stereochemistry, and conformation (1984) (54)
- Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols. (2002) (54)
- Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes: construction of the pentacyclic core structure of daphnilactone B. (2009) (53)
- Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. 11. The Synthesis of (+)-Crotanecine (1997) (53)
- Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides. (2006) (53)
- On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR. (2009) (53)
- Auxiliary-based, asymmetric SN2' reactions: a case of 1,7-relative stereogenesis (1990) (53)
- Synthesis of (-)-7-epiaustraline and (-)-1-epicastanospermine. (2000) (53)
- Organocerium Additions to Hydrazones: Effects of Reagent Stoichiometry on Efficiency and Selectivity (1993) (52)
- INVESTIGATIONS ON TRANSITION-STATE GEOMETRY IN THE ALDOL CONDENSATION (1989) (52)
- Tandem Intramolecular Silylformylation and Silicon-Assisted Cross-Coupling Reactions. Synthesis of Geometrically Defined α,β-Unsaturated Aldehydes (2003) (52)
- Allylation of Carbonyls: Methodology and Stereochemistry (2007) (52)
- Configuration, Conformation, and Colligative Properties of a Phosphorus-Stabilized Anion (1991) (51)
- On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides. (2010) (51)
- Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. Preparative and stereochemical aspects. (2014) (51)
- Silicon‐Directed Nazarov Reactions III. Stereochemical and Mechanistic Considerations (1983) (51)
- N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis (2010) (51)
- Synthesis of (+)-1-epiaustraline. (2001) (50)
- Triarylcarbenium ions as catalysts in the Mukaiyama Aldol addition: A mechanistic investigation (1994) (50)
- Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. 13. The Synthesis of (−)-Detoxinine (1997) (50)
- ExCage (2020) (50)
- A New, General, and Stereoselective Method for the Synthesis of Trisubstituted Alkenes (1993) (49)
- Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates. (2002) (49)
- Enantioselective, Lewis Base-Catalyzed Carbosulfenylation of Alkenylboronates by 1,2-Boronate Migration. (2018) (49)
- Asymmetric Carboalkoxyalkylidenation with a Chiral Horner-Wadsworth-Emmons Reagent (1994) (49)
- Solution and solid-state structure of the "Wittig-Furukawa" cyclopropanation reagent (1991) (48)
- A General Method for the Preparation of 2,2-Disubstituted 1-Nitroalkenes (1993) (48)
- Asymmetric Nitroalkene [4 + 2] Cycloadditions: Enantioselective Synthesis of 3-Substituted and 3,4-Disubstituted Pyrrolidines (1995) (48)
- The Chemistry of Trichlorosilyl Enolates. 6. Mechanistic Duality in the Lewis Base-Catalyzed Aldol Addition Reaction (1998) (48)
- Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects. (2006) (48)
- Lewis base activation of Lewis acids: catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes. (2008) (48)
- Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides. (2004) (47)
- The Nazarov cyclization (1995) (47)
- Catalytic, nucleophilic allylation of aldehydes with allyl acetate. (2009) (46)
- 1-Methyl-1-vinyl- and 1-Methyl-1-(prop-2-enyl)silacyclobutane: Reagents for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Halides (2000) (46)
- Phosphine Oxides as Stabilizing Ligands for the Palladium-Catalyzed Cross-Coupling of Potassium Aryldimethylsilanolates. (2007) (46)
- Sequential ring-closing metathesis/Pd-catalyzed, Si-assisted cross-coupling reactions: general synthesis of highly substituted unsaturated alcohols and medium-sized rings containing a 1,3-cis-cis diene unit (2004) (46)
- Sequential silylcarbocyclization/silicon-based cross-coupling reactions. (2007) (45)
- Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes. (2003) (45)
- Stereochemical studies on the addition of allylstannanes to aldehydes. The SE' component (1994) (45)
- Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. II. The effect of promoter structure on selectivity (1995) (45)
- Electrophilic activation of the Horner-Wadsworth-Emmons-Wittig reaction: highly selective synthesis of dissymmetric olefins (1992) (44)
- Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. I. Optimization of reaction protocol (1995) (44)
- Lewis Base-Catalyzed, Asymmetric Aldol Additions of Methyl Ketone Enolates† (1998) (44)
- Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol. (2012) (44)
- Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate. (2003) (44)
- Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles. (2018) (44)
- Structure and Dynamics of Phosphorus(V)-Stabilized Carbanions: A Comparison of Theoretical, Crystallographic, and Solution Structures (1994) (44)
- Mechanistic and stereochemical divergence in the allylsilane-acetal addition reaction (1989) (44)
- Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols (2017) (44)
- Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins (1986) (43)
- 6-Oxo-1,1,4,4-tetramethyl-1,4-diazepinium Salts. A New Class of Catalysts for Efficient Epoxidation of Olefins with Oxone† (1998) (43)
- Investigations on Transition-State Geometry in the Lewis Acid- (Mukaiyama) and Fluoride-Promoted Aldol Reactions (1994) (42)
- The chemistry of enoxysilacyclobutanes : highly selective, uncatalyzed aldol additions (1993) (42)
- SYNTHESIS, STRUCTURE, AND REACTIVITY OF AN ORGANOGERMANIUM LEWIS ACID (1990) (42)
- The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: Solution Structure of Their Lewis Acid Complexes+ (1989) (41)
- Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 17. The Spiro Mode. Efficient and Highly Selective Synthesis of Azapropellanes (1998) (41)
- On the Stereoselective Opening of Achiral Dioxane Acetals (1991) (40)
- Lewis base activation of Lewis acids: catalytic enantioselective glycolate aldol reactions. (2008) (40)
- Nazarov and Related Cationic Cyclizations (1991) (40)
- A general synthesis of N-vinyl nitrones. (2006) (40)
- Palladium-Catalyzed Conjugate Addition of Organosiloxanes to α,β-Unsaturated Carbonyl Compounds and Nitroalkenes (2003) (40)
- Carbanion-accelerated Claisen rearrangements. 8. Phosphonamide anion-stabilizing groups (1991) (40)
- Catalytic, Enantioselective syn-Diamination of Alkenes. (2019) (39)
- Total syntheses of isodomoic acids G and H. (2009) (39)
- Stereoselective alkylations of chiral, phosphorus-stabilized benzylic carbanions (1990) (39)
- 2-silyloxy-1,2-oxazines, a new type of acetals of conjugated nitroso alkenes. (2003) (38)
- The Tandem Cycloaddition Chemistry of Nitroalkenes. A Novel Synthesis of (-)-Hastanecine (1994) (38)
- Silicon-directed nazarov cyclizations-IV : Further studies in stereochemical control (1986) (38)
- Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides (2006) (38)
- Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. 15. The Bridged Mode (α-Tether) (1997) (37)
- Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines (2017) (37)
- Development of a general, sequential, ring-closing metathesis/intramolecular cross-coupling reaction for the synthesis of polyunsaturated macrolactones. (2010) (37)
- Cross-coupling of vinylpolysiloxanes with aryl iodides (2001) (36)
- Studies on the addition of allyl oxides to sulfonylallenes. Preparation of highly substituted allyl vinyl ethers for carbanionic Claisen rearrangements (1987) (36)
- Intramolecular [4+2] cycloadditions of nitrosoalkenes with olefins (1984) (36)
- Diphenylmethylsilyl Ether (DPMS): A Protecting Group for Alcohols (1987) (35)
- Design, validation, and implementation of a rapid-injection NMR system. (2010) (35)
- Preparation of 2,3-Disubstituted Indoles by Sequential Larock Heteroannulation and Silicon-Based Cross-Coupling Reactions. (2009) (35)
- Solid State and Solution Structural Studies of Chiral Phosphoramide- Tin Complexes Relevant to Lewis Base Catalyzed Aldol Reactions † (1999) (35)
- Studies on the Bisoxazoline and (-)-Sparteine Mediated Enantioselective Addition of Organolithium Reagents to Imines. (2008) (34)
- Asymmetric Michael Addition Reaction of Phosphorus-Stabilized Allyl Anions with Cyclic Enones (1995) (34)
- Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis. (2020) (34)
- Alkylation of chiral, phosphorus-stabilized carbanions : substituent effects on the alkylation selectivity (1994) (34)
- An Ab initio Study of the P-C Bond Rotation in Phosphoryl- and Thiophosphoryl-Stabilized Carbanions: Five- and Six-Membered Heterocycles (1996) (34)
- Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes. (2004) (34)
- Lewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions. (2013) (34)
- Lewis acid-promoted conjugate addition of dienol silyl ethers to nitroalkenes: synthesis of 3-substituted azepanes. (2007) (33)
- Organocerium Additions to Chiral α,α-Dialkoxy Hydrazones: Asymmetric Synthesis of N-Protected α-Amino Acetals and α-Amino Aldehydes (1993) (33)
- Palladium-Promoted Intramolecular Addition of an Aryl Iodide to a Nitroalkene (1995) (33)
- A qualitative examination of the effects of silicon substituents on the efficiency of cross-coupling reactions. (2006) (33)
- Silicon‐Directed Nazarov Cyclizations. Part VI. The anomalous cyclization of vinyl dienyl ketones (1988) (33)
- Demystifying the asymmetry-amplifying, autocatalytic behavior of the Soai reaction through structural, mechanistic, and computational studies (2020) (32)
- Tandem Inter [4 + 2]/Intra [3 + 2] Nitroalkene Cycloadditions. 5. Origin of the Lewis Acid Dependent Reversal of Stereoselectivity (1993) (32)
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- An ab Initio Study of the P-C Bond Rotation in Phosphorus-Stabilized Carbanions: The Phosphoryl versus Thiophosphoryl Group (1995) (31)
- Carbanion-accelerated Claisen rearrangements. 4. Asymmetric induction via 1,3,2-oxazaphosphorinanes (1987) (31)
- Asymmetric aldol additions catalyzed by chiral phosphoramides: Electronic effects of the aldehyde component ☆ (1998) (31)
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- Construction of quaternary stereogenic carbon centers by the Lewis base catalyzed conjugate addition of silyl ketene imines to α,β- unsaturated aldehydes and ketones (2010) (30)
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- Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-azafenestrane with discovery of an unexpected dyotropic rearrangement. (2005) (29)
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- Carbonylative ring opening of terminal epoxides at atmospheric pressure. (2007) (29)
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- Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3-(Hydroxymethyl)-1H-pyrrolizine-1,2,7-triol: 7-Epiaustraline (1998) (28)
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- Kinetic Analysis of the Divergence of Reaction Pathways in the Chiral Lewis Base Promoted Aldol Additions of Trichlorosilyl Enol Ethers: A Rapid-Injection NMR Study (2000) (27)
- Preparation of 1,4: 5,8-dimethano-1,2,3,4,5,6,7,8-octahydro-9,10-dimethoxyanthracenium hexachloroantimonate (4+•SbCl6 -): A highly robust radical-cation salt: [1,4:5,8-dimethanoanthracene, 1,2,3,4,5,6,7,8-octahydro-9,10-dimethoxy-, radical ion(1+), hexachloroantimonate(1-)] (2005) (26)
- Deconstructing quinine. Part 1. Toward an understanding of the remarkable performance of cinchona alkaloids in asymmetric phase transfer catalysis (2010) (26)
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- Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters. (2019) (26)
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- The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates. (2002) (25)
- Lewis Base Activation of Lewis Acids: Vinylogous Aldol Additions of Silyl Dienol Ethers to Aldehydes (2004) (25)
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- Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids (2016) (23)
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- Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon–Carbon Bond Formation Driven by the Rhodium-Catalyzed Water–Gas Shift Reaction (2017) (23)
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- Mechanistic Significance of the Si–O–Pd Bond in the Palladium-Catalyzed Cross-Coupling Reactions of Alkenylsilanolates (2015) (23)
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- Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. 12. Synthesis of (-)-Platynecine. (1997) (22)
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- Carbanion-Accelerated Claisen Rearrangements. 7. Phosphine Oxide and Phosphonate Anion Stabilizing Groups (1991) (22)
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- A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization. (2019) (22)
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- An AB initio study of the [1,2] proton transfer from phosphine oxide to phosphinic acid (1987) (22)
- ASYMMETRIC 2,3-WITTIG REARRANGEMENTS WITH CHIRAL, PHOSPHORUS ANION-STABILIZING GROUPS (1995) (21)
- Investigations into transition-state geometry in the Mukaiyama directed aldol reaction. (2008) (21)
- Tandem inter [4+2]/intra [3+2] cycloadditions. 3. The stereochemical influence of the Lewis acid (1991) (21)
- Mechanistic insights into the chiral phosphoramide-catalyzed, enantioselective crossed-aldol reactions of aldehydes. (2005) (21)
- Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. Asymmetric Synthesis of Highly Functionalized Aminocyclopentanes Using the Bridged Mode (beta-Tether) Process. (1998) (21)
- A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione (1984) (21)
- Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases Response to the Communication by G. Buono et al. (2001) (20)
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- Preparation of enantiomerically enriched (1S)-1-phenylpropan-1-amine hydrochloride by a catalytic addition of diorganozinc reagents to imines :[Benzenemethanamine, -ethyl-, hydrochloride, (S)-] (2006) (20)
- A stereochemical study on the intramolecular hydrosilylation of α,β-unsaturated esters (1992) (20)
- Carbanion-accelerated Claisen rearrangements 5. Studies on stereocontrol with phosphorus-stabilized anions (1989) (20)
- ASYMMETRIC SYNTHESIS OF THE ABCD RING SYSTEM OF DAPHNILACTONE B VIA A TANDEM, DOUBLE INTRAMOLECULAR, [4+2]/[3+2] CYCLOADDITION STRATEGY. (2009) (20)
- Chemistry of Enoxysilacyclobutanes. 3. Uncatalyzed, Syn-Selective, Asymmetric Aldol Additions (1994) (19)
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- Asymmetric Hydrogenation of Unfunctionalized, Tetrasubstituted, Acyclic Olefins. (2019) (18)
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- (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS. (2008) (15)
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- Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis. (2001) (15)
- Platinum catalyzed hydrosilylation and palladium catalyzed cross-coupling: One-pot hydroarylation of 1-heptyne to (E)-1-(1-heptenyl)-4-methoxybenzene :[Benzene, 1-(1e)-1-heptenyl-4-methoxy-] (2005) (15)
- Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes (2017) (14)
- Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. Application to the Synthesis of Aminocarbasugars (2002) (14)
- THE CHEMISTRY OF CHLOROSILYL ENOLATES 3. : VARIATION OF THE SILYL GROUP AND THE EFFECT ON RATE AND ENANTIOMERIC EXCESS OF ACETATE ALDOL ADDITIONS (1997) (14)
- A theoretical investigation on the mechanism and stereochemical course of the addition of (E)-2-butenyltrimethylsilane to acetaldehyde by electrophilic and nucleophilic activation. (2013) (14)
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- Palladium‐Catalyzed Cross‐Coupling Reactions of Organosilanols and Their Salts: Practical Alternatives to Boron‐ and Tin‐Based Methods (2009) (13)
- Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters. (2005) (13)
- Heteroaryl-Heteroaryl, Suzuki-Miyaura, Anhydrous Cross-Coupling Reactions Enabled by Trimethyl Borate. (2021) (13)
- Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-azafenestrane. (2002) (13)
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- Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones (2003) (12)
- Unexpected ambidoselectivity in crossed-aldol reactions of α-oxy aldehyde trichlorosilyl enolates (2007) (12)
- Heck reactions of aryl chlorides catalyzed by palladium/TRI-tert-butylphosphine: (E)-2-Methyl-3-phenylacrylic acid butyl ester and (E)-4-(2-phenylethenyl)benzonitrile: [2-propenoic acid, 2-methyl-3-phenyl-, butyl ester and benzonitrile, 4-[(1e)-2-phenylethenyl]] (2005) (12)
- Investigations on transition state geometry of the aldol condensation in aqueous medium (1992) (12)
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- Transformation of primary amines to N-monoalkylhydroxylamines: N-hydroxy-(S)-1-phenylethylamine oxalate: [(Benzenemethanamine, N-hydroxy--methyl-, (S)-, ethanedioate)] (2003) (11)
- Reduction of Allylpalladium(II)chloride Dimer by Formation of Allyloxysilanes (2006) (10)
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- Organosilicon Compounds in Cross-Coupling Reactions (2013) (10)
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- The Stereochemical Course of Migration from Phosphorus to Nitrogen in the Photo-Curtius Rearrangement of Phosphinic Azides (Harger Reaction) (1989) (10)
- Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*) (2016) (9)
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- Generation and [2+2] cycloadditions of thio-substituted ketenes: trans-1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)azetidin-2-one [(2-azetidinone, 1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)-, trans-)] (2003) (9)
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- Intramolecular anti-hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted homoallylic alcohols. (2003) (8)
- Synthesis of (+)-(1S,2R)- AND (í)-(1R,2S)-trans-2-phenylcyclohexanol via sharpless asymmetric dihydroxylation (AD): [Cyclohexanol, 2-phenyl-, (1s-trans)- and cyclohexanol, 2-phenyl-, (1r-trans)-] (2002) (8)
- Stereoselective alkylations of chiral nitro imine and nitro hydrazone dianions. Synthesis of enantiomerically enriched 3-substituted 1-nitrocyclohexenes. (2008) (8)
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- Intramolecular [4 + 2]-cycloadditions of vinylnitrosonium cations with olefins (1987) (7)
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- Synthesis of acylsilanes from morpholine amides. Synthesis of 1-(dimethyl(phenyl)silyl)propan-1-one [dimethyl(1-oxopropyl)phenylsilane] (2007) (7)
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- Potassium Trimethylsilanolate-Promoted, Anhydrous Suzuki-Miyaura Cross-Coupling Reaction Proceeds via the "Boronate Mechanism": Evidence for the Alternative Fork in the Trail. (2022) (7)
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- Enantioselective synthesis of alkylidene cyclohexanes by an asymmetric olefination/cross‐coupling sequence (1995) (6)
- Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis? (2019) (6)
- Redefining q: quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc00071h (2015) (6)
- Synthesis of 2-substituted biaryls via Cu/Pd-catalyzed decarboxylative cross-coupling of 2-substituted potassium benzoates: 4-Methyl-2'-nitrobiphenyl and 2-acetyl-4'-methylbiphenyl: [Biphenyl, 4-Methyl-2’-nitro-] [Biphenyl, 4-Methyl-2’-acetyl-] (2008) (6)
- Palladium Catalyzed Cross‐Coupling of (Z)‐1‐Heptenyldimethylsilanol with 4‐Iodoanisole: (Z)‐1‐Heptenyl)‐4‐methoxybenzene (2005) (6)
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- Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions (2017) (5)
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- Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*) (2016) (4)
- Synthesis of α- and β-branched ethers from alcohols by reaction of acetals with grignard reagents: synthesis of isopropyl and isobutyl ethers of (1S*,2R*S*,4R*)-6-methylenebicyclo[2.2.2]octan-2-ol (1991) (4)
- Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho-Geranylphenols in Hexafluoroisopropyl Alcohol (2019) (4)
- Preparation of enantiomerically pure (R,R)-BozPHOS: [(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide] (2006) (4)
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- SYNTHETIC ANALOGS OF THE ACTIVE SITES OF IRON-SULFUR PROTEINS PART 11, SYNTHESIS AND PROPERTIES OF COMPLEXES CONTAINING THE FE2S2 CORE AND THE STRUCTURES OF BIS(O-XYLYL-ALPHA,ALPHA′-DITHIOLATO-MU-SULFIDO-FERRATE(III)) AND BIS(P-TOLYLTHIOLATO-MU-SULFIDO-FERRATE(III)) DIANIONS (1975) (1)
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- SILICON-DIRECTED NAZAROV REACTIONS. III. STEREOCHEMICAL AND MECHANISTIC CONSIDERATIONS (1984) (0)
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- Tandem (4 + 2)/(3 + 2) Cycloadditions of Nitroalkenes. Part 9. Synthesis of (‐)‐Rosmarinecine. (1997) (0)
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- Silyl Ketene Imines: Highly Versatile Nucleophiles for Catalytic, Asymmetric Synthesis (2013) (0)
- Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. Part 20. Asymmetric Synthesis of Highly Functionalized Aminocyclopentanes Using the Bridged Mode (β‐Tether) Process. (2010) (0)
- Preface to volume 92 (2017) (0)
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- Synthesis of RK-397 (2005) (0)
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- Organocerium Additions to Chiral α,α-Dialkoxy Hydrazones: Asymmetric Synthesis of N-Protected α-Amino Acetals and α- Amino Aldehydes. (1994) (0)
- 1,5‐Pentanediamine, N,N′‐Bis[(11bR)‐3,5‐dihydro‐3,5‐dimethyl‐4‐oxido‐4H‐dinaphtho[2,1‐d:1′,2′‐f]‐[1,3,2]diazaphosphepin‐4‐yl]‐N,N′‐dimethyl (2008) (0)
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- Carbanion-Accelerated Claisen Rearrangements. Part 7. Phosphine Oxide and Phosphonate Anion Stabilizing Groups. (1991) (0)
- The Stereochemical Course of Migration from Phosphorus to Nitrogen in the Photo-Curtius Rearrangement of Phosphinic Azides (Harger Reaction). (1989) (0)
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- New synthetic methods. III: Preface (1992) (0)
- Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser (2010) (0)
- Auxiliary-Based, Asymmetric SN2′ Reactions: A Case of 1,7-Relative Stereogenesis. (1990) (0)
- Asymmetric Carboalkoxyalkylidenation with a Chiral Horner‐Wadsworth‐ Emmons Reagent. (1995) (0)
- Comprar Organic Reactions, Volume 73 | Scott E. Denmark | 9780470436905 | Wiley (2009) (0)
- Asymmetric Allylation of Aldehydes with Chiral Lewis Bases. (1995) (0)
- A General Strategy for the Synthesis of cis-Substituted Pyrrolizidine Bases. The Synthesis of (-)-Rosmarinecine (XIII). (1995) (0)
- Organic syntheses. Volume 85, 2008 (2008) (0)
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- Catalytic Epoxidation of Alkenes with Oxone. Part 3. 6-Oxo-1,1,4,4-tetramethyl-1,4-diazepinium Salts. A New Class of Catalysts for Efficient Epoxidation of Olefins with Oxone. (2010) (0)
- Catalytic, Enantioselective, Vinylogous Aldol Reactions (2005) (0)
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- Catalytic Epoxidation of Alkenes with Oxone. Part 2. Fluoro Ketones. (2010) (0)
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- Cover Picture: Silicon Meets Cyclotron: Muon Spin Resonance of Organosilicon Radicals / The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity / Enantioselective Construction of Quaternary Stereogenic Carbon Atoms b (2014) (0)
- Comprar Organic Reactions, Volume 72 | Scott E. Denmark | 9780470423745 | Wiley (2008) (0)
- RuCl3-Catalyzed Allylation of Aldehydes with AllylAcetate (2009) (0)
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- 133 NONINVASIVE ANALYSIS OF EMBRYO METABOLITES USING NUCLEAR MAGNETIC RESONANCE (2015) (0)
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- Comprar Metals in Medicine | Scott E. Denmark | 9780470681978 | Wiley (2009) (0)
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- CARBANION-ACCELERATED CLAISEN REARRANGEMENTS. 3. VICINAL QUATERNARY CENTERS (1984) (0)
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- Preparation of 2-chloro-1,3 bis(dimethylamino) trimethinium hexafluorophosphate [[methanaminium, N-[2-chloro-3-(dimethylamino)-2-propenylidene]-N-methyl-, hexafluorophosphate(1-)]] (2003) (0)
- Comprar Organic Reactions, Volume 74 | Geoffrey Alan Lawrance | 9780470530481 | Wiley (2009) (0)
- Total Syntheses of Isodomoic Acids G (Ia) and H (Ib). (2010) (0)
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- Synthesis of α‐ and β‐Branched Ethers from Alcohols by Reaction of Acetals with Grignard Reagents: Synthesis of Isopropyl and Isobutyl Ethers of (1S*,2R*S*,4R*)‐6‐Methylenebicyclo(2.2.2)octan‐2‐ol. (1992) (0)
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- Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases Response to the Communication by G. Buono et al. We are grateful to the National Science Foundation (CHE-9803124) (2001) (0)
- Comprar Organic Syntheses, Volume 85 | Scott E. Denmark | 9780470432273 | Wiley (2008) (0)
- Diastereoselective Approach to Non-racemic Bipyridine bis-N-Oxides (2006) (0)
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- A General Method for the Preparation of y-Substituted Cyclohexenals and Cycloheptenalst (1985) (0)
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- Organic Syntheses: Preface (2008) (0)
- Bisoxazoline- and (-)-Sparteine-Mediated Enantioselective Addition of Organolithium Reagents to Imines. (2008) (0)
- The Chemistry of Trichlorosilyl Enolates. Part 8. Highly 1,4‐Syn Diastereoselective, Phosphoramide‐Catalyzed Aldol Additions of Chiral Methyl Ketone Enolates. (1999) (0)
- Palladium‐Catalyzed Cross‐Coupling Reactions of Heterocyclic Silanolates with Substituted Aryl Iodides and Bromides. (2006) (0)
- Diastereoselective alkylations of chiral, phosphorus-stabilized carbanions : N-alkyl substituent effects in P-alkyl-1,3,2-diazaphosphorinane 2-oxides : supplementary unpublished material (2000) (0)
- Tandem [4 + 2]/[3 + 2] Cycloadditions with Nitroethylene. (1998) (0)
- Chiral Phosphoramide‐Catalyzed Enantioselective Addition of Allylic Trichlorosilanes to Aldehydes. Preparative and Mechanistic Studies with Monodentate Phosphorus‐Based Amides. (2006) (0)
- Palladium-catalyzed conjugate addition of organosiloxanes to alpha,beta-unsaturated carbonyl compounds and nitroalkenes. (2003) (0)
- Highly Stereospecific, Palladium-Catalyzed Cross-Coupling of Alkenylsilanols. (2000) (0)
- Lewis Acid Promoted Conjugate Addition of Dienol Silyl Ethers to Nitroalkenes: Synthesis of 3-Substituted Azepanes. (2008) (0)
- The total syntheses of (+)-crotanecine, ( - )-hastanecine and ( - )-rosmarinecine utilizing the tandem (4+2)/(3+2) cycloadditions of nitroalkenes (1996) (0)
- Catalytic, Enantioselective Addition of Substituted Allylic Trichlorosilanes Using a Rationally‐Designed 2,2′‐Bispyrrolidine‐Based Bisphosphoramide (2010) (0)
- Preface to volume 88 (2015) (0)
- Preface to volume 97 (2019) (0)
- Enoxysilacyclobutanes. Part 3. Uncatalyzed, Syn‐Selective, Asymmetric Aldol Additions. (1995) (0)
- Tandem Inter (4 + 2)/Intra (3 + 2) Cycloadditions. Part 6. The Bridged Mode. (1995) (0)
- Cross-Coupling of Silanolates with Aromatic Halides (2009) (0)
- Diphenylmethylsilyl Ether (DPMS): A Protecting Group for Alcohols. (1987) (0)
- The Vinylogous Anomeric Effect in 3-Alkyl-2-chlorocyclohexanone Oximes and Oxime Ethers. (1990) (0)
- The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: Solution Structure of Their Lewis Acid Complexes. (1990) (0)
- A Comparison of (Chloromethyl)‐ and (Iodomethyl)zinc Cyclopropanation Reagents. (1992) (0)
- Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities (2016) (0)
- An ab initio Study of the P‐C Bond Rotation in Phosphoryl‐ and Thiophosphoryl‐Stabilized Carbanions: Five‐ and Six‐Membered Heterocycles. (1997) (0)
- rel-(1R,6S,7S,8R,9S)-9-methyl-8-phenyl-6-[(1s,2R)-(2-phenylcyclohexyl) oxy]-4-aza-3,5-dioxatricyclo[5.2.1.0(4,9)]decane. (1996) (0)
- Cobalt-Catalyzed Carbonylative Ring Opening of Epoxides (2008) (0)
- Diastereoselective Aldol Additions of Chiral β-Hydroxy Ethyl Ketone Enolates Catalyzed by Lewis Bases. (2003) (0)
- Preface for volume 100 (2019) (0)
- Syntheses of Isodomoic Acids G and H (2010) (0)
- The synthesis and use of cyclic nitronic esters (1993) (0)
- Silicon-Directed Nazarov Cyclizations. Part 6. The Anomalous Cyclization of Vinyl Dienyl Ketones. (1988) (0)
- 2‐Silyloxy‐1,2‐oxazines, a New Type of Acetals to Conjugated Nitroso Alkenes. (2004) (0)
- ASYMMETRIC CONSTRUCTION OF QUATERNARY STEREOGENIC CENTERS VIA AUXILIARY-BASED SN2' REACTIONS : A CASE OF 1,7-RELATIVE STEREOGENESIS (Dedicated to Professor Victor Snieckus on the occasion of his 77th birthday) (2014) (0)
- A VINYLSILANE ROUTE TO TRANS-7A-METHYLHYDRIND-4-ENE-1,6-DIONE (1984) (0)
- SnCl4(4-tBuC6H4CHO)2. X-Ray Crystal Structure, Solution NMR, and Implications for Reactions at Complexed Carbonyls. (1987) (0)
- Reducing protodeboronation using a novel boronic ester in the late-stage copper-mediated radiofluorination (2022) (0)
- Ethers via Catalytic Asymmetric Thiofunctionalization ofAlkenyl Alcohols (2011) (0)
- A Stereochemical Study on the Intramolecular Hydrosilylation of α,β-Unsaturated Esters. (1993) (0)
- Leveraging Machine Learning for Enantioselective Catalysis: From Dream to Reality. (2021) (0)
- Enantioselective Synthesis of Alkylidene Cyclohexanes by an Asymmetric Olefination/Cross-Coupling Sequence. (1995) (0)
- A General Method for the Preparation of 2,2‐Disubstituted 1‐ Nitroalkenes. (1993) (0)
- 130 METABOLIC PROFILING OF MALE AND FEMALE BOVINE EMBRYOS USING NUCLEAR MAGNETIC RESONANCE (NMR) IMAGING (2015) (0)
- The Tandem Cycloaddition Chemistry of Nitroalkenes. A Novel Synthesis of (-)-Hastanecine. (1995) (0)
- INTRAMOLECULAR (4 + 2) CYCLOADDITIONS OF NITROSOALKENES WITH OLEFINS (1985) (0)
- Silicon-Directed Nazarov Cyclizations. Part 7. Linearly-Fused Tricyclics. (1988) (0)
- Catalytic Enantioselective Cyclopropanation with Bis(halomethyl)zinc Reagents. Part 2. The Effect of Promoter Structure on Selectivity. (1995) (0)
- The Chemistry of Trichlorosilyl Enolates. Part 2. Highly‐Selective Asymmetric Aldol Additions of Ketone Enolates. (1997) (0)
- On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence. (1992) (0)
- Preface to volume 96 (2018) (0)
- Topics in Stereochemistry: Introduction to the series (2006) (0)
- CCDC 603732: Experimental Crystal Structure Determination (2006) (0)
- Alkylations of Chiral, Phosphoryl‐ and Thiophosphoryl‐Stabilized Carbanions. (1996) (0)
- Effect of Ligand Structure in the Bisoxazoline Mediated Asymmetric Addition of Methyllithium to Imines. (2000) (0)
- (R,R)‐1,2‐(Methanesulfonamido)‐cyclohexane (2002) (0)
- Synthesis of Enantioenriched 3,4-Disubstituted Chromans through Lewis Base Catalyzed Carbosulfenylation. (2021) (0)
- Synthesis of 3,4,5‐Trisubstituted Isoxazoles via Sequential [3 + 2] Cycloaddition/Silicon‐Based Cross‐Coupling Reactions. (2005) (0)
- SILICON-DIRECTED NAZAROV REACTIONS. II. PREPARATION AND CYCLIZATION OF β-SILYL-SUBSTITUTED DIVINYL KETONES (1984) (0)
- Tandem Double Intramolecular [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. The Fused/Bridged Mode. (2004) (0)
- Coupling of Aryl Bromides with Tetravinyltetrasiloxane (2006) (0)
- Tandem (4 + 2)/(3 + 2) Cycloadditions of Nitroalkenes. Part 10. trans‐ 2‐(1‐Methyl‐1‐phenylethyl)cyclohexanol as a New Auxiliary. (1997) (0)
- 91 embryo sugar consumption during in vitro development (2016) (0)
- O‐(tert‐Butyldimethylsilyl)hydroxylamine (2001) (0)
- The Tandem Cycloaddition Chemistry of Nitroalkenes. (1995) (0)
- Preface to volume 89 (2016) (0)
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