Stephen L. Buchwald
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American chemist
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Stephen L. Buchwaldchemistry Degrees
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#178
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#34
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Organic Chemistry
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#11
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Why Is Stephen L. Buchwald Influential?
(Suggest an Edit or Addition)According to Wikipedia, Stephen L. Buchwald is a U.S. chemist and Camille Dreyfus Professor of Chemistry at MIT. He is known for his involvement in the development of the Buchwald-Hartwig amination and the discovery of the dialkylbiaryl phosphine ligand family for promoting this reaction and related transformations. He was elected as a fellow of the American Academy of Arts and Sciences and as a member of the National Academy of Sciences in 2000 and 2008, respectively.
Stephen L. Buchwald's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands. (2008) (1634)
- Biaryl phosphane ligands in palladium-catalyzed amination. (2008) (1561)
- Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions (2016) (1390)
- Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure. (2005) (1304)
- Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation (1998) (1244)
- Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide. (2010) (1024)
- Practical Palladium Catalysts for C-N and C-O Bond Formation (2002) (801)
- Highly Active Palladium Catalysts for Suzuki Coupling Reactions (1999) (796)
- A general and efficient copper catalyst for the amidation of aryl halides and the N-arylation of nitrogen heterocycles. (2001) (733)
- A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines (1995) (708)
- A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides (1998) (664)
- A rationally designed universal catalyst for Suzuki-Miyaura coupling processes. (2004) (662)
- A general and efficient copper catalyst for the amidation of aryl halides. (2002) (652)
- Palladium-catalyzed amination of aryl halides and sulfonates (1999) (594)
- The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides (2010) (581)
- Expanding Pd-catalyzed C-N bond-forming processes: the first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions. (2003) (572)
- Combined C-H functionalization/C-N bond formation route to carbazoles. (2005) (532)
- Simple, efficient catalyst system for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates. (2000) (513)
- Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides (2009) (486)
- Diamine Ligands in Copper-Catalyzed Reactions. (2010) (480)
- Palladium-Catalyzed Aromatic Aminations with in situ Generated Aminostannanes (1994) (479)
- C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines. (2008) (468)
- A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids. (2010) (467)
- Copper-diamine-catalyzed N-arylation of pyrroles, pyrazoles, indazoles, imidazoles, and triazoles. (2004) (444)
- An Improved Catalyst System for Aromatic Carbon−Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates (1996) (444)
- Highly efficient monophosphine-based catalyst for the palladium-catalyzed suzuki-miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters. (2007) (443)
- Palladium-Catalyzed α-Arylation of Ketones (1997) (438)
- The copper-catalyzed N-arylation of indoles. (2002) (416)
- Identification and Rescue of α-Synuclein Toxicity in Parkinson Patient–Derived Neurons (2013) (410)
- A general, efficient, and inexpensive catalyst system for the coupling of aryl iodides and thiols. (2002) (409)
- Industrial-Scale Palladium-Catalyzed Coupling of Aryl Halides and Amines –A Personal Account (2006) (396)
- Copper-catalyzed coupling of alkylamines and aryl iodides: an efficient system even in an air atmosphere. (2002) (396)
- On the role of metal contaminants in catalyses with FeCl3. (2009) (395)
- Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions. (2012) (381)
- A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides. (2008) (372)
- A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: novel ligand coordination. (2002) (367)
- Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones (2000) (367)
- Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers (1999) (355)
- Pd-catalyzed intermolecular amidation of aryl halides: the discovery that xantphos can be trans-chelating in a palladium complex. (2002) (351)
- Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes. (2015) (344)
- Copper-catalyzed trifluoromethylation of unactivated olefins. (2011) (338)
- General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water. (2005) (333)
- Scope and limitations of the Pd/BINAP-catalyzed amination of aryl bromides. (2000) (333)
- A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides. (2008) (329)
- A general and efficient method for the palladium-catalyzed cross-coupling of thiols and secondary phosphines (2004) (325)
- Group 4 Metal Complexes of Benzynes, Cycloalkynes, Acyclic Alkynes, and Alkenes (1988) (324)
- The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans. (2006) (323)
- Highly selective room-temperature copper-catalyzed C-N coupling reactions. (2006) (321)
- Palladium-catalyzed intermolecular coupling of aryl halides and amides. (2000) (319)
- A Catalytic Asymmetric Suzuki Coupling for the Synthesis of Axially Chiral Biaryl Compounds (2000) (318)
- Pd(PhCN)(2)Cl(2)/P(t-Bu)(3): a versatile catalyst for Sonogashira reactions of aryl bromides at room temperature. (2000) (316)
- Aryl amination using ligand-free Ni(II) salts and photoredox catalysis (2016) (311)
- The first general palladium catalyst for the Suzuki-Miyaura and carbonyl enolate coupling of aryl arenesulfonates. (2003) (310)
- Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction. (2002) (310)
- Copper-catalyzed oxytrifluoromethylation of unactivated alkenes. (2012) (302)
- Cross-coupling in flow. (2011) (301)
- A highly active catalyst for Suzuki-Miyaura cross-coupling reactions of heteroaryl compounds. (2006) (297)
- Domino cu-catalyzed C--N coupling/hydroamidation: a highly efficient synthesis of nitrogen heterocycles. (2006) (294)
- Copper-catalyzed coupling of amides and carbamates with vinyl halides. (2003) (294)
- A GENERAL COPPER-CATALYZED SYNTHESIS OF DIARYL ETHERS (1997) (293)
- An extremely active catalyst for the Negishi cross-coupling reaction. (2004) (289)
- Copper-catalyzed domino halide exchange-cyanation of aryl bromides. (2003) (288)
- Pd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions. (2011) (287)
- Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines. (2003) (287)
- Enantio- and regioselective CuH-catalyzed hydroamination of alkenes. (2013) (287)
- Efficient palladium-catalyzed coupling of aryl chlorides and tosylates with terminal alkynes: use of a copper cocatalyst inhibits the reaction. (2003) (283)
- Copper-catalyzed coupling of aryl iodides with aliphatic alcohols. (2002) (282)
- Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions. (2010) (279)
- Organometallic Palladium Reagents for Cysteine Bioconjugation (2015) (274)
- Palladium-catalyzed borylation of aryl chlorides: scope, applications, and computational studies. (2007) (274)
- An efficient copper-catalyzed coupling of aryl halides with imidazoles (1999) (262)
- Synthesis of Substituted Oxindoles from α-Chloroacetanilides via Palladium-Catalyzed C−H Functionalization (2003) (261)
- Significantly improved method for the pd-catalyzed coupling of phenols with aryl halides: understanding ligand effects. (2006) (251)
- Palladium-catalyzed aminocarbonylation of aryl chlorides at atmospheric pressure: the dual role of sodium phenoxide. (2007) (250)
- Palladium-Catalyzed Coupling of Functionalized Primary and Secondary Amines with Aryl and Heteroaryl Halides: Two Ligands Suffice in Most Cases. (2010) (250)
- The Synthesis of Aminopyridines: A Method Employing Palladium-Catalyzed Carbon-Nitrogen Bond Formation. (1996) (245)
- Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides. (2008) (242)
- Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling. (2011) (241)
- Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines (2015) (240)
- Palladium(0)-catalyzed arylative dearomatization of phenols. (2011) (235)
- An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates (1997) (234)
- Selective palladium-catalyzed arylation of ammonia: synthesis of anilines as well as symmetrical and unsymmetrical di- and triarylamines. (2007) (233)
- Mechanistic studies on the copper-catalyzed N-arylation of amides. (2008) (233)
- Yeast Reveal a “Druggable” Rsp5/Nedd4 Network that Ameliorates α-Synuclein Toxicity in Neurons (2013) (230)
- Copper-catalyzed C-P bond construction via direct coupling of secondary phosphines and phosphites with aryl and vinyl halides. (2003) (230)
- N- versus O-arylation of aminoalcohols: orthogonal selectivity in copper-based catalysts. (2007) (226)
- Monodentate phosphines provide highly active catalysts for Pd-catalyzed C-N bond-forming reactions of heteroaromatic halides/amines and (H)N-heterocycles. (2006) (226)
- Palladium-catalyzed carbonylation reactions of aryl bromides at atmospheric pressure: a general system based on Xantphos. (2008) (222)
- Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. (2006) (211)
- Copper-catalyzed N-arylation of imidazoles and benzimidazoles. (2007) (211)
- Palladium-catalyzed intramolecular C-O bond formation. (2001) (210)
- Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes. (2013) (209)
- Asymmetric Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine−Copper Catalyst (1999) (208)
- Catalytic enantioselective conjugate reduction of lactones and lactams. (2003) (208)
- Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation. (2008) (206)
- The role of chelating diamine ligands in the goldberg reaction: a kinetic study on the copper-catalyzed amidation of aryl iodides. (2005) (205)
- Nickel-Catalyzed Amination of Aryl Chlorides (1997) (203)
- 4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles. (2006) (201)
- Practical, high-yield, regioselective, rhodium-catalyzed hydroformylation of functionalized .alpha.-olefins (1993) (201)
- Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations. (2010) (200)
- Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds Catalyzed by a Copper Carbene Complex (2003) (198)
- Water-mediated catalyst preactivation: an efficient protocol for C-N cross-coupling reactions. (2008) (198)
- Overcoming the Challenges of Solid Bridging and Constriction during Pd-Catalyzed C−N Bond Formation in Microreactors (2010) (197)
- A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis (1998) (196)
- Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides. (2009) (193)
- Synthesis of N-aryl hydrazides by copper-catalyzed coupling of hydrazides with aryl iodides. (2001) (192)
- Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand. (2009) (192)
- An integrated microreactor system for self-optimization of a Heck reaction: from micro- to mesoscale flow systems. (2010) (190)
- Accelerating reactions with microreactors at elevated temperatures and pressures: profiling aminocarbonylation reactions. (2007) (190)
- Efficient pd-catalyzed amination of heteroaryl halides. (2005) (190)
- A multiligand based Pd catalyst for C-N cross-coupling reactions. (2010) (190)
- Use of tunable ligands allows for intermolecular Pd-catalyzed C--O bond formation. (2005) (189)
- An improved catalyst for the asymmetric arylation of ketone enolates. (2002) (189)
- Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation. (2007) (189)
- Copper-catalyzed coupling of arylboronic acids and amines. (2001) (189)
- Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes (2015) (188)
- A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis (1999) (186)
- An improved Cu-based catalyst system for the reactions of alcohols with aryl halides. (2008) (185)
- Pd-catalyzed N-arylation of secondary acyclic amides: catalyst development, scope, and computational study. (2009) (185)
- A general and efficient method for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles. (2008) (184)
- Palladium-Catalyzed α-Arylation of Esters (2001) (183)
- Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation. (2013) (182)
- Structural reevaluation of the electrophilic hypervalent iodine reagent for trifluoromethylthiolation supported by the crystalline sponge method for X-ray analysis. (2014) (181)
- Asymmetric Arylation of Ketone Enolates (1998) (181)
- An efficient intermolecular palladium-catalyzed synthesis of aryl ethers. (2001) (180)
- CATALYTIC ASYMMETRIC HYDROGENATION OF IMINES WITH A CHIRAL TITANOCENE CATALYST : SCOPE AND LIMITATIONS (1994) (180)
- Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates. (2012) (178)
- Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C−O Bond-Forming Reaction (1996) (172)
- An improved synthesis of functionalized biphenyl-based phosphine ligands. (2000) (172)
- Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation. (2003) (170)
- Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics. (2009) (170)
- Intramolecular palladium-catalyzed aryl amination and aryl amidation (1996) (169)
- Copper-catalyzed selective hydroamination reactions of alkynes (2014) (168)
- Palladium-catalyzed amination reactions in flow: overcoming the challenges of clogging via acoustic irradiation (2011) (166)
- Orthogonal Cu- and Pd-based catalyst systems for the O- and N-arylation of aminophenols. (2009) (161)
- Highly Enantioselective Imine Hydrosilylation Using (S,S)-Ethylenebis(η5-tetrahydroindenyl)titanium Difluoride (1996) (160)
- Palladium-catalyzed carbonylation of aryl tosylates and mesylates. (2008) (158)
- Suzuki-Miyaura cross-coupling reactions in flow: multistep synthesis enabled by a microfluidic extraction. (2011) (157)
- Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones (2016) (154)
- Cu-catalyzed arylation of phenols: synthesis of sterically hindered and heteroaryl diaryl ethers. (2010) (153)
- Synthesis of heterocycles via Pd-ligand controlled cyclization of 2-chloro-N-(2-vinyl)aniline: preparation of carbazoles, indoles, dibenzazepines, and acridines. (2010) (153)
- Synthesis of medium ring nitrogen heterocycles via a tandem copper-catalyzed C-N bond formation-ring-expansion process. (2004) (151)
- Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols (2016) (151)
- Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis (2016) (148)
- Efficient palladium-catalyzed N-arylation of indoles. (2000) (148)
- Palladium-catalyzed asymmetric dearomatization of naphthalene derivatives. (2009) (148)
- An efficient process for pd-catalyzed C-N cross-coupling reactions of aryl iodides: insight into controlling factors. (2009) (148)
- Pd-catalyzed Kumada-Corriu cross-coupling reactions at low temperatures allow the use of Knochel-type Grignard reagents. (2007) (148)
- A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols. (2011) (147)
- A general and mild copper-catalyzed arylation of diethyl malonate. (2002) (147)
- An improved system for the palladium-catalyzed borylation of aryl halides with pinacol borane. (2008) (146)
- The synthesis, reactions and molecular structure of zirconocene-alkyne complexes (1987) (145)
- Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates. (2013) (145)
- Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes (2014) (145)
- Structural Insights into Active Catalyst Structures and Oxidative Addition to (Biaryl)phosphine−Palladium Complexes via Density Functional Theory and Experimental Studies (2007) (143)
- Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes. (2009) (142)
- N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings (2014) (142)
- The development of efficient protocols for the palladium-catalyzed cyclization reactions of secondary amides and carbamates. (1999) (141)
- Palladium-Catalyzed Intermolecular Carbon−Oxygen Bond Formation: A New Synthesis of Aryl Ethers (1997) (139)
- A domino copper-catalyzed C-O coupling-Claisen rearrangement process. (2003) (139)
- New ammonia equivalents for the Pd-catalyzed amination of aryl halides. (2001) (137)
- Orthogonal Pd- and Cu-based catalyst systems for C- and N-arylation of oxindoles. (2008) (137)
- Palladium-Catalyzed Coupling of Optically Active Amines with Aryl Bromides (1997) (137)
- Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity (1999) (136)
- Sequential Cu-catalyzed amidation-base-mediated camps cyclization: a two-step synthesis of 2-Aryl-4-quinolones from o-halophenones. (2007) (134)
- Rationale behind the resistance of dialkylbiaryl phosphines toward oxidation by molecular oxygen. (2007) (134)
- Multistep microchemical synthesis enabled by microfluidic distillation. (2010) (133)
- An annulative approach to highly substituted indoles: unusual effect of phenolic additives on the success of the arylation of ketone enolates. (2002) (133)
- Cp2TiCH2 complexes in synthetic applications (1983) (132)
- The palladium-catalyzed trifluoromethylation of vinyl sulfonates. (2011) (132)
- Copper-Catalyzed Arylation of β-Amino Alcohols (2002) (131)
- Nickel-BINAP Catalyzed Enantioselective a-Arylation of a-Substituted ?-Butyrolactones (2002) (131)
- Palladium-Catalyzed Amination of Aryl Triflates (1997) (130)
- Asymmetric titanocene-catalyzed hydrogenation of imines (1992) (129)
- Zirconocene complexes of imines. General synthesis, structure, reactivity, and in situ generation to prepare geometrically pure allylic amines (1989) (128)
- Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides. (2011) (127)
- Synthesis of β-Alkyl Cyclopentanones in High Enantiomeric Excess via Copper-Catalyzed Asymmetric Conjugate Reduction (2000) (126)
- Use of polymer-supported dialkylphosphinobiphenyl ligands for palladium-catalyzed amination and Suzuki reactions. (2001) (125)
- Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction. (2007) (125)
- A general, practical palladium-catalyzed cyanation of (hetero)aryl chlorides and bromides. (2013) (124)
- Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system. (2013) (123)
- Efficient catalyst for the Suzuki-Miyaura coupling of potassium aryl trifluoroborates with aryl chlorides. (2004) (123)
- Palladium-Catalyzed Synthesis of Monodisperse, Controlled-Length, and Functionalized Oligoanilines (1998) (123)
- Palladium-Catalyzed Amination of Aryl Bromides: Use of Phosphinoether Ligands for the Efficient Coupling of Acyclic Secondary Amines (1997) (123)
- Highly N2-selective palladium-catalyzed arylation of 1,2,3-triazoles. (2011) (122)
- Trimethylphosphine adduct of the zirconocene-benzyne complex: synthesis, reactions, and x-ray crystal structure (1986) (118)
- A Phosphane‐Free Catalyst System for the Heck Arylation of Disubstituted Alkenes: Application to the Synthesis of Trisubstituted Olefins (1999) (117)
- Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides. (2013) (117)
- Selective, zirconium-mediated cross-coupling of alkynes: the synthesis of isomerically pure 1,3-dienes and 1,4-diiodo-1,3-dienes (1989) (116)
- An air and thermally stable one- component catalyst for the amination of aryl chlorides. (2003) (115)
- Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides (2014) (114)
- Cu-catalyzed N- and O-arylation of 2-, 3-, and 4-hydroxypyridines and hydroxyquinolines. (2007) (114)
- PALLADIUM-CATALYZED AMINATION OF ARYL IODIDES (1996) (113)
- Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst (2014) (113)
- Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds. (2011) (112)
- Insights into amine binding to biaryl phosphine palladium oxidative addition complexes and reductive elimination from biaryl phosphine arylpalladium amido complexes via density functional theory. (2007) (111)
- Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactor. (2011) (111)
- Enantioselective hydrosilylation of ketones with a chiral titanocene catalyst (1994) (110)
- Rational Ligand Design for the Arylation of Hindered Primary Amines Guided by Reaction Progress Kinetic Analysis (2015) (110)
- Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes. (2014) (109)
- A Modified Procedure for the Preparation of Cp2Zr(H)Cl (Schwartz's Reagent) (1987) (109)
- CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition. (2020) (109)
- Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins. (2017) (109)
- Arylation Chemistry for Bioconjugation. (2019) (107)
- A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles. (2007) (107)
- Catalytic asymmetric vinylation of ketone enolates. (2001) (105)
- Amine Additives Greatly Expand the Scope of Asymmetric Hydrosilylation of Imines. (1998) (104)
- Sequential copper-catalyzed vinylation/cyclization: an efficient synthesis of functionalized oxazoles. (2007) (103)
- Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands. (2013) (102)
- A catalytic method for the reduction of esters to alcohols (1991) (102)
- Microfluidic electrochemistry for single-electron transfer redox-neutral reactions (2020) (102)
- DIRECT OBSERVATION OF C-O REDUCTIVE ELIMINATION FROM PALLADIUM ARYL ALKOXIDE COMPLEXES TO FORM ARYL ETHERS (1997) (102)
- Cu-catalyzed tandem C-N bond formation for the synthesis of pyrroles and heteroarylpyrroles. (2007) (101)
- A versatile catalyst system for Suzuki-Miyaura cross-coupling reactions of C(sp(2))-tosylates and mesylates. (2009) (101)
- A Mild General Procedure for the One‐Pot Conversion of Amides to Aldehydes (1996) (100)
- A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles (2000) (100)
- Enantioselective synthesis of α-aminosilanes by copper-catalyzed hydroamination of vinylsilanes. (2014) (100)
- An Efficient System For the Pd-Catalyzed Cross-Coupling of Amides and Aryl Chlorides. (2009) (99)
- Concise palladium-catalyzed synthesis of dibenzodiazepines and structural analogues. (2011) (98)
- CATALYTIC ASYMMETRIC HYDROGENATION OF IMINES WITH A CHIRAL TITANOCENE CATALYST : KINETIC AND MECHANISTIC INVESTIGATIONS (1994) (98)
- CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications. (2018) (98)
- An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates. (2013) (97)
- Breaking the Base Barrier: An Electron-Deficient Palladium Catalyst Enables the Use of a Common Soluble Base in C-N Coupling. (2018) (97)
- The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination (2016) (96)
- Palladium-catalyzed amination of aryl nonaflates. (2003) (96)
- Packed-bed reactors for continuous-flow C-N cross-coupling. (2010) (96)
- Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst (1999) (96)
- Palladium-Catalyzed Intramolecular a-Arylation of a-Amino Acid Esters (2002) (96)
- Carbonylation of aryl chlorides with oxygen nucleophiles at atmospheric pressure. Preparation of phenyl esters as acyl transfer agents and the direct preparation of alkyl esters and carboxylic acids. (2008) (95)
- An air-stable catalyst system for the conversion of esters to alcohols (1992) (94)
- A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles. (2012) (94)
- Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination (2015) (93)
- Copper-catalyzed vinylation of hydrazides. A regioselective entry to highly substituted pyrroles. (2007) (93)
- Titanocene-Catalyzed Cyclocarbonylation of Enynes to Cyclopentenones (1996) (93)
- Biaryl Monophosphine Ligands in Palladium-Catalyzed C-N Coupling: An Updated User's Guide. (2019) (93)
- Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts. (2012) (92)
- Enantioselective, zirconium-mediated synthesis of allylic amines (1991) (92)
- A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions. (2011) (92)
- Asymmetric hydrogenation of unfunctionalized trisubstituted olefins with a chiral titanocene catalyst (1993) (92)
- Highly Enantioselective Catalytic Pauson−Khand Type Formation of Bicyclic Cyclopentenones (1996) (91)
- Highly Diastereo- and Enantioselective CuH-Catalyzed Synthesis of 2,3-Disubstituted Indolines (2015) (91)
- Expedited palladium-catalyzed amination of aryl nonaflates through the use of microwave-irradiation and soluble organic amine bases. (2006) (91)
- Palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate: a practical synthesis of unsymmetrical ureas. (2012) (91)
- Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization. (2012) (90)
- Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents (2014) (90)
- Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media (2015) (89)
- Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins (2015) (89)
- A direct approach to amines with remote stereocenters by enantioselective CuH-catalysed reductive relay hydroamination (2015) (89)
- Continuous-flow synthesis of biaryls enabled by multistep solid-handling in a lithiation/borylation/Suzuki-Miyaura cross-coupling sequence. (2011) (88)
- Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides. (2010) (88)
- A General Method for the Direct α‐Arylation of Aldehydes with Aryl Bromides and Chlorides (2007) (88)
- The Use of Catalytic Amounts of CuCl and Other Improvements in the Benzyne Route to Biphenyl‐Based Phosphine Ligands (2001) (86)
- Synthesis of indolines via a domino Cu-catalyzed amidation/cyclization reaction. (2008) (85)
- An Intramolecular Titanium-Catalyzed Asymmetric Pauson−Khand Type Reaction1 (1999) (85)
- A method for the asymmetric hydrosilylation of N-aryl imines. (2000) (85)
- IMPROVED FUNCTIONAL GROUP COMPATIBILITY IN THE PALLADIUM-CATALYZED AMINATION OF ARYL BROMIDES (1997) (85)
- Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach (2015) (84)
- Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles (2017) (84)
- An improved method for the palladium-catalyzed amination of aryl iodides. (2001) (84)
- Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions† (2011) (84)
- Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions. (2002) (83)
- Completely N1-selective palladium-catalyzed arylation of unsymmetric imidazoles: application to the synthesis of nilotinib. (2012) (83)
- Palladium-catalyzed N-monoarylation of amidines and a one-pot synthesis of quinazoline derivatives. (2012) (83)
- A highly active palladium catalyst system for the arylation of anilines (1998) (82)
- Mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow: application to the synthesis of functionalized heterocycles. (2013) (82)
- A Nickel(0)-Catalyzed Process for the Transformation of Enynes to Bicyclic Cyclopentenones. (1996) (82)
- Rational Development of Practical Catalysts for Aromatic Carbon—Nitrogen Bond Formation (1999) (82)
- Palladium-catalyzed monoarylation of nitroalkanes. (2002) (81)
- Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes. (2016) (80)
- Scope of the Intramolecular Titanocene-Catalyzed Pauson−Khand Type Reaction1 (1999) (80)
- Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acids. (2013) (80)
- Palladium‐Catalyzed Stille Cross‐Coupling Reaction of Aryl Chlorides using a Pre‐Milled Palladium Acetate and XPhos Catalyst System (2008) (80)
- ELECTRONIC DEPENDENCE OF C-O REDUCTIVE ELIMINATION FROM PALLADIUM (ARYL)NEOPENTOXIDE COMPLEXES (1998) (80)
- Palladium‐Catalyzed Aromatic Carbon‐Nitrogen Bond Formation (2008) (80)
- Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration (2016) (80)
- Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides. (2001) (80)
- Novel Syntheses of Tetrahydropyrroloquinolines: Applications to Alkaloid Synthesis (1996) (80)
- Continuous-flow synthesis of monoarylated acetaldehydes using aryldiazonium salts. (2012) (80)
- Copper-catalyzed regiospecific synthesis of N-alkylbenzimidazoles. (2007) (79)
- Pharmaceutical diversification via palladium oxidative addition complexes (2019) (79)
- Pd-catalyzed O-arylation of ethyl acetohydroximate: synthesis of O-arylhydroxylamines and substituted benzofurans. (2010) (79)
- Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes. (2012) (79)
- Rapid and efficient copper-catalyzed Finkelstein reaction of (hetero)aromatics under continuous-flow conditions. (2015) (79)
- A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins. (2017) (79)
- Asymmetric palladium-catalyzed intramolecular alpha-arylation of aldehydes. (2008) (78)
- Copper-catalyzed asymmetric conjugate reduction as a route to novel beta-azaheterocyclic acid derivatives. (2004) (78)
- Pd-catalyzed cross-coupling reactions of amides and aryl mesylates. (2010) (78)
- Palladium‐Catalyzed γ‐Arylation of β,γ‐Unsaturated Ketones: Application to a One‐Pot Synthesis of Tricyclic Indolines (2008) (77)
- Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins. (2011) (77)
- Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides. (2009) (77)
- A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes. (2018) (77)
- Synthesis, structure, and reactions of a zirconocene-cyclohexyne complex (1986) (77)
- Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile. (2018) (76)
- Palladium-Mediated Arylation of Lysine in Unprotected Peptides. (2017) (76)
- Electronic effects on the selectivity of pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: the competitive roles of amine binding and acidity. (2007) (76)
- Improved functional group compatibility in the palladium-catalyzed synthesis of aryl amines. (2002) (76)
- Continuous-flow synthesis of 3,3-disubstituted oxindoles by a palladium-catalyzed α-arylation/alkylation sequence. (2011) (75)
- ASYMMETRIC HYDROGENATION OF ENAMINES WITH A CHIRAL TITANOCENE CATALYST (1994) (74)
- A GENERAL SYNTHESIS OF END-FUNCTIONALIZED OLIGOANILINES VIA PALLADIUM-CATALYZED AMINATION (1998) (74)
- Mild and highly selective palladium-catalyzed monoarylation of ammonia enabled by the use of bulky biarylphosphine ligands and palladacycle precatalysts. (2013) (74)
- Dynamic kinetic resolution via asymmetric conjugate reduction: enantio- and diastereoselective synthesis of 2,4-dialkyl cyclopentanones. (2002) (74)
- One-pot sequential Cu-catalyzed reduction and Pd-catalyzed arylation of silyl enol ethers. (2004) (73)
- Synthesis of highly enantiomerically enriched cyclic amines by the catalytic asymmetric hydrogenation of cyclic imines (1993) (73)
- One-pot synthesis of unsymmetrical triarylamines from aniline precursors. (2000) (73)
- A Titanocene-Catalyzed Intramolecular Ene Reaction: Cycloisomerization of Enynes and Dienynes (1999) (72)
- Mechanistically Guided Design of Ligands That Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions. (2018) (71)
- Convenient method for the preparation of Weinreb amides via Pd-catalyzed aminocarbonylation of aryl bromides at atmospheric pressure. (2006) (70)
- Catalyst-controlled chemoselective arylation of 2-aminobenzimidazoles. (2012) (70)
- A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides (2015) (70)
- Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination (2016) (70)
- Continuous-flow synthesis of 1-substituted benzotriazoles from chloronitrobenzenes and amines in a C-N bond formation/hydrogenation/diazotization/cyclization sequence. (2013) (70)
- Enantioselective β-arylation of ketones enabled by lithiation/borylation/1,4-addition sequence under flow conditions. (2012) (70)
- Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct. (2019) (68)
- Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes. (2012) (68)
- Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles. (2014) (68)
- CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence. (2018) (67)
- A titanium vinylidene route to substituted allenes (1983) (67)
- New insights into Xantphos/Pd-Catalyzed C-N bond forming reactions : A structural and kinetic study (2006) (67)
- A general method for the preparation of zirconocene complexes of substituted benzynes: in situ generation, coupling reactions, and use in the synthesis of polyfunctionalized aromatic compounds (1987) (67)
- Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalyst. (2013) (67)
- Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides (1991) (66)
- Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines. (2015) (66)
- Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. (2007) (66)
- An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles. (2016) (66)
- Halide and Amine Influence in the Equilibrium Formation of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes from Palladium Aryl Halide Dimers (1996) (66)
- Suzuki–Miyaura cross-coupling optimization enabled by automated feedback† †Electronic supplementary information (ESI) available: Details regarding system operation and optimization method, optimization data, and spectroscopic data. See DOI: 10.1039/c6re00153j Click here for additional data file. (2016) (65)
- Synthesis and structure of a seven-membered cyclic cumulene (1993) (65)
- Synthesis of Polysubstituted Indoles and Indolines by Means of Zirconocene-Stabilized Benzyne Complexes (1994) (65)
- Controlled Acceleration and Inhibition of Bergman Cyclization by Metal Chlorides (1995) (65)
- Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids (2016) (65)
- Efficient kinetic resolution in the asymmetric hydrosilylation of imines of 3-substituted indanones and 4-substituted tetralones. (2000) (65)
- Sequential N-Arylation of Primary Amines as a Route To Alkyldiarylamines (1999) (65)
- Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions. (2013) (64)
- Synthesis of unsymmetrical diarylureas via Pd-catalyzed C-N cross-coupling reactions. (2011) (64)
- Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction (1994) (64)
- An Improved Method for the Palladium-Catalyzed Amination of Aryl Triflates (1997) (63)
- Cobalt-phosphite-catalyzed asymmetric Pauson-Khand reaction. (2002) (63)
- CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines. (2017) (63)
- Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to γ-Butyrolactones (1997) (61)
- Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides (2014) (61)
- Direct and selective elimination of specific prions and amyloids by 4,5-dianilinophthalimide and analogs (2008) (61)
- Room Temperature Catalytic Amination of Aryl Iodides (1997) (60)
- Dosage Delivery of Sensitive Reagents Enables Glove Box-Free Synthesis (2015) (60)
- Stereochemistry of nucleophilic displacement on two phosphoric monoesters and a phosphoguanidine: the role of metaphosphate (1984) (60)
- Evidence for the formation and structure of palladacycles during Pd-catalyzed C-N bond formation with catalysts derived from bulky monophosphinobiaryl ligands. (2006) (59)
- Easy access to novel substituted 6-aminoimidazo[1,2-a]pyridines using palladium- and copper-catalyzed aminations. (2003) (59)
- Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates. (2017) (59)
- CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes. (2018) (59)
- Efficient Synthesis of Well-Defined, High Molecular Weight, and Processible Polyanilines under Mild Conditions via Palladium-Catalyzed Amination (2000) (58)
- The methylenation of enolizable ketones and esters using organotitanium chemistry (1985) (58)
- An Inexpensive Air-Stable Titanium-Based System for the Conversion of Esters to Primary Alcohols (1995) (57)
- Reductive Cyclization of Enones by a Titanium Catalyst (1995) (57)
- Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes (2016) (57)
- Olefin insertion in a metal alkyl in a Ziegler polymerization system (1985) (57)
- Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes. (2012) (56)
- Palladium Oxidative Addition Complexes for Peptide and Protein Cross-linking. (2018) (55)
- Short Enantioselective Total Syntheses of the Piperidine Alkaloids (S)-Coniine and (2R,6R)-trans-Solenopsin A via Catalytic Asymmetric Imine Hydrosilylation. (1998) (55)
- Molecular Design of Deep Blue Thermally Activated Delayed Fluorescence Materials Employing a Homoconjugative Triptycene Scaffold and Dihedral Angle Tuning (2018) (55)
- An improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides. (2011) (55)
- Titanocene-Catalyzed Reduction of Esters Using Polymethylhydrosiloxane as the Stoichiometric Reductant (1994) (54)
- Titanocene-catalyzed conversion of enynes to bicyclic cyclopentenones (1993) (54)
- Pyrrole-2-carboxylic acid as a ligand for the Cu-catalyzed reactions of primary anilines with aryl halides. (2008) (54)
- Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols. (2018) (54)
- Divergent unprotected peptide macrocyclisation by palladium-mediated cysteine arylation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05454d Click here for additional data file. (2016) (54)
- An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides (2015) (54)
- A chemoselective strategy for late-stage functionalization of complex small molecules with polypeptides and proteins (2018) (54)
- Pd-catalyzed Suzuki–Miyaura reactions of aryl halides using bulky biarylmonophosphine ligands (2007) (53)
- One-pot synthesis of enantiomerically enriched 2,3-disubstituted cyclopentanones via copper-catalyzed 1,4-reduction and alkylation. (2001) (53)
- Palladium-Catalyzed Amination of Unprotected Five-Membered Heterocyclic Bromides (2014) (53)
- Titanocene-Catalyzed Reduction of Lactones to Lactols. (1997) (52)
- Diastereoselective Synthesis of γ-Butyrolactones from Enones Mediated or Catalyzed by a Titanocene Complex (1996) (52)
- Dynamic Kinetic Resolution of α,β‐Unsaturated Lactones through Asymmetric Copper‐Catalyzed Conjugate Reduction: Application to the Total Synthesis of Eupomatilone‐3 (2005) (52)
- Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst (2014) (52)
- Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes (2019) (52)
- Continuous-Flow Synthesis of Biaryls by Negishi Cross-Coupling of Fluoro- and Trifluoromethyl-Substituted (Hetero)arenes. (2016) (51)
- A Practical Electrophilic Nitrogen Source for the Synthesis of Chiral Primary Amines by Copper-Catalyzed Hydroamination. (2018) (51)
- Water-Soluble Palladium Reagents for Cysteine S-Arylation under Ambient Aqueous Conditions. (2017) (51)
- Reductive cyclization of ester-containing enynes with a practical titanocene reagent. Synthesis of bicyclic cyclopentenones and iminocyclopentenes (1992) (51)
- A general method for Suzuki-Miyaura coupling reactions using lithium triisopropyl borates. (2012) (51)
- Preparation of 2-amino-2′-hydroxy-1,1′-binaphthyl and N-arylated 2-amino-1,1′-binaphthyl derivatives via palladium-catalyzed amination (1999) (50)
- Synthesis of 5,5-disubstituted butenolides based on a Pd-catalyzed gamma-arylation strategy. (2009) (50)
- Catalytic Method for the Reduction of Lactones to Lactols (1995) (49)
- Rhodium‐Catalyzed Hydroformylation of Internal Alkynes to α,β‐Unsaturated Aldehydes (1995) (49)
- Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes. (2018) (49)
- Virtually instantaneous, room-temperature [(11)C]-cyanation using biaryl phosphine Pd(0) complexes. (2015) (49)
- A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination. (2018) (48)
- Efficient Pd-catalyzed amination reactions for heterocycle functionalization. (2010) (48)
- P-chirogenic binaphthyl-substituted monophosphines: synthesis and use in enolate vinylation/arylation reactions. (2002) (48)
- Synthesis of substituted pyrroles via zirconocene complexes of imines (1989) (48)
- Formation of Palladium Bis(amine) Complexes from Reaction of Amine with Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes (1996) (47)
- Pd-Catalyzed C-N Coupling Reactions Facilitated by Organic Bases: Mechanistic Investigation Leads to Enhanced Reactivity in the Arylation of Weakly Binding Amines. (2019) (47)
- Palladium-catalyzed regioselective hydrodebromination of dibromoindoles: application to the enantioselective synthesis of indolodioxane U86192A. (2004) (46)
- Monocyclopentadienyltitanium aryloxide complexes: Preparation, characterization, and application in cyclization reactions (2002) (46)
- Palladium-catalyzed amination of unprotected halo-7-azaindoles. (2010) (46)
- Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands. (2017) (45)
- Catalytic Asymmetric Cyclocarbonylation of Nitrogen-Containing Enynes. (1999) (45)
- Synthesis and Solution Structure of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes (1996) (45)
- Titanocene-Based Method for Indole Synthesis (1998) (44)
- An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides. (2008) (44)
- Development of a Method for the N-Arylation of Amino Acid Esters with Aryl Triflates (2016) (44)
- Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions. (2012) (44)
- Palladium-catalyzed completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles. (2013) (44)
- An efficient one-pot method for the preparation of polysubstituted benzothiophenes (1989) (43)
- Cu-catalyzed Goldberg and Ullmann reactions of aryl halides using chelating N- and O-based ligands (2007) (43)
- Palladium-catalyzed N-arylation of 2-aminothiazoles. (2012) (42)
- A bimetallic zirconium complex containing an in-plane bridging aromatic ring (1989) (42)
- Stereochemical evidence for pseudorotation in the reaction of a phosphoric monoester (1984) (41)
- Use of precatalysts greatly facilitate palladium-catalyzed alkynylations in batch and continuous-flow conditions (2011) (41)
- Mechanistic Insight Leads to a Ligand Which Facilitates the Palladium-Catalyzed Formation of 2-(Hetero)Arylaminooxazoles and 4-(Hetero)Arylaminothiazoles. (2017) (41)
- Synthesis and x-ray crystal structure of a zirconocene complex of a cyclopentyne and its use to prepare bicyclic cyclopentenones (1989) (40)
- Stereochemistry of phospho transfer catalyzed by bovine liver acid phosphatase. (1981) (40)
- Synthesis, characterization, and reactivity of zirconocene and hafnocene silyl hydride complexes (1991) (40)
- Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions. (2017) (40)
- Use of a "Catalytic" Cosolvent, N,N-Dimethyl Octanamide, Allows the Flow Synthesis of Imatinib with no Solvent Switch. (2016) (40)
- Development of a Method for the Reductive Cyclization of Enones by a Titanium Catalyst (1996) (40)
- Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Aryl Triflates by Deuterium Labeling (2014) (40)
- Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles. (2019) (39)
- A general and efficient method for the copper-catalyzed cross-coupling of amides and thiophenols with 6-halogenoimidazo[1,2-a]pyridines (2006) (38)
- PREPARATION AND X-RAY STRUCTURE OF CP2TI(PH2SIH2)(PME3) (1994) (38)
- Chiral [16O, 17O, 18O]phosphoric monoesters as stereochemical probes of phosphotransferases. (1982) (37)
- Preparation of Novel Titanium Complexes Bearing o-Phosphinophenol Ligands (1996) (37)
- Synthesis of optically pure 2-trifluoromethyl lactic acid by asymmetric hydroformylation. (2013) (37)
- Kinetic resolution of racemic disubstituted 1-pyrrolines via asymmetric reduction with a chiral titanocene catalyst (1994) (36)
- Palladium-catalyzed synthesis of N-aryl carbamates. (2013) (36)
- C—H Functionalization/C—N Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines. (2008) (36)
- Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Bases. (2019) (35)
- Kinetics and substituent effects in the formation of zirconocene thioaldehyde complexes: .beta.-hydride elimination versus cyclometalation (1988) (35)
- The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C-N Cross-Coupling. (2020) (35)
- A Catalytic Method for the Conversion of Silanes to Stannanes (1994) (34)
- Simple, Efficient Protocols for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine. (2009) (34)
- Determination of the absolute configuration of [16O,17O,18O]phosphate monoesters by using phosphorus-31 NMR (1980) (34)
- The synthesis, structure and reactivity of trimethylphosphine-zirconocene thioaldehyde complexes (1987) (33)
- CONVENIENT TWO-STEP CONVERSION OF LACTONES INTO CYCLIC ETHERS (1998) (33)
- A Practical Titanium-Catalyzed Synthesis of Bicyclic Cyclopentenones and Allylic Amines. (1996) (33)
- Visible Light-Mediated (Hetero)aryl Amination Using Ni(II) Salts and Photoredox Catalysis in Flow: A Synthesis of Tetracaine. (2020) (32)
- Cross coupling. (2008) (32)
- Synthesis of 3,4-disubstituted indoles via a sequential olefin-insertion/ene route (1991) (31)
- Synthesis, structure, and reactions of a zirconocene-benzdiyne complex (1987) (31)
- Synthesis and Reactions of 3-(Bromomethyl)-1-carbethoxy-4-iodoindole: The Preparation of 3,4-Differentially Substituted Indoles (1994) (31)
- Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles. (2020) (31)
- An Improved Synthesis of BrettPhos and RockPhos-Type Biarylphosphine Ligands. (2012) (31)
- Suzuki–Miyaura cross-coupling optimization enabled by automated feedback (2016) (31)
- Cascade palladium catalysis: a predictable and selectable regiocontrolled synthesis of N-arylbenzimidazoles. (2013) (31)
- A new method for the preparation of 3,5-disubstituted butenolides (1988) (31)
- Synthesis, structure, and reactivity of a zirconocene complex of cyclobutene (1990) (31)
- Ipso- or cine-substitutions of 6-haloimidazo[1,2-a]pyridine derivatives with different azoles depending on the reaction conditions. (2003) (31)
- A Fungal-Selective Cytochrome bc1 Inhibitor Impairs Virulence and Prevents the Evolution of Drug Resistance. (2016) (30)
- A regiospecific method for the hydrocyanation of olefins (1987) (30)
- Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles. (2019) (30)
- A Highly Active Catalyst for Pd‐Catalyzed Amination Reactions: Cross‐Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides. (2009) (30)
- Enantioselective Olefin Hydrocyanation Without Cyanide. (2019) (30)
- In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides (2015) (30)
- CuH-Catalyzed Asymmetric Reduction of α,β-Unsaturated Carboxylic Acids to β-Chiral Aldehydes. (2018) (30)
- Copper-Catalyzed RegioselectiveorthoCH Cyanation of Vinylarenes (2014) (30)
- A new approach to the synthesis of the CC-1065/duocarmycin pharmacophore (1992) (29)
- Use of a Droplet Platform To Optimize Pd-Catalyzed C–N Coupling Reactions Promoted by Organic Bases (2019) (28)
- Preparation, crystal structure analysis, and catalytic application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2 (2002) (28)
- The zirconocene induced coupling of benzyne with nitriles: Synthesis, structure and reactions of novel azametallacyclopentenes (1987) (27)
- Oxygen-atom transfer from nitrous oxide. Synthesis and structure of a zirconocene oxametallacyclobutene complex (1988) (27)
- Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes. (2019) (27)
- Catalysts for Suzuki—Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure. (2005) (27)
- Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids (1995) (26)
- Highly Enantioselective Synthesis of Indazoles with a C3-Quaternary Chiral Center Using CuH Catalysis. (2019) (26)
- Synthesis of 4,5-dianilinophthalimide and related analogues for potential treatment of Alzheimer's disease via palladium-catalyzed amination. (2005) (26)
- Synthesis, structure, and reactions of (1-ethoxyethyl)zirconocene chloride, a stable acyclic secondary zirconocene alkyl (1988) (25)
- A Combined Zirconocene Benzyne−Palladium Cross-Coupling Route to Substituted Biphenyls and Terphenyls (1999) (25)
- Synthesis, reactions, and x-ray crystal structure determination of hafnocene complex Cp2Hf(isobutylene).cntdot.PMe3 (1990) (25)
- Organic chemistry: A radical approach to diversity (2011) (25)
- Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination. (2019) (25)
- Structure and Reactivity of [(L•Pd)n•(1,5-cyclooctadiene)] (n=1-2) Complexes Bearing Biaryl Phosphine Ligands. (2014) (24)
- Pd-catalyzed amination reactions of aryl halides using bulky biarylmonophosphine ligands (2007) (24)
- An air-stable catalyst system for the conversion of esters to alcohols. [Erratum to document cited in CA117(3):25599z] (1993) (24)
- Palladium-Catalyzed Negishi Coupling of α-CF3 Oxiranyl Zincate: Access to Chiral CF3-Substituted Benzylic Tertiary Alcohols. (2017) (24)
- Protein-Protein Cross-Coupling via Palladium-Protein Oxidative Addition Complexes from Cysteine Residues. (2020) (24)
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- Development of a Method for the Reductive Cyclization of Enones by a Titanium Catalyst. (1996) (3)
- Cu-Catalyzed Tandem C—N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles. (2008) (3)
- Convenient Two-Step Conversion of Lactones into Cyclic Ethers. (1998) (3)
- Highly Diastereo- and Enantioselective CuH-Catalyzed Synthesis of 2,3-Disubstituted Indolines. (2015) (3)
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- Efficient Catalyst for the Suzuki—Miyaura Coupling of Potassium Aryl Trifluoroborates with Aryl Chlorides. (2004) (3)
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- Enantioselective Hydrocarbamoylation of Alkenes (2022) (3)
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- Palladium Mediated Synthesis of Protein-Polyarene Conjugates. (2022) (2)
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- Improved Catalyst System for Aromatic Carbon-Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates. (1996) (2)
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- A Titanocene-Catalyzed Intramolecular Ene Reaction: Cycloisomerization of Enynes and Dienynes. (1999) (2)
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- A General and Efficient Method for the Copper‐Catalyzed Cross‐Coupling of Amides and Thiophenols with 6‐Halogenoimidazo[1,2‐a]pyridines. (2006) (2)
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- Cu‐Catalyzed N‐ and O‐Arylation of 2‐, 3‐, and 4‐Hydroxypyridines and Hydroxyquinolines. (2007) (1)
- Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction. (1995) (1)
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- Palladium-Catalyzed γ-Arylation of β,γ-Unsaturated Ketones: Application to a One-Pot Synthesis of Tricyclic Indolines. (2008) (1)
- Convenient Method for the Preparation of Weinreb Amides via Pd‐Catalyzed Aminocarbonylation of Aryl Bromides at Atmospheric Pressure. (2007) (1)
- Titanocene‐Catalyzed Cyclocarbonylation of o‐Allyl Aryl Ketones to . gamma.‐Butyrolactones. (1997) (1)
- An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates. (1997) (1)
- Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis. (2016) (1)
- Regioselective 2‐Amination of Polychloropyrimidines. (2016) (1)
- Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity. (1999) (0)
- A Rationally Designed Universal Catalyst for Suzuki—Miyaura Coupling Processes. (2004) (0)
- Mild and General Conditions for Negishi Cross‐Coupling Enabled by the Use of Palladacycle Precatalysts. (2013) (0)
- Yeun Chung Derived Neurons − Patient-Synuclein Toxicity in Parkinson α Identification and Rescue (2016) (0)
- Preparation of 2-Amino-2′-hydroxy-1,1′-binaphthyl and N-Arylated 2-Amino-1,1′-binaphthyl Derivatives via Palladium-Catalyzed Amination. (1999) (0)
- Highly Selective Room‐Temperature Copper‐Catalyzed C—N Coupling Reactions. (2006) (0)
- Nickel(0)-Catalyzed Process for the Transformation of Enynes to Bicyclic Cyclopentenones. (1996) (0)
- Zirconocene Complexes of Imines: General Synthesis, Structure, Reactivity, and in situ Generation to Prepare Geometrically Pure Allylic Amines. (1989) (0)
- Oxygen‐Atom Transfer from Nitrous Oxide. Synthesis and Structure of a Zirconocene Oxametallacyclobutene Complex. (1989) (0)
- Halobenzyl Ethers as Protecting Groups for Organic Synthesis. (2000) (0)
- Conjugate reduction of alpha,beta-unsaturated carbonyl compounds catalyzed by a copper carbene complex. (2003) (0)
- Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination (2008) (0)
- Copper-Catalyzed Regioselective ortho C—H Cyanation of Vinylarenes. (2015) (0)
- Synthesis of Substituted Pyrroles via Cu-Catalyzed Vinylation of Hydrazides (2007) (0)
- Magical Power of d-Block Transition Metals—Pd-Catalyzed Cross-Coupling and Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA) (2011) (0)
- Aryl ether synthesis, methods and related reagents. (1997) (0)
- Ligands for metals and metal catalyzed improved processes based thereon. (1999) (0)
- Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki—Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters. (2007) (0)
- Copper‐Catalyzed Coupling of Arylboronic Acids and Amines. (2001) (0)
- Who's who in Chemical Science (2011) (0)
- Pyrroles and Pyrazoles by a C-N Coupling-Hydroamination Sequence (2007) (0)
- Synthesis of (Alkoxymethyl)zirconocene Chlorides: Stereochemistry of Carbon‐Carbon Bond Formation in a Zirconocene‐Wittig Rearrangement. (1989) (0)
- Pd-Catalyzed Borylation of Aryl Halides Using Pinacol Borane (2008) (0)
- Synthesis, Reactions, and X-Ray Crystal Structure Determinaton of Cp2Hf(isobutylene)·PMe3. (1990) (0)
- The Palladium-Catalyzed Trifluoromethylaiton of Vinyl Sulfonates. (2012) (0)
- ChemInform Abstract: P-Chirogenic Binaphthyl-Substituted Monophosphines: Synthesis and Use in Enolate Vinylation/Arylation Reactions. (2002) (0)
- The Zirconocene Induced Coupling of Benzyne with Nitriles: Synthesis, Structure, and Reactions of Novel Azametallacyclopentenes. (1987) (0)
- A General and Mild Copper‐Catalyzed Arylation of Diethyl Malonate. (2002) (0)
- Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification. (2023) (0)
- APPLICATION OF DEUTERIUM MAGNETIC RESONANCE TO BIOSYNTHETIC STUDIES. 1. BIOSYNTHESIS OF OVALICIN (1977) (0)
- Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides. (2015) (0)
- Synthesis, Structure, and Reactions of a Zirconocene-Benzdiyne Complex. (1987) (0)
- Rapid and Efficient Trifluoromethylation of Aromatic and Heteroaromatic Compounds Using Potassium Trifluoroacetate Enable by a Flow System. (2014) (0)
- A Multiligand-Based Palladium Catalyst for C-NCross-Coupling Reactions (2011) (0)
- Mild Pd‐Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst. (2015) (0)
- A General Method for the Direct α-Arylation of Aldehydes with Aryl Bromides and Chlorides. (2008) (0)
- Palladium-catalyzed intramolecular alpha-arylation of alpha-amino acid esters. (2002) (0)
- Regiospecific Synthesis of Polysubstituted Naphthalenes and Iodoacylnaphthoquinones via Zirconocene Complexes of Naphthalynes. (1991) (0)
- Catalyst‐Controlled Chemoselective Arylation of 2‐Aminobenzimidazoles. (2013) (0)
- Synthesis and Structure of a Seven-Membered Cyclic Cumulene. (1994) (0)
- Buchwald Ligands and Precatalysts Table of Contents (2014) (0)
- Titanocene-Catalyzed Conversion of Enynes to Bicyclic Cyclopentenones. (1993) (0)
- Sequential Cu-Catalyzed Amidation/Base-Mediated Camps Cyclization: A Two-Step Synthesis of 2-Aryl-4-quinolones from o-Halophenones. (2008) (0)
- United States Patent ( 10 ) Patent No . : US 7 , 399 , 488 B 2 (2017) (0)
- A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis. (1998) (0)
- A Great Chemist and Friend (2022) (0)
- Mechanistic Studies of Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification (2021) (0)
- Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki—Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations. (2011) (0)
- A Neophyl Palladacycle as an Air- and Thermally Stable Precursor to Oxidative Addition Complexes. (2021) (0)
- Pd-Ligand Controlled Cyclization for the Preparation of Heteroaromatics (2011) (0)
- Palladium‐Catalyzed Borylation of Aryl Chlorides: Scope, Applications, and Computational Studies. (2007) (0)
- Titanocene-Based Method for Indole Synthesis. (1998) (0)
- Correction to A General Method for Suzuki–Miyaura Coupling Reactions Using Lithium Triisopropyl Borates (2013) (0)
- Cascade Palladium Catalysis: A Predictable and Selectable Regiocontrolled Synthesis of N‐Arylbenzimidazoles. (2014) (0)
- Nickel-BINAP catalyzed enantioselective alpha-arylation of alpha-substituted gamma-butyrolactones. (2002) (0)
- Zirconocene(iso-butyl) Chloride: In situ Generation of a Zirconocene( methyl) Chloride Equivalent for Use in Organic Synthesis. (1992) (0)
- Synthesis of Heterocycles via Pd‐Ligand Controlled Cyclization of 2‐Chloro‐N‐(2‐vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridines. (2011) (0)
- A Method for the Asymmetric Hydrosilylation of N‐Aryl Imines. (2000) (0)
- Virtually Instantaneous, Room-Temperature [[superscript 11]C]-Cyanation Using Biaryl Phosphine Pd(0) Complexes (2015) (0)
- Pd(0)-Catalyzed Intermolecular Amination of Unactivated C(sp3)– (2012) (0)
- Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C[3 over sp]-H Bonds (2011) (0)
- The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides. (2010) (0)
- Pd ( 0 )-Catalyzed Intermolecular Amination of Unactivated C ( sp 3 ) – H Bonds * * (2012) (0)
- Chung Derived Neurons − Patient-Synuclein Toxicity in Parkinson α Identification and Rescue of (2014) (0)
- A Versatile Ligand for Suzuki-Miyaura Coupling ofTosylates and Mesylates (2009) (0)
- Palladium‐Catalyzed Carbonylation of Aryl Tosylates and Mesylates. (2008) (0)
- Rhodium-Catalyzed Enantioselective Hydroamination of Alkenes (2010) (0)
- Synthesis and Structure of a Novel Bis(stibole). (1995) (0)
- Simple, Efficient Protocols for the Pd‐Catalyzed Cross‐Coupling Reaction of Aryl Chlorides and Dimethylamine. (2009) (0)
- The Unexpected Formation of 3,4,7,8‐Tetramethyl‐1,2,5,6‐ tetrahydrodicyclobuta(a,e)cyclooctene from a Zirconacyclopentadiene. (1993) (0)
- Synthesis and Structure of Stibaindoles. (1990) (0)
- A Highly Active Catalyst for Suzuki—Miyaura Cross-Coupling Reactions of Heteroaryl Compounds. (2006) (0)
- Concise Palladium-Catalyzed Synthesis of Dibenzodiazepines (2011) (0)
- Palladium‐Catalyzed Monoarylation of Nitroalkanes. (2002) (0)
- Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV) (2007) (0)
- Synthesis and Reactions of 3‐(Bromomethyl)‐1‐carbethoxy‐4‐iodoindole: The Preparation of 3,4‐Differentially Substituted Indoles. (1995) (0)
- Eric Jacobsen @60 (2020) (0)
- Synthesis of NPS R-568 Utilizing Titanium-Catalyzed Asymmetric Hydrosilylation. (1999) (0)
- Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation from 1,3-Diene Pronucleophiles (2019) (0)
- A Bimetallic Zirconium Complex Containing an In-Plane Bridging Aromatic Ring. (1989) (0)
- Concise Palladium-Catalyzed Synthesis of Dibenzodiazepines and Structural Analogs (2011) (0)
- Dynamic kinetic resolution of alpha,beta-unsaturated lactones through asymmetric copper-catalyzed conjugate reduction: application to the total synthesis of eupomatilone-3. (2005) (0)
- Palladium-catalyzed gamma-arylation of beta,gamma-unsaturated ketones: application to a one-pot synthesis of tricyclic indolines. (2008) (0)
- Synthesis of 5,5-Disubstituted Butenolides Based on a Pd-Catalyzed γ-Arylation Strategy (2009) (0)
- Cover Picture: Industrial‐Scale Palladium‐Catalyzed Coupling of Aryl Halides and Amines –A Personal Account (Adv. Synth. Catal. 1‐2/2006) (2006) (0)
- Efficient Synthesis of N-Aryl-aza-crown Ethers via Palladium-Catalyzed Amination. (2001) (0)
- Copper‐Catalyzed Domino Halide Exchange‐Cyanation of Aryl Bromides. (2003) (0)
- A Catalytic Method for the Reduction of Esters to Alcohols. (1991) (0)
- Pd-Catalyzed Asymmetric α-Arylation and α-Vinylationof Oxindoles (2009) (0)
- Palladium-Catalyzed Asymmetric Dearomatization (2009) (0)
- A Bulky Biaryl Phosphine Ligand Allows for Palladium‐Catalyzed Amidation of Five‐Membered Heterocycles as Electrophiles. (2012) (0)
- A General Synthesis of End‐Functionalized Oligoanilines via Palladium‐Catalyzed Amination. (2010) (0)
- Suzuki—Miyaura Cross‐Coupling Reactions in Flow: Multistep Synthesis Enabled by a Microfluidic Extraction. (2011) (0)
- Palladium‐Catalyzed Intermolecular Coupling of Aryl Halides and Amides. (2000) (0)
- Synthesis, Characterization, and Reactivity of Zirconocene and Hafnocene Silyl Hydride Complexes. (1992) (0)
- Erratum: Copper-catalysed selective hydroamination reactions of alkynes (2015) (0)
- Monodentate Phosphines Provide Highly Active Catalysts for Pd-Catalyzed C—N Bond-Forming Reactions of Heteroaromatic Halides/Amines and (H)-N-Heterocycles. (2007) (0)
- An Efficient One-Pot Method for the Preparation of Polysubstituted Benzothiophenes. (1989) (0)
- Palladium‐Catalyzed Coupling of Optically Active Amines with Aryl Bromides. (1997) (0)
- A General Method for the Preparation of Zirconocene Complexes of Substituted Benzynes: in situ Generation, Coupling Reactions, and Use in the Synthesis of Polyfunctionalized Aromatic Compounds. (1988) (0)
- Pd‐Catalyzed Cross‐Coupling Reactions of Amides and Aryl Mesylates. (2010) (0)
- Palladium‐Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos. (2009) (0)
- Correction to Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridines. (2012) (0)
- Dynamic Kinetic Resolution in Cu-Catalyzed Conjugate Hydride Addition (2006) (0)
- The Evolution of Pd Citation (2016) (0)
- Enantioselective β‐Arylation of Ketones Enabled by Lithiation/Borylation/1,4‐Addition Sequence under Flow Conditions. (2012) (0)
- Palladium-Catalyzed N-Arylation of 2-Aminothiazoles Citation (2012) (0)
- Synthesis of Substituted Pyrroles via Zirconocene Complexes of Imines. (1989) (0)
- Synthesis, Structure, and Reactivity of a Zirconocene Complex of Cyclobutene. (1990) (0)
- A Combined Zirconocene Benzyne—Palladium Cross‐Coupling Route to Substituted Biphenyls and Terphenyls. (2000) (0)
- Synthesis of Heteroaromatic Amines by C-N Cross-Coupling (2005) (0)
- Palladium‐Catalyzed Amination of Aryl Bromides: Use of Phosphinoether Ligands for the Efficient Coupling of Acyclic Secondary Amines. (1997) (0)
- Improved Functional Group Compatibility in the Palladium-Catalyzed Amination of Aryl Bromides. (2010) (0)
- An Improved Cu‐Based Catalyst System for the Reactions of Alcohols with Aryl Halides. (2008) (0)
- Correction to "Protein-Protein Cross-Coupling via Palladium-Protein Oxidative Addition Complexes from Cysteine Residues". (2020) (0)
- Pd-mediated Arylation of Lysine in Unprotected Peptides (2017) (0)
- Palladium-Catalyzed Intramolecular C-H Difluoroalkylation : Synthesis of Substituted 3 , 3-Difluoro-2-oxindoles Citation (2015) (0)
- Pd‐Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics. (2010) (0)
- Synthesis of Polysubstituted Indoles and Indolines by Means of Zirconocene-Stabilized Benzyne Complexes. (1995) (0)
- A Mild Copper-Catalyzed Amination of Haloarenes (2006) (0)
- Highly Enantioselective Catalytic Pauson‐Khand Type Formation of Bicyclic Cyclopentenones. (1997) (0)
- Palladium-Catalyzed Packed-Bed Continuous-Flow C-NCross-Coupling (2011) (0)
- Accelerating Pd-Catalyzed C — F Bond Formation : Use of a Microflow Packed-Bed Reactor (2012) (0)
- Confronting the Challenging Asymmetric Addition of Vinyl Arene Pronucleophiles into Ketones: Ligand-Controlled Regiodivergent Processes Through a Dearomatized Allyl-Cu Species (2021) (0)
- Palladium‐Catalyzed Intramolecular α‐Arylation of α‐Amino Acid Esters. (2002) (0)
- Synthesis of N-Aryl Benzimidazoles by Pd-Catalyzed Amination-Heteroannulation (2008) (0)
- Catalytic Method for the Reduction of Lactones to Lactols. (1996) (0)
- Regioselective, Directed Meta Acylation of Aromatic Compounds. (1999) (0)
- A Highly Active Catalyst for the Room‐Temperature Amination and Suzuki Coupling of Aryl Chlorides. (1999) (0)
- A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis. (2000) (0)
- Synthesis, Structure, and Reactions of a Zirconocene-Cyclohexyne Complex. (1987) (0)
- Carboxylic Acid Derivatives through Carbonylation of ArylChlorides (2008) (0)
- A Domino Copper-Catalyzed CO CouplingClaisen Rearrangement Process. (2003) (0)
- The Synthesis, Reactions, and Molecular Structure of Zirconocene-Alkyne Complexes. (1987) (0)
- Synthesis of 3,4-Disubstituted Indoles via a Sequential Olefin- Insertion/Ene Route. (1991) (0)
- Palladium‐Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide. (2008) (0)
- Palladium-Catalyzed Stille Cross-Coupling Reaction of Aryl Chlorides Using a Pre-Milled Palladium Acetate and XPhos Catalyst System. (2008) (0)
- Intramolecular Palladium‐Catalyzed Aryl Amination and Aryl Amidation. (1996) (0)
- Copper‐Catalyzed Arylation of β‐Amino Alcohols. (2003) (0)
- Low-Temperature Cross-Coupling of Functionalized Grignard Reagents (2007) (0)
- Analogues de daph et inhibition d'agregation de proteines (2005) (0)
- A Regiospecific Method for the Hydrocyanation of Olefins. (1987) (0)
- The Use of Palladium Chloride as a Precatalyst for the Amination of Aryl Bromides. (2002) (0)
- Industrial-Scale Palladium-Catalyzed Coupling of Aryl Halides and Amines — A Personal Account (2006) (0)
- Continuous-Flow Synthesis of 1-Substituted Benzotriazoles from Chloronitrobenzenes and Amines in a C—N Bond Formation/Hydrogenation/Diazotization/Cyclization Sequence. (2013) (0)
- A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp[superscript 2])-Tosylates and Mesylates (2009) (0)
- N- and C-Arylations of Oxindoles: Orthogonal Selectivityof Pd and Cu Catalysts (2008) (0)
- Pd‐Catalyzed Kumada—Corriu Cross‐Coupling Reactions at Low Temperatures Allow the Use of Knochel‐Type Grignard Reagents. (2007) (0)
- Me[subscript 3](OMe)tBuXPhos: A Surrogate Ligand for Me[subscript 4]tBuXPhos in Palladium-Catalyzed C-N and C-O Bond-Forming Reactions (2012) (0)
- Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C—H Functionalization. (2012) (0)
- A New Method for the Preparation of 3,5-Disubstituted Butenolides. (1988) (0)
- Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst. (1999) (0)
- A Mild General Procedure for the One‐Pot Conversion of Amides to Aldehydes. (1996) (0)
- Stibathiolanes: Synthesis, Solid-State Structure, and Solution Behavior. (2010) (0)
- Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids. (1995) (0)
- Stille Cross‐Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System (2010) (0)
- Kinetic Resolution of Racemic Disubstituted 1-Pyrrolines via Asymmetric Reduction with a Chiral Titanocene Catalyst. (2010) (0)
- Iron(II)‐Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates. (2012) (0)
- Pd-Catalyzed Synthesis of (Het)Ar-SCF3 Compounds (2011) (0)
- The Unexpected Formation of 1,5-Bis(cyclobuta)-3,4,7,8- tetramethylcyclooctatetraene from a Zirconacyclopentadiene (1992) (0)
- Stephen L. Buchwald (2019) (0)
- Rhodium‐Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes. (2010) (0)
- Pd-Catalyzed Carbonylation of Aryl Bromides at AtmosphericPressure (2008) (0)
- Pd/BrettPhos: A Highly Active Catalyst for [nl]C-NCross-Coupling Reactions (2009) (0)
- Synthesis and X-Ray Structure of a Zirconacyclopropene-Alkyne Complex: On the Mechanism of Zirconium-Mediated Reductive Coupling of Alkynes (1993) (0)
- Thorium benzyne: Reactivity of the Cp*{sub 2}Th(C{sub 6}H{sub 4}) moiety with Lewis bases (1993) (0)
- COPPER-CATALYZED HYDROFUNCTIONALIZATION REACTIONS (2018) (0)
- Cobalt—Phosphite-Catalyzed Asymmetric Pauson—Khand Reaction. (2002) (0)
- A New Approach to the Synthesis of the CC-1065/Duocarmycin Pharmacophore. (1993) (0)
- Cis Difunctionalization of Cyclic Olefins with Use of Organozirconium Intermediates. (1991) (0)
- Copper-Catalyzed C-N Bond Coupling Approach to Highly Substituted Oxazoles (2008) (0)
- Synthesis, Structure, and Reactions of (1-Ethoxyethyl)zirconocene Chloride, a Stable Acyclic Secondary Zirconocene Alkyl. (1989) (0)
- Zirconocene Complexes of Unsaturated Organic Molecules (1990) (0)
- Water-Mediated Catalyst Preactivation for Efficient Pd-CatalyzedAminations (2008) (0)
- Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,. beta.-Unsaturated Aldehydes. (1995) (0)
- Catalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines. (2015) (0)
- α-Arylation of Aldehydes Using Electron-Rich ArylHalides (2009) (0)
- Palladium-Catalyzed Heck Alkynylation of Benzyl Chlorides. (2007) (0)
- Carbonylation of Aryl Tosylates and Mesylates (2008) (0)
- Completely N[superscript 1]-Selective Palladium-Catalyzed Arylation of Unsymmetric Imidazoles: Application to the Synthesis of Nilotinib (2011) (0)
- Synthesis of Unsymmetrical Diarylureas via Pd-Catalyzed C—N Cross-Coupling Reactions. (2011) (0)
- A General Method for Suzuki—Miyaura Coupling Reactions Using Lithium Triisopropyl Borates. (2012) (0)
- Heidelberg Forum of Molecular Catalysis Molecular Catalysis (2013) (0)
- Synthesis and X-Ray Crystal Structure of the Zirconocene Complex of a Cyclopentyne and Its Use to Prepare Bicyclic Cyclopentenones. (1990) (0)
- Regio- and Diastereoselective Copper-Catalyzed Allylation of Imines (2016) (0)
- Palladium-Catalyzed Borylation and Homocoupling of Aryl Chlorides (2007) (0)
- Pd‐Catalyzed Synthesis of Ar—SCF3 Compounds under Mild Conditions. (2011) (0)
- Synthesis, Structure, and Reactivity of Trimethylphosphine‐Zirconocene Thioaldehyde Complexes. (1987) (0)
- Enantioselective Allylation from Allene, a Petroleum Cracking Byproduct (2018) (0)
- DETERMINATION OF THE ABSOLUTE CONFIGURATION OF (16O,17O,18O)PHOSPHATE MONOESTERS BY USING PHOSPHORUS-31 NMR (1981) (0)
- Copper‐Catalyzed Trifluoromethylation of Unactivated Olefins. (2012) (0)
- An Improved Catalyst System for Ullmann-Type Couplings between Alcohols and Aryl Halides (2008) (0)
- Copper-Catalyzed Enantioselective Synthesis of Carbo- and Heterocycles (2015) (0)
- Ring-Opening Reactions of Cyclic Allylic Ethers by Zirconocene Complexes of Cyclic Alkynes. (2010) (0)
- Selective N‐Arylation of p ‐Aminophenylalanine in Unprotected Peptides with Organometallic Palladium Reagents (2021) (0)
- Correction to "Palladium-Mediated Incorporation of Carboranes into Small Molecules, Peptides, and Proteins". (2022) (0)
- Palladium–peptide oxidative addition complexes for bioconjugation (2022) (0)
- Palladium-Catalyzed Intramolecular C—O Bond Formation. (2002) (0)
- A Dual Pd- and CuH-Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins (2017) (0)
- Synthesis and Reactions of a Zirconocene‐Benzdiyne Equivalent. (1991) (0)
- Synthesis of Chiral 3-Substituted Indanones via an Enantioselective Reductive Heck Reaction. (2008) (0)
- Palladium-Catalyzed Conversion of Aryl Triflates to ArylFluorides (2010) (0)
- Switching Between N- and O-Arylation of Aminoalcohols (2007) (0)
- Palladium‐Catalyzed Intramolecular C—H Difluoroalkylation: Synthesis of Substituted 3,3‐Difluoro‐2‐oxindoles. (2015) (0)
- Regiospecific Synthesis of N-Alkyl-benzimidazoles from o-Haloanilines (2008) (0)
- Synthesis and Structure of Novel Antimony Thiametallacycles. (1989) (0)
- A Catalytic Method for the Conversion of Silanes to Stannanes. (1995) (0)
- Cu-Catalyzed Domino Synthesis of Indolines (2008) (0)
- Synthesis of Thermochromic Dibismuthines with Nonthermochromic Distibine Analogues. (1993) (0)
- A Highly Active Palladium Catalyst System for the Arylation of Anilines. (1998) (0)
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