Tamio Hayashi

Tamio Hayashi's AcademicInfluence.com Rankings

Tamio Hayashi

Chemistry

#1341

World Rank

#2034

Historical Rank

Organic Chemistry

#155

World Rank

#197

Historical Rank

chemistry Degrees

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Chemistry

Tamio Hayashi's Degrees

PhD Chemistry University of Tokyo
Masters Chemistry University of Tokyo
Bachelors Chemistry University of Tokyo

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Tamio Hayashi's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions. (2003) (1049)
Catalytic asymmetric aldol reaction: reaction of aldehydes with isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex (1986) (563)
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides (1984) (519)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones (1998) (496)
Catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of organoboronic acids. Arylrhodium, oxa-pi-allylrhodium, and hydroxorhodium intermediates. (2002) (410)
tert-Butoxide-mediated arylation of benzene with aryl halides in the presence of a catalytic 1,10-phenanthroline derivative. (2010) (391)
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine–Transition Metal Complexes. I. Preparation of Chiral Ferrocenylphosphines (1980) (348)
A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition. (2003) (334)
C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines. (2004) (308)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine - transition-metal complexes. 8. Palladium-catalyzed asymmetric allylic amination (1989) (248)
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins. (2006) (240)
Catalytic asymmetric arylation of 2,3-dihydrofuran with aryl triflates (1991) (229)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst (1988) (224)
Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens. (2004) (219)
Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst (1991) (213)
Synthesis of optically active 2-(diarylphosphino)-1,1'-binaphthyls, efficient chiral monodentate phosphine ligands (1993) (207)
Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides. (2005) (196)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids and Their Derivatives to Electron Deficient Olefins (2001) (189)
Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst. (1999) (186)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 2. Nickel- and palladium-catalyzed asymmetric Grignard cross-coupling (1986) (184)
Catalytic asymmetric hydroboration of styrenes (1989) (182)
Modification of optically active ferrocenylphosphine ligands for palladium-catalyzed asymmetric allylic alkylation (1986) (180)
Generation of Tertiary Phosphine-Coordinated Pd(0) Species from Pd(OAc)2 in the Catalytic Heck Reaction (1992) (170)
Asymmetric synthesis of (triaryl)methylamines by rhodium-catalyzed addition of arylboroxines to cyclic N-sulfonyl ketimines. (2012) (169)
Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids. (2005) (167)
Asymmetric synthesis catalyzed by transition-metal complexes with functionalized chiral ferrocenylphosphine ligands (1982) (161)
Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran with phenyl triflate. A novel asymmetric catalysis involving a kinetic resolution process (1993) (160)
Catalytic Asymmetric Wacker-Type Cyclization (1997) (158)
Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides. (2006) (158)
Catalytic asymmetric arylative cyclization of alkynals: phosphine-free rhodium/diene complexes as efficient catalysts. (2005) (152)
OPTICALLY ACTIVE ALLYLSILANES. 1. PREPARATION BY PALLADIUM-CATALYZED ASYMMETRIC GRIGNARD CROSS-COUPLING AND ANTI STEREOCHEMISTRY IN ELECTROPHILIC SUBSTITUTION REACTIONS (1982) (151)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 5. Palladium-catalyzed asymmetric allylation of active methine compounds (1988) (149)
Palladium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzosiloles via enantioselective C-H bond functionalization. (2012) (146)
C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines. (2005) (137)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-metal complexes (1988) (135)
Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes (2000) (135)
Asymmetric synthesis of β-hydroxy-α-alkylamino acids by asymmetric aldol reaction of α-isocyanocarboxylates catalyzed by chiral ferrocenylphosphine-gold(I) complexes (1988) (133)
Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines. (2009) (133)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 3. Preparation of optically active allylsilanes by palladium-catalyzed asymmetric Grignard cross-coupling (1986) (132)
Mizoroki-heck-type reaction mediated by potassium tert-butoxide. (2011) (131)
High stereoselectivity in asymmetric Grignard cross-coupling catalyzed by nickel complexes of chiral (aminoalkylferrocenyl)phosphines (1976) (128)
Catalytic asymmetric synthesis of axially chiral biaryls by palladium-catalyzed enantioposition-selective cross-coupling. (1995) (128)
Chiral (.beta.-aminoalkyl)phosphines. Highly efficient phosphine ligands for catalytic asymmetric Grignard cross-coupling (1983) (126)
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine. (2005) (125)
Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds. (2004) (124)
Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents. (2005) (123)
Chiral phosphine-olefin ligands in the rhodium-catalyzed asymmetric 1,4-addition reactions. (2007) (122)
Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates (1999) (121)
Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters. (2009) (120)
Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes. (2016) (119)
A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst. (2002) (119)
Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complexes (1994) (118)
Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates (1986) (117)
Palladium-catalyzed [3 + 3] cycloaddition of trimethylenemethane with azomethine imines. (2006) (117)
Iron-copper cooperative catalysis in the reactions of alkyl Grignard reagents: exchange reaction with alkenes and carbometalation of alkynes. (2012) (114)
Copper-catalyzed asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates. (2011) (114)
Rhodium-catalyzed asymmetric arylation of N-tosyl ketimines. (2010) (112)
Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines. (2015) (112)
Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to α,β-unsaturated esters (1999) (111)
The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes. (2009) (110)
High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates. (2003) (110)
Asymmetric hydrosilylation of olefins catalyzed by a chiral ferrocenylphosphine-palladium complex. Asymmetric synthesis of optically active alcohols and bromides from olefins (1980) (108)
Simple chiral diene ligands provide high enantioselectivities in transition-metal-catalyzed conjugate addition reactions. (2008) (106)
Tandem catalysis of amines using porous graphene oxide. (2015) (106)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine transition metal complexes. 10 gold(i)-catalyzed asymmetric aldol reaction of isocyanoacetate (1992) (105)
Asymmetric catalytic hydrosilylation of ketones preparation of chiral ferrocenylphosphines as chiral ligands (1974) (103)
Retention of Regiochemistry of Allylic Esters in Palladium-Catalyzed Allylic Alkylation in the Presence of a MOP Ligand (1998) (103)
Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds. (2010) (102)
A kinetic study on Rh/binap-catalyzed 1,4-addition of phenylboronic acid to enones: negative nonlinear effect caused by predominant homochiral dimer contribution. (2006) (102)
Optically active allylsilanes. 2. High stereoselectivity in asymmetric reaction with aldehydes producing homoallylic alcohols (1982) (102)
Asymmetric aldol reaction of an isocyanoacetate with aldehydes bychiral ferrocenylphosphine-gold(I) complexes: Design and preparation of new efficient ferrocenylphosphine ligands (1987) (102)
Palladium-catalyzed enantioselective desymmetrization of silacyclobutanes: construction of silacycles possessing a tetraorganosilicon stereocenter. (2011) (101)
Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as mild and reproducible agents for rhodium-catalyzed 1,4-addition reactions. (2007) (101)
Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones. (2008) (101)
Functionalization on silica gel with allylsilanes. A new method of covalent attachment of organic functional groups on silica gel. (2003) (101)
Rhodium-catalyzed enantioselective 1,6-addition of arylboronic acids to enynamides: asymmetric synthesis of axially chiral allenylsilanes. (2010) (100)
Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones. (2007) (99)
Preparation of optically active binaphthylmonophosphines (MOP's) containing various functional groups (1994) (98)
Transition-Metal-Free Coupling Reactions of Aryl Halides (2012) (98)
Iron-catalyzed oxidative coupling of alkylamides with arenes through oxidation of alkylamides followed by Friedel-Crafts alkylation. (2011) (96)
Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes. (2005) (96)
Stereochemistry of oxidative addition of an optically active allyl acetate to a palladium(0) complex (1983) (95)
γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4 + 3] Cycloaddition with Nitrones (2007) (94)
A new entry of nucleophiles in rhodium-catalyzed asymmetric 1,4-addition reactions: addition of organozinc reagents for the synthesis of 2-aryl-4-piperidones. (2004) (94)
Rhodium-catalyzed asymmetric synthesis of spirocarbocycles: arylboron reagents as surrogates of 1,2-dimetalloarenes. (2010) (94)
Hydroxorhodium/chiral diene complexes as effective catalysts for the asymmetric arylation of 3-aryl-3-hydroxyisoindolin-1-ones. (2013) (93)
Rhodium-Catalyzed Asymmetric Addition of Organo-Boron and -Titanium Reagents to Electron-Deficient Olefins (2004) (93)
Rhodium-catalyzed asymmetric 1,6-addition of aryltitanates to enynones giving axially chiral allenes. (2004) (92)
Copper-catalyzed 1,4-addition of organoboronates to alkylidene cyanoacetates: mechanistic insight and application to asymmetric catalysis. (2011) (91)
Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes. (2005) (91)
Asymmetric aldol reaction of α-isocyanocarboxylates with paraformaldehyde catalyzed by chiral ferrocenylphosphine-gold(I) complexes: Catalytic asymmetric synthesis of α-alkylserines (1988) (91)
Optically-Active Ruthenocenylbis(Phosphines) - New Efficient Chiral Phosphine-Ligands for Catalytic Asymmetric Reactions (1994) (90)
Nickel-catalyzed three-component domino reactions of aryl Grignard reagents, alkynes, and aryl halides producing tetrasubstituted alkenes. (2015) (89)
Asymmetric synthesis of diarylmethyl amines by rhodium-catalyzed asymmetric addition of aryl titanium reagents to imines. (2004) (88)
Palladium-catalyzed asymmetric 1,4-disilylation of .alpha.,.beta.-unsaturated ketones: catalytic asymmetric synthesis of .beta.-hydroxy ketones (1988) (88)
Homochiral 2,2′-bis(oxazolyl)-1,1′-binaphthyls as ligands for copper(I)-catalyzed asymmetric cyclopropanation (1996) (88)
Asymmetric construction of chiral C–N axes through rhodium-catalyzed 1,4-addition (2007) (88)
Asymmetric hydrogenation of trisubstituted acrylic acids catalyzed by a chiral (aminoalkyl)ferrocenylphosphine-rhodium complex (1987) (87)
Catalytic asymmetric reactions via π-allylpalladium complexes coordinated with chiral monophosphine ligands ☆ (1999) (87)
Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation. (2013) (87)
Rhodium-catalyzed asymmetric addition of potassium organotrifluoroborates to N-sulfonyl ketimines. (2011) (87)
Stereoselective synthesis of spirooxindoles by palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins. (2009) (87)
High performance of a palladium phosphinooxazoline catalyst in the asymmetric arylation of cyclic N-sulfonyl ketimines. (2014) (86)
A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes. (2003) (86)
Rhodium-catalyzed isomerization of alpha-arylpropargyl alcohols to indanones: involvement of an unexpected reaction cascade. (2005) (85)
Nickel-catalyzed asymmetric grignard cross-coupling of dinaphthothiophene giving axially chiral 1,1'-binaphthyls. (2002) (84)
Asymmetric synthesis of P-stereogenic diarylphosphinites by palladium-catalyzed enantioselective addition of diarylphosphines to benzoquinones. (2014) (84)
Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex (1989) (84)
SILVER(I)-CATALYZED ASYMMETRIC ALDOL REACTION OF ISOCYANOACETATE (1991) (83)
Deuterium-labeling studies establishing stereochemistry at the oxypalladation step in Wacker-type oxidative cyclization of an o-allylphenol. (2004) (83)
Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids. (2006) (82)
Rhodium-catalyzed asymmetric 1,4-addition of 2-alkenyl-1,3,2-benzodioxaboroles to α,β-unsaturated ketones (1998) (82)
High Performance of a Chiral Diene−Rhodium Catalyst for the Asymmetric 1,4-Addition of Arylboroxines to α,β-Unsaturated Ketones (2006) (82)
Catalytic asymmetric construction of morpholines and piperazines by palladium-catalyzed tandem allylic substitution reactions (1993) (80)
Erythro-Selective aldol-type reaction of N-sulfonylaldimines with methyl isocyanoacetate catalyzed by gold(I) (1996) (80)
Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to beta,beta-disubstituted alpha,beta-unsaturated ketones. (2010) (80)
Axially chiral allenylboranes: catalytic asymmetric synthesis by palladium-catalysed hydroboration of but-1-en-3-ynes and their reaction with an aldehyde (1993) (80)
Nickel-catalyzed cross-coupling of silyl enol ethers with grignard reagents. Regio- and stereocontrolled synthesis of olefins (1981) (80)
NEW AMPHIPHILIC PALLADIUM-PHOSPHINE COMPLEXES BOUND TO SOLID SUPPORTS : PREPARATION AND USE FOR CATALYTIC ALLYLIC SUBSTITUTION IN AQUEOUS MEDIA (1997) (79)
Cross-coupling of aryl Grignard reagents with aryl iodides and bromides through S(RN)1 pathway. (2012) (78)
REGIO- AND ENANTIO-SELECTIVE ALLYLIC ALKYLATION CATALYSED BY A CHIRAL MONOPHOSPHINE-PALLADIUM COMPLEX (1997) (78)
Enantioselective [3 + 2] annulation via C–H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes (2013) (78)
Asymmetric synthesis of threo- and erythro-sphingosines by asymmetric aldol reaction of α-isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex (1988) (77)
Rhodium-catalyzed asymmetric 1,6-addition of aryl zinc reagents to dienones. (2005) (77)
Catalytic asymmetric induction of planar chirality by palladium-catalyzed asymmetric cross-coupling of a meso (arene)chromium complex (1993) (77)
Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-heterocyclic carbene ligand. (2007) (77)
Erythroselectivity in addition of γ-substituted allylsilanes to aldehydes in the presence of titanium chloride (1983) (76)
A new type of catalytic tandem 1,4-addition-aldol reaction which proceeds through an (oxa-pi-allyl)rhodium intermediate. (2002) (76)
C2-Symmetric bicyclo[3.3.1]nona-2,6-diene and bicyclo[3.3.2]deca-2,6-diene: new chiral diene ligands based on the 1,5-cyclooctadiene framework (2005) (76)
Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction. (2005) (76)
Palladium-catalyzed asymmetric allylic substitution in aqueous media using amphiphilic resin-supported MOP ligands (1998) (74)
Expanding the C2-symmetric bicyclo[2.2.1]hepta-2,5-diene ligand family: concise synthesis and catalytic activity in rhodium-catalyzed asymmetric addition. (2006) (74)
Asymmetric functionalization of bicycloalkenes by catalytic enantioposition-selective hydrosilylation (1992) (74)
Asymmetric cyclopropanation of alkenes with dimethyl diazomalonate catalyzed by chiral diene-rhodium complexes. (2010) (73)
Enantiomerically pure rhodium complexes bearing 1,5-diphenyl-1,5-cyclooctadiene as a chiral diene ligand. Their use as catalysts for asymmetric 1,4-addition of phenylzinc chloride. (2005) (72)
Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes. (2010) (72)
Palladium-assisted alkylation of olefins (1980) (72)
Palladium-catalyzed asymmetric decarboxylative lactamization of gamma-methylidene-delta-valerolactones with isocyanates: conversion of racemic lactones to enantioenriched lactams. (2008) (71)
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates. (2008) (71)
Palladium-phosphine complex catalyzed cross-coupling reaction of 1-methyl-2-pyrrolyl-magnesium bromide and -zinc chloride with organic halides (1981) (71)
Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates. (2010) (70)
Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation. (2009) (70)
Rhodium-catalyzed asymmetric [5+2] cycloaddition of alkyne-vinylcyclopropanes. (2009) (69)
Optically active cyclic allylsilanes: Preparation by asymmetric hydrosilylation and anti stereochemistry in SE' reactions☆ (1983) (69)
Asymmetric Hydrosilylation of 1-Alkenes Catalyzed by Palladium-MOP (1995) (68)
Control of reactive site in palladium-catalyzed Grignard cross-coupling of arenes containing both bromide and triflate (1997) (68)
Asymmetric allylic amination catalyzed by chiral ferrocenylphosphine-palladium complexes (1990) (68)
Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis (2012) (68)
Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines. (2006) (68)
Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides (2005) (68)
Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines via enantioselective transmetalation. (2012) (67)
Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones. (2007) (67)
Palladium-catalyzed desymmetrization of silacyclobutanes with alkynes: enantioselective synthesis of silicon-stereogenic 1-sila-2-cyclohexenes and mechanistic considerations. (2012) (67)
Reduction of alkynes into 1,2-dideuterioalkenes with hexamethyldisilane and deuterium oxide in the presence of a palladium catalyst. (2005) (67)
Highly diastereoselective aldol reaction of fluoroalkyl aryl ketones with methyl isocyanoacetate catalyzed by silver(I)/triethylamine (1994) (67)
Gold(I)-catalyzed asymmetric aldol reactions of fluorinated benzaldehydes with an α-isocyanoacetamide (1994) (66)
Optically active 2,2′-bis(diphenylphosphinomethyl)-1,1′-binaphthyl: a new chiral bidentate phosphine ligand for transition-metal complex catalyzed asymmetric reactions (1977) (66)
Cobalt-catalyzed asymmetric 1,6-addition of (triisopropylsilyl)-acetylene to α,β,γ,δ-unsaturated carbonyl compounds. (2012) (66)
Palladium-catalyzed asymmetric alkenylation of cyclic olefins (1993) (66)
Rhodium-catalyzed asymmetric 1,4-addition of arylboron compounds generated in situ from aryl bromides (1999) (65)
Chiral β-dimethylaminoalkylphosphines. Highly efficient ligands for a nickel complex catalyzed asymmetric grignard cross-coupling reaction (1980) (65)
Rhodium-catalyzed asymmetric 1,4-addition of aryltitanium reagents generating chiral titanium enolates: isolation as silyl enol ethers. (2002) (64)
Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones. (2007) (64)
CATIONIC PALLADIUM/BOXAX COMPLEXES FOR CATALYTIC ASYMMETRIC WACKER-TYPE CYCLIZATION (1998) (63)
Rhodium-catalyzed Synthesis of Indenols by Regioselective Coupling of Alkynes with Ortho-carbonylated Arylboronic Acids (2005) (63)
Rhodium-catalyzed asymmetric addition of arylboronic acids to beta-phthaliminoacrylate esters toward the synthesis of beta-amino acids. (2010) (63)
Effect of chiral diene ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated sulfonyl compounds. (2012) (63)
A cationic rhodium-chiral diene complex as a high-performance catalyst for the intramolecular asymmetric [4+2] cycloaddition of alkyne-1,3-dienes. (2007) (63)
Enantioselective synthesis of α-tri- and α-tetrasubstituted allylsilanes by copper-catalyzed asymmetric allylic substitution of allyl phosphates with silylboronates. (2013) (63)
Rhodium-catalyzed multicomponent-coupling reactions involving a carborhodation-cross-coupling sequence. (2006) (63)
Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes. (2007) (62)
Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane. (2005) (62)
Gold(I)-catalyzed asymmetric aldol reaction of methyl isocyanoacetate with fluorinated benzaldehydes (1994) (61)
Chiral diene-phosphine tridentate ligands for rhodium-catalyzed asymmetric cycloisomerization of 1,6-enynes. (2011) (61)
Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes. (2008) (61)
Design and Preparation of 3,3'-Disubstituted 2,2'-Bis(oxazolyl)-1,1'-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization. (1999) (60)
Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines. (2013) (60)
Asymmetric cyclization of 2-butenylene dicarbamates catalyzed by chiral ferrocenylphosphine-palladium complexes: Catalytic asymmetric synthesis of optically active 2-amino-3-butenols (1988) (59)
Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step. (2002) (59)
CATALYTIC ASYMMETRIC HYDROSILYLATION OF KETONES WITH NEW CHIRAL FERROCENYLPHOSPHINE-IMINE LIGANDS (1995) (59)
Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with a C2-Symmetric Tetrafluorobenzobarrelene Ligand (2009) (59)
A New Approach to Axially Chiral Bipyridine N,N′-Dioxides Bearing Aromatic Substituents and their Use for Catalytic Asymmetric Allylation of Aldehydes with Allyl(trichloro)silane (2004) (59)
Transition Metal/Base-Catalyzed Aldol Reactions of Isocyanoacetic Acid Derivatives with Prochiral Ketones, a Straightforward Approach to Stereochemically Defined β,β-Disubstituted-β-hydroxy-α-amino Acids.1 Scope and Limitations (1997) (59)
Organocatalytic asymmetric Mannich-type reaction of N-sulfonylimines with isocyanoacetate leading to optically active 2-imidazoline-4-carboxylates (2010) (58)
Palladium(0)-catalyzed hydroboration of 1-buten-3-ynes: preparation of allenylboranes (1992) (58)
Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage. (2008) (58)
Palladium-catalyzed decarboxylative [4 + 3] cyclization of gamma-methylidene-delta-valerolactones with 1,1-dicyanocyclopropanes. (2009) (58)
Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base (1992) (57)
Synthesis and application of novel chiral phosphino-oxazoline ligands with 1,1′-binaphthyl skeleton (1998) (57)
Asymmetric synthesis of 2-amino-1-arylethanols by catalytic asymmetric hydrogenation (1979) (57)
Rhodium-catalyzed asymmetric synthesis of indanones: development of a new "axially chiral" bisphosphine ligand. (2006) (57)
Gold(I)-catalyzed asymmetric aldol reactions of isocyanoacetic acid derivatives with fluoroaryl aldehydes (1996) (57)
Synthesis of 2,5-Bis(binaphthyl)phospholes and Phosphametallocene Derivatives and Their Application in Palladium-Catalyzed Asymmetric Hydrosilylation (2006) (57)
Rhodium-catalyzed asymmetric 1,4-addition of sodium tetraarylborates to β,β-disubstituted α,β-unsaturated esters. (2011) (57)
Catalytic asymmetric arylation of N-substituted 2-pyrrolines with aryl triflates (1992) (57)
Palladium-Catalyzed Synthesis of Spiro[2.4]heptanes: Ligand-Dependent Position Control in the Nucleophilic Attack to a π-Allylpalladium Intermediate (2007) (56)
Allylic substitution in water catalyzed by amphiphilic resin-supported palladium-phosphine complexes (1999) (56)
Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes. (2012) (56)
Selective mono-alkylation and arylation of aromatic dihalides by palladium-catalyzed cross-coupling with the Grignard and organozinc reagents (1980) (56)
Rhodium-Catalyzed Addition of Arylzinc Reagents to Aryl Alkynyl Ketones: Synthesis of β,β-Disubstituted Indanones (2005) (56)
A chiral (hydroxyalkylferrocenyl)phosphine ligand. Highly stereoselective catalytic asymmetric hydrogenation of prochiral carbonyl compounds (1976) (56)
Asymmetric aldol reaction of α-isocyanoacetamides with aldehydes catalyzed by a chiral ferrocenylphosphine-gold(I) complex (1988) (55)
A New Reactive System for Catalytic Bis-Silylation of Acetylenes and Olefins (1994) (55)
Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes. (2009) (55)
Asymmetric synthesis of axially chiral 1,1′:5′,1″- and 1,1′:4′,1″-ternaphthalenes by asymmetric cross-coupling with a chiral ferrocenylphosphine-nickel catalyst (1989) (55)
Fluorinated polysilanes. palladium-catalyzed disilane metathesis, double silylation of acetylenes, and the stereo chemical course (1976) (55)
Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling reaction of a secondary alkyl grignard reagent with organic halides (1979) (55)
π-Allylpalladium-Mediated Catalytic Synthesis of Functionalized Allenes (2000) (54)
Asymmetric synthesis of axially chiral biaryls by nickel-catalyzed grignard cross-coupling of dibenzothiophenes. (2004) (54)
Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex. (2006) (54)
Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones. (2008) (54)
Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water. (2004) (53)
Catalytic asymmetric induction of planar chirality : palladium-catalyzed asymmetric cross-coupling of meso tricarbonyl(arene) chromium complexes with alkenyl- and arylboronic acids (1994) (53)
A new route to methyl (R,E)-(-)-tetradeca-2,4,5-trienoate (pheromone of Acanthoscelides obtectus) utilizing a palladium-catalyzed asymmetric allene formation reaction. (2005) (53)
Palladium‐Catalyzed Heck and Carbonylation Reactions of a Dinaphthaleneiodonium Salt Forming Functionalized 2‐Iodo‐1,1′‐binaphthyls (2004) (53)
Metathesis route to bridged metallocenes. (2002) (53)
Regio- and stereo-chemistry in allylation of aryl Grignard reagents catalyzed by phosphine-nickel and -palladium complexes☆ (1985) (53)
Cross-Coupling of Enol Phosphates with Trimethylsilylmethylmagnesium Halides Catalyzed by Nickel or Palladium Complexes; A Selective Synthesis of Allylsilanes (1981) (52)
A new cine-substitution of alkenyl sulfones with aryltitanium reagents catalyzed by rhodium: mechanistic studies and catalytic asymmetric synthesis of allylarenes. (2003) (52)
Asymmetric hydrosilylation of dihydrofurans by use of palladium-MOP catalyst (1993) (51)
CROSS-COUPLING OF TERTIARY ALKYL GRIGNARD REAGENTS WITH β-BROMOSTYRENE CATALYZED BY DICHLORO[1,1′-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) (1980) (51)
Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: protonation as a key step. (2013) (50)
Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]2 (2007) (50)
Asymmetric Cross-coupling of Organozinc Reagents with Alkenyl Bromides Catalyzed by a Chiral Ferrocenylphosphine-Palladium Complex (1983) (50)
Asymmetric 1,4‐Addition of Organoboron Reagents to Quinone Monoketals Catalyzed by a Chiral Diene/Rhodium Complex: A New Synthetic Route to Enantioenriched 2‐Aryltetralones (2007) (49)
Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Chirality Transfer to Stereogenic Carbon Centers in SE‘ Reactions (2003) (49)
Asymmetric aldol reaction of α-ketoesters with isocyanoacetate and isocyanoacetamide catalyzed by a chiral ferrocenylphosphine-gold(I) complex (1989) (49)
Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines (2001) (49)
Kinetic Studies Prove High Catalytic Activity of a Diene–Rhodium Complex in 1,4‐Addition of Phenylboronic Acid to α,β‐Unsaturated Ketones (2006) (48)
2,2‘-Bis(diphenylphosphino)-1,1‘-biphenyl: New Entry of Bidentate Triarylphosphine Ligand to Transition Metal Catalysts (2000) (48)
Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution. (2011) (48)
Asymmetric hydrogenation catalyzed by a chiral ferrocenylphosphine-rhodium complex (1976) (48)
Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene–Rhodium Complex (2005) (47)
Catalytic asymmetric hydrosilylation of ketones : II. Chiral phosphinerhodium complex-catalyzed hydrosilylation (1976) (47)
Asymmetric synthesis of bifunctional organosilicon compounds via hydrosilylation (1974) (47)
A Novel Chiral Phosphino−Phosphaferrocene: Its Coordination Behavior and Application to Palladium-Catalyzed Asymmetric Allylic Alkylation (2001) (47)
Tuning the chiral environment of C2-symmetric diene ligands: development of 3,7-disubstituted bicyclo[3.3.1]nona-2,6-dienes. (2009) (46)
Kinetic resolution of racemic allyl acetates in asymmetric allylic alkylation catalysed by a chiral ferrocenylphosphine–palladium complex (1986) (45)
Immobilization of chiral phosphine ligands on silica gel by means of the allylsilane method and their use for catalytic asymmetric reactions (2004) (45)
Highly Selective 1,6‐Addition of Aryl Boronic Acids to α,β,γ,δ‐Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex (2006) (45)
Generation of Chiral Boron Enolates by Rhodium-Catalyzed Asymmetric 1,4-Addition of 9-Aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to α,β-Unsaturated Ketones (2003) (45)
NMR studies of the gold(I)-catalyzed asymmetric aldol reaction of isocyanoacetate (1990) (45)
Enantioposition-selective arylation of biaryl ditriflates by palladium-catalyzed asymmetric Grignard cross-coupling (1999) (45)
Asymmetric Conjugate Alkynylation of Cyclic α,β-Unsaturated Carbonyl Compounds with a Chiral Diene Rhodium Catalyst. (2016) (44)
Catalytic asymmetric synthesis of β-hydroxy ketones by palladium-catalyzed asymmetric 1,4-disilylation of α,β-unsaturated ketones (1994) (44)
Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones. (2011) (44)
Optically active allylsilanes. 4. Enantioselective allylation of aldehydes with an optically active allylsilane (1983) (44)
Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols. (2009) (44)
Asymmetric [3 + 2] cycloaddition of 2-(sulfonylmethyl)-2-propenyl carbonate catalyzed by chiral ferrocenylphosphine-palladium complexes (1989) (44)
Bipyridyl-based diphosphine as an efficient ligand in the rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to α,β-unsaturated ketones (2003) (44)
Enantioposition-selective alkynylation of biaryl ditriflates by palladium-catalyzed asymmetric cross-coupling (1996) (44)
Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids (2008) (44)
The origins of enantioselectivity in Rh-diene complex catalysed arylation of cyclohex-2-enones. (2012) (44)
Palladium-catalysed asymmetric hydrosilylation of styrenes with a new chiral monodentate phosphine ligand (1995) (44)
Modification of Chiral Monodentate Phosphine Ligands (MOP) for Palladium‐Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3‐Dienes (2001) (44)
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines. (2011) (43)
Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides. (2012) (43)
Asymmetric Hydrosilylation of Olefins Catalyzed by MOP-Palladium Complexes (1996) (43)
Preparation of optically active allylsilanes by catalytic asymmetric hydrosilylation of 1-arylbutadienes1 (1985) (42)
Rhodium‐Catalyzed Aryl Transfer from Trisubstituted Aryl Methanols to α,β‐Unsaturated Carbonyl Compounds (2007) (42)
Enantioselective synthesis of 1-metallocenylalkanols by catalytic asymmetric alkylation of metallocenecarboxaldehydes with dialkylzincs (1993) (42)
Mechanistic investigation of the palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isocyanates: kinetic studies and origin of the site selectivity in the nucleophilic attack at a (pi-allyl)palladium. (2010) (41)
Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones. (2012) (41)
Rhodium-catalyzed asymmetric arylation of azomethine imines. (2010) (41)
Asymmetric homogeneous hydrosilylation with platinum(II) complexes of chiral phosphines (1971) (41)
Asymmetric hydrosilylation of ketones catalyzed by chiral phosphine—platinum(II) complexes (1972) (40)
Insertion of alkenes into a palladium–acetyl bond (1991) (40)
Stereochemistry and mechanism of asymmetric allylation of aldehydes with optically active allylsiliconates (1988) (40)
Regio- and enantioselective hydrosilylation of 1-arylalkenes by use of palladium-MOP catalyst (1993) (39)
Palladium-catalyzed asymmetric intramolecular allylation forming optically active vinylcyclopropane and vinyldihydrofurans (1988) (39)
Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene. (2002) (39)
Anti stereochemistry in protodesilylation of an optically active allylsilane with trifluoroacetic acid-D (1982) (39)
Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides (2013) (39)
Dichloro[(2-dimethylamino)propyldiphenylphosphine]palladium(II) (PdCl2(alaphos)): An Efficient Catalyst for Cross-Coupling of Aryl Triflates with Alkynyl Grignard Reagents1 (1998) (39)
New chiral ligands designed for palladium-catalysed asymmetric allylic alkylation (1982) (38)
Optically active allylsilanes. 8. Stereochemistry in the reaction of optically active allylsilanes with m-chloroperoxybenzoic acid (1984) (38)
Rhodium-catalyzed asymmetric arylation of allyl sulfones under the conditions of isomerization into alkenyl sulfones. (2015) (38)
Palladium/chiral phosphine–olefin complexes: X-ray crystallographic analysis and the use in catalytic asymmetric allylic alkylation (2005) (38)
Iron-catalyzed aryl- and alkenyllithiation of alkynes and its application to benzosilole synthesis. (2011) (38)
Synthesis and Characterization of a Novel Chiral Phosphole and Its Derivatives (2001) (37)
Asymmetric aza-Claisen rearrangement of allyl imidates catalyzed by homochiral cationic palladium(II) complexes (1998) (37)
Catalytic asymmetric synthesis of optically active alcohols via hydrosilylation of olefins with a chiral monophosphine-palladium catalyst (1992) (37)
Asymmetric hydrosilylation of cyclic 1,3-dienes catalyzed by an axially chiral monophosphine-palladium complex (1996) (37)
Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates. (2013) (37)
Dynamic Kinetic Resolution in Rhodium-Catalyzed Asymmetric Arylation of Phospholene Oxides. (2017) (37)
Catalytic asymmetric cross-coupling (2002) (36)
Guiding the nitrogen nucleophile to the middle: palladium-catalyzed decarboxylative cyclopropanation of 2-alkylidenetrimethylene carbonates with isocyanates. (2011) (36)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes: VII. New chiral ferrocenylphosphines with C2 symmetry☆ (1989) (36)
A new chiral ferrocenylphosphine ligand with C2 symmetry: prepration and use for palladium-catalysed asymmetric cross-coupling (1989) (35)
Asymmetric synthesis of allylsilanes by palladium-catalyzed asymmetric reduction of allylic carbonates with formic acid☆ (1994) (35)
Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes (2010) (34)
Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates. (2018) (34)
Palladium-catalyzed allylation of α-isocyanocarboxylates (1987) (34)
Catalytic asymmetric hydrogenation of β-disubstituted α-phenylacrylic acids asymmetric synthesis of carboxylic acids containing two vicinal chiral carbon centers (1988) (34)
Catalytic asymmetric hydrosilylation of 1,3-dienes with new chiral ferrocenylphosphine-palladium complexes (1990) (34)
Single-electron-transfer-induced coupling of arylzinc reagents with aryl and alkenyl halides. (2014) (34)
Palladium-Catalyzed Enantioselective Carbonylative Cyclization of Aryl and Alkenyl Triflates with Carbon Monoxide (1999) (34)
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to chromones: a highly enantioselective pathway for accessing chiral flavanones. (2015) (34)
Regioselective allylation of a grignard reagent catalysed by phosphine–nickel and –palladium complexes (1981) (34)
Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes. (2008) (34)
Rhodium-catalyzed asymmetric conjugate addition of arylboroxines to borylalkenes: asymmetric synthesis of β-arylalkylboranes. (2010) (33)
Preparation and use of chiral ferrocenylphosphines containing new alkyl substituents on the ferrocenylmethyl position (1995) (33)
Asymmetric double hydroboration of 1,3-dienes catalyzed by chiral phosphine-rhodium complexes (1991) (33)
Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes. (2007) (33)
Palladium(0)-catalyzed cyclization of 2-butenylene dicarbamates forming 4-vinyl-2-oxazolidones (1987) (33)
REDUCTIVE ELIMINATION OF CIS-PTME(SIPH3)(PMEPH2)2 (1994) (32)
Synthesis of quaternary carbon stereocenters by copper-catalyzed asymmetric allylic substitution of allyl phosphates with arylboronates. (2014) (32)
Silver-catalyzed alkyl-alkyl homo-coupling of Grignard reagents (2005) (32)
Palladium-catalyzed silylation of alcohols with hexamethyldisilane. (2006) (32)
Effects of Bidentate Phosphine Ligands on syn−anti Isomerization in π-Allylpalladium Complexes (2002) (31)
Palladium(II) assisted alkylation of olefins with stabilized carbanions (1977) (31)
Asymmetric conjugate addition of cis-2-arylethenylboronic acids catalyzed by chiral diene/rhodium complexes: 1,4-rhodium shift from alkenylrhodium to arylrhodium intermediates (2012) (31)
Rhodium-catalyzed asymmetric 1,4-addition of alkenylsilanes generated by hydrosilylation of alkynes: a one-pot procedure where a rhodium/(S)-binap complex catalyzes the two successive reactions (2004) (31)
Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes. (2013) (30)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes: IX. Preparation of chiral ferrocenylbisphosphines containing an aminoalkyl side chain (1991) (30)
Base-Free Conditions for Rhodium-Catalyzed Asymmetric Arylation To Produce Stereochemically Labile α-Aryl Ketones. (2016) (30)
Asymmetric hydrosilylation of ketones catalyzed by a chiral cationic rhodium complex (1973) (30)
Iridium-catalyzed [3 + 2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition. (2007) (30)
Synthesis of nine-membered azlactones by palladium-catalyzed ring-expansion of γ-methylidene-δ-valerolactones with aziridines. (2011) (30)
New chiral phosphine ligands containing (η6-arene)chromium and catalytic asymmetric cross-coupling reactions (1992) (29)
Interaction of silanes with bis(triphenylphosphine)ethyleneplatinum(0); hydrosilylation of olefins with this complex (1971) (29)
Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines (2008) (29)
Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents. (2013) (29)
Transition metal-catalyzed diastereoselective aldol reactions of prochiral ketones with methyl isocyanoacetate (1996) (29)
Highly enantioselective 1,4-addition of arylzinc reagents to 3-arylpropenals catalyzed by a rhodium–binap complex in the presence of chlorotrimethylsilane (2006) (29)
A New Optically Active Monodentate Phosphine Ligand, (R)-(+)-3-Diphenylphosphino-3′-methoxy-4,4′-biphenanthryl (MOP-phen): Preparation and Use for Palladium-Catalyzed Asymmetric Reduction of Allylic Esters with Formic Acid (1994) (29)
C2-Symmetric tetrafluorobenzobarrelenes as highly efficient ligands for the iridium-catalyzed asymmetric annulation of 1,3-dienes with 2-formylphenylboron reagents (2008) (29)
Palladium- or nickel-catalyzed cross-coupling of organotitanium reagents with aryl triflates and halides (2002) (28)
Palladium-catalyzed Decarboxylative [4 + 1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides (2009) (28)
Cyclization of o-Allylstyrene via Hydrosilylation: Mechanistic Aspects of Hydrosilylation of Styrenes Catalyzed by Palladium-Phosphine Complexes. (1998) (28)
Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes. (2010) (28)
Iron-catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds (2011) (28)
Rhodium-Catalyzed Enantioposition-Selective Hydroarylation of Divinylphosphine Oxides with Aryl Boroxines. (2018) (27)
Rhodium(I)‐Catalyzed Asymmetric Addition of Organometallic Reagents to Electron‐Deficient Olefins (2005) (27)
Ruthenium-catalyzed transformation of alkenyl triflates to alkenyl halides. (2009) (27)
Stereoselective synthesis of nipecotic acid derivatives via palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with imines. (2009) (27)
Asymmetric total synthesis of optically active α-curcumene (1979) (27)
1 Rhodium- and Palladium-Catalyzed Asymmetric Conjugate Additions (2010) (26)
Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters. (2011) (26)
Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates. (2007) (26)
Fe-Cu cooperative catalysis in the isomerization of alkyl Grignard reagents. (2008) (26)
Synthesis of 1,1‘-Diphospha[4]ferrocenophanes by Molybdenum-Catalyzed Ring-Closing Metathesis (2003) (26)
Modified Amino Acid-Derived Phosphine-Imine Ligands for Palladium-Catalyzed Asymmetric Arylation of Cyclic N-Sulfonyl Imines (2017) (26)
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes: IV. Crystal structure of dichloro[N,N-dimethyl-1-[1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine]palladium(II) (PdCl2[BPPFA]) (1987) (26)
Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. (2006) (25)
Palladium-Catalyzed Asymmetric Reduction of Racemic Allylic Esters with Formic Acid: Effects of Phosphine Ligands on Isomerization of π-Allylpalladium Intermediates and Enantioselectivity (2000) (25)
Palladium-catalyzed 1, 4-disylation of α, β-unsaturated ketones with 1, 1-dichloro-1-phenyl-2,2,2-trimethyldisilane (1988) (25)
Catalytic asymmetric hydrosilylation of ketones: I. Chiral phosphine-platinum(II) complex-catalyzed hydrosilylation. (1976) (24)
Preparation of New Ferrocenylmonophosphine Ligands Containing Two Planar Chiral Ferrocenyl Moieties and Their Use for Palladium‐Catalyzed Asymmetric Hydrosilylation of 1,3‐Dienes (2002) (24)
Rhodium/Chiral Diene-Catalyzed Asymmetric Cyclopolymerization of Achiral 1,8-Diynes (2011) (24)
Palladium-catalysed asymmetric hydroalkenylation of norbornene (1994) (24)
Stereochemistry of the reaction of an optically active π-allylpalladium complex with nucleophiles (1984) (24)
Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes (2010) (23)
CATALYTIC ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE ALKENES BY PALLADIUM-CATALYSED ASYMMETRIC REDUCTION OF RACEMIC ALLYLIC ESTERS WITH FORMIC ACID (1996) (23)
Palladium-catalyzed conjugate reduction of enones into α,β-dideuterioketones with hexamethyldisilane and deuterium oxide (2007) (23)
Enantioselective Synthesis of 3,3'-Diaryl-SPINOLs: Rhodium-Catalyzed Asymmetric Arylation/BF3 -Promoted Spirocyclization Sequence. (2019) (23)
Asymmetric allylic alkylation of 1,3-disubstituted 2-propenyl acetates catalyzed by a chiral ferrocenylphosphine-palladium complex (1987) (23)
Preparation of silafunctional allylsilanes by palladium-catalyzed silylation of allylic chlorides with 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane (1993) (22)
Asymmetric grignard cross-coupling by means of polymer-supported optically active β-dimethylaminoalkylphosphine-nickel catalysts (1980) (22)
Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to α,β-unsaturated ketones (2004) (22)
Regiocontrol in palladium-catalysed allylic alkylation by addition of lithium iodide (1998) (22)
Palladium-Catalyzed Asymmetric Allylic Alkylations of Colby Pro-Enolates with MBH Carbonates: Enantioselective Access to Quaternary C-F Oxindoles. (2018) (22)
Iron-catalyzed carbolithiation of alkynes having no heteroatoms. (2009) (22)
Axially chiral monophosphine ligands (MOPs) and their use for palladium-catalyzed asymmetric hydrosilylation of olefins (2000) (21)
Palladium-catalyzed synthesis of 4-oxaspiro[2.4]heptanes via central attack of oxygen nucleophiles to π-allylpalladium intermediates. (2012) (21)
Palladium-Catalyzed Asymmetric Arylation of Trifluoromethylated/Perfluoroalkylated 2-Quinazolinones with High Enantioselectivity. (2016) (21)
An optically active propargylsilane: Preparation by asymmetric grignard cross-coupling and stereochemistry in an electrophilic substitution (1983) (21)
Cobalt-catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents (2008) (21)
Selective 1,4-Hydroboration of Phenyl 1-Alkenyl Ketones with 9-Borabicyclo [3.3.1]nonane and Catecholborane Forming Boron (Z)-Enolates (1991) (20)
Chirality transfer from optically active allylsilanes to π-allylpalladium complexes (1983) (19)
γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones (2008) (19)
Synthesis of enantiomerically pure P-stereogenic diphosphacrowns and their palladium complexes. (2011) (19)
Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. o-Methoxyarylation through 1,4-Rhodium Shift. (2016) (19)
Rhodium-catalyzed aryl- and alkylation-oligomerization of alkynoates with organoboron reagents giving salicylates. (2010) (19)
Redox Catalysis of Halide Ion for Formal Cross-dehydrogenative Coupling: Bromide Ion-catalyzed Direct Oxidative α-Acetoxylation of Ketones (2010) (19)
Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst (2002) (18)
Palladium Catalysts for Cross-Coupling of Ortho-Substituted Aryl Triflates with Grignard Reagents (1997) (18)
Rhodium-catalyzed Asymmetric 1,4- Addition of 3-Thiopheneboronic Acid to a,b-Unsaturated Carbonyl Compounds (2003) (18)
Selective synthesis of (E)-crotylsilanes by reaction of crotylmagnesium bromide with hydrosilanes in the presence of dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II) (1984) (17)
Kinetic resolution of racemic Grignard reagents by nickel-catalyzed asymmetric Grignard cross-coupling (1981) (17)
Preparation of (R)-N,N-dimethyl-1-(2-(diphenylphosphino)ferrocenyl)-2-propanamines and asymmetric Grignard cross-coupling catalyzed by nickel complexes with the phosphine ligands. (1981) (17)
Palladium catalyzed allylic alkylation of olefins (1978) (17)
Synthesis and Characterization of 1,1‘-Diphospharuthenocenes (2002) (17)
Palladium-catalyzed asymmetric hydrosilylation of styrenes with trichlorosilane (2014) (17)
Induction of Atropisomeric Chirality on Heavily Substituted Phosphametallocenes (2003) (17)
Palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary carbon stereocenter. (2012) (17)
Optically active allylsilanes. II. Stereochemistry in electrophilic substitution (SE') reactions of optically active allylfluorosilanes (1987) (16)
Ruthenium-catalyzed 1,4-Addition of Organoboronic Acids to α,β-Unsaturated Ketones (2008) (16)
5 – Asymmetric Coupling Reactions (1985) (15)
Synthesis of Planar Chiral Shvo Catalysts for Asymmetric Transfer Hydrogenation (2016) (15)
Stereochemistry in Palladium-Catalyzed Cyclization Forming a Vinyldihydrofuran via a pi-Allylpalladium Intermediate. (1997) (15)
Cross-coupling reaction of secondary alkyl grignard reagents with allylic alcohols catalyzed by dichloro[1,1′-bis(diphenylphosphino)-ferrocene]palladium(II) (1980) (15)
Synthesis of Arylacetaldehydes by Iridium-Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids. (2019) (15)
Synthesis, circular dichroism, and absolute stereochemistry of 1,1′:4′,1′-ternaphthalene compounds (1997) (15)
Selective Synthesis of (Z)-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes (1990) (14)
Rhodium‐ and Palladium‐Catalyzed Asymmetric Conjugate Additions of Organoboronic Acids (2011) (14)
Rhodium-Catalyzed Arylzincation of Alkynes: Ligand Control of 1,4-Migration Selectivity. (2018) (13)
Palladium(Ti)-Catalyzed Claisen Rearrangement of 1-Phenylethenyl 2-Propenyl Ethers (1989) (13)
Novel Palladium Chiral Phosphinooxazoline Complexes: Crystal Strucutre Studies and Application to Asymmetric Heck Reaction (2000) (13)
Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes (2001) (13)
Palladium-catalyzed intramolecular decarboxylative allylic arylation of alpha-aryl-gamma-methylidene-delta-valerolactones. (2010) (13)
Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands (2007) (13)
Palladium-Catalyzed Synthesis of Butatrienes (2000) (12)
Platinum-Catalyzed Addition of Dimethylsilylene to β-Methyl α,β-Unsaturated Ketones: γ-Silylation Forming 1-Oxa-2-silacyclohex-5-enes (2007) (12)
Asymmetric hydrosilylation of cyclohexa-1,3-diene with trichlorosilane by palladium catalysts coordinated with chiral phosphoramidite ligands (2013) (12)
A new asymmetric grignard cross-coupling reaction via an alkyl group isomerization catalyzed by chiral phosphine-nickel complexes (1977) (12)
Platinum-catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β-Unsaturated Ketones (2008) (12)
MOP: A Monodentate Chiral Phosphine Ligand for Catalytic Asymmetric Reactions. (1994) (12)
A chiral phosphine–olefin ligand derived from l-hydroxyproline and its use in the rhodium-catalyzed asymmetric 1,4-addition (2015) (11)
Improved Procedure for Single-electron-transfer-induced Grignard Cross-coupling Reaction (2014) (11)
Palladium-catalyzed asymmetric allylic alkylation with an indenide (2004) (11)
Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide. (2017) (11)
(S)-Phenylalanine-derived chiral phosphorus–olefin ligands in rhodium-catalyzed asymmetric 1,4-addition reactions (2012) (11)
C–E Bond Formation through Asymmetric Hydrosilylation of Alkenes (2007) (11)
Catalytic asymmetric hydrosilylation of olefins – catalytic asymmetric synthesis of alcohols with high enantiomeric purity (1999) (11)
Asymmetric synthesis (1998) (11)
Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex. (1987) (10)
Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboroxines to β,β‐Disubstituted α,β‐Unsaturated Ketones. (2010) (10)
Chiral Diene Ligands in Asymmetric Catalysis. (2010) (10)
Palladium-catalyzed asymmetric allylic substitution with a cyclopentadienide: asymmetric synthesis of metallocenes (2003) (10)
Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene‐Catalyzed 1,4‐Addition to β,β‐Disubstituted α,β‐Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters. (2010) (10)
Platinum-catalyzed 1,4-Addition of Arylboronic Acids to β-Substituted α,β-Unsaturated Ketones (2008) (10)
Rhodium(I)/Chiral Diene-Catalyzed Enantioselective Addition of Boronic Acids to N-Unsubstituted Isatin-Derived Ketimines. (2020) (10)
Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine (2012) (10)
Catalytic asymmetric elimination forming chiral 1,3-dienes via π-allylpalladium intermediate (1991) (10)
Rhodium-Catalyzed Diverse Arylation of 2,5-Dihydrofuran: Controllable Divergent Synthesis via Four Pathways (2020) (9)
Intermolecular interaction between multifunctional porphyrin and ubiquinone analogues (1994) (9)
1,1,1-Trichloro-2,2,2-trimethyldisilane: reagent for stereospecific silylation of π-allylpalladium complexes (1987) (9)
Rhodium-catalyzed asymmetric 1,4-addition of organometallic reagents (2003) (8)
Rhodium-catalyzed oxidative alkynylation of acrylate esters with propargylic alcohols (2011) (8)
Asymmetric Allylic Substitution and Grignard Cross-Coupling (1994) (8)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones. (1998) (8)
(R)‐2‐Diphenylphosphino‐2′‐Methoxy‐1,1′‐Binaphthyl (2003) (8)
(R)-3-phenylcyclohexanone (2002) (8)
Ruthenium-catalyzed reaction of alkenyl triflates with zinc thiolates (2011) (8)
Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates (2018) (8)
Cross-Coupling of Aryl Grignard Reagents with Aryl Iodides and Bromides Through SRN1 Pathway. (2012) (7)
Catalytic Asymmetric Conjugate Arylation of γ,δ-Unsaturated β-Dicarbonyl Compounds. (2018) (7)
Anti stereochemistry in SE" reaction of an optically active 2,4-dienylsilane. (1987) (7)
Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates. (2002) (7)
Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the C═O Double Bond (2007) (7)
Stereochemistry in the reaction of an optically active secondary alkyl chloride with triphenylsilyl-lithium (1982) (7)
Reactions of bis(silyl)palladium(II) complexes with allyl halides. Synthesis of mono(silyl)palladium(II) halides and X-ray structure of trans-PdCl(SiF2Ph)(PMe2Ph)2 (1999) (7)
Hydrosilylation of Carbon—Carbon Double Bonds (2000) (7)
Stereochemistry and mechanism of the ligand-coupling reaction of an optically active acetylacetonato(π-allyl) palladium complex (1988) (7)
Iron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing β-Hydrogens. (2004) (6)
Frontiers in Natural Product Chemistry (2009) (6)
Access to Chiral HWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of γ,δ-Unsaturated β-Ketophosphonates. (2018) (6)
A chiral bicyclo[2.2.2]octa-2,5-diene ligand substituted with the ferrocenyl group and its use for rhodium-catalyzed asymmetric 1,4-addition reactions (2015) (6)
A chiral bicyclo[2.2.2]octa-2,5-diene ligand substituted with the ferrocenyl group and its use for rhodium-catalyzed asymmetric 1,4-addition reactions (2015) (6)
Copper-catalyzed Oxidative C–C, C–O, and C–N Bond Forming Reactions of Arylboronic Acids (2013) (6)
Asymmetric Hydrosilylation of Carbon–Carbon Double Bonds and Related Reactions (2010) (6)
Determination of Enantiomeric Purity of 1-Phenylalkanols Using a Chiral NMR Shift Reagent (1974) (6)
Rhodium-and Palladium-Catalyzed Asymmetric Conjugate Additions (2011) (6)
Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Chirality Transfer to Stereogenic Carbon Centers in SE′ Reactions. (2003) (5)
Chiral Ferrocenylphosphines and their Use as Ligands for Transition Metal Complex Catalyzed Asymmetric Synthesis (1978) (5)
Transition Metal/Base-Catalyzed Aldol Reactions of Isocyanoacetic Acid Derivatives with Prochiral Ketones, a Straightforward Approach to Stereochemically Defined β,β-Disubstituted-β-hydroxy-. alpha.-amino Acids. Scope and Limitations. (1997) (5)
Solid‐Phase Palladium Catalysis for High‐Throughput Organic Synthesis (2005) (5)
Metathesis Route to Bridged Metallocenes [J. Am. Chem. Soc. 2002, 124 (31), 9068−9069]. (2002) (5)
Palladium‐Catalyzed Asymmetric Cross‐Coupling (2003) (5)
Iron-catalyzed Pinacol Coupling of Aryl Ketones with a Phenyltitanium Reagent: A New Type of Catalytic Reaction (2011) (5)
Asymmetric Synthesis of Alkylzincs by Rhodium-Catalyzed Enantioselective Arylative Cyclization of 1,6-Enynes with Arylzincs. (2020) (5)
Hydroboration of Carbon—Carbon Double Bonds (2000) (5)
Ligand Design for CC Bond Formation (2006) (5)
Asymmetric Grignard Cross-Coupling Catalyzed by Chiral Phosphine—Nickel and Phosphine—Palladium Complexes (1982) (5)
Asymmetric Synthesis of β‐Alkynyl Aldehydes by Rhodium‐Catalyzed Conjugate Alkynylation. (2010) (5)
Synthesis of Quaternary Carbon Stereocenters by Copper‐Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates. (2014) (5)
Rhodium‐Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2‐Dimetalloarenes. (2010) (5)
Catalytic Asymmetric Arylative Cyclization of Alkynals: Phosphine‐Free Rhodium/Diene Complexes as Efficient Catalysts. (2005) (4)
Rhodium‐Catalyzed Asymmetric [5 + 2] Cycloaddition of Alkyne—Vinylcyclopropanes. (2010) (4)
Transition Metal‐Catalyzed Synthesis of Allenes (2008) (4)
Control of Reactive Site in Palladium‐Catalyzed Grignard Cross‐Coupling of Arenes Containing Both Bromide and Triflate. (1998) (4)
Asymmetric Synthesis of Fluorinated Allenes by Rhodium-Catalyzed Enantioselective Alkylation/Defluorination of Propargyl Difluorides with Alkylzincs. (2021) (4)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Compounds Generated in situ from Aryl Bromides. (1999) (4)
Rhodium/Chiral Diene‐Catalyzed Asymmetric 1,4‐Addition of Arylboronic Acids to Arylmethylene Cyanoacetates. (2008) (4)
A Remarkable Difference in the Reactivity between cis- and trans-Silylplatinum Complexes toword Insertion of Acetylene (1995) (4)
Rhodium‐Catalyzed Additions of Boronic Acids to Alkenes and Carbonyl Compounds (2006) (4)
Ruthenium‐Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides. (2013) (4)
Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates. (2000) (4)
Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones (2007) (4)
Rhodium‐Catalyzed Isomerization of α‐Arylpropargyl Alcohols to Indanones: Involvement of an Unexpected Reaction Cascade. (2005) (3)
Palladium‐Catalyzed Asymmetric Decarboxylative Lactamization of γ‐Methylidene‐δ‐valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams. (2009) (3)
Highly Chemo‐ and Enantioselective Arylative Cyclization of Alkyne‐Tethered Electron‐Deficient Olefins Catalyzed by Rhodium Complexes with Chiral Dienes. (2005) (3)
Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complexes. (2010) (3)
Asymmetric Synthesis of Chiral Bicyclo[2.2.1]hepta-2,5-diene Ligands through Rhodium-Catalyzed Asymmetric Arylative Bis-cyclization of a 1,6-Enyne. (2021) (3)
The Development and Application of a New Class of Monodentate Optically Active Phosphines (MOP's). Asymmetric Hydrosilylation of Olefins Catalyzed by Palladium-MOP Complexes (1993) (3)
Catalytic Asymmetric Heck Reaction (1993) (3)
Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C—H Bond Functionalization. (2012) (3)
C2‐Symmetric Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Iridium‐Catalyzed Asymmetric Annulation of 1,3‐Dienes with 2‐Formylphenylboron Reagents. (2009) (3)
Palladium(0)‐Catalyzed Hydroboration of 1‐Buten‐3‐ynes: Preparation of Allenylboranes. (1992) (3)
Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes. (2001) (3)
Rhodium‐Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon—Carbon Bond Cleavage. (2008) (3)
Palladium‐Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter. (2012) (3)
Cobalt‐Catalyzed Asymmetric 1,6‐Addition of (Triisopropylsilyl)acetylene to α,β,γ,δ‐Unsaturated Carbonyl Compounds. (2013) (3)
OPTICALLY ACTIVE ALLYLSILANES (1986) (2)
Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3‐Aryl‐3‐hydroxyisoindolin‐1‐ones. (2013) (2)
Iridium/Chiral Diene‐Catalyzed Asymmetric 1,6‐Addition of Arylboroxines to α,β,γ,δ‐Unsaturated Carbonyl Compounds. (2010) (2)
Rhodium‐Catalyzed Asymmetric Arylation of Imines with Organostannanes. Asymmetric Synthesis of Diarylmethylamines. (2000) (2)
The Concise Synthesis of Chiral Tfb Ligands and Their Application to the Rhodium‐Catalyzed Asymmetric Arylation of Aldehydes. (2010) (2)
Transition Metal Catalyzed Diastereoselective Aldol Reactions of Prochiral Ketones with Methyl Isocyanoacetate. (1997) (2)
Asymmetric Addition to Isatins (2010) (2)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Organoboron Reagents to 5,6‐Dihydro‐2(1H)‐pyridinones. Asymmetric Synthesis of 4‐Aryl‐2‐piperidinones. (2002) (2)
High Performance of a Palladium Phosphinooxazoline Catalyst in the Asymmetric Arylation of Cyclic N‐Sulfonyl Ketimines. (2015) (2)
Stereoselective Synthesis 1: Stereoselective Reactions of Carbon–Carbon Double Bonds (2011) (2)
Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins. (2010) (2)
Electronic Tuning of Chiral Diene Ligands in Iridium‐Catalyzed Asymmetric 1,6‐Addition of Arylboroxines to δ‐Aryl‐α,β,γ,δ‐unsaturated Ketones. (2012) (2)
Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium‐Catalyzed Decarboxylative Cyclization of γ‐Methylidene‐δ‐valerolactones with Imines. (2009) (2)
Highly Diastereoselective Aldol Reaction of Fluoroalkyl Aryl Ketones with Methyl Isocyanoacetate Catalyzed by Silver(I)/Triethylamine. (1994) (2)
DICHLORO(1,1′-BIS(DIPHENYLPHOSPHINO)FERROCENE)PALLADIUM(II): AN EFFECTIVE CATALYST FOR CROSS-COUPLING REACTION OF A SECONDARY ALKYL GRIGNARD REAGENT WITH ORGANIC HALIDES (1979) (2)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition of 3‐Thiopheneboronic Acid to α,β‐Unsaturated Carbonyl Compounds. (2003) (2)
Asymmetric synthesis catalyzed by chiral phosphine-metal complexes. (1989) (2)
Gold(I)‐Catalyzed Asymmetric Aldol Reactions of Isocyanoacetic Acid Derivatives with Fluoroaryl Aldehydes. (1996) (2)
Gold(I)‐Catalyzed Asymmetric Aldol Reactions of Fluorinated Benzaldehydes with an α‐Isocyanoacetamide. (2010) (2)
Gold(I)-Catalyzed Asymmetric Aldol Reaction of Methyl Isocyanoacetate with Fluorinated Benzaldehydes. (1994) (2)
Palladium‐Catalyzed Asymmetric Arylation of 2,3‐Dihydrofuran with Phenyl Triflate. A Novel Asymmetric Catalysis Involving a Kinetic Resolution Process. (1994) (2)
erythro-Selective Aldol-Type Reaction of N-Sulfonylaldimines with Methyl Isocyanoacetate Catalyzed by Gold(I). (2010) (2)
C2‐Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands: Their High Performance in Rhodium‐Catalyzed Asymmetric Arylation of N‐Tosylarylimines. (2005) (2)
Iron‐Catalyzed Oxidative Homo‐Coupling of Aryl Grignard Reagents. (2005) (2)
Stereo- and Regiochemistry in Palladium-Catalyzed Nucleophilic Substitution of Optically Active (E)- and (Z)-Allyl Acetates. (1986) (2)
Chiral Phosphine—Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Aryl Boronic Acids to Maleimides. (2005) (2)
Palladium-Catalyzed Asymmetric Reduction of Racemic Allylic Esters with Formic Acid: Effects of Phosphine Ligands on Isomerization of π-Allylpalladium Intermediates and Enantioselectivity. (2010) (2)
A Novel Axially Chiral 2,2′‐Bipyridine N,N′‐Dioxide. Its Preparation and Use for Asymmetric Allylation of Aldehydes with Allyl(trichloro)silane as a Highly Efficient Catalyst. (2002) (1)
Modification of Optically Active Ferrocenylphosphine Ligands for Palladium‐Catalyzed Asymmetric Allylic Alkylation. (1986) (1)
Asymmetric Construction of Chiral C—N Axes Through Rhodium-Catalyzed 1,4-Addition. (2007) (1)
γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition: Palladium-Catalyzed [4 + 3] Cycloaddition with Nitrones. (2008) (1)
Hydrosilylation of Olefins (1999) (1)
Catalytic Asymmetric Reactions via π‐Allylpalladium Complexes Coordinated with Chiral Monophosphine Ligands (1999) (1)
Palladium‐ or Nickel‐Catalyzed Cross‐Coupling of Organotitanium Reagents with Aryl Triflates and Halides. (2002) (1)
Iridium‐Catalyzed [3 + 2] Annulation of Cyclic N‐Sulfonyl Ketimines with 1,3‐Dienes via C—H Activation. (2013) (1)
Preparation of C2‐Symmetric Bicyclo[2.2.2]octa‐2,5‐diene Ligands and Their Use for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboronic Acids. (2005) (1)
Palladium-catalyzed synthesis of spiro[2.4]heptanes: ligand-dependent position control in the nucleophilic attack to a pi-allylpalladium intermediate. (2007) (1)
Palladium(0)-Catalyzed Cyclization of 2-Butenylene Dicarbamates Forming 4-Vinyl-2-oxazolidones. (1988) (1)
Generation of Chiral Boron Enolates by Rhodium-Catalyzed Asymmetric 1,4-Addition of 9-Aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to α,β-Unsaturated Ketones. (2003) (1)
Chiral Diene‐Phosphine Tridentate Ligands for Rhodium‐Catalyzed Asymmetric Cycloisomerization of 1,6‐Enynes. (2011) (1)
Modification of Chiral Monodentate Phosphine Ligands (MOP) for Palladium‐Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3‐Dienes. (2001) (1)
Design and Preparation of 3,3′-Disubstituted 2,2′-Bis(oxazolyl)-1,1′-binaphthyls (boxax): New Chiral Bis(oxazoline) Ligands for Catalytic Asymmetric Wacker-Type Cyclization. (1999) (1)
Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes. (2002) (1)
Asymmetric Addition of Dimethylzinc to N-Tosylarylimines Catalyzed by a Rhodium—Diene Complex Toward the Synthesis of Chiral 1-Arylethylamines. (2006) (1)
Catalytic asymmetric hydrosilylation of olefins. : II. Chiral phosphine—nickel(II) and -rhodium(I) complex-catalyzed reaction (1976) (1)
Catalytic Asymmetric Cross-Coupling. (2002) (1)
Reagent for Asymmetric Cross-Coupling (Chiral Ferrocenylphosphine-Pd Complex) (1990) (1)
Palladium-catalyzed asymmetric synthesis of axially chiral (allenylmethyl)silanes and chirality transfer to stereogenic carbon centers in S(E)' reactions. (2003) (1)
Asymmetric Carbon–Carbon Bond‐Forming Reactions: Asymmetric Cross‐Coupling Reactions (2005) (1)
Organocatalytic Asymmetric Mannich‐Type Reaction of N‐Sulfonylimines with Isocyanoacetate Leading to Optically Active 2‐Imidazoline‐4‐carboxylates. (2011) (1)
A New Type of Catalytic Tandem 1,4-Addition—Aldol Reaction which Proceeds Through an (Oxa-π-allyl)rhodium Intermediate. (2003) (1)
π-Allylpalladium-Mediated Catalytic Synthesis of Functionalized Allenes. (2000) (1)
Catalytic Asymmetric Synthesis of Optically Active Alcohols via Hydrosilylation of Olefins with a Chiral Monophosphinepalladium Catalyst (1993) (1)
Cross‐Coupling Reactions (2000) (1)
Rhodium‐Catalyzed Asymmetric Arylation of N‐Tosyl Ketimines. (2011) (1)
Improved Procedure for Single‐Electron‐Transfer‐Induced Grignard Cross‐Coupling Reaction. (2015) (1)
Catalytic Asymmetric Hydrosilylation of 1,3-Dienes with New Chiral Ferrocenylphosphine-Palladium Complexes. (1990) (1)
Nickel-Catalyzed Three-Component Domino Reactions (2015) (1)
Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes (2010) (1)
Design and Synthesis of New Chiral Phosphorus—Olefin Bidentate Ligands and Their Use in the Rhodium-Catalyzed Asymmetric Addition of Organoboroxines to N-Sulfonyl Imines. (2011) (1)
Concise Synthesis of β,β-Diaryl Esters and Ketones from Ethynylcarbonyl Compounds by Rhodium-catalyzed Double Arylation with Arylboroxins (2011) (1)
A New cine‐Substitution of Alkenyl Sulfones with Aryltitanium Reagents Catalyzed by Rhodium: Mechanistic Studies and Catalytic Asymmetric Synthesis of Allylarenes. (2003) (1)
A New Reactive System for Catalytic Bis‐Silylation of Acetylenes and Olefins. (1995) (1)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition and Its Related Asymmetric Reactions (2003) (1)
Nickel‐Catalyzed Conjugate Addition of Arylboron Reagents to α,β‐Unsaturated Carbonyl Compounds with the Aid of a Catalytic Amount of an Alkyne. (2006) (1)
New Chiral Phosphine Ligands Containing (η6‐Arene)chromium and Catalytic Asymmetric Cross‐Coupling Reactions. (1992) (1)
ASYMMETRIC CATALYTIC HYDROSILYLATION OF KETONES, PREPARATION OF CHIRAL FERROCENYLPHOSPHINES AS CHIRAL LIGANDS (1975) (1)
Catalytic Asymmetric Synthesis of Optically Active 2-Alkanols via Hydrosilylation of 1-Alkenes with a Chiral Monophosphine-Palladium Catalyst. (1992) (1)
Axially Chiral Allenylboranes: Catalytic Asymmetric Synthesis by Palladium-Catalyzed Hydroboration of But-1-en-3-ynes and Their Reaction with an Aldehyde. (1994) (1)
Asymmetric Cyclopropanation Using Dimethyl Diazomalonate (2010) (1)
Palladium-Catalyzed Synthesis of Butatrienes. (2000) (1)
Dichloro[(2‐dimethylamino)propyldiphenylphosphine]palladium(II) (PdCl2(alaphos)): An Efficient Catalyst for Cross‐Coupling of Aryl Triflates with Alkynyl Grignard Reagents. (1999) (1)
Synthesis of Arylacetaldehydes by Iridium‐Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids (2019) (1)
Asymmetric (3 + 2)Cycloaddition of 2-(Sulfonylmethyl)-2-propenyl Carbonate Catalyzed by Chiral Ferrocenylphosphine-Palladium Complexes. (1989) (1)
Cross‐Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin‐Supported Palladium Catalyst. (2010) (1)
A New Optically Active Monodentate Phosphine Ligand, (R)‐(+)‐3‐ Diphenylphosphino‐3′‐methoxy‐4,4′‐biphenanthryl (MOP‐phen): Preparation and Use for Palladium‐Catalyzed Asymmetric Reduction of Allylic Esters with Formic Acid. (1994) (1)
Asymmetric Hydroboration of Styrenes Catalyzed by Cationic Chiral Phosphine-Rhodium(I) Complexes. (1991) (1)
Chiral Phosphine—Olefin Ligands in the Rhodium‐Catalyzed Asymmetric 1,4‐Addition Reactions. (2007) (1)
Chiral Monodentate Phosphine Ligand MOP for Transition-Metal-Catalyzed Asymmetric Reactions (2010) (1)
Catalytic Asymmetric Wacker-Type Cyclization. (1997) (1)
Enantioselective Synthesis of 1‐Metallocenylalkanols by Catalytic Asymmetric Alkylation of Metallocenecarboxaldehydes with Dialkylzincs. (1993) (1)
Rhodium‐Catalyzed Asymmetric Addition of Aryl‐ and Alkenylboronic Acids to Isatins. (2006) (1)
Palladium-Catalyzed Intramolecular Decarboxylative Allylic Arylation of α-Aryl-γ-methylidene-δ-valerolactones. (2010) (1)
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. Part 8. Palladium-Catalyzed Asymmetric Allylic Amination. (1989) (1)
Asymmetric Construction of Quaternary Carbon Stereocenters (2006) (1)
Rhodium‐Catalyzed Addition of Arylzinc Reagents to Aryl Alkynyl Ketones: Synthesis of β,β‐Disubstituted Indanones. (2005) (1)
Selective 1,4‐Hydroboration of Phenyl 1‐Alkenyl Ketones with 9‐ Borabicyclo(3.3.1)nonane and Catecholborane Forming Boron Z‐Enolates. (1992) (1)
ChemInform Abstract: Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters Toward the Synthesis of β-Amino Acids. (2010) (1)
Catalytic Asymmetric Hydrosilylation of Olefins: Catalytic Asymmetric Synthesis of Alcohols with High Enantiomeric Purity (2000) (1)
Asymmetric Double Hydroboration of 1,3-Dienes Catalyzed by Chiral Phosphine-Rhodium Complexes. (1992) (1)
Rhodium‐Catalyzed Synthesis of Indenols by Regioselective Coupling of Alkynes with ortho‐Carbonylated Arylboronic Acids. (2006) (1)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboronic Acids to Coumarins: Asymmetric Synthesis of (R)‐Tolterodine. (2005) (1)
Asymmetric Conjugate Alkynylation of Cyclic α,β‐Unsaturated Carbonyl Compounds with a Chiral Diene Rhodium Catalyst. (2016) (0)
1,1,1-Trichloro-2,2,2-trimethyldisilane: Reagent for Stereospecific Silylation of π-Allylpalladium Complexes. (1987) (0)
Asymmetric Aldol Reaction Catalyzed by Chiral Complexes (1990) (0)
Synthesis of Chiral Allylic Phosphine Oxides (2006) (0)
Chiral Diene-Rhodium Complex Catalyzed 1,4-Addition of Arylboronic Acids (2005) (0)
Rhodium-Catalyzed Asymmetric 1,6-Addition of Enynamides (2010) (0)
Palladium-Catalyzed Enantioselective Carbonylative Cyclization of Aryl and Alkenyl Triflates with Carbon Monoxide. (2000) (0)
New Chiral Diene Ligands for Iridium-Catalyzed [3+2] Annulation (2008) (0)
Rhodium-Catalyzed Asymmetric Conjugate Alkynylation (2010) (0)
Modification of Chiral Monodentate Phosphine (MOP) Ligands for Palladium-Catalyzed Asymmetric Hydrosilylation of Styrenes. (2001) (0)
Regio‐ and Enantioselective Hydrosilylation of 1‐Arylalkenes by Use of Palladium‐MOP Catalyst. (2010) (0)
Asymmetric Synthesis of (Triaryl)methylamines by Rhodium‐Catalyzed Addition of Arylboroxines to Cyclic N‐Sulfonyl Ketimines. (2012) (0)
Catalytic Asymmetric Hydrogenation of β‐Disubstituted α‐Phenylacrylic Acids. Asymmetric Synthesis of Carboxylic Acids Containing Two Vicinal Chiral Carbon Centers. (1989) (0)
Iron-Catalyzed Ayrl- and Alkenyllithiation of Alkynes and Its Application to Benzosilole Synthesis. (2012) (0)
A New Route to Methyl (R,E)-(-)-Tetradeca-2,4,5-trienoate (VIII) (Pheromone of Acanthoscelides obtectus) Utilizing a Palladium-Catalyzed Asymmetric Allene Formation Reaction. (2005) (0)
Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones. (2006) (0)
Rhodium‐Catalyzed Asymmetric Cycloisomerization of 1,6‐Ene‐ynamides. (2013) (0)
Synthesis of (R)-Tolterodine (2005) (0)
Synthesis and Application of Novel Chiral Phosphino‐oxazoline Ligands with 1,1′‐Binaphthyl Skeleton. (1998) (0)
A Chiral Phosphine—Olefin Ligand Derived from L‐Hydroxyproline and Its Use in the Rhodium‐Catalyzed Asymmetric 1,4‐Addition. (2015) (0)
Platinum-catalyzed addition of dimethylsilylene to beta-methyl alpha,beta-unsaturated ketones: gamma-silylation forming 1-oxa-2-silacyclohex-5-enes. (2007) (0)
Asymmetric Hydrosilylation of Carbon—Carbon Double Bonds and Related Reactions (2011) (0)
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine‐ Transition Metal Complexes. Part 10. Gold(I)‐Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate. (1992) (0)
Asymmetric Hydrosilylation of Dihydrofurans by Use of Palladium‐MOP Catalyst. (1993) (0)
Platinum‐Catalyzed Addition of Dimethylsilylene to β‐Methyl α,β‐Unsaturated Ketones: γ‐Silylation Forming 1‐Oxa‐2‐silacyclohex‐5‐enes. (2008) (0)
Copper-Catalyzed Oxidative C—C, C—O, and C—N Bond Forming Reactions of Arylboronic Acids (2013) (0)
Silafunctional Compounds in Organic Synthesis. Part 48. Ortho‐ Lithiation Directed by Amino Groups on Silicon in Phenylsilane Derivatives. (1991) (0)
Single Electron Transfer‐Induced Grignard Cross‐Coupling Involving Ion Radicals as Exclusive Intermediates. (2013) (0)
Secondary Phosphine Sulfide-Enabled Iridium-Catalyzed Asymmetric Allylic Substitution. (2022) (0)
Asymmetric Allylic Substitution (2011) (0)
Asymmetric Synthesis of Axially Chiral 1,1′:5′,1′′‐ and 1,1′:4′,1′′‐Ternaphthalenes by Asymmetric Cross‐Coupling with a Chiral Ferrocenylphosphine‐Nickel Catalyst. (1989) (0)
CATALYTIC ASYMMETRIC HYDROSILYLATION OF KETONES. I. CHIRAL PHOSPHINE-PLATINUM(II) COMPLEX-CATALYZED HYDROSILYLATION (1976) (0)
Bicyclo[2.2.2]octa‐2,5‐diene, 2,5‐Bis(phenylmethyl)‐, (1S,4S), Bicyclo[2.2.2]octa‐2,5‐diene, 2,5‐Bis(phenylmethyl)‐, (1R,4R) (2009) (0)
Palladium‐Catalyzed Asymmetric Hydrosilylation of Styrenes with Trichlorosilane (2014) (0)
Rhodium‐Catalyzed Asymmetric 1,4‐Addition of 2‐Alkenyl‐1,3,2‐benzodioxaboroles to α,β‐Unsaturated Ketones. (1999) (0)
Palladium‐Catalyzed Conjugate Reduction of Enones into α,β‐Dideuterioketones with Hexamethyldisilane and Deuterium Oxide. (2007) (0)
A New Synthetic Route to Enantiomerically Pure Axially Chiral 2,2′‐Bipyridine N,N′‐Dioxides. Highly Efficient Catalysts for Asymmetric Allylation of Aldehydes with Allyl(trichloro)silanes. (2003) (0)
Rhodium/diene‐Catalyzed Asymmetric 1,4‐Addition of Arylboronic Acids to α,β‐Unsaturated Weinreb Amides. (2005) (0)
1,1‐Dichloro‐2,2,2‐trimethyl‐1‐phenyldisilane (2001) (0)
Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes (III), (V). (2011) (0)
Chloroprene as a Source of Fine Chemicals: Palladium‐Catalyzed Synthesis of Terminal Allenes. (2001) (0)
Asymmetric Cross-Coupling Reactions (2010) (0)
A New Entry of Nucleophiles in Rhodium‐Catalyzed Asymmetric 1,4‐Addition Reactions: Addition of Organozinc Reagents for the Synthesis of 2‐Aryl‐4‐piperidones. (2004) (0)
Chiral Tridentate Ligand for Rhodium-Catalyzed Cycloisomerization (2011) (0)
Kinetic Resolution of Racemic Allyl Acetates in Asymmetric Allylic Alkylation Catalysed by a Chiral Ferrocenylphosphine-Palladium Complex. (1986) (0)
Enantioposition‐Selective Arylation of Biaryl Ditriflates by Palladium‐Catalyzed Asymmetric Grignard Cross‐Coupling. (1999) (0)
Rhodium‐Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3‐Alkynyl‐1‐indanones. (2008) (0)
CATALYTIC ASYMMETRIC HYDROSILYLATION OF OLEFINS. III. CHIRAL PHOSPHINE-PALLADIUM(II) COMPLEXES AS HYDROSILYLATION CATALYSTS (1977) (0)
Enantioselective Addition of Organoboron Nucleophiles to Conjugated Alkenes (2008) (0)
Bicyclo[2.2.2]octa-2,5-diene, 2,5-Diphenyl-, (1R,4R) and Bicyclo[2.2.2]octa-2,5-diene, 2,5-Diphenyl-, (1S,4S) (2011) (0)
DETERMINATION OF ENANTIOMERIC PURITY OF 1‐PHENYLKALKANOLS USING A CHIRAL NMR SHIFT REAGENT (1974) (0)
Composés diphenylphosphino-binaphtyle optiquement actives et metaux de transition complexes comme catalyseurs (1992) (0)
Synthesis of Chiral Allylsilanes by Enantioselective Conjugate Addition (2008) (0)
Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones. (2007) (0)
Enantioposition-Selective Alkynylation of Biaryl Ditriflates by Palladium-Catalyzed Asymmetric Cross-Coupling. (1996) (0)
Asymmetric Hydrosilylation of Carbon—Carbon Double Bonds (2011) (0)
Rhodium-Catalyzed 1,4-Addition of Arylzinc Reagents (2006) (0)
Preparation of Enantiomerically Pure 2′‐Substituted 2‐Diphenylphosphino‐1,1′‐binaphthyls by Reductive Cleavage of the Carbon—Phosphorus Bond in a Borane Complex of 2‐Diphenylphosphino‐2′‐diphenylphosphinyl‐1,1′‐binaphthyl. (2002) (0)
Preparation of New Ferrocenylmonophosphine Ligands Containing Two Planar Chiral Ferrocenyl Moieties and Their Use for Palladium-Catalyzed Asymmetric Hydrosilylation of 1,3-Dienes. (2003) (0)
Rhodium‐Catalyzed Asymmetric Ring‐Opening Alkynylation of Azabenzonorbornadienes. (2009) (0)
The Development and Application of a New Class of Monodentate Optically Active Phosphines (MOP′s). Asymmetric Hydrosilylation of Olefins Catalyzed by Palladium-MOP Complexes (1994) (0)
Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds. (2007) (0)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Reagents to α,β-Unsaturated Esters. (2000) (0)
Cobalt‐Catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents. (2008) (0)
Rhodium-Catalyzed Asymmetric Conjugate Addition to γ-Substituted α,β-Unsaturated γ-Lactams through Dynamic Kinetic Resolution: Asymmetric Synthesis of trans-β,γ-Disubstituted γ-Lactams (2023) (0)
Allylic Substitution in Water Catalyzed by Amphiphilic Resin-Supported Palladium—Phosphine Complexes. (2000) (0)
PB33 ASYMMETRIC SYNTHESIS OF β-HYDROXYL-α-AMINO ACIDS BY ASYMMETRIC ALDOL REACTION OF α-ISOCYANOCARBOXYLATES CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-GOLD (I) COMPLEXES (1988) (0)
Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides. (2005) (0)
Insertion of Alkenes into a Palladium-Acetyl Bond. (1992) (0)
Ruthenium-Catalyzed 1,4-Addition of Organoboronic Acids to α,β-Unsaturated Ketones. (2008) (0)
Silver(I)‐Catalyzed Asymmetric Aldol Rection of Isocyanoacetate. (2010) (0)
Highly Enantioselective 1,4-Addition of Arylzinc Reagents to 3-Arylpropenals Catalyzed by a Rhodium—Binap Complex in the Presence of Chlorotrimethylsilane. (2006) (0)
Silver‐Catalyzed Alkyl—Alkyl Homo‐Coupling of Grignard Reagents. (2006) (0)
High performance of a chiral diene-rhodium catalyst for the asymmetric 1,4-addition of arylboroxines to alpha,beta-unsaturated ketones. (2006) (0)
Rhodium-Catalyzed Asymmetric 1,4-Addition of Alkenylsilanes Generated by Hydrosilylation of Alkynes: A One-Pot Procedure Where a Rhodium/(S)-Binap Complex Catalyzes the Two Successive Reactions. (2005) (0)
Cobalt‐Catalyzed Cross‐Coupling of Alkynyl Grignard Reagents with Alkenyl Triflates. (2008) (0)
Palladium‐Catalyzed Decarboxylative [4 + 1] Cyclization of γ‐Methylidene‐δ‐valerolactones with Isocyanides. (2009) (0)
Iridium-Catalyzed [3 + 2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Catalyzed Process Involving Regioselective 1,2-Addition. (2007) (0)
CATALYTIC ASYMMETRIC HYDROSILYLATION OF KETONES. II. CHIRAL PHOSPHINE-RHODIUM M COMPLEX-CATALYZED HYDROSILYLATION (1976) (0)
Preparation of Optically Active Binaphthylmonophosphines (MOP′s) Containing Various Functional Groups. (1994) (0)
Rhodium/Chiral Diene-Catalyzed Asymmetric Methylation of N-Sulfonylarylimines with Trimethylboroxine. (2012) (0)
Arylmagnesiation of Alkynes Catalyzed by Iron and Copper Complexes (2006) (0)
Palladium‐Catalyzed Synthesis of 4‐Oxaspiro[2.4]heptanes via Central Attack of Oxygen Nucleophiles to π‐Allylpalladium Intermediates. (2012) (0)
Rhodium‐Catalyzed Asymmetric Synthesis of 3,3‐Disubstituted 1‐Indanones. (2007) (0)
Ruthenium-Catalyzed Reaction of Alkenyl Triflates with Zinc Thiolates. (2012) (0)
Palladium-Catalyzed Asymmetric Arylation of 2,3-Dihydrofuran: 1,8-Bis( dimethylamino)naphthalene as an Efficient Base. (2010) (0)
Asymmetric Arylation of N-TosylKetimines (2010) (0)
CROSS-COUPLING REACTION OF SECONDARY ALKYL GRIGNARD REAGENTS WITH ALLYLIC ALCOHOLS CATALYZED BY DICHLORO(1,1′-BIS(DIPHENYLPHOSPHINO)FERROCENE)PALLADIUM(II) (1980) (0)
Catalytic Asymmetric Construction of Morpholines and Piperazines by Palladium-Catalyzed Tandem Allylic Substitution Reactions. (1994) (0)
Iron-Catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds. (2012) (0)
Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes (2010) (0)
Asymmetric Functionalization of Bicycloalkenes by Catalytic Enantioposition-Selective Hydrosilylation. (1993) (0)
Cobalt‐Catalyzed Conjugate Addition of Silylacetylenes to α,β‐Unsaturated Ketones. (2012) (0)
Asymmetric Allylic Amination Catalyzed by Chiral Ferrocenylphosphine-Palladium Complexes. (1990) (0)
Synthesis of Planar Chiral Shvo Catalysts for Asymmetric Transfer Hydrogenation. (2016) (0)
Chiral Pd(0) and Pd(II) Complexes (2003) (0)
Palladium‐Catalyzed Allylation of α‐Isocyanocarboxylates. (1988) (0)
Highly Selective 1,6‐Addition of Aryl Boronic Acids to α,β,γ,δ‐Unsaturated Carbonyl Compounds Catalyzed by an Iridium Complex. (2006) (0)
PREPARATION OF (R)‐N,N‐DIMETHYL‐1‐(2‐(DIPHENYLPHOSPHINO)FERROCENYL)‐2‐PROPANAMINES AND ASYMMETRIC GRIGNARD CROSS‐COUPLING CATALYZED BY NICKEL COMPLEXES WITH THE PHOSPHINE LIGANDS (1982) (0)
Rhodium-Catalyzed 1,4-Addition of Boronic Acids to α,β-UnsaturatedKetones (2009) (0)
Rhodium-Catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines. (2008) (0)
Palladium-Catalyzed Synthesis of Chiral Lactams from RacemicLactones (2009) (0)
CCDC 262190: Experimental Crystal Structure Determination (2005) (0)
Asymmetric Hydrosilylation of 1,3-Dienes (2011) (0)
Preparation and Use of Chiral Ferrocenylphosphines Containing New Alkyl Substituents on the Ferrocenylmethyl Position. (1996) (0)
Kinetic Resolution of Homoallylic Alcohols by Retro-Allylation (2008) (0)
Palladium‐Catalyzed Synthesis of Spiro[2.4]heptanes: Ligand‐Dependent Position Control in the Nucleophilic Attack to a π‐Allylpalladium Intermediate. (2008) (0)
Catalytic Asymmetric Hydrosilylation of Ketones with New Chiral Ferrocenylphosphine-Imine Ligands. (1996) (0)
Asymmetric Synthesis of Fluorinated Allenes by Rhodium‐Catalyzed Enantioselective Alkylation/Defluorination of Propargyl Difluorides with Alkylzincs (2021) (0)
Asymmetric Allylic Alkylation of 1,3-Disubstituted 2-Propenyl Acetates Catalyzed by a Chiral Ferrocenylphosphine-Palladium Complex. (1987) (0)
Axially Chiral Monophosphine Ligands (MOPs) and Their Use for Palladium‐Catalyzed Asymmetric Hydrosilylation of Olefins (2001) (0)
CROSS-COUPLING OF TERTIARY ALKYL GRIGNARD REAGENTS WITH β-BROMOSTYRENE CATALYZED BY DICHLORO (1,1′-BIS(DIPHENYLPHOSPHINO)FERROCENE)NICKEL(II) (1980) (0)
CROSS-COUPLING OF ENOL PHOSPHATES WITH TRIMETHYLSILYLMETHYLMAGNESIUM HALIDES CATALYZED BY NICKEL OR PALLADIUM COMPLEXES: A SELECTIVE SYNTHESIS OF ALLYLSILANES (1982) (0)
Catalytic Asymmetric Hydroboration of Styrenes. (1989) (0)
Palladium-Catalyzed Asymmetric Hydroalkenylation of Norbornene. (1994) (0)
ASYMMETRIC SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL COMPLEXES. I. PREPARATION OF CHIRAL FERROCENYLPHOSPHINES (1980) (0)
Catalytic Asymmetric Elimination Forming Chiral 1,3-Dienes via π- Allylpalladium Intermediate. (1991) (0)
Iridium-Catalyzed Enantioselective 1,6-Addition (2010) (0)
Mizoroki—Heck‐Type Reaction Mediated by Potassium tert‐Butoxide. (2011) (0)
Rhodium‐Catalyzed Asymmetric Addition of Organo‐Boron and ‐Titanium Reagents to Electron‐Deficient Olefins (2004) (0)
Asymmetric Hydrosilylation of 1-Alkenes Catalyzed by Palladium-MOP. (1995) (0)
Rhodium‐Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols: Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones. (2008) (0)
Catalytic Asymmetric Induction of Planar Chirality by Palladium- Catalyzed Asymmetric Cross-Coupling of a meso-(Arene)chromium Complex. (1993) (0)
Untitled Document (2000) (0)
Synthesis of All-Carbon Quaternary Stereocenters (2009) (0)
Preparation and Reaction of Optically Active Allylsilanes (1985) (0)
Palladium‐Catalyzed Asymmetric [3 + 3] Cycloaddition of Trimethylenemethane Derivatives with Nitrones. (2007) (0)
(R)‐3‐Phenylcyclohexanon (2003) (0)
Asymmetric Reactions Catalyzed by Palladium‐MOP Complexes (1999) (0)
Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Design and Preparation of New Efficient Ferrocenylphosphine Ligands. (1988) (0)
Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene—Rhodium Complex. (2006) (0)
Catalytic Asymmetric Arylation of N‐Substituted 2‐Pyrrolines with Aryl Triflates. (1992) (0)
Iron‐Catalyzed Pinacol Coupling of Aryl Ketones with a Phenyltitanium Reagent: A New Type of Catalytic Reaction. (2011) (0)
(R)‐N,N‐Dimethyl‐1‐[(S)‐2‐(diphenylphosphino)ferrocenyl]ethylamine (2001) (0)
Rhodium-Catalyzed Rearrangement of Propargyl Alcohols (2008) (0)
Catalytic Asymmetric Hydrosilylation of Olefins and Ketones (1975) (0)
Asymmetric Aldol Reaction of α-Keto Esters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine/Gold(I) Complex. (1990) (0)
A Cationic Rhodium—Chiral Diene Complex as a High‐Performance Catalyst for the Intramolecular Asymmetric [4 + 2] Cycloaddition of Alkyne‐1,3‐dienes. (2008) (0)
Redox Catalysis of Halide Ion for Formal Cross-Dehydrogenative Coupling: Bromide Ion-Catalyzed Direct Oxidative α-Acetoxylation of Ketones. (2011) (0)
Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles (2010) (0)
Rhodium‐Catalyzed Aryl‐ and Alkylation—Oligomerization of Alkynoates with Organoboron Reagents Giving Salicylates. (2010) (0)
Asymmetric Aldol Reaction of α-Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of α-Alkylserines. (1988) (0)
Asymmetric Hydrosilylation of Styrenes Catalyzed by Palladium—MOP Complexes: Ligand Modification and Mechanistic Studies. (2001) (0)
Enantioselective Desymmetrization via Ring Opening of StrainedAlkenes (2008) (0)
Enantioselective Rhodium-Catalyzed Synthesis of N-Arylsuccinimides (2007) (0)
Rhodium‐Catalyzed Asymmetric Arylation of α,β‐Unsaturated Imines with Arylstannanes. Catalytic Asymmetric Synthesis of Allylic Amines. (2001) (0)
Asymmetric Hydrosilylation of Styrenes (2011) (0)
MOP: A Monodentate Chiral Phosphine Ligand for Catalytic Asymmetric Reactions (1995) (0)
Palladium-Catalyzed Asymmetric Allylic Substitution in Aqueous Media Using Amphiphilic Resin-Supported MOP Ligands. (2010) (0)
Asymmetric Synthesis of 1‐Aryl‐1,2‐ethanediols from Arylacetylenes by Palladium‐Catalyzed Asymmetric Hydrosilylation as a Key Step. (2002) (0)
Stereoselective Synthesis of Spirooxindoles (2009) (0)
Regiocontrol in Palladium-Catalyzed Allylic Alkylation by Addition of Lithium Iodide. (1998) (0)
Palladium‐Catalyzed Asymmetric Hydrosilylation of 1,3‐Dienes (2011) (0)
Synthesis of Optically Active 2‐(Diarylphosphino)‐1,1′‐binaphthyls, Efficient Chiral Monodentate Phosphine Ligands. (2010) (0)
Optically Active Allylsilanes. Part 16. Selective Synthesis of Z-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes. (1991) (0)
Palladium Catalysts for Cross‐Coupling of Ortho‐Substituted Aryl Triflates with Grignard Reagents. (1997) (0)
Rhodium‐Catalyzed Aryl Transfer from Trisubstituted Aryl Methanols to α,β‐Unsaturated Carbonyl Compounds. (2007) (0)
Optically Active Allylsilanes. Part 19. Asymmetric Synthesis of Allylsilanes by Palladium‐Catalyzed Asymmetric Reduction of Allylic Carbonates with Formic Acid. (1994) (0)
Carbon—Carbon Bond‐Forming Enantioselective Synthesis of Chiral Organosilicon Compounds by Rhodium/Chiral Diene‐Catalyzed Asymmetric 1,4‐Addition Reaction. (2006) (0)
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphin-Transition Metal Complexes. Part 7. New Chiral Ferrocenylphosphines with C2 Symmetry. (1990) (0)
ASYMMETRIC GRIGNARD CROSS-COUPLING BY MEANS OF POLYMER-SUPPORTED OPTICALLY ACTIVE β-DIMETHYLAMINOALKYLPHOSPHINENICKEL CATALYSTS (1981) (0)
Asymmetric Hydrogenation of Trisubstituted Acrylic Acids Catalyzed by a Chiral (Aminoalkyl)ferrocenylphosphine-Rhodium Complex. (1988) (0)
Palladium-Catalyzed Asymmetric Allylic Alkylation with an Indenide. (2004) (0)
Homochiral 2,2′-Bis(oxazolyl)-1,1′-binaphthyls as Ligands for Copper(I) -Catalyzed Asymmetric Cyclopropanation. (1996) (0)
FLUORINATED POLYSILANES. PALLADIUM-CATALYZED DISILANE METATHESIS, DOUBLE SILYLATION OF ACETYLENES, AND THE STEREOCHEMICAL COURSE (1976) (0)
Catalytic Asymmetric Arylation of 2,3-Dihydrofuran with Aryl Triflates. (1991) (0)
Rhodium‐Catalyzed Enantioselective Alkynylative Cyclization of Allenyl Aldehydes with Terminal Alkynes. (2011) (0)
Optically Active Allylsilanes. Part 17. Preparation of Silafunctional Allylsilanes by Palladium-Catalyzed Silylation of Allylic Chlorides with 1,1-Dichloro-1-phenyl-2,2,2-trimethyldisilane. (2010) (0)
Asymmetric Aldol Reaction of α-Isocyanoacetamides with Aldehydes Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex. (1989) (0)
METAL COMPLEX CATALYZED ASYMMETRIC SYNTHESIS (1978) (0)
Optically Active Allylsilanes. Part 14. Stereochemistry and Mechanism of Asymmetric Allylation of Aldehydes with Optically Active Allylsiliconates. (1989) (0)
Platinum‐Catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β‐Unsaturated Ketones. (2008) (0)
Tuning the Chiral Environment of C2‐Symmetric Diene Ligands: Development of 3,7‐Disubstituted Bicyclo[3.3.1]nona‐2,6‐dienes. (2009) (0)
Anti Stereochemistry in SE′′ Reaction of an Optically Active 2,4-Dienylsilane. (1988) (0)
New Amphiphilic Palladium‐Phosphine Complexes Bound to Solid Supports: Preparation and Use for Catalytic Allylic Substitution in Aqueous Media. (1997) (0)
Cobalt‐Catalyzed Asymmetric Addition of Silylacetylenes to Oxa‐ and Azabenzonorbornadienes. (2012) (0)
Asymmetric 1,4-Addition of Organoboron Reagents to Quinone Monoketals Catalyzed by a Chiral Diene/Rhodium Complex: A New Synthetic Route to Enantioenriched 2-Aryltetralones. (2007) (0)
Rhodium-Catalyzed Hydroalkynylation of Internal Alkynes with Silylacetylenes: An Alkynylrhodium(I) Intermediate Generated from the Hydroxorhodium(I) Complex [Rh(OH)(binap)]2. (2008) (0)
Concise Synthesis of β,β-Diaryl Esters and Ketones from Ethynylcarbonyl Compounds by Rhodium-Catalyzed Double Arylation with Arylboroxins. (2012) (0)
Bipyridyl-Based Diphosphine as an Efficient Ligand in the Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Ketones. (2003) (0)
Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to alpha,beta-unsaturated ketones. (2004) (0)
High Performance of a Chiral Diene—Rhodium Catalyst for the Asymmetric 1,4-Addition of Arylboroxines to α,β-Unsaturated Ketones. (2006) (0)
Enantioselective [3 + 2] Annulation via C—H Activation Between Cyclic N‐Acyl Ketimines and 1,3‐Dienes Catalyzed by Iridium/Chiral Diene Complexes. (2014) (0)
Asymmetric Alkynylation of Nitroalkenes (2010) (0)
Preparation of an Amphiphilic Resin‐Supported BINAP Ligand and Its Use for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Phenylboronic Acid in Water. (2005) (0)
Palladium/Chiral Phosphine‐Olefin Complexes: X‐Ray Crystallographic Analysis and the Use in Catalytic Asymmetric Allylic Alkylation. (2006) (0)
Platinum-Catalyzed 1,4-Addition of Arylboronic Acids to β-Substituted α,β-Unsaturated Ketones. (2009) (0)
Palladium-Catalyzed Asymmetric Alkenylation of Cyclic Olefins. (1993) (0)
Copper-Catalyzed 1,4-Addition of Organo-boronates to AlkylideneCyanoacetates (2011) (0)
Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones. (2003) (0)
Palladium-Catalyzed Decarboxylative Cyclization (2009) (0)
Rhodium‐Catalyzed Multicomponent‐Coupling Reactions Involving a Carborhodation—Cross‐Coupling Sequence. (2007) (0)
Bis[(1R)‐[1,1′‐binaphthalene]‐2,2′‐diylbis[diphenylphosphine‐κP]]di‐μ‐hydroxydirhodium (2008) (0)
Palladium-Catalyzed Enantioselective Synthesis of Silacyles (2011) (0)
Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids. (2009) (0)
A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts: Its Preparation and Use for the Rhodium‐Catalyzed Asymmetric 1,4‐Addition. (2004) (0)
Asymmetric Synthesis Catalyzed by Chiral Phosphine Metal Complexes. (1990) (0)
Rhodium‐Catalyzed Asymmetric Addition of Arylboroxines to β‐Alkoxyacrylate Esters. (2012) (0)
Fe—Cu Cooperative Catalysis in the Isomerization of Alkyl Grignard Reagents. (2008) (0)
Rhodium-Catalyzed Conjugate Addition of Sterically Bulky Silylacetylene to Enones (2008) (0)
Palladium-catalyzed conjugate reduction of enones into alpha,beta-dideuterioketones with hexamethyldisilane and deuterium oxide. (2007) (0)
OPTICALLY ACTIVE 2,2′‐BIS(DIPHENYLPHOSPHINOMETHYL)‐1,1′‐BINAPHTHYL‐ A NEW CHIRAL BIDENTATE PHOSPHINE LIGAND FOR TRANSITION‐METAL COMPLEX CATALYZED ASYMMETRIC REACTIONS (1977) (0)
Palladium-Catalyzed Asymmetric Intramolecular Allylation Forming Optically Active Vinylcyclopropane and Vinyldihydrofurans. (1988) (0)
Rhodium-Catalyzed Oxidative Alkynylation of Acrylate Esters with Propargylic Alcohols. (2011) (0)
Asymmetric Synthesis of β-Hydroxy-α-alkylamino Acids by Asymmetric Aldol Reaction of α-Isocyanocarboxylates Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes. (1989) (0)
SELECTIVE SYNTHESIS OF (E)-CROTYLSILANES BY REACTION OF CROTYLMAGNESIUM BROMIDE WITH HYDROSILANES IN THE PRESENCE OF DICHLORO(1,1′-BIS(DIPHENYLPHOSPHINO)FERROCENE)NICKEL(II) (1984) (0)
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. Part 6. Practical Asymmetric Synthesis of 1,1′-Binaphthyls via Asymmetric Cross-Coupling with a Chiral ((Alkoxyalkyl)ferrocenyl)monophosphine/Nic (1989) (0)
Rhodium-catalyzed addition of arylzinc reagents to aryl alkynyl ketones: synthesis of beta,beta-disubstituted indanones. (2005) (0)
Catalytic Asymmetric Synthesis of β‐Hydroxy Ketones by Palladium‐ Catalyzed Asymmetric 1,4‐Disilylation of α,β‐Unsaturated Ketones. (1994) (0)

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