Thomas Bruice
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Why Is Thomas Bruice Influential?
(Suggest an Edit or Addition)According to Wikipedia, Thomas C. Bruice was a professor of chemistry and biochemistry at University of California, Santa Barbara. He was elected to the National Academy of Sciences in 1974. He was a pioneering researcher in the area of chemical biology, and is one of the 50 most cited chemists.
Thomas Bruice's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Chemical basis for enzyme catalysis. (2000) (202)
- Mechanisms of flavin catalysis (1980) (199)
- Mechanism of alkene epoxidation by iron, chromium, and manganese higher valent oxo-metalloporphyrins (1992) (194)
- Ground State and Transition State Contributions to the Rates of Intramolecular and Enzymatic Reactions (1999) (191)
- The Effect of Geminal Substitution Ring Size and Rotamer Distribution on the Intramolecular Nucleophilic Catalysis of the Hydrolysis of Monophenyl Esters of Dibasic Acids and the Solvolysis of the Intermediate Anhydrides (1960) (181)
- A view at the millennium: the efficiency of enzymatic catalysis. (2002) (174)
- Mechanism of manganese porphyrin-catalyzed oxidation of alkenes. Role of manganese(IV)-oxo species (1993) (154)
- Reactions of Hydroperoxides with Metallotetraphenylporphyrins in Aqueous Solutions (1991) (141)
- Ground State Conformations and Entropic and Enthalpic Factors in the Efficiency of Intramolecular and Enzymatic Reactions. 1. Cyclic Anhydride Formation by Substituted Glutarates, Succinate, and 3,6-Endoxo-Δ4-tetrahydrophthalate Monophenyl Esters (1996) (139)
- The near attack conformation approach to the study of the chorismate to prephenate reaction (2003) (136)
- Recent advances in atomic force microscopy of DNA. (1993) (135)
- Imidazole Catalysis. II. The Reaction of Substituted Imidazoles with Phenyl Acetates in Aqueous Solution (1958) (135)
- Influence of hydrogen ion activity and general acid-base catalysis on the rate of decomposition of hydrogen peroxide by a novel nonaggregating water-soluble iron(III) tetraphenylporphyrin derivative (1986) (116)
- Imidazole Catalysis. I. The Catalysis of the Hydrolysis of Phenyl Acetates by Imidazole (1957) (116)
- Reactions of tetranitromethane. I. Kinetics and mechanism of nitration of phenols by tetranitromethane (1968) (106)
- Simple synthesis of a 4a-hydroperoxy adduct of a 1,5-dihydroflavine: preliminary studies of a model for bacterial luciferase. (1976) (105)
- On the electronic nature of low-barrier hydrogen bonds in enzymatic reactions. (1998) (104)
- Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 5. Epoxidation of alkenes catalyzed by a sterically hindered (meso-tetrakis(2,6-dibromophenyl)porphinato)iron(III) chloride (1989) (102)
- Characterization of the Short Strong Hydrogen Bond in Benzoylacetone by ab Initio Calculations and Accurate Diffraction Experiments. Implications for the Electronic Nature of Low-Barrier Hydrogen Bonds in Enzymatic Reactions (1998) (101)
- Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 1. cis-Stilbene as a mechanistic probe (1988) (100)
- Parameterization of OPLS–AA force field for the conformational analysis of macrocyclic polyketides (2002) (95)
- Ferricyanide oxidation of dihydropyridines and analogs (1984) (94)
- Oxygen‐Flavin Chemistry (1984) (91)
- RECENT STUDIES OF NUCLEOPHILIC, GENERAL-ACID, AND METAL ION CATALYSIS OF PHOSPHATE DIESTER HYDROLYSIS (1999) (89)
- Computational approaches: reaction trajectories, structures, and atomic motions. Enzyme reactions and proficiency. (2006) (89)
- INTRAMOLECULAR MODELS DEPICTING THE KINETIC IMPORTANCE OF "FIT" IN ENZYMATIC CATALYSIS. (1960) (84)
- Oxidation of amines by a 4a-hydroperoxyflavin (1980) (84)
- Monooxygen donation potential of 4a-hydroperoxyflavins as compared with those of a percarboxylic acid and other hydroperoxides. Monooxygen donation to olefin, tertiary amine, alkyl sulfide, and iodide ion (1983) (84)
- Evaluation of the factors influencing reactivity and stereospecificity in NAD(P)H dependent dehydrogenase enzymes (1993) (83)
- The Compensation in ΔH[UNK] and ΔS[UNK] Accompanying the Conversion of Lower Order Nucleophilic Displacement Reactions to Higher Order Catalytic Processes. The Temperature Dependence of the Hydrazinolysis and Imidazole-Catalyzed Hydrolysis of Substituted Phenyl Acetates (1964) (80)
- Chemiluminescent reactions of lucigenin. 1. Reactions of lucigenin with hydrogen peroxide (1979) (79)
- Effect of isotope scrambling and tunneling on the kinetic and product isotope effects for reduced nicotinamide adenine dinucleotide model hydride transfer reactions (1983) (77)
- Influence of nitrogen base ligation and hydrogen bonding on the rate constants for oxygen transfer from percarboxylic acids and alkyl hydroperoxides to (meso-tetraphenylporphinato)manganese(III) chloride (1986) (76)
- Bending and straightening of DNA induced by the same ligand: characterization with the atomic force microscope. (1994) (76)
- alpha. Effect. V. Kinetic and thermodynamic nature of the .alpha. effect for amine nucleophiles (1972) (74)
- Hydroxyl Group Catalysis. III.1 The Nature of Neighboring Hydroxyl Group Assistance in the Alkaline Hydrolysis of the Ester Bond (1962) (72)
- Enzymatic mechanism and product specificity of SET-domain protein lysine methyltransferases (2008) (71)
- Study of (tetraphenylporphinato)manganese(III)-catalyzed epoxidation and demethylation using p-cyano-N,N-dimethylaniline N-oxide as oxygen donor in a homogeneous system. Kinetics, radiochemical ligation studies, and reaction mechanism for a model of cytochrome P-450 (1984) (70)
- Chemical properties of phenanthrolinequinones and the mechanism of amine oxidation by o-quinones of medium redox potentials (1983) (70)
- Synthesis and characterization of a meso-tetrakis(4-ferrocenylphenyl)porphyrin and examination of its ability to undergo intramolecular photocatalyzed electron transfer (1986) (69)
- Importance of Correlated Motions in Forming Highly Reactive Near Attack Conformations in Catechol O-Methyltransferase (1998) (69)
- A THEORETICAL EXAMINATION OF THE FACTORS CONTROLLING THE CATALYTIC EFFICIENCY OF A TRANSMETHYLATION ENZYME : CATECHOL O-METHYLTRANSFERASE (1997) (68)
- THE TEMPERATURE DEPENDENCE OF THE ΔpD CORRECTION FOR THE USE OF THE GLASS ELECTRODE IN D2O (1961) (67)
- Is a linear relationship between the free energies of activation and one-electron oxidation potential evidence for one-electron transfer being rate determining? Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 4. Epoxidation of a series of alkenes by oxo(meso-tetrakis(2,6-dibr (1989) (67)
- Aminolysis of Phenyl Acetates in Aqueous Solutions. VII.1 Observations on the Influence of Salts, Amine Structure, and Base Strength (1967) (66)
- Homolytic and heterolytic oxygen−oxygen bond scissions accompanying oxygen transfer to iron(III) porphyrins by percarboxylic acids and hydroperoxides. A mechanistic criterion for peroxidase and cytochrome P-450 (1985) (65)
- One- and Two-Metal Ion Catalysis of the Hydrolysis of Adenosine 3‘-Alkyl Phosphate Esters. Models for One- and Two-Metal Ion Catalysis of RNA Hydrolysis (1996) (65)
- Oscillating reaction. Reaction of potassium bromate, ceric sulfate, and a dicarboxylic acid (1971) (64)
- Incorporation of positively charged linkages into DNA and RNA backbones: a novel strategy for antigene and antisense agents. (2012) (64)
- The chemistry of a 1,5-diblocked flavin. 2. Proton and electron transfer steps in the reaction of dihydroflavins with oxygen (1983) (63)
- The Influence of the Leaving Tendency of the Phenoxy Group on the Ammonolysis and Hydrolysis of Substituted Phenyl Acetates (1960) (63)
- Catalytic mechanism of quinoprotein methanol dehydrogenase: A theoretical and x-ray crystallographic investigation. (2001) (62)
- Nature of the epoxidizing species generated by reaction of alkyl hydroperoxides with iron(III) porphyrins. Oxidations of cis-stilbene and (Z)-1,2-bis(trans-2, trans-3-diphenylcyclopropyl)ethene by tert-BuOOH in the presence of [meso-tetrakis(2,4,6-trimethylphenyl)porphinato]-, [meso-tetrakis(2,6-dic (1991) (61)
- A correlation of thyroxine-like activity and chemical structure. (1956) (60)
- A Homolytic Mechanism of O-O Bond Scission Prevails in the Reactions of Alkyl Hydroperoxides with an Octacationic Tetraphenylporphinato-Iron(III) Complex in Aqueous-Solution (1995) (60)
- The mechanism of cis-trans isomerization of prolyl peptides by cyclophilin. (2002) (60)
- Syntheses of quadruply two- and three-atom, aza-bridged, cofacial bis(5,10,15,20-tetraphenylporphyrins) (1991) (59)
- Reaction mechanism of soluble epoxide hydrolase: insights from molecular dynamics simulations. (2002) (58)
- Synthesis of 7,9-didecarboxymethoxatin (4,5-dihydro-4,5-dioxo-1H-pyrrolo[2,3-f]quinoline-2-carboxylic acid) and comparison of its chemical properties with those of methoxatin and analogous o-quinones: model studies directed toward the action of PQQ requiring bacterial oxidoreductases and mammalian p (1985) (58)
- Comparison of formation of reactive conformers (NACs) for the Claisen rearrangement of chorismate to prephenate in water and in the E. coli mutase: the efficiency of the enzyme catalysis. (2003) (58)
- Oxidation of thiophenol and nitroalkanes by an electron deficient isoalloxazine (1975) (58)
- Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 2. Use of the trans-2,trans-3-diphenylcyclopropyl substituent in a search for radical intermediates (1988) (58)
- A Comparison of the Bimolecular and Intramolecular Nucleophilic Catalysis of the Hydrolysis of Substituted Phenyl Acylates by the Dimethylamino Group (1963) (58)
- Conformation of coenzyme pyrroloquinoline quinone and role of Ca2+ in the catalytic mechanism of quinoprotein methanol dehydrogenase. (1997) (57)
- Imidazole Catalysis. IV.1 The Reaction of General Bases with p-Nitrophenyl Acetate in Aqueous Solution (1958) (57)
- MECHANISM OF THE AROMATIZATION OF ARENE OXIDES. (1972) (57)
- Enzymes do what is expected (chalcone isomerase versus chorismate mutase). (2003) (56)
- Synthesis of the Polycation Thymidyl DNG, Its Fidelity in Binding Polyanionic DNA/RNA, and the Stability and Nature of the Hybrid Complexes (1995) (56)
- alpha. Effect. IV. Additional observation on the .alpha. effect employing malachite green as substrate (1971) (55)
- The importance of reactant positioning in enzyme catalysis: a hybrid quantum mechanics/molecular mechanics study of a haloalkane dehalogenase. (2000) (55)
- Dynamics of the reaction of hydrogen peroxide with a water soluble non .mu.-oxo dimer forming iron(III) tetraphenylporphyrin. 2. The reaction of hydrogen peroxide with 5,10,15,20-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinato iron(III) in aqueous solution (1990) (55)
- Use of the N-oxide of p-cyano-N,N-dimethylaniline as an "oxygen" donor in a cytochrome P-450 model system (1982) (52)
- Catalytic Reactions Involving Azomethines. VIII.1Water and Alanine Catalysis of the Transamination of 3-Hydroxypyridine-4-Aldehyde by Alanine (1967) (51)
- Hydroxyl group catalysis. II. The reactivity of the hydroxyl group of serine. The nucleophilicity of alcohols and the ease of hydrolysis of their acetyl esters as related to their pKa. (1962) (50)
- Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 3. Mechanism of oxygen transfer from substituted oxochromium(V) porphyrins to olefinic substrates (1989) (50)
- A definitive mechanism for chorismate mutase. (2005) (50)
- Symmetrical and unsymmetrical quadruply aza bridged closely interspaced cofacial bis(5,10,15,20-tetraphenylporphyrins). 3. Interplanar distances, proton NMR chemical shifts, and the catalysis of the electrochemical reduction of oxygen (1992) (50)
- The mechanism of catalysis of the chorismate to prephenate reaction by the Escherichia coli mutase enzyme (2002) (49)
- Catalysis in Water and Ice. A Comparison of the Kinetics of Hydrolysis of Acetic Anhydride, β-Propiolactone, and p-Nitrophenyl Acetate and the Dehydration of 5-Hydro-6-hydroxydeoxyuridine in Water and Ice (1964) (49)
- Focal-point conformational analysis of ethanol, propanol, and isopropanol. (2005) (49)
- Chemiluminescent reactions and electrophilic oxygen donating ability of 4a-hydroperoxyflavins: general synthetic method for the preparation of N5-alkyl-1,5-dihydroflavins. (1977) (49)
- Phosphonate Ester Hydrolysis Catalyzed by Two Lanthanum Ions. Intramolecular Nucleophilic Attack of Coordinated Hydroxide and Lewis Acid Activation (1995) (48)
- CATALYTIC REACTIONS INVOLVING AZOMETHINES. V. RATES AND EQUILIBRIA OF IMINE FORMATION WITH 3-HYDROXYPYRIDINE-4-ALDEHYDE AND AMINO ACIDS. (1965) (48)
- The kinetics for the reaction of hypochlorite with a manganese(III) porphyrin and subsequent epoxidation of alkenes in a homogeneous solution (1989) (48)
- Synthesis, biophysical properties, and nuclease resistance properties of mixed backbone oligodeoxynucleotides containing cationic internucleoside guanidinium linkages: deoxynucleic guanidine/DNA chimeras. (1998) (48)
- Catalase modeling. 2. Dynamics of reaction of a water-soluble and non .mu.-oxo dimer forming manganese(III) porphyrin with hydrogen peroxide (1987) (47)
- Statistical coevolution analysis and molecular dynamics: identification of amino acid pairs essential for catalysis. (2005) (47)
- Just a near attack conformer for catalysis (chorismate to prephenate rearrangements in water, antibody, enzymes, and their mutants). (2003) (47)
- Probing the Ser-Ser-Lys catalytic triad mechanism of peptide amidase: computational studies of the ground state, transition state, and intermediate. (2004) (47)
- Hydride vs. electron transfer in the reduction of flavin and flavin radical by 1,4-dihydropyridines (1983) (47)
- The mechanism of M.HhaI DNA C5 cytosine methyltransferase enzyme: a quantum mechanics/molecular mechanics approach. (2006) (47)
- Demonstration of a direct hydrogen transfer between NADH and a deazaflavin. (1972) (46)
- Dynamic structures of horse liver alcohol dehydrogenase (HLADH): results of molecular dynamics simulations of HLADH-NAD(+)-PhCH(2)OH, HLADH-NAD(+)-PhCH(2)O(-), and HLADH-NADH-PhCHO. (2001) (45)
- Separation of Ground State and Transition State Effects in Intramolecular and Enzymatic Reactions. 2. A Theoretical Study of the Formation of Transition States in Cyclic Anhydride Formation (1997) (45)
- Reaction of thiol anions with benzene oxide and malachite green (1976) (45)
- A novel P-450 model system for the N-dealkylation reaction (1981) (45)
- Mechanism of aldehyde oxidation catalyzed by horse liver alcohol dehydrogenase. (1996) (44)
- Stabilization of higher-valent states of iron porphyrin by hydroxide and methoxide ligands: electrochemical generation of iron(IV)-oxo porphyrins. (1985) (44)
- Imidazole Catalysis. V. The Intramolecular Participation of the Imidazolyl Group in the Hydrolysis of Some Esters and the Amide of γ-(4-Imidazolyl)-butyric Acid and 4-(2'-Acetoxyethyl)-imidazole2 (1959) (44)
- On the concept of orbital steering in catalytic reactions. (1971) (43)
- Remarkable (.apprx.1013) Rate Enhancement in Phosphonate Ester Hydrolysis Catalyzed by Two Metal Ions (1994) (43)
- Catalysis in Water and Ice. II.1 The Reaction of Thiolactones with Morpholine in Frozen Systems (1964) (43)
- Nucleophilic micelles. II. Effect on the rate of solvolysis of neutral, positively, and negatively charged esters of varied chain length when incorporated into nonfunctional and functional micelles of neutral, positive, and negative charge (1968) (43)
- 4a-Hydroperoxyflavin N-oxidation of tertiary amines (1979) (43)
- Glycoside hydrolysis. II. Intramolecular carboxyl and acetamido group catalysis in beta-glycoside hydrolysis. (1968) (42)
- Design and synthesis of deoxynucleic guanidine: a polycation analogue of DNA. (1994) (42)
- Glycoside hydrolysis. I. Intramolecular acetamido and hydroxyl group catalysis in glycoside hydrolysis (1967) (42)
- Demethylation of N,N-dimethylaniline and p-cyano-N,N-dimethylaniline and their N-oxides by cytochromes P450LM2 and P450CAM (1984) (42)
- The Synthesis of a Disulfenic Acid. Anthraquinone-1,4-disulfenic Acid (1957) (41)
- GEMINAL-DIALKYL SUBSTITUTION, INTRAMOLECULAR REACTIONS, AND ENZYME EFFICIENCY (1994) (41)
- Some electrochemical and chemical properties of methoxatin and analogous quinoquinones. (1982) (41)
- The carbanion mechanism (ElcB) of ester hydrolysis. III. Some structure-reactivity studies and the ketene intermediate (1970) (41)
- Solid-Phase Synthesis of Deoxynucleic Guanidine (DNG) Oligomers and Melting Point and Circular Dichroism Analysis of Binding Fidelity of Octameric Thymidyl Oligomers with DNA Oligomers (1999) (41)
- Mechanism of one-electron oxidation of NAD(P)H and function of NADPH bound to catalase (1993) (40)
- The Interconversion of the 5,6,7,8-Tetrahydro-, 7,8-Dihydro-, and Radical Forms of 6,6,7,7-Tetramethyldihydropterin. A Model for the Biopterin Center of Aromatic Amino Acid Mixed Function Oxidases (1984) (40)
- Chemiluminescent reactions of lucigenin. 2. Reactions of lucigenin with hydroxide ion and other nucleophiles (1979) (39)
- The mechanism of oxygen atom transfer to tetraphenylporphinato chromic chloride (1985) (39)
- alpha. Effect. II. Displacements on sp3 carbon (1967) (39)
- Spectral and electrochemical identification of iron(IV)-oxo porphyrin and iron(IV)-oxo porphyrin .pi.-cation species (1985) (39)
- Redox chemistry of water-soluble iron, manganese, and chromium metalloporphyrins and acid-base behavior of their lyate axial ligands in aqueous solution: influence of electronic effects (1992) (39)
- Kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p-cyano-N,N-dimethylaniline N-oxide with meso-(tetraphenylporphinato)iron(III) (1985) (38)
- A kinetic study of the epoxidation of 2,3-dimethyl-2-butene by tert-butyl hydroperoxide catalyzed by imidazole ligated (meso-tetraphenylporphinato)manganese(III) (1987) (38)
- Electron tunneling and ab initio calculations related to the one-electron oxidation of NAD(P)H bound to catalase. (1995) (38)
- Chemistry of phosphodiesters, DNA and models. 4. Microgonotropens and their interactions with DNA. 2. Quantitative evaluation of equilibrium constants for 1:1 and 2:1 binding of dien-microgonotropen-a, -b, and -c as well as distamycin and Hoechst 33258 to d(GGCGCAAATTTGGCGG)/d(CCGCCAAATTTGCGCC) (1993) (37)
- The kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 4. Catalysis by meso-[tetrakis(2,6-dimethylphenyl)porphinato]iron(III) chloride (1986) (37)
- Neighboring carboxyl group participation in the hydrolysis of monoesters of phthalic acid. The dependence of mechanisms on leaving group tendencies. (1966) (37)
- Rate-determining general-base catalysis in an obligate 1e- oxidation of a dihydropyridine (1984) (37)
- Ten-nanosecond molecular dynamics simulation of the motions of the horse liver alcohol dehydrogenase⋅PhCH2O− complex (2002) (37)
- Calculation of the Potential Energy Surface for Intermolecular Amide Hydrogen Bonds Using Semiempirical and Ab Initio Methods (1996) (37)
- Molecular Dynamics Simulations of Ground and Transition States for the Hydride Transfer from Formate to NAD+ in the Active Site of Formate Dehydrogenase (1999) (37)
- Histone lysine methyltransferase SET7/9: formation of a water channel precedes each methyl transfer. (2007) (37)
- Reaction of hydroxide ion with manganese(III) tetramesitylporphyrin and the oxidation states of manganese tetramesitylporphyrins (1990) (37)
- Synthesis and evaluation of a model for the so-called "charge-relay" system of the serine esterases. (1974) (36)
- Iron-sulfur clusters II: Kinetics of ligand exchange studied on a water-soluble Fe(4)S(4)(SR)(4) cluster. (1975) (36)
- Nucleophilic Displacement Reactions at the Thiol Ester Bond. IV. General Base Catalyzed Hydrolysis of Ethyl Trifluorothiolacetate. Kinetic Evidence for the Formation of a Tetrahedral Intermediate1 (1965) (36)
- COMPARISON OF THE MECHANISMS OF SOLVOLYSIS AND REARRANGEMENT OF K-REGION VS. NON-K-REGION ARENE OXIDES OF PHENANTHRENE. COMPARATIVE SOLVOLYTIC RATE CONSTANTS OF K-REGION AND NON-K-REGION ARENE OXIDES (1976) (36)
- Chemistry of phosphodiesters, DNA and models. 3. Microgonotropens and their interactions with DNA. 1. Synthesis of the tripyrrole peptides dien-microgonotropen-a, -b, and -c and characterization of their interactions with dsDNA (1993) (36)
- A theoretical examination of the acid-catalyzed and noncatalyzed ring-opening reaction of an oxirane by nucleophilic addition of acetate. Implications to epoxide hydrolases. (2001) (36)
- The thyroxine-like activity of some new thyroxine analogues in amphibia. (1954) (36)
- Reaction of methoxatin and 9-decarboxymethoxatin with benzylamine. Dynamics and products (1989) (36)
- Dynamics of reaction of [meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]iron(III) hydrate with tert-butyl hydroperoxide in aqueous solution. II. Establishment of a mechanism that involves homolytic oxygen-oxygen bond breaking and one-electron oxidation of the iron(III) porphyrin (1989) (36)
- Non-enzymatic and enzymatic hydrolysis of alkyl halides: a haloalkane dehalogenation enzyme evolved to stabilize the gas-phase transition state of an SN2 displacement reaction. (1997) (36)
- Solvolytic Chemistry of 1,4-Dimethylbenzene Oxide. A New and Novel Mechanism for the NIH Shift (1972) (36)
- REINVESTIGATION OF NADH ANALOG REDOX REACTIONS IN ACETONITRILE: CONSEQUENCES OF ISOTOPE SCRAMBLING ON KINETIC AND PRODUCT ISOTOPE EFFECTS (1982) (35)
- The gem effect. II. The influence of 3-mono- and 3,3-disubstitution on the rates of solvolysis of mono-p-bromophenyl glutarate. (1965) (35)
- Theoretical examination of Mg(2+)-mediated hydrolysis of a phosphodiester linkage as proposed for the hammerhead ribozyme. (2003) (35)
- Nucleophilic displacement on the arene oxides of phenanthrene (1976) (35)
- Molecular Dynamics Simulations of Ground and Transition States for the SN2 Displacement of Cl- from 1,2-Dichloroethane at the Active Site of Xanthobacter autotrophicus Haloalkane Dehalogenase† (1998) (35)
- The Mechanism of Phosphodiester Hydrolysis: Near In-line Attack Conformations in the Hammerhead Ribozyme (2000) (35)
- Catalytic Reactions Involving Azomethines. VII.1Rates and Equilibria of Aldimine Formation with 3-Hydroxypyridine-4-aldehyde and Alanine (1967) (35)
- Molecular mechanics calculations of the structures of polyamide nucleic acid DNA duplexes and triple helical hybrids. (1993) (35)
- Solid-phase synthesis of oligopurine deoxynucleic guanidine (DNG) and analysis of binding with DNA oligomers. (2001) (34)
- The mechanism of hydroperoxide oxygen-oxygen bond scission on reaction of hydroperoxides with iron(III) porphyrins (1988) (34)
- Catalytic Reactions Involving Azomethines. I. The Imidazole Catalysis of the Transamination of Pyridoxal by α-Aminophenylacetic Acid (1963) (34)
- Nucleophilic Displacement Reactions at the Thiol-Ester Bond of δ-Thiolvalerolactone (1963) (34)
- Transition-State and Ground-State Structures and Their Interaction with the Active-Site Residues in Catechol O-Methyltransferase (2000) (34)
- Redox chemistry of N5-ethyl-3-methyllumiflavinium cation and N5-ethyl-4a-hydroperoxy-3-methyllumiflavin in dimethylformamide. Evidence for the formation of the N5-ethyl-4a-hydroperoxy-3-methyllumiflavin anion via radical-radical coupling with superoxide ion (1981) (34)
- Mechanism of methanol oxidation by quinoprotein methanol dehydrogenase (2007) (33)
- Synthesis of a thymidyl pentamer of deoxyribonucleic guanidine and binding studies with DNA homopolynucleotides. (1995) (33)
- Comparison of formation of reactive conformers for the SN2 displacements by CH3CO2- in water and by Asp124-CO2- in a haloalkane dehalogenase. (2003) (33)
- The Structure of Anthraquinone-1-sulfenic Acid (Fries' Acid) and Related Compounds (1959) (33)
- The dynamics of reaction of a water-soluble and non-.mu.-oxo dimer forming iron(III) porphyrin with tert-butyl hydroperoxide in aqueous solution. 1. Studies using a trap for immediate oxidation products (1988) (33)
- Recognition in the minor groove of double-stranded DNA by microgonotropens. (2002) (33)
- Intramolecular catalysis of ester hydrolysis by metal complexed hydroxide ion. Acyl oxygen bond scission in cobalt(2+) and nickel(2+) carboxylic acid complexes (1977) (33)
- Peptide nucleic acid (PNA) conformation and polymorphism in PNA-DNA and PNA-RNA hybrids. (1993) (33)
- Preequilibrium complex formation and nucleophilic addition (and its position) as factors in flavine-catalyzed oxidations (1971) (32)
- Steric and electronic effects on the neighboring general acid catalyzed hydrolysis of methyl phenyl acetals of formaldehyde (1970) (32)
- REACTION OF 3O2 WITH DIHYDROFLAVINS. 1. N3,5-DIMETHYL-1,5-DIHYDROLUMIFLAVIN AND 1,5-DIHYDROISOALLOXAZINES (1978) (32)
- Anticorrelated motions as a driving force in enzyme catalysis: the dehydrogenase reaction. (2004) (32)
- The Influence of Mechanism on the Apparent pKa' of Participating Groups in Enzymic Reactions (1959) (31)
- Radical intermediates in the epoxidation of alkenes by cytochrome P-450 model systems: the design of a hypersensitive radical probe (1988) (31)
- The reaction of 5,10,15,20-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinatoiron(III) hydrate with alkyl and acyl hydroperoxides. The dynamics of reaction of water-soluble and non .mu.-oxo dimer forming iron(III) porphyrins in aqueous solution. 7 (1990) (31)
- Unusual behavior of 5,10,15,20-tetraphenylporphine diacid toward oxygen Broensted bases (1992) (31)
- The pH dependence of the mechanism of reaction of hydrogen peroxide with a nonaggregating, non-mu-oxo dimer-forming iron (III) porphyrin in water. (1986) (31)
- A search for carboxyl-group catalysis in ketal hydrolysis (1967) (31)
- 4 Proximity Effects and Enzyme Catalysis (1970) (30)
- Recognition of nine base pairs in the minor groove of DNA by a tripyrrole peptide-Hoechst conjugate. (2001) (30)
- Differentiation between the concerted and stepwise mechanisms for aromatization (NIH-shift) of arene epoxides (1972) (30)
- Acyl transfer reactions from and to the ureido functional group. III. Mechanim of intramolecular nucleophilic attack of the ureido functional group upon acyl groups (1970) (30)
- Active site dynamics of the HhaI methyltransferase: insights from computer simulation. (1999) (29)
- Transition state geometry in epoxidation by iron-oxo porphyrin at the compound I oxidation level. Epoxidation of alkenes catalyzed by a sterically hindered meso-tetrakis(2,6-dibromophenyl)porphinato iron(III) chloride (1988) (29)
- Pendant-capped porphyrins. 1. The synthesis of a biphenyl pendant-capped iron(III) porphyrin model of catalase (1991) (29)
- Consequences of breaking the Asp-His hydrogen bond of the catalytic triad: effects on the structure and dynamics of the serine esterase cutinase. (1999) (29)
- Molecular dynamics study displays near in-line attack conformations in the hammerhead ribozyme self-cleavage reaction. (1998) (29)
- Symmetrical and unsymmetrical quadruply aza-bridged closely interspaced cofacial bis(5,10,15,20-tetraphenylporphyrins). 4. Structure and conformational effects on electrochemistry and the catalysis of electrochemical reduction of dioxygen by doubly, triply, and quadruply N,N-dimethylene sulfonamide (1993) (29)
- Molecular dynamic study of orotidine-5′-monophosphate decarboxylase in ground state and in intermediate state: A role of the 203–218 loop dynamics (2002) (28)
- Displacement Reactions on 2-Acetyl-3,4-dimethylthiazolium Iodide (1966) (28)
- Transfer of oxygen from percarboxylic acids and alkyl hydroperoxides to (meso-tetraphenylporphinato)cobalt(III) chloride (1986) (28)
- Changes in the chemistry of an isoalloxazine brought about by substitution at the 7 and 8 positions by a strongly electronegative substituent. (1977) (28)
- Chemistry of phosphodiesters, DNA, and models. 2. The hydrolysis of bis(8-hydroxyquinoline) phosphate in the absence and presence of metal ions (1992) (28)
- Control of modes of intramolecular imidazole catalysis of ester hydrolysis by steric and electronic effects (1974) (28)
- Reduction of pyridoxal phosphate (and analogs) by 1,4-dihydropyridine. (1972) (28)
- Association of Short-Strand DNA Oligomers with Guanidinium-Linked Nucleosides. A Kinetic and Thermodynamic Study (1996) (28)
- Boric acid esters. I. General survey of aromatic ligands and the kinetics and mechanism of the formation and hydrolysis of boric acid esters of salicylamide, N-phenylsalicylamide, and disalicylimide (1967) (28)
- Imidazole Catalysis. VI.1 The Intramolecular Nucleophilic Catalysis of the Hydrolysis of an Acyl Thiol. The Hydrolysis of n-Propyl γ-(4-Imidazolyl)-thiolbutyrate (1959) (28)
- A computational approach to the mechanism of self-cleavage of hammerhead RNA. (1989) (27)
- Synthesis of 9-decarboxymethoxatin. Metal complexation of methoxatin as a possible requirement for its biological activity (1985) (27)
- Chemiluminescence accompanying the decomposition of 4a-flavin alkyl peroxide. Model studies of bacterial luciferase. (1977) (27)
- Kinetic Importance of Conformations of Nicotinamide Adenine Dinucleotide in the Reactions of Dehydrogenase Enzymes (1992) (27)
- Comparison of the Dynamics for Ground-State and Transition-State Structures in the Active Site of Catechol O-Methyltransferase (2000) (27)
- Hydroxyl Group Catalysis. IV. The Mechanism of Intramolecular Participation of the Aliphatic Hydroxyl Group in Amide Hydrolysis (1962) (27)
- One and two electron reduction of oxygen by 1,5-dihydroflavins (1982) (27)
- Electrochemical generation of iron(IV)-oxo porphyrins and iron(IV)-oxo porphyrin .pi. cation radicals (1986) (27)
- .alpha. Effects. III. Reaction of malachite green with primary amines, methoxylamine, and hydrazines (1971) (27)
- Reactions of S-acylisothioureas. II. Effects of structure and stereochemistry on the rates of hydrolysis, thiol elimination, and S to N acyl migration in acylic systems (1972) (27)
- Solution chemistry of arene oxides (1976) (27)
- Solid-phase synthesis of positively charged deoxynucleic guanidine (DNG) oligonucleotide mixed sequences. (2003) (27)
- Acyl transfer reactions from and to the ureido functional group. II. Mechanisms of aminolysis of an O-acylisourea (2-amino-4,5-benzo-6-oxo-1,3-oxazine) (1970) (26)
- Dependence of the primary isotope effect (kH/kD) on base strength for the primary amine catalyzed ionization of nitroethane (1970) (26)
- Rational design of substituted tripyrrole peptides that complex with DNA by both selective minor-groove binding and electrostatic interaction with the phosphate backbone. (1992) (26)
- Oxygen transfer from percarboxylic acids and alkyl hydroperoxides to (meso-tetraphenylporphinato)iron(III) and -chromium(III) (1988) (26)
- The kinetics and mechanisms of 1,5-dihydroflavin reduction of carbonyl compounds and flavin oxidation of alcohols. 2. Ethyl pyruvate, pyruvamide, and pyruvic acid (1976) (26)
- REPLACEMENT OF THE NEGATIVE PHOSPHODIESTER LINKAGES OF DNA BY POSITIVE S-METHYLTHIOUREA LINKERS : A NOVEL APPROACH TO PUTATIVE ANTISENSE AGENTS (1998) (26)
- Microgonotropens and Their Interactions with DNA. 5. Structural Characterization of the 1:1 Complex of d(CGCAAATTTGCG)2 and Tren-Microgonotropen-b by 2D NMR Spectroscopy and Restrained Molecular Modeling (1994) (26)
- Enthalpy and Entropy in Ring Closure Reactions (1998) (25)
- Theoretical Investigation of the Hydride Transfer from Formate to NAD+ and the Implications for the Catalytic Mechanism of Formate Dehydrogenase (1998) (25)
- Covalent intermediates and enzyme proficiency. (2005) (25)
- The identification of histidine-15 as part of an esteratic site of hen's egg white lysozyme. (1968) (25)
- Kinetics and mechanism of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. VII: Oxygen atom transfer to and from (meso-tetrakis(pentafluorophenyl)porphinato)iron(III) chloride (1987) (24)
- Electrostatic catalysis. IV. Intramolecular carboxyl group electrostatic facilitation of the A-1-catalyzed hydrolysis of alkyl phenyl acetals of formaldehyde. Influence of oxocarbonium ion stability (1971) (24)
- The Reaction of Aliphatic Diamines with Phenyl Acetate (1965) (24)
- Chiral recognition of prochiral centers. (2S,9S)-2,9-Diamino-4,7-diazadecanecobalt(III) mediated decarboxylation of aminoalkylmalonic acids (1974) (24)
- Reaction of sulfite with isoalloxazines. (1973) (24)
- In silico studies of the mechanism of methanol oxidation by quinoprotein methanol dehydrogenase. (2003) (24)
- Carbonion (ElcB)mechanism of ester hydrolysis. I. Hydrolysis of malonate esters (1969) (24)
- The Mechanism of the Reaction of Tris-(hydroxymethyl)-aminomethane and Pentaerythritol with Phenyl Esters (1961) (24)
- THE SYNTHESIS OF SOME NEW THYROXINE ANALOGS (1953) (24)
- Symmetrical and unsymmetrical quadruply aza-bridged, closely interspaced, cofacial bis(5,10,15,20-tetraphenylporphyrin)s. 2. Synthesis, characterization, and conformational effects of solvents (1992) (24)
- Transition state stabilization by general acid catalysis, water expulsion, and enzyme reorganization in Medicago savita chalcone isomerase. (2004) (24)
- Letter: The importance of 1,2-enediols in the reduction of lumiflavin by alpha-ketols. (1974) (23)
- Catalytic reactions involving azomethines. VI. The mechanism of the transamination of 3-hydroxypyridine-4-aldehyde by glutamic acid. (1965) (23)
- What Is the Mechanism of Catalysis of Ester Aminolysis by Weak Amine Bases? Comparison of Experimental Studies and Theoretical Investigation of the Aminolysis of Substituted Phenyl Esters of Quinoline-6- and -8-Carboxylic Acids (1998) (23)
- Sequence specific DNA binding of Ets-1 transcription factor: molecular dynamics study on the Ets domain--DNA complexes. (2003) (23)
- Leaving group tendencies and the rates of mono-oxygen donation by hydrogen peroxide, organic hydroperoxides, and peroxycarboxylic acids (1983) (23)
- Systematic convergence of energies with respect to basis set and treatment of electron correlation: focal-point conformational analysis of methanol (2004) (23)
- Nucleophilic Displacement Reactions at the Thiolester Bond. III.1Kinetic Demonstration of Metastable Intermediates in the Hydroxylaminolysis and Methoxylaminolysis of Thiolesters and Thiolactones in Aqueous Solutions (1964) (23)
- Double-stranded DNA binding characteristics and subcellular distribution of a minor groove binding diphenyl ether bisbenzimidazole. (2001) (23)
- Nucleophilic Displacement Reactions at the Thiol Ester Bond. V. Reactions of 2,2,2-Trifluoroethyl Thiolacetate (1967) (23)
- Binding studies of cationic thymidyl deoxyribonucleic guanidine to RNA homopolynucleotides. (1995) (23)
- Ring strain and general acid catalysis of acetal hydrolysis. Lysozyme catalysis (1974) (23)
- Synthesis of ribonucleic guanidine: replacement of the negative phosphodiester linkages of RNA with positive guanidinium linkages (2002) (23)
- Targeting E2F1-DNA complexes with microgonotropen DNA binding agents. (1997) (23)
- Mechanism of mercury(II) reductase and influence of ligation on the reduction of mercury(II) by a water soluble 1,5-dihydroflavin. (1989) (22)
- Solid-phase synthesis of positively charged deoxynucleic guanidine (DNG) tethering a Hoechst 33258 analogue: triplex and duplex stabilization by simultaneous minor groove binding. (2004) (22)
- The importance of the ".alpha. effect" in amine general base catalyzed ionization of nitroethane (1967) (22)
- Microgonotropens and Their Interactions with DNA. 4. Synthesis of the Tripyrrole Peptides Tren-Microgonotropen-a and -b and Characterization of Their Interactions with dsDNA (1994) (22)
- Glycoside hydrolysis. III. Intramolecular acetamido group participation in the specific acid catalyzed hydrolysis of methyl 2-acetamido-2-deoxy-.beta.-D-glucopyranoside (1968) (22)
- Model reactions which establish a facile reduction of pyridoxal phosphate and analogs by 1,4-dihydropyridines. (1973) (22)
- The Acid-Base Properties, Hydrolytic Mechanism, and Susceptibility to O2 Oxidation of Fe4S4(SR)4-2 Clusters (1975) (22)
- Determination of enzyme mechanisms by molecular dynamics: Studies on quinoproteins, methanol dehydrogenase, and soluble glucose dehydrogenase (2004) (22)
- The chemistry of a 1,5-diblocked flavin. I: Interconversion of the reduced, radical, and oxidized forms of 1,10-ethano-5-ethyllumiflavin (1983) (22)
- DNG cytidine: synthesis and binding properties of octameric guanidinium-linked deoxycytidine oligomer. (2004) (22)
- Aminolysis of esters. IX. Nature of transition states in the aminolysis of phenyl acetates (1970) (22)
- Mechanism of product specificity of AdoMet methylation catalyzed by lysine methyltransferases: transcriptional factor p53 methylation by histone lysine methyltransferase SET7/9. (2008) (22)
- Triple-helix formation of DNA oligomers with methylthiourea-linked nucleosides (DNmt): a kinetic and thermodynamic analysis. (1999) (22)
- Product specificity and mechanism of protein lysine methyltransferases: insights from the histone lysine methyltransferase SET8. (2008) (22)
- On the Dehalogenation Mechanism of 4-Chlorobenzoyl CoA by 4-Chlorobenzoyl CoA Dehalogenase: Insights from Study Based on the Nonenzymatic Reaction (1997) (22)
- Electrostatic catalysis. II. Comparison of spontaneous and alkaline hydrolytic rate constants for .alpha.-substituted o-nitrophenyl esters (1969) (22)
- Evaluation of the selectivity of the epoxidation of cis- versus trans-alkenes by oxo[meso-tetrakis(2,6-dibromophenyl)porphinato]chromium(V). Dynamics, products, and Van der Waals energies (1991) (22)
- Stoichiometry and structure of complexes of DNA oligomers with microgonotropens and distamycin by 1H NMR spectroscopy and molecular modeling. (1993) (22)
- Reaction of [meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]iron(III) hydrate with various acyl and alkyl hydroperoxides in aqueous solution (1989) (21)
- CATALYTIC REACTIONS INVOLVING AZOMETHINES. IV. RATES AND EQUILIBRIA OF IMINE FORMATION WITH PYRIDINE-4-ALDEHYDE AND VARIOUS AMINO ACIDS. (1964) (21)
- Replacement of the phosphorodiester linkages of RNA with guanidinium linkages: the solid-phase synthesis of ribonucleic guanidine. (2000) (21)
- Oxygen walk as a complementary observation to the NIH shift (1973) (21)
- Question of Covalent Intermediate Formation in the Flavine-Catalyzed Carbonyl to Carbinol Oxidation-Reduction Reaction (1973) (21)
- Proton NMR investigation of iron(III) 5,10,15,20-tetrakis(2,6-disubstituted phenyl)porphyrins. Isolation and characterization of hydroxy-ligated (5,10,15,20-tetrakis(2,6-difluorophenyl)porphinato)iron(III) (1986) (21)
- Intramolecular general-base-catalyzed hydrolysis and aminolysis of the ester bond by imidazole and quinoline bases (1969) (21)
- Derivatives of Sulfenic Acids. V. 1-Fluorenone Sulfur Compounds1 (1951) (21)
- Kinetics and mechanisms of the 1,5-dihydroflavin reduction of carbonyl compounds and the flavin oxidation of alcohols. 4. Interconversion of formaldehyde and methanol. (1977) (21)
- A theoretical examination of the factors controlling the catalytic efficiency of the DNA-(adenine-N6)-methyltransferase from Thermus aquaticus (2002) (21)
- Multiple pathways for aromatization of 8,9-indan oxide (1973) (21)
- Oxygen transfer involving non-heme iron. The reaction of (EDTA)Fe(III) with m-chloroperbenzoic acid (1986) (20)
- Electrochemistry and the dependence of potentials on pH of iron and manganese tetraphenylporphyrins in aqueous solution (1991) (20)
- Synthesis of fluorescent microgonotropens (FMGTs) and their interactions with dsDNA. (2000) (20)
- Influence of nitrogen base ligation on the rate of reaction of [5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]iron(III) hydrate with tert-BuOOH in aqueous solution (1993) (20)
- Nanosecond Molecular Dynamics of Hybrid Triplex and Duplex of Polycation Deoxyribonucleic Guanidine Strands with a Complimentary DNA Strand (1998) (20)
- Reactions of S-acylisothioureas. I. S- to N-acyl migrations in S-benzoylisothiobiotin and analogs. (1971) (20)
- Solvation and approximation. Solvent effects on the bimolecular and intramolecular nucleophilic attack of carboxyl anion on phenyl esters (1970) (20)
- A synthetic tetranuclear iron-sulfur complex with ionized side chains: the crystal structure of (Fe4S4(S(CH2)2COO)4)(6-)-(Na5-N(C4H9)4)(6+)-5C5H9NO. (1977) (20)
- Catalytic reactions involving azomethines. X. Transamination of 1-methyl-4-formylpyridinium iodide. (1968) (20)
- Differentiation between Criegee rearrangement and dioxetane rearrangement mechanisms for the decomposition of .alpha.,.beta.-unsaturated hydroperoxides (1980) (20)
- Sequence selective recognition in the minor groove of dsDNA by pyrrole, imidazole-substituted bis-benzimidazole conjugates. (2003) (20)
- Electrostatic catalysis. III. Comparison of the reactivity of .alpha.-substituted o-nitrophenyl esters with anionic and amine nucleophiles (1969) (20)
- Catalytic reactions involving azomethines. XII. Mechanism of hydrolysis of primary and secondary enamines (1969) (19)
- Comparison of the rate constants for general base catalyzed prototropy and racemization of the aldimine species formed from 3-hydroxypyridine-4-carboxaldehyde and alanine. (1973) (19)
- The gem effect. I. The influence of 3-substituents on the rates of solvolysis of glutaric anhydride. A conformational analysis. (1965) (19)
- Hydroxyl Group (V)1 and Imidazole (X)2 Catalysis. The General Base Catalysis of Ester Hydrolysis by Imidazole and the Influence of a Neighboring Hydroxyl Group (1962) (19)
- The mechanism of flavin 4a substitution which accompanies photolytic decarboxylation of .alpha.-substituted acetic acids. Carbanion vs. radical intermediates (1980) (19)
- Mechanisms of isoalloxazine (flavine) hydrolysis. (1975) (19)
- Bicyclo[2.2.2]octane-capped porphyrins. 1. Synthesis, characterization, and solution three-dimensional structure (1992) (18)
- Oxygen donation to manganese(III) tetraphenylporphyrin chloride. Low reactivity of hydroperoxides as oxygen donors to manganese(III) porphyrins (1985) (18)
- ELECTROCHEMICAL LUMINESCENCE WITH N(5)‐ETHYL‐4a‐HYDROXY‐3‐METHYL‐4a, 5‐DIHYDROLUMIFLAVIN. THE MECHANISM OF BACTERIAL LUCIFERASE (1990) (18)
- Chemical Studies Pertaining to the Chemistry of Cytochrome P‐450 and the Peroxidases a (1986) (18)
- Catalytic mechanism and product specificity of rubisco large subunit methyltransferase: QM/MM and MD investigations. (2007) (18)
- Conformations and dynamics of Ets-1 ETS domain–DNA complexes (2003) (18)
- Intramolecular general base catalyzed hydrolysis and tertiary amine nucleophilic attack vs. general base catalyzed hydrolysis of substituted phenyl quinoline-8- and -6-carboxylates (1974) (17)
- Imidazole Catalysis. VII. The Dependence of Imidazole Catalysis of Ester Hydrolysis on the Nature of the Acyl Group1 (1960) (17)
- Design and synthesis of ribonucleic guanidine: a polycationic analog of RNA. (1996) (17)
- The rate-limiting step in the one-electron oxidation of an alkene by oxo[meso-tetrakis(2,6-dibromophenyl)porphinato]-chromium(V) is the formation of a charge-transfer complex (1991) (17)
- DNA sequence recognition in the minor groove by hairpin pyrrole polyamide-Hoechst 33258 analogue conjugate. (2004) (17)
- Solid-phase synthesis of positively charged deoxynucleic guanidine (DNG) modified oligonucleotides containing neutral urea linkages: effect of charge deletions on binding and fidelity. (2000) (17)
- One and two electron transfer reactions of glucose oxidase. (1977) (17)
- The Linear Dependence of Log(kcat/Km) for Reduction of NAD+ by PhCH2OH on the Distance between Reactants when Catalyzed by Horse Liver Alcohol Dehydrogenase and 203 Single Point Mutants☆ (1999) (17)
- Assistance of protodemercuration by bis-thiol ligation and nucleophilic catalysis: a model study which relates to the organomercurial lyase reaction (1987) (17)
- Multiple substrate binding states and chiral recognition in cofactor-independent glutamate racemase: a molecular dynamics study. (2004) (17)
- Mechanism of glucose oxidation by quinoprotein soluble glucose dehydrogenase: insights from molecular dynamics studies. (2004) (17)
- Kinetics and mechanism of the isoalloxazine (flavine) dehydrogenation of dimethyl dihydrophthalates. (1972) (17)
- Intramolecular amine-catalyzed ketone enolization. A search for concerted intramolecular general-base, general-acid catalysis (1969) (17)
- Catalytic Reactions Involving Azomethines. III.1 The Influence of Morpholine upon the Imidazole Catalysis of the Transamination of Pyridoxal by α-Aminophenylacetic Acid. The Transamination of the Morpholine Imine of Pyridoxal (1963) (17)
- Nonenzymatic and enzymatic hydrolysis of alkyl halides: a theoretical study of the SN2 reactions of acetate and hydroxide ions with alkyl chlorides. (1997) (17)
- Participation of Two Carboxyl Groups in Phosphodiester Hydrolysis. 2. A Kinetic, Isotopic, and 31P NMR Study of the Hydrolysis of a Phosphodiester with Carboxyl Groups Fixed in an Attack Conformation (1995) (16)
- The question of the importance of electrostatic catalysis. I. Comparison of the reactivity of o-nitrophenyl hydrogen oxalate and ethyl o-nitrophenyl oxalate toward nucleophiles. (1967) (16)
- Role of intramolecular bifunctional catalysis of ester hydrolysis in water (1971) (16)
- Reaction of nitroxides with 1,5-dihydroflavins and N3,5-dimethyl-1,5-dihydrolumiflavin. (1977) (16)
- SYNTHESIS AND CHARACTERIZATION OF THE FIRST WATER-SOLUBLE CLOSELY INTERSPACED COFACIAL PORPHYRIN DIMER (1991) (16)
- Isolation of a tetrahedral intermediate in an acetyl transfer reaction (1973) (16)
- TRANSFER OF OXYGEN FROM A 4A-HYDROPEROXYFLAVIN ANION TO A PHENOLATE ION. A FLAVIN-CATALYZED DIOXYGENATION REACTION (1979) (16)
- A novel mechanism for the NIH-shift. (1972) (16)
- Neighboring Hydroxyl Group Assistance. VI. In Amide Hydrolysis (1965) (16)
- Synthesis and Characterization of an Octacationic Iron(III) Tetraphenylporphyrin, Which Is Soluble in Water and Non-.mu.-Oxo Dimer Forming (1995) (16)
- Catalytic Reactions Involving Azomethines. II. The pH Dependence of the Imidazole Catalysis of the Transamination of Pyridoxal by α-Aminophenylacetic Acid (1963) (16)
- Reactions of 4a-peroxides and 4a-pseudobases of N10- and N5-phenethylflavins (1980) (16)
- Biotin and the nucleophilicity of 2-methoxy-2-imidazoline toward the sp2 carbonyl carbon (1969) (16)
- Studies on a hydrocarbon capped free base tetraphenylporphyrin and its conjugate acids - first observation of a monoprotonated tetrapehylporphyrin &{;CapTPP(H3+)CF3CO2−&}; (1993) (15)
- Comparison of Reaction Energetics and Leaving Group Interactions during the Enzyme-Catalyzed and Uncatalyzed Displacement of Chloride from Haloalkanes (2003) (15)
- Notes - Reaction of Cyanide with Triketohydrindane Hydrate (Ninhydrin) (1958) (15)
- Biotin-bound CO2 and the mechanism of enzymatic carboxylation reactions. (1970) (15)
- Deoxynucleic Guanidine/Peptide Nucleic Acid Chimeras: Synthesis, Binding and Invasion Studies with DNA (2000) (15)
- ON THE MECHANISM OF FLAVIN-CATALYZED DEHYDROGENATION α,β TO AN ACYL FUNCTION. THE MECHANISM OF 1,5-DIHYDROFLAVIN REDUCTION OF MALEIMIDES (1984) (15)
- Theoretical investigation of the [1,2]-sigmatropic hydrogen migration in the mechanism of oxidation of 2-aminobenzoyl-CoA by 2-aminobenzoyl-CoA monooxygenase/reductase. (1999) (15)
- Observations and comments on the mechanism of epoxidation of alkenes by manganese(III) porphyrins with hypochlorite. (1988) (15)
- Computational study of IAG-nucleoside hydrolase: determination of the preferred ground state conformation and the role of active site residues. (2005) (15)
- Lack of concertedness in the catalysis of the enolization of oxaloacetic acid by general acids and bases. Formation of a carbinolamine intermediate in the tertiary amine catalyzed enolization reaction (1978) (15)
- Computational study of ketosteroid isomerase: insights from molecular dynamics simulation of enzyme bound substrate and intermediate. (2003) (15)
- Temperature-Dependent Structure of the E·S Complex of Bacillus stearothermophilus Alcohol Dehydrogenase† (2007) (15)
- Deoxynucleic guanidine; synthesis and incorporation of purine nucleosides into positively charged DNG oligonucleotides. (2004) (15)
- Molecular dynamics studies of ground state and intermediate of the hyperthermophilic indole-3-glycerol phosphate synthase. (2004) (15)
- The chemistry of an N5-methyl-1,5-dihydroflavin and its aminium cation radical. (1976) (15)
- Positively Charged Deoxynucleic Methylthioureas: Synthesis and Binding Properties of Pentameric Thymidyl Methylthiourea (1998) (15)
- A View at the Millennium: The Efficiency of Enzymatic Catalysis (2002) (15)
- The Mechanism of the Reaction of Hydroxylamine with γ-Butyro- and δ-Valerolactones. Examples of Reactions Kinetically both Third and Fourth Order (1961) (15)
- Incorporation of positively charged deoxynucleic S-methylthiourea linkages into oligodeoxyribonucleotides. (2001) (15)
- Reaction of indolenine salts with nucleophiles (1967) (15)
- Radical mechanisms for 1,5-dihydroflavin reduction of carbonyl compounds. (1975) (15)
- Mechanism of hydrolysis of benzoyl glucose acylals (1973) (15)
- Role of a critical water in scytalone dehydratase-catalyzed reaction. (1998) (15)
- THE KINETICS AND MECHANISMS OF 1,5-DIHYDROFLAVIN REDUCTION OF CARBONYL COMPOUNDS AND FLAVIN OXIDATION OF ALCOHOLS. 3. OXIDATION OF BENZOIN BY FLAVIN N AND REDUCTION OF BENZIL BY 1,5-DIHYDROFLAVIN (1976) (15)
- Mechanism for chiral recognition of a prochiral center and for amino acid complexation to a cobalt(3) tetramine. The crystal structure, absolute configuration, and circular dichroism of lambda(-)436-beta2-(2S,9S)-2,9-diamino-4,7-diazadecanecobalt(3) aminomethylmalonate) perchlorate monohydrate. (1974) (15)
- Oxidation of aminophenols by 4a-hydroperoxy-5-ethyllumiflavin anion. Flavoenzyme hydroxylase mechanism (1990) (14)
- Synthesis and study of a 6-amino-5-oxo-3H,5H-uracil and derivatives. The structure of an intermediate proposed in mechanisms of flavin and pterin oxygenases (1983) (14)
- A microgonotropen branched decaaza decabutylamine and its DNA and DNA/transcription factor interactions. (1997) (14)
- Mechanisms of ammonia activation and ammonium ion inhibition of quinoprotein methanol dehydrogenase: a computational approach. (2004) (14)
- The active site dynamics of 4-chlorobenzoyl-CoA dehalogenase (2001) (14)
- The Negative Charge of Alkyl Phosphate Diesters and The Slow-Gaited Hydrolysis of RNA and DNA. Catalysis of RNA Hydrolysis through Metal Ion Ligation to the Ester >PO2- Moiety (1994) (14)
- The formation of thiiranes from olefins in the course of the deoxygenation of tertiary amine N-oxides by carbon disulfide (1985) (14)
- Hydrolytic Reactions of 4(5)-Hydroxymethylimidazolyl Acetate, 1-Methyl-5-Hydroxymethylimidazolyl Acetate, 4(5)-Chloromethylimidazole, and 1-Methyl-5-chloromethylimidazole (1964) (14)
- Synthesis of protected guanidinium linked dinucleoside incorporable into an oligonucleotide using solid phase DNA methodology. (1998) (14)
- Dynamics of reaction of [5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]iron(III) hydrate with tert-butyl hydroperoxide in aqueous solution. 3. Comparison of refined kinetic parameters and D2O solvent isotope effects to those for [5,10,15,20-tetrakis(2,6-dichloro-3-sulfonatophenyl)por (1991) (14)
- Fidelity of binding of the guanidinium nucleic acid (DNG) d(Tg)4-T-azido with short strand DNA oligomers (A5G3A5, GA4G3A4G, G2A3G3A3G2, G2A2G5A2G2). A kinetic and thermodynamic study. (1997) (14)
- Extended ElcB mechanism for ester hydrolysis: allylic substitution via carbanion in ester hydrolysis (1982) (14)
- DNA sequence recognition by Hoechst 33258 conjugates of hairpin pyrrole/imidazole polyamides. (2006) (14)
- Radical mechanisms for 1,5-dihydro-5-methylflavine reduction of carbonyl compounds. (1975) (14)
- Hydrolysis and aminolysis of O-acylhydroxyquinolines. Intracomplex general base-catalyzed aminolysis (1971) (13)
- Nucleophilic Displacement Reactions at the Thiolester Bond. II. Hydrazinolysis and Morpholinolysis in Aqueous Solution (1964) (13)
- Concerning 1e- transfer in reduction by dihydronicotinamide: reaction of oxidized flavin and flavin radical with N-benzyl-1,5-dihydronicotinamide. (1982) (13)
- The dynamics of the reactions of methyl diphenylhydroperoxyacetate with meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinatomanganese(III) hydrate and meso-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinatomanganese(III) hydrate and imidazole complexes. Comparison of the reactions of manganese(II (1991) (13)
- MECHANISMS OF ISOALLOXAZINE (FLAVINE) HYDROLYSIS (1975) (13)
- Chemistry of 1-carba-1-deaza-N5-ethyl-N3-methyllumiflavins. Influence of the N1 upon the reactivity of flavin 4a-hydroperoxides (1981) (13)
- Formation of a nonchemiluminescent excited-state species in the decomposition of 4a-(alkylperoxy)flavins (1980) (13)
- Solution chemistry of the syn- and anti-tetrahydrodiol epoxides, the syn- and anti-tetrahydrodimethoxy epoxides, and the 1,2- and 1,4-tetrahydro epoxides of naphthalene (1979) (13)
- Diels-Alder ribozyme catalysis: a computational approach. (2007) (13)
- The Kinetic Demonstration of a Metastable Intermediate in a Nucleophilic Displacement at a Thiol-Ester Bond (1964) (13)
- Inactivation of glyceraldehyde-3-phosphate dehydrogenase and yeast alcohol dehydrogenase by arene oxides. (1978) (13)
- Computational study of the ground state of thermophilic indole glycerol phosphate synthase: structural alterations at the active site with temperature. (2004) (13)
- Binding studies of cationic uridyl ribonucleic guanidine (RNG) to DNA. (2005) (13)
- Recognition of a 10 base pair sequence of DNA and stereochemical control of the binding affinity of chiral hairpin polyamide-Hoechst 33258 conjugates. (2005) (13)
- Solid-phase synthesis of oligomeric deoxynucleic guanidine (DNG): a polycationic analogue of DNA. (1998) (13)
- A microgonotropen pentaaza pentabutylamine and its interactions with DNA. (1996) (13)
- Solid-phase synthesis of positively charged deoxynucleic guanidine (DNG) oligonucleotide incorporating 7-deazaguanine bases. (2006) (12)
- Synthesis of a spheroidal bis-porphyrin: a ligand designed to accept two catalytic metal ions in an isolated environment (1994) (12)
- Studies on the radical species of 9-decarboxymethoxatin (1987) (12)
- Physical organic models for the mechanism of lysozyme action. (1973) (12)
- Generation and evaluation of putative neuroregenerative drugs. Part 2: screening virtual libraries of novel polyketides which possess the binding domain of rapamycin. (2000) (12)
- The mechanisms for chymotrypsin. (1961) (12)
- The gem effect. IV. Activation parameters accompanying the increased steric requirements of 3,3'-substituents in the solvolysis of mono(p-bromophenyl) glutarates (1968) (12)
- Oxidation of N-nitrosodibenzylamine and related compounds by metalloporphyrin-catalysed model systems for the cytochrome P450 dependent mono-oxygenases (1984) (12)
- Recognition of nine base pair sequences in the minor groove of DNA at subpicomolar concentrations by a novel microgonotropen. (2002) (12)
- Catalytic reactions involving azomethines. XII. Transamination of 1-methyl-3-hydroxy-4-formylpyridinium chloride. (1970) (12)
- Inhibiting transcription factor/DNA complexes using fluorescent microgonotropens (FMGTs). (2002) (12)
- Mechanisms of formation and equilibria of 4a and 5 adducts of an isoalloxazine. Reaction of 10-(2',6'-dimethylphenyl)-3-methylisoalloxazine-6,8-disulfonate with sulfite in aqueous media. (1973) (12)
- First synthesis of a pendant-capped porphyrin. A biphenyl pendant-capped porphyrin model of catalase (1990) (12)
- Recent Studies of Nucleophilic, General‐Acid, and Metal Ion Catalysis of Phosphate Diester Hydrolysis (1999) (12)
- Synthesis of 2-oxabicyclo[2.2.2]octane (1970) (12)
- Low-frequency normal modes in horse liver alcohol dehydrogenase and motions of residues involved in the enzymatic reaction. (2007) (12)
- Ribonucleic guanidine demonstrates an unexpected marked preference for complementary DNA rather than RNA. (2006) (12)
- Aminolysis of Phenyl Acetates in Aqueous Solutions. V.1 Hypernucleophilicity Associated with Constraint of Bond Angles (1966) (12)
- Carbanion mechanism of ester hydrolysis. II. o-Nitrophenyl .alpha.-cyano- and .alpha.-dimethylsulfonioacetate esters (1969) (12)
- Photocatalysis of oxygen transfer from p-cyano-N,N-dimethylaniline N-oxide to meso-(tetraphenylporphinato)chromium(III) chloride (1985) (12)
- Kinetics and mechanism of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 6. Oxygen atom transfer to and from the iron(III) C/sub 2/Cap porphyrin of Baldwin (1987) (11)
- The chemistry of an electron-deficient 5-deazaflavin. 8-Cyano-10-methyl-5-deazaisoalloxazine. (1977) (11)
- The catalysis of the hydrolysis of p-nitrophenyl acetate by imidazole and its derivatives. (1956) (11)
- Nucleophilic micelles. I. (1967) (11)
- Establishment of a carbanion mechanism for ester hydrolysis and the unimportance of electrostatic effects of .alpha. substituents on the rates of hydroxide ion attack at the ester carbonyl group (1968) (11)
- Imidazole Catalysis. III.1 The Solvolysis of 4-(2'-Acetoxyphenyl)-imidazole (1958) (11)
- Exploring nucleoside hydrolase catalysis in silico: molecular dynamics study of enzyme-bound substrate and transition state. (2002) (11)
- Subchoroidal Release of VEGF and bFGF Produces Choroidal Neovascularization in Rabbit (2017) (11)
- Synthesis of a fluorescent microgonotropen (FMGT-1) and its interactions with the dodecamer d(CCGGAATTCCGG). (1999) (11)
- Reaction of primary amines with the dichlorocarbene complex of iron(II) tetraphenylporphyrin [FeIITPP(CCl2)] (1981) (11)
- The nature of neighboring hydroxyl group assistance in the alkaline hydrolysis of the ester bond (1961) (11)
- Oxygen transfer involving nonheme iron: the influence of leaving group ability on the rate constant for oxygen transfer to (EDTA)Fe(III) from peroxycarboxylic acids and hydroperoxides. (1987) (11)
- Quinoprotein methanol dehydrogenase: a molecular dynamics study and comparison with crystal structure (2003) (11)
- A quantum mechanics/molecular mechanics study of the catalytic mechanism and product specificity of viral histone lysine methyltransferase. (2007) (11)
- Aminolysis of substituted phenyl quinoline-8- and -6-carboxylates with primary and secondary amines. Involvement of proton-slide catalysis (1974) (11)
- Protein engineering of nitrile hydratase activity of papain: molecular dynamics study of a mutant and wild-type enzyme. (2002) (11)
- Lack of an .alpha. effect for proton abstraction from carbon acids (1972) (11)
- Catalytic reactions involving azomethines. XI. Kinetics of condensation of histamine with 3-hydroxypyridine-4-carboxaldehyde. An intramolecular Mannich reaction (1969) (11)
- A novel minor groove binding reagent designed to serve as a "truck" to carry DNA modifying moieties into the major groove. (1995) (10)
- Neighboring carboxyl group catalysis of hydrolysis of methyl phenyl acetals of formaldehyde. Electrostatic and solvent effects (1970) (10)
- Derivatives of Sulfenic Acids. XVII. The Hydrolysis of 2,4-Dinitrobenzenesulfenyl Chloride (1955) (10)
- Dynamics of the reactions of [meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]-manganese(III) hydrate with various alkyl hydroperoxides in aqueous solution. Product studies and comparison of kinetic parameters (1992) (10)
- Oxidation of (tetraphenylporphyrin)chromium(III) chloride by styrene ozonide (1986) (10)
- Generation and evaluation of putative neuroregenerative drugs. Part 1: virtual point mutations to the polyketide rapamycin. (2000) (10)
- Oxidation of 9-hydroxy- and 9-methoxyfluorene carbanions by flavin. Proof of radical mechanism (1977) (10)
- Dioxygen transfer from 4a-hydroperoxyflavin anion. 2. Oxygen transfer to the 10 position of 9-hydroxyphenanthrene anions and to 3,5-di-tert-butylcatechol anion (1980) (10)
- Solid-phase synthesis of oligomeric deoxynucleic-thiourea (DNT) and deoxynucleic S-methylthiourea (DNmt): a neutral/polycationic analogue of DNA. (2000) (10)
- Mechanisms of acyl group transfer from a tetrahedral intermediate (1974) (10)
- Equilibrium titration and pH-stat cell for a Cary 15 spectrophotometer. (1970) (10)
- Incorporation of positively charged ribonucleic guanidine linkages into oligodeoxyribonucleotides: Development of potent antisense agents. (2008) (10)
- Chemistry of phosphodiesters, DNA and models. 5. Microgonotropens and their interactions with DNA. 3. Structural analysis of the 1:1 complex of d(CGCAAATTTGCG)2 and dien-microgonotropen-c by 2D NMR spectroscopy and restrained molecular modeling (1993) (10)
- Dynamics of reaction of [meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]-iron(III) hydrate with various alkyl hydroperoxides in aqueous solution. 4. Comparison of kinetic parameters and D2O solvent isotope effects (1991) (10)
- Epoxidation of alkenes by oxo[5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]chromium(V) in aqueous solution (1990) (10)
- THE IMPORTANCE OF 1,2-ENEDIOLS IN THE REDUCTION OF LUMIFLAVIN BY ALPHA-KETOLS (1975) (10)
- Diphtheria toxin catalyzed hydrolysis of NAD(+): molecular dynamics study of enzyme-bound substrate, transition state, and inhibitor. (2001) (10)
- FIDELITY OF DEOXYNUCLEIC S-METHYTHIOUREA (DNMT) BINDING TO DNA OLIGOMERS :INFLUENCE OF C MISMATCHES (1999) (10)
- Oxygen transfer from p-cyano-N,N-dimethylaniline N-oxide to the .mu.-oxo dimer of (meso-tetraphenylporphinato)iron(III) (1988) (10)
- Evidence for an intermediate adduct in the ethylenediaminetetraacetic acid mediated photoreduction of flavines (1973) (10)
- Binding properties of positively charged deoxynucleic guanidine (DNG), AgTgAgTgAgT and DNG/DNA chimeras to DNA. (2008) (10)
- Is strong hydrogen bonding in the transition state enough to account for the observed rate acceleration in a mutant of papain? (1997) (10)
- NANOSECOND MOLECULAR DYNAMICS STUDY OF A POLYCATION RIBONUCLEIC GUANIDINE (RNG) DUPLEXED WITH A COMPLEMENTARY DNA OLIGOMER STRAND (1997) (10)
- Interaction of cellodextrins with lysozyme: the necessity of the 2-acetamido group for binding and hydrolysis. (1969) (10)
- Design, synthesis, and characterization of a "shopping basket" bisporphyrin. The first examples of triply bridged closely interspaced cofacial porphyrin dimers (1992) (9)
- Intramolecular amine-catalyzed aminolysis of an ester (1969) (9)
- Complexation of single strand telomere and telomerase RNA template polyanions by deoxyribonucleic guanidine (DNG) polycations: plausible anticancer agents. (2008) (9)
- Low-frequency normal mode in DNA HhaI methyltransferase and motions of residues involved in the base flipping. (2005) (9)
- Dioxygen transfer from 4a-hydroperoxyflavin anion. 4. Dioxygen transfer to phenolate anion as a means of aromatic hydroxylation (1982) (9)
- Importance of C4a- and N5-covalent adducts in the flavin oxidation of carbanions. (1978) (9)
- 1H NMR Study of the Rates and Isotope Effects of the NADH Model Hydride Transfer Reaction (1993) (9)
- Comparative chemistry of the bay- and non-bay-region tetrahydro epoxides of phenanthrene (1979) (9)
- Deoxynucleic Guanidines/PNA (DNG/PNA) Chimeras: Oligonucleoside Analogue Containing Cationic Guanidinium and Neutral Amide Linkages (1999) (9)
- A Facile Base-catalyzed Ester Hydrolysis Involving Alkyl-Oxygen Cleavage. The Mechanism of Hydrolysis of Esters of 4(5)-Hydroxymethylimidazole1 (1961) (9)
- Reaction mechanism of guanidinoacetate methyltransferase, concerted or step-wise (2006) (9)
- A molecular dynamics approach to the study of symmetrical and unsymmetrical quadruply bridged, closely interspaced cofacial tetraphenylporphyrin dimers (1992) (9)
- Participation of Two Carboxyl Groups in Phosphodiester Hydrolysis. 1. Hydrolysis of Bis(2-carboxyphenyl) Phosphate (1995) (9)
- Influence of steric effects upon the rate constants for competing BAC2 and E1cB ester hydrolyses (1983) (8)
- Amine catalysis and spontaneous and specific acid catalyses of the dienone-phenol rearrangement (1977) (8)
- THE LACK OF CONCERTEDNESS IN THE GENERAL ACID-BASE CATALYSIS OF THE ENOLIZATION OF OXALACETIC ACID. A CASE FOR STEPWISE NUCLEOPHILIC-GENERAL BASE CATALYSIS (1976) (8)
- Use of an oxaziridine as an oxene transfer agent to manganese(III)tetraphenylporphyrin chloride (1985) (8)
- Comparative mechanisms of reaction of K-region and non-K-region arene oxides of phenanthrene (1974) (8)
- Use of riboflavin-binding protein to investigate steric and electronic relationships in flavin analogs and models. (1984) (8)
- Acyl transfer reactions from and to the Ureido functional group. IV. Neighboring carboxyl group general acid catalysis in the hydrolysis of an O-acylisourea (2-amino-8-carboxy-4-oxo-3,1,4-benzoxazine (1971) (8)
- The importance of intramolecular hydrogen bonding on the reactivity of tetrahydro diol epoxides (1978) (8)
- The synthesis of a porphyrin with a hydrocarbon encapsulated face (1991) (8)
- Effect of transfer from water to 1.0 M water in dimethyl sulfoxide on the reaction of nucleophiles with phenyl esters (1972) (8)
- Development of potential anticancer agents that target the telomere sequence. (2010) (8)
- Decarboxylated methoxatin analogs. Synthesis of 7- and 9-decarboxymethoxatin (1987) (8)
- Dioxygen transfer from 4a-hydroperoxyflavin anion. 3. Oxygen transfer to the 3-position of substituted indoles (1980) (8)
- Synthesis and DNA-binding studies of new cationic guanidine and betaineamide tetraphenylporphyrins (1991) (8)
- High- and low-potential flavin mimics (based on the pyrimidino[5,4-g]pteridine and imidazo[4,5-g]pteridine system). 1. General chemistry (1983) (8)
- Comparison of positively charged DNG with DNA duplexes: a computational approach. (2005) (8)
- Nature of the intermediate between 4a-hydroperoxyflavin and 4a-hydroxyflavin in the hydroxylation reaction of p-hydroxybenzoate hydroxylase. Synthesis of 6-aminopyrimidine-2,4,5(3H)-triones and the mechanism of aromatic hydroxylation by flavin monooxygenases (1981) (8)
- Computer simulations of trypanosomal nucleoside hydrolase: determination of the protonation state of the bound transition-state analogue. (2002) (8)
- High- and low-potential flavin mimics. 2. 3,7,10-Trimethyl-(1H,3H,5H,7H,9H,10H)-pyrimido[5,4-g]pteridine-2,4,6,8-tetrone dianion reduction of carbonyl, nicotinamides, and alkyl disulfide functional groups (1983) (7)
- Pendant-capped porphyrins. 2. Structural analysis and dynamics of the biphenyl pendant-capped porphyrin model of catalase and its iron(III) complex by one- and two-dimensional proton NMR spectroscopy and distance geometry/molecular modeling refinement (1993) (7)
- Electrophilicity of the 8 position of the isoalloxazine (flavine) ring system. Mechanism of oxidation of dihydroisoalloxazine (1974) (7)
- Flavin Oxygen Chemistry Brought to Date (1985) (7)
- The possibility that the spectrum of intermediate two, seen in the course of reaction of flavoenzyme phenol hydroxylases, may be attributable to iminol isomers of a flavin-derived 6-arylamino-5-oxo(3H,5H)uracil. (1984) (7)
- COMPARATIVE MECHANISMS OF REACTION OF K‐REGION AND NON‐K‐REGION ARENE OXIDES OF PHENANTHRENE (1974) (7)
- Imidazole Catalysis. IX.1 The Bell-shaped pH-Dependence of the Rate of Imidazole Catalysis of δ-Thiovalerolactone Hydrolysis (1962) (7)
- α-Ketoamides and α-Ketocarbonyls: Conformational analysis and development of all-atom OPLS force field (2000) (7)
- Electrochemical potentials and associated pKa values for the various oxidation states of a water-soluble, non .mu.-oxo dimer forming chromium tetraphenylporphyrin in aqueous solution (1991) (7)
- Replacement of methoxatin by 4,7-phenanthroline-5,6-dione and the inability of other phenanthroline quinones, as well as 7,9-di-decarboxy methoxatin, to serve as cofactors for the methoxatin-requiring glucose dehydrogenase of Acinetobacter calcoaceticus. (1985) (7)
- The acid-base properties and kinetics of dissolution of the Fe4S4 cores of Chromatin ferredoxin and high potential iron protein. (1975) (7)
- Kinetic study of the dissolution of Fe4S4(2-)-cluster core ions of ferredoxins and high potential iron protein. (1977) (7)
- Computational Approaches: Reaction Trajectories, Structures, and Atomic Motions. Enzyme Reactions and Proficiency (2006) (7)
- Reactions of tetranitromethane. II. Kinetics and products for the reactions of tetranitromethane with inorganic ions and alcohols (1971) (7)
- Effects of 1,7- and 1,10-phenanthroline dione on tissue culture cells. (1983) (7)
- The Preparation and Metal Complexing of 2-(2'-Pyridyl)-10-hydroxybenzo[h]quinoline-4-carboanilide (1957) (7)
- Synthesis of 9-Decarboxymethoxatin. Metal Complexation of Methoxatin as a Possible Requirement for Its Biological Activity. (1986) (7)
- O-vs.N-Attack of Hydroxylamine onn-Butyl Thiolacetate and the Establishment that N-Attack Passes through a Metastable Intermediate (1964) (7)
- An intramolecular model for an esteratic enzyme. (1958) (7)
- The proficiency of a thermophilic chorismate mutase enzyme is solely through an entropic advantage in the enzyme reaction. (2005) (7)
- Anionic nucleophilic attack upon a carboxyl anion (1969) (7)
- Aromatization of 4-carboxybenzene oxide (1974) (7)
- SOLUTION CHEMISTRY OF THE SYN‐ AND ANTI‐TETRAHYDRODIOL EPOXIDES, THE SYN‐ AND ANTI‐TETRAHYDRODIMETHOXY EPOXIDES, AND THE 1,2‐ AND 1,4‐TETRAHYDRO EPOXIDES OF NAPHTHALENE (1980) (6)
- Structural Features Which Determine the Carcinogenesis, Mutagenesis, and Rates of Acid- and Water-Mediated Solvolysis of and Nucleophilic Attack Upon Diol Epoxides, Bay-Region and Non-Bay-Region Tetrahydro Epoxides, and K-Region and N (1978) (6)
- Relative nucleophilicity of thiols and glutathione towards benzene oxide (1974) (6)
- Reactions of tetranitromethane. Mechanism of the reaction of tetranitromethane with pseudo acids. (1972) (6)
- The Imidazole-Catalyzed (Non-Metal Ion Mediated) Transamination of Phenylglycine by Pyridoxal. A Reaction Occurring at Ambient Temperatures by Way of Michaelis-Menten Kinetics (1962) (6)
- THE INTERCONVERSION OF THE 5,6,7,8-TETRAHYDRO-, 6,7,8-DIHYDRO-, AND RADICAL FORMS OF 6,6,7,7-TETRAMETHYLDIHYDROPTERIN. A MODEL FOR THE BIOPTERIN CENTER OF AROMATIC AMINO ACID MIXED FUNCTION OXIDASES (1985) (6)
- Intramolecular hydrolysis of a methyl ester by substrate bound metal hydroxide (1976) (6)
- The kinetic influence of increasing steric hindrance to metallation by zinc(II) which accompanies the inclusion of 5,10,15,20-meso (tetraphenyl) porphyrin into capped and quadruply bridged closely spaced bis-porphyrin structures (1996) (6)
- REACTION OF NITROXIDES WITH 1,5-DIHYDROFLAVINES AND N3,5-DIMETHYL-1,5-DIHYDROLUMIFLAVINE (1978) (6)
- Kinetic Evidence for the Formation of a Tetrahedral Intermediate in the Aqueous Solvolysis of Ethyl Trifluorothiolacetate (1964) (6)
- Nucleophilic catalysis of the aromatization of an arene oxide. Reaction of trimethylamine with 4-carb-o-tert-butoxybenzene oxide (1975) (6)
- Nucleophilic displacements upon phenyl esters in which the direct relationship between basicity of the leaving group and rate is determined by ground state conformations. A question of concerted catalysis in the hydrolysis of hexachlorophene esters (1974) (5)
- Diethyl oxaloacetate. Nonconcerted general catalysis of enolization, tertiary amine catalyzed enolization via an addition-elimination mechanism, and general-acid-catalyzed dehydration and cleavage (1978) (5)
- Mechanistic investigation of the oxidation of the carbanion of methyl 2-methoxy-2-phenylacetate by an isoalloxazine (1980) (5)
- Modes of acid catalysis in the aromatization of arene oxides (1976) (5)
- IONIC REACTIONS IN FROZEN AQUEOUS SYSTEMS. (1965) (5)
- Temperature dependence of the structure of the substrate and active site of the Thermus thermophilus chorismate mutase E x S complex. (2006) (5)
- RADICAL MECHANISMS FOR 1,5-DIHYDRO-5-METHYLFLAVINE REDUCTION OF CARBONYL COMPOUNDS (1975) (5)
- Rapid Enzyme-Catalyzed Heterolytic C−H Bond Cleavage by a Base Strength Amplification Mechanism: A Theoretical Examination of the Mechanism of Oxidation of Vitamin K (1998) (5)
- A convenient synthesis of the cytidyl 3′-terminal monomer for solid-phase synthesis of RNG oligonucleotides (2012) (5)
- THE CHEMISTRY AND BIOCHEMISTRY OF THE ACYL THIOLS (1961) (5)
- Metalloporphyrin-mediated radical cycloadditions of p-cyano-N,N-dimethylaniline (1986) (5)
- Formation and Alkene Epoxidation by Higher-Valent Oxo-Metalloporphyrins (1993) (5)
- Determination of the kinetic pKa of a flavin 4a-pseudobase from a study of the hydrolysis of 4a-hydroxy-5-ethyl-3-methyl-lumiflavin in H2O. The oxygen donation potential of 4a-hydroperoxyflavins (1984) (5)
- The reaction of nucleophilic species with quinonoid 6,6,7,7-tetramethyldihydropterin (1986) (5)
- 3,3-Diphenylglutaric Acid. A Novel Carbanion Condensation Reaction (1963) (5)
- Relevance of the reaction of a manganese(III) chelate with hydroxide ion to photosynthesis: Reaction of hydroxide ion with 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphinatomanganese(III) in ligating and nonligating solvents. (1988) (4)
- Microgonotropens and Their Interactions with DNA. Part 2. Quantitative Evaluation of Equilibrium Constants for 1:1 and 2:1 Binding of Dien- Microgonotropen-a, -b, and -c as Well as Distamycin and Hoechst 33258 to d(GGCGCAAATTTGGCGG)/d(CCGCCAAATTTGCGCC). (1993) (4)
- Aminolysis of esters. VII. The reaction of lysine with phenyl acetate and triacetin. (1967) (4)
- Synthesis and Characterization of the First Water-Soluble Closely Interspaced Cofacial Porphyrin Dimer. (1991) (4)
- Stopped-Flow Apparatus for a Zeiss PMQ II Spectrophotometer (1965) (4)
- Products of the decomposition of the anion of a 4a-hydroperoxyisoalloxazine hindered in the 9a and 10a positions (1980) (4)
- Computational enzymology. (2000) (4)
- An investigation of the ionic and solvation patterns of dsDNG versus dsDNA by use of molecular dynamics simulations. (2007) (4)
- HYDROLYSIS OF A PHOSPHATE DIESTER BY SIMULTANEOUS CARBOXYLATE AND CARBOXYLGROUP PARTICIPATION IN A RIGID SYSTEMS WITH KINETICALLY UNFAVORABLE ROTAMER S FROZEN OUT (1995) (4)
- Chiral recognition of a prochiral (meso-carbon) centre by Λ(–)436-α-l,l-2,9-diamino-4,7-diazadecanecobaltate (1973) (4)
- Carbon–carbon double bond formation accompanying hydride transfer from a carbanion to 5-carbalumiflavin (1984) (4)
- 5 vs. 4a Addition to isoalloxazines (1972) (4)
- Oxidations by a 4a-hydroperoxyisoalloxazine hindered in the 9a and 10a positions (1979) (4)
- Effect of Self-Association on the Spectrophotometric Determination of Association Constants. A Computational Analysis (1966) (4)
- Kinetic study of the fate of a covalent intermediate of the type proposed to be involved in flavin catalysis (1974) (4)
- Propensity toward formation of higher aggregates in anionic and cationic iron tetraphenylporphyrin μ-oxo dimers: evidence from 1H and 13C NMR spectroscopy (1992) (4)
- DNA sequence recognition in the minor groove by hairpin microgonotropens. (2006) (4)
- KINETICS AND MECHANISMS OF THE 1,5-DIHYDROFLAVIN REDUCTION OF CARBONYL COMPOUNDS AND THE FLAVIN OXIDATION OF ALCOHOLS. 4. INTERCONVERSION OF FORMALDEHYDE AND METHANOL (1977) (4)
- Planarity as a factor in determining the rate constant and mechanism of acetal hydrolysis (1970) (4)
- N-nitrosodialkylamines do not function as substrates for liver monoamine oxidase. (1985) (4)
- SYNTHESIS AND EVALUATION OF A MODEL FOR THE SO-CALLED ′CHARGE-RELAY′ SYSTEM OF THE SERINE ESTERASES (1974) (4)
- Identifying the Intermediate in the Dioxygen Transfer from 4a-Hydroperoxyflavin Anion to Phenolate and Indole Anions☆ (1997) (3)
- Hydride vs. electron transfer in the oxidation of NADH model compounds. (1988) (3)
- CHIRAL RECOGNITION OF PROCHIRAL CENTERS, THE (2S,9S)-2,9-DIAMINO-4,7-DIAZADECANECOBALT(III) MEDIATED DECARBOXYLATION OF AMINOALKYLMALONIC ACIDS (1974) (3)
- Carbon Acid Oxidations and Oxygen Activation by Flavins (1980) (3)
- ELECTROPHILICITY OF THE 8 POSITION OF THE ISOALLOXAZINE (FLAVINE) RING SYSTEM, COMMENT ON THE MECHANISM OF OXIDATION OF DIHYDROISOALLOXAZINE (1974) (3)
- Oxygen Donation to Manganese(III) Tetraphenylporphyrin Chloride. Low Reactivity of Hydroperoxides as Oxygen Donors to Manganese(III) Porphyrins. (1985) (3)
- A Kinetic Study of the Reaction of a “Meso-ionic” Compound (Dehydrodithizone) with Haloacetates (1961) (3)
- Alpha-ketoamides and alpha-ketocarbonyls: conformational analysis and development of all-atom OPLS force field. (2000) (3)
- Mechanistic change from (ElcB)R to (ElcB)i brought about by a sterically bulky substituent in ester hydrolysis (1986) (3)
- Dependence of the rates of dissolution of the Fe4S4 clusters of Chromatium vinosum high-potential iron protein and ferredoxin on cluster oxidation state. (1977) (3)
- Chromophoric lactones and the mechanism of chymotrypsin action. (1970) (3)
- Isoalloxazine (flavin) dehydrogenation of dimethyl trans-1,2-dihydrophthalate (1972) (3)
- An Improved Synthesis of 2,4-Diacetoxymercurianiline (1950) (3)
- Nucleophilic selectivity in attack at amide bonds. Reactivity of oxygen and nitrogen nucleophiles with N-acetyldehydrophenylalanyl-L-proline diketopiperazine. (1972) (3)
- NMR structure of d(CGCA3T3GCG)2:tren-microgonotropen-b:Zn(II) complex and solution studies of metal ion complexes of tren-microgonotropen-b interacting with DNA. (1995) (3)
- Both Edema and Leakage Are Expressed and Are Separable in Long-Term Experimental CNV via Sustained Simultaneous Release of VEGF and bFGF Within the Suprachoroidal Space Through Transcleral Implantation of a Delivery Device (2008) (3)
- Molecular mechanics calculations of the riboacetal internucleotide linkage in double and triple helices. (1996) (3)
- A NEW “META” ANALOG OF THYROXINE (1954) (3)
- The Mechanism of Hydroperoxide O‐O Bond Scission on Reaction of Hydroperoxides with Iron(III) Porphyrins. (1989) (3)
- Envisioning the Loop Movements and Rotation of the Two Subdomains of Dihydrofolate Reductase by Elastic Normal Mode Analysis (2009) (3)
- [88] Acyl imidazoles (1963) (2)
- High- and Low-Potential Flavin Mimics. Part 3. 3,7,10-Trimethyl-(1H,3H,5H,7H,9H,10H)-pyrimido[5,4-g]pteridine-2,4,6,8-tetrone-Mediated Reduction of Carbon - Carbon Double Bonds α - β to an Acyl Function. (1986) (2)
- Opening of a cyclopropyl ring in (diphenylcyclopropyl)alkenes promoted by electron transfer from potassium 4,4'-di-tert-butylbiphenyl radical anion and x-ray and theoretical calculations of the structure of (Z)-1,2-bis(trans-2,trans-3-diphenylcyclopropyl)ethene (1993) (2)
- Characterization and one- and two-electron redox chemistry of 1,5-dicarba-1,5-dideazaisoalloxazines (flavins) (1978) (2)
- Design, synthesis, and characterization of a novel hexa-azacyclophane and interactions with d(CGCA3T3GCG)2, ctDNA and T4DNA (1997) (2)
- The Mechanisms of Oxygen Transfer from Acyl and Alkyl Hydroperoxides to Metal(III) Porphyrins and the Epoxidation of Alkenes by the Resultant Hypervalent Metal-Oxo Porphyrin Products (1989) (2)
- AROMATIZATION OF 4‐CARBOXYBENZENE OXIDE (1974) (2)
- HOMOLYTIC AND HETEROLYTIC OXYGEN-OXYGEN BOND SCISSIONS ACCOMPANYING OXYGEN TRANSFER TO IRON(III) PORPHYRINS BY PERCARBOXYLIC ACIDS AND HYDROPEROXIDES. A MECHANISTIC CRITERION FOR PEROXIDASE AND CYTOCHROME P-450 (1985) (2)
- Intramolecular catalysts in the aminolysis of thiol esters (1972) (2)
- The reaction of ribonuclease-A with o-nitrophenyl hydrogen oxalate. (1967) (2)
- THE IMIDAZOLE-IMIDAZOLIUM ION CONCERTED GENERAL ACID, GENERAL BASE CATALYSIS OF THE TRANSAMINATION OF PYRIDOXAL BY α-AMINOPHENYLACETIC ACID (1963) (2)
- Syntheses of Quadruply Two- and Three-Atom, Aza-Bridged, Cofacial Bis( 5,10,15,20-tetraphenylporphyrins). (1991) (2)
- High- and low-potential flavin mimics. 3. 3,7,10-Trimethyl-(1H,3H,5H,7H,9H,10H)-pyrimido[5,4-g]pteridine-2,4,6,8-tetrone-mediated reduction of carbon-carbon double bonds .alpha.,.beta. to an acyl function (1986) (2)
- Comparison of formation of reactive conformers for the SN2 displacements by CH3CO\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \setlength{\oddsidemargin}{-69pt} \begin{document} \begin{equa (2003) (2)
- Redox reactions of a tetrahydro- or hexahydropyrido[2,3-d:6,5-d']dipyrimidine tetrone couple. A high- vs. low-potential 5-carba-5-deazaflavin mimic (1984) (2)
- SYNTHESIS OF 7,9-DIDECARBOXYMETHOXATIN (4,5-DIHYDRO-4,5-DIOXO-1H-PYRROLO(2,3-F)QUINOLINE-2-CARBOXYLIC ACID) AND COMPARISON OF ITS CHEMICAL PROPERTIES WITH THOSE OF METHOXATIN AND ANALOGOUS O-QUINONES. MODEL STUDIES DIRECTED TOWARD THE (1985) (2)
- Experimental CNV After Transcleral Implantation of VEGF/bFGF-Implant Within the Suprachoroidal Space for Defining Potential Long-Term Synergistic Actions of Ranibizumab (Lucentis) With Small Low Cost Molecules in Ameliorating Wet AMD (2008) (2)
- Temperature-dependent structure of the E x S complex of Bacillus stearothermophilus alcohol dehydrogenase. (2007) (2)
- Stabilization of carbinylcarbocation by and nucleophilic attack upon cyclopropyl and trans-2, trans-3-diphenylcyclopropyl rings. Reduction of (trans-2, trans-3-diphenylcyclopropyl)methanol and (trans-2, trans-3-diphenylcyclopropyl)cyclopropylmethanol (1992) (2)
- Structural Properties of Hybrid Triplex of Polycation Deoxyribonucleic S-methylthiourea (DNmt) Strands with a Complementary DNA Strand, Probed by Nanosecond Molecular Dynamics (2000) (2)
- Microgonotropens and Their Interactions with DNA. Part 3. Structural Analysis of the 1:1 Complex of d(CGCAAATTTGCG)2 and Dien- Microgonotropen-c by 2D NMR Spectroscopy and Restrained Molecular Modeling. (1993) (2)
- Rates and equilibrium constants of imine formation with pyridine-4-aldehyde and various amino acids. (1964) (1)
- Additions and Corrections - Nucleophilic Micelles. II. The Effect on the Rate of Solvolysis of Neutral, Positively, and Negatively Charged Esters of Varied Chain Length when Incorporated into Nonfunctional and Functional Micelles of Neutral, Positive, and Negative Charges (1968) (1)
- Utility Of Dual Electrochemical Gsh And Gssh Evaluation And Other Redox/detoxification Quantitation As Functional Parameters In Assessment Of Retinal Toxicity During In Vivo Drug Studies With Large Animal Eyes (2012) (1)
- Chemistry of Phosphodiesters, DNA and Models. Part 2. The Hydrolysis of Bis(8-hydroxyquinoline) Phosphate in the Absence and Presence of Metal Ions (1992) (1)
- The Structures of the Enzyme–Substrate Complex and Transition State Formed in the SN2 Displacement of Cl−from 1,2-Dichloroethane at the Active Site ofXanthobacter autotrophicusHaloalkane Dehalogenase (1998) (1)
- The Acid-Base Properties, Hydrolytic Mechanism, and Susceptibility to O(2) Oxidation of Fe(4)S(4)(SR)(4) Clusters. (1975) (1)
- Additions and Corrections - 4a-Hydroperoxyflavin N-Oxidation of Tertiary Amines (1979) (1)
- The Formation of Thiiranes from Olefins in the Course of the Deoxygenation of Tertiary Amine N-Oxides by Carbon Disulfide. (1986) (1)
- THE CHEMISTRY OF 1,5-DIBLOCKED FLAVIN. 1. INTERCONVERSION OF THE REDUCED, RADICAL, AND OXIDIZED FORMS OF 1,10-ETHANO-5-ETHYLLUMIFLAVIN (1984) (1)
- Additions and Corrections - Chiral Recognition of Prochiral Centers. The (2S,9S)-2,9-Diamino-4,7-diazadecanecobalt(III) Mediated Decarboxylation of Aminoalkylmalonic Acids (1974) (1)
- Oxygen Transfer from p-Cyano-N,N-dimethylaniline N-Oxide to the μ-Oxo Dimer of (meso-Tetraphenylporphinato)iron(III). (1988) (1)
- The Synthesis of a Porphyrin with a Hydrocarbon Encapsulated Face. (1992) (1)
- REDOX REACTIONS OF A TETRAHYDRO- OR HEXAHYDROPYRIDO(2,3-D:6,5-D′)DIPYRIMIDINE TETRONE COUPLE. A HIGH- VS. LOW-POTENTIAL 5-CARBA-5-DEAZAFLAVIN MIMIC (1984) (1)
- Kinetics and Mechanisms of Oxygen Transfer in the Reaction of p-Cyano-N,N-dimethylaniline N-Oxide with Metalloporphyrin Salts. (1986) (1)
- NMR structure of d(CGCA3T3GCG)2:tren-microgonotropen-b:Zn(II) complex and solution studies of metal ion complexes of tren-microgonotropen-b interacting with DNA. (1995) (1)
- An intramolecular acyl transfer reaction limited by substrate isomerization (1971) (1)
- Dioxygen Transfer from 4a-Hydroperoxyflavin Anion to Isomeric Aminophenolates (1990) (1)
- Mechanisms of Reaction of Hypervalent Oxochromium, Iron, and Manganese Tetraphenylporphyrins with Alkenes (1995) (1)
- Structural features which determine the carcinogenesis, mutagenesis, and rates of acid- and water-mediated solvolysis of and nucleophilic attack upon diol epoxides, bay-region and non-bay-region tetrahydro epoxides, and K-region and non-K-region arene oxides (1978) (1)
- Intramolecular catalysis and the mechanism of chymotrypsin action. (1962) (1)
- OXIDATION OF N-NITROSODIBENZYLAMINE AND RELATED COMPOUNDS BY METALLOPORPHYRIN-CATALYZED MODEL SYSTEMS FOR THE CYTOCHROME P450 DEPENDENT MONO-OXYGENASES (1984) (1)
- DIFFERENTIATION BETWEEN CRIEGEE REARRANGEMENT AND DIOXETANE REARRANGEMENT MECHANISMS FOR THE DECOMPOSITION OF α,β-UNSATURATED HYDROPEROXIDES (1981) (1)
- Chemiluminescent reactions and electrophilic oxygen donating ability of 4 a-hydroperoxyflavins : General synthetic method for the preparation of N 5-alkyl-1 , 5-dihydroflavins ( N 5-alkyl flavin mononucleotides / bacterial luciferase ) (1)
- The cyanolysis of ethyl thiolacetate (1969) (1)
- THE MECHANISMS OF ACYL GROUP TRANSFER FROM A TETRAHEDRAL INTERMEDIATE (1974) (0)
- The Synthesis and DNA/RNA Hybridization Properties of DNG, a Putative Antisense Agent with an Attractive Polycationic Guanidinium Backbone (1996) (0)
- Oxidation of (Tetraphenylporphyrin)chromium(III) Chloride by Styrene Ozonide. (1987) (0)
- A SYNTHETIC TETRANUCLEAR IRON-SULFUR COMPLEX WITH IONIZED SIDE CHAINS- THE CRYSTAL STRUCTURE OF (FE4S4(S(CH2)2COO)4)6-.(NA5.N(C4H9)4)6+.5C5H9NO (1977) (0)
- Stabilization of Carbinylcarbocation by and Nucleophilic Attack Upon Cyclopropyl and trans-2, trans-3-Diphenylcyclopropyl Rings. Reduction of (trans-2, trans-3-Diphenylcyclopropyl)methanol and (trans-2, trans- 3-Diphenylcyclopropyl)cyclopropylmethanol. (1992) (0)
- Kinetics and Mechanism of Oxygen Transfer in the Reaction of p-Cyano-N,N-dimethylaniline N-Oxide with Metalloporphyrin Salts. Part 5. The Influence of Imidazole Ligation of (meso-Tetrakis(2,6-dimethylphenyl)porphinato)manganese(III) C (1987) (0)
- Porphyrin iron (III) mixed function oxidases: an evolutionary endpoint for transition metal (III) reactions with oxygen donors. (1987) (0)
- The Kinetics for the Reaction of Hypochlorite with a Manganese(III) Porphyrin and Subsequent Epoxidation of Alkenes in a Homogeneous Solution. (1989) (0)
- Catalysis by lmidazole and by the Imidazol-4-ylacetate Ion in the Hydrolysis of Aryl Acetates (2016) (0)
- Solvation as the determining factor for the redox potential of Fe4S4[S–(CH2)nCO2]6– cluster ions (1978) (0)
- Recognition in the Minor Groove of Double‐Stranded DNA by Microgonotropens (2002) (0)
- STUDY OF (TETRAPHENYLPORPHINATO)MANGANESE(III)-CATALYZED EPOXIDATION AND DEMETHYLATION USING P-CYANO-N,N-DIMETHYLANILINE N-OXIDE AS OXYGEN DONOR IN A HOMOGENEOUS SYSTEM. KINETICS, RADIOCHEMICAL LIGATION STUDIES, AND REACTION MECHANISM (1984) (0)
- Concerning leT transfer in reduction by dihydronicotinamide : Reaction of oxidized flavin and flavin radical with N-benzyl-1 , 4-dihydronicotinamide ( hydride / redox ) (0)
- Intermediates in the Epoxidation of Alkenes by Cytochrome P-450 Models. Part 1. cis-Stilbene as a Mechanistic Probe. (1988) (0)
- EVIDENCE FOR AN INTERMEDIATE ADDUCT IN THE ETHYLENDIAMINETETRAACETIC ACID MEDIATED PHOTOREDUKTION OF FLAVINES (1974) (0)
- THE MECHANISM OF FLAVIN 4A SUBSTITUTION WHICH ACCOMPANIES PHOTOLYTIC DECARBOXYLATION OF α-SUBSTITUTED ACETIC ACIDS. CARBANION VS. RADICAL INTERMEDIATES (1980) (0)
- Epoxidation of Alkenes by Oxo(5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato)chromium(V) in Aqueous Solution. (1990) (0)
- NATURE OF THE INTERMEDIATE BETWEEN 4A-HYDROPEROXYFLAVIN AND 4A-HYDROXYFLAVIN IN THE HYDROXYLATION REACTION OF P-HYDROXYBENZOATE HYDROXYLASE. SYNTHESIS OF 6-AMINOPYRIMIDINE-2,4,5(3H)-TRIONES AND THE MECHANISM OF AROMATIC HYDROXYLATION (1982) (0)
- Kinetics and Mechanism of Oxygen Transfer in the Reaction of p-Cyano-N,N-dimethylaniline N-Oxide with Metalloporphyrin Salts. Part 6. Oxygen Atom Transfer to and from the Iron(III) C2cap Porphyrin of Baldwin. (1987) (0)
- SYNTH. VON 2-OXA-BICYCLO(2,2,2)OCTAN (1970) (0)
- MECHANISM FOR CHIRAL RECOGNITION OF A PROCHIRAL CENTER AND FOR AMINO ACID COMPLEXATION TO A COBALT(III) TETRAMINE,THE CRYSTAL STRUCTURE,ABSOLUTE CONFIGURATION,AND CIRCULAR DICHROISM OF LAMBDA(‐)436‐BETA(2)‐((2S,9S)‐2,9‐DIAMINO‐4,7‐DIAZADECANE‐COBALT(III)‐AMINOMETHYLMALONATE) PERCHLORATE MONOHYDRATE (1974) (0)
- Radical Intermediates in the Epoxidation of Alkenes by Cytochrome P-450 Model Systems. The Design of a Hypersensitive Radical Probe. (1988) (0)
- Oxidation of Aminophenols by 4a-Hydroperoxy-5-ethyllumiflavin Anion. Flavoenzyme Hydroxylase Mechanism. (1990) (0)
- • Correlations between Enzyme Catalysis, Heterogeneous Catalysis and Homogeneous Catalysis • New Methods of Catalyst Synthesis • Characterization of Catalysts under Reaction Conditions • Global Catalytic Processes (2001) (0)
- INTRAMOLECULAR CATALYSIS OF ESTER HYDROLYSIS BY METAL COMPLEXED HYDROXIDE ION. ACYL OXYGEN BOND SCISSION IN COBALT(2+) AND NICKEL(2+) CARBOXYLIC ACI COMPLEXES (1977) (0)
- A KINETIC STUDY OF THE FATE OF A COVALENT INTERMEDIATE OF THE TYPE PROPOSED TO BE INVOLVED IN FLAVIN CATALYSIS (1974) (0)
- Oxygen Transfer Involving Non-Heme Iron. The Reaction of (EDTA)Fe(III) with m-Chloroperbenzoic Acid. (1987) (0)
- Catalase Modeling. Part 2. Dynamcis of Reaction of a Water-Soluble and Non μ-Oxo Dimer Forming Manganese(III) Porphyrin with Hydrogen Peroxide. (1988) (0)
- Transition-State Geometry in Epoxidation by Iron-Oxo Porphyrin at the Compound I Oxidation Level. Epoxidation of Alkenes Catalyzed by a Sterically Hindered (meso-Tetrakis(2,6-dibromophenyl)porphinato)iron(III) Chloride (1989) (0)
- The Synthesis of Chemiluminescent Flavoabzymes and Their Use in Metal Ion Detection (1992) (0)
- Design, Synthesis, and Characterization of a Novel Hexaazacyclophane and Interactions with d(CGCA3T3GCG)2, ctDNA and T4DNA. (1997) (0)
- Kinetics and Mechanism of Oxygen Transfer in the Reaction of p-Cyano-N,N-dimethylaniline N-Oxide with Metalloporphyrin Salts. Part 7. Oxygen Atom Transfer to and from (meso-Tetrakis(pentafluorophenyl)porphinato)iron(III) Chloride. (1987) (0)
- Dual and Simultaneous Roles of Nucleophillic Delivery. (1999) (0)
- Metalloporphyrin-Mediated Radical Cycloadditions of p-Cyano-N,N-dimethylaniline. (1987) (0)
- Dynamics of the Reaction of Hydrogen Peroxide with a Water Soluble Non μ-Oxo Dimer Forming Iron(III) Tetraphenylporphyrin. Part 2. The Reaction of Hydrogen Peroxide with 5,10,15,20-Tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinatoiro (1990) (0)
- DNG and RNG Phylogenetic Single Cell Probes. (1999) (0)
- Electrochemical Generation of Iron(IV)-Oxo Porphyrins and Iron(IV)-Oxo Porphyrin π Cation Radicals. (1987) (0)
- Mechanistic Change from (ElcB)R to (ElcB)i Brought About by a Sterically Bulky Substituent in Ester Hydrolysis. (1986) (0)
- The preparation and study of a low potential flavin analog (1982) (0)
- 1H NMR Investigation of Iron(III) 5,10,15,20-Tetrakis(2,6-disubstituted phenyl)porphyrins. Isolation and Characterization of Hydroxy-Ligated (5,10,15,20-Tetrakis(2,6-difluorophenyl)porphinato)iron(III). (1987) (0)
- THE CHEMISTRY OF AN N5-METHYL-1,5-DIHYDROFLAVIN AND ITS AMINIUM CATION RADICAL (1976) (0)
- THE CHEMISTRY OF AN ELECTRON‐DEFICIENT 5‐DEAZAFLAVIN. 8‐CYANO‐10‐METHYL‐5‐DEAZAISOALLOXAZINE (1978) (0)
- The Kinetics and Mechanisms of Oxygen Transfer in the Reaction of p-Cyano-N,N-dimethylaniline N-Oxide with Metalloporphyrin Salts. Part 4. Catalysis by meso-(Tetrakis(2,6-dimethylphenyl)porphinato)iron(III) Chloride. (1986) (0)
- Additions and Corrections - Catalytic Reactions Involving Azomethines. VIII. Water and Alanine Catalysis of the Transamination of 3-Hydroxypyridine-4-aldehyde by Alanine (1967) (0)
- Influence of Steric Effects upon the Rate Constants for Competing BAC2 and E1cB Ester Hydrolyses. (1984) (0)
- The Dynamics of Reaction of a Water-Soluble and Non-μ-Oxo Dimer Forming Iron(III) Porphyrin with tert.-Butyl Hydroperoxide in Aqueous Solution. Part 1. Studies Using a Trap for Immediate Oxidation Products. (1989) (0)
- Bicyclo(2.2.2)octane-Capped Porphyrins. Part 1. Synthesis, Characterization, and Solution Three-Dimensional Structure. (1992) (0)
- Radical Mechanisms for1,5-Dihydroflavi n Reduction ofCarbonyl Compounds (1975) (0)
- Mechanism of the solvolysis of 4-(2′-acetoxyphenyl)imidazole (1968) (0)
- Studies on the Radical Species of 9-Decarboxymethoxatin. (1987) (0)
- The Dual and Simultaneous Roles of Nucleophilic Delivery and Assistance of Leaving Group Departure by Metal Ions in Phosphate Transfer from Phosphate Diesters (1993) (0)
- NUCLEOPHILIC DISPLACEMENTS UPON PHENYL ESTERS IN WHICH THE DIRECT RELATIONSHIP BETWEEN BASICITY OF THE LEAVING GROUP AND RATE IS DETERMINED BY GROUND STATE CONFORMATIONS, A QUESTION OF CONCERTED CATALYSIS IN THE HYDROLYSIS OF HEXACHLO (1974) (0)
- Synthesis and DNA-Binding Studies of New Guanidine and Betaineamide Tetraphenylporphyrins (I). (1992) (0)
- A Kinetic Study of the Epoxidation of 2,3‐Dimethyl‐2‐butene by tert‐Butyl Hydroperoxide Catalyzed by Imidazole Ligated (meso‐Tetraphenylporphinato)manganese(III). (1987) (0)
- Oxygen Transfer from Percarboxylic Acids and Alkyl Hydroperoxides to (meso-Tetraphenylporphinato)iron(III) and -chromium(III). (1988) (0)
- Influence of Nitrogen Base Ligation and Hydrogen Bonding on the Rate Constants for Oxygen Transfer from Percarboxylic Acids (I) and Alkyl Hydroperoxides (II) to (meso-Tetraphenylporphinato)manganese(III) Chloride (1986) (0)
- Decarboxylated Methoxatin Analogues. Synthesis of 7- (Ia) and 9-Decarboxymethoxatin (Ib). (1987) (0)
- RING STRAIN AND GENERAL ACID CATALYSIS OF ACETAL HYDROLYSIS, LYSOZYME CATALYSIS (1974) (0)
- THE QUESTION OF COVALENT INTERMEDIATE FORMATION IN THE FLAVINE-CATALYZED CARBONYL TO CARBINOL OXIDATION-REDUCTION REACTION (1974) (0)
- Microgonotropens and Their Interactions with DNA. Part 1. Synthesis of the Tripyrrole Peptides Dien‐Microgonotropen‐a, ‐b, and ‐c and Characterization of Their Interactions with dsDNA. (1993) (0)
- Simultaneous sustained release of VEGF and bFGF from a non-biodegradable implant in the supra-choroidal space induces experimental choroidal neovascularization in both New Zealand white and Dutch belt rabbits. (2015) (0)
- Participation of Two Carboxyl Groups in Phosphodiester Hydrolysis. 1. Hydrolysis of Bis(2-carboxyphenyl) Phosphate J. Am. Chem. Soc. 1995, 117, 12064−12069 (1996) (0)
- Intermediates in the Epoxidation of Alkenes by Cytochrome P-450 Models. Part 2. Use of the trans-2,trans-3-Diphenylcyclopropyl Substituent in a Search for Radical Intermediates. (1989) (0)
- CHANGES IN THE CHEMISTRY OF AN ISOALLOXAZINE BROUGHT ABOUT BY SUBSTITUTION AT THE 7 AND 8 POSITIONS BY A STRONGLY ELECTRONEGATIVE SUBSTITUENT (1977) (0)
- Analyzing enzyme dynamics 1092 Lab yeast evolves faster 1181 What you see is what you hear 1205 No go for the Nogo receptor 1252 Eliminating patents to increase innovation ? (2005) (0)
- Synthesis and Characterization of a meso-Tetrakis(4-ferrocenylphenyl)porphyrin and Examination of Its Ability to Undergo Intramolecular Photocatalyzed Electron Transfer. (1987) (0)
- The Reaction of 5,10,15,20-Tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinatoiron(III) Hydrate with Alkyl and Acyl Hydroperoxides. The Dynamics of Reaction of Water-Soluble and Non μ-Oxo Dimer Forming Iron(III) Porphyrins in Aqueous S (1990) (0)
- First Synthesis of a Pendant-Capped Porphyrin. A Biphenyl Pendant-Capped Porphyrin Model (VII) of Catalase. (1990) (0)
- ADDITION IN 5- BZW. 4A-STELLUNG IN ISOALLOXAZINEN (1973) (0)
- SYNTHESIS OF GEM-DISUBSTITUTED THIAZOLINES (1962) (0)
- Reaction of Methoxatin and 9-Decarboxymethoxatin with Benzylamine. Dynamics and Products. (1990) (0)
- The influence of electron delocalization on the rate constants for competing BAc2 and E1cb ester hydrolyses (1981) (0)
- CHEMILUMINESCENCE DERIVED FROM 4a-(ALKYLPEROXY) FLAVINS (1981) (0)
- Synthesis of a Spheroidal Bis-porphyrin: A Ligand Designed to Accept Two Catalytic Metal Ions in an Isolated Environment. (1995) (0)
- Oxidation of 3-Phenoxymesitol (1958) (0)
- INTRAMOLECULAR GENERAL BASE CATALYZED HYDROLYSIS AND TERTIARY AMINE NUCLEOPHILIC ATTAC VERSUS GENERAL BASE CATALYZED HYDROLYSIS OF SUBSTITUTED PHENYL QUINOLINE-8- AND -6-CARBOXYLATES (1974) (0)
- CHEMILUMINESCENCE ACCOMPANYING THE DECOMPOSITION OF 4A-FLAVIN ALKYL PEROXIDE. MODEL STUDIES OF BACTERIAL LUCIFERASE (1978) (0)
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