Steen Steenken
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Steen Steenkenchemistry Degrees
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Physical Chemistry
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Chemistry
Steen Steenken's Degrees
- PhD Chemistry University of California, Berkeley
- Masters Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
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(Suggest an Edit or Addition)Steen Steenken's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- How Easily Oxidizable Is DNA? One-Electron Reduction Potentials of Adenosine and Guanosine Radicals in Aqueous Solution (1997) (1046)
- Purine bases, nucleosides, and nucleotides: aqueous solution redox chemistry and transformation reactions of their radical cations and e- and OH adducts (1989) (956)
- Flavonoids as Antioxidants (1994) (845)
- Reaction pathways and mechanisms of photodegradation of pesticides. (2002) (530)
- H-Atom Transfer Is A Preferred Antioxidant Mechanism of Curcumin (1999) (394)
- One-electron redox potentials of phenols. Hydroxy- and aminophenols and related compounds of biological interest (1982) (334)
- Reduction potentials of flavonoid and model phenoxyl radicals. Which ring in flavonoids is responsible for antioxidant activity (1996) (308)
- Formation of 8-hydroxy(deoxy)guanosine and generation of strand breaks at guanine residues in DNA by singlet oxygen. (1991) (278)
- Structure and acid-base properties of one-electron-oxidized deoxyguanosine, guanosine, and 1-methylguanosine (1989) (275)
- Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report) (2015) (259)
- How curcumin works preferentially with water soluble antioxidants. (2001) (246)
- Antioxidant Potential of Gallocatechins. A Pulse Radiolysis and Laser Photolysis Study (1995) (242)
- Pattern of hydroxyl radical addition to uracil and methyl- and carboxyl-substituted uracils. Electron transfer of hydroxyl adducts with N,N,N',N'-tetramethyl-p-phenylenediamine and tetranitromethane (1981) (229)
- The trap depth (in DNA) of 8-oxo-7,8-dihydro-2'deoxyguanosine as derived from electron-transfer equilibria in aqueous solution (2000) (203)
- Formation of radical cations of methoxylated benzenes by reaction with hydroxyl radicals, thallium(2+), silver(2+), and peroxysulfate (SO4.-) in aqueous solution. Optical and conductometric pulse radiolysis and in situ radiolysis electron spin resonance study (1975) (190)
- Electrophilic reaction of the hydroxyl radical with phenol. Determination of the distribution of isomeric dihydroxycyclohexadienyl radicals (1980) (168)
- Antioxidant properties of flavonoids: reduction potentials and electron transfer reactions of flavonoid radicals (1998) (168)
- Reaction of HO* with guanine derivatives in aqueous solution: formation of two different redox-active OH-adduct radicals and their unimolecular transformation reactions. Properties of G(-H)*. (2000) (165)
- One-electron-reduction potentials of pyrimidine bases, nucleosides, and nucleotides in aqueous solution. Consequences for DNA redox chemistry (1992) (160)
- Ionization of purine nucleosides and nucleotides and their components by 193-nm laser photolysis in aqueous solution : model studies for oxidative damage of DNA (1992) (157)
- Reaction of tert-butoxy radicals with phenols. Comparison with the reactions of carbonyl triplets (1981) (131)
- Electron transfer in DNA? Competition by ultra-fast proton transfer? (1997) (128)
- Pattern of hydroxyl radical addition to cytosine and 1-, 3-, 5-, and 6-substituted cytosines. Electron transfer and dehydration reactions of the hydroxyl adducts (1983) (120)
- Pulse radiolysis and electron spin resonance studies concerning the reaction of SO4.cntdot.- with alcohols and ethers in aqueous solution (1978) (117)
- Electron-transfer-induced acidity/basicity and reactivity changes of purine and pyrimidine bases. Consequences of redox processes for DNA base pairs. (1992) (116)
- Pattern of OH radical reaction with adenine and its nucleosides and nucleotides. Characterization of two types of isomeric OH adduct and their unimolecular transformation reactions (1990) (115)
- Addition–elimination paths in electron-transfer reactions between radicals and molecules. Oxidation of organic molecules by the OH radical (1987) (114)
- Electron transfer in di(deoxy)nucleoside phosphates in aqueous solution: rapid migration of oxidative damage (via adenine) to guanine (1993) (106)
- Flash-photolysis generation and reactivities of triarylmethyl and diarylmethyl cations in aqueous solutions (1989) (103)
- Electron transfer rates and equilibriums between substituted phenoxide ions and phenoxyl radicals (1979) (100)
- Photo-heterolysis and -homolysis of substituted diphenylmethyl halides, acetates, and phenyl ethers in acetonitrile : characterization of diphenylmethyl cations and radicals generated by 248-nm laser flash photolysis (1990) (89)
- Oxidation of Sulfides by Peroxidases. Involvement of Radical Cations and the Rate of the Oxygen Rebound Step (1996) (87)
- Reactivities of triarylmethyl and diarylmethyl cations with azide ion investigated by laser flash photolysis. Diffusion-controlled reactions (1991) (83)
- Phenoxyl radical complexes of gallium, scandium, iron and manganese. (1997) (82)
- Direct evidence for the formation of thymine radical cations from the reaction of sulfate (SO4.cntdot.-) with thymine derivatives: A pulse radiolysis study with optical and conductance detection (1990) (81)
- Nanosecond laser flash photolytic generation and lifetimes in solvolytic media of diarylmethyl and p-methoxyphenethyl cations (1988) (75)
- One-electron reduction of nitrobenzenes by .alpha.-hydroxyalkyl radicals via addition/elimination. An example of an organic inner-sphere electron-transfer reaction (1984) (73)
- Pattern of hydroxyl radical reaction with 6- and 9-substituted purines: effect of substituents on the rates and activation parameters of the unimolecular transformation reactions of two isomeric hydroxyl adducts (1987) (73)
- Solvent effects in the reactions of peroxyl radicals with organic reductants: evidence for proton-transfer-mediated electron transfer (1989) (72)
- Antioxidant Potential of Theaflavins. A Pulse Radiolysis Study (1997) (71)
- Mechanisms of direct and TiO2-photocatalysed UV degradation of phenylurea herbicides. (2005) (70)
- Pattern of OH radical reaction with N6,N6-dimethyladenosine. Production of three isomeric OH adducts and their dehydration and ring-opening reactions (1987) (70)
- Laser Flash Photolysis Generation, Spectra, and Lifetimes of Phenylcarbenium Ions in Trifluoroethanol and Hexafluoroisopropyl Alcohol. On the UV Spectrum of the Benzyl Cation (1991) (67)
- Laser flash photolysis of 9-fluorenol. Production and reactivities of the 9-fluorenol radical cation and the 9-fluorenyl cation (1990) (67)
- Ferrocenyl-functionalised terpyridines and their transition-metal complexes: syntheses, structures and spectroscopic and electrochemical properties. (2003) (63)
- Lifetime, Reduction Potential and Base-Induced Fragmentation of the Veratryl Alcohol Radical Cation in Aqueous Solution. Pulse Radiolysis Studies on a Ligninase ``Mediator'' (1998) (62)
- Spectral properties and absolute rate constants for beta-scission of ring-substituted cumyloxyl radicals. A laser flash photolysis study. (2002) (62)
- Kinetics of the reactions of laser-flash photolytically generated carbenium ions with alkyl and silyl enol ethers. Comparison with the reactivity toward alkenes, allylsilanes and alcohols (1991) (60)
- DFT calculations on the electrophilic reaction with water of the guanine and adenine radical cations. A model for the situation in DNAElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b109204a/ (2002) (57)
- Intramolecular Electron Transfer from Mn or Ligand Phenolate to Photochemically Generated RuIII in Multinuclear Ru/Mn Complexes. Laser Flash Photolysis and EPR Studies on Photosystem II Models (1999) (57)
- Reactivities of diarylmethyl and triarylmethyl cations with primary amines in aqueous acetonitrile solutions. The importance of amine hydration (1992) (56)
- Antioxidant activity of the pyridoindole stobadine. Pulse radiolytic characterization of one-electron-oxidized stobadine and quenching of singlet molecular oxygen. (1992) (56)
- Rate constants for reduction of substituted methylperoxyl radicals by ascorbate ions and N,N,N',N'-tetramethyl-p-phenylenediamine (1989) (55)
- Substituent effects on the spectral, acid-base, and redox properties of indolyl radicals: a pulse radiolysis study (1992) (54)
- Selective para hydroxylation of phenol and aniline by singlet molecular oxygen. (1993) (51)
- Generation and Reactivity of Aromatic Thioether Radical Cations in Aqueous Solution As Studied by Pulse Radiolysis (1997) (51)
- Oxidative demethoxylation of methoxylated phenols and hydroxybenzoic acids by the hydroxyl radical. An in situ electron spin resonance, conductometric pulse radiolysis and product analysis study (1977) (50)
- Oxidation of phenolates and phenylenediamines by 2-alkononyl radicals produced from 1,2-dihydroxy- and 1-hydroxy-2-alkoxyalkyl radicals (1979) (50)
- Carbenes and the oxygen-hydrogen bond: spectroscopic evidence for protonation of diarylcarbenes to give diarylcarbenium ions (1990) (49)
- Iron complexes of gallocatechins. Antioxidant action or iron regulation (1998) (49)
- ESR studies of electron and hydrogen adducts of thymine and uracil and their derivatives and of 4,6-dihydroxypyrimidines in aqueous solution: comparison with data from solid state. The protonation at carbon of the electron adducts (1986) (49)
- Electron adducts of adenine nucleosides and nucleotides in aqueous solution : protonation at two carbon sites (C2 and C8) and intra- and intermolecular catalysis by phosphate (1992) (48)
- Lifetimes of .alpha.-dialkoxy carbocations produced via radical cations generated by electron transfer and photoionization in aqueous solution (1989) (47)
- Electrophilic reactivity of the triphenylmethyl carbocation in aqueous solutions (1986) (47)
- Ionization of polynucleotides and DNA in aqueous solution by 193 nm pulsed laser light: identification of base-derived radicals. (1992) (46)
- Generation of radical-cations from naphthalene and some derivatives, both by photoionization and reaction with SO4–˙: formation and reactions studied by laser flash photolysis (1990) (45)
- Reaction of Hydrated Electrons with Guanine Nucleosides: Fast Protonation on Carbon of the Electron Adduct (1992) (45)
- On the hydrolysis of AgII, TlII, SnIII and CuIII (1978) (43)
- Electrophilic reactions of xanthylium carbocations produced by flash photolysis of 9-xanthenols (1989) (43)
- Kinetics and energetics of one-electron-transfer reactions involving tryptophan neutral and cation radicals (1991) (41)
- Formation of Radical Cations of Methoxylated Benzenes by Reaction with OH Radicals, Tl2+, Ag2+, and S04- in Aqueous Solution. An Optical and Conductometric Pulse Radiolysis and in situ Radiolysis Electron Spin Resonance Study (1976) (41)
- Radiation Chemistry of DNA Model Compounds. Part IV. Phosphate Ester Cleavage in Radicals Derived from Glycerol Phosphates (1974) (41)
- Lifetimes and UV-visible absorption spectra of benzyl, phenethyl, and cumyl carbocations and corresponding vinyl cations. A laser flash photolysis study (1999) (41)
- Pulse radiolysis and election spin resonance studies of the dehydration of radicals from 1,2-diols and related compounds (1986) (40)
- Oxidation of substituted alkyl radicals by hexachloroiridate(2-), hexacyanoferrate(3-), and permanganate ions in aqueous solution. Electron transfer versus chlorine transfer from hexachloroiridate(2-) ion (1982) (40)
- Reaction of 6-yl radicals of uracil, thymine, and cytosine and their nucleosides and nucleotides with nitrobenzenes via addition to give nitroxide radicals. Hydroxide ion-catalyzed nitroxide heterolysis (1985) (39)
- One-electron oxidation of alkylbenzenes in acetonitrile by photochemically produced nitrate radical: evidence for an inner-sphere mechanism (1993) (36)
- Pattern of addition of hydroxyl radicals to the spin traps .alpha.-pyridyl 1-oxide N-tert-butyl nitrone (1980) (36)
- Photophysical and Redox Properties of a Series of Phthalocyanines: Relation with Their Photodynamic Activities on TF‐1 and Daudi Leukemic Cells (1996) (36)
- Redox reactivity of bis(1,4,7-triazacyclononane)iron(II/III) complexes in alkaline solution and characterization of a deprotonated species: amidoiron(III) vs aminyliron(II) ground-state formulation. EPR, kinetic, pulse radiolysis, and laser photolysis study (1988) (36)
- DFT studies on the pairing abilities of the one-electron reduced or oxidized adenine–thymine base pair (2002) (36)
- Photoionization (.lambda. = 248 or 308 nm) of triphenylmethyl radical in aqueous solution. Formation of triphenylmethyl carbocation (1990) (35)
- One-electron oxidation of .alpha.-monoalkoxyalkyl radicals by tetranitromethane via an intermediate adduct. Influence of the radical structure on the rate of decomposition of the adduct (1980) (35)
- Direct observation of β-fluoro-substituted 4-methoxyphenethyl cations by laser flash photolysis (1993) (33)
- Formation of radical zwitterions from methoxylated benzoic acids. 1. One electron oxidation by thallium(2+), silver(2+), and sulfate(1-) ions (1977) (33)
- Site of OH radical attack on dihydrouracil and some of its methyl derivatives. (1984) (33)
- (Photo)ionization of tris(phenolato)iron(III) complexes: generation of phenoxyl radical as ligand (1993) (32)
- Reactivity of .alpha.-heteroatom-substituted alkyl radicals with nitrobenzenes in aqueous solution: an entropy controlled electron transfer/addition mechanism (1988) (32)
- Transient Phenoxyl Radicals: Formation and Properties in Aqueous Solutions (2005) (32)
- Side-Chain Fragmentation of Arylalkanol Radical Cations. Carbon−Carbon and Carbon−Hydrogen Bond Cleavage and the Role of α- and β-OH Groups (1996) (32)
- Solvent-dependent C-OH homolysis and heterolysis in electronically excited 9-fluorenol: the life and solvation time of the 9-fluorenyl cation in water. (2001) (31)
- First stages of photodegradation of the urea herbicides Fenuron, Monuron and Diuron (2001) (31)
- Antioxidant action of stobadine. (1994) (30)
- Adjacent guanines as preferred sites for strand breaks in plasmid DNA irradiated with 193 nm and 248 nm UV laser light. (1996) (30)
- One-electron reduction potentials of 5-indoxyl radicals: a pulse radiolysis and laser photolysis study (1990) (29)
- Radiation-chemical production and lifetimes of trialkoxymethyl carbocations in aqueous solution (1986) (29)
- On the kinetics and energetics of one-electron oxidation of 1,3,5-triazines. (2003) (29)
- DNA-base radicals. Their base pairing abilities as calculated by DFT (2002) (28)
- [3 + 2] Cycloadditions and Protonation by Alcohols of Photochemically Generated Nitrile Ylides from 2H-Azirines. Formation and Reactivities of Azaallenium Cations (1997) (28)
- Structure, acid/base properties and transformation reactions of purine radicals. (1989) (28)
- Reactions of oxidizing radicals with 4,6-dihydroxypyrimidines as model compounds for uracil, thymine, and cytosine (1987) (27)
- Electron spin resonance and pulse radiolysis studies on the reaction of OH sup sm bullet and SO sub 4 sup sm bullet minus with five-membered heterocyclic compounds in aqueous solution (1990) (27)
- The complexation energy of the one-electron oxidized guanine–cytosine base pair and its parent system with small cations. A DFT-study (2003) (27)
- Fragmentation of .alpha.-alkoxyalkyl radicals. Electron paramagnetic resonance study (1975) (27)
- Photoionization of Organic Phosphates by 193 nm Laser Light in Aqueous Solution: Rapid Intramolecular H-Transfer to the Primarily Formed Phosphate Radical. A Model for Ionization-Induced Chain-Breakage in DNA? (1998) (26)
- Direct Evidence for the Formation of Thymine Radical Cations from the Reaction of SO‐ 4 with Thymine Derivatives: A Pulse Radiolysis Study with Optical and Conductance Detection (1991) (26)
- Multiple Bonds between Main Group Elements and Transition Metals. 144.1 Photoreactivity of Organorhenium(VII) Oxides (1995) (26)
- Reversible nitrogen-nitrogen bond homolysis in tetrakis(trifluoromethylthio)hydrazine at room temperature. Electron spin resonance, thermodynamic, and kinetic results (1983) (25)
- Formation of radical cations and zwitterions versus demethoxylation in the reaction of OH with a series of methoxylated benzenes and benzoic acids. An example of the electrophilic nature of the OH radical (1977) (24)
- Reactivities of 9-arylfluoren-9-yl and 1-(4-dimethylaminophenyl)ethyl cations in water and trifluoroethanol studied by laser flash photolysis (1992) (24)
- Making Photochemically Generated Phenyl Cations Visible by Addition to Aromatics: Production of Phenylcyclohexadienyl Cations and Their Reactions with Bases/Nucleophiles (1998) (24)
- Is "frank" DNA-strand breakage via the guanine radical thermodynamically and sterically possible? (2001) (23)
- Oxygen Acidity of 1-Arylalkanol Radical Cations. 4-Methoxycumyloxyl Radical as −C(Me)2−O--to-Nucleus Electron-Transfer Intermediate in the Reaction of 4-Methoxycumyl Alcohol Radical Cation with OH- (1998) (23)
- Oxidation of methoxyhydroxycyclohexadienyl radicals by quinones. The influence of the isomeric structure of the radical on the rate constant for electron transfer (1979) (23)
- One‐Electron‐Reduction Potentials of Pyrimidine Bases, Nucleosides, and Nucleotides in Aqueous Solution. Consequences for DNA Redox Chemistry. (1992) (23)
- Base-Catalyzed C−H Deprotonation of 4-Methoxybenzyl Alcohol Radical Cations in Water: Evidence for a Carbon-to-Oxygen 1,2-H-Shift Mechanism (1997) (23)
- Hydrogen bonding between histidine and lignin model compounds or redox mediators as calculated with the DFT method. Effects on the ease of oxidation. (2004) (22)
- Selectivity of addition of the hydroxyl radical to ring positions of pyridine and pyridine mono- and dicarboxylic acids. An electron spin resonance investigation (1978) (22)
- 248-nm Laser flash photoprotonation of mesitylene, hexamethylbenzene, and 1,3,5-trimethoxybenzene in 1,1,1,3,3,3-hexafluoroisopropyl alcohol. Formation and electrophilic reactivities of the cyclohexadienyl cations (1990) (21)
- Photoionization of diarylmethyl radicals in acetonitrile and alcohol-water : laser flash production of diarylcarbenium ions (1993) (21)
- Carbon-carbon bond homolysis in hexakis(trifluoromethylmercapto)ethane at room temperature. Thermodynamic, kinetic, and electron spin resonance results (1979) (20)
- Photo- and radiation-induced chemical generation and reactions of styrene radical cations in polar and non-polar solvents (1995) (20)
- Oxygen Versus Carbon Acidity in the Side-Chain Fragmentation of 2-, 3-, and 4-Arylalkanol Radical Cations in Aqueous Solution: The Influence of the Distance between the OH Group and the Aromatic Ring1 (1999) (19)
- Kinetic and Product Studies on the Side‐Chain Fragmentation of 1‐Arylalkanol Radical Cations in Aqueous Solution: Oxygen versus Carbon Acidity (1999) (19)
- One-electron reduction of nitrobenzenes by hydroxyl and hydrogen radical adducts to 6-methyluracil and 6-methylisocytosine via electron transfer and addition/elimination: effect of substituents on rates and activation parameters for formation and heterolysis of nitroxyl-type tetrahedral intermediate (1988) (19)
- Radiation chemical production, lifetimes, and structure-activity relations for .alpha.-dialkoxyalkyl carbocations in aqueous solutions: Importance of solvation for cation reactivity (1988) (18)
- Hydroxyl radical induced damage to the purine bases of DNA : in vitro studies (1993) (18)
- Photo‐ and Radiation‐Chemical Generation and Thermodynamic Properties of the Aminium and Aminyl Radicals Derived from N‐Phenylglycine and (N‐Chloro,N‐phenyl)glycine in Aqueous Solution: Evidence for a New Photoionization Mechanism for Aromatic Amines (1999) (18)
- A kinetic method for the measurement of the pKR value of the triphenylmethyl cation in the aqueous standard state (1990) (18)
- Pulse Radiolysis and Electron Spin Resonance Studies on the Formation of Phenoxyl Radicals by Reaction of OH Radicals with Methoxylated Phenols and Hydroxybenzoic Acids (1977) (17)
- Observation of Cationic Intermediates in the Photolysis of 1-Phenylcyclohexene (1993) (17)
- Multiple-Photon Chemistry of 9-(Phenoxymethyl)- and 9,10-Bis(phenoxymethyl)anthracenes in the Laser-Jet: Generation, Photochemistry, and Time-Resolved Laser-Flash Spectroscopy of Anthracenylmethyl Radicals and Pulse Radiolysis of 9-(Bromomethyl)anthracene (1997) (17)
- PATTERN OF HYDROXYL RADICAL ADDITION TO URACIL AND METHYL- AND CARBOXYL-SUBSTITUTED URACILS. ELECTRON TRANSFER OF HYDROXYL ADDUCTS WITH N,N,N′,N′-TETRAMETHYL-P-PHENYLENEDIAMINE AND TETRANITROMETHANE (1981) (17)
- RADICAL-CATION [3+2] CYCLOADDITIONS OF 2H-AZIRINES - MECHANISTIC STUDIES CONCERNING THE INTERMEDIATE RADICAL-CATION (1993) (16)
- PHOTOFRAGMENTATION OF HYDROXYACETONE, 1.3‐DIHYDROXYACETONE, AND 1.3‐DICARBOXYACETONE IN AQUEOUS SOLUTION. AN EPR STUDY (1975) (16)
- DFT calculations on the deprotonation site of the one-electron oxidised guanine-cytosine base pair. (2010) (16)
- One-electron reduction of 2-aminopurine in the aqueous phase. A DFT and pulse radiolysis study. (2005) (16)
- Laser flash photolysis observation of the 1-p-methoxyphenylvlnyl cation by photoprotonation of p-methoxyphenylacetylene. Comparison with the 1-p-methoxyphenethyl cation. (1990) (16)
- Photodissociation of N-(Triphenylmethyl)anilines: A Laser Flash Photolysis, ESR, and Product Analysis Study1 (1998) (15)
- Oxidation vs. fragmentation in radiosensitization. Reactions of α-alkoxyalkyl radicals with 4-nitrobenzonitrile and oxygen. A pulse radiolysis and product analysis study (1995) (15)
- Laser Flash Photolysis Study of Arylcyclopropylcarbenium Ions: Cation Stabilizing Abilities of Cyclopropyl and Phenyl Groups (1996) (15)
- Photochemistry of 2,3-dimethyl-2,3-diphenylbutane: carbon-carbon homolysis and protonation-induced side-chain fragmentation (1992) (15)
- One-electron redox reactions between radicals and organic molecules. An addition/elimination (inner-sphere) path [1] (1996) (15)
- IONIZATION OF 1,3-DIOXOLES IN AQUEOUS-SOLUTION BY 248-NM LASER FLASH-PHOTOLYSIS - CHARACTERIZATION OF THE RADICAL CATIONS (1989) (15)
- Substituent Effects on the Spectral, Acid-Base, and Redox Properties of Indolyl Radicals: A Pulse Radiolysis Study. (1992) (15)
- Fragmentation of radicals derived from glycolaldehyde and glyceraldehyde in aqueous solution. An EPR study. (1973) (15)
- Pattern of OH Radical Reaction with 6- and 9-Substituted Purines (I)-(III). Effect of Substituents on the Rates and Activation Parameters of the Unimolecular Transformation Reactions of Two Isomeric OH Adducts (1987) (15)
- Regioselective photoprotonation of 1,3-dimethoxybenzenes in 1,1,1,3,3,3-hexafluoroisopropyl alcohol. H-D isotope-exchange and laser flash photolysis studies (1992) (15)
- Pronounced solvent effect on the absorption spectra of the photochemically produced 2,4-dinitrobenzyl carbanion (1987) (14)
- Photoionization of β-carotene via electron transfer from excited states to chlorinated hydrocarbon solvents. A picosecond transient absorption study (2002) (14)
- Photo- and radiation-chemical production of radical cations of methylbenzenes and benzyl alcohols and their reactivity in aqueous solution (2002) (14)
- Formation of radical zwitterions from methoxylated benzoic acids. 2. Hydroxyl adducts as precursors (1977) (14)
- Reaction of .alpha.-hydroxyalkyl radicals and their anions with oxidized dithiothreitol: a pulse radiolysis and product analysis study (1989) (14)
- Solvent Induced Intramolecular Electron Exchange Kinetics in 1,3‐Isodisubstituted Aromatic Radical Anions II. Activation Parameters (1990) (14)
- Production of α-Siloxycarbenium Ions by Protonation of Photochemically Generated α-Siloxycarbenes. Formation Mechanism and Reactivities with Nucleophiles (1996) (14)
- ONE-ELECTRON REDUCTION OF NITROBENZENES BY α-HYDROXYALKYL RADICALS VIA ADDITION/ELIMINATION. AN EXAMPLE OF AN ORGANIC INNER-SPHERE ELECTRON-TRANSFER REACTION (1985) (13)
- Photo- and radiation-chemical formation and electrophilic and electron transfer reactivities of enolether radical cations in aqueous solution. (2001) (13)
- Photochemical Formation and Electrophilic Reactivities of Vinyl Cations. Influence of Substituents, Anionic Leaving Groups, Solvents, and Excitation Wavelength on Photoheterolysis and Photohomolysis of 1-(p-R-Phenyl)-2-(2,2'-biphenyldiyl)vinyl Halides (1994) (13)
- The calculated base pairing energy of 8-oxoguanine in the syn-anti conformation with cytosine, thymine, adenine and guanine (2005) (12)
- Photoreaction of Biacetyl and 1,3‐Dioxole Derivatives: Modification of the Mechanism of the Photoreaction of Carbonyl Compounds with Electron‐Rich Olefins (1984) (12)
- Formation of cyclic sulphuranyl radicals of the type [RSSR2] from 1,3-bis(alkylthio)propanes by laser flash photolysis of 1,n-bis(alkylthio)alkanes (1988) (12)
- Reaction of OH radicals with nitrophenols in aqueous solution (1978) (12)
- Pattern of hydroxyl radical reaction with N6,N6,9-trimethyladenine: dehydroxylation and ring opening of isomeric hydroxyl adducts (1991) (12)
- CYCLOHEXADIENYL-TYPE CATIONIC INTERMEDIATES IN THE FRIEDEL-CRAFTS ALKYLATION OF BENZENE DERIVATIVES WITH THE 9-FLUORENYL CATION : OBSERVATION BY LASER FLASH PHOTOLYSIS (1992) (12)
- Flash photolysis study of a Friedel–Crafts alkylation. Reaction of the photogenerated 9-fluorenyl cation with aromatic compounds (1996) (11)
- Common Origin of Enthalpic and Entropic Substituent Effects in Reactions of Benzhydryl Cations with Nucleophiles (1995) (11)
- Photodissociation of N-Arylmethylanilines: A Laser Flash Photolysis, Fluorescence, and Product Analysis Study(1). (1999) (11)
- Reaction of hydroxyl radicals with 2- and 4-pyridones in aqueous solution. An electron spin resonance and pulse radiolysis study (1979) (11)
- Radical cations of phenyl-substituted aziridines: what are the conditions for ring opening? (2005) (10)
- Kinetic and Stereochemistry of the SO 4⊙⊖‐Induced Hydroxylation of Cyclohexenes in Aqueous Solution (1988) (9)
- Laser flash photolysis of aziridines. Spectroscopic and kinetic characterization of azomethine ylides. Their [3 + 2] cyclization with alkenes and protonation by water–alcohols to yield iminium ions1 (1998) (9)
- Photoionization versus photoheterolysis of all-trans-retinol. The effects of solvent and laser radiation intensity. (2007) (9)
- PHOTOFRAGMENTATION OF α‐OXOCARBOXYLIC ACIDS IN AQUEOUS SOLUTION. AN EPR STUDY. FORMATION OF SEMIDIONE RADICALS BY DECARBOXYLATIVE SUBSTITUTION OF α‐OXOCARBOXYLIC ACIDS BY ACYL RADICALS‐I: GLYOXYLIC, PYRUVIC, α‐OXOBUTYRIC, α‐OXOGLUTARIC AND α‐OXOISOCAPROlC ACIDS (1975) (9)
- EPR INVESTIGATIONS CONCERNING THE STRUCTURE OF THE ASCORBIC ACID RADICAL IN WATER, ALCOHOL, AND DIMETHYLSULFOXIDE (1973) (9)
- One-Electron Redox Reactions Between Radicals and Molecules. Dominance of Inner-Sphere Mechanisms (1989) (9)
- −OH-Induced shift from carbon to oxygen acidity in the side-chain deprotonation of 2-, 3- and 4-methoxybenzyl alcohol radical cations in aqueous solution: results from pulse radiolysis and DFT calculations (2003) (8)
- Structural effects on the OH-promoted fragmentation of methoxy-substituted 1-arylalkanol radical cations in aqueous solution: the role of oxygen acidity. (2001) (8)
- Structure and Acid-Base Properties of One-Electron-Oxidized Deoxyguanosine, Guanosine, and 1-Methylguanosine. (1989) (7)
- Flash photolysis production of the tetrahedral intermediate of the methanolysis of methyl benzoate. Direct measurement of the rate of breakdown of the conjugate base form (1990) (7)
- Radical oxidation of xanthines : a reaction pathway to uric acid ? (1996) (7)
- Fumarate and maleate as spin traps for acyl radicals. Decarboxylation of the adduct radicals to yield 1-carboxy-3-oxyallyl radical dianions (1977) (7)
- Photohomolysis and Photoionization of Substituted Tetraphenylethanes and C–C Fragmentation of 1,1,2,2‐Tetra(p‐R‐phenyl)ethane Radical Cations (R=H, CH3, OCH3, Cl) (1998) (7)
- Production of carbenium ions from carbenes by protonation (1998) (7)
- Reactivity of [CoIIIW12O40]5– with organic radicals in aqueous solution. Evidence for an electron transfer mechanism (1996) (6)
- Styrene triplets: Absorption spectra, lifetimes and quantum yields (1996) (6)
- Generation of High‐Oxidation States of Myoglobin in the Nanosecond Time‐Scale by Laser Photoionization (1998) (6)
- Transformation Reactions of Two Isomeric OH-Adducts of 2’-Deoxyguanosine (1991) (5)
- Photoionization of α-alkoxybenzyl radicals to yieldα-alkoxybenzyl cations. Photochemistry ofω,ω-dimethoxy-ω-phenylacetophenone in polar solvents at high light intensities1 (1997) (5)
- Detection of Phenyl-Substituted Radical Cations Derived from Cyclopentyl- and Urazole-Type Azoalkanes by Pulse Radiolysis: Influence of Heteroatom Substitution on the Radical Cation Reactivities (1997) (5)
- Intramolecular electron exchange with solvent participation: electron spin resonance study of the radical-anion of benzene-1,3-dicarbaldehyde in propan-2-ol–water mixtures (1986) (5)
- Photochemistry of Phenylallenes in Protic Media. Formation of Allyl Cations by Way of Vinylcarbenes (1995) (5)
- Flash photolysis observation and lifetimes of the cation intermediates in the intramolecular photoprotonation of tryptamine, tryptophan and their N-methyl derivatives (1992) (5)
- One-Electron Reduction Potentials of 5-Indoxyl Radicals. A Pulse Radiolysis and Laser Photolysis Study. (1990) (5)
- An In situ photolysis-e.s.r. investigation of 5-bromo- and 5-nitro-2-furoic acid (1985) (5)
- Chemical Reactivity of DNA Radicals - A Reflection of their Redox Properties (1991) (5)
- CHEMILUMINESCENCE ON OXIDATION OF ACRIDAN BY DIBENZOYLPEROXIDE (1970) (4)
- ONE-ELECTRON OXIDATION OF α-MONOALKOXYALKYL RADICALS BY TETRANITROMETHANE VIA AN INTERMEDIATE ADDUCT. INFLUENCE OF THE RADICAL STRUCTURE ON THE RATE OF DECOMPOSITION OF THE ADDUCT (1980) (4)
- Water-Assisted Intramolecular Electron Transfer from the Ring to the Side Chain in N,N,N',N'-Tetraalkyl-para-phenylenediamine Radicals-The Reverse of Side Chain Deprotonation of Radical Cations. (2001) (4)
- Two Routes in the Formation of Hydrogen Halides from OH Adducts of Halogenated Anisoles in Aqueous Solution (1978) (4)
- Photochemistry of 3H-indazoles in protic media. Benzyl cations via protonation of 2-methylene-3,5-cyclohexadienylidenes (1995) (4)
- BIPHOTONIC GENERATION OF CARBENES AND CARBOCATIONS BY LASER FLASH PHOTOLYSIS (1996) (4)
- One-Electron Redox Reactions Between Radicals and Organic Molecules. An Addition/Elimination (Inner-Sphere) Path (1996) (4)
- ESR Studies of Electron and Hydrogen Adducts of Thymine and Uracil and Their Derivatives and of 4,6-Dihydroxypyrimidines in Aqueous Solution. (1986) (4)
- Reaction of 6-yl Radicals of Uracil, Thymine, and Cytosine and Their Nucleosides and Nucleotides with Nitrobenzenes via Addition To Give Nitroxide Radicals. (1986) (3)
- Pulse-radiolytic studies on the reactions of SO - · 4 with uracil dervivatives (1990) (3)
- Photochemical generation of the N-isopropylbenzonitrilium ion and unusually slow trapping by azide ion (1999) (3)
- Formation of Radical Cations from 1,2‐ and 1,4‐Dimethoxybenzene by Electron Transfer to TI2+ and Ag2+ in Aqueous Solution (1975) (3)
- Multiple-Photon Chemistry in the Laser-Jet: Photochemistry and Time-Resolved Laser-Flash Spectroscopy of the 1-Naphthylmethyl Radical (1997) (3)
- Generation of Radical Cations from Naphthalene and Some Derivatives (I), Both by Photoionization and Reaction with SO-· 4: Formation and Reactions Studied by Laser Flash Photolysis (1990) (3)
- Photo‐Heterolysis and ‐Homolysis of Substituted Diphenylmethyl Halides, Acetates, and Phenyl Ethers in Acetonitrile: Characterization of Diphenylmethyl Cations and Radicals Generated by 248‐nm Laser Flash Photolysis (1991) (3)
- Comparison of reactions of radical cations of 1-phenylalkanols produced by photoionization and by one-electron oxidation in aqueous solution (2001) (3)
- ESR and Pulse Radiolysis Studies on the Reaction of OH· and SO·- 4 with Five-Membered Heterocyclic Compounds in Aqueous Solution. (1990) (3)
- Flash Photolysis Generation and Reactivities of Triarylmethyl and Diarylmethyl Cations in Aqueous Solutions. (1989) (3)
- Radicals in Aqueous Solution from Fe(III) Complexes with Macrocyclic Ligands Containing Phenolates (1997) (2)
- Pattern of OH Radical Reaction with N6,N6,9-Trimethyladenine. Dehydroxylation and Ring Opening of Isomeric OH Adducts. (1992) (2)
- Formation of radical cations of aziridines generated by laser flash photolysis. (2004) (2)
- Radiation Chemistry of Phenols (2005) (2)
- Structure of radicals derived from hydroxypyrimidines in aqueous solution (2002) (1)
- Kinetic Method for the Measurement of the pKR Value of the Triphenylmethyl Cation in the Aqueous Standard State. (1991) (1)
- Generation of a Heterocyclic 1,3‐Cyclopentanediyl Radical Cation by Chemically Induced Electron Transfer Oxidation and Pulse Radiolysis (1996) (1)
- Photoionization of Diarylmethyl Radicals in Acetonitrile and Alcohol- Water: Laser Flash Production of Diarylcarbenium Ions (1993) (1)
- Rate Constants for Reduction of Substituted Methylperoxyl Radicals by Ascorbate Ions and N,N,N′,N′-Tetramethyl-p-phenylenediamine. (1989) (1)
- A quantum chemical investigation of the anisole radical cation with inclusion of aqueous solvation effects (1991) (1)
- Electron Transfer in Radicals (2008) (1)
- Reactivity of α-Heteroatom-Substituted Alkyl Radicals with Nitrobenzenes in Aqueous Solution: An Entropy-Controlled Electron-Transfer/Addition Mechanism. (1988) (1)
- PHOTOIONIZATION OF ALPHA -ALKOXYBENZYL RADICALS TO YIELD ALPHA -ALKOXYBENZYL CATIONS. PHOTOCHEMISTRY OF OMEGA ,OMEGA -DINETHOXY-OMEGA -PHENYLACETOPHEN ONE IN POLAR SOLVENTS AT HIGH LIGHT INTENSITIES (1997) (1)
- PHOTOFRAGMENTATION OF α‐OXOCARBOXYLIC ACIDS IN AQUEOUS SOLUTION. AN EPR STUDY. FORMATION OF SEMIDIONE RADICALS BY DECARBOXYLATIVE SUBSTITUTION OF α‐OXOCARBOXYLIC ACIDS BY ACYL RADICALS–II. OXALOACETIC ACID (OXOSUCCINIC ACID) * (1975) (1)
- Reactivities of Diarylmethyl and Triarylmethyl Cations with Primary Amines in Aqueous Acetonitrile Solutions. The Importance of Amine Hydration. (1992) (1)
- LASER FLASH PHOTOLYSIS OF SOME PHENYLAZIRIDINES (1998) (1)
- 248‐nm Laser Flash Photoprotonation of Mesitylene, Hexamethylbenzene, and 1,3,5‐Trimethoxybenzene in 1,1,1,3,3,3‐Hexafluoroisopropyl Alcohol. Formation and Electrophilic Reactivities of the Cyclohexadienyl Cations. (1991) (1)
- Mechanisms of the Oxidation of Alkylaromatics and Aromatic Sulfides by Cytochrome P-450 and Peroxidases (1997) (1)
- Pulse Radiolysis and ESR Studies of the Dehydration of Radicals from 1,2-Diols and Related Compounds. (1986) (1)
- Formation of semidione radicals on production of 1,2-dihydroxyalkl radicals in the presence of peroxides in basic solution. An electron spin resonance study (1976) (1)
- Kinetic isotope effect in the chemiluminescent oxidation of acridan by dibenzoylperoxide (1970) (1)
- Reactivities of Triarylmethyl and Diarylmethyl Cations with Azide Ion Investigated by Laser Flash Photolysis. Diffusion‐Controlled Reactions (1991) (1)
- Kinetics of the Reactions of Laser‐Flash Photolytically Generated Carbenium Ions with Alkyl and Silyl Enol Ethers. Comparison with the Reactivity Toward Alkenes, Allylsilanes and Alcohols (1992) (1)
- PHOTOREACTION OF BIACETYL WITH 1,3-DIOXOLE DERIVATIVES: MODIFICATION OF THE MECHANISM OF PHOTOREACTION OF CARBONYL COMPOUNDS WITH ELECTRON-RICH OLEFINS (1984) (0)
- OXIDATION OF METHOXYHYDROXYCYCLOHEXADIENYL RADICALS BY QUINONES. THE INFLUENCE OF THE ISOMERIC STRUCTURE OF THE RADICAL ON THE RATE CONSTANT FOR ELECTRO TRANSFER (1980) (0)
- Kinetics and Stereochemistry of the SO·‐ 4‐Induced Hydroxylation of Cyclohexenes in Aqueous Solution (1988) (0)
- Photochemistry of 2,3‐Dimethyl‐2,3‐diphenylbutane: C‐C Homolysis and Protonation‐Induced Side‐Chain Fragmentation. (1993) (0)
- Pulse Radiolysis and Laser Photolysis Studies on Nucleotide Radicals. The Protonation State of the Radicals (1996) (0)
- Cyclohexadienyl-Type Cationic Intermediates in the Friedel-Crafts Alkylation of Benzene Derivatives with the 9-Fluorenyl Cation - Observation by Laser Flash Photolysis. (1992) (0)
- Formation of cis‐ and trans‐Semidione Radical Anions by Addition of Acyl Radicals to α‐Oxo Carboxylic Acids (1975) (0)
- ON THE HYDROLYSIS OF SILVER(II), THALLIUM(II), TIN(III), AND COPPER(III) (1978) (0)
- Direct Observation of β‐Fluoro‐Substituted 4‐Methoxyphenethyl Cations by Laser Flash Photolysis. (2010) (0)
- Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications (1996) (0)
- Radiation Chemical Production and Lifetimes of Trialkoxymethyl Carbocations in Aqueous Solution. (1986) (0)
- Editors' Note (2003) (0)
- Reactions of Oxidizing Radicals with 4,6‐Dihydroxypyrimidines as Model Compounds for Uracil, Thymine, and Cytosine. (1987) (0)
- Radical Chemistry in Crystals, Matrices and in Aqueous Solution. Redox Properties and Proton Transfer Processes. (1991) (0)
- Letter: Radiation chemistry of DNA model compounds. IV. Phosphate ester cleavage in radicals derived from glycerol phosphates. (1974) (0)
- [3 + 2] Cycloadditions and Protonation by Alcohols of Photochemically Generated Nitrile Ylides from 2H-Azirines. Formation and Reactivities of Azaallenium Cations. (1998) (0)
- Crown Thioether Complexes of Cobalt(III): Ligand Structure and Redox Reactivity. Crystal Structure, Electrochemistry, and Kinetics of the Electron Transfer Exchange Reactions of (Co(tacn)(ttcn))Br3·3 H2O (tacn = 1,4,7-Triazacyclononan (1989) (0)
- The (CF3S)2N. radical : preparation, dimerization, ESR-studies (1980) (0)
- Carbenes and the O-H Bond: Spectroscopic Evidence for Protonation of Diarylcarbenes to Give Diarylcarbenium Ions. (1990) (0)
- UV Spectrum of the Benzyl Cation: Generation, UV Spectra and Reactivities of Phenyl Carbenium Ions in Trifluoroethanol and Hexafluoro‐2‐propanol. (1991) (0)
- Laser flash photolysis of 2H-azirines nitrile ylides and azaallenium cations (1994) (0)
- Electrophilic Reactions of Xanthylium Carbocations Produced by Flash Photolysis of 9-Xanthenols. (1989) (0)
- P32 08 tP – REACTION OF OH RADICAL WITH ADENINE, ITS NUCLEOSIDES, NUCLEOTIDES AND SOME ALKYLATED DERIVATIVES (1991) (0)
- Photodissociation of N-(Triphenylmethyl)anilines: A Laser Flash Photolysis, ESR, and Product Analysis Study. (1998) (0)
- Photoionization of Ferrocytochrome c by 248 nm Laser Light and the Observation of the Early Stages of Ferricytochrome c Unfolding in the Nanosecond‐to‐millisecond Timescale (1999) (0)
- Regioselective Photoprotonation of 1,3-Dimethoxybenzenes in 1,1,1,3,3, 3-Hexafluoroisopropyl Alcohol. H-D Isotope-Exchange and Laser Flash Photolysis Studies. (1992) (0)
- Photofragmentation of alpha-oxocarboxylic acids in aqueous solution. An EPR study. Formation of semidione radicals by decarboxylative substitution of alpha-oxocarboxylic acids by acyl radicals. I. Glyoxylic, pyruvic, alpha-oxobutyric, alpha-oxoglutaric and alpha-oxoisocaproic acids. (1975) (0)
- Redox Reactivity of Bis(1,4,7-triazacyclononane)iron(II/III) Complexes in Alkaline Solution and Characterization of a Deprotonated Species: Amidoiron(III) vs Aminyliron(II) Ground-State Formulation. EPR, Kinetics, Pulse Radiolysis, an (1988) (0)
- The Role of Solvent Dynamics in Inter- and Intramolecular Electron Exchange Reactions (1988) (0)
- Lifetimes of α-Dialkoxy Carbocations Produced via Radical Cations Generated by Electron Transfer and Photoionization in Aqueous Solution. (1989) (0)
- Intramolecular Electron Exchange with Solvent Participation: ESR Study of the Radical-Anion of Benzene-1,3-dicarbaldehyde in Propan-2-ol-Water Mixtures. (1987) (0)
- Oxidation of Alkylaromatics and Aromatic Sulfides by Cytochrome P-450 and Peroxidases (Mechanisms) (1997) (0)
- Radiation Chemical Production, Lifetimes, and Structure-Activity Relations for α-Dialkoxyalkyl Carbocations in Aqueous Solutions: Importance of Solvation for Cation Reactivity. (1988) (0)
- Reactivities of 9‐Arylfluoren‐9‐yl and 1‐(4‐Dimethylaminophenyl)ethyl Cations in Water and Trifluoroethanol Studied by Laser Flash Photolysis (1993) (0)
- Laser Flash Photolysis of 9-Fluorenol. Production and Reactivities of the 9-Fluorenol Radical Cation and the 9-Fluorenyl Cation. (1990) (0)
- Heterolysis of o-(ɑ-Hydroxyalkyl)-4-cyanophenyl Nitrite: Simultaneous Polar & Steric Effects (1988) (0)
- Radial cations of styrenes: photo and radiation chemical formation and characterization of the reactivity (1994) (0)
- Laser Flash Photolysis of Aziridines. Spectroscopic and Kinetic Characterization of Azomethine Ylides. Their [3 + 2] Cyclization with Alkenes and Protonation by Water—Alcohols to Yield Iminium Ions. (1999) (0)
- Observation of Cationic Intermediates in the Photolysis of 1- Phenylcyclohexene (1993) (0)
- Photoionization (λ = 248 or 308 nm) of Triphenylmethyl Radical in Aqueous Solution. Formation of Triphenylmethyl Carbocation (1990) (0)
- Ionization of 1,3-Dioxoles (I) and (II) in Aqueous Solution by 248 nm Laser Flash Photolysis. Characterization of the Radical Cations (1990) (0)
- One Electron Oxidation of α‐Hydroxyalkyl Radicals by Substituted Nitrobenzenes via an Intermediate Adduct. Effect of Substitution on the Rates of Decomposition of the Adducts (2010) (0)
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